Volume 249
Main Index

Issue 1, Pages 1-302 (21 June 1983)

Introduction Pages ix-x Evelyn A.V. Ebsworth

Note by the editors Page xi C. Eaborn, R. B. King, E. O. Fischer, M. Kumada, J. F. Normant, O. A. Reutov

Solvent-induced linkage isomerism and ionization in solutions of triphenyllead selenocyanate Pages c9-c12 M. Onyszchuk, I. Wharf

A new reaction of fluorinated phosphites: the preparation of η5-cyclopentadienylbis[tris(2,2,2-trifluoroethyl)phosphito]iodoiron(II) Pages c13-c15 Jean'ne M. Shreeve, Stanley M. Williamson

Author index Page c16

Preparation and X-ray crystal structures of the dimeric aldiminoborane (PhCH=NBMe2)2 and monomeric paddle-wheel shaped tris(ketimino)borane B(N=CBut2)3 Pages c1-c5 J. Robert Jennings, Ronald Snaith, Muayyad M. Mahmoud, Stephen C. Wallwork, Stephen J. Bryan, Joan Halfpenny, Elizabeth P. Petch and, Kenneth Wade

An unusual halogen exchange in a closo-carborane system Pages c6-c8 Keith Fuller, Thomas Onak

Synthesis of lithiomethanes (CH4−nLin) and characterization of the vapor species of lithiomethanes by flash vaporization mass spectroscopy Pages 1-9 F. J. Landro, J. A. Gurak, J. W. ChinnJr., R. J. Lagow

The first osmaboranes and a new iridatetraborane Pages 11-21 Jonathan Bould, Norman N. Greenwood, John D. Kennedy

Some tris(trimethylsilyl)methyl derivatives of boron, aluminum and gallium Pages 23-31 Colin Eaborn, Mohamed N. El-Kheli, Negussie Retta, J. David Smith

Novel inorganic ring systems : XXXIX. A dimeric cycloalumadisilatriazane Pages 33-46 Ulrich Wannagat, Thomas Blumenthal, David J. Brauer and, Hans Bürger

Stabilisation of silicenium ylids by adduct formation with aluminium trihalides: the crystal structure of [(Me3C)2SiNCMe3]2AlClF2 Pages 47-54 William Clegg, Uwe Klingebiel, Jutta Neemann, George M. Sheldrick

Highly hindered iodotris- and tetrakis-(pentacarbonylmetal)silane derivatives containing manganese and rhenium Pages 55-61 B. J. Aylett, M. T. Taghipour

Substituted heptaphosphanortricyclenes: Derivatives and homologues of P7(SiMe3)3 Pages 63-80 G. Fritz, K. D. Hoppe, W. Hönle, D. Weber, C. Mujica, V. Manriquez and, H. G. v. Schnering

Di-and triorganotin(IV) derivatives of 2-benzoylbenzoic acid Pages 81-96 S. W. Ng, J. J. Zuckerman

The synthesis and structures of silver complexes with trimeric thioformaldehyde and trimeric selenoformaldehyde Pages 97-102 Hartmut Hofmann, Peter G. Jones, Mathias Noltemeyer, Egon Peymann, Waltraud Pinkert, Herbert W. Roesky, George M. Sheldrick

Alternativ-liganden : XVI. Komplexe M(CO)nL (M = Cr, Mo, W) der chelatliganden (2-Me2E′C6H4)Si(EMe2)Me2 und (4-XC6H4SiMe(EMe2)CH2CH2E′Me2 (Me = CH3; X = F,Cl; E, E′ = N, P, As) Pages 103-126 P. Aslanidis, J. Grobe

Reactions of bimetallic group VI complexes : II. Phosphine and phosphite derivatives: Ligand transfer and oxidative decarbonylation; the crystal structure of [(C5H5)(OC)2(CO)3I] Pages 127-135 J. L. Le Quéré, F. Y. Pétillon, J. E. Guerchais, Lj. Manojlovi-Muir, K. W. Muir and, D. W. A. Sharp

Photochemistry of the group VI metal hexacarbonyls in polyvinyl-chloride film matrices at 12-298 K. The reactivity of the species M(CO)5 and M(CO)5(THF) Pages 137-147 Richard H. Hooker, Antony J. Rest

