Issue 1, Pages 1-126 (26 June 1990)
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Cr(CO)5(CNCN), a complex in which the coordinated CN group of isocyanogen binds and vibrates like a CO ligand Pages c1-c5 G. C. Schoemaker, D. J. Stufkens, S. J. Goede, T. van der Does and, F. Bickelhaupt |
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Author index Page c20 |
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Indium monohalide insertion reactions into metal—metal bonds. Crystal structure of [InCl(THF){Mo(CO)3(η-C5H5)}2] Pages c10-c15 L. M. Clarkson, N. C. Norman, L. J. Farrugia |
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Asymmetric synthesis of chiral amines via nucleophilic addition to ferrocenylalkyl substituted imines Pages c6-c9 Dorothy M. David, Leon A. P. Kane-Maguire, Stephen G. Pyne |
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Distinct reaction pathways for some classical and nonclassical transition metal dihydrides Pages c16-c19 Claudio Bianchini, Maurizio Peruzzini, Fabrizio Zanobini |
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Modifizierte Isopinocampheyldibromborane; selektive Katalysatoren für asymmetrische Diels-Alder-rekationen Pages 1-6 Gerhard Bir, Dieter Kaufmann |
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Reaction of phenyl(trimethylsilyl)silylene with chloromethanes; Insertion into the C---Cl bond and abstraction of chlorine and HCl Pages 7-18 Kunio Oka, Ren Nakao |
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Synthesis of triorganostannate esters of dicarboxylic acids. Crystal structure of bis(dicyclohexylammonium) trisoxalatotetrakis(tri-n-butylstannate) · 2 ethanol Pages 19-28 Seik Weng Ng, V. G. Kumar Das, M. B. Hossain, F. Goerlitz and, Dick van der Helm |
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The crystal and molecular structure of chloro-p-ethoxyphenyl-2-(2-pyridyl)phenyltelluronium(IV) trichloromercurate(II), a novel telluronium salt Pages 29-34 Tarlok S. Lobana, Shaaban A. Mbogo, William R. McWhinnie, Wyona C. Patalinghug and, Allan H. White |
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Dicyclopentadienylsamarium complexes with t-butyl substituents in the ring. Crystal and molecular structures of the solvate (η5-C5H3Bu2t)2Sm · OC4H8 and homoleptic ate complex [NaSm(η5:η2-C5H4But)3 · OC4H8]n Pages 35-44 V. K. Bel'sky, Yu. K. Gunko, B. M. Bulychev, A. I. Sizov, G. L. Soloveichik |
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Metallorganische verbindungen der lanthanoide : LVI. Synthese und röntgenstrukturanalyse von [Li(THF)4][(C5H5)2Lu(NPh2)2] Pages 45-52 Herbert Schumann, Eftimios Palamidis, Jörg Loebel |
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Metallacyclen des zirkonocens Pages 53-60 Helmut G. Alt, Christine E. Denner |
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Matrix photochemistry of the complexes (CO)5M = C(OMe)Ph (M = Cr, W) having close-lying reactive MLCT and LF states Pages 61-71 Peter C. Servaas, Derk J. Stufkens, Ad Oskam |
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Synthesis of new ferrocenyl amine sulfide and selenide complexes of group 10 metals and their catalytic activities toward selective hydrogenation, isomerization, and asymmetric Grignard cross-coupling reactions Pages 73-90 Ahmad A. Naiini, Chung-Kung Lai, Donald L. Ward, Carl H. BrubakerJr. |
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Kinetics and mechanism of the addition of methoxide ion to the π-hydrocarbon ligands in [HOs3(η2-CH=CH2)(CO)10] and [CpFe(CO)2(η2-CH2=CH2)]PF6 Pages 91-95 Tahany Ghazy, Leon A. P. Kane-Maguire, Kim Do |
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Reductive carbonylation of cobalt(II) salts containing weakly-coordinating anions in the presence of diphosphine ligands Pages 97-104 Alessandro Del Zotto, Pierluigi Rigo |
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Hex-1-ene hydroformylation catalyzed by Rh(acac){P(OPh)3}2 modified with amines, formation of reactive HRh(CO){P(OPh)3}3 and unreactive Rh4(CO)8{P(OPh)3}4 species Pages 105-111 A. M. Trzeciak |
