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Volume 98
Main Index

Issue 1


A new method for the determination of intersystem crossing quantum yields. Application to benzene and its methyl derivatives
Felix A. Carroll and Frank H. Quina
pp 1 - 6; DOI:
10.1021/ja00417a001
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Radiative and nonradiative transitions in solution. First excited singlet state of benzene and its methyl derivatives
Frank H. Quina and Felix A. Carroll
pp 6 - 9; DOI:
10.1021/ja00417a002
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Molecular orbital theory of the electronic structure of organic compounds. XXII. Structures and stabilities of C3H3+ and C3H+ cations
Leo Radom, P. C. Hariharan, John A. Pople, and Paul v. R. Schleyer
pp 10 - 14; DOI:
10.1021/ja00417a003
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Phosphorus-31 nuclear magnetic resonance spectroscopy in the determination of conformational free energies of phosphorus groups on the cyclohexane ring
Michael D. Gordon and Louis D. Quin
pp 15 - 23; DOI:
10.1021/ja00417a004
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A new approach to empirical intermolecular and conformational potential energy functions. III. Application of EPEN to the conformational analysis of 1,2-disubstituted ethanes
Antony W. Burgess, Lester L. Shipman, Raphael A. Nemenoff, and Harold A. Scheraga
pp 23 - 29; DOI:
10.1021/ja00417a005
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Solution and complexing studies. III. Further evidence for a microscopic partitioning theory of solution
R. J. Laub and J. H. Purnell
pp 30 - 35; DOI:
10.1021/ja00417a006
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Solution and Complexing Studies. VI. Extension of Microscopic Partition Theory to Include Nonstoichiometric Complexation and Solvent Effects, and the Correlation of GLC, Uv, and NMR data
R. J. Laub and J. H. Purnell
pp 35 - 39; DOI:
10.1021/ja00417a007
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Predominant scalar interactions in selective broadening of ligand nuclear magnetic resonance by copper(II) ions
William G. Espersen and R. Bruce Martin
pp 40 - 44; DOI:
10.1021/ja00417a008
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Photoassisted electrolysis of water by ultraviolet irradiation of an antimony doped stannic oxide electrode
Mark S. Wrighton, David L. Morse, Arthur B. Ellis, David S. Ginley, and Harmon B. Abrahamson
pp 44 - 48; DOI:
10.1021/ja00417a009
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Flash kinetic spectroscopy of octachlorodirhenate(2-) octabromodirhenate(2-)
R. H. Fleming, G. L. Geoffroy, Harry B. Gray, A. Gupta, G. S. Hammond, D. S. Kliger, and V. M. Miskowski
pp 48 - 50; DOI:
10.1021/ja00417a010
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The helium(I) photoelectron spectra and electronic structure of (.eta.5-cyclopentadienyl) d6 metal carbonyls
Dennis L. Lichtenberger and Richard F. Fenske
pp 50 - 63; DOI:
10.1021/ja00417a011
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Thermolysis of diene iron tricarbonyl complexes. Cis-trans isomerization and hydrogen scrambling reactions in cyclic and acyclic complexes
Thomas H. Whitesides and James P. Neilan
pp 63 - 73; DOI:
10.1021/ja00417a012
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"Side-on" dinitrogen-transition metal complexes. The molecular structure of {C6H5[Na.O(C2H5)2]2[(C6H5)2Ni]2N2NaLi6(OC2H5)4.O(C2H5)2}2
K. Jonas, D. J. Brauer, C. Krueger, P. J. Roberts, and Y. H. Tsay
pp 74 - 81; DOI:
10.1021/ja00417a013
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The Crystal structure of ferrioxamine E
Dick Van der Helm and M. Poling
pp 82 - 86; DOI:
10.1021/ja00417a014
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The reactivity of cobalt(I) complexes containing unsaturated macrocyclic ligands in aqueous solution
A. Martin Tait, Morton Z. Hoffman, and E. Hayon
pp 86 - 93; DOI:
10.1021/ja00417a015
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Nitric oxide complexes of manganese and chromium tetraphenylporphyrin
B. B. Wayland, L. W. Olson, and Z. U. Siddiqui
pp 94 - 98; DOI:
10.1021/ja00417a016
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Energetics of electrode reactions. II. The relationship between redox potentials, ionization potentials, electron affinities, and solvation energies of aromatic hydrocarbons
Vernon D. Parker
pp 98 - 103; DOI:
10.1021/ja00417a017
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Photochemistry of ketoalkyltrimethylstannanes in alkanes and in carbon tetrachloride
Henry G. Kuivila, Perry L. Maxfield, Kuang-Hsin Tsai, and James E. Dixon
pp 104 - 109; DOI:
10.1021/ja00417a018
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Photoelectron spectra and molecular properties. L. On the blue color of bis(trimethylsilyl)diimine
H. Bock, K. Wittel, M. Veith, and N. Wiberg
pp 109 - 114; DOI:
10.1021/ja00417a019
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Reaction of thiol anions with benzene oxide and malachite green
D. M. E. Reuben and Thomas C. Bruice
pp 114 - 121; DOI:
10.1021/ja00417a020
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Thermal stereomutation of cyclopropanes
Jerome A. Berson, Larry D. Pedersen, and Barry K. Carpenter
pp 122 - 143; DOI:
10.1021/ja00417a021
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Cycloaddition. XIX. Competing concerted and stepwise [2 + 4]cycloaddition of the dichlorodifluoroethylenes to butadiene and 2,4-hexadiene
Paul D. Bartlett and Jacques J. B. Mallet
pp 143 - 151; DOI:
10.1021/ja00417a022
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Homotropylium-8-sulfinate complexes by antimony pentafluoride-promoted ring opening of 9-thiabicyclo[4.2.1]nona-2,4,7-triene and 9-thiabarbaralane 9,9-dioxides
Leo A. Paquette, Ulla Jacobsson, and Steven V. Ley
pp 152 - 158; DOI:
10.1021/ja00417a023
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The general acid catalyzed displacement of amines from o-hydroxylaminobenzamides in aqueous and nonaqueous solvents
Brian G. Cox and Alexander E. A. Porter
pp 159 - 162; DOI:
10.1021/ja00417a024
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The disproportionation of trityl benzyl ethers. Kinetic analysis of the trityl salt catalyzed reaction. Evidence for the involvement of ion pairs in the hydrogen transfer step
Michael P. Doyle and Bernard Siegfried
pp 163 - 166; DOI:
10.1021/ja00417a025
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Ring-cleavage rearrangement of the Grignard reagent from 2-methylcyclobutylmethyl chloride. Observations on possible radical mechanisms of Grignard rearrangement
E. Alexander Hill, Augustin T. Chen, and Alan Doughty
pp 167 - 170; DOI:
10.1021/ja00417a026
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Equilibration studies. Protomeric equilibria of 2- and 4-hydroxypyridines, 2- and 4-hydroxypyrimidines, 2- and 4-mercaptopyridines, and structurally related compounds in the gas phase
Peter Beak, Fred S. Fry, Jaekeun Lee, and Frank Steele
pp 171 - 179; DOI:
10.1021/ja00417a027
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Ionization of oxyphosphoranes. Phosphonium ions and hexacoordinated phosphorus anions
Charles L. Lerman and F. H. Westheimer
pp 179 - 184; DOI:
10.1021/ja00417a028
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Rates of ionization of phosphoranes
Don I. Phillips, Ivanka Szele, and F. H. Westheimer
pp 184 - 189; DOI:
10.1021/ja00417a029
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Computer-assisted synthetic analysis. Synthetic strategies based on appendages and the use of reconnective transforms
E. J. Corey and William L. Jorgensen
pp 189 - 203; DOI:
10.1021/ja00417a030
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Computer-assisted synthetic analysis. Generation of synthetic sequences involving sequential functional group interchanges
E. J. Corey and William L. Jorgensen
pp 203 - 209; DOI:
10.1021/ja00417a031
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Computer-assisted synthetic analysis. The identification and protection of interfering functionality in machine-generated synthetic intermediates
E. J. Corey, H. W. Orf, and David A. Pensak
pp 210 - 221; DOI:
10.1021/ja00417a032
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A stereoselective synthesis of (+-)-11-hydroxy-trans-8-dodecenoic acid lactone, a naturally occurring macrolide from Cephalosporium recifei
E. J. Corey, Peter Ulrich, and J. Michael Fitzpatrick
pp 222 - 224; DOI:
10.1021/ja00417a033
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Total synthesis of gentiocrucine, an unusual alkaloid containing a stable primary enamide
Bruce Ganem
pp 224 - 226; DOI:
10.1021/ja00417a034
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A method for determining the conformational preference of nonrigid radicals by electron paramagnetic resonance
John B. Lisle, Lawrence F. Williams, and David Eldon Wood
pp 227 - 228; DOI:
10.1021/ja00417a035
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Barrier to pyramidal inversion in the tert-butyl radical by electron spin resonance
P. J. Krusic and P. Meakin
pp 228 - 230; DOI:
10.1021/ja00417a036
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An electron spin resonance study of the substituent effects causing nonplanarity in alkyl radicals. Electronegativity vs. .pi.-conjugative destabilization
P. J. Krusic and R. C. Bingham
pp 230 - 232; DOI:
10.1021/ja00417a037
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A novel quasi-one-dimensional zig-zag platinum atom chain in K1.75Pt(CN)4.1.5H2O. A neutron diffraction study
Keith D. Keefer, Donald M. Washecheck, Nancy P. Enright, and Jack M. Williams
pp 233 - 234; DOI:
10.1021/ja00417a038
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A partially oxidized one-dimensional complex containing a distorted platinum chain. The molecular and crystal structure of K1.75Pt(CN)4.1.5H2O
A. H. Reis, S. W. Peterson, D. M. Washecheck, and Joel S. Miller
pp 234 - 236; DOI:
10.1021/ja00417a039
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Allenic retinals and visual pigment analogues
K. Nakanishi, Anthony P. Yudd, R. K. Crouch, G. L. Olson, H. C. Cheung, R. Govindjee, T. G. Ebrey, and D. J. Patel
pp 236 - 238; DOI:
10.1021/ja00417a040
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Micellar effects on the photochemistry of rhodopsin
Walter H. Waddell, Anthony P. Yudd, and Koji Nakanishi
pp 238 - 239; DOI:
10.1021/ja00417a041
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A rotation-controlled excited-state reaction. The photoenolization of ortho alkyl phenyl ketones
Peter J. Wagner and C. P. Chen
pp 239 - 241; DOI:
10.1021/ja00417a042
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Enhanced photocyclization of .alpha.-fluoro ketones
Peter J. Wagner and Michael J. Thomas
pp 241 - 243; DOI:
10.1021/ja00417a043
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Time resolved electron spin resonance spectroscopy. III. Electron spin resonance emission from the hydrated electron. Possible evidence for reaction to the triplet state
Richard W. Fessenden and N. C. Verma
pp 243 - 244; DOI:
10.1021/ja00417a044
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Correlation of STO-3G calculated substituent effects on the proton affinity of benzene with .sigma.+ parameters
John M. McKelvey, Spiro Alexandratos, Andrew Streitwieser, Jose L. M. Abboud, and Warren J. Hehre
pp 244 - 246; DOI:
10.1021/ja00417a045
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Structure and synthesis of verruculotoxin, a new mycotoxin from Penicillium verruculosum Peyronel
James G. Macmillan, James P. Springer, Jon Clardy, Richard J. Cole, and Jerry W. Kirksey
pp 246 - 247; DOI:
10.1021/ja00417a046
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Synergism of the effect of solvent and of general base catalysis in the hydrolysis of a Schiff base
Ralph M. Pollack and Margaret Brault
pp 247 - 248; DOI:
10.1021/ja00417a047
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New synthetic methods. A stereocontrolled approach to cyclopentane annelation
Barry M. Trost and Donald E. Keeley
pp 248 - 250; DOI:
10.1021/ja00417a048
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Resonance Raman spectroelectrochemistry. IV. The oxygen decay chemistry of the tetracyanoquinodimethane dianion
Mary R. Suchanski and Richard P. Van Duyne
pp 250 - 252; DOI:
10.1021/ja00417a049
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Dehydrotetrathianaphthazarin
F. Wudl, D. E. Schafer, and B. Miller
pp 252 - 254; DOI:
10.1021/ja00417a050
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On the sensitive probe for double layer structure. Potential dependent competitive cyanation and methoxylation of 1,4-dimethoxybenzene
Kunihisa Yoshida
pp 254 - 254; DOI:
10.1021/ja00417a051
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Reduction of .eta.5-cyclopentadienyldicarbonylcobalt. Formation of tetracarbonylcobaltate and [.eta.5-C5H5CoCO]2.-. A binuclear cobalt radical anion
Casmir S. Henda, Neil E. Schore, and Robert G. Bergman
pp 255 - 256; DOI:
10.1021/ja00417a052
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Crystal and molecular structure, spectroscopic properties, and redox behavior of [.eta.5-C5H5CoCO]2.-, a "mixed-valence" organometallic radical anion having a high degree of intramolecular delocalization and cobalt in formal oxidation state +0.5
Neil E. Schore, Casmir S. Ilenda, and Robert G. Bergman
pp 256 - 258; DOI:
10.1021/ja00417a053
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Cooperative catalysis of the cleavage of an amide by carboxylate and phenolic groups in a carboxypeptidase A model
Ronald Breslow and David E. McClure
pp 258 - 259; DOI:
10.1021/ja00417a054
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On the mechanism of catalysis by carboxypeptidase A
Ronald Breslow and David Wernick
pp 259 - 261; DOI:
10.1021/ja00417a055
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Benzocyclobutadiene
O. L. Chapman, C. C. Chang, and N. R. Rosenquist
pp 261 - 262; DOI:
10.1021/ja00417a056
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Hydrozirconation. V. .gamma.,.delta.-Unsaturated aldehydes and halides from 1,3-dienes via organozirconium(IV) intermediates
Christopher A. Bertelo and Jeffrey Schwartz
pp 262 - 264; DOI:
10.1021/ja00417a057
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Nonexponential methyl proton spin-lattice relaxation in the C-terminal tetrapeptide of gastrin
John D. Cutnell and Jay A. Glasel
pp 264 - 265; DOI:
10.1021/ja00417a058
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Gas phase proton affinities of molecules in excited electronic states by ion cyclotron resonance spectroscopy
B. S. Freiser and J. L. Beauchamp
pp 265 - 266; DOI:
10.1021/ja00417a059
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Total synthesis of (+-)-steganacin
Andrew S. Kende and Lanny S. Liebeskind
pp 267 - 268; DOI:
10.1021/ja00417a060
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Formation of radical anion from tetracyanoethylene in dimethyl sulfoxide
Nobuo Kushibiki and Hiroshi Yoshida
pp 268 - 269; DOI:
10.1021/ja00417a061
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Allylic amination of olefins and acetylenes by imido selenium compounds
K. B. Sharpless, Tetsuo Hori, L. K. Truesdale, and C. O. Dietrich
pp 269 - 271; DOI:
10.1021/ja00417a062
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A reiterative functionalization of unactivated carbon-hydrogen bonds. Photolysis of .alpha.-peracetoxynitriles
David S. Watt
pp 271 - 273; DOI:
10.1021/ja00417a063
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Alkyl substituent effects in electrophilic substitution at saturated carbon. Inapplicability of Taft .sigma.* values
William A. Nugent and Jay K. Kochi
pp 273 - 274; DOI:
10.1021/ja00417a064
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Stereospecific incorporation of oxygen-18 into manganese and rhenium pentacarbonyl derivatives via exchange reactions with water (oxygen-18)
Donald J. Darensbourg and D. Drew
pp 275 - 276; DOI:
10.1021/ja00417a065
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A long range deuterium isotope effect on a lanthanide induced chemical shift
C. H. DePuy, P. C. Fuenfschilling, and J. M. Olson
pp 276 - 278; DOI:
10.1021/ja00417a066
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Structures of zinc octaethyl formylbiliverdinate hydrate and its dehydrated bis-helical dimer
G. Struckmeier, U. Thewalt, and J. H. Fuhrhop
pp 278 - 279; DOI:
10.1021/ja00417a067
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The bicyclooctatetraenyl tetraanion. A quadruply charged 20 .pi.-electron biphenyl analog
Leo A. Paquette, Gary D. Ewing, and Sean G. Traynor
pp 279 - 281; DOI:
10.1021/ja00417a068
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Dissymmetric 1,3-dienes. III. Enantiomerization barriers in some cyclic vic-dialkylidene compounds
Lynn W. Jelinski and Edgar F. Kiefer
pp 281 - 282; DOI:
10.1021/ja00417a069
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Dissymmetric 1,3-dienes. IV. Syntheses and enantiomerization barriers of some acyclic vic-dialkylidene compounds
Lynn W. Jelinski and Edgar F. Kiefer
pp 282 - 283; DOI:
10.1021/ja00417a070
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Alkane diazotates. Part XX. The ethylation of syn- and anti-1-phenylethane diazotate. Dependence of reaction stereochemistry on configuration at the diazo linkage
Robert A. Moss and Clois E. Powell
pp 283 - 285; DOI:
10.1021/ja00417a071
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Evidence for radical intermediates in the addition of tetracyanoethylene to pentakis(methyl isocyanide)cobalt(I)
Alan L. Balch
pp 285 - 286; DOI:
10.1021/ja00417a072
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Electron transfer quenching of excited states of metal complexes
Roger C. Young, Thomas J. Meyer, and David G. Whitten
pp 286 - 287; DOI:
10.1021/ja00417a073
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Isotope effects on gas phase reaction processes. I. The determination of equilibrium isotope effects by ion cyclotron resonance spectroscopy
J. Frederick Wolf, John L Devlin, Robert W. Taft, Max Wolfsberg, and Warren J. Hehre
pp 287 - 289; DOI:
10.1021/ja00417a074
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Organic synthesis using enzymes in two-phase aqueous ternary polymer systems
Alfred Pollak and George M. Whitesides
pp 289 - 291; DOI:
10.1021/ja00417a075
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The sign of the bridgehead-bridgehead carbon-13-carbon-13 coupling constant in a bicyclobutane
Martin Pomerantz, Rina Fink, and George A. Gray
pp 291 - 292; DOI:
10.1021/ja00417a076
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Lack of selectivity in the electrophilic addition of p-toluenesulfonylnitrene to tertiary amines. Conformational equilibrium in N-methylpiperidines
D. C. Appleton, J. McKenna, J. M. McKenna, L. B. Sims, and A. R. Walley
pp 292 - 293; DOI:
10.1021/ja00417a077
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Tunneling rotation of the methyl radical in the sodium acetate trihydrate-d6
Shozo Kubota, Masamoto Iwaizumi, and Taro Isobe
pp 293 - 294; DOI:
10.1021/ja00417a078
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Crossed beams chemistry: barium(1S) + sulfur dioxide(1A) .far. barium oxide(1.SIGMA.+) + sulfur monoxide(3.SIGMA.-)
R. Behrens, A. Freedman, R. R. Herm, and T. P. Parr
pp 294 - 296; DOI:
10.1021/ja00417a079
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Aromatic substitution. XXXIX. Varying selectivity in electrophilic formylation of toluene and benzene
George A. Olah, Franco Pelizza, Shiro Kobayashi, and Judith A. Olah
pp 296 - 297; DOI:
10.1021/ja00417a080
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Cyclopropanation transition states. The electronic effect
David S. Crumrine and Hui-Hsien B. Yen
pp 297 - 298; DOI:
10.1021/ja00417a081
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Berninamycin. I. The structure of berninamycinic acid
Jerrold M. Liesch, Joyce A. McMillan, Ramesh C. Pandey, Iain C. Paul, Kenneth L Rinehart, and Fritz Reusser
pp 299 - 300; DOI:
10.1021/ja00417a082
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Selenium dioxide oxidation of ketones and aldehydes. Evidence for the intermediacy of .beta.-ketoseleninic
K. Barry Sharpless and Kenneth M. Gordon
pp 300 - 301; DOI:
10.1021/ja00417a083
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Chemistry of the sulfur-nitrogen bond. X. Barriers to planar inversion in N-(4,4'-dimethylbenzophenylidene)arenesulfenamides and -selenenamides
Franklin A. Davis and Edward W. Kluger
pp 302 - 303; DOI:
10.1021/ja00417a084
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The ground and excited states of trimethylenemethane
James H. Davis and William A. Goddard
pp 303 - 304; DOI:
10.1021/ja00417a085
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Spectroscopic studies of bicyclo[2.2.2]octa-2,5,7-triene. I. Spectroscopic studies of bicyclo[2.2.2]octa-2,5,7-triene. Magnetic circular dichroism spectrum in the region 200-350 nm
F. A. Van-Catledge and C. E. McBride
pp 304 - 307; DOI:
10.1021/ja00417a086
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Book Reviews

pp 307 - 310; DOI:
10.1021/ja00417a600
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Issue 2


Quantitative proton affinities, ionization potentials, and hydrogen affinities of alkylamines
Donald H. Aue, Hugh M. Webb, and Michael T. Bowers
pp 311 - 317; DOI:
10.1021/ja00418a001
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A thermodynamic analysis of solvation effects on the basicities of alkylamines. An electrostatic analysis of substituent effects
Donald H. Aue, Hugh M. Webb, and Michael T. Bowers
pp 318 - 329; DOI:
10.1021/ja00418a002
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A model for the triplet state photochemical isomerization of azomethine dyes
William G. Herkstroeter
pp 330 - 336; DOI:
10.1021/ja00418a003
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The photodissociation and high resolution laser photodissociation of halogen-substituted toluene cations
Emil W. Fu, Paul P. Dymerski, and Robert C. Dunbar
pp 337 - 342; DOI:
10.1021/ja00418a004
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Magnetic circular dichroism studies of myoglobin complexes. Correlations with heme spin state and axial ligation
Larry Vickery, Tsunenori Nozawa, and Kenneth Sauer
pp 343 - 350; DOI:
10.1021/ja00418a005
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Magnetic circular dichroism studies of low-spin cytochromes. Temperature dependence and effects of axial coordination on the spectra of cytochrome c and cytochrome b5
Larry Vickery, Tsunenori Nozawa, and Kenneth Sauer
pp 351 - 357; DOI:
10.1021/ja00418a006
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The effect of temperature and solvent environment on the conformational stability of 11-cis-retinal
Robert R. Birge, Michael J. Sullivan, and Bryan E. Kohler
pp 358 - 367; DOI:
10.1021/ja00418a007
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Proton magnetic resonance studies of the effects of sugar hydroxyl dissociation on nucleoside conformation. Arabinosyl nucleosides with an intramolecular hydrogen bond between the pentose O(5') and O(2')
M. Remin, E. Darzynkiewicz, A. Dworak, and D. Shugar
pp 367 - 376; DOI:
10.1021/ja00418a008
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The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities
Mortimer J. Kamlet and R. W. Taft
pp 377 - 383; DOI:
10.1021/ja00418a009
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Observed and calculated Faraday B terms in monosubstituted benzenes
Akira Kaito, Akio Tajiri, and Masahiro Hatano
pp 384 - 388; DOI:
10.1021/ja00418a010
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Ab initio SCF computations on benzene and the benzenium ion using a large contracted gaussian basis set
Walter C. Ermler, Robert S. Mulliken, and Enrico Clementi
pp 388 - 394; DOI:
10.1021/ja00418a011
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An ab initio calculation of the bonding, excited states, and g value of tetrachlorocobaltate(II), (CoCl4)2-
Ian H. Hillier, John Kendrick, Frank E. Mabbs, and C. David Garner
pp 395 - 397; DOI:
10.1021/ja00418a012
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Fluorescence of carbonyl compounds. III. Reactivity of n,.pi.* excited states of alkanals
J. Christopher Dalton, Margaret W. Geiger, and John J. Snyder
pp 398 - 401; DOI:
10.1021/ja00418a013
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Electronic structure of dicarbonyls. Glyoxal excited states
Clifford E. Dykstra and Henry F. Schaefer
pp 401 - 406; DOI:
10.1021/ja00418a014
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Theory and application of photoelectron spectroscopy. 60. Phospholes. Electronic structure
Werner Schaefer, Armin Schweig, and Francois Mathey
pp 407 - 414; DOI:
10.1021/ja00418a015
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Mechanisms of ligand association in complexes of the type RML3+X- (M = nickel, palladium, platinum). I. Mechanistic aspects of nuclear magnetic resonance line shape analysis for intermolecular exchange in non-first-order multispin systems
P. Meakin, A. D. English, and J. P. Jesson
pp 414 - 421; DOI:
10.1021/ja00418a016
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Mechanisms of ligand association in complexes of the type RML3+X- (M = nickel, palladium, platinum). II. The mechanisms of the reactions HML3+ + L .dha. HML4+ (L = triethylphosphine)
A. D. English, P. Meakin, and J. P. Jesson
pp 422 - 436; DOI:
10.1021/ja00418a017
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Site of nucleophilic attack on acylpentacarbonylmanganese(I) compounds
Charles P. Casey and Charles A. Bunnell
pp 436 - 441; DOI:
10.1021/ja00418a018
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MO calculations on metal carbene complexes and metal acyl complexes. The importance of the LUMO in determining the site of nucleophilic attack
Toby F. Block, Richard F. Fenske, and Charles P. Casey
pp 441 - 443; DOI:
10.1021/ja00418a019
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Nitrosoarene complexes of ruthenium. Nitrosation of activated aromatic compounds by the coordinated nitrosyl group
William L. Bowden, William F. Little, and Thomas J. Meyer
pp 444 - 448; DOI:
10.1021/ja00418a020
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Derivatives of the hypho class of boron hydrides. I. The molecular structure and nuclear magnetic resonance spectra of stereochemically nonrigid bis(trimethylphosphine)hexaborane(10)
Margaret Mangion, R. K. Hertz, M. L. Denniston, J. R. Long, W. R. Clayton, and S. G. Shore
pp 449 - 453; DOI:
10.1021/ja00418a021
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On the stereochemistry of polar 2 + 2 cycloadditions
N. D. Epiotis, R. L. Yates, D. Carlberg, and F. Bernardi
pp 453 - 461; DOI:
10.1021/ja00418a022
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Overlap repulsion as an important contributor to aromaticity
Nicolaos D. Epiotis and Ronald L. Yates
pp 461 - 469; DOI:
10.1021/ja00418a023
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A molecular orbital interpretation of the static, dynamic, and chemical properties of CH2X radicals
Fernando Bernardi, Nicolaos D. Epiotis, William Cherry, H. Bernhard Schlegel, Myung-Hwan Whangbo, and Saul Wolfe
pp 469 - 478; DOI:
10.1021/ja00418a024
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The temperature dependence of carbon-13 nuclear magnetic resonance shifts. Limiting factors and stereochemical applications
Hans Joerg Schneider and Wolfgang Freitag
pp 478 - 481; DOI:
10.1021/ja00418a025
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Resonance Raman study of the thermochromic phase transition of a polydiacetylene
Gregory J. Exarhos, William M. Risen, and Ray H. Baughman
pp 481 - 487; DOI:
10.1021/ja00418a026
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The ionization of feeble organic acids in DMSO-water mixtures. Acidity constants derived by extrapolation to the aqueous state
Robin A. Cox and Ross Stewart
pp 488 - 494; DOI:
10.1021/ja00418a027
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Carbon-13 nuclear magnetic resonance spectroscopy, a probe to dynamic solvation. Anisotropic and internal motion in aminobiphenyls and their salts
George C. Levy, Tadeusz Holak, and Alois Steigel
pp 495 - 499; DOI:
10.1021/ja00418a028
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A reinterpretation of paramagnetic line broadening in the nuclear magnetic resonance spectra of amino acids and peptides. I. The copper(II)-glycine system
James K. Beattie, Donald J. Fensom, and Hans C. Freeman
pp 500 - 507; DOI:
10.1021/ja00418a029
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Determination of positional weighting factors for the Swain and Lupton substituent constants f and r
S. G. Williams and F. E. Norrington
pp 508 - 516; DOI:
10.1021/ja00418a030
PDF
Nitrogen-centered free radicals. IX. The ease of formation of thionitroxide radicals
Wayne C. Danen and David D. Newkirk
pp 516 - 520; DOI:
10.1021/ja00418a031
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. XXII. Dialkylaminothiyl radicals
B. Maillard and K. U. Ingold
pp 520 - 523; DOI:
10.1021/ja00418a032
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. XXIII. Cyanomethyl radicals
R. A. Kaba and K. U. Ingold
pp 523 - 526; DOI:
10.1021/ja00418a033
PDF
Analysis of the reactivity of alkenylidenecyclopropanes in cycloaddition reactions
Daniel J. Pasto, John K. Borchardt, Thomas P. Fehlner, Harry F. Baney, and Maurice E. Schwartz
pp 526 - 529; DOI:
10.1021/ja00418a034
PDF
On the orbital interactions of three-membered rings with .pi. systems. Electronic structure of alkenylidenecyclopropanes
Daniel J. Pasto, Thomas P. Fehlner, Maurice E. Schwartz, and Harry F. Baney
pp 530 - 534; DOI:
10.1021/ja00418a035
PDF
The stereochemical consequences of electron delocalization in extended .pi. systems. An interpretation of the cis effect exhibited by 1,2-disubstituted ethylenes and related phenomena
Richard C. Bingham
pp 535 - 540; DOI:
10.1021/ja00418a036
PDF
Elimination reactions induced by photoenolization of o-alkylbenzophenones
Shin-Shyong Tseng and Edwin F. Ullman
pp 541 - 544; DOI:
10.1021/ja00418a037
PDF
Kinetic and equilibrium chlorine isotope effects in the cyclization of 2-chloroethanol in protic solvents
Thomas H. Cromartie and C. Gardner Swain
pp 545 - 550; DOI:
10.1021/ja00418a038
PDF
Pentacarbonyliron(0) photocatalyzed hydrogenation and isomerization of olefins
Mark A. Schroeder and Mark S. Wrighton
pp 551 - 558; DOI:
10.1021/ja00418a039
PDF
Alkylation of tetracyanoethylene. Reaction with Grignard reagents
Hugh C. Gardner and Jay K. Kochi
pp 558 - 566; DOI:
10.1021/ja00418a040
PDF
Asymmetric synthesis of R and S .alpha.-alkylalkanoic acids from metalation and alkylation of chiral 2-oxazolines
A. I. Meyers, Gerald Knaus, Kazuyuki Kamata, and Michael E. Ford
pp 567 - 576; DOI:
10.1021/ja00418a041
PDF
Stable carbocations. 184. 2,4-Dehydro-5-homoadamantyl cations
George A. Olah, Gao Liang, Kevin A. Babiak, Thomas K. Morgan, and Roger K. Murray
pp 576 - 580; DOI:
10.1021/ja00418a042
PDF
Crystal and molecular structure of pentaphenoxyphosphorane, (C6H5O)5P. The configuration of acyclic, monocyclic, and spirobicyclic pentaoxyphosphoranes
Raghupathy Sarma, Fausto Ramirez, Brian McKeever, James F. Marecek, and Shuyan Lee
pp 581 - 587; DOI:
10.1021/ja00418a043
PDF
Thyroid hormone stereochemistry. IV. Molecular conformation of 3'-isopropyl-3,5-diiodo-L-thyronine in the crystal and in solution
J. Keith Fawcett, Norman Camerman, and Arthur Camerman
pp 587 - 591; DOI:
10.1021/ja00418a044
PDF
On the question of paramagnetic "ring currents" in pyracylene and related molecules
C. A. Coulson and R. B. Mallion
pp 592 - 598; DOI:
10.1021/ja00418a045
PDF
The electronic origin of geometrical deformations in cyclohexadienyl and cyclobutenyl transition metal complexes
Roald Hoffmann and Peter Hofmann
pp 598 - 604; DOI:
10.1021/ja00418a046
PDF
Selectivity in the olefin metathesis of unsymmetrically substituted ethylenes
James McGinnis, Thomas J. Katz, and Samuel Hurwitz
pp 605 - 606; DOI:
10.1021/ja00418a047
PDF
Metathesis of a cyclic trisubstituted alkene. Preparation of polyisoprene from 1-methylcyclobutene
Thomas J. Katz, James McGinnis, and Craig Altus
pp 606 - 608; DOI:
10.1021/ja00418a048
PDF
Reactions of (CO)5WC(Tol)2 with alkenes. A Model for structural selectivity in the olefin metathesis reaction
Charles P. Casey, Hendrik E. Tuinstra, and Marian C. Saeman
pp 608 - 609; DOI:
10.1021/ja00418a049
PDF
Negatively substituted trimethylenecyclopropane dianions
Tadamichi Fukunaga
pp 610 - 611; DOI:
10.1021/ja00418a050
PDF
Negatively substituted trimethylenecyclopropanes and their radical anions
Tadamichi Fukunaga, Michael D. Gordon, and Paul J. Krusic
pp 611 - 613; DOI:
10.1021/ja00418a051
PDF
Synthetic models of deoxyribonucleic acid complexes with antimalarial compounds. I. Interaction of aminoquinoline with adenine and thymine
J. Bolte, C. Demuynck, and J. Lhomme
pp 613 - 615; DOI:
10.1021/ja00418a052
PDF
Fast thermal Z,E isomerization in symmetrical overcrowded ethylenes. Low barriers due to ground-state destabilization
Israel Agranat and Yitzhak Tapuhi
pp 615 - 616; DOI:
10.1021/ja00418a053
PDF
Electron spin resonance studies of the photolysis of trialkylsilyl peroxides
Peter G. Cookson, Alwyn G. Davies, Nasir A. Fazal, and Brian P. Roberts
pp 616 - 618; DOI:
10.1021/ja00418a054
PDF
Photolysis of silyl azides. Generation and reactions of silicon-nitrogen (p.pi.-p.pi.) doubly bonded intermediates. [R2Si:NR]
D. R. Parker and L. H. Sommer
pp 618 - 620; DOI:
10.1021/ja00418a055
PDF
Laser fluorimetry. Sub-part-per-trillion detection of solutes
A. Beatrice Bradley and Richard N. Zare
pp 620 - 621; DOI:
10.1021/ja00418a056
PDF
Thermodynamics of exciplex formation by time-resolved nanosecond flash spectroscopy
David Creed, Paul H. Wine, Richard A. Caldwell, and Lynn A. Melton
pp 621 - 623; DOI:
10.1021/ja00418a057
PDF
Characterization and molecular structure of 1-hydro-2,8,9-trioxa-1-phospha-5-aza-tricyclo[3.3.3.0]undecane tetrafluoroborate. Pentacoordination of phosphorus
J. C. Clardy, D. S. Milbrath, J. P. Springer, and J. G. Verkade
pp 623 - 624; DOI:
10.1021/ja00418a058
PDF
Directive effects in the electrophilic substitution of deltahedral boranes and heteroboranes. Halogenation of 1-thiadecaborane(9). Unusually long boron-11 spin-lattice relaxation times
Wayne L. Smith, B. J. Meneghelli, Natalie McClure, and R. W. Rudolph
pp 624 - 626; DOI:
10.1021/ja00418a059
PDF
Trivalent copper as a probable intermediate in the reaction catalyzed by galactose oxidase
Gary R. Dyrkacz, R. Daniel Libby, and Gordon A. Hamilton
pp 626 - 628; DOI:
10.1021/ja00418a060
PDF
Benzo[1,2:3,4]dicyclobutene
Randolph P. Thummel
pp 628 - 629; DOI:
10.1021/ja00418a061
PDF
Cobalt-59 nuclear quadrupole resonance spectra and low temperature carbon-13 magnetic resonance spectra of X3SnCo(CO)4 compounds
Dennis L. Lichtenberger, Dennis R. Kidd, Paul A. Loeffler, and Theodore L. Brown
pp 629 - 630; DOI:
10.1021/ja00418a062
PDF
New synthetic reactions. Catalytic vs. stoichiometric allylic alkylation. Stereocontrolled approach to steroid side chain
Barry M. Trost and Thomas R. Verhoeven
pp 630 - 632; DOI:
10.1021/ja00418a063
PDF
The nitrogen-15 nuclear magnetic resonance of friend leukemic cell [Gly-15N] hemoglobin. The resolution of noncovalent bonding interactions
A. Lapidot, C. S. Irving, and Z. Malik
pp 632 - 634; DOI:
10.1021/ja00418a064
PDF
Synthesis of (+-)-crotepoxide, (+-)-epicrotepoxide, and (+-)-isocrotepoxide
Martin R. Demuth, Patricia E. Garrett, and James D. White
pp 634 - 635; DOI:
10.1021/ja00418a065
PDF
Photosensitized oxygenation of Nb-methoxycarbonyltryptophan methyl ester and Nb-methoxycarbonyltryptamine. Isolation and novel transformations of a 3a-hydroxyperoxypyrroloindole
Masako Nakagawa, Haruo Okajima, and Tohru Hino
pp 635 - 637; DOI:
10.1021/ja00418a066
PDF
The reduction of molybdenum(II) trifluoroacetate by pulse radiolysis in methanol
J. H. Baxendale, C. David Garner, Roger G. Senior, and Peter Sharpe
pp 637 - 638; DOI:
10.1021/ja00418a067
PDF
Complexation of carbonyl oxide zwitterions
Philip S. Bailey, A. Rustaiyan, and T. M. Ferrell
pp 638 - 639; DOI:
10.1021/ja00418a068
PDF
Cyclopentadienylnitrosylthiocarbonylmanganese dimer. A novel complex believed to contain carbon-bridging thiocarbonyl groups
Avi Efraty, Ruza Arneri, and M. H. A. Huang
pp 639 - 640; DOI:
10.1021/ja00418a069
PDF
Additions and Corrections - Estimation of Solvolysis Rates of Cyclic Secondary Substrates
Milton Harris, and Samuel P. McManus
pp 641 - 641; DOI:
10.1021/ja00418a600
PDF
Additions and Corrections - Effect of Crown Ether on the Conformational Equilibrium of Sodium Acetylacetonate
Eric A. Noe, and Morton Raban
pp 641 - 641; DOI:
10.1021/ja00418a601
PDF
Additions and Corrections - Matrix Photolysis of 1,2,3-Thiadiazole. On the Possible Involvement of Thiirene
A. Krantz, and J. Laureni
pp 641 - 641; DOI:
10.1021/ja00418a602
PDF
Additions and Corrections - Remote Anodic Substitution of Ketones
James Y. Becker, Larry R. Byrd, Larry L. Miller, and Ying-Hung So
pp 641 - 641; DOI:
10.1021/ja00418a603
PDF
Additions and Corrections - Enantioselective Oxirane Synthesis by Means of Dimethylsulfonium Metylide and Chiral Phase-Transfer Catalysts
Tamejiro Hiyama, Takashi Mishima, Hiroyuki Sawada, and Hitosi Nozaki
pp 641 - 641; DOI:
10.1021/ja00418a604
PDF
Additions and Cotrrections - Phase Transfer Catalysis. An Evaluation of Catalysts.
Arthur W. Herriott, and Donald Picker
pp 641 - 641; DOI:
10.1021/ja00418a605
PDF
Additions and Corrections - Irreversible Inhibition of Δ5-3-Ketosteroid Isomerase by 5,10-Secosteroids
F. H. Batzold, and C. H. Robinson
pp 641 - 641; DOI:
10.1021/ja00418a606
PDF
Additions and Corrections - A General Synthetic Method for Non-K-Region Arene Oxides
Haruhiko Yagi, and Donald M. Jerina
pp 641 - 641; DOI:
10.1021/ja00418a607
PDF
Addtions and Corrections - A Critical Examination of the Applicability of J13CH as a Criterion for the Presence of σ Bridging in Cyclopropylcarbinyl Cations
David P. Kelly, and Herbert C. Brown
pp 642 - 642; DOI:
10.1021/ja00418a608
PDF
Additions and Corrections - Stable Carbocations. CLXXXII. The Acetoacetylium and Diacetoacetylium Ions.
G. A. Olah, Alain Germain, Henry C. Lin, and Kenneth Dunne
pp 642 - 642; DOI:
10.1021/ja00418a609
PDF
Book Reviews

pp 642 - 642; DOI:
10.1021/ja00418a610
PDF

Issue 3


Diffusion in liquids. II. The dependence of the diffusion coefficients on molecular weight and on temperature
Eli Grushka and Edward J. Kikta
pp 643 - 648; DOI:
10.1021/ja00419a001
PDF
All-electron nonempirical calculations of potential surfaces. III. Dissociation of ketene into methylene and carbon monoxide
Phil Pendergast and William H. Fink
pp 648 - 655; DOI:
10.1021/ja00419a002
PDF
Hydrogen exchange studies. X. Base-catalyzed isotopic exchange of molecular hydrogen. III. Transition-state vs. initial-state solvation in the dimethyl sulfoxide-water system
E. Buncel and E. A. Symons
pp 656 - 660; DOI:
10.1021/ja00419a003
PDF
Normal coordinates, structure, and bonding of benzyne
Jean W. Laing and R. Stephen Berry
pp 660 - 664; DOI:
10.1021/ja00419a004
PDF
Torsional potentials of methyl rotors attached to polar linkages
Warren J. Hehre, John A. Pople, and Alain J. P. Devaquet
pp 664 - 668; DOI:
10.1021/ja00419a005
PDF
Photoelectron spectra and molecular properties. LI. Ionization potentials of silanes SinH2n+2
H. Bock, W. Ensslin, F. Feher, and R. Freund
pp 668 - 674; DOI:
10.1021/ja00419a006
PDF
The luminescence of heterobischelated complexes of iridium(III). II. Analysis of the thermally nonequilibrated levels in the luminescence of cis-dichloro(1,10-phenanthroline)(4,7-dimethyl-1,10-phenanthroline)iridium(III) chloride
Richard J. Watts, B. G. Griffith, and J. S. Harrington
pp 674 - 679; DOI:
10.1021/ja00419a007
PDF
Molecular and magnetic structure of the paramagnetic ion pair bis(tetraglyme)rubidium biphenyl, Rb+[CH3O(CH2CH2O)4CH3]2C12H10-
J. J. Mooij, A. A. K. Klaassen, E. De Boer, H. M. L. Degens, Th. E. M. Van den Hark, and J. H. Noordik
pp 680 - 685; DOI:
10.1021/ja00419a008
PDF
Magnetic investigation of the electronic structure of hexakis(pyridine N-oxide)cobalt(II) perchlorate
R. L. Carlin, C. J. O'Connor, and S. N. Bhatia
pp 685 - 688; DOI:
10.1021/ja00419a009
PDF
Ammineruthenium complexes of hydrogen sulfide and related sulfur ligands
C. C. Kuehn and H. Taube
pp 689 - 702; DOI:
10.1021/ja00419a010
PDF
Tris(.eta.5-cyclopentadienyl)alkyl and -alkenyl compounds of thorium(IV)
Tobin J. Marks and William A. Wachter
pp 703 - 710; DOI:
10.1021/ja00419a011
PDF
Structural studies of copper(I) binding by hydrotris(1-pyrazolyl)borate and hydrotris(3,5-dimethyl-1-pyrazolyl)borate in the solid state and in solution
Carlo Mealli, Cathy S. Arcus, Joseph L. Wilkinson, Tobin J. Marks, and James A. Ibers
pp 711 - 718; DOI:
10.1021/ja00419a012
PDF
Synthesis and molecular structure of 1-(.pi.-cyclopentadienyl)-1-triphenylphosphine-2,3,4,5-tetrakis(pentafluorophenyl)cobaltole
R. G. Gastinger, M. D. Rausch, D. A. Sullivan, and Gus J. Palenik
pp 719 - 723; DOI:
10.1021/ja00419a013
PDF
Kinetic study of the copper(II)-catalyzed enolization, ketonization, and decarboxylation of oxaloacetate
N. V. Raghavan and D. L. Leussing
pp 723 - 730; DOI:
10.1021/ja00419a014
PDF
Ternary complexes in solution. XXIV. Metal ion bridging of stacked purine-indole adducts. The mixed-ligand complexes of adenosine 5'-triphosphate, tryptophan, and manganese(II), copper(II), or zinc(II)
Helmut Sigel and Christoph F. Naumann
pp 730 - 739; DOI:
10.1021/ja00419a015
PDF
Interaction of metal ions with 8-azapurines. II. Synthesis and structure of bis(8-azahypoxanthinato)tetraaquocadmium(II)
Linda G. Purnell, Eva D. Estes, and Derek J. Hodgson
pp 740 - 743; DOI:
10.1021/ja00419a016
PDF
Resonance Raman spectra of "blue" copper proteins and the nature of their copper sites
Olavi Siiman, N. Martin Young, and Paul R. Carey
pp 744 - 748; DOI:
10.1021/ja00419a017
PDF
Kinetics and mechanism of the copper(I)-induced homogeneous Ullmann coupling of o-bromonitrobenzene
Theodore Cohen and Ioan Cristea
pp 748 - 753; DOI:
10.1021/ja00419a018
PDF
Organometallic compounds of Group III. XXXIII. Polar and stereochemical factors in the carbalumination of olefins. Addition of triphenylaluminum to 6-substituted benzonorbornadienes
John J. Eisch and Nicholas E. Burlinson
pp 753 - 761; DOI:
10.1021/ja00419a019
PDF
Structures of the macrocyclic polythiaether 1,4,8,11-tetrathiacyclotetradecane and implications for transition-metal chemistry
Richard E. DeSimone and Milton D. Glick
pp 762 - 767; DOI:
10.1021/ja00419a020
PDF
Difluorophenylphosphoranes containing four-membered rings
Norman J. De'Ath, Donald B. Denney, Dorothy Z. Denney, and Y. F. Hsu
pp 768 - 770; DOI:
10.1021/ja00419a021
PDF
Nucleophilic cleavage of the sulfur-sulfur bond by phosphorus nucleophiles. IV. Kinetic study of the reduction of alkyl disulfides with triphenylphosphine and water
Larry E. Overman and Edward M. O'Connor
pp 771 - 775; DOI:
10.1021/ja00419a022
PDF
Reactivity-selectivity relationships. II. A simple model to explain nucleophile-electrophile combination reactions and its implications for the reactivity-selectivity principle
Addy Pross
pp 776 - 778; DOI:
10.1021/ja00419a023
PDF
Activation volume as a measure of E2-E1cB character in elimination reactions
K. R. Brower, Muhamed Muhsin, and H. Elise Brower
pp 779 - 782; DOI:
10.1021/ja00419a024
PDF
General acid-specific base catalyzed isomerization of tert-butyl thiolbut-3-enoate to tert-butyl thiolcrotonate
Leo Fedor and Patrick H. Gray
pp 783 - 787; DOI:
10.1021/ja00419a025
PDF
Dehydration of a carbinolhydrazine in the solid state. Correlation with crystal structure of the dehydration of 2-hydroxy-2-(.beta.-benzoyl-.beta.-phenylhydrazyl)indan-1,3-dione
Sherrill A. Puckett, Iain C. Paul, and David Y. Curtin
pp 787 - 792; DOI:
10.1021/ja00419a026
PDF
Proton exchange in benzyl alcohols. Acid, base, intramolecular, and bifunctional catalyses
F. M. Menger, H. K. Rhee, and J. U. Rhee
pp 792 - 797; DOI:
10.1021/ja00419a027
PDF
The case for .pi.-assisted ionization in the solvolysis of 9-bicyclo[4.2.1]nona-2,4,7-trienyl esters
A. Diaz and John Fulcher
pp 798 - 802; DOI:
10.1021/ja00419a028
PDF
On the mechanism of the sensitized photooxygenation of pyrroles
David A. Lightner, Gregory S. Bisacchi, and Robert D. Norris
pp 802 - 807; DOI:
10.1021/ja00419a029
PDF
Theoretical calculations on thiamine and related compounds. II. Conformational analysis and electronic properties of 2-(.alpha.-hydroxyethyl)thiamine
Frank Jordan
pp 808 - 813; DOI:
10.1021/ja00419a030
PDF
Kinetic studies of the helix-coil transition in aqueous solutions of poly(.alpha.-L-glutamic acid) using the electric field pulse method
Yoshikuni Tsuji, Tatsuya Yasunaga, Takayuki Sano, and Hidetoshi Ushio
pp 813 - 818; DOI:
10.1021/ja00419a031
PDF
Electronic relaxation processes in retinol and retinal: anomalous external heavy-atom effects and temperature dependence of fluorescence
Pill-Soon Song, Quae Chae, Masahisa Fujita, and Hiroaki Baba
pp 819 - 824; DOI:
10.1021/ja00419a032
PDF
Conformational barriers in nucleoside analogs: the crystal structure of 3-deazaadenosine
Phirtu Singh, Jesse May, Leroy B. Townsend, and Derek J. Hodgson
pp 825 - 830; DOI:
10.1021/ja00419a033
PDF
Syntheses of isoalloxazines and isoalloxazine 5-oxides. A new synthesis of riboflavin
Fumio Yoneda, Yoshiharu Sakuma, Misuzu Ichiba, and Kazuko Shinomura
pp 830 - 835; DOI:
10.1021/ja00419a034
PDF
On the superexchange mechanism in polymeric, pyrazine-bridged copper(II) complexes
H. Wayne Richardson and William E. Hatfield
pp 835 - 839; DOI:
10.1021/ja00419a035
PDF
Photochemistry of alkenes. V. [1,3]-Sigmatropic hydrogen shifts
Paul J. Kropp, Harold G. Fravel, and T. Randall Fields
pp 840 - 841; DOI:
10.1021/ja00419a036
PDF
Synthesis and crystal structure of a novel electron-rich nido trimetallocarborane
Chris G. Salentine, Charles E. Strouse, and M. Frederick Hawthorne
pp 841 - 842; DOI:
10.1021/ja00419a037
PDF
Light-sensitive amides. The photosolvolysis of substituted 1-acyl-7-nitroindolines
B. Amit, D. A. Ben-Efraim, and A. Patchornik
pp 843 - 844; DOI:
10.1021/ja00419a038
PDF
The lack of concertedness in the general acid-base catalysis of the enolization of oxalacetic acid. A case for stepwise nucleophilic-general base catalysis
Paula Y. Bruice and Thomas C. Bruice
pp 844 - 845; DOI:
10.1021/ja00419a039
PDF
A thallium-205 nuclear magnetic resonance method of determining solvation effects on alkali ion selectivity
James J. Dechter and Jeffrey I. Zink
pp 845 - 846; DOI:
10.1021/ja00419a040
PDF
On the mechanism of a rhodium-complex-catalyzed carbonylation of methanol to acetic acid
Denis Forster
pp 846 - 848; DOI:
10.1021/ja00419a041
PDF
Metal assisted carbon-carbon bond formation. Synthesis of hydroazulene complexes
N. Genco, D. Marten, S. Raghu, and M. Rosenblum
pp 848 - 849; DOI:
10.1021/ja00419a042
PDF
The Hofmann-Loeffler-Freytag bridge between mass spectrometry and free radical chemistry
Mark M. Green, J. M. Moldowan, Mark W. Armstrong, Tim L. Thompson, Kevin J. Sprague, Alan J. Hass, and Juan J. Artus
pp 849 - 851; DOI:
10.1021/ja00419a043
PDF
Observation of the effect of water on the phosphorus-31 nuclear magnetic resonance spectra of dipalmitoyllecithin
R. G. Griffin
pp 851 - 853; DOI:
10.1021/ja00419a044
PDF
Iodine-fluorine bond strength in IIF, ClIF, and HIF
James J. Valentini, M. J. Coggiola, and Y. T. Lee
pp 853 - 854; DOI:
10.1021/ja00419a045
PDF
A quantitative comparison of gas- and solution-phase basicities of substituted pyridines
Donald H. Aue, Hugh M. Webb, Michael T. Bowers, Charles L. Liotta, C. J. Alexander, and Harry P. Hopkins
pp 854 - 856; DOI:
10.1021/ja00419a046
PDF
Isomerization on metals. Correlation between metal particle size and reaction mechanisms
Jean M. Dartigues, Alain Chambellan, and F. G. Gault
pp 856 - 857; DOI:
10.1021/ja00419a047
PDF
Conformational and stereochemical control of an unprecedented neighboring group participation. A new, stereospecific chloroepoxide synthesis
Bruce Ganem
pp 858 - 859; DOI:
10.1021/ja00419a048
PDF
Aliphatic hydroxylation via oxygen rebound. Oxygen transfer catalyzed by iron
John T. Groves and Gary A. McClusky
pp 859 - 861; DOI:
10.1021/ja00419a049
PDF
Chemistry of bent bonds. XLVI. Metathesis. Diene and cyclobutane interconversions
Paul G. Gassman and Thomas H. Johnson
pp 861 - 862; DOI:
10.1021/ja00419a050
PDF
Influence of neighboring phenyl participation on the .alpha.-deuterium isotope effect on solvolysis rates. Neophyl esters
V. J. Shiner and R. C. Seib
pp 862 - 864; DOI:
10.1021/ja00419a051
PDF
Preferred base sites of actinomycin-deoxyribonucleic acid bindings by circular dichroism
F. S. Allen, R. P. Moen, and U. Hollstein
pp 864 - 865; DOI:
10.1021/ja00419a052
PDF
The formation of a semiquinone form of deazaFAD bound to D-amino acid oxidase
Louis B. Hersh, Marilyn S. Jorns, Julian Peterson, and Mark Currie
pp 865 - 867; DOI:
10.1021/ja00419a053
PDF
Benzo[c]selenophene. A base-catalyzed selenoxide dehydration
Lydia E. Saris and Michael P. Cava
pp 867 - 868; DOI:
10.1021/ja00419a054
PDF
Evidence for the dimerization of dimethylsilylene to tetramethyldisilene
Robert T. Conlin and Peter P. Gaspar
pp 868 - 870; DOI:
10.1021/ja00419a055
PDF
Chemistry and biochemistry of the streptovaricins. XV. Protostreptovaricins I-V
Prabhakar V. Deshmukh, Katsumi Kakinuma, John J. Ameel, Kenneth L. Rinehart, Paul F. Wiley, and Li H. Li
pp 870 - 872; DOI:
10.1021/ja00419a056
PDF
Stable chromium(V) compounds
Miroslav Krumpolc and Jan Rocek
pp 872 - 873; DOI:
10.1021/ja00419a057
PDF
Chemistry of superoxide ion. II. Reaction with hydroperoxides
John W. Peters and Christopher S. Foote
pp 873 - 875; DOI:
10.1021/ja00419a058
PDF
Classical and nonclassical structures of the vinyl cation. An accurate computational determination of their relative stabilities and optimum rearrangement path
J. Weber and A. D. McLean
pp 875 - 876; DOI:
10.1021/ja00419a059
PDF