Structure and reactivity of the anionic alkeneosmium cluster, [1,1,1,2,2,2,3,3,3,3-decacarbonyl-2-bromo-1-η2-trans-1,1,1,4,4,4-hexafluorobut-2-ene-triangulo-triosmium]−: X-ray crystal structures of [(Ph3P)2N][Os3(CO)10CF3(H)C=C(H)CF3Br], [(Ph3P)2N][Os3(CO)9CF3(H)C=C(H)CF3(μ-Br)], and [HOs3(CO)9CF3(H)C=C(H)CF3(μ-Br)] Pages 149-164 Zain Dawoodi, Martin J. Mays, Paul R. Raithby, Kim Henrick, William Clegg and, Gabriela Weber

Substituted 2,2′-bipyridines as ligands. preparation and characterization of 4,4′-disubstituted 2,2′-bipyridine derivatives of the hexacarbonyls of chromium, molybdenum and tungsten Pages 165-174 Joseph A. Connor, Colin Overton

Solid state studies : XXVIII. Raman intensity anomalies and intermediate mode behaviour in the ν(CO) region in mixed crystals of M(CO)5X (M = Mn, Re; X = Cl, Br) Pages 175-181 Mona Arif, Sidney F. A. Kettle

Ferrocenyllithium derivatives: lithiation of α-N,N-deimethylaminoethylferrocene and the single crystal X-ray structure of [(η5-C5H4Li)Fe(η5-C5H3LiCH(Me)NMe2)]4[LiOEt]2(TMED)2 Pages 183-194 Ian R. Butler, William R. Cullen, John Reglinski, Steven J. Rettig

Organometallic derivatives of the transition elements : IV. Ferrocenes via the reaction of iron atoms with alkynes Pages 195-203 L. H. Simons, J. J. Lagowski

The synthesis and electrochemistry of some perfluoroalkylcobalt organometallic compounds Pages 205-225 A. M. Van den Bergen, D. J. Brockway, B. O. West

The preparation and properties of some iridium-substituted difluorophosphines: synthesis of some PF2-bridged heterometal complexes Pages 227-242 E. A. V. Ebsworth, Robert O. Gould, Neil T. McManus, David W. H. Rankin, Malcolm D. Walkinshaw, John D. Whitelock

Syntheses and 31P NMR studies of some cycloocta-1,5-dienerhodium(I) complexes containing coordinated 1,3-DI-t-butyl- 2,4-dihalogenocyclodiphosphazanes, [PXNtBu]2 (X = Cl, F) and related ligands. Crystal and molecular structure of bis(chloro)(cycloocta-1,5-diene)1,3-di-t-butyl-2,4-difluorocyclodiphosphazanedirhodium(I) Pages 243-254 James Burckett, Burckett St. Laurent, Peter B. Hitchcock, John F. Nixon

Metal-carbido complexes of ruthenium and osmium Pages 255-272 Brian F. G. Johnson, Jack Lewis, William J. H. Nelson, J. Nicola Nicholls, Maria D. Vargas

Metal framework arrangements in pentanuclear gold-ruthenium clusters. Crystal structures of [Au2Ru3(μ3-S)(CO)8(PPh3)3] and [Au2Ru3(μ-H)(μ3-COMe)(CO)9(PPh3)2] Pages 273-288 Louis J. Farrugia, Mark J. Freeman, Michael Green, A. Guy Orpen, F. Gordon, A. Stone, Ian D. Salter

Crystal and molecular structure of [CH3C(S)CHC(S)CH3][CH3S(O)(CH2)2]Ni Pages 289-292 D. S. Dudis, J. P. FacklerJr.

Nitrogen-15 NMR comparisons of (alkyl and perfluoroalkyl) C-nitroso compounds, and bent and linear nitrosyl ligands in transition metal complexes Pages 293-298 Dominic H. Evans, D. Michael P. Mingos, Joan Mason, Adrian Richards

Fast atom bombardment (FAB) mass spectrometry: a new technique for the organometallic chemist Pages 299-302 Jack M. Miller

Issue 2, Pages 303-443 (28 June 1983)

Synthese und reaktivität von dienylmetallverbindungen : XV. Cyclopentadienylnickel-komplexe mit seleno- und telluro-ethern als liganden Pages c28-c30 N. Kuhn, M. Winter

Synthesis and structural characterization of the [Fe3(CO)9(μ3-O)]2− dianion: a model compound for an adsorbed oxygen atom Pages c35-c37 A. Ceriotti, L. Resconi, F. Demartin, G. Longoni, M. Manassero and, M. Sansoni

Author index Pages c41-c42

Die photochemische synthese von tetracarbonyl-η3-pentadienylmangan(I) Pages c31-c34 Michael Leyendecker, Cornelius G. Kreiter

Subject index Pages c42-c48

The synthesis and X-ray analysis of HOs8(CO)22I Pages c21-c24 Brian F. G. Johnson, Jack Lewis, William J. H. Nelson, Maria Vargas, Dario Braga and, Mary McPartlin

Generation of dimethylgermathione and dimethylsilathione and their detection in the gas phase by photo-electron spectroscopy Pages c17-c20 C. Guimon, G. Pfister-Guillouzu, H. Lavayssiere, G. Dousse, J. Barrau and, J. Satge

Structure cristalline du bis[tris(trimethylsilyl)methyl]-diphosphene Pages c25-c27 J. Jaud, C. Couret, J. Escudie

Stoichiometric insertion of carbon dioxide and ethylene into nickel---carbon bonds Pages c38-c40 Arno Behr, Wilhelm Keim, Gerhard Thelen

The geometry and bonding of magnesocene. An AB-initio MO-LCAO investigation Pages 303-313 K. Faegri Jr., J. Almlöf, H. P. Lüth

Une methode tres simple et reproductible de dosage des solutions etherees de LiAlH4 Pages 315-317 J. Villieras, M. Rambaud, B. Kirschleger

Interaction of vinylgermanes with iron carbonyls. X-ray crystal structure of the Ge[Fe(CO)4]4 complex Pages 319-326 A. S. Batsanov, L. V. Rybin, M. I. Rybinskaya, Yu. T. Struchkov, I. M. Salimgareeva and, N. G. Bogatova

Phosphorus-31, tin-119 and platinum-195 NMR studies on some platinum(II)-tin bonded compounds Pages 327-334 Stuart Carr, Ray Colton, Dainis Dakternieks

Synthese von 1-phenyl-2,5-diaryl(dialkyl)-arsolen; umsetzung der arsole mit alkalimetallen und lithiumorganylen Pages 335-363 G. Märkl, H. Hauptmann, A. Merz

Complex catalysis : XIV. Structure-activity relationships of complex catalysts for olefin metathesis; a theoretical consideration Pages 365-369 Rudolf Taube, Karl Seyferth

Réactions d'insertion du cyanoacétylène et du dicyanoacétylène dans les deux liaisons métal---hydrogène des dihydrures [(C5H5)2MH2] (M = Mo ou W) Pages 371-389 Henri Scordia, Rene Kergoat, Marek M. Kubicki, Jacques E. Guerchais

Multi-site bound hydrocarbyls on osmium clusters. The reactions of t-butylacetylene with Os3(CO)12 and H2Os3(CO)10. Characterization of the products and crystal structure of HOs3(CO)10(HC=CHBut) Pages 391-404 Enrico Sappa, Antonio Tiripicchio, Anna Maria Manotti Lanfredi

Determination of kinetic parameters of the thermal decomposition reaction of carbonyl complexes by TPDE method; application to unsupported Co4(CO)12 in flowing hydrogen Pages 405-410 D. Labroue, R. Pince, R. Queau

Effect of solvent viscosity on the reaction of styrenes with HCo(CO)4 and CO Pages 411-414 Ferenc Ungváry, László Markó

Rhodium(I) and platinum(II) complexes with chelating bidentate isonitrile ligands Pages 415-428 Mark L. Winzenburg, Joseph A. Kargol, Robert J. Angelici

Synthesis of [Rh4(μ-PPh2)4(μ-CO)2(CO)4] and crystal structure of its monoclinic form Pages 429-436 C. P. Lau, C. Y. Ren, Langford Book and, Thomas C. W. Mak

Synthesis and reactions of di-μ-halo- or -pseudohalotetrakis(pentafluorophenyl)digold(III) Pages 437-443 Rafael Usón, Antonio Laguna, Mariano Laguna, Miguel Abad