Volume 327
Main Index

Issue 1, Pages 1-145 (16 June 1987)

The formal umpolung behaviour of protonic acids containing coordinating anions towards diphosphazane-bridged derivatives of nonacarbonyldiruthenium Pages C18-C24 John S. Field, Raymond J. Haines, Eric Minshall, Clifford N. Sampson, Jörg Sundermeyer

Optically active phenanthrolines in asymmetric catalysis. Rhodium-catalyzed asymmetric transfer hydrogenation of acetophenone Pages C15-C17 Serafino Gladiali, Giorgio Chelucci, Giovanna Chessa, Giovanna Delogu, Franco Soccolini

Oxydation catalytique de l'octéne-1 en présence de complexes de rhodium(III) ou de palladium(II) associés à des acides phosphomolybdovanadiques et au dioxygéne Pages C9-C14 Bassal El Ali, Jean-Marie Brégeault, Jacques Martin

Thermal and photochemical olefin isomerizations with complex [(C5Me4H)2Ti(CH3)2] as initiator Pages C1-C4 P. Courtot, R. Pichon, Y. Raoult, J. Y. Salaün

Synthesis of coordinated carbon monoxide from isocyanide iron(II) compounds. Crystal structure of [Fe(dppe)(CO)(CN-p-tol)(p-tolN=C---N-p-tol---C=;N-p-tol)] Pages C5-C8 Victor Riera, Javiex Ruiz, Antonio Tiripicchio and, Marisa Tiripicchio Camellini

Author index Page C24

A simple access to tetrazamborol-2-ines Pages 1-5 F. Truchet, B. Carboni, M. Vaultier, R. Carrié

Organylselenoacetylene und selenocyanate; 77Se- und 13C-NMR-chemische verschiebungen und 77Se- 13C-spin-kopplungskonstanten Pages 7-15 Helmut Poleschner, Reiner Radeglia, Matthias Kuprat, Andreas M. Richter, Egon Fanghänel

Synthese und reaktivität von dienylmetall-verbindungen XXVIII. Über kationen des typs [C5H5Fe(CO)L(EME2)]+ (E = S, Se, Te) Pages 17-29 N. Kuhn, H. Schumann, E. Zauder

Formation and molecular structure of permethylyttrocene methyl tetrahydrofuranate Pages 31-38 Klaas H. Den Haan, Jan L. De Boer, Jan H. Teuben, Wilberth J. J. Smeets and, Anthony L. Spek

The formation, crystal and molecular structures of bis(η5-indenyl)dicarbonyltitanium and bis(η5-indenyl)dicarbonylzirconium Pages 39-54 Marvin D. Rausch, Kevin J. Moriarty, Jerry L. Atwood and, William E. Hunter, Edmond Samuel

Metal-stabilized carbanions IX. The influence of metal basicity on the η6 η5 Haptotropic equilibrium of (fluorenyl)-Cr-(CO)2L anions (L = CO, P(OPh),3, PPh3, P(n-Bu)3) Pages 56-62 Alberto Ceccon, Alessandro Gambaro, Alfonso Venzo, Vittorio Lucchini, Thomas E. Bitterwolf and, Joyce Shade

Kinetische und mechanistische untersuchungen von übergangsmetall-komplex-reaktionen XXII. Konkurrenz zwischen dissoziativem und assoziativem mechanismus bei der reaktion von pentacarbonyl(diphenylcarben)wolfram mit nitrilen Pages 63-75 Helmut Fischer, Siegfried Zeuner

Friedel—Crafts alkylations of ferrocene with unsaturated lactones. Some unusual reactions caused by the β-ferrocenylcarbenium ion Pages 77-83 M. Salisvá, . Toma, E. Solániová

Übergangsmetall-heteroallen-komplexe XVII .Reaktionen des aza-allyl-komplexes (ketenimin)Fe2(CO)6 mit phosphanen Pages 85-99 Thomas Sielisch, Ulrich Behrens

