Volume 545-546
Main Index

Pages 1-636 (30 October 1997)

One the structure of bis(9-fluorenyl) dimethylsilane: a sterically crowded molecule with relatively low barriers of rotations around the Si-C(fluorenyl) bonds X-ray diffraction analysis and AM1 molecular orbital calculations Pages 1-8 Luminita Silaghi-Dumitrescu, Ionel Haiduc, Raymundo Cea-Olivares, Ioan Silaghi-Dumitrescu, Jean Escudié, Claude Couret

Nucleophilic addition of chromium and tungsten carbene anions to cationic organotricarbonylmetallic complexes Pages 9-16 Francoise Rose-Munch, Claudine Le Corre-Susanne, Frédéric Balssa, Eric Rose, Jacqueline Vaisserman, Emanuela Licandro, Antonio Papagni, Stefano Maiorana, Wie-dong Meng, G. Richard Stephenson

Kohlenwasserstoffverbrückte Metallkomplexe: XXXVII. Mono- und dimetallierte Heterocyclopentedione mit Molybdän-, Wolfram-, Mangan- und Rheniumcarbonylen Pages 17-25 Martin J. Schweiger, Theodor Ederer, Karlheinz Sünkel, Wolfgang Beck

Ring functionalized cyclopentadienyl derivatives of niobium and tantalum: molecular structures of (η5-C5H4-CO2CH3)M(CO)4 where M = Nb and Ta and (η5-C5H4-CO2CH2C6H5)Nb(CO)4 Pages 27-33 Thomas E. Bitterwolf, Skip Gallagher, Arnold L. Rheingold, Glenn P. A. Yap

New ethylene bridged monofluorenyl-amido group 4 complexes Pages 35-38 Patrick Foster, James C. W. Chien, Marvin D. Rausch

Thermochemistry of pentacarbonyl(2-propenyl) manganese and tetracarbonyl(η3-2-propenyl) manganese. Thermochemical considerations in alkenyl isomerisation reactions Pages 39-43 Susan J. Addison, Joseph A. Connor, John A. Kincaid

Gas phase alkylation of phenyltrimethylgermanes Pages 45-51 Barbara Chiavarino, Maria Elisa Crestoni, Simonetta Fornarini

Gas phase germylation of simple aromatics by Me3Ge+ ions Pages 53-59 Barbara Chiavarino, Maria Elisa Crestoni, Simonetta Fornarini

Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3 CSi(C6H4OMe-p)2X Pages 61-65 Kazem D. Safa, Ashraf Asadi, Mohsen Sargordan

Alkylferrocenes: A simple preparation from lithioferrocenes and their aqueous electrochemistry Pages 67-70 Steven D. Dietz, William L. Bell, Ronald L. Cook

Stoichiometric and catalytic activation of sp2 C-H bonds: molecular structure of Os3(μ-H) (μ3-nBuOC=CHPEt2)(CO)9 and catalytic properties of this and related Os and Ru clusters Pages 71-78 Alexander Z. Voskoboynikov, Marina A. Osina, Alla K. Shestakova, Marina A. Kazankova, Inna G. Trostyanskaya, Irina P. Beletskaya, Fedor M. Dolgushin, Alexander I. Yanovsky, Yuri T. Struchkov

Metal complexes with atropisomeric sulfur ligands in asymmetric hydroformylation X-ray structure of [Rh2(μ-biphes)(cod)2] (H2biphes = 4,4′-biphenanthrene-3,3′-dithiol) Pages 79-87 Nuria Ruiz, Abdellatif Aaliti, Jorge Forniés-Cámer, Aurora Ruiz, Carmen Claver, Christine J. Cardin, Davide Fabbri, Serafino Gladiali

Crystal structure of a palladium metallacyclic complex: A key-intermediate in the carbonylation of nitrobenzene to isocyanates and carbamates Pages 89-91 Andrea Sessanta o Santi, Barbara Milani, Giovanni Mestroni, Ennio Zangrando, Lucio Randaccio

Crystal structure of [Rh(SnCl3)(norbornadiene)(dppb)] and [Rh(SnCl3)(1,5-cyclooctadiene)(dppb)] (dppb = 1,4-bis(diphenylphosphino)butane) Pages 93-97 Victoria García, María A. Garralda, Elena Pinilla

