Volume 334
Main Index

Issues 1-2, Pages 1-261 (3 November 1987)

Preface Page vii Akira Nakamura

The preparation and reductive elimination behavior of trans-Pd(COPh)(CONMe2)(PMe3)2: a model intermediate in the catalytic double carbonylation of aryl halides with amines to give α-keto amides Pages C9-C13 Fumiyuki Ozawa, Li Huang, Akio Yamamoto

Reactions of dicarboalkoxy(di-μ-methylene)bis(pentamethyl-cyclopentadienylrhodium); alkyl acrylates from a three-carbon coupling Pages C17-C19 Isabel M. Saez, David G. Andrews, Peter M. Maitlis

Effects of Lewis acids and bases on the carbotitanation of unsaturated hydrocarbons and ketones with η3-allyl(di-η5-cyclopentadienyl)titanium(III) Pages C1-C4 John J. Eisch, Marek P. Boleslawski

A palladium(II) catalyst for oxygenation of terminal olefins with molecular oxygen Pages C5-C8 Takahiro Hosokawa, Tsukasa Takahashi, Toshiyuki Ohta, Shin-ichi Murahashi

New models for the formation of oxygenates in the Fischer-Tropsch reaction Pages C14-C16 Isabel M. Saez, Peter M. Maitlis

Author index Page C20

Organometallic compounds of the lanthanides : XXXIX. Cyclopentadienylytterbium(II) chlorides, C5R5YbCl(L) Pages 1-7 S. Jagannatha Swamy, Herbert Schumann

Solvent, chelation and concentration effects on the benzannulation reaction of chromium carbene complexes and acetylenes Pages 9-56 Kin Shing Chan, Glen A. Peterson, Timothy A. Brandvold, Katherine L. Faron, Cynthia A. Challener, Carol Hyldahl, William D. Wulff

Metal carbene chelates: stable reactive intermediates in cycloaddition reactions Pages 57-75 Karl Heinz Dötz, Michael Popall, Gerhard Müller

A molecular model for the reductive cleavage of carbon monoxide to carbide and oxide on reduced metal oxides Pages 77-84 Malcolm H. Chisholm

Structural study of titanated phosphonoacetates: reagents for stereoconvergent Knoevenagel condensations Pages 85-92 Manfred T. Reetz, Mark von Itzstein

Synthesis of group 4 metallocene-substituted ylides and their reaction with ketones Pages 91-108 Gerhard Erker, Peter Czisch, Richard Mynott

Activation of C---C bonds in alkanes and cycloalkanes by Ziegler-type systems Pages 109-116 M. E. Vol'pin, I. S. Akhrem, S. V. Reznichenko, V. V. Grushin

Synthesis of Cp(CO)CoPt(PPh3)2(μ-CH2) and Cp2Co2Pt(PPh3)2(μ-CO)2 from the reaction of Pt(PPh3)2(C2H4) with [CPCo(CO)]2(μ-CH2) Pages 117-128 Phillip D. Macklin, Chad A. Mirkin, Nathan Viswanathan, Gregory D. Williams, Gregory L. Geoffroy, Arnold L. Rheingold

Rhodium carbonyl-catalyzed carbonylation of unsaturated compounds : III. Synthesis of α,β-unsaturated ethyl ketones by cross-hydrocarbonylation of acetylenes and ethylene with carbon monoxide and hydrogen Pages 129-140 Pangbu Hong, Takaya Mise, Hiroshi Yamazaki

Reaction of nickel polymerization catalysts with carbon monoxide Pages 141-156 U. Klabunde, T. H. Tulip, D. C. Roe, S. D. Ittel

Novel organic syntheses catalyzed by (cyclooctadiene) (cyclooctatriene) ruthenium and its derivatives Pages 157-167 Take-aki Mitsudo, Yoji Hori, Yoshihisa Watanabe

Stoichiometric and catalytic hydroxy-palladation of conjugated dienes Pages 169-180 Jan-Erik Nyström, Björn Söderberg, Björn Åkermark, Jan-E. Bäckvall

Palladium-catalyzed or -promoted reductive carbon-carbon coupling. Effects of phosphines and carbon ligands Pages 181-194 Ei-ichi Negishi, Tamotsu Takahashi, Kazunari Akiyoshi

Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes : IV. Crystal structure of dichloro[N,N-dimethyl-1-[1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine]palladium(II) (PdCl2[BPPFA]) Pages 195-203 Tamio Hayashi, Makoto Kumada, Taiichi Higuchi and, Ken Hirotsu

Efficient acid fluoride synthesis via carbonylation of organic halides Pages 205-211 Toshiyasu Sakakura, Malinee Chaisupakitsin, Teruyuki Hayashi, Masato Tanaka

Heterocyclic synthesis by the use of the oxidizing potential of palladium(II) Pages 213-223 Yoshinao Tamaru, Zen-ichi Yoshida

A new furan annelation reaction by the palladium-catalyzed reaction of 2-alkynyl carbonates or 2-(1-alkynyl)oxiranes with β-keto esters Pages 225-242 Ichiro Minami, Masami Yuhara, Hiroyuki Watanabe, Jiro Tsuji

Molecular basis of catalytic reactions involving η3-allyl complexes of group 10 metals as key intermediates Pages 243-253 Hideo Kurosawa

From 2-thienylcopper couplings to trimethylsilyl-promoted organocopper additions Pages 255-261 Eva-Lotte Lindstedt, Martin Nilsson, Thomas Olsson

Issue 3, Pages 263-408 (10 November 1987)

Trimethylsilylsubstituierte Cyclopentadienylindium(I) Verbindungen; Synthese and Eigenschaften Pages C24-C26 P. Jutzi, W. Leffers, G. ller

Oxidative addition of O---H bond to a metal centre: synthesis and crystal structure of trans-(PhO)(H)Pd(PCy3)2·PhOH Pages C46-C48 Dario Braga, Piera Sabatino, Cristina Di Bugno, Piero Leoni and, Marco Pasquali

Author index Pages C53-C54

Cyclooctaselenadiazole: synthesis, decomposition pathway, and reaction with (η5-C5H5) Co(L)2 (L = C2H4, PPh3). Crystal and molecular structure of [(η5-C5H5)CO]2(μ2-η3,η2-C8H6Se) Pages C39-C42 Joachim Knebel, Christopher P. Morley, GüntherWilke, Carl Krüger, Julian M. Wallis

Gmelin Handbook of Inorganic Chemistry, 8th edit., Boron Compounds. 3rd Supplement. Volume 2. Boron and Oxygen : by G. Heller, Springer, Berlin, 1987, xvi + 186 pages. ISBN 3-540-93543-6 DM833. Page C51 J. David Smith

Dictionary of Organometallic Compounds. Second Supplement : J.E. Macintyre (Ed.), Chapman and Hall, London, 1986, xiii + 626 pages, £135.00. ISBN 0-412-26331-0. Page C50 Colin Eaborn

Gmelin Handbook of Inorganic Chemistry, 8th edition, Organogallium Compounds, Part 1 : by J.-C. Maire, U. Krüerke, M. Mirbach, W. Petz and C. Siebert. Springer, Berlin, 1987, xiv + 514 pages. ISBN 3-540-93545-2, DM1998. Pages C51-C52 J. David Smith

Subject index Pages C55-C59

Synthesis of binuclear tungsten carbonyls bridged both by hydride and by bidentate phosphine ligands, (μ-H)(μ-Ph2P(CH2)nPPh2)W2(CO)8− (n = 1–4), (μ-H)(μ-(Ph2PCH2)3CMe)W2(CO)8−, and (μ-H)(μ-(η5-C5H4PPh2)2Fe)W2(CO)8− Pages C31-C34 Jiann T'suen Lin, Yu Mei Shiao

The crystal and molecular structure of bis[2-((dimethylamino)methyl)phenyl]cadmium(II) Pages C27-C30 Omar F. Z. Khan, Dario M. Frigo, Paul O'Brien, Andrew Howes, Michael B. Hursthouse

Reaktive π-Komplexe der elektronenreichen Übergangsmetalle, IV. Cyclisierungsreaktionen von t-Butylphosphaacetylen an π-Areneisen-Komplexen Pages C35-C38 M. Driess, D. Hu, H. Pritzkow, H. Schäufele, U. Zenneck, M. Regitz and, W. Rösch

Hypercarbon Chemistry : by G.A. Olah, G.K.S. Prakash, R.E. Williams, L.D. Field, and K. Wade, Wiley, New York, Chichester etc., 1987. xvi + 311 pages £47.95. ISBN 0-471-06473-4. Pages C49-C50 Colin Eaborn

