Editorial Pages 1-2 |
Synthesis, characterization and reactivity of ionic palladium(II) complexes containing bidentate nitrogen ligands in a unidentate coordination mode, Pages 3-13 J. H. Groen, B. J. de Jong, J. -M. Ernsting, P. W. N. M. van Leeuwen, K. Vrieze, W. J. J. Smeets, A. L. Spek |
Ring opening of 1,3-dithietane-1,1-dioxide by a triosmium cluster Pages 14-21 Richard D. Adams, Wen Huang |
Organometallic cluster complexes with face-capping arene ligands, 9. Hydrogenation of the side-chain in [{(C5H5)Co}3(μ3-alkenylbenzene)]: synthesis and structure of the cluster complexes [{(C5H5)Co}3(μ3-η2:η2:η2-C6H5–CHR1–CH2R2)] Pages 22-29 Hubert Wadepohl, Klaus Büchner, Michael Herrmann, Hans Pritzkow |
Allenyl–propargyl tautomerism at palladium(IV) and platinum(IV) centres Pages 30-35 Allan J. Canty, Hong Jin, Justin D. Penny |
Synthesis, structure and electrochemistry of ferrocenylethynylsilanes and their complexes with dicobalt octacarbonyl Pages 36-46 Noel W. Duffy, Brian H. Robinson, Jim Simpson |
Synthesis, structure and electrochemical studies of the first mixed-metal clusters with the P–N–P assembling ligands (Ph2P)2NH (dppa), (Ph2P)2N(CH3) (dppam) and (Ph2P)2N(CH2)3Si(OEt)3 (dppaSi) Pages 47-59 Isolde Bachert, Pierre Braunstein, Mark K. McCart, Fabrizia Fabrizi de Biani, Franco Laschi, Piero Zanello, Guido Kickelbick, Ulrich Schubert |
A structural redetermination of Co4(CO)12: evidence for dynamic disorder and the pathway of metal atom migration in the crystalline phase Pages 60-66 Louis J. Farrugia, Dario Braga, Fabrizia Grepioni |
Cyanide bridged trinuclear complexes with bent M–NC–Fe–CN–M and M–CN–Fe–NC–M arrangements—synthesis and physical properties Pages 67-72 Nianyong Zhu, Heinrich Vahrenkamp |
Inorganic–organometallic crystal synthesis. The role of charge-assisted C–H…O and C–H…Cl hydrogen bonds in crystalline [(η5-C5H5)2Co][H2PO4]·3H2O and [(η6-C6H5Me)2Cr][Cl] Pages 73-77 Dario Braga, Sylvia M. Draper, Elise Champeil, Fabrizia Grepioni |
Reactions of TiCl4 with phosphines and alkylating reagents: an organometallic route to a titanium(II) cluster compound Pages 78-86 F. Albert Cotton, Carlos A. Murillo, Marina A. Petrukhina |
Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X=Cl, Br; dppm=Ph2PCH2PPh2) with isocyanides. Part XVII. Isomerizations of triply bonded dirhenium complexes of the type [Re2X3(μ-dppm)2(CO)(CNXyl)(CNR)]+(R=Xyl or t-Bu) with open bioctahedral structures to di-μ-chloro edge-sharing bioctahedral structures with no Re–Re bond Pages 87-95 Yan Ding, David A. Kort, Wengan Wu, Phillip E. Fanwick, Richard A. Walton |
The molecular structure and one-pot synthesis of [Li(thf)3 · Sn(SiMe3)3] Pages 96-100 Christine J. Cardin, David J. Cardin, William Clegg, Simon J. Coles, Steven P. Constantine, Jeanette R. Rowe, Simon J. Teat |
A clash of cultures: metal carbonyl functionalized Werner complexes Pages 101-108 Edwin C. Constable*, Catherine E. Housecroft, Alain G. Schneider |
The cleavage of coordinated organoisothiocyanates to give heteronuclear clusters containing organoisocyanides as ligands: Preparation, spectra and structure of [{Co(η-C5H5)}2{Fe(CO)2(PPh3)}(μ3-S){μ3-CNC(O)C6H5}], [{Co(η-C5H5)}2{Fe(CO)(CNC6H4Me-4)(PPh3)}(μ3-S)(μ3-CO)], and related complexes Pages 109-120 Anthony R. Manning, Liam O’Dwyer, Patrick A. McArdle, Desmond Cunningham |
Remarkably stable radical anions derived from clusters [HOs3(CO)9(L)], L=ortho-metallated α-diimine: a spectro-electrochemical study and theoretical rationalization Pages 121-133 J. Nijhoff, F. Hartl, J. W. M. van Outersterp, D. J. Stufkens, M. J. Calhorda, L. F. Veiros |
Cyclo-addition of buta-1,3-dene to cluster-bound dicarbon: X-ray structure of Ru5(μ3-C6H6)(μ3-SMe)2(μ-PPh2)2(CO)10 Pages 134-138 Chris J. Adams, Michael I. Bruce, Brian W. Skelton, Allan H. White |
Complexes of transition metal carbonyls with alkynes. Closo- and nido-pentagonal bipyramidal clusters Pages 139-155 Enrico Sappa |
Synthesis of mixed-metal Li/M, M/M′ and mixed valence MI/MIII chelate amido complexes of the heavy Group 13 metals (M=In, Tl) Pages 156-164 Konrad W. Hellmann, Annina Bergner, Lutz H. Gade, Ian J. Scowen, Mary McPartlin |
The first examples of η5-bonding of a carbaborylphosphine ligand to transition metals. Synthesis and characterisation of 7-{PPh2AuPPh3}-8-Ph-7,8-nido-C2B9H10, 1-{PPh2AuCl}-2-Ph-3-(p-cymene)-3,1,2-pseudocloso-RuC2B9H9 and 1-{PPh2AuCl}-2-Ph-3-(η-C5Me5)-3,1,2-pseudocloso-RhC2B9H9, Pages 165-170 M. Anna McWhannell, Georgina M. Rosair, Alan J. Welch, Francesc Teixidor, Clara Viñas |
Syntheses, structures and magnetism of homoleptic complexes of 4-{pyrid-4-yloxy}-2,2,6,6-tetramethyl-1-piperidinoxyl, a new spin-labelled pyridine Pages 171-179 Malcolm A. Halcrow, Lide M. Rodriguez-Martinez, Euan K. Brechin, John E. Davies, Ian J. Scowen, Mary McPartlin |
Reactions of the mixed-metal alkyne-bridged complexes [(η5-C5H5)(OC)2M{μ-C2(CO2Me)2}Co(CO)3] (M=Mo or W) with Ph2PC![]() Pages 180-188 John E. Davies, Martin J. Mays, Paul R. Raithby, Koshala Sarveswaran, Gregory P. Shields |
Synthesis, characterization and molecular structures of some tetraosmium carbonyl clusters containing pyridine or phenanthroline type ligands Pages 189-201 Ya-Yin Choi, Wing-Tak Wong |
Bimetallic mixed oxidation state complexes derived by coupling nitrosyl- and oxo-molybdenum cores Pages 202-210 Elizabeth R. Humphrey, Van An Ung, John P. Maher, Jon A. McCleverty, Michael D. Ward |
Control of the photochemistry of Ru3(CO)12 and Os3(CO)12 by variation of the solvent Pages 211-216 Nicholas E. Leadbeater |
Exceptional substitutional lability of the ‘raft’ cluster Os6(CO)20NCMe Pages 217-224 David H. Farrar, Anthony J. Poë, Ravindranath Ramachandran |
Reaction of ruthenium carbonyl chloride with iridium tetracarbonyl anion. Synthesis, crystal structure and characterisation of [Ru2Ir2H(CO)12Cl]: a heterometallic tetranuclear butterfly cluster with chloride bridge Pages 225-231 Aapo U. Härkönen, Markku Ahlgrén, Tapani A. Pakkanen, Jouni Pursiainen |
The reaction of azide ions, N3−, with metal carbonyl compounds; an electrospray mass spectrometry study Pages 232-236 J. Scott McIndoe, Brian K. Nicholson |
Cluster build-up reactions via the ionic coupling of tetraosmium anions and the [RhCp*(NCMe)3]2+ cation; the crystal and molecular structures of [Os4Rh(μ-H)3(MeC=NH)(CO)11(η5-Cp*)], [Os4Rh(μ-H)2(CO)13(η5-Cp*)] and [Os4Rh2(μ-H)2(CO)11(η5-Cp*)2] (Cp*=C5Me5) Pages 237-246 William Clegg, Neil Feeder, Ana M. Martin Castro, Saifun Nahar, Paul R. Raithby, Gregory P. Shields, Simon J. Teat |
High nuclearity clusters of osmium and ruthenium containing the [Au2(Ph2PCH2PPh2)]2+ cation; the X-ray structures of [Os4H4(CO)11Au2(Ph2PCH2PPh2)] and [Ru10C(CO)24Au2(Ph2PCH2PPh2)] Pages 247-253 Angelo J. Amoroso, Michael A. Beswick, Chi-Keung Li, Jack Lewis, Paul R. Raithby, M. Carmen Ramirez de Arellano |
Solid state studies (X-ray and 1H-, 13C-NMR) on (NMe4)4−x[HxNi12(CO)21] · S (x=1, S=Me2CO; x=2, S=2THF) Pages 254-260 James V. Barkley, Taro Eguchi, Rachel A. Harding, Brian T. Heaton, Giuliano Longoni, Lucia Manzi, Hirokazu Nakayama, Kei Miyagi, Anthony K. Smith, Alexander Steiner |
Synthesis, chemical characterisation and molecular structure of [Ag3{μ3-Fe(CO)4}(dppm)3][NO3] and [Au3{μ-Fe(CO)4}(dppm)2][Cl] Pages 261-266 Vincenzo G. Albano, Carlo Castellari, M. Carmela Iapalucci, Giuliano Longoni, Magda Monari, Alessandro Paselli, Stefano Zacchini |
Reactions of organolithium complexes with elemental selenium: insertion producing [PhC![]() Pages 267-271 Michael A. Beswick, Christopher N. Harmer, Paul R. Raithby, Alexander Steiner, Mustafa Tombul, Dominic S. Wright |
Synthesis and characterization of diphenyl-2-thienylphosphine derivatives of di- and tricobalt carbonyl complexes Pages 272-278 Jason D. King, Magda Monari, Ebbe Nordlander |
Deboronation of 9-substituted-ortho- and -meta-carboranes Pages 279-291 Mark A. Fox, Kenneth Wade |
Chloroaluminate(III) ionic liquid mediated synthesis of transition metal–cyclophane; complexes: their role as solvent and Lewis acid catalyst Pages 292-298 David Crofts, Paul J. Dyson, Katharine M. Sanderson, Narmatha Srinivasan, Thomas Welton |
Structural characterisation of the giant organometallic platinum cluster Pt309(phen*)36O30 using EXAFS Pages 299-304 R. E. Benfield, A. Filipponi, N. Morgante, G. Schmid |
Towards an understanding of the conjugate addition of organolithium reagents to α,β-unsaturated ketones: the isolation and solid-state structure of a monomeric lithium aluminate with very short agostic Li![]() Pages 305-312 William Clegg, Elinor Lamb, Stephen T. Liddle, Ronald Snaith, Andrew E. H. Wheatley |
Syntheses and structural characterisation of the compounds [Pd(dba)L2] (where L=PBz3 and PPh2Np) and the novel dimer [Pd2(μ-dba)(μ-SO2)(PBz3)2] Pages 313-322 Andrew D. Burrows, Nick Choi, Mary McPartlin, D. Michael P. Mingos, Stephen V. Tarlton, Ramón Vilar |
Index Page 323 |
Index Pages 324-329 |