Issue 4


Substituent effects and the cis-trans isomerization of diazenes
James M. Howell and Lawrence J. Kirschenbaum
pp 877 - 885; DOI:
10.1021/ja00420a001
PDF
Resonance theory. IX. Charge distributions and isomer stability of the fluoro derivatives of methylenimide
James M. Howell
pp 886 - 887; DOI:
10.1021/ja00420a002
PDF
Ionization potentials of .pi. molecular hydrocarbons
William C. Herndon
pp 887 - 889; DOI:
10.1021/ja00420a003
PDF
Relationship between Ion-Pair Dissociation Constants of Some Substituted Cyclooctatetraene Dianions and Electronic Structure
Gerald R. Stevenson and Ignacio Ocasio
pp 890 - 893; DOI:
10.1021/ja00420a004
PDF
Gas-phase SN2 reactions at silicon and carbon centers. An experimental appraisal of theory
J. D. Payzant, K. Tanaka, L. D. Betowski, and D. K. Bohme
pp 894 - 899; DOI:
10.1021/ja00420a005
PDF
Molecular structure of 1,2-bis(trifluoromethyl)dithiete by vapor phase electron diffraction
J. Lawrence Hencher, Quang Shen, and Dennis G. Tuck
pp 899 - 902; DOI:
10.1021/ja00420a006
PDF
Cyclooctatetraene complexes of niobium and tantalum and the structure of Nb(.eta.4-C8H8)[.eta.5-C8H8(C6H5)][(CH3)2AsC6H4As(CH3)2]
R. R. Schrock, L. J. Guggenberger, and A. D. English
pp 903 - 913; DOI:
10.1021/ja00420a007
PDF
Crystal and molecular structure of an N-Substituted porphyrin, chloro(2,3,7,8,12,13,17,18-octaethyl-N-ethylacetatoporphine)cobalt(II)
David E. Goldberg and K. Mark Thomas
pp 913 - 919; DOI:
10.1021/ja00420a008
PDF
Kinetics of reactions in solutions under pressure. XXXVII. Pressure effects in solvolysis and solvolytic fragmentation. A correlation of activation volume with concertedness
W. J. Le Noble, H. Guggisberg, T. Asano, L. Cho, and C. A. Grob
pp 920 - 924; DOI:
10.1021/ja00420a009
PDF
Multiple fluorescences. II. A new scheme for 4-(N,N-dimethylamino)benzonitrile including proton transfer
Edward M. Kosower and Hanna Dodiuk
pp 924 - 929; DOI:
10.1021/ja00420a010
PDF
.pi.,.pi.-Biradicaloid hydrocarbons. The pleiadene family. II. A doubly excited state of pleiadene
Jaroslav Kolc, John W. Downing, Anthony P. Manzara, and Josef Michl
pp 930 - 937; DOI:
10.1021/ja00420a011
PDF
Ionization potentials, electron affinities, and reactivities of cyanoalkenes and related electron-deficient alkenes. A frontier molecular orbital treatment of cyanoalkene reactivities in cycloaddition, electrophilic, nucleophilic, and radical reactions
K. N. Houk and Linda L. Munchausen
pp 937 - 946; DOI:
10.1021/ja00420a012
PDF
Cyclopropyl substituent effects on acid-catalyzed hydration of alkenes. Correlation by .sigma.+ parameters
Kiyotaka Oyama and Thomas T. Tidwell
pp 947 - 951; DOI:
10.1021/ja00420a013
PDF
The stereochemistry of free radical eliminations on .beta.-phenylthio radicals
Thomas E. Boothe, Joseph L. Greene, and Philip B. Shevlin
pp 951 - 956; DOI:
10.1021/ja00420a014
PDF
Conformational analysis. XXXI. Conformational equilibria of 1,3-dioxanes with polar substituents at C-5
Moses K. Kaloustian, Nicholas Dennis, Sorin Mager, Slayton A. Evans, Felipe Alcudia, and Ernest L. Eliel
pp 956 - 965; DOI:
10.1021/ja00420a015
PDF
The structure of dehydromethionine. An azasulfonium salt
Richard S. Glass and John R. Duchek
pp 965 - 969; DOI:
10.1021/ja00420a016
PDF
Polynucleotides.clouridine phosphate. Hybridization with the oligomer of S-cycloadenosine phosphate to form left-handed helical complexes
Seiichi Uesugi, Toru Tezuka, and Morio Ikehara
pp 969 - 973; DOI:
10.1021/ja00420a017
PDF
Secretin. VI. Simultaneous "in situ" syntheses of three analogues of the C-terminal tricosapeptide and a study of their conformation
Mary L. Fink and Miklos Bodanszky
pp 974 - 977; DOI:
10.1021/ja00420a018
PDF
Carbonic anhydrase catalyzed hydration studied by carbon-13 and oxygen-18 labeling of carbon dioxide
D. N. Silverman and C. K. Tu
pp 978 - 984; DOI:
10.1021/ja00420a019
PDF
Effects of freezing an internal rotation on intramolecular catalysis by an imidazolyl group. Synthesis and hydrolysis of 4,5-[1'(4')-acetoxymethyltetramethylene]imidazoles and 4,5-[1'(5')-acetoxymethylpentamethylene]imidazole
Masanori Utaka, Junichi Koyama, and Akira Takeda
pp 984 - 990; DOI:
10.1021/ja00420a020
PDF
Laser-excited Raman spectroscopy of biomolecules. VIII. Conformational study of bovine serum albumin
M. C. Chen and R. C. Lord
pp 990 - 992; DOI:
10.1021/ja00420a021
PDF
The secondary .beta.-deuterium isotope effect in the formation of ethyl radical from decomposition of methylethylethyl-2,2,2-d3-carbinyloxy radical
Alexandros Tsolis, Paul P. Hunt, Jay K. Kochi, and Stanley Seltzer
pp 992 - 997; DOI:
10.1021/ja00420a022
PDF
Kinetics and mechanisms of the reactions of organic cation radicals and dications. IV. First- and second-order reactions of thianthrene cation radical with phenol
Ulla Svanholm and Vernon D. Parker
pp 997 - 1001; DOI:
10.1021/ja00420a023
PDF
Internal heavy-atom effects on the photodimerization of acenaphthylene
Joseph C. Koziar and Dwaine O. Cowan
pp 1001 - 1007; DOI:
10.1021/ja00420a024
PDF
Effect of carbon-13-nitrogen dipolar interactions on spin-lattice relaxation times and intensities of nonprotonated carbon resonances
Raymond S. Norton and Adam Allerhand
pp 1007 - 1014; DOI:
10.1021/ja00420a025
PDF
Catalysis and chiral recognition through designed complexation of transition states in transacylations of amino ester salts
Y. Chao and Donald J. Cram
pp 1015 - 1017; DOI:
10.1021/ja00420a026
PDF
Reaction of singlet oxygen with .alpha.-ketocarboxylic acids. Oxidative decarboxylation and peroxyacid formation
Charles W. Jefford, Andre F. Boschung, Theodorus A. B. M. Bolsman, Robert M. Moriarty, and Bennett Melnick
pp 1017 - 1018; DOI:
10.1021/ja00420a027
PDF
Stable cis and trans rotational isomers of 1,8-di-o-tolylnaphthalene
Roger L. Clough and John D. Roberts
pp 1018 - 1020; DOI:
10.1021/ja00420a028
PDF
Origin of the bisfuran ring structure in aflatoxin biosynthesis
D. P. H. Hsieh, R. C. Yao, D. L. Fitzell, and C. A. Reece
pp 1020 - 1021; DOI:
10.1021/ja00420a029
PDF
Solvated nickel atoms and their free cluster formation in organic media
K. J. Klabunde, H. F. Efner, T. O. Murdock, and R. Ropple
pp 1021 - 1023; DOI:
10.1021/ja00420a030
PDF
Carbon-13 spin lattice relaxation in the neuraminic acids. Evidence for an unusual intramolecular hydrogen bonding network
Michael F. Czarniecki and Edward R. Thornton
pp 1023 - 1025; DOI:
10.1021/ja00420a031
PDF
Stability of some C7 tertiary alkyl carbonium ions
M. Meot-Ner, J. J. Solomon, and F. H. Field
pp 1025 - 1026; DOI:
10.1021/ja00420a032
PDF
Catalyzed oxidation reactions. I. Picolinic acid catalysis of the chromic acid oxidation of isopropyl alcohol
T. Y. Peng and J. Rocek
pp 1026 - 1027; DOI:
10.1021/ja00420a033
PDF
Sterol metabolism. XXXIX. Singlet molecular oxygen from hydrogen peroxide disproportionation
Leland L. Smith and Martin J. Kulig
pp 1027 - 1029; DOI:
10.1021/ja00420a034
PDF
Susceptibility studies of laccase and oxyhemocyanin using an ultrasensitive magnetometer. Antiferromagnetic behavior of the type 3 copper in Rhus laccase
Edward I. Solomon, David M. Dooley, Run-Han Wang, Harry B. Gray, M. Cerdonio, F. Mogno, and G. L. Romani
pp 1029 - 1031; DOI:
10.1021/ja00420a035
PDF
Carbon-13 nuclear magnetic resonance of polymers spinning at the magic angle
Jacob Schaefer and E. O. Stejskal
pp 1031 - 1032; DOI:
10.1021/ja00420a036
PDF
Temporal fluctuations in the emission from irradiated acetone solutions
Thomas L. Nemzek and J. E. Guillet
pp 1032 - 1034; DOI:
10.1021/ja00420a037
PDF
Gas phase dioxetane chemistry. Formaldehyde (A .far. X) chemiluminescence from the reaction of molecular oxygen (1.DELTA.g) with ethylene
Denis J. Bogan, Ronald S. Sheinson, and Frederick W. Williams
pp 1034 - 1036; DOI:
10.1021/ja00420a038
PDF
Ammonia-catalyzed photoaddition of tert-butyl alcohol to 9,10-anthraquinone. Electron transfer catalysis of a photochemical hydrogen abstraction reaction
Gene G. Wubbels, William J. Monaco, Douglas E. Johnson, and Robert S. Meredith
pp 1036 - 1037; DOI:
10.1021/ja00420a039
PDF
Biomimetic polyene cyclizations. Asymmetric induction by a chiral center remote from the initiating cationic center. 11.alpha.-Methylprogesterone
William S. Johnson and Grant E. DuBois
pp 1038 - 1039; DOI:
10.1021/ja00420a040
PDF
A stereospecific total synthesis of racemic 11.alpha.-hydroxyprogesterone via a biomimetic polyene cyclization
William S. Johnson, Sina Escher, and Brian W. Metcalf
pp 1039 - 1041; DOI:
10.1021/ja00420a041
PDF
Determination of signs of long-range carbon-carbon coupling constants. The SPT-difference spectroscopy method
Svend A. Linde and Hans J. Jakobsen
pp 1041 - 1043; DOI:
10.1021/ja00420a042
PDF
Stereochemistry and mechanism of reactions catalyzed by tryptophanase and tryptophan synthetase
E. Schleicher, K. Mascaro, R. Potts, D. R. Mann, and H. G. Floss
pp 1043 - 1044; DOI:
10.1021/ja00420a043
PDF
Bis(2,6-dimethylpyridine)chromium. A .pi.-heterocyclic complex
L. H. Simons, P. E. Riley, R. E. Davis, and J. J. Lagowski
pp 1044 - 1045; DOI:
10.1021/ja00420a044
PDF
On the energy threshold and population mechanism of one metastable methane ion
J. P. Flamme, J. Momigny, and H. Wankenne
pp 1045 - 1047; DOI:
10.1021/ja00420a045
PDF
Electron and energy transfer mechanisms in the quenching of the tris(2,2'-bipyridine)ruthenium(II) luminescence by cyanide complexes
A. Juris, M. T. Gandolfi, M. F. Manfrin, and V. Balzani
pp 1047 - 1048; DOI:
10.1021/ja00420a046
PDF
Photochemical transformations of small ring heterocyclic compounds. 71. Intramolecular 1,1-cycloaddition reactions of nitrile ylides
Albert Padwa, Audrey Ku, Arthur Mazzu, and Stanley I. Wetmore
pp 1048 - 1050; DOI:
10.1021/ja00420a047
PDF
Photochemistry of methyl 1-methylbicyclo[3.3.1] nonan-9-one-3-carboxylates
David S. Weiss, Martin Haslanger, and Richard G. Lawton
pp 1050 - 1052; DOI:
10.1021/ja00420a048
PDF
Photochemistry of o-vinylstilbenes. I. A [2 + 2] cycloaddition of an o-divinylbenzene derivative
M. Sindler-Kulyk and W. H. Laarhoven
pp 1052 - 1053; DOI:
10.1021/ja00420a049
PDF
On the "Utilization of excited state pK's to initiate a ground state chemical reaction"
Edwin A. Chandross
pp 1053 - 1054; DOI:
10.1021/ja00420a050
PDF
Molecular mechanics of the ferroelectric to paraelectric phase transition in lithium tantalate via optical second harmonic generation
John G. Bergman
pp 1054 - 1055; DOI:
10.1021/ja00420a051
PDF
The interaction of decacarbonyldihydrotriosmium with alkenes. Intermediates in hydrogenation and carbon-hydrogen bond activation
Jerome B. Keister and John R. Shapley
pp 1056 - 1057; DOI:
10.1021/ja00420a052
PDF
General base catalysis in nucleophilic attack at sp3 carbon of methylase model compounds
James K. Coward, Roger Lok, and Orinne Takagi
pp 1057 - 1059; DOI:
10.1021/ja00420a053
PDF
Dinosterol, the major sterol with a unique side chain in the toxic dinoflagellate, Gonyaulax tamarensis
Yuzuru Shimizu, Maktoob Alam, and Akio Kobayashi
pp 1059 - 1060; DOI:
10.1021/ja00420a054
PDF
Use of kinetic isotope effects in mechanism studies. Anomalous Arrhenius parameters in the study of elimination reactions
H. F. Koch, D. B. Dahlberg, M. F. McEntee, and C. J. Klecha
pp 1060 - 1061; DOI:
10.1021/ja00420a055
PDF
Book Reviews

pp 1062 - 1064; DOI:
10.1021/ja00420a600
PDF

Issue 5


Studies on polynucleotides. CXLIII. A rapid and convenient method for the synthesis of deoxyribooligonucleotides carrying 5'-phosphate end groups using a new protecting group
K. L. Agarwal, Y. A. Berlin, H. J. Fritz, M. J. Gait, D. G. Kleid, R. G. Lees, K. E. Norris, B. Ramamoorthy, and H. G. Khorana
pp 1065 - 1072; DOI:
10.1021/ja00421a001
PDF
Crystal structure and conformation of the cyclic dipeptide cyclo-(L-threonyl-L-histidyl) dihydrate
Michel Cotrait, Marius Ptak, Bernard Busetta, and Annie Heitz
pp 1073 - 1076; DOI:
10.1021/ja00421a002
PDF
Specific inactivation of solid carbonic anhydrase upon x-ray resonance absorption in the constituent zinc atom
B. Diehn, A. Halpern, and G. Stoecklin
pp 1077 - 1079; DOI:
10.1021/ja00421a003
PDF
Photoionization of anions in rigid media: absorption and emission spectroscopy of cyclooctatetraene radical anions, its ion pairs, and triple ions
Vladimir Dvorak and Josef Michl
pp 1080 - 1086; DOI:
10.1021/ja00421a004
PDF
Thermolysis of tetramethoxy- and p-dioxenedioxetanes. Kinetic parameters, chemiluminescence, and yields of excited products
Therese Wilson, David E. Golan, M. Scott Harris, and Alfons L. Baumstark
pp 1086 - 1091; DOI:
10.1021/ja00421a005
PDF
The measurement and interpretation of hydrogen-tritium kinetic isotope effects in borane and borohydride reductions of ketones. Implications on steric approach control vs. product development control
Daniel J. Pasto and Bohumir Lepeska
pp 1091 - 1095; DOI:
10.1021/ja00421a006
PDF
Time-resolved fluorescence study of triple exciplex formation in 1,3-dinaphthylpropane and 1,4-dicyanobenzene
Tsutomu Mimura and Michiya Itoh
pp 1095 - 1099; DOI:
10.1021/ja00421a007
PDF
N-Alkylformimidoyl cyanides and isocyanides
Joseph H. Boyer and Johannes Kooi
pp 1099 - 1103; DOI:
10.1021/ja00421a008
PDF
Metal-metal interactions in linear chains. The structure and characterization of bis(pyridine-2-carboxaldoximinato)platinum(II) dihydrate
K. W. Nordquest, Daniel W. Phelps, William F. Little, and Derek J. Hodgson
pp 1104 - 1107; DOI:
10.1021/ja00421a009
PDF
Microwave spectrum, structure, and dipole moment of bicyclo[2.1.1]hex-2-ene
Charlene S. Wang and Marlin D. Harmony
pp 1108 - 1111; DOI:
10.1021/ja00421a010
PDF
Interpretation of the electronic spectra of low-spin d6 M(CO)5X complexes. Primary excited state decay paths in Re(CO)5X complexes
Mark S. Wrighton, David L. Morse, Harry B. Gray, and David K. Ottesen
pp 1111 - 1119; DOI:
10.1021/ja00421a011
PDF
Substituent effects in cluster species. Photoelectron spectra of 1-, 2-, and .mu.-substituted pentaborane(9)
J. A. Ulman and T. P. Fehlner
pp 1119 - 1125; DOI:
10.1021/ja00421a012
PDF
Polyene spectroscopy. Photoelectron spectra of the diphenylpolyenes
Bruce S. Hudson, J. Neil A. Ridyard, and James Diamond
pp 1126 - 1129; DOI:
10.1021/ja00421a013
PDF
Electronic states of methylene from ketene photodissociation between 214 and 313 nm
Vaclav P. Zabransky and Robert W. Carr
pp 1130 - 1135; DOI:
10.1021/ja00421a014
PDF
The inversion barrier in AH3 molecules
William Cherry and Nicolaos Epiotis
pp 1135 - 1140; DOI:
10.1021/ja00421a015
PDF
Molecular dynamics of the hydrogen iodide and hydrogen-iodine exchange reactions
R. L. Jaffe, J. M. Henry, and J. B. Anderson
pp 1140 - 1155; DOI:
10.1021/ja00421a016
PDF
Thermodynamic study of hydrogen bonding to chloride ions
S. Y. Lam, C. Louis, and R. L. Benoit
pp 1156 - 1160; DOI:
10.1021/ja00421a017
PDF
Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity
S. A. Sullivan and J. L. Beauchamp
pp 1160 - 1165; DOI:
10.1021/ja00421a018
PDF
Synthesis, crystal structure, and stability of pyruvoylpentacarbonylmanganese(I)
Charles P. Casey, Charles A. Bunnell, and Joseph C. Calabrese
pp 1166 - 1171; DOI:
10.1021/ja00421a019
PDF
Kinetics and mechanism of the reactions between the oxygen-bonded complexes 4-, 3-, and 2-pyridinecarboxylatopentaamminecobalt(III) and aquopentacyanoferrate(II)
Jing-Jer Jwo and Albert Haim
pp 1172 - 1176; DOI:
10.1021/ja00421a020
PDF
A ligand-induced proton shift (LIPS) in two cobaloxime complexes. The crystal and molecular structures of chloro(dimethylglyoximato)(dimethylglyoxime)(sulfanilamide)cobalt(III) monohydrate and chloro(dimethylglyoximato)(dimethylglyoxime)(4-chloroaniline)cobalt(III) dihydrate
Gus J. Palenik, Douglas A. Sullivan, and Datta V. Naik
pp 1177 - 1182; DOI:
10.1021/ja00421a021
PDF
Application of carbon-13 magnetic resonance to isoprenoid biosynthesis. II. Ovalicin and the use of doubly labeled mevalonate
David E. Cane and Ronald H. Levin
pp 1183 - 1188; DOI:
10.1021/ja00421a022
PDF
Low-resolution microwave spectroscopy. III. Three conformers in ethyl trifluoroacetate, ethyl chloroformate, and ethyl cyanoformate
Nancy S. True and Robert K. Bohn
pp 1188 - 1194; DOI:
10.1021/ja00421a023
PDF
Reactions of alkylcyclopropanes with bromine and with hydrogen bromide
Philip S. Skell, James C. Day, and Kenneth J. Shea
pp 1195 - 1204; DOI:
10.1021/ja00421a024
PDF
Bromomalonates as synthetic reagents. Transfer alkylations
Barry M. Trost and Lawrence S. Melvin
pp 1204 - 1212; DOI:
10.1021/ja00421a025
PDF
Electronic states of organic molecules. I. Potential functions for the deformation of methane
Kenneth B. Wiberg, G. Barney Ellison, and John J. Wendoloski
pp 1212 - 1218; DOI:
10.1021/ja00421a026
PDF
Mechanisms of photochemical reactions in solution. LXXVII. Energy wastage and exciplex formation in the quenching of a ketone triplet by sterically hindered alkenes
Amitava Gupta and George S. Hammond
pp 1218 - 1223; DOI:
10.1021/ja00421a027
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. XXIV. Neophyl rearrangements
B. Maillard and K. U. Ingold
pp 1224 - 1226; DOI:
10.1021/ja00421a028
PDF
The total synthesis of (+-)-.alpha.- and (+-)-.beta.-pinene. A general route to bicyclic mono- and sesquiterpenes
Mullapponmannil Thomas Thomas and Alex G. Fallis
pp 1227 - 1231; DOI:
10.1021/ja00421a029
PDF
Substituent effects of alkoxy and amino groups directly bonded to cationic carbon in the perpendicularly twisted geometry. 2-Oxa- and 2-aza-1-adamantyl tosylates
William P. Meyer and J. C. Martin
pp 1231 - 1241; DOI:
10.1021/ja00421a030
PDF
Anionic rearrangement of 7-norbornadienol: a 1,3-sigmatropic shift
Boris Franzus, Monte L. Scheinbaum, Deborah L. Waters, and Harold B. Bowlin
pp 1241 - 1247; DOI:
10.1021/ja00421a031
PDF
Nuclear magnetic resonance studies of photochromism. The photoredox of tris-N,N-dibenzyldithiocarbamatonickel(IV) bromide
Dwight P. Schwendiman and Jeffrey I. Zink
pp 1248 - 1252; DOI:
10.1021/ja00421a032
PDF
Reaction of 1-halonaphthalenes with nucleophiles by the SRN1 mechanism of aromatic substitution
Roberto A. Rossi, Rita H. De Rossi, and Antonio F. Lopez
pp 1252 - 1257; DOI:
10.1021/ja00421a033
PDF
1H-Benzazirines. Intermediates in the ring contraction of iminocyclohexadienylidenes and arylnitrenes
Celestin Thetaz and Curt Wentrup
pp 1258 - 1259; DOI:
10.1021/ja00421a034
PDF
Pyridylnitrenes. Mechanism of ring contraction to cyanopyrroles
Raymond Harder and Curt Wentrup
pp 1259 - 1260; DOI:
10.1021/ja00421a035
PDF
Experimental evidence for geometrical variations in the transition state of the SN2 reaction
Ulf Berg, Roger Gallo, Jacques Metzger, and Michel Chanon
pp 1260 - 1262; DOI:
10.1021/ja00421a036
PDF
Thermal decomposition of cis- and trans-3,4- and -3,6-dimethyl-3,4,5,6-tetrahydropyridazines. Evidence against the hot diradical postulate for azo decompositions
Peter B. Dervan and Tadao Uyehara
pp 1262 - 1264; DOI:
10.1021/ja00421a037
PDF
Sulfine
Eric Block, Robert E. Penn, Robert J. Olsen, and Paul F. Sherwin
pp 1264 - 1265; DOI:
10.1021/ja00421a038
PDF
Trimethylsilylpotassium. Deoxygenation of epoxides with inversion of stereochemistry
Peter B. Dervan and Michael A. Shippey
pp 1265 - 1267; DOI:
10.1021/ja00421a039
PDF
Novel aromatic systems. III. The 1,3,5,7-tetramethylcyclooctatetraene dication, the first 8C-6.pi. Hueckeloid system
George A. Olah, John S. Staral, and Leo A. Paquette
pp 1267 - 1269; DOI:
10.1021/ja00421a040
PDF
Spin-lattice relaxation of protons. A general, quantitative evaluation of contributions from the intramolecular dipole-dipole mechanism
Laurance D. Hall and Howard D. W. Hill
pp 1269 - 1270; DOI:
10.1021/ja00421a041
PDF
Chemical shift elements for the aromatic nitrogen from nuclear magnetic resonance measurements on solutions
P. H. Von Dreele
pp 1270 - 1271; DOI:
10.1021/ja00421a042
PDF
Relative and absolute rate constants for photochemical 1,2-migration of hydrogen, methyl, and phenyl in trans-.beta.-substituted-styrenes
Stephen S. Hixson
pp 1271 - 1273; DOI:
10.1021/ja00421a043
PDF
Tris(.eta.5-cyclopentadienyl)tricarbonyltricobalt. An exceptionally deformable molecule
F. Albert Cotton and Jackie D. Jamerson
pp 1273 - 1274; DOI:
10.1021/ja00421a044
PDF
Nonspecific biosynthesis of hopane triterpenes in a cell-free system from Acetobacter rancens
Claude Anding, Michel Rohmer, and Guy Ourisson
pp 1274 - 1275; DOI:
10.1021/ja00421a045
PDF
Base-promoted hydrolysis of amides at ambient temperatures
Paul G. Gassman, Philip K. G. Hodgson, and Robert J. Balchunis
pp 1275 - 1276; DOI:
10.1021/ja00421a046
PDF
Magnetic resonance spectroscopy on carbon-13 labeled uracil in transfer ribonucleic acid
W. David Hamiill, David M. Grant, W. James Horton, Ronald Lundquist, and Sherman Dickman
pp 1276 - 1278; DOI:
10.1021/ja00421a047
PDF
Perfluorohexamethylbicyclopropenyl
Michael W. Grayston and David M. Lemal
pp 1278 - 1280; DOI:
10.1021/ja00421a048
PDF
Effect of added electrolyte on the binding of tetracycline to paramagnetic ion probes. A carbon-13 and proton nuclear magnetic resonance study
Janet Gulbis, Grover W. Everett, and C. W. Frank
pp 1280 - 1281; DOI:
10.1021/ja00421a049
PDF
Transition-metal-promoted aldehyde-alkene addition reactions
Charles F. Lochow and Roy G. Miller
pp 1281 - 1283; DOI:
10.1021/ja00421a050
PDF
Olefin metathesis reaction. III. Mechanistic considerations
M. T. Mocella, M. A. Busch, and E. L. Muetterties
pp 1283 - 1285; DOI:
10.1021/ja00421a051
PDF
Prostaglandins. I. Direct synthesis of optically active Corey-intermediate from (S)-(-)-malic acid
K. G. Paul, Francis Johnson, and D. Favara
pp 1285 - 1286; DOI:
10.1021/ja00421a052
PDF
Molybdenum x-ray absorption edge spectra. The chemical state of molybdenum in nitrogenase
S. P. Cramer, T. K. Eccles, F. W. Kutzler, Keith O. Hodgson, and L. E. Mortenson
pp 1287 - 1288; DOI:
10.1021/ja00421a053
PDF
Evidence for reaction of hydrogen iodide dimers with fluorine
Jean F. Durana and J. D. McDonald
pp 1289 - 1290; DOI:
10.1021/ja00421a054
PDF
Consistent inversion in the base-induced reaction of iodine with organoboranes. A convenient procedure for the synthesis of optically active iodides
Herbert C. Brown, Norman R. De Lue, George W. Kabalka, and Herbert C. Hedgecock
pp 1290 - 1291; DOI:
10.1021/ja00421a055
PDF
Application of unreactive analogs of terpenoid pyrophosphates to studies of multistep biosynthesis. Demonstration that "presqualene pyrophosphate" is an essential intermediate on the path to squalene
E. J. Corey and R. P. Volante
pp 1291 - 1293; DOI:
10.1021/ja00421a056
PDF
Effect of photoselection on fluorescence-detected circular dichroism
B. Ehrenberg and I. Z. Steinberg
pp 1293 - 1295; DOI:
10.1021/ja00421a057
PDF
The relative stability of alkyl-substituted benzene anions in the gas phase
K. D. Jordan, J. A. Michejda, and P. D. Burrow
pp 1295 - 1296; DOI:
10.1021/ja00421a058
PDF
Metal clusters in catalysis. IV. Catalytic hydrogen reduction of carbon monoxide to alkanes
M. G. Thomas, B. F. Beier, and E. L. Muetterties
pp 1296 - 1297; DOI:
10.1021/ja00421a059
PDF
An intramolecular model for the enzymic insertion of coenzyme B12 into unactivated carbon-hydrogen bonds
Ronald Breslow and Pyare L. Khanna
pp 1297 - 1299; DOI:
10.1021/ja00421a060
PDF
Book Reviews

pp 1299 - 1300; DOI:
10.1021/ja00421a600
PDF

Issue 6


Chemical ionization of amino acids
C. W. Tsang and A. G. Harrison
pp 1301 - 1308; DOI:
10.1021/ja00422a001
PDF
The dependence of geminal hydrogen-hydrogen spin-spin coupling constants on .phi. and .psi. angles of peptides in solution
M. Barfield, V. J. Hruby, and J. P. Meraldi
pp 1308 - 1314; DOI:
10.1021/ja00422a002
PDF
Kinetics of phase equilibrium in a binary mixture of phospholipids
Philippe Brulet and Harden M. McConnell
pp 1314 - 1318; DOI:
10.1021/ja00422a003
PDF
.pi.-Spin distribution in the radical anions of [2.2]paracyclophane and some of its symmetric benzo derivatives
F. Gerson, W. B. Martin, and C. Wydler
pp 1318 - 1320; DOI:
10.1021/ja00422a004
PDF
Gas-phase basicities and proton affinities of compounds between water and ammonia and substituted benzenes from a continuous ladder of proton transfer equilibria measurements
Raghavendra Yamdagni and Paul Kebarle
pp 1320 - 1324; DOI:
10.1021/ja00422a005
PDF
Crossed beam studies of ion-molecule reactions in methane and ammonia
G. P. K. Smith, M. Saunders, and R. J. Cross
pp 1324 - 1330; DOI:
10.1021/ja00422a006
PDF
Effects of random coordinate error in analyses of lanthanide-induced pseudocontact shifts. Axially symmetric case
C. C. Hinckley and W. C. Brumley
pp 1331 - 1336; DOI:
10.1021/ja00422a007
PDF
CIDNP kinetics from Fourier transform NMR
C. F. Poranski, S. A. Sojka, and W. B. Moniz
pp 1337 - 1341; DOI:
10.1021/ja00422a008
PDF
Ab-initio LCAO-MO-SCF calculations of morphine and nalorphine and measurement of their photoelectron spectra
Herbert E. Popkie, Walter S. Koski, and Joyce J. Kaufman
pp 1342 - 1345; DOI:
10.1021/ja00422a009
PDF
Valence electronic structure and internal rotation barrier of the molecules XH3YH3 (X, Y = carbon, silicon, germanium) by a pseudopotential method
G. Nicolas, J. C. Barthelat, and P. Durand
pp 1346 - 1350; DOI:
10.1021/ja00422a010
PDF
Molecular structure of ion pairs from electric dipole moments. III. Substituted anilinium chlorides and p-toluenesulfonates in octanoic acid
Ting-Po I and Ernest Grunwald
pp 1351 - 1354; DOI:
10.1021/ja00422a011
PDF
The thermochemistry of diphenylcyclopropenone. Strain vs. delocalization energy
Harry P. Hopkins, David Bostwick, and C. J. Alexander
pp 1355 - 1357; DOI:
10.1021/ja00422a012
PDF
Transfer hydrogenation in the presence of a homogeneous rhodium catalyst
C. Masters, A. A. Kiffen, and J. P. Visser
pp 1357 - 1364; DOI:
10.1021/ja00422a013
PDF
The catalytic reduction of nitric oxide by carbon monoxide using dichlorodicarbonylrhodium(I) anion
Carol D. Meyer and Richard Eisenberg
pp 1364 - 1371; DOI:
10.1021/ja00422a014
PDF
Catalysis in oxidation reactions. II. The oxalic acid catalyzed oxidation of iodide
George F. Vandegrift and Jan Rocek
pp 1371 - 1376; DOI:
10.1021/ja00422a015
PDF
Oxidative coupling of the phenylethynyl group in .mu.-(1-3.eta.:2-4.eta.-trans,trans-1,4-diphenylbutadiene)-bis(bis(.eta.5-methylcyclopentadienyl)titanium) and the reaction of 1,4-diphenyl-1,3-butadiene with bis(cyclopentadienyl)titanium(II)
Dennis G. Sekutowski and Galen D. Stucky
pp 1376 - 1382; DOI:
10.1021/ja00422a016
PDF
Solvation of the tris(1,10-phenanthroline)iron(II) cation as measured by solubility and nuclear magnetic resonance shifts
F. M. Van Meter and H. M. Neumann
pp 1382 - 1388; DOI:
10.1021/ja00422a017
PDF
The rates of racemization and dissociation of the tris(1,10-phenanthroline)iron(II) cation in various solvents
F. M. Van Meter and H. M. Neumann
pp 1388 - 1394; DOI:
10.1021/ja00422a018
PDF
Organometallic conformational equilibriums. XX. Preferred orientations and rotational barriers of .pi.-olefins in chiral tin-iron compounds. The isolation of diastereoisomers in prochiral olefin derivatives
J. W. Faller, Bryce V. Johnson, and Charles D. Schaeffer
pp 1395 - 1400; DOI:
10.1021/ja00422a019
PDF
Reaction mechanisms of metal-metal bonded carbonyls. X. Thermal decomposition of decacarbonyldimanganese and decacarbonylmanganeserhenium in decalin
J. Paul Fawcett, Anthony Poe, and Kumud R. Sharma
pp 1401 - 1407; DOI:
10.1021/ja00422a020
PDF
Stereochemically nonrigid six-coordinate metal carbonyl complexes. II. A carbon-13 nuclear magnetic resonance study of the series M(CO)4(EMe3)2 (M = iron, ruthenium, osmium; E = silicon, germanium, tin, lead)
Liviu Vancea, Roland K. Pomeroy, and William A. G. Graham
pp 1407 - 1413; DOI:
10.1021/ja00422a021
PDF
Carbon-13 nuclear magnetic resonance study of the fluxional behavior of cyclooctatetraenetricarbonyliron and -ruthenium
F. Albert Cotton and Douglas L. Hunter
pp 1413 - 1417; DOI:
10.1021/ja00422a022
PDF
Calculation of the ground state electronic structures and electronic spectra of di- and trisulfide radical anions by the scattered wave-SCF-X.alpha. method
F. Albert Cotton, Jane B. Harmon, and Richard M. Hedges
pp 1417 - 1424; DOI:
10.1021/ja00422a023
PDF
Molecular structure and magnetic properties of .mu.-dihydroxo-bis[2,6-pyridinedicarboxylatoaquoiron(III)] and .mu.-dihydroxo-bis[4-hydroxo-2,6-pyridinedicarboxylatoaquoiron(III)] tetrahydrate
John A. Thich, Chia Chih Ou, Dana Powers, Byron Vasiliou, Donald Mastropaolo, Joseph A. Potenza, and Harvey J. Schugar
pp 1425 - 1433; DOI:
10.1021/ja00422a024
PDF
Acid-base properties and gas-phase ion chemistry of trimethylborane
M. K. Murphy and J. L. Beauchamp
pp 1433 - 1440; DOI:
10.1021/ja00422a025
PDF
Deltahedral and deltahedral-fragment thiaboranes with 12-, 11-, 10-, and 9-vertex frameworks, their syntheses and characterization
W. R. Pretzer and R. W. Rudolph
pp 1441 - 1447; DOI:
10.1021/ja00422a026
PDF
The electron spin resonance of tetra(p-carboxylphenyl)porphinatocobalt(II) in pyridine at 77 K
W. C. Lin and P. W. Lau
pp 1447 - 1450; DOI:
10.1021/ja00422a027
PDF
Intramolecular ligand exchange in phosphoranes. A comparison of Berry pseudorotation and turnstile rotation
Julianna A. Altmann, Keith Yates, and I. G. Csizmadia
pp 1450 - 1454; DOI:
10.1021/ja00422a028
PDF
Mercury 6(3P1) photosensitization of trifluoroethylene. A source of the difluorovinylidene carbene
R. J. Norstrom, H. E. Gunning, and O. P. Strausz
pp 1454 - 1461; DOI:
10.1021/ja00422a029
PDF
The strange behavior of lithium salt of tetraphenylethylene dianion
G. Levin, B. Lundgren, M. Mohammad, and M. Szwarc
pp 1461 - 1463; DOI:
10.1021/ja00422a030
PDF
Spectra of tetracyanoquinodimethane monovalent anion: vibrational structure and polarization of electronic transitions
Ivan Haller and F. B. Kaufman
pp 1464 - 1468; DOI:
10.1021/ja00422a031
PDF
Heats of alkylation of substituted pyridines. A comparison of carbon basicity, proton affinity, and nucleophilicity
Edward M. Arnett and Craig Petro
pp 1468 - 1471; DOI:
10.1021/ja00422a032
PDF
Peri- and regioselectivities of the nickel(0)-catalyzed valence isomerization of the 1,8-bishomocubane system. A molecular orbital consideration
R. Noyori, M. Yamakawa, and H. Takaya
pp 1471 - 1478; DOI:
10.1021/ja00422a033
PDF
Ring contraction of 2-azidopyridine 1-oxides and related compounds. 2-Cyano-1-hydroxypyrroles and -imidazoles
Rudolph A. Abramovitch and Berkeley W. Cue
pp 1478 - 1486; DOI:
10.1021/ja00422a034
PDF
The reduction of cyanopyridine complexes of pentaamminecobalt(III) by chromium(II). Orbital paths for reduction of the linkage isomers of 4-cyanopyridine
Robert J. Balahura
pp 1487 - 1492; DOI:
10.1021/ja00422a035
PDF
Synthesis of 3-deazaguanine, 3-deazaguanosine, and 3-deazaguanylic acid by a novel ring closure of imidazole precursors
P. Dan Cook, Robert J. Rousseau, A. Mohsin Mian, Phoebe Dea, Rich B. Meyer, and Roland K. Robins
pp 1492 - 1498; DOI:
10.1021/ja00422a036
PDF
An application of artificial intelligence to organic synthesis
Paul E. Blower and Howard W. Whitlock
pp 1499 - 1510; DOI:
10.1021/ja00422a037
PDF
Chemistry of superoxide ion. I. Oxidation of 3,5-di-tert-butylcatechol with potassium superoxide
Yoshihiko Morooka and Christopher S. Foote
pp 1510 - 1514; DOI:
10.1021/ja00422a038
PDF
Scope and mechanism of aromatic iodination with electrochemically generated iodine(I)
Larry L. Miller and Bruce F. Watkins
pp 1515 - 1519; DOI:
10.1021/ja00422a039
PDF
Reactions of alkali benzophenone ketyls with alkyl iodides
John F. Garst and Calvin D. Smith
pp 1520 - 1526; DOI:
10.1021/ja00422a040
PDF
Wittig rearrangements of aralkyl alkyl ethers
John F. Garst and Calvin D. Smith
pp 1526 - 1537; DOI:
10.1021/ja00422a041
PDF
Acidities of alkylarenes from the equilibriums of their sodium salts
G. Gau and S. Marques
pp 1538 - 1541; DOI:
10.1021/ja00422a042
PDF
Solvolysis mechanisms. Kinetic solvent isotope effects for alkyl tosylates in acetic acid and acetic acid-d
Theresa S. C. C. Huang and Edward R. Thornton
pp 1542 - 1545; DOI:
10.1021/ja00422a043
PDF
Rearrangement of nonamethylbicyclo[3.2.1]octa-3,6-dien-2-yl cation to the corresponding [3.3.0] cation
Harold Hart and Masayuki Kuzuya
pp 1545 - 1550; DOI:
10.1021/ja00422a044
PDF
Circumambulation, bridge shifts, and cyclopropylcarbinyl rearrangements in bicyclo[3.2.1]octadienyl carbocations
Harold Hart and Masayuki Kuzuya
pp 1551 - 1563; DOI:
10.1021/ja00422a045
PDF
Kinetics and mechanism of hydration of strained bridgehead bicyclic olefins
Y. Chiang, A. J. Kresge, and J. R. Wiseman
pp 1564 - 1566; DOI:
10.1021/ja00422a046
PDF
Reversible reactions of gaseous ions. X. The intrinsic stability of the norbornyl cation
J. J. Solomon and F. H. Field
pp 1567 - 1569; DOI:
10.1021/ja00422a047
PDF
Structure of sarracenin. An unusual enol diacetal monoterpene from the insectivorous plant Sarracenia flava
D. Howard Miles, Udom Kokpol, J. Bhattacharyya, Jerry L. Atwood, Karen E. Stone, Thomas A. Bryson, and Charles Wilson
pp 1569 - 1573; DOI:
10.1021/ja00422a048
PDF
Flow nuclear magnetic resonance study of the dehydration of the tetrahedral intermediate resulting from the addition of hydroxylamine to acetaldehyde
Michael Cocivera, Colin A. Fyfe, Adan Effio, Shiv P. Vaish, and Holger E. Chen
pp 1573 - 1578; DOI:
10.1021/ja00422a049
PDF
Crystal and molecular structure of the calcium ion complex of A23187
G. D. Smith and W. L. Duax
pp 1578 - 1580; DOI:
10.1021/ja00422a050
PDF
An x-ray diffraction and infrared-Raman spectroscopic study of the hydrogen dinitrate ion, (O2NO-H-ONO2)-, in cesium hydrogen dinitrate
Jack M. Williams, Noreen Dowling, R. Gunde, D. Hadzi, and B. Orel
pp 1581 - 1582; DOI:
10.1021/ja00422a051
PDF
Neutron-scattering spectrum of cesium hydrogen dinitrate
Jacques Roziere and C. V. Berney
pp 1582 - 1583; DOI:
10.1021/ja00422a052
PDF
Chiral synthesis of prostaglandins from carbohydrates. Synthesis of (+)-15-(S)-prostaglandin A2
Gilbert Stork and Stanley Raucher
pp 1583 - 1584; DOI:
10.1021/ja00422a053
PDF
Environmental control of reactions: enhancement of .mu.-oxo dimer formation from iron(III) porphyrins in organized monolayer assemblies as a model for membrane catalysis
F. R. Hopf, D. Moebius, and D. G. Whitten
pp 1584 - 1586; DOI:
10.1021/ja00422a054
PDF
Intervalence (charge-transfer) bands in symmetrical and unsymmetrical bispyridinium-pyridinyl radical complexes, (Py.cntdot.)32+
Edward M. Kosower and Avraham Teuerstein
pp 1586 - 1587; DOI:
10.1021/ja00422a055
PDF
Synthesis of C-5 substituted pyrimidine nucleosides via organopalladium intermediates
Donald E. Bergstrom and Jerry L. Ruth
pp 1587 - 1589; DOI:
10.1021/ja00422a056
PDF
Biosynthesis of uroporphyrinogen III from porphobilinogen. Resolution of the enigmatic "switch" mechanism
A. Ian Scott, K. S. Ho, M. Kajiwara, and T. Takahashi
pp 1589 - 1591; DOI:
10.1021/ja00422a057
PDF
Matrix reactions of alkali metal fluoride molecules with fluorine. Infrared and Raman spectra of the trifluoride ion in the M+F3- species
Bruce S. Ault and Lester Andrews
pp 1591 - 1593; DOI:
10.1021/ja00422a058
PDF
Four degenerate thermal isomerizations of 1-methylspiro[2.4]hepta-4,6-diene. A test for the Smith mechanism
Kevin E. Gilbert and John E. Baldwin
pp 1593 - 1595; DOI:
10.1021/ja00422a059
PDF
Temperature and pH dependence of the tetramer-dimer equilibrium of carbomonoxyhemoglobin A0
G. J. Ide, A. D. Barksdale, and A. Rosenberg
pp 1595 - 1596; DOI:
10.1021/ja00422a060
PDF
Electrochemical preparation and control of stoichiometry for donor-halide salts: TTFXn and TSeFXn
F. B. Kaufman, E. M. Engler, D. C. Green, and J. Q. Chambers
pp 1596 - 1597; DOI:
10.1021/ja00422a061
PDF
Bidentate and monodentate bonding modes of the 1,3-diaryltriazenido ligand in ruthenium(II) and platinum(II) complexes
Leo D. Brown and James A. Ibers
pp 1597 - 1598; DOI:
10.1021/ja00422a062
PDF
Exhaustive protonation of benzenepolycarboxylic acid polymethyl esters. Polycarbenium ions surrounding a benzene ring
Daniel Bruck and Mordecai Rabinovitz
pp 1599 - 1600; DOI:
10.1021/ja00422a063
PDF
Cobalt-boron clusters
Vernon R. Miller and Russell N. Grimes
pp 1600 - 1601; DOI:
10.1021/ja00422a064
PDF
Intercalate of xenon hexafluoride in graphite. A potential mild fluorinating agent of aromatic compounds
Henry Selig, Mordecai Rabinovitz, Israel Agranat, Chun-Hsu Lin, and Lawrence Ebert
pp 1601 - 1602; DOI:
10.1021/ja00422a065
PDF
Fluorine control of regioselectivity in photocycloaddition reactions. The direct functionalization of uracil via a novel 1,4-fragmentation
Allan Wexler and John S. Swenton
pp 1602 - 1604; DOI:
10.1021/ja00422a066
PDF
Carbon-13 nuclear magnetic resonance spectra of zinc(II) coproporphyrins. A modus operandi for reproducible measurement of porphyrin spectra
Raymond J. Abraham, Harry Pearson, and Kevin M. Smith
pp 1604 - 1606; DOI:
10.1021/ja00422a067
PDF
Thermal decomposition of tricyclo[6.4.0.23,6]tetradeca-1(8),4,13-triene. A process involving a series of intramolecular and retro-Diels-Alder reactions
A. Gilbert and R. Walsh
pp 1606 - 1607; DOI:
10.1021/ja00422a068
PDF
Oxygen binding to mercaptide-heme complexes. Models for reduced cytochrome P-450
C. K. Chang and D. Dolphin
pp 1607 - 1609; DOI:
10.1021/ja00422a069
PDF
Photochemistry as a probe of the excited state properties of molecules. IV. A determination of the relative triplet reactivities of the carbon-nitrogen and carbon-oxygen chromophores of 4-acylpyrimidines. Photochemical cyclopropanol formation
Edward C. Alexander and Roy J. Jackson
pp 1609 - 1610; DOI:
10.1021/ja00422a070
PDF
A paramagnetic, square-pyramidal nickel(II) alkyl complex
M. J. D'Aniello and E. Kent Barefield
pp 1610 - 1611; DOI:
10.1021/ja00422a071
PDF
Total synthesis of (.+-.)-vernolepin and (.+-.)-vernomenin
Paul A. Grieco, Mugio Nishizawa, S. D. Burke, and N. Marinovic
pp 1612 - 1613; DOI:
10.1021/ja00422a072
PDF
Reaction rate difference in the laser excitation of different vibrational modes of 1,1-dichloro-1,1,2,2-tetrafluoroethane
R. N. Zitter and D. F. Koster
pp 1613 - 1614; DOI:
10.1021/ja00422a073
PDF
Carbon dioxide coordination chemistry. The structure and some chemistry of the novel carbon dioxide addition product chlorobis(carbon dioxide)tris(trimethylphosphine)iridium
Thomas Herskovitz and Lloyd J. Guggenberger
pp 1615 - 1616; DOI:
10.1021/ja00422a074
PDF
Detection of covalent intermediates by nucleophile trapping in the hydrolysis of phenyl tetrahydrofurfuryl sulfite catalyzed by pepsin
Y. Nakagawa, L. H. King Sun, and E. T. Kaiser
pp 1616 - 1617; DOI:
10.1021/ja00422a075
PDF
Isotope effects in hydrophobic binding measured by high-pressure liquid chromatography
Nobuo Tanaka and Edward R. Thornton
pp 1617 - 1619; DOI:
10.1021/ja00422a076
PDF
Cesium-133 nuclear magnetic resonance study of crown and cryptate complexes of cesium(1+) ion in nonaqueous solvents
Elizabeth Mei, James L. Dye, and Alexander I. Popov
pp 1619 - 1620; DOI:
10.1021/ja00422a077
PDF
A new method of enantiomeric purification via a topochemical photodimerization reaction. Application to three 1-aryl ethanols
Meir Lahav, Felix Laub, Edna Gati, Leslie Leiserowitz, and Zvi Ludmer
pp 1620 - 1622; DOI:
10.1021/ja00422a078
PDF
The ground electronic state of silaethylene. An ab initio molecular orbital study of the lower electronic manifold
O. P. Strausz, L. Gammie, G. Theodorakoupoulos, P. G. Mezey, and I. G. Csizmadia
pp 1622 - 1624; DOI:
10.1021/ja00422a079
PDF
Crystal and molecular structure of a novel asymmetrical neodymium-cyclooctatetraene compound, cyclooctatetraenylbis(tetrahydrofuran)neodymium(III) bis(cyclooctatetraenyl)neodymate(III)
Stephen R. Ely, Ted E. Hopkins, and Carroll W. DeKock
pp 1624 - 1625; DOI:
10.1021/ja00422a080
PDF
Effect of irradiation with ultraviolet light on spectral sensitization of the photoelectrochemical process of a zinc oxide single-crystal electrode
Akira Fujishima, Takashi Iwase, and Kenichi Honda
pp 1625 - 1627; DOI:
10.1021/ja00422a081
PDF
Oxidative deamination of primary amines by copper halide nitrosyls. The formation of geminal dihalides
Michael P. Doyle, Bernard Siegfried, and James J. Hammond
pp 1627 - 1629; DOI:
10.1021/ja00422a082
PDF
A novel oxidative transformation: oxidative esterification
Tomoya Ogawa and Masanao Matsui
pp 1629 - 1630; DOI:
10.1021/ja00422a083
PDF
The reactivity of monomeric metaphosphate
Leslie M. Loew
pp 1630 - 1632; DOI:
10.1021/ja00422a084
PDF
Kinetics and mechanism of hydrolysis of aryloxyphosphonium salts
Charles M. Lonzetta, Steven J. Kubisen, and F. H. Westheimer
pp 1632 - 1634; DOI:
10.1021/ja00422a085
PDF
Stereospecific conversion of diosgenin to .alpha.-ecdysone
Eun Lee, Y. T. Liu, Philippa H. Solomon, and K. Nakanishi
pp 1634 - 1635; DOI:
10.1021/ja00422a086
PDF
Visible light to electrical energy conversion. Stable cadmium sulfide and cadmium selenide photoelectrodes in aqueous electrolytes
Arthur B. Ellis, Steven W. Kaiser, and Mark S. Wrighton
pp 1635 - 1637; DOI:
10.1021/ja00422a087
PDF
Ground and excited state correlations in the rupture of oxygen-oxygen bonds in peroxides
E. M. Evleth
pp 1637 - 1639; DOI:
10.1021/ja00422a088
PDF
Book Reviews

pp 1639 - 1646; DOI:
10.1021/ja00422a600
PDF

Issue 7


Sulfuranes. Theoretical aspects of bonding, substituent site preferences, and geometrical distortions
Maynard M. L. Chen and Roald Hoffmann
pp 1647 - 1653; DOI:
10.1021/ja00423a001
PDF
The least-motion insertion reaction methylene(1A1) + molecular hydrogen .fwdarw. methane. Theoretical study of a process forbidden by orbital symmetry
Charles W. Bauschlicher, Henry F. Schaefer, and Charles F. Bender
pp 1653 - 1658; DOI:
10.1021/ja00423a002
PDF
Molecular structure of the chlorine difluoride and chlorine tetrafluoride radicals. A theoretical study
Steven R. Ungemach and Henry F. Schaefer
pp 1658 - 1662; DOI:
10.1021/ja00423a003
PDF
Molecular orbital theory of the electronic structure of molecules. XXVII. Energies and conformations of XCH2Y systems involving lithium, beryllium, and boron
James D. Dill, Paul v. R. Schleyer, and John A. Pople
pp 1663 - 1668; DOI:
10.1021/ja00423a004
PDF
Conformational study of cyclic and acyclic phosphate esters. CNDO/2 calculations of angle strain and torsional strain
David G. Gorenstein, Debojyoti Kar, Bruce A. Luxon, and Robert K. Momii
pp 1668 - 1673; DOI:
10.1021/ja00423a005
PDF
Free-radical chemistry of organophosphorus compounds. V. Reactions of thiyl radicals with alkylphosphonites. Effects of activation energies and A values on the .alpha. vs. .beta. scission competition
Wesley G. Bentrude and Peter E. Rogers
pp 1674 - 1677; DOI:
10.1021/ja00423a006
PDF
Chemiluminescence and energy transfer in systems of electrogenerated aromatic anions and benzoyl peroxide
T. D. Santa Cruz, D. L. Akins, and Ronald L. Birke
pp 1677 - 1682; DOI:
10.1021/ja00423a007
PDF
Kinetics of the oxidation of hydrazine by hydrogen peroxide, catalyzed by hydrated copper(II)
Carl R. Wellman, J. Richard Ward, and Lester P. Kuhn
pp 1683 - 1684; DOI:
10.1021/ja00423a008
PDF
Theoretical study of the azido-tetrazole isomerization
Luke A. Burke, Jose Elguero, Georges Leroy, and Michel Sana
pp 1685 - 1690; DOI:
10.1021/ja00423a009
PDF
The mercury 6(3P1), cadmium 5(3P1), and benzene (3B1u) photosensitization of vinyl fluoride
S. Tsunashima, H. E. Gunning, and O. P. Strausz
pp 1690 - 1696; DOI:
10.1021/ja00423a010
PDF
Carbon-13 spin-lattice relaxation studies of perfluoroalkanes
J. R. Lyerla and David L. VanderHart
pp 1697 - 1700; DOI:
10.1021/ja00423a011
PDF
Substituent effects in the naphthalene ring system by fluorine-19 NMR
W. Adcock, J. Alste, S. Q. A. Rizvi, and M. Aurangzeb
pp 1701 - 1711; DOI:
10.1021/ja00423a012
PDF
ESR and x-ray study of the structure of diquat (6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazinediium) cation radical and dication
Paul D. Sullivan and Michael L. Williams
pp 1711 - 1716; DOI:
10.1021/ja00423a013
PDF
Molecular structure of ion pairs from electric dipole moments. IV. Ion-pair solvation in acetic acid
Ernest Grunwald, M. R. Crampton, A. Effio, and Ting-Po I
pp 1716 - 1720; DOI:
10.1021/ja00423a014
PDF
Effects of chloride ion on oscillations in the bromate-cerium-malonic acid system
Steven S. Jacobs and Irving R. Epstein
pp 1721 - 1724; DOI:
10.1021/ja00423a015
PDF
Structural entropy changes in infinitely dilute solutions and pure liquids
Howard DeVoe
pp 1724 - 1729; DOI:
10.1021/ja00423a016
PDF
Structure and chemistry of bis(cyclopentadienyl)-MLn complexes
Joseph W. Lauher and Roald Hoffmann
pp 1729 - 1742; DOI:
10.1021/ja00423a017
PDF
Molecular dynamics of .alpha.-cyclodextrin inclusion complexes
J. P. Behr and J. M. Lehn
pp 1743 - 1747; DOI:
10.1021/ja00423a018
PDF
Metal-metal interactions involving metalloporphyrins. III. Conversion of tetraphenylporphinatoiron(III) azide to an N-bridged hemin dimer
David A. Summerville and Irwin A. Cohen
pp 1747 - 1752; DOI:
10.1021/ja00423a019
PDF
The synthesis, structures, and properties of new macrocyclic ligands and novel sexadentate iron complexes produced by electrophilic reactions of the iron derivatives
Dennis P. Riley, John A. Stone, and Daryle H. Busch
pp 1752 - 1762; DOI:
10.1021/ja00423a020
PDF
Coordination isomers of biological iron transport compounds. V. The preparation and chirality of the chromium(III) enterobactin complex and model tris(catechol)chromium(III) analogues
Stephan S. Isied, Gilbert Kuo, and Kenneth N. Raymond
pp 1763 - 1767; DOI:
10.1021/ja00423a021
PDF
Coordination isomers of biological iron transport compounds. VI. Models of the enterobactin coordination site. A crystal field effect in the structure of potassium tris(catecholato)chromate(III) and -ferrate(III) sesquihydrates, K3[M(O2C6H4)3].cntdot.1.5H2O, M = chromium, iron
Kenneth N. Raymond, Stephan S. Isied, Leo D. Brown, Frank R. Fronczek, and J. Hunter Nibert
pp 1767 - 1774; DOI:
10.1021/ja00423a022
PDF
Metal-metal multiple bonds in organometallic compounds. I. (Di-tert-butylacetylene)hexacarbonyldiiron and -dicobalt
F. Albert Cotton, Jackie D. Jamerson, and B. Ray Stults
pp 1774 - 1779; DOI:
10.1021/ja00423a023
PDF
Molecular structure and bonding of a silacyclopropane, dimethyldispiro[bicyclo[4.1.0]heptane-7,2'-silacyclopropane-3',7''-bicyclo[4.1.0]heptane]
Gerald L. Delker, Yu Wang, Galen D. Stucky, Robert L. Lambert, Carol K. Haas, and Dietmar Seyferth
pp 1779 - 1784; DOI:
10.1021/ja00423a024
PDF
Hydroboration. XL. Hydroboration of alkenes and alkynes with monochloroborane etherates. Convenient procedures for the preparation of dialkyl-, monoalkyl-, and dialkenylchloroboranes and their derivatives
Herbert C. Brown and N. Ravindran
pp 1785 - 1798; DOI:
10.1021/ja00423a025
PDF
Hydroboration. XLI. Hydroboration of alkenes and alkynes with dichloroborane etherates. Convenient procedures for the preparation of alkyl- and alkenyldichloroboranes and their derivatives
Herbert C. Brown and N. Ravindran
pp 1798 - 1806; DOI:
10.1021/ja00423a026
PDF
The palladium(II) catalyzed olefin carbonylation reaction. The stereochemistry of methoxypalladation
D. E. James, L. F. Hines, and J. K. Stille
pp 1806 - 1809; DOI:
10.1021/ja00423a027
PDF
The palladium(II) catalyzed olefin carbonylation reaction. Mechanisms and synthetic utility
D. E. James and J. K. Stille
pp 1810 - 1823; DOI:
10.1021/ja00423a028
PDF
Gas-phase alkylation of xylenes by tert-butyl(1+) ions
Pierluigi Giacomello and Fulvio Cacace
pp 1823 - 1828; DOI:
10.1021/ja00423a029
PDF
Reaction of oxygen(3P) atoms with toluene and 1-methylcyclohexene
J. S. Gaffney, R. Atkinson, and J. N. Pitts
pp 1828 - 1832; DOI:
10.1021/ja00423a030
PDF
Chiral nuclear magnetic resonance solvating agents. Resolution, determination of enantiomeric purity, and assignment of absolute configuration of cyclic and acyclic sulfinate esters
William H. Pirkle and Marvin S. Hoekstra
pp 1832 - 1839; DOI:
10.1021/ja00423a031
PDF
Aromatic substitution. XXXVII. Stannic and aluminum chloride catalyzed Friedel-Crafts alkylation of naphthalene with alkyl halides. Differentiation of kinetically and thermodynamically controlled product compositions, and the isomerization of alkylnaphthalenes
George A. Olah and Judith A. Olah
pp 1839 - 1842; DOI:
10.1021/ja00423a032
PDF
Nitrogen inversion rates in bicyclo[2.2.2]octyl hydrazines and amines by carbon-13 NMR
S. F. Nelsen and G. R. Weisman
pp 1842 - 1850; DOI:
10.1021/ja00423a033
PDF
Conformations of saturated phosphorus heterocycles. IV. Proton, carbon-13, and phosphorus-31 nuclear magnetic resonance studies of geometrical isomers of 2-Z-4-methyl- and 4-tert-butyl-1,3,2-dioxaphospholanes
Wesley G. Bentrude and Han-Wan Tan
pp 1850 - 1859; DOI:
10.1021/ja00423a034
PDF
Locked aryl rotation in cis-diarylacenaphthenes, torsionally rigid analogues of cis-1,2-diarylcyclopentanes
Arnold R. Miller and David Y. Curtin
pp 1860 - 1865; DOI:
10.1021/ja00423a035
PDF
The effect of transient photoproducts in benzophenone-hydrogen donor systems
Jonathan Chilton, Linda Giering, and Colin Steel
pp 1865 - 1870; DOI:
10.1021/ja00423a036
PDF
Activation volumes and volumes of reaction for the proton-transfer reaction between 4-nitrophenylnitromethane and 1,1',3,3'-tetramethylguanidine in some aprotic solvents
Colin D. Hubbard, Christopher J. Wilson, and Edward F. Caldin
pp 1870 - 1875; DOI:
10.1021/ja00423a037
PDF
The mechanism of allene cycloaddition. III. Thermal and photochemical generation of 2,2'-bis(1,1-dimethylallyl) biradical from an azocyclane precursor
Thomas J. Levek and Edgar F. Kiefer
pp 1875 - 1879; DOI:
10.1021/ja00423a038
PDF
Ozonization of organic substrates. Hydrotrioxide formation and decomposition to give singlet oxygen
Frank E. Stary, Dale E. Emge, and Robert W. Murray
pp 1880 - 1884; DOI:
10.1021/ja00423a039
PDF
Oxidation of primary amines bound to bis(2,2'-bipyridine)ruthenium(II)
F. Richard Keene, Dennis J. Salmon, and Thomas J. Meyer
pp 1884 - 1889; DOI:
10.1021/ja00423a040
PDF
Electrostatic facilitation of general acid catalyzed .alpha.-oxonium ion formation in a lysozyme-like environment: synthesis of the models
Denis E. Ryono and Gordon M. Loudon
pp 1889 - 1899; DOI:
10.1021/ja00423a041
PDF
Electrostatic facilitation of general acid catalyzed .alpha.-oxonium ion formation in a lysozyme-like environment: kinetic investigations
Gordon M. Loudon and Denis E. Ryono
pp 1900 - 1907; DOI:
10.1021/ja00423a042
PDF
Some very rapid reactions of porphyrins in aqueous solution
Robert F. Pasternack, Norman Sutin, and Douglas H. Turner
pp 1908 - 1913; DOI:
10.1021/ja00423a043
PDF
Nitrosylmetalloporphyrins. III. Synthesis and molecular stereochemistry of nitrosyl-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinato(1-methylimidazole)iron(II)
W. Robert Scheidt and Paul L. Piciulo
pp 1913 - 1919; DOI:
10.1021/ja00423a044
PDF
Molecular structure of biotin. Results of two independent crystal structure investigations
George T. DeTitta, James W. Edmonds, William Stallings, and Jerry Donohue
pp 1920 - 1926; DOI:
10.1021/ja00423a045
PDF
Structure of the antibiotic griseoviridin
George I. Birnbaum and Sydney R. Hall
pp 1926 - 1931; DOI:
10.1021/ja00423a046
PDF
Internal rotations of side chains and backbone in luteinizing hormone-releasing hormone (LH-RH). Analysis of carbon-13 spin-lattice relaxation times
Roxanne Deslauriers and R. L. Somorjai
pp 1931 - 1939; DOI:
10.1021/ja00423a047
PDF
The pH dependence of the nitrotyrosine-248 and arsanilazotyrosine-248 carboxypeptidase A catalyzed hydrolysis of O-(trans-p-chlorocinnamoyl)-L-.beta.-phenyllactate
Junghun Suh and Emil T. Kaiser
pp 1940 - 1947; DOI:
10.1021/ja00423a048
PDF
Conformation and reactivity of the macrocyclic tumor-inhibitory alkaloid tetrandrine
Christopher J. Gilmore, Robert F. Bryan, and S. Morris Kupchan
pp 1947 - 1952; DOI:
10.1021/ja00423a049
PDF
Enzymic hydration of [18O]epoxides. Role of nucleophilic mechanisms
Robert P. Hanzlik, Marshall Edelman, William J. Michaely, and Georganna Scott
pp 1952 - 1955; DOI:
10.1021/ja00423a050
PDF
Biotransformation of 1-benzyl-1,2,3,4-tetrahydro-2-methylisoquinolines into tetrahydroprotoberberines with rat liver enzymes
Tetsuji Kametani, Makoto Takemura, Masataka Ihara, Keiichi Takahashi, and Keiichiro Fukumoto
pp 1956 - 1959; DOI:
10.1021/ja00423a051
PDF
Hydride mobility in pyridinium salt-dihydropyridine mixtures. A Biomimetic pyridine nucleotide transhydrogenation
T. J. Van Bergen, Titi Mulder, and Richard M. Kellogg
pp 1960 - 1962; DOI:
10.1021/ja00423a052
PDF
Hydride transfer from NADH models to sp3-hybridized carbon. Competition with enamine alkylation
T. J. Van Bergen and Richard M. Kellogg
pp 1962 - 1964; DOI:
10.1021/ja00423a053
PDF
The facile rearrangement of lithium dialkyl-9-borabicyclo[3.3.1]nonane "ate" complexes via hydride transfer. A simple synthetic route to cis-bicyclo[3.3.0]oct-1-yldialkylboranes and derivatives
Gary W. Kramer and Herbert C. Brown
pp 1964 - 1965; DOI:
10.1021/ja00423a054
PDF
Stereo-, chemo-, and regioselective reductions of carbonyl groups via the lithium di-n-butyl-9-borabicyclo[3.3.1]nonane "ate" complex
Yoshinori Yamamoto, Hiroo Toi, Akio Sonoda, and Shunichi Murahashi
pp 1965 - 1967; DOI:
10.1021/ja00423a055
PDF
Total synthesis of (.+-.)-daunomycinone and (.+-.)-carminomycinone
Andrew S. Kende, Yuh-Geng Tsay, and John E. Mills
pp 1967 - 1969; DOI:
10.1021/ja00423a056
PDF
Synthetic approaches to adriamycin. Degradation of daunorubicin to nonasymmetric tetracyclic ketone and refunctionalization of the A-ring to adriamycin
Thomas H. Smith, Allan N. Fujiwara, David W. Henry, and William W. Lee
pp 1969 - 1971; DOI:
10.1021/ja00423a057
PDF
Stable cis dialkyldiazenes (azoalkanes): cis-di-1-adamantyldiazene and cis-di-1-norbornyldiazene
Paul S. Engel, Robert A. Melaugh, Matthew A. Page, S. Szilagyi, and J. W. Timberlake
pp 1971 - 1972; DOI:
10.1021/ja00423a058
PDF
Thermochemistry of cyclic 1,2-dialkyldiazenes (azo compounds). The effect of strain energy on thermal lability
Paul S. Engel
pp 1972 - 1974; DOI:
10.1021/ja00423a059
PDF
Spectroscopic evidence for the generation of singlet oxygen in self-reaction of sec-peroxy radicals
Minoru Nakano, Kiyoshige Takayama, Yoshiaki Shimizu, Yasuhiro Tsuji, Humio Inaba, and Toshihiko Migita
pp 1974 - 1975; DOI:
10.1021/ja00423a060
PDF
Rearrangement of optically active ethyl (E)-3-methyl-3-phenylglycidate. Evidence for concerted carbethoxy migration
John M. Domagala, Robert D. Bach, and James Wemple
pp 1975 - 1977; DOI:
10.1021/ja00423a061
PDF
Coupling constants between directly bonded silicon atoms
Kenneth G. Sharp, Paul A. Sutor, Elizabeth A. Williams, Joseph D. Cargioli, Thomas C. Farrar, and K. Ishibitsu
pp 1977 - 1979; DOI:
10.1021/ja00423a062
PDF
Cocatalysis of phenolate phosphorylation in biphasic media
R. W. Ridgway, H. S. Greenside, and H. H. Freedman
pp 1979 - 1980; DOI:
10.1021/ja00423a063
PDF
Electrochemical synthesis and structural characterization of the iron-sulfur cluster cation bis(.eta.5-2,4-cyclopentadien-1-yl)[.mu.-(dithio)]bis[.mu.-(ethanethiolato)]diiron(1+)
P. J. Vergamini, R. R. Ryan, and G. J. Kubas
pp 1980 - 1982; DOI:
10.1021/ja00423a064
PDF
Regiospecific quinone isoprenylation. Examples of remarkably facile [3,3] sigmatropic processes
D. A. Evans and J. M. Hoffman
pp 1983 - 1984; DOI:
10.1021/ja00423a065
PDF
Chemistry of superoxide ion. III. Quenching of singlet oxygen
Henri J. Guiraud and Christopher S. Foote
pp 1984 - 1986; DOI:
10.1021/ja00423a066
PDF
Osmium catalyzed vicinal hydroxylation of olefins by tert-butyl hydroperoxide under alkaline conditions
K. Barry Sharpless and Kageyasu Akashi
pp 1986 - 1987; DOI:
10.1021/ja00423a067
PDF
Free energies of hydration and hydrolysis of gaseous acetamide
Richard Wolfenden
pp 1987 - 1988; DOI:
10.1021/ja00423a068
PDF
2a,8a,8b,8c-Tetrahydropentaleno[6,1,2-aji]azulene
Barry M. Trost and William B. Herdle
pp 1988 - 1990; DOI:
10.1021/ja00423a069
PDF
The proton affinities of toluene
John L. Devlin, J. Fredrick Wolf, Robert W. Taft, and Warren J. Hehre
pp 1990 - 1992; DOI:
10.1021/ja00423a070
PDF
Organic reactions at high pressure. Cycloadditions with furans
William G. Dauben and Herman O. Krabbenhoft
pp 1992 - 1993; DOI:
10.1021/ja00423a071
PDF
Solvent isotope effect in inorganic pyrophosphatase-catalyzed hydrolysis of inorganic pyrophosphate
Luray M. Konsowitz and Barry S. Cooperman
pp 1993 - 1995; DOI:
10.1021/ja00423a072
PDF
Nature of the detectable intermediate in the permanganate oxidation of trans-cinnamic acid
Laszlo I. Simandi and Miklos Jaky
pp 1995 - 1997; DOI:
10.1021/ja00423a073
PDF
On the use of proton nuclear magnetic resonance as a tool in determining long range .pi.-interactions in carbanions
G. B. Trimitsis and A. Tuncay
pp 1997 - 1999; DOI:
10.1021/ja00423a074
PDF
The geometry of bicyclo[5.4.1]dodecapentaenylium ion
Riccardo Destro, Tullio Pilati, and Massimo Simonetta
pp 1999 - 2000; DOI:
10.1021/ja00423a075
PDF
Phosphorescence of substituted benzophenones in solution. Probes for the conformation of hydrocarbon chains in polar and protic solvents
Mitchell A. Winnik, Alberta Lemire, Douglas S. Saunders, and Chung Kwong Lee
pp 2000 - 2002; DOI:
10.1021/ja00423a076
PDF
Exciplex substitution (Sex). A new photophysical process
Hiroyuki Ohta, David Creed, Paul H. Wine, Richard A. Caldwell, and Lynn A. Melton
pp 2002 - 2003; DOI:
10.1021/ja00423a077
PDF
A stereochemical test of similarly substituted tetramethylenediazene and cyclic azo decompositions in the gas phase at the same temperature
Peter B. Dervan and Tadao Uyehara
pp 2003 - 2005; DOI:
10.1021/ja00423a078
PDF
1,3-Dithiepin anion. A 10.pi.-heteroaromatic system
Carol L. Semmelhack, I-Ching Chiu, and Klaus G. Grohmann
pp 2005 - 2006; DOI:
10.1021/ja00423a079
PDF
Photochemical transformations of small ring heterocyclic compounds. 74. A stepwise 1,3-dipolar cycloaddition reaction
Albert Padwa and Per H. J. Carlsen
pp 2006 - 2008; DOI:
10.1021/ja00423a080
PDF
Preparation and reactions of 2-(alkoxy)-1-(alkyl or arylthio)vinyllithium. Application in the synthesis of 9-desoxo-9-thiaprostaglandins
Isidoros Vlattas, Laurence Della Vecchia, and Avelina Ong Lee
pp 2008 - 2010; DOI:
10.1021/ja00423a081
PDF
Evidence against product development control as an important factor in the reduction of ketones by simple and complex metal hydrides
E. C. Ashby and S. A. Noding
pp 2010 - 2011; DOI:
10.1021/ja00423a082
PDF
Alkane elimination in mass spectrometry. A counterpart to the McLafferty rearrangement
J. F. Litton, T. L. Kruger, and R. G. Cooks
pp 2011 - 2013; DOI:
10.1021/ja00423a083
PDF
The photochemical induced cyclization of allyl Grignard reagents
Samuel Cohen and Amnon Yogev
pp 2013 - 2014; DOI:
10.1021/ja00423a084
PDF
A novel tridentate ligand formed by the condensation and rearrangement of three ethoxycarbonyl isothiocyanate molecules in the presence of tris(triphenylphosphine)chlororhodium(I)
Yoshio Ishii, Kenji Itoh, Isamu Matsuda, Fujio Ueda, and James A. Ibers
pp 2014 - 2015; DOI:
10.1021/ja00423a085
PDF
An electron spin resonance study of the radical anions derived from metal carbene complexes of chromium, molybdenum, and tungsten
P. J. Krusic, U. Klabunde, C. P. Casey, and T. F. Block
pp 2015 - 2018; DOI:
10.1021/ja00423a086
PDF
Squalene synthetase. Differentiation between the two substrate binding sites by a substrate analogue
Paul R. Ortiz de Montellano, Rafael Castillo, Wayne Vinson, and Jeng Shu Wei
pp 2018 - 2019; DOI:
10.1021/ja00423a087
PDF
Maintenance of chirality in a photochemical methylenecyclopropane rearrangement
W. A. Gros, T. Luo, and J. C. Gilbert
pp 2019 - 2020; DOI:
10.1021/ja00423a088
PDF
Nonadditive carbon-13 substituent and solvent effects in substituted benzenes
J. Bromilow, R. T. C. Brownlee, R. D. Topsom, and R. W. Taft
pp 2020 - 2022; DOI:
10.1021/ja00423a089
PDF
Photochemistry of a cyclohex-3-enone. Evidence for a stepwise pathway in an oxadi-.pi.-methane rearrangement
Beat Winter and Kurt Schaffner
pp 2022 - 2023; DOI:
10.1021/ja00423a090
PDF
Modes of acid catalysis in the aromatization of arene oxides
Paula Y. Bruice and Thomas C. Bruice
pp 2023 - 2025; DOI:
10.1021/ja00423a091
PDF
Book Reviews

