Reactivity of cyclometallated semicarbazone complexes of Pd(II): crystal and molecular structures of [Pd{C6H4C(Et)=NN(H)C(=O)NH2}(PPh3)][ClO4] and [Pd{C6H4C(Et)=NN(H)C(=O)NH2}{(Ph2PCH2CH2)2PPh-P,P,P}][Cl] Pages 1-12 Alberto Fernández, Margarita López-Torres, Antonio Suárez, Juan M. Ortigueira, Teresa Pereira, Jesús J. Fernández, José M. Vila, Harry Adams |
Syntheses of cationic four-coordinated aluminum complexes: counter-ion induced aggregation through the N---H![]() Pages 13-19 Bao-Tsan Ko, Ying-Chieh Chao, Chu-Chieh Lin |
Alkyne insertion reactions of [RuH(κ2-S2CNEt2)(CO)(PPh3)2]: synthesis of alkenyl, alkynyl and enynyl complexes Pages 20-23 Robin B. Bedford, Catherine S. J. Cazin |
Synthesis of the diphenylacetylene-based, tetra-amine ligand 1,2-bis(3,5-bis[(dimethylamino)methyl]phenyl)acetylene by palladium-catalysed cross-coupling: isolation and crystal structure of the catalyst trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide Pages 24-27 Marieke P. R. Spee, Bart Ader, Pablo Steenwinkel, Huub Kooijman, Anthony L. Spek, Gerard van Koten |
Reactions of metalloalkynes: Part 6. Synthesis of open tetrametallic clusters. Reaction of [Ru(CO)4(ethene)] with ethyne-1,2-diyl compounds. Single crystal X-ray structural determinations of [Ru4(μ4-CC)(η-C5H4R)2(μ-CO)2(CO)8] (R=H, Me) Pages 28-35 Lindsay T. Byrne, James P. Hos, George A. Koutsantonis, Brian W. Skelton, Allan H. White |
Isolation of new polynuclear aluminium amides; trinuclear [AlCl(MeNCH2CH2NMe)2(Al(NMe2)Cl)(Al(NMe2)2)] and fluxional adamantane-like [Al4Cl2(NMe2)6(NMe)O] Pages 36-41 Graham Leggett, Majid Motevalli, Alice C. Sullivan |
Synthesis and properties of some novel ferrocene macrocyclic dioxopolyamines Pages 42-48 Peng Xue, Enqin Fu, Guochao Wang, Cuiqin Gao, Maohai Fang, Chengtai Wu |
Synthesis and crystal structures of the monomeric organotellurium(IV) trihalides: trans-2-ethoxy-cyclohexyl-tellurium(IV) trichloride, trichloro(2-chlorobicyclo[2.2.1]hept-7-yl)-λ4-tellurane, and mesityltellurium(IV) tribromide Pages 49-54 Dainis Dakternieks, Jenny O’Connell, Edward R. T. Tiekink |
Development of a T-joint for covalent molecular construction based on 2,2′-bipyridine and phenanthroline isocyanide metal complexes Pages 55-62 Yu-Bin Dong, Luqin Yang, Kung-Kai Cheung, Andreas Mayr |
Cyano-bridged extended heteronuclear supramolecular architectures with hexacyanoferrates(II) as building blocks Pages 63-70 Hua-Xin Zhang, Ye-Xiang Tong, Zhong-Ning Chen, Kai-Bei Yu, Bei-Sheng Kang |
Influence of phenyl ring substituents in the cyclometallation of Schiff base ligands: crystal and molecular structures of [Pd-{3,4-(OCH2O)C6H2C(H)=N(Cy)-C2,N}(μ-O2CMe)]2 and [Pd-{3,4-(OCH2CH2O)C6H2C(H)=N(Cy)-C6,N}(μ-O2CMe)]2 Pages 71-79 Berta Teijido, Alberto Fernández, Margarita López-Torres, Samuel Castro-Juiz, Antonio Suárez, Juan M. Ortigueira, José M. Vila, Jesús J. Fernández |
Diverse reactivity of rhodium β-(tetraphenyl)tetraphenyl porphyrin chlorides with benzonitrile: formation of Rh porphyrin arene and imine complexes Pages 80-86 Xiang Zhou, Man Kin Tse, De-Dong Wu, Thomas C. W. Mak, Kin Shing Chan |