Cyclometallated compounds II. Proton and carbon-13 nuclear magnetic resonance spectral assignments of cyclopalladated compounds Pages 101-114 Peter J. Steel, Graham B. Caygill

Cyclometallated compounds III. Cyclopalladation of phenyl pyrazoles. Crystal structure of acetylacetonato[2-(3-methyl-5-phenylpyrazol-1)C1,N2′]palladium(II) Pages 115-123 Graham B. Caygill, Peter J. Steel

Synthesis and structure of cis-PtX2(P(t-Bu)2CH2CH2CH=CHCH3) (X = Cl, Br), A platinum π-olefin complex formed by the intramolecular activation of a cyclopropylphosphine Pages 125-136 Barbara L. Simms, James A. Ibers

Synthesis and structure of trans-PtCl2(P(t-Bu)2CH2H2)2, A platinum(II) complex containing the new ligand (DI-t-Butyl)cyclobutylmethylphosphine Pages 137-145 Barbara L. Simms, James A. Ibers

Issue 2, Pages 147-283 (23 June 1987)

Synthesis, characterization, and reactivity of the neutral metal formyl (η5-C5Me5)(CO)2(PPh3)MoCHO. A new route to monocationic secondary alkoxycarbene complexes [(η5-C5Me5)(CO)2(PPh3)Mo(CHOE)]+ X− (E = H, Me) Pages C33-C36 Ali Asdar, Claude Lapinte

The photoreaction of the (η-C5H5)Fe(CO)2I—diisopropylamine system with pyrrole and indole Pages C41-C42 Janusz Zakrzewski

The formation and synthetic applications of new acetonitrile derivatives of cycloheptatrienyl-molybdenum and -tungsten complexes; synthesis of binuclear [M(CO)3(η-C5R5)M(CO)2(η-C7H7)] (M = Mo, R = H or Me; M = W, R = H) Pages C29-C32 Roy Breeze, Allen Ricalton, Mark W. Whiteley

Detection of the motions of ancillary bridging ligands during carbon monoxide replacement by trimethylphosphite Pages C37-C40 André Darchen, El Kbir Lhadi, Henri Patin

Author index Page C58

Thia-6 diphényl-3,3 sila-3 (et germa-3)bicyclo[3.1.0]hexanes Pages C25-C28 G. Manuel, A. Faucher, P. Mazerolles

Gmelin handbook of inorganic chemistry, 8th Edition, F — Fluorine, Supplement Volume 4: Compounds with Oxygen and Nitrogen : Springer-Verlag, Berlin, Heidelberg, New York, Tokyo, 1986, xviii + 409 pages, DM 1684. ISBN3-540-93536-3. Page C57 Kenneth R. Seddon

The formation of metal clusters by the facile condensation of electron-deficient metal centres; X-ray crystal structures of (η-C5H5)2Rh4(CO)4Cl2(CF3C2CF3) and (η-C5H5)4Rh4Pt(CO)2(CF3C2CF3)2 Pages C51-C56 Ron S. Dickson, Gary D. Fallon, Michael J. Liddell, Brian W. Skelton and, Alln H. White

A dinuclear triple bonded Ru---Ru compound: preparation and crystal structure of μ,μ′-1,2-phenylenediimine-(N,N′)-dicarbonylbis(triphenylphosphine)diruthenium(Ru---Ru) (I) Pages C43-C46 Adela Anillo, Victor Riera, Ricardo Obeso-Rosete, Manuel Font-Altaba and, Xavier Solans

Synthesis, isolation, and some reactions of hydroxycarbonyl- and alkoxycarbonylruthenium complexes Pages C47-C50 Hiroharu Suzuki, Hideki Omori, Yoshihiko Mor-oka

Single crystal and molecular structure of methylphenyltin(IV) dichloride, intermediate between polymeric and monomeric R2SnCl2 structures Pages 147-155 M. M. Amini, E. M. Holt, J. J. Zuckerman