Synthesis and characterization of [Me2M-μ-N(H)NMe2]2 (M = Al, Ga). Crystal structure of trans [Me2Al-μ-N(H)NMe2]2 Pages 99-103 Younsoo Kim, Jae H. Kim, Jae E. Park, Hyunjoon Song, Joon T. Park

The X-ray structure of Fe(fulvene)2: The missing link in the direct synthesis of ansa- and Cpi-metallocenes (Cpi = C5H4CHMe2) Pages 105-110 Roland Teuber, Ralf Köppe, Gerald Linti, Matthias Tacke

Triphenylbismuthine complexes of group 6 metal carbonyls: X-ray crystal structures of [M(CO)5(BiPh3)] (M = Mo or W) Pages 111-115 Nicholas J. Holmes, William Levason, Michael Webster

Synthesis and spectroscopic properties of heteropolynuclear cyano-bridged complexes Pages 117-123 Silvia Bordoni, Luigi Busetto, Patrizia Colucci, Antonio Palazzi, Valerio Zanotti

Synthesis and characterisation of some new water soluble π-allyl dicarbonyl complexes of molybdenum(II) Pages 125-129 Paul K. Baker, Alyn E. Jenkins

Steric and electronic effects on E/Z composition of exocyclic cyclopalladated N-benzylideneamines Pages 131-137 Joan Albert, Jaume Granell, Anna Luque, Mercè Font-Bardía, Xavier Solans

Quaternary ammonium salts of phosphines as ligands and their recycling by membrane techniques or phase separation. Part I: monophasic systems Pages 139-149 Helmut Bahrmann, Michael Haubs, Thomas Müller, Norbert Schöpper, Boy Cornils

Simple and effective synthesis of pentamethylcyclopentadienyl oxo-peroxo and dioxo tungsten acetylide complexes Pages 151-156 Chin-Wei Shiu, Chi-Jung Su, Chih-Wei Pin, Yun Chi, P. Shie-Ming Peng, Gene-Hsiang Lee

Examination of the LnCl3/RLi alkylation system for organic synthesis using yttrium as a probe including the X-ray crystal structure of Li2Y8Cl18O4(THF)12 Pages 157-162 William J. Evans, Mohammad A. Ansari, Jay D. Feldman, Robert J. Doedens, Joseph W. Ziller

Convenient synthesis of K[(C5H4MeMnH(CO)2] and reactions with Cl2B[N(SiMe3)2] and B2R2Cl2 (R = Me2N, Me3C) Pages 163-167 Holger Braunschweig, Beate Ganter

Darstellung und Struktur von hetero- und homoleptischen Thiomethylnickelkomplexen Pages 169-178 Frank Becke, Tobias Rüffer, Roland Boese, Dieter Bläser, Dirk Steinborn

Photoexcitation of iron-allyl complexes (η5:η1-C5H4CH2CH2PPh2)Fe(CO)(η1-CH2 CR = CH2) (R = H, CH3) which contains a tethered phosphine ligand Pages 179-184 Tein-Fu Wang, Ching-Yih Lai

Simplified preparations of trialkylsilyl- and bis(trialkylsilyl) dihalomethanes via the deprotonation of dihalomethanes Pages 185-189 Yoon Kunsang, David Y. Son

Structure of Z- and E-2-bromo-1-ferrocenyl-1-phenylcyclopropanes and 3-ferrocenyl-3-phenylcyclopropene and their three-membered ring opening reactions Pages 191-199 Elena I. Klimova, B. Tatiana Klimova, Lena Ruíz Ramírez, G. Marcos Martínez, T. Cecilio Alvarez, P. Georgina Espinosa, Ruben A. Toscano

Parahydrogen induced polarization in the Pt(0)-mediated hydrogenation of alkynes and alkenes Pages 201-205 Stefan Klages, Alexei B. Permin, Valery S. Petrosyan, Joachim Bargon

Some Au3Ru3 clusters. X-ray structures of Ru3(μ3-CMeCHCMe)(CO)8{Au3(PPh3)3} and Ru3(μ3-C2Ph)(CO)8{Au3(PPh3)3} Pages 207-218 Michael I. Bruce, Paul A. Humphrey, Brian W. Skelton, Allan H. White

