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Volume 103
Main Index

Issue 1


Rectifying interfaces using two-layer films of electrochemically polymerized vinylpyridine and vinylbipyridine complexes of ruthenium and iron on electrodes
H. D. Abruna, P. Denisevich, M. Umana, Thomas J. Meyer, and Royce W. Murray
pp 1 - 5; DOI:
10.1021/ja00391a001
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Natural correlation diagrams. A unifying theoretical basis for analysis of n orbital initiated ketone photoreactions
Bernard Bigot, Alain Devaquet, and Nicholas J. Turro
pp 6 - 12; DOI:
10.1021/ja00391a002
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Collision-induced dissociation mass spectrometry: target gas effects upon scattering and charge exchange
J. A. Laramee, D. Cameron, and R. G. Cooks
pp 12 - 17; DOI:
10.1021/ja00391a003
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A structural study of tris(.beta.-diketonate)europium(III) complexes in solution using magnetic circularly polarized luminescence spectroscopy
Frederick S. Richardson and Harry G. Brittain
pp 18 - 24; DOI:
10.1021/ja00391a004
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An unexpectedly strong hydrogen bond: ab initio calculations and spectroscopic studies of amide-fluoride systems
John Emsley, Deborah J. Jones, Jack M. Miller, Richard E. Overill, and Roland A. Waddilove
pp 24 - 28; DOI:
10.1021/ja00391a005
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NMR study of molecular reorientation under fivefold symmetry - solid permethylferrocene
D. E. Wemmer, D. J. Ruben, and A. Pines
pp 28 - 33; DOI:
10.1021/ja00391a006
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Carbon-13 chemical shifts in solid metal sandwich compounds
D. E. Wemmer and A. Pines
pp 34 - 36; DOI:
10.1021/ja00391a007
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Unimolecular reactions of ionized methyl acetate and its enol: mechanism for the enol to keto isomerization
Judit Hegedus Vajda, Alex G. Harrison, Akira Hirota, and Fred W. McLafferty
pp 36 - 39; DOI:
10.1021/ja00391a008
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The isolated molecule approach. Theoretical studies of the inductive effect
Ronald D. Topsom
pp 39 - 44; DOI:
10.1021/ja00391a009
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3,3'-Bicyclopropenyl: evidence for novel long-range conjugation of .pi. orbitals
Arthur Greenberg and Joel F. Liebman
pp 44 - 48; DOI:
10.1021/ja00391a010
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Interligand steric effects in metal complexes in solution studied through the residual circular dichroism of the d-d transitions: application to tetraaminecobalt(III)-amino acid complexes
Robert Job and Pieter E. Schipper
pp 48 - 51; DOI:
10.1021/ja00391a011
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Reactions involving hydrogen peroxide, iodine, and iodate ion. 7. The smooth catalytic decomposition of hydrogen peroxide, mainly at 50.degree.C
Herman A. Liebhafsky, Ryusaburo Furuichi, and Glenn M. Roe
pp 51 - 56; DOI:
10.1021/ja00391a012
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Redox properties of metalloporphyrin excited states, lifetimes, and related properties of a series of para-substituted tetraphenylporphine carbonyl complexes of ruthenium(II)
D. P. Rillema, J. K. Nagle, L. F. Barringer, and T. J. Meyer
pp 56 - 62; DOI:
10.1021/ja00391a013
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Transition-metal methylene complexes. 14. Reactions of an electron-rich dimetallacyclopropane with protic acids: synthesis and x-ray crystal structures of novel rhodium-methyl and -methylidyne complexes
Wolfgang A. Herrmann, Johann Plank, Doris Riedel, Manfred L. Ziegler, Klaus Weidenhammer, Ernst Guggolz, and Barbara Balbach
pp 63 - 75; DOI:
10.1021/ja00391a014
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A metal ion complex of vitamin B1: the preparation and structure of Cd(thiamine)Cl3.0.6H2O
Roger E. Cramer, Richard B. Maynard, and James A. Ibers
pp 76 - 81; DOI:
10.1021/ja00391a015
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Total synthesis of (.+-.)-isocomene and related studies
Michael C. Pirrung
pp 82 - 87; DOI:
10.1021/ja00391a016
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Formation of vinyl halides from vinyl cations generated by acetylenic participation in biomimetic polyene cyclizations
William S. Johnson, Carl E. Ward, Sharon G. Boots, Michael B. Gravestock, Ronald L. Markezich, Brian E. McCarry, Dominic A. Okorie, and Ronald J. Parry
pp 88 - 98; DOI:
10.1021/ja00391a017
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Ultraviolet absorption spectra and photochemical rearrangements of benzyl and tropylium cations in solid argon
Lester Andrews and Brian W. Keelan
pp 99 - 103; DOI:
10.1021/ja00391a018
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Intramolecular electron transfer and dehalogenation of anion radicals. 3. Halobenzonitriles and cyanobenzyl halides
P. Neta and D. Behar
pp 103 - 106; DOI:
10.1021/ja00391a019
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Computation of peptide-protein interactions. Catalysis by chymotrypsin: prediction of relative substrate reactivities
DeLos F. DeTar
pp 107 - 110; DOI:
10.1021/ja00391a020
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Photoresponsive crown ethers. 2. Photocontrol of ion extraction and ion transport by a bis(crown ether) with a butterfly-like motion
Seiji Shinkai, Takahiro Nakaji, Toshiyuki Ogawa, Kazuyoshi Shigematsu, and Osamu Manabe
pp 111 - 115; DOI:
10.1021/ja00391a021
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Minor and trace sterols in marine invertebrates. 19. Isolation, structure elucidation, and partial synthesis of 24-methylene-25-ethylcholesterol (mutasterol): first example of sterol side-chain bioalkylation at position 25
Lian Niang Li, Ulf Sjoestrand, and Carl Djerassi
pp 115 - 119; DOI:
10.1021/ja00391a022
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Diaryltetraoxypersulfuranes: preparation, characterization, and reactions
William Y. Lam and J. C. Martin
pp 120 - 127; DOI:
10.1021/ja00391a023
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A comparison of hypervalent bond polarizabilities in sulfuranes (10-S-4 species) and persulfuranes (12-S-6 species)
William Y. Lam, Eileen N. Duesler, and J. C. Martin
pp 127 - 135; DOI:
10.1021/ja00391a024
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Rational mechanism for homogeneous hydrogenation of carbon monoxide to alcohols, polyols, and esters
Darryl R. Fahey
pp 136 - 141; DOI:
10.1021/ja00391a025
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Kinetics and mechanism of the conjugate addition of lithium dimethylcuprate to .alpha.,.beta.-unsaturated ketones
Susan Ruth Krauss and Stanley G. Smith
pp 141 - 148; DOI:
10.1021/ja00391a026
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Kinetics of free radicals produced by infrared multiphoton-induced decompositions. 1. Reactions of allyl radicals with nitrogen dioxide and bromine
Irene R. Slagle, Fumiaki Yamada, and David Gutman
pp 149 - 153; DOI:
10.1021/ja00391a027
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High acylation rates and enantioselectivity with cyclodextrin complexes of rigid substrates
George L. Trainor and Ronald Breslow
pp 154 - 158; DOI:
10.1021/ja00391a028
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Molecules with a helix structure. 3. Sulfur-bridged peri-naphthalenes: synthesis, conformational analysis, and photoelectron spectroscopy of the mono-, di-, and trisulfides of 1,8-dimethylnaphthalene
Hans G. Guttenberger, Hans J. Bestmann, Franz L. Dickert, Flemming S. Jorgensen, and James P. Snyder
pp 159 - 168; DOI:
10.1021/ja00391a029
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Low-temperature neutron diffraction studies of carbon-hydrogen-metal interactions in two tantalum-neopentylidene complexes: [Ta(CHCMe3)(PMe3)Cl3]2 [T = 110 K] and the first alkylidene/olefin complex, Ta(.eta.5-C5Me5)(CHCMe3)(.eta.2-C2H4)(PMe3) [T = 20 K]
Arthur J. Schultz, Richard K. Brown, Jack M. Williams, and Richard R. Schrock
pp 169 - 176; DOI:
10.1021/ja00391a030
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Crystal and molecular structure of the isobacteriochlorin: (2,3,7,8-tetrahydro-5,10,15,20-tetraphenylporphinato)(pyridine)zinc(II) benzene solvate
K. M. Barkigia, J. Fajer, L. D. Spaulding, and G. J. B. Williams
pp 176 - 181; DOI:
10.1021/ja00391a031
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Oxidation of dithiols by flavopapain
Herbert E. Fried and E. T. Kaiser
pp 182 - 184; DOI:
10.1021/ja00391a032
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Carbon monoxide bridges two copper centers which experience a very short metal-metal proximity in [Cu2(tmen)2(.mu.-CO)(.mu.-PhCO2)](BPh4)
Marco Pasquali, Carlo Floriani, Amelia Gaetani-Manfredotti, and Carlo Guastini
pp 185 - 186; DOI:
10.1021/ja00391a033
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Reduction of bis(histidine)hemin; model for the proton-coupled reduction of hemoproteins
David A. Baldwin, Vivien M. Campbell, Luigi A. Carleo, Helder M. Marques, and John M. Pratt
pp 186 - 188; DOI:
10.1021/ja00391a034
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Formation of superoxide ion from singlet oxygen. Use of a water-soluble singlet oxygen source
Isao Saito, Teruo Matsuura, and Kenzo Inoue
pp 188 - 190; DOI:
10.1021/ja00391a035
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Metal-hydrogen bond energies in protonated transition-metal complexes
Amy E. Stevens and J. L. Beauchamp
pp 190 - 192; DOI:
10.1021/ja00391a036
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Delocalized .pi. bonding in tetraazadiene metallocycles
Michal E. Gross, William C. Trogler, and James A. Ibers
pp 192 - 193; DOI:
10.1021/ja00391a037
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Total synthesis of (.+-.)-modhephene
Amos B. Smith and Paula J. Jerris
pp 194 - 195; DOI:
10.1021/ja00391a038
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Interaction frontier orbitals
Kenichi Fukui, Nobuaki Koga, and Hiroshi Fujimoto
pp 196 - 197; DOI:
10.1021/ja00391a039
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CNDO/2-predicted charge alternation
Robert D. Stolow, Peter W. Samal, and Thomas W. Giants
pp 197 - 199; DOI:
10.1021/ja00391a040
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Heme asymmetry in deuterohemin-reconstituted cytochrome peroxidase
James D. Satterlee and James E. Erman
pp 199 - 200; DOI:
10.1021/ja00391a041
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Silicon photocathode behavior in acidic vanadium(II)-vanadium(III) solutions
A. Heller, H. J. Lewerenz, and B. Miller
pp 200 - 201; DOI:
10.1021/ja00391a042
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Absence of internal return in the reaction of (4-nitrophenyl)nitromethane with amine bases in toluene solution. Implication on unusually large isotope effects reported for this reaction
A. J. Kresge and M. F. Powell
pp 201 - 202; DOI:
10.1021/ja00391a043
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Kinetics of the reaction of (4-nitrophenyl)nitromethane with tetramethylguanidine in toluene
E. F. Caldin, S. Mateo, and P. Warrick
pp 202 - 204; DOI:
10.1021/ja00391a044
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The circular dichroism and absolute configuration of C3-chiral derivatives of cyclotriveratrylene
Andre Collet and Giovanni Gottarelli
pp 204 - 205; DOI:
10.1021/ja00391a045
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The decomposition of bicyclic endoperoxides: an isomorphous synthesis of frontalin via 1,5-dimethyl-6,7-dioxabicyclo[3.2.1]octane
R. Marshall Wilson and John W. Rekers
pp 206 - 207; DOI:
10.1021/ja00391a046
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2,2',5,5'-Tetramethyldistibolyl. A thermochromic distibine
Arthur J. Ashe, William Butler, and Timothy R. Diephouse
pp 207 - 209; DOI:
10.1021/ja00391a047
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A bridging acetyl group from the reaction of a dinuclear methyl complex with carbon monoxide
Bruno Longato, Jack R. Norton, John C. Huffman, John A. Marsella, and Kenneth G. Caulton
pp 209 - 210; DOI:
10.1021/ja00391a048
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Synthesis and structure of Cu5(BTA)6(t-C4H9NC)4, a mixed-valent copper-nitrogen cluster containing eta3-benzotriazolate
Vicky L. Himes, Alan D. Mighell, and Allen R. Siedle
pp 211 - 212; DOI:
10.1021/ja00391a049
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Evidence for a novel carbene-carbene rearrangement of a new foiled methylene
Udo H. Brinker and Lothar Koenig
pp 212 - 214; DOI:
10.1021/ja00391a050
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Cis-trans isomers of 12-S-6 species--dissociative permutational isomerization of a persulfurane
Ronald S. Michalak and J. C. Martin
pp 214 - 215; DOI:
10.1021/ja00391a051
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Synthesis, structure, and stability of (i,o)-bicyclo[6.2.2]dodeca-9,11-dienes. Generation of unusually expanded carbon-carbon-carbon bond angles
Paul G. Gassman and Rebecca C. Hoye
pp 215 - 217; DOI:
10.1021/ja00391a052
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High methane formation during the temperature-programmed decomposition in flowing hydrogen of supported mononuclear and polynuclear carbonyl complexes
Dennis A. Hucul and Alan Brenner
pp 217 - 219; DOI:
10.1021/ja00391a053
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A strategy for the total synthesis of jatrophone: synthesis of normethyljatrophone
Amos B. Smith, Michael A. Guaciaro, Steven R. Schow, Peter M. Wovkulich, Bruce H. Toder, and Tse Wai Hall
pp 219 - 222; DOI:
10.1021/ja00391a054
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Total synthesis of (.+-.)-lycodoline
Clayton H. Heathcock and Edward F. Kleinman
pp 222 - 223; DOI:
10.1021/ja00391a055
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Isolation and characterization of bicycloendoperoxides derived from methyl linolenate
David E. O'Connor, Edward D. Mihelich, and Milton C. Coleman
pp 223 - 224; DOI:
10.1021/ja00391a056
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Influence of nitrogen-14 on carbon-13 NMR spectra of solids
J. G. Hexem, M. H. Frey, and S. J. Opella
pp 224 - 226; DOI:
10.1021/ja00391a057
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Unusual photoisomerization of an "encased" .alpha.-diketone
Douglas W. Balogh, Leo A. Paquette, Peter Engel, and John F. Blount
pp 226 - 228; DOI:
10.1021/ja00391a058
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Model approach to the pentagonal dodecahedrane. Synthesis and properties of a monoseco derivative
Leo A. Paquette, Douglas W. Balogh, and John F. Blount
pp 228 - 230; DOI:
10.1021/ja00391a059
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Carbon-13 NMR spectra of carbonium ions in the solid state: the sec-butyl cation
Philip C. Myhre and Costantino S. Yannoni
pp 230 - 232; DOI:
10.1021/ja00391a060
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Interaction of metal ions with streptonigrin. 1. Formation of copper(II) and zinc(II) complexes of the antitumor antibiotic
Joseph Hajdu and Ellen C. Armstrong
pp 232 - 234; DOI:
10.1021/ja00391a061
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Resonance enhanced Raman identification of the zinc-oxygen bond in a horse liver alcohol dehydrogenase-nicotinamide adenine dinucleotide-aldehyde transient chemical intermediate
Paul W. Jagodzinski and Warner L. Peticolas
pp 234 - 236; DOI:
10.1021/ja00391a062
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Convenient thermal sources of .beta.-cyanoalkyl radicals from .alpha.-hydroxydiazenes
Avtar S. Nazran and John Warkentin
pp 236 - 237; DOI:
10.1021/ja00391a063
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Stereocontrolled synthesis of steroidal side chains
William G. Dauben and Todd Brookhart
pp 237 - 238; DOI:
10.1021/ja00391a064
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Alkylidene complexes from the reactions of transition-metal dianions with iminium salts: synthesis and spectral characterization of [Mo(CO)5CPh2]
Richard P. Beatty, John M. Maher, and N. John Cooper
pp 238 - 239; DOI:
10.1021/ja00391a065
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A mild procedure for the generation of azomethine imines. Stereochemical factors in the intramolecular 1,3-dipolar addition of azomethine imines and a synthetic approach to saxitoxin
Peter A. Jacobi, Allen Brownstein, Michael Martinelli, and Karl Grozinger
pp 239 - 241; DOI:
10.1021/ja00391a066
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First manganese(III) spin crossover, first d4 crossover. Comment on cytochrome oxidase
P. Greig Sim and Ekk Sinn
pp 241 - 243; DOI:
10.1021/ja00391a067
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A new aqueous chemistry of organometallic, trinuclear cluster compounds of molybdenum
Avi Bino, F. Albert Cotton, and Zvi Dori
pp 243 - 244; DOI:
10.1021/ja00391a068
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Deuterium magnetic resonance study of .alpha.,.omega.-dicarboxylic acid guests in disk micelles of varied bilayer thickness
Bruce J. Forrest, Laura Hecker De Carvalho, L. W. Reeves, and Charles Rodger
pp 245 - 246; DOI:
10.1021/ja00391a069
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Issue 2


Macrochelate formation in monomeric metal ion complexes of nucleoside 5'-triphosphates and the promotion of stacking by metal ions. Comparison of the self-association of purine and pyrimidine 5'-triphosphates using proton nuclear magnetic resonance
Kurt H. Scheller, Fritz Hofstetter, Paul R. Mitchell, Bernhard Prijs, and Helmut Sigel
pp 247 - 260; DOI:
10.1021/ja00392a001
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Nonpotential energy (NPE) effects in organic chemical reactions: development of a suitable force field
Christine D. Chalk, Barrie G. Hutley, James McKenna, Leslie B. Sims, and Ian H. Williams
pp 260 - 268; DOI:
10.1021/ja00392a002
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Calculations of kinetic isotope effects for SN2 bromine exchange reactions of alkyl bromides: development of transition-state force field for calculation of nonpotential energy effects
James McKenna, Leslie B. Sims, and Ian H. Williams
pp 268 - 272; DOI:
10.1021/ja00392a003
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NPE effects in bimolecular nucleophilic substitution
Christine D. Chalk, James McKenna, and Ian H. Williams
pp 272 - 281; DOI:
10.1021/ja00392a004
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NPE effects in bimolecular elimination
Christine D. Chalk, James McKenna, Leslie B. Sims, and Ian H. Williams
pp 281 - 284; DOI:
10.1021/ja00392a005
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A theoretical approach to the Birch reduction. Structures and stabilities of cyclohexadienes
Arthur J. Birch, Alan L. Hinde, and Leo Radom
pp 284 - 289; DOI:
10.1021/ja00392a006
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Molecular structure of selected S-methylthiophenium tetrafluoroborates and dibenzothiophene 5-oxide
J. A. Hashmall, V. Horak, L. E. Khoo, C. O. Quicksall, and M. K. Sun
pp 289 - 295; DOI:
10.1021/ja00392a007
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Optical rotatory dispersion studies. 132. Conformational isotope effect in deuterium-substituted cyclohexanones
Shy-Fuh Lee, Guenter Barth, and Carl Djerassi
pp 295 - 301; DOI:
10.1021/ja00392a008
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Stereospecific transformation of 2,2-dimethylcyclobutanols into optically active 1,2-cis-disubstituted cyclopropanes
Martin Karpf and Carl Djerassi
pp 302 - 306; DOI:
10.1021/ja00392a009
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An electrode-supported oxidation catalyst based on ruthenium(IV). pH "encapsulation" in a polymer film
George J. Samuels and Thomas J. Meyer
pp 307 - 312; DOI:
10.1021/ja00392a010
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Isomers and isomerization: elements of Redfield's combinatorial theory
R. A. Davidson
pp 312 - 314; DOI:
10.1021/ja00392a011
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Proton transfers in hydrogen-bonded systems. Cationic oligomers of water
Steve Scheiner
pp 315 - 320; DOI:
10.1021/ja00392a012
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Photoredox reactions in functional micellar assemblies. Use of amphiphilic redox relays to achieve light energy conversion and charge separation
Pierre Alain Brugger, Pierre P. Infelta, Andre M. Braun, and Michael Gratzel
pp 320 - 326; DOI:
10.1021/ja00392a013
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Laser excitation and emission spectra of the hexafluorobenzene cation in the gas phase
Trevor Sears, Terry A. Miller, and V. E. Bondybey
pp 326 - 329; DOI:
10.1021/ja00392a014
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Charge distribution and bonding in the series (CF3)2On (n = 0-3) and in CF3SCF3 deduced from gas-phase x-ray photoelectron spectroscopy. Evidence for double bonding in saturated compounds
Patrick Brant, Joseph A. Hashmall, Forrest L. Carter, Ronald De Marco, and William B. Fox
pp 329 - 334; DOI:
10.1021/ja00392a015
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Quantum and statistical mechanical studies of liquids. 10. Transferable intermolecular potential functions for water, alcohols, and ethers. Application to liquid water
William L. Jorgensen
pp 335 - 340; DOI:
10.1021/ja00392a016
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Quantum and statistical mechanical studies of liquids. 11. Transferable intermolecular potential functions. Application to liquid methanol including internal rotation
William L. Jorgensen
pp 341 - 345; DOI:
10.1021/ja00392a017
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Quantum and statistical mechanical studies of liquids. 12. Simulation of liquid ethanol including internal rotation
William L. Jorgensen
pp 345 - 350; DOI:
10.1021/ja00392a018
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Synthesis and structure of carborane-substituted cyclic and polymeric phosphazenes
H. R. Allcock, A. G. Scopelianos, J. P. O'Brien, and M. Y. Bernheim
pp 350 - 357; DOI:
10.1021/ja00392a019
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Structures of [(CH3)2(t-BuN)W]2(.mu.-t-BuN)2 and [((CH3)2N)2Ti]2(.mu.-t-BuN)2. A molecular orbital explanation of the existence of unsymmetrically or symmetrically bridging organoimido ligands
David L. Thorn, William A. Nugent, and Richard L. Harlow
pp 357 - 363; DOI:
10.1021/ja00392a020
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Electronic structure of the rhodium-rhodium bond in Rh2(O2CR)2(PY3)2 by electron spin resonance study of their cation radicals
Takashi Kawamura, Kadzuhiko Fukamachi, Takayoshi Sowa, Shigeru Hayashida, and Teijiro Yonezawa
pp 364 - 369; DOI:
10.1021/ja00392a021
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Mechanism of the formation of dihydrogen from the photoinduced reactions of poly(pyridine)ruthenium(II) and poly(pyridine)rhodium(III) complexes
S.-F. Chan, Mei Chou, Carol Creutz, Tadashi Matsubara, and Norman Sutin
pp 369 - 379; DOI:
10.1021/ja00392a022
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Photogeneration of reactive [ReH(diphos)2]. Its reversible coordination of carbon dioxide and activation of aromatic carbon-hydrogen bonds
Mark G. Bradley, David A. Roberts, and Gregory L. Geoffroy
pp 379 - 384; DOI:
10.1021/ja00392a023
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Magnetic exchange interactions in binuclear copper(II) complexes with only a single hydroxo bridge: the x-ray structure of .mu.-hydroxo-tetrakis(2,2'-bipyridine)dicopper(II) perchlorate
Muin S. Haddad, Scott R. Wilson, Derek J. Hodgson, and David N. Hendrickson
pp 384 - 391; DOI:
10.1021/ja00392a024
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Electrostatic ligand-ligand interactions in ternary amino acid-palladium(II) complexes. Synthetic studies and spectroscopic evidence
Osamu Yamauchi and Akira Odani
pp 391 - 398; DOI:
10.1021/ja00392a025
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Chemical and x-ray structural studies on the (acetato)- and (trifluoroacetato)pentacarbonylmetalates of chromium and molybdenum
F. Albert Cotton, D. J. Darensbourg, and B. W. S. Kolthammer
pp 398 - 405; DOI:
10.1021/ja00392a026
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X-ray crystallographic studies on a sulfurane with a diequatorial four-membered ring and on a fluorinated cyclic disulfoxide
Dietmar Schomburg, Qui-Chee Mir, and Jean'ne M. Shreeve
pp 406 - 409; DOI:
10.1021/ja00392a027
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Stabilization of charged substrates by first- and second-row heteroatoms
James R. Larson and N. D. Epiotis
pp 410 - 416; DOI:
10.1021/ja00392a028
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Addition of aromatic thiols to conjugated cycloalkenones, catalyzed by chiral .beta.-hydroxy amines. A mechanistic study of homogeneous catalytic asymmetric synthesis
Henk Hiemstra and Hans Wynberg
pp 417 - 430; DOI:
10.1021/ja00392a029
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Kinetic isotope effect study on methyl participation in solvolysis of neopentyl-type arenesulfonates
Takashi Ando, Hiroshi Yamataka, Hisao Morisaki, Junko Yamawaki, Junjiro Kuramochi, and Yasuhide Yukawa
pp 430 - 436; DOI:
10.1021/ja00392a030
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Deuterium isotope effects for migrating and nonmigrating groups in the solvolysis of neopentyl-type esters
V. J. Shiner and Jimmy J. Tai
pp 436 - 442; DOI:
10.1021/ja00392a031
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Acid-catalyzed decomposition of trialkyltriazenes: protected alkyldiazonium ions
David H. Sieh and Christopher J. Michejda
pp 442 - 445; DOI:
10.1021/ja00392a032
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Energetics of heme-protein interactions in hemoglobin
Arieh Warshel and Robert M. Weiss
pp 446 - 451; DOI:
10.1021/ja00392a033
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A reinvestigation of the mechanism of Pseudomonas testosteroni .DELTA.5-3-ketosteroid isomerase
Antoinette Viger, Suzy Coustal, and Andree Marquet
pp 451 - 458; DOI:
10.1021/ja00392a034
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Transition-metal binding site of bleomycin. Cobalt(III) bleomycin
M. Tsukayama, C. R. Randall, F. S. Santillo, and J. C. Dabrowiak
pp 458 - 461; DOI:
10.1021/ja00392a035
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Total synthesis of (.+-.)-dihydroperiphylline
Harry H. Wasserman and Haruo Matsuyama
pp 461 - 462; DOI:
10.1021/ja00392a036
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Epoxy alcohol rearrangements: hydroxyl-mediated delivery of Lewis acid promoters
D. J. Morgans, K. B. Sharpless, and Sean G. Traynor
pp 462 - 464; DOI:
10.1021/ja00392a037
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Asymmetric epoxidation provides shortest routes to four chiral epoxy alcohols which are key intermediates in syntheses of methymycin, erythromycin, leukotriene C-1, and disparlure
Bryant E. Rossiter, Tsutomu Katsuki, and K. Barry Sharpless
pp 464 - 465; DOI:
10.1021/ja00392a038
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Unimolecular dissociations at short times. A comparison of angle-resolved mass spectrometry and field ionization kinetics
D. J. Burinsky, G. L. Glish, R. G. Cooks, J. J. Zwinselman, and N. M. M. Nibbering
pp 465 - 467; DOI:
10.1021/ja00392a039
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Observation of conformationally distinct proline residues in two cyclic peptides by solid-state nuclear magnetic resonance
L. G. Pease, M. H. Frey, and S. J. Opella
pp 467 - 468; DOI:
10.1021/ja00392a040
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1-Azetine: thermal ring opening to 2-azabutadiene
J. C. Guillemin, J. M. Denis, and A. Lablache-Combier
pp 468 - 469; DOI:
10.1021/ja00392a041
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Use of singly modified cytochrome c derivatives to determine the site for electron transfer in reactions with inorganic complexes
J. Butler, D. M. Davies, A. G. Sykes, W. H. Koppenol, N. Osheroff, and E. Margoliash
pp 469 - 471; DOI:
10.1021/ja00392a042
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Liquid crystal characterization of compounds chiral by deuterium substitution
Giovanni Gottarelli, Bruno Samori, Claudio Fuganti, and Piero Grasselli
pp 471 - 472; DOI:
10.1021/ja00392a043
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Biosynthetic intermediates to the macrocyclic trichothecenes
Bruce B. Jarvis, Gowsala Pavanasasivam, C. E. Holmlund, Tuley DeSilva, G. Patrick Stahly, and Eugene P. Mazzola
pp 472 - 474; DOI:
10.1021/ja00392a044
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A synthetic route to the C4 octadienic esters of trichothecenes from D-glucose
Deen Bhandu Tulshian and Bert Fraser-Reid
pp 474 - 475; DOI:
10.1021/ja00392a045
PDF
New stereoselective synthesis of steroids
Yoshihiko Ito, Masashi Nakatsuka, and Takeo Saegusa
pp 476 - 477; DOI:
10.1021/ja00392a046
PDF
Directional preferences of nonbonded atomic contacts with divalent sulfur in terms of its orbital orientations. 2. Sulfur.cntdot..cntdot..cntdot.sulfur interactions and nonspherical shape of sulfur in crystals
T. N. Guru Row and R. Parthasarathy
pp 477 - 479; DOI:
10.1021/ja00392a047
PDF
Gas-phase reactions of cyclic silanes
S. A. Sullivan, C. H. DePuy, and R. Damrauer
pp 480 - 481; DOI:
10.1021/ja00392a048
PDF
Thermodynamics of solution of nonpolar gases in a fused salt. Hydrophobic bonding behavior in a nonaqueous system
D. Fennell Evans, Shaw-Horng Chen, George W. Schriver, and Edward M. Arnett
pp 481 - 482; DOI:
10.1021/ja00392a049
PDF

