Volume 370
Main Index

Issues 1-3, Pages 1-419 (11 July 1989)

Asymmetric reactions catalyzed by chiral metal complexes : XXXII. Efficient asymmetric hydrogenation of itaconic acid derivatives catalyzed by rhodium complexes of improved (2S,4S)-N-(t-butoxycarbonyl)-4-(diphenylphosphino)-2-[(diphenylphosphino)methyl]pyrrolidine (BPPM) analogues Pages C9-C12 Kiyoshi Inoguchi, Toshiaki Morimoto, Kazuo Achiwa

Asymmetric cyclization of 2-alkenylphenols. A comparative study on the use of palladium(II) and titanium(IV) complexes Pages C13-C16 Takahiro Hosokawa, Takanori Kono, Toru Shinohara, Shun-Ichi Murahashi

Asymmetric synthesis of R-α-methyl-o-methoxybenzyl methyl ether via the diastereoselective functionalisation of +(−)-(o-methoxybenzyl methyl ether)chromium tricarbonyl Pages C5-C8 Stephen G. Davies, Craig L. Goodfellow

Author index Pages C22-C23

The stereochemistry at silicon of an iron to cyclopentadienyl ligand silyl group migration in (η5-C5H5)Fe(CO)2SiR3 Pages C1-C4 Stuart R. Berryhill, Robert J. P. Corriu

Subject index Pages C24-C28

Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives Pages C17-C21 Dennis M. Dalton, J. A. Gladysz

Asymmetric deuteration and deuteriooligomerization of 1-pentene Pages 1-7 P. Pino, M. Galimberti

Hypervalent silicon hydrides: evidence of their intermediacy in the reaction of optically active 1-NpPhMeSiH(D) with hydrides Pages 9-15 J. L. Brefort, R. Corriu, C. Guérin, B. Henner

Asymmetrische katalysen : XLVI. Enantioselektive Hydrosilylierung von Ketonen mit [Rh(COD)Cl]2 und optisch aktiven Stickstoff-Liganden Pages 17-31 Carlo Botteghi, Alberto Schionato, Giorgio Chelucci, Henri Brunner, Alfred Kürzinger and, Uwe Obermann

Diastereoselective synthesis of a resolved secondary arsine complex: asymmetric synthesis of (R-(−)589-ethylmethylphenylarsine Pages 33-41 Geoffrey Salem, S. Bruce Wild

Asymmetric oxidation of some 1,3-dithianes in presence of chiral titanium complexes Pages 43-50 O. Samuel, B. Ronan, H. B. Kagan

Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L = (+)-neomenthyl-PPh2) Pages 51-64 Gerard Jaouen, James A. S. Howell, Marie-Claire Tirvengadum, Patrick McArdle and, Desmond Cunningham

Framework chirality and optical activity of organometallic cluster compounds Pages 65-73 Heinrich Vahrenkamp

Synthesis and properties of optically active organomolybdenum compounds Pages 75-80 Kevin J. Moriarty, Marvin D. Rausch

Enantioselective epoxidation of unfunctionalized simple olefins by non-racemic molybdenum(VI)(oxo-diperoxo) complexes Pages 81-96 V. Schurig, K. Hintzer, U. Leyrer, C. Mark, P. Pitchen and, H. B. Kagan

Transition metal mediated asymmetric synthesis : X. Homochiral π-complexes with planar chirality: synthetic equivalents of chiral cyclohexadiene dications Pages 97-109 Philip W. Howard, G. Richard Stephenson, Stephen C. Taylor

Enantioselective benzylidene transfer reactions using the chiral-at-iron benzylidene complexes (SFeSc)- and (RFeSc)-Cp(CO)(Ph2RP_Fe=CH6H5+ (R = (S-2-methylbutyl) and SFe- and (RFe)-Cp(CO)PEt3Fe=CHC6H5+ Pages 111-127 Maurice Brookhart, Robert C.Buck

Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes : VII. New chiral ferrocenylphosphines with C2 symmetry Pages 129-139 Tamio Hayashi, Akihiro Yamamoto, Masahiro Hojo, Kohei Kishi, Yoshihiko Ito, Eriko Nishioka, Hitoshi Miura and, Kazunori Yanagi

Rhodium(I) complexes of β-diketonates and related ligands as hydrosilylation catalysts Pages 141-154 William R. Cullen, Eugene B. Wickenheiser

Resolution of the chiral η6-methyl-o-toluate complex [RuCl2(η6-o-MeC6H4CO2Me)]2. Crystal structure and absolute configuration of the (+)-neomenthyldiphenylphosphine (NMDPP) complex RuCl2(η6-o-MeC6H4CO2Me)-[(+)-NMDPP] Pages 155-171 Piero Salvadori, Paolo Pertici, Fabio Marchetti, Raffaello Lazzaroni, Giovanni Vitulli, Martin A. Bennett

Preparation, crystal structure, absolute configuration, and conformational analysis of (−)436-(S)-(−)-diphenyl-1-phenylethylaminophosphine(η5-pentamethylcyclopentadienyl)-dimethylphosphonato)cobalt(III) Pages 173-185 Chet Jablonski, Timothy Burrow, Peter G. Jones