Co2(CO)8-mediated and -catalyzed carbonylation of diaryl diselenides and ditellurides to seleno and telluro esters Pages C43-C45 Hidetaka Takahashi, Kouichi Ohe, Sakae Uemura, Nobuyuki Sugita

Polylithiumorganische Verbindungen , : VII. Dilithioacetylen statt 1,2-Dilithioethan bei der Reaktion von Ethylen mit Lithium, eine Korrektur Pages C21-C23 Adalbert Maercker, Burkhard Grebe

Sur l'effet ipso du silicium lors de l'acylation du m-trimethylsilylanisole Pages 263-267 B. Bennetau, M. Krempp, J. Dunoguès

The molecular structure of triphenylsilane from gas-phase electron diffraction Pages 269-276 Béla Rozsondai, István Hargittai

Zur Synthese von Siloxanen : VIII. Zum Mechanismus der Säurekatalyse bei der Hydrolyse von Chlorsiloxanen Pages 277-282 J. Brumme, U. Scheim, A. Porzel, K. Rühlmann and, H. Grosse-Ruyken

Crystal structure of tribenzyl(2-pyridinethiolato-N-oxide)tin(IV): a rare example of a square pyramidal organotin(IV) compound Pages 283-293 Seik Weng Ng, Chen Wei, V. G. Kumar Das, Thomas C. W. Mak

Skew-trapezoidal bipyramidal diorganotin(IV) bischelates. Crystal structure of dimethylbis(2-pyridinethiolato-N-oxide)tin(IV) Pages 295-305 Seik Weng Ng, Chen Wei, V. G. Komar Das, Thomas C. W. Mak

Studies on C-heterocyclic tin compounds. The synthesis and spectral characterization of some thienyl tetraorganotin(IV) compounds Pages 307-322 V. G. Kumar Das, Lo Kong Mun, Stephen J. Blunden

The preparations and properties of tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf = CF3, C2F5, n-C3F7, n-C4F9, n-C6F13, n-C8 F17, C6F5) Pages 323-328 Dieter Naumann, Wieland Tyrra

The use of aminoiminomethanesulfinic acid (thiourea dioxide) under phase transfer conditions for generating organochalcogenate anions. Synthesis of sulfides, selenides and tellurides Pages 329-340 J. V. Comasseto, E. S. Lang, J. Tercio, B. Ferreira and, F. Simonelli, V. R. Correia

The crystal structure of tetrachloro(diethylphthalate)titanium(IV) Pages 341-345 Józef Utko, Piotr Sobota, Tadeusz Lis

Synthese und Reaktivität von ferrocenyl-pentacarbonylmangan, Mn(CO)5Fc Pages 347-358 Max Herberhold, Heidemarie Kniesel

Synthesis and multinuclear NMR data of the ferrocenes (Me3Ecp)2Fe (E = C, Si, Ge, Sn, Pb) Pages 359-367 F. H. Köhler, W. A. Geike, N. Hertkorn

Asymmetrische Katalysen : XXXV. Neue optisch aktive, einzähnige Phosphine aus α-Pinen und Mannit. Rhodium-Komplexe und enantioselektive Katalysen Pages 369-376 Henri Brunner, Helmut Leyerer

Aktivierung von Kohlendioxid an Übergangsmetallzentren: Selektive Cooligomerisation mit Hexin(−3) durch das Katalysatorsystem Acetonitril/Trialkylphosphan/Nickel(0) und Struktur eines Nickel(0)-Komplexes mit side-on gebundenem Acetonitril Pages 377-388 Dirk Walther, Hartmut Schönberg, Eckard Dinjus, Joachim Sieler

Perhalophenyl complexes of palladium(II) containing keto-stabilized phosphorus ylides of the type Ph2P(CH2)nPPh2CHC(O)R Pages 389-397 R. Usón, J. Forniés, R. Navarro, A. M. Ortega

Synthesis and reactivity of palladium complexes with N,N′-di-p-tolyl-formamidine, -triazene or -formamidinato ligands. Insertion of CNC6H4Me-p, CS2 or CO2 into a Pd---N bond Pages 399-408 Rafael Usón, Juan Fornies, Pablo Espinet, Elena Lalinde