Synthesis and structural characterization of triphenyltin halide-lactam complexes Pages 157-166 Tadasu Tahara, Hideyuki Imazaki, Katsuyuki Aoki and, Hiroshi Yamazaki

Crystal and molecular structure of 1-(iododimethylsilylmethyl)piperidone-2 Pages 167-172 A. A. Macharashvili, V. E. Shklover, Yu. T. Struchkov, Yu. I. Baukov, E. P. Kramarova and, G. I. Oleneva

Eighteen- and fourteen-electron alumohydride complexes of dicyclopentadienyllutetium. The crystal and molecular structure of monomer (η5-C5H5)2Lu(μ2-H)AlH3·NEt3 with a monodentate alumohydride group Pages 173-179 S. Ya. Knjazhanski, B. M. Bulychev, V. K. Belsky, G. L. Soloveichik

Synthesis and characterization of di-and triorganotin(IV) diethyldithiophosphinates. The crystal and molecular structure of bis(diethyldithiophosphinato)dimethyltin(IV), Me2Sn(S2PEt2)2 Pages 181-191 Cristian Silvestru, Ionel Haiduc, Simona Klima and, Ulf Thewalt, Marcel Gielen, J. J. Zuckerman

Selective carbometallation of α,β-unsaturated carbonyl compounds and substituted oxacyclopropanes with zirconium-diene complexes Pages 193-209 M. Akita, K. Matsuoka, K. Asami, H. Yasuda, A. Nakamura

Bimetallic biphenylene biscarbene complexes: synthesis, x-ray crystal structure and reactivity towards some nucleopphilic reagents Pages 211-221 N. Hoa Tran Huy, P. Lefloch, F. Robert and, Y. Jeannin

Diaminodiphosphen- und aminophosphiniden-komplexe Pages 223-235 Jutta Borm, Gottfried Huttner, Laszlo Zsolnai, Kaspar Evertz, Heinz Berke

Darstellung und charakterisierung kationischer η4-alkenylketonkomplexe des wolframs. Molekülstruktur von {η5-C5Me5(CO)2W[η4-PhCH---CHCOMe]}{BF4}·CH2Cl2 Pages 237-246 Helmut G. Alt, Georg S. Herrmann, Ulf Thewalt

Synthesis and structure of η6-(biphenyl)-η5- (cyclopentadienyl)iron(II) hexaflourophosphates Pages 247-254 R. M. G. Roberts, J. Silver, A. S. Wells, S. P. Wilkonson

Synthese und reaktivität ternärer cluster: thermisch ausgelöste addition von alkinen an (ν3-RP)Fe3(CO)10 Pages 255-267 Konrad Knoll, Gottfried Huttner, Thomas Fässler, Laszlo Zsolnai

Catalytic asymmetric syntheses II. Hydrogenation of α,β-unsaturated ketones using chiral ruthenium complexes Pages 269-273 Viviane Massonneau, Paul Le Maux, Gérard Simonneaux

Synthesis and reactions of some sulfur ylide complexes of palladium Pages 275-283 M. C. Cheng, S. M. Peng, I. J. B. Lin, B. H. H. Meng and, C. H. Liu

Issue 3, Pages 285-436 (7 July 1987)

Subject index Pages C69-C74

Author index Pages C67-C68

Übergangsmetall-substituierte Diphosphene VII. Schwefelylidkomplexe XXIV : Diphosphiranyl-Komplexe [(C5Me5)(CO)2M-2,4,6-t-Bu3C6H2] (M = Fe, Ru) durch Reaktion von Diphosphenyl-Komplexen mit dem Schwefelylid Me2S(O)=CH2 Pages C63-C66 L. Weber, E. Lücke

New molybdenocene dihydrocarbyls Pages C59-C62 A. R. Dias, M. H. Garcia, A. M. Martins, C. I. Pinheiro, C. C. Romão, L. F. Veiros

Synthesis of palladium-tin carbonylphosphine clusters and X-ray study of the Pd3Sn2(acac)4(CO)2(PPh3)3 cluster Pages 285-293 V. V. Bashilov, V. I. Sokolov, Yu. L. Slovokhotov, Yu. T. Struchkov, E. G. Mednikov and, N. K. Eremenko