Issue 3


Vibrational circular dichroism in (R)-cyclohexanone-3-d, (R)-3-methylcyclohexanone, and (1S)-2-adamantanone-4-13C
Curtis Marcott, Kerin Scanlon, John Overend, and Albert Moscowitz
pp 483 - 485; DOI:
10.1021/ja00393a001
PDF
Characterization of matrix-isolated antiaromatic three-membered heterocycles. Preparation of the elusive thiirene molecule
A. Krantz and J. Laureni
pp 486 - 496; DOI:
10.1021/ja00393a002
PDF
Kinetics and thermodynamics for ion-molecule association reactions
J. S. Chang and D. M. Golden
pp 496 - 500; DOI:
10.1021/ja00393a003
PDF
Protein hydration from water oxygen-17 magnetic relaxation
Bertil Halle, Thomas Andersson, Sture Forsen, Bjoern Lindman, and Bjoern Lindman
pp 500 - 508; DOI:
10.1021/ja00393a004
PDF
Gas-phase ion chemistry of titanium tetrachloride and methyltitanium chloride (CH3TiCl3). Reaction of CH3TiCl2+ with ethylene
Jack S. Uppal, Douglas E. Johnson, and Ralph H. Staley
pp 508 - 511; DOI:
10.1021/ja00393a005
PDF
Electrogenerated chemiluminescence. 37. Aqueous ecl systems based on tris(2,2'-bipyridine)ruthenium(2+) and oxalate or organic acids
Israel Rubinstein and Allen J. Bard
pp 512 - 516; DOI:
10.1021/ja00393a006
PDF
Synthesis of "face to face" porphyrin dimers linked by 5,15-substituents: potential binuclear multielectron redox catalysts
James P. Collman, Anthony O. Chong, Geoffrey B. Jameson, Richard T. Oakley, Eric Rose, Eric R. Schmittou, and James A. Ibers
pp 516 - 533; DOI:
10.1021/ja00393a007
PDF
The synthesis and x-ray crystal structure of a novel Vilsmeier-Haack adduct: [tris(2-aminoethyl)amine][3-(dimethylamino)-2-aminoacrylyl chloride]cobalt(III) chloride tetrachlorozincate hydrate
W. G. Jackson, A. M. Sargeson, P. A. Tucker, and A. D. Watson
pp 533 - 540; DOI:
10.1021/ja00393a008
PDF
Sterically induced, spontaneous cobalt-carbon bond homolysis and .beta.-elimination reactions of primary and secondary organocobalamins
Gerhard N. Schrauzer and John H. Grate
pp 541 - 546; DOI:
10.1021/ja00393a009
PDF
Aspects of the hydrogenation of carbon disulfide by transition-metal cluster compounds. The reactions of carbon disulfide with hydridotriosmium-carbonyl clusters
Richard D. Adams, Nancy M. Golembeski, and John P. Selegue
pp 546 - 555; DOI:
10.1021/ja00393a010
PDF
Catalytic hydrogenation of aromatic hydrocarbons. Stereochemical definition of the catalytic cycle for .eta.3-C3H5Co(P(OCH3)3)3
J. R. Bleeke and E. L. Muetterties
pp 556 - 564; DOI:
10.1021/ja00393a011
PDF
Molecular design by cycloaddition reactions. 37. Peri-, stereo-, and regioselectivities in cycloaddition reactions of 7-isopropylidenebenzonorbornadiene
Tadashi Sasaki, Kenji Hayakawa, Takashi Manabe, and Sumio Nishida
pp 565 - 572; DOI:
10.1021/ja00393a012
PDF
Catalysis of the methoxyaminolysis of phenyl acetate by a preassociation mechanism with a solvent isotope effect maximum
Michael M. Cox and William P. Jencks
pp 572 - 580; DOI:
10.1021/ja00393a013
PDF
Concerted bifunctional proton transfer and general-base catalysis in the methoxyaminolysis of phenyl acetate
Michael M. Cox and William P. Jencks
pp 580 - 587; DOI:
10.1021/ja00393a014
PDF
Dimethylcyclodecyl cations. Evidence for .mu.-hydrido bridging
R. P. Kirchen, K. Ranganayakulu, A. Rauk, B. P. Singh, and T. S. Sorensen
pp 588 - 596; DOI:
10.1021/ja00393a015
PDF
.mu.-Hydrido bridging between secondary and tertiary "carbocationic" ends and the analogy to unsymmetrical allyl cations
R. P. Kirchen, N. Okazawa, K. Ranganayakulu, A. Rauk, and T. S. Sorensen
pp 597 - 604; DOI:
10.1021/ja00393a016
PDF
Structure of saxitoxin in solutions and stereochemistry of dihydrosaxitoxins
Yuzuru Shimizu, Chien-Ping Hsu, and Almoursi Genenah
pp 605 - 609; DOI:
10.1021/ja00393a017
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 36. Stereoelectronic effects in hydrogen atom abstraction from ethers
V. Malatesta and K. U. Ingold
pp 609 - 614; DOI:
10.1021/ja00393a018
PDF
Stereoelectronic effects in hydrogen atom abstraction from substituted 1,3-dioxanes
A. L. J. Beckwith and C. J. Easton
pp 615 - 619; DOI:
10.1021/ja00393a019
PDF
Absolute rate constants for the reactions of tert-butoxyl, tert-butylperoxyl, and benzophenone triplet with amines: the importance of a stereoelectronic effect
D. Griller, J. A. Howard, P. R. Marriott, and J. C. Scaiano
pp 619 - 623; DOI:
10.1021/ja00393a020
PDF
The structure of amidyl radicals. Evidence for the .pi.-electronic ground state and for twist about the acyl-nitrogen bond by electron paramagnetic resonance spectroscopy
R. Sutcliffe, D. Griller, J. Lessard, and K. U. Ingold
pp 624 - 628; DOI:
10.1021/ja00393a021
PDF
Dehydration and enolization rates of oxalacetate: catalysis by tertiary amines
Mark Emly and Daniel L. Leussing
pp 628 - 634; DOI:
10.1021/ja00393a022
PDF
Exciplex emissions of intra- and intermolecular benzophenone and N,N-dimethylaniline systems
Hiroshi Masuhara, Yasuhiro Maeda, Hirochika Nakajo, Noboru Mataga, Kyoichi Tomita, Hitoshi Tatemitsu, Yoshiteru Sakata, and Soichi Misumi
pp 634 - 640; DOI:
10.1021/ja00393a023
PDF
Photosensitized dissociation of di-tert-butyl peroxide. Energy transfer to a repulsive excited state
J. C. Scaiano and Gene G. Wubbels
pp 640 - 645; DOI:
10.1021/ja00393a024
PDF
Acid-catalyzed reactions of N-arylhydroxylamines and related compounds with benzene. Iminium-benzenium ions
Koichi Shudo, Toshiharu Ohta, and Toshihiko Okamoto
pp 645 - 653; DOI:
10.1021/ja00393a025
PDF
A phosphonamidate dipeptide analog as an inhibitor of carboxypeptidase A
Neil E. Jacobsen and Paul A. Bartlett
pp 654 - 657; DOI:
10.1021/ja00393a026
PDF
The incorporation of [1-13C,14C,methylamino-15N]-N-methylputrescine into nicotine and scopolamine established by means of carbon-13 nuclear magnetic resonance
Edward Leete and James A. McDonell
pp 658 - 662; DOI:
10.1021/ja00393a027
PDF
Electron pathways in catalase and peroxidase enzymic catalysis. Metal and macrocycle oxidations of iron porphyrins and chlorins
Louise Karle Hanson, Chi K. Chang, Mary S. Davis, and Jack Fajer
pp 663 - 670; DOI:
10.1021/ja00393a028
PDF
Cycloreversion reactions of phenylated cage compounds induced by electron transfer
Toshio Mukai, Katsuhiro Sato, and Yoshiro Yamashita
pp 670 - 672; DOI:
10.1021/ja00393a029
PDF
Statistical state solvation sites
P. K. Mehrotra, Francis T. Marchese, and David L. Beveridge
pp 672 - 673; DOI:
10.1021/ja00393a030
PDF
Molybdenum(0)/dehydroxylated alumina catalysts
Ryuichi Nakamura, Robert G. Bowman, and Robert L. Burwell
pp 673 - 674; DOI:
10.1021/ja00393a031
PDF
Gas-phase nucleophilic addition reactions of phenylnitrene anion radical with certain carbonyl-containing molecules
Richard N. McDonald and A. Kasem Chowdhury
pp 674 - 676; DOI:
10.1021/ja00393a032
PDF
Gas-phase ion-molecule reactions of phenylnitrene anion
Mark J. Pellerite and John I. Brauman
pp 676 - 677; DOI:
10.1021/ja00393a033
PDF
Internal rotation in liquid 1,2-dichloroethane and n-butane
William L. Jorgensen
pp 677 - 679; DOI:
10.1021/ja00393a034
PDF
Design, synthesis, and characterization of a cytotoxic peptide with melittin-like activity
William F. DeGrado, F. J. Kezdy, and E. T. Kaiser
pp 679 - 681; DOI:
10.1021/ja00393a035
PDF
Evidence for a second mode of hydroxypalladation in aqueous solution
N. Gragor and P. M. Henry
pp 681 - 682; DOI:
10.1021/ja00393a036
PDF
Isotopic labeling at natural abundance: multiphoton dissociation of perfluoropropene
P. A. Hackett, C. Willis, and W. S. Nip
pp 682 - 683; DOI:
10.1021/ja00393a037
PDF
Hydroxide ion as a catalyst for nucleophilic substitution of thiamin analogs by thiolate ions. A rival for sulfite ion
John A. Zoltewicz and Georg Uray
pp 683 - 684; DOI:
10.1021/ja00393a038
PDF
Identification of a biradical as the reactive form of the 2-isopropylidenecyclopentane-1,3-diyl singlet species
Mark R. Mazur and Jerome A. Berson
pp 684 - 686; DOI:
10.1021/ja00393a039
PDF
Oxygen-atom transfer from iodosobenzene to ketenes, .alpha.-keto carboxylic acids, and ketones
Robert M. Moriarty, Satish C. Gupta, Henry Hu, Daniel R. Berenschot, and Kenneth B. White
pp 686 - 688; DOI:
10.1021/ja00393a040
PDF
Synthetic studies on arene-olefin cycloadditions: total synthesis of (.+-.)-.alpha.-cedrene
P. A. Wender and J. J. Howbert
pp 688 - 690; DOI:
10.1021/ja00393a041
PDF
A type I aqueous cholesteric lyomesophase
B. J. Forrest, L. W. Reeves, M. R. Vist, C. Rodger, and M. E. Marcondes Helene
pp 690 - 691; DOI:
10.1021/ja00393a042
PDF
Radical coupling of mercaptide ligands upon oxidation of organometallic mercaptide complexes
P. M. Treichel and L. D. Rosenhein
pp 691 - 692; DOI:
10.1021/ja00393a043
PDF
First authentic example of a difference in the structural organometallic chemistry of zirconium and hafnium: crystal and molecular structure of bis(.eta.5-cyclopentadienyl)bis(.eta.1-cyclopentadienyl)hafnium
Robin D. Rogers, R. Vann Bynum, and Jerry L. Atwood
pp 692 - 693; DOI:
10.1021/ja00393a044
PDF
Manifestations of sulfur to sulfur through-bond interactions in complex ion spectra
C. A. Stein and Henry Taube
pp 693 - 695; DOI:
10.1021/ja00393a045
PDF
Photochemistry of transition-metal polyhydrides: dimerization of tris(dimethylphenylphosphine)pentahydrorhenium following photodissociation of phosphine
M. A. Green, J. C. Huffman, and K. G. Caulton
pp 695 - 696; DOI:
10.1021/ja00393a046
PDF
On the mechanism of T4 RNA ligase
F. R. Bryant and S. J. Benkovic
pp 696 - 697; DOI:
10.1021/ja00393a047
PDF
Mechanistic photochemistry of acylsilanes. 1. Reaction with alcohols
Robert A. Bourque, Paul D. Davis, and J. Christopher Dalton
pp 697 - 699; DOI:
10.1021/ja00393a048
PDF
Mechanistic photochemistry of acylsilanes. 2. Reaction with electron-poor olefins
J. Christopher Dalton and Robert A. Bourque
pp 699 - 700; DOI:
10.1021/ja00393a049
PDF
Chiral and functionalized face-discriminated and side-discriminated macrocyclic polyethers. Syntheses and crystal structures
J. P. Behr, J. M. Lehn, D. Moras, and J. C. Thierry
pp 701 - 703; DOI:
10.1021/ja00393a050
PDF
Di-.mu.-oxo-(.eta.1:.eta.5-1,2,3,4-tetramethyl-5-methylene-1,3-cyclopentadiene)-bis[(.eta.-pentamethylcyclopentadienyl)titanium], (.mu.-0)2[.mu.-[.eta.1:.eta.5-C5(CH2)(CH3)4]][Ti(.eta.5-C5(CH3)5)]]2, a complex containing a bridging tetramethylmethylenecyclopentadienyl ligand
Frank Bottomley, Ivan J. B. Lin, and Peter S. White
pp 703 - 704; DOI:
10.1021/ja00393a051
PDF
Conformational mobility in 1,4-bridged cyclooctanes. Carbon-13 NMR evidence for facile chirality inversion
Rainer Dyllick-Brenzinger and Henrik Olsen
pp 704 - 706; DOI:
10.1021/ja00393a052
PDF
Solid-phase synthesis of hentriacontanucleotide
Piotr Dembek, Kenichi Miyoshi, and Keiichi Itakura
pp 706 - 708; DOI:
10.1021/ja00393a053
PDF
Cyclization dynamics of polymers. 4. Electron exchange between chromophores on the ends of alkyl chains: diffusion-controlled or conformationally controlled cyclization?
Mitchell A. Winnik
pp 708 - 709; DOI:
10.1021/ja00393a054
PDF
Hydrogenations with molybdenum hydrides formed in the reaction of molybdenum atoms with tetrahydrofuran
Austin H. Reid, Philip B. Shevlin, Sock Sung Yun, and Thomas R. Webb
pp 709 - 711; DOI:
10.1021/ja00393a055
PDF
Regiospecific A,C- and A,D-disulfonate capping of .beta.-cyclodextrin
Iwao Tabushi, Yasuhisa Kuroda, Kanichi Yokota, and Lung Chi Yuan
pp 711 - 712; DOI:
10.1021/ja00393a056
PDF
Facile degradation by superoxide ion of carbon tetrachloride, chloroform, methylene chloride, and p,p'-DDT in aprotic media
Julian L. Roberts and Donald T. Sawyer
pp 712 - 714; DOI:
10.1021/ja00393a057
PDF
Ferrocenyl-stabilized two-coordinate phosphorus cations: synthesis, coordination chemistry, and Moessbauer spectroscopy
S. G. Baxter, R. L. Collins, A. H. Cowley, and S. F. Sena
pp 714 - 715; DOI:
10.1021/ja00393a058
PDF
Thermal rearrangement of 1,1-difluorospiropentane
William R. Dolbier, Simon F. Sellers, Basil H. Al-Sader, and Seth Elsheimer
pp 715 - 717; DOI:
10.1021/ja00393a059
PDF
Thermal rearrangements of 1,1,2,2- and 1,1,4,4-tetrafluorospiropentanes
William R. Dolbier, Simon F. Sellers, Basil H. Al-Sader, and Thomas H. Fielder
pp 717 - 718; DOI:
10.1021/ja00393a060
PDF
Cation-radical catalyzed Diels-Alder reaction
Dennis J. Bellville, David W. Wirth, and Nathan L. Bauld
pp 718 - 720; DOI:
10.1021/ja00393a061
PDF
Electronic spin of the ground state of m-naphthoquinomethane, a non-Kekule molecule with nondegenerate Hueckel nonbonding molecular orbitals (NBMOs)
David E. Seeger, Edwin F. Hilinski, and Jerome A. Berson
pp 720 - 721; DOI:
10.1021/ja00393a062
PDF
Chirally directed synthesis of (-)-methyl 5(S), 6(S)-oxido-7-hydroxyheptanoate, a key intermediate for the total synthesis of leukotrienes A, C, D and E
E. J. Corey, Shunichi Hashimoto, and Alan E. Barton
pp 721 - 722; DOI:
10.1021/ja00393a063
PDF
Short, stereospecific total syntheses of (.+-.)-modhephene and (.+-.)-epimodhephene
Heinrich Schostarez and Leo A. Paquette
pp 722 - 724; DOI:
10.1021/ja00393a064
PDF
A total synthesis of racemic eriolanin
M. R. Roberts and R. H. Schlessinger
pp 724 - 725; DOI:
10.1021/ja00393a065
PDF
Concerted mechanism of intramolecular 1,1-cycloaddition reaction of allyldiazomethane
Tsutomu Miyashi, Yosuke Fujii, Yoshinori Nishizawa, and Toshio Mukai
pp 725 - 727; DOI:
10.1021/ja00393a066
PDF
Enhancement of silicon-29 or tin-119 NMR signals in the compounds M(CH3)(n)Cl(4-n) M = Silicon or tin, n = 4, 3, 2) using proton polarization transfer. Dependence of the enhancement on the number of scalar coupled protons
David M. Doddrell, David T. Pegg, William Brooks, and M. Robin Bendall
pp 727 - 728; DOI:
10.1021/ja00393a067
PDF
Functionalized vesicular assembly. Enantioselective catalysis of ester hydrolysis
Yukito Murakami, Akio Nakano, Akira Yoshimatsu, and Kiyoshi Fukuya
pp 728 - 730; DOI:
10.1021/ja00393a068
PDF
Phase-transfer free-radical reactions: the crown ether/potassium peroxydisulfate initiator system
Jerald K. Rasmussen and Howell K. Smith
pp 730 - 731; DOI:
10.1021/ja00393a069
PDF
Book Reviews

