Contents list for Chemical Communications, issue 5, 2004
Front Cover
Focus
Medicinal chemistry in academia: molecular recognition with biological receptors
Fraser Hof and François Diederich,
Chem. Commun., 2004, 477
DOI: 10.1039/b314081b
Feature Article
Iron oxide chemistry. From molecular clusters to extended solid networks
Jean-Pierre Jolivet, Corinne Chanéac and Elisabeth Tronc,
Chem. Commun., 2004, 481
DOI: 10.1039/b304532n
Communications
A
monomolecularly imprinted dendrimer (MID) capable of selective binding
with a tris(2-aminoethyl)amine guest through multiple functional group
interactions
James B. Beil and Steven C. Zimmerman,
Chem. Commun., 2004, 488
DOI: 10.1039/b316248f
Self-assembly of heteroleptic [2 × 2] and [2 × 3] nanogrids
Michael Schmittel, Venkateshwarlu Kalsani, Dieter Fenske and Andreas Wiegrefe,
Chem. Commun., 2004, 490
DOI: 10.1039/b312807e
A host–guest complex between a metal–organic cyclotriveratrylene analog and a polyoxometalate: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40(M = Mo or W)
Jacqueline M. Knaust, Chad Inman and Steven W. Keller,
Chem. Commun., 2004, 492
DOI: 10.1039/b309255k
Synthesis and X-ray single crystal structure of a bivalent glycocluster
Manuela Tosin, Helge Müller-Bunz and Paul V. Murphy,
Chem. Commun., 2004, 494
DOI: 10.1039/b313934d
A ratiometric fluorescent probe for imaging hydroxyl radicals in living cells
Nobuaki Soh, Koji Makihara, Emino Sakoda and Toshihiko Imato,
Chem. Commun., 2004, 496
DOI: 10.1039/b314204c
The
influence of solvation on short strong hydrogen bonds: a density
functional theory study of the Asp-His interaction in subtilisins
Birgit Schiøtt,
Chem. Commun., 2004, 498
DOI: 10.1039/b314228k
Confined organization of Au nanocrystals in glycolipid nanotube hollow cylinders
Bo Yang, Shoko Kamiya, Kaname Yoshida and Toshimi Shimizu,
Chem. Commun., 2004, 500
DOI: 10.1039/b313100a
Self-indicating amine scavenger resins
Jin Ku Cho, Peter D. White, Wolfgang Klute, Tony W. Dean and Mark Bradley,
Chem. Commun., 2004, 502
DOI: 10.1039/b315426b
From metal to ligand electroactivity in nickel(II) oxamato complexes
Xavier
Ottenwaelder, Rafael Ruiz-García, Geneviève Blondin, Rosa Carasco, Joan
Cano, Doris Lexa, Yves Journaux and Ally Aukauloo, Chem. Commun., 2004, 504
DOI: 10.1039/b312295f
Influence of substrate on self-assembled photonic crystal
Sachiko I. Matsushita and Masatsugu Shimomura,
Chem. Commun., 2004, 506
DOI: 10.1039/b313410e
Highly substituted pyridines via tethered imine–enamine (TIE) methodology
Steven A. Raw and Richard J. K. Taylor,
Chem. Commun., 2004, 508
DOI: 10.1039/b316107b
Total synthesis of (+)-belactosin A
Alan Armstrong and James N. Scutt,
Chem. Commun., 2004, 510
DOI: 10.1039/b316142k
Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations
Max J. Cryle, Julia M. U. Stuthe, Paul R. Ortiz de Montellano and James J. De Voss,
Chem. Commun., 2004, 512
DOI: 10.1039/b315911f
The Sonogashira coupling reaction catalyzed by ultrafine nickel(0) powder
Lei Wang, Pinhua Li and Yicheng Zhang,
Chem. Commun., 2004, 514
DOI: 10.1039/b314246a
Nucleic acid binding properties of thyminyl and adeninyl pyrrolidine-amide oligonucleotide mimics (POM)
T. H. Samuel Tan, David T. Hickman, Jordi Morral, Ian G. Beadham and Jason Micklefield,
Chem. Commun., 2004, 516
DOI: 10.1039/b315768g
Controlled functionalization of gold nanoparticles through a solid phase synthesis approach
James G. Worden, Andrew W. Shaffer and Qun Huo,
Chem. Commun., 2004, 518
DOI: 10.1039/b312819a
VIII(OH){O2C–C6H4–CO2}.(HO2C–C6H4–CO2H)x(DMF)y(H2O)z(or
MIL-68), a new vanadocarboxylate with a large pore hybrid topology :
reticular synthesis with infinite inorganic building blocks?