pp 2025 - 2026; DOI:
10.1021/ja00423a600
PDF

Issue 8


Thermal, photochemical, and photophysical processes in cyclopropanone vapor
Hector J. Rodriguez, Jung-Ching Chang, and Timothy F. Thomas
pp 2027 - 2034; DOI:
10.1021/ja00424a001
PDF
Selection rules for the charge transfer transitions in the symmetrical tetracyano-p-quinodimethane-anthracene molecular complex
C. J. Eckhardt and R. R. Pennelly
pp 2034 - 2040; DOI:
10.1021/ja00424a002
PDF
Molecular orbital theory of the hydrogen bond. XV. Ring closure and proton transfer in formic acid dimer and .beta.-hydroxyacrolein
Janet E. Del Bene and William L. Kochenour
pp 2041 - 2046; DOI:
10.1021/ja00424a003
PDF
Comparison of equilibrium reactions in the gaseous and liquid phases. A new, improved theoretical estimate
Sidney W. Benson and G. David Mendenhall
pp 2046 - 2048; DOI:
10.1021/ja00424a004
PDF
The gas phase reaction of fluoride(1-) and hydroxide(1-) ions with alkyl formates
J. Fernando G. Faigle, Paulo C. Isolani, and Jose M. Riveros
pp 2049 - 2052; DOI:
10.1021/ja00424a005
PDF
Free radicals in an adamantane matrix. XII. EPR and INDO study of .sigma.*-.pi.* crossover in fluorinated benzene anions
Moon B. Yim and David E. Wood
pp 2053 - 2059; DOI:
10.1021/ja00424a006
PDF
Dynamics of eight-membered rings. 1,3-Dioxocane and its gem-dimethyl derivatives
F. A. L. Anet, P. J. Degen, and J. Krane
pp 2059 - 2066; DOI:
10.1021/ja00424a007
PDF
The electronic structure of molecules by a many-body approach. IV. Ionization potentials and one-electron properties of pyrrole and phosphole
W. Von Niessen, L. S. Cederbaum, and G. H. F. Diercksen
pp 2066 - 2073; DOI:
10.1021/ja00424a008
PDF
The crystal and molecular structure of the antifolate drug trimethoprim (2,4-diamino-5-(3,4,5-trimethoxybenzyl)pyrimidine). A neutron diffraction study
T. F. Koetzle and G. J. B. Williams
pp 2074 - 2078; DOI:
10.1021/ja00424a009
PDF
Electronic structure of sulfur compounds. XXI. Application of photoelectron spectroscopy to conformational analysis of S-tetrathianes
M. F. Guimon, C. Guimon, F. Metras, and G. Pfister-Guillouzo
pp 2078 - 2081; DOI:
10.1021/ja00424a010
PDF
Relationship between orbital ionization energies and molecular properties. Proton affinities and photoelectron spectra of nitriles
Ralph H. Staley, James E. Kleckner, and J. L. Beauchamp
pp 2081 - 2085; DOI:
10.1021/ja00424a011
PDF
Localized molecular orbitals for polyatomic molecules. IV. Large boron hydrides
D. A. Dixon, D. A. Kleier, T. A. Halgren, and W. N. Lipscomb
pp 2086 - 2096; DOI:
10.1021/ja00424a012
PDF
Vibrational spectra and structure of methylberyllium borohydride
Louis J. Allamandola and Joseph W. Nibler
pp 2096 - 2100; DOI:
10.1021/ja00424a013
PDF
A semiempirical theory of substituent-induced carbon-13 chemical shifts in .pi. systems
D. J. Sardella
pp 2100 - 2104; DOI:
10.1021/ja00424a014
PDF
Evaluation of contact and dipolar contributions to proton and carbon-13 paramagnetic NMR shifts in axially symmetric lanthanide chelates
J. F. Desreux and Charles N. Reilley
pp 2105 - 2109; DOI:
10.1021/ja00424a015
PDF
Carbon-13 nuclear magnetic resonance of organophosphorus compounds. X. Ring-size variation in heterocyclic phosphines, phosphonium salts, and phosphine oxides
George A. Gray, Sheldon E. Cremer, and K. L. Marsi
pp 2109 - 2118; DOI:
10.1021/ja00424a016
PDF
Proton NMR studies of the interaction of metalloporphyrins with .pi. acceptors and donors. I. Effect of .pi.-complex formation on the electronic structure of low-spin cobalt(II)
George P. Fulton and Gerd N. La Mar
pp 2119 - 2124; DOI:
10.1021/ja00424a017
PDF
Proton NMR studies of the interaction of metalloporphyrins with .pi. acceptors and donors. II. Solution structure of the 1:1 adduct of 1,3,5-trinitrobenzene with tetra-p-tolylporphinatocobalt(II)
George P. Fulton and Gerd N. La Mar
pp 2124 - 2128; DOI:
10.1021/ja00424a018
PDF
A comparison of isomeric carbene (ylide) and amidine complexes of cobalt(III). An approach to the study of carbon-coordinated imidazole
Daniel J. Doonan, John E. Parks, and Alan L. Balch
pp 2129 - 2134; DOI:
10.1021/ja00424a019
PDF
Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins
Richard R. Schrock and John A. Osborn
pp 2134 - 2143; DOI:
10.1021/ja00424a020
PDF
Catalytic hydrogenation using cationic rhodium complexes. II. The selective hydrogenation of alkynes to cis olefins
Richard R. Schrock and John A. Osborn
pp 2143 - 2147; DOI:
10.1021/ja00424a021
PDF
Optical spectra of the difluoride, dichloride, and trichloride ions in the matrix-isolated M+F2-, M+Cl2-, and M+Cl3- species
Lester Andrews
pp 2147 - 2152; DOI:
10.1021/ja00424a022
PDF
Optical spectra of the dibromide and diiodide ions in the matrix-isolated M+Br2- and M+I2- species
Lester Andrews
pp 2152 - 2156; DOI:
10.1021/ja00424a023
PDF
A new class of nickel hydrides. HNiL3CN
J. D. Druliner, A. D. English, J. P. Jesson, P. Meakin, and C. A. Tolman
pp 2156 - 2160; DOI:
10.1021/ja00424a024
PDF
The nature of the fluorine exchange processes in some alkyl- and dimethylaminofluorophosphoranes
C. G. Moreland, G. O. Doak, L. B. Littlefield, N. S. Walker, J. W. Gilje, R. W. Braun, and A. H. Cowley
pp 2161 - 2165; DOI:
10.1021/ja00424a025
PDF
Stereochemistry of eight-coordinate mixed-ligand complexes of zirconium. II. Characterization and the crystal and molecular structure of nitratotris(acetylacetonato)zirconium(IV)
E. Gordon Muller, Victor W. Day, and Robert C. Fay
pp 2165 - 2172; DOI:
10.1021/ja00424a026
PDF
Rate controlling chelate ring closing in the complexing of nickel(II) by picolinic and fusaric acids
R. H. Voss and R. B. Jordan
pp 2173 - 2177; DOI:
10.1021/ja00424a027
PDF
Kinetic studies of the oxidation and reduction of Chromatium high potential iron-sulfur protein (HiPIP) by inorganic complexes. Comparison of the electron transfer reactivities of HiPIP and horse heart cytochrome c
Jill Rawlings, Scot Wherland, and Harry B. Gray
pp 2177 - 2180; DOI:
10.1021/ja00424a028
PDF
Preparation and stereochemistry of an unusual copper(II)-purine complex. Axial and equatorial purine ligands in the square-pyramidal complex bis(theophyllinato)(diethylenetriamine)copper(II) dihydrate
Theophilus Sorrell, Luigi G. Marzilli, and Thomas J. Kistenmacher
pp 2181 - 2188; DOI:
10.1021/ja00424a029
PDF
Carbon acidity. LII. Equilibrium acidity of cyclopentadiene in water and in cyclohexylamine
Andrew Streitwieser and Linda L. Nebenzahl
pp 2188 - 2190; DOI:
10.1021/ja00424a030
PDF
Organic transition states. V. The Diels-Alder reaction
R. E. Townshend, G. Ramunni, G. Segal, W. J. Hehre, and L. Salem
pp 2190 - 2198; DOI:
10.1021/ja00424a031
PDF
Kinetics of the stereospecific photochemical cyclodimerization of 2-butene in the liquid phase
H. Yamazaki, R. J. Cvetanovic, and R. S. Irwin
pp 2198 - 2205; DOI:
10.1021/ja00424a032
PDF
Kinetic study of triplet excimer formation in fluid solution by means of phosphorimetry
Takeshi Takemura, Masayuki Aikawa, Hiroaki Baba, and Yoshio Shindo
pp 2205 - 2210; DOI:
10.1021/ja00424a033
PDF
The optical activity of low-symmetry ketones in absorption and emission
H. P. J. M. Dekkers and Liselotte E. Closs
pp 2210 - 2219; DOI:
10.1021/ja00424a034
PDF
Photochemical synthesis. 63. Thione photochemistry. 20. Cycloaddition in a saturated alicyclic system
A. H. Lawrence, C. C. Liao, P. De Mayo, and V. Ramamurthy
pp 2219 - 2226; DOI:
10.1021/ja00424a035
PDF
Reactions of cyclohexadienones. XXXVI. Allyl and benzyl migrations in the rearrangements of naphthalenones
Bernard Miller and Mohammed R. Saidi
pp 2227 - 2238; DOI:
10.1021/ja00424a036
PDF
Vinylic cations from solvolysis. XXIII. Degenerate .beta.-anisyl rearrangement during the solvolysis of 2-anisyl-1,2-diphenylvinyl bromides. Free ions as intermediates
Zvi Rappoport, Etta Noy, and Yoram Houminer
pp 2238 - 2244; DOI:
10.1021/ja00424a037
PDF
Oxyfunctionalization of hydrocarbons. 1. Protolytic cleavage-rearrangement reactions of tertiary alkyl hydroperoxides with magic acid
George A. Olah, David G. Parker, Norihiko Yoneda, and Franco Pelizza
pp 2245 - 2250; DOI:
10.1021/ja00424a038
PDF
Oxyfunctionalization of hydrocarbons. 2. Ozonolysis of alkylcarbenium ions
George A. Olah, Norihiko Yoneda, and David G. Parker
pp 2251 - 2254; DOI:
10.1021/ja00424a039
PDF
Isotope effects in hydrogen atom transfers. IV. Alkyl halides with trialkyltin hydrides
S. Kozuka and Edward S. Lewis
pp 2254 - 2256; DOI:
10.1021/ja00424a040
PDF
Isotope effects in hydrogen atom transfers. V. The reactions of olefins with mercaptans
E. S. Lewis and M. M. Butler
pp 2257 - 2260; DOI:
10.1021/ja00424a041
PDF
Isotope effects in hydrogen atom transfers. VI. Radicals from azo compounds in thiophenol
E. S. Lewis and K. Ogino
pp 2260 - 2264; DOI:
10.1021/ja00424a042
PDF
Isotope effects in hydrogen atom transfer. VII. Benzylic hydrogen abstraction by tert-butoxy and other radicals
E. S. Lewis and K. Ogino
pp 2264 - 2268; DOI:
10.1021/ja00424a043
PDF
Isotope effects in hydrogen atom transfers. VIII. Addition of dimethyl phosphonate and thiophosphonate to olefins
E. S. Lewis and E. C. Nieh
pp 2268 - 2271; DOI:
10.1021/ja00424a044
PDF
Nucleophilic substitution reactions in fluorinated bis(arene)chromium complexes
Michael J. McGlinchey and Teong-Seng Tan
pp 2271 - 2275; DOI:
10.1021/ja00424a045
PDF
Mechanism of the sodium cyanoborohydride reduction of .alpha.,.beta.-unsaturated tosylhydrazones
Evelyn J. Taylor and Carl Djerassi
pp 2275 - 2281; DOI:
10.1021/ja00424a046
PDF
A study on the mechanism of the reaction of N-(2,4-dinitrophenyl)-3-carbamoylpyridinium chloride with amines and amino acids with reference to effect of polyelectrolyte addition
Shigeru Kunugi, Tsuneo Okubo, and Norio Ise
pp 2282 - 2287; DOI:
10.1021/ja00424a047
PDF
In vitro solar conversion after the primary light reaction in photosynthesis. Reversible photogalvanic effects of chlorophyll-quinhydrone half-cell reactions
Francis K. Fong and Nicholas Winograd
pp 2287 - 2289; DOI:
10.1021/ja00424a048
PDF
Oxazolines. XXI. Kinetic resolution of sec-alkyl halides and simultaneous asymmetric synthesis of 3-alkylalkanoic acids using a chiral oxazoline. A method for determining absolute configurations and maximum optical rotations
A. I. Meyers and K. Kamata
pp 2290 - 2294; DOI:
10.1021/ja00424a049
PDF
Tumor inhibitors. 111. Structure and stereochemistry of jatrophone, a novel macrocyclic diterpenoid tumor inhibitor
S. Morris Kupchan, Carl W. Sigel, Marilyn J. Matz, Christopher J. Gilmore, and Robert F. Bryan
pp 2295 - 2300; DOI:
10.1021/ja00424a050
PDF
Pteridines. XXXVII. A total synthesis of L-erythro-biopterin and some related 6-(polyhydroxyalkyl)pterins
Edward C. Taylor and Peter A. Jacobi
pp 2301 - 2307; DOI:
10.1021/ja00424a051
PDF
Interaction of uridine and cytidine monophosphates with ribonuclease A. IV. Phosphorus-31 nuclear magnetic resonance studies
David G. Gorenstein, Alice M. Wyrwicz, and Jurgen Bode
pp 2308 - 2314; DOI:
10.1021/ja00424a052
PDF
Dehalogenation of 5-bromo-6-methoxy-5,6-dihydrothymine by cysteine
Frank A. Sedor and Eugene G. Sander
pp 2314 - 2319; DOI:
10.1021/ja00424a053
PDF
Monosodium urate monohydrate, the gout culprit
Neil S. Mandel and Gretchen S. Mandel
pp 2319 - 2323; DOI:
10.1021/ja00424a054
PDF
Synthesis of a nonadecapeptide corresponding to residues 37-55 of ovine prolactin. Detection and isolation of the sulfonium form of methionine-containing peptides
Richard L. Noble, Donald Yamashiro, and Choh Hao Li
pp 2324 - 2328; DOI:
10.1021/ja00424a055
PDF
Polycyclic K-region arene oxides. Products and kinetics of solvolysis
John W. Keller and Charles Heidelberger
pp 2328 - 2336; DOI:
10.1021/ja00424a056
PDF
Photochemical reactions in organized monolayer assemblies. III. Photochemical cleavage of water: a system for solar energy conversion using monolayer-bound transition metal complexes
Gerhard Sprintschnik, Hertha W. Sprintschnik, Pierre P. Kirsch, and David G. Whitten
pp 2337 - 2338; DOI:
10.1021/ja00424a057
PDF
Binuclear nature of the aquomolybdenum(IV) ion in solution
M. Ardon, A. Bino, and G. Yahav
pp 2338 - 2339; DOI:
10.1021/ja00424a058
PDF
Selenium protection against mercury toxicity. Binding of methylmercury by the selenohydryl-containing ligand
Yukio Sugiura, Yasuji Hojo, Yoichi Tamai, and Hisashi Tanaka
pp 2339 - 2341; DOI:
10.1021/ja00424a059
PDF
(2 + 4) (.pi. + .pi..pi.) and (2 + 4) (n + .pi..pi.) Modes of addition in the reaction between sulfur dioxide and a diene. Kinetic vs. thermodynamic control
R. F. Heldeweg and H. Hogeveen
pp 2341 - 2342; DOI:
10.1021/ja00424a060
PDF
Studies on .beta.-lactam antibiotics. III. Synthesis of 2-methyl-3-cephem derivatives
Takashi Kamiya, Tsutomu Teraji, Masashi Hashimoto, Osamu Nakaguchi, and Teruo Oku
pp 2342 - 2344; DOI:
10.1021/ja00424a061
PDF
A synthesis of N-substituted 1,2-dihydropyridines
John N. Bonfiglio, Iltifat Hasan, John J. Piwinski, Barry Weinstein, and Frank W. Fowler
pp 2344 - 2345; DOI:
10.1021/ja00424a062
PDF
An oxygen-17 nuclear magnetic resonance chemical shift scale for polyoxomolybdates
M. Filowitz, W. G. Klemperer, L. Messerle, and W. Shum
pp 2345 - 2346; DOI:
10.1021/ja00424a063
PDF
Quaternary ammonium enolates as synthetic intermediates. Trimethylsilylacetate: a new class of silylating reagent for ketones and alcohols
Eiichi Nakamura, Toshiaki Murofushi, Makoto Shimizu, and Isao Kuwajima
pp 2346 - 2348; DOI:
10.1021/ja00424a064
PDF
Isolation, structure, and biosynthesis of 6-ketoprostaglandin F1.alpha. in the rat stomach
C. Pace-Asciak
pp 2348 - 2349; DOI:
10.1021/ja00424a065
PDF
Photochemistry of the phthalimide system. VII. Regioselective remote photocyclization. Examples of a photochemical macrocyclic synthesis with sulfide-containing phthalimides
Y. Sato, H. Nakai, T. Mizoguchi, Y. Hatanaka, and Y. Kanaoka
pp 2349 - 2351; DOI:
10.1021/ja00424a066
PDF
A new synthesis of vinylogous aldols and polyenones
Gilbert Stork and George A. Kraus
pp 2351 - 2352; DOI:
10.1021/ja00424a067
PDF
Synthesis of trichloroacetamido-1,3-dienes. Useful aminobutadiene equivalents for the Diels-Alder reaction
Larry E. Overman and Lane A. Clizbe
pp 2352 - 2354; DOI:
10.1021/ja00424a068
PDF
Association of isocyanide complexes of rhodium(I) and rhodium(III) in solution
Alan L. Balch and Marilyn M. Olmstead
pp 2354 - 2356; DOI:
10.1021/ja00424a069
PDF
Coordination geometries and bond types in three-coordinate phosphine complexes of copper(I), silver(I), and gold(I)
M. Barrow, H. B. Buergi, D. K. Johnson, and L. M. Venanzi
pp 2356 - 2357; DOI:
10.1021/ja00424a070
PDF
Attack by phosphorus nucleophiles on a cluster-bound vinyl group. The crystal structure of HOs3(CO)10(CHCH2PMe2Ph)
Melvyn R. Churchill, Barry G. DeBoer, John R. Shapley, and Jerome B. Keister
pp 2357 - 2358; DOI:
10.1021/ja00424a071
PDF
Kinetic confirmation and synthetic circumvention of the cascade mechanism for population of the triplet ground state of a trimethylenemethane
Jerome A. Berson, Charles D. Duncan, Genevieve C. O'Connell, and Matthew S. Platz
pp 2358 - 2360; DOI:
10.1021/ja00424a072
PDF
Temperature dependence of positron lifetimes in carbonic anhydrase
Edward D. Handel, G. Graf, and James C. Glass
pp 2360 - 2361; DOI:
10.1021/ja00424a073
PDF
A comparison of translational energies released during metastable decomposition following electron impact and field ionization. A test of the QET model and mechanistic probe
Peter J. Derrick and Alexander G. Loudon
pp 2361 - 2362; DOI:
10.1021/ja00424a074
PDF
Stereoselective one-pot dialkylation of gem-dihalocyclopropanes. A simple route to dl-sesquicarene and dl-sirenin
Katuzi Kitatani, Tamejiro Hiyama, and Hitosi Nozaki
pp 2362 - 2364; DOI:
10.1021/ja00424a075
PDF
Determination of Gibbs energies for solid-solid phase transitions in electrochemical double cells without liquid junction: calcite, aragonite, and vaterite
Peter A. Rock and Arnold Z. Gordon
pp 2364 - 2365; DOI:
10.1021/ja00424a076
PDF
Reactions of coordinated molecules. V. Preparation of cis-(OC)4Re[C(CH3)O...H...OC(CH3]: the enol tautomer of a metalloacetylacetone molecule
C. M. Lukehart and Jane V. Zeile
pp 2365 - 2367; DOI:
10.1021/ja00424a077
PDF
Nonreducible cyclic analogues of somatostatin
Daniel F. Veber, Robert G. Strachan, Susan J. Bergstrand, Frederick W. Holly, Carl F. Homnick, Ralph Hirschmann, Mary L. Torchiana, and Richard Saperstein
pp 2367 - 2369; DOI:
10.1021/ja00424a078
PDF
X-ray photoelectron spectroscopic studies of the thermal stability of chlorophyll a monohydrate
Nicholas Winograd, Allan Shepard, Dale H. Karweik, Vaughn J. Koester, and Francis K. Fong
pp 2369 - 2370; DOI:
10.1021/ja00424a079
PDF
Additions and Corrections - A Synthesis of d,l-Muscone from Cyclododecanone
Gilbert Stork, and T. L. MacDonald
pp 2370 - 2370; DOI:
10.1021/ja00424a600
PDF
Additions and Corrections - Concerning the Intermediacy of Uro'gen III and of a Heptacarboxylic Uro'Gen in Corrinoid Biosynthesis
A. Ian Scott, N. Georgopapadakou, K. S. Ho, S. Klioze, E. Lee, S. L. Lee, G. H. Temme, III., and C. A. Townsend
pp 2371 - 2371; DOI:
10.1021/ja00424a601
PDF
Additions and Corrections - An Investigation of Potassium Perchromate as a Source of Singlet Oxygen
John W. Peters, Paul J. Bekowies, Arthur M. Winer, and James N. Pitts, Jr.
pp 2371 - 2371; DOI:
10.1021/ja00424a602
PDF
Additions and Corrections - Molecular Orbital Theory of the Electronic Structure of Organic Compounds. XXIV. Geometries and Energies of Small Boron Compounds. Comparisons with Carbocations.
J. D. Dill, P. v. R. Schleyer, and J. A. Pople
pp 2371 - 2371; DOI:
10.1021/ja00424a603
PDF
Additions and Corrections - Photoelectron Spectra of Open Chain C6H6 Isomers
Peter Bischof, Rolf Gleiter, Hennig Hopf, and Frank T. Lenich
pp 2371 - 2371; DOI:
10.1021/ja00424a604
PDF
Additions and Corrections - Melochinone, a Novel Quinolinone from Melochia tomentosa
Govind J. Kapadia, Buddha D. Paul, J. V. Silverton, Henry M. Fales, and Edward A. Sokoloski
pp 2371 - 2371; DOI:
10.1021/ja00424a605
PDF
Additions and Corrections - A Method for Determining the Conformational Preference of Nonrigid Radicals by Electron Paramagnetic Resonance
John B. Lisle, Lawrence F. Williams, and David Eldon Wood
pp 2371 - 2371; DOI:
10.1021/ja00424a606
PDF
Additions and Corrections - A Reiterative Functionalization of Unactivated Carbon-Hydrogen Bonds. Photolysis of α-Peracetoxynitriles
David S. Watt
pp 2371 - 2371; DOI:
10.1021/ja00424a607
PDF
Additions and Corrections - Dehydration of a Carbinolhydrazine in the Solid State. Correlation with Crystal Structure of the Dehydration of 2-Hydroxy-2-(β-benzoyl-β-phenylhydrazyl)indan-1,3-dione
S. A. Puckett, I. C. Paul, and D. Y. Curtin
pp 2371 - 2371; DOI:
10.1021/ja00424a608
PDF
Additions and Corrections - The Hoffman-Loefller-Freytag Bridge between Mass Spectrometry and Free Radical Chemistry
Mark M. Green, J. M. Moldowan, Mark W. Armstrong, Tim L. Thompson, Kevin J. Sprague, Alan J. Hass, and Juan J. Artus
pp 2371 - 2371; DOI:
10.1021/ja00424a609
PDF
Book Reviews

pp 2372 - 2372; DOI:
10.1021/ja00424a610
PDF

Issue 9


Anharmonic force constants of polyatomic molecules. Test of the procedure for deducing a force field from the vibration-rotation spectrum
Donald G. Truhlar, Radley W. Olson, Anthony C. Jeannotte, and John Overend
pp 2373 - 2379; DOI:
10.1021/ja00425a001
PDF
Further studies of the core binding energy-proton affinity correlation in molecules
B. E. Mills, R. L. Martin, and D. A. Shirley
pp 2380 - 2385; DOI:
10.1021/ja00425a002
PDF
Nonbonded attraction in methyl vinyl ether
Fernando Bernardi, Nicolaos D. Epiotis, Ronald L. Yates, and H. Bernhard Schlegel
pp 2385 - 2390; DOI:
10.1021/ja00425a003
PDF
Fluorescence probing of inverted micelles. The state of solubilized water clusters in alkane/diisooctyl sulfosuccinate (aerosol OT) solution
M. Wong, J. K. Thomas, and M. Graetzel
pp 2391 - 2397; DOI:
10.1021/ja00425a004
PDF
Photoelectron spectra of diazabasketene, diazadeltacyclene, and related polycyclic cis-azoalkanes
Russell J. Boyd, Jean C. G. Bunzli, and James P. Snyder
pp 2398 - 2406; DOI:
10.1021/ja00425a005
PDF
The structure of visual pigments. I. Carbon-13 nuclear magnetic resonance spectroscopy of N-all-trans-retinylidenepropylimine and its protonated species
John Shriver, Edwin W. Abrahamson, and Gheorghe D. Mateescu
pp 2407 - 2409; DOI:
10.1021/ja00425a006
PDF
Organometallic chemistry of the transition metals. XXXII. Some reactions of iron carbonyls with dimethylenecyclobutane derivatives
R. B. King and C. A. Harmon
pp 2409 - 2414; DOI:
10.1021/ja00425a007
PDF
Axial ligation modes in iron(III) porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate
S. C. Tang, S. Koch, G. C. Papaefthymiou, S. Foner, R. B. Frankel, James A. Ibers, and R. H. Holm
pp 2414 - 2434; DOI:
10.1021/ja00425a008
PDF
The crystal structure of disodium tetracarbonylferrate. Distortion of the tetracarbonylferrate(2-) anion in the solid state
Henry B. Chin and Robert Bau
pp 2434 - 2439; DOI:
10.1021/ja00425a009
PDF
Structural effect of adding paired and unpaired electrons to otherwise identical transition metal systems. Magnetic and structural properties in iron(III) complexes, new intermediate iron(III) spin state, and structures of benzene solvated tris(4-morpholinecarbodithioato-S,S') type compounds
Ray J. Butcher and Ekk Sinn
pp 2440 - 2449; DOI:
10.1021/ja00425a010
PDF
Preparation and properties of aluminum hydride
Frank M. Brower, Norman E. Matzek, Paul F. Reigler, Harold W. Rinn, Charles B. Roberts, Donald L. Schmidt, John A. Snover, and Kazuji Terada
pp 2450 - 2453; DOI:
10.1021/ja00425a011
PDF
The molecular structure of 1,1-bis(.eta.5-cyclopentadienyl)-2,3,4,5-tetraphenyltitanole and its hafnium analogue
Jerry L. Atwood, William E. Hunter, Helmut Alt, and Marvin D. Rausch
pp 2454 - 2459; DOI:
10.1021/ja00425a012
PDF
Charge transfer spectra and the alkylation of tetracyanoethylene with the organometallic derivatives of lead, tin, and mercury
Hugh C. Gardner and Jay K. Kochi
pp 2460 - 2469; DOI:
10.1021/ja00425a013
PDF
Thin layer spectroelectrochemical study of vitamin B12 and related cobalamin compounds in aqueous media
Thomas M. Kenyhercz, Thomas P. DeAngelis, Barbara J. Norris, William R. Heineman, and Harry B. Mark
pp 2469 - 2477; DOI:
10.1021/ja00425a014
PDF
Preparation and spectroscopic properties of cobalt(III) complexes containing phosphine ligands. The electronic structural description of side-bonded dioxygen
Vincent M. Miskowski, John L. Robbins, George S. Hammond, and Harry B. Gray
pp 2477 - 2483; DOI:
10.1021/ja00425a015
PDF
Bicapped tetrahedral, trigonal prismatic, and octahedral alternatives in main and transition group six-coordination
Roald Hoffmann, James M. Howell, and Angelo R. Rossi
pp 2484 - 2492; DOI:
10.1021/ja00425a016
PDF
Stable carbocations. 185. Carbon-fluorine spin-spin coupling in carbocations
Robert J. Spear, David A. Forsyth, and George A. Olah
pp 2493 - 2500; DOI:
10.1021/ja00425a017
PDF
Stable carbocations. 192. Acyclic carbodications
George A. Olah, James L. Grant, Robert J. Spear, J. Martin Bollinger, Art Serianz, and Gyorgy Sipos
pp 2501 - 2507; DOI:
10.1021/ja00425a018
PDF
Stable carbocations. 193. The structure of the 2-bicyclo[2.1.1]hexyl cations based on their proton and carbon-13 nuclear magnetic resonance spectroscopic study
George A. Olah, Gao Liang, and Satya P. Jindal
pp 2508 - 2511; DOI:
10.1021/ja00425a019
PDF
Stable carbocations. 194. Patterns of carbon-13 chemical shift response to substituent effects in arylcarbenium ions. The phenyl, phenylethynyl, and naphthyl systems
David A. Forsyth, Robert J. Spear, and George A. Olah
pp 2512 - 2518; DOI:
10.1021/ja00425a020
PDF
Mechanism of the olefin metathesis of 2,2'-divinylbiphenyl
Thomas J. Katz and Robert Rothchild
pp 2519 - 2526; DOI:
10.1021/ja00425a021
PDF
On the mechanism of cleavage of aryl alkanesulfonates by electron donors
J. C. Carnahan, W. D. Closson, J. R. Ganson, D. A. Juckett, and K. S. Quaal
pp 2526 - 2531; DOI:
10.1021/ja00425a022
PDF
Structural effects in solvolytic reactions. 14. Solvolysis of the 2-aryl-2-benzonorbornenyl p-nitrobenzoates. Application of the tool of increasing electron demand as a test for .pi. participation in the high exo:endo rate ratios
Herbert C. Brown, Shiro Ikegami, Kwang-Ting Liu, and Gary L. Tritle
pp 2531 - 2536; DOI:
10.1021/ja00425a023
PDF
General acid catalysis of the hydrolysis of acetal analogues of high basicity. The hydrolysis of 2-(substituted phenyl)-N,N-dimethyl-1,3-imidazolidines
Thomas H. Fife and J. E. C. Hutchins
pp 2536 - 2543; DOI:
10.1021/ja00425a024
PDF
Concerted vs. free radical migration mechanisms in the rearrangements of seminaphthalenes
Bernard Miller and Mohammed R. Saidi
pp 2544 - 2550; DOI:
10.1021/ja00425a025
PDF
Generation and characterization of a bridged 1,8-naphthoquinodimethane
C. R. Watson, R. M. Pagni, J. R. Dodd, and J. E. Bloor
pp 2551 - 2562; DOI:
10.1021/ja00425a026
PDF
Protonation kinetics and mechanism for 1,8-dihydroxyanthraquinone and anthraquinone anion radicals in dimethylformamide solvent
R. M. Wightman, J. R. Cockrell, Royce W. Murray, J. N. Burnett, and S. B. Jones
pp 2562 - 2570; DOI:
10.1021/ja00425a027
PDF
Anodic oxidation of phenolic compounds. 4. Scope and mechanism of the anodic intramolecular coupling of phenolic diarylalkanes
Ulf Palmquist, Anders Nilsson, Vernon D. Parker, and Alvin Ronlan
pp 2571 - 2580; DOI:
10.1021/ja00425a028
PDF
Dimer formation during reactions of benzylic halides with lithium naphthalene and mechanisms of dimer formation from reactions of benzylic halides with benzylic carbanions
Herman E. Zieger, Isaac Angres, and Donald Mathisen
pp 2580 - 2585; DOI:
10.1021/ja00425a029
PDF
Cheletropic reactions of fluorocarbenes with norbornadienes
Charles W. Jefford, Jiri Mareda, Jean C. E. Gehret, Tanda Kebengele, William David Graham, and Ulrich Burger
pp 2585 - 2593; DOI:
10.1021/ja00425a030
PDF
.beta.-Epimerization and .gamma.-hydrogen abstraction via homoenolate ions
A. Nickon, J. L. Lambert, J. E. Oliver, D. F. Covey, and J. Morgan
pp 2593 - 2599; DOI:
10.1021/ja00425a031
PDF
Photochemical rearrangements of some benzo C9H10 isomers
R. C. Hahn and R. P. Johnson
pp 2600 - 2604; DOI:
10.1021/ja00425a032
PDF
Photochemical transformations of small ring heterocyclic compounds. 75. Photochemistry of arylazirines in hydroxylic media
Albert Padwa, Jerald K. Rasmussen, and Alan Tremper
pp 2605 - 2614; DOI:
10.1021/ja00425a033
PDF
Sulfur isotope effects in substitution reactions of trimethylsulfonium ion
Ronald T. Hargreaves, Arthur M. Katz, and William H. Saunders
pp 2614 - 2617; DOI:
10.1021/ja00425a034
PDF
Alkaloids of Delphinium staphisagria. The structure and stereochemistry of delphisine, neoline, chasmanine, and homochasmanine
S. W. Pelletier, Z. Djarmati, S. Lajsic, and Wilson H. De Camp
pp 2617 - 2625; DOI:
10.1021/ja00425a035
PDF
Carbon-13 nuclear magnetic resonance: aconitine-type diterpenoid alkaloids from Aconitum and Delphinium species
S. W. Pelletier and Z. Djarmati
pp 2626 - 2636; DOI:
10.1021/ja00425a036
PDF
A carbon-13 nuclear magnetic resonance study of mollisin and its biosynthesis
Martha L. Casey, Robert C. Paulick, and Howard W. Whitlock
pp 2636 - 2640; DOI:
10.1021/ja00425a037
PDF
Heavy metal-nucleotide interactions. 8. Binding of cis-diammineplatinum(II) and ethylenediamineplatinum(II) to inosine, 1-methylinosine, and 5'-inosine monophosphate in aqueous solution
Grace Y. H. Chu and R. Stuart Tobias
pp 2641 - 2651; DOI:
10.1021/ja00425a038
PDF
Electrochemistry of vitamin B12. I. Role of the base-on/base-off reaction in the oxidoreduction mechanism of the B12r-B12s system
D. Lexa and J. M. Saveant
pp 2652 - 2658; DOI:
10.1021/ja00425a039
PDF
A circular dichroism study of the first excited electronic state in propylene episulfoxide
G. L. Bendazzoli, P. Palmieri, G. Gottarelli, I. Moretti, and G. Torre
pp 2659 - 2660; DOI:
10.1021/ja00425a040
PDF
Assignment of a methylated sulfur dioxide structure, [CH3O:S:O]+, to the species present in methyl fluoride-antimony pentafluoride-sulfur dioxide solutions and precipitation of a salt of [CH3O:S:O]+ upon addition of sulfur dioxide to methyl fluoride-antimony pentafluoride-sulfuryl chloride fluoride
Paul E. Peterson, Rhett Brockington, and D. Warren Vidrine
pp 2660 - 2661; DOI:
10.1021/ja00425a041
PDF
Friedel-Crafts chemistry. 10. Observation of the methyl fluoride-antimony pentafluoride complex in sulfuryl fluoride solution, an exceedingly low nucleophilicity solvent. Reinvestigation of the complex in sulfur dioxide and sulfuryl chloride fluoride solution showing O-methylation
George A. Olah, Daniel J. Donovan, and Henry C. Lin
pp 2661 - 2663; DOI:
10.1021/ja00425a042
PDF
Inversion at pyramidal oxygen and sulfur
S. Brownstein
pp 2663 - 2664; DOI:
10.1021/ja00425a043
PDF
Synthesis of a protein with the properties of the apolipoprotein C-I (ApoLP-Ser)
D. R. K. Harding, J. E. Battersby, D. R. Husbands, and W. S. Hancock
pp 2664 - 2665; DOI:
10.1021/ja00425a044
PDF
Low temperature studies on propionyl benzoyl peroxide and propionyl peroxide. The ethyl radical
J. Pacansky, G. P. Gardini, and Joachim Bargon
pp 2665 - 2666; DOI:
10.1021/ja00425a045
PDF
1,5,9-Cyclododecatriyne. Synthesis and conversion to intermediate 1,2:3,4:5,6-tricyclobutabenzene
A. J. Barkovich and K. P. C. Vollhardt
pp 2667 - 2668; DOI:
10.1021/ja00425a046
PDF
Topomerization of the (Z,E)-1,3-diphenyl-2-cyanoallyl anion
Gernot Boche, Diether Martens, and Hans Ulrich Wagner
pp 2668 - 2669; DOI:
10.1021/ja00425a047
PDF
On the donor-acceptor relationship in cyclic additions
Hiroshi Fujimoto, Satoshi Inagaki, and Kenichi Fukui
pp 2670 - 2671; DOI:
10.1021/ja00425a048
PDF
Dynamic nuclear magnetic resonance. An alternative method for acidity measurements. Application to superacids
Jean Sommer, Paul Rimmelin, and Torbjorn Drakenberg
pp 2671 - 2672; DOI:
10.1021/ja00425a049
PDF
Origin of the anomalous Soret spectra of carboxycytochrome P-450
Louise Karle Hanson, William A. Eaton, Stephen G. Sligar, I. C. Gunsalus, Martin Gouterman, and Charles R. Connell
pp 2672 - 2674; DOI:
10.1021/ja00425a050
PDF
Palladium assisted intramolecular amination of olefins. A new synthesis of indoles
L. S. Hegedus, G. F. Allen, and E. L. Waterman
pp 2674 - 2676; DOI:
10.1021/ja00425a051
PDF
A novel synthetic route to cyclopropane derivatives from olefins
Nariyoshi Kawabata, Michiharu Naka, and Shinzo Yamashita
pp 2676 - 2677; DOI:
10.1021/ja00425a052
PDF
Oligopeptides as potential antiaggregation agent for proteins: hemoglobin S gel and insulin dimer
Shigeo Kubota, Chiang Tung Chang, Tatsuya Samejima, and Jen Tsi Yang
pp 2677 - 2678; DOI:
10.1021/ja00425a053
PDF
Interpretation of mass spectroscopic fragmentation by state correlation diagrams
Christian Minot, Nguyen Trong Anh, and Lionel Salem
pp 2678 - 2681; DOI:
10.1021/ja00425a054
PDF
On the properties of fused 4n .pi.-electron systems. The 8,9-benzobicyclo[5.2.0]nonatetraenyl anion
Stuart W. Staley, Friedrich Heinrich, and Arnold W. Ordeval
pp 2681 - 2682; DOI:
10.1021/ja00425a055
PDF
Gas phase carboxylate anions from N-acetyl-p-nitrobenzyl amino acid esters
Costello L. Brown and Carcy L. Chan
pp 2682 - 2683; DOI:
10.1021/ja00425a056
PDF
Photochemical .gamma.-hydrogen abstraction in an .alpha.-acetylenic ketone. Comparison with an analogous enone
Paul S. Engel, Myron E. Schroeder, and Mary A. Schexnayder
pp 2683 - 2684; DOI:
10.1021/ja00425a057
PDF
Bovine serum albumin as a catalyst. 4. Identification of the active site
Ronald P. Taylor
pp 2684 - 2686; DOI:
10.1021/ja00425a058
PDF
First example of photochemical allowed [4.pi. + 2.sigma. + 2.sigma.] cycloaddition
Tadashi Sasaki, Ken Kanematsu, Ichiro Ando, and Osamu Yamashita
pp 2686 - 2687; DOI:
10.1021/ja00425a059
PDF
Book Reviews

pp 2687 - 2688; DOI:
10.1021/ja00425a600
PDF

Issue 10


Excited electronic states of ketene
Clifford E. Dykstra and Henry F. Schaefer
pp 2689 - 2695; DOI:
10.1021/ja00426a001
PDF
A configuration interaction treatment of 1E' trimethylenemethane
Weston T. Borden
pp 2695 - 2700; DOI:
10.1021/ja00426a002
PDF
Use of the point dipole approximation for nitroxide biradicals
William B. Gleason and Ronald E. Barnett
pp 2701 - 2705; DOI:
10.1021/ja00426a003
PDF
Photoionization mass spectrometry of 2-fluoropropane and 2,2-difluoropropane. A novel determination of the proton affinity of vinyl fluoride and 1,1-difluoroethylene
Ashley D. Williamson, P. R. LeBreton, and J. L. Beauchamp
pp 2705 - 2709; DOI:
10.1021/ja00426a004
PDF
Extrinsic circular dichroism in twisted nematic mesophases
F. D. Saeva and G. R. Olin
pp 2709 - 2711; DOI:
10.1021/ja00426a005
PDF
Effect of 1,3 carbon/carbon interactions on spin density in organic radicals
James Cessac and Nathan L. Bauld
pp 2712 - 2714; DOI:
10.1021/ja00426a006
PDF
Vibrational circular dichroism
L. A. Nafie, T. A. Keiderling, and P. J. Stephens
pp 2715 - 2723; DOI:
10.1021/ja00426a007
PDF
Nuclear magnetic resonance spectroscopy. Spin-lattice relaxation of the acetic acid carboxyl carbon
Devens Gust, Harry Pearson, Ian M. Armitage, and John D. Roberts
pp 2723 - 2726; DOI:
10.1021/ja00426a008
PDF
Carbon-13 spin-lattice relaxation in triethyl-n-hexylammonium triethyl-n-hexylboride, a viscous liquid salt
Warren T. Ford
pp 2727 - 2733; DOI:
10.1021/ja00426a009
PDF
Reassignment of the chirality to a series of 2,6-disubstituted spiro[3.3]heptanes by x-ray methods and implications thereof on empirical rules and theoretical models
L. A. Hulshof, Hans Wynberg, B. Van Dijk, and J. L. De Boer
pp 2733 - 2740; DOI:
10.1021/ja00426a010
PDF
Conformational analysis. CXI. The calculation of the structures and energies of disulfides by the molecular mechanics method
N. L. Allinger, Mary J. Hickey, and James Kao
pp 2741 - 2745; DOI:
10.1021/ja00426a011
PDF
Conformational analysis. CXII. Conformations, energies, and electronic absorption spectra of .alpha.,.beta.-unsaturated aldehydes and ketones
Tommy Liljefors and Norman L. Allinger
pp 2745 - 2749; DOI:
10.1021/ja00426a012
PDF
A new definition of Dewar-type resonance energies
Junichi Aihara
pp 2750 - 2758; DOI:
10.1021/ja00426a013
PDF
Preresonance Raman spectra of crystals of retinal isomers
Robert E. Cookingham, Aaron Lewis, David W. Collins, and Michael A. Marcus
pp 2759 - 2763; DOI:
10.1021/ja00426a014
PDF
Resonance Raman spectra of tetra(n-butylammonium) salts of the octachlorodirhenate(III) and octabromodirhenate(III) ions
Robin J. H. Clark and Malcolm L. Franks
pp 2763 - 2767; DOI:
10.1021/ja00426a015
PDF
Investigations of quadruple bonds by polarized crystal spectra. I. The interpretation of the spectrum of tetra(n-butylammonium) octachlorodirhenate. The disordered crystal structure
F. Albert Cotton, Bertram A. Frenz, B. Ray Stults, and Thomas R. Webb
pp 2768 - 2773; DOI:
10.1021/ja00426a016
PDF
Strontium titanate photoelectrodes. Efficient photoassisted electrolysis of water at zero applied potential
Mark S. Wrighton, Arthur B. Ellis, Peter T. Wolczanski, David L. Morse, Harmon B. Abrahamson, and David S. Ginley
pp 2774 - 2779; DOI:
10.1021/ja00426a017
PDF
A calorimetric and proton nuclear magnetic resonance investigation of the reaction of triphenyl phosphite with compounds of the type trans-dichloro(pyridine)(olefin)platinum(II)
Walter Partenheimer
pp 2779 - 2784; DOI:
10.1021/ja00426a018
PDF
Thermodynamic and spectroscopic studies of the reaction of Lewis bases with di-.mu.-chloro-tetracarbonyldirhodium(I)
Alan J. Pribula and Russell S. Drago
pp 2784 - 2788; DOI:
10.1021/ja00426a019
PDF
Mechanism of the thermal decomposition of carbonyl(.eta.5-cyclopentadienyl)triphenylphosphineiron(II) alkyl derivatives into carbonyl(.eta.5-cyclopentadienyl)hydrido(triphenylphosphine)iron(II) and olefin
D. L. Reger and E. C. Culbertson
pp 2789 - 2794; DOI:
10.1021/ja00426a020
PDF
Iron and cobalt complexes of thioacroleins derived from thietes
Donald C. Dittmer, Kozo Takahashi, Masaru Iwanami, Amy I. Tsai, Peter L. Chang, Bruce B. Blidner, and Ioannis K. Stamos
pp 2795 - 2803; DOI:
10.1021/ja00426a021
PDF
A proton nuclear magnetic resonance study of imidazole-iron bonding in low-spin ferric complexes with synthetic porphyrins
James D. Satterlee and Gerd N. La Mar
pp 2804 - 2808; DOI:
10.1021/ja00426a022
PDF
A resonance Raman study of the copper protein, hemocyanin. New evidence for the structure of the oxygen-binding site
Teresa B. Freedman, Joann S. Loehr, and Thomas M. Loehr
pp 2809 - 2815; DOI:
10.1021/ja00426a023
PDF
The chemical evolution of a nitrogenase model. XI. Reduction of molecular nitrogen in molybdocyanide systems
G. N. Schrauzer, P. R. Robinson, E. L. Moorehead, and T. M. Vickrey
pp 2815 - 2820; DOI:
10.1021/ja00426a024
PDF
Model studies on the coordination of copper in enzymes. IV. Structure and stability of cuprous complexes with sulfur-containing ligands
V. Vortisch, P. Kroneck, and P. Hemmerich
pp 2821 - 2826; DOI:
10.1021/ja00426a025
PDF
Electronic spectra of .alpha.,.beta.-unsaturated carbonyl compounds. I. An evaluation of increments characteristic of changes in configuration (cis/trans) and conformation (s-cis/s-trans) based on direct observation of the isomerization of enamino aldehydes and ketones
Janusz Dabrowski and Krystyna Kamienska-Trela
pp 2826 - 2834; DOI:
10.1021/ja00426a026
PDF
Three different consecutive orbital symmetry-controlled reactions in the novel stereospecific synthesis of 1-phenyl-4-(1-phenylethenyl)naphthalene. The reaction of 3,4-diphenylthiophene 1,1-dioxide with ethynylbenzene
R. G. Nelb and J. K. Stille
pp 2834 - 2839; DOI:
10.1021/ja00426a027
PDF
Arylcyclopropane photochemistry. The role of orbital overlap control in the photochemical cis-trans isomerization of arylcyclopropanes
Stephen S. Hixson and Joseph Borovsky
pp 2840 - 2847; DOI:
10.1021/ja00426a028
PDF
The gear effect. V. A model for conformational transmission
C. Roussel, A. Liden, M. Chanon, J. Metzger, and J. Sandstrom
pp 2847 - 2852; DOI:
10.1021/ja00426a029
PDF
The gear effect. VI. Conformational analysis of molecules with two interacting isopropyl groups
A. Liden, C. Roussel, T. Liljefors, M. Chanon, R. E. Carter, J. Metzger, and J. Sandstrom
pp 2853 - 2860; DOI:
10.1021/ja00426a030
PDF
Solvolysis mechanisms. Sulfur kinetic isotope effects in the hydrolysis of substituted benzyldimethylsulfonium tosylates
Michael P. Friedberger and Edward R. Thornton
pp 2861 - 2865; DOI:
10.1021/ja00426a031
PDF
Stereochemistry of solvolytic substitution of cyclopentyl p-bromobenzenesulfonate
K. Humski, V. Sendijarevic, and V. J. Shiner
pp 2865 - 2868; DOI:
10.1021/ja00426a032
PDF
The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
Robert E. Ireland, Richard H. Mueller, and Alvin K. Willard
pp 2868 - 2877; DOI:
10.1021/ja00426a033
PDF
Ozonolysis of trans-2,3-dichloro-2-butene. Isolation of .alpha.-chloro peroxides
Karl Griesbaum and Peter Hofmann
pp 2877 - 2881; DOI:
10.1021/ja00426a034
PDF
Electron bridges in the mechanisms of chromic acid oxidation of alcohols
H. Kwart and J. H. Nickle
pp 2881 - 2886; DOI:
10.1021/ja00426a035
PDF
The solvatochromic comparison method. 2. The .alpha.-scale of solvent hydrogen-bond donor (HBD) acidities
R. W. Taft and Mortimer J. Kamlet
pp 2886 - 2894; DOI:
10.1021/ja00426a036
PDF
Sulfuranes. XXI. Pseudorotation and fragmentation of perfluoropinacol orthosulfite. A tetraoxysulfurane
Gary W. Astrologes and J. C. Martin
pp 2895 - 2900; DOI:
10.1021/ja00426a037
PDF
A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions
Larry E. Overman
pp 2901 - 2910; DOI:
10.1021/ja00426a038
PDF
Chlorocyanation of barrelenes as a route to 1-cyanosemibullvalenes. Convenient introduction of an efficient .pi.-electron acceptor substituent and its influence on the Cope equilibrium
Leo A. Paquette and William E. Volz
pp 2910 - 2917; DOI:
10.1021/ja00426a039
PDF
Free radical studies of organophosphorus compounds. VI. Formation, permutation, and .beta. scission of tetraalkoxyphosphoranyl radicals, (RO)4P.cntdot.
Wesley G. Bentrude and Tae B. Min
pp 2918 - 2924; DOI:
10.1021/ja00426a040
PDF
Some caged polycyclic phosphoranes
Bradley S. Campbell, Norman J. De'Ath, Donald B. Denney, Dorothy Z. Denney, Irving S. Kipnis, and Tae B. Min
pp 2924 - 2927; DOI:
10.1021/ja00426a041
PDF
Phosphorescence of substituted benzophenones in solution. A probe of hydrocarbon chain conformation in three nonpolar solvents
Mitchell A. Winnik, Soumyendu N. Basu, Chung Kwong Lee, and Douglas S. Saunders
pp 2928 - 2935; DOI:
10.1021/ja00426a042
PDF
Photochemistry of polyenes. IX. Excitation, relaxation, and deactivation of dienes, trienes, and higher polyenes in the vitamin A series in the sensitized isomerization reaction
V. Ramamurthy and R. S. H. Liu
pp 2935 - 2942; DOI:
10.1021/ja00426a043
PDF
Kinetics and mechanisms of the reactions of organic cation radicals and dications. III. Arylation of aromatic hydrocarbon cation radicals
Ulla Svanholm and Vernon D. Parker
pp 2942 - 2946; DOI:
10.1021/ja00426a044
PDF
Heterodiene syntheses. XV. Kinetics of the reaction between 4-arylidene-5-pyrazolones and alkyl vinyl ethers: a frontier-controlled cycloaddition
G. Desimoni, A. Gamba, M. Monticelli, M. Nicola, and G. Tacconi
pp 2947 - 2952; DOI:
10.1021/ja00426a045
PDF
Solvolysis of .beta.-(7-norbornadienyl)ethyl p-bromobenzenesulfonate. A search for unsymmetrical [20 + 20 + 1+] laticyclic stabilization
Robert S. Bly, Ruta K. Bly, George B. Konizer, and Satya P. Jindal
pp 2953 - 2962; DOI:
10.1021/ja00426a046
PDF
Entering chloride kinetic isotope effects in protic and aprotic solvents
Thomas H. Cromartie and C. Gardner Swain
pp 2962 - 2965; DOI:
10.1021/ja00426a047
PDF
Comparison of the mechanisms of solvolysis and rearrangement of K-region vs. non-K-region arene oxides of phenanthrene. Comparative solvolytic rate constants of K-region and non-K-region arene oxides
Paula Y. Bruice, Thomas C. Bruice, Patrick M. Dansette, Hans G. Selander, Haruhiko Yagi, and Donald M. Jerina
pp 2965 - 2973; DOI:
10.1021/ja00426a048
PDF
Nucleophilic displacement on the arene oxides of phenanthrene
Paula Y. Bruice, Thomas C. Bruice, Haruhiko Yagi, and Donald M. Jerina
pp 2973 - 2981; DOI:
10.1021/ja00426a049
PDF
High-pressure studies. XX. Deacylation of acyl-.alpha.-chymotrypsins
Robert C. Neuman, Dennis Owen, and George D. Lockyer
pp 2982 - 2985; DOI:
10.1021/ja00426a050
PDF
Unusual metalloporphyrin derivative. Insertion of an ethoxycarbonylcarbene fragment into a nickel-nitrogen bond of nickel(II) meso-tetraphenylporphine. Crystal and molecular structure of the complex
Bernard Chevrier and Raymond Weiss
pp 2985 - 2990; DOI:
10.1021/ja00426a051
PDF
Conformational energy analysis of the molecule, luteinizing hormone-releasing hormone. 1. Native decapeptide
F. A. Momany
pp 2990 - 2996; DOI:
10.1021/ja00426a052
PDF
Conformational energy analysis of the molecule, luteinizing hormone-releasing hormone. 2. Tetrapeptide and decapeptide analogues
F. A. Momany
pp 2996 - 3000; DOI:
10.1021/ja00426a053
PDF
Glutathione. 13. Mechanism of thiol oxidation by diazenedicarboxylic acid derivatives
Edward M. Kosower and Hanna Kanety-Londner
pp 3001 - 3007; DOI:
10.1021/ja00426a054
PDF
Polygluosidic metabolites of Oleaceae. The chain sequence of oleoside aglucon, tyrosol, and glucose units in three metabolites from Fraxinus americana
Robert T. LaLonde, Chunfook Wong, and Amy I. M. Tsai
pp 3007 - 3013; DOI:
10.1021/ja00426a055
PDF
Mechanism of autoreduction of ferric porphyrins and the activation of coordinated ligands. 1. Detection of one-electron oxidized substrates
John Del Gaudio and Gerd N. La Mar
pp 3014 - 3015; DOI:
10.1021/ja00426a056
PDF
Cotton effect behavior of skewed 1,3-cyclohexadienes. Evidence for dominance of homoannular allylic chirality contributions
Albert W. Burgstahler, Leland O. Weigel, and Jacek K. Gawronski
pp 3015 - 3016; DOI:
10.1021/ja00426a057
PDF
Diffusion in mixed solvents. 3. The heat of mixing parameter and the Soret coefficient
P. A. Carapellucci
pp 3016 - 3018; DOI:
10.1021/ja00426a058
PDF
Nitroso compounds and azo dioxides as quenchers of singlet oxygen (1.DELTA.g) and sensitizer triplet states
Prithipal Singh and Edwin F. Ullman
pp 3018 - 3019; DOI:
10.1021/ja00426a059
PDF
Squalene biosynthesis. Role of the 3-methyl group in farnesyl pyrophosphate
Paul R. Ortiz de Montellano, Rafael Castillo, Wayne Vinson, and Jeng Shu Wei
pp 3020 - 3021; DOI:
10.1021/ja00426a060
PDF
2,3-Thiophyne
Manfred G. Reinecke and James G. Newsom
pp 3021 - 3022; DOI:
10.1021/ja00426a061
PDF
Synthesis of the non-tryptamine moiety of the aspidosperma-type indole alkaloids via cleavage of cyclic .alpha.-diketone monothioketal. An efficient synthesis of (dl)-quebrachamine and a formal synthesis of (dl)-tabersonine
Seiichi Takano, Susumi Hatakeyama, and Kunio Ogasawara
pp 3022 - 3023; DOI:
10.1021/ja00426a062
PDF
Nocardicin A and B, monocyclic .beta.-lactam antibiotics from a Nocardia species
Masashi Hashimoto, Tadaaki Komori, and Takashi Kamiya
pp 3023 - 3025; DOI:
10.1021/ja00426a063
PDF
Spectinomycin biosynthesis studied by carbon magnetic resonance spectroscopy
R. M. Stroshane, M. Taniguchi, K. L. Rinehart, J. P. Rolls, W. J. Haak, and B. A. Ruff
pp 3025 - 3027; DOI:
10.1021/ja00426a064
PDF
Electrochemical reduction and bonding in the oxygen (O2), sulfur (S2), and selenium (Se2) adducts of bis[1,2-ethanediylbis(diphenylphosphine)-P,P']iridium(1+)
Boon-Keng Teo, A. P. Ginsberg, and J. C. Calabrese
pp 3027 - 3028; DOI:
10.1021/ja00426a065
PDF
A remarkable epoxide opening. An expeditious synthesis of vernolepin and vernomenin
Samuel Danishefsky, Takeshi Kitahara, Paul F. Schuda, and Sarah J. Etheredge
pp 3028 - 3030; DOI:
10.1021/ja00426a066
PDF
The "methane carbon" stereochemistry of the acyclic oxadi-.pi.-methane photorearrangement
William G. Dauben, Gerrit Lodder, and Jeffrey D. Robbins
pp 3030 - 3031; DOI:
10.1021/ja00426a067
PDF
Enantioselective alkylation of cyclohexanone via chiral lithio-chelated enamines
A. I. Meyers, Donald R. Williams, and Melvin Druelinger
pp 3032 - 3033; DOI:
10.1021/ja00426a068
PDF
Novel aromatic systems. 5. The 1,2-dimethylbenzocyclobutadiene dication, an 8c-6.pi. Hueckeloid system
George A. Olah and Gao Liang
pp 3033 - 3034; DOI:
10.1021/ja00426a069
PDF
Fluorination at saturated carbon. 1. Direct substitution of adamantanes
Derek H. R. Barton, Robert H. Hesse, Roger E. Markwell, Maurice M. Pechet, and Hee T. Toh
pp 3034 - 3035; DOI:
10.1021/ja00426a070
PDF
Fluorination at saturated carbon. 2. Direct fluorination of steroids
Derek H. R. Barton, Robert H. Hesse, Roger E. Markwell, Maurice M. Pechet, and Shlomo Rozen
pp 3036 - 3037; DOI:
10.1021/ja00426a071
PDF
Thallium in organic synthesis. 43. Novel oxidative rearrangements with thallium(III) nitrate (TTN) in trimethyl orthoformate (TMOF)
Edward C. Taylor, R. L. Robey, K. T. Liu, B. Favre, H. T. Bozimo, R. A. Conley, C. S. Chiang, A. McKillop, and M. E. Ford
pp 3037 - 3038; DOI:
10.1021/ja00426a072
PDF
Total chromatographic optical resolutions of .alpha.-amino acid and ester salts through chiral recognition by a host covalently bound to polystyrene resin
G. Dotsevi, Y. Sogah, and D. J. Cram
pp 3038 - 3041; DOI:
10.1021/ja00426a073
PDF
Enhanced dimol emission of singlet oxygen by cyclic tertiary diamines
Carl F. Deneke and Norman I. Krinsky
pp 3041 - 3042; DOI:
10.1021/ja00426a074
PDF
Reduction of molecular nitrogen to hydrazine. Structure of a dinitrogen complex of bis(pentamethylcyclopentadienyl)zirconium(II) and an nitrogen-15 labeling study of its reaction with hydrogen chloride
Juan M. Manriquez, Robert D. Sanner, Richard E. Marsh, and John E. Bercaw
pp 3042 - 3044; DOI:
10.1021/ja00426a075
PDF
A new measurement of surface charge in model and biological lipid membranes
Betty J. Gaffney and Robert J. Mich
pp 3044 - 3045; DOI:
10.1021/ja00426a076
PDF
Stereospecific synthesis of penicillins. Conversion from a peptide precursor
Jack E. Baldwin, Michael A. Christie, Stephen B. Haber, and Lawrence I. Kruse
pp 3045 - 3047; DOI:
10.1021/ja00426a077
PDF
Molecular structure and copper(II)-mercaptide charge-transfer spectra of a novel Cu14[SC(CH3)2CH2NH2]12Cl cluster
H. J. Schugar, C. Ou, J. A. Thich, J. A. Potenza, R. A. Lalancette, and W. Furey
pp 3047 - 3048; DOI:
10.1021/ja00426a078
PDF
SN2-like transition for methyl transfer catalyzed by catechol-O-methyltransferase
Mohamed F. Hegazi, Ronald T. Borchardt, and Richard L. Schowen
pp 3048 - 3049; DOI:
10.1021/ja00426a079
PDF
The synthesis of zoanthoxanthins
Manfred Braun and George H. Buechi
pp 3049 - 3050; DOI:
10.1021/ja00426a080
PDF
The structure of the heteropolytungstate (NH4)17NA|NaW21Sb9O86|.cntdot.14H2O. An inorganic cryptate
Jean Fischer, Louis Ricard, and Raymond Weiss
pp 3050 - 3052; DOI:
10.1021/ja00426a081
PDF
Side-chain substituted 2,2,5,5-tetramethylpyrrolidine-N-oxyl (proxyl) nitroxides. A new series of lipid spin labels showing improved properties for the study of biological membranes
John F. Keana, Terry D. Lee, and Edward M. Bernard
pp 3052 - 3053; DOI:
10.1021/ja00426a082
PDF
Micelle catalyzed reactions are models of enzyme catalyzed reactions which show positive homotropic interactions
Dennis Piszkiewicz
pp 3053 - 3055; DOI:
10.1021/ja00426a083
PDF
Long-lived radical cations from mesocyclic dithioethers
W. K. Musker and T. L. Wolford
pp 3055 - 3056; DOI:
10.1021/ja00426a084
PDF
Book Reviews