pp 732 - 732; DOI:
10.1021/ja00393a600
PDF

Issue 4


Secondary ion mass spectrometry of small-molecule solids at cryogenic temperatures. 1. Nitrogen and carbon monoxide
Harry T. Jonkman and Josef Michl
pp 733 - 737; DOI:
10.1021/ja00394a001
PDF
The conformation of biphenyls in nematic liquid crystalline solution. The relationship between the torsional angles and the size of the halogens in 2,6-dihalogenated derivatives
Leslie D. Field and Sever Sternhell
pp 738 - 741; DOI:
10.1021/ja00394a002
PDF
Quantum effects in electron-transfer reactions
P. Siders and R. A. Marcus
pp 741 - 747; DOI:
10.1021/ja00394a003
PDF
Quantum effects for electron-transfer reactions in the "inverted region"
P. Siders and R. A. Marcus
pp 748 - 752; DOI:
10.1021/ja00394a004
PDF
Structure and bonding of bis(fulvalene) dinickel
Paul R. Sharp, Kenneth N. Raymond, James C. Smart, and Ronald J. McKinney
pp 753 - 757; DOI:
10.1021/ja00394a005
PDF
Syntheses, characterizations, and stereoelectronic stabilization of organometallic electron reservoirs: the 19-electron d7 redox catalysts .eta.5-C5R5Fe-.eta.6-C6R'6
Jean Rene Hamon, Didier Astruc, and Pascal Michaud
pp 758 - 766; DOI:
10.1021/ja00394a006
PDF
Coordination chemistry of metal surfaces. 2. Chemistry of acetonitrile and methyl isocyanide on nickel surfaces
C. M. Friend, Judith Stein, and E. L. Muetterties
pp 767 - 772; DOI:
10.1021/ja00394a007
PDF
Coordination chemistry of metal surfaces. 3. Benzene and toluene interactions with nickel surfaces
C. M. Friend and E. L. Muetterties
pp 773 - 779; DOI:
10.1021/ja00394a008
PDF
The tetradecaisopropoxydihydridotetratungsten story
M. Akiyama, M. H. Chisholm, F. A. Cotton, M. W. Extine, D. A. Haitko, J. Leonelli, and D. Little
pp 779 - 784; DOI:
10.1021/ja00394a009
PDF
Ion beam studies of the reactions of atomic cobalt ions with alkanes: determination of metal-hydrogen and metal-carbon bond energies and an examination of the mechanism by which transition metals cleave carbon-carbon bonds
P. B. Armentrout and J. L. Beauchamp
pp 784 - 791; DOI:
10.1021/ja00394a010
PDF
Intramolecular carbinolamine and imine formation with cobalt(III)-amine complexes. Synthesis, structure, and reactivity
A. R. Gainsford, R. D. Pizer, A. M. Sargeson, and P. O. Whimp
pp 792 - 805; DOI:
10.1021/ja00394a011
PDF
Sites of palladium(II) binding to mixtures of nucleoside monophosphates
Per Ivar Vestues and R. Bruce Martin
pp 806 - 809; DOI:
10.1021/ja00394a012
PDF
Ten-vertex closo- and hyper-closo-phosphinometallocarborane complexes derived from sodium dodecahydro-1,3-dicarba-arachno-nonaborate(1-)
C. W. Jung, R. T. Baker, and M. F. Hawthorne
pp 810 - 816; DOI:
10.1021/ja00394a013
PDF
Reactions of the dithiocarbene complex W(CO)5[C(SCH3)2] with phosphines. Crystal structure of a phosphorane product W(CO)5[(CH3S)2C:PPh2(CH3)]
Ruth A. Pickering, Robert A. Jacobson, and Robert J. Angelici
pp 817 - 821; DOI:
10.1021/ja00394a014
PDF
Absorption spectra and rearrangements of halotoluene parent cations in solid argon
Brian W. Keelan and Lester Andrews
pp 822 - 829; DOI:
10.1021/ja00394a015
PDF
Visible absorption spectra and two-photon photodissociation of halobenzene cations in solid argon
Brian W. Keelan and Lester Andrews
pp 829 - 832; DOI:
10.1021/ja00394a016
PDF
Electron-transfer, halogen-metal exchange, and direct processes in formal nucleophilic substitutions on alkyl halides by trimethyltinsodium
Gary F. Smith, Henry G. Kuivila, Reyna Simon, and Leslie Sultan
pp 833 - 839; DOI:
10.1021/ja00394a017
PDF
Electron-transfer reactions and conformational changes associated with the reduction of bianthrone
Bernard A. Olsen and Dennis H. Evans
pp 839 - 843; DOI:
10.1021/ja00394a018
PDF
Electron-transfer reactions accompanied by large structural changes. 1. Lucigenin-10,10'-dimethyl-9,9'-biacridylidene redox system
Elisabet Ahlberg, Ole Hammerich, and Vernon D. Parker
pp 844 - 849; DOI:
10.1021/ja00394a019
PDF
Electron-transfer chemistry of the merostabilized 3,5,5-trimethyl-2-morpholinon-3-yl radical
John M. Burns, Donald L. Wharry, and Tad H. Koch
pp 849 - 856; DOI:
10.1021/ja00394a020
PDF
Catalysis mechanism of phosphonium salts supported on silica gel in organic-aqueous two-phase systems
Pietro Tundo and Paolo Venturello
pp 856 - 861; DOI:
10.1021/ja00394a021
PDF
Synthesis of crobarbatine acetate. A macrocyclic pyrrolizidine alkaloid ester
Jamin Huang and Jerrold Meinwald
pp 861 - 867; DOI:
10.1021/ja00394a022
PDF
Preparation of tribenzo[21]aneN6: a metal template synthesis
G. J. Grant and D. J. Royer
pp 867 - 869; DOI:
10.1021/ja00394a023
PDF
Mechanism of hydrolysis of vinyl selenides and stability of .alpha.-selenocarbonium ions
Laszlo Hevesi, Jean Luc Piquard, and Henri Wautier
pp 870 - 875; DOI:
10.1021/ja00394a024
PDF
Chemical consequences of a polar axis in a solid-gas reaction. Reaction of p-bromobenzoic anhydride crystals with ammonia gas. The absolute direction of a polar unitropic reaction and the relationship of absolute configuration with crystal morphology
Eileen N. Duesler, Ruth B. Kress, Chung-Tan Lin, Wen-I Shiau, Iain C. Paul, and David Y. Curtin
pp 875 - 879; DOI:
10.1021/ja00394a025
PDF
Deuterium isotope effects in the solvolysis of benzal chlorides. 4. Salt effects and .alpha.-deuterium isotope effects
V. P. Vitullo and F. P. Wilgis
pp 880 - 883; DOI:
10.1021/ja00394a026
PDF
Thiamin-catalyzed decarboxylation of pyruvate. Synthesis and reactivity analysis of the central, elusive intermediate, .alpha.-lactylthiamin
Ronald Kluger, Jik Chin, and Timothy Smyth
pp 884 - 888; DOI:
10.1021/ja00394a027
PDF
Photochemistry of alkenes. 6. Direct irradiation of 1,5-hexadienes: [1,2] and [1,3] sigmatropic allyl shifts
T. D. R. Manning and Paul J. Kropp
pp 889 - 897; DOI:
10.1021/ja00394a028
PDF
Aromatization of arene 1,2-oxides. Comparison of the aromatization pathways of 1-carboxy-, 1-carbomethoxy-, 1-formyl-, 1-(hydroxymethyl)-, and 1-(2-hydroxy-2-propyl)benzene oxide
Herbert S. I. Chao and Glenn A. Berchtold
pp 898 - 902; DOI:
10.1021/ja00394a029
PDF
Special behavior of octamethylbiphenylene in acid. Acid-catalyzed electron transfer
Harold Hart, Avraham Teuerstein, and Mary Ann Babin
pp 903 - 906; DOI:
10.1021/ja00394a030
PDF
Crystal and molecular structure of the lithium salt of nicotinamide adenine dinucleotide dihydrate (NAD+, DPN+, cozymase, codehydrase I)
B. S. Reddy, W. Saenger, K. Muehlegger, and G. Weimann
pp 907 - 914; DOI:
10.1021/ja00394a031
PDF
Cyclonerodiol biosynthesis and the enzymic conversion of farnesyl to nerolidyl pyrophosphate
David E. Cane, Radha Iyengar, and Ming-Shi Shiao
pp 914 - 931; DOI:
10.1021/ja00394a032
PDF
Smooth and efficient deoxygenation of secondary alcohols. A general procedure for the conversion of ribonucleosides to 2'-deoxynucleosides
Morris J. Robins and John S. Wilson
pp 932 - 933; DOI:
10.1021/ja00394a033
PDF
Conformational analysis of the C(6)-O(1)-C(5)-C(4) fragment in acetylcholine by carbon-13 NMR spectroscopy
L. Cassidei and O. Sciacovelli
pp 933 - 934; DOI:
10.1021/ja00394a034
PDF
NMR of protons coupled to carbon-13 nuclei only
M. R. Bendall, D. T. Pegg, D. M. Doddrell, and J. Field
pp 934 - 936; DOI:
10.1021/ja00394a035
PDF
A new approach to the conformational analysis of seven-membered rings
Francoise Sauriol-Lord and T. Bruce Grindley
pp 936 - 938; DOI:
10.1021/ja00394a036
PDF
Oxidation of olefins by potassium permanganate. Mechanism of .alpha.-ketol formation
Saul Wolfe, Christopher F. Ingold, and Raymond U. Lemieux
pp 938 - 939; DOI:
10.1021/ja00394a037
PDF
Oxidation of olefins by potassium permanganate. Oxygen-labeling experiments and mechanism of the oxidation of 1,5-hexadiene. Evidence for a manganese intermediate with coordination number greater than four
Saul Wolfe and Christopher F. Ingold
pp 940 - 941; DOI:
10.1021/ja00394a038
PDF
Total synthesis of antitumor agent AT-125, (.alpha.S,5S)-.alpha.-amino-3-chloro-4,5-dihydro-5-isoxazoleacetic acid
Jack E. Baldwin, Lawrence I. Kruse, and Jin-Kun Cha
pp 942 - 943; DOI:
10.1021/ja00394a039
PDF
An unusual nucleophilic attack on a carbonyl oxygen. Reaction of a positively charged oxygen atom
Koichi Shudo, Yutaka Orihara, Toshiharu Ohta, and Toshihiko Okamoto
pp 943 - 944; DOI:
10.1021/ja00394a040
PDF
Direct determination of the temperature dependence of the reactions of a singlet carbene. Intersystem crossing and the cyclopropanation of olefins by fluorenylidene in acetonitrile solution
Joseph J. Zupancic and Gary B. Schuster
pp 944 - 946; DOI:
10.1021/ja00394a041
PDF
Strong dependence of the incidence of internal return during solvolysis of sec-alkyl benzenesulfonates on the structure of the alkyl group
Cristina Paradisi and J. F. Bunnett
pp 946 - 948; DOI:
10.1021/ja00394a042
PDF
Ring strain in bis(triethylphosphine)-3,3-dimethylplatinacyclobutane is small
Stephen S. Moore, Robert DiCosimo, Allan F. Sowinski, and George M. Whitesides
pp 948 - 949; DOI:
10.1021/ja00394a043
PDF
Conformational control of reactivity and regioselectivity in singlet oxygen ene reactions: relationship to the rotational barriers of acyclic alkylethylenes
K. N. Houk, John C. Williams, Pamela A. Mitchell, and K. Yamaguchi
pp 949 - 951; DOI:
10.1021/ja00394a044
PDF
Structural characterization of the neutral-ionic phase transition in tetrathiafulvalene-chloranil: evidence for C-H.cntdot..cntdot..cntdot.O hydrogen bonding
P. Batail, S. J. LaPlaca, J. J. Mayerle, and J. B. Torrance
pp 951 - 953; DOI:
10.1021/ja00394a045
PDF
Kinetics of lithium(+) and calcium(2+) complexation by 211 cryptand using a stopped-flow calorimeter
Gerard W. Liesegang
pp 953 - 955; DOI:
10.1021/ja00394a046
PDF
Mechanism of the benzidine rearrangement. Kinetic isotope effects and transition states. Evidence for concerted rearrangement
Henry J. Shine, Henryk Zmuda, Koon Ha Park, Harold Kwart, Ann Gaffney Horgan, Clair Collins, and Brian E. Maxwell
pp 955 - 956; DOI:
10.1021/ja00394a047
PDF
Stereoisomerism and correlated rotation in molecular gear systems. Residual diastereomers of bis(2,3-dimethyl-9-triptycyl)methane
Franco Cozzi, Alberto Guenzi, Constance A. Johnson, Kurt Mislow, W. Douglas Hounshell, and John F. Blount
pp 957 - 958; DOI:
10.1021/ja00394a048
PDF
Bis(4-chloro-1-triptycyl) ether. Separation of a pair of phase isomers of labeled bevel gears
Yuzo Kawada and Hiizu Iwamura
pp 958 - 960; DOI:
10.1021/ja00394a049
PDF
Synthesis and structure of trans-[[[cis-tetracarbonylbis(N-((2-diphenylphosphinamido)ethyl)salicylaldimino-P)]molybdenum(0)]-N,N1,O,O1]nickel(II), a novel bimetal trans-ligating tetradentate Schiff base complex with a "fly-over" chain containing a metal atom
Charles S. Kraihanzel, Ekk Sinn, and Gary M. Gray
pp 960 - 962; DOI:
10.1021/ja00394a050
PDF
Formation of chromium carbene ions by reaction of electronically excited chromium ions with methane in the gas phase
L. F. Halle, P. B. Armentrout, and J. L. Beauchamp
pp 962 - 963; DOI:
10.1021/ja00394a051
PDF
First evidence for manganese binding to sulfur donor group in metalloprotein, manganese(III)-containing acid phosphatase
Yukio Sugiura, Hideo Kawabe, Hisashi Tanaka, Sadaki Fujimoto, and Akira Ohara
pp 963 - 964; DOI:
10.1021/ja00394a052
PDF
Multiple metal-carbon bonds. 20. Tungsten methylidyne complexes
Paul R. Sharp, Steven J. Holmes, Richard R. Schrock, Melvyn Rowen Churchill, and Harvey J. Wasserman
pp 965 - 966; DOI:
10.1021/ja00394a053
PDF
Preparation of tris(.mu.2-hydro)-nonacarbonyl-.mu.3-ethylidyne-triiron from pentacarbonyliron
Kwai Sam Wong and Thomas P. Fehlner
pp 966 - 967; DOI:
10.1021/ja00394a054
PDF
.pi.- and .sigma.-Acetoxy radicals
P. S. Skell and D. D. May
pp 967 - 968; DOI:
10.1021/ja00394a055
PDF
Chiral aggregation phenomena. 2. Evidence for partial "two-dimensional resolution" in a chiral monolayer
Edward M. Arnett and Orlean Thompson
pp 968 - 970; DOI:
10.1021/ja00394a056
PDF
Octafluorocyclooctatetraene transition-metal chemistry: 1,2-.eta. and 1,2,3,6-.eta. complexes of iron and platinum
Aldos C. Barefoot, Edward W. Corcoran, Russell P. Hughes, David M. Lemal, W. Daniel Saunders, Brian B. Laird, and Raymond E. Davis
pp 970 - 972; DOI:
10.1021/ja00394a057
PDF
The mechanism of proton transfer from intramolecularily hydrogen-bonded acids. Differences between nitrogen-to-oxygen and nitrogen-to-nitrogen proton transfer
A. J. Kresge and M. F. Powell
pp 972 - 973; DOI:
10.1021/ja00394a058
PDF
Metal hydride reductions via single electron transfer. 2. Evidence for an electron transfer pathway in the reactions of simple and complex metal hydrides of the main group metals with polynuclear hydrocarbons
E. C. Ashby, A. B. Goel, R. N. DePriest, and H. S. Prasad
pp 973 - 975; DOI:
10.1021/ja00394a059
PDF
Photogeneration of very active homogeneous catalysts using laser light excitation of iron carbonyl precursors
James C. Mitchener and Mark S. Wrighton
pp 975 - 977; DOI:
10.1021/ja00394a060
PDF
Fourier-transform infrared measurement of the catalyst lifetime in the pentacarbonyliron(0) photocatalyzed olefin isomerization
D. B. Chase and F. J. Weigert
pp 977 - 978; DOI:
10.1021/ja00394a061
PDF
Bridging the gap between the gas phase and solution: transition in the kinetics of nucleophilic displacement reactions
Diethard K. Bohme and Gervase I. Mackay
pp 978 - 979; DOI:
10.1021/ja00394a062
PDF
Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+
M. Brookhart, James R. Tucker, and G. Ronald Husk
pp 979 - 981; DOI:
10.1021/ja00394a063
PDF
Benzoquinone diimine bridged ruthenium ammines, a novel type of mixed-valence complexes
Stefan Joss, Heinz Reust, and Andreas Ludi
pp 981 - 982; DOI:
10.1021/ja00394a064
PDF
Formation and molecular structure of bis(.eta.5-cyclopentadienyl)bis(trifluorophosphine)titanium
David J. Sikora, Marvin D. Rausch, Robin D. Rogers, and Jerry L. Atwood
pp 982 - 984; DOI:
10.1021/ja00394a065
PDF
Copper site of molluscan oxyhemocyanins. Structural evidence from x-ray absorption spectroscopy
Man Sung Co, Keith O. Hodgson, Thomas K. Eccles, and Rene Lontie
pp 984 - 986; DOI:
10.1021/ja00394a066
PDF
Metalloprotein EXAFS. A group fitting procedure for imidazole ligands
Man Sung Co, Robert A. Scott, and Keith O. Hodgson
pp 986 - 988; DOI:
10.1021/ja00394a067
PDF
New, systematic, good yield syntheses of boron hydrides: preparation of tetraborane(10) and pentaborane(11). A practical conversion of pentaborane(9) to decaborane(14)
John B. Leach, Mark A. Toft, Francis L. Himpsl, and Sheldon G. Shore
pp 988 - 989; DOI:
10.1021/ja00394a068
PDF
Preparation and reactivity of the (cyclohexadiene)manganese tricarbonyl anion. Potentially useful methods of arene and carbon-hydrogen bond activation
W. Lamanna and M. Brookhart
pp 989 - 991; DOI:
10.1021/ja00394a069
PDF
Analogs for acetoacetate as an enzyme substrate. Stereochemical preferences
Steven A. Benner and Thomas Hellman Morton
pp 991 - 993; DOI:
10.1021/ja00394a070
PDF
Stereospecificity and stereochemical infidelity of acetoacetate decarboxylase (AAD)
Steven A. Benner, J. David Rozzell, and Thomas Hellman Morton
pp 993 - 994; DOI:
10.1021/ja00394a071
PDF
Increase of carbon-13 NMR relaxation times in proteins due to picosecond motional averaging
Ronald M. Levy, Martin Karplus, and J. Andrew McCammon
pp 994 - 996; DOI:
10.1021/ja00394a072
PDF
Solvent isotope effect on the quartet .fwdarw. doublet intersystem crossing efficiencies of tris(2,2'-bipyridine)chromium(3+) and tris(1,10-phenanthroline)chromium(3+)
R. Sriram, Morton Z. Hoffman, and Nick Serpone
pp 997 - 998; DOI:
10.1021/ja00394a073
PDF
Reluctant azoalkanes: short-wavelength (185 nm) liquid-phase photolysis and high-temperature (400-1000.degree.C) gas-phase pyrolysis of 3,3,5,5-tetramethylpyrazolin-4-one
Waldemar Adam, Andreas Fuss, Francois P. Mazenod, and Helmut Quast
pp 998 - 1000; DOI:
10.1021/ja00394a074
PDF

