Volume 536-537
Main Index

Pages 1-565 (30 May 1997)

Introduction Pages 1-3 M.E. Vol'pin, V.I. Sokolov, A.I. Yanovsky

Preface Page 5 Irena Akhrem

Organometallic structural units in solid state ternary transition metal carbides Pages 7-15 R. Bruce King

Novel types of hydrogen bonding with transition metal π-complexes and hydrides Pages 17-29 Elena S. Shubina, Natalia V. Belkova, Lina M. Epstein

Novel generation of organometallic systems. Metal carbonyl complexes with silacarbacyclic π-ligands, synthetic and structural investigations Pages 31-49 O.B. Afanasova, N.I. Kirillova, E.A. Chernyshev, Yu.T. Struchkov

Semi-sandwich platinum metals metallacarboranes derived from nido-C2B9H12−: Chemistry and structural studies Pages 51-63 Igor T. Chizhevsky, Alexandr I. Yanovsky, Yuri T. Struchkov

X-ray study of organic and organoelement compounds of the lanthanides Pages 65-71 Lev N. Zakharov, Yuri T. Struchkov

The new organometallic polydentate ligand trans-bis(2-(diphenylphosphino) pyrimidine) tricarbonyliron(0) and its mono-, di- and tridentate coordination modes towards mercury(II) halide/pseudohalide Pages 73-86 Song-lin Li, Zheng-Zhi Zhang, Thomas C.W. Mak

Reactions of pentaphenylantimony with dicarboxylic acids Pages 87-92 Vladimir V. Sharutin, Olga K. Sharutina, Antonida P. Pakusina, Vitaly K. Belsky

Preparation and thermolysis of complexes derived from some trinuclear ruthenium clusters and 1,4-diphenylbuta-1,3-diyne Pages 93-107 Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton, Allan H. White

A heterometallic alkoxide combining hard and soft Lewis acids (Et3PO)2 Ba2Cu4(OtBu)8 Pages 109-113 Bjöm Borup, John C. Huffman, Kenneth G. Caulton

Organotransition-metal metallacarboranes 45. Synthesis and structure of hydridoruthenacarborane double-decker and triple-decker sandwich complexes Pages 115-121 Eric J. Houser, Michael A. Curtis, Michal Sabat, Russell N. Grimes

Behaviour of triphenylphosphine-substituted ruthenium carbonyl carboxylates with hydrogen Pages 123-138 Piero Frediani, Cristina Faggi, Sandro Papaleo, Antonella Salvini, Mario Bianchi, Franco Piacenti, Sandra Ianelli, Mario Nardelli

Dihydrogen addition to (PiPr3) 2OsXnH4−n Pages 139-147 Roger Kuhlman, Dmitry G. Gusev, Igor L. Eremenko, Heinz Berke, John C. Huffman, Kenneth G. Caulton

The tert-butylchloride—lithium naphthalene radical anion and tert-butyllithium—naphthalene systems. Mechanism of metallation Pages 149-163 Constantinos G. Screttas, Maria Micha-Screttas, Barry R. Steele

Metallation of bicymantrenyl and synthesis of polycymantrenyls Pages 165-175 A.G. Ginzburg, S.V. Suprunovich, F.M. Dolgushin, A.I. Yanovsky, E.V. Vorontsov, V.I. Sokolov

Synthesis and characterisation of trifluoro(η5-n-propyltetramethylcyclopentadienyl) metal(IV)-compounds of the elements of group IV Pages 177-180 Antje Künzel, Emilio Parisini, Herbert W. Roesky, George M. Sheldrick

The electrochemical synthesis of η5-cyclopentadienylcobalt-η4-tetraphenylbutadiene and its reaction with iodine in the presence of electron donor ligands Pages 181-189 V.A. Knizhnikov, V.L. Shirokii, A.N. Ryabtsev, N.A. Maier

Ring-methyl activation in pentamethylcyclopentadienyl complexes 7 reactions of [Ru(η2:η5-C5Me4CH2O(CH2)nCH=CHR2)(CO)2]+BF4− with nucleophiles Pages 191-196 Oleg V. Gusev, Larisa N. Morozova, Tat'ayana A. Peganova, Mikhail Yu. Antipin, Konstantin A. Lyssenko, Alfred F. Noels, Shane R. O'Leary, Peter M. Maitlis