pp 3057 - 3066; DOI:
10.1021/ja00426a600
PDF

Issue 11


Minimum energy coordinates. A relation between molecular vibrations and reaction coordinates
B. I. Swanson
pp 3067 - 3071; DOI:
10.1021/ja00427a001
PDF
Transition states for the abstraction reactions of triplet methylene with hydrogen and methane
Charles W. Bauschlicher, Charles F. Bender, and Henry F. Schaefer
pp 3072 - 3074; DOI:
10.1021/ja00427a002
PDF
Proton magnetic resonance spectra of cubane derivatives. I. Syntheses and spectra of mono- and 1,4-disubstituted cubanes
John T. Edward, Patrick G. Farrell, and Gordon E. Langford
pp 3075 - 3085; DOI:
10.1021/ja00427a003
PDF
Proton magnetic resonance spectra of cubane derivatives. II. Aromatic solvent-induced shifts
John T. Edward, Patrick G. Farrell, and Gordon E. Langford
pp 3085 - 3088; DOI:
10.1021/ja00427a004
PDF
Studies of the binding of calcium and lanthanum ions to D-lyxose and D-ribose in aqueous solutions using proton magnetic resonance
Robert E. Lenkinski and Jacques Reuben
pp 3089 - 3094; DOI:
10.1021/ja00427a005
PDF
Poly(.gamma.-benzyl L-glutamate) helix-coil transition. Pretransition phenomena in the liquid crystal phase
Russell W. Duke, Donald B. Du Pre, William A. Hines, and Edward T. Samulski
pp 3094 - 3101; DOI:
10.1021/ja00427a006
PDF
Thermodynamics of molecular association. 9. An NMR study of hydrogen bonding of chloroform and bromoform to di-n-octyl ether, di-n-octyl thioether, and di-n-octylmethylamine
D. E. Martire, J. P. Sheridan, J. W. King, and S. E. O'Donnell
pp 3101 - 3106; DOI:
10.1021/ja00427a007
PDF
Carbon-13-proton coupling constants in carbocations. II. Angular dependence of 1JCH in groups adjacent to cationic carbons. A new criterion for interpreting NMR spectra of carbocations
David P. Kelly, Graham R. Underwood, and Peter F. Barron
pp 3106 - 3111; DOI:
10.1021/ja00427a008
PDF
Correlation analysis of carbon-13 and fluorine-19 NMR substituent effects in arylplatinum complexes
D. Robert Coulson
pp 3111 - 3119; DOI:
10.1021/ja00427a009
PDF
New insights into the Lewis acidity of bis(hexafluoroacetylacetonato)copper(II) from EPR and calorimetry studies
David R. McMillin, Russell S. Drago, and James A. Nusz
pp 3120 - 3126; DOI:
10.1021/ja00427a010
PDF
Infrared, conductance, and kinetic evidence for alkali metal ion interactions with derivatives of manganese carbonylates
M. York Darensbourg, D. J. Darensbourg, Drusilla Burns, and D. A. Drew
pp 3127 - 3136; DOI:
10.1021/ja00427a011
PDF
Photochemistry of organic ions in the gas phase. Comparison of the gas phase photodissociation and solution absorption spectra of benzoyl cation, protonated benzene, and protonated mesitylene
B. S. Freiser and J. L. Beauchamp
pp 3136 - 3139; DOI:
10.1021/ja00427a012
PDF
Ab initio calculation of structure and inversion in difluoramine and dimethylamine
Steen Skaarup, Lawrence L. Griffin, and James E. Boggs
pp 3140 - 3143; DOI:
10.1021/ja00427a013
PDF
An ab initio molecular orbital study of polyoxides. 2. Fluorine and alkyl polyoxides (difluorine trioxide, difluorine tetroxide, dimethyl trioxide, bis(trifluoromethyl) trioxide)
Bozo Plesnicar, Darko Kocjan, Stanko Murovec, and Andrej Azman
pp 3143 - 3145; DOI:
10.1021/ja00427a014
PDF
The octant rule. 5. Nature of the third nodal surface. An understanding of "anti-octant" and front octant effects by a CNDO/S study of rotatory strengths of the carbonyl n .fwdarw. .pi.* transition
Thomas D. Bouman and David A. Lightner
pp 3145 - 3154; DOI:
10.1021/ja00427a015
PDF
Cis labilization of ligand dissociation. 2. Substitution and carbon-13 monoxide exchange reactions of cis monosubstituted manganese and rhenium carbonyl bromides
Jim D. Atwood and Theodore L. Brown
pp 3155 - 3159; DOI:
10.1021/ja00427a016
PDF
Cis labilization of ligand dissociation. 3. Survey of group 6 and 7 six-coordinate carbonyl compounds. The site preference model for ligand labilization effects
Jim D. Atwood and Theodore L. Brown
pp 3160 - 3166; DOI:
10.1021/ja00427a017
PDF
Synthesis using metal vapors. Silver carbonyls. Matrix infrared, ultraviolet-visible, and electron spin resonance spectra, structures, and bonding of silver tricarbonyl, silver dicarbonyl, silver monocarbonyl, and disilver hexacarbonyl
D. McIntosh and G. A. Ozin
pp 3167 - 3175; DOI:
10.1021/ja00427a018
PDF
Direct synthesis with vanadium atoms. II. Synthesis and characterization of vanadium hexadinitrogen, V(N2)6, in low-temperature matrices
Helmut Huber, T. A. Ford, W. Klotzbuecher, and G. A. Ozin
pp 3176 - 3178; DOI:
10.1021/ja00427a019
PDF
.pi.-Donor relaxation in the oxygen 1s ionization of carbonyl compounds
William L. Jolly and Theodore F. Schaaf
pp 3178 - 3181; DOI:
10.1021/ja00427a020
PDF
Bis(fulvalene)diiron, its mono- and dications. Intramolecular exchange interactions in a rigid system
Carole LeVanda, Klaus Bechgaard, Dwaine O. Cowan, Ulrich T. Mueller-Westerhoff, Peter Eilbracht, George A. Candela, and R. L. Collins
pp 3181 - 3187; DOI:
10.1021/ja00427a021
PDF
Photochemical and photophysical properties of rhodium(III) complexes. Aquation and luminescence resulting from ligand field excitation of pentaamminerhodium(III) complexes, Rh(NH3)5L3+
John D. Petersen, Richard J. Watts, and Peter C. Ford
pp 3188 - 3194; DOI:
10.1021/ja00427a022
PDF
The temperature dependence of the crystal and molecular structure of .DELTA.2,2'-bi-1,3-dithiole [TTF] 7,7,8,8-tetracyano-p-quinodimethane [TCNQ]
Arthur J. Schultz, Galen D. Stucky, Robert H. Blessing, and Philip Coppens
pp 3194 - 3201; DOI:
10.1021/ja00427a023
PDF
Oxygen complexation by cobaltous chelates of multidentate pyridyl-type ligands. Equilibriums, reactions, and electron structure of the complexes
Raymond F. Bogucki, George McLendon, and Arthur E. Martell
pp 3202 - 3205; DOI:
10.1021/ja00427a024
PDF
Infrared spectral studies of metal binding effects on the secondary structure of bean plastocyanin
Jeffrey W. Hare, Edward I. Solomon, and Harry B. Gray
pp 3205 - 3209; DOI:
10.1021/ja00427a025
PDF
Structural and electronic spectroscopic investigation of [(Me2N)3C3]2[Pt2Cl6]
Charles D. Cowman, Jack C. Thibeault, Ronald F. Ziolo, and Harry B. Gray
pp 3209 - 3214; DOI:
10.1021/ja00427a026
PDF
Confirmatory evidence for ortho metalation of coordinated triphenyl phosphite using carbon-13 nuclear magnetic resonance spectroscopy
Robert P. Stewart, Lester R. Isbrandt, James J. Benedict, and John G. Palmer
pp 3215 - 3219; DOI:
10.1021/ja00427a027
PDF
Triple-decker sandwiches
Joseph W. Lauher, Mihai Elian, Richard H. Summerville, and Roald Hoffmann
pp 3219 - 3224; DOI:
10.1021/ja00427a028
PDF
A heuristic solution to the functional group switching problem in organic synthesis
H. W. Whitlock
pp 3225 - 3233; DOI:
10.1021/ja00427a029
PDF
The solvatochromic comparison method. 3. Hydrogen bonding by some 2-nitroaniline derivatives
Tai Yokoyama, R. W. Taft, and Mortimer J. Kamlet
pp 3233 - 3237; DOI:
10.1021/ja00427a030
PDF
Phenolic and ketonic tautomers in polycyclic aromatic hydrocarbons
Melvin S. Newman, V. Sankaran, and Daniel R. Olson
pp 3237 - 3242; DOI:
10.1021/ja00427a031
PDF
Photophysical properties of .beta.-amino ketones. Investigation of tropinone, N-methyl-4-piperidone, and 1-diethylamino-3-butanone
Arthur M. Halpern and Arthur L. Lyons
pp 3242 - 3247; DOI:
10.1021/ja00427a032
PDF
A photoisomer of 1,3,6,8-tetraphenylcyclooctatetraene as a 1:1 mixture of 1,2,4,7-tetraphenylcyclooctatetraene and 2,5,7,8-tetraphenylbicyclo[4.2.0]octatriene in dynamic equilibrium. A structural enigma
Emil H. White, Robert L. Stern, Thomas J. Lobl, Stephen H. Smallcombe, Howard Maskill, and Earl W. Friend
pp 3247 - 3254; DOI:
10.1021/ja00427a033
PDF
Photochemical heavy-atom effect. VII. Steric and spin-orbital effects on the photodimerization of thianaphthene 1,1-dioxide
William W. Schloman and Benjamin F. Plummer
pp 3254 - 3262; DOI:
10.1021/ja00427a034
PDF
Photocyclization of diethylstilbestrol. Isolation of a stable, self-trapping dihydrophenanthrene intermediate
Thomas D. Doyle, Walter R. Benson, and Nicolae Filipescu
pp 3262 - 3267; DOI:
10.1021/ja00427a035
PDF
Probing the endo cavity of bicyclo[2.2.1]heptane systems. Imidogen proton exchange, nitrogen inversion, and amine quaternization of exo- and endo-2-dimethylaminonorbornane
F. M. Menger and T. E. Thanos
pp 3267 - 3272; DOI:
10.1021/ja00427a036
PDF
Homoallyl interaction between the nitrogen lone pair and the nonadjacent .pi.-bond in cyclic and bicyclic amines. V. The stereospecific orientation of the lone pair electrons in 7-azanorbornene derivatives
Kenichi Yoshikawa, Katsutoshi Bekki, Masanori Karatsu, Koji Toyoda, Tetsuki Kamio, and Isao Morishima
pp 3272 - 3281; DOI:
10.1021/ja00427a037
PDF
Conformational interconversions in hexahydropyridazine derivatives
S. F. Nelsen and G. R. Weisman
pp 3281 - 3287; DOI:
10.1021/ja00427a038
PDF
Catalysis of .alpha.-hydrogen exchange. XIX. Bifunctional catalysis of the dedeuteration of acetone-d6 by conformationally constrained derivatives of N,N-dimethyl-1,3-propanediamine
Jack Hine and Wu-Shyong Li
pp 3287 - 3294; DOI:
10.1021/ja00427a039
PDF
Electrophilic additions to acetylenes. V. Stereochemistry of the electrophilic addition of alkyl halides and hydrogen halides to phenyl-substituted acetylenes
Franco Marcuzzi and Giovanni Melloni
pp 3295 - 3300; DOI:
10.1021/ja00427a040
PDF
Dediazoniation of arenediazonium ions in homogeneous solution. 7. Intermediacy of the phenyl cation
Robert G. Bergstrom, Robin G. M. Landells, George H. Wahl, and H. Zollinger
pp 3301 - 3305; DOI:
10.1021/ja00427a041
PDF
Synthesis of .beta.-acylacrylic esters and .alpha.,.beta.-butenolides via .beta.-keto sulfoxide alkylation
Paul A. Bartlett
pp 3305 - 3312; DOI:
10.1021/ja00427a042
PDF
Organic sulfur mechanisms. 18. The sulfo-Cope rearrangement and other thermal reactions of unsaturated sulfonyl species
J. F. King and D. R. K. Harding
pp 3312 - 3316; DOI:
10.1021/ja00427a043
PDF
Reduction of dimensionality in radical decay kinetics induced by micellar systems
A. J. Frank, M. Graetzel, and John J. Kozak
pp 3317 - 3321; DOI:
10.1021/ja00427a044
PDF
Effect of crown ethers on rates and product distributions in the oligomerization of ethylene oxide in butanol
Jon A. Orvik
pp 3322 - 3325; DOI:
10.1021/ja00427a045
PDF
Solvent and substituent effects on the redox reactions of para-substituted tetraphenylporphyrin
Karl M. Kadish and Mark M. Morrison
pp 3326 - 3328; DOI:
10.1021/ja00427a046
PDF
Association of imidazoles and L-histidine with the pentacyanoiron(II) and -(III) moieties
Rex E. Shepherd
pp 3329 - 3335; DOI:
10.1021/ja00427a047
PDF
Electrostatic potentials of proteins. 1. Carboxypeptidase A
David M. Hayes and Peter A. Kollman
pp 3335 - 3345; DOI:
10.1021/ja00427a048
PDF
4'-Substituted nucleosides. 2. Synthesis of the nucleoside antibiotic nucleocidin
Ian D. Jenkins, Julien P. H. Verheyden, and John G. Moffatt
pp 3346 - 3357; DOI:
10.1021/ja00427a049
PDF
Topography of cyclodextrin inclusion complexes. 8. Crystal and molecular structure of the .alpha.-cyclodextrin-methanol-pentahydrate complex. Disorder in a hydrophobic cage
B. Hingerty and W. Saenger
pp 3357 - 3365; DOI:
10.1021/ja00427a050
PDF
Malformin C, a new metabolite of Aspergillus niger
Robert J. Anderegg, Klaus Biemann, George Buechi, and Mark Cushman
pp 3365 - 3370; DOI:
10.1021/ja00427a051
PDF
A carbon-13 nuclear magnetic resonance study of the biosynthesis of daunomycin from sodium acetate (carbon-13)
Robert C. Paulick, Martha L. Casey, and H. W. Whitlock
pp 3370 - 3371; DOI:
10.1021/ja00427a052
PDF
A stereospecific phenol coupling reaction
Ben Feringa and Hans Wynberg
pp 3372 - 3373; DOI:
10.1021/ja00427a053
PDF
Organoplatinum complexes related to the cyclodimerization of 1,3-dienes. Reactions of 2,3-dimethylbuta-1,3-diene and buta-1,3-diene with bis(cycloocta-1,5-diene)platinum or bis(ethylene)trimethylphosphineplatinum
Geoffrey K. Barker, Michael Green, Judith A. K. Howard, John L. Spencer, and F. Gordon A. Stone
pp 3373 - 3374; DOI:
10.1021/ja00427a054
PDF
Interactions of sugars with the sodium cation. Sensitivity of the sodium-23 nuclear magnetic resonance line width in pyridine solution
Christian Detellier, Jean Grandjean, and Pierre Laszlo
pp 3375 - 3376; DOI:
10.1021/ja00427a055
PDF
Prenyltransferase. The mechanism of the reaction
C. Dale Poulter, Dennis M. Satterwhite, and Hans C. Rilling
pp 3376 - 3377; DOI:
10.1021/ja00427a056
PDF
A formal regio- and stereoselective total synthesis of estrone. A convenient synthesis of D-homoestrone
Tetsuji Kametani, Hideo Nemoto, Hisako Ishikawa, Keiko Shiroyama, and Keiichiro Fukumoto
pp 3378 - 3379; DOI:
10.1021/ja00427a057
PDF
The total synthesis of (.+-.)-damsin
Richard A. Kretchmer and Wayne J. Thompson
pp 3379 - 3380; DOI:
10.1021/ja00427a058
PDF
A molecular orbital model for bridging regioselectivity in di-.pi.-methane rearrangements
Cielo Santiago and K. N. Houk
pp 3380 - 3381; DOI:
10.1021/ja00427a059
PDF
Silicon-carbon double bonds: new route, new substituents, new behavior
A. G. Brook and J. W. Harris
pp 3381 - 3383; DOI:
10.1021/ja00427a060
PDF
Lithium trisiamylborohydride. A new sterically hindered reagent for the reduction of cyclic ketones with exceptional stereoselectivity
S. Krishnamurthy and Herbert C. Brown
pp 3383 - 3384; DOI:
10.1021/ja00427a061
PDF
Synthetic methods for sesquiterpene .alpha.-methylene-.gamma.-lactones
M. F. Semmelhack and E. S. C. Wu
pp 3384 - 3386; DOI:
10.1021/ja00427a062
PDF
Entropic control of chemiluminescent reactions
Eduardo Lissi
pp 3386 - 3387; DOI:
10.1021/ja00427a063
PDF
Does the second law of thermodynamics restrict chemiluminescent reactions?
E. Bright Wilson
pp 3387 - 3388; DOI:
10.1021/ja00427a064
PDF
Conformational interconversion in the formation of .eta.5-cyclopentadienyl-.eta.3-allylmolybdenum carbonyl nitrosyl cations
J. W. Faller and A. M. Rosan
pp 3388 - 3389; DOI:
10.1021/ja00427a065
PDF
Chemistry of the macrocyclic cobalt(II) complex, [Co(C22H22N4)]. Reactions with halogens, molecular oxygen, alkynes, and nitriles
Marvin C. Weiss and Virgil L. Goedken
pp 3389 - 3392; DOI:
10.1021/ja00427a066
PDF
Solution photochemistry of diazoacetone. Wolff rearrangement and acetylmethylene
Heinz D. Roth and Marcia L. Manion
pp 3392 - 3393; DOI:
10.1021/ja00427a067
PDF
The thermal dimer and ketene cycloadduct of .DELTA.1,4-bicyclo[2.2.0]hexene
Kenneth B. Wiberg and Mark E. Jason
pp 3393 - 3395; DOI:
10.1021/ja00427a068
PDF
Dual pathways of heme protein model compound reactions with carbon monoxide
John Cannon, Jon Geibel, Martha Whipple, and T. G. Traylor
pp 3395 - 3396; DOI:
10.1021/ja00427a069
PDF
Stereospecific synthesis of isotopically labeled serine at carbon 3 and stereochemical analysis of D-serine dehydrase reaction
Yak-Fa Cheung and Christopher Walsh
pp 3397 - 3398; DOI:
10.1021/ja00427a070
PDF

Issue 12


Intrinsic acidities of carbon and nitrogen acids measured by gas phase proton transfer equilibriums. Substituent effects on the stabilities of gas phase carbanions and nitrogen anions
T. B. McMahon and P. Kebarle
pp 3399 - 3406; DOI:
10.1021/ja00428a001
PDF
Long-range carbon-carbon spin-spin coupling constants in carboxyl labeled aromatic carboxylic acids and dihydro aromatic carboxylic acids
James L. Marshall, Larry G. Faehl, Arthur M. Ihrig, and Michael Barfield
pp 3406 - 3410; DOI:
10.1021/ja00428a002
PDF
An experimental determination of the free energy of hydrogen bonding to an anion radical
Gerald R. Stevenson, Yvonne Fraticelli, and Rosario Concepcion
pp 3410 - 3414; DOI:
10.1021/ja00428a003
PDF
Theory of the chemical bond. 1. Implicit perturbation theory and dipole moment model for diatomic molecules
Robert L. Matcha and Stephen C. Jr. King
pp 3415 - 3420; DOI:
10.1021/ja00428a004
PDF
Theory of the chemical bond. 2. Dipole moments of alkali halide molecules, bond polarity, and differential charge affinity
Robert L. Matcha and Stephen C. King
pp 3420 - 3432; DOI:
10.1021/ja00428a005
PDF
A localized molecular orbital interpretation of the dipole moment derivatives of ammonia. A reexamination of the bond moment model description of infrared intensities
Roy E. Bruns, A. B. M. S. Bassi, and Paul M. Kuznesof
pp 3432 - 3435; DOI:
10.1021/ja00428a006
PDF
Molecular orbital theory of the electronic structure of molecules. 29. The interaction of molecular hydrogen with simple Lewis acids
John B. Collins, Paul v. R. Schleyer, J. Stephen Binkley, John A. Pople, and Leo Radom
pp 3436 - 3441; DOI:
10.1021/ja00428a007
PDF
A molecular orbital study of the role of borane(5) in the hydrolysis of tetrahydroborate ion
Irene M. Pepperberg, Thomas A. Halgren, and William N. Lipscomb
pp 3442 - 3451; DOI:
10.1021/ja00428a008
PDF
A theoretical study of the electronic structure of .beta.-substituted alkyl radicals
Angelo R. Rossi and David E. Wood
pp 3452 - 3456; DOI:
10.1021/ja00428a009
PDF
Electron paramagnetic resonance study of x-irradiated perfluoroneopentane
Moon B. Yim and David E. Wood
pp 3457 - 3460; DOI:
10.1021/ja00428a010
PDF
Single crystal EPR, zero-field ODMR, and phosphorescence studies of the T1 state of coumarin
Edward T. Harrigan, Asok Chakrabarti, and Noboru Hirota
pp 3460 - 3465; DOI:
10.1021/ja00428a011
PDF
Mean-squared optical anisotropies for alkanes containing a single trifunctional or tetrafunctional branch point
Wayne L. Mattice
pp 3466 - 3470; DOI:
10.1021/ja00428a012
PDF
Vacuum ultraviolet circular dichroism of .beta.-forming alkyl oligopeptides
James S. Balcerski, E. S. Pysh, G. M. Bonora, and C. Toniolo
pp 3470 - 3473; DOI:
10.1021/ja00428a013
PDF
Effect of additives on the reaction of monomeric silicon difluoride with 1,3-butadiene
O. F. Zeck, Y. Y. Su, G. P. Gennaro, and Y. N. Tang
pp 3474 - 3477; DOI:
10.1021/ja00428a014
PDF
Consideration of the mechanism of the metal catalyzed olefin metathesis reaction
Robert H. Grubbs, D. D. Carr, C. Hoppin, and P. L. Burk
pp 3478 - 3483; DOI:
10.1021/ja00428a015
PDF
Electronic effects in transition metal porphyrins. 2. The sensitivity of redox and ligand addition reactions in para-substituted tetraphenylporphyrin complexes of cobalt(II)
F. Ann Walker, D. Beroiz, and K. M. Kadish
pp 3484 - 3489; DOI:
10.1021/ja00428a016
PDF
Structural consequences of electron hyperdeficiency. Synthesis and crystal structure of an iron-cobalt metallocarborane having two closed polyhedra fused along an edge
William M. Maxwell, Ekk Sinn, and Russell N. Grimes
pp 3490 - 3495; DOI:
10.1021/ja00428a017
PDF
Chemistry of dicarbonyl .eta.5-cyclopentadienyl-.eta.1-allyl- and -.eta.2-olefiniron complexes. Preparation and cycloaddition reactions
A. Cutler, D. Ehntholt, W. P. Giering, P. Lennon, S. Raghu, A. Rosan, M. Rosenblum, J. Tancrede, and D. Wells
pp 3495 - 3507; DOI:
10.1021/ja00428a018
PDF
Hydrogen evolving systems. 1. The formation of molecular hydrogen from aqueous suspensions of iron(II) hydroxide and reactions with reducible substrates, including molecular nitrogen
G. N. Schrauzer and T. D. Guth
pp 3508 - 3513; DOI:
10.1021/ja00428a019
PDF
Hydrogen abstractions from an olefinic di(tertiary phosphine) promoted by complexes of divalent nickel, palladium, and platinum. Chelate .eta.3-allyl, .eta.1-allyl, and .eta.1-alkenyl complexes and the crystal and molecular structure of chelate .eta.1-allylpalladium(II) complex
M. A. Bennett, R. N. Johnson, G. B. Robertson, I. B. Tomkins, and P. O. Whimp
pp 3514 - 3523; DOI:
10.1021/ja00428a020
PDF
Large zero field splitting and subcritical antiferromagnetic interactions in hexakis(pyridine N-oxide)nickel diperchlorate
Richard L. Carlin, Charles J. O'Connor, and Som H. Bhatia
pp 3523 - 3526; DOI:
10.1021/ja00428a021
PDF
Preparation and characterization of chromium(II) molybdenum(II) tetraacetate. A compound containing a heteronuclear quadruple metal-metal bond
C. David Garner, Roger G. Senior, and Trevor J. King
pp 3526 - 3529; DOI:
10.1021/ja00428a022
PDF
Direct synthesis of fluorinated peroxides. 6. The addition of fluorinated hydroperoxides to perfluoro-2-azapropene and the preparation of the first perfluorooxazirine
E. R. Falardeau and D. D. DesMarteau
pp 3529 - 3532; DOI:
10.1021/ja00428a023
PDF
Pseudorotation in a sterically hindered phosphorane
Ivanka Szele, Steven J. Kubisen, and F. H. Westheimer
pp 3533 - 3536; DOI:
10.1021/ja00428a024
PDF
Conformational analysis by lanthanide shift reagents. Application of a topological approach to the study of the conformational equilibriums of 2-substituted 5-tert-butyl-2-oxo-1,3,2-dioxaphosphorinanes
Paolo Finocchiaro, Antonino Recca, Wesley G. Bentrude, Han-Wan Tan, and K. C. Yee
pp 3537 - 3541; DOI:
10.1021/ja00428a025
PDF
Aqueous solution conformation of rigid nucleosides and nucleotides
Che-Hung Lee and Ramaswamy H. Sarma
pp 3541 - 3548; DOI:
10.1021/ja00428a026
PDF
Laser photoionization and light-initiated redox reactions of tetramethylbenzidine in organic solvents and aqueous micellar solution
S. A. Alkaitis and M. Graetzel
pp 3549 - 3554; DOI:
10.1021/ja00428a027
PDF
Carbonyl group photochemistry via the enol form. Photoisomerization of 4-substituted 3-chromanones
Albert Padwa, Andrew Au, George A. Lee, and William Owens
pp 3555 - 3564; DOI:
10.1021/ja00428a028
PDF
Thiocarbonyl ylides. Photogeneration, rearrangement, and cycloaddition reactions
Arthur G. Schultz and Marvin B. DeTar
pp 3564 - 3572; DOI:
10.1021/ja00428a029
PDF
Photochemical synthesis. 64. Thione photochemistry. 21. Mechanism of the short-wavelength cycloaddition of adamantanethione: evidence for an excimer derived from S2
A. H. Lawrence, C. C. Liao, P. De Mayo, and V. Ramamurthy
pp 3572 - 3579; DOI:
10.1021/ja00428a030
PDF
Cyclobuta[1,2-d]benzyne. Generation, trapping, and dimerization to 2,3:6,7-dicyclobutabiphenylene
R. L. Hillard and K. P. C. Vollhardt
pp 3579 - 3582; DOI:
10.1021/ja00428a031
PDF
Carbon-13 nuclear magnetic resonance spectra of saturated heterocycles. 3. 1,3-Dithianes
Ernest L. Eliel, V. S. Rao, and Frank G. Riddell
pp 3583 - 3590; DOI:
10.1021/ja00428a032
PDF
Aminolysis of .alpha.-acetoxystyrenes. The pKa of acetophenones in aqueous solution
Michael Novak and Gordon M. Loudon
pp 3591 - 3597; DOI:
10.1021/ja00428a033
PDF
Intramolecular carboxyl group participation in the hydrolysis of an acyl imidazole
Jerry H. Smith
pp 3598 - 3601; DOI:
10.1021/ja00428a034
PDF
Mechanism of decarboxylation of 1,3-dimethylorotic acid. A model for orotidine 5'-phosphate decarboxylase
Peter Beak and Brock Siegel
pp 3601 - 3606; DOI:
10.1021/ja00428a035
PDF
Kinetics and mechanism of the outer-sphere oxidation of cyclohexanone by tris(polypyridyl) complexes of iron(III) and ruthenium(III)
Flora T. T. Ng and Patrick M. Henry
pp 3606 - 3611; DOI:
10.1021/ja00428a036
PDF
Studies of intramolecular excimer formation in dibenzyl ether, dibenzylamine, and its derivatives
Yung-Chyung Wang and Herbert Morawetz
pp 3611 - 3615; DOI:
10.1021/ja00428a037
PDF
Rearrangement kinetics of 10-aryl-10-thiaanthracenes
Fumio Ogura, W. Douglas Hounshell, Cynthia A. Maryanoff, W. Juergen Richter, and Kurt Mislow
pp 3615 - 3621; DOI:
10.1021/ja00428a038
PDF
Dipole stabilized carbanions: N-methyl carboxamides
Peter Beak, Gaylen R. Brubaker, and Robert F. Farney
pp 3621 - 3627; DOI:
10.1021/ja00428a039
PDF
Zinc-induced reactions of bromo ketones. 6,7-Dihydrodibenzo- and 6,7-dihydrodithieno[a,c]cyclooctene-5,8-diones and their dehydro derivatives
E. Ghera, Y. Gaoni, and S. Shoua
pp 3627 - 3632; DOI:
10.1021/ja00428a040
PDF
Nucleophilic substitution reactions of trans-3-methoxy-4'-substituted acrylophenones
Jee-Young H. Chu, B. S. R. Murty, and Leo Fedor
pp 3632 - 3635; DOI:
10.1021/ja00428a041
PDF
Homotropilidenes. 3. Synthetic and structural studies of dihydroazabullvalenes
Grant R. Krow, James Reilly, Der Min Fan, J. Marakowski, and Kermit C. Ramey
pp 3636 - 3640; DOI:
10.1021/ja00428a042
PDF
Synthesis and properties of deltic acid (dihydroxycyclopropenone) and the deltate ion
David Eggerding and Robert West
pp 3641 - 3644; DOI:
10.1021/ja00428a043
PDF
General methods of synthesis of indole alkaloids. 14. Short routes of construction of yohimboid and ajmalicinoid alkaloid systems and their carbon-13 nuclear magnetic resonance spectral analysis
Ernest Wenkert, Ching-Jer Chang, H. P. S. Chawla, David W. Cochran, Edward W. Hagaman, James C. King, and Kazuhiko Orito
pp 3645 - 3655; DOI:
10.1021/ja00428a044
PDF
Synthesis of thymidine oligonucleotides by phosphite triester intermediates
Robert L. Letsinger and Willie B. Lunsford
pp 3655 - 3661; DOI:
10.1021/ja00428a045
PDF
Synthesis of the witchweed seed germination stimulant (+)-strigol
J. B. Heather, R. S. D. Mittal, and Charles J. Sih
pp 3661 - 3669; DOI:
10.1021/ja00428a046
PDF
The chemistry of the Euphorbiaceae. A new diterpene from Croton californicus
Stephen R. Wilson, Leonard A. Neubert, and John C. Huffman
pp 3669 - 3674; DOI:
10.1021/ja00428a047
PDF
The triplet state of chlorophylls
Richard H. Clarke, Robert E. Connors, Tjeerd J. Schaafsma, Joop F. Kleibeuker, and Roelof J. Platenkamp
pp 3674 - 3677; DOI:
10.1021/ja00428a048
PDF
Studies on models for tetrahydrofolic acid. 7. Reactions and mechanisms of tetrahydroquinoxaline derivatives at the formaldehyde level of oxidation
T. H. Barrows, P. R. Farina, R. L. Chrzanowski, P. A. Benkovic, and S. J. Benkovic
pp 3678 - 3689; DOI:
10.1021/ja00428a049
PDF
Model studies on the mechanism of biotin dependent carboxylations
Harold Kohn
pp 3690 - 3694; DOI:
10.1021/ja00428a050
PDF
Conformational analyses of phosphocreatine and N-methylcreatine, a steric model for phosphocreatine
George L. Kenyon, Gary E. Struve, Peter A. Kollman, and Timothy I. Moder
pp 3695 - 3699; DOI:
10.1021/ja00428a051
PDF
Phosphorus-31 nuclear magnetic resonance studies on nucleoside phosphates in nonaqueous media
Richard J. Labotka, Thomas Glonek, and Terrell C. Myers
pp 3699 - 3704; DOI:
10.1021/ja00428a052
PDF
Phosphorus-31 chemical shift anisotropy in unsonicated phospholipid bilayers
Werner Niederberger and Joachim Seelig
pp 3704 - 3706; DOI:
10.1021/ja00428a053
PDF
Magnetic circular dichroism studies. 43. Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism
John Harold Dawson, R. H. Holm, James R. Trudell, Guenther Barth, Robert E. Linder, Edward Bunnenberg, Carl Djerassi, and S. C. Tang
pp 3707 - 3709; DOI:
10.1021/ja00428a054
PDF
Magnetic circular dichroism studies. 44. Chloroperoxidase. Evidence for P-450 type heme environment from magnetic circular dichroism spectroscopy
John Harold Dawson, James R. Trudell, Guenther Barth, Robert E. Linder, Edward Bunnenberg, Carl Djerassi, Robert Chiang, and L. P. Hager
pp 3709 - 3710; DOI:
10.1021/ja00428a055
PDF
CIDNP from Grignard reagents undergoing iron-catalyzed halogen-metal exchange
Ronald G. Lawler and Peter Livant
pp 3710 - 3712; DOI:
10.1021/ja00428a056
PDF
On the origin of chemically induced dynamic nuclear polarization [CIDNP] observed during the Grignard formation reaction
B. J. Schaart, H. W. H. J. Bodewitz, C. Blomberg, and F. Bickelhaupt
pp 3712 - 3713; DOI:
10.1021/ja00428a057
PDF
Ring-bridged bis(cyclopentadienyl)uranium(IV)halides
Cynthia A. Secaur, Victor W. Day, Richard D. Ernst, William J. Kennelly, and Tobin J. Marks
pp 3713 - 3715; DOI:
10.1021/ja00428a058
PDF
Tetramethylsilacyclopropene
Robert T. Conlin and Peter P. Gaspar
pp 3715 - 3716; DOI:
10.1021/ja00428a059
PDF
Oxygen binding to iron porphyrins. An ab initio calculation
A. Dedieu, M. M. Rohmer, M. Benard, and A. Veillard
pp 3717 - 3718; DOI:
10.1021/ja00428a060
PDF
High stereoselectivity in asymmetric Grignard cross-coupling catalyzed by nickel complexes of chiral (aminoalkylferrocenyl)phosphines
Tamio Hayashi, Masatoyo Tajika, Kohei Tamao, and Makoto Kumada
pp 3718 - 3719; DOI:
10.1021/ja00428a061
PDF
Mechanisms of photochemical reactions in solution. 80. Photochemical oxidation of tris(2,2'-bipyridyl)ruthenium(II) by molecular oxygen
John S. Winterle, David S. Kliger, and George S. Hammond
pp 3719 - 3721; DOI:
10.1021/ja00428a062
PDF
A novel rearrangement of angularly fused cyclobutanone. Stereospecific syntheses of intermediates to the diterpene alkaloids and the C20 gibberellins
Usha R. Ghatak, Baijayanti Sanyal, and Subrata Ghosh
pp 3721 - 3722; DOI:
10.1021/ja00428a063
PDF
Laser flash spectroscopy of tris(2,2'-bipyridine)ruthenium(II) in solution
R. Bensasson, C. Salet, and V. Balzani
pp 3722 - 3724; DOI:
10.1021/ja00428a064
PDF
A nonenzymic model intermediate for the coenzyme B12 dependent isomerization of methylmalonyl coenzyme A to succinyl coenzyme A
Paul Dowd and Moritz Shapiro
pp 3724 - 3725; DOI:
10.1021/ja00428a065
PDF
.alpha.-Aminoacrylate Schiff base in nonenzymic pyridoxal catalysis
Yoshiharu Karube and Yoshikazu Matsushima
pp 3725 - 3726; DOI:
10.1021/ja00428a066
PDF
Aqueous lanthanide shift reagents. 2. Interaction of the ethylenediaminetetraacetate chelates with the anions of salicylaldehyde and o-nitrophenol
Jacques Reuben
pp 3726 - 3728; DOI:
10.1021/ja00428a067
PDF
Chlorocyanoketene. A new .beta.-lactam synthesis
Harold W. Moore, Louis Hernandez, and Annlie Sing
pp 3728 - 3730; DOI:
10.1021/ja00428a068
PDF
Oscillations in chemical systems. 15. Deliberate generation of trigger waves of chemical reactivity
Kenneth Showalter and Richard M. Noyes
pp 3730 - 3731; DOI:
10.1021/ja00428a069
PDF
Laser photoelectron spectrometry of methylene(1-). Singlet-triplet splitting and electron affinity of methylene
P. F. Zittel, G. B. Ellison, S. V ONeil, E. Herbst, W. C. Lineberger, and W. P. Reinhardt
pp 3731 - 3732; DOI:
10.1021/ja00428a070
PDF
Oxidative coupling of optically active vinylcopper reagents. Stereospecific generation of a novel dissymmetric conjugated diene
R. Bruce Banks and H. M. Walborsky
pp 3732 - 3734; DOI:
10.1021/ja00428a071
PDF
Quantitative preparation and enthalpy of rearrangement of the sec-butyl cation
E. W. Bittner, E. M. Arnett, and M. Saunders
pp 3734 - 3735; DOI:
10.1021/ja00428a072
PDF
Conformational analysis of the triphosphate side chain of adenosine 5'-triphosphate. Phosphorus-proton nuclear Overhauser effects
Phillip A. Hart
pp 3735 - 3737; DOI:
10.1021/ja00428a073
PDF
Bifunctional proton transfer of the conjugate base of uracil compared with that of imidazole in aqueous solution
Kuang-Chou Chang and Ernest Grunwald
pp 3737 - 3738; DOI:
10.1021/ja00428a074
PDF
Synthesis of L-lysine. Simultaneous resolution/racemization of .alpha.-amino-.epsilon.-caprolactam
Stylianos Sifniades, William J. Boyle, and Jan F. Van Peppen
pp 3738 - 3739; DOI:
10.1021/ja00428a075
PDF
A stereoselective synthesis of the 24(R),25-dihydroxycholesterol side chain
John J. Partridge, Voldemar Toome, and Milan R. Uskokovic
pp 3739 - 3741; DOI:
10.1021/ja00428a076
PDF
A reaction proceeding through intramolecular phosphorylation of a urea. A chemical mechanism for enzymic carboxylation of biotin involving cleavage of adenosine 5'-triphosphate
Ronald Kluger and P. D. Adawadkar
pp 3741 - 3742; DOI:
10.1021/ja00428a077
PDF
Book Reviews

pp 3743 - 3744; DOI:
10.1021/ja00428a600
PDF

Issue 13


The principle of maximum overlap
F. Weinhold and T. K. Brunck
pp 3745 - 3749; DOI:
10.1021/ja00429a001
PDF
Fluorine-19 nuclear magnetic resonance studies of lipid bilayer systems. 1
M. P. N. Gent, I. M. Armitage, and J. H. Prestegard
pp 3749 - 3755; DOI:
10.1021/ja00429a002
PDF
Random-coil dimensions of poly(trimethylene oxide), an unusually compact chain molecule
Y. Takahashi and J. E. Mark
pp 3756 - 3760; DOI:
10.1021/ja00429a003
PDF
Nuclear magnetic resonance studies on pyridine dinucleotides. 4. Measurements of correlation times and the binding of oxidized nicotinamide adenine dinucleotide and adenosine 5'-monophosphate to lactate dehydrogenase as viewed by deuterium and carbon-13 relaxation times
Albert P. Zens, Patricia T. Fogle, Thomas A. Bryson, R. Bruce Dunlap, Ronald R. Fisher, and Paul D. Ellis
pp 3760 - 3764; DOI:
10.1021/ja00429a004
PDF
Structure of ethylene oxide oligomer complexes. 5. A complex of tetraethylene glycol dimethyl ether with cadmium chloride
Reikichi Iwamoto and Hiromutsu Wakano
pp 3764 - 3768; DOI:
10.1021/ja00429a005
PDF
Nuclear magnetic resonance study of the solution structures of some crown ethers and their cation complexes
David Live and Sunney I. Chan
pp 3769 - 3778; DOI:
10.1021/ja00429a006
PDF
Carbon-13 chemical shifts of the pentamethylene heterocycles
Joseph B. Lambert, Daniel A. Netzel, Hsiang-Ning Sun, and Karen K. Lilianstrom
pp 3778 - 3783; DOI:
10.1021/ja00429a007
PDF
Carbon-13 spin-lattice relaxation times of the pentamethylene heterocycles
Joseph B. Lambert and Daniel A. Netzel
pp 3783 - 3787; DOI:
10.1021/ja00429a008
PDF
Studies on the proton and carbon-13 contact shifts for .sigma.-bonded molecules. Stereospecific electron spin transmission in cyclic and bicyclic amines
Isao Morishima, Kenichi Yoshikawa, and Koji Okada
pp 3787 - 3793; DOI:
10.1021/ja00429a009
PDF
Stable hydrogen-bonded adducts of unstable polyhalogenated gem-diols
E. M. Schulman, O. D. Bonner, D. R. Schulman, and F. M. Laskovics
pp 3793 - 3799; DOI:
10.1021/ja00429a010
PDF
Borine carbonyl. Bonding and properties in the single-determinant approximation
W. C. Ermler, F. D. Glasser, and C. W. Kern
pp 3799 - 3807; DOI:
10.1021/ja00429a011
PDF
Free radical induced contact shift studies. 12. Stable free radicals as NMR spin probe for studying intermolecular interactions. 12. Carbon-13 contact shifts and electron spin delocalization induced by charge transfer interaction between halogenated molecules and stable free radicals
Isao Morishima, Toshiro Inubushi, and Teijiro Yonezawa
pp 3808 - 3814; DOI:
10.1021/ja00429a012
PDF
Photoelectron spectroscopy of carbonyls. Ureas, uracils, and thymine
D. Dougherty, K. Wittel, J. Meeks, and S. P. McGlynn
pp 3815 - 3820; DOI:
10.1021/ja00429a013
PDF
Reaction of atomic carbon with ethylene oxide. A MINDO/3 study of possible pathways
Juan M. Figuera, Philip B. Shevlin, and S. D. Worley
pp 3820 - 3825; DOI:
10.1021/ja00429a014
PDF
Conversion of hydroxyphenyl to phenoxyl radicals: a radiolytic study of the reduction of bromophenols in aqueous solution
Robert H. Schuler, P. Neta, Haya Zemel, and Richard W. Fessenden
pp 3825 - 3831; DOI:
10.1021/ja00429a015
PDF
Molecular orbital study of a cobalt reversible oxygen carrier
P. Fantucci and V. Valenti
pp 3832 - 3838; DOI:
10.1021/ja00429a016
PDF
Localized molecular orbital studies of chemical reactions. Deformation, rearrangement, and spin polarization of bonds involved in radical reactions
Shigeru Nagase, Kazuo Takatsuka, and Takayuki Fueno
pp 3838 - 3844; DOI:
10.1021/ja00429a017
PDF
Solid state polymerization of sulfur nitride (S2N2) to (SN)x
Marshall J. Cohen, A. F. Garito, A. J. Heeger, A. G. MacDiarmid, C. M. Mikulski, M. S. Saran, and J. Kleppinger
pp 3844 - 3848; DOI:
10.1021/ja00429a018
PDF
The identification of S5+ as a paramagnetic species in sulfur-oleum solutions by electron spin resonance
Hansen S. Low and Robert A. Beaudet
pp 3849 - 3852; DOI:
10.1021/ja00429a019
PDF
An investigation of the ring size of cyclopolyphosphines
Lawrence R. Smith and Jerry L. Mills
pp 3852 - 3857; DOI:
10.1021/ja00429a020
PDF
Nitrogen-15 nuclear magnetic resonance of organophosphorus compounds. Experimental determination and SCF-MO finite perturbation calculation of nitrogen-15-phosphorus-31 nuclear spin coupling constants in tris(dimethylamino)phosphine, -phosphine sulfide, and -phosphine oxide
George A. Gray and Thomas A. Albright
pp 3857 - 3861; DOI:
10.1021/ja00429a021
PDF
Nitrosyl transfer reactions
C. B. Ungermann and K. G. Caulton
pp 3862 - 3868; DOI:
10.1021/ja00429a022
PDF
Transition metal complexes of diazenes. 7. Photochemical substitution and [4 + 2] cycloadditions of a 1,1,1,1-tetracarbonyl-2,3,1-diazaferrole derivative with triphenylphosphine, diphenylacetylene, and 2,3-dimethylbutadiene
Angelo Albini and Horst Kisch
pp 3869 - 3874; DOI:
10.1021/ja00429a023
PDF
Carbon-hydrogen bond activation by transition metal complexes. Oxidative addition of alkyl methacrylate to ruthenium. The structure of hydrido(2-n-butoxycarbonylpropenyl-C1,O)tris(triphenylphosphine)ruthenium(II)
Sanshiro Komiya, Takashi Ito, Martin Cowie, Akio Yamamoto, and James A. Ibers
pp 3874 - 3884; DOI:
10.1021/ja00429a024
PDF
Quenching of triplet states by inorganic ions. Energy transfer and charge transfer mechanisms
A. Treinin and E. Hayon
pp 3884 - 3891; DOI:
10.1021/ja00429a025
PDF
Hydroxyl deformation frequencies as a probe of hydrogen bonding in lasalocid A (X-537A) and its sodium complex
George D. J. Phillies and H. Eugene Stanley
pp 3892 - 3897; DOI:
10.1021/ja00429a026
PDF
Wurster's blue as a fluorescence quencher for anthracene, perylene, and fluoranthene
Geoffrey W. Kinka and Larry R. Faulkner
pp 3897 - 3901; DOI:
10.1021/ja00429a027
PDF
Reactions of .pi.-allylnickel bromide complexes with quinones. Synthesis of isoprenoid quinones
L. S. Hegedus, B. R. Evans, D. E. Korte, E. L. Waterman, and K. Sjoberg
pp 3901 - 3909; DOI:
10.1021/ja00429a028
PDF
Regioselectivity in the reductive cleavage of syn- and anti-2-methylspiro[cyclopropane-1,1'-indene]. Elucidation of the role of steric effects
Stuart W. Staley, Marye Anne Fox, and Timothy K. Hirzel
pp 3910 - 3916; DOI:
10.1021/ja00429a029
PDF
Synthesis of electrically conductive organic solids
R. C. Wheland and J. L. Gillson
pp 3916 - 3925; DOI:
10.1021/ja00429a030
PDF
Correlation of electrical conductivity in charge-transfer complexes with redox potentials, steric factors, and heavy atom effects
Robert C. Wheland
pp 3926 - 3930; DOI:
10.1021/ja00429a031
PDF
Photochemistry of metal-metal bonded complexes. 5. Cleavage of the M-M bond in (OC)5M-M(CO)3L by irradiation into a low-lying M .fwdarw. L charge-transfer band
David L. Morse and Mark S. Wrighton
pp 3931 - 3934; DOI:
10.1021/ja00429a032
PDF
Excited states of bridged [14]annulenes with anthracene perimeter: absorption, polarized emission, linear dichroism, and magnetic circular dichroism
Jaroslav Kolc, Josef Michl, and Emanuel Vogel
pp 3935 - 3948; DOI:
10.1021/ja00429a033
PDF
Electronic excited states of D-(-)-luciferin and related chromophores
Jin Jung, Chen-An Chin, and Pill-Soon Song
pp 3949 - 3954; DOI:
10.1021/ja00429a034
PDF
The chemistry of an N5-methyl-1,5-dihydroflavin and its aminium cation radical
Cemal Kemal and Thomas C. Bruice
pp 3955 - 3964; DOI:
10.1021/ja00429a035
PDF
Conformational interconversions of cis,cis-cyclooctadiene-1,5
Otto Ermer
pp 3964 - 3970; DOI:
10.1021/ja00429a036
PDF
Conformations of glycyl-trans-4-fluoro-L-prolyl-L-tryptophan in aqueous solution
J. T. Gerig and R. S. McLeod
pp 3970 - 3975; DOI:
10.1021/ja00429a037
PDF
Photoisomerization kinetics of 11-cis-retinal, its Schiff base, and its protonated Schiff base
Eva L. Menger and David S. Kliger
pp 3975 - 3979; DOI:
10.1021/ja00429a038
PDF
Structural implications of the electronic spectra of quinacrine-deoxyribonucleic acid complexes in the ultraviolet region (250-300 nm)
M. Nastasi, J. M. Morris, D. M. Rayner, V. L. Seligy, A. G. Szabo, D. F. Williams, R. E. Williams, and R. W. Yip
pp 3979 - 3986; DOI:
10.1021/ja00429a039
PDF
Defined dimensional changes in enzyme substrates and cofactors. Synthesis of lin-benzoadenosine and enzymic evaluation of derivatives of the benzopurines
Nelson J. Leonard, Mark A. Sprecker, and Alan G. Morrice
pp 3987 - 3994; DOI:
10.1021/ja00429a040
PDF
The structure of vinyl bridged aluminum derivatives. A .pi.-electron stabilized electron deficient bridge bond
Michael J. Albright, William M. Butler, Thomas J. Anderson, Milton D. Glick, and John P. Oliver
pp 3995 - 3996; DOI:
10.1021/ja00429a041
PDF
Intersystem crossing in chromium(III) photochemistry
N. A. P. Kane-Maguire, D. E. Richardson, and C. G. Toney
pp 3996 - 3997; DOI:
10.1021/ja00429a042
PDF
Carbonyl compounds as primary products in the reduction of alkyldioxycobaloximes by sodium borohydride
Claude Bied-Charreton and Alain Gaudemer
pp 3997 - 3998; DOI:
10.1021/ja00429a043
PDF
Quantitative metal-ligand bond dissociation energies in the gas phase by ion cyclotron resonance spectroscopy
Reed R. Corderman and J. L. Beauchamp
pp 3998 - 4000; DOI:
10.1021/ja00429a044
PDF
Synthesis of di- and trinuclear methyl osmium complexes via cis-hydridomethyltetracarbonylosmium
John Evans, Stanley J. Okrasinski, Alan J. Pribula, and Jack R. Norton
pp 4000 - 4001; DOI:
10.1021/ja00429a045
PDF
Free energy profile for an electron transfer reaction
James K. Hurst
pp 4001 - 4003; DOI:
10.1021/ja00429a046
PDF
The stabilization of trivalent nickel in deprotonated-peptide complexes
Frank P. Bossu and Dale W. Margerum
pp 4003 - 4004; DOI:
10.1021/ja00429a047
PDF
The effect of crystal packing and defects on desolvation of hydrate crystals of caffeine and L-(-)-1,4-cyclohexadiene-1-alanine
Stephen R. Byrn and Chung-Tang Lin
pp 4004 - 4005; DOI:
10.1021/ja00429a048
PDF
Computer recognition of activity class from molecular transforms
Leonard J. Soltzberg and Charles L. Wilkins
pp 4006 - 4006; DOI:
10.1021/ja00429a049
PDF
Electron spin resonance spectrum of the perfluorocyclobutane radical anion
Masaru Shiotani and Ffrancon Williams
pp 4006 - 4008; DOI:
10.1021/ja00429a050
PDF
The role of the excited singlet state of dyes in dye sensitized photooxygenation reactions
R. S. Davidson and K. R. Trethewey
pp 4008 - 4009; DOI:
10.1021/ja00429a051
PDF
Assessment of the thioallylic rearrangement by a simplified technique for high-precision measurement of isotope effects
H. Kwart and J. Stanulonis
pp 4009 - 4010; DOI:
10.1021/ja00429a052
PDF
A new diisocyanide of novel ring structure from a sponge
J. T. Baker, R. J. Wells, W. E. Oberhaensli, and G. B. Hawes
pp 4010 - 4012; DOI:
10.1021/ja00429a053
PDF
Ozonolysis of fluoroalkenes: the synthesis, conformation, and microwave spectrum of 3-fluoro-1,2,4-trioxolane
R. P. Lattimer, U. Mazur, and R. L. Kuczkowski
pp 4012 - 4013; DOI:
10.1021/ja00429a054
PDF
Discandium and dititanium, their synthesis and optical spectra in low temperature argon matrices
R. Busby, W. Klotzbucher, and G. A. Ozin
pp 4013 - 4015; DOI:
10.1021/ja00429a055
PDF
Vinylmethylene and the ring opening of cyclopropene. Ab initio generalized valence bond and configuration interaction studies
James H. Davis, William A. Goddard, and Robert G. Bergman
pp 4015 - 4017; DOI:
10.1021/ja00429a056
PDF
The alleged existence of partially oxidized Mg[Pt(CN)4]Cl0.28.7H2O and the attempted preparation of the analogous beryllium(2+) and barium(2+) derivatives. A caveat
T. R. Koch, E. Gebert, and Jack M. Williams
pp 4017 - 4018; DOI:
10.1021/ja00429a057
PDF
Synthesis and binding characteristics of macrocyclic polyethers containing convergent methoxyaryl or phenolic groups
Karl E. Koenig, Roger C. Helgeson, and Donald J. Cram
pp 4018 - 4020; DOI:
10.1021/ja00429a058
PDF
Effect of pressure on the stereochemistry of ion pair collapse in the N-nitrosamide deamination
William J. Le Noble, Emil H. White, and Petar M. Dzadzic
pp 4020 - 4021; DOI:
10.1021/ja00429a059
PDF
The intramolecular hydrogen bond in malonaldehyde
Walter F. Rowe, Richard W. Duerst, and E. Bright Wilson
pp 4021 - 4023; DOI:
10.1021/ja00429a060
PDF
Kinetics of reduction of horse-heart ferricytochrome c by catechol
David L. Toppen
pp 4023 - 4024; DOI:
10.1021/ja00429a061
PDF
Biotin biosynthesis. 1. The incorporation of specifically tritiated dethiobiotin into biotin
Ronald J. Parry and Michael G. Kunitani
pp 4024 - 4026; DOI:
10.1021/ja00429a062
PDF
Book Reviews

pp 4026 - 4028; DOI:
10.1021/ja00429a600
PDF

Issue 14


Resonance Raman spectroelectrochemistry. 2. Scattering spectroscopy accompanying excitation of the lowest 2B1u excited state of the tetracyanoquinodimethane anion radical
David L. Jeanmaire and Richard P. Van Duyne
pp 4029 - 4033; DOI:
10.1021/ja00430a001
PDF
Resonance Raman spectroelectrochemistry. 3. Tunable dye laser excitation spectroscopy of the lowest 2B1u excited state of the tetracyanoquinodimethane anion radical
David L. Jeanmaire and Richard P. Van Duyne
pp 4034 - 4039; DOI:
10.1021/ja00430a002
PDF
The relation of heat of vaporization to surface tension for liquids of nonpolar spherical molecules
S. F. Abdulnur
pp 4039 - 4043; DOI:
10.1021/ja00430a003
PDF
Approximate selection rules for resonance Raman spectroscopy
J. M. Friedman and R. M. Hochstrasser
pp 4043 - 4048; DOI:
10.1021/ja00430a004
PDF
Group contributions to the electrostatic molecular potential
Rosanna Bonaccorsi, Eolo Scrocco, and Jacopo Tomasi
pp 4049 - 4054; DOI:
10.1021/ja00430a005
PDF
Orbital mixing rule
Satoshi Inagaki, Hiroshi Fujimoto, and Kenichi Fukui
pp 4054 - 4061; DOI:
10.1021/ja00430a006
PDF
Molecular orbital studies of the protonation of the methylanisoles
Raymond S. Greenberg, Maurice M. Bursey, and Lee G. Pedersen
pp 4061 - 4064; DOI:
10.1021/ja00430a007
PDF
A multisite model for lanthanide shift reagent coordination to monofunctional substrates. Effects of rotational and site averaging on shifts and relaxation rates
Robert E. Lenkinski and Jacques Reuben
pp 4065 - 4068; DOI:
10.1021/ja00430a008
PDF
Conformational studies of 1,3-dienes
Alain J. P. Devaquet, Roderick E. Townshend, and Warren J. Hehre
pp 4068 - 4076; DOI:
10.1021/ja00430a009
PDF
Nucleophilic additions to phosphine oxides. A model study of anionic trigonal bipyramidal intermediates
Carol A. Deakyne and Leland C. Allen
pp 4076 - 4080; DOI:
10.1021/ja00430a010
PDF
Carbon-13 nuclear magnetic resonance and ring currents in vinyl cross-linked annulenes
Barry M. Trost and William B. Herdle
pp 4080 - 4086; DOI:
10.1021/ja00430a011
PDF
Oxidation of polycyclic arenes in antimony(V) fluoride/sulfuryl chloride fluoride. Formation of arene dications and observation of electron exchange with radical cations based on carbon-13 nuclear magnetic resonance studies
David A. Forsyth and George A. Olah
pp 4086 - 4090; DOI:
10.1021/ja00430a012
PDF
Intermolecular association in adenosine 5'-monophosphate. A deuterium nuclear magnetic resonance investigation
William Egan
pp 4091 - 4093; DOI:
10.1021/ja00430a013
PDF
Electron nuclear double resonance on heme compounds. ENDOR from the iron ligands in protohemin chloride and protohemin bromide
H. L. Van Camp, C. P. Scholes, and C. F. Mulks
pp 4094 - 4098; DOI:
10.1021/ja00430a014
PDF
Structure of lithium dimethylcuprate and mechanism of the Corey-Posner reaction
Ralph G. Pearson and Carl D. Gregory
pp 4098 - 4104; DOI:
10.1021/ja00430a015
PDF
Photosubstitution reactivity of a series of pentacarbonylpyridinotungsten(0) complexes having ligand field or charge-transfer lowest excited states
Mark S. Wrighton, Harmon B. Abrahamson, and David L. Morse
pp 4105 - 4109; DOI:
10.1021/ja00430a016
PDF
Synthesis and reactions of cis- and trans-W(CO)4(13CO)(L) compounds
B. Duane Dombek and Robert J. Angelici
pp 4110 - 4115; DOI:
10.1021/ja00430a017
PDF
The mechanism of carbonylation of halo(bis ligand)organoplatinum(II), -palladium(II), and -nickel(II) complexes
Philip E. Garrou and Richard F. Heck
pp 4115 - 4127; DOI:
10.1021/ja00430a018
PDF
The oxidation of manganese(II) by chromium(VI) in the presence of oxalate ion
Charles F. Huber and G. P. Haight
pp 4128 - 4131; DOI:
10.1021/ja00430a019
PDF
Tripositive mercury. Low temperature electrochemical oxidation of 1,4,8,11-tetraazacyclotetradecanemercury(II) tetrafluoroborate
Richard L. Deming, A. L. Allred, Alan R. Dahl, Albert W. Herlinger, and Mark O. Kestner
pp 4132 - 4137; DOI:
10.1021/ja00430a020
PDF
Synthesis and structure of the hydroxyl derivative of "titanocene"
Lloyd J. Guggenberger and Fred N. Tebbe
pp 4137 - 4143; DOI:
10.1021/ja00430a021
PDF
Phosphorus-nitrogen compounds. 25. Substituent exchange and carbon-oxygen bond cleavage with aryloxycyclophosphazenes
H. R. Allcock and L. A. Smeltz
pp 4143 - 4149; DOI:
10.1021/ja00430a022
PDF
Labilization of the 3-carbon hydrogens in chelated (2S)-aspartic acid and erythro- and threo-(2S)-3-methylaspartic acid
Judith A. McClarin, Larry A. Dressel, and J. Ivan Legg
pp 4150 - 4154; DOI:
10.1021/ja00430a023
PDF
Rate-determining processes in the hydrolysis of maleanilinic acids in acidic solutions
Ronald Kluger and C. H. Lam
pp 4154 - 4158; DOI:
10.1021/ja00430a024
PDF
Carbenoids with neighboring heteroatoms. V. Nucleophilic reactions of lithium carbenoids of the exo-8-halo-3,5-dioxabicyclo[5.1.0]octyl system
K. Grant Taylor and James Chaney
pp 4158 - 4163; DOI:
10.1021/ja00430a025
PDF
Carbenoids with neighboring heteroatoms. VI. Electrophilic reactions of .alpha.-chlorocyclopropyllithium compounds which are epimeric at the carbenoid center
K. Grant Taylor, James Chaney, and Joseph C. Deck
pp 4163 - 4167; DOI:
10.1021/ja00430a026
PDF
Reactions of palladium(II) chloride with aziridine rings. Catalytic rearrangement of N-carbethoxy-8-azabicyclo[5.1.0]oct-3-ene to N-carbethoxynortropidine
George R. Wiger and Michael F. Rettig
pp 4168 - 4174; DOI:
10.1021/ja00430a027
PDF
Trifluoroethylamine-catalyzed isomerization of .beta.,.gamma.-unsaturated ketones. Nucleophilic catalysis via Schiff base formation
Ralph M. Pollack and Robert H. Kayser
pp 4174 - 4181; DOI:
10.1021/ja00430a028
PDF
The photochemistry of substituted bicyclo[3.2.1]octan-6-ones. Chair-chair conformational inversion of biradical intermediates
William C. Agosta and Steven Wolff
pp 4182 - 4188; DOI:
10.1021/ja00430a029
PDF
Quantitative aspects of the photochemistry of isomeric retinals and visual pigments
Walter H. Waddell, Rosalie Crouch, Koji Nakanishi, and Nicholas J. Turro
pp 4189 - 4192; DOI:
10.1021/ja00430a030
PDF
Photooxidation of olefins sensitized by .alpha.-diketones and by benzophenone. A practical epoxidation method with biacetyl
Nobujiro Shimizu and Paul D. Bartlett
pp 4193 - 4200; DOI:
10.1021/ja00430a031
PDF
Kinetic secondary deuterium isotope effects for substituted benzaldehyde cyanohydrin formation
Valkiria Okano, Luciano Do Amaral, and E. H. Cordes
pp 4201 - 4203; DOI:
10.1021/ja00430a032
PDF
.pi.-Electron steric effects on conformational equilibria
Joseph B. Lambert and Richard R. Clikeman
pp 4203 - 4211; DOI:
10.1021/ja00430a033
PDF
Effect of solvents and counterions on the equilibrium and kinetics of disproportionation of tetracenide radical ions
G. Levin and M. Szwarc
pp 4211 - 4216; DOI:
10.1021/ja00430a034
PDF
Structural effects in solvolytic reactions. 15. Solvolysis of 1-arylcyclohexyl and 1-arylcyclohex-2-enyl p-nitrobenzoates. Effect of increasing electron demand on the contributions of an allylic double bond in the solvolysis of tertiary cyclohex-2-enyl derivatives
Herbert C. Brown, M. Ravindranathan, and Morris M. Rho
pp 4216 - 4218; DOI:
10.1021/ja00430a035
PDF
Low-energy singlet-triplet and singlet-singlet transitions in cycloalkenes
Isidor Sauers, Loretta A. Grezzo, Stuart W. Staley, and John H. Moore
pp 4218 - 4222; DOI:
10.1021/ja00430a036
PDF
Thermodynamic measurements on unsubstituted cyclopropenyl radical and anion, and derivatives, by second harmonic alternating current voltammetry of cyclopropenyl cations
Michael R. Wasielewski and Ronald Breslow
pp 4222 - 4229; DOI:
10.1021/ja00430a037
PDF
Flowing afterglow studies of the reactions of hydroxide, amide, and methoxide ions with ethylene oxide and propylene oxide
Veronica M. Bierbaum, C. H. DePuy, R. H. Shapiro, and John H. Stewart
pp 4229 - 4235; DOI:
10.1021/ja00430a038
PDF
Benzidine rearrangement in the presence and absence of micelles. Evidence for rate-limiting proton transfer
Clifford A. Bunton and Ronald J. Rubin
pp 4236 - 4246; DOI:
10.1021/ja00430a039
PDF
Aromatic protodealkylation. Evidence for an A-1 reaction mechanism
Tomasz A. Modro and Keith Yates
pp 4247 - 4250; DOI:
10.1021/ja00430a040
PDF
Contact vs. pseudocontact contributions to lanthanide-induced shifts in the nuclear magnetic resonance spectra of isoquinoline and of endo-norbornenol
Otto A. Gansow, Paul A. Loeffler, Raymond E. Davis, Robert E. Lenkinski, and M. Robert Wilcott
pp 4250 - 4258; DOI:
10.1021/ja00430a041
PDF
Relative nucleophilicity of common nucleophiles toward sulfinyl sulfur. Comparison of the relative reactivity of different nucleophiles toward sulfinyl vs. sulfonyl sulfur
John L. Kice and Lawrence F. Mullan
pp 4259 - 4268; DOI:
10.1021/ja00430a042
PDF
Insertion of sulfonylnitrenes into the carbon-hydrogen bonds of saturated hydrocarbons. Acid-catalyzed thermolysis of N-alkyl sulfonamides
David S. Breslow, Eleanor I. Edwards, Ernest C. Linsay, and Hisanori Omura
pp 4268 - 4275; DOI:
10.1021/ja00430a043
PDF
Steric acceleration of lactonization reaction: an analysis of "stereopopulation control"
Claudia Danforth, Allen W. Nicholson, John C. James, and Gordon M. Loudon
pp 4275 - 4281; DOI:
10.1021/ja00430a044
PDF
Comparison of stereopopulation control with conventional steric effects in lactonization of hydrocoumarinic acids
Randall E. Winans and Charles F. Wilcox
pp 4281 - 4285; DOI:
10.1021/ja00430a045
PDF
Nuclear magnetic resonance studies on pyridine dinucleotides. 6. Dependence of the carbon-13 spin-lattice relaxation time of 1-methylnicotinamide and nicotinamide adenine dinucleotide as a function of pD and phosphate concentration
Robert M. Riddle, Taffy J. Williams, Thomas A. Bryson, R. Bruce Dunlap, Ronald R. Fisher, and Paul D. Ellis
pp 4286 - 4290; DOI:
10.1021/ja00430a046
PDF
Optical properties of sugars. 3. Circular dichroism of aldo- and ketopyranose anomers
Richard G. Nelson and W. Curtis Johnson
pp 4290 - 4295; DOI:
10.1021/ja00430a047
PDF
Optical properties of sugars. 4. Circular dichroism of methyl aldopyranosides
Richard G. Nelson and W. Curtis Johnson
pp 4296 - 4301; DOI:
10.1021/ja00430a048
PDF
Biosynthesis of ophiocarpine. Introduction of a stereospecific label through transannular cyclization
Peter W. Jeffs and Jeffrey D. Scharver
pp 4301 - 4310; DOI:
10.1021/ja00430a049
PDF
Syntheses from perfluoro-2-butyne. 2. Perfluorooctamethylcubane, perfluorooctamethylcuneane, and perfluorooctamethylcyclooctatetraene
Lorenzo F. Pelosi and William T. Miller
pp 4311 - 4312; DOI:
10.1021/ja00430a050
PDF
The stereoselective total synthesis of pseudoguaianolides: confertin
James A. Marshall and Robert H. Ellison
pp 4312 - 4313; DOI:
10.1021/ja00430a051
PDF
New synthetic reactions. Oxidative seco rearrangement
Barry M. Trost and Kunio Hiroi
pp 4313 - 4315; DOI:
10.1021/ja00430a052
PDF
Acid-base catalysis and autocatalysis of a dehydrochlorination
Thomas I. Crowell and Lucy Hwang
pp 4315 - 4316; DOI:
10.1021/ja00430a053
PDF
Stereoselectivity of hydrogen transfer in the photochemical isomerization of bicyclo[3.2.1]octan-6-one. Evidence for a stereoelectronic effect
William C. Agosta and Steven Wolff
pp 4316 - 4317; DOI:
10.1021/ja00430a054
PDF
Kinetic ambiguity between the Id and D mechanisms in ligand substitution reactions. The intimate mechanism for axial base-ligand exchange reactions in alkyl(base)cobaloximes and related species
J. A. Ewen and D. J. Darensbourg
pp 4317 - 4319; DOI:
10.1021/ja00430a055
PDF
Photochemistry of alkyl halides. 3. Generation of vinyl cations
Steven A. McNeely and Paul J. Kropp
pp 4319 - 4320; DOI:
10.1021/ja00430a056
PDF
Thermolysis and photochemistry of cyclic azo compounds. A novel chemiluminescent reaction and alternate route to Dewar benzene
Nicholas J. Turro, Carl A. Renner, Walter H. Waddell, and Thomas J. Katz
pp 4320 - 4322; DOI:
10.1021/ja00430a057
PDF
Redox properties of copper-thiaether complexes. Comparison to blue copper protein behavior
E. R. Dockal, Thomas E. Jones, W. F. Sokol, R. J. Engerer, D. B. Rorabacher, and L. A. Ochrymowycz
pp 4322 - 4324; DOI:
10.1021/ja00430a058
PDF
The photochemical synthesis of a tricyclo[2.2.0.02,5]hexane
Edward C. Alexander and Joseph Uliana
pp 4324 - 4325; DOI:
10.1021/ja00430a059
PDF
An extraordinarily facile sulfoxide automerization
James A. Ross, Reginald P. Seiders, and David M. Lemal
pp 4325 - 4327; DOI:
10.1021/ja00430a060
PDF
Novel aromatic system. 6. The bis(tetramethylhomocyclopropenyl) dication
George A. Olah, Gao Liang, Leo A. Paquette, and William P. Melega
pp 4327 - 4329; DOI:
10.1021/ja00430a061
PDF
A trans cyclohexene
R. Bonneau, J. Joussot-Dubien, L. Salem, and A. J. Yarwood
pp 4329 - 4330; DOI:
10.1021/ja00430a062
PDF
Experimental evidence in support of oxyphosphorane intermediates in reactions of cyclic phosphate esters
Fausto Ramirez, Mark Nowakowski, and James F. Marecek
pp 4330 - 4332; DOI:
10.1021/ja00430a063
PDF
Stabilization of perpendicular olefins. The structures and rotational barriers of singlet and triplet 1,1-dilithioethylenes
Yitzhak Apeloig, Paul v. R. Schleyer, J. Stephen Binkley, and John A. Pople
pp 4332 - 4334; DOI:
10.1021/ja00430a064
PDF
Evidence on internal return from isotope effects in the hydrogen-deuterium exchange of benzyl sulfoxides. A caveat re-interpretation of isotopic exchange rates
Robert R. Fraser and L. K. Ng
pp 4334 - 4336; DOI:
10.1021/ja00430a065
PDF
Intramolecular hydrolysis of a methyl ester by substrate bound metal hydroxide
Michael A. Wells, Gary A. Rogers, and Thomas C. Bruice
pp 4336 - 4338; DOI:
10.1021/ja00430a066
PDF
The diphenylvinylene carbonate-diene exciplex. Solvent dependence of radiative and nonradiative decay processes
Frederick D. Lewis and Charles E. Hoyle
pp 4338 - 4340; DOI:
10.1021/ja00430a067
PDF
Synthesis of ternary metal sulfide arrays
J. C. Huffman, R. S. Roth, and A. R. Siedle
pp 4340 - 4341; DOI:
10.1021/ja00430a068
PDF
Heavy-ion radiolysis of solid glycine
T. L. Tung, G. P. Welch, H. A. Sokol, W. Bennett-Corniea, and W. M. Garrison
pp 4341 - 4342; DOI:
10.1021/ja00430a069
PDF
Formation of highly conducting organic salts by photooxidation of heterofulvalene .pi.-donors in halocarbon solutions
B. A. Scott, F. B. Kaufman, and E. M. Engler
pp 4342 - 4344; DOI:
10.1021/ja00430a070
PDF

