Volume 680
Main Index

Issues 1-2, Pages 1-345 (29 August 2003)

Title Page Page iii

Table of Contents Pages vii-xvii

Introduction: Frontiers in Boron Chemistry: Dedicated to Professor M. Frederick Hawthorne in celebration of his 75th birthday Pages 1-2 Todd B. Marder

Transition metal-catalyzed borylation of alkanes and arenes via C---H activation Pages 3-11 Tatsuo Ishiyama, Norio Miyaura

The use of organoboron chlorides and bromides in organic synthesis Pages 12-22 G. W. Kabalka, Zhongzhi Wu, Yuhong Ju

The chemistry of the azanonaborane cluster RNH2---B8H11NHR Pages 23-26 Detlef Gabel, Claudia Bauer, Mohamed E. El-Zaria, Afaf R. Genady, Udo Dörfler

Poly(cyclodiborazane)s Pages 27-30 Fukashi Matsumoto, Yoshiki Chujo

The chemistry of [1]borametallocenophanes and related compounds Pages 31-42 Holger Braunschweig, Frank M. Breitling, Emanuel Gullo, Mario Kraft

Regio- and stereoselective synthesis of boryl-substituted allylsilanes via transition metal-catalyzed silaboration Pages 43-50 Michinori Suginome, Yoshihiko Ito

Small cobaltacarborane clusters in synthesis. Peralkylation, perhalogenation, and macrocycle construction Pages 51-60 Haijun Yao, Russell N. Grimes

Synthesis and structural characterization of an 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9 Pages 61-65 Daewon Hong, Patrick J. Carroll, Larry G. Sneddon

Reactions of nido-1,2-(Cp*RuH)2B3H7 with RCCR′ (R, R′=H, Ph; Me, Me) to yield novel metallacarboranes Pages 66-80 Hong Yan, Alicia M. Beatty, Thomas P. Fehlner

Reactions of the dichloroboryl complex of osmium, Os(BCl2)Cl(CO)(PPh3)2, with water, alcohols, and amines: Crystal structures of Os[B(OH)2]Cl(CO)(PPh3)2, Os[B(OEt)2]Cl(CO)(PPh3)2, and Pages 81-88 George R. Clark, Geoffrey J. Irvine, Warren R. Roper, L. James Wright

A versatile rigid binucleating ligand for Rh2(μ-Cl)2 moieties: its application as a catalyst in hydrogenation and cyclopropanation: Crystal structure of [Rh(C5Me5)Cl{7,8-μ-S(4′-C6H3(CH3))S-C2B9H10}][7,8-μ-S(4′-C6H3(CH3))S-C2B9H10]·THF Pages 89-99 Francesc Teixidor, M Rosa Cirera, Clara Viñas, Raikko Kivekäs, Reijo Sillanpää, Albert Demonceau

Bromination of tri(isopropyl)boroxine and asymmetric synthesis of (2-cyano-3,3-dimethylcyclopropyl)boronic esters Pages 100-105 Donald S. Matteson, Dilinie Fernando

[C2B10]---[B12] double cage boron compounds—a new approach to the synthesis of water-soluble boron-rich compounds for BNCT Pages 106-110 Igor B. Sivaev, Stefan Sjöberg, Vladimir I. Bregadze

First agostic closo-metallacarboranes with η3-cyclooctenyl type ligand: synthesis and structural characterization of closo-3-[η3-(endo-1,5-dimethylcycloocten-1-yl)]-1,2-μ-(1′,2′-xylylene)-3,1,2-IrC2B9H9 and its isomerization to closo-3-[η3-(exo-1-methylene-5-methylcyclooctene-1-yl)]-1,2-μ-[η2-(1′,2′-xylylene)]-3,1,2-IrC2B9H9 Pages 111-123 Alexander V. Safronov, Tatiana V. Zinevich, Fedor M. Dolgushin, Evgenii V. Vorontsov, Oleg L. Tok, Igor T. Chizhevsky

Synthesis of adenosine containing carborane modification Pages 124-126 Agnieszka B. Olejniczak, Andrey Semenuk, Marek Kwiatkowski, Zbigniew J. Lesnikowski

exo-closo-Rhodacarboranes: synthesis and characterisation of [{exo-(R3P)2Rh}(closo-CB11H12)] [R3P=P(OMe)3, PCy3, 1/2dppe] Pages 127-135 A. Rifat, V. E. Laing, G. Kociok-Köhn, M. F. Mahon, G. D. Ruggiero, A. S. Weller

Synthesis and reaction of secondary and primary diorganozinc reagents using a boron–zinc exchange reaction: A useful method for the stereo- and regioselective formation of new carbon---carbon bonds Pages 136-142 Eike Hupe, M. Isabel Calaza, Paul Knochel

Catalyzed hydroboration of allyl sulfonamides Pages 143-147 Michael G. Hamilton, Catrin E. Hughes, Alison M. Irving, Christopher M. Vogels, Stephen A. Westcott

Density functional theory studies on structural isomers and bonding of catecholborane adducts of Group 5 metallocene (Nb, Ta) hydride complexes Pages 148-154 Dan Liu, King-Chung Lam, Zhenyang Lin

Big macrocyclic assemblies of carboranes (big MACs): synthesis and crystal structure of a macrocyclic assembly of four carboranes containing alternate ortho- and meta-carborane icosahedra linked by para-phenylene units Pages 155-164 Mark A. Fox, Judith A. K. Howard, J. A. Hugh MacBride, Angus Mackinnon, Kenneth Wade

