Volume 186
Main Index

Issue 1, Pages 1-145 (19 February 1980)

The preparation of η5-cyclopentadienylvanadium dihalide complexes Pages C12-C14 J. Nieman, H. Scholtens, J. H. Teuben

Reduktion von isopropyl- und butylantimonbromiden mit magnesium Pages C5-C8 Hans Joachim Breunig, Walter Kanig

Mise en evidence et etude de l'addition d'enamines stanniques a divers alcenes electrophiles Pages C9-C11 Bernard de Jeso, Jean-Claude Pommier

Cross-coupling reaction of secondary alkyl grignard reagents with allylic alcohols catalyzed by dichloro[1,1′-bis(diphenylphosphino)-ferrocene]palladium(II) Pages C1-C4 Tamio Hayashi, Mitsuo Konishi, Makoto Kumada

A stereospecific rhodium catalyzed hydroacylation. Cyclization of trans-4-hexenal-1-d Pages C27-C31 Richard E. CampbellJr., Roy G. Miller

Coordinatively unsaturated molybdenum and tungsten acetylene complexes [M(η5-C5 H5)Cl(CF3 CCCF3)2]: reactions with charged and uncharged nucleophiles Pages C19-C22 Jack L. Davidson

Chimie des complexes nitrosyles : II. Formation du cation Fe(CO)(NO)[P(C6H5)3]2+ par protonation d'un hydrure nitrosyle du fer. Decomposition par transfert de NO Pages C23-C26 J. L. A. Roustan, J. Y. Merour, A. Forgues

Co-ordination Chemistry of Macrocyclic Compounds : edited by G.A. Melson. Plenum Press, New York, 1979, xiv + 664 pages. Price $49.50 Page C32 A. Pidcock

Dynamic stereochemistry of ligand substitution at a chiral titanium center. Synthesis of asymmetrical halidopseudohalidotitanocene complexes Pages C15-C18 J. Besançon, D. Camboli, J. Tirouflet

Molecular orbital correlation of arylmethyl chloride atom abstraction by stannyl radicals Pages 1-6 Helene Soppe-Mbang, Gerald Jay Gleicher

Phenylazotriorganosilanes as silylated phenyldiazenes; a convenient precursor for phenyldiazene Pages 7-11 Hamao Watanabe, Ken-Ichi Awano, Manabu Ohmori, Nobuhiro Kodama, Jun-Ichi Sakamoto, Yutaka Onodera, Yoichiro Nagai

29Si NMR of five- and six-coordinate organosilicon complexes Pages 13-17 J. A. Cella, J. D. Cargioli, E. A. Williams

A re-examination of the electrochemical reduction of halosilanes and halogermanes Pages 19-24 R. J. P. Corriu, G. Dabosi, M. Martineau

The nature of the interaction of nucleophiles such as HMPT, DMSO, DMF and Ph3PO with triorganohalo-silanes, -germanes, and -stannanes and organophosphorus compounds. Mechanism of nucleophile induced racemization and substitution at metal Pages 25-37 R. J. P. Corriu, G. Dabosi, M. Martineau

Organoarsenverbindungen : XXXVIII. 1,3-benzoxarsole; stabile sauerstoffhaltige element-Vb-aromaten Pages 39-50 J. Heinicke, B. Raap, A. Tzschach

Reaction of disilanes with acetylenes : I. Stereoselective addition of methoxymethyldisilanes to phenylacetylene catalyzed by group-VIII metal phosphine complexes Pages 51-62 Hamao Watanabe, Mitsunobu Kobayashi, Kazuaki Higuchi, auYoichiro Nagai

Calculations of transition metal compounds using an extension of the CNDO formalism : III. Application to the co insertion reaction as an example for mechanistic studies Pages 63-75 D. Saddei, H. -J. Freund, G. Hohlneicher