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Crystal and molecular structure of 2,3-η2-(1,4-dimethoxybut-2-yne)bis(tricyclohexylphosphane)nickel(0), (Cy3P)2Ni(MeOCH2C---CCH2OMe); influence of phosphane ligands on acetylene complexation in nickel(0) complexes Pages 113-120 U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. V. Polyakov, A. I. Yanovsky and, Yu. T. Struchkov |
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Carbon-carbon bond formation upon ligand displacement from bis(chloromethyl)(1,5-cyclooctadiene)platinum(II) with tricyclohexylphosphine. X-ray structure of trans-di-μ-chlorobis(2-tricyclohexylphosphonioethyl)-bis(tricyclohexylphosphine)diplatinum(II) bis(hexafluorophosphate) Pages 121-126 Robert McCrindle, George Ferguson, Gilles J. Arsenault, Mark J. Hampden-Smith, Alan J. McAlees, Barbara L. Ruhl |
Issue 2, Pages 127-274 (3 July 1990)
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Synthesis and molecular structure of [η5-C5H5Mo(CO)2]2(μ,η2-Sb2). Formation of an Sb=Sb double bond from metallic antimony Pages c36-c38 James R. Harper, Arnold L. Rheingold |
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Bindungscharakteristik der H2-koordinierenden Fragmente W(CO)3(PR3)2. Aussergewöhnliche optische und elektrochemische Eigenschaften zweikerniger Pyrazinkomplexe Pages c45-c49 Wolfgang Bruns, Wolfgang Kaim |
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Reaction of alkenyl carbonyl ruthenium(II) complexes with t-butyl isocyanide. Synthesis of η1-acylruthenium(II) complexes by intramolecular CO insertion Pages c57-c60 Julio Montoya, Amelia Santos, Antonio M. Echavarren, Josep Ros |
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Photochemical generation of pyridine- and polypyridine-Co(I) complexes by visible light irradiation of [Co(bpy)3](BPh4)2 and [Co(py)6](BPh4)2 Pages c61-c63 Paolo Biagini, Tiziana Funaioli, Alberto Juris, Giuseppe Fachinetti |
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On the stereochemistry of chiral (η5-C9H7)Rh(diphosphine) complexes Pages c64-c68 Franco Morandini, Giambattista Consiglio |
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Electrogeneration of the molybdenum-molybdenum double bond from thiolate-bridged dinuclear precursors: carbon monoxide catalysed isomerisation about the Mo=Mo bond Pages c39-c44 Christine Le Floc'h, François Y. Pétillon, Christopher J. Pickett, Jean Talarmin |
Synthesis and structure of heterometallic cluster complexes. Reaction of imido complex LWRu2(CO)8(μ-H)(μ3-NPh), L = CP and Cp , with the tungsten acetylide complex CpW(CO)3C CPhPages c50-c56 Yun Chi, Ling-Kang Liu, Gottfried Huttner, Laszlo Zsolnai |
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The Elements : by John Emsley, Oxford University Press, Oxford, 1989, vii + 256 pages, £9.95 (soft cover). ISBN 0-19-855237-8 Pages c69-c70 Penny A. Chaloner |
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Author index Page c72 |
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1,1,2,2,9,9,10,10-Octamethyl-1,2,9,10- tetragerma[2.2]paracyclophane: the first [2.2]paracyclophane bridged by two Ge---Ge bonds Pages c27-c31 Akira Sekiguchi, Tetsuo Yatabe, Chizuko Kabuto, Hideki Sakurai |
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Charge relocation in cationic diene complexes: formation of an iminium-substituted allyl complex and its deprotonation to an enamine Pages c32-c35 Stephen A. Benyunes, Michael Green |
Synthesis of organozinc enolates of N,N-disubstituted glycine esters. Crystal structure of [Et (t-Bu)Me]4Pages c21-c26 Fred H. van der Steen, Jaap Boersma, Anthony L. Spek, Gerard van Koten |
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Comparison of the allylation reactions of aldehydes using allylstannanes with boron trifluoride etherate and boron trichloride Pages 127-138 Daniele Marton, Giuseppe Tagliavini, Michele Zordan, James L. Wardell |