Issue 5


Vibrational spectra of twist-boat cyclohexane
Janet L. Offenbach, Leif Fredin, and Herbert L. Strauss
pp 1001 - 1006; DOI:
10.1021/ja00395a001
PDF
Ejection dynamics and electronic processes governing secondary particle emission in SIMS
P. Terrence Murray and J. Wayne Rabalais
pp 1007 - 1013; DOI:
10.1021/ja00395a002
PDF
Reversed micelles of Aerosol-OT in benzene. 2. Equilibrium studies using vapor pressure osmometry and spectrophotometry with picric acid as indicator
Kiyoshi Tamura and Z. A. Schelly
pp 1013 - 1018; DOI:
10.1021/ja00395a003
PDF
Reversed micelle of Aerosol-OT in benzene. 3. Dynamics of the solubilization of picric acid
Kiyoshi Tamura and Z. A. Schelly
pp 1018 - 1022; DOI:
10.1021/ja00395a004
PDF
The optical activity of the three-membered ring: oxiranes, aziridines, diaziridines, and oxaziridines
Arvi Rauk
pp 1023 - 1030; DOI:
10.1021/ja00395a005
PDF
High-resolution optical studies on C-phycocyanin via photochemical hole burning
J. Friedrich, H. Scheer, B. Zickendraht-Wendelstadt, and D. Haarer
pp 1030 - 1035; DOI:
10.1021/ja00395a006
PDF
Time-resolved resonance Raman spectroscopy: the triplet state of all-trans-retinal
R. Wilbrandt and N. H. Jensen
pp 1036 - 1041; DOI:
10.1021/ja00395a007
PDF
Free radical induced nuclear magnetic resonance shifts: comments on contact shift mechanisms
Dan Draney and Charles A. Kingsbury
pp 1041 - 1047; DOI:
10.1021/ja00395a008
PDF
Nanosecond flash studies of reduction of benzophenone by aliphatic amines. Quantum yields and kinetic isotope effects
Shai Inbar, Henry Linschitz, and Saul G. Cohen
pp 1048 - 1054; DOI:
10.1021/ja00395a009
PDF
Solvent dependence of the kinetics of formation and dissociation of cryptate complexes
B. G. Cox, J. Garcia-Rosas, and H. Schneider
pp 1054 - 1059; DOI:
10.1021/ja00395a010
PDF
Storage of electrons in aqueous solution: the rates of chemical charging and discharging the colloidal silver microelectrode
A. Henglein and J. Lilie
pp 1059 - 1066; DOI:
10.1021/ja00395a011
PDF
The conformations and energetics of simple ylides
Robert A. Eades, Paul G. Gassman, and David A. Dixon
pp 1066 - 1068; DOI:
10.1021/ja00395a012
PDF
9-Naphthylmethylenecyclooctatrienyl anions. Conformational analysis and bond rotation
Stuart W. Staley, Charles K. Dustman, and Gerard E. Linkowski
pp 1069 - 1073; DOI:
10.1021/ja00395a013
PDF
Triboluminescence-structure relationships in polymorphs of hexaphenylcarbodiphosphorane and anthranilic acid, molecular crystals, and salts
Gordon E. Hardy, William C. Kaska, B. P. Chandra, and Jeffrey I. Zink
pp 1074 - 1079; DOI:
10.1021/ja00395a014
PDF
Solvatochromic comparison method. 20. Linear solvation energy relationships. 12. The d.delta. term in the solvatochromic equations
R. W. Taft, Jose-Luis M. Abboud, and Mortimer J. Kamlet
pp 1080 - 1086; DOI:
10.1021/ja00395a015
PDF
Metal-nitroxyl interactions. 20. Electron paramagnetic resonance spectra of spin-labeled vanadyl and silver porphyrins
Kundalika M. More, Sandra S. Eaton, and Gareth R. Eaton
pp 1087 - 1090; DOI:
10.1021/ja00395a016
PDF
Chromium(II)-polypyridyl complexes: formation, spectra, and electron-transfer kinetics
Nick Serpone, Mary A. Jamieson, Salvatore S. Emmi, Pier G. Fuochi, Quinto G. Mulazzani, and Morton Z. Hoffman
pp 1091 - 1098; DOI:
10.1021/ja00395a017
PDF
Preparation of aluminoborane analogs of the lower boron hydrides
Francis L. Himpsl and Arthur C. Bond
pp 1098 - 1102; DOI:
10.1021/ja00395a018
PDF
Metal atom syntheses of metallaboron clusters. 2. Synthesis of cobaltathiaborane and cobaltadithiaborane complexes. Crystal and molecular structures of 2,3,6-(.eta.-C5H5)2Co2SB5H7 and 7,6,8-(.eta.-C5H5)CoS2B6H8
George J. Zimmerman and Larry G. Sneddon
pp 1102 - 1111; DOI:
10.1021/ja00395a019
PDF
Unusual platinum complexes of deprotonated 1-methylcytosine: bis(.mu.-1-methylcytosinato-N3,N4)-bis(cis-diammineplatinum(II)) dinitrate dihydrate, [(NH3)2Pt(C5H6N3O)2Pt(NH3)2](NO3)2.2H2O, and [diaquahydrogen(1+)][bis(.mu.-1-methylcytosinato-N3,N4)-bis(cis-nitrodiammineplatinum)(Pt-Pt) dinitrate, (H5O2)[(NH3)2(NO2)Pt(C5H6N3O)2Pt(NH3)2(NO2)](NO3)2
R. Faggiani, B. Lippert, C. J. L. Lock, and R. A. Speranzini
pp 1111 - 1120; DOI:
10.1021/ja00395a020
PDF
Nitrogen-15 NMR spectrum of a 1,1-diazene. N-(2,2,6,6-tetramethylpiperidyl)nitrene
Peter B. Dervan, Michael E. Squillacote, Paul M. Lahti, Alan P. Sylwester, and John D. Roberts
pp 1120 - 1122; DOI:
10.1021/ja00395a021
PDF
Carbon-13 NMR spectroscopic study of the application of the "tool of increasing electron demand" to the 7-aryl-1-norbornenyl, 7-aryl-7-norbornyl, 2-aryl-2-bicyclo[2.1.1]hexyl, 1-aryl-1-cyclobutyl, and 3-aryl-3-nortricyclyl cations
George A. Olah, Arthur L. Berrier, Massoud Arvanaghi, and G. K. Surya Prakash
pp 1122 - 1128; DOI:
10.1021/ja00395a022
PDF
Oxygen-17 NMR studies of substituent and hydrogen-bonding effects in substituted acetophenones and benzaldehydes
Thomas E. St. Amour, Matija I. Burgar, Bill Valentine, and Daniel Fiat
pp 1128 - 1136; DOI:
10.1021/ja00395a023
PDF
Substitution reactions of alkanesulfonyl derivatives: direct substitution vs. elimination-addition mechanisms in substitution reactions of alkyl .alpha.-disulfones
Lieh-Pao O. Farng and John L. Kice
pp 1137 - 1145; DOI:
10.1021/ja00395a024
PDF
Reactions of (9-anthryl)arylmethyl chloride and its homologs with nucleophiles under solvolytic conditions. Notable effects of reaction conditions and substituents on the reaction sites
Fujimaro Ogata, Masato Takagi, Masatomo Nojima, and Shigekazu Kusabayashi
pp 1145 - 1153; DOI:
10.1021/ja00395a025
PDF
Permanganate ion oxidations. 13. Soluble manganese(IV) species in the oxidation of 2,4(1H,3H)-pyrimidinediones (uracils)
Fillmore Freeman, Charles O. Fuselier, Charles R. Armstead, Charlotte E. Dalton, Pamela A. Davidson, Elaine M. Karchesfski, Deborah E. Krochman, Michael N. Johnson, and Nikola K. Jones
pp 1154 - 1159; DOI:
10.1021/ja00395a026
PDF
Intramolecular catalysis of organic oxidation and reduction reactions: rapid and microscopically reversible thioether-sulfoxide interconversions in dilute acid
Joyce Takahashi Doi and W. Kenneth Musker
pp 1159 - 1163; DOI:
10.1021/ja00395a027
PDF
Synthesis and complexation properties of macrocyclic polyethers derived from chiral and meso-1,1'-bicyclohexyl-2,2'-diols
Thomas W. Bell
pp 1163 - 1171; DOI:
10.1021/ja00395a028
PDF
Electroorganic chemistry. 46. A new carbon-carbon bond forming reaction at the .alpha.-position of amines utilizing anodic oxidation as a key step
Tatsuya Shono, Yoshihiro Matsumura, and Kenji Tsubata
pp 1172 - 1176; DOI:
10.1021/ja00395a029
PDF
Monomeric metaphosphate anion: reaction with carbonyl groups
Arnold C. Satterthwait and F. H. Westheimer
pp 1177 - 1180; DOI:
10.1021/ja00395a030
PDF
Tetraneopentyltitanium as a polymerization catalyst
James C. W. Chien, Jiun-Chen Wu, and Marvin D. Rausch
pp 1180 - 1185; DOI:
10.1021/ja00395a031
PDF
Exo stereoselectivity in electrophilic attack on bicyclo[4.3.1]decatetraenyl anion and in deprotonation of tricyclo[4.3.1.0]deca-2,4,7-triene
Kazuko Takahashi, Kahei Takase, and Takashi Kagawa
pp 1186 - 1192; DOI:
10.1021/ja00395a032
PDF
Long-range triplet-triplet energy transfer within metal-substituted hemoglobins
Haya Zemel and Brian M. Hoffman
pp 1192 - 1201; DOI:
10.1021/ja00395a033
PDF
General-acid catalysis of imidazolidine ring opening. The hydrolysis of ethyl N,N'-[1-(p-(dimethylamino)phenyl)propenediyl]-p-[((2-tetrahydroquinolinyl)methylene)amino]denzoate
Thomas H. Fife and August M. Pellino
pp 1201 - 1207; DOI:
10.1021/ja00395a034
PDF
Limits on the expression of enzyme-mediated solvent isotope effects
Dexter B. Northrop
pp 1208 - 1212; DOI:
10.1021/ja00395a035
PDF
First ionization band of 1,1-dimethylsilaethylene by transient photoelectron spectroscopy
T. Koenig and William McKenna
pp 1212 - 1213; DOI:
10.1021/ja00395a036
PDF
A possible nucleophilic ipso-aromatic substitution with a benzyl anion as the leaving group
Clair J. Collins, Hans Peter Hombach, Brian E. Maxwell, Ben M. Benjamin, and Donna McKamey
pp 1213 - 1214; DOI:
10.1021/ja00395a037
PDF
Interaction of pyruvate-thiamin diphosphate adducts with pyruvate decarboxylase. Catalysis through "closed" transition states
Ronald Kluger and Timothy Smyth
pp 1214 - 1216; DOI:
10.1021/ja00395a038
PDF
Isolation of a (carbon, nitrogen)-bonded formamido complex and its isomerization to a (carbon, oxygen)-bonded form on the edge of a triosmium cluster. Crystal and molecular structure of a urethane derivative of the (carbon, nitrogen)bonded formamido complex
Y. C. Lin, C. B. Knobler, and H. D. Kaesz
pp 1216 - 1218; DOI:
10.1021/ja00395a039
PDF
A new molybdenum(IV) thioanion containing the Mo:St unit. Synthesis and structural characterization of bis(tetraethylammonium) nonathiomolybdate
E. D. Simhon, N. C. Baenziger, M. Kanatzidis, M. Draganjac, and D. Coucouvanis
pp 1218 - 1219; DOI:
10.1021/ja00395a040
PDF
Chemistry of singlet oxygen. 34. Unexpected solvent deuterium isotope effects on the lifetime of singlet molecular oxygen (1.DELTA.g)
Peter R. Ogilby and Christopher S. Foote
pp 1219 - 1221; DOI:
10.1021/ja00395a041
PDF
Chiral discrimination in the energetics of ion aggregation
Edward M. Arnett and S. Patricia Zingg
pp 1221 - 1222; DOI:
10.1021/ja00395a042
PDF
Synthesis of 16-membered-ring macrolide antibiotics. 3. Carbomycin B and leucomycin A3: retrosynthetic studies
K. C. Nicolaou, S. P. Seitz, and M. R. Pavia
pp 1222 - 1224; DOI:
10.1021/ja00395a043
PDF
Synthesis of 16-membered-ring macrolide antibiotics. 4. Carbomycin B and leucomycin A3: total synthesis of cyclic key intermediate
K. C. Nicolaou, M. R. Pavia, and S. P. Seitz
pp 1224 - 1226; DOI:
10.1021/ja00395a044
PDF
Photoatropisomerization of "picket-fence" porphyrins and their metal complexes
Ruth A. Freitag, Janet A. Mercer-Smith, and David G. Whitten
pp 1226 - 1228; DOI:
10.1021/ja00395a045
PDF
Isolation and structures of trichilins, antifeedants against the Southern army worm
Munehiro Nakatani, John C. James, and Koji Nakanishi
pp 1228 - 1230; DOI:
10.1021/ja00395a046
PDF
New reaction chemistry of cis-diammineplatinum with .alpha.-pyridone crystalline relatives of cis-diammineplatinum .alpha.-pyridone blue
L. Steven Hollis and Stephen J. Lippard
pp 1230 - 1232; DOI:
10.1021/ja00395a047
PDF
Structure of the reaction barrier in the selenoxide-mediated formation of olefins
L. D. Kwart, A. G. Horgan, and H. Kwart
pp 1232 - 1234; DOI:
10.1021/ja00395a048
PDF
A stable monocyclic triarylalkoxy P-H phosphorane, a 10-P-5 species with an apical phosphorus-hydrogen bond, and its conjugate base, a phosphoranide
Michael R. Ross and J. C. Martin
pp 1234 - 1235; DOI:
10.1021/ja00395a049
PDF
Reversible dioxygen binding by a totally synthetic nonporphyrin macrobicyclic iron(II) complex containing a persistent void
Norman Herron and Daryle H. Busch
pp 1236 - 1237; DOI:
10.1021/ja00395a050
PDF
Isotope enrichment by photolysis on ordered surfaces
Gary A. Epling and Emily Florio
pp 1237 - 1238; DOI:
10.1021/ja00395a051
PDF
Quadrupolar carbon-13-nitrogen-14 couplings and nitrogen-14 relaxations in aggregated and nonaggregated choline phospholipids
Ramaswamy Murari and Wolfgang J. Baumann
pp 1238 - 1240; DOI:
10.1021/ja00395a052
PDF
NMR investigation of a surface compound on colloidal silica
A. R. Siedle and R. A. Newmark
pp 1240 - 1241; DOI:
10.1021/ja00395a053
PDF
Structures of BBM-928 A, B, and C. Novel antitumor antibiotics from Actinomadura luzonensis
Masataka Konishi, Hiroaki Ohkuma, Fumihide Sakai, Takashi Tsuno, Hideo Koshiyama, Takayuki Naito, and Hiroshi Kawaguchi
pp 1241 - 1243; DOI:
10.1021/ja00395a054
PDF
Crystal and molecular structure of BBM-928 A, a novel antitumor antibiotic from Actinomadura luzonensis
Edward Arnold and Jon Clardy
pp 1243 - 1244; DOI:
10.1021/ja00395a055
PDF
Cyclopropylidene radical anion and 1,4-elimination-type remote ionization effect in the reduction of bi(gem-dihalocyclopropane) systems
Akira Oku, Hideo Tsuji, Mitsuhiro Yoshida, and Naoto Yoshiura
pp 1244 - 1246; DOI:
10.1021/ja00395a056
PDF
Photoinduced electron-transfer reactions. Radical cations of norbornadiene and quadricyclene
Heinz D. Roth, Marcia L. Manion Schilling, and Guilford Jones
pp 1246 - 1248; DOI:
10.1021/ja00395a057
PDF
Useful impurities for optical resolutions. 1. Crystallization of photopolymerizing dienes in the presence of their chiral topochemical products
Jan Van Mil, Edna Gati, Lia Addadi, and Meir Lahav
pp 1248 - 1249; DOI:
10.1021/ja00395a058
PDF
Useful impurities for optical resolutions. 2. Generality and mechanism of the rule of reversal
Lia Addadi, Jan Van Mil, and Meir Lahav
pp 1249 - 1251; DOI:
10.1021/ja00395a059
PDF
Useful impurities for optical resolutions. 3. An improved Pasteur-type resolution of conglomerates and a new empirical method for assignment of absolute configuration
Lia Addadi, Edna Gati, and Meir Lahav
pp 1251 - 1252; DOI:
10.1021/ja00395a060
PDF
Synthesis and structure proof of a vitamin D3 metabolite, 25(s),26-dihydroxycholecalciferol
John J. Partridge, Shian Jan Shiuey, Naresh K. Chadha, Enrico G. Baggiolini, John F. Blount, and Milan R. Uskokovic
pp 1253 - 1255; DOI:
10.1021/ja00395a061
PDF
Carbon-13 NMR spectra of the uranyl tricarbonate-bicarbonate system
E. Thomas Strom, Donald E. Woessner, and William B. Smith
pp 1255 - 1256; DOI:
10.1021/ja00395a062
PDF
Concerted ring-opening reaction of cyclobutenes. The extraordinary accelerating effects of arylsulfoxy and sulfonyl carbanion substituents
Tetsuji Kametani, Masayoshi Tsubuki, Hideo Nemoto, and Koji Suzuki
pp 1256 - 1258; DOI:
10.1021/ja00395a063
PDF
Photochemistry of metal-metal bonded complexes: one-electron oxidation of photogenerated seventeen-valence-electron radicals
Aloysius F. Hepp and Mark S. Wrighton
pp 1258 - 1261; DOI:
10.1021/ja00395a064
PDF
Fermi level pinning of p-type semiconducting indium phosphide contacting liquid electrolyte solutions: rationale for efficient photoelectrochemical energy conversion
Raymond N. Dominey, Nathan S. Lewis, and Mark S. Wrighton
pp 1261 - 1263; DOI:
10.1021/ja00395a065
PDF
Dianions of 2-methyl-2-butene: evidence for the stability of a Y-aromatic species
Nancy S. Mills, James Shapiro, and Mark Hollingsworth
pp 1263 - 1264; DOI:
10.1021/ja00395a066
PDF
A new geometrical form for tin. Synthesis and structure of the tetramethylammonium chloride adduct of the spirobis(dithiastannole) [(CH3)4N]+[(C7H6S2)2SnCl]-
Arjun C. Sau, Roberta O. Day, and Robert R. Holmes
pp 1264 - 1265; DOI:
10.1021/ja00395a067
PDF
New syntheses and molecular structures of the decamethylmetallocene dicarbonyls (.eta.5-C5Me5)2M(CO)2 (M = titanium, zirconium, hafnium)
David J. Sikora, Marvin D. Rausch, Robin D. Rogers, and Jerry L. Atwood
pp 1265 - 1267; DOI:
10.1021/ja00395a068
PDF
Transformation of coordinatively unsaturated .eta.1-vinylmolybdenum complexes into three-electron .eta.2-bonded cyclic alkylidene species
Michael Green, Nicholas C. Norman, and A. Guy Orpen
pp 1267 - 1269; DOI:
10.1021/ja00395a069
PDF
Linking of four acetylene molecules at a dimolybdenum center and the protonation of the resulting metallacyclononatetraene to form a cation containing a bridging MoHC system
Michael Green, Nicholas C. Norman, and A. Guy Orpen
pp 1269 - 1271; DOI:
10.1021/ja00395a070
PDF
A new and efficient total synthesis of streptonigrin
Andrew S. Kende, Dennis P. Lorah, and Rodney J. Boatman
pp 1271 - 1273; DOI:
10.1021/ja00395a071
PDF
Binuclear copper complexes: an open and shut case. A strong antiferromagnetically coupled .mu.-monohydroxo bridged complex
Patrick L. Burk, John A. Osborn, Marie Therese Youinou, Yvette Agnus, Remy Louis, and Raymond Weiss
pp 1273 - 1274; DOI:
10.1021/ja00395a072
PDF
Photoreduction of 5-bromouracil. Ionic and free-radical pathways
Barry J. Swanson, J. Christopher Kutzer, and Tad H. Koch
pp 1274 - 1276; DOI:
10.1021/ja00395a073
PDF
1,1-Dimetalloalkenes containing aluminum as well as titanium or zirconium. Their structures and use as novel alkenylidene and alkenyl transfer agents
Tadao Yoshida and Eiichi Negishi
pp 1276 - 1277; DOI:
10.1021/ja00395a074
PDF
Stepwise reduction of carbon monoxide to methane on a triosmium cluster face. Preparation and characterization of undecacarbonyl(methylene)triosmium
Guy R. Steinmetz and Gregory L. Geoffroy
pp 1278 - 1279; DOI:
10.1021/ja00395a075
PDF
Improvement of energy conversion efficiency by specific chemical treatments of molybdenum selenide (n-MoSe2) and tungsten selenide (n-WSe2) photoanodes
D. Canfield and B. A. Parkinson
pp 1279 - 1281; DOI:
10.1021/ja00395a076
PDF
Anion receptor molecules. Synthesis and anion-binding properties of polyammonium macrocycles
B. Dietrich, M. W. Hosseini, J. M. Lehn, and R. B. Sessions
pp 1282 - 1283; DOI:
10.1021/ja00395a077
PDF
A highly stereoselective synthesis of transepoxides via arsonium ylides
W. Clark Still and Vance J. Novack
pp 1283 - 1285; DOI:
10.1021/ja00395a078
PDF
Nonconcertedness of allylic cation promoted .pi.-cyclization reactions
Mladen Ladika, Ivo Bregovec, and Dionis E. Sunko
pp 1285 - 1286; DOI:
10.1021/ja00395a079
PDF
Gas-phase oxidation catalysis by transition-metal cations
Manfred M. Kappes and Ralph H. Staley
pp 1286 - 1287; DOI:
10.1021/ja00395a080
PDF
Mechanism of the Fischer-Tropsch reaction. The chain propagation step
Robert C. Brady and R. Pettit
pp 1287 - 1289; DOI:
10.1021/ja00395a081
PDF
A novel synthesis of .beta.-lactams
Howard Alper, Chulangani P. Perera, and Farid R. Ahmed
pp 1289 - 1291; DOI:
10.1021/ja00395a082
PDF
Cyclen phosphonium and homologous cations. Dimerization in strained PN4+ systems
Jack E. Richman, O. D. Gupta, and Robert B. Flay
pp 1291 - 1292; DOI:
10.1021/ja00395a083
PDF
Chemiluminescence of dioxetanone investigated by self-consistent-field theory
Steven P. Schmidt, Mark A. Vincent, Clifford E. Dykstra, and Gary B. Schuster
pp 1292 - 1293; DOI:
10.1021/ja00395a084
PDF
C-20 Stereospecific introduction of a steroid side chain
Andrew D. Batcho, Donald E. Berger, Milan R. Uskokovic, and Barry B. Snider
pp 1293 - 1295; DOI:
10.1021/ja00395a085
PDF
Laser-desorption mass spectrometry/mass spectrometry and the mechanism of desorption ionization
D. Zakett, A. E. Schoen, R. G. Cooks, and P. H. Hemberger
pp 1295 - 1297; DOI:
10.1021/ja00395a086
PDF
Formate ion as a monodentate ligand. Synthesis, structure, and decarboxylation of (.eta.5-cyclopentadienyl)dicarbonyl(formato)iron
Donald J. Darensbourg, Mark B. Fischer, Raymond E. Schmidt, and Brenda J. Baldwin
pp 1297 - 1298; DOI:
10.1021/ja00395a087
PDF
Luminescence and redox photochemistry of the molybdenum(II) cluster Mo6Cl142-
Andrew W. Maverick and Harry B. Gray
pp 1298 - 1300; DOI:
10.1021/ja00395a088
PDF
Eigenfunctions of open-shell molecules: experimental spin densities in hexafluorochromate(3-) and tetrachlorocobaltate(2-)
Ronald Mason, Andrew R. P. Smith, Joseph N. Varghese, Graham S. Chandler, Brian N. Figgis, Robin A. Phillips, and Geoffrey A. Williams
pp 1300 - 1301; DOI:
10.1021/ja00395a089
PDF
Secondary deuterium/hydrogen isotope effects on carbon-13 chemical shifts in cycloalkanes. Downfield shifts over three and four bonds
Rafet Aydin and Harald Guenther
pp 1301 - 1303; DOI:
10.1021/ja00395a090
PDF
Relatively high-yield syntheses of rotaxanes. Syntheses and properties of compounds consisting of cyclodextrins threaded by .alpha.,.omega.-diaminoalkanes coordinated to cobalt(III) complexes
Hiroshi Ogino
pp 1303 - 1304; DOI:
10.1021/ja00395a091
PDF
Facile cleavage of the molybdenum.tplbond.molybdenum bond in reactions between Mo2(OBut)6 and aryl azides and molecular oxygen
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, Charles C. Kirkpatrick, and Andrew L. Ratermann
pp 1305 - 1306; DOI:
10.1021/ja00395a092
PDF
Book Reviews