Platinum(II) and palladium(II) compounds derived from [(η5-C5H5)Fe{(η5-C5H4)---CH=N---CH2---CH2---OH}] Pages 87-102 Concepción López, Amparo Caubet, Xavier Solans, Mercè Font-Bardía |
The synthesis and characterisation of bis(phenylpyridylphosphino)ethane Pages 103-107 Ian R. Butler, Peter Licence, Simon J. Coles, Michael B. Hursthouse |
Ferrocenyl ligands in mixed valence high-oxidation state rhenium complexes Pages 108-115 Otto Knoesen, Helmar Görls, Simon Lotz |
Water soluble phosphines: Part XIII. Chiral phosphine ligands with amino acid moieties Pages 116-126 David J. Brauer, Stefan Schenk, Stefan Roßenbach, Michael Tepper, Othmar Stelzer, Thomas Häusler, William S. Sheldrick |
(Fluoroorgano)fluoroboranes and -fluoroborates I: synthesis and spectroscopic characterization of potassium fluoroaryltrifluoroborates and fluoroaryldifluoroboranes Pages 127-135 H. -J. Frohn, H. Franke, P. Fritzen, V. V. Bardin |
Geometrical and electronic structures of the acetyl complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M=Mn,Re Pages 136-141 Thomas Scheiring, Wolfgang Kaim, Jan Fiedler |
Reactions of transition-metal η1-propargyl complexes with sulfur dioxide and sulfur trioxide: transition-metal–carbon bond cleaving reactions of the cycloadducts which yield 1,2-oxathiole-2-oxides and -2,2-dioxides Pages 150-159 Allison L. Hurley, Mark E. Welker, Cynthia S. Day |
Synthesis, characterization and X-ray structure of stannocanes substituted with a cyclic dithiophosphate ligand X(CH2CH2S)2SnnBu [S2P(OCH2C(Et2)CH2O)], (X=O, S): a study about the conformational tendencies and the relationship with the anomeric effect of the stannocane rings Pages 160-166 Patricia García y García, Raymundo Cruz-Almanza, Rubén-Alfredo Toscano, Raymundo Cea-Olivares |
Synthesis and reactivity of new oxo alkyl or oxo acyl niobocene complexes and crystal structure of Cp′2Nb(=O)(OC(O)CF3) (Cp′=η5-C5H4SiMe3) Pages 167-173 Antonio Antiñolo*, Isabel del Hierro, Isabel López-Solera, Santiago García-Yuste, Antonio Otero*, Mariano Fajardo, Ana Rodríguez |
Use of cis-dichloro[(S)-α-methylbenzylamine](ethylene)Pt(II) as a chiral derivatizing agent for the determination by 195Pt-NMR of the enantiomeric composition of unsaturated ethers or alcohols having a quaternary chiral carbon atom Pages 174-178 Gloria Uccello-Barretta, Raffaella Bernardini, Raffaello Lazzaroni, Piero Salvadori |
Non-bridged amido cyclopentadienyl complexes of titanium: synthesis, characterization, and olefin polymerization catalysis Pages 179-181 Piet-Jan Sinnema, Thomas P. Spaniol, Jun Okuda |
Preparation of [Et2InSb(SiMe3)2]3; a trimeric single-source precursor to indium antimonide Pages 182-186 Edward E. Foos, Richard J. Jouet, Richard L. Wells, Peter S. White |
Organotin mediated nitration in heteroaromatic series using tetranitromethane or dinitrogen tetroxide Pages 187-190 Fabien Favresse, Valérie Fargeas, Pierre Charrue, Bruno Lebret, Marc Piteau, Jean-Paul Quintard |
Implementation of the IPPP–CLOPPA–INDO/S method for the study of indirect nuclear spin coupling constants and its application to molecules containing tin nuclei Pages 193-201 Edith L. Botek, Gustavo A. Aucar, Marshall G. Cory, Michael C. Zerner |