Structural correlation between Rh-P and Rh-C bond distances vs. 31P and 13C NMR parameters in monocarbonylphosphinerhodium(I) complexes: Crystal structure of (methyl 2-(amino)-1-cyclopentene-1-dithio arboxylato-κN, κS)-carbonyl(triphenylphosphine) rhodium(I) Pages 197-205 Gideon J.J. Steyn, Andreas Roodt, Irina Poletaeva, Yury S. Varshavsky

Template synthesis, structure and electrochemistry of trinuclear iron(II) clathrochelate dioximates with ferrocenylboron fragments Pages 207-216 Yan Z. Voloshin, Tatyana E. Kron, Vitaly K. Belsky, Valery E. Zavodnik, Yurii A. Maletin, Sergey G. Kozachkov

The molecular structure of a germacyclobutane by gas electron diffraction and ab initio molecular orbital calculations Pages 217-221 Arne Haaland, Svein Samdal, Tor G. Strand, Maxim A. Tafipolsky, Hans Vidar Volden, Bartholomeus J.J. van de Heisteeg, Otto S. Akkerman, Friedrich Bickelhaupt

Synthesis, structure and reactivity of a novel monocarbon hydridorhodacarborane closo-2,2-(Ph3P)2-2-H-1-(Me3N)-2,1-RhCB10H10 molecular structure of 16-electron closo-2-(Ph3P)-2-Cl-1-(Me3N)-2,1-RhCB10H10 and closely related 18-electron closo-3,3-(Ph3P)2-3-Cl-3,1,2-RhC2B9H11 Pages 223-231 Igor T. Chizhevsky, Irina V. Pisareva, Evgenii V. Vorontzov, Vladimir I. Bregadze, Fedor M. Dolgushin, Alexandr I. Yanovsky, Yuri T. Struchkov, Carolyn B. Knobler, M. Frederick Hawthorne

Synthesis and structure of β-tellurovinylcarbonyl compounds Pages 233-248 V.I. Minkin, I.D. Sadekov, B.B. Rivkin, A.V. Zakharov, V.L. Nivorozhkin, O.E. Kompan, Yu.T. Struchkov

The activation of C-H bonds in terminal olefins by cyclopentadienylnickel species Pages 249-256 S. Pasynkiewicz, W. Buchowicz, A. Pietrzykowski, T. Głowiak

Preparation of stable α-(nonamethylmetallocenyl)-α-hydroxycarbocations and their transformations Pages 257-264 M.I. Rybinskaya, A.Z. Kreindlin, L.N. Kiseleva, N.V. Kruglova, A.A. Kamyshova, P.V. Petrovskii, U. Turpeinen

The role of Ni(0) complexes in electrochemical phosphorylation of organic halides part 1. Factors determining catalytic activity Pages 265-272 Yulia H. Budnikova, Yuri M. Kargin

[4 + 2] Cycloaddition reactions involving 1,3-diphosphacyclopentadiene and 1,2,4-triphosphacyclopentadiene: Crystal and molecular structures of the exo-compounds P5C5tBu5H2 and P4C6tBu6H2 Pages 273-279 Vinicius Caliman, Peter B. Hitchcock, John F. Nixon

X-ray structures of decamethylplatinocene dication in the crystal of [Pt(η5-C5Me5)2]2+(PF6−)2 and decamethyliridocenium cation in the crystal of [Ir(η5-C5Me5)2]+(BPh4−) · CH2Cl2 Pages 281-284 Yu.T. Struchkov, M.Yu. Antipin, K.A. Lyssenko, O.V. Gusev, T.A. Peganova, N.A. Ustynyuk

The interaction of unsaturated C8-ring systems with ruthenium carbonyl clusters Pages 285-291 David B. Brown, Brian F.G. Johnson, Caroline M. Martin, Simon Parsons

Reactions of the phenyl-substituted five-membered titanacyclocumulene — Unusual coupling of a 1,4-disubstituted 1,3-butadiyne with two titanium atoms Pages 293-297 Vladimir V. Burlakov, Normen Peulecke, Wolfgang Baumann, Anke Spannenberg, Rhett Kempe, Uwe Rosenthal

Sterically encumbered charge-compensated carbaboranes: Synthesis and reactivity molecular structures of 7-Ph-11-SMe2-7,8-nido-C2B9H10 and 1-Ph-3,3-(CO)2-7-SMe2-3,1,2-closo-RhC2B9H8 Pages 299-308 Georgina M. Rosair, Alan J. Welch, Andrew S. Weller, Stephan K. Zahn