pp 1306 - 1312; DOI:
10.1021/ja00395a600
PDF

Issue 6


Proton affinities from dissociations of proton-bound dimers
S. A. McLuckey, D. Cameron, and R. G. Cooks
pp 1313 - 1317; DOI:
10.1021/ja00396a001
PDF
An electrochemical investigation of photosubstitution processes at glassy-carbon electrodes coated with polymer-bound ruthenium complexes
Otto Haas, Monika Kriens, and Johannes G. Vos
pp 1318 - 1319; DOI:
10.1021/ja00396a002
PDF
Photoelectron spectra of polynuclear aromatics. 6. Applications to structural elucidation: "circumanthracene"
E. Clar, J. M. Robertson, R. Schloegl, and W. Schmidt
pp 1320 - 1328; DOI:
10.1021/ja00396a003
PDF
A molecular orbital study of hydrogen, methyl, and phenyl bridging in beryllium compounds
Dennis S. Marynick
pp 1328 - 1333; DOI:
10.1021/ja00396a004
PDF
Chair-boat equilibriums in bicyclo[3.3.1]nonane at 65 and 400.degree.C studied by electron diffraction and molecular mechanics
V. S. Mastryukov, M. V. Popik, O. V. Dorofeeva, A. V. Golubinskii, L. V. Vilkov, N. A. Belikova, and N. L. Allinger
pp 1333 - 1337; DOI:
10.1021/ja00396a005
PDF
The addition of carbanions to the carbonyl group in the gas phase
J. E. Bartmess, R. L. Hays, and G. Caldwell
pp 1338 - 1344; DOI:
10.1021/ja00396a006
PDF
The relationship between substituent-induced energy and charge effects in proton-transfer equilibriums
Warren J. Hehre, Mare Taagepera, Robert W. Taft, and Ronald D. Topsom
pp 1344 - 1349; DOI:
10.1021/ja00396a007
PDF
The electronic structure of .beta.-thioxoketones. A photoelectron spectroscopic study of the enol-enethiol tautomerism of thioacetylacetone and related compounds
Flemming S. Joergensen, Lars Carlsen, and Fritz Duus
pp 1350 - 1353; DOI:
10.1021/ja00396a008
PDF
In-plane vibrational modes in the uracil molecule from an ab initio MO calculation
Yoshifumi Nishimura, Masamichi Tsuboi, Shigeki Kato, and Keiji Morokuma
pp 1354 - 1358; DOI:
10.1021/ja00396a009
PDF
VCNDO/S method for second-row atoms
J. A. Singerman and H. H. Jaffe
pp 1358 - 1360; DOI:
10.1021/ja00396a010
PDF
Quantum chemical and statistical thermodynamic investigations of anesthetic activity. 1. The interaction between chloroform, fluoroform, cyclopropane and an O-H.cntdot..cntdot..cntdot.O hydrogen bond
Pavel Hobza, Fred Mulder, and Camille Sandorfy
pp 1360 - 1366; DOI:
10.1021/ja00396a011
PDF
A sudden-polarization model to predict regioselectivities and periselectivities of the 1,7-sigmatropic shifts and electrocyclizations of singlet excited states of cycloheptatrienes
T. Tezuka, O. Kikuchi, K. N. Houk, M. N. Paddon-Row, Cielo M. Santiago, Nelson G. Rondan, John C. Williams, and Ruth Wells Gandour
pp 1367 - 1371; DOI:
10.1021/ja00396a012
PDF
Homoaromaticity and bicycloaromaticity in carbanions
John B. Grutzner and William L. Jorgensen
pp 1372 - 1375; DOI:
10.1021/ja00396a013
PDF
Elusiveness of bishomoaromaticity in anionic systems: the bicyclo[3.2.1]octa-3,6-dien-2-yl anion
Elmar Kaufmann, Herbert Mayr, Jayaraman Chandrasekhar, and Paul von Rague Schleyer
pp 1375 - 1380; DOI:
10.1021/ja00396a014
PDF
Sodium(1+) complexes with acyclic polyethers. Stabilities, enthalpies, and entropies of reaction in acetonitrile and pyridine. A sodium-23 NMR study
Jean Grandjean, Pierre Laszlo, Werner Offermann, and Peter L. Rinaldi
pp 1380 - 1383; DOI:
10.1021/ja00396a015
PDF
Solvent dependence of the stability of cryptate complexes
B. G. Cox, J. Garcia-Rosas, and H. Schneider
pp 1384 - 1389; DOI:
10.1021/ja00396a016
PDF
The binding of ethylene to platinum and palladium. An ab initio study of the MCl3(C2H4)- species
P. Jeffrey Hay
pp 1390 - 1393; DOI:
10.1021/ja00396a017
PDF
Heterobimetallic complexes. The preparation, solid-state structure, and fluxional behavior of (C5Me5)Rh(.mu.-PMe2)2Mo(CO)4
Richard G. Finke, Glen Gaughan, Cortlandt Pierpont, and Marion E. Cass
pp 1394 - 1399; DOI:
10.1021/ja00396a018
PDF
Intramolecular boron-boron linkage between polyhedral cages in a commo-metallacarborane. Synthesis and structure of a fluxional metal-boron cluster, [.eta.5-C5(CH3)5]2Co3(CH3)4C4B8H7
David C. Finster, Ekk Sinn, and Russell N. Grimes
pp 1399 - 1407; DOI:
10.1021/ja00396a019
PDF
Synthesis, structure, and reactions of [Mo(SnCl3)(CN-tert-Bu)6][(Ph3B)2CN], containing a potentially useful new anion for crystallizations
Christen M. Giandomenico, John C. Dewan, and Stephen J. Lippard
pp 1407 - 1412; DOI:
10.1021/ja00396a020
PDF
The MNDOC method, a correlated version of the MNDO model
Walter Thiel
pp 1413 - 1420; DOI:
10.1021/ja00396a021
PDF
MNDOC study of reactive intermediates and transition states
Walter Thiel
pp 1420 - 1425; DOI:
10.1021/ja00396a022
PDF
MNDOC study of excited states
Armin Schweig and Walter Thiel
pp 1425 - 1431; DOI:
10.1021/ja00396a023
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Structure-reactivity relations and reorganizational barriers for outer-sphere electron-transfer reactions of low-spin cobalt(III)-cobalt(II) couples
John F. Endicott, Bill Durham, Milton D. Glick, Thomas J. Anderson, James M. Kuszaj, William G. Schmonsees, and K. P. Balakrishnan
pp 1431 - 1440; DOI:
10.1021/ja00396a024
PDF
Multiple metal-carbon bonds. 19. How niobium and tantalum complexes of the type M(CHCMe3)(PR3)2Cl3 can be modified to give olefin metathesis catalysts
S. M. Rocklage, J. D. Fellmann, G. A. Rupprecht, L. W. Messerle, and R. R. Schrock
pp 1440 - 1447; DOI:
10.1021/ja00396a025
PDF
"Triple-decker" sandwich complexes of cyclo-triphosphorus with 4d and 5d metals
Claudio Bianchini, Massimo Di Vaira, Andrea Meli, and Luigi Sacconi
pp 1448 - 1452; DOI:
10.1021/ja00396a026
PDF
An inelastic electron-tunneling spectroscopic study of the interaction of bis(chlorodicarbonylrhodium) with an aluminum oxide surface
W. M. Bowser and W. H. Weinberg
pp 1453 - 1458; DOI:
10.1021/ja00396a027
PDF
An interstitial hydrogen atom in a hexanuclear metal cluster: x-ray and neutron diffraction analysis of [(Ph3P)2N]+[HCo6(CO)15]-
Donald W. Hart, Raymond G. Teller, Chiau-Yu Wei, Robert Bau, Giuliano Longoni, Stefano Campanella, Paolo Chini, and Thomas F. Koetzle
pp 1458 - 1466; DOI:
10.1021/ja00396a028
PDF
Metalla derivatives of amino acids and peptides. 1. Rhena derivatives of glycine, L-alanine, and glycylglycine. A new N-terminal and protecting group and heavy-atom label
A. J. Baskar, C. M. Lukehart, and K. Srinivasan
pp 1467 - 1472; DOI:
10.1021/ja00396a029
PDF
Molecular species containing persistent voids. Template synthesis and characterization of a series of lacunar-nickel(II) complexes and the corresponding free ligands
Daryle H. Busch, Dennis J. Olszanski, James C. Stevens, Wayne P. Schammel, Masaaki Kojima, Norman Herron, L. Lawrence Zimmer, Katherine A. Holter, and Jan Mocak
pp 1472 - 1478; DOI:
10.1021/ja00396a030
PDF
Reaction of .alpha.,.beta.-unsaturated acid chlorides with tris(triphenylphosphine)chlororhodium(I): formation of phosphonium salts
J. A. Kampmeier, S. H. Harris, and R. M. Rodehorst
pp 1478 - 1485; DOI:
10.1021/ja00396a031
PDF
A closed three-center carbon-hydrogen-metal interaction. A neutron diffraction study of HFe4(.eta.2-CH)(CO)12
M. A. Beno, Jack M. Williams, M. Tachikawa, and E. L. Muetterties
pp 1485 - 1492; DOI:
10.1021/ja00396a032
PDF
Crystal structures and conformational calculations of fragments of alamethicin containing aminoisobutyric acid
G. David Smith, Vladimir Z. Pletnev, William L. Duax, T. M. Balasubramanian, H. E. Bosshard, E. W. Czerwinski, Nancy E. Kendrick, F. Scott Mathews, and Garland R. Marshall
pp 1493 - 1501; DOI:
10.1021/ja00396a033
PDF
Synthesis and reactions of simple 3(2H)-furanones
Amos B. Smith, Patricia A. Levenberg, Paula J. Jerris, Robert M. Scarborough, and Peter M. Wovkulich
pp 1501 - 1513; DOI:
10.1021/ja00396a034
PDF
Aromatic substitution in the gas phase. Alkylation of arenes by gaseous C4H9+ cations
Fulvio Cacace, Giovanna Ciranni, and Pierluigi Giacomello
pp 1513 - 1516; DOI:
10.1021/ja00396a035
PDF
Phosphine substitution in (.eta.5-cyclopentadienyl)bis(triphenylphosphine)cobalt(I): evidence for a dissociative mechanism
Andrew H. Janowicz, Henry E. Bryndza, and Robert G. Bergman
pp 1516 - 1518; DOI:
10.1021/ja00396a036
PDF
Complete substitution stereochemistry of solvolysis of 1-methyl-2-adamantyl tosylate and 4-methyl-exo- and 4-methyl-endo-4-protoadamantyl 3,5-dinitrobenzoate
J. Eric Nordlander and Jerome E. Haky
pp 1518 - 1521; DOI:
10.1021/ja00396a037
PDF
Studies of free radicals at high pressures. 2. Kinetics for a variety of reactions
P. R. Marriott and D. Griller
pp 1521 - 1525; DOI:
10.1021/ja00396a038
PDF
The decomposition of .beta.-phenethylsulfonyl azides. Solution chemistry and flash vacuum pyrolysis
Rudolph A. Abramovitch, William D. Holcomb, and Shigeo Wake
pp 1525 - 1533; DOI:
10.1021/ja00396a039
PDF
Buffer catalysis in the hydrolysis of picrylimidazole
Rita H. De Rossi and Elba B. De Vargas
pp 1533 - 1540; DOI:
10.1021/ja00396a040
PDF
1,5-Dithia-2,4,6,8-tetrazocine: a novel heterocycle of unusual properties
I. Ernest, W. Holick, G. Rihs, D. Schomburg, G. Shoham, D. Wenkert, and R. B. Woodward
pp 1540 - 1544; DOI:
10.1021/ja00396a041
PDF
The active site electrostatic potential of human carbonic anhydrase
Robert P. Sheridan and Leland C. Allen
pp 1544 - 1550; DOI:
10.1021/ja00396a042
PDF
The reactions of semi-met forms of hemerythrin
P. C. Harrington and R. G. Wilkins
pp 1550 - 1556; DOI:
10.1021/ja00396a043
PDF
A free-radical chain reaction involving electron transfer. The replacement of the nitro group by hydrogen using trialkyltin hydride, a variation of the Kornblum reaction
Dennis D. Tanner, Edward V. Blackburn, and Gilberto E. Diaz
pp 1557 - 1559; DOI:
10.1021/ja00396a044
PDF
Photooxidation of (2,2'-bipyridine)(3,4-toluenedithiolato)platinum(II) following ligand-to-ligand and charge-transfer excitation
Arnd Vogler and Horst Kunkely
pp 1559 - 1560; DOI:
10.1021/ja00396a045
PDF
Radical anions of triptycene bis- and tris(quinones)
Glen A. Russell, N. K. Suleman, Hiizu Iwamura, and Owen W. Webster
pp 1560 - 1561; DOI:
10.1021/ja00396a046
PDF
Anthracyclines and related substances. 3. Regiospecific total synthesis of 11-deoxydaunomycinone
S. David Kimball, David R. Walt, and Francis Johnson
pp 1561 - 1563; DOI:
10.1021/ja00396a047
PDF
Photochemistry of a 1,1-diazene, N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene
Peter G. Schultz and Peter B. Dervan
pp 1563 - 1564; DOI:
10.1021/ja00396a048
PDF
Secondary ion mass spectrometry of molecular solids: a source of cluster ions
Robert G. Orth, Harry T. Jonkman, and Josef Michl
pp 1564 - 1565; DOI:
10.1021/ja00396a049
PDF
Stereoselective aldol condensation. Use of chiral boron enolates
Satoru Masamune, William Choy, Francis A. J. Kerdesky, and Barbara Imperiali
pp 1566 - 1568; DOI:
10.1021/ja00396a050
PDF
Total synthesis of 6-deoxyerythronolide B
Satoru Masamune, Masahiro Hirama, Sachio Mori, Sk. Asrof Ali, and David S. Garvey
pp 1568 - 1571; DOI:
10.1021/ja00396a051
PDF
Tritium labeling of organic compounds by HNaY zeolite catalyzed exchange with tritiated water and their analysis by tritium NMR
M. A. Long, J. L. Garnett, P. G. Williams, and T. Mole
pp 1571 - 1572; DOI:
10.1021/ja00396a052
PDF
Synthesis and characterization of a nitrosyl, a nitrido, and an imido carbonyl cluster
Douglas E. Fjare and Wayne L. Gladfelter
pp 1572 - 1574; DOI:
10.1021/ja00396a053
PDF
Methane activation. Photochemical reaction of copper atoms in solid methane
Geoffrey A. Ozin, Douglas F. McIntosh, Steven A. Mitchell, and J. Garcia Prieto
pp 1574 - 1575; DOI:
10.1021/ja00396a054
PDF
Reaction of two-coordinate phosphorus compounds with Group IIIA alkyls: a novel double group shift and concomitant cyclization
A. H. Cowley, J. E. Kilduff, and J. C. Wilburn
pp 1575 - 1577; DOI:
10.1021/ja00396a055
PDF
Nature of species present in an aqueous solution of potassium silicate
R. K. Harris, C. T. G. Knight, and W. E. Hull
pp 1577 - 1578; DOI:
10.1021/ja00396a056
PDF
Trispiro[tricyclo[3.3.3.01,5]undecane-2,1.8,1":9,1'"-tris[cyclopropane]] a chiral fluxional hydrocarbon
John E. Maggio, Howard E. Simmons, and Jay K. Kouba
pp 1579 - 1581; DOI:
10.1021/ja00396a057
PDF
Rearrangement of a geometrically restricted triepoxide to the first topologically nonplanar molecule: a reaction path elucidated by using oxygen isotope effects on carbon-13 chemical shifts
Steven A. Benner, John E. Maggio, and Howard E. Simmons
pp 1581 - 1582; DOI:
10.1021/ja00396a058
PDF
The 9-barbaralyl cation. Isotopic perturbation by eight deuteriums of a totally degenerate carbon-13-labeled C9H9+ carbonium ion
Per Ahlberg, Carin Engdahl, and Goeran Jonsaell
pp 1583 - 1584; DOI:
10.1021/ja00396a059
PDF
The question of ground-state perpendicular olefins. Rehybridization of twisted olefins
Philip Warner and Richard F. Palmer
pp 1584 - 1586; DOI:
10.1021/ja00396a060
PDF
Thermochemistry of .alpha.-aminoalkyl radicals
D. Griller and F. P. Lossing
pp 1586 - 1587; DOI:
10.1021/ja00396a061
PDF
Trivacant heteropolytungstate derivatives: the rational synthesis, characterization, and tungsten-183 NMR spectra of P2W18M4(H2O)2O6810- (M = cobalt,copper,zinc)
Richard G. Finke, Mike Droege, James R. Hutchinson, and Otto Gansow
pp 1587 - 1589; DOI:
10.1021/ja00396a062
PDF
X-ray absorption spectra of permanganate(1-) and permanganate(2-) ions with synchrotron radiation: a study of structure and bonding properties of transition-metal complexes in solution
Tsun K. Sham and Bruce S. Brunschwig
pp 1590 - 1591; DOI:
10.1021/ja00396a063
PDF
Photodissociation spectra of pyridinyl radical dimers detected by reverse pulse polarography. Revised view of the electrochemistry of nicotinamide adenine dinucleotide (NAD+)
Joshua Hermolin, Emilia Kirowa-Eisner, and Edward M. Kosower
pp 1591 - 1593; DOI:
10.1021/ja00396a064
PDF
Metal-metal interactions in binuclear rhodium isocyanide complexes. Polarized single-crystal spectroscopic studies of the lowest triplet.rarw.singlet system in tetrakis(1,3-diisocyanopropane)dirhodium(2+)
Steven F. Rice and Harry B. Gray
pp 1593 - 1595; DOI:
10.1021/ja00396a065
PDF
Metal-metal interactions in binuclear rhodium isocyanide complexes. Resonance Raman spectra of the 1Alg and Eu3A2u electronic states of tetrakis(1,3-diisocyanopropane)dirhodium(I)
Richard F. Dallinger, Vincent M. Miskowski, Harry B. Gray, and William H. Woodruff
pp 1595 - 1596; DOI:
10.1021/ja00396a066
PDF
Thermal desorption of quaternary ammonium cations
Robert J. Cotter and Alfred L. Yergey
pp 1596 - 1598; DOI:
10.1021/ja00396a067
PDF
A novel photoreaction of thymidine with lysine. Photoinduced migration of thymine from DNA to lysine
Isao Saito, Hiroshi Sugiyama, Satoru Ito, Nobuyuki Furukawa, and Teruo Matsuura
pp 1598 - 1600; DOI:
10.1021/ja00396a068
PDF
Tricyclo[4.2.2.22,5]dodeca-1,5-diene
Kenneth B. Wiberg, Michael Matturro, and Richard Adams
pp 1600 - 1602; DOI:
10.1021/ja00396a069
PDF
Total synthesis of pretyrosine (arogenate)
Samuel Danishefsky, Joel Morris, and Lane A. Clizbe
pp 1602 - 1604; DOI:
10.1021/ja00396a070
PDF
(Trimethylsilyl)cyclopentene annulation: a regiocontrolled approach to the synthesis of five-membered rings
Rick L. Danheiser, David J. Carini, and Ajoy Basak
pp 1604 - 1606; DOI:
10.1021/ja00396a071
PDF
In vitro reactivity of the meso and di dimers of the 3,5,5-trimethyl-2-oxomorpholin-3-yl radical with adriamycin and daunomycin
Anthony D. Barone, Richard F. Atkinson, Donald L. Wharry, and Tad H. Koch
pp 1606 - 1607; DOI:
10.1021/ja00396a072
PDF
Exchange interaction contribution to energy transfer between ions in the rapid-diffusion limit
Claude F. Meares and Simon M. Yeh
pp 1607 - 1609; DOI:
10.1021/ja00396a073
PDF
Observation of a fully protected oligonucleotide dimer at m/z 12637 by californium-252 plasma desorption mass spectrometry
Catherine J. McNeal and Ronald D. Macfarlane
pp 1609 - 1610; DOI:
10.1021/ja00396a074
PDF
Book Reviews