Dimesitylborane monomer-dimer equilibrium in solution, and the solid-state structure of the dimer by single crystal neutron and X-ray diffraction Pages 165-172 Christopher D. Entwistle, Todd B. Marder, Philip S. Smith, Judith A. K. Howard, Mark A. Fox, Sax A. Mason

Group 4 metallacarboranes of constrained geometries derived from B(cage)- and C(cage)-silylamido-substituted carborane ligands: a synthetic and structural investigation Pages 173-181 Jianhui Wang, Yinghuai Zhu, Shoujian Li, Chong Zheng, John A. Maguire, Narayan S. Hosmane

9-BBN activation. Synthesis, crystal structure and theoretical characterization of the ruthenium complex Ru[(μ-H)2BC8H14]2(PCy3) Pages 182-187 Khaled Essalah, Jean-Claude Barthelat, Virginia Montiel, Sébastien Lachaize, Bruno Donnadieu, Bruno Chaudret, Sylviane Sabo-Etienne

High yield [125I]iodide-labeling of iodinated carboranes by palladium-catalyzed isotopic exchange Pages 188-192 Karl Johan Winberg, Gemma Barberà, Ludvig Eriksson, Francesc Teixidor, Vladimir Tolmachev, Clara Viñas, Stefan Sjöberg

Ansa-metallocenes with B---N and B---P linkages: the importance of N---HF---C hydrogen bonding in pentafluorophenyl boron compounds Pages 193-205 Simon J. Lancaster, Andrew J. Mountford, David L. Hughes, Mark Schormann, Manfred Bochmann

Enantioselective rhodium-catalysed addition of boronic acids using C2-symmetric aryl diphosphite ligands Pages 206-211 Christopher J. Chapman, Kelly J. Wadsworth, Christopher G. Frost

Functionalization of the macropolyhedral borate anion cluster [B22H22]2−: isolation and characterization of the OH and OEt derivatives Pages 212-217 O. Volkov, N. P. Rath, L. Barton

Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4 Pages 218-222 Roland Roesler, Warren E. Piers, Masood Parvez

A new strategy for molecular modeling and receptor-based design of carborane containing compounds Pages 223-231 Jayaseharan Johnsamuel, Youngjoo Byun, Thomas P. Jones, Yasuyuki Endo, Werner Tjarks

Synthesis of ether- and carbon-linked polycarboranyl porphyrin dimers for cancer therapies Pages 232-243 Meden F. Isaac, Stephen B. Kahl

Two-electron homoaromatics with heteroatom bridges Pages 244-256 Yüksel Sahin, Andreas Ziegler, Thorsten Happel, Harald Meyer, Michael J. Bayer, Hans Pritzkow, Werner Massa, Matthias Hofmann, Paul von Ragué Schleyer, Walter Siebert, Armin Berndt

Synthesis and structure of potential Lewis acid–Lewis base bifunctional catalysts: 1-N,N-dimethylamino-8-borononaphthalene derivatives Pages 257-262 Richard L. Giles, Judith A. K. Howard, Leonard G. F. Patrick, Michael R. Probert, Gillian E. Smith, Andrew Whiting

Design of chiral boronate-substituted acrylanilides.: Self-activation and boron-transmitted 1,8-stereoinduction in [4+2] cycloaddition Pages 263-270 Jason W. J. Kennedy, Dennis G. Hall

1,3,2-Diazastanna-[3]ferrocenophanes bearing alkyn-1-yl groups at tin and their 1,1-organoboration with triethylborane—molecular structure of a novel spirotin compound Pages 271-280 Bernd Wrackmeyer, Heidi E. Maisel, Wolfgang Milius, Max Herberhold

Synthesis of enantiomerically pure vinylcyclopropylboronic esters via cross-metathesis Pages 281-285 Pilar Garcia Garcia, Erwin Hohn, Jörg Pietruszka

Platination of [3-X-7,8-Ph2-7,8-nido-C2B9H8]2− (X=Et, F): Synthesis and characterisation of slipped and 1,2→1,7 isomerised products Pages 286-293 Susan Robertson, David Ellis, Georgina M. Rosair, Alan J. Welch

Synthesis, structures and reactivity of macrocyclic imidazolylboranes Pages 294-300 Andre Weiss, Victor Barba, Hans Pritzkow, Walter Siebert

The chemistry of the undecaborates Pages 301-311 Oleg Volkov, Peter Paetzold

Macropolyhedral boron-containing cluster chemistry. Aspects of the S2B16H16 system. Preparation, structure, NMR spectroscopy and isomerism Pages 312-322 Pervinder K. Dosangh, Jonathan Bould, Michael G. S. Londesborough, Tomá Jelínek, Mark Thornton-Pett, Bohumil tíbr, John D. Kennedy

Synthesis of homoleptic Re(I) complexes of isocyano-carboranes and the X-ray structure of hexakis(p-carboran-1-yl-isonitrile)Re(I) Pages 323-328 Paul Schaffer, James F. Britten, Alan Davison, Alun G. Jones, John F. Valliant

Mechanistic and synthetic aspects of hydroboration with a simple atropisomeric ligand prepared from 1-(1′-(isoquinolyl)-2-naphthol Pages 329-334 Andrei Korostylev, Ilya Gridnev, John M. Brown

Author Index Pages 335-336

Subject Index Pages 337-342

Contents Index Pages 343-345