K. Barthelet, J. Marrot, G. Férey and D. Riou,
Chem. Commun., 2004, 520
DOI: 10.1039/b312589k
Electrospray mass spectrometry of undiluted ionic liquids
Glen P. Jackson and Douglas C. Duckworth,
Chem. Commun., 2004, 522
DOI: 10.1039/b314754a
Surface energy and surface area measurements by 19F MAS NMR of adsorbed trifluoroacetic acid
Vitaliy L. Budarin, James H. Clark and Stewart J. Tavener,
Chem. Commun., 2004, 524
DOI: 10.1039/b315005d
Carbon nanotube conducting arrays by consecutive amidation reactions
Dae-Hwan Jung, Myung Sup Jung, Young Koan Ko, Seung Joo Seo and Hee-Tae Jung,
Chem. Commun., 2004, 526
DOI: 10.1039/b315348g
Preparation of highly accessible mordenite coatings on ceramic monoliths at loadings exceeding 50% by weight
M. A. Ulla, E. Miro, R. Mallada, J. Coronas and J. Santamaría,
Chem. Commun., 2004, 528
DOI: 10.1039/b315386j
Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P–C cross-coupling
Christian Korff and Günter Helmchen,
Chem. Commun., 2004, 530
DOI: 10.1039/b315009g
Nickel-catalyzed
highly chemoselective cocyclotrimerization of arynes with allenes: a
novel method for 10-methylene-9,10-dihydrophenanthrenes
Jen-Chieh Hsieh, Dinesh Kumar Rayabarapu and Chien-Hong Cheng,
Chem. Commun., 2004, 532
DOI: 10.1039/b315795d
Prediction of formation constants of metal–ammonia complexes in aqueous solution using density functional theory calculations
Robert D. Hancock and Libero J. Bartolotti,
Chem. Commun., 2004, 534
DOI: 10.1039/b312518c
Novel imprinted soluble microgels with hydrolytic catalytic activity
Stacey C. Maddock, Pamela Pasetto and Marina Resmini,
Chem. Commun., 2004, 536
DOI: 10.1039/b312631e
Cooperative C–F
Si interaction in optically active helical polysilanes
Sun-Young Kim, Anubhav Saxena, Giseop Kwak, Michiya Fujiki and Yusuke Kawakami,
Chem. Commun., 2004, 538
DOI: 10.1039/b314723a
Easy access to diastereomerically pure platinacycles
Concepción López, Amparo Caubet, Sonia Pérez, Xavier Solans and Mercè Font-Bardía,
Chem. Commun., 2004, 540
DOI: 10.1039/b315157c
The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X–: evidence for monomer-dependent early or late transition states
Fuquan Song, Roderick D. Cannon and Manfred Bochmann,
Chem. Commun., 2004, 542
DOI: 10.1039/b314845a
First three examples of taxane-derived di-propellanes in Taxus canadensis needles
Qing Wen Shi, Françoise Sauriol, Alain Lesimple and Lolita O. Zamir,
Chem. Commun., 2004, 544
DOI: 10.1039/b316051c
Insights into the reactivity and structure of silylene phosphonium ions
Rudolf Pietschnig,
Chem. Commun., 2004, 546
DOI: 10.1039/b315001a
Fabrication of two-dimensionally ordered macroporous silica materials with controllable dimensions
Mandakini Kanungo and Maryanne M. Collinson,
Chem. Commun., 2004, 548
DOI: 10.1039/b311936j
Sn-Beta
zeolite as diastereoselective water-resistant heterogeneous Lewis-acid
catalyst for carbon–carbon bond formation in the intramolecular
carbonyl–ene reaction
Avelino Corma and Michael Renz,
Chem. Commun., 2004, 550
DOI: 10.1039/b313738d
Porphyrin–acetylene–thiophene polymer wires
Guangtao
Li, Tianyu Wang, Andrea Schulz, Sheshanath Bhosale, Matthias Lauer,
Pamela Espindola, Jürgen Heinze and Jürgen-Hinrich Fuhrhop, Chem. Commun., 2004, 552
DOI: 10.1039/b313415f
Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host
Samiran Bhattacharjee and James A. Anderson,
Chem. Commun., 2004, 554
DOI: 10.1039/b315325h
Template-free synthesis of single-crystalline cadmium nanotubes