Issue 15


Oscillations in chemical systems. 13. A detailed molecular mechanism for the Bray-Liebhafsky reaction of iodate and hydrogen peroxide
Kumud R. Sharma and Richard M. Noyes
pp 4345 - 4361; DOI:
10.1021/ja00431a001
PDF
A simple theoretical molecular orbital model for five-membered heterocycles
N. D. Epiotis, W. R. Cherry, F. Bernardi, and W. J. Hehre
pp 4361 - 4364; DOI:
10.1021/ja00431a002
PDF
On the aromaticity of phospholes and arsoles
Nicolaos D. Epiotis and William Cherry
pp 4365 - 4370; DOI:
10.1021/ja00431a003
PDF
Theoretical approaches to rearrangements in carbocations. 3. The homocyclopropenyl cation
Warren J. Hehre and Alain J. P. Devaquet
pp 4370 - 4377; DOI:
10.1021/ja00431a004
PDF
Molecular orbital theory of the electronic structure of organic compounds. 28. Geometries and energies of singlet and triplet states of the C3H2 hydrocarbons
W. J. Hehre, J. A. Pople, W. A. Lathan, L. Radom, E. Wasserman, and Z. R. Wasserman
pp 4378 - 4383; DOI:
10.1021/ja00431a005
PDF
One- and two-configuration Hartree-Fock limit predictions for the singlet-triplet separation in methylene and silylene
James H. Meadows and Henry F. Schaefer
pp 4383 - 4386; DOI:
10.1021/ja00431a006
PDF
Nuclear magnetic resonance and conformational studies on amylose and model compounds in dimethyl sulfoxide solution
M. St.-Jacques, P. R. Sundararajan, K. J. Taylor, and R. H. Marchessault
pp 4386 - 4391; DOI:
10.1021/ja00431a007
PDF
Conceptual model of "through-bonds" interactions
T. K. Brunck and F. Weinhold
pp 4392 - 4393; DOI:
10.1021/ja00431a008
PDF
Aqueous vs. gas-phase acidities of the haloacetic acids. Enthalpies of hydration of haloacetic acids and haloacetate ions
Paul Haberfield and Animesh K. Rakshit
pp 4393 - 4394; DOI:
10.1021/ja00431a009
PDF
The nitrogen hyperfine splitting constant of the nitroxide functional group as a solvent polarity parameter. The relative importance for a solvent polarity parameter of its being a cybotactic probe vs. its being a model process
Bruce R. Knauer and James J. Napier
pp 4395 - 4400; DOI:
10.1021/ja00431a010
PDF
Origin of alkyl substituent effect in the proton affinity of amines, alcohols, and ethers
Hideaki Umeyama and Keiji Morokuma
pp 4400 - 4404; DOI:
10.1021/ja00431a011
PDF
Dynamic nuclear polarization studies of labile complex formation between lithium ion and nitronyl nitroxide or imidazoline-1-oxyl radical ligands
B. E. Wagner, J. W. Linowski, J. A. Potenza, R. D. Bates, J. N. Helbert, and E. H. Poindexter
pp 4405 - 4409; DOI:
10.1021/ja00431a012
PDF
Theory and application of photoelectron spectroscopy. 65. Nature of bonding in .lambda.5-phosphorins
Werner Schaefer, Armin Schweig, Karl Dimroth, and Hartmut Kanter
pp 4410 - 4418; DOI:
10.1021/ja00431a013
PDF
Dynamics and thermodynamics of axial ligation in metalloporphyrins. 4. Kinetics of porphyrin inversion in high-spin ferric complexes
Richard V. Snyder and Gerd N. La Mar
pp 4419 - 4424; DOI:
10.1021/ja00431a014
PDF
Solute complexes in aqueous gadolinium(III) chloride solutions
Marcus L. Steele and D. L. Wertz
pp 4424 - 4428; DOI:
10.1021/ja00431a015
PDF
Quadrupole coupling constants of square-planar copper(II)-sulfur complexes from single-crystal electron paramagnetic resonance spectroscopy
Lawrence K. White and R. Linn Belford
pp 4428 - 4438; DOI:
10.1021/ja00431a016
PDF
Photoredox photochemistry of tris(dibenzyldithiocarbamato)iron(III)
Dwight P. Schwendiman and Jeffrey I. Zink
pp 4439 - 4443; DOI:
10.1021/ja00431a017
PDF
Spectral properties of organometallic transition metal complexes. 2. The solution structure of sodium dicarbonyl(.eta.5-cyclopentadienyl)ferrate involving direct sodium-iron ion pairing
K. H. Pannell and David Jackson
pp 4443 - 4446; DOI:
10.1021/ja00431a018
PDF
Isotropic proton shifts for Co(salen)
Chit Srivanavit and Dennis G. Brown
pp 4447 - 4449; DOI:
10.1021/ja00431a019
PDF
Catalytic hydrogenation using cationic rhodium complexes. 3. The selective hydrogenation of dienes to monoenes
Richard R. Schrock and John A. Osborn
pp 4450 - 4455; DOI:
10.1021/ja00431a020
PDF
Electron spin resonance of electrochemically generated rhodium(0) complexes
Horia Caldararu, M. Keith DeArmond, Kenneth W. Hanck, and Victor E. Sahini
pp 4455 - 4457; DOI:
10.1021/ja00431a021
PDF
Reduction of pentaamminecobalt(III) complexes of aromatic nitriles by chromium(II)
Robert J. Balahura and W. L. Purcell
pp 4457 - 4462; DOI:
10.1021/ja00431a022
PDF
Kinetics and mechanism of the formation of organochromium(III) complexes in the reactions of organic peroxides with chromium(II)
Michael R. Hyde and James H. Espenson
pp 4463 - 4469; DOI:
10.1021/ja00431a023
PDF
The molybdenum-molybdenum triple bond. 1. Hexakis(dimethylamido)dimolybdenum and some homologs: preparation, structure, and properties
Malcolm H. Chisholm, F. Albert Cotton, B. A. Frenz, W. W. Reichert, L. W. Shive, and B. Ray Stults
pp 4469 - 4476; DOI:
10.1021/ja00431a024
PDF
The tungsten-tungsten triple bond. 1. Preparation, properties, and structural characterization of hexakis(dimethylamido)ditungsten(III) and some homologs
Malcolm H. Chisholm, F. Albert Cotton, Michael Extine, and B. Ray Stults
pp 4477 - 4485; DOI:
10.1021/ja00431a025
PDF
The tungsten-tungsten triple bond. 2. Preparation, structure, and dynamical behavior of dichlorotetrakis(diethylamido)ditungsten
Malcolm H. Chisholm, F. Albert Cotton, Michael Extine, Michelle Millar, and B. Ray Stults
pp 4486 - 4491; DOI:
10.1021/ja00431a026
PDF
X-ray and neutron diffraction studies on .lambda.-hydrido-octacarbonyl(nitrosyl)(trimethyl phosphite)ditungsten. A compound with a slightly asymmetric hydrogen bridge bond
Richard A. Love, Henry B. Chin, Thomas F. Koetzle, Stephen W. Kirtley, Bruce R. Whittlesey, and Robert Bau
pp 4491 - 4498; DOI:
10.1021/ja00431a027
PDF
Reversible oxidative addition of triphenylphosphine to zero-valent nickel and palladium complexes
Darryl R. Fahey and John E. Mahan
pp 4499 - 4503; DOI:
10.1021/ja00431a028
PDF
Kinetics, steric course, and mechanism of stereoisomerization of aluminum .beta.-diketonates
Miles Pickering, Berardo Jurado, and Charles S. Springer
pp 4503 - 4515; DOI:
10.1021/ja00431a029
PDF
Solvent specific photochemistry involving an intramolecular amino ketone triplet exciplex
P. J. Wagner and D. A. Ersfeld
pp 4515 - 4518; DOI:
10.1021/ja00431a030
PDF
Kinetics and mechanism for addition of amines to formyl-1-methylpyridinium ions
P. Sojo, F. Viloria, L. Malave, R. Possamai, M. Calzadilla, J. Baumrucker, A. Malpica, R. Moscovici, and L. Do Amaral
pp 4519 - 4525; DOI:
10.1021/ja00431a031
PDF
Oxygen-18 tracer use in ozonolysis mechanism studies. Results using the triphenylphosphine reduction method
David P. Higley and Robert W. Murray
pp 4526 - 4533; DOI:
10.1021/ja00431a032
PDF
Electronic states of acenaphthylene. Linear dichroism in stretched polyethylene and magnetic circular dichroism
Erik W. Thulstrup and Josef Michl
pp 4533 - 4540; DOI:
10.1021/ja00431a033
PDF
Electronic states of pleiadiene (cyclohepta[de]naphthalene). Linear dichroism in stretched polyethylene and magnetic circular dichroism
Jaroslav Kolc and Josef Michl
pp 4540 - 4545; DOI:
10.1021/ja00431a034
PDF
Acenaphthylene and pleiadiene (cyclohepta[de]naphthalene): a case of approximate orbital and state cross-pairing
Josef Michl
pp 4546 - 4549; DOI:
10.1021/ja00431a035
PDF
Nonalternant hydrocarbons: a classification of excited states in acenaphthylene and pleiadiene (cyclohepta[de]naphthalene) families
Josef Michl and J. F. Muller
pp 4550 - 4553; DOI:
10.1021/ja00431a036
PDF
Structure of transition states. 4. MINDO/2 study of rearrangements in the C6H10 system
Andrew Komornicki and James W. McIver
pp 4553 - 4561; DOI:
10.1021/ja00431a037
PDF
The cyclobutene/butadiene anion radical electrocyclic reaction
Nathan L. Bauld, James Cessac, Chiu-Shan Chang, Frank R. Farr, and Robert Holloway
pp 4561 - 4567; DOI:
10.1021/ja00431a038
PDF
Calculations of steric hindrance in ester hydrolysis based on estimation of van der Waals strain energies of alkanes
DeLos F. DeTar and Carl J. Tenpas
pp 4567 - 4571; DOI:
10.1021/ja00431a039
PDF
Application of carbon-13 nuclear magnetic resonance spectroscopy to the analysis of charge distribution patterns in unsaturated carbonyl-containing compounds
Melanie J. Loots, Linda R. Weingarten, and Ronald H. Levin
pp 4571 - 4577; DOI:
10.1021/ja00431a040
PDF
.gamma.-Chloroallyl sulfoxides as latent .alpha.,.beta.-unsaturated carbonyl compounds. A new approach to steroid synthesis
P. T. Lansbury and R. W. Britt
pp 4577 - 4581; DOI:
10.1021/ja00431a041
PDF
Molecular rearrangements with ethoxycarbonyl group migrations. 1. The rearrangement of epoxides
Jacques Kagan, Dalmacio A. Agdeppa, S. P. Singh, David A. Mayers, Charles Boyajian, Carol Poorker, and Bruce E. Firth
pp 4581 - 4588; DOI:
10.1021/ja00431a042
PDF
Molecular rearrangements with thiol ester group migration. S-Phenyl (E)- and (Z)-2,3-diphenylthiolglycidates
Robert A. Gorski, Dineshkumar J. Dagli, and James Wemple
pp 4588 - 4593; DOI:
10.1021/ja00431a043
PDF
Studies on terpenes. 4. Synthesis of optically active grandisol, the boll weevil pheromone
Peter D. Hobbs and Philip D. Magnus
pp 4594 - 4600; DOI:
10.1021/ja00431a044
PDF
Experimental and theoretical studies of the barrier to rotation about the N-C.alpha. and C.alpha.-C' bonds (.vphi. and .psi.) in amides and peptides
A. T. Hagler, L. Leiserowitz, and M. Tuval
pp 4600 - 4612; DOI:
10.1021/ja00431a045
PDF
Structure of a derivative of streptovaricin C triacetate. Crystal and molecular structure of the atropisomer of the cyclic p-bromobenzeneboronate ester of streptovaricin C triacetate: methylene dichloride 1:1 solvate
Andrew H. J. Wang and Iain C. Paul
pp 4612 - 4619; DOI:
10.1021/ja00431a046
PDF
Model dehydrogenase reactions. Zinc ion catalyzed reduction of chelating aldehydes by N-propyl-1,4-dihydronicotinamides and borohydride
Donald J. Creighton, Joseph Hajdu, and David S. Sigman
pp 4619 - 4625; DOI:
10.1021/ja00431a047
PDF
Model studies for coenzyme B12 dependent enzyme-catalyzed rearrangements. Evidence for cobalt(III)-olefin .pi. complexes
Richard B. Silverman and D. Dolphin
pp 4626 - 4633; DOI:
10.1021/ja00431a048
PDF
Model studies for coenzyme B12 dependent enzyme-catalyzed rearrangements. Kinetics and mechanism of decomposition of formylmethylcobalamin and its acetals
Richard B. Silverman and D. Dolphin
pp 4633 - 4639; DOI:
10.1021/ja00431a049
PDF
Intramolecular hydrogen bonding and acidities of nucleoside sugar hydroxyls. Crystal structure and conformation of O2,2'-anhydro-1-.alpha.-D-xylofuranosyluracil
George I. Birnbaum, Jerzy Giziewicz, Carol P. Huber, and David Shugar
pp 4640 - 4644; DOI:
10.1021/ja00431a050
PDF
Metal clusters in catalysis. 5. Four-electron .eta.2-ligand bonding in clusters and catalytic intermediates
M. G. Thomas, E. L. Muetterties, R. O. Day, and V. W. Day
pp 4645 - 4646; DOI:
10.1021/ja00431a051
PDF
Organosilicon compounds with functional groups proximate to silicon. Feasible route to 1,2-epoxyalkyllithium reagents via the lithiation of epoxyethylsilanes
John J. Eisch and James E. Galle
pp 4646 - 4648; DOI:
10.1021/ja00431a052
PDF
Tetraethyldioxetane and 3,4-dimethyl-3,4-di-n-butyl-1,2-dioxetane. High ratio of triplet to singlet excited products from the thermolysis of both dioxetanes
Etelvino J. H. Bechara, Alfons L. Baumstark, and Therese Wilson
pp 4648 - 4649; DOI:
10.1021/ja00431a053
PDF
Bovine serum albumin as a catalyst. 5. A sensitive assay of the correct refolding of individual fragments of the protein
Ronald P. Taylor and Ann Silver
pp 4650 - 4651; DOI:
10.1021/ja00431a054
PDF
Activation of hydrocarbons by unsaturated metal cluster complexes. 4. Decacarbonyltriosmium complexes of some conjugated dienes. The crystal structures of Os3(CO)10(s-cis-C4H6) and Os3(CO)10(s-trans-C4H6)
Mamoru Tachikawa, John R. Shapley, R. Curtis Haltiwanger, and Cortland G. Pierpont
pp 4651 - 4652; DOI:
10.1021/ja00431a055
PDF
A novel catalytic property of magnesium oxide for hydrogenation of 1,3-butadiene
Hideshi Hattori, Yasutaka Tanaka, and Kozo Tanabe
pp 4652 - 4653; DOI:
10.1021/ja00431a056
PDF
Short-lived intermediates. 6. Cyclization of the 1,4-diradical in ester photochemistry. Completion of an analogy found wanting
Neil A. Marron and James E. Gano
pp 4653 - 4655; DOI:
10.1021/ja00431a057
PDF
Models for NADH dependent enzymes. Solvent effects in dihydronicotinamide reductions
Paul Van Eikeren and David L. Grier
pp 4655 - 4657; DOI:
10.1021/ja00431a058
PDF
Chemical probes of nitrogenase. 1. Cyclopropene. Nitrogenase-catalyzed reduction to propene and cyclopropane
Charles E. McKenna, Marie C. McKenna, and Melvin T. Higa
pp 4657 - 4659; DOI:
10.1021/ja00431a059
PDF
Enzymic cyclization of (R,S)-14,15-oxidogeranylgeranyl pyrophosphate to 3.alpha.- and 3.beta.-hydroxykaurene
R. M. Coates, R. A. Conradi, D. A. Ley, A. Akeson, J. Harada, S. C. Lee, and C. A. West
pp 4659 - 4661; DOI:
10.1021/ja00431a060
PDF
Direct observation by Raman spectroscopy of the coexistence of a variety of ion-paired species in liquid ammonia solutions of alkali metal salts
P. Gans, J. B. Gill, and M. Griffin
pp 4661 - 4662; DOI:
10.1021/ja00431a061
PDF
The role of water in the rhodium(I) catalyzed reduction of nitric oxide by carbon monoxide. An isotope labeling study
Dan E. Hendriksen and Richard Eisenberg
pp 4662 - 4664; DOI:
10.1021/ja00431a062
PDF
A novel diterpene from Dollabella californica
Chris Ireland, D. J. Faulkner, Janet Finer, and Jon Clardy
pp 4664 - 4665; DOI:
10.1021/ja00431a063
PDF
Reductive elimination reactions
E. L. Muetterties and Patricia L. Watson
pp 4665 - 4667; DOI:
10.1021/ja00431a064
PDF
Mechanism of the formation of cyclopentadienone derivatives from 4-aryl-2,6-di-tert-butylphenols by base-catalyzed oxygenation
Akira Nishinaga and Anton Rieker
pp 4667 - 4668; DOI:
10.1021/ja00431a065
PDF
Toward metallocyclopropenium ions: redox cleavage of diorganyldichalcogenides by trichlorocyclopropenium salts
R. Weiss, C. Schlierf, and K. Schloter
pp 4668 - 4669; DOI:
10.1021/ja00431a066
PDF
N-Methyltetraphenylporphyrin complexes. Crystal and molecular structure of chloro-N-methyl-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatocobalt(II)
Oren P. Anderson and David K. Lavallee
pp 4670 - 4671; DOI:
10.1021/ja00431a067
PDF
Laser photodissociation spectrum of gas-phase 1,3,5-hexatriene radical cation
Robert C. Dunbar
pp 4671 - 4672; DOI:
10.1021/ja00431a068
PDF
Reactions of 5-norbornene-2-diazonium ions and nortricyclene-3-diazonium ions
Wolfgang Kirmse and Norbert Knoepfel
pp 4672 - 4674; DOI:
10.1021/ja00431a069
PDF
2-Alkenyl anions and their surprising endo preference. Facile and extreme stereocontrol over carbon-carbon linking reactions with organometallics of the allyl type
Manfred Schlosser and Juergen Hartmann
pp 4674 - 4676; DOI:
10.1021/ja00431a070
PDF
Crossed molecular beam measurement of the intrinsic activation barrier for the endoergic reaction Hg + I2 .fwdarw. HgI + I
B. E. Wilcomb, T. M. Mayer, R. B. Bernstein, and R. W. Bickes
pp 4676 - 4677; DOI:
10.1021/ja00431a071
PDF
Antineoplastic agents. 46. The isolation and structure of dolatriol
George R. Pettit, Richard H. Ode, Cherry L. Herald, Robert B. Von Dreele, and Claude Michel
pp 4677 - 4678; DOI:
10.1021/ja00431a072
PDF
An acylsilane derivative of a transition metal
J. R. Anglin and W. A. G. Graham
pp 4678 - 4679; DOI:
10.1021/ja00431a073
PDF
New 1,4-diketone synthesis using nitroolefins and trimethylsilyl enol ethers. A convenient regiospecific route to cyclopentenones
Masaaki Miyashita, Tetsuji Yanami, and Akira Yoshikoshi
pp 4679 - 4681; DOI:
10.1021/ja00431a074
PDF
Electronic spectra of crystals of dimolybdenum tetraformate and the tetrasulfatodimolybdenum(II) ion
F. A. Cotton, Don S. Martin, Phillip E. Fanwick, Timothy J. Peters, and Thomas R. Webb
pp 4681 - 4682; DOI:
10.1021/ja00431a075
PDF
Insertion reactions of carbon dioxide with triply bonded ditungsten dialkylamido compounds. Structures and dynamic properties of the resulting carbamato complexes
Malcolm H. Chisholm, Michael Extine, F. Albert Cotton, and B. Ray Stults
pp 4683 - 4684; DOI:
10.1021/ja00431a076
PDF
An electron filtering membrane
Iwao Tabushi and Mitsuru Funakura
pp 4684 - 4685; DOI:
10.1021/ja00431a077
PDF
Binuclear clusters in organic synthesis. Synthetic and mechanistic studies of the reduction of .alpha.,.beta.-unsaturated carbonyl compounds by sodium hydrogen octacarbonyldiferrate
James P. Collman, Richard G. Finke, Paul L. Matlock, Robert Wahren, and John I. Brauman
pp 4685 - 4687; DOI:
10.1021/ja00431a078
PDF
The molecular structure of dodecacarbonyltetra-.mu.3-hydrotetrarhenium. Evidence for face-bridging hydrogen atoms
Robert D. Wilson and Robert Bau
pp 4687 - 4689; DOI:
10.1021/ja00431a079
PDF
Mechanism of the olefin metathesis reaction. 4. Catalyst precursors in tungsten(VI) based systems
M. T. Mocella, R. Rovner, and E. L. Muetterties
pp 4689 - 4690; DOI:
10.1021/ja00431a080
PDF
Additions and Corrections - Photochemistry of Bicyclo[3.2.0.]hept-3-en-2-oness
Robert L. Cargill, A. Bradford Sears, Jeffrey Boehm, and M. Robert Willcott
pp 4691 - 4691; DOI:
10.1021/ja00431a600
PDF
Additions and Corrections - Reaction of N,N-Dichlorourethane and of Diethyl Azodicarboxylate with Alkoxide
Ronald E. White, and Peter Kovacic
pp 4691 - 4691; DOI:
10.1021/ja00431a601
PDF
Additions and Corrections - Behavior of N,N-Dichlorocarbamates toward Nucleophiles
Ronald E. White, and Peter Kovacic
pp 4691 - 4691; DOI:
10.1021/ja00431a602
PDF
Additions and Corrections - "K-Region" Oxides and Related Oxidized Metabolites of Carcinogenic Aromatic Hydrocarbons
Ronald G. Harvey, Swee Hock Goh, and Cecilia Cortez
pp 4691 - 4691; DOI:
10.1021/ja00431a603
PDF
Additions and Corrections - Nuclear Magnetic Resonance Studies of Planar Low-Spin Complexes of Cobalt(II) with Schiff Bases. N,N -Ethylene-bis(salicylideneiminato)cobalt(II) in Noncoordinating Solvents
Kuoto Migata, Masamoto Iwaizumi, and Taro Isobe
pp 4691 - 4691; DOI:
10.1021/ja00431a604
PDF
Additions and Corrections - Crystal and Molecular Structure of Pentaphenoxyphosphorane, (C6H5O)5P. The Configuration of Acyclic, Monocyclic, and Spirobicyclic Pentaoxyphosphoranes
Raghupathy Sarma, Fausto Ramirez, Brian McKeever, James F. Marecek, and Shuyan Lee
pp 4691 - 4691; DOI:
10.1021/ja00431a605
PDF
Additions and Corrections - Preparation and Properties of Uranocene, Di-π-cyclooctatetraneuranium(IV)
A. Streitwieser, Jr., U. Muller-Westerhoff, G. Sonnichsen, F., D. G. Morrell, Keith O. Hodgson, and C. A. Harmon
pp 4691 - 4692; DOI:
10.1021/ja00431a606
PDF
Additions and Corrections - Reactivity-Selectivity Relationships. II. A Simple Model to Explain Nucleophile-Electrophile Combination Reactions and Its Implications for the Reactivity-Selectivity Principle.
Addy Pross
pp 4692 - 4692; DOI:
10.1021/ja00431a607
PDF
Additions and Corrections - Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. XXIV. Neophyl Rearrangements.
B. Maillard, and K. U. Ingold
pp 4692 - 4692; DOI:
10.1021/ja00431a608
PDF
Additions and Corrections - pH Dependence of the Nitrotyrosine-248 and Arsanilazotyrosine-248 Carboxypeptidase A Catalyzed Hydrolysis of O-(trans-p-Chlorocinnamoyl) - L-β-phenyllactate
Junghun Suh, and Emil Thomas Kaiser
pp 4692 - 4692; DOI:
10.1021/ja00431a609
PDF
Book Reviews

pp 4692 - 4692; DOI:
10.1021/ja00431a610
PDF

Issue 16


Orbital interaction in three systems
Satoshi Inagaki, Hiroshi Fujimoto, and Kenichi Fukui
pp 4693 - 4701; DOI:
10.1021/ja00432a001
PDF
Theory and calculation of carbon-nitrogen spin-spin coupling constants
Jerome M. Schulman and Thomas Venanzi
pp 4701 - 4705; DOI:
10.1021/ja00432a002
PDF
Exciplex photophysics. III. Kinetics of fluorescence quenching of .alpha.-cyanonaphthalene by dimethylcyclopentene-1,2 in hexane
Desmond V. O'Connor and William R. Ware
pp 4706 - 4711; DOI:
10.1021/ja00432a003
PDF
Exciplex photophysics. IV. Effect of diffusion-controlled quenching on exciplex photokinetics
Man Him Hui and William R. Ware
pp 4712 - 4717; DOI:
10.1021/ja00432a004
PDF
Exciplex photophysics. V. The kinetics of fluorescence quenching of anthracene by N,N-dimethylaniline in cyclohexane
Man Him Hui and William R. Ware
pp 4718 - 4727; DOI:
10.1021/ja00432a005
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 25. Radicals formed by spin trapping with di-tert-butyl thioketone
J. C. Scaiano and K. U. Ingold
pp 4727 - 4732; DOI:
10.1021/ja00432a006
PDF
Photoelectron spectra of sterically congested alkenes and dienes
Phillip D. Mollere, K. N. Houk, David S. Bomse, and Thomas Hellman Morton
pp 4732 - 4736; DOI:
10.1021/ja00432a007
PDF
Carbon-13 magnetic resonance spectra of C-nucleosides. 3. Tautomerism in formycin and formycin B and certain pyrazolo[4,3-d]pyrimidines
Marie T. Chenon, Raymond P. Panzica, James C. Smith, Ronald J. Pugmire, David M. Grant, and Leroy B. Townsend
pp 4736 - 4745; DOI:
10.1021/ja00432a008
PDF
The pH dependence of carbon-13 nuclear magnetic resonance shifts of tetracycline. Microscopic dissociation constants
G. L. Asleson and C. W. Frank
pp 4745 - 4749; DOI:
10.1021/ja00432a009
PDF
Charge distributions and chemical effects. 11. Charge dependence of carbon-13 chemical shifts in adamantane and related six-membered polycyclic molecules
G. Kean, D. Gravel, and S. Fliszar
pp 4749 - 4754; DOI:
10.1021/ja00432a010
PDF
Aqueous lanthanide shift reagents. 1. Interaction of the ethylenediaminetetraacetate chelates with carboxylates. The pH dependence, ionic medium effects, and chelate structure
Gabriel A. Elgavish and Jacques Reuben
pp 4755 - 4759; DOI:
10.1021/ja00432a011
PDF
Synthesis and structural characterization of 9-ethylguaninium tetrachloroplatinate(II) dihydrate. A crystallographic and proton nuclear magnetic resonance study
Linda G. Purnell and Derek J. Hodgson
pp 4759 - 4763; DOI:
10.1021/ja00432a012
PDF
Electronic structure of substituted diphenylmethylcarbenium ions. A proton magnetic resonance and MO-INDO study
Bernard Ancian, Jean P. Doucet, and Jacques E. Dubois
pp 4764 - 4769; DOI:
10.1021/ja00432a013
PDF
Molecular orbital studies of enzyme activity. 2. Nucleophilic attack on carbonyl systems with comments on orbital steering
Steve Scheiner, William N. Lipscomb, and Daniel A. Kleier
pp 4770 - 4777; DOI:
10.1021/ja00432a014
PDF
Ab initio SCF-MO calculations of methyllithium and related systems. Absence of covalent character in the carbon-lithium bonds
Andrew Streitwieser, James E. Williams, Spiro Alexandratos, and John M. McKelvey
pp 4778 - 4784; DOI:
10.1021/ja00432a015
PDF
Mechanism of the Wolff rearrangement. 6. Ab initio molecular orbital calculations on the thermodynamic and kinetic stability of the oxirene molecule
O. P. Strausz, R. K. Gosavi, A. S. Denes, and I. G. Csizmadia
pp 4784 - 4786; DOI:
10.1021/ja00432a016
PDF
Theoretical study of SN2 reactions. Ab initio computations on HF and CI level
Frerich Keil and Reinhart Ahlrichs
pp 4787 - 4793; DOI:
10.1021/ja00432a017
PDF
Ab initio calculations on large molecules using molecular fragments. Configuration interaction calculations on the ground and lower excited states of carbazole
L. E. Nitzsche, Cary Chabalowski, and R. E. Christoffersen
pp 4794 - 4801; DOI:
10.1021/ja00432a018
PDF
Dimeric structure of di-tert-butylphosphinic acid
M. E. Druyan, A. H. Reis, E. Gebert, S. W. Peterson, G. W. Mason, and D. F. Peppard
pp 4801 - 4805; DOI:
10.1021/ja00432a019
PDF
Nucleophilic substitution at phosphorus in tertiary phosphines. Evidence against pseudorotation in a potential intermediate
Evan P. Kyba
pp 4805 - 4809; DOI:
10.1021/ja00432a020
PDF
Heterodimetallic cycloheptatrienyl complexes of the transition metals: synthesis, properties, and structure
M. J. Bennett, J. L. Pratt, K. A. Simpson, L. K. K. LiShingMan, and Josef Takats
pp 4810 - 4817; DOI:
10.1021/ja00432a021
PDF
Cobalt-hydrogen metallocarboranes. Synthesis of closo-[(CH3)2C2B4H4]2CoH and nido,closo-[(CH3)2C2B3H5]CoH[(CH3)2C2B4H4] and their conversion to new cobalt-cobalt bonded metallocarboranes
William M. Maxwell, Vernon R. Miller, and Russell N. Grimes
pp 4818 - 4823; DOI:
10.1021/ja00432a022
PDF
Variable spin iron(III) chelates with hexadentate ligands derived from triethylenetetramine and various salicylaldehydes. Synthesis, characterization, and solution state studies of a new 2T .dblarw. 6A spin equilibrium system
Michael F. Tweedle and Lon J. Wilson
pp 4824 - 4834; DOI:
10.1021/ja00432a023
PDF
Coordination properties of o-benzoquinones. Structure and bonding in tris(tetrachloro-1,2-benzoquinone)chromium(0)
Cortlandt G. Pierpont and Hartley H. Downs
pp 4834 - 4838; DOI:
10.1021/ja00432a024
PDF
Kinetics and mechanism of the reactions of organochromium complexes with mercury(II) and methylmercury(II) ions
John P. Leslie and James H. Espenson
pp 4839 - 4844; DOI:
10.1021/ja00432a025
PDF
Preparation and some reactions of dimeric isocyanide complexes of palladium(I) and platinum(I)
John R. Boehm, Daniel J. Doonan, and Alan L. Balch
pp 4845 - 4850; DOI:
10.1021/ja00432a026
PDF
The mechanism of the rearrangement of the hydrocobalt carbonyl catalyzed isomerization of 3-phenylpropene
William T. Hendrix and J. L. Von Rosenberg
pp 4850 - 4852; DOI:
10.1021/ja00432a027
PDF
Temperature dependence of the photophysical and photochemical properties of the tris(2,2'-bipyridyl)ruthenium(II) ion in aqueous solution
J. Van Houten and R. J. Watts
pp 4853 - 4858; DOI:
10.1021/ja00432a028
PDF
Photochemistry of azoisopropane
Laurence D. Fogel and Colin Steel
pp 4859 - 4867; DOI:
10.1021/ja00432a029
PDF
Thermolyses of tert-butyl .DELTA.1,1'-dicyclohexenylperoxyacetate. Electrocyclic and other transformations of a pentadienyl radical
Roland E. Lehr, J. Michael Wilson, John W. Harder, and Patrick T. Cohenour
pp 4867 - 4875; DOI:
10.1021/ja00432a030
PDF
Rate constants for some electrophilic reactions of benzyl, benzhydryl, and trityl cations in solution
Richard J. Sujdak, R. Lorin Jones, and Leon M. Dorfman
pp 4875 - 4879; DOI:
10.1021/ja00432a031
PDF
Radical additions to di-tert-butylsulfur diimide and di-tert-butylcarbodiimide
G. Brunton, J. F. Taylor, and K. U. Ingold
pp 4879 - 4882; DOI:
10.1021/ja00432a032
PDF
Aminocyclopropyl sulfoxides. Preparation and reaction with acids
Ronald H. Rynbrandt, Fred E. Dutton, and Constance G. Chidester
pp 4882 - 4886; DOI:
10.1021/ja00432a033
PDF
New synthetic reactions. Sulfenylations and dehydrosulfenylations of esters and ketones
Barry M. Trost, Thomas N. Salzmann, and Kunio Hiroi
pp 4887 - 4902; DOI:
10.1021/ja00432a034
PDF
Electron spin resonance studies of the reduction of transition metal complexes with Grignard reagents. 1. Dianion radicals of .beta.-diketonates
C. L. Kwan and J. K. Kochi
pp 4903 - 4912; DOI:
10.1021/ja00432a035
PDF
Amide-phosphate interactions: acid catalysis in amide-assisted hydrolysis of phosphonate esters
Ronald Kluger and Joseph L. W. Chan
pp 4913 - 4917; DOI:
10.1021/ja00432a036
PDF
Hydroboration. 42. Cyclic hydroboration of representative acyclic .alpha.,.omega.-dienes with monochloroborane etherate
Herbert C. Brown and Marek Zaidlewicz
pp 4917 - 4925; DOI:
10.1021/ja00432a037
PDF
Selective .gamma. alkylation of dienolate anions derived from .alpha.,.beta.-unsaturated acids. Applications to the synthesis of isoprenoid olefins
John A. Katzenellenbogen and Ann L. Crumrine
pp 4925 - 4935; DOI:
10.1021/ja00432a038
PDF
Bond fixation in annulenes. 3. The structural consequences of tetra- and pentamethyl substitution of the cyclooctatetraene ring
Leo A. Paquette and James M. Photis
pp 4936 - 4945; DOI:
10.1021/ja00432a039
PDF
Stereochemical analysis of 1,1,2,2-tetraarylethanes. 1. Static stereochemistry
Paolo Finocchiaro, Devens Gust, W. Douglas Hounshell, John P. Hummel, Pietro Maravigna, and Kurt Mislow
pp 4945 - 4952; DOI:
10.1021/ja00432a040
PDF
Stereochemical analysis of 1,1,2,2-tetraarylethanes. 2. Dynamic stereochemistry of selected tetraarylethanes and the use of residual stereoisomerism and residual stereotopism as a tool for differentiating among divers stereoisomerization pathways
Paolo Finocchiaro, W. Douglas Hounshell, and Kurt Mislow
pp 4952 - 4963; DOI:
10.1021/ja00432a041
PDF
Reactions of the K-region oxides of carcinogenic and related polycyclic hydrocarbons with nucleophiles: stereochemistry and regioselectivity
Frederick A. Beland and Ronald G. Harvey
pp 4963 - 4970; DOI:
10.1021/ja00432a042
PDF
Synthesis and isolation of optically pure L- and D-2-2H amino acids via cobalt(III) chelates
William E. Keyes and J. Ivan Legg
pp 4970 - 4975; DOI:
10.1021/ja00432a043
PDF
Optically specific synthesis of estrone and 19-norsteroids from 2,6-lutidine
Samuel Danishefsky and Paul Cain
pp 4975 - 4983; DOI:
10.1021/ja00432a044
PDF
Crystal and molecular structure of d,l-dethiobiotin. Role of sulfur in biotin stereochemistry
Cheng-San Chen, R. Parthasarathy, and George T. DeTitta
pp 4983 - 4990; DOI:
10.1021/ja00432a045
PDF
Mechanism of phosphorylation by N'-phosphorocreatine. Concurrent formation of creatine and creatinine
Gary W. Allen and Paul Haake
pp 4990 - 4996; DOI:
10.1021/ja00432a046
PDF
Structural chemistry of cyclic nucleotides. 5. Methyl .alpha.-D-glucopyranoside cyclic 4,6-phosphate
Charles L. Coulter
pp 4997 - 5000; DOI:
10.1021/ja00432a047
PDF
Dynamic interactions of fluorescence probes with the solvent environment
Robert P. DeToma, J. Hamilton Easter, and Ludwig Brand
pp 5001 - 5007; DOI:
10.1021/ja00432a048
PDF
Latent quinone carbanions via anodic oxidation of 2-bromo-1,4-dimethoxybenzene. An "umpolung" reagent for quinones
Michael J. Manning, Peter W. Raynolds, and John S. Swenton
pp 5008 - 5009; DOI:
10.1021/ja00432a049
PDF
Inverse substituent effects and paramagnetic ring currents in 9-arylmethylenecyclooctatrienyl anions
Stuart W. Staley and Gerard E. Linkowski
pp 5010 - 5011; DOI:
10.1021/ja00432a050
PDF
Nitrogen to nitrogen proton transfer. The significance of large negative entropies of activation
F. M. Menger, T. D. Singh, and F. L. Bayer
pp 5011 - 5012; DOI:
10.1021/ja00432a051
PDF
Nybomycin. 8. Biosynthetic origin of the central ring carbons studied by 13C-labeled substrates
Alex M. Nadzan and Kenneth L. Rinehart
pp 5012 - 5014; DOI:
10.1021/ja00432a052
PDF
2,6-Substituted homotropilidenes. Influence of substituents on valence topomerization
H. Kessler and W. Ott
pp 5014 - 5016; DOI:
10.1021/ja00432a053
PDF
Stereochemistry of conversion of allylic halides to cyclopropanes via .gamma.-haloalkylboranes
Harlan L. Goering and Steven L. Trenbeath
pp 5016 - 5017; DOI:
10.1021/ja00432a054
PDF
New synthetic reagents. 2-Methoxy-3-phenylthiobuta-1,3-diene. A novel annelating agent
Barry M. Trost and Alex J. Bridges
pp 5017 - 5019; DOI:
10.1021/ja00432a055
PDF
Syntheses and reactions of substituent stabilized thione methylides
A. J. Arduengo and Edward M. Burgess
pp 5020 - 5021; DOI:
10.1021/ja00432a056
PDF
The structure of a substituent stabilized thione methylide
A. J. Arduengo and Edward M. Burgess
pp 5021 - 5023; DOI:
10.1021/ja00432a057
PDF
Mechanistic photochemistry of .beta.,.gamma.-unsaturated ketones. An alternative excited state assignment for the 1,3-acyl shift reaction of alkyl .beta.,.gamma.-enones
J. Christopher Dalton, Ming Shen, and John J. Snyder
pp 5023 - 5025; DOI:
10.1021/ja00432a058
PDF
Photochemistry of ketones in solution. 50. Fluorescence lifetimes of .beta.,.gamma.-unsaturated ketones. Structural dependence of rate constants for reaction and decay of singlet excited states
David I. Schuster, Jens Eriksen, Paul S. Engel, and Mary A. Schexnayder
pp 5025 - 5027; DOI:
10.1021/ja00432a059
PDF
Stabilization of carbonyl clusters by a carbide atom. Synthesis and characterization of carbonoctadecacarbonyloctacobaltate(2-) and of paramagnetic carbontetradecacarbonylhexacobaltate(1-) anions
Vincenzo G. Albano, Paolo Chini, Gianfranco Ciani, Mirella Sansoni, Donatella Strumolo, Brian T. Heaton, and Secondo Martinengo
pp 5027 - 5028; DOI:
10.1021/ja00432a060
PDF
Chromium(II) porphyrins and an irreversible dioxygen complex
Stephen K. Cheung, Carol J. Grimes, Janice Wong, and Christopher A. Reed
pp 5028 - 5030; DOI:
10.1021/ja00432a061
PDF
Novel nonenzymic heterolysis of an allyl phosphate ester by organoaluminum reagents
Yoshizo Kitagawa, Shinsuke Hashimoto, Satoshi Iemura, Hisashi Yamamoto, and Hitosi Nozaki
pp 5030 - 5031; DOI:
10.1021/ja00432a062
PDF
Zero-coordinate rubidium(1+). A rubidium ion whose interionic contacts are all unconventionally long by more than 1.5 .ANG.
Roger L. Firor and Karl Seff
pp 5031 - 5033; DOI:
10.1021/ja00432a063
PDF
Resonance Raman spectroscopy with unsymmetrically isotopic ligands. Differentiation of possible structures of hemerythrin complexes
Donald M. Kurtz, Duward F. Shriver, and Irving M. Klotz
pp 5033 - 5035; DOI:
10.1021/ja00432a064
PDF
High yield generation of a persistent, saturated lithium ketyl in solution. Characteristic reactions and identification by electron spin resonance
Valentin Rautenstrauch and Michel Geoffroy
pp 5035 - 5037; DOI:
10.1021/ja00432a065
PDF
Coexistence of two oppositely polarized zwitterionic forms on the lowest excited singlet surface of terminally twisted butadiene. Two-funnel photochemistry with dual stereochemistry
Peter Bruckmann and Lionel Salem
pp 5037 - 5038; DOI:
10.1021/ja00432a066
PDF
Conjugated allenic 3-oxo-5,10-secosteroids. Irreversible inhibitors of .DELTA.5-3-ketosteroid isomerase
Douglas F. Covey and C. H. Robinson
pp 5038 - 5040; DOI:
10.1021/ja00432a067
PDF
Azetidinone antibiotics. 17. A rearrangement of penicillin sulfoxides to 3-methylenecephams via sulfinyl intermediates
Stjepan Kukolja, Steven R. Lammert, Michael R. B. Gleissner, and Alvin I. Ellis
pp 5040 - 5041; DOI:
10.1021/ja00432a068
PDF
5-Iodoacetamidomethyl-2'-deoxyuridine 5'-phosphate. A selective inhibitor of mammalian thymidylate synthetases
Roxane L. Barfknecht, Rocio A. Huet-Rose, Arieh Kampf, and Mathias P. Mertes
pp 5041 - 5043; DOI:
10.1021/ja00432a069
PDF
Carbon-13 nuclear magnetic resonance probe of the active site of carbonic anhydrase
D. J. Strader and R. G. Khalifah
pp 5043 - 5044; DOI:
10.1021/ja00432a070
PDF
The structure of Q* nucleoside isolated from rabbit liver transfer ribonucleic acid
H. Kasai, K. Nakanishi, R. D. Macfarlane, D. F. Torgerson, Z. Ohashi, J. A. McCloskey, H. J. Gross, and S. Nishimura
pp 5044 - 5046; DOI:
10.1021/ja00432a071
PDF
Synthesis and structural characterization of a new type of metal cluster system, octacarbonylhexakis(.mu.4-phenylphosphido)octanickel, containing a completely bonding metal cube. A transition metal analog of cubane, C8H8
Loren D. Lower and Lawrence F. Dahl
pp 5046 - 5047; DOI:
10.1021/ja00432a072
PDF
Book Reviews

pp 5048 - 5054; DOI:
10.1021/ja00432a600
PDF

Issue 17


Megawatt infrared laser chemistry of chlorotrifluoromethane and trichlorofluoromethane. 1. Photochemistry, photophysics, and effect of hydrogen
David F. Dever and Ernest Grunwald
pp 5055 - 5062; DOI:
10.1021/ja00433a001
PDF
Intramolecular hydrogen bonding involving hydroxyl groups in mono- and dianions of diprotic acids in acetonitrile and dimethyl sulfoxide
I. M. Kolthoff and M. K. Chantooni
pp 5063 - 5068; DOI:
10.1021/ja00433a002
PDF
Hydrogen bonding and related association in linear aliphatic amino alcohols as probed by carbon-13 spin-lattice relaxation times
Ulf Edlund, Clive Holloway, and George C. Levy
pp 5069 - 5073; DOI:
10.1021/ja00433a003
PDF
Carbon-13 chemical shifts of the carbonyl group. 8. Approximate self-consistent-field perturbation theory
Gary E. Maciel, Jerry L. Dallas, and Don P. Miller
pp 5074 - 5082; DOI:
10.1021/ja00433a004
PDF
Conformational analysis by nuclear magnetic resonance. Nitrogen-15 and carbon-13 spectra of lactams
Kenneth L. Williamson and John D. Roberts
pp 5082 - 5086; DOI:
10.1021/ja00433a005
PDF
Proton localization in chemical ionization fragmentation
Ian Jardine and Catherine Fenselau
pp 5086 - 5089; DOI:
10.1021/ja00433a006
PDF
An ESR study of the acid dissociation of imidogen protons. 1. Linear peptide radicals and related radicals
Yutaka Kirino and Hitoshi Taniguchi
pp 5089 - 5096; DOI:
10.1021/ja00433a007
PDF
Isotope effects on gas phase reaction processes. 2. Equilibrium isotope effects on the proton transfer reactions of methylbenzenes
J. Fredrick Wolf, John L. Devlin, Douglas J. DeFrees, Robert W. Taft, and Warren J. Hehre
pp 5097 - 5101; DOI:
10.1021/ja00433a008
PDF
Determination of precise and reliable gas diffusion coefficients by gas chromatography
Frank Yang, Stephen Hawkes, and F. T. Lindstrom
pp 5101 - 5107; DOI:
10.1021/ja00433a009
PDF
Representations of molecular force fields. 2. A modified Urey-Bradley field and an examination of Allinger's gauche hydrogen hypothesis
Susan Fitzwater and L. S. Bartell
pp 5107 - 5115; DOI:
10.1021/ja00433a010
PDF
Trends in molecular properties by the method of structural fragments. Bond angles in triatomic molecules, pyramidal inversion barriers, and singlet-triplet energy differences
Joel F. Liebman, Peter Politzer, and William A. Sanders
pp 5115 - 5119; DOI:
10.1021/ja00433a011
PDF
Phosphorus-nitrogen compounds. 26. Molecular motion and molecular separations in cyclophosphazene clathrates
H. R. Allcock, R. W. Allen, E. C. Bissell, L. A. Smeltz, and Martha Teeter
pp 5120 - 5125; DOI:
10.1021/ja00433a012
PDF
A preliminary report of the coordination of lanthanum(III) in lanthanum chloride-methanol solutions
Leonard S. Smith, Douglas C. McCain, and David L. Wertz
pp 5125 - 5128; DOI:
10.1021/ja00433a013
PDF
An acid-base model for mixed metal dimer formation: enthalpies of dimer cleavage and adduct formation of 1,5-cyclooctadiene-rhodium(I) chloride dimer
Marinda P. Li and Russell S. Drago
pp 5129 - 5135; DOI:
10.1021/ja00433a014
PDF
The structure of a monomeric oxygen carrying cobalt complex: dioxygen-N,N'-(1,1,2,2-tetramethyl)ethylenebis(3-tert-butylsalicylideniminato)(1-benzylimidazole)cobalt(II)
Robert S. Gall, John F. Rogers, William P. Schaefer, and Gary G. Christoph
pp 5135 - 5144; DOI:
10.1021/ja00433a015
PDF
Nature of the bound oxygen in a series of cobalt dioxygen adducts
Benjamin S. Tovrog, David J. Kitko, and Russell S. Drago
pp 5144 - 5153; DOI:
10.1021/ja00433a016
PDF
Reversible oxygen carriers. The synthesis and low temperature (-171.degree.) structure of an unstable monomeric dioxygen adduct of N,N'-(1,1,2,2-tetramethyl)ethylenebis(3-fluorosalicylideniminato)(1-methylimidazole)cobalt(II), Co(3-F-Saltmen)(1-Me-Imid)(O2).2Me2CO
Alex Avdeef and William P. Schaefer
pp 5153 - 5159; DOI:
10.1021/ja00433a017
PDF
Relation between magnetism and structure of iron(III) complexes exhibiting an S = 3/2 .dblharw. S = 5/2 spin state equilibrium. Structures of chloroform and water solvated tris(4-morpholinecarbodithioato-S,S')iron(III) and -manganese(III)
Raymond J. Butcher and Ekk Sinn
pp 5159 - 5168; DOI:
10.1021/ja00433a018
PDF
Nature of the iron-ligand bond in ferrous low spin hemoproteins studied by resonance Raman scattering
T. Kitagawa, Y. Kyogoku, T. Iizuka, and M. I. Saito
pp 5169 - 5173; DOI:
10.1021/ja00433a019
PDF
Tetrakis(methyl isocyanide)palladium(II) tetrakis(7,7,8,8-tetracyano-p-quinodimethane), [Pd(CNMe)4](TCNQ)4.2MeCN: synthesis, structure, and physical properties
Stephen Z. Goldberg, Richard Eisenberg, Joel S. Miller, and Arthur J. Epstein
pp 5173 - 5182; DOI:
10.1021/ja00433a020
PDF
Metal to ligand charge-transfer spectra in tetra-n-butylammonium dicyanoaurate(I)
W. Roy Mason
pp 5182 - 5187; DOI:
10.1021/ja00433a021
PDF
The electron paramagnetic resonance and optical spectra of vanadium hexacarbonyl
Kenneth A. Rubinson
pp 5188 - 5191; DOI:
10.1021/ja00433a022
PDF
The heat capacity, conductivity, and crystal structure of tetrathiafulvalenium 2,5-diethytetracyanoquinodimethane
Arthur J. Schultz, Galen D. Stucky, Robert Craven, Mark J. Schaffman, and Myron B. Salamon
pp 5191 - 5197; DOI:
10.1021/ja00433a023
PDF
Substituent effects on the stability of cation complexes of 4'-substituted monobenzo crown ethers
R. Ungaro, B. El Haj, and J. Smid
pp 5198 - 5202; DOI:
10.1021/ja00433a024
PDF
Chemically induced dynamic electron polarization. Ionic strength and radical concentration dependence
A. D. Trifunac
pp 5202 - 5206; DOI:
10.1021/ja00433a025
PDF
Studies on the formation of topological isomers by statistical methods
Giora Agam, Daniel Graiver, and Albert Zilkha
pp 5206 - 5214; DOI:
10.1021/ja00433a026
PDF
Synthesis of a catenane by a statistical double-stage method
Giora Agam and Albert Zilkha
pp 5214 - 5216; DOI:
10.1021/ja00433a027
PDF
Multiple n.pi.* transitions in tetramethyl-1,3-cyclobutanedione. I. Spectroscopic assignments
R. Spafford, J. Baiardo, J. Wrobel, and M. Vala
pp 5217 - 5225; DOI:
10.1021/ja00433a028
PDF
Multiple n.pi.* transitions in tetramethyl-1,3-cyclobutanedione. II. Through-bond effects
J. Baiardo, R. Spafford, and M. Vala
pp 5225 - 5228; DOI:
10.1021/ja00433a029
PDF
Carbon acidity. 53. Kinetic and equilibrium acidities of fluorinated bicycloalkanes
Andrew Streitwieser, David Holtz, Gene R. Ziegler, James O. Stoffer, M. Lee Brokaw, and Francois Guibe
pp 5229 - 5234; DOI:
10.1021/ja00433a030
PDF
Method for estimating the magnitude of equilibrium constants for covalent addition of nucleophilic reagents to heteroaromatic molecules
Ian H. Pitman and Larry A. Sternson
pp 5234 - 5238; DOI:
10.1021/ja00433a031
PDF
Evaluation of possible SN2 transition-state models for reaction of n-butyl chloride using chlorine kinetic isotope effects
Robert L. Julian and James W. Taylor
pp 5238 - 5248; DOI:
10.1021/ja00433a032
PDF
Transition state structure in gas phase thermolytic .beta.-elimination processes probed by isotope effect criteria
H. Kwart and J. J. Stanulonis
pp 5249 - 5253; DOI:
10.1021/ja00433a033
PDF
Hydrocarbon degenerate thermal rearrangements. A reinterpretation of the data and proposed mechanism for the (Z)-2-methylethylidenecyclobutane self-interconversion. Stereochemistry of cyclobutane ring openings
Joseph J. Gajewski
pp 5254 - 5261; DOI:
10.1021/ja00433a034
PDF
Oxyfunctionalization of hydrocarbons. 3. Superacid catalyzed oxygenation of alkanes with ozone involving protonated ozone, O3H+
George A. Olah, Norihiko Yoneda, and David G. Parker
pp 5261 - 5268; DOI:
10.1021/ja00433a035
PDF
Single-electron oxidation equilibriums of tetraalkylhydrazines. Comparison of solution E0 values and vapor-phase ionization potentials
S. F. Nelsen, V. Peacock, and G. R. Weisman
pp 5269 - 5277; DOI:
10.1021/ja00433a036
PDF
Electroinitiated Friedel-Crafts transalkylations in a room-temperature molten-salt medium
V. R. Koch, L. L. Miller, and R. A. Osteryoung
pp 5277 - 5284; DOI:
10.1021/ja00433a037
PDF
Nuclear magnetic resonance investigation of the spontaneous decarboxylation of oxalo-2-propionic acid
N. Y. Sakkab and A. E. Martell
pp 5285 - 5290; DOI:
10.1021/ja00433a038
PDF
Stereospecific aliphatic hydroxylation by iron-hydrogen peroxide. Evidence for a stepwise process
John T. Groves and Michael Van der Puy
pp 5290 - 5297; DOI:
10.1021/ja00433a039
PDF
Hydroboration. 43. Effect of structure on the reactivity of representative olefins toward hydroboration by 9-borabicyclo[3.3.1]nonane
Herbert C. Brown, Ronald Liotta, and Charles G. Scouten
pp 5297 - 5301; DOI:
10.1021/ja00433a040
PDF
Solvolysis of 1-substituted-2-adamantyl sulfonates. Bridging or no bridging?
D. Farcasiu
pp 5301 - 5305; DOI:
10.1021/ja00433a041
PDF
Intramolecular general base catalysis in aprotic solvents
Lucio Senatore, Ennio Ciuffarin, Mauro Isola, and Mario Vichi
pp 5306 - 5309; DOI:
10.1021/ja00433a042
PDF
One-flask synthesis of unsymmetrical phosphodiesters. Selective amine catalysis of the phosphorylation of primary vs. secondary alcohols
Fausto Ramirez, James F. Marecek, and Hiroshi Okazaki
pp 5310 - 5319; DOI:
10.1021/ja00433a043
PDF
Quenching of aromatic hydrocarbon singlets and aryl ketone triplets by alkyl disulfides
William L. Wallace, Richard P. Van Duyne, and Frederick D. Lewis
pp 5319 - 5326; DOI:
10.1021/ja00433a044
PDF
Solid-state chemistry of organic polyvalent iodine compounds. 8. Solid-state chemistry and molecular and crystal structures of two polymorphs of 1-methoxy-1,2-benziodoxolin-3-one
Margaret C. Etter
pp 5326 - 5331; DOI:
10.1021/ja00433a045
PDF
Solid-state chemistry of organic polyvalent iodine compounds. 9. Topotactic reactions of two polymorphs of 1-methoxy-1,2-benziodoxolin-3-one
Margaret C. Etter
pp 5331 - 5339; DOI:
10.1021/ja00433a046
PDF
Molecular criteria of solid-state structure in organic charge-transfer salts. 2. Effect of methyl substitution on stacking interactions of p-phenylenediamine cation radicals
Frank B. Kaufman
pp 5339 - 5344; DOI:
10.1021/ja00433a047
PDF
Absolute configuration of an ansa compound: gentisic acid nonamethylene ether
Leonard H. Schwartz and Baldev L. Bathija
pp 5344 - 5347; DOI:
10.1021/ja00433a048
PDF
Free radical studies of organophosphorus compounds. 7. The stereochemistries of alkoxy and thiyl radical oxidations of phosphines and cyclic phosphites. Possible permutational isomerization modes for phosphoranyl radicals
Wesley G. Bentrude, J. Howard Hargis, Nelson A. Johnson, Tae B. Min, Paul E. Rusek, Han-Wan Tan, and Richard A. Wielesek
pp 5348 - 5357; DOI:
10.1021/ja00433a049
PDF
Cyclic peptides. 14. Conformational energy and circular dichroism of proline-containing cyclic dipeptides
Vincent Madison, Paul E. Young, and Elkan R. Blout
pp 5358 - 5364; DOI:
10.1021/ja00433a050
PDF
Cyclic peptides. 15. Lanthanide-assisted carbon-13 and proton NMR analysis of preferred side-chain rotamers in proline-containing cyclic dipeptides
Paul E. Young, Vincent Madison, and Elkan R. Blout
pp 5365 - 5371; DOI:
10.1021/ja00433a051
PDF
Spatial configuration of ordered polynucleotide chains. 3. Polycyclonucleotides
Wilma K. Olson and Rama D. Dasika
pp 5371 - 5380; DOI:
10.1021/ja00433a052
PDF
Biosynthesis of griseofulvin
Constance M. Harris, Jill S. Roberson, and Thomas M. Harris
pp 5380 - 5386; DOI:
10.1021/ja00433a053
PDF
Reactions of di-.mu.-oxo-dioxodimolybdenum(2+) with mercaptans and implications for molybdoenzymes
W. E. Newton, Grace J. J. Chen, and John W. McDonald
pp 5387 - 5388; DOI:
10.1021/ja00433a054
PDF
Monomeric molybdenum(V) complexes showing hydrogen-1, hydrogen-2, and nitrogen-14 superhyperfine splitting in their electron paramagnetic resonance spectra. Implications for molybdenum enzymes
Narayanankutty Pariyadath, W. E. Newton, and Edward I. Stiefel
pp 5388 - 5390; DOI:
10.1021/ja00433a055
PDF
Metal atom synthesis of .eta.6-toluenebis(F-phenyl)cobalt(II) [.eta.6-C6H5CH3(C6F5)2Co], a new type of .pi.-arene complex. X-ray structure determination
B. B. Anderson, C. L. Behrens, L. J. Radonovich, and K. J. Klabunde
pp 5390 - 5391; DOI:
10.1021/ja00433a056
PDF
Isocyanide insertion rearrangements and their bonding to transition metal atoms
Richard D. Adams and Daniel F. Chodosh
pp 5391 - 5393; DOI:
10.1021/ja00433a057
PDF
Novel chiral triorganotin halides. Stabilization of optically active tin centers by intramolecular coordination
Gerard Van Koten and Jan G. Noltes
pp 5393 - 5395; DOI:
10.1021/ja00433a058
PDF
Synthesis of transition metal formyl compounds by nucleophilic attack of hydride on coordinated carbon monoxide
Charles P. Casey and Stephen M. Neumann
pp 5395 - 5396; DOI:
10.1021/ja00433a059
PDF
A new structural type for M3(CO)12 molecules and their derivatives. The molecular structure of decacarbonyl(1,2-diazine)triruthenium
F. A. Cotton and J. D. Jamerson
pp 5396 - 5397; DOI:
10.1021/ja00433a060
PDF
2,4,6-Tris(2-pyrimidyl)- and 2,4,6-tris(2-pyridyl)-1,3,5-triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)carboximidato chelate complex
E. I. Lerner and S. J. Lippard
pp 5397 - 5398; DOI:
10.1021/ja00433a061
PDF
Multiple metal-carbon bonds. 5. The reaction of niobium and tantalum neopentylidene complexes with the carbonyl function
Richard R. Schrock
pp 5399 - 5400; DOI:
10.1021/ja00433a062
PDF
Transition metal catalyzed asymmetric organic synthesis via polymer bound chiral ligands. Synthesis of R amino acids and hydratropic acid by hydrogenation
Naotake Takaishi, Hirosuke Imai, Christopher A. Bertelo, and J. K. Stille
pp 5400 - 5402; DOI:
10.1021/ja00433a063
PDF
Unusual selectivities in hydroformylations catalyzed by polymer-attached carbonylhydrotris(triphenylphosphine)rhodium
Charles U. Pittman and Ronnie M. Hanes
pp 5402 - 5405; DOI:
10.1021/ja00433a064
PDF
Reductive elimination of organometals by free radical chain mechanisms. Enhanced activation of .beta.-hydrogens in dialkylmercury
William A. Nugent and Jay K. Kochi
pp 5405 - 5406; DOI:
10.1021/ja00433a065
PDF
A covalently bound dimeric derivative of pyrochlorophyllide a. A Possible model for reaction center chlorophyll
S. G. Boxer and G. L. Closs
pp 5406 - 5408; DOI:
10.1021/ja00433a066
PDF
The absolute stereochemistries of 6,15-dihydro-6,15-ethanonaphtho[2.3-c]pentaphene and related homologs as determined by both exciton chirality and x-ray Bijvoet methods
Nobuyuki Harada, Yuki Takuma, and Hisashi Uda
pp 5408 - 5409; DOI:
10.1021/ja00433a067
PDF
Laser excitation of spin forbidden bands. Triplet photochemistry of cobalt(III) ammines
Cooper H. Langford and Carol P. J. Vuik
pp 5409 - 5410; DOI:
10.1021/ja00433a068
PDF
Enthalpy of the metal catalyzed isomerizations of quadricyclane and of tricyclo[4.1.0.02,7]heptane
Kenneth B. Wiberg and Helen A. Connon
pp 5411 - 5412; DOI:
10.1021/ja00433a069
PDF
Isolation and synthesis of pinoresinol diglucoside, a major antihypertensive principle of Tu-Chung (Eucommia ulmoides, Oliver)
Charles J. Sih, P. R. Ravikumar, Fu-Chih Huang, Carl Buckner, and Howard Whitlock
pp 5412 - 5413; DOI:
10.1021/ja00433a070
PDF
Strong acid chemistry. 3. Alkene-alkane alkylations in hydrofluoric acid-tantalum pentafluoride. Evidence for the presence of ethyl(1+) ion in solution
Michael Siskin
pp 5413 - 5414; DOI:
10.1021/ja00433a071
PDF
Structures of gonyautoxin II and III from the east coast toxic dinoflagellate Gonyaulax tamarensis
Yuzuru Shimizu, Lawrence J. Buckley, Maktoob Alam, Yasukatsu Oshima, William E. Fallon, Hiroshi Kasai, Iwao Miura, Vincent P. Gullo, and Koji Nakanishi
pp 5414 - 5416; DOI:
10.1021/ja00433a072
PDF
Book Reviews