Silicon-carbon bridged bis(fluorenyl) and bis(octahydrofluorenyl) ansa-zirconocenes: synthesis, characterization and ethylene polymerization catalysis Pages 219-224 Reko Leino, Hendrik J. G. Luttikhedde, Ari Lehtonen, Carl-Eric Wilén, Jan H. Näsman

Stereoselective synthesis and some reactions of β-(η6-arene)Cr(CO)3 complexes of podocarpic acid derivatives Pages 225-247 George R. Clark, Bianca Kuipers, Michael R. Metzler, Manh H. Nguyen, Paul D. Woodgate

Adducts of GaI3 and InI3 with Ph3P and Ph3As Pages 249-255 L. -J. Baker, Lars A. Kloo, Clifton E. F. Rickard, Michael J. Taylor

{[Bis(dimethylamino)boryl]methyl}dimethylphosphane as ligand in transition metal complexes Pages 257-266 Holger Braunschweig, Regina Dirk, Beate Ganter

Einkernige Derivate der Hexacarbonylmetalle, M(CO)6 (M = Cr, Mo, W), mit dem mehrzähnigen Liganden Tri(1-cyclohepta-2,4,6-trienyl)phosphan, P(C7H7)3 Pages 267-276 Max Herberhold, Kurt Bauer, Wolfgang Milius

Synthesis and molecular structure of [Cp′2V(μ-S)2VCp′]2(μ-O) Pages 277-280 Omar M. Kekia, Arnold L. Rheingold

Funktionalisierungen und vernetzungsreaktionen an siliciumor-ganischen polymeren Pages 281-289 Wolfram Uhlig

Cyclopenta[1]phenanthrene titanium trichloride derivatives: syntheses, crystal structure and properties as catalysts for styrene polymerization Pages 291-295 Nicole Schneider, Marc-Heinrich Prosenc, Hans-Herbert Brintzinger

Reactivity of bicyclic N-pyrrolylboranes Pages 297-308 Bernd Wrackmeyer, Bernd Schwarze, Wolfgang Milius

Insertion of dimethylsilanone into a Ln-N bond and X-ray crystal structure of the insertion product [MeCpDy(η2-PzMe2)(μ-η1:η2-OSiMe2PzMe2)] Pages 309-314 Xi-geng Zhou, Wei-wen Ma, Zu-en Huang, Rui-fang Cai, Xiao-zeng You, Xiao-ying Huang

187Os, 31P and 17O NMR study of carbonylated and alkylated (p-cymene)OsI (L)PR3 complexes Pages 315-326 Andreas Gisler, Martina Schaade, Eric J. M. Meier, Anthony Linden, Wolfgang von Philipsborn

Preparation and reactivity of mono- and binuclear nitrosyl molybdenum complexes containing S2CPCy3 ligands. Crystal structure of [(OC)2(ON)Mo(μ-Br)(μ-S2CPCy3)Mo(CO)2(PEt3)] Pages 327-336 Daniel Miguel, Víctor Riera, Wang Mei, Claudette Bois, Yves Jeannin

Catalytic formation of carbamates and cyclic carbonates by copper complex of 2,5,19,22-tetraaza[6,6](1,1′)ferrocenophane-1,5-diene X-ray crystal structure of [Cu(1)]PF6 Pages 337-344 Hak-Soo Kim, Jeong-Won Kim, Soon-Chul Kwon, Sang-Chul Shim, Tae-Jeong Kim

Synthesis and reactions of coordinatively unsaturated 16-electron chalcogenolate complexes, Ru(EAr)2(η6-arene) and cationic binuclear chalcogenolate complexes, [(η6-arene)Ru(μ-EPh)3Ru(η6-arene)]PF6 Pages 345-356 Kazushi Mashima, Sei-ichi Kaneko, Kazuhide Tani, Hiromu Kaneyoshi, Akira Nakamura

Voie d'accès aux sels de pyryliumγ-benchrotréniques synthèse des premiers sels de pyrylium organométalliques à cycles condensés Etude RMN et application à la synthèse de nouveaux complexes du benzène chrometricarbonyle Pages 357-368 F. Robin-Le Guen, M. C. Senechal-Tocquer, D. Senechal, B. Caro

Preparation and electrochemical reactions of nickel(II) complexes containing isocyanide and mono- or di-phosphines Pages 369-379 Yasuhiro Yamamoto, Hiroyuki Takahata, Fumie Takei