Reaction de metathese des olefines induite photochimiquement en presence d'un complexe de metal de transition : VI. Existence probable d'un metallodichlorocarbene primaire Pages 77-83 F. Garnier, P. Krausz, H. Rudler

Organometalloidal derivatives of the transition metals : IV. A Mössbauer and infrared spectral study of the iron—silicon or carbon bond in the system (η5-C5H5)Fe(CO)2R Pages 85-90 K. H. Pannell, C. C. Wu, Gary J. Long

Zur bildung, reaktivität und molekülgeometrie von zweikernigen tri-t-butylphosphin-substituierten ruthenium(I)-komplexen Pages 91-99 H. Schumann, J. Opitz

Trimethylphosphite derivatives of mixed cobalt-rhodium tetranuclear clusters Pages 101-108 D. Labroue, R. Queau, R. Poilblanc

Metal complexes with allylanilines : IV. Synthesis and reactivity of rhodium(I) complexes with 2-allylaniline and N-allylaniline Pages 109-120 M. Aresta, M. De Fazio

Dinuclear bridged d8 metal complexes : IX. Preparation and structure of the complexes [Ir2(μ-SBu-t)2(CO)2(PR3)2] and [Ir2(μ-SBu-t)2(CO)3(PR3)] Pages 121-130 Dominique de Montauzon, Philippe Kalck, René Poilblanc

Ring opening of 3,3,4,4-tetracyano-2,2-bis(triphenylarsine)-1-oxa-3-platinacyclobutane promoted by various phosphines Pages 131-135 P. Dall'Antonia, M. Graziani, M. Lenarda

Stereochemistry at secondary carbon in organometallic insertion reactions Pages 137-145 J. D. Cotton, G. T. Crisp

Issue 2, Pages 147-296 (26 February 1980)

Catalytic hydrogenation in organic syntheses : by Paul N. Rylander, New York, San Francisco, London, Academic Press, 1979, x and 325 pages, $34.00. Pages C53-C54 William H. Rastetter

Reaktionen von phosphor-yliden mit übergangsmetallverbindungen : IX. Komplexe mit unsymmetrisch substituierten iminen Pages C42-C44 L. Knoll

Eine neue darstellungsmethode für permethylierte cyclosilane Pages C45-C48 E. Hengge, H. G. Schuster, W. Peter

Reduction electrochimique du ferrocene Pages C49-C52 Y. Mugnier, C. Moise, J. Tirouflet, E. Laviron

The Bridge Reversal Barrier for 1,2,3- Trithia-[3]-ferrocenophane Pages C37-C41 Edward W. Abel, Martin Booth, Keith G. Orrell

Iododestannylation. Position-specific synthesis of iodotamoxifen Pages C33-C36 David E. Seitz, Glenn L. Tonnesen, Samuel Hellman, Robert N. Hanson and, S. James Adelstein

Polyorganometallic heterocycles. 2,6-dilithiopyridine Pages 147-153 George R. Newkome, Jerry M. Roper

A convenient method for the accurate estimation of concentrations of alkyllithium reagents Pages 155-158 Michael F. Lipton, Charles M. Sorensen, Alan C. Sadler, Robert H. Shapiro

Reactions of zinc hydride and magnesium hydride with pyridine; synthesis and characterization of 1,4-dihydro-1-pyridylzinc and -magnesium complexes Pages 159-172 A. J. de Koning, J. Boersma, G. J. M. van der Kerk

Bis(1,4-dihydro-1-pyridyl)zinc and bis(1,4-dihydro-1-pyridyl)magnesium complexes; reducing properties of the 1,4-dihydropyridyl group bound to zinc or magnesium Pages 173-184 A. J. de Koning, J. Boersma, G. J. M. van der Kerk

Reactions of tetraalkylaluminoxanes with amines Pages 185-191 A. Piotrowski, A. Kunicki, S. Pasynkiewicz

