Volume 578
Main Index

Issues 1-2, Pages 1-275 (22 April 1999)

Foreword to the special volume on Carbon-rich Organometallics Page 1

Luminescent polynuclear metal acetylides Pages 3-30 Vivian Wing-Wah Yam, Kenneth Kam-Wing Lo, Keith Man-Chung Wong

Ferrocenophanes with all carbon bridges Pages 31-42 Richard W. Heo, T. Randall Lee

Syntheses and crystal structures of strained planar silacyclynes containing a diacetylene unit Pages 43-54 Li Guo, Joseph M. Hrabusa III, Claire A. Tessier, Wiley J. Youngs, Robert Lattimer

The synthesis and structural analyses of ruthenium carbonyl cluster complexes containing the bis-(trimethylsilyl)hexatriyne ligand Pages 55-60 Richard D. Adams, Uwe H. F. Bunz, Wei Fu, Gaby Roidl

Coupling of alkynes promoted by Ru(CO)3(PPh3)2 and carbon dioxide: syntheses and structures of (η4-C4R2R′2CO)Ru(CO)2(PPh3) (R=R′=Ph; R=Ph, R′=CCPh) and {Ph2C4(CCPh)2}Ru(CO)(PPh3)2 Pages 61-67 Shinsaku Yamazaki, Zenei Taira

Cobalt-templated radical processes: inter- and intramolecular coupling of propargyl radicals Pages 68-75 Gagik G. Melikyan, Asatour Deravakian, Steven Myer, Sarkhadoun Yadegar, Kenneth I. Hardcastle, Joana Ciurash, Pogban Toure

First synthesis and spectroscopic characterization of isolated butatrienylidene complexes of transition metals Pages 76-84 Françoise Coat, Maud Guillemot, Frédéric Paul, Claude Lapinte

Organometallic C70 chemistry. Preparation and crystallographic studies of (η2-C70)Pd(PPh3)2 · CH2Cl2 and (C70) · 2{(η5-C5H5)2Fe} Pages 85-90 Marilyn M. Olmstead, Leijun Hao, Alan L. Balch

The synthesis and structural analysis of the bis-Co2(CO)6 adduct of the cyclic tetrayne C20H8 Pages 91-94 Richard D. Adams, Uwe H. F. Bunz, Wei Fu, Lamvien Nguyen

Redox active alkenyl-bridged bi- and trinuclear arene–Cr(CO)3-complexes by Horner–Emmons–Wadsworth olefinations Pages 95-102 Thomas J. J. Müller

Synthesis and structure of metallocarbon clusters bearing pendant ethynyl ligands. X-ray crystal structures of Os3(CO)9(μ-CO)(μ3-η1,η1,η2-Me3SiCCC2CCSiMe3), Os3Ru(CO)12(μ4-η1,η2,η1,η2-Me3SiCCC2CCSiMe3), Ru4(CO)12(μ4-η1,η2,η1,η2-Me3SiCCC2CCSiMe3) and {Ru4(CO)12}{Co2(CO)6}(μ4-η1,η2,η1,η2:μ-η2,η2-Me3SiC2CCC2SiMe3) Pages 103-114 Paul J. Low, Konstantin A. Udachin, Gary D. Enright, Arthur J. Carty

Coupling of σ-acetylide ligands at Group 4 metallocene complexes to yield methylenecyclopropene-type frameworks Pages 115-124 Wolfgang Ahlers, Gerhard Erker, Roland Fröhlich, Ulrich Peuchert

Dimerization of titanacyclocumulenes to titanium substituted radialenes: synthesis, stability and reactions of five-membered titanacyclocumulenes with a coupling of two 1,4-diphenyl-1,3-butadiyne between two titanocene molecules to radialene-like fused titanacyclopentadiene compounds Pages 125-132 Paul-Michael Pellny, Vladimir V. Burlakov, Normen Peulecke, Wolfgang Baumann, Anke Spannenberg, Rhett Kempe, Volkhard Francke, Uwe Rosenthal

The cyclo-C3 ligand: trimetallic cyclopropenium complexes of Group 6–8 metals, including the X-ray crystal structure of [{Fe(CO)2(Cp)}3(μ3-C3)][SbF6] Pages 133-143 Michael S. Morton, John P. Selegue

An alternative synthesis of Vollhardt’s [1,2-diethynyl-3,4-bis(trimethylsilyl)cyclobutadiene]cyclopentadienylcobalt and selective formation of its dimer Pages 144-149 Gaby Roidl, Volker Enkelmann, Richard D. Adams, Uwe H. F. Bunz