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Isotope 13/12C effects on 119Sn nucleus shielding in ethynylstannanes Pages 139-152 E. Liepi   , I. Bir ele, E. Lukevics, E. T. Bogoradovsky and, V. S. Zavgorodny |
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The crystal and molecular structure of the 20-electron alumohydride complex of bis(t-butylcyclopentadienyl)samarium {[(η5-C5H4But)2Sm(μ3-H)][(μ2-H)2AlH·OC4H8]}2 Pages 153-158 Yu. K. Gun'ko, B. M. Bulychev, A. I. Sizov, V. K. Bel'sky, G. L. Soloveichik |
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Acetylenkomplexe des titanocens als ausgangsverbindungen für fünfgliedrige titanacyclen Pages 159-169 Helmut G. Alt, Georg S. Herrmann |
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Note on the solvent dependence of the 1H-NMR coordination chemical shifts of tricarbonyl(η6-[8]paracyclophane) chromium. A caveat concerning its interpretation Pages 171-177 L. W. Jenneskens, W. H. de Wolf, F. Bickelhaupt |
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Friedel-Crafts acylation of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe(η5-C5H5) and crystal structure of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe(η5-C5H4)C(O)(η5-C5H4)Cr(CO)2(NO) Pages 179-192 Yu-Pin Wang, Jin-Mei Hwu, Sue-Lein Wang |
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Amidinato complexes of dicyclopentadienylmolybdenum. Synthesis and redox properties Pages 193-201 A. R. Dias, M. A. Queirós |
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Organometallic derivatives of diphosphinoamines, X2PN(R)PX2. Reactions with carbonyl derivatives of group 6 metals and iron pentacarbonyl. The crystal structures of [Mo(CO)4PhN(P(OPh)2)2] and [W(CO)4iPrN(PPh2)2] Pages 203-216 M. S. Balakrishna, T. K. Prakasha, S. S. Krishnamurthy, U. Siriwardane and, N. S. Hosmane |
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Spectroscopic investigation of chalcone-analogous ferrocenes ortho-substituted in the aromatic ring Pages 217-225 Ágnes G. Nagy, Pál Sohár |
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Cryptates from cryptands containing the ferrocene unit. Determination of equilibria stoicheiometries and stability constants Pages 227-235 C. Dennis Hall, Ian P. Danks, Nelson W. Sharpe |
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Diazadiene stabilized butadiene nickel(0) complexes: Synthesis, characterization and reaction with acetylene and carbon monoxide. Crystal structures of (dad)Ni-μ[σ1,4; η1–4-C4H4]Ni(dad) and (dad)Ni-μ[σ1,4; η1–4-C4H4]Ni(CO)2 Pages 237-250 Jacobus C. M. Sinnema, Gert H. B. Fendesak, Heindirk tom Dieck |
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Conformational effects in elementary steps in catalytic reactions. Oxidative addition of 3-bromoprop-1-ene to a palladium(II) metallacyclic complex Pages 251-255 Marta Catellani, Brian E. Mann |
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Synthesis and reactivity of palladium and platinum complexes containing the bis(diphenylphosphino) methanide ligand Pages 257-265 J. Forniés, R. Navarro, E. P. Urriolabeitia |
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Carbon monoxide insertion into trans-Pt(η1-C3H5)-(phosphine2)Cl complexes in benzene. Crystal structure of trans-[Pt(COCH2CH=CH2](PPh3)2Cl Pages 267-274 S. Dirè, R. Campostrini, G. Carturan, M. Calligaris and, G. Nardin |
Issue 3, Pages 275-407 (10 July 1990)
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Cyclopalladated 2-t-butyl-4,4-dimethyl-2-oxazoline: its preparation, and use in the functionalisation of a non-activated carbon-hydrogen bond Pages c84-c88 G. Balavoine, J. C. Clinet |
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Subject index Pages c95-c102 |
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Unusually facile formation of a hexa-coordinated bisamine adduct by tetrakis(pentafluorophenyl)porphinatocobalt(II) and azaferrocene Pages c77-c80 Janusz Zakrzewski, Charles Giannotti |
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Synthesis of tris(trifluoromethyl)gallium and its adducts Pages c73-c76 M. A. Guerra, S. K. Mehrotra, D. W. Dyer, R. J. Lagow |
Relative donor properties of sp3 and sp2 hybridised phosphorus atoms of the azadiphosphetine ring system R R′ (R = Et3C, R′ = But) towards transition metalsPages c89-c92 Robson Matos, Mohamed F. Meidine, John F. Nixon, Bernadette F. Trigo Passos, Edgar Niecke and, Detlef Barion |
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Author index Pages c93-c94 |
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Asymmetric catalysis LVI. Enantioselective hydrosilylation of acetophenone with a rhodium/picolineoxazoline catalyst 1:1 Pages c81-c83 Henri Brunner, Paul Brandl |
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The reaction of benzotrihalides and benzal halides with magnesium. Synthetic and mechanistic studies Pages 275-292 E. C. Ashby, Dheya M. Al-Fekri |
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Monoorganomercury and diorganothallium derivatives of 2-thiobarbituric acid Pages 293-300 3aría S. García Tasende, Maria I. Suárez Gimeno, A. Sánchez, J. S. Casas, J. Sordo |
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Metallorganische verbindungen der lanthanoide LVIII. Zur struktur des dicyclopentadienyl-bis(trimethylsilyl)lutetat-anions Pages 301-308 Herbert Schumann, Juliana A. Meese-Marktscheffel, F. Ekkehardt Hahn |
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[(Me3Sn)2(Me3Sb)M(CN)6]∞ (M = Fe, Ru): Neuartige Organo-SnIV/SbV-Polymere von besonderer chemischer und thermischer stabilität Pages 309-315 Stefan Eller, Susan Dülsen, R. Dieter Fischer |
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Phosphiniden- und arsiniden-komplexe mit pentamethylcyclopentadienyl (Cp)-liganden am gruppe 15-element: Synthese und Cp-übertragung Pages 317-322 Peter Jutzi, Rainer Kroos |
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Reaktionen von (η2-formaldehyd)zirconocen-dimer mit heterokumulenen Pages 323-331 Gerhard Erker, Miguel Mena, Stefan Werner and, Carl Krüger |
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Synthesis, structure and properties of molybdenum(0) bialkyne complexes Pages 333-337 J. S. Lain, C. H. Cheng, C. Y. Cheng, S. L. Wang |
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Synthese und Charakterisierung von 1,3-dithia-2-boryl-[3]ferrocenophanen Pages 339-344 Dietmar Fest, Carl D. Habben |
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Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where DPPF = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes Pages 345-350 T. S. Andy Hor, Lai-Tee Phang |
Reactions of tungsten and molybdenum propargyl complexes with Co2(CO)8, Co4(CO)12, and Cp2Mo2(CO)4. A crossover study of formation of (CO)3 Cp(CO)2Pages 351-360 George H. Young, Andrew Wojcicki |
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Carbene derivatives of areneruthenium(II) complexes in one step from terminal alkynes Pages 371-378 Dominique Devanne, Pierre H. Dixneuf |
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Arene—ruthenaborane clusters I. Products of the reaction between [{(η6-C6Me6)2Ru2H4}RuB10H8(OEt)2] and carbon monoxide. Nuclear magnetic resonance studies and the crystal structure of [{(η6-C6Me6)2Ru2H2(CO)2}RuB10H8(OEt)2] Pages 379-387 M. Bown, J. M. Waters, X. L. R. Fontaine and, J. D. Kennedy |
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Efficient palladium-catalyzed synthesis of unsymmetrical donor—acceptor biaryls and polyaryls Pages 389-398 Christian Amatore, Anny Jutand, Serge Negri, Jean-Francois Fauvarque |
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Synthesis and decomposition of neutral palladium(IV) complexes containing fac-PdMe2R groups, including reductive elimination by η1-propenylpalladium(IV) complexes to form η3-propenylpalladium(II) species Pages 399-407 Peter K. Byers, Allan J. Canty, Peter R. Traill, Andrew A. Watson |