Synthesis and structure of novel chiral oxazolinylferrocenes and oxazolinylferrocenylphosphines, and their rhodium(I)-complexes Pages 381-398 Yoshiaki Nishibayashi, Kyohei Segawa, Yasuyoshi Arikawa, Kouichi Ohe, Masanobu Hidai, Sakae Uemura

Bridged half-sandwich niobiocenes by intramolecular CH activation Pages 399-405 Laurent Djakovitch, Wolfgang A. Herrmann

Chirale Tripod-Liganden mit einer Cyclopentadienyl- und zwei Phosphin-Donorfunktionen: Synthese und Komplexchemie Pages 407-420 Björn Antelmann, Ute Winterhalter, Gottfried Huttner, Bernd Christian Janssen, Joachim Vogelgesang

Synthese, Struktur von 3-(N,N-dimethylamino) propyl- und 2-(Dimethylaminomethyl) ferrocenyl-Derivaten des Goldes und Platins Pages 421-433 K. Jacob, F. Voigt, K. Merzweiler, C. Pietzsch

Thermal rearrangement reaction of disilyl-bridged bis(tetramethyl cyclopentadienyl) tetracarbonyl diiron The molecular structures of (Me2SiSiMe2) [(η5-C5Me4)Fe(CO)]2(μ-CO)2 and [(Me2Si) (η5-C5Me4)Fe(CO)2]2 Pages 435-439 Zhou Xiuzhong, Zhong Xiubin, Zhang Yongqiang, Xu Shansheng

New chelating pyridyl-indenyl and quinolyl-indenyl ligands leading to C1 symmetrical complexes of zirconium via amine elimination. X-ray structure of [3-(2-pyridylmethyl)(indenyl)]tris(dimethylamido)Zr(IV) Pages 441-446 Zeev Ziniuk, Israel Goldberg, Moshe Kol

Reaction of carbanion of Fischer-type carbene complexes with pyrylium salts. One pot substituted benzophenones formation by subsequent cyclization and double hydrogen β-elimination Pages 447-450 Pascal Le Poul, Françoise Robin-Le Guen, Marie-Claude Sénéchal-Tocquer, Bertrand Caro

Dreikomponentenreaktionen unter photochemischen Bedingungen--der Transformationsweg des P4-Phosphors in der Koordinationssphäre von Co-Komplexen Pages 451-460 Manfred Scheer, Uta Becker

Arranging phosphoryl ligands on a calixarene platform Pages 461-473 Cedric B. Dieleman, Dominique Matt, Peter G. Jones

Free radical chemistry associated with H(RSiH)nH Pages 475-481 C. Chatgilialoglu, C. Ferreri, D. Vecchi, M. Lucarini, G. F. Pedulli

Ab initio study of the basicity and propensity of siloxanols towards hydrogen bond formation Pages 483-493 Marek Cypryk

Reactions of OsH2(η2-CH2=CHEt)(CO)(PiPr3)2 with unsaturated organic molecules Pages 495-506 María J. Albéniz, María L. Buil, Miguel A. Esteruelas, Ana M. López

Tris(diphenylthiophosphinoyl)methanide as tripod ligand in rhodium(III), iridium(III) and ruthenium(II) complexes. Crystal structures of [(η5-C5Me5)Ir{η3-(SPPh2)3C-S,S′,S″}]BF4 and [(η6-MeC6H4Pri)Ru{η3-(SPPh2)3C-S,S′,S″}]BPh4 Pages 507-517 Mauricio Valderrama, Raúl Contreras, Verónica Arancibia, Patricio Muñoz, Daphne Boys, M. Pilar Lamata, Fernando Viguri, Daniel Carmona, Fernando J. Lahoz, José A. López, Luis A. Oro

Mixed-metal cluster chemistry VII: some phosphine and alkyne chemistry of Cp2Mo2Ir2(CO)10; X-ray crystal structures of Cp2Mo2Ir2(μ-CO)3(CO)6(PMe3) and Cp2Mo2Ir2(μ4-η2-HC2Ph)(μ-CO)4(CO)4 Pages 519-530 N. T. Lucas, M. G. Humphrey, P. C. Healy, M. L. Williams

Di- and trinuclear complexes of palladium with a triphosphine ligand, bis(diphenylphosphinomethyl) phenylphosphine Pages 531-541 Tomoaki Tanase, Hiroyuki Takahata, Masaru Hasegawa, Yasuhiro Yamamoto

Coordination of alane and aluminum alkyls to the N-donor atom of side chain functionalized cyclopentadienyl iron and nickel complexes; structure of {[(C5H5) (C5H4CH2NMe2)]Fe}2AlH3 Pages 543-548 Sylvain Nlate, Eberhardt Herdtweck, Janet Blümel, Roland A. Fischer

Ligand exchange reactions of a 1,3-butadiene complex of magnesium Pages 549-552 Kazushi Mashima, Yutaka Matsuo, Hiroki Fukumoto, Kazuhide Tani, Hajime Yasuda, Akira Nakamura

ansa-Bis(fluorenyl) komplexe des Zirconiums und Hafniums mit Silicium in der Brücke: Synthese und Polymerisationseigenschaften Pages 553-557 Peter Schertl, Helmut G. Alt

Synthesis and structureso f intramolecularly hexacoordinated organotin chlorides containing the (3-(2-methoxy) ethoxy) propyl moiety Pages 559-565 J. Susperregui, M. Bayle, J. M. Léger, G. Déléris, M. Biesemans, R. Willem, M. Kemmer, M. Gielen

The synthesis of novel neutral mononuclear ruthenium fragments for cluster capping reactions and their reactivity Pages 567-572 Nicholas E. Leadbeater, Jack Lewis, Paul R. Raithby, Andrew J. Edwards

Octamethylferrocenylethynyl units as peripheral groups in rigid, π-conjugated molecular architectures Pages 573-576 Peter Jutzi, Birgit Kleinebekel

Dimeric complexes of ruthenium(II) and rhodium(III) bridged by 1,1′-bis(diphenylphosphinomethyl) ferrocene Pages 577-579 Jian-Fang Ma, Yasuhiro Yamamoto

Arene ruthenium complexes with chiral Schiff bases derived from pyridine-2-carboxaldehyde or 2-acetylpyridine Pages 581-585 David L. Davies, John Fawcett, Roland Krafczyk, David R. Russell

The first heterotrinuclear Pd-Cu cluster with two μ3-S bridging atoms Synthesis and structure of [Pd2(PPh3)4(μ3-S)2(CuPPh3)]2(W6O19) Pages 587-589 Wu Biao, Wen-Jian Zhang, Shu-Yan Yu, Tian-Lu Sheng, Xin-Tao Wu

π-Complexation between a mixed methylalkenylcuprate and an alkyne. Further insight into the mechanism of organocopper additions to ynoates Pages 591-595 Karolina Nilsson, Thomas Andersson, Christina Ullenius

Preparation of (Cp*) {C5Me4CH2B(C6F5)3}ZrPh, a novel zwitterionic single-component alkene polymerisation catalyst Pages 597-600 Xuejing Song, Manfred Bochmann

Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente XLIII Züchtung größerer Tris(bis(trimethylsilyl) methyl) lanthanid-Einkristalle für optische und magnetochemische Untersuchungen Pages 601-606 Clemens Guttenberger, Hanns-Dieter Amberger

Fulleride compounds of the transition metals: NaCoC60 · 3THF Pages 607-610 Dhimant K. Patel, David M. Thompson, Michael C. Baird, Laurence K. Thompson, Keith F. Preston

Thermolysis of 1,1-dimesityl-3-phenyl-2-trimethylsilyl-1-silacyclopropene: silylene transfer reactions to 1,4-bis(silyl)butadiynes Pages 611-613 Atsutaka Kunai, Toshiyuki Mihara, Yoichi Matsuo, Joji Ohshita, Akinobu Naka, Mitsuo Ishikawa

Palladium-Copper catalyzed coupling of iron σ-metalla-alkynes with aryl halides. A simple way to link electroactive organoiron complexes with aromatic structures Pages 615-618 Raphaël Denis, Tania Weyland, Frédéric Paul, Claude Lapinte

Osmium complexes containing either chelating or non-chelating 8-quinolyl ligands Pages 619-622 Alex M. Clark, Clifton E. F. Rickard, Warren R. Roper, L. James Wright

Index Pages 625-626

Index Pages 627-636