Carbanionen-umlagerungen durch intramolekulare 1,ω-protonverschiebung II. Zur reaktionsweise von 3-, 4- und 5-lithioalkyl-trimethylsilanen Pages 193-205 Adalbert Maercker, Mechthild Eckers, Michael Passlack

Metallorganische verbindungen des 1,2-diethinylbenzols vom typ o-C6H4(CCMR3)2 (M = Si, Ge, Pb) Pages 207-212 R. Nast, H. Grouthi

The Mössbauer recoil-free fraction and structure : II. Di-μ3-oxo-bis-(μ-dichloro)-bis[μ-dimethyltin(IV)]-bis-[chlorodimethyltin(IV)], and its ethyl homologue Pages 213-236 Philip G. Harrison, M. J. Begley, K. C. Molloy

Synthesis of monocyclopentadienyltricarbonyl-niobium (and-tantalum) dichlorides Pages 237-240 Ana M. Cardoso, Robin J. H. Clark, Stephen Moorhouse

Syntheses of early transition-metal complexes containing metal---silicon bonds Pages 241-245 Ana M. Cardoso, Robin J. H. Clark, Stephen Moorhouse

Iron carbonyl complexes of 2,3,5,6-tetrakis(methylene)-7-oxabicyclo[2.2.1]heptane. Crystal and molecular structure of (C10H10O)Fe(CO)3 and (C9H10CO)Fe2(CO)6 Pages 247-264 Eric Meier, Olivier Cherpillod, Tristano Boschi, Raymond Roulet, Pierre Vogel and, Cyril Mahaim, Alan A. Pinkerton, Dieter Schwarzenbach and, Gervais Chapuis

Ligand exchange of some heterocyclic analogues of fluorene and anthracene with ferrocene Pages 265-270 C. C. Lee, B. R. Steele, R. G. Sutherland

Kinetics and mechanism of the anchoring of RuCl3NO(SbPh3)2 to polymer-bound phosphinic ligands Pages 271-277 Giuseppe Innorta, Alberto Modelli, Francesco Scagnolari, Antonio Foffani

Paramagnetic carbonyl cobalt(II) complexes. Molecular structure of bromocarbonyl-1,1,1-tris(diphenylphosphinomethyl)ethanecobalt(II) tetraphenylborate Pages 279-287 C. A. Ghilardi, S. Midollini, L. Sacconi

Proton spin lattice relaxation rates of substituted ferrocene derivatives; assignment of resonances and determination of motional correlation times Pages 289-296 Michael J. Adam, Laurance D. Hall

Issue 3, Pages 297-445 (4 March 1980)

[Fe(CO)2P(OPh)32(CS)]. The first stable thiocarbonyl derivative of iron(0) pentacarbonyl Pages C64-C66 Paul Conway, A. R. Manning, F. S. Stephens

A new and unusual isomerism in [Fe(CO)2 {P(OR)3}2 (SO2)] complexes (R = aryl) Pages C61-C63 Paul Conway, Seamus M. Grant, A. R. Manning, F. S. Stephens

Nucleophilic addition to the tricarbonyl(η-cycloheptadienylium)iron cation by alkoxide ions. Formation of carboalkoxy intermediates Pages C58-C60 David A. Brown, William K. Glass, Farouk M. Hussein

Stabilization of platinum(II) hydrides by tri-t-butylarsine; facile syntheses of stable trans-PtH2[As(t-Bu)3]2 and trans-PtHX[As(t-Bu)3]2 complexes Pages C67-C68 Ram G. Goel, William O. Ogini

The reduction of osmium carbonyl clusters by nitriles Pages C69-C71 David J. Cox, Glyn R. John, Brian F. G. Johnson, Jack Lewis

Remarkable countercation effect in the reaction of organoboranes with enolates Pages C55-C57 Michael J. Idacavage, Ei-Ichi Negishi, Charles Allan Brown