Enantioselective hydrogen transfer reactions from propan-2-ol to ketones catalyzed by pentacoordinate iridium(I) complexes with chiral Schiff bases Pages 187-202 Grazia Zassinovich, Roberto Bettella, Giovanni Mestroni, Nevenka Bresciani-Pahor, Silvano Geremia, Lucio Randaccio

Preparation of optically active peralkyldiphosphines and their use, as the rhodium(I) complex, in the asymmetric catalytic hydrogenation of ketones Pages 203-221 Kazuhide Tani, Kenichi Suwa, Eiji Tanigawa, Tomokazu Ise, Tsuneaki Yamagata, Yoshitaka Tatsuno, Sei Otsuka

Enantioselektive Katalyse : VII. Komplexe von (P(R,S),3R,4R,P′(R,S))-3,4-Bis(phenylphosphino)pyrrolidinen. Die Darstellung optisch reiner 1,2-Bisphosphanliganden mit vier Stereozentren, die zusätzliche funktionnelle Gruppen enthalten Pages 223-239 Ulrich Nagel, Bernhard Rieger, Alexander Bublewitz

Carbohydrate phosphinites as chiral ligands for asymmetric synthesis catalyzed by complexes : V. New rhodium(I)-chelates prepared by precipitation from the equilibrium between neutral and cationic complexes and hydrolysis of their bonded ligands Pages 241-248 Rüdiger Selke

Carbohydrate phosphinites as chiral ligands for asymmetric synthesis catalyzed by complexes : VI. Rhodium(I)-[2,3-O-bis(diphenylphosphino)-β--glucopyranoside] chelates with free hydroxyl groups in the 4,6-positions of the carbohydrate as excellent catalysts in asymmetric hydrogenation Pages 249-256 Rüdiger Selke

Asymmetric hydroformylation with Pt-phosphine-SnCl2 and Pt-bisphosphine-CuCl2 (or CuCl) catalytic systems Pages 257-261 László Kollár, József Bakos, Imre Tóth, Bálint Heil

Catalytic and structural studies of RhI complexes of (−)-(2S,4S)-2,4-bis(diphenylphosphino)pentane. Asymmetric hydrogenation of acetophenonebenzylimine and acetophenone Pages 263-276 J. Bakos, I. Tóth, B. Heil, G. Szalontai, L. Párkányi and, V. Fülöp

Chiral sulphonated phosphines : II. Influence of water on the enantioselectivity in the reduction of dehydro-aminoacids Pages 277-284 Loïc Lecomte, Denis Sinou, Jozsef Bakos, Imre Tóth and, Balint Heil

Optically active phenanthrolines in asymmetric catalysis : II. Enantioselective transfer hydrogenation of acetophenone by rhodium/alkyl phenanthroline catalysts Pages 285-294 Serafino Gladiali, Giorgio Chelucci, Franco Soccolini, Giovanna Delogu, Giovanna Chessa

Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from -glucose and -galactose Pages 295-304 Vitomir unji, Ivan Habu, Günther Snatzke

Indenyl complexes of ruthenium(II) containing optically active diphosphines. X-ray structures of (S,S)-(η5-C9H7)-Ru{Ph2PCH(CH3)CH(CH3)PPh2}Cl and of its η5-C5H5 analogue Pages 305-318 Franco Morandini, Giambattista Consiglio, Angelo Sironi, Massimo Moret

Optimization of asymmetric hydrogenation of 3-phenyl-3-butenoic acid catalyzed by rhodium(I)-4,5-bis[(diphenylphosphino)methyl]-2,2-dimethyldioxolane (DIOP), Pages 319-332 Keiji Yamamoto, Kiyoshi Ikeda, Leong Kwai Yin

Utilisation des ligands aminophosphinephosphinites en hydroformylation catalysée par le rhodium: amélioration de l'énantioselectivité par synthèse selective des hydrures RhH(CO)2L2 Pages 333-342 Y. Pottier, A. Mortreux, F. Petit

Metal controlled enantioselectivity in the catalytic asymmetric hydrosilylation Pages 343-349 Annegret Kinting, Hans-Jörn Kreuzfeld, Hans-Peter Abicht

Homogeneous asymmetric catalysis by means of chiral metal complexes of 2,3-bis(dimenthylphosphino)maleic anhydride and of 2,3-bis(dimenthylphosphino)maleimide derivatives Pages 351-356 Annegret Kinting, Christian Döbler

Transition metal catalyzed asymmetric cross coupling reactions. New ligands and the effects of added salts. Crystal structures of [Ph2PCH2CH{(CH2)3SMe}NMe2]·PdCl2 and [Ph2PCH2CH{(CH2)2SMe}NMe2]·PdCl2 Pages 357-381 Graham Cross, Bindert K. Vriesema, Gerd Boven, Richard M. Kellogg, F. van Bolhuis

Palladium-catalyzed asymmetric synthesis of axially chiral molecules Pages 383-396 J. C. Fiaud, J. Y. Legros

Reactive intermediates in asymmetric cross-coupling catalysed by palladium P-N chelates Pages 397-406 Karen V. Baker, John M. Brown, Neil A. Cooley, Gareth D. Hughes, Richard J. Taylor

Dynamic behaviour and X-ray analysis of chiral η3-allylpalladium complexes. II Pages 407-419 Edoardo Cesarotti, Maria Grassi, Laura Prati, Francesco Demartin