Molecular structure and conformation of trimethylsilylbenzene: A study by gas-phase electron diffraction and theoretical calculations Pages 309-318 Anna Rita Campanelli, Fabio Ramondo, Aldo Domenicano, István Hargittai

Structure of a Pt/Re cluster complex: Aggregation of ions in crystals of [Pt3Re(CO)2P(OMe)3μ3-O)2(μ-dppm)3][AsF6] Pages 319-326 Kenneth W. Muir, Ljubica Manojlovic-Muir, Ali Ashgar Torabi

Directive effects in the hydroboration of 1-alkenyl derivatives of o-carborane with representative hydroborating agents Pages 327-337 G.W. Kabalka, G. Hondrogiannis

Reactions of diacetylene ligands with trinuclear clusters II. Reactions of hexa-2,4-diyne-1,6-diol and 1,4-diphenyl-1,3-butadiyne with Ru3(CO)12 Pages 339-343 S.P. Tunik, E.V. Grachova, V.R. Denisov, G.L. Starova, A.B. Nikol'skii, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov

Reactions of dodecacarbonyltriruthenium with unsaturated α,β-diketones Pages 345-353 M.I. Rybinskaya, L.V. Rybin, S.V. Osintseva, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, P.V. Petrovskii

Solid state conformation of the anomeric effect in 2-phosphoryl-, 2-thiophosphoryl- and 2-selenophosphoryl-substituted 1,3-dithiolanes Pages 355-360 Marian Mikołajczyk, Tomasz Łuczak, Piotr P. Graczyk, Michał W. Wieczorek, Jarosław Błaszczyk, Grzegorz D. Bujacz, Wiesław R. Majzner

Polyelement substituted cyclopentadienes and indenes — Novel ligand precursors for organotransition metal chemistry Pages 361-373 Konstantin Rufanov, Evgeni Avtomonov, Nadezhda Kazennova, Vasilij Kotov, Alexander Khvorost, Dmitry Lemenovskii, Jörg Lorberth

Synthesis and structure of 3-(cyclohexylamino) propyldimethylsilanol Pages 375-379 Wolfgang Ziche, Bernhard Herrschaft, Friedemann Hahn, Peter John, Johann Weis, Norbert Auner

Synthesis and structure of the heteronuclear alkyne cluster RuOs3(μ4-HC2Me)(CO)12 Pages 381-384 A.A. Koridze, A.M. Sheloumov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, P.V. Petrovskii

The influence of aryl ligands on the chemical hardness of triarylitin cations Pages 385-388 Dmitrii N. Kravtsov, Alexander S. Peregudov, Valentina M. Pachevskaya, Lyudmila S. Golovchenko

Crystalline-state β—α photoisomerization of cobaloxime complexes, part 1 generation of asymmetry in chiral crystal environment Pages 389-398 Akiko Sekine, Hiroaki Tatsuki, Yuji Ohashi

Synthesis and crystal structure of enantiomeric N-(dimethylfluorosilylmethyl) and N-(dimethylchlorosilylmethyl)-[N-(S)-1-phenylethyl)] acetamides Pages 399-403 Yuri I. Baukov, Yuri E. Ovchinnikov, Aleksandr G. Shipov, Evgeniya P. Kramarova, Vadim V. Negrebetsky, Yuri T. Struchkov

Ligand effects in the hydrogenation of methacycline to doxycycline and epi-doxycycline catalysed by rhodium complexes molecular structure of the key catalyst [closo-3,3-(η2,3-C7H7CH2)-3,1,2-RhC2B9H11] Pages 405-412 A. Felekidis, M. Goblet-Stachow, J.F. Liégeois, B. Pirotte, J. Delarge, A. Demonceau, M. Fontaine, A.F. Noels, I.T. Chizhevsky, T.V. Zinevich, V.I. Bregadze, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov

Crown compounds for anions. A new approach to the description of chemical bonds in the complexes of halide anions with polymercury-containing macrocycles Pages 413-424 A.L. Chistyakov, I.V. Stankevich, N.P. Gambaryan, Yu.T. Struchkov, A.I. Yanovsky, I.A. Tikhonova, V.B. Shur