Catalysis of hydrosilyation. : XII. Spectrophotometric study of the reactivity of the [RhCl(COD)]2-bis(dipenylphosphinoethyl)-tetramethyldisiloxane complex with substrates of the hydrosilylation reaction Pages 295-302 Wojciech Duczmal, Bogdan Marciniec, Wodzimierz Urbaniak

Synthesis of monomeric and oligomeric carbodiimides with polysilane and siloxane fragments Pages 303-309 G. A. Razuvaev, A. S. Gordetsov, A. P. Kozina, T. N. Brevnova, V. V. Semenov, S. E. Skobeleva, N. A. Boxer, Yu. I. Dergunov

Structural studies on octahedral diorganotin(IV) complexes: the influence of substituents in carbon- and heteroatom-donor ligands on [SnR2] skeletal geometry Pages 311-326 V. G. Kumar Das, Yap Chee-Keong, Peter J. Smith

The use of N-benzenethiophthalimide as a reagent in organometallic syntheses: benzenethiolato- and N-phthalimidometal carbonyl complexes Pages 327-337 P. M. Treichel, P. C. Nakagaki, K. J. Haller

Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté Pages 339-356 A. Parlier, H. Rudler, J. C. Daran, C. Alvarez and, F. Delgado Reyes

Übergangsmetall-Silyl-Komplexe : XIX. Mn,H,Si-Dreizentrenbindung in Komplexen mit Phosphinoethylsilyl-chelatiganden Pages 357-363 U. Schubert, K. Bahr, J. Müller

Structure and electron counting of tetrahedral and butterfly M2E2 clusters: an Mo analysis of (LnM)2(μ-X2) (X = P, PR, PM′L5) complexes Pages 365-377 J. -F. Halet, J. -Y. Saillard

Synthese und reaktivität ternärer cluster: Photochemisch ausgelöste insertion von alkinen in (μ3-RP)Fe3(CO)10 Pages 379-392 Konrad Knoll, Gottfried Huttner, Laszlo Zsolnai, Olli Orama

Transition metal-cyanocarbon chemistry : VI. Insertions of cyano- and dicyano-acetylenes into the iron-hydride bonds in (C5H5)(CO)LFeH (L --- CO, PPh3) and [(C5H5)(CO)FeH]2 [μ-(C6H5)2PCH2CH2P(C6H5)2] complexes Pages 393-401 Monique Cariou, Michel Etienne, Jacques E. Guerchais, Rene Kergoat, Marek M. Kubicki

Übergangsmetallkomplexe mit Schwefelliganden : XXX. Struktur, stereoisomerie und reaktivität von eisen-, molybdän- und ruthenium-komplexen mit den fünfzähnigen thioether-thiolat-liganden dpttd2 = 2,3,11,12-dibenzo-1,4,7,10,13-pentathiatridecan(−2) und tbu4-dpttd2− = 14,16,18,20-tetra-t-butyl-2,3,11,12-dibenzo-1,4,7,10,13-pentathiatridecan(−2) Pages 403-418 Dieter Sellmann, Gerhard Binker, Matthias Moll, Eberhardt Herdtweck

Komplexkatalyse : XXVII. Zur anionenkoordination in η3-allylbis-(triphenylphosphit)nickel(II)-komplexen [C3H5Ni(P(OPh)3)2]X (X = PF6, B(O2C6H4)2, BF4, AlBr4, CH3C6H4SO3, Cl, Br, I) und deren einfluss auf die katalytische aktivität der komplexe für die stereospezifische butadienpolymerisation Pages 419-427 Rudolf Taube, Jörg-Peter Gehrke

Stöchiometrische und katalytische CC-verknüpfungen zwischen 1,3-butadien und phenylisocyanat an nickel(0)-komplexen Pages 429-436 Elisa Hernandez, Heinz Hoberg