pp 1611 - 1612; DOI:
10.1021/ja00396a600
PDF

Issue 7


Analogy of multiple-quantum NMR to isotopic spin labeling
W. S. Warren and A. Pines
pp 1613 - 1617; DOI:
10.1021/ja00397a001
PDF
Geometrical structure of solvated electrons in ethanol glass determined from electron spin echo modulation analyses
M. Narayana and Larry Kevan
pp 1618 - 1622; DOI:
10.1021/ja00397a002
PDF
Semiconductor electrodes. 32. n- and p-gallium arsenide n- and p-silicon, and n-titanium dioxide in liquid ammonia
Richard E. Malpas, Kingo Itaya, and Allen J. Bard
pp 1622 - 1627; DOI:
10.1021/ja00397a003
PDF
Raman intensity and conjugation. 5. A quantitative relationship between Raman intensity and the length of conjugation and an analysis of the Raman intensities of some substituted benzenes and biphenyls
Eduard D. Schmid and Ronald D. Topsom
pp 1628 - 1632; DOI:
10.1021/ja00397a004
PDF
Are the oxocarbon dianions really aromatic?
Junichi Aihara
pp 1633 - 1635; DOI:
10.1021/ja00397a005
PDF
Measurement of the optical activity of triplet-singlet transitions. The circular polarization of phosphorescence of camphorquinone and benzophenone
N. Steinberg, A. Gafni, and I. Z. Steinberg
pp 1636 - 1640; DOI:
10.1021/ja00397a006
PDF
Type I CM-type II DM transitions of lyotropic liquid crystals
Bruce J. Forrest and Leonard W. Reeves
pp 1641 - 1647; DOI:
10.1021/ja00397a007
PDF
Luminescent photoelectrochemical cells. 5. Multiple emission from tellurium-doped cadmium sulfide photoelectrodes and implications regarding excited-state communication
Bradley R. Karas, Holger H. Streckert, Rodney Schreiner, and Arthur B. Ellis
pp 1648 - 1651; DOI:
10.1021/ja00397a008
PDF
A theoretical study of propadienone and its isomers propynal and cyclopropenone
Andrew Komornicki, Clifford E. Dykstra, Mark A. Vincent, and Leo Radom
pp 1652 - 1656; DOI:
10.1021/ja00397a009
PDF
Hexaammineruthenium(II,III) and pentaamminedinitrogenruthenium(II). A Hartree-Fock-Slater study
Mary J. Ondrechen, Mary Jo Ondrechen, and D. E. Ellis
pp 1656 - 1659; DOI:
10.1021/ja00397a010
PDF
A two-group model for Raman optical activity. Application to methylene vibrations
Arthur Gohin and Martin Moskovits
pp 1660 - 1664; DOI:
10.1021/ja00397a011
PDF
Tungsten-183 NMR and x-ray study of a heteropolyanion [As2W21O69(H2O)]6- exhibiting a rare square-pyramidal environment for some tungsten(VI)
Y. Jeannin and J. Martin-Frere
pp 1664 - 1667; DOI:
10.1021/ja00397a012
PDF
Experimental evidence for orbital symmetry control of stereochemistry in some (methylenecyclopropane)iron-carbonyl reactions
Allan R. Pinhas, Ashoka G. Samuelson, Rafael Risemberg, Edward V. Arnold, Jon Clardy, and Barry K. Carpenter
pp 1668 - 1675; DOI:
10.1021/ja00397a013
PDF
Apparent fluxionality in diethyl(triethylphosphine)platinum(II), a coordinatively unsaturated intermediate in .beta.-hydride elimination
Thomas J. McCarthy, Ralph G. Nuzzo, and George M. Whitesides
pp 1676 - 1678; DOI:
10.1021/ja00397a014
PDF
Intramolecular electron transfer from pentacyanoferrate(II) to pentaamminecobalt(III) via an imidazolate bridge. The role of distance in inner-sphere reactions
Alek P. Szecsy and Albert Haim
pp 1679 - 1683; DOI:
10.1021/ja00397a015
PDF
Studies of the photochemical behavior of (undecacarbonyl)triferrate(2-) in solution
David R. Tyler and Harry B. Gray
pp 1683 - 1686; DOI:
10.1021/ja00397a016
PDF
Electronic spectra of copper(II)-imidazole and copper(II)-pyrazole chromophores
Ernest Bernarducci, William F. Schwindinger, Joseph L. Hughey, Karsten Krogh-Jespersen, and Harvey J. Schugar
pp 1686 - 1691; DOI:
10.1021/ja00397a017
PDF
Metal-carbonyl syntheses. 9. Carbon monoxide - a six-electron ligand? Synthesis and structural characterization of the unusual carbonylniobium cluster heptacarbonyltris(.eta.5-cyclopentadienyl)triniobium
Wolfgang A. Herrmann, Helmut Biersack, Manfred L. Ziegler, Klaus Weidenhammer, Rolf Siegel, and Dieter Rehder
pp 1692 - 1699; DOI:
10.1021/ja00397a018
PDF
Crystal structure and low-temperature proton NMR spectrum of tetramesityldiphosphine. Evidence for the anticonformational preference in tetraaryldiphosphines
S. G. Baxter, Alan H. Cowley, Raymond E. Davis, and Paul E. Riley
pp 1699 - 1702; DOI:
10.1021/ja00397a019
PDF
.beta.-Turn conformation of N-acetyl-L-prolylglycyl-L-phenylalanine. Crystal structure and solution studies
Samir K. Brahmachari, T. N. Bhat, V. Sudhakar, M. Vijayan, R. S. Rapaka, R. S. Bhatnagar, and V. S. Ananthanarayanan
pp 1703 - 1708; DOI:
10.1021/ja00397a020
PDF
Topography of cyclodextrin inclusion complexes. 15. Crystal and molecular structure of the cyclohexaamylose-7.57 water complex, form III. Four- and six-membered circular hydrogen bonds
K. K. Chacko and W. Saenger
pp 1708 - 1715; DOI:
10.1021/ja00397a021
PDF
Crystal structure and solution studies of the molecular conformation of the cyclic hexapeptide cyclo-(Gly-L-His-Gly-L-Ala-L-Tyr-Gly)
Chia-Hsi Yang, Joe N. Brown, and Kenneth D. Kopple
pp 1715 - 1719; DOI:
10.1021/ja00397a022
PDF
Absolute configuration of sparsomycin. A chiroptical study of sulfoxides
Harry C. J. Ottenheijm, Rob M. J. Liskamp, Paul Helquist, Joseph W. Lauher, and Mohammed Shekhani
pp 1720 - 1723; DOI:
10.1021/ja00397a023
PDF
Reactivity and mechanism of hydrolysis of phosphonamides
Jubrail Rahil and Paul Haake
pp 1723 - 1734; DOI:
10.1021/ja00397a024
PDF
Coal. Kinetics of O-alkylation
Ronald Liotta and Glen Brons
pp 1735 - 1742; DOI:
10.1021/ja00397a025
PDF
Liquid-phase autoxidation of organic compounds at elevated temperatures. 2. Kinetics and mechanisms of the formation of cleavage products in n-hexadecane autoxidation
R. K. Jensen, S. Korcek, L. R. Mahoney, and M. Zinbo
pp 1742 - 1749; DOI:
10.1021/ja00397a026
PDF
Binding mechanisms in cyclohexaamylose complexes
Robert I. Gelb, Lowell M. Schwartz, Beatriz Cardelino, Howard S. Fuhrman, Robert F. Johnson, and Daniel A. Laufer
pp 1750 - 1757; DOI:
10.1021/ja00397a027
PDF
The mechanism of catalysis of the thio-Claisen rearrangement
H. Kwart, W. H. Miles, A. G. Horgan, and L. D. Kwart
pp 1757 - 1760; DOI:
10.1021/ja00397a028
PDF
Simple enols. 1. The generation of vinyl alcohol in solution and its detection and characterization by NMR spectroscopy
Brian Capon, David S. Rycroft, Thomas W. Watson, and Cesar Zucco
pp 1761 - 1765; DOI:
10.1021/ja00397a029
PDF
Tetrahedral intermediates. 2. The detection of hemiorthoesters in the hydration of ketene acetals and the mechanism of their breakdown
Brian Capon and Ashim Kumar Ghosh
pp 1765 - 1768; DOI:
10.1021/ja00397a030
PDF
A new synthetic route to 2-azetidinones. Ring contraction of 4-azido-2-pyrrolinones to 3-cyano-2-azetidinones
Harold W. Moore, Louis Hernandez, Donna M. Kunert, Frank Mercer, and Annlie Sing
pp 1769 - 1777; DOI:
10.1021/ja00397a031
PDF
A study of the synthesis and properties of [26](1,2,3,4,5,6)cyclophane (superphane)
Yasuo Sekine and V. Boekelheide
pp 1777 - 1785; DOI:
10.1021/ja00397a032
PDF
Preparation and chemistry of penta- and hexacoordinated phosphorus compounds containing trifluoroethoxy groups
Donald B. Denney, Dorothy Z. Denney, Philip J. Hammond, and Yu-Pin Wang
pp 1785 - 1789; DOI:
10.1021/ja00397a033
PDF
Formation of the crossed product 1,4-disubstituted 2,3,5,6,11-pentaoxabicyclo[5.3.1]undecane from a mixture of two kinds of ozonides in the presence of an acid catalyst. Elucidation of the intermediates in the acidolysis of an ozonide
Masahiro Miura, Masatomo Nojima, Shigekazu Kusabayashi, and Shigeru Nagase
pp 1789 - 1796; DOI:
10.1021/ja00397a034
PDF
Pericyclic reactions of free cyclopentadienone
F. Gavina, A. M. Costero, P. Gil, B. Palazon, and S. V. Luis
pp 1797 - 1798; DOI:
10.1021/ja00397a035
PDF
Photodissociation spectroscopy of hexadiene radical ions: structural rearrangements in the gas-phase ions
Robert C. Benz, Robert C. Dunbar, and Paul C. Claspy
pp 1799 - 1802; DOI:
10.1021/ja00397a036
PDF
Photodetachment of the azide anion in the gas phase. Electron affinity of the azide radical
Robert L. Jackson, Mark J. Pellerite, and John I. Brauman
pp 1802 - 1805; DOI:
10.1021/ja00397a037
PDF
Direct photolysis at 185 nm of simple alkynes. Intra- and intermolecular hydrogen abstractions
Yoshihisa Inoue, Yasutaka Ueda, and Tadao Hakushi
pp 1806 - 1808; DOI:
10.1021/ja00397a038
PDF
Tricyclo[5.3.0.01,6]decan-5-one and tricyclo[5.4.0.01,6]undecan-5-one. Synthesis and selective transformation to spiro and fused bicyclic systems
John F. Ruppert and James D. White
pp 1808 - 1813; DOI:
10.1021/ja00397a039
PDF
Spiroannelation via intramolecular ketocarbenoid addition. Stereocontrolled synthesis of (-)-acorenone B and (.+-.)-.alpha.-chamigrene
James D. White, John F. Ruppert, Mitchell A. Avery, Sigeru Torii, and Junzo Nokami
pp 1813 - 1821; DOI:
10.1021/ja00397a040
PDF
Cation-complexing properties of synthetic macrocyclic polyether-diester ligands containing the furan, benzene, tetrahydrofuran, and thiophene subcyclic units
Jerald S. Bradshaw, Steven L. Baxter, John D. Lamb, Reed M. Izatt, and James J. Christensen
pp 1821 - 1827; DOI:
10.1021/ja00397a041
PDF
Solvent effects on the deacylation of acyl-chymotrypsins: a critical comment on the charge-relay hypothesis
Susan E. Hamilton and Burt Zerner
pp 1827 - 1831; DOI:
10.1021/ja00397a042
PDF
A vinylsilane route of (.+-.)-gymnomitrol
Leo A. Paquette and Yeun-Kwei Han
pp 1831 - 1835; DOI:
10.1021/ja00397a043
PDF
Total synthesis of (.+-.)-isocomene, a naturally occurring triquinane
Leo A. Paquette and Yeun-Kwei Han
pp 1835 - 1838; DOI:
10.1021/ja00397a044
PDF
Stereochemical studies of isoprenoid biosynthesis. Biosynthesis of pentalenolactone from [U-13C6]glucose and [6-2H2]glucose
David E. Cane, Thomas Rossi, Ann Marie Tillman, and J. Paul Pachlatko
pp 1838 - 1843; DOI:
10.1021/ja00397a045
PDF
Evidence for the isomerization of 1-methylsilene to dimethylsilylene
Robert T. Conlin and David L. Wood
pp 1843 - 1844; DOI:
10.1021/ja00397a046
PDF
Photoisomerization of dimethylsilylene to 2-silapropene and thermal reversion to dimethylsilylene
Timothy J. Drahnak, Josef Michl, and Robert West
pp 1845 - 1846; DOI:
10.1021/ja00397a047
PDF
Stereochemical aspects of the nickel-catalyzed alkylation of allylic alcohols
Giambattista Consiglio, Franco Morandini, and Oreste Piccolo
pp 1846 - 1847; DOI:
10.1021/ja00397a048
PDF
Stoichiometric decarbonylation of benzoyl chloride by chlorotris(triphenylphosphine)rhodium(I)
J. A. Kampmeier, R. M. Rodehorst, and J. B. Philip
pp 1847 - 1849; DOI:
10.1021/ja00397a049
PDF
Stabilization of n-type silicon photoelectrodes to surface oxidation in aqueous electrolyte solution and mediation of oxidation reaction by surface-attached organic conducting polymer
Rommel Noufi, Arthur J. Frank, and Arthur J. Nozik
pp 1849 - 1850; DOI:
10.1021/ja00397a050
PDF
Low-valent molybdenum porphyrin derivatives: synthesis and structure of a .pi.-bonded diphenylacetylene adduct of molybdenum(II) (meso-tetra-p-tolylporphyrin)
Andre De Cian, Jocelyne Colin, Michel Schappacher, Louis Ricard, and Raymond Weiss
pp 1850 - 1851; DOI:
10.1021/ja00397a051
PDF
Enantiospecific total synthesis of dendrobatid toxin 251D. A short chiral entry to the cardiac-active pumiliotoxin A alkaloids via stereospecific iminium ion-vinylsilane cyclizations
Larry E. Overman and Kenneth L. Bell
pp 1851 - 1853; DOI:
10.1021/ja00397a052
PDF
Tandem Cope-Claisen rearrangements for the construction of (E,E)-1,6-cyclodecadienes. Effect of ketene acetal substituents on .DELTA.G.dbldag.Claisen
Stanley Raucher, John E. Burks, Ki-Jun Hwang, and Dana P. Svedberg
pp 1853 - 1855; DOI:
10.1021/ja00397a053
PDF
Electron-transfer photooxygenation. 6. Indirect sensitized photooxygenation of aryl olefins
Dale S. Steichen and Christopher S. Foote
pp 1855 - 1857; DOI:
10.1021/ja00397a054
PDF
Structures of the didemnins, antiviral and cytotoxic depsipeptides from a Caribbean tunicate
Kenneth L. Rinehart, James B. Gloer, J. Carter Cook, Stephen A. Mizsak, and Terrence A. Scahill
pp 1857 - 1859; DOI:
10.1021/ja00397a055
PDF
Regioselectivity in the intramolecular ene reaction of cyclopropene derivatives
Albert Padwa and William F. Rieker
pp 1859 - 1860; DOI:
10.1021/ja00397a056
PDF
Azide photoaffinity analogs for acridine dye binding sites
David M. Mueller, Richard A. Hudson, and Chuan-Pu Lee
pp 1860 - 1862; DOI:
10.1021/ja00397a057
PDF
Ethylidenation of olefins using a convenient iron-containing cyclopropanation reagent
Kenneth A. M. Kremer, Paul Helquist, and Robert C. Kerber
pp 1862 - 1864; DOI:
10.1021/ja00397a058
PDF
Chirality transfer via organopalladium chemistry. A synthesis of optically active vitamin E side chain from D-glucose
Barry M. Trost and Thomas P. Klun
pp 1864 - 1865; DOI:
10.1021/ja00397a059
PDF
New tungstophosphates: Cs6W5P2O23, Cs7W10PO36, and Cs7Na2W10PO37
W. H. Knoth and R. L. Harlow
pp 1865 - 1867; DOI:
10.1021/ja00397a060
PDF
Photogeneration of an active formate-decomposition catalyst
A. D. King, R. B. King, and E. L. Sailers
pp 1867 - 1868; DOI:
10.1021/ja00397a061
PDF
Isolation and characterization of the first host recognition substance for parasitic angiosperms
David G. Lynn, John C. Steffens, Vinayak S. Kamut, David W. Graden, Jeffrey Shabanowitz, and James L. Riopel
pp 1868 - 1870; DOI:
10.1021/ja00397a062
PDF
Oxygen chiral phosphodiesters. 3. Use of oxygen-17 NMR spectroscopy to demonstrate configurational differences in the diastereomers of cyclic 2'-deoxyadenosine 3',5'-[17O,18O]monophosphate
Jeffrey A. Coderre, Shujaath Mehdi, Peter C. Demou, Richard Weber, Daniel D. Traficante, and John A. Gerlt
pp 1870 - 1872; DOI:
10.1021/ja00397a063
PDF
Oxygen chiral phosphodiesters. 4. Stereochemical course of the hydrolysis of 2'-deoxyadenosine cyclic 3',5'-[17O, 18O]monophosphate in water(oxygen-16) catalyzed by bovine heart cyclic nucleotide phosphodiesterase
Jeffrey A. Coderre, Shujaath Mehdi, and John A. Gerlt
pp 1872 - 1875; DOI:
10.1021/ja00397a064
PDF
Bis(pentamethylcyclopentadienyl)chlorouranium.tetrahydrofuran oxidative-addition reaction. 2. A kinetic and mechanistic study
Richard G. Finke, David A. Schiraldi, and Yoshiki Hirose
pp 1875 - 1876; DOI:
10.1021/ja00397a065
PDF
Stereochemistry of an enzymic Baeyer-Villiger reaction. Application of deuterium NMR
John M. Schwab
pp 1876 - 1878; DOI:
10.1021/ja00397a066
PDF
Additions and Corrections - Extreme Conformational Flexibility of the Furanose 2607 in DNA and RNA
M. Levitt, and Arieh Warshel
pp 1879 - 1879; DOI:
10.1021/ja00397a600
PDF
Book Reviews

pp 1880 - 1880; DOI:
10.1021/ja00397a601
PDF

Issue 8


The ground-state dipole moments of all-trans- and 9-cis-retinal
Anne B. Myers and Robert R. Birge
pp 1881 - 1885; DOI:
10.1021/ja00398a001
PDF
A MINDO/3 theoretical study on structure, fragmentation, and scrambling reaction in the phenyl cation
Mutsumi Tasaka, Michihiko Ogata, and Hiroshi Ichikawa
pp 1885 - 1891; DOI:
10.1021/ja00398a002
PDF
Evaluation and prediction of the stability of bridgehead olefins
Wilhelm F. Maier and Paul Von Rague Schleyer
pp 1891 - 1900; DOI:
10.1021/ja00398a003
PDF
Tunneling in the unimolecular decomposition of formaldehyde: a more quantitative study
Stephen K. Gray, William H. Miller, Yukio Yamaguchi, and Henry F. Schaefer
pp 1900 - 1904; DOI:
10.1021/ja00398a004
PDF
Vinylidene: a very shallow minimum on the C2H2 potential energy surface
Yoshihiro Osamura, Henry F. Schaefer, Stephen K. Gray, and William H. Miller
pp 1904 - 1907; DOI:
10.1021/ja00398a005
PDF
Near-ultraviolet vibronic transitions of adenosine 5'-phosphate, adenosine, and its complexes with cis- and trans-diamminedichloroplatinum(II): spectral study of isotropic absorption, linear dichroism, and circular dichroism
Daniel Fornasiero, Ian A. G. Roos, Kerry Anne Rye, and Tomas Kurucsev
pp 1908 - 1913; DOI:
10.1021/ja00398a006
PDF
The oxygen analog of the protonated cyclopropane problem. A theoretical study of the C2H5O+ potential energy surface
Ross H. Nobes, William R. Rodwell, Willem J. Bouma, and Leo Radom
pp 1913 - 1922; DOI:
10.1021/ja00398a007
PDF
An investigation of the mechanism of phosphine photolysis
J. P. Ferris and Robert Benson
pp 1922 - 1927; DOI:
10.1021/ja00398a008
PDF
The molecular structure of the cubanelike compound, [Mo(NC6H4CH3)(.mu.3-S)(S2P(OC2H5)2)]4, and a description of its bonding
A. W. Edelblut, K. Folting, J. C. Huffman, and R. A. D. Wentworth
pp 1927 - 1931; DOI:
10.1021/ja00398a009
PDF
Structural characterization of the [Fe4(S2C2(CF3)2)4(.mu.3-S)4]2- dianion. Stereochemical relationship between the cubanelike Fe4S4 cores of this Balch dithiolene dianion and the [Fe4(.eta.5-C5H5)4(.mu.3-S)4]2+ dication and resulting electronic implications
Timothy H. Lemmen, Joseph A. Kocal, Frederick Yip-Kwai Lo, Michael W. Chen, and Lawrence F. Dahl
pp 1932 - 1941; DOI:
10.1021/ja00398a010
PDF
Synthesis and stereochemical analysis of the triangular cobalt-dinickel clusters, (.eta.5-C5H5-nMen)CoNi2(.eta.5-C5H5)2(.mu.3-CO)2 (where n = 0, 1, 5): direct evidence for the antibonding trimetal character of the unpaired electron in the Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2 and resulting geometrical effects upon formal oxidation by replacement of a nickel with a cobalt atom
Lance R. Byers, Vernon A. Uchtman, and Lawrence F. Dahl
pp 1942 - 1951; DOI:
10.1021/ja00398a011
PDF
Bis[bis(F-methyl)sulfimide], N-chlorobis(F-methyl)sulfimide, and N-fluorobis(F-methyl)sulfimide
Ramesh C. Kumar and Jean'ne M. Shreeve
pp 1951 - 1952; DOI:
10.1021/ja00398a012
PDF
Electronic properties of thiolate compounds of oxomolybdenum(V) and their tungsten and selenium analogs. Effects of oxygen-17, molybdenum-98, and molybdenum-95 isotope substitution upon ESR spectra
Graeme R. Hanson, Andrew A. Brunette, Angus C. McDonell, Keith S. Murray, and Anthony G. Wedd
pp 1953 - 1959; DOI:
10.1021/ja00398a013
PDF
Redox properties of thiolate compounds of oxomolybdenum(V) and their tungsten and selenium analogs
Julie R. Bradbury, Anthony F. Masters, Angus C. McDonell, Andrew A. Brunette, Alan M. Bond, and Anthony C. Wedd
pp 1959 - 1964; DOI:
10.1021/ja00398a014
PDF
Reaction of fluoroxysulfate with aromatic compounds
Dominic P. Ip, Carol D. Arthur, Randall E. Winans, and Evan H. Appelman
pp 1964 - 1968; DOI:
10.1021/ja00398a015
PDF
Reaction of allylic boron and aluminum "ate" complexes with organic halides and carbonyl compounds. Trialkylboranes as regio-, stereo-, and chemoselective control elements
Yoshinori Yamamoto, Hidetaka Yatagai, and Kazuhiro Maruyama
pp 1969 - 1975; DOI:
10.1021/ja00398a016
PDF
Intramolecular lactonization at a metal center. The rapid reactions of coordinated water and hydroxy(1-) ion with an adjacent carboxylic acid residue
C. J. Boreham, D. A. Buckingham, D. J. Francis, A. M. Sargeson, and L. G. Warner
pp 1975 - 1981; DOI:
10.1021/ja00398a017
PDF
Deuterium isotope effects in the solvolysis of benzal chlorides. 5. Salt effects and solvent isotope effects
V. P. Vitullo and F. P. Wilgis
pp 1982 - 1984; DOI:
10.1021/ja00398a018
PDF
Total synthesis of isopavine and intermediates for the preparation of substituted amitriptyline analogs: facile routes to substituted dibenzocyclooctatrienes and dibenzocycloheptatrienes
Michael E. Jung and Steven J. Miller
pp 1984 - 1992; DOI:
10.1021/ja00398a019
PDF
Simple o-quinodimethane route to (.+-.)-4-demethoxydaunomycinone
Francis A. J. Kerdesky, Robert J. Ardecky, M. V. Lakshmikantham, and Michael P. Cava
pp 1992 - 1996; DOI:
10.1021/ja00398a020
PDF
Lewis acid promoted decomposition of unsaturated .alpha.-diazo ketones. 1. An efficient approach to simple and annulated cyclopentenones
Amos B. Smith, Bruce H. Toder, Stephen J. Branca, and R. Karl Dieter
pp 1996 - 2008; DOI:
10.1021/ja00398a021
PDF
Lewis acid promoted decomposition of unsaturated .alpha.-diazo ketones. 2. A new initiator for polyolefinic cation cyclization
Amos B. Smith and R. Karl Dieter
pp 2009 - 2016; DOI:
10.1021/ja00398a022
PDF
Lewis acid promoted decomposition of unsaturated .alpha.-diazo ketones. 3. Stereochemical consequences of polyolefinic cyclizations initiated by the .alpha.-diazo ketone functionality
Amos B. Smith and R. Karl Dieter
pp 2017 - 2022; DOI:
10.1021/ja00398a023
PDF
Double-bond deformation in two crystalline derivatives of syn-sesquinorbornene (.DELTA.4a,8a-octahydro-1,4,5,8-dimethanonaphthalene)
William H. Watson, Jean Galloy, Paul D. Bartlett, and Antonius A. M. Roof
pp 2022 - 2031; DOI:
10.1021/ja00398a024
PDF
Carbon-phosphorus heterocycles. Synthesis of phosphorus-containing cannabinoid precursors and a single-crystal analysis of 1,2,3,4-tetrahydro-10-hydroxy-8-n-pentyl-5H-phosphorino[3,4-c][1]benzopyran-5-one 3-oxide
Jang. B. Rampal, K. Darrell Berlin, Nantelle S. Pantaleo, Ann McGuffy, and Dick Van der Helm
pp 2032 - 2036; DOI:
10.1021/ja00398a025
PDF
Reactions of (alkylperoxy)cobaloximes in acidic aqueous solutions
James H. Espenson and Jwu-Ting Chen
pp 2036 - 2041; DOI:
10.1021/ja00398a026
PDF
Reduction by a model of NAD(P)H. 29. Kinetics and isotope effects for the reduction of substituted trifluoroacetophenone
Atsuyoshi Ohno, Hiroyuki Yamamoto, and Shinzaburo Oka
pp 2041 - 2045; DOI:
10.1021/ja00398a027
PDF
Reduction by a model of NAD(P)H. 30. Proof for the electron-proton-electron-transfer mechanism
Atsuyoshi Ohno, Tohru Shio, Hiroyuki Yamamoto, and Shinzaburo Oka
pp 2045 - 2048; DOI:
10.1021/ja00398a028
PDF
Photoepoxidation of olefins with benzoins and oxygen. Epoxidation with acylperoxy radical
Yasuhiko Sawaki and Yoshiro Ogata
pp 2049 - 2053; DOI:
10.1021/ja00398a029
PDF
Structures of some condensation products of .alpha.-dicarbonyl compounds and tris(amino)phosphines in solution
Donald B. Denney, Dorothy Z. Denney, Philip J. Hammond, and Kuo-Shu Tseng
pp 2054 - 2057; DOI:
10.1021/ja00398a030
PDF
Ipso nitration. Solvolytic behavior of 1,4-dimethyl-4-nitrocyclohexadienyl acetate and 1,4-dimethyl-4-nitrocyclohexadienol
J. T. Geppert, M. W. Johnson, P. C. Myhre, and S. P. Woods
pp 2057 - 2062; DOI:
10.1021/ja00398a031
PDF
Protonation of polymethylnaphthalenes and hexahydropyrene. Formation of stable naphthalenium ions and observation of isomerizations based on proton and carbon-13 nuclear magnetic resonance studies
Koop Lammertsma
pp 2062 - 2069; DOI:
10.1021/ja00398a032
PDF
Coenzyme models. 25. Facile oxidation of hemithiol acetals by flavin. Supporting evidence for the enediol mechanism of glyoxalase I
Seiji Shinkai, Takaharu Yamashita, Yumiko Kusano, and Osamu Manabe
pp 2070 - 2074; DOI:
10.1021/ja00398a033
PDF
Biosynthesis of oleanene- and ursene-type triterpenes from [4-13C]mevalonolactone and sodium [1,2-13C2]acetate in tissue cultures of Isodon japonicus Hara
Shujiro Seo, Yutaka Tomita, and Kazuo Tori
pp 2075 - 2080; DOI:
10.1021/ja00398a034
PDF
Sequential polypeptides of elastin: cyclic conformational correlates of the linear polypentapeptide
Dan W. Urry, Tina L. Trapane, Hiroshi Sugano, and Kari U. Prasad
pp 2080 - 2089; DOI:
10.1021/ja00398a035
PDF
Diels-Alder reaction of 1-azadienes
Yea-Shun Cheng, Frank W. Fowler, and Andrew T. Lupo
pp 2090 - 2091; DOI:
10.1021/ja00398a036
PDF
Asymmetric reductions with 1,4-dihydropyridines contained in chiral macrocycles
Patrick Jouin, Coos B. Troostwijk, and Richard M. Kellogg
pp 2091 - 2093; DOI:
10.1021/ja00398a037
PDF
Charge-transfer transition for symmetry-forbidden charge-transfer interaction in 1,4-dihydro-1,4-bis(dicyanomethylene)triptycenes
Satoshi Inagaki, Kimiaki Yamamura, Kazuhiro Nakasuji, Tomoo Nakazawa, and Ichiro Murata
pp 2093 - 2094; DOI:
10.1021/ja00398a038
PDF
Nonplanarity of .pi. systems in 5,6-bis(methylene)-7-oxanorborn-2-ene
Alan A. Pinkerton, Dieter Schwarzenbach, John H. A. Stibbard, Pierre Alain Carrupt, and Pierre Vogel
pp 2095 - 2096; DOI:
10.1021/ja00398a039
PDF
Oxygenation reactions of the adamantylideneadamantane cation radical
Stephen F. Nelsen and Ryoichi Akaba
pp 2096 - 2097; DOI:
10.1021/ja00398a040
PDF
Electroorganic synthesis. 1. Electrode-catalyzed synthesis of a dioxetane
E. L. Clennan, W. Simmons, and C. W. Almgren
pp 2098 - 2099; DOI:
10.1021/ja00398a041
PDF
Direct evidence from multiple carbon-13-labeling and homonuclear decoupling for the labeling pattern by glucose of the m-aminobenzoyl (C7N) unit of pactamycin
Kenneth L. Rinehart, Maria Potgieter, Dana L. Delaware, and Haruo Seto
pp 2099 - 2101; DOI:
10.1021/ja00398a042
PDF
Electron spin resonance-high-performance liquid chromatography study of organometallic free radical reactions: separation and characterization of the rhenium carbonyl-o-quinone radical complex
K. A. M. Creber and J. K. S. Wan
pp 2101 - 2102; DOI:
10.1021/ja00398a043
PDF
An NMR technique for tracing out the carbon skeleton of an organic molecule
Ad Bax, Ray Freeman, and Thomas A. Frenkiel
pp 2102 - 2104; DOI:
10.1021/ja00398a044
PDF
The principle of cooperativity in asymmetric induction. A demanding test for concertedness
Laren M. Tolbert and Mahfuza B. Ali
pp 2104 - 2105; DOI:
10.1021/ja00398a045
PDF
Production of orbitally forbidden products in the IR-laser-induced isomerization of cis-3,4-dichlorocyclobutene
Chung-Rei Mao, Nathan Presser, Lian-Shun John, Robert M. Moriarty, and Robert J. Gordon
pp 2105 - 2106; DOI:
10.1021/ja00398a046
PDF
Erythro-selective aldol reaction via tris(dialkylamino)sulfonium enolates
R. Noyori, I. Nishida, and J. sakata
pp 2106 - 2108; DOI:
10.1021/ja00398a047
PDF
A triply convergent total synthesis of l(-)-prostaglandin E2
R. E. Donaldson and P. L. Fuchs
pp 2108 - 2110; DOI:
10.1021/ja00398a048
PDF
Enantioconvergent syntheses of two classes of chiral cyclopentenyl sulfone synthons
J. C. Saddler, R. E. Donaldson, and P. L. Fuchs
pp 2110 - 2112; DOI:
10.1021/ja00398a049
PDF
Enantiospecific syntheses of .gamma.-substituted enones: organometallic SN2' conjugate-addition reactions of epoxy vinyl sulfones
J. C. Saddler and P. L. Fuchs
pp 2112 - 2114; DOI:
10.1021/ja00398a050
PDF
Reaction of allylically substituted enolates with organometallic reagents: a convenient source of enolonium ion equivalents
Paul A. Wender, Jeanette M. Erhardt, and Leo J. Letendre
pp 2114 - 2116; DOI:
10.1021/ja00398a051
PDF
Temperature dependence of carbene-carbene rearrangements. A new method for the generation of carbenes
Udo H. Brinker and Joachim Ritzer
pp 2116 - 2119; DOI:
10.1021/ja00398a052
PDF
Carbon-13 magnetic resonance dipolar spectroscopy. Orientation of the chemical shift tensor in cyclopropane
Kurt W. Zilm, Alvin J. Beeler, David M. Grant, Josef Michl, Teh Chang Chou, and Evan L. Allred
pp 2119 - 2120; DOI:
10.1021/ja00398a053
PDF
Thermal and photochemical studies of a monomeric rhodium(II) radical
Ursula Tinner and James H. Espenson
pp 2120 - 2121; DOI:
10.1021/ja00398a054
PDF
Synthesis and molecular structure of the dissymmetric molybdenum.cntdot.molybdenum compound [(.eta.5-C5H5)2Mo2(CO)3(C6H5P(OCH2CH2)NH)]: first example of direct carbonyl-substitution in bis[(.eta.5-cyclopentadienyl)dicarbonylmolybdenum]
Joachim Wachter, Andre Mitschler, and Jean G. Riess
pp 2121 - 2123; DOI:
10.1021/ja00398a055
PDF
Electrochemically activated binding of benzo[a]pyrene and 6-methylbenzo[a]pyrene to DNA
Donald A. Tryk and Su-Moon Park
pp 2123 - 2124; DOI:
10.1021/ja00398a056
PDF
Acyl transfer reactions in the gas phase. The question of tetrahedral intermediates
Jhong K. Kim and Marjorie C. Caserio
pp 2124 - 2127; DOI:
10.1021/ja00398a057
PDF
Enantioselective aldol condensations. 2. Erythro-selective chiral aldol condensations via boron enolates
D. A. Evans, J. Bartroli, and T. L. Shih
pp 2127 - 2129; DOI:
10.1021/ja00398a058
PDF
ESR study of iron carbonyl radical anions
Paul J. Krusic, Joseph San Filippo, B. Hutchinson, R. L. Hance, and L. M. Daniels
pp 2129 - 2131; DOI:
10.1021/ja00398a059
PDF
ESR study of paramagnetic iron carbonyl hydrides
Paul J. Krusic
pp 2131 - 2133; DOI:
10.1021/ja00398a060
PDF
A systematically designed homogeneous oscillating reaction: the arsenite-iodate-chlorite system
Patrick De Kepper, Irving R. Epstein, and Kenneth Kustin
pp 2133 - 2134; DOI:
10.1021/ja00398a061
PDF
Pentaprismane
Philip E. Eaton, Yat Sun Or, and Stephen J. Branca
pp 2134 - 2136; DOI:
10.1021/ja00398a062
PDF
Trichodiene biosynthesis and the enzymic cyclization of farnesyl pyrophosphate
David E. Cane, Stephen Swanson, and Pushpalatha P. N. Murthy
pp 2136 - 2138; DOI:
10.1021/ja00398a063
PDF
Thermal rearrangement of 2,2-difluorovinylcyclopropane. A concerted pathway?
William R. Dolbier, B. H. Al-Sader, Simon F. Sellers, and Henryk Koroniak
pp 2138 - 2139; DOI:
10.1021/ja00398a064
PDF
Experimental test for micelle porosity
F. M. Menger and J. M. Bonicamp
pp 2140 - 2141; DOI:
10.1021/ja00398a065
PDF
Homogeneous catalysis of the photoreduction of water by visible light. 2. Mediation by a tris(2,2'-bipyridine)ruthenium(II)-cobalt(II) bipyridine system
C. V. Krishnan and Norman Sutin
pp 2141 - 2142; DOI:
10.1021/ja00398a066
PDF
Correction. Synthesis of Compounds Related to Equilenin
W. E. Bachmann, and R. E. Holmen
pp 2143 - 2143; DOI:
10.1021/ja00398a600
PDF
Correction. Mechanisms of 1,1-Reductive Elimination from Palladium
Arlene Grille, and J. K. Stille
pp 2143 - 2143; DOI:
10.1021/ja00398a601
PDF
Correction - Model Studies on the Mechanism of Botin-Dependent Carboxylations. 2. Site of Protonation vs. CO2 Transfer
Melanie J. Cravey, and Harold Kohn
pp 2143 - 2143; DOI:
10.1021/ja00398a602
PDF
Correction. Varying Selectivities of Triplet Ketones toward p-Cymene: A Measure of the Extent of Charge Transfer in Triplet Exciplexes
Peter J. Wagner, and Allan E. Puchalski
pp 2143 - 2143; DOI:
10.1021/ja00398a603
PDF
Correction. Thermal and Photochemical Smiles Rearrangements of β-(Nitrophenoxy)ethylamines
Gene G. Wubbles, Ann M. Halverson, and Joe D. Oxman
pp 2143 - 2143; DOI:
10.1021/ja00398a604
PDF
Correction. Dogger Bank Itch. The Allergen is (2-Hydroxyethyl)dimethylsulfonium Ion
Jørgen S. Carle, and Carsten Christophersen
pp 2143 - 2143; DOI:
10.1021/ja00398a605
PDF
Correction. Ionization of Aryloxyphosphoranes in Acetonitrile: Rates and Equilibria
Irving S. Sigal, and F. H. Westheimer
pp 2143 - 2143; DOI:
10.1021/ja00398a606
PDF
Correction. BC(DEF) Parameters. 1. The Intrinsic Dimensionality of Intermolecular Interactions in the Liquid State
Richard D. Cramer, III
pp 2143 - 2143; DOI:
10.1021/ja00398a607
PDF
Correction. Catalysis by Multimetallics. Catalyzed Homogeneous Oxidation of Alcohols and Ketones with Molecular Oxygen in the Presence of Hexarhodium Hexadecacarbonyl and Dirhenium Decacarbonyl.
D. Max Roundhill, Mark K. Dickson, Nagaraj S. Dixit, and B. P. Sudha-Dixit
pp 2143 - 2143; DOI:
10.1021/ja00398a608
PDF
Book Reviews