Formation of vinyl ether derivatives in the reaction of tributyltin hydride with cluster supported Fischer carbene complexes: structural characterisation of [(CO)6Fe2Te2{μ-PhC=CC(OEt)}W(CO)5] Pages 150-154 Pradeep Mathur, Sundargopal Ghosh, Shubhangi B. Umbarkar, Mrinalini G. Walawalkar, Vedavati G. Puranik

Reactions of M(CCCCR)(CO)3Cp [M=Mo, W; R=H, Fe(CO)2Cp, M(CO)3Cp] with cobalt carbonyls: X-ray structures of {Cp(OC)8Co2M(μ3-C)}CC{(μ3-C)Co2M′(CO)8Cp} (M=M′=Mo, W; M=Mo, M′=W) Pages 155-168 Michael I. Bruce, Jean-François Halet, Samia Kahlal, Paul J. Low, Brian W. Skelton, Allan H. White

Reactions of acetylene-bridged diplatinum complexes with tetracyanoethylene Pages 169-177 Kiyotaka Onitsuka, Nobuo Ose, Fumiyuki Ozawa, Shigetoshi Takahashi

Novel mixed-metal–alkynyl complexes stabilised by di-imine ligands: synthesis, characterisation and electrochemistry of [(tBu2bipy)Pt(CCR)2M(SCN)] (R=C6H4Me, SiMe3; M=Cu, Ag) Pages 178-185 Christopher J. Adams, Paul R. Raithby

Synthesis of triynylcarbene complexes and of bi- and trinuclear complexes with heptatriynylidene C7-bridges Pages 186-192 Cornelia Hartbaum, Helmut Fischer

Acetylenic NIR-chromophores: 2,3-dialkynyl-1,4-diazabuta-1,3-diene complexes of Ni(0) and Ni(II) Pages 193-197 Rüdiger Faust, Bernd Göbelt, Christian Weber

Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)2Ru(Cl)(CC–C6H4-p-NO2)], [(dppe)2Ru(Cl)(CC–C6H3-o-CH3-p-NO2)] and [(dppm)2Os(CC–C6H4-p-CH3)(CC–C6H4-p-NO2)] Pages 198-209 Muhammad Younus, Nicholas J. Long, Paul R. Raithby, Jack Lewis, Nicola A. Page, Andrew J. P. White, David J. Williams, Michael C. B. Colbert, Andrew J. Hodge, Muhammad S. Khan, David G. Parker

A convenient short cut from aromatic iodides to alkynylstannanes and their use for the straightforward preparation of polyacetylene and polymetallaacetylene polymers Pages 210-222 Eleonora Antonelli, Patrizia Rosi, Claudio Lo Sterzo, Egidio Viola

Reactions of complex ligands 85: chiral quinoid and hydroquinoid [2.2]metacyclophanes via chromium-mediated intramolecular benzannulation Pages 223-228 K. H. Dötz, A. Gerhardt

Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((CC)n-p-C6H4Me) Pages 229-246 Roman Dembinski, Tadeusz Lis, Slawomir Szafert, Charles L. Mayne, Tamás Bartik, J. A. Gladysz

Hydrocarbon bridged metal complexes: XLV. Dinuclear polyene-bridged Fischer carbene complexes and a star-shaped benzene-bridged tris(ferrocenyl-decapentaenyl) compound Pages 247-251 Oliver Briel, Armin Fehn, Wolfgang Beck

Dialkynylated and functionalized alkynylated areneCr(CO)3-complexes—syntheses and structures of carbon rich chromium-complexed benzenes Pages 252-259 Thomas J. J. Müller, Markus Ansorge, Kurt Polborn

Rapid assembly of rigid rods by metal complexation of bis(terpyridyl) ligands Pages 260-263 Thomas E. Janini, Jennifer L. Fattore, Debra L. Mohler

Unprecedented coupling of vinylidene and allenylidene ligands with dithiocarbamates: X-ray structure of [Ru{C(=C=CPh2)SC(NMe2)S}(S2CNMe2)(CO)(PPh3)] Pages 264-267 Beatrice Buriez, Darren J. Cook, Karsten J. Harlow, Anthony F. Hill, Thomas Welton, Andrew J. P. White, David J. Williams, James D. E. T. Wilton-Ely

Index Page 269

Index Pages 271-275