On some reactions of undecamethylcyclohexasilanyl-substituted silanes Pages 202-210 Ulrich Englich, Susanne Graschy, Edwin Hengge, Uwe Hermann, Christoph Marschner, Christian Mechtler, Erich Pinter, Karin Ruhlandt-Senge, Frank Uhlig |
Synthesis and decomposition of bis(alkoxyethynyl)dimethyltin Pages 211-214 Bernd Wrackmeyer, Sergej V. Ponomarev |
Synthesis, characterization and solution studies on heteronuclear iron–copper clusters containing diphosphine ligands: crystal structure of the dicluster [{Fe2(μ-CO)(CO)6(μ-PPh2)Cu}2(dppp)] Pages 215-221 Montserrat Ferrer, Oriol Rossell, Miquel Seco, Mónica Soler, Mercè Font-Bardía, Xavier Solans, Dominique de Montauzon |
Direct displacement of chlorine or iodine in reactions of (Me3Si)3CSiRR′X with metal salts Pages 222-227 Kazem D. Safa, Mohammad G. Asadi, Abdolreza Abri, Ali Mohammadpour, Hadi Kiae |
Preparation of some dinuclear rhodium complexes with the orthometallated ligand [2,6-(PPh2CH2)2C6H3]− and their catalytic activity for polymerization of phenylacetylene Pages 228-234 Junzhi Yao, Wing Tak Wong, Guochen Jia |
2-Thioanisyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterization of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines Pages 235-242 Riitta H. Laitinen, Ville Heikkinen, Matti Haukka, Ari M. P. Koskinen, Jouni Pursiainen |
Interaction of bis(trimethylsilyl)acetylene complex of titanocene with tris(pentafluorophenyl)borane. Synthesis and structure of a new type of zwitterionic metallocene (η5-C5H5){η5-[C5H4B(C6F5)3]}Ti Pages 243-247 V. V. Burlakov, S. I. Troyanov, A. V. Letov, L. I. Strunkina, M. Kh. Minacheva, G. G. Furin, U. Rosenthal, V. B. Shur |
Synthesis, structure and coordination chemistry of mono- and bis-heterocyclic-ferrocenyl derivatives Pages 248-253 Christian J. Isaac, Clayton Price, Benjamin R. Horrocks, Andrew Houlton, Mark R. J. Elsegood, William Clegg |
Synthesis and some chemical properties of 3-ferrocenyl-3-isopropylcyclopropene: 3-ferrocenyl-3-isopropylstructures of cyclopropene and its adducts with 1,3-diphenylisobenzofuran Pages 254-261 Elena I. Klimova, Marcos Martínez García, Tatiana Klimova, Cecilio Alvarez Toledano, Ruben Alfredo Toscano, Lena Ruíz Ramírez |
Bromination and nitration reactions of metallated (Ru and Os) multiaromatic ligands and crystal structures of selected products Pages 262-275 Alex M. Clark, Clifton E. F. Rickard, Warren R. Roper*, L. James Wright* |
Mesitylpseudohalogermanes Mes2Ge(CN)2 and Mes3GeX (X=CN, NCS, N3, NCO and OH; Mes=2,4,6-trimethylphenyl): syntheses, crystal and molecular structures Pages 276-285 Goro Hihara, Rosemary C. Hynes, Anne-Marie Lebuis, Monique Rivière-Baudet, Ivor Wharf*, Mario Onyszchuk* |
Crystal structures and spectroscopic properties of platina-β-diketones — a new mode of stacking in platinum complexes Pages 286-291 Dirk Steinborn, Michael Gerisch, Tobias Hoffmann, Clemens Bruhn, Gunter Israel, Franz W. Müller |
Dimere der Ethene Me2E=C(SiMe3)2 (E=Si, Ge, Sn): Auf welchem Wege entstehen sie aus Me2EX---CM(SiMe3)2? Wie sind sie strukturiert? Pages 292-303 N. Wiberg, T. Passler, S. Wagner, K. Polborn |