pp 5416 - 5418; DOI:
10.1021/ja00433a600
PDF

Issue 18


Stabilization of planar tetracoordinate carbon
John B. Collins, James D. Dill, Eluvathingal D. Jemmis, Yitzhak Apeloig, Paul v. R. Schleyer, Rolf Seeger, and John A. Pople
pp 5419 - 5427; DOI:
10.1021/ja00434a001
PDF
Molecular orbital theory of the electronic structure of molecules. 30. Structure and energy of the phenyl cation
James D. Dill, Paul v. R. Schleyer, J. Stephen Binkley, Rolf Seeger, John A. Pople, and Edwin Haselbach
pp 5428 - 5431; DOI:
10.1021/ja00434a002
PDF
An MO study of the orientational selectivity in nucleophilic substitution reactions of polyhalobenzenes
Nick D. Epiotis and William Cherry
pp 5432 - 5435; DOI:
10.1021/ja00434a003
PDF
A theoretical analysis of the factors determining the conformations and stabilities of oxy- and thiocarbanions
Nicolaos D. Epiotis, Ronald L. Yates, Fernando Bernardi, and Saul Wolfe
pp 5435 - 5439; DOI:
10.1021/ja00434a004
PDF
Theory and application of photoelectron spectroscopy. 61. Detection of rotational isomers by variable temperature photoelectron spectroscopy. A new technique in the realm of molecular conformational analysis
Claus Mueller, Werner Schaefer, Armin Schweig, Nikolaus Thon, and Hans Vermeer
pp 5440 - 5443; DOI:
10.1021/ja00434a005
PDF
Isotopically selective spectroscopy and photochemistry of s-tetrazine in crystals and mixed crystals at low temperature
R. M. Hochstrasser and D. S. King
pp 5443 - 5450; DOI:
10.1021/ja00434a006
PDF
The nuclear magnetic resonance spectra of phosphabenzene, arsabenzene, and stibabenzene
Arthur J. Ashe, Robert R. Sharp, and John W. Tolan
pp 5451 - 5456; DOI:
10.1021/ja00434a007
PDF
Internal rotation in some oxalyl halides. A theoretical investigation
James Tyrrell
pp 5456 - 5459; DOI:
10.1021/ja00434a008
PDF
Gas phase molecular complexes. Multiple charge-transfer bands in the spectra of alkyl halide-iodine atom systems
Robert L. Strong and Jack A. Kaye
pp 5460 - 5464; DOI:
10.1021/ja00434a009
PDF
Electronic states of organic molecules. 2. Vibrational intensities for ethylene
Kenneth B. Wiberg and John J. Wendoloski
pp 5465 - 5469; DOI:
10.1021/ja00434a010
PDF
Heats of formation of disodium and dipotassium cyclooctatetraenide
Gerald R. Stevenson, Ignacio Ocasio, and Alex Bonilla
pp 5469 - 5473; DOI:
10.1021/ja00434a011
PDF
The dioxygen adduct of meso-tetraphenylporphyrinmanganese(II), a synthetic oxygen carrier
Brian M. Hoffman, Charles J. Weschler, and Fred Basolo
pp 5473 - 5482; DOI:
10.1021/ja00434a012
PDF
Protein control of porphyrin conformation. Comparison of resonance Raman spectra of heme proteins with mesoporphyrin IX analogs
Thomas G. Spiro and J. Michael Burke
pp 5482 - 5489; DOI:
10.1021/ja00434a013
PDF
The low temperature crystal and molecular structure of beryllium bis(octahydrotriborate), Be(B3H8)2
Joseph C. Calabrese, Donald F. Gaines, Steven J. Hildebrandt, and John H. Morris
pp 5489 - 5492; DOI:
10.1021/ja00434a014
PDF
Phosphorus ester basicity dependence on constraint. Crystal and molecular structures of P(OCH2)3CCH2Br and O:P(OCH2)2C(CH3)O
D. S. Milbrath, J. P. Springer, J. C. Clardy, and J. G. Verkade
pp 5493 - 5496; DOI:
10.1021/ja00434a015
PDF
Structure and conformation of cyclo(tri-L-prolyl) in the crystalline state
Mary E. Druyan, Charles L. Coulter, Roderich Walter, G. Kartha, and G. K. Ambady
pp 5496 - 5502; DOI:
10.1021/ja00434a016
PDF
Kinetics and mechanism of molybdate and tungstate complex formation with catechol derivatives
Katharine Gilbert and Kenneth Kustin
pp 5502 - 5512; DOI:
10.1021/ja00434a017
PDF
Intramolecular electron transfer mediated by 4,4'-bipyridine and related bridging groups
H. Fischer, G. M. Tom, and H. Taube
pp 5512 - 5517; DOI:
10.1021/ja00434a018
PDF
Mechanism of acetone bromination in methanol containing small amounts of water - competition between enol path and enol ether path
Jean Toullec and Jacques E. Dubois
pp 5518 - 5524; DOI:
10.1021/ja00434a019
PDF
Mechanism of lithium aluminum hydride reduction of ketones. Kinetics of reduction of mesityl phenyl ketone
E. C. Ashby and James R. Boone
pp 5524 - 5531; DOI:
10.1021/ja00434a020
PDF
Effects of reduction on the olefinic bond in two stilbene dilithium complexes
Michael Walczak and Galen Stucky
pp 5531 - 5539; DOI:
10.1021/ja00434a021
PDF
Halogen cleavage reactions of dicarbonyl-.eta.5-cyclopentadienyl-threo-.alpha.,.beta.-dideuteriophenethyliron(II)
D. A. Slack and M. C. Baird
pp 5539 - 5546; DOI:
10.1021/ja00434a022
PDF
The isomerization of bicyclo[2.1.0]pent-2-enes
William E. Farneth, Michael B. D'Amore, and John I. Brauman
pp 5546 - 5552; DOI:
10.1021/ja00434a023
PDF
Electronic effects in transition metal porphyrins. The reactions of imidazoles and pyridines with a series of para-substituted tetraphenylporphyrin complexes of chloroiron(III)
F. Ann Walker, Man-Wai Lo, and Molly T. Ree
pp 5552 - 5560; DOI:
10.1021/ja00434a024
PDF
Electrochemical reduction of sym-dibenzocyclooctatetraene, sym-dibenzo-1,5-cyclooctadiene-3,7-diyne, and sym-dibenzo-1,3,5-cyclooctatrien-7-yne
Hiroyuki Kojima, Allen J. Bard, Henry N. C. Wong, and Franz Sondheimer
pp 5560 - 5565; DOI:
10.1021/ja00434a025
PDF
Interaction of low-energy electrons with conjugated cyclic perchlorocarbons
Albert F. T. Chen and Costello L. Brown
pp 5565 - 5569; DOI:
10.1021/ja00434a026
PDF
Energy transfer from exciplexes to hydrocarbon quenchers in polar solvents
Hiroyasu Tachikawa and Larry R. Faulkner
pp 5569 - 5573; DOI:
10.1021/ja00434a027
PDF
Molecular rearrangements of excited states generated by intramolecular dioxetane scission. Photochemistry without light. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman, Gary E. Keck, and Janet L. Pflederer
pp 5574 - 5581; DOI:
10.1021/ja00434a028
PDF
Photochemical transformations of small-ring carbonyl compounds. 79. Involvement of enol tautomers in the photoisomerization of 3-substituted isochromanones
Albert Padwa and Andrew Au
pp 5581 - 5590; DOI:
10.1021/ja00434a029
PDF
Organofluorine synthesis via photofluorination: 3-fluoro-D-alanine and 2-deuterio analog, antibacterials related to the bacterial cell wall
J. Kollonitsch and L. Barash
pp 5591 - 5593; DOI:
10.1021/ja00434a030
PDF
Stable fluorinated cyclobutenyl cations
B. E. Smart and G. S. Reddy
pp 5593 - 5597; DOI:
10.1021/ja00434a031
PDF
Participation of the styrene group as a terminator of biomimetic polyene cyclizations. Formation of the trans-8-methylhydrindan ring system
William S. Johnson and Leonard A. Bunes
pp 5597 - 5602; DOI:
10.1021/ja00434a032
PDF
Structure sensitivity in the hydrogenation of hindered hydrocarbons
Harold H. Kung, Regis J. Pellet, and Robert L. Burwell
pp 5603 - 5611; DOI:
10.1021/ja00434a033
PDF
Silicon substitution for the stabilization of silicenium ions
Joseph B. Lambert and Hsiang-Ning Sun
pp 5611 - 5615; DOI:
10.1021/ja00434a034
PDF
Rearrangement of organosilyl groups between oxygen and nitrogen in tris(organosilyl)hydroxylamines: a possible dyotropic rearrangement
Peter Nowakowski and Robert West
pp 5616 - 5620; DOI:
10.1021/ja00434a035
PDF
Irreversible thermal rearrangement of tris(organosilyl)hydroxylamines
Robert West, Peter Nowakowski, and Philip Boudjouk
pp 5620 - 5627; DOI:
10.1021/ja00434a036
PDF
Correlation of rates of solvolysis of secondary tosylates with tertiary benzylic derivatives
Edward Norman Peters
pp 5627 - 5632; DOI:
10.1021/ja00434a037
PDF
Vinylic cations from solvolysis. 24. Degenerate .beta.-aryl rearrangements during the solvolysis of 1,2-dianisyl-2-phenylvinyl bromides and trianisylvinyl bromide. Free vinyl cations as intermediates
Yoram Houminer, Etta Noy, and Zvi Rappoport
pp 5632 - 5642; DOI:
10.1021/ja00434a038
PDF
A depressing specific salt effect on the hydrolysis of an iminium ion
John L. Hogg and William P. Jencks
pp 5643 - 5645; DOI:
10.1021/ja00434a039
PDF
Dilute acid-catalyzed amide hydrolysis: efficiency of the N-protonation mechanism
Andrew Williams
pp 5645 - 5651; DOI:
10.1021/ja00434a040
PDF
Metal ion and nucleophilic catalysis of pyridine-2-carbaldoximyl phosphate hydrolysis
Chih-Min Hsu and Barry S. Cooperman
pp 5652 - 5657; DOI:
10.1021/ja00434a041
PDF
Metal-ion catalysis of phosphoryl transfer via a ternary complex. Effects of changes in leaving group, metal ion, and attacking nucleophile
Chih-Min Hsu and Barry S. Cooperman
pp 5657 - 5663; DOI:
10.1021/ja00434a042
PDF
Aromatic nucleophilic substitution in nucleophilic surfactants. Comparison with alkoxide reactions
Clifford A. Bunton and Simon Diaz
pp 5663 - 5671; DOI:
10.1021/ja00434a043
PDF
Alkylation of pyridine 1-oxides and related compounds with activated acetylenes. A novel molecular rearrangement of heteroaromatic N-oxides
Rudolph A. Abramovitch, George Grins, Richard B. Rogers, and Ichiro Shinkai
pp 5671 - 5677; DOI:
10.1021/ja00434a044
PDF
Chemistry of N-haloamines. 25. Amination of acyclic and cyclic alkanes with trichloramine-aluminum chloride
Thomas A. Wnuk, Sohan S. Chaudhary, and Peter Kovacic
pp 5678 - 5682; DOI:
10.1021/ja00434a045
PDF
A comparison of the glutamate dehydrogenase catalyzed oxidation of NADPH by trinitrobenzenesulfonate with the uncatalyzed reaction
Allister Brown and Harvey F. Fisher
pp 5682 - 5688; DOI:
10.1021/ja00434a046
PDF
Nicotinamide coenzyme regeneration by dihydropyridine and pyridinium compounds
Keith E. Taylor and J. Bryan Jones
pp 5689 - 5694; DOI:
10.1021/ja00434a047
PDF
A reconsideration of the generation of silylenium ions in solution
Thomas J. Barton, Allan K. Hovland, and Christopher R. Tully
pp 5695 - 5696; DOI:
10.1021/ja00434a048
PDF
1,2-Hydrogen shifts in carbenes. The question of stereoelectronic control of migration
Evan P. Kyba and Carl W. Hudson
pp 5696 - 5697; DOI:
10.1021/ja00434a049
PDF
Photolysis of carbonyl ylides. Double-irradiation studies
G. W. Griffin, K. Ishikawa, and I. J. Lev
pp 5697 - 5699; DOI:
10.1021/ja00434a050
PDF
Photochemical reactions of cyclic, unsaturated diketones
Mordecai B. Rubin, Moshe Weiner, and Hans D. Scharf
pp 5699 - 5700; DOI:
10.1021/ja00434a051
PDF
Ion cyclotron resonance investigation of the decarbonylation of aldehydes by (.eta.5-cyclopentadienyl)nickel(1+)
Reed R. Corderman and J. L. Beauchamp
pp 5700 - 5702; DOI:
10.1021/ja00434a052
PDF
Boron analogs of amino acids. Synthesis and biological activity of boron analogs of betaine
Bernard F. Spielvogel, Leonard Wojnowich, Mrinal K. Das, Andrew T. McPhail, and Karl D. Hargrave
pp 5702 - 5703; DOI:
10.1021/ja00434a053
PDF
9,10-Dehydroanthracene. A derivative of 1,4-dehydrobenzene
O. L. Chapman, C. C. Chang, and J. Kolc
pp 5703 - 5705; DOI:
10.1021/ja00434a054
PDF
A novel heterometallic molecule consisting of a new triangular tungsten cluster bridged by oxochromium and alkoxy ligands
V. Katovic, J. L. Templeton, and R. E. McCarley
pp 5705 - 5706; DOI:
10.1021/ja00434a055
PDF
Disproportionation of lithium salts of radical anions of planar aromatic hydrocarbons in diethyl ether. Its large magnitude and correlation with the cation-anion Coulomb energy
G. Levin, B. E. Holloway, and M. Szwarc
pp 5706 - 5709; DOI:
10.1021/ja00434a056
PDF
Solvolyses of pseudo-geminal "equatorial" and "axial" systems of tris[2.2.2]paraxylylene and related compounds. An extremely large difference in rates due to phenyl conjugation and transannular interaction
Iwao Tabushi, Zenichi Yoshida, and Fumio Imashiro
pp 5709 - 5710; DOI:
10.1021/ja00434a057
PDF
Cadmium-113 Fourier transform nuclear magnetic resonance of cadmium(II) carbonic anhydrases and cadmium(II) alkaline phosphatase
Ian M. Armitage, Raymond T. Pajer, A. J. M. Schoot Uiterkamp, Jan F. Chlebowski, and Joseph E. Coleman
pp 5710 - 5712; DOI:
10.1021/ja00434a058
PDF
The use of carbon-13 spin lattice relaxation times for determining the position of the proton in an intramolecular hydrogen bond
L. M. Jackman and J. C. Trewella
pp 5712 - 5714; DOI:
10.1021/ja00434a059
PDF
Benzo[a]pyrene-nucleic acid derivative found in vivo: structure of a benzo[a]pyrenetetrahydrodiol epoxide-guanosine adduct
A. M. Jeffrey, K. W. Jennette, S. H. Blobstein, I. B. Weinstein, F. A. Beland, R. G. Harvey, H. Kasai, I. Miura, and K. Nakanishi
pp 5714 - 5715; DOI:
10.1021/ja00434a060
PDF
1,3-Dithietane
Eric Block, Eugene R. Corey, Robert E. Penn, Terry L. Renken, and Paul F. Sherwin
pp 5715 - 5717; DOI:
10.1021/ja00434a061
PDF
Thermolysis of bicyclo[2.2.0]hex-2-ene
M. J. Goldstein, R. S. Leight, and M. S. Lipton
pp 5717 - 5718; DOI:
10.1021/ja00434a062
PDF
Gnidimacrin and gnidimacrin 20-palmitate, novel macrocyclic antileukemic diterpenoid esters from Gnidia subcordata
S. Morris Kupchan, Yoshikazu Shizuri, Tatsushi Murae, James G. Sweeny, H. Richard Haynes, Ming-Shing Shen, James C. Barrick, Robert F. Bryan, Dick Van der Helm, and Kang K. Wu
pp 5719 - 5720; DOI:
10.1021/ja00434a063
PDF
Imidazolate-bridged complexes of copper(II)
G. Kolks, C. R. Frihart, H. N. Rabinowitz, and S. J. Lippard
pp 5720 - 5721; DOI:
10.1021/ja00434a064
PDF
The crystal and molecular structures of [(C6H5)4P]2Fe(S2C4O2)2 and [(C6H5)4P]2Fe(SC6H5)4, a structural analog of reduced rubredoxin
D. Coucouvanis, D. Swenson, N. C. Baenziger, D. G. Holah, A. Kostikas, A. Simpoulos, and V. Petrouleas
pp 5721 - 5723; DOI:
10.1021/ja00434a065
PDF
The influence of substituents on the molecular orbital energies and ground electronic states of substituted trimethylenemethanes
Barry K. Carpenter, R. Daniel Little, and Jerome A. Berson
pp 5723 - 5725; DOI:
10.1021/ja00434a066
PDF
Triplet ground states of trimethylenemethanes
Matthew S. Platz, J. M. McBride, R. Daniel Little, James J. Harrison, Andrew Shaw, Stephen E. Potter, and Jerome A. Berson
pp 5725 - 5726; DOI:
10.1021/ja00434a067
PDF
Trimethylenemethane. Experimental demonstration that the triplet state is the ground state
Robert J. Baseman, David W. Pratt, Mudan Chow, and Paul Dowd
pp 5726 - 5727; DOI:
10.1021/ja00434a068
PDF
Water soluble heterocyclophane as a novel class of inclusion host
Iwao Tabushi, Hideaki Sasaki, and Yasuhisa Kuroda
pp 5727 - 5728; DOI:
10.1021/ja00434a069
PDF
Freezing out the fluxional behavior in iron pentacarbonyl and other metal carbonyls
J. K. Burdett, J. M. Grzybowski, M. Poliakoff, and J. J. Turner
pp 5728 - 5729; DOI:
10.1021/ja00434a070
PDF
Synthesis and structure of a stable, crystalline complex of methyl isocyanate
Roger Richards and George Rouschias
pp 5729 - 5731; DOI:
10.1021/ja00434a071
PDF
Book Reviews

pp 5731 - 5732; DOI:
10.1021/ja00434a600
PDF

Issue 19


Macrocyclization equilibriums. 1. Theory
P. J. Flory, U. W. Suter, and M. Mutter
pp 5733 - 5739; DOI:
10.1021/ja00435a001
PDF
Macrocyclization equilibriums. 2. Poly(dimethylsiloxane)
U. W. Suter, M. Mutter, and P. J. Flory
pp 5740 - 5745; DOI:
10.1021/ja00435a002
PDF
Macrocyclization equilibriums. 3. Poly(6-aminocaproamide)
M. Mutter, U. W. Suter, and P. J. Flory
pp 5745 - 5748; DOI:
10.1021/ja00435a003
PDF
The conformational analysis of saturated heterocycles. 77. Rationalization of the equilibriums of tetraalkylhexahydro-1,2,4,5-tetrazines
Victor J. Baker, Alan R. Katritzky, Jean P. Majoral, Arnold R. Martin, and John M. Sullivan
pp 5748 - 5759; DOI:
10.1021/ja00435a004
PDF
Conformations of methylated cycloheptanones
M. St.-Jacques, C. Vaziri, D. A. Frenette, A. Goursot, and S. Fliszar
pp 5759 - 5765; DOI:
10.1021/ja00435a005
PDF
Model of hydrogen-bond interactions near the equilibrium configuration. Application to vibrational energy transfer in DF(v = n) DF(v = 0)
Hyung Kyu Shin
pp 5765 - 5772; DOI:
10.1021/ja00435a006
PDF
Internal energy effects on the reaction of hydrogen ion(H3+) with ethylene
Andre S. Fiaux, David L. Smith, and Jean H. Futrell
pp 5773 - 5780; DOI:
10.1021/ja00435a007
PDF
Positive ion chemistry of fluoromethylsilanes, (CH3)nSiF4-n(n = 1-3), by ion cyclotron resonance spectroscopy. Fluorine and methyl substituent effects on the relative stabilities of siliconium ions, R+, and disilylfluoronium ions, RR'F+, in the gas phase
M. K. Murphy and J. L. Beauchamp
pp 5781 - 5788; DOI:
10.1021/ja00435a008
PDF
Binding of dioxygen to metal complexes. The oxygen adduct of Co(acacen)
Alain Dedieu, Marie M. Rohmer, and Alain Veillard
pp 5789 - 5800; DOI:
10.1021/ja00435a009
PDF
Luminescence quenching of the tris(2,2'-bipyridine)ruthenium(II) and tris(1,10-phenanthroline)ruthenium(II) cations
J. N. Demas and J. W. Addington
pp 5800 - 5806; DOI:
10.1021/ja00435a010
PDF
Carbon-13 nuclear magnetic resonance spectroscopy of [1-13C] enriched monosaccharides. Signal assignments and orientational dependence of geminal and vicinal carbon-carbon and carbon-hydrogen spin-spin coupling constants
T. E. Walker, R. E. London, T. W. Whaley, R. Barker, and N. A. Matwiyoff
pp 5807 - 5813; DOI:
10.1021/ja00435a011
PDF
Metal-metal interactions involving metalloporphyrins. 4. A new antiferromagnetic phase of tetraphenylporphinatoiron(III) fluoride
Irwin A. Cohen, David A. Summerville, and Sophia R. Su
pp 5813 - 5816; DOI:
10.1021/ja00435a012
PDF
A carbon-13 and proton magnetic resonance examination of solute structures, equilibriums, and structural interconversions in some dinuclear .eta.5-dienylruthenium, -iron, and -nickel carbonyls
Otto A. Gansow, Aaron R. Burke, and William D. Vernon
pp 5817 - 5826; DOI:
10.1021/ja00435a013
PDF
A crystal field model for calculating Moessbauer quadrupole splittings of iron complexes. Application to pseudo-D3 and pseudo-D2h low-spin ferrous complexes
Susan C. Jackels, Ernest R. Davidson, and Norman J. Rose
pp 5826 - 5832; DOI:
10.1021/ja00435a014
PDF
Oxidative addition of benzyl halides to zero-valent palladium complexes. Inversion of configuration at carbon
K. S. Y. Lau, P. K. Wong, and J. K. Stille
pp 5832 - 5840; DOI:
10.1021/ja00435a015
PDF
Oxidative addition of alkyl halides to zero-valent palladium complexes. Mechanisms
J. K. Stille and K. S. Y. Lau
pp 5841 - 5849; DOI:
10.1021/ja00435a016
PDF
Bis(tertiary phosphine)palladium(0) and -platinum(0) complexes: preparations and crystal and molecular structures
S. Otsuka, T. Yoshida, M. Matsumoto, and K. Nakatsu
pp 5850 - 5858; DOI:
10.1021/ja00435a017
PDF
Circularly polarized emission studies on the chiral nuclear magnetic resonance lanthanide shift reagent tris(3-trifluoroacetyl-d-camphorato)europium(III)
Harry G. Brittain and F. S. Richardson
pp 5858 - 5863; DOI:
10.1021/ja00435a018
PDF
Proton acid catalyzed hydride transfer from alkanes to methylated benzyl cations. 3. Solvated alkanes as hydrogen-donating intermediates
Pieter Van Pelt and Henk M. Buck
pp 5864 - 5870; DOI:
10.1021/ja00435a019
PDF
Carbanions. Electron transfer vs. proton capture. 4. Products of base-catalyzed reactions of various 9-substituted fluorenes with aromatic nitro compounds
Robert D. Guthrie, David P. Wesley, George W. Pendygraft, and Ainslie T. Young
pp 5870 - 5877; DOI:
10.1021/ja00435a020
PDF
Carbanions. Electron transfer vs. proton capture. 5. Reaction of 9-methoxyfluorene with aromatic nitro compounds catalyzed by alkali metal and tetraalkylammonium methoxides
Robert D. Guthrie, George W. Pendygraft, and Ainslie T. Young
pp 5877 - 5883; DOI:
10.1021/ja00435a021
PDF
Meisenheimer complexes: a kinetic study of water and hydroxide ion attacks on 4,6-dinitrobenzofuroxan in aqueous solution
Francois Terrier, Francois Millot, and William P. Norris
pp 5883 - 5890; DOI:
10.1021/ja00435a022
PDF
Characterization of the solvent dependence of the nonbonded atom interaction energy by the stereoselectivity of asymmetric reactions
Fong-Jpi Hwang, Lawrence C. De Bolt, and Herbert Morawetz
pp 5890 - 5894; DOI:
10.1021/ja00435a023
PDF
Effects of stereochemistry on the rates of hydrogen-deuterium exchange of protons .alpha. to the nitrosamino group
Robert R. Fraser and L. K. Ng
pp 5895 - 5899; DOI:
10.1021/ja00435a024
PDF
Stereochemical and mechanistic aspects of the di-.pi.-methane rearrangement. Effect of structural constraints which preclude preferred modes
Patrick S. Mariano, Richard B. Steitle, Darrel G. Watson, Michael J. Peters, and Elliott Bay
pp 5899 - 5906; DOI:
10.1021/ja00435a025
PDF
Cyclohexadienyl cations. 6. Methyl group isotope effects in the dienone-phenol rearrangement
V. P. Vitullo and Elizabeth A. Logue
pp 5906 - 5909; DOI:
10.1021/ja00435a026
PDF
Excimer fluorescence and photodimerization of anthracenophanes and 1,2-dianthrylethanes
Toyoharu Hayashi, Noboru Mataga, Yoshiteru Sakata, Soichi Misumi, Masaharu Morita, and Jiro Tanaka
pp 5910 - 5913; DOI:
10.1021/ja00435a027
PDF
Photochemical cycloaddition of singlet and triplet diphenylvinylene carbonate with conjugated dienes
Frederick D. Lewis and Richard H. Hirsch
pp 5914 - 5924; DOI:
10.1021/ja00435a028
PDF
Stereomutation of 1-hydroxyallyl cations. Thermal and photochemical isomerizations of protonated enones
Ronald F. Childs, Eunice F. Lund, Allan G. Marshall, William J. Morrisey, and Carol V. Rogerson
pp 5924 - 5931; DOI:
10.1021/ja00435a029
PDF
Radical ions in photochemistry. 3. Photosensitized (electron transfer) cleavage of .beta.-phenethyl ethers
D. R. Arnold and A. J. Maroulis
pp 5931 - 5937; DOI:
10.1021/ja00435a030
PDF
Formation and thermal rearrangements of some dimers of butadiene and piperylene. Tests of the validity of thermochemical-kinetic arguments for identification of common biradical intermediates
Jerome A. Berson, Peter B. Dervan, Roger Malherbe, and Jerry A. Jenkins
pp 5937 - 5968; DOI:
10.1021/ja00435a031
PDF
Conformation of protected amino acids. V. Application of lanthanide-shift reagents for conformational studies of tert-butoxycarbonyl .alpha.-amino acid esters: equilibrium changes and kinetics of the isomerization
Horst Kessler and Michael Molter
pp 5969 - 5973; DOI:
10.1021/ja00435a032
PDF
Reductive demercuration of hex-5-enyl-1-mercuric bromide by metal hydrides. Rearrangement, isotope effects, and mechanism
Roderic P. Quirk and Robert E. Lea
pp 5973 - 5978; DOI:
10.1021/ja00435a033
PDF
Electrophilic substitution at saturated carbon in mercurials. Alkyl ligands as mechanistic probes in the cleavage of organometals
William A. Nugent and Jay K. Kochi
pp 5979 - 5988; DOI:
10.1021/ja00435a034
PDF
Dihydrodiols from anthracene and phenanthrene
D. M. Jerina, H. Selander, H. Yagi, Martha C. Wells, J. F. Davey, V. Mahadevan, and D. T. Gibson
pp 5988 - 5996; DOI:
10.1021/ja00435a035
PDF
Poly(vinylamine hydrochloride). Synthesis and utilization for the preparation of water-soluble polymeric dyes
Daniel J. Dawson, Richard D. Gless, and Robert E. Wingard
pp 5996 - 6000; DOI:
10.1021/ja00435a036
PDF
The formation of cyclic peroxides from unsaturated hydroperoxides: models for prostaglandin biosynthesis
Ned. A. Porter, Max O. Funk, Dennis Gilmore, Ramdas Isaac, and John Nixon
pp 6000 - 6005; DOI:
10.1021/ja00435a037
PDF
Biosynthetic studies with carbon-13 dioxide of secondary plant metabolites. Nicotiana alkaloids. 1. Initial experiments
C. Richard Hutchinson, M. T. Stephen Hsia, and Richard A. Carver
pp 6006 - 6011; DOI:
10.1021/ja00435a038
PDF
Chemical-structural properties of tetracycline derivatives. 1. Molecular structure and conformation of the free base derivatives
John J. Stezowski
pp 6012 - 6018; DOI:
10.1021/ja00435a039
PDF
Chemical-structural properties of tetracycline derivatives. 2. Coordination and conformational aspects of oxytetracycline metal ion complexation
Kurt H. Jogun and John J. Stezowski
pp 6018 - 6026; DOI:
10.1021/ja00435a040
PDF
Ultraviolet and .gamma.-ray-induced free-radical reactions of nucleic acid constituents. Selectivity of some reactions for purines. Suppression of the reactivity of pyrimidines
A. A. Frimer, A. Havron, D. Leonov, J. Sperling, and D. Elad
pp 6026 - 6033; DOI:
10.1021/ja00435a041
PDF
Fragmentation reaction of ylide. 5. A new metabolic reaction of aziridine derivatives
Y. Hata, M. Watanabe, T. Matsubara, and A. Touchi
pp 6033 - 6036; DOI:
10.1021/ja00435a042
PDF
Observation of ketenimine carboxylates and their conversion to four-membered heterocycles
D. J. Woodman, P. M. Stonebraker, and Larry Weiler
pp 6036 - 6037; DOI:
10.1021/ja00435a043
PDF
Rearrangements of free radicals. 5. Sigmatropic and electrocyclic reactions of bicyclo[3.1.0]hexenyl radical
Reiner Sustmann and Fritz Luebbe
pp 6037 - 6039; DOI:
10.1021/ja00435a044
PDF
A novel intramolecular exchange reaction between coordinated nitrosyl and nitro groups in cis-nitrosylnitrobis(dithiocarbamato)iron
Oliver A. Heperuma and Robert D. Feltham
pp 6039 - 6040; DOI:
10.1021/ja00435a045
PDF
Novel rhodium-catalyzed additions of carbon monoxide to reactive dienes and enones with formation of five-membered rings
R. F. Heldeweg and H. Hogeveen
pp 6040 - 6042; DOI:
10.1021/ja00435a046
PDF
Structure elucidation with lanthanide-induced shifts. The use of bound shifts and high-symmetry substrates
M. D. Johnston, D. J. Raber, N. K. DeGennaro, A. D'Angelo, and J. W. Perry
pp 6042 - 6044; DOI:
10.1021/ja00435a047
PDF
CIDNP evidence for stereoselectivity in the disproportionation of two cyclohexyl radicals
Peter Livant and Ronald G. Lawler
pp 6044 - 6045; DOI:
10.1021/ja00435a048
PDF
Intramolecular electron transfer induced by visible light
Debra A. Piering and John M. Malin
pp 6045 - 6046; DOI:
10.1021/ja00435a049
PDF
The remarkable alcoholysis reaction and structure of trans-bis(.alpha.-chlorovinyl)bis(dimethylphenylphosphine)platinum(II)
Robert A. Bell, Malcolm H. Chisholm, and Gary G. Christoph
pp 6046 - 6048; DOI:
10.1021/ja00435a050
PDF
Application of ion cyclotron resonance spectroscopic gas-phase basicities to the study of tautomeric equilibriums
M. J. Cook, A. R. Katritzky, M. Taagepera, T. D. Singh, and R. W. Taft
pp 6048 - 6049; DOI:
10.1021/ja00435a051
PDF
Intramolecular photochemical hydrogen abstraction reactions in the solid state. Correlation with x-ray crystal structure data
Alice A. Dzakpasu, Simon E. V. Phillips, John R. Scheffer, and James Trotter
pp 6049 - 6051; DOI:
10.1021/ja00435a052
PDF
Thermally induced decarbonylation of cage ketones
T. Tezuka, Y. Yamashita, and T. Mukai
pp 6051 - 6052; DOI:
10.1021/ja00435a053
PDF
A reactivity criterion of aromaticity and antiaromaticity in macrocyclic annulenes
Richard H. Wightman, Terry M. Cresp, and Franz Sondheimer
pp 6052 - 6053; DOI:
10.1021/ja00435a054
PDF
Unstable intermediates. 4. Thioformaldehyde
B. Solouki, P. Rosmus, and H. Bock
pp 6054 - 6055; DOI:
10.1021/ja00435a055
PDF
Quenching of olefin metathesis. Evidence for the generation of metal-carbene intermediates from noncarbenoid precursors
Paul G. Gassman and Thomas H. Johnson
pp 6055 - 6057; DOI:
10.1021/ja00435a056
PDF
Retrocarbene additions. Dissection of alkyl-substituted cyclopropanes under metathesis conditions
Paul G. Gassman and Thomas H. Johnson
pp 6057 - 6058; DOI:
10.1021/ja00435a057
PDF
Cyclopropane-olefin cross metathesis
Paul G. Gassman and Thomas H. Johnson
pp 6058 - 6059; DOI:
10.1021/ja00435a058
PDF
Model dehydrogenase reactions. Direct observation of a charge-transfer complex in a dihydronicotinamide reduction
Joseph Hajdu and David S. Sigman
pp 6060 - 6061; DOI:
10.1021/ja00435a059
PDF
Nasute termite soldier frontal gland secretions. 1. Structure of trinervi-2.beta.,3.alpha.,9.alpha.-triol 9-O-acetate, a novel diterpene from Trinervitermes soldiers
Glenn D. Prestwich, Steven P. Tanis, James P. Springer, and Jon Clardy
pp 6061 - 6062; DOI:
10.1021/ja00435a060
PDF
Nasute termite soldier frontal gland secretions. 2. Structures of trinervitene congeners from Trinervitermes soldiers
Glenn D. Prestwich, Steven P. Tanis, Frank G. Pilkiewicz, Iwao Miura, and Koji Nakanishi
pp 6062 - 6064; DOI:
10.1021/ja00435a061
PDF
Inelastic electron tunneling spectroscopy of carbon monoxide chemisorbed on alumina-supported transition metals
Paul K. Hansma, William C. Kaska, and R. M. Laine
pp 6064 - 6065; DOI:
10.1021/ja00435a062
PDF
Biogenetic-type syntheses of emodin and chrysophanol
Thomas M. Harris, Aileen D. Webb, Constance M. Harris, Philip J. Wittek, and Thomas P. Murray
pp 6065 - 6067; DOI:
10.1021/ja00435a063
PDF
Nuclear magnetic resonance in pulse radiolysis. Chemically induced dynamic nuclear polarization
A. D. Trifunac, K. W. Johnson, and R. H. Lowers
pp 6067 - 6068; DOI:
10.1021/ja00435a064
PDF
1,6-Methano[10]annulen-11-ylidene
Jane B. Carlton, Ronald H. Levin, and Jon Clardy
pp 6068 - 6070; DOI:
10.1021/ja00435a065
PDF
Ion structure determination by gas phase derivatization and collisional activation mass spectrometry
Paul P. Dymerski and F. W. McLafferty
pp 6070 - 6072; DOI:
10.1021/ja00435a066
PDF
Benzyl cation. A long-lived species in the gas phase?
Jose L. M. Abbound, Warren J. Hehre, and Robert W. Taft
pp 6072 - 6073; DOI:
10.1021/ja00435a067
PDF
Novel carbon-hydrogen bond cleavage by bis(dimethylphosphino)ethane complexes of iron, ruthenium, and osmium
S. D. Ittel, C. A. Tolman, A. D. English, and J. P. Jesson
pp 6073 - 6075; DOI:
10.1021/ja00435a068
PDF
Total synthesis of marasmic acid
W. J. Greenlee and R. B. Woodward
pp 6075 - 6076; DOI:
10.1021/ja00435a069
PDF
An electrochemical determination of the pKa of isobutane
Ronald Breslow and Richard Goodin
pp 6076 - 6077; DOI:
10.1021/ja00435a070
PDF
Book Reviews

pp 6078 - 6080; DOI:
10.1021/ja00435a600
PDF

Issue 20


Least motion paths in unimolecular decompositions
S. Ehrenson
pp 6081 - 6088; DOI:
10.1021/ja00436a001
PDF
Mechanism of ozonolysis. Ab initio study of the primary ozonide and its cleavage to the Criegee intermediate
Philippe C. Hiberty
pp 6088 - 6092; DOI:
10.1021/ja00436a002
PDF
The generalized valence bond description of the low-lying states of ketene
Lawrence B. Harding and William A. Goddard
pp 6093 - 6099; DOI:
10.1021/ja00436a003
PDF
Electronic structures of cephalosporins and penicillins. 5. Optical activity of the penicillin nucleus chromophores
Donald B. Boyd, Chin-Yah Yeh, and F. S. Richardson
pp 6100 - 6106; DOI:
10.1021/ja00436a004
PDF
Structure and force fields of the isomers of dinitrogen dioxide
Steen Skaarup, Per N. Skancke, and James E. Boggs
pp 6106 - 6109; DOI:
10.1021/ja00436a005
PDF
Vapor phase hydrogen bonding of 2,2,2-trifluoroethanol with acetone
Edwin E. Tucker and Sherril D. Christian
pp 6109 - 6111; DOI:
10.1021/ja00436a006
PDF
Kinetics of the gas phase reaction of pentafluoroethyl iodide with hydrogen iodide. Enthalpy of formation of the pentafluoroethyl radical and the .pi. bond dissociation energy in tetrafluoroethylene
E-Chung Wu and A. S. Rodgers
pp 6112 - 6115; DOI:
10.1021/ja00436a007
PDF
Kinetics of the gas phase addition of bromine to 1,1-difluoroethylene. .pi. Bond dissociation energy of 1,1-difluoroethylene
J. M. Pickard and A. S. Rodgers
pp 6115 - 6118; DOI:
10.1021/ja00436a008
PDF
Stabilities and energetics of pentacoordinated carbonium ions. The isomeric protonated ethane ions and some higher analogs: protonated propane and protonated butane
Kenzo Hiraoka and Paul Kebarle
pp 6119 - 6125; DOI:
10.1021/ja00436a009
PDF
Ionic solvation by aprotic solvents. Gas phase solvation of the alkali ions by acetonitrile
W. R. Davidson and P. Kebarle
pp 6125 - 6133; DOI:
10.1021/ja00436a010
PDF
Binding energies and stabilities of potassium ion complexes from studies of the gas phase ion equilibriums K+ + M = K+M
W. R. Davidson and P. Kebarle
pp 6133 - 6138; DOI:
10.1021/ja00436a011
PDF
MCD spectra of diphenylmethyl cation and anion. A test of the pairing theorem
Karl L. Tseng and Josef Michl
pp 6138 - 6141; DOI:
10.1021/ja00436a012
PDF
Comparison of enthalpies of hydrogen bonding determined by a gas-liquid chromatography method with those obtained by calorimetric or frequency shift methods
Craig S. Chamberlain and Russell S. Drago
pp 6142 - 6144; DOI:
10.1021/ja00436a013
PDF
Pulse radiolysis study of the reactions of some reduced metal ions with molecular oxygen in aqueous solution
Robin M. Sellers and Michael G. Simic
pp 6145 - 6150; DOI:
10.1021/ja00436a014
PDF
Alkyl cleavages from organomercurials. 2. Electron transfer process with hexachloroiridate(IV)
J. Y. Chen, H. C. Gardner, and J. K. Kochi
pp 6150 - 6159; DOI:
10.1021/ja00436a015
PDF
Metallointercalation reagents. Synthesis, characterization, and structural properties of thiolato(2,2',2''-terpyridine)platinum(II) complexes
K. W. Jennette, J. T. Gill, J. A. Sadownick, and S. J. Lippard
pp 6159 - 6168; DOI:
10.1021/ja00436a016
PDF
Applications of artificial intelligence for chemical inference. 22. Automatic rule formation in mass spectrometry by means of the meta-DENDRAL program
B. G. Buchanan, D. H. Smith, W. C. White, R. J. Gritter, E. A. Feigenbaum, J. Lederberg, and Carl Djerassi
pp 6168 - 6178; DOI:
10.1021/ja00436a017
PDF
Organometallic chemistry of the carbon-nitrogen double bond. 1. Nickel complexes prepared from iminium cations and the x-ray structure of {[(C6H5)3P]Ni[CH2N(CH3)2]Cl}
Dennis J. Sepelak, Cortlandt G. Pierpont, E. Kent Barefield, Jerome T. Budz, and Craig A. Poffenberger
pp 6178 - 6185; DOI:
10.1021/ja00436a018
PDF
Iminoketene cycloaddition. 1. A facile synthesis of quinazolone system by condensation of iminoketene with imines - a total synthesis of evodiamine and rutecarpine by retro mass-spectral synthesis
Tetsuji Kametani, Terumi Higa, Chu Van Loc, Masataka Ihara, Masuo Koizumi, and Keiichiro Fukumoto
pp 6186 - 6188; DOI:
10.1021/ja00436a019
PDF
Biomimetic polyene cyclizations. Asymmetric induction in the cyclization of a dienic acetal
William S. Johnson, Charles A. Harbert, Bruce E. Ratcliffe, and Robert D. Stipanovic
pp 6188 - 6193; DOI:
10.1021/ja00436a020
PDF
Substituent effects. 5. Resonance saturation effects in anilines having a .pi.-donor group in para position
A. J. Hoefnagel, M. A. Hoefnagel, and B. M. Wepster
pp 6194 - 6197; DOI:
10.1021/ja00436a021
PDF
Mechanism of aminolysis of .delta.-lactones. Kinetic behavior of tri-O-methyl-2-deoxyglucono-.delta.-lactone, solvent deuterium isotope effects, and transition-state characterization
Y. Pocker and Edmond Green
pp 6197 - 6202; DOI:
10.1021/ja00436a022
PDF
Favorskii-type ring contraction in bicyclic chloro ketones. A stereochemistry- and medium-dependent photochemical solvolysis
Guilford Jones and Lorraine P. McDonnell
pp 6203 - 6210; DOI:
10.1021/ja00436a023
PDF
Excited-state multiplicity for the direct photochemical isomerization of azomethine dyes
William G. Herkstroeter
pp 6210 - 6218; DOI:
10.1021/ja00436a024
PDF
Photochemical synthesis. 65. Thione photochemistry. 22. Intramolecular cyclization of aralkyl thiones from S2
A. Couture, K. Ho, M. Hoshino, P. De Mayo, R. Suau, and W. R. Ware
pp 6218 - 6225; DOI:
10.1021/ja00436a025
PDF
Electronic excited states of small ring compounds. 3: Cyclopropene, vinylcarbene, and vinylmethylene
D. R. Arnold, R. W. Humphreys, W. J. Leigh, and G. E. Palmer
pp 6225 - 6233; DOI:
10.1021/ja00436a026
PDF
Photochemistry of quaternary salts of 1,2-bispyridylethylenes. Heavy atom induced singlet-triplet intersystem crossing as a path for decay in charge-transfer exciplexes
Adolfo R. Gutierrez and David G. Whitten
pp 6233 - 6237; DOI:
10.1021/ja00436a027
PDF
Gas-phase reactivity of alkenes toward methylmercury cation
Robert D. Bach, A. Thomas Weibel, Joseph Patane, and Larry Kevan
pp 6237 - 6241; DOI:
10.1021/ja00436a028
PDF
Nuclear magnetic resonance studies on anion-exchange reactions of alkylmercury mercaptides
Robert D. Bach and A. Thomas Weibel
pp 6241 - 6249; DOI:
10.1021/ja00436a029
PDF
Nuclear magnetic resonance studies. 5. Properties of phosphorus-carbon ylides
Thomas A. Albright, Michael D. Gordon, Walter J. Freeman, and Edward E. Schweizer
pp 6249 - 6252; DOI:
10.1021/ja00436a030
PDF
Experimental and theoretical studies of the conformational and substituent dependencies of vicinal carbon-13-carbon-13 coupling constants. Impinging multiple rear-lobe effects
Michael Barfield, Shareen A. Conn, James L. Marshall, and Denis E. Miiller
pp 6253 - 6260; DOI:
10.1021/ja00436a031
PDF
Theoretical study of nucleophilic substitution on simple alkyl systems
J. J. Dannenberg
pp 6261 - 6265; DOI:
10.1021/ja00436a032
PDF
Intermediates in nucleophilic aromatic substitution. 15. Spiro Meisenheimer complex from catechol 2,4,6-trinitrophenyl ether. Rate-limiting proton transfer as a consequence of a very fast intramolecular nucleophilic attack
Claude F. Bernasconi and Hsien-Chang Wang
pp 6265 - 6270; DOI:
10.1021/ja00436a033
PDF
Triphase catalysis. Kinetics of cyanide displacement on 1-bromooctane
Steven L. Regen
pp 6270 - 6274; DOI:
10.1021/ja00436a034
PDF
Polar radicals. 9. Kinetics and mechanism of the vapor-phase bromination of 1-bromobutane
Dennis D. Tanner, Yoshio Kosugi, Richard Arhart, Naoto Wada, Tony Pace, and Tomoki Ruo
pp 6275 - 6284; DOI:
10.1021/ja00436a035
PDF
Stable carbocations. 195. Rearrangement of ethylenebenzenium ions to .alpha.-phenylethyl(styryl) cations. Determination of the relative energies of the .sigma.-bridged ethylenebenzenium ion, the open-chain 2-phenylethyl cation, and the .alpha.-styryl cation
George A. Olah, Robert J. Spear, and David A. Forsyth
pp 6284 - 6289; DOI:
10.1021/ja00436a036
PDF
Novel aromatic systems. 4. Cyclobutadiene dications
George A. Olah and John S. Staral
pp 6290 - 6304; DOI:
10.1021/ja00436a037
PDF
Stable carbocations. 187. Tertiary 2-benzonorbornenyl cations
George A. Olah and Gao Liang
pp 6304 - 6308; DOI:
10.1021/ja00436a038
PDF
Structures of modified cardenolides. 1. Lactam analogs of isodigitoxigenin
Douglas C. Rohrer, William L. Duax, Julio A. Munoz, and Manfred E. Wolff
pp 6308 - 6312; DOI:
10.1021/ja00436a039
PDF
Studies on the synthesis of vitamin B12. 1. Introduction and model studies
Robert V. Stevens, J. Michael Fitzpatrick, Paul B. Germeraad, Boyd L. Harrison, and Richard Lapalme
pp 6313 - 6317; DOI:
10.1021/ja00436a040
PDF
Studies on the synthesis of vitamin B12. 2. Synthesis of the "southern" half
Robert V. Stevens, Richard E. Cherpeck, Boyd L. Harrison, John Lai, and Richard Lapalme
pp 6317 - 6321; DOI:
10.1021/ja00436a041
PDF
Biosynthesis of shihunine in Dendrobium pierardii
Edward Leete and George B. Bodem
pp 6321 - 6325; DOI:
10.1021/ja00436a042
PDF
Incorporation of [2-14C]- and [6-14C]nicotinic acid into the tobacco alkaloids. Biosynthesis of anatabine and .alpha.,.beta.-dipyridyl
Edward Leete and Sheila A. Slattery
pp 6326 - 6330; DOI:
10.1021/ja00436a043
PDF
The mechanism of action of adenosylcobalamin
Bernard T. Golding and Leo Radom
pp 6331 - 6338; DOI:
10.1021/ja00436a044
PDF
Tautomerism in cytosine and 3-methylcytosine. A thermodynamic and kinetic study
M. Dreyfus, O. Bensaude, G. Dodin, and J. E. Dubois
pp 6338 - 6349; DOI:
10.1021/ja00436a045
PDF
sym-Oxepin oxide
William H. Rastetter
pp 6350 - 6353; DOI:
10.1021/ja00436a046
PDF
Proton magnetic resonance studies of sym-oxepin oxide
Daniel D. Haas and William H. Rastetter
pp 6353 - 6359; DOI:
10.1021/ja00436a047
PDF
Circular dichroism studies on .alpha.-L-glutamic acid oligomers in solution
Marguerite Rinaudo and Alain Domard
pp 6360 - 6364; DOI:
10.1021/ja00436a048
PDF
Ionic strength and pH effects on the rates of reduction of blue copper proteins by iron(EDTA)2-. Comparison of the reactivities of Pseudomonas aeruginosa azurin and bean plastocyanin with various redox agents
R. C. Rosenberg, Scot Wherland, R. A. Holwerda, and Harry B. Gray
pp 6364 - 6369; DOI:
10.1021/ja00436a049
PDF
Modification of the reactive sulfhydryl group in phosphofructokinase
Kenneth J. Schwartz, Y. Nakagawa, and E. T. Kaiser
pp 6369 - 6378; DOI:
10.1021/ja00436a050
PDF
Binuclear mixed valence rutheniumammine complexes with tert-butylmalononitrile as bridging ligand
Heinz Krentzien and Henry Taube
pp 6379 - 6380; DOI:
10.1021/ja00436a051
PDF
Biosynthesis of Cephalotaxus alkaloids. 2. Biosynthesis of the acyl portion of deoxyharringtonine
Ronald J. Parry, Daniel D. Sternbach, and Michael D. Cabelli
pp 6380 - 6382; DOI:
10.1021/ja00436a052
PDF
1,1-Dimethyl-2,3-bis(trimethylsilyl)-1-silirene, a stable silacyclopropene
Dietmar Seyferth, Dennis C. Annarelli, and Steven C. Vick
pp 6382 - 6384; DOI:
10.1021/ja00436a053
PDF
Electron-transfer reactions of excited states: direct evidence for reduction of the charge-transfer excited state of tris(2,2'-bipyridine)ruthenium(II)
Carol Creutz and Norman Sutin
pp 6384 - 6385; DOI:
10.1021/ja00436a054
PDF
Homoallylic interaction involving nitrogen lone pairs, a reexamination
John B. Grutzner
pp 6385 - 6387; DOI:
10.1021/ja00436a055
PDF
.eta.5-Cyclohexadienyltricarbonylchromium(0) intermediates in the reaction of carbanions with .eta.6-arenetricarbonylchromium(0)
M. F. Semmelhack, H. T. Hall, and M. Yoshifuji
pp 6387 - 6389; DOI:
10.1021/ja00436a056
PDF
Isosteganacin
Andrew S. Kende, Lanny S. Liebeskind, Clifford Kubiak, and Richard Eisenberg
pp 6389 - 6391; DOI:
10.1021/ja00436a057
PDF
Circumambulatory rearrangements of homotropylium cations: photoisomerization of 2-hydroxyhomotropylium cations
Ronald F. Childs and Carol V. Rogerson
pp 6391 - 6392; DOI:
10.1021/ja00436a058
PDF
Experimental study of the negative ion states of styrene. A test of the pairing theorem
P. D. Burrow, J. A. Michejda, and K. D. Jordan
pp 6392 - 6393; DOI:
10.1021/ja00436a059
PDF
Concerning the formation of compounds containing metal-to-metal multiple bonds. A stereospecific alkyl-for-chlorine exchange reaction involving compounds with tungsten-to-tungsten triple bonds
Malcolm H. Chisholm and Michael W. Extine
pp 6393 - 6395; DOI:
10.1021/ja00436a060
PDF
Reaction ergodography. Methane-tritium reaction
Shigeki Kato and Kenichi Fukui
pp 6395 - 6397; DOI:
10.1021/ja00436a061
PDF
Geometries of nitrilium betaines. The clarification of apparently anomalous reactions of 1,3-dipoles
Pierluigi Caramella and K. N. Houk
pp 6397 - 6399; DOI:
10.1021/ja00436a062
PDF
Cyclization and rearrangement in the reaction of allylbis(dimethylglyoximato)cobalt(III) complexes with tetracyanoethylene. Crystal structure of trans-3,3,4,4-tetracyano-2-phenylcyclopentylbis(dimethylglyoximato)imidazolecobalt(III)
D. Dodd, M. D. Johnson, I. P. Steeples, and E. D. McKenzie
pp 6399 - 6401; DOI:
10.1021/ja00436a063
PDF
Photochemistry of aromatic compounds. Photosolvolysis of 2-(3,5-dimethoxyphenyl)ethyl methanesulfonate
David A. Jaeger
pp 6401 - 6402; DOI:
10.1021/ja00436a064
PDF
Solution structure and ligand exchange in the five-coordinate molecular complexes NiX2(PMe3)3
Pierre Meier, Andre E. Merbach, Michele Dartiguenave, and Yves Dartiguenave
pp 6402 - 6403; DOI:
10.1021/ja00436a065
PDF
Anion cryptates: highly stable and selective macrotricyclic anion inclusion complexes
Ernest Graf and Jean M. Lehn
pp 6403 - 6405; DOI:
10.1021/ja00436a066
PDF
Chemical exploration of the C8H8S energy surface under conditions of mild thermal activation. Bond relocations and cycloadditions
A. G. Anastassiou, J. C. Wetzel, and B. Chao
pp 6405 - 6406; DOI:
10.1021/ja00436a067
PDF
Optical spectroscopic study of (Chl a.H2O)2 according to the proposed C2 symmetrical molecular structure for the P700 photoactive aggregate in photosynthesis
F. K. Fong, V. J. Koester, and J. S. Polles
pp 6406 - 6408; DOI:
10.1021/ja00436a068
PDF
Studies on the molecular association of oxytocin and related compounds in dimethyl sulfoxide
Jean P. Meraldi and Victor J. Hruby
pp 6408 - 6410; DOI:
10.1021/ja00436a069
PDF
5,8,16,19-Tetra-tert-butyl-6,17,23-trisdehydro[22]bi[10.10.2]annulene. A condensed nonbenzenoid aromatic system consisting of two 14.pi.-electron systems
Shuzo Akiyama, Masahiko Iyoda, and Masazumi Nakagawa
pp 6410 - 6412; DOI:
10.1021/ja00436a070
PDF
Reversal of stereospecificity during allylic hydroperoxidation of 3-norcarene and bicyclo[4.2.0]oct-3-ene derivatives arising from structurally enforced quenching of singlet oxygen by the hydrazide functionality
Leo A. Paquette, C. C. Liao, Dennis C. Liotta, and William E. Fristad
pp 6412 - 6413; DOI:
10.1021/ja00436a071
PDF
Endoperoxidation of conformationally fixed norcaradienes by singlet oxygen. Frontier molecular orbital basis for the operability of 1O2 quenching by hydrazides
Leo A. Paquette, Dennis C. Liotta, C. C. Liao, T. Gary Wallis, Nancy Eickman, Jon Clardy, and Rolf Gleiter
pp 6413 - 6416; DOI:
10.1021/ja00436a072
PDF
Mechanism of thermal decomposition of diazirine. Evidence for diazomethane intermediate
Barry M. Jennings and Michael T. H. Liu
pp 6416 - 6417; DOI:
10.1021/ja00436a073
PDF
A direct, stereocontrolled total synthesis of the 9,11-azo analog of the prostaglandin endoperoxide, PGH2
E. J. Corey, Koichi Narasaka, and Masakatsu Shibasaki
pp 6417 - 6418; DOI:
10.1021/ja00436a074
PDF
Optical to electrical energy conversion: cadmium telluride-based photoelectrochemical cells employing telluride/ditelluride electrolytes
Arthur B. Ellis, Steven W. Kaiser, and Mark S. Wrighton
pp 6418 - 6420; DOI:
10.1021/ja00436a075
PDF
Book Reviews