Pingàn Hu, Yunqi Liu, Lei Fu, Lingchao Cao and Daoben Zhu,
Chem. Commun., 2004, 556
DOI: 10.1039/b312708g
Utilisation of [11C]-labelled boron carbonyl complexes in palladium carbonylation reaction
Hélène Audrain, Laurent Martarello, Antony Gee and Dirk Bender,
Chem. Commun., 2004, 558
DOI: 10.1039/b314982j
New magnetically responsive polydicarbazole-magnetite nanoparticles
Jean-Paul Lellouche, Nurit Perlman, Augustine Joseph, Senthil Govindaraji, Ludmila Buzhansky, Aline Yakir and Ian Bruce,
Chem. Commun., 2004, 560
DOI: 10.1039/b309375a
Mesocellular polymer foams with unprecedented uniform large mesopores and high surface areas
Jinwoo Lee, Jaeyun Kim, Sang-Wook Kim, Chae-Ho Shin and Taeghwan Hyeon,
Chem. Commun., 2004, 562
DOI: 10.1039/b310713b
Microwave-assisted Negishi and Kumada cross-coupling reactions of aryl chlorides
Peter Walla and C. Oliver Kappe,
Chem. Commun., 2004, 564
DOI: 10.1039/b313887a
C1 Coupling via bromine activation and tandem catalytic condensation and neutralization over CaO/zeolite composites
Ivan Lorkovic, Maria Noy, Mike Weiss, Jeff Sherman, Eric McFarland, Galen D. Stucky and Peter C. Ford,
Chem. Commun., 2004, 566
DOI: 10.1039/b314118g
Spontaneous template-free assembly of ordered macroporous titania
Andrew Collins, Daniel Carriazo, Sean A. Davis and Stephen Mann,
Chem. Commun., 2004, 568
DOI: 10.1039/b315018f
Synthesis
and structural characterisation of a novel phosphine-borane-stabilised
dicarbanion and an unusual bis(phosphine-borane)
Keith Izod, William McFarlane, Brent V. Tyson, William Clegg and Ross W. Harrington,
Chem. Commun., 2004, 570
DOI: 10.1039/b315068b
A versatile pathway for the direct assembly of organo-functional mesostructures from sodium silicate
Jainisha Shah, Seong-Su Kim and Thomas J. Pinnavaia,
Chem. Commun., 2004, 572
DOI: 10.1039/b315032a
Protein–DNA interaction: impedance study of MutS binding to a DNA mismatch
Chen-Zhong Li, Yi-Tao Long, Jeremy S. Lee and Heinz-Bernhard Kraatz,
Chem. Commun., 2004, 574
DOI: 10.1039/b314642a
Single-step
fabrication of drug-encapsulated inorganic microspheres with complex
form by sonication-induced nanoparticle assembly
Alexander Kulak, Simon R. Hall and Stephen Mann,
Chem. Commun., 2004, 576
DOI: 10.1039/b314465h
Electrochromic tetrathiafulvalene derivatives functionalised with 2,5-diaryl-1,3,4-oxadiazole chromophores
Changsheng Wang, Andrei S. Batsanov and Martin R. Bryce,
Chem. Commun., 2004, 578
DOI: 10.1039/b316243p
Reactive barium-promoted Reformatsky-type reaction of 
-chloroketones with aldehydes
Akira Yanagisawa, Hiroshi Takahashi and Takayoshi Arai,
Chem. Commun., 2004, 580
DOI: 10.1039/b314752p
Direct
epoxidation of propylene by molecular oxygen over a catalyst system
containing palladium and a peroxo-heteropoly compound in methanol
Yanyong Liu, Kazuhisa Murata and Megumu Inaba,
Chem. Commun., 2004, 582
DOI: 10.1039/b316100p
Formation of cyclic compounds and carbenium ions by conversion of methanol on weakly dealuminated zeolite H-ZSM-5 investigated via a novel in situ CF MAS NMR/UV-Vis technique
Michael Hunger and Wei Wang,
Chem. Commun., 2004, 584
DOI: 10.1039/b315779b
A new method of solvent free O- and N-glycosylation
using activated carbon fiber (ACF) as a promoter. Application to the
synthesis of saponin and nucleoside analogues
Sophie Lautrette, Robert Granet and Pierre Krausz,
Chem. Commun., 2004, 586
DOI: 10.1039/b315699k
A powerful route to C-functionalised tetraazamacrocycles