Synthesis of boron stabilised carbanions Pages 297-300 John W. Wilson

Unsaturated bridgehead silicon intermediates. Dipolar character of unsaturated silicon---nitrogen bonds in such intermediates Pages 301-308 Maher Elseikh, Leo H. Sommer

Thermolysis of [tris(trimethylsilyl)methyl](diphenyl)fluorosilane. Isomerization of a sila-olefin intermediate Pages 309-323 Colin Eaborn, Duncan A. R. Happer, Peter B. Hitchcock, Steven P. Hopper, Kazem D. Safa, Stephen S. Washburne, David R. M. Walton

The effect of medium acidity on the rate of protonation of 6-dimethylaminofulventricarbonyl-chromium, -molybdenum, -tungsten and comparison of their basicity Pages 325-330 V. N. Setkina, B. N. Strunin, D. N. Kursanov

π-Complexes as ligands in transition metal compounds : II. Bis-(π-pyrrolyltricarbonylmanganese)tricarbonylmanganese halides Pages 331-338 N. I. Pyshnograeva, V. N. Setkina, V. G. Andrianov, Yu. T. Struchkov, D. N. Kursanov

Free radical intermediates in the reaction between decacarbonyldirhenium and triphenylphosphane Pages 339-345 David J. Cox, Reg Davis

The reactions of decacarbonyldirhenium with some organo-phosphanes and phosphites Pages 347-352 David J. Cox, Reg Davis

Reactions of the unsaturated anions [H3Re3(CO)10]2− and [H4Re3(CO)10]− with iodine in various solvents. X-ray characterization of the derivative H3Re3(CO)10(py)2 Pages 353-360 G. Ciani, G. D'Alfonso, M. Freni, P. Romiti, A. Sironi

Zur Kenntnis der Chemie der Metallcarbonyle und der Cyano-Komplexe in flüssigem ammoniak : XXXIX. Über die Reaktionen von ein - und zweikernigen, kationischen η5-Cyclopentadienyl-carbonyl-Komplexen des Eisens, Rutheniums und Osmiums mit flüssigem Ammoniak oberhalb 10°C Pages 361-370 Anton Jungbauer, Helmut Behrens

Zur Kenntnis der Chemie der Metallcarbonyle und der Cyano-Komplexe in flüssigem ammoniak : XL. Über die Reaktion kationischer Cyclopentadienyl-carbonyl-nitrosyl-Komplexe des Mangans und Rheniums mit flüssigem Ammoniak Pages 371-387 Helmut Behrens, Günter Landgraf, Peter Merbach, Matthias Moll

Etude de substances modeles susceptibles de complexer les metaux de transition dans les fractions lourdes du petrole : I. Caracterisation par ESCA et LAMMA de complexes au nickel, cobalt et rhodium avec des ligandes sulfures Pages 389-400 J. F. Muller, J. M. Magar, D. Cagniant, J. Grimblot and, J. P. Bonnelle

The catalysis of the electrochemical reduction of alkyl bromides by nickel complexes: The formation of carbon---carbon bonds Pages 401-409 Cary Gosden, Derek Pletcher

Platinum(II) and palladium(II) complexes of thiacyclooct-4-enes; an unusual metal-catalyzed olefin isomerization Pages 411-418 Luigi Busetto

The photodecomposition of platinacycloalkanes in solution. : I. 1,3-propanediylplatinum(IV) compounds Pages 419-426 Duncan C. L. Perkins, Richard J. Puddephatt, Charles F. H. Tipper

Group IB organometallic chemistry : XXXIII. ArAuPPh3, ArAu(CNR), (ArAu)n and Ar4Cu2Au2 compounds in which the aryl group contains 2-MeO, 2,6-(MeO)2, 2-Me2N, 2-Me2NCH2 and (S)- or (R)-2-Me2NCHMe substituents as potential ligands Pages 427-445 Gerard Van Koten, Cees A. Schaap, Johann T. B. H. Jastrzebski, Jan G. Noltes