pp 6420 - 6426; DOI:
10.1021/ja00436a600
PDF

Issue 21


Excited potential energy hypersurfaces for hydrogen (H4) at trapezoidal geometries. Relation to photochemical 2s + 2s processes
Wolfgang Gerhartz, Ronald D. Poshusta, and Josef Michl
pp 6427 - 6443; DOI:
10.1021/ja00437a001
PDF
Properties of benzopyrene-DNA complexes investigated by fluorescence and triplet flash photolysis techniques
Nicholas E. Geacintov, Thaddeus Prusik, and John M. Khosrofian
pp 6444 - 6452; DOI:
10.1021/ja00437a002
PDF
Fluorescence detected circular dichroism. Theory
Ignacio Tinoco and Douglas H. Turner
pp 6453 - 6456; DOI:
10.1021/ja00437a003
PDF
Optical rotatory dispersion and absolute configuration. 18. Studies in the chiroptical properties of selenoamino acids
J. Cymerman Craig, S. Y. Catherine Lee, Goran Zdansky, and Arne Fredga
pp 6456 - 6459; DOI:
10.1021/ja00437a004
PDF
Anisotropic rotational diffusion and intramolecular motion in cyclic amino acids and peptides. An interpretation of carbon-13 spin-lattice relaxation data
R. L. Somorjai and Roxanne Deslauriers
pp 6460 - 6467; DOI:
10.1021/ja00437a005
PDF
Conformational energies and the random-coil dimensions and dipole moments of the polyoxides CH3O[(CH2)yO]xCH3
Akihiro Abe and James E. Mark
pp 6468 - 6476; DOI:
10.1021/ja00437a006
PDF
Conformational analysis of 2-methoxytetrahydropyran in relation to the anomeric effect
Akihiro Abe
pp 6477 - 6480; DOI:
10.1021/ja00437a007
PDF
Electron impact studies. C. Doubly charged negative ions
John H. Bowie and B. Jane Stapleton
pp 6480 - 6483; DOI:
10.1021/ja00437a008
PDF
Shape and angle strain in organic intermediates. A model study of alkyl radicals, anions, and cations
Eluvathingal D. Jemmis, Volker Buss, Paul v. R. Schleyer, and Leland C. Allen
pp 6483 - 6489; DOI:
10.1021/ja00437a009
PDF
Deuteron spin-lattice relaxations at axial and equatorial deuterons in 2,2,6,6-tetradeuterio-4-tert-butylcyclohexanone
Jan B. Wooten, Adolph L. Beyerlein, John Jacobus, and George B. Savitsky
pp 6490 - 6492; DOI:
10.1021/ja00437a010
PDF
Gaseous ionic acetylation of some substitute anisoles. Evidence for an intermediate .pi. complex
Dale A. Chatfield and Maurice M. Bursey
pp 6492 - 6495; DOI:
10.1021/ja00437a011
PDF
Polarization characteristics of flavin spectra. Specular reflectivity of bis(10-methylisoalloxazine)copper(II) perchlorate tetrahydrate
Mei W. Yu, Charles J. Fritchie, Anthony F. Fucaloro, and Basil G. Anex
pp 6496 - 6500; DOI:
10.1021/ja00437a012
PDF
Prediction of core electron binding energies with a four-parameter equation
William L. Jolly and Albert A. Bakke
pp 6500 - 6504; DOI:
10.1021/ja00437a013
PDF
A study of bridging and terminal carbonyl groups in transition metal complexes by x-ray photoelectron spectroscopy
Steven C. Avanzino and William L. Jolly
pp 6505 - 6507; DOI:
10.1021/ja00437a014
PDF
Modeling catalytic reactions with transition metal atoms. 1. Synthesis and characterization of reactive intermediates in the nickel-ethylene system, (C2H4)nNi (where n = 1, 2, or 3) in low temperature matrices
H. Huber, G. A. Ozin, and W. J. Power
pp 6508 - 6511; DOI:
10.1021/ja00437a015
PDF
Toward a theory of the spectral and magnetic properties of transition metal ions occupying low-symmetry sites in metalloproteins. Application of the angular overlap model to distorted tetrahedral tetrachlorocobaltate(2-) ions
William D. Horrocks and Dominick A. Burlone
pp 6512 - 6516; DOI:
10.1021/ja00437a016
PDF
The kinetics of ligand detachment from labile cobalt(II)-amine complexes in aqueous solution
J. Lilie, N. Shinohara, and M. G. Simic
pp 6516 - 6520; DOI:
10.1021/ja00437a017
PDF
Thermal decomposition of bis(phosphine)platinum(II) metallocycles
Joseph X. McDermott, John F. White, and George M. Whitesides
pp 6521 - 6528; DOI:
10.1021/ja00437a018
PDF
Synthesis and reactions of bis(cyclopentadienyl)titanium(IV) metallocycles
Joseph X. McDermott, Michael E. Wilson, and George M. Whitesides
pp 6529 - 6536; DOI:
10.1021/ja00437a019
PDF
Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by iron(III), chromium(III), and europium(III) ions
C. T. Lin, W. Boettcher, M. Chou, C. Creutz, and N. Sutin
pp 6536 - 6544; DOI:
10.1021/ja00437a020
PDF
Trifluoromethyldisulfane. A reactive nucleophile toward fluorinated acid halides
Craig A. Burton and Jean'ne M. Shreeve
pp 6545 - 6547; DOI:
10.1021/ja00437a021
PDF
Axial and equatorial phosphorus-oxygen basicity in a six-membered ring phosphate anion: effect of the countercation
A. P. Hong, J. B. Lee, and J. G. Verkade
pp 6547 - 6550; DOI:
10.1021/ja00437a022
PDF
High-resolution boron-11 nuclear magnetic resonance spectroscopy. 6. Application of relaxation time measurements to boron hydrides
Edward J. Stampf, Albert R. Garber, Jerome D. Odom, and Paul D. Ellis
pp 6550 - 6554; DOI:
10.1021/ja00437a023
PDF
The chemical evolution of a nitrogenase model. 12. Stoichiometric reduction of acetylene and of molecular nitrogen by mononuclear cyano complexes of oxomolybdate(IV)
E. L. Moorehead, P. R. Robinson, T. M. Vickrey, and G. N. Schrauzer
pp 6555 - 6561; DOI:
10.1021/ja00437a024
PDF
Organometallic reaction mechanisms. 14. Role of transition metal catalysts in the formation of aromatic pinacols and hydrols during Grignard reagent addition to ketones
E. C. Ashby, J. D. Buhler, I. G. Lopp, T. L. Wiesemann, J. S. Bowers, and J. T. Laemmle
pp 6561 - 6570; DOI:
10.1021/ja00437a025
PDF
Oxygen activation by transition metal complexes. 2. Bis(acetylacetonato)cobalt(II)-catalyzed oxidation of tributylphosphine
Robert P. Hanzlik and Dale Williamson
pp 6570 - 6573; DOI:
10.1021/ja00437a026
PDF
Three-electron oxidations. 11. Chromium(V) oxidation of alcohols
Fariza Hasan and Jan Rocek
pp 6574 - 6578; DOI:
10.1021/ja00437a027
PDF
Alkene epoxidation by intermediates formed during the ozonation of alkynes
Robert E. Keay and Gordon A. Hamilton
pp 6578 - 6582; DOI:
10.1021/ja00437a028
PDF
Molar ellipticity of the pure enantiomer by partial photoresolution. Photoreaction of 4,4,4',4'-tetramethyl-2,2,3',3'-tetraazaspiro[4.4]nona-2,2'-diene
Ruediger Blume, Hermann Rau, and Otto Schuster
pp 6583 - 6586; DOI:
10.1021/ja00437a029
PDF
Chemistry of exciplexes. 5. Photochemistry of anthracene in the presence and absence of dimethylaniline
N. C. Yang, David M. Shold, and Bongsub Kim
pp 6587 - 6596; DOI:
10.1021/ja00437a030
PDF
Solvent cage effect in the photolysis of azomethane in aqueous alcohols and other media: a semiempirical correlation with macroscopic solvent parameters
Neil Nodelman and J. C. Martin
pp 6597 - 6608; DOI:
10.1021/ja00437a031
PDF
Cyclopropyl triflates. Neighboring-group and solvent effects
Xavier Creary
pp 6608 - 6613; DOI:
10.1021/ja00437a032
PDF
Effect of surfactant micelles on the stereochemistry and rate of "amsylate" solvolytic displacement reactions in water
Chaim N. Sukenik and Robert G. Bergman
pp 6613 - 6623; DOI:
10.1021/ja00437a033
PDF
Molecular stereochemistry of a nitrogen-bridged metalloporphyrin: .mu.-nitrido-bis[.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatoiron]
W. Robert Scheidt, David A. Summerville, and Irwin A. Cohen
pp 6623 - 6628; DOI:
10.1021/ja00437a034
PDF
The crystal structure of 1-decyl .alpha.-D-glucopyranoside: a polar bilayer with a hydrocarbon subcell
Paul C. Moews and James R. Knox
pp 6628 - 6633; DOI:
10.1021/ja00437a035
PDF
X-ray and NMR studies on thiazolidines: crystal structure and conformational equilibriums of N-acetyl-2-(p-tolyl)thiazolidine-4-carboxylic acid ad related thiazolidine derivatives
R. Parthasarathy, B. Paul, and W. Korytnyk
pp 6634 - 6643; DOI:
10.1021/ja00437a036
PDF
Single-atom peri-bridged naphthalenes. 2. Synthesis, crystal structure, and reactions of naphtho[1,8-bc]thiete derivatives
Jerrold Meinwald, Spencer Knapp, S. Kay Obendorf, and Robert E. Hughes
pp 6643 - 6649; DOI:
10.1021/ja00437a037
PDF
Synthesis of cis- and trans-4a-phenyldecahydroisoquinolines
Dwight D. Weller and Henry Rapoport
pp 6650 - 6657; DOI:
10.1021/ja00437a038
PDF
Acetolysis of 4-homoadamantyl tosylate. Multiple degenerate rearrangements and mechanism
J. Eric Nordlander, John B. Hamilton, Felicia Y. H. Wu, Satya P. Jindal, and Robert R. Gruetzmacher
pp 6658 - 6669; DOI:
10.1021/ja00437a039
PDF
Interaction of .alpha.-L-aspartyl-L-phenylalanine methyl ester with the receptor site of the sweet taste bud
F. Lelj, T. Tancredi, P. A. Temussi, and C. Toniolo
pp 6669 - 6675; DOI:
10.1021/ja00437a040
PDF
Conformational studies on peptides. X-ray structure determinations of six N-methylated cyclic dipeptides derived from alanine, valine, and phenylalanine
Ettore Benedetti, Richard E. Marsh, and Murray Goodman
pp 6676 - 6684; DOI:
10.1021/ja00437a041
PDF
Nature of the amino-enzyme intermediate in pepsin-catalyzed reactions
Marc S. Silver, Mai Stoddard, and Michael H. Kelleher
pp 6684 - 6690; DOI:
10.1021/ja00437a042
PDF
Correlation between three-dimensional structure and reactivity for a series of locked substrates of chymotrypsin
P. S. Rodgers, L. C. G. Goaman, and D. M. Blow
pp 6690 - 6695; DOI:
10.1021/ja00437a043
PDF
A stable enolate complex from tetramethyl-3-thietanone and diiron nonacarbonyl: .mu.-O-.mu.-S-(2,4-dimethyl-4-thiolato-2-penten-3-olato)diiron hexacarbonyl
Bernhard Czauderna, Kurt H. Jogun, John J. Stezowski, and Baldur Foehlisch
pp 6696 - 6697; DOI:
10.1021/ja00437a044
PDF
Regiospecific homolytic displacement, with rearrangement, of cobaloxime(II) from allylcobaloxime(III) complexes by trichloromethyl radicals
B. Dass Gupta, Takuzo Funabiki, and Michael D. Johnson
pp 6697 - 6698; DOI:
10.1021/ja00437a045
PDF
Manganese(II) and manganese(III) 8-quinolinol complexes. Redox model for mitochondrial superoxide dismutase
John K. Howie and Donald T. Sawyer
pp 6698 - 6700; DOI:
10.1021/ja00437a046
PDF
Heats of formation of C3H5+ ions. Allyl, vinyl, and cyclopropyl cations in gas-phase proton-transfer reactions
Donald H. Aue, William R. Davidson, and Michael T. Bowers
pp 6700 - 6702; DOI:
10.1021/ja00437a047
PDF
The oxidation of amines with sulfonyl peroxides
Robert V. Hoffman
pp 6702 - 6704; DOI:
10.1021/ja00437a048
PDF
The structure of xylomollin, a secoiridoid hemiacetal acetal
Isao Kubo, Iwao Miura, and Koji Nakanishi
pp 6704 - 6705; DOI:
10.1021/ja00437a049
PDF
Thermal isomerization of (+)-(1S,2S)-trans,trans-2-methyl-1-propenylcyclopropane: quantification of four stereochemical paths in a vinylcyclopropane rearrangement
Gerald D. Andrews and John E. Baldwin
pp 6705 - 6706; DOI:
10.1021/ja00437a050
PDF
Stereochemical specificity in the vinylcyclopropane rearrangement vs. MINDO/3 calculations
Gerald D. Andrews and John E. Baldwin
pp 6706 - 6707; DOI:
10.1021/ja00437a051
PDF
Rearrangement of the o-tolyl radical to the benzyl radical at zero pressure
D. M. Brenner, G. P. Smith, and R. N. Zare
pp 6707 - 6708; DOI:
10.1021/ja00437a052
PDF
Models for copper-containing proteins: five-coordinate complexes of copper(I)
Robert R. Gagne
pp 6709 - 6710; DOI:
10.1021/ja00437a053
PDF
Pseudodilution, the solid-phase immobilization of benzyne
P. Jayalekshmy and Stephen Mazur
pp 6710 - 6711; DOI:
10.1021/ja00437a054
PDF
Charge-transfer-induced photosolvolysis of benzyl alcohols
Cheng-I Lin, Prithipal Singh, and Edwin F. Ullman
pp 6711 - 6713; DOI:
10.1021/ja00437a055
PDF
Symmetry vs. fluxionality, a radical anion with borderline properties
Stephen Mazur, C. Streekumar, and Albert H. Schroeder
pp 6713 - 6714; DOI:
10.1021/ja00437a056
PDF
The conversion of berberine into(.+-.)-.alpha.- and (.+-.)-.beta.-hydrastine
Jerome L. Moniot and Maurice Shamma
pp 6714 - 6715; DOI:
10.1021/ja00437a057
PDF
Reactions of silyl enol ethers and lactone enolates with dimethyl(methylene)ammonium iodide. The bis-.alpha.-methylenation of pre-vernolepin and pre-vernomenin
Samuel Danishefsky, Takeshi Kitahara, Robert McKee, and Paul F. Schuda
pp 6715 - 6717; DOI:
10.1021/ja00437a058
PDF
Synthetic methods and reactions. 17. Uranium hexafluoride, a convenient new oxidizing agent for organic synthesis
George A. Olah, John Welch, and Tse-Lok Ho
pp 6717 - 6718; DOI:
10.1021/ja00437a059
PDF
Mercury in organic chemistry. 9. A novel synthesis of .pi.-allylpalladium compounds
Richard C. Larock and Mark A. Mitchell
pp 6718 - 6720; DOI:
10.1021/ja00437a060
PDF
Alkylation of polyguanylic acid at the 2-amino group and phosphate by the potent mutagen (.+-.)-7.beta.,8.alpha.-dihydroxy-9.beta.,10.beta.-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene
Masato Koreeda, Patrick D. Moore, Haruhiko Yagi, Herman J. C. Yeh, and Donald M. Jerina
pp 6720 - 6722; DOI:
10.1021/ja00437a061
PDF
A total synthesis of d,l-luciduline by a regioselective intramolecular addition of an N-alkenylnitrone
Wolfgang Oppolzer and Martin Petrzilka
pp 6722 - 6723; DOI:
10.1021/ja00437a062
PDF
A total synthesis of gliotoxin
Tohru Fukuyama and Yoshito Kishi
pp 6723 - 6724; DOI:
10.1021/ja00437a063
PDF
Organocobalt cluster complexes. 20. Novel chemistry of acyl- and aroylmethylidynetricobalt nonacarbonyl complexes. Unusual thermal ketone decarbonylation reactions
Dietmar Seyferth, Mara O. Nestle, and C. Scott Eschbach
pp 6724 - 6726; DOI:
10.1021/ja00437a064
PDF
The biosynthesis of the lupine alkaloids. A reexamination
W. Marek Golebiewski and Ian D. Spenser
pp 6726 - 6728; DOI:
10.1021/ja00437a065
PDF
Complexed radicals. 3. Radical catalyzed epoxidation with oxygen
Christopher J. Michejda and Dwane H. Campbell
pp 6728 - 6729; DOI:
10.1021/ja00437a066
PDF
A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides
Shigeru Baba and Eiichi Negishi
pp 6729 - 6731; DOI:
10.1021/ja00437a067
PDF
The role of distance in electron transfer in solution. Experimental verification of the Hush-Marcus theory using mixed-valence complexes
Michael J. Powers, Dennis J. Salmon, Robert W. Callahan, and Thomas J. Meyer
pp 6731 - 6733; DOI:
10.1021/ja00437a068
PDF
Stoichiometric hydrogen reduction of carbon monoxide to methanol promoted by derivatives of bis(pentamethylcyclopentadienyl)zirconium
Juan M. Manriquez, Donald R. McAlister, Robert D. Sanner, and John E. Bercaw
pp 6733 - 6735; DOI:
10.1021/ja00437a069
PDF
Studies on transition metal complexes with cyclic carbene ligands. 4. Electrochemical oxidation of dicarbene metal carbonyl complexes. Isomerization via an electrochemical reaction with no net current flow
Reuben D. Rieke, Hiroyuki Kojima, and Karl Oefele
pp 6735 - 6737; DOI:
10.1021/ja00437a070
PDF
Polymer supported reagents. Chromic acid on anion exchange resins. A simple and practical oxidation of alcohols to aldehydes and ketones
G. Cainelli, G. Cardillo, M. Orena, and S. Sandri
pp 6737 - 6738; DOI:
10.1021/ja00437a071
PDF
Synthesis of tricyclo[3.3.3.02,6]undec-2(6)-ene. A novel bridgehead olefin
Robert Greenhouse, T. Ravindranathan, and Weston T. Borden
pp 6738 - 6739; DOI:
10.1021/ja00437a072
PDF
The relation between 15N13C coupling constants and hybridization
Jerome M. Schulman and Thomas Venanzi
pp 6739 - 6741; DOI:
10.1021/ja00437a073
PDF
The structure of chetomin
A. G. McInnes, A. Taylor, and J. A. Walter
pp 6741 - 6741; DOI:
10.1021/ja00437a074
PDF
Antineoplastic agents. 47. Structure of an antineoplastic agent from Streptomyces griseoluteus
George R. Pettit, Robert B. Von Dreele, Delbert L. Herald, Mark T. Edgar, and Harry B. Wood
pp 6742 - 6743; DOI:
10.1021/ja00437a075
PDF
Absolute rates of triplet-triplet dimerization and cycloaddition of trimethylenemethane biradicals
Matthew S. Platz and Jerome A. Berson
pp 6743 - 6744; DOI:
10.1021/ja00437a076
PDF
A functionalized trisecododecahedrane having C2 symmetry
Leo A. Paquette, Matthew J. Wyvratt, Otto Schallner, David F. Schneider, William J. Begley, and Robert M. Blankenship
pp 6744 - 6745; DOI:
10.1021/ja00437a077
PDF
Preparation and reactivity of dithioether dications [R2S+-+SR2]: a new functional group
W. Kenneth Musker and Patricia B. Roush
pp 6745 - 6746; DOI:
10.1021/ja00437a078
PDF
4-Homoadamanten-4-yl triflate. Ring contraction and ion pair return in trifluoroethanol
Richard Partch and Dan Margosian
pp 6746 - 6747; DOI:
10.1021/ja00437a079
PDF
The ene reaction as a route to 3-hydroxycyclopentanone derivatives. Application to the prostaglandins
Gilbert Stork and George Kraus
pp 6747 - 6748; DOI:
10.1021/ja00437a080
PDF
Austin, a novel polyisoprenoid mycotoxin from Aspergillus ustus
K. K. Chexal, James P. Springer, Jon Clardy, Richard J. Cole, Jerry W. Kirksey, Joe W. Dorner, Horace G. Cutler, and Billy J. Strawter
pp 6748 - 6750; DOI:
10.1021/ja00437a081
PDF
Thallium in organic synthesis. 44. Oxidative rearrangements via oxythallation with thallium(III) nitrate supported on clay
Edward C. Taylor, Chih-Shu Chiang, A. McKillop, and J. F. White
pp 6750 - 6752; DOI:
10.1021/ja00437a082
PDF
Propellanes. 12. A bridgehead olefin transoid in a six-membered ring. Formation of a stable cyclopropanone
Philip Warner and Shih-Lai Lu
pp 6752 - 6753; DOI:
10.1021/ja00437a083
PDF
Stabilization of aryldiazonium ions by crown ether complexation
Richard A. Bartsch, Hsien Chen, Neil F. Haddock, and Pedro N. Juri
pp 6753 - 6754; DOI:
10.1021/ja00437a084
PDF
Potassium hexamethoxyphosphate
Donald B. Denney, Dorothy Z. Denney, and Chi-Fei Ling
pp 6755 - 6755; DOI:
10.1021/ja00437a085
PDF
In situ generation and intramolecular trapping of o-xylylenes by cobalt-catalyzed acetylene cooligomerizations. A one-step synthesis of polycycles
Raymond L. Funk and K. Peter C. Vollhardt
pp 6755 - 6757; DOI:
10.1021/ja00437a086
PDF
Structure of tetrakis(N,N-diethylmonothiocarbamato)titanium(IV). A limitation on Orgel's rule
William L. Steffen, Stephen L. Hawthorne, and Robert C. Fay
pp 6757 - 6758; DOI:
10.1021/ja00437a087
PDF
Reaction of strained acetylenes with molecular oxygen. A novel chemiluminescent reaction, evidence for a dioxetene, and a mechanism for thermal generation of singlet oxygen
Nicholas J. Turro, V. Ramamurthy, Kou-Chang Liu, Adolf Krebs, and Reinhard Kemper
pp 6758 - 6761; DOI:
10.1021/ja00437a088
PDF
Optical detection of magnetic resonance of glucagon and glucagon peptides in solution. A conformational change related to critical length of the peptide chain
J. B. Alexander Ross, Kenneth W. Rousslang, David A. Deranleau, and Alvin L. Kwiram
pp 6761 - 6762; DOI:
10.1021/ja00437a089
PDF
The irreversible inhibition of mouse brain .gamma.-aminobutyric acid (GABA)-.alpha.-ketoglutaric acid transaminase by gabaculine
R. R. Rando and F. W. Bangerter
pp 6762 - 6764; DOI:
10.1021/ja00437a090
PDF
Additions and Corrections - Stereochemistry of Metal Anion Substitutions on Carbon
G. S. Koermer, M. L . Hall, and T. G. Traylor
pp 6764 - 6764; DOI:
10.1021/ja00437a600
PDF
Additions and Corrections - Photochemical Rearrangement of β-tert-Butylstyrenes. Stereochemistry.
Stephen S. Hixson, and Timothy P. Cutler
pp 6764 - 6764; DOI:
10.1021/ja00437a601
PDF
Additions and Corrections - Substituent Effects on π-π Rearrangements. Methyl Migration in β-tert-Butylstyrenes.
Stephen S. Hixson, and Timothy P. Cutler
pp 6764 - 6764; DOI:
10.1021/ja00437a602
PDF
Additions and Corrections - Arylcyclopropane Photochemistry. A Photochemical Probe into the Stereoelectronic Requirements for Excited State Interaction between Aromatic and Cyclopropane Rings in Arylcyclopropanes.
Stephen S. Hixson, and Joseph Borovsky
pp 6765 - 6765; DOI:
10.1021/ja00437a603
PDF
Additions and Corrections - Arylcyclopropane Photochemistry. The Role of Orbital Overlap Control in the Photochemical Cis-Trans Isomerization of Arylcyclopropanes.
Stephen S. Hixson, and Joseph Borovsky
pp 6765 - 6765; DOI:
10.1021/ja00437a604
PDF
Additions and Corrections - Peracid Oxidation of Imines. Kinetics and Mechanism of Competitive Formation of Nitrones and Oxaziranes from Cyclic and Acyclic Imines.
Yoshiro Ogata, and Yashuhiko Sawaki
pp 6765 - 6765; DOI:
10.1021/ja00437a605
PDF
Additions and Corrections - Neighboring Group Effect in Heme-Carbon Monoxide Bonding
C. K. Chang, and T. G. Traylor
pp 6765 - 6765; DOI:
10.1021/ja00437a606
PDF
Additions and Corrections - a Fluxional, Catalytically Active Metal Cluster, Ni4[CNC)CH3)3]7
V. W. Day, R.O. Day, J. S. Kristoff, F. J. Hirsekorn, and E. L. Muetterties
pp 6765 - 6765; DOI:
10.1021/ja00437a607
PDF
Additions and Corrections - Biosynthetic Studies Using 13C Enriched Precursors on the 16-Membered Macrolide Antiobiotic Leucomycin
S. Omura, A. Nakagawa, H. Takeshima, K. Atsumi, J. Miyazawa, F. Piriou, and G. Lukacs
pp 6765 - 6765; DOI:
10.1021/ja00437a608
PDF
Additions and Corrections - Electronic Relaxation Processes in Retinol and Retinal: Anomalous External Heavy-Atom Effects and Temperature Dependence of Fluorescence
Pill-Soon Song, Quae Chae, Masahisa Fujita, and Hiroaki Baba
pp 6765 - 6765; DOI:
10.1021/ja00437a609
PDF
Additions and Corrections - An Intramolecular Model for the Enzymatic Insertion of Coenzyme B12 into Unactivated Carbon-Hydrogen Bonds
Ronald Breslow, and Pyare L. Khanna
pp 6765 - 6765; DOI:
10.1021/ja00437a610
PDF
Additions and Corrections - Nitrogen Inversion Rates in Bicyclo[2.2.2]octyl Hydrazines and Amines by 13C NMR
S. F. Nelsen, and G. R. Wesiman
pp 6765 - 6765; DOI:
10.1021/ja00437a611
PDF
Additions and Corrections - A Synthesis of N-Substituted 1,2-Dihydropyridines
John N. Bonfiglio, Iltifat Hasan, John J. Piwinski, Barry Weinstein, and Frank W. Fowler
pp 6765 - 6765; DOI:
10.1021/ja00437a612
PDF
Additions and Corrections - Assessment of the Thioallylic Rearrangement by a Simplified Technique for High-Precision Measurement of Isotope Effects
H. Kwart, and J. Stanulonis
pp 6765 - 6765; DOI:
10.1021/ja00437a613
PDF
Additions and Corrections - Relative Nucleophilicity of Common Nucleophiles toward Sulfinyl Sulfur. Comparison of the Relative Reactivity of Different Nucleophiles toward Sulfinyl vs. Sulfonyl Sulfur
John L. Kice, and Lawrence F. Mullan
pp 6766 - 6766; DOI:
10.1021/ja00437a614
PDF
Additions and Corrections - Exciplex Photolysis. III. Kinetics of Fluorescence Quenching of α-Cyanonaphthalene by Dimethylcyclopentene-1,2 in Hexane
Desmond V. O'Connor, and William R. Ware
pp 6766 - 6766; DOI:
10.1021/ja00437a615
PDF
Additions and Corrections - Multiple Metal-Carbon Bonds. 5. The Reaction of Niobium and Tantalum Neopentylidene Complexes with the Carbonyl Function
Richard R. Schrock
pp 6766 - 6766; DOI:
10.1021/ja00437a616
PDF
Additons and Corrections - Additions and Corrections for "Preparation and Properties of Uranocene, Di-π-cyclooctatetraeneuranium(IV)
A. Streitwieser, U. Muller-Westerhoff, G. Sonnichsen, F. Mares, D. G. Morrell, Keith O. Hodgson, and C. A. Harmon
pp 6766 - 6766; DOI:
10.1021/ja00437a617
PDF
Book Reviews

pp 6766 - 6770; DOI:
10.1021/ja00437a618
PDF

Issue 22


Composition of trajectory calculations, transition state theory, quantum mechanical reaction probabilities, and rate constants for the collinear reaction atomic H + Cl2→HCl + Cl
Donald G. Truhlar, Jean A. Merrick, and James W. Duff
pp 6771 - 6783; DOI:
10.1021/ja00438a001
PDF
Chemical consequences of orbital interactions. 3. Energetic impact of monohomoaromaticity
William L. Jorgensen
pp 6784 - 6789; DOI:
10.1021/ja00438a002
PDF
Degree of order of lamellar and hexagonal mesophases with and without cholesterol additions
F. Y. Fujiwara and L. W. Reeves
pp 6790 - 6798; DOI:
10.1021/ja00438a003
PDF
Conformational analysis. 118. Application of the molecular-mechanics method to alcohols and ethers
N. L. Allinger and D. Y. Chung
pp 6798 - 6803; DOI:
10.1021/ja00438a004
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 26. Quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals
G. Brunton, D. Griller, L. R. C. Barclay, and K. U. Ingold
pp 6803 - 6811; DOI:
10.1021/ja00438a005
PDF
Temperature dependence of the reaction of oxygen atoms with olefins
D. L. Singleton and R. J. Cvetanovic
pp 6812 - 6819; DOI:
10.1021/ja00438a006
PDF
Hydration of ammonium fluoride
Peter Kollman and Irwin Kuntz
pp 6820 - 6825; DOI:
10.1021/ja00438a007
PDF
Solvated electron reaction rates in alcohols and water. Solvent effect
Gerald L. Bolton and Gordon R. Freeman
pp 6825 - 6830; DOI:
10.1021/ja00438a008
PDF
Dye laser-induced photodissociation of C7H8+ ions in gaseous toluene
John R. Eyler
pp 6831 - 6834; DOI:
10.1021/ja00438a009
PDF
Isomerization of protonated cyclopropane cations
Paul P. Dymerski, Richard M. Prinstein, P. F. Bente, and F. W. McLafferty
pp 6834 - 6836; DOI:
10.1021/ja00438a010
PDF
Molecular orbital theory of the electronic structure of organic compounds. 25. Conformations of methyl- and fluoro-substituted cyclopentanes and cyclohexanes
D. Cremer, J. S. Binkley, and J. A. Pople
pp 6836 - 6839; DOI:
10.1021/ja00438a011
PDF
General rules for constructing Hueckel molecular orbital characteristic polynomials
Junichi Aihara
pp 6840 - 6844; DOI:
10.1021/ja00438a012
PDF
Unrestricted open-shell calculations by MINDO/3. Geometries and electronic structure of radicals
P. Bischof
pp 6844 - 6849; DOI:
10.1021/ja00438a013
PDF
Extent of localization of orbitals in loges and the electron pair concept
Mel Levy
pp 6849 - 6851; DOI:
10.1021/ja00438a014
PDF
Correlation effects on barriers to proton transfer in intramolecular hydrogen bonds. The enol tautomer of malondialdehyde studied by ab initio SCF-CI calculations
G. Karlstrom, B. Jonsson, B. Roos, and H. Wennerstrom
pp 6851 - 6854; DOI:
10.1021/ja00438a015
PDF
Optical to electrical energy conversion. Characterization of cadmium sulfide and cadmium selenide based photoelectrochemical cells
Arthur B. Ellis, Steven W. Kaiser, and Mark S. Wrighton
pp 6855 - 6866; DOI:
10.1021/ja00438a016
PDF
Electrochemical studies on sulfur and sulfides in aluminum chloride-sodium chloride melts
Knut A. Paulsen and Robert A. Osteryoung
pp 6866 - 6872; DOI:
10.1021/ja00438a017
PDF
Electrochemical and electron paramagnetic resonance studies of a series of ammonium and phosphonium compounds
Reuben D. Rieke, C. Kenneth White, and Charles M. Milliren
pp 6872 - 6877; DOI:
10.1021/ja00438a018
PDF
Exchange and inversion in 2-methylbutyllithium: proton nuclear magnetic resonance line shapes at 300 MHz
Gideon Fraenkel, William E. Beckenbaugh, and Ping Pin Yang
pp 6878 - 6885; DOI:
10.1021/ja00438a019
PDF
Nitrogen-15 nuclear magnetic resonance spectroscopy. The nebramycin aminoglycosides
Douglas E. Dorman, Jonathan W. Paschal, and Kurt E. Merkel
pp 6885 - 6888; DOI:
10.1021/ja00438a020
PDF
ESR and ENDOR studies of the .pi. cation radical of bacteriochlorophyll
D. C. Borg, A. Forman, and J. Fajer
pp 6889 - 6893; DOI:
10.1021/ja00438a021
PDF
Carbon-13 NMR studies of 9-methyl-9-azabicyclo[3.3.1]nonane and related compounds
S. F. Nelsen, G. R. Weisman, E. L. Clennan, and V. E. Peacock
pp 6893 - 6896; DOI:
10.1021/ja00438a022
PDF
Conformation of 4-vinylpyridine in the gas phase. A microwave spectroscopic investigation
Wiktor M. Ralowski, P. Johan Mjoberg, and Stig O. Ljunggren
pp 6897 - 6899; DOI:
10.1021/ja00438a023
PDF
Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes
Judy Schander and B. R. Russell
pp 6900 - 6904; DOI:
10.1021/ja00438a024
PDF
Ultrasonic absorption kinetic studies of the complexation of aqueous potassium and cesium ions by 18-crown-6
Gerard W. Liesegang, Michael M. Farrow, Neil Purdie, and Edward M. Eyring
pp 6905 - 6908; DOI:
10.1021/ja00438a025
PDF
Skeletal molecular structure of monocarbahexaborane from microwave spectral studies
Gary L. McKown, Betsey P. Don, Robert A. Beaudet, Phillip J. Vergamini, and Llewellyn H. Jones
pp 6909 - 6912; DOI:
10.1021/ja00438a026
PDF
Oxidation of olefins by palladium(II). 9. Mechanism of the oxidation of olefins by the dimeric species, disodium dipalladium hexaacetate, in acetic acid
Saul Winstein, John McCaskie, Hing-Biu Lee, and Patrick M. Henry
pp 6913 - 6918; DOI:
10.1021/ja00438a027
PDF
Restricted rotation in amides. 8. Steric and electronic effects on lanthanide-amide equilibriums
Anita H Lewin and R. Alekel
pp 6919 - 6922; DOI:
10.1021/ja00438a028
PDF
Synthesis and structure of dilithium octamethyldirhenate(III)
F. Albert Cotton, Larry D. Gage, Kostas Mertis, Larry W. Shive, and Geoffrey Wilkinson
pp 6922 - 6926; DOI:
10.1021/ja00438a029
PDF
Rate controlling proton transfer in the complexing of copper(II) and nickel(II) by 2-aminomethylpyridine
R. H. Voss and R. B. Jordan
pp 6926 - 6932; DOI:
10.1021/ja00438a030
PDF
Synthesis, characterization, and x-ray structure of .eta.5-cyclopentadienyltris(N,N-dimethyldithiocarbamato)zirconium(IV)
Alan H. Bruder, Robert C. Fay, David F. Lewis, and Alice A. Sayler
pp 6932 - 6938; DOI:
10.1021/ja00438a031
PDF
The importance of side chain intramolecular interaction on the stereochemical course of the 2-carbon deuteration of amino acids complexed to cobalt(III)
William E. Keyes, Ruth E. Caputo, Roger D. Willett, and J. Ivan Legg
pp 6939 - 6945; DOI:
10.1021/ja00438a032
PDF
Five-coordinate amino acid complexes. Synthesis and characterization of nickel(II), copper(II), and zinc(II) complexes of 1,5-diazacyclooctane-N-monoacetic acid
Michael H. West and J. Ivan Legg
pp 6945 - 6951; DOI:
10.1021/ja00438a033
PDF
Sulfur-bridged binuclear iron(II) complexes. Effect of ligand constraints on their physical properties; reactions with carbon monoxide and alkyl isocyanides
Kenneth D. Karlin and Stephen J. Lippard
pp 6951 - 6957; DOI:
10.1021/ja00438a034
PDF
Orbitally dependent exchange in two sulfur-bridged binuclear iron(II) complexes. Magnetic exchange in transition metal complexes. 11
A. P. Ginsberg, M. E. Lines, K. D. Karlin, S. J. Lippard, and F. J. DiSalvo
pp 6958 - 6966; DOI:
10.1021/ja00438a035
PDF
Direct measurement of spin-state lifetimes in solution for some iron(II) spin equilibrium complexes derived from hexadentate ligands
Mitchell A. Hoselton, Russell S. Drago, Lon J. Wilson, and Norman Sutin
pp 6967 - 6969; DOI:
10.1021/ja00438a036
PDF
Synthesis and Moessbauer spectra of octaethylporphyrin ferrous complexes
David Dolphin, John R. Sams, Tsang Bik Tsin, and Kit L. Wong
pp 6970 - 6975; DOI:
10.1021/ja00438a037
PDF
High pressure studies. 21. Volume changes for base-catalyzed hydrolysis of p-nitrophenyl esters
Robert C. Neuman, George D. Lockyer, and Janine Marin
pp 6975 - 6978; DOI:
10.1021/ja00438a038
PDF
Intramolecular nucleophilic aminolysis of aliphatic esters. Cyclization of methyl 2-aminomethylbenzoate to phthalimidine
Thomas H. Fife and Bruce R. DeMark
pp 6978 - 6982; DOI:
10.1021/ja00438a039
PDF
Flow nuclear magnetic resonance investigation of the transient and stable species formed by the attack of alkoxide ions on 2,4,6-trinitrotoluene
Colin A. Fyfe, Chris D. Malkiewich, Sadrudin W. H. Damji, and Albert R. Norris
pp 6983 - 6988; DOI:
10.1021/ja00438a040
PDF
Gas-phase methylene reactions with carbonyls. 1. Propanal
T. L. Rose and P. J. Fuqua
pp 6988 - 6993; DOI:
10.1021/ja00438a041
PDF
Metathetical transposition of bis-tert-alkyl ketones. 1. A model for a study of group migration
J. E. Dubois and P. Bauer
pp 6993 - 6999; DOI:
10.1021/ja00438a042
PDF
Metathetical transposition of bis-tert-alkyl ketones. 2. Structural effects on alkyl migration. Existence of linear relation networks
P. Bauer and J. E. Dubois
pp 6999 - 7007; DOI:
10.1021/ja00438a043
PDF
Conformational preferences of hexahydropyridazine derivatives
G. R. Weisman and S. F. Nelsen
pp 7007 - 7013; DOI:
10.1021/ja00438a044
PDF
Conformational analysis of intramolecular hydrogen-bonded amino alcohols. Determination of the NH/N-electron pair equilibrium and assignment of conformational free energies for interactions in decahydroquinoline and piperidine compounds in a dilute nonpolar medium
Herbert S. Aaron and C. Parker Ferguson
pp 7013 - 7017; DOI:
10.1021/ja00438a045
PDF
Application of a modification of the Polonovski reaction to the synthesis of vinblastine-type alkaloids
Nicole Langlois, Francoise Gueritte, Yves Langlois, and Pierre Potier
pp 7017 - 7024; DOI:
10.1021/ja00438a046
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl
B. Maillard, D. Forrest, and K. U. Ingold
pp 7024 - 7026; DOI:
10.1021/ja00438a047
PDF
Stable carbocations. 196. 3-Tricyclo[3.2.1.02,7]octyl (3-homonortricyclyl) cations. Steric criteria in degenerate cyclopropylcarbinyl rearrangements and the classical vs. nonclassical nature of cyclopropylcarbinyl cations
George A. Olah and Gao Liang
pp 7026 - 7033; DOI:
10.1021/ja00438a048
PDF
Cytochrome c peroxidase catalyzed oxidations of substitution inert iron(II) complexes
W. L. Purcell and James E. Erman
pp 7033 - 7037; DOI:
10.1021/ja00438a049
PDF
Catalysis of internucleotide bond formation by divalent metal ions
Hiroaki Sawai
pp 7037 - 7039; DOI:
10.1021/ja00438a050
PDF
Organic photochemistry. 16. Photochemical hydrogen abstraction reactions proceeding through five-membered transition states. Product control through restriction of rotation in diradical intermediates
John R. Scheffer, Barry M. Jennings, and John P. Louwerens
pp 7040 - 7048; DOI:
10.1021/ja00438a051
PDF
Titration properties of homodinucleoside monophosphates. Determination of overlapping ionization constants and intramolecular stacking equilibrium quotients of ApA, CpC, GpG, and UpU
Naotake Ogasawara and Yasuo Inoue
pp 7048 - 7053; DOI:
10.1021/ja00438a052
PDF
Titration and temperature-dependent properties of homodinucleoside monophosphates. Evaluation of stacking equilibrium quotients for neutral and half-ionized ApA, CpC, GpG, and UpU
Naotake Ogasawara and Yasuo Inoue
pp 7054 - 7060; DOI:
10.1021/ja00438a053
PDF
Catalysis of decarboxylation of nitrobenzisoxazolecarboxylic acid and of cyanophenylacetic acid by modified polyethylenimines
Junghun Suh, Ioannis S. Scarpa, and Irving M. Klotz
pp 7060 - 7064; DOI:
10.1021/ja00438a054
PDF
Substituent effects on the solution conformation of rifamycin S
M. F. Dampier, C. W. Chen, and H. W. Whitlock
pp 7064 - 7069; DOI:
10.1021/ja00438a055
PDF
Studies on the mode of action of the mitomycin antibiotics. Reversible conversion of mitomycin C into sodium 7-aminomitosane-9a-sulfonate
Ulfert Hornemann, Yau-Kwan Ho, Jesse K. Mackey, and Suresh C. Srivastava
pp 7069 - 7074; DOI:
10.1021/ja00438a056
PDF
Determination of the secondary structure of proteins by laser Raman spectroscopy
J. L. Lippert, D. Tyminski, and P. J. Desmeules
pp 7075 - 7080; DOI:
10.1021/ja00438a057
PDF
Heterocyclobutanylidenes. A unique synthesis of tetramethylallene episulfide
Alfred G. Hortmann and Anup Bhattacharjya
pp 7081 - 7082; DOI:
10.1021/ja00438a058
PDF
The temperature dependence of an electron impact induced stereoselective rearrangement reaction
Mark M. Green, Thomas J. Mangner, Stuart P. Turner, and F. J. Brown
pp 7082 - 7083; DOI:
10.1021/ja00438a059
PDF
A new entry into the synthesis of the nine-membered indole alkaloids related to cleavamine. A stereospecific synthesis of (dl)-4.alpha.-dihydrocleavamine and (dl)-quebrachamine via the thio-Claisen rearrangement
Seiichi Takano, Michiyasu Hirama, Tsutomu Araki, and Kunio Ogasawara
pp 7084 - 7085; DOI:
10.1021/ja00438a060
PDF
The ferraborane B5H9Fe(CO)3 and its conjugate base B5H8Fe(CO)3-
T. P. Fehlner, J. Ragaini, M. Mangion, and S. G. Shore
pp 7085 - 7086; DOI:
10.1021/ja00438a061
PDF
Oxidative decarboxylation of a tripeptide. The reaction of copper(II) hydroxide and glycylglycyl-L-histidine
Patrice De Meester and Derek J. Hodgson
pp 7086 - 7087; DOI:
10.1021/ja00438a062
PDF
Photochemistry in the electronic ground state. 4. Infrared laser induced isomerization of labeled compounds. A possible route for isotope separation
Ilana Glatt and Amnon Yogev
pp 7087 - 7088; DOI:
10.1021/ja00438a063
PDF
Fluxional isomerization of cyclobutadiene
E. A. Halevi, F. A. Matsen, and T. L. Welsher
pp 7088 - 7090; DOI:
10.1021/ja00438a064
PDF
The nuclear Overhauser enhancement of the phosphorus-31 magnetic resonance spectrum of inorganic orthophosphate in aqueous and nonaqueous media
Thomas Glonek
pp 7090 - 7092; DOI:
10.1021/ja00438a065
PDF
Tumor inhibitors. 119. Baccharin, a novel potent antileukemic trichothecene triepoxide from Baccharis megapotamica
S. Morris Kupchan, Bruce B. Jarvis, Richard G. Dailey, William Bright, Robert F. Bryan, and Yoshikazu Shizuri
pp 7092 - 7093; DOI:
10.1021/ja00438a066
PDF
[Mo3(OAc)6(CH3CH2O)2(H2O)3]2+ and other new products of the reaction between molybdenum hexacarbonyl and acetic acid
A. Bino, M. Ardon, I. Maor, M. Kaftory, and Z. Dori
pp 7093 - 7095; DOI:
10.1021/ja00438a067
PDF
The [6 + 4] cycloadditions of diethylaminobutadiene to fulvenes. A new synthesis of azulenes
Lee C. Dunn, Yau-Min Chang, and K. N. Houk
pp 7095 - 7096; DOI:
10.1021/ja00438a068
PDF
Bond fixation in annulenes. 4. The ability of 1,2,3-trimethylcyclooctatetraene to support optical activity
Leo A. Paquette, John M. Gardlik, and James M. Photis
pp 7096 - 7098; DOI:
10.1021/ja00438a069
PDF
The structure of the fluorescent adduct formed in the reaction of o-phthalaldehyde and thiols with amines
S. Stoney Simons and David F. Johnson
pp 7098 - 7099; DOI:
10.1021/ja00438a070
PDF
Emission spectroscopy and state ordering of retinals
Takeshi Takemura, P. K. Das, Gordon Hug, and Ralph S. Becker
pp 7099 - 7101; DOI:
10.1021/ja00438a071
PDF
Electronic isotopic substitution in flow and stopped flow nuclear magnetic resonance studies of chemical reactions
Colin A. Fyfe, William E. Sanford, and Costantino S. Yannoni
pp 7101 - 7102; DOI:
10.1021/ja00438a072
PDF
Remote double bond migration via rhodium catalysis: a novel enone transposition
Paul A. Grieco, Mugio Nishizawa, Nebojsa Marinovic, and William J. Ehmann
pp 7102 - 7104; DOI:
10.1021/ja00438a073
PDF
The reaction of tertiary ethynyl alcohols with formamide acetals: formation of dienamines and enamine orthoformates
Kathlyn A. Parker, Raymond W. Kosley, Stephen L. Buchwald, and Joseph J. Petraitis
pp 7104 - 7105; DOI:
10.1021/ja00438a074
PDF
A new method for the preparation of sequential polypeptides using matrix-controlled thermal polymerization
Maria Sakarellos-Daitsiotis, Chaim Gilon, Constantinos Sakarellos, and Murray Goodman
pp 7105 - 7107; DOI:
10.1021/ja00438a075
PDF
Remarkably stable organoboranes derived from the hydroboration of olefins with 9-borabicyclo[3.3.1]nonane. Utilization to achieve the successful synthesis of stereospecific derivatives in 1-substituted cyclooctenes and similar related derivatives
Hiroaki Taniguchi, Lazaro Brener, and Herbert C. Brown
pp 7107 - 7108; DOI:
10.1021/ja00438a076
PDF
Aporphines. 22. Electrochemical synthesis of aporphines via cathodic cyclization of iodobenzylisoquinolinium salts
Raphael Gottlieb and John L. Neumeyer
pp 7108 - 7109; DOI:
10.1021/ja00438a077
PDF
Oligomerization stereochemistry of vinyl monomers. 2. Effect of ion pair structure on the methylation stereochemistry of 1,3-di(2-pyridyl)butane anion
C. F. Tien and T. E. Hogen-Esch
pp 7109 - 7110; DOI:
10.1021/ja00438a078
PDF
A chiral synthesis of D-(+)-2,6-dideoxystreptamine and its microbial incorporation into novel antibiotics
Jeanine Cleophax, Stephan D. Gero, Jean Leboul, Muhammad Akhtar, John E. G. Barnett, and Cedric J. Pearce
pp 7110 - 7112; DOI:
10.1021/ja00438a079
PDF
Electrochemical generation of a dimeric macrocyclic complex
Francis C. McElroy and James C. Dabrowiak
pp 7112 - 7113; DOI:
10.1021/ja00438a080
PDF
Resonance Raman spectra of heme proteins at low temperature
P. M. Champion, D. W. Collins, and D. B. Fitchen
pp 7114 - 7115; DOI:
10.1021/ja00438a081
PDF
Allylic cyanobis(methylthio)methylation. Insertion of a functionalized carbon in an allylic carbon-hydrogen bond
Barry B. Snider, Nicholas J. Hrib, and Laszlo Fuzesi
pp 7115 - 7117; DOI:
10.1021/ja00438a082
PDF
Book Reviews

pp 7117 - 7118; DOI:
10.1021/ja00438a600
PDF

Issue 23


Structure and reactivity of the hypervalent phosphoranyl radicals
James M. Howell and John F. Olsen
pp 7119 - 7127; DOI:
10.1021/ja00439a001
PDF
Ionic cycloreversion reactions in tetralin derivatives. Structure of C8H8O ions from 1-tetralol
Michael L. Gross and Fred L. DeRoos
pp 7128 - 7132; DOI:
10.1021/ja00439a002
PDF
Application of the principle of least motion to organic reactions. 4. More complex molecular rearrangements
Julianna A. Altmann, O. S. Tee, and Keith Yates
pp 7132 - 7138; DOI:
10.1021/ja00439a003
PDF
Evaluation and comparison of pattern classifiers for chemical applications
Leonard J. Soltzberg, Charles L. Wilkins, Steven L. Kaberline, T. Fai Lam, and Thomas R. Brunner
pp 7139 - 7144; DOI:
10.1021/ja00439a004
PDF
Evaluation and comparison of pattern classifiers for chemical applications: adaptive digital learning networks and linear discriminants
Leonard J. Soltzberg, Charles L. Wilkins, Steven L. Kaberline, T. Fai Lam, and T. L. Brunner
pp 7144 - 7151; DOI:
10.1021/ja00439a005
PDF
All-electron nonempirical calculations of potential surfaces. 4. Abstraction reactions of chlorine on methane
Edwin L. Motell and William H. Fink
pp 7152 - 7156; DOI:
10.1021/ja00439a006
PDF
Lanthanide porphyrin complexes. Evaluation of nuclear magnetic resonance dipolar probe and shift reagent capabilities
William D. Horrocks and Ching-Ping Wong
pp 7157 - 7162; DOI:
10.1021/ja00439a007
PDF
Limitations of lanthanide shift reagents for determination of conformation of nonrigid molecules
Glenn R. Sullivan
pp 7162 - 7169; DOI:
10.1021/ja00439a008
PDF
Conformational analysis of carbocyanine dyes with variable-temperature proton Fourier transform nuclear magnetic resonance spectroscopy
P. M. Henrichs and S. Gross
pp 7169 - 7175; DOI:
10.1021/ja00439a009
PDF
Evidence for the electronic states of recoil carbon atoms undergoing reaction
Kathleen K. Taylor, Hans J. Ache, and Alfred P. Wolf
pp 7176 - 7178; DOI:
10.1021/ja00439a010
PDF
Electronic states of organic molecules. 3. Photoelectron spectra of cycloalkenes and methylenecycloalkanes
Kenneth B. Wiberg, G. Barney Ellison, John J. Wendoloski, C. R. Brundle, and N. A. Kuebler
pp 7179 - 7182; DOI:
10.1021/ja00439a011
PDF
Molecular structure of acrolein electronic states
Clifford E. Dykstra
pp 7182 - 7187; DOI:
10.1021/ja00439a012
PDF
Theory and application of photoelectron spectroscopy. 69. Thieno[3,4-c]thiophenes. Electronic structure
Claus Mueller, Armin Schweig, Michael P. Cava, and M. V. Lakshmikantham
pp 7187 - 7189; DOI:
10.1021/ja00439a013
PDF
Electron transmission studies of the negative ion states of substituted benzenes in the gas phase
K. D. Jordan, J. A. Michejda, and P. D. Burrow
pp 7189 - 7191; DOI:
10.1021/ja00439a014
PDF
The development of quantum mechanical solvent effect models. Macroscopic electrostatic contributions
James H. McCreery, Ralph E. Christoffersen, and George G. Hall
pp 7191 - 7197; DOI:
10.1021/ja00439a015
PDF
The development of quantum mechanical solvent effect models. Microscopic electrostatic contributions
Jane H. McCreery, Ralph E. Christoffersen, and George G. Hall
pp 7198 - 7202; DOI:
10.1021/ja00439a016
PDF
Photoelectron ejection from tetraaminoethylenes in aromatic hydrocarbons. Role of the molecular "Rydberg" state in excited charge-transfer states and long-range electron-transfer processes
Yoshihiro Nakato
pp 7203 - 7208; DOI:
10.1021/ja00439a017
PDF
Molecular orbital studies of electron donor-acceptor complexes. 3. Energy and charge decomposition analyses for several strong complexes: carbon monoxide-borane, ammonia-borane, methylamine-borane, trimethylamine-borane, and ammonia-boron trifluoride
Hideaki Umeyama and Keiji Morokuma
pp 7208 - 7220; DOI:
10.1021/ja00439a018
PDF
Reaction path analysis. 2. The nine-atom family
L. J. Guggenberger and E. L. Muetterties
pp 7221 - 7225; DOI:
10.1021/ja00439a019
PDF
Synthesis and chemical characterization of platinum carbonyl dianions [Pt3(CO)6]n2- (n = .apprx.10,6,5,4,3,2,1). A new series of inorganic oligomers
G. Longoni and P. Chini
pp 7225 - 7231; DOI:
10.1021/ja00439a020
PDF
Reaction of a disilene and benzaldehyde
Thomas J. Barton and John A. Kilgour
pp 7231 - 7234; DOI:
10.1021/ja00439a021
PDF
Stable homopolyatomic anions of the post-transition metals. "Zintl ions". The synthesis and structure of a salt containing the heptantimonide(3-) anion
Douglas G. Adolphson, John D. Corbett, and Don J. Merryman
pp 7234 - 7239; DOI:
10.1021/ja00439a022
PDF
Tetrahedral and other M2L6 transition metal dimers
Richard H. Summerville and Roald Hoffmann
pp 7240 - 7254; DOI:
10.1021/ja00439a023
PDF
Reductive elimination and isomerization of organogold complexes. Theoretical studies of trialkylgold species as reactive intermediates
Sanshiro Komiya, Thomas A. Albright, Roald Hoffmann, and Jay K. Kochi
pp 7255 - 7265; DOI:
10.1021/ja00439a024
PDF
Stereoelectronic properties of metalloenzymes. 4. Bis(imidotetraphenyldithiodiphosphino-S,S')copper(II) as a tetrahedral model for type I copper(II)
Robert D. Bereman, Francis T. Wang, James Najdzionek, and David M. Braitsch
pp 7266 - 7268; DOI:
10.1021/ja00439a025
PDF
Kinetics of copper(II)-glycylglycyl-L-histidine reactions. Acid decomposition and proton-assisted nucleophilic displacement by triethylenetetramine
Louis F. Wong, John C. Cooper, and Dale W. Margerum
pp 7268 - 7274; DOI:
10.1021/ja00439a026
PDF
Dynamics and thermodynamics of axial ligation in metalloporphyrins. 5. Affinity of ferric porphyrins for nitrogenous bases and the stoichiometry and spin states of the product complexes
James D. Satterlee, Gerd N. La Mar, and James S. Frye
pp 7275 - 7282; DOI:
10.1021/ja00439a027
PDF
Reactivity of coordinated nucleophiles. A comparison of metal bound imidazolate and hydro xide ions as models for carbonic anhydrase
J. M. Harrowfield, V. Norris, and A. M. Sargeson
pp 7282 - 7289; DOI:
10.1021/ja00439a028
PDF
Hydrogen evolving systems. 2. The reduction of molecular nitrogen, organic substrates, and protons by vanadium(II)
S. I. Zones, T. M. Vickrey, J. G. Palmer, and G. N. Schrauzer
pp 7289 - 7295; DOI:
10.1021/ja00439a029
PDF
The relative importance of .pi. inductive effects and polar field effects on fluorine-19 chemical shifts in aromatic derivatives
William F. Reynolds and Gordon K. Hamer
pp 7296 - 7299; DOI:
10.1021/ja00439a030
PDF
Aromatic substitution in the gas phase. Ambident behavior of halo- and dihalobenzenes toward D2T+. Tritiodeprotonation vs. tritiodehalogenation
Fulvio Cacace and Maurizio Speranza
pp 7299 - 7304; DOI:
10.1021/ja00439a031
PDF
Gas-phase aromatic substitution. Isomerization of gaseous arenium ions from the attack of D2T+ on dihalobenzenes
Fulvio Cacace and Maurizio Speranza
pp 7305 - 7307; DOI:
10.1021/ja00439a032
PDF
Chemical consequences of electron impact. Neutral C4H8 fragments expelled from molecular ions in the gas phase
Frank B. Burns and Thomas H. Morton
pp 7308 - 7313; DOI:
10.1021/ja00439a033
PDF
Stereochemistry of electron-impact and lead tetraacetate induced hydrogen-abstraction reactions
George Eadon
pp 7313 - 7319; DOI:
10.1021/ja00439a034
PDF
Mechanism of the acid- and general-base-catalyzed conjugation of 3-cyclopentenone and 3-cyclohexenone; electrostatic effects in the conjugation of .beta.,.gamma.-unsaturated ketones
Dale L. Whalen, John F. Weimaster, Angela M. Ross, and Richard Radhe
pp 7319 - 7324; DOI:
10.1021/ja00439a035
PDF
Photolysis of .alpha.-hydroperoxy ketones
Yasuhiko Sawaki and Yoshiro Ogata
pp 7324 - 7327; DOI:
10.1021/ja00439a036
PDF
.alpha.-Diazobenzylphosphonate dianions
Jorge A. Goldstein, Charles McKenna, and F. H. Westheimer
pp 7327 - 7332; DOI:
10.1021/ja00439a037
PDF
Stable Carbocations. 198. Formation of Allyl Cations via Protonation of Alkynes in Magic Acid Solution. Evidence for 1,2-Hydrogen and Alkyl Shifts in the Intermediate Vinyl Cations
George A. Olah, and Herbert Mayr
pp 7333 - 7340; DOI:
10.1021/ja00439a600
PDF
Oxyfunctionalization of hydrocarbons. 6. Electrophilic oxygenation of aliphatic alcohols, ketones, and aldehydes with ozone in superacids. Preparation of bifunctional derivatives
George A. Olah, Norihiko Yoneda, and Ryuichiro Ohnishi
pp 7341 - 7345; DOI:
10.1021/ja00439a038
PDF
Heats of ionization of some phenols and benzoic acids in dimethyl sulfoxide. Heats of solvation of oxyanions in dimethyl sulfoxide and water
Edward M. Arnett, Leonard E. Small, Dimitru Oancea, and Dale Johnston
pp 7346 - 7350; DOI:
10.1021/ja00439a039
PDF
Immobilized radicals. 2. Hydrogen bonding of the semiquinone anion radical
Brian J. Hales
pp 7350 - 7357; DOI:
10.1021/ja00439a040
PDF
tert-Butoxycarbonylaminoacyl-4-(oxymethyl)phenylacetamidomethyl-resin, a more acid-resistant support for solid-phase peptide synthesis
A. R. Mitchell, B. W. Erickson, M. N. Ryabtsev, R. S. Hodges, and R. B. Merrifield
pp 7357 - 7362; DOI:
10.1021/ja00439a041
PDF
Reaction of hydroxylamine with ethyl acetoacetate. Details of the addition and cyclization steps studied by flow nuclear magnetic resonance
Michael Cocivera, Adan Effio, Holger E. Chen, and Shiv Vaish
pp 7362 - 7366; DOI:
10.1021/ja00439a042
PDF
Flow nuclear magnetic resonance study of the addition, cyclization, and dehydration steps for the reaction of hydroxylamine with acetylacetone
Michael Cocivera and Kyu W. Woo
pp 7366 - 7371; DOI:
10.1021/ja00439a043
PDF
Flow nuclear magnetic resonance study of the rapid addition of hydroxylamine to acetone and the rate-determining dehydration of the carbinolamine
Michael Cocivera and Adan Effio
pp 7371 - 7374; DOI:
10.1021/ja00439a044
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 28. N-Alkoxy-N-alkylamino, N-alkoxyamino, and N-alkoxyanilino radicals
R. A. Kaba and K. U. Ingold
pp 7375 - 7380; DOI:
10.1021/ja00439a045
PDF
Nucleic acid related compounds. 21. Direct fluorination of uracil and cytosine bases and nucleosides using trifluoromethyl hypofluorite. Mechanism, stereochemistry, and synthetic applications
Morris J. Robins, Malcolm MacCoss, S. R. Naik, and G. Ramani
pp 7381 - 7389; DOI:
10.1021/ja00439a046
PDF
Hydrolysis of nucleoside phosphates. 6. The mechanism of the metal ion promoted dephosphorylation of purine nucleoside 5'-triphosphates
Helmut Sigel and Peter E. Amsler
pp 7390 - 7400; DOI:
10.1021/ja00439a047
PDF
Crystal and molecular structure of 3,N4-ethenocytidine hydrochloride. A study of the dimensions and molecular interactions of the fluorescent .epsilon.-cytidine system
Andrew H. J. Wang, Jorge R. Barrio, and Iain C. Paul
pp 7401 - 7408; DOI:
10.1021/ja00439a048
PDF
Species responsible for the fluorescence of 3,N4-ethenocytidine
Jorge R. Barrio, Prem D. Sattsangi, Bruce A. Gruber, Laurence G. Dammann, and Nelson J. Leonard
pp 7408 - 7413; DOI:
10.1021/ja00439a049
PDF
Macrocyclic ligands composed of tetrahydrofuran for selective transport of monovalent cations through liquid membranes
Yoshiaki Kobuke, Katsumi Hanji, Koichi Horiguchi, Masahiro Asada, Yoshinori Nakayama, and Junji Furukawa
pp 7414 - 7419; DOI:
10.1021/ja00439a050
PDF
Metal-assisted terpenoid synthesis. 3. A myrcene magnesium compound as a new example of an enediylmetal system formed from a conjugated diene and its synthetic applications
Susumu Akutagawa and Sei Otsuka
pp 7420 - 7421; DOI:
10.1021/ja00439a051
PDF
Evidence for the pyrolytic generation of methyleneketene (propadienone)
Roger F. C. Brown, Frank W. Eastwood, and Gabrielle L. McMullen
pp 7421 - 7422; DOI:
10.1021/ja00439a052
PDF
Photochemical reactions in organized monolayer assemblies. 5. Photochemical and thermal reactions of reactive intermediates formed by ligand photoejection in ruthenium porphyrins
Frederick R. Hopf and David G. Whitten
pp 7422 - 7424; DOI:
10.1021/ja00439a053
PDF
Chemistry of organosilicon compounds. 93. New photochemical reactions of vinyldisilanes through silaethene or silacyclopropane intermediates
H. Sakurai, Y. Kamiyama, and Y. Nakadaira
pp 7424 - 7425; DOI:
10.1021/ja00439a054
PDF
Salem diagrams as a device for the elucidation of photochemical reaction mechanisms. Application to the cleavage of cyclic alkanones
Nicholas J. Turro, William E. Farneth, and Alain Devaquet
pp 7425 - 7427; DOI:
10.1021/ja00439a055
PDF
The solvation of diphenylmethyl carbanions using variable temperature carbon-13 magnetic resonance
Daniel H. O'Brien, Charles R. Russell, and Alan J. Hart
pp 7427 - 7429; DOI:
10.1021/ja00439a056
PDF
Electron paramagnetic resonance of metastable [7]paracyclophane: out-of-plane distortions of a triplet benzene
E. Wasserman, R. S. Hutton, and F. B. Bramwell
pp 7429 - 7431; DOI:
10.1021/ja00439a057
PDF
The preparation and structure of the linear tripalladium cations (CH3NC)8Pd32+ and (CH3NC)6{(C6H5)3P}2Pd32+
Alan L. Balch, John R. Boehm, Hakon Hope, and Marilyn M. Olmstead
pp 7431 - 7432; DOI:
10.1021/ja00439a058
PDF
Bimolecular electron transfer processes of electronically excited tris(2,2'-bipyridine)chromium(III)
R. Ballardini, G. Varani, F. Scandola, and V. Balzani
pp 7432 - 7433; DOI:
10.1021/ja00439a059
PDF
Intracluster ligand mobility. 3. Tri-.mu.2-carbonyl-tris(.eta.5-cyclopentadienyl)-triangulo-trirhodium. A new, improved preparation and some observations on its dynamic properties
R. Joe Lawson and John R. Shapley
pp 7433 - 7435; DOI:
10.1021/ja00439a060
PDF
Chemically modified electrodes. 3. Tin dioxide and titanium dioxide electrodes bearing an electroactive reagent
P. R. Moses and Royce W. Murray
pp 7435 - 7436; DOI:
10.1021/ja00439a061
PDF
Synthesis of a doubly alkylated binuclear cobalt carbonyl complex. Generation of acetone, a process involving the formation of two new carbon-carbon bonds, in its thermal decomposition
Neil E. Schore, Casmir Ilenda, and Robert G. Bergman
pp 7436 - 7438; DOI:
10.1021/ja00439a062
PDF
Calculation of polar substituent parameters by ab initio molecular orbital methods. Proton affinities of substituted primary amines
M. Taagepera, W. J. Hehre, R. D. Topsom, and R. W. Taft
pp 7438 - 7440; DOI:
10.1021/ja00439a063
PDF
Photodesulfurization be distannane. Photochemical synthesis of tetrathiofulvalenes
Y. Ueno, A. Nakayama, and M. Okawara
pp 7440 - 7441; DOI:
10.1021/ja00439a064
PDF
Cleavage of carbon-carbon bonds. Copper(II)-induced oxygenolysis of o-quinones, catechols, and phenols
Milorad M. Rogic, Timothy R. Demmin, and Willis B. Hammond
pp 7441 - 7443; DOI:
10.1021/ja00439a065
PDF
Bridging regioselectivity in triplet-sensitized di-.pi.-methane photorearrangements of ortho-substituted benzonorbornadienes. A case for the importance of benzene HOMO and LUMO polarization
Cielo Santiago, K. N. Houk, Robert A. Snow, and Leo A. Paquette
pp 7443 - 7445; DOI:
10.1021/ja00439a066
PDF
Reactions of transition metal ions with alkyl halides and alcohols in the gas phase: evidence for metal insertion and .beta.-hydrogen atom shift
J. Allison and D. P. Ridge
pp 7445 - 7447; DOI:
10.1021/ja00439a067
PDF
Alkali .beta.-ketoenolates as ion pairs
Edward M. Arnett and Vincent M. DePalma
pp 7447 - 7448; DOI:
10.1021/ja00439a068
PDF
A high yield regiospecific preparation of iminium salts
Richard T. Dean, Henry C. Padgett, and Henry Rapoport
pp 7448 - 7449; DOI:
10.1021/ja00439a069
PDF
Octamethyl-1,4-cyclohexanedione. Chair conformation in the crystal state
H. M. R. Hoffmann and M. B. Hursthouse
pp 7449 - 7450; DOI:
10.1021/ja00439a070
PDF
Asymmetric syntheses using tert-leucine. 1. An asymmetric synthesis of .beta.-substituted aldehydes via 1,4-addition of Grignard reagents to chiral .alpha.,.beta.-unsaturated aldimines
Shunichi Hashimoto, Shunichi Yamada, and Kenji Koga
pp 7450 - 7452; DOI:
10.1021/ja00439a071
PDF
Substituent effects on the intrinsic basicity of benzene: proton affinities of substituted benzenes
Yan K. Lau and Paul Kebarle
pp 7452 - 7453; DOI:
10.1021/ja00439a072
PDF
Chemistry of organosilicon compounds. 95. .eta.3-1-Silapropenyltricarbonyliron complexes. The first stable compound of doubly bonded silicon
Hideki Sakurai, Yoshiyasu Kamiyama, and Yasuhiro Nakadaira
pp 7453 - 7454; DOI:
10.1021/ja00439a073
PDF
Copper(I) catalysis of olefin photoreactions. Photorearrangement and photofragmentation of 7-methylenenorcarane
Robert G. Salomon and Mary F. Salomon
pp 7454 - 7456; DOI:
10.1021/ja00439a074
PDF
Stereochemical consequences of the vinylogous Wolff rearrangement
Amos B. Smith, Bruce H. Toder, and Stephen J. Branca
pp 7456 - 7458; DOI:
10.1021/ja00439a075
PDF
The photochemical reactions of azidopentaamminechromium(III). Evidence for a first transition series coordinated nitrene intermediate
Micheal Katz and Harry D. Gafney
pp 7458 - 7460; DOI:
10.1021/ja00439a076
PDF
Glyoxalase I enzyme studies. 2. Nuclear magnetic resonance evidence for an enediol-proton transfer mechanism
Stan S. Hall, Arthur M. Doweyko, and Frank Jordan
pp 7460 - 7461; DOI:
10.1021/ja00439a077
PDF
Oligomerization and two-center oxidative addition reactions of a dimeric rhodium(I) complex
Nathan S. Lewis, Kent R. Mann, J. G. Gordon, and Harry B. Gray
pp 7461 - 7463; DOI:
10.1021/ja00439a078
PDF
Book Reviews

