Volume 295
Main Index

Issue 1, Pages 1-130 (5 November 1985)

Tris(trimethylsilyl)methyl-ditelluro-di-t-butylphosphan, (Me3Si)3CTeTeP(t-Bu)2, das erste ditellurophosphan Pages c1-c2 Fritz Sladky, Benno Bildstein, Dagmar Obendorf

The synthesis and characterisation of new triosmium and triruthenium main-group metal clusters M3(H)(CO)11(M′R3) and Os3(H)(CO)10(CH3CN)(M′R3) (M = Os, Ru; M′ = Ge, Sn; R, aryl, alkyl) Pages c3-c6 K. Burgess, C. Guerin, B. F. G. Johnson, J. Lewis

Author index Page c16

Reactions of the carbido cluster anion [Re7C(CO)21]3− with group IB metals: X-ray crystal structure of the novel heterometallic carbide [{Re7AgC(CO)21}2Br]5− Pages c7-c10 T. Beringhelli, G. D'Alfonso, M. Freni, G. Ciani and, A. Sironi

Erratum Page c16

Stabile palladium(II)-stannylkomplexe: Alkinyl-halogen austausch zwischen alkinylstannanen und 1,2-bis(diphenylphosphino)ethanpalladium(II)chlorid Pages c11-c15 Carin Stader, Bernd Wrackmeyer

B-t-butyl-borazine und -diazadiboretidine Pages 1-6 Holger-A. Steuer, Anton Meller, Gernot Elter

Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen : XXII. Synthese und molekülstruktur des 1,2-bis(2,4,6-tri-t-butylphenyl)-3,3-di-t-butyl-1,2,3-diphosphasilirans Pages 7-14 Manfred Weidenbruch, Marlies Herrndorf, Annemarie Schäfer, Karl Peters and, Hans Georg von Schnering

Asymmetry parameters of the electric field gradient at the 35Cl nuclei of (3-chloropropyl)trichlorostannane Pages 15-19 V. P. Feshin, G. V. Dolgushin, M. G. Voronkov, Ju. E. Sapozhnikov and, Ja. B. Jasman, V. I. Shirjaev

Synthesis of tetraphenylstibonium alkyl- and aryl- sulphonates. Crystal structure of tetraphenylstibonium benzenesulphonate hydrate Pages 21-28 Robert Rüther, Friedo Huber, Hans Preut

The synthesis of 1,6-distibatriptycene (5,10-o-benzenostibanthrene), Sb2(C6H4)3 Pages 29-32 N. A. A. Al-Jabar, D. Bowen, A. G. Massey

Über antimon-haltige heterocyclen : III. Phenylierte stibocane, ψ-oktaedrische 5- und ψ-monocapped-oktaedrische 6-koordination um antimon(III) Pages 33-46 Harald M. Hoffmann, Martin Dräger

A convenient preparation of di-η5-cyclopentadienyltitana(IV)-cyclohexasulfane Pages 47-49 Ali R. Koray, Vefa Ahsen, Füsun Gökçeli, Emel Yilmazer, Özer Bekrolu

π-Arene complexes : II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) Pages 51-61 Simon Lotz, Minet Schindehutte, Marthie M. van Dyk, Jan L. M. Dillen and, Petrus H. van Rooyen

Reaktionen mit metall-koordinierten olefinen : IV. Synthese und reaktivität von kationischen cyclopentadienyl-mangan-allyl-komplexen Pages 63-71 B. Buchmann, A. Salzer

Multiple reaction pathways in the reactions of carbonylferrate anions with chalcogens, and with chalcogen-containing anions Pages 73-78 Christopher Glidewell

Ruthenium-catalysed rearrangements of azobenzenes : II. The preparation of 1-phenylbenzimidazoles from azobenzene derivatives and primary alcohols catalysed by ruthenium complexes Pages 79-89 Alwyn Spencer

Ruthenium-catalysed rearrangements of azobenzenes : III. Preparation of N-phenyl-1,2-phenylenediamine and N1-phenyl-N2-(sec-alkyl)-1,2-phenylenediamine and derivatives thereof by the ruthenium-catalysed reaction of azobenzenes with secondary alcohols Pages 91-97 Alwyn Spencer