Vibrational spectra of disilenes. Normal coordinate analysis and identification of the v(Si=Si) stretching vibration Pages 425-432 L.A. Leites, S.S. Bukalov, I.A. Garbuzova, R. West, J. Mangette, H. Spitzner

Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe3)]2(μ4-S) [PtMe3(μ-I)]2 Pages 433-436 A.A. Pasynskii, Y.V. Torubaev, S.E. Nefedov, I.L. Eremenko, O.G. Ellert, V.K. Belsky, A.I. Stastch

Benzylic functionalization of (η6-alkylarene)chromium tricarbonyl complexes Pages 437-455 Valery N. Kalinin, Il'ya A. Cherepanov, Sergey K. Moiseev

Variety of naphthalene coordination modes in the polynuclear (pentamethylcyclopentadienyl) lutetium naphthalene complex [(C5Me5Lu)3(C10H8)(C10H7)(H)][(Na(THF)3]2C10H8 Pages 457-463 Andrei V. Protchenko, Oksana G. Almazova, Lev N. Zakharov, Georgi K. Fukin, Yuri T. Struchkov, Mikhail N. Bochkarev

Chelating organophosphines: The use of comparative structural investigations to determine ligand properties Pages 465-472 Joachim Bruckmann, Carl Krüger

Organometallic chemistry of the actinides. Part 3 novel 1-aza-allyl- and β-diketiminatothorium chlorides; X-ray structures of and [LL′ = N(SiMe3)C(But)C(H)SiMe3; LL = N(SiMe3)C(Ph)2CH] Pages 473-480 Peter B. Hitchcock, Jin Hu, Michael F. Lappert, Shun Tian

The MM3 force field for 12-vertex boranes and carboranes Pages 481-488 Tatjana V. Timofeeva, Kyrill Yu. Suponitsky, Alexander I. Yanovsky, Norman L. Allinger

Polyhalomethanes combined with aluminum halides as generators of superelectrophiles of a novel type Pages 489-495 I.S. Akhrem, A.L. Chistyakov, N.P. Gambaryan, I.V. Stankevich, M.E. Vol'pin

Synthesis of diphosphine-substituted selenido carbonyl iron clusters: Progressive deformation of the Fe3Se2 core in the nido clusters [Fe3Se2(CO)7μ-(Ph2P)2R] by widening the bite of the bridging ligand Pages 497-507 Daniele Cauzzi, Claudia Graiff, Maurizio Lanfranchi, Giovanni Predieri, Antonio Tiripicchio

Reactivity of the electron deficient compound [(μ-H)Os3(CO)9μ3-η2-C9H5(CH3)N] with thiols Pages 509-517 Shariff E. Kabir, Heinrich Vahrenkamp, Michael B. Hursthouse, K.M. Abdul Malik

Vibrational spectra and structure of trimethylindium and trimethylthallium Pages 519-529 A.P. Kurbakova, S.S. Bukalov, L.A. Leites, L.M. Golubinskaya, V.I. Bregadze

Novel group 4b ansa-metallocene complexes with the shortest bridge: [1,1′-isopropylydene-3,3′-di-t.Bu-bis(η5-cyclopentadienyl)] Ti and Zr dichlorides Pages 531-536 Igor F. Urazowski, Lev O. Atovmyan, Shaen G. Mkoyan, Roland Broussier, Patrice Perron, Bernard Gautheron, Francis Robert

Synthesis and characterization of the first charge-compensated monocarbollide(octacarbonyl) triosmium complex Pages 537-539 Vyacheslav N. Lebedev, Donald F. Mullica, Eric L. Sappenfield, F. Gordon A. Stone

Organometallic compounds of the lanthanides CXV. Donor substituted chiral ansa-lanthanidocenes: Synthesis of dimehyl(dimethylaminoethylcyclopentadienyl) (tetramethylcyclopentadienl) silane dipotassium and of some chiral ansa-metallocene derivatives of Y, Sm, Ho, Er and Lu Pages 541-547 Herbert Schumann, Frank Erbstein, Roman Weimann, Jörg Demtschuk

Synthesis and structural characterisation of [Os4H2(CO)11Au2(DPPM)2]: The first cluster with an Os4Au4 core Pages 549-551 Muna R.A. Al-Mandhary, Jack Lewis, Paul R. Raithby

Author index of volumes 536–537 Pages 553-554

Subject index of volumes 536–537 Pages 555-565