pp 7463 - 7464; DOI:
10.1021/ja00439a601
PDF

Issue 24


Intramolecular hydrogen bonding in monoanions and solvation of dianions of aromatic dicarboxylic acids in acetonitrile and dimethyl sulfoxide
I. M. Kolthoff and M. K. Chantooni
pp 7465 - 7470; DOI:
10.1021/ja00440a001
PDF
Stable carbocations. 200. 1-Methylcyclopropylcarbinyl cations
George A. Olah, Robert J. Spear, Philippe C. Hiberty, and Warren J. Hehre
pp 7470 - 7475; DOI:
10.1021/ja00440a002
PDF
Molecular structure of 1-methyl-1-silabicyclo[2.2.1]heptane by gas-phase electron diffraction. Structural support for the trigonal bipyramidal transition state in SN2-silicon reactions
Richard L. Hilderbrandt, G. David Homer, and Philip Boudjouk
pp 7476 - 7480; DOI:
10.1021/ja00440a003
PDF
Conformational analysis of triarylsilanes
John P. Hummel, E. Peter Zurbach, E. N. DiCarlo, and Kurt Mislow
pp 7480 - 7483; DOI:
10.1021/ja00440a004
PDF
Conformational studies by dynamic NMR. V. The stereodynamics of hindered aliphatic hydrazones
L. Lunazzi, G. Cerioni, and K. U. Ingold
pp 7484 - 7488; DOI:
10.1021/ja00440a005
PDF
Electronic properties of aliphatic xanthate ions
Katsuyuki Takahashi
pp 7488 - 7498; DOI:
10.1021/ja00440a006
PDF
Stereoelectronic effects. 5. Stereoelectronic properties, stereospecificity, and stabilization of .alpha.-oxa and .alpha.-thia carbanions
Jean M. Lehn and Georges Wipff
pp 7498 - 7505; DOI:
10.1021/ja00440a007
PDF
Electron exchange and electron transfer of semiquinones in aqueous solutions
Dan Meisel and Richard W. Fessenden
pp 7505 - 7510; DOI:
10.1021/ja00440a008
PDF
Transmission of substituent effects. Generalization of the ellipsoidal cavity field effect model
S. Ehrenson
pp 7510 - 7514; DOI:
10.1021/ja00440a009
PDF
Barriers to internal rotation in 1,3,5-trineopentylbenzenes. 8. Molecular mechanics calculations. Theoretical evidence for attractive steric effects
Robert E. Carter and Peter Stilbs
pp 7515 - 7521; DOI:
10.1021/ja00440a010
PDF
Ability of the CNDO/2 and INDO MO methods to cope with nonbonded interactions
Allan R. Gregory and Michael N. Paddon-Row
pp 7521 - 7523; DOI:
10.1021/ja00440a011
PDF
Theoretical study of the protonation of glycine in gas-phase ion-molecule reactions
K. Chung, R. M. Hedges, and R. D. Macfarlane
pp 7523 - 7525; DOI:
10.1021/ja00440a012
PDF
A molecular orbital study of protonation substituted carbonyl compounds
Janet E. Del Bene and Anthony Vaccaro
pp 7526 - 7532; DOI:
10.1021/ja00440a013
PDF
.PI. And .SIGMA. states of the N-formamido radical: an ab initio molecular orbital study
N. Colin Baird and Harichand B. Kathpal
pp 7532 - 7535; DOI:
10.1021/ja00440a014
PDF
Optical activity of uridylyl-(3',5')-adenosine. Crystal structures and solution conformation
Neil P. Johnson, Eugene Switkes, and Thomas Schleich
pp 7535 - 7541; DOI:
10.1021/ja00440a015
PDF
Cross correlation and spin-rotation effects on methyl spin-lattice relaxation in peptides. Tetragastrin
J. D. Cutnell and Jay A. Glasel
pp 7542 - 7547; DOI:
10.1021/ja00440a016
PDF
Proton magnetic resonance and conformational energy calculations of repeat pepetides of tropoelastin: the tetrapeptide
M. Abu Khaled, V. Renugopalakrishnan, and D. W. Urry
pp 7547 - 7553; DOI:
10.1021/ja00440a017
PDF
Nitrogen-15 nuclear magnetic resonance spectrum of alumichrome. Detection by a double resonance Fourier transform technique
Miguel Llinas, William J. Horsley, and Melvin P. Klein
pp 7554 - 7558; DOI:
10.1021/ja00440a018
PDF
Nuclear magnetic resonance studies on pyridine dinucleotides. 7. The solution conformational dynamics of the adenosine portion of nicotinamide adenine dinucleotide and other related purine containing compounds
Albert P. Zens, Thomas A. Bryson, R. Bruce Dunlap, Ronald R. Fisher, and Paul D. Ellis
pp 7559 - 7564; DOI:
10.1021/ja00440a019
PDF
Crystal structure and molecular conformation of the hydrated cyclic hexapeptide cyclo(L-Ala-L-Pro-D-Phe)2
J. N. Brown and R. G. Teller
pp 7565 - 7569; DOI:
10.1021/ja00440a020
PDF
The novel crystal and molecular structure of bis[bis(2-pyridyl) disulfide]copper(I) perchlorate
Mavis M. Kadooka, Larry G. Warner, and Karl Seff
pp 7569 - 7578; DOI:
10.1021/ja00440a021
PDF
Valence level photoelectron spectra of some heavy group 4-6 diatomic molecules
M Wu and T. P. Fehlner
pp 7578 - 7585; DOI:
10.1021/ja00440a022
PDF
Photoelectron spectroscopy of bis(.pi.-allyl)nickel and its methyl substituted derivatives: support for the near validity of Koopmans' theorem
C. D. Batich
pp 7585 - 7590; DOI:
10.1021/ja00440a023
PDF
The mechanism of ligand dissociation in Group 8 ML5 complexes
A. D. English, P. Meakin, and J. P. Jesson
pp 7590 - 7598; DOI:
10.1021/ja00440a024
PDF
Electrophilic cleavage of organogold complexes with acids. The mechanism of the reductive elimination of dialkyl(aniono)gold(III) species
S. Komiya and J. K. Kochi
pp 7599 - 7607; DOI:
10.1021/ja00440a025
PDF
Aryldiazo complexes. Synthesis and structure of a five-coordinate complex possessing a "half doubly bent" aryldiazo ligand and an intermediate coordination geometry, chloro(phenyldiazo)tris(methyldiphenylphosphine)iridium hexafluorophosphate
Martin Cowie, Barry L. Haymore, and James A. Ibers
pp 7608 - 7617; DOI:
10.1021/ja00440a026
PDF
Charge-transfer complexes. NH3O3, NH3SO2, and N(CH3)3SO2
Robert R. Lucchese, Kenneth Haber, and Henry F. Schaefer
pp 7617 - 7620; DOI:
10.1021/ja00440a027
PDF
Calorimetric titration study of the interaction of several uni- and bivalent cations with 15-crown-5, 18-crown-6, and two isomers of dicyclohexo-18-crown-6 in aqueous solution at 25.degree.C and .mu. = 0.1
R. M. Izatt, R. E. Terry, B. L. Haymore, L. D. Hansen, N. K. Dalley, A. G. Avondet, and J. J. Christensen
pp 7620 - 7626; DOI:
10.1021/ja00440a028
PDF
Calorimetric titration study of the interaction of some uni- and bivalent cations with benzo-15-crown-5, 18-crown-6, dibenzo-24-crown-8, and dibenzo-27-crown-9 in methanol-water solvents, at 25.degree.C and .mu. = 0.1
R. M. Izatt, R. E. Terry, D. P. Nelson, Y. Chan, D. J. Eatough, J. S. Bradshaw, L. D. Hansen, and J. J. Christensen
pp 7626 - 7630; DOI:
10.1021/ja00440a029
PDF
Boroacetylation of carbohydrates. Correlations between structure and mass spectral behavior in monoacetylhexose cyclic boronic esters
Jacek Wiecko and William R. Sherman
pp 7631 - 7637; DOI:
10.1021/ja00440a030
PDF
Synthesis and vapor spectrum of zinc tetrabenzporphine
Lawrence Edwards, Martin Gouterman, and Charles B. Rose
pp 7638 - 7641; DOI:
10.1021/ja00440a031
PDF
An unusual reversible valence bond isomerization hemi-Dewar naphthalene to naphthalene
Ira B. Goldberg, H. R. Crowe, and Richard W. Franck
pp 7641 - 7645; DOI:
10.1021/ja00440a032
PDF
Ionization of methyl derivatives of imidazole, histidine, thyreotropin releasing factor, and related compounds
Antonio C. M. Paiva, Luiz Juliano, and Paulo Boschcov
pp 7645 - 7648; DOI:
10.1021/ja00440a033
PDF
Deuterium isotope effects in the general base catalyzed deprotonation of methylcreatininium ion
R. Srinivasan and Ross Stewart
pp 7648 - 7651; DOI:
10.1021/ja00440a034
PDF
Hydrolysis of arylsulfonylmethyl perchlorates. A simple model to explain electrolyte effects on a water-catalyzed deprotonation reaction
Lubbertus Menninga and Jan B. F. N. Engberts
pp 7652 - 7657; DOI:
10.1021/ja00440a035
PDF
The SN2-SN1 spectrum. 1. Role of nucleophilic solvent assistance and nucleophilically solvated ion pair intermediates in solvolyses of primary and secondary arenesulfonates
T. William Bentley and Paul v. R. Schleyer
pp 7658 - 7666; DOI:
10.1021/ja00440a036
PDF
The SN2-SN1 spectrum. 2. Quantitative treatments of nucleophilic solvent assistance. A scale of solvent nucleophilicities
Frank L. Schadt, T. William Bentley, and Paul v. R. Schleyer
pp 7667 - 7675; DOI:
10.1021/ja00440a037
PDF
Effects of methyl substitution on the photoreactivity of phenyl ketones. The inapplicability of Hammett .sigma. values in correlations of excitation energies
Peter J. Wagner, M. J. Thomas, and E. Harris
pp 7675 - 7679; DOI:
10.1021/ja00440a038
PDF
Independent generation of cyclopropyldicarbinyl diradical species of the di-.pi.-methane rearrangement. Excited singlet, triplet, and ground-state hypersurfaces of barrelene photochemistry. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman, Robert J. Boettcher, Niklaus E. Buehler, Gary E. Keck, and Mark G. Steinmetz
pp 7680 - 7689; DOI:
10.1021/ja00440a039
PDF
Skeletal rearrangement of carbon-13 labeled methylpentenes and methylhexenes on supported p-toluenesulfonic acid
Francois Fajula and Francois G. Gault
pp 7690 - 7698; DOI:
10.1021/ja00440a040
PDF
Cycloadditions. 12. The stereochemistry of cycloadditions of ketenes to unsymmetrical alkenes. Evidence for nonparallel transition states
Alfred Hassner, Robert M. Cory, and Nelson Sartoris
pp 7698 - 7704; DOI:
10.1021/ja00440a041
PDF
The stereochemistry of the intramolecular reactions of cyclopropylcarbenes
Robert R. Gallucci and Maitland Jones
pp 7704 - 7711; DOI:
10.1021/ja00440a042
PDF
A search for an .alpha.-disulfoxide as an intermediate in the oxidation of an aryl thiolsulfinate
Michael M. Chau and John L. Kice
pp 7711 - 7716; DOI:
10.1021/ja00440a043
PDF
Electron spin resonance study of liquids during photolysis. 21. Dipeptides
David G. Doherty, Ralph Livingston, and Henry Zeldes
pp 7717 - 7723; DOI:
10.1021/ja00440a044
PDF
Strong acid chemistry. 4. Direct reduction of alkyl chlorides
Richard H. Schlosberg, Michael Siskin, William P. Kocsi, and Frederick J. Parker
pp 7723 - 7725; DOI:
10.1021/ja00440a045
PDF
Vinylic cations from solvolysis. 25. Ion pairs in the solvolysis, isomerization, and rearrangement of .alpha.-arylvinyl halides in pivalic acid
Zvi Rappoport, Ilan Schnabel, and Peniel Greenzaid
pp 7726 - 7733; DOI:
10.1021/ja00440a046
PDF
Formation of trianions of 2,4,6-triketones. Synthesis of 3,5,7-triketo acids using lithium diisopropylamide
Thomas M. Harris, George P. Murphy, and Albert J. Poje
pp 7733 - 7741; DOI:
10.1021/ja00440a047
PDF
Reactions of aromatic radical anions. 12. Kinetic studies of the reaction of radical anions of varying reduction potential with n-hexyl bromides, iodides, and chlorides
Shelton Bank and Donald A. Juckett
pp 7742 - 7746; DOI:
10.1021/ja00440a048
PDF
An alternative mechanism for the formation of 1,4-disilacyclohexa-2,5-dienes from acetylenes and silylenes
Thomas J. Barton and John A. Kilgour
pp 7746 - 7752; DOI:
10.1021/ja00440a049
PDF
The kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. 2. Ethyl pyruvate, pyruvamide, and pyruvic acid
Robert F. Williams and Thomas C. Bruice
pp 7752 - 7768; DOI:
10.1021/ja00440a050
PDF
The kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. 3. Oxidation of benzoin by flavin and reduction of benzil by 1,5-dihydroflavin
Thomas C. Bruice and Joseph P. Taulane
pp 7769 - 7776; DOI:
10.1021/ja00440a051
PDF
Equilibriums and kinetics of N-hydroxymethylamine formation from aromatic exocyclic amines and formaldehyde. Effects of nucleophilicity and catalyst strength upon mechanisms of catalysis of carbinolamine formation
William R. Abrams and Roland G. Kallen
pp 7777 - 7789; DOI:
10.1021/ja00440a052
PDF
Estimates of microscopic ionization constants for heteroaromatic exocyclic amines including purine and pyrimidine nucleotides and amides based upon a reactivity-basicity correlation for N-hydroxymethylation reactions with formaldehyde
William R. Abrams and Roland G. Kallen
pp 7789 - 7792; DOI:
10.1021/ja00440a053
PDF
Multifunctional hydrolytic catalyses. 7. Cooperative catalysis of the hydrolysis of phenyl esters by a copolymer of N-methylacrylohydroxamic acid and 4-vinylimidazole
Toyoki Kunitake and Yoshio Okahata
pp 7793 - 7799; DOI:
10.1021/ja00440a054
PDF
Multifunctional hydrolytic catalyses. 8. Remarkable acceleration of the hydrolysis of p-nitrophenyl acetate by micellar bifunctional catalysts
Toyoki Kunitake, Yoshio Okahata, and Tetsuo Sakamoto
pp 7799 - 7806; DOI:
10.1021/ja00440a055
PDF
Calculations of optical properties of biliverdin in various conformations
G. Wagniere and G. Blauer
pp 7806 - 7810; DOI:
10.1021/ja00440a056
PDF
Electrostatic potentials of proteins. 2. Role of electrostatics in a possible catalytic mechanism for carboxypeptidase A
David M. Hayes and Peter A. Kollman
pp 7811 - 7816; DOI:
10.1021/ja00440a057
PDF
Synthesis of methylenecyclopropenes
W. E. Billups and A. J. Blakeney
pp 7817 - 7818; DOI:
10.1021/ja00440a058
PDF
Directional specificity and stereoselectivity in the metathesis of a trisubstituted olefin
Steven J. Lee, James McGinnis, and Thomas J. Katz
pp 7818 - 7819; DOI:
10.1021/ja00440a059
PDF
New mechanistic criterion for early and late transition states
Rolf Huisgen and Reinhard Schug
pp 7819 - 7821; DOI:
10.1021/ja00440a060
PDF
Concerted cycloreversion in solution: medium influence on nitrogen extrusion
James P. Snyder and David N. Harpp
pp 7821 - 7823; DOI:
10.1021/ja00440a061
PDF
The synthesis and structure of mercuric halide complexes of triphenylphosphonium cyclopentadienylide. The first x-ray structure of a mercury cyclopentadienyl
Norman L. Holy, Norman C. Baenziger, Richard M. Flynn, and Dale C. Swenson
pp 7823 - 7824; DOI:
10.1021/ja00440a062
PDF
Preparation and properties of dinitrogen-molybdenum complexes. 5. Conversion of the coordinated dinitrogen into a hydrazone type N2CRR' ligand
Masanobu Hidai, Yasushi Mizobe, and Yasuzo Uchida
pp 7824 - 7825; DOI:
10.1021/ja00440a063
PDF
Azetidin-2-oxo-4-thiones. Novel thermolytic products of .beta.-lactam sulfoxides
Mario D. Bachi and Jacob Vaya
pp 7825 - 7826; DOI:
10.1021/ja00440a064
PDF
Extensive redistribution of fluorine and hydrogen in the reaction of trifluoromethyl(1+) ions with silane
J. R. Krause and F. W. Lampe
pp 7826 - 7827; DOI:
10.1021/ja00440a065
PDF
Deuterium labeling studies of bicyclo[3.1.0]hexatriene
William N. Washburn and Robert Zahler
pp 7827 - 7828; DOI:
10.1021/ja00440a066
PDF
Chemistry of bicyclo[3.1.0]hexatriene
William N. Washburn and Robert Zahler
pp 7828 - 7830; DOI:
10.1021/ja00440a067
PDF
Use of circular dichroism measurements to determine the formation constant of the complex between an optically active benzo-15-crown-5 and sodium ion
Mark P. Mack, Richard R. Hendrixson, Richard A. Palmer, and Robert G. Ghirardelli
pp 7830 - 7832; DOI:
10.1021/ja00440a068
PDF
Conjugate addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to methyl vinyl ketone. A convenient synthesis of .gamma.,.delta.-unsaturated ketones
Peyton Jacob and Herbert Brown
pp 7832 - 7833; DOI:
10.1021/ja00440a069
PDF
Hydride transfer reactions. Oxidation of N-methylacridan by 1,4-benzoquinone and related .pi. acceptors
Allan K. Colter, Gunzi Saito, Frances J. Sharom, and Anita P. Hong
pp 7833 - 7835; DOI:
10.1021/ja00440a070
PDF
Carbanions. 18. Spiro anions from reactions of 2- and 3-p-biphenylylalkyl chlorides with cesium-potassium-sodium alloy
J. A. Bertrand, Erling Grovenstein, Pang-Chia Lu, and Don VanDerveer
pp 7835 - 7836; DOI:
10.1021/ja00440a071
PDF
Progress toward the development of totally synthetic heme-protein models - the use of substituents to control the oxidation-reduction properties of metal ions in complexes with macrocyclic ligands
Dale G. Pillsbury and Daryle H. Busch
pp 7836 - 7839; DOI:
10.1021/ja00440a072
PDF
A novel partially oxidized distorted one-dimensional platinum chain in K1.6Pt(C2O4)2.1.2H2O
A. H. Reis, S. W. Peterson, and S. C. Lin
pp 7839 - 7840; DOI:
10.1021/ja00440a073
PDF
Energy upconversion and the minimum quantum requirement in photosynthesis
F. K. Fong
pp 7840 - 7843; DOI:
10.1021/ja00440a074
PDF
A new route to pentacovalent cyclic acyloxyphosphoranes
Takeo Saegusa, Shiro Kobayashi, Yoshiharu Kimura, and Tsunenori Yokoyama
pp 7843 - 7844; DOI:
10.1021/ja00440a075
PDF
1,1,2-Trimethylsilaethylene
O. L. Chapman, C. C. Chang, J. Kolc, M. E. Jung, J. A. Lowe, T. J. Barton, and M. L. Tumey
pp 7844 - 7846; DOI:
10.1021/ja00440a076
PDF
Solid state chemistry. Discrete trimethysilylmethylene
M. R. Chedekel, M. Skoglund, R. L. Kreeger, and H. Shechter
pp 7846 - 7848; DOI:
10.1021/ja00440a077
PDF
Wavelength dependent carbonium ion formation by photosolvolysis of benzoates
Cheng-I Lin, Prithipal Singh, and Edwin F. Ullman
pp 7848 - 7850; DOI:
10.1021/ja00440a078
PDF
Internal reflection resonance Raman spectroscopy for studies of adsorbed dye layers at electrode-solution interface
Masamichi Fujihira and Tetsuo Osa
pp 7850 - 7851; DOI:
10.1021/ja00440a079
PDF
Anchimerically accelerated bond homolysis. 8. Direct observation of a sulfurane intermediate in the neighboring-sulfide-assisted thermolysis of a perester
P. Livant and J. C. Martin
pp 7851 - 7853; DOI:
10.1021/ja00440a080
PDF
Reactions of magnesium atoms with cyclic ketones
Lyle D. Wescott, Clint Williford, Frank Parks, Margaret Dowling, Susan Sublett, and Kenneth J. Klabunde
pp 7853 - 7854; DOI:
10.1021/ja00440a081
PDF
The stereochemistry of conversion of allylic esters to olefins with lithium dialkylcuprates
Harlan L. Goering and Victor D. Singleton
pp 7854 - 7855; DOI:
10.1021/ja00440a082
PDF
Capped cyclodextrin
Iwao Tabushi, Kazuhiro Shimokawa, Nobuaki Shimizu, Hiroko Shirakata, and Kahee Fujita
pp 7855 - 7856; DOI:
10.1021/ja00440a083
PDF
Stereoselective formation of diepoxides by an enzyme system of Pseudomonas oleovorans
Sheldon W. May, Michael S. Steltenkamp, Robert D. Schwartz, and Carlton J. McCoy
pp 7856 - 7858; DOI:
10.1021/ja00440a084
PDF
Benzoylamination of uridine derivatives
Oyo Mitsunobu, Susumu Takizawa, and Hiroo Morimato
pp 7858 - 7859; DOI:
10.1021/ja00440a085
PDF
Specific effects of chloride ion on epoxide hydrolysis. The pH-dependence of the rates and mechanisms for the hydrolysis of indene oxide
Dale L. Whalen and Angela M. Ross
pp 7859 - 7861; DOI:
10.1021/ja00440a086
PDF
1,1-Dimethyl-.lambda.5-phosphabenzene and 1,1-dimethyl-.lambda.5-arsabenzene
Arthur J. Ashe and Timothy W. Smith
pp 7861 - 7862; DOI:
10.1021/ja00440a087
PDF
Ligand effects and product distributions in molybdothiol catalyst systems
James L. Corbin, Narayanankutty Pariyadath, and Edward I. Stiefel
pp 7862 - 7864; DOI:
10.1021/ja00440a088
PDF
Novel thioxo-.beta.-lactams from thiosulfinates derived from penicillin sulfoxides
T. S. Chou, G. A. Koppel, D. E. Dorman, and J. W. Paschal
pp 7864 - 7865; DOI:
10.1021/ja00440a089
PDF
Molecular structure of .mu.-(9-methyladenine-N1,N7)-bis(di-isopropyl sulfoxide-S)-trans-dichloroplatinum(II)
Colin J. L. Lock, Robert A. Speranzini, Graham Turner, and John Powell
pp 7865 - 7866; DOI:
10.1021/ja00440a090
PDF
Resonance Raman spectra of liganded and unliganded carp hemoglobin in both R and T states
D. M. Scholler, B. M. Hoffman, and D. F. Shriver
pp 7866 - 7868; DOI:
10.1021/ja00440a091
PDF
A novel method for converting ketones to .alpha.-diketones. The reaction of enamino ketones with singlet oxygen
H. H. Wasserman and J. L. Ives
pp 7868 - 7869; DOI:
10.1021/ja00440a092
PDF
Nonempirical electronegativity scale
Gary Simons, Melvin E. Zandler, and Erach R. Talaty
pp 7869 - 7870; DOI:
10.1021/ja00440a093
PDF
Synthesis of 2-amino-5-cyano-7-(.beta.-D-ribofuranosyl)pyrrolo[2,3-d]pyrimidin-4-one. An important precursor for the synthesis of nucleoside Q and Q*
Chin Shu Cheng, Barbara C. Hinshaw, Raymond P. Panzica, and Leroy B. Townsend
pp 7870 - 7872; DOI:
10.1021/ja00440a094
PDF
Photolysis of isotopically labeled 1,2,3-selenadiazole and 1,2,3-thiadiazole
J. Laureni, A. Krantz, and R. A. Hajdu
pp 7872 - 7874; DOI:
10.1021/ja00440a095
PDF
Tylonolide hemiacetal, the aglycone of tylosin and its partial synthesis
Satoru Masamune, Yoshio Hayase, Wan Kit Chan, and Ronald L. Sobczak
pp 7874 - 7875; DOI:
10.1021/ja00440a096
PDF
Vitamin B12 model studies. Migration of the acrylate fragment in the carbon-skeleton rearrangement leading to .alpha.-methyleneglutaric acid
Paul Dowd, B. K. Trivedi, Moritz Shapiro, and Lalat K. Marwaha
pp 7875 - 7877; DOI:
10.1021/ja00440a097
PDF
Time resolved infrared laser photochemistry and spectroscopy: the methyl fluoride sensitized decomposition of tetramethyl-1,2-dioxetane. An example of infrared laser induced electronic excitation
William F. Farneth, George Flynn, Richard Slater, and Nicholas J. Turro
pp 7877 - 7878; DOI:
10.1021/ja00440a098
PDF
Salt-type complexes of porphyrins: monocation octaethylporphinium tri-.mu.-halogeno-hexacarbonyldirhenate(I)
C. P. Hrung, M. Tsutsui, D. L. Cullen, and E. F. Meyer
pp 7878 - 7880; DOI:
10.1021/ja00440a099
PDF
Excited state acid-base reactions of transition metal complexes: dicyanobis(2,2'-bipyridine) ruthenium(III) in aqueous acid
Steven H. Peterson and J. N. Demas
pp 7880 - 7881; DOI:
10.1021/ja00440a100
PDF
Pseudorotation in diphenyltrifluoroarsorane
Lory B. Littlefield and G. O. Doak
pp 7881 - 7882; DOI:
10.1021/ja00440a101
PDF
Oxidation of ethers via hydride abstraction: a new procedure for selective oxidation of primary, secondary diols at the secondary position
Michael E. Jung and Laurine M. Speltz
pp 7882 - 7884; DOI:
10.1021/ja00440a102
PDF
Restricted rotation of .sigma.-alkyl intermediates on a molybdenum disulfide catalyst
Toshio Okuhara and Kenichi Tanaka
pp 7884 - 7886; DOI:
10.1021/ja00440a103
PDF
UDPgalactose 4-epimerase catalyzed oxygen dependent reduction of a free radical substrate analog by two electron reducing agents
Shan S. Wong and Perry A. Frey
pp 7886 - 7887; DOI:
10.1021/ja00440a104
PDF
Book Reviews

pp 7888 - 7890; DOI:
10.1021/ja00440a600
PDF

Issue 25


Dynamics of proton transfer involving delocalized negative ions in the gas phase
William E. Farneth and John I. Brauman
pp 7891 - 7898; DOI:
10.1021/ja00441a001
PDF
Relative gas-phase acidities and basicities from a proton potential model
D. W. Davis and D. A. Shirley
pp 7898 - 7903; DOI:
10.1021/ja00441a002
PDF
Theoretical calculation of steric effects in ester hydrolysis
DeLos F. DeTar and Carl J. Tenpas
pp 7903 - 7908; DOI:
10.1021/ja00441a003
PDF
Generalized valence bond description of the low-lying states of nickel carbonyl (NiCO)
Stephen P. Walch and W. A. Goddard
pp 7908 - 7917; DOI:
10.1021/ja00441a004
PDF
Electronic structure of chromium hexacarbonyl at liquid nitrogen temperature. 2. Experimental study (x-ray and neutron diffraction) of .sigma. and .pi. bonding
Bernard Rees and Andre Mitschler
pp 7918 - 7924; DOI:
10.1021/ja00441a005
PDF
The electronic spectrum of actinomycin D
Julia C. Tai, William S. Craig, and Bruce P. Gaber
pp 7925 - 7927; DOI:
10.1021/ja00441a006
PDF
Conformational analysis. 120. Small polyenes
Julia C. Tai and Norman L. Allinger
pp 7928 - 7932; DOI:
10.1021/ja00441a007
PDF
Experimental and theoretical studies on magnetic circular dichroism and circular dichroism of triptycene derivatives
Akira Kaito, Akio Tajiri, Masahiro Hatano, Fumio Ogura, and Masazumi Nakagawa
pp 7932 - 7938; DOI:
10.1021/ja00441a008
PDF
Use of dispersion-induced circular dichroism (DICD) in spectroscopic assignment: applications to copper(II) complexes
Pieter E. Schipper
pp 7938 - 7944; DOI:
10.1021/ja00441a009
PDF
An analysis of the endostatic transformation of thermodynamic functions
Gary L. Bertrand and Thomas F. Fagley
pp 7944 - 7947; DOI:
10.1021/ja00441a010
PDF
Correlation contribution to ionization potentials and excitation energies of ammonia, nitrogen, oxygen, and ethylene
H. Onder Pamuk
pp 7948 - 7950; DOI:
10.1021/ja00441a011
PDF
Free energies and free energies of activation for ion pairing and hydrogen bonding to an anion radical
Gerald R. Stevenson and Carlos A. Castillo
pp 7950 - 7954; DOI:
10.1021/ja00441a012
PDF
The use of gas solubilities for the determination of solvation numbers and to detect ion pairing involving alkali metal cations
Wilson Martir, Antonio E. Alegria, and Gerald R. Stevenson
pp 7955 - 7959; DOI:
10.1021/ja00441a013
PDF
The simplest metallocene: cyclopentadienyllithium
Spiro Alexandratos, Andrew Streitwieser, and Henry F. Schaefer
pp 7959 - 7962; DOI:
10.1021/ja00441a014
PDF
Model organometallic systems. The interaction of 2S beryllium(1+) ion, 1S beryllium, and 3P beryllium atoms with acetylene and ethylene
William C. Swope and Henry F. Schaefer
pp 7962 - 7967; DOI:
10.1021/ja00441a015
PDF
Phosphorus-31 spin-lattice relaxation. 2. Inorganic ring and chain phosphates
Thomas Glonek, Priestley J. Wang, and John R. Van Wazer
pp 7968 - 7973; DOI:
10.1021/ja00441a016
PDF
Ion binding to nucleosides. A chlorine-35 and lithium-7 NMR study
Albert C. Plaush and Robert R. Sharp
pp 7973 - 7980; DOI:
10.1021/ja00441a017
PDF
Molecular Rydberg transitions. 3. A linear combination of Rydberg orbitals (LCRO) model for the two-chromophoric system 2,2,4,4-tetramethylcyclobutane-1,3-dione (TMCBD)
P. Brint, K. Wittel, P. Hochmann, W. S. Felps, and S. P. McGlynn
pp 7980 - 7989; DOI:
10.1021/ja00441a018
PDF
Coupled Hartree-Fock calculations of nuclear magnetic resonance carbon-carbon coupling constants in substituted benzenes
Paolo Lazzeretti, Ferdinando Taddei, and Riccardo Zanasi
pp 7989 - 7993; DOI:
10.1021/ja00441a019
PDF
Photodissociation spectroscopy of methylnaphthalene cations and the state assignment of naphthalene ions
Robert C. Dunbar and Robert Klein
pp 7994 - 7999; DOI:
10.1021/ja00441a020
PDF
Resonance Raman studies of macrocyclic complexes. 1. Structural and electronic effects in synthetic metal(II) porphyrin analogs
William H. Woodruff, Richard W. Pastor, and James C. Dabrowiak
pp 7999 - 8006; DOI:
10.1021/ja00441a021
PDF
Resonance Raman studies of macrocyclic complexes. 2. Antiresonance and selective intensity enhancement in synthetic metal(II) porphyrin analogs
Laurence A. Nafie, Richard W. Pastor, James C. Dabrowiak, and William H. Woodruff
pp 8007 - 8014; DOI:
10.1021/ja00441a022
PDF
Structure relations between the four-coordinate, S = 1, macrocyclic complex, [Fe(C22H22N4)], and the neutral ligand, C22H24N4
Virgil L. Goedken, Joseph J. Pluth, Shie-Ming Peng, and Bruce Bursten
pp 8014 - 8021; DOI:
10.1021/ja00441a023
PDF
Effects of peripheral steric constraints and metal ion size on the structure of three five-coordinate macrocyclic ligand complexes of the type [M(C22H22N4)X], M = cobalt(III), iron(III), manganese(II); X = iodine, chlorine, triethylamine
Marvin C. Weiss, Bruce Bursten, Shie-Ming Peng, and Virgil L. Goedken
pp 8021 - 8031; DOI:
10.1021/ja00441a024
PDF
Stereochemistry of carbonylmetalloporphyrins. The structure of (pyridine)(carbonyl)(5,10,15,20-tetraphenylporphinato)iron(II)
Shie-Ming Peng and James A. Ibers
pp 8032 - 8036; DOI:
10.1021/ja00441a025
PDF
Crystal and molecular structure of bis[(tetramethyl[14]hexaenatotetraaza)nickel] bis(trifluoromethanesulfonate): conversion of a metal-stabilized .pi.-radical to a diamagnetic dimer with a long metal-metal bond and eclipsed macrocyclic ligands upon crystallization
S.M. Peng, James A. Ibers, M. Millar, and R. H. Holm
pp 8037 - 8041; DOI:
10.1021/ja00441a026
PDF
The stabilization of .alpha.- and .beta.-diimines: hexaammineruthenium(III), -osmium(III), and -platinum(IV) condensed with .alpha.- and .beta.-diketones
I. P. Evans, G. W. Everett, and A. M. Sargeson
pp 8041 - 8046; DOI:
10.1021/ja00441a027
PDF
Infrared and visible circular dichroism and magnetic circular dichroism studies on cobalt(II)-substituted blue copper proteins
Edward I. Solomon, Jill Rawlings, David R. McMillin, P. J. Stephens, and Harry B. Gray
pp 8046 - 8048; DOI:
10.1021/ja00441a028
PDF
Dimeric rhodium(I) and rhodium(II) complexes with bridging phosphine or arsine ligands
Alan L. Balch
pp 8049 - 8054; DOI:
10.1021/ja00441a029
PDF
Photochemistry of transition metal hydride complexes. 1. Photoinduced elimination of molecular hydrogen from chlorodihydrotris(triphenylphosphine)iridium and trihydrotris(triphenylphosphine)iridium
Gregory L. Geoffroy and Ronald Pierantozzi
pp 8054 - 8059; DOI:
10.1021/ja00441a030
PDF
Applications of x-ray photoabsorption spectroscopy to the determination of local structure in organometallic compounds
S. P. Cramer, T. K. Eccles, F. Kutzler, Keith O. Hodgson, and S. Doniach
pp 8059 - 8069; DOI:
10.1021/ja00441a031
PDF
Crystal structure, Raman spectrum, and nuclear magnetic resonance spectrum of methoxythionyl .mu.-fluoro-bis(pentafluoroantimonate(V)), CH3OSO+Sb2F11-
R. J. Gillespie, F. G. Riddell, and D. R. Slim
pp 8069 - 8072; DOI:
10.1021/ja00441a032
PDF
Chemistry of .mu.-(.eta.1:.eta.5-cyclopentadienyl)-tris(.eta.-cyclopentadienyl)dititanium(Ti-Ti). 1. Synthesis and structural studies
Guido P. Pez
pp 8072 - 8078; DOI:
10.1021/ja00441a033
PDF
Chemistry of .mu.-(.eta.1:.eta.5-cyclopentadienyl)-tris(.eta.-cyclopentadienyl)dititanium(Ti-Ti). 2. Reactivity with hydrogen and nitrogen and catalytic properties
Guido P. Pez and Stephen C. Kwan
pp 8079 - 8083; DOI:
10.1021/ja00441a034
PDF
The synthesis and structure of a dispirotetrasilazane
Harold Rosenberg, Tsu-Tzu Tsai, W. Wade Adams, Matatiahu T. Gehatia, Albert V. Fratini, and Donald R. Wiff
pp 8083 - 8087; DOI:
10.1021/ja00441a035
PDF
Studies of propanediol-chromium(III) species in acidic solution
Kenneth C. Showalter and Edward L. King
pp 8087 - 8093; DOI:
10.1021/ja00441a036
PDF
The role of second triplet states in solution photochemistry. 10. Energy transfer from the second triplet state of naphthalene and other aromatic compounds
Catherine C. Ladwig and R. S. H. Liu
pp 8093 - 8097; DOI:
10.1021/ja00441a037
PDF
Reactions of anodically generated radicals with oxygen
John E. Barry, Manuel Finkelstein, Edward A. Mayeda, and Sidney D. Ross
pp 8098 - 8101; DOI:
10.1021/ja00441a038
PDF
Plasmolysis of 2-butene
J. G. Huntington and L. L. Miller
pp 8101 - 8107; DOI:
10.1021/ja00441a039
PDF
Simulation and evaluation of chemical synthesis. Congestion: a conformation-dependent function of steric environment at a reaction center. Application with torsional terms to stereoselectivity of nucleophilic additions to ketones
W. Todd Wipke and P. Gund
pp 8107 - 8118; DOI:
10.1021/ja00441a040
PDF
Carbon-13 nuclear magnetic resonance spectroscopy of evolving reactions. Indanones via aluminum chloride- and sulfuric acid-catalyzed cyclialkylations
Seemon H. Pines and Alan W. Douglas
pp 8119 - 8125; DOI:
10.1021/ja00441a041
PDF
Competing photocyclization and photoenolization of phenyl .alpha.-diketones
Peter J. Wagner, Richard G. Zepp, Kou-Chang Liu, Michael Thomas, Ta-Jyh Lee, and Nicholas J. Turro
pp 8125 - 8134; DOI:
10.1021/ja00441a042
PDF
Photochemistry of alkyl halides. 4. 1-Norbornyl, 1-norbornylmethyl, 1- and 2-adamantyl, and 1-octyl bromides and iodides
Paul J. Kropp, Graham S. Poindexter, Norbert J. Pienta, and David C. Hamilton
pp 8135 - 8144; DOI:
10.1021/ja00441a043
PDF
Strained ring systems. 16. Substituent effects on the pKa values of cis- and trans-1,2-dimethyl-2-X-cyclopropane-1-carboxylic acids and related bicyclo[n.1.0]alkane-1-carboxylic acids
Richard N. McDonald and Robert R. Reitz
pp 8144 - 8155; DOI:
10.1021/ja00441a044
PDF
Synthesis and reactions of the tautomeric complexes .eta.-2,3,4,5-cyclooctatrienoneiron tricarbonyl and bicyclo[4.2.0]octa-2,4-dien-7-oneiron tricarbonyl. Generation of bicyclo[4.2.0]octa-2,4-dien-7-one
Maurice S. Brookhart, George W. Koszalka, Gregory O. Nelson, Gary Scholes, and R. A. Watson
pp 8155 - 8161; DOI:
10.1021/ja00441a045
PDF
Formation of monohomocyclooctatetraene dianions in liquid ammonia. Analysis of the nucleophilic reactivity of the cyclononatrienyl anions generated upon solvent protonation
Leo A. Paquette, Steven V. Ley, Sean G. Traynor, Jeffrey T. Martin, and J. M. Geckle
pp 8162 - 8172; DOI:
10.1021/ja00441a046
PDF
An electron spin resonance study of the radical anions of two dimethylcyclooctatetraenes
James H. Hammons, Charles T. Kresge, and Leo A. Paquette
pp 8172 - 8174; DOI:
10.1021/ja00441a047
PDF
Thermally promoted ring cleavage reactions of stereoisomeric tetracyclo[4.3.0.02,5.07,9]non-3-enes, pentacyclo[5.3.0.02,6.03,5.08,10]decanes, and their epoxide counterparts
Leo A. Paquette and Michael J. Carmody
pp 8175 - 8181; DOI:
10.1021/ja00441a048
PDF
Pressure dependence of the thermolysis of tetramethyl-1,2-dioxetane: the volume of activation and its mechanistic implications
R. Schmidt, H. C. Steinmetzer, H. D. Brauer, and H. Kelm
pp 8181 - 8185; DOI:
10.1021/ja00441a049
PDF
Studies on the syntheses of heterocyclic compounds. 675. A facile regiospecific and stereocontrolled synthesis of a diterpene alkaloid intermediate from benzocyclobutenes
Tetsuji Kametani, Yasuyuki Kato, Toshio Honda, and Keiichiro Fukumoto
pp 8185 - 8190; DOI:
10.1021/ja00441a050
PDF
Kinetic studies on diarylcarbenes
G. L. Closs and B. E. Rabinow
pp 8190 - 8198; DOI:
10.1021/ja00441a051
PDF
Catalysis of decarboxylation of oxalacetic acid by modified poly(ethylenimines)
Wayne J. Spetnagel and Irving M. Klotz
pp 8199 - 8204; DOI:
10.1021/ja00441a052
PDF
Nucleic acid related compounds. 22. Transformation of ribonucleoside 2',3'-O-ortho esters into halo, deoxy, and epoxy sugar nucleosides using acyl halides. Mechanism and structure of products
Morris J. Robins, Rudolf Mengel, Roger A. Jones, and Yves Fouron
pp 8204 - 8213; DOI:
10.1021/ja00441a053
PDF
Nucleic acid related compounds. 23. Transformation of ribonucleoside 2',3'-O-ortho esters into unsaturated and deoxy sugar nucleosides via enol ester-substituted iodo intermediates
Morris J. Robins, Roger A. Jones, and Rudolf Mengel
pp 8213 - 8217; DOI:
10.1021/ja00441a054
PDF
Synthesis of cytosine radiolysis products: cis- and trans-1-carbamoyl-4,5-dihydroxyimidazolidin-2-one
Nelson J. Leonard and David F. Wiemer
pp 8218 - 8221; DOI:
10.1021/ja00441a055
PDF
An analysis of the visible absorption spectrum of chlorophyll a monomer, dimer, and oligomers in solution
Lester L. Shipman, Therese M. Cotton, James R. Norris, and Joseph J. Katz
pp 8222 - 8230; DOI:
10.1021/ja00441a056
PDF
Mechanistic studies of carboxypeptidase Y. Kinetic detection of an acyl-enzyme intermediate in trimethylacetate esterase action
K. T. Douglas, Y. Nakagawa, and E. T. Kaiser
pp 8231 - 8236; DOI:
10.1021/ja00441a057
PDF
Berninamycin. 2. Products of acidic hydrolysis, methanolysis, and acetolysis of berninamycin A
Jerrold M. Liesch, David S. Millington, Ramesh C. Pandey, and Kenneth L. Rinehart
pp 8237 - 8249; DOI:
10.1021/ja00441a058
PDF
Determination of rotational correlation times of proteins in solution from carbon-13 spin-lattice relaxation measurements. Effect of magnetic field strength and anisotropic rotation
David J. Wilbur, Raymond S. Norton, Arthur O. Clouse, Robert Addleman, and Adam Allerhand
pp 8250 - 8254; DOI:
10.1021/ja00441a059
PDF
Terbium(III) emission as a probe of calcium(II) binding sites in proteins
Harry G. Brittain, Frederick S. Richardson, and R. Bruce Martin
pp 8255 - 8260; DOI:
10.1021/ja00441a060
PDF
Carbenic rearrangement and fragmentation of bicyclo[4.2.2]deca-2,4,9-trien-7-ylidene and bicyclo[4.2.1]nona-2,4,7-trien-9-ylidene
T. V. Rajan Babu and H. Shechter
pp 8261 - 8262; DOI:
10.1021/ja00441a061
PDF
Stereochemical rigidity and enantiomerization of bis(diisopropylamino)dialkylaminoboranes
Kay K. Curry and John W. Gilje
pp 8262 - 8264; DOI:
10.1021/ja00441a062
PDF
Chemistry of metal carbonyl anions. 8. Derivatives of pentacarbonylvanadate(-III), V(CO)53-
John E. Ellis and Michael C. Palazzotto
pp 8264 - 8264; DOI:
10.1021/ja00441a063
PDF
Asymmetric hydrogenation with new chiral functionalized bisphosphine-rhodium complexes
Kazuo Achiwa
pp 8265 - 8266; DOI:
10.1021/ja00441a064
PDF
An examination of the heteronins by carbon-13 nuclear magnetic resonance
A. G. Anastassiou and E. Reichmanis
pp 8266 - 8267; DOI:
10.1021/ja00441a065
PDF
An examination of the 9-heterobicyclo[4.2.1]nona-2,4,7-trienes by carbon-13 nuclear magnetic resonance
A. G. Anastassiou and E. Reichmanis
pp 8267 - 8268; DOI:
10.1021/ja00441a066
PDF
A novel base-catalyzed rearrangement. Formation of dibenzo[cd,gh]pentalenide dianion
Arie Dagan and Mordecai Rabinovitz
pp 8268 - 8270; DOI:
10.1021/ja00441a067
PDF
The preservation of metal-carbon bonds and metalloid-carbon bonds during direct fluorination: a surprise even to fluorine chemists
Edmund K. S. Liu and Richard J. Lagow
pp 8270 - 8271; DOI:
10.1021/ja00441a068
PDF
Anodic and cathodic reactions on a chemically modified edge surface of graphite
Bruce E. Firth, Larry L. Miller, Michiharu Mitani, Thomas Rogers, John Lennox, and Royce W. Murray
pp 8271 - 8272; DOI:
10.1021/ja00441a069
PDF
Oxidations on DSA and chirally modified DSA and tin dioxide electrodes
Bruce E. Firth and Larry L. Miller
pp 8272 - 8273; DOI:
10.1021/ja00441a070
PDF
Carbanion chemistry. A room temperature retro-Diels-Alder reaction
Elizabeth S. Bowman, Graham B. Hughes, and John B. Grutzner
pp 8273 - 8274; DOI:
10.1021/ja00441a071
PDF
Molecular beam chemistry: reactions of cesium(1+) ion with chlorobenzene and the electronic state of the phenyl cation
R. C. Horvat, G. D. Miller, and S. A. Safron
pp 8274 - 8276; DOI:
10.1021/ja00441a072
PDF
Hydrolysis of syn- and anti-benzo[a]pyrene diol epoxides: stereochemistry, kinetics, and the effect of an intramolecular hydrogen bond on the rate of syn-diol epoxide solvolysis
John W. Keller, Charles Heidelberger, Fred A. Beland, and Ronald G. Harvey
pp 8276 - 8277; DOI:
10.1021/ja00441a073
PDF
Construction of the 1,5-methano[10]annulene (bicyclo[5.3.1]-undeca-1,3,5,7,9-pentaene) system
Satoru Masamune, Dee W. Brooks, Kazuhiko Morio, and Ronald L. Sobczak
pp 8277 - 8279; DOI:
10.1021/ja00441a074
PDF
Chemistry of organosilicon compounds. 92. An electron spin resonance study on the spiro cyclohexadienyl radicals
Hideki Sakurai, Iko Nozue, and Akira Hosomi
pp 8279 - 8280; DOI:
10.1021/ja00441a075
PDF
A novel photochemical rearrangement of 3-phenylated 2(3H)-oxepinones
Kazuhiro Sato, Hisahiro Hagiwara, Hisashi Uda, Masaji Sato, and Nobuyuki Harada
pp 8281 - 8282; DOI:
10.1021/ja00441a076
PDF
The chemospecific, homogeneous, ambient temperature Ullmann coupling of o-haloarylimines
Frederick E. Ziegler, Kerry W. Fowler, and Sheldon Kanfer
pp 8282 - 8283; DOI:
10.1021/ja00441a077
PDF
Thermal isomerization of (-)-(1R,5R)-6-exo-vinylbicyclo[3.1.0]hex-2-ene to (-)-(1R,5R)-bicyclo[3.2.1]octa-2,6-diene: one-center thermal epimerization of a cyclopropane
John E. Baldwin and Kevin E. Gilbert
pp 8283 - 8284; DOI:
10.1021/ja00441a078
PDF
Structural studies of tautomeric systems: the importance of association for 2-hydroxypyridine-2-pyridone and 2-mercaptopyridine-2-thiopyridone
Peter Beak, Johnny B. Covington, and Stanley G. Smith
pp 8284 - 8286; DOI:
10.1021/ja00441a079
PDF
Exploratory field desorption mass analysis of the photoconversion of adsorbed polycyclic aromatic hydrocarbons
Douglas F. Barofsky and Edward J. Baum
pp 8286 - 8287; DOI:
10.1021/ja00441a080
PDF
Crystal structure of "carboxyethylgermanium sesquioxide"
Minoru Tsutsui, Norihiro Kakimoto, Darrell D. Axtell, Hiroshi Oikawa, and K. Asai
pp 8287 - 8289; DOI:
10.1021/ja00441a081
PDF
Metal clusters in catalysis. 7. Molecular/structure and chemical properties of a novel/metal-metal bonded nickel complex
V. W. Day, S. S. Abdel-Meguid, S. Dabestani, M. G. Thomas, W. R. Pretzer, and E. L. Muetterties
pp 8289 - 8291; DOI:
10.1021/ja00441a082
PDF
Synthesis and interconversion of the isomeric .alpha.- and .beta.-molybdate (Mo8O264-) ions
W. G. Klemperer and W. Shum
pp 8291 - 8293; DOI:
10.1021/ja00441a083
PDF
Collisional activation and metastable ion characteristics. 52. Formation of ethylenebenzenium and protonated benzocyclobutene, but not .alpha.-phenylethyl, cations from the ionization of gaseous .beta.-phenylethyl halides
Claus Koeppel and F. W. McLafferty
pp 8293 - 8294; DOI:
10.1021/ja00441a084
PDF
Additions and Corrections - Some Very Rapid Reactions of Porphyrins in Aqueous Solution
Robert F. Pasternak, Norman Sutin, and Douglas H. Turner
pp 8295 - 8295; DOI:
10.1021/ja00441a600
PDF
Additions and Corrections - Synthesis of Trichloroacetamido-1,3-dienes. Useful Aminobutadiene Equivalents for the Diels-Alder Reaction
Larry E. Overman, and Lane A. Clizbe
pp 8295 - 8295; DOI:
10.1021/ja00441a601
PDF
Additions and Corrections - Application of 13C Nuclear Magnetic Resonance Spectroscopy to the Analysis of Charge Distribution Patterns in Unsaturated Carbonyl-Containing Compounds
Melanie J. Loots, Linda R. Weingarten, and Ronald H. Levin
pp 8295 - 8295; DOI:
10.1021/ja00441a602
PDF
Additions and Corrections - Molecular Orbital Studies of the Protonation of the Methylanisoles
Raymond S. Greenberg, Maurice M. Bursey, and Lee G. Pedersen
pp 8295 - 8295; DOI:
10.1021/ja00441a603
PDF
Additions and Corrections - Nuclear Magnetic Resonance in Pulse Radiolysis. Chemically Induced Dynamic Nuclear Polarization.
A. D. Trifunac, K. W. Johnson, and R. H. Lowers
pp 8295 - 8295; DOI:
10.1021/ja00441a604
PDF
Additions and Corrections - Hydration of NH4F
Peter Kollman, and Irwin Kuntz
pp 8295 - 8296; DOI:
10.1021/ja00441a605
PDF
Book Reviews

pp 8296 - 8300; DOI:
10.1021/ja00441a606
PDF

Issue 26


Statistical phase space theory of polyatomic systems. Application to the cross section and product kinetic energy distribution of the reaction C2H4.cntdot.+ + C2H4 .fwdarw. C3H5+ + CH3
W. J. Chesnavich and M. T. Bowers
pp 8301 - 8309; DOI:
10.1021/ja00442a001
PDF
A theoretical study of intramolecular hydrogen bonding in ortho-substituted phenols and thiophenols
Stephen W. Dietrich, Eugene C. Jorgensen, Peter A. Kollman, and Steve Rothenberg
pp 8310 - 8324; DOI:
10.1021/ja00442a002
PDF
Ab initio calculations on large molecules using molecular fragments. Generalization and characteristics of floating spherical Gaussian basis sets
Gerald M. Maggiora and Ralph E. Christoffersen
pp 8325 - 8332; DOI:
10.1021/ja00442a003
PDF
Stereochemistry in trivalent nitrogen compounds. 30. Torsional and inversional barriers in sulfenylaziridines
Daniel Kost and Morton Rabin
pp 8333 - 8338; DOI:
10.1021/ja00442a004
PDF
Vapor-phase structure and conformation of a long-chain n-alkane. An electron diffraction study
Susan Fitzwater and L. S. Bartell
pp 8338 - 8344; DOI:
10.1021/ja00442a005
PDF
Electronic spectra of substituted copper(II) thioether complexes
Vincent M. Miskowski, John A. Thich, Raymond Solomon, and Harvey J. Schugar
pp 8344 - 8350; DOI:
10.1021/ja00442a006
PDF
Structure of .mu.-dinitrogen-bis(bis(pentamethylcyclopentadienyl)dinitrogenzirconium(II)), {(.eta.5-C5(CH3)5)2ZrN2}2N2
Robert D. Sanner, Juan M. Manriquez, Richard E. Marsh, and John E. Bercaw
pp 8351 - 8357; DOI:
10.1021/ja00442a007
PDF
Structure and magnetism of .mu.-dinitrogen-bis(bis(pentamethylcyclopentadienyl)titanium(II)), {(.eta.5-C5(CH3)5)2Ti}2N2
Robert D. Sanner, D. Michael Duggan, Thomas C. McKenzie, Richard E. Marsh, and John E. Bercaw
pp 8358 - 8365; DOI:
10.1021/ja00442a008
PDF
Electrochemical and spectroscopic studies of manganese(II), -(III), and -(IV) gluconate complexes. 2. Reactivity and equilibriums with molecular oxygen and hydrogen peroxide
Mario E. Bodini and Donald T. Sawyer
pp 8366 - 8371; DOI:
10.1021/ja00442a009
PDF
Observation of a direct interaction between the carbonyl oxygen, O(6), of a N(7)-bonded 6-oxopurine and a metal center. Preparation and crystal and molecular structure of (N-3,4-benzosalicylidene-N',N'-dimethylethylenediamine)(theophyllinato)copper(II) monohydrate
David J. Szalda, Thomas J. Kistenmacher, and Luigi G. Marzilli
pp 8371 - 8377; DOI:
10.1021/ja00442a010
PDF
Oxygenation equilibriums of cobalt(II) complexes of amino acids and dipeptides
Wesley R. Harris, George McLendon, and Arthur E. Martell
pp 8378 - 8381; DOI:
10.1021/ja00442a011
PDF
Mechanisms of reduction of cobaltic porphyrins with various reducing agents
Everly B. Fleischer and Stephen K. Cheung
pp 8381 - 8387; DOI:
10.1021/ja00442a012
PDF
A study of solvent and substituent effects on the redox potentials and electron-transfer rate constants of substituted iron meso-tetraphenylporphyrins
K. M. Kadish, M. M. Morrison, L. A. Constant, L. Dickens, and D. G. Davis
pp 8387 - 8390; DOI:
10.1021/ja00442a013
PDF
Carbon monoxide complexes of iron(II): synthesis and structural studies of five- and six-coordinate complexes of the macrocyclic ligand, C22H22N42-
Virgil L. Goedken, Shie-Ming Peng, Jo A. Molin-Norris, and Young-Ae Park
pp 8391 - 8400; DOI:
10.1021/ja00442a014
PDF
A quantitative treatment of spiroconjugation. Long-range "through-space" interactions and chemical reactivity of spirenes
Michael D. Gordon, Tadamichi Fukunaga, and Howard E. Simmons
pp 8401 - 8407; DOI:
10.1021/ja00442a015
PDF
Conformational analysis and chromic acid oxidation. The rationalization of the rates of oxidation of secondary alcohols
Paul Mueller and Jean C. Perlberger
pp 8407 - 8413; DOI:
10.1021/ja00442a016
PDF
Polylithium compounds. 8. Synthesis of allenes and acetylenes from perlithiopropyne, trilithiobutyne, and dilithio-3-methylbutyne
Witta Priester, Robert West, and T. Ling Chwang
pp 8413 - 8421; DOI:
10.1021/ja00442a017
PDF
Polylithium compounds. 9. Sequential derivatizations of tetralithiopropyne, trilithio-1-butyne, and dilithio-3-methylbutyne with diethyl sulfate and trimethylchlorosilane
Witta Priester and Robert West
pp 8421 - 8425; DOI:
10.1021/ja00442a018
PDF
Polylithium compounds. 10. Preparation and chemistry of polylithiated 2,4-hexadiyne
Witta Priester and Robert West
pp 8426 - 8432; DOI:
10.1021/ja00442a019
PDF
Photochemistry of organochalcogen compounds. 3. Photochemistry of bis(benzoylmethyl)tellurium dichloride
D. G. Marsh, J. Y. C. Chu, J. W. Lewicki, and J. L. Weaver
pp 8432 - 8437; DOI:
10.1021/ja00442a020
PDF
Photochemical cycloaddition of singlet and triplet diphenylvinylene carbonate with vinyl ethers
Frederick D. Lewis, Richard H. Hirsch, Paula M. Roach, and Douglas E. Johnson
pp 8438 - 8446; DOI:
10.1021/ja00442a021
PDF
Cyclophanes. 8. [2.2](1,4)Tropylioparacyclophane tetrafluoroborate. Synthesis and charge-transfer interaction
Joseph G. O'Connor and Philip M. Keehn
pp 8446 - 8450; DOI:
10.1021/ja00442a022
PDF
Intermediates in nucleophilic aromatic substitution. 16. Toward a complete characterization of the mechanism of nucleophilic aromatic substitution by an amine. Kinetics of spiro Meisenheimer complexes derived from N-methylethanolamine
Claude F. Bernasconi, Constantin L. Gehriger, and Rita H. De Rossi
pp 8451 - 8459; DOI:
10.1021/ja00442a023
PDF
Nucleophilic attacks on carbon-nitrogen double bonds. 3. Diversity of mechanisms for the substitution of diarylimidoyl chlorides by amines in acetonitrile
Rachel Ta-Shma and Zvi Rappoport
pp 8460 - 8467; DOI:
10.1021/ja00442a024
PDF
Kinetic studies of the reduction of hemoglobin and myoglobin by chromium(II)
Stanley W. Huth, Kent E. Kimberly, Dennis Piszkiewicz, and Everly B. Fleischer
pp 8467 - 8471; DOI:
10.1021/ja00442a025
PDF
Model compounds for protein nucleic acid interactions. 4. Synthesis and structure of a nucleoside dipeptide, N-(9-.beta.-D-ribofuranosylpurin-6-yl)glycyl-L-alanine-water (1/1.5)
Poojappan Narayanan, Helen M. Berman, and Robert Rousseau
pp 8472 - 8475; DOI:
10.1021/ja00442a026
PDF
Stereoselective horse liver alcohol dehydrogenase catalyzed oxidoreductions of some bicyclic [2.2.1] and [3.2.1] ketones and alcohols
Anthony J. Irwin and J. Bryan Jones
pp 8476 - 8482; DOI:
10.1021/ja00442a027
PDF
Secondary deuterium kinetic isotope effects and the intervention of nonclassical ions in the solvolysis of exo-norborn-2-yl bromobenzene-p-sulfonate
H. Maskill
pp 8482 - 8485; DOI:
10.1021/ja00442a028
PDF
Photoelectron spectra and molecular properties. 57. Electronic structure and reactivity of ylidic systems. 7. Phosphorus ylides: gas phase ionization potentials and charge distribution
K. A. Ostoja Starzewski, H. Tom Dieck, and H. Bock
pp 8486 - 8494; DOI:
10.1021/ja00442a029
PDF
Preparation structure, and role of tetrakis(methoxycarbonyl)palladiacyclopentadiene cyclic diolefin complexes in selective palladium-catalyzed cyclocotrimerization of acetylenes with olefins
Hiroharu Suzuki, Kenji Itoh, Yoshio Ishii, Kalman Simon, and James A. Ibers
pp 8494 - 8500; DOI:
10.1021/ja00442a030
PDF
Cofacial dimer of a dihydrooctaaza[14]annulene complex containing a nickel-nickel bond and related monomeric complexes
Shie-Ming Peng and Virgil L. Goedken
pp 8500 - 8510; DOI:
10.1021/ja00442a031
PDF
Photochemical generation of stable o-xylylene derivatives by the electrocyclic ring opening of some polycyclic benzocyclobutene derivatives
Robert D. Miller, Jaroslav Kolc, and Josef Michl
pp 8510 - 8514; DOI:
10.1021/ja00442a032
PDF
A polyamide support for oligonucleotide synthesis
M. J. Gait and R. C. Sheppard
pp 8514 - 8516; DOI:
10.1021/ja00442a033
PDF
Palladium catalyzed cyclizations to alkaloid skeletons. Facile synthesis of desethylibogamine
Barry M. Trost and Jean P. Genet
pp 8516 - 8517; DOI:
10.1021/ja00442a034
PDF
Opto-galvanic detection of species in flames
R. B. Green, R. A. Keller, P. K. Schenck, J. C. Travis, and G. G. Luther
pp 8517 - 8518; DOI:
10.1021/ja00442a035
PDF