The reactions of free and surface anchored phosphines with multidentate ligand stabilised metal carbonyl cluster complexes Pages 99-108 Douglas F. Foster, Jane Harrison, Barry S. Nicholls, Anthony K. Smith

The addition of metal nucleophiles (η-C5R5)M(CO)L to the dirhodium complex (η-C5H5)2Rh2(μ-CO)(μ-CF3C2CF3); Crystal structure of (η-C5H5)2(η-C5Me5)Rh3(CO)(gm-CO){μ-C(O)C2(CF3)2} Pages 109-124 Ron S. Dickson, Gary S. Evans, Gary D. Fallon, Geoff N. Pain

Gold(III) complexes containing 2-[(phenylazo)phenyl] as a chelating ligand Pages 125-130 J. Vicente, M. T. Chicote, M. D. Bermudez, M. Garcia-Garcia

Issue 2, Pages 131-264 (12 November 1985)

α, ω-Disäureamide aus 1,2-alkadienen und isocyanaten an nickel(O)-komplexen Pages c21-c23 Heinz Hoberg, Elisa Hernandez, Klaus Sümmermann

Group IB metal exchange reactions: A novel, high yield route to heteronuclear cluster compounds containing M(PPh3) (M = Cu, Ag or Au) moieties Pages c17-c20 Ian D. Salter

Author Index Page c24

Oxymetallation : XIX. Preparation of the first oxymercurials derived from cyclopropane Pages 131-135 A. J. Bloodworth, Christopher J. Cooksey

Diiod(methylthio)gallan. Darstellung und reaktivität Pages 137-148 Gerhard G. Hoffmann, Peter Resch

Preparation and spectroscopic studies of some cyclic urea adducts of triphenyl-tin and -lead halides Pages 149-158 Clare T. Aitken, Mario Onyszchuk

Alkylzirconium-(III) and -(IV) complexes Pages 159-165 T. Cuenca, P. Royo

Insertion of activated acetylenes into the metal-hydride bond of [(η5-C5H5)2M(CO)H] (M = Nb, Ta) Pages 167-174 Jacques Amaudrut, Jean-Claude Leblanc, Claude Moïse, Jean Sala-Pala

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : XVIII. Heterometallische selenido-komplexe Pages 175-187 Wolfgang A. Herrmann, Jürgen Rohrmann, Manfred L. Ziegler and, Thomas Zahn

Electrochemistry of phosphaferrocenes : II. Electrochemical behavior of 3,3′,4,4′-tetramethyl-1,1′- diphosphaferrocene bonded to M(CO)5 (M = Cr, Mo, W) fragments forming heterometallic complexes with multiple redox centers Pages 189-197 Paul Lemoine, Maurice Gross, Pierre Braunstein, François Mathey, Bernard Deschamps, John H. Nelson

Ruthenium-catalysed rearrangements of azobenzenes : IV. Rearrangement of deuterated azobenzenes to 1-phenylbenzimidazole and N-phenyl-1,2-phenylenediamine derivatives Pages 199-210 Alwyn Spencer

Asymmetrische katalysen : XXVII. Rh-komplexe mit von tropolon abgeleiteten optisch aktiven liganden Pages 211-221 Henri Brunner, Alfons Knott, Reinhard Benn and, Anna Rufiska

The reactions of a secondary phosphite with chloro- and pentan-2,4-dionato complexes of iridium(I) and rhodium(I) Pages 223-231 M. A. Bennett, T. R. B. Mitchell

Molecular structure of η5-[Pd(CH2CHCMeCH2CH2CH=CMe2)-(MeCN)](BF4), A cationic π-allylpalladium complex with an almost in-plane intramolecular olefin coordination Pages 233-238 Rosaria Ciajolo, Mohamud A. Jama, Angela Tuzi, Aldo Vitagliano

195Pt, 119Sn and 31P NMR studies of alkyl, aryl and acyl trichlorostannate complexes of platinum(II). The crystal structure of trans-[Pt(SnCl3)(COC6H5)(PEt3)2] Pages 239-256 Alberto Albinati, Urs Von Gunten, Paul S. Pregosin, Hubert J. Ruegg

Reactions of diphosphineplatinum(II) oxalate complexes with phenylacetylene. Formation of phenylalkynylplatinum complexes Pages 257-264 Gordon K. Anderson, Gregg J. Lumetta

Issue 3, Pages 265-405 (19 November 1985)

Erratum Pages c45-c46

Übergängsmetallcarbin-komplexe , : LXXX. Darstellung, spektroskopische eigenschaften und reaktivität eines phosphansubstituierten nickelcarben-und eines neuartigen kationischen nickelcarbin-komplexes Pages c29-c34 Ernst Otto Fischer, Johannes Rudolf Schneider

Subject index Pages c47-c52

Reactions of transition metal σ-acetylide complexes : III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(C=CPhN=NC6H3Me2-3,4)(PPh3)2(η-C5H5)][BF4] · 0.67CH2Cl2 and [Ru{C=CPh(C7H7)}(DPPE)(η-C5H5)][PF6] · 0.63CH2Cl2 Pages c40-c44 Michael I. Bruce, Christopher Dean, D. Neil Duffy, Mark G. Humphrey, George A. Koutsantonis

13C NMR Investigation of the properties of the anion [Re3(μ-H)3(CO)10]2− in solution Pages c35-c39 Tiziana Beringhelli, Giuseppe D'Alfonso, Henriette Molinari

n-Butylsodium: The preparation, properties and NMR spectra of a hydrocarbon- and tetrahydrofuran-soluble reagent Pages c25-c28 Christian Schade, Walter Bauer, Paul Von Ragué Schleyer

Author index Pages c46-c47

The alcoholysis of hydrosilanes Pages 265-315 E. Lukevics, M. Dzintara

The use of bulky x-ligands in the synthesis of new Cp2MX2 compounds (M = UIV; ThIV; Cp = η5-C5H5) Pages 317-326 G. Paolucci, P. Zanella, A. Berton

Olefin complexes of vanadocene Pages 327-331 M. Morán, J. J. Santos-García, J. R. Masaguer, V. Fernández

Electric dipole moments and anisotropic optical polarisabilities of methyl- and t-butyl-substituted (η6-benzene)tricarbonylchromium(0) complexes: Their relevance to the nature of the chromium-arene bond Pages 333-342 M. J. Aroney, M. K. Cooper, R. K. Pierens, S. J. Pratten, S. W. Filipczuk

An unusual route to the isopolymolybdates; Octamolybdate β-[Mo8O26]4− and hexamolybdate [Mo6O19]2−. Reaction of dioxomolybdenum complexes with triphenylphosphonium ylides. Crystal structures of the salts [PPh3CH2COOEt]+2[NH2Et]+2 [Mo8O26]4−, [PPh3CH2COOEt]+2 [Mo6O19]2−, and [PPh3CH2Ph]+2 [Mo6O19]2− Pages 343-352 Henri Arzoumanian, André Baldy, Richard Lai, América Odreman, Jacques Metzger, Marcel Pierrot

Preparation of the monodentate dithiophosphate complexes CpFe(CO)2(η1-SP(S)(OR)2), (Cp = η-C5H5, η-C5H4Me, η-C5Me5) Pages 353-363 M. Morán, I. Cuadrado

Triosmium clusters derived from α,β-unsaturated aldehydes Pages 365-369 Alejandro J. Arce, Ysaura De Sanctis, Antony J. Deeming

Factors affecting the regioselectivity in the rhodium-catalysed hydroformylation of vinyl ethers Pages 371-376 Raffaello Lazzaroni, Sergio Bertozzi, Paolo Pocai, Francesco Troiani, Piero Salvadori

X-ray crystal structure of the dimeric η3-cyclopropenylnickel(0) complex [(C3Ph3)Ni(CO)Br]2 Pages 377-381 Carlo A. Ghilardi, Stefano Midollini, Annabella Orlandini

Palladium-catalyzed asymmetric coupling reactions between allylic acetates and organozinc reagents. Mechanistic implications Pages 383-387 Jean-Claude Fiaud, Louisa Aribi-Zouioueche

Molecular orbital analysis of the bonding in penta- and hepta-nuclear gold tertiary phosphine clusters Pages 389-400 David G. Evans, D. Michael P. Mingos

Dimethylmetal(III) pyrazolides Pages 401-405 Peter K. Byers, Allan J. Canty, Karen Mills, Louise Titcombe