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Title page Page iii |
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Table of contents Pages vii-xi |
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Preface Page 1 Helmut Werner |
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Catalytic oxidations by peroxy, peroxo and oxo metal complexes: an interdisciplinary account with a personal view Pages 3-16 Waldemar Adam, Wolfgang Malisch, Konrad J. Roschmann, Chantu R. Saha-Möller, Wolfdieter A. Schenk |
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Biocatalytic synthesis of optically active oxyfunctionalized building blocks with enzymes, chemoenzymes and microorganisms Pages 17-29 Waldemar Adam, Frank Heckel, Chantu R. Saha-Möller, Peter Schreier |
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The lactone concept—a novel approach to the metal-assisted atroposelective construction of axially chiral biaryl systems Pages 31-47 Gerhard Bringmann, Matthias Breuning, Robert-M. Pfeifer, Wolfdieter A. Schenk, Ken Kamikawa, Motokazu Uemura |
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The directed synthesis of axially chiral ligands, reagents, catalysts, and natural products through the ‘lactone methodology’ Pages 49-65 Gerhard Bringmann, Stefan Tasler, Robert-M. Pfeifer, Matthias Breuning |
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Transition metal-catalyzed oxidations of bishomoallylic alcohols Pages 67-84 Jens Hartung, Marco Greb |
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Transition metal complexes with polydentate amido ligands: novel structural building blocks and chemical reagents Pages 85-94 Lutz H. Gade |
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Hydrophosphination with cationic primary phosphine iron complexes: synthesis of P-chiral functionalized phosphines Pages 95-110 Wolfgang Malisch, Bernd Klüpfel, Dirk Schumacher, Martin Nieger |
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Phosphane- and phosphorane Janus Head ligands in metal coordination Pages 111-127 Frank Baier, Zhaofu Fei, Heinz Gornitzka, Alexander Murso, Stefan Neufeld, Matthias Pfeiffer, Ina Rüdenauer, Alexander Steiner, Thomas Stey, Dietmar Stalke |
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Stereoselective addition reactions of ruthenium thioaldehyde complexes Pages 129-136 Wolfdieter A. Schenk |
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Iridium-containing cumulenes: how to prepare and how to use Pages 137-147 Helmut Werner, Kerstin Ilg, Raimund Lass, Justin Wolf |
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Enantiomerically enriched ‘carbanions’:: Studies on the stereochemical course of selective transformations of metal alkyls Pages 149-158 Carsten Strohmann, Bors C. Abele, Klaus Lehmen, Fernando Villafañe, Luisa Sierra, Susana Martín-Barrios, Daniel Schildbach |
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Selective reactions of transition-metal-generated radicals Pages 159-167 Torsten Linker |
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One-electron oxidation of metal enolates and metal phenolates Pages 169-179 Michael Schmittel, Andreas Haeuseler |
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The metal---carbon bond in vinylidene, carbonyl, isocyanide and ethylene complexes Pages 181-190 D. Moigno, B. Callejas-Gaspar, J. Gil-Rubio, H. Werner, W. Kiefer |
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Time-resolved photoelectron spectroscopy:: A unique tool to monitor the vibrational and fragmentation dynamics of metal carbonyls Pages 191-197 M. Erdmann, O. Rubner, Z. Shen, V. Engel |
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Time-resolved organometallic photochemistry: Femtosecond fragmentation and adaptive control of CpFe(CO)2X (X=Cl, Br, I) Pages 199-209 M. Bergt, T. Brixner, C. Dietl, B. Kiefer, G. Gerber |
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Author index Page 211 |
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Subject index Pages 213-215 |
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Contents index Page 217 |