Frédéric Boschetti, Franck Denat, Enrique Espinosa, Jean-Marie Lagrange and Roger Guilard,
Chem. Commun., 2004, 588
DOI: 10.1039/b315285e
Modelling
catalytic turnover frequencies in ionic liquids: the determination of
the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate
Konrad Swiderski, Andrew McLean, Charles M. Gordon and D. H. Vaughan,
Chem. Commun., 2004, 590
DOI: 10.1039/b315781d
Identification of 5-fluoro-5-deoxy-D-ribose-1-phosphate as an intermediate in fluorometabolite biosynthesis in Streptomyces cattleya
Steven L. Cobb, Hai Deng, John T. G. Hamilton, Ryan P. McGlinchey and David O'Hagan,
Chem. Commun., 2004, 592
DOI: 10.1039/b400754a
The first general method for -trifluoromethylation of carboxylic acids using BrF3
Aviv Hagooly and Shlomo Rozen,
Chem. Commun., 2004, 594
DOI: 10.1039/b315705a
A practical synthesis of amphiphilic cyclodextrins fully substituted with sugar residues on the primary face
Florence Sallas, Kenichi Niikura and Shin-Ichiro Nishimura,
Chem. Commun., 2004, 596
DOI: 10.1039/b316365b
A direct meta-lithiation route to 1,3-disubstituted ferrocenes
Christophe Pichon, Barbara Odell and John M. Brown,
Chem. Commun., 2004, 598
DOI: 10.1039/b314641c
The first fullerene–heterofullerene dyad
Frank Hauke, M. Ángeles Herranz, Luis Echegoyen, Dirk Guldi, Andreas Hirsch and Stefan Atalick,
Chem. Commun., 2004, 600
DOI: 10.1039/b315006b
Well-defined self-assembling supramolecular structures in water containing a small amount of C60
Jingcheng Hao, Hongguang Li, Weimin Liu and Andreas Hirsch,
Chem. Commun., 2004, 602
DOI: 10.1039/b312549a
Communications
Poly(ethylene glycol) as solvent for transition metal mediated living radical polymerisation
Sébastien Perrier, Hesna Gemici and Song Li, Chem. Commun., 2004, 604
DOI: 10.1039/b313061d
Tandem aminoxylation–allylation reactions: a rapid, asymmetric conversion of aldehydes to mono-substituted 1,2-diols
Guofu Zhong, Chem. Commun., 2004, 606
DOI: 10.1039/b314356b
An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins
Susana L. H. Rebelo, Mário M. Q. Simões, M. Graça P. M. S. Neves, Artur M. S. Silva and José A. S. Cavaleiro, Chem. Commun., 2004, 608
DOI: 10.1039/b313683c
The affinity of phosphates to zinc(II) complexes can be increased with hydrogen bond donors
Juan C. Mareque-Rivas, Rafael Torres Martín de Rosales and Simon Parsons, Chem. Commun., 2004, 610
DOI: 10.1039/b314616b
Continuous flow homogeneous catalysis using supercritical fluids
Paul B. Webb and David J. Cole-Hamilton, Chem. Commun., 2004, 612
DOI: 10.1039/b316311c
A novel scandium fluoride, [C2N2H10]0.5[ScF4], with an unprecedented tungsten bronze-related layer structure.
Nicholas F. Stephens, Alexandra M. Z. Slawin and Philip Lightfoot, Chem. Commun., 2004, 614
DOI: 10.1039/b316312a
Biotinylated and enzyme-immobilized carrier prepared by hetero-bifunctional latex beads
Yong-Zhong Du, Takenori Tomohiro, Gao Zhang, Kazuhiko Nakamura and Masato Kodaka, Chem. Commun., 2004, 616
DOI: 10.1039/b313611f
On the regioselectivity of Pd-catalyzed additions of organoboronic acids to unsymmetrical alkynes
Nakjoon Kim, Ki Seong Kim, Aruna Kumar Gupta and Chang Ho Oh, Chem. Commun., 2004, 618
DOI: 10.1039/b316446b
Cubane-like structure of a silanethiol – primary amine assembly – a novel, unusual hydrogen bond pattern
Barbara Becker, Katarzyna Baranowska, Jaros
aw Chojnacki and Wiesaw Wojnowski, Chem. Commun., 2004, 620
DOI: 10.1039/b313576d