Addukte der Ethene Me2E=C(SiMe3)2 (E=Si, Ge, Sn) mit LiR und RN3: Wie rasch bilden sie sich? Pages 304-312 N. Wiberg, T. Passler, S. Wagner |
Synthesis and crystal structure of [U(η-C8H8)]2[μ-η4:η4-HN(CH2)3N(CH2)2N(CH2)3NH], a dinuclear compound with a bridging tetra-amide ligand Pages 313-317 Thierry Le Borgne, Monique Lance, Martine Nierlich, Michel Ephritikhine |
Activation of a coordinated alkyne by electron transfer: crystal structures of [![]() ![]() ![]() Pages 318-328 M. Fernanda N. N. Carvalho, Adelino M. Galvão, Armando J. L. Pombeiro, Jan ![]() ![]() ![]() |
P,N-Heterodifunctional ligands by selective Staüdinger reaction of β-substituted vinylazides with (Z)-1,2-bis(diphenylphosphanyl)ethene and formation of cyclometalled complexes of palladium(II) of these ligands — crystal and molecular structure of a new chiral cyclometallaphosphoraniminophosphane of palladium(II) Pages 329-338 Antonio Arques*, Pedro Molina*, David Auñón, María Jesús Vilaplana, M. Desamparados Velasco, Francisco Martínez, Delia Bautista, Fernando J. Lahoz |
Syntheses of titanium μ-arylimido and μ-pyridylimido complexes bearing (un)substituted cyclopentadienyl ligand Pages 339-347 Zheng Li, Jiling Huang, Tianer Yao, Yanlong Qian, Meiyu Leng |
Conversion of tributylstannylferrocene to a variety of heteroaryl ferrocenes Pages 348-352 Chao-Min Liu, Bao-Hua Chen, Wan-Yi Liu, Xiao-Li Wu, Yong-Xiang Ma |
Syntheses, characterization and structures of chromium group carbonyl complexes containing a multifunctional Ph2P(o-C6H4)CH=N(CH2)2(o-C6H4N) ligand Pages 353-358 Ching-Chao Yang, Wen-Yann Yeh, Gene-Hsiang Lee, Shie-Ming Peng |
Heteroleptic diphenylamido complexes of ytterbium: syntheses and molecular structures of (MeC5H4)2YbNPh2(THF) and (C5Me5)2YbNPh2 Pages 359-364 Yaorong Wang, Qi Shen, Feng Xue, Kaibei Yu |
New 1,1′- or 1,2- or 1,3-bis(diphenylphosphino)ferrocenes Pages 365-373 Roland Broussier, Emmanuelle Bentabet, Patrick Mellet, Olivier Blacque, Patricia Boyer, Marek M. Kubicki, Bernard Gautheron |
A theoretical study of gas-phase and solid-state Hg(CF3)2 Pages 374-380 Meng-Sheng Liao, Song-Ping D. Huang |
Preparation of germatranyl triflates: reactions of germatranes N(CH2CHRO)3X (X=Br, OTf, OSiMe3; R=H, Me) with lithium reagents Pages 387-394 Sergey S. Karlov, Pavel L. Shutov, Novruz G. Akhmedov, Markus A. Seip, Jörg Lorberth*, Galina S. Zaitseva* |
Head-to-head versus head-to-tail dimerizations of transient silenes — the generation and dimerization behavior of 2-(2-dimethylaminoaryl)-1,1-bis(trimethylsilyl)silenes Pages 395-402 Douglas Hoffmann, Thoralf Gross, Rhett Kempe, Hartmut Oehme |
Carbonyl insertion into zirconium–nitrogen bonds; synthesis and X-ray structure of a carbene complex composed of [Zr(NMe2)4]2 and three Fe(CO)5 units containing Fe→Zr donor–acceptor interactions Pages 403-408 Wolfgang Petz, Frank Weller, Evgeni V. Avtomonov |
Fluoroalkylated N-heterocyclic carbene complexes of palladium Pages 409-416 Lijin Xu, Weiping Chen, Jamie F. Bickley, Alexander Steiner, Jianliang Xiao |
Index Pages 419-420 |
Index Pages 421-429 |