pp 2144 - 2146; DOI:
10.1021/ja00398a609
PDF

Issue 9


Structures and stabilities of isomeric [10]annulenes
Leslie Farnell, James Kao, Leo Radom, and Henry F. Schaefer
pp 2147 - 2151; DOI:
10.1021/ja00399a001
PDF
Molecular mechanics calculations and experimental studies of conformations of .delta.-valerolactone
Thomas Philip, Robert L. Cook, Thomas B. Malloy, Norman L. Allinger, Scott Chang, and Young Yuh
pp 2151 - 2156; DOI:
10.1021/ja00399a002
PDF
Direct measurements of tetraphenylethylene torsional motion by picosecond spectroscopy
P. F. Barbara, S. D. Rand, and P. M. Rentzepis
pp 2156 - 2162; DOI:
10.1021/ja00399a003
PDF
Vibrational studies of (tetraphenylporphyrinato)cobalt(II) and its adducts with carbon monoxide, nitric oxide, and oxygen in gas matrixes
Muneteru Kozuka and Kazuo Nakamoto
pp 2162 - 2168; DOI:
10.1021/ja00399a004
PDF
Proton transfers in hydrogen-bonded systems. 2. Electron correlation effects in diamminehydrogen(1+)
Steve Scheiner and Lawrence B. Harding
pp 2169 - 2173; DOI:
10.1021/ja00399a005
PDF
Gas-phase proton affinities for water, ethylene, and ethane
Diethard K. Bohme and Gervase I. Mackay
pp 2173 - 2175; DOI:
10.1021/ja00399a006
PDF
A theoretical study of the structure and stability of H+(CO)n, H+(N2)n, and H+(O2)n clusters (n = 1-6)
Shinichi Yamabe and Kimihiko Hirao
pp 2176 - 2179; DOI:
10.1021/ja00399a007
PDF
Electronic spectroscopy in condensed media. Monte-Carlo simulation of spectral properties of the aqueous nitrite ion
Ajit Banerjee and Jack Simons
pp 2180 - 2186; DOI:
10.1021/ja00399a008
PDF
360-MHz hydrogen-1 NMR conformational analysis of Gly-Pro-X peptides (X = Ala, Cha, Phe)
Marc J. O. Anteunis, Frans A. M. Borremans, John M. Stewart, and Robert E. London
pp 2187 - 2191; DOI:
10.1021/ja00399a009
PDF
Structure and properties of transition-metal ylide complexes. 2. Organometallic complexes of gold(III)
Judith Stein, John P. Fackler, C. Paparizos, and H. W. Chen
pp 2192 - 2198; DOI:
10.1021/ja00399a010
PDF
The crystal and molecular structure of new tetravalent ruthenium porphyrin. .mu.-Oxo-bis[(octaethylporphinato)ruthenium(IV) hydroxide]
Hideki Masuda, Tooru Taga, Kenji Osaki, Hiroshi Sugimoto, Masayasu Mori, and Hisanobu Ogoshi
pp 2199 - 2203; DOI:
10.1021/ja00399a011
PDF
Preparation and thermal decomposition of pernitric acid (HOONO2) in aqueous media
Richard A. Kenley, Paula L. Trevor, and Bosco Y. Lan
pp 2203 - 2206; DOI:
10.1021/ja00399a012
PDF
Insertion of carbon monoxide into metal-nitrogen bonds. Synthesis, chemistry, structures, and structural dynamics of bis(pentamethylcyclopentadienyl) organoactinide dialkylamides and .eta.2-carbamoyls
Paul J. Fagan, Juan M. Manriquez, Sarah H. Vollmer, Cynthia Secaur Day, Victor W. Day, and Tobin J. Marks
pp 2206 - 2220; DOI:
10.1021/ja00399a013
PDF
Characterization of cationic rhodium isocyanide oligomers in aqueous solutions
I. S. Sigal and Harry B. Gray
pp 2220 - 2225; DOI:
10.1021/ja00399a014
PDF
Hydrogen isotope effects on the excited-state decay properties of polynuclear metal carbonyl hydrides. Emission properties of (dodecacarbonyl)tetrakis(hydrorhenium) and bis(tetrabutylammonium)(dodecacarbonyl)hexahydrotetrarhenate
James L. Graff and Mark S. Wrighton
pp 2225 - 2231; DOI:
10.1021/ja00399a015
PDF
Siderophilin metal coordination. 1. Complexation of thorium by transferrin: structure-function implications
Wesley R. Harris, Carl J. Carrano, Vincent L. Pecoraro, and Kenneth N. Raymond
pp 2231 - 2237; DOI:
10.1021/ja00399a016
PDF
Charge-transfer spectra of iron(II)- and ruthenium(II)-tris(2,2'-bipyridyl) complexes
A. Ceulemans and L. G. Vanquickenborne
pp 2238 - 2241; DOI:
10.1021/ja00399a017
PDF
Organometallic reaction mechanisms. 17. Nature of alkyl transfer in reactions of Grignard reagents with ketones. Evidence for radical intermediates in the formation of 1,2-addition product involving tertiary and primary Grignard reagents
E. C. Ashby and Joseph R. Bowers
pp 2242 - 2250; DOI:
10.1021/ja00399a018
PDF
Synthesis and hydrolysis of hexakis(imidazolyl)cyclotriphosphazene
H. R. Allcock and T. J. Fuller
pp 2250 - 2256; DOI:
10.1021/ja00399a019
PDF
Organometallic phosphazenes: synthesis and rearrangement of propynyl- and propadienylcyclotriphosphazenes
H. R. Allcock, P. J. Harris, and R. A. Nissan
pp 2256 - 2261; DOI:
10.1021/ja00399a020
PDF
Bond fixation in annulenes. 11. Synthesis and absolute configuration of the enantiomeric 1,3-di-tert-butylcyclooctatetraenes. Quantitative kinetic assessment of the effect of nonvicinal tert-butyl groups on [8]annulene ring-inversion and bond-shifting barriers
Leo A. Paquette, Yuji Hanzawa, Kevin J. McCullough, Bruce Tagle, Wendy Swenson, and Jon Clardy
pp 2262 - 2269; DOI:
10.1021/ja00399a021
PDF
Bond fixation in annulenes. 12. Effect of vicinal di-tert-butyl substitution on cyclooctatetraene valence isomerization. 7,8-Di-tert-butylbicyclo[4.2.0]octa-2,4,7-triene
Yuji Hanzawa and Leo A. Paquette
pp 2269 - 2272; DOI:
10.1021/ja00399a022
PDF
Asymmetric synthesis. Asymmetric catalytic hydrogenation using chiral chelating six-membered ring diphosphines
Patricia A. MacNeil, Nicholas K. Roberts, and B. Bosnich
pp 2273 - 2280; DOI:
10.1021/ja00399a023
PDF
Intramolecular electron transfer and dehalogenation of anion radicals. 4. Haloacetophenones and related compounds
D. Behar and P. Neta
pp 2280 - 2283; DOI:
10.1021/ja00399a024
PDF
Thermal valence isomerization of cis-fused bicyclic cyclobutenes. A study of orbital symmetry control
William G. Dauben and Drake M. Michno
pp 2284 - 2292; DOI:
10.1021/ja00399a025
PDF
Phospho-Cope rearrangement of sodium allylvinylphosphinate
David I. Loewus
pp 2292 - 2296; DOI:
10.1021/ja00399a026
PDF
Dynamic stereochemistry of tetra-o-tolylcyclopentadienone
Rudolph Willem, Henri Pepermans, Cornelis Hoogzand, Klaas Hallenga, and Marcel Gielen
pp 2297 - 2306; DOI:
10.1021/ja00399a027
PDF
Adamantane rearrangement of [3.3.2]propellanes
Yoshito Tobe, Kaoru Terashima, Yasuo Sakai, and Yoshinobu Odaira
pp 2307 - 2309; DOI:
10.1021/ja00399a028
PDF
Substituent effects in [2.sigma. + 2.sigma. + 2.sigma.] thermal decarbonylation of cage ketones. Remarkably effective elongation of strained carbon-carbon bond by through-bond coupling
Kazunobu Harano, Takashi Ban, Masami Yasuda, Eiji Osawa, and Ken Kanematsu
pp 2310 - 2317; DOI:
10.1021/ja00399a029
PDF
Palladium(II)-catalyzed asymmetric oxidative cyclization of 2-allylphenols in the presence of copper(II) acetate and molecular oxygen. Study of the catalysis of the Wacker-type oxidation
Takahiro Hosokawa, Tetsuyuki Uno, Shiro Inui, and Shunichi Murahashi
pp 2318 - 2323; DOI:
10.1021/ja00399a030
PDF
Photochemically generated silicon-carbon double-bonded intermediates. 13. The formation and reactions of 1,2-disilacyclobutanes
Mitsuo Ishikawa, Dieter Kovar, Takamasa Fuchikami, Kunio Nishimura, Makoto Kumada, Taiichi Higuchi, and Setsuro Miyamoto
pp 2324 - 2328; DOI:
10.1021/ja00399a031
PDF
Quenching of aromatic ketone phosphorescence by simple alkenes: an Arrhenius study
Utam Maharaj and Mitchell A. Winnik
pp 2328 - 2333; DOI:
10.1021/ja00399a032
PDF
Unimolecular reactions of ionized alkanes
Jens F. Wendelboe, Richard D. Bowen, and Dudley H. Williams
pp 2333 - 2339; DOI:
10.1021/ja00399a033
PDF
Preparation and NMR studies of tetraalkoxyselenuranes and tetraalkoxytelluranes
Donald B. Denney, Dorothy Z. Denney, Philip J. Hammond, and Y. F. Hsu
pp 2340 - 2347; DOI:
10.1021/ja00399a034
PDF
Isolation and characterization of pyrimidine-psoralen photoadducts from DNA
Kenneth Straub, David Kanne, John E. Hearst, and Henry Rapoport
pp 2347 - 2355; DOI:
10.1021/ja00399a035
PDF
Solvolysis of 1-pent-3-ynyl triflate. Mechanism of the homopropargyl rearrangement
Michael Hanack, Clair J. Collins, H. Stutz, and Ben M. Benjamin
pp 2356 - 2360; DOI:
10.1021/ja00399a036
PDF
Product and mechanistic studies of the anodic oxidation of methoxylated naphthalenes. The EECrCp mechanism
Mark G. Dolson and John S. Swenton
pp 2361 - 2371; DOI:
10.1021/ja00399a037
PDF
Nuclear magnetic resonance and conformational energy calculations of repeat peptides of elastin. Conformational characterization of cyclopentadecapeptide cyclo-(L-Val-L-Pro-Gly-L-Val-Gly)3
C. M. Venkatachalam, M. A. Khaled, H. Sugano, and D. W. Urry
pp 2372 - 2379; DOI:
10.1021/ja00399a038
PDF
The role of adsorption in the initial one-electron electrochemical reduction of nicotinamide adenine dinucleotide (NAD+)
William T. Bresnahan and Philip J. Elving
pp 2379 - 2386; DOI:
10.1021/ja00399a039
PDF
Vibrational circular dichroism of six-membered-ring monoterpenes. Consistent force field, fixed partial charge calculations
R. D. Singh and T. A. Keiderling
pp 2387 - 2394; DOI:
10.1021/ja00399a040
PDF
Vibrational circular dichroism of optically active cyclopropanes. Experimental results
V. J. Heintz and T. A. Keiderling
pp 2395 - 2403; DOI:
10.1021/ja00399a041
PDF
Silver-promoted isomerizations of some cyclopropene derivatives
Albert Padwa, Thomas J. Blacklock, and Roman Loza
pp 2404 - 2405; DOI:
10.1021/ja00399a042
PDF
Synthesis of (S)- and (R)-4[(methoxycarbonyl)methyl]-2-azetidinone by chemicoenzymic approach
Masaji Ohno, Susumu Kobayashi, Takamasa Iimori, Yi-Fong Wang, and Toshio Izawa
pp 2405 - 2406; DOI:
10.1021/ja00399a043
PDF
Ph3P-(PyS)2-CH3CN as an excellent condensing system for .beta.-lactam formation from .beta.-amino acids
Susumu Kobayashi, Takamasa Iimori, Toshio Izawa, and Masaji Ohno
pp 2406 - 2408; DOI:
10.1021/ja00399a044
PDF
24-Methyl-25-azacycloartanol, an analog of a carbonium ion high-energy intermediate, is a potent inhibitor of (S)-adenosyl-L-methionine: sterol C-24-methyltransferase in higher plant cells
Acharan S. Narula, Alain Rahier, Pierre Benveniste, and Francis Schuber
pp 2408 - 2409; DOI:
10.1021/ja00399a045
PDF
Total synthesis of 2'-deoxymugineic acid, the metal chelator excreted from wheat root
Yasufumi Ohfune, Masako Tomita, and Kyosuke Nomoto
pp 2409 - 2410; DOI:
10.1021/ja00399a046
PDF
Matrix photolysis of tetracarbonyldihydridoiron. Evidence for oxidative addition of dihydrogen on tetracarbonyliron
Ray L. Sweany
pp 2410 - 2412; DOI:
10.1021/ja00399a047
PDF
Direct evidence for exciplex formation between a triplet alkanone and an alkylbenzene
Therese Wilson and Arthur M. Halpern
pp 2412 - 2413; DOI:
10.1021/ja00399a048
PDF
Carbenic philicity: 6,6-dimethylfulvene as an indicator substrate
Robert A. Moss, Claire M. Young, Leon A. Perez, and Karsten Krogh-Jespersen
pp 2413 - 2415; DOI:
10.1021/ja00399a049
PDF
Heat capacities of activation for displacements at primary and secondary carbon centers in water
Michael Jesse Blandamer, Ross Elmore Robertson, Peter David Golding, Joseph Mark MacNeil, and John Marshall William Scott
pp 2415 - 2416; DOI:
10.1021/ja00399a050
PDF
Neutral products from nucleophilic substitution in the gas phase. Displacement of water from protonated secondary alcohols
David G. Hall, Chakra Gupta, and Thomas Hellman Morton
pp 2416 - 2417; DOI:
10.1021/ja00399a051
PDF
.alpha.-Silylation of lithium ester enolates
Gerald L. Larson and Lelia M. Fuentes
pp 2418 - 2419; DOI:
10.1021/ja00399a052
PDF
Indole alkaloid synthesis via Claisen rearrangement. Total synthesis of secodine
Stanley Raucher, James E. Macdonald, and Ross F. Lawrence
pp 2419 - 2421; DOI:
10.1021/ja00399a053
PDF
Guest-host association by transition-metal complexes containing permanent voids - progress toward models for the ternary complex of cytochrome P450
Kenneth J. Takeuchi, Daryle H. Busch, and Nathanial Alcock
pp 2421 - 2422; DOI:
10.1021/ja00399a054
PDF
Nonstereoselective cyclopropanation of olefins by singlet fluorenylidene
Joseph J. Zupancic, Peter B. Grasse, and Gary B. Schuster
pp 2423 - 2425; DOI:
10.1021/ja00399a055
PDF
Total synthesis of (.+-.)-trihydroxydecipiadiene
Mark L. Greenlee
pp 2425 - 2426; DOI:
10.1021/ja00399a056
PDF
Synthesis of (.+-.)-fomannosin
M. F. Semmelhack and Shuji Tomoda
pp 2427 - 2428; DOI:
10.1021/ja00399a057
PDF
Stereochemical features of the 1,3-chloropalladation of bicyclic methylenecyclopropanes
Paula R. Clemens, Russell P. Hughes, and Lawrence D. Margerum
pp 2428 - 2430; DOI:
10.1021/ja00399a058
PDF
Mixed-metal clusters by metal hydride coupling. Crystal structures of (.mu.-H)Os3Re(CO)15(NCCH3) and (.mu.-H)5Os3Re(CO)12. Direct conversion of a metalloligated cluster to a closed polyhedron
Melvyn Rowen Churchill, Frederick J. Hollander, Romana A. Lashewycz, Gregory A. Pearson, and John R. Shapley
pp 2430 - 2431; DOI:
10.1021/ja00399a059
PDF
.eta.5-Benzyl: crystal structure, nucleophilic properties, and electron-transfer reactions of CpFe(.eta.5-C6Me5CH2), an intermediate in carbon-hydrogen activation by oxygen via O2-
Jean Rene Hamon, Didier Astruc, Enrique Roman, Patrick Batail, and James J. Mayerle
pp 2431 - 2433; DOI:
10.1021/ja00399a060
PDF
Photochemical formation of the ketone tautomer of 3,4-dihydro-9-hydroxy-2(1H)-anthracenone from 2,3-benzospiro[4.5]deca-2,6-diene-1,8-dione
Masaru Kimura and Shiro Morosawa
pp 2433 - 2434; DOI:
10.1021/ja00399a061
PDF
Total synthesis of racemic siccanin
Michiharu Kato, Kiyoshi Heima, Yukio Matsumura, and Akira Yoshikoshi
pp 2434 - 2435; DOI:
10.1021/ja00399a062
PDF
Nonplanar alkenes and carbonyls: a molecular distortion which parallels addition stereoselectivity
Nelson G. Rondan, Michael N. Paddon-Row, Pierluigi Caramella, and K. N. Houk
pp 2436 - 2438; DOI:
10.1021/ja00399a063
PDF
Origin of .pi.-facial stereoselectivity in additions to .pi.-bonds: generality of the anti-periplanar effect
Pierluigi Caramella, Nelson G. Rondan, Michael N. Paddon-Row, and K. N. Houk
pp 2438 - 2440; DOI:
10.1021/ja00399a064
PDF
Superconductivity in an organic solid. Synthesis, structure, and conductivity of bis(tetramethyltetraselenafulvalenium) perchlorate, (TMTSF)2ClO4
K. Bechgaard, K. Carneiro, F. B. Rasmussen, M. Olsen, G. Rindorf, C. S. Jacobsen, H. J. Pedersen, and J. C. Scott
pp 2440 - 2442; DOI:
10.1021/ja00399a065
PDF
Degree of charge transfer in organic conductors by infrared absorption spectroscopy
J. S. Chappell, A. N. Bloch, W. A. Bryden, M. Maxfield, T. O. Poehler, and D. O. Cowan
pp 2442 - 2443; DOI:
10.1021/ja00399a066
PDF
Stereoselective synthesis of cyclopentene derivatives from 1,3-dienes
Rick L. Danheiser, Carlos Martinez-Davila, Richard J. Auchus, and James T. Kadonaga
pp 2443 - 2446; DOI:
10.1021/ja00399a067
PDF
Efficient, stereoselective total synthesis of (.+-.)-aphidicolin
Robert E. Ireland, Jollie D. Godfrey, and Suvit Thaisrivongs
pp 2446 - 2448; DOI:
10.1021/ja00399a068
PDF
Hydridometallacycloalkane complexes of iridium. Unassisted intramolecular distal carbon-hydrogen bond activation
T. H. Tulip and D. L. Thorn
pp 2448 - 2450; DOI:
10.1021/ja00399a069
PDF
The "pocket" porphyrin: a hemoprotein model with lowered carbon monoxide affinity
James P. Collman, John I. Brauman, Terrence J. Collins, Brent Iverson, and Jonathan L. Sessler
pp 2450 - 2452; DOI:
10.1021/ja00399a070
PDF
Theoretical challenge to the experimentally determined geometrical structure of dimethylsilaethylene
Yasunori Yoshioka, John D. Goddard, and Henry F. Schaefer
pp 2452 - 2453; DOI:
10.1021/ja00399a071
PDF
Metal vapor microsolution optical spectroscopy
Geoffrey A. Ozin, Colin G. Francis, Helmut X. Huber, Mark Andrews, and Linda Nazar
pp 2453 - 2456; DOI:
10.1021/ja00399a072
PDF
Ru5(CO)13(C.tplbond.CPh)(PPh2): a square pyramidal ruthenium cluster with a single .mu.4-bound acetylide
Arthur J. Carty, Shane A. MacLaughlin, and Nicholas J. Taylor
pp 2456 - 2457; DOI:
10.1021/ja00399a073
PDF
Large, inverse solvent isotope effects: a simple test for the E1cB mechanism
James R. Keeffe and William P. Jencks
pp 2457 - 2459; DOI:
10.1021/ja00399a074
PDF
Asymmetric synthesis of .alpha.-amino acids using chiral cobalt(III) complexes
Masanobu Ajioka, Shigenobu Yano, Kenichi Matsuda, and Sadao Yoshikawa
pp 2459 - 2460; DOI:
10.1021/ja00399a075
PDF
Observation of an unprecedented heavy-atom effect on the rate of 1n,.pi. in a .beta.,.gamma.-unsaturated ketone
Lidia T. Calcaterra and David I. Schuster
pp 2460 - 2461; DOI:
10.1021/ja00399a076
PDF
Modeling heterogeneous catalysts with homogeneous catalysts. Comparison of catalytic exchange of deuterium for hydrogen at the .alpha. and .beta. positions of tertiary amines by using either palladium black or dodecacarbonyltriruthenium
Y. Shvo, D. W. Thomas, and R. M. Laine
pp 2461 - 2463; DOI:
10.1021/ja00399a077
PDF
Stabilization of .alpha.-keto cations by carbonyl conjugation
Xavier Creary
pp 2463 - 2465; DOI:
10.1021/ja00399a078
PDF
Syntheses of trifluoromethylated thiadiphosphanorbornadiene and thiadiphosphole
Yoshiro Kobayashi, Shomi Fujino, and Itsumaro Kumadaki
pp 2465 - 2466; DOI:
10.1021/ja00399a079
PDF
Reversible, nitrogen-assisted migration of a phenyl group from phosphorus to iron in CpFe(CO)[PhP(OCH2CH2)2NH]+PF6-
Pierre Vierling, Jean G. Riess, and Andre Grand
pp 2466 - 2467; DOI:
10.1021/ja00399a080
PDF
Acanthifolicin, a new episulfide-containing polyether carboxylic acid from extracts of the marine sponge Pandaros acanthifolium
Francis J. Schmitz, Ravi S. Prasad, Yalamanchili Gopichand, M. Bilayet Hossain, Dick Van der Helm, and Paul Schmidt
pp 2467 - 2469; DOI:
10.1021/ja00399a081
PDF
Okadaic acid, a cytotoxic polyether from two marine sponges of the genus Halichondria
Kazuo Tachibana, Paul J. Scheuer, Yasumasa Tsukitani, Hiroyuki Kikuchi, Donna Van Engen, Jon Clardy, Yalamanchili Gopichand, and Francis J. Schmitz
pp 2469 - 2471; DOI:
10.1021/ja00399a082
PDF
Aspects of homogeneous carbon monoxide fixation: selective conversion of two carbonyl ligands on (.eta.5-C5H5)Fe(CO)3+ to C2 organic compounds
Thomas Bodnar, Gene Coman, Stephen LaCroce, Carol Lambert, Kevin Menard, and Alan Cutler
pp 2471 - 2472; DOI:
10.1021/ja00399a083
PDF
Thermolysis of 2-methoxy-2,5,5-trimethyl-.DELTA.3-1,3,4-oxadiazoline. Carbenes from thermal fragmentation of a carbonyl ylide intermediate
Michel Bekhazi and John Warkentin
pp 2473 - 2474; DOI:
10.1021/ja00399a084
PDF
Biosynthesis of macrolide antibiotics. 3. Regiochemistry of isotopic hydrogen labeling of brefeldin A by acetate
C. Richard Hutchinson, Itsuo Kurobane, Clayton T. Mabuni, Robert W. Kumola, A. Gavin McInnes, and John A. Walter
pp 2474 - 2477; DOI:
10.1021/ja00399a085
PDF
Biosynthesis of macrolide antibiotics. 4. Stereochemistry of hydrogen labeling of brefeldin A by [2-2H3]acetate
C. Richard Hutchinson, Itsuo Kurobane, David E. Cane, Heinz Hasler, and A. G. McInnes
pp 2477 - 2480; DOI:
10.1021/ja00399a086
PDF
Naked-metal clusters in solution. 4. Indications of the variety of cluster species obtainable by extraction of Zintl phases: Sn42-, TlSn85-, Sn9-xGex4- (x = 0-9), and SnTe44-
Ralph W. Rudolph, William L. Wilson, and R. Craig Taylor
pp 2480 - 2481; DOI:
10.1021/ja00399a087
PDF
Prediction of fluxional behavior for Sn42- in solution
Michael J. Rothman, Lawrence S. Bartell, and Lawrence L. Lohr
pp 2482 - 2483; DOI:
10.1021/ja00399a088
PDF
Azidomethyl phenyl sulfide. A synthon for NH2
Barry M. Trost and William H. Pearson
pp 2483 - 2485; DOI:
10.1021/ja00399a089
PDF
Stereo- and regiochemistry of a palladium-catalyzed oxygen to carbon migration
Barry M. Trost and Thomas A. Runge
pp 2485 - 2487; DOI:
10.1021/ja00399a090
PDF
Methane-producing hydrogenolysis of (.eta.5-cyclopentadienyl)(triphenylphosphine)dimethylcobalt(III). An autocatalytic mechanism involving a binuclear metal dihydride/metal dialkyl reaction as a critical step
Andrew H. Janowicz and Robert G. Bergman
pp 2488 - 2489; DOI:
10.1021/ja00399a091
PDF
Synthesis and reactions of a binuclear cobalt bridging methylene (.mu.-CH2) complex. Conversion to .mu.-CH2 rhodium/cobalt and rhodium/rhodium complexes and methylene transfer to ethylene involving activation by a second metal complex
Klaus H. Theopold and Robert G. Bergman
pp 2489 - 2491; DOI:
10.1021/ja00399a092
PDF
Structure of palytoxin
Richard E. Moore and Giovanni Bartolini
pp 2491 - 2494; DOI:
10.1021/ja00399a093
PDF
Transient Raman observation of quinoxaline aqueous protonation kinetics
S. M. Beck and L. E. Brus
pp 2495 - 2496; DOI:
10.1021/ja00399a094
PDF
Anomalous cycloaddition reactions of distorted cyclohexa-1,4-dienes. Cycloaddition of N-phenyltriazolinedione to (i,o)-bicyclo[n.2.2]alkadienes
Paul G. Gassman and Rebecca C. Hoye
pp 2496 - 2498; DOI:
10.1021/ja00399a095
PDF
Synthesis, structure, and reactivity of the (i,o)-diazabicyclo[n.2.2]alkene skeleton. Extremely facile cleavage of a carbon-nitrogen bond
Paul G. Gassman and Rebecca C. Hoye
pp 2498 - 2500; DOI:
10.1021/ja00399a096
PDF
Book Reviews

pp 2501 - 2502; DOI:
10.1021/ja00399a600
PDF

Issue 10


An INDO MO study of conformational and substituent effects upon vicinal fluorine-19-carbon-13 coupling constants
Victor Wray
pp 2503 - 2507; DOI:
10.1021/ja00400a001
PDF
Aspects of artificial photosynthesis. Photosensitized electron transfer across bilayers, charge separation, and hydrogen production in anionic surfactant vesicles
Mohammad S. Tunuli and Janos H. Fendler
pp 2507 - 2513; DOI:
10.1021/ja00400a002
PDF
Solid state disproportionation enthalpies
Gerald R. Stevenson and Steven S. Zigler
pp 2513 - 2515; DOI:
10.1021/ja00400a003
PDF
Study of the photolysis of dimethyl-s-tetrazine using a holographic technique
C. Braeuchle, D. M. Burland, and G. C. Bjorklund
pp 2515 - 2519; DOI:
10.1021/ja00400a004
PDF
Free-energy relationships for reversible and irreversible electron-transfer processes
Franco Scandola, Vincenzo Balzani, and Gary B. Schuster
pp 2519 - 2523; DOI:
10.1021/ja00400a005
PDF
Diffractive spectroelectrochemistry. Use of diffracted light for monitoring electrogenerated chromophores
Paula Rossi, C. William McCurdy, and Richard L. McCreery
pp 2524 - 2529; DOI:
10.1021/ja00400a006
PDF
Two-dimensional rotational spin-echo nuclear magnetic resonance in solids: correlation of chemical shift and dipolar interactions
M. G. Munowitz, R. G. Griffin, G. Bodenhausen, and T. H. Huang
pp 2529 - 2533; DOI:
10.1021/ja00400a007
PDF
Determination of bond distances and bond angles by solid-state nuclear magnetic resonance. Carbon-13 and nitrogen-14 NMR study of glycine
R. A. Haberkorn, R. E. Stark, H. Van Willigen, and R. G. Griffin
pp 2534 - 2539; DOI:
10.1021/ja00400a008
PDF
Pattern of hydroxyl radical addition to uracil and methyl- and carboxyl-substituted uracils. Electron transfer of hydroxyl adducts with N,N,N',N'-tetramethyl-p-phenylenediamine and tetranitromethane
S. Fujita and S. Steenken
pp 2540 - 2545; DOI:
10.1021/ja00400a009
PDF
Substituent effects in hydroboration: reaction pathways for the Markownikoff and anti-Markownikoff addition of borane to propylene and cyanoethylene
Glenn D. Graham, Steven C. Freilich, and William N. Lipscomb
pp 2546 - 2552; DOI:
10.1021/ja00400a010
PDF
Electrochemical responses of electrodes coated with redox polymers. Evidence for control of charge-transfer rates across polymeric layers by electron exchange between incorporated redox sites
Kiyotaka Shigehara, Noboru Oyama, and Fred C. Anson
pp 2552 - 2558; DOI:
10.1021/ja00400a011
PDF
Theoretical study of concerted vs. stepwise fragmentation of 2-carbena-1,3-dioxolane
David Feller, Ernest R. Davidson, and Weston Thatcher Borden
pp 2558 - 2560; DOI:
10.1021/ja00400a012
PDF
Microwave spectrum, structure, and dipole moment of sulfuric acid
Robert L. Kuczkowski, R. D. Suenram, and Frank J. Lovas
pp 2561 - 2566; DOI:
10.1021/ja00400a013
PDF
1-Iodoacetylenes. 1. Spectroscopic evidence of their complexes with Lewis bases. A spectroscopic scale of soft basicity
C. Laurence, M. Queignec-Cabanetos, T. Dziembowska, R. Queignec, and B. Wojtkowiak
pp 2567 - 2573; DOI:
10.1021/ja00400a014
PDF
The role of collision complexes in the reaction of silyl ions with ethylene
R. N. Abernathy and F. W. Lampe
pp 2573 - 2578; DOI:
10.1021/ja00400a015
PDF
Infrared spectrum of the primary ozonide of ethylene in solid xenon
Christopher K. Kohlmiller and Lester Andrews
pp 2578 - 2583; DOI:
10.1021/ja00400a016
PDF
Secondary ion mass spectra of coordination compounds and organometallics
Janelle Pierce, Kenneth L. Busch, R. A. Walton, and R. G. Cooks
pp 2583 - 2588; DOI:
10.1021/ja00400a017
PDF
Aromaticity in small rings containing boron and carbon, ((CH)2(BH)n, n = 1,2): comarisons with isoelectronic carbocations. The decisive roles of orbital mixing and nonbonded 1,3-interactions in the structures of four-membered rings
K. Krogh-Jespersen, D. Cremer, J. D. Dill, J. A. Pople, and P. R. Schleyer
pp 2589 - 2594; DOI:
10.1021/ja00400a018
PDF
Nickelacyclopentane complexes. A theoretical investigation
Ronald J. McKinney, David L. Thorn, Roald Hoffmann, and Armel Stockis
pp 2595 - 2603; DOI:
10.1021/ja00400a019
PDF
Thermochromic phase transitions in copper(II) halide salts. 1. Crystal structure and magnetic resonance studies of isopropylammonium trichlorocuprate(II)
S. A. Roberts, D. R. Bloomquist, R. D. Willett, and H. W. Dodgen
pp 2603 - 2610; DOI:
10.1021/ja00400a020
PDF
Thermochromism in copper(II) halide salts. 2. Bis(isopropylammonium) tetrachlorocuprate(II)
Darrel R. Bloomquist, Roger D. Willett, and Harold W. Dodgen
pp 2610 - 2615; DOI:
10.1021/ja00400a021
PDF
Thermochromism in copper halide salts. 3. Isopropylammonium tribromocuprate(II)
Darrel R. Bloomquist and Roger D. Willett
pp 2615 - 2619; DOI:
10.1021/ja00400a022
PDF
The preparation and characterization of several meso-tetracarboranylporphyrins
R. C. Haushalter, W. M. Butler, and R. W. Rudolph
pp 2620 - 2627; DOI:
10.1021/ja00400a023
PDF
Heteroatomic polyanions of post-transition metals. Synthesis and structure of dithalliumditellurium(2-), Tl2Te22-. Skeletal requirements for bonding
Robert C. Burns and John D. Corbett
pp 2627 - 2632; DOI:
10.1021/ja00400a024
PDF
Structure and g tensor orientation of the (tetraphenylporphyrinato)iron(III) bis(benzenethiolate) anion
Marianne P. Byrn and Charles E. Strouse
pp 2633 - 2635; DOI:
10.1021/ja00400a025
PDF
Linear to bent geometry changes in the gas- and solution-phase photochemistry of tricarbonylnitrosylcobalt
Wayne Evans and Jeffrey I. Zink
pp 2635 - 2640; DOI:
10.1021/ja00400a026
PDF
Imidazolate- and oxo-bridged metalloporphyrins
John T. Landrum, David Grimmett, Kenneth J. Haller, W. Robert Scheidt, and Christopher A. Reed
pp 2640 - 2650; DOI:
10.1021/ja00400a027
PDF
Migratory insertion reactions of carbenes. Kinetics and mechanism of migratory insertion reactions of zirconoxy carbene complexes of niobocene hydride and alkyls
Richard S. Threlkel and John E. Bercaw
pp 2650 - 2659; DOI:
10.1021/ja00400a028
PDF
Hydrogen-evolving systems. 4. The reduction of molecular nitrogen and of other substrates in the vanadium(II)-pyrocatechol system
Gerhard N. Schrauzer and Miles R. Palmer
pp 2659 - 2667; DOI:
10.1021/ja00400a029
PDF
Ferric ion sequestering agents. 6. The spectrophotometric and potentiometric evaluation of sulfonated tricatecholate ligands
Wesley R. Harris, Kenneth N. Raymond, and Frederick L. Weitl
pp 2667 - 2675; DOI:
10.1021/ja00400a030
PDF
Electron-rich carboranes. Studies of a stereochemically novel system, (CH3)4C4B7H9, an 11-vertex arachno cluster
David C. Finster and Russell N. Grimes
pp 2675 - 2683; DOI:
10.1021/ja00400a031
PDF
Excited states of mixed-ligand chelates of ruthenium(II). Quantum yield and decay time measurements
W. H. Elfring and G. A. Crosby
pp 2683 - 2687; DOI:
10.1021/ja00400a032
PDF
Preparation of zirconium(II) complexes by ligand-induced reductive elimination. Bis(.eta.5-cyclopentadienyl)bis(phosphine)zirconium(II) complexes and their reactions
Kerrie I. Gell and Jeffrey Schwartz
pp 2687 - 2695; DOI:
10.1021/ja00400a033
PDF
Detailed mechanism of thermal hydrogen migration in cyclohexadieneiron tricarbonyl
Karin J. Karel, M. Brookhart, and R. Aumann
pp 2695 - 2698; DOI:
10.1021/ja00400a034
PDF
Homogeneous catalysis of the water gas shift reaction with the use of Group 6 transition metal carbonyls: hexacarbonylchromium, hexacarbonylmolybdenum, and hexacarbonyltungsten
A. D. King, R. B. King, and D. B. Yang
pp 2699 - 2704; DOI:
10.1021/ja00400a035
PDF
Reactions of iron porphyrins with methyl radicals
D. Brault and P. Neta
pp 2705 - 2710; DOI:
10.1021/ja00400a036
PDF
Stable monocyclic monoalkoxyhalophosphoranes: possible examples of structures on the borderline between haloalkoxyphosphoranes and alkoxyphosphonium halides
Itshak Granoth and J. C. Martin
pp 2711 - 2715; DOI:
10.1021/ja00400a037
PDF
Synthesis of 2,5-dihydrotellurophene - a new heterocyclic compound
Jan Bergman and Lars Engman
pp 2715 - 2718; DOI:
10.1021/ja00400a038
PDF
Synthesis of megaphone
George Buechi and Ping-Sun Chu
pp 2718 - 2721; DOI:
10.1021/ja00400a039
PDF
Kinetics and mechanism of the oxidation of (.alpha.-hydroxyalkyl)chromium complexes by copper(II) and iron(III) ions
Andreja Bakac and James H. Espenson
pp 2721 - 2728; DOI:
10.1021/ja00400a040
PDF
Concurrent electrophilic and oxidative pathways for reactions of .alpha.-hydroxyalkyl and .alpha.-alkoxyalkyl complexes of chromium(III) with mercury(II) ions
James H. Espenson and Andreja Bakac
pp 2728 - 2733; DOI:
10.1021/ja00400a041
PDF
Mechanism of the hydroxyl radical induced oxidation of methionine in aqueous solution
K. O. Hiller, B. Masloch, M. Goebl, and K. D. Asmus
pp 2734 - 2743; DOI:
10.1021/ja00400a042
PDF
Intramolecular diyl trapping. Total synthesis of dl-hirsutene
R. Daniel Little and George W. Muller
pp 2744 - 2749; DOI:
10.1021/ja00400a043
PDF
General-base catalysis of the hydrolysis of p-nitrophenyl carboxylates by micellar surfactants involving a histidyl residue
Yukito Murakami, Akio Nakano, Akira Yoshimatsu, and Kiyoshi Matsumoto
pp 2750 - 2756; DOI:
10.1021/ja00400a044
PDF
New molecular rearrangement of 1,3-oxathioles via thiocarbonyl ylides
Kitaro Oka, Akira Dobashi, and Shoji Hara
pp 2757 - 2759; DOI:
10.1021/ja00400a045
PDF
Thermolysis of thiophenedicarboxylic acid anhydrides as a route to five-membered hetarynes
Manfred G. Reinecke, James G. Newsom, and Lao-Jer Chen
pp 2760 - 2769; DOI:
10.1021/ja00400a046
PDF
Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: experimental and computational evidence for the formation of stable .alpha.-arylvinyl cations both by direct means and by spontaneous exothermic isomerization of unstable isomeric ions
Yitzhak Apeloig, Wilfried Franke, Zvi Rappoport, Helmut Schwarz, and Daniel Stahl
pp 2770 - 2780; DOI:
10.1021/ja00400a047
PDF
Template effects. 3. The quantitative determination of the catalytic effects of alkali and alkaline earth cations in the formation of benzo-18-crown-6 in methanol solution
Gianfranco Ercolani, Luigi Mandolini, and Bernardo Masci
pp 2780 - 2782; DOI:
10.1021/ja00400a048
PDF
Electrophilic additions to olefins. A new approach to unifying the mechanisms of bromination and oxymercuration
S. Fukuzumi and J. K. Kochi
pp 2783 - 2791; DOI:
10.1021/ja00400a049
PDF
Gas-phase binding energies and spectroscopic properties of nitrosyl(1+) charge-transfer complexes
W. D. Reents and B. S. Freiser
pp 2791 - 2797; DOI:
10.1021/ja00400a050
PDF
Redox chemistry of N5-ethyl-3-methyllumiflavinium cation and N5-ethyl-4a-hydroperoxy-3-methyllumiflavin in dimethylformamide. Evidence for the formation of the N5-ethyl-4a-hydroperoxy-3-methyllumiflavin anion via radical-radical coupling with superoxide ion
Edward J. Nanni, Donald T. Sawyer, Sheldon S. