Issues 1-2, Pages 1-433 (23 August 1996)
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Editorial Board Page iii |
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Editorial note Page ix Colin Eaborn |
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Preface (English and French) Pages xi-xv Joël Moreau |
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Poly(silylenemethylenes) — a novel class of organosilicon polymers Pages 1-10 L. V. Interrante, Q. Liu, I. Rushkin, Q. Shen |
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Silyl substitution as an aid in polymerization reactions: oxidative coupling of silylthiophene, a route to highly conjugated polythiophene Pages 11-19 Jean-Pierre Lère-Porte, Joël J. E. Moreau, Jean-Louis Sauvajol |
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Ring-opening polymerization of nitrogen-containing cyclic organosilicon monomers Pages 21-27 M. Bouquey, C. Brochon, S. Bruzaud, A-F. Mingotaud, M. Schappacher, A. Soum |
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Synthesis and structure of 1,6-diaza-2,2-dimethoxy-2-silacyclooctane Pages 29-31 Wolfgang Ziche, Burkhard Ziemer, Peter John, Johann Weis, Norbert Auner |
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Cobalt deposition in porous silicon by chemical vapour infiltration and deposition; the effects of precursor instability Pages 33-37 B. J. Aylett, L. G. Earwaker, K. Forcey, T. Giaddui, I. S. Harding |
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Zinc silanethiolates: synthesis and properties. Crystal structures of bis(tri-tert-butoxysilanethiolato)(acetonitrile)zinc(II) and bis(tri-tert-butoxysilanethiolato)(bipyridine)zinc(II) Pages 39-49 Barbara Becker, Krzysztof Radacki, Wies  aw Wojnowski |
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Interactions in crystals CX. The structure of 9,10-bis(diisopropylsilyl) anthracene and of its “naked” radical anion Pages 51-63 Hans Bock, Manssur Ansari, Norbert Nagel, Rodney F. C. Claridge |
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Hydrosilane cleavage reactions accelerated by tartaric acid and dimethyl sulphoxide Pages 65-74 Michael J. Roth, Michael A. Brook, Helen B. Penny |
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Reactions of symmetrical and unsymmetrical disilanes in the presence of Cp2MCl2/nBuLi (M = Ti, Zr, Hf) Pages 75-91 J. Y. Corey, S. M. Rooney |
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Gas phase studies of silacyclobutanes: recent developments employing triple quadrupole detection Pages 93-98 Robert Damrauer, Joseph A. Hankin |
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Synthesis of disilylmethanes and polysilacarbosilanes, precursors of silicon carbide-based materials Pages 99-107 Eric Bacqué, Marc Birot, Jean-Paul Pillot, Paulette Lapouyade, Pierre Gerval, Claude Biran, Jacques Dunoguès |
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A bulky tris(trisilyl)methyl ligand incorporating a donor sulfur atom: some (Me3Si)2(PhSMe2Si)CSnMe2X compounds Pages 109-112 Dmitry A. Antonov, Colin Eaborn, J. David Smith, Peter B. Hitchcock, Elias Molla, Valeria I. Rozenberg, W  odzimierz A. Sta cyk, Anna Kowaleska |
Iodo(methoxydimethylsilyl)bis(trimethylsilyl)methane: a reagent for the preparation of novel organometallic compounds. Crystal structures of  Me)}2 and MgI2(OEt2)2Pages 113-120 Colin Eaborn, Peter B. Hitchcock, Anna Kowalewska, Zheng-Rong Lu, J. David Smith, Wlodzimierz A. Sta  czyk |
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The reactions of phenyldimethylsilyllithium with nitriles Pages 121-124 Ian Fleming, Monica Solay, Frederik Stolwijk |
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Formation of organosilicon compounds 115: the applicability as precursors for β-SiC of carbosilanes resulting from the gas phase pyrolysis of methylsilanes Pages 125-131 D. Tögel, A. Antony, J. Bill, Petra Scheer, A. Eichhöfer, G. Fritz |
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A systematic analysis of the structure-reactivity trends for some ‘cation-like’ early transition metal catalysts for dehydropolymerization of silanes Pages 133-143 Vladimir K. Dioumaev, John F. Harrod |
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Si---H-containing cyclosilanes and their behaviour in the dehydrogenative polymerization reaction Pages 145-155 Edwin Hengge, Peter Gspaltl, Erich Pinter |
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NMR spectra of phenoxysilanes with various silyl groups Pages 157-162 Paul F. Hudrlik, Donald K. Minus |
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Palladium-catalyzed reactions of 1,1,2,2-tetraethyl- and 1,1,2,2-tetra(isopropyl)-3,4-benzo-1,2-disilacyclobut-3-ene with alkynes Pages 163-170 Akinobu Naka, Taiichi Okada, Mitsuo Ishikawa |
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A reappraisal of the stereochemistry of polysilylenes formed by the Wurtz reductive-coupling reaction Pages 171-176 Richard G. Jones, Robert E. Benfield, Philip J. Evans, Simon J. Holder, Julius A. M. Locke |
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2-(Alkoxymethyl)phenylsilicon compounds: the search for pentacoordination Pages 177-183 A. Mix, U. H. Berlekamp, H. -G. Stammler, B. Neumann, P. Jutzi |
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Penta- and hexacoordinate silicon compounds with phosphorus donors Pages 185-190 Hans H. Karsch, Roland Richter, Eva Witt |
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Addition and cycloaddition reactions of di-tert-butyl(di-tert-butylphenylsilylimino) silane Pages 191-197 Jörg Niesmann, Uwe Klingebiel, Mathias Noltemeyer |
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Silsesquioxanes as synthetic platforms. II. Epoxy-functionalized inorganic-organic hybrid species Pages 199-201 Chunxin Zhang, Richard M. Laine |
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The β-effect of silicon in the orthogonal geometry Pages 203-210 Joseph B. Lambert, Xiaoyang Liu |
Synthesis, structures and oxidative addition reactions of new thermally stable silylenes; crystal structures of [ (CH2tBu)}2C6H4-1,2] and [((CH2tBu)}2C6H4-1,2)(μ-E)]2 (E = Se or Te)Pages 211-220 Barbara Gehrhus, Peter B. Hitchcock, Michael F. Lappert, Joachim Heinicke, Roland Boese, Dieter Bläser |
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The chemistry of fumarate and maleate inhibitors with platinum hydrosilylation catalysts Pages 221-227 Larry N. Lewis, Judith Stein, Robert E. Colborn, Yan Gao, Jun Dong |
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Oxidation of sterically hindered organosilicon hydrides using potassium permanganate Pages 229-234 Paul D. Lickiss, Ronan Lucas |
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Silyl isoxazolines-2: synthesis, structure and properties Pages 235-244 E. Lukevics, V. Dirnens, A. Kemme, J. Popelis |
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Competitive dehydrogenative silylation and hydrogenative dimerization of vinyltriethoxysilane catalyzed by the [Ni(acac)2] + PPh3 system, intermediate and mechanistic implications Pages 245-251 B. Marciniec, H. Maciejewski, J. Guli  ski, B. Maciejewska, W. Duczmal |
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Organogermanium dendrimers Pages 253-260 Vincent Huc, Paul Boussaguet, Pierre Mazerolles |
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Characterization of polyfunctional alkoxysilanes using potassium (K+) ionization of desorbed species mass spectrometry Pages 261-266 Michael J. Michalczyk, William J. Simonsick Jr., Kenneth G. Sharp |
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Hydrosilylation of acetylenes using a H2PtCl6/CO catalytic system; significantly enhanced yields of α-products Pages 267-270 Mirna Rivera-Claudio, James Rozell, Eulalia Ramirez-Oliva, Jorge Cervantes, Keith H. Pannell |
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Density functional theory (DFT)/IGLO 29Si NMR study of trialkylsilylated arenium, bromonium, oxonium and nitrilium ions, comparison with experimental data and the question of persistent trialkylsilicenium ions in solution Pages 271-277 George A. Olah, Golam Rasul, G. K. Surya Prakash |
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Infrared and 29Si NMR spectroscopic investigations on metallasiloxanes derived from organosilanetriols Pages 279-286 Andreas Voigt, Ramaswamy Murugavel, Uwe Ritter, Herbert W. Roesky |
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Polymerization of in situ generated disilenes Pages 287-293 Hideki Sakurai, Masaru Yoshida, Kenkichi Sakamoto |
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Long-chain alkanes with an internal ---H2Si---SiH2--- linkage Pages 295-299 Marcus Söldner, Annette Schier, Hubert Schmidbaur |
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Synthesis and structural characterisation of the novel metallasiloxane compound [Cp2*ZrOSiPh2OLiOH]2 Pages 301-304 Isaac Abrahams, Charlotte Simon, Majid Motevalli, Syed A. A. Shah, Alice C. Sullivan |
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Pharmacological discrimination between enantiomeric germanes by muscarinic receptors: a study on germanium/silicon bioisosterism Pages 305-323 Reinhold Tacke, Dirk Reichel, Peter G. Jones, Xue Hou, Magali Waelbroeck, Jan Gross, Ernst Mutschler, Günter Lambrecht |
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Time-resolved gas-phase kinetic studies of the reactions of silylene with disilane and trisilane Pages 343-349 Rosa Becerra, H. Monty Frey, Ben P. Mason, Robin Walsh |
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Ruthenium-catalyzed regioselective step-growth copolymerization of 3′,4′-methylenedioxyacetophenone and α,ω-dienes Pages 351-354 Guohong Wang, Hongjie Guo, William P. Weber |
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Silylene and disilene reactions with electron-poor 1,3-dienes: new ring systems and complete degradation of a CF3 group Pages 355-362 Manfred Weidenbruch, Peter Will, Karl Peters, Hans Georg von Schnering, Heinrich Marsmann |
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The reactivity of tetramesityldisilene with epoxides: dependence of product distributions on steric and structural characteristics of the epoxide Pages 363-375 John E. Mangette, Douglas R. Powell, Timothy K. Firman, Robert West |
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Supersilylierte Disilene, Cyclotri-, Cyclotetra- sowie Tetrahedrosilane: Erzeugung, Strukturen, Bildungswege Pages 377-386 Nils Wiberg, Christian M. M. Finger, Harald Auer, Kurt Polborn |
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Stereospecific insertion of germylene into the vinyl chloride bond Pages 387-389 Harunobu Ohgaki, Wataru Ando |
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Derivatisation of octasilsesquioxane with alcohols and silanols Pages 391-393 Alan R. Bassindale, Theresa Gentle |
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Gas-phase reactions of silicon-centred intermediates with chlorofluorocarbons Pages 395-396 Michael P. Clarke, Martin Conqueror, Geraint H. Morgan, Iain M. T. Davidson |
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BiCl3-catalyzed Mukaiyama-aldol and carbonyl-ene reactions Pages 397-399 Laurence Peidro, Christophe Le Roux, André Laporterie, Jacques Dubac |
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Reactions of an incompletely-condensed silsesquioxane with Ph3PCH2: a new procedure for derivatizing silsesquioxanes with important implications for the chemistry of silica surfaces Pages 401-403 Frank J. Feher, Shawn H. Phillips |
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Double oxidative addition of the Si---Si and Si---Ge bonds onto isonitrile-platinum(0) complexes leading to the formation of tetrakis(organosilyl)- and bis(organogermyl)bis(organosilyl)platinum(IV) complexes Pages 405-408 Michinori Suginome, Hideaki Oike, Philippa H. Shuff, Yoshihiko Ito |
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Oxaoctasilahomocubane and dioxaoctasilabishomocubane: novel silicon ring systems Pages 409-411 Masafumi Unno, Tomonao Yokota, Hideyuki Matsumoto |
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Kinetic study on thermal syn-anti isomerization of dodecaisopropyltricyclo[4.2.0.02,5]octasilane Pages 413-415 Soichiro Kyushin, Yusuke Yagihashi, Hideyuki Matsumoto |
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Extension of the Benkeser reaction to the reductive trichlorosilylation of main group element chlorides Pages 417-419 Wolf-Walther du Mont, Lutz Peter Müller, Lars Müller, Sebastian Vollbrecht, Andreas Zanin |
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New cascade silylcarbocyclization (SiCaC) of enediynes Pages 421-423 Iwao Ojima, James V. McCullagh, William R. Shay |
Cross-conjugated polymers via condensation of a zirconocene alkynyl(benzyne) derivative generated by thermolysis of Cp2ZrMe(C6H4C CSiMe3)Pages 425-428 Shane S. H. Mao, T. D. Tilley |
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Synthese und Struktur eines neuartigen molekularen λ5-Organospirosilikats und dessen dynamisches Verhalten in Lösung Pages 429-433 Michael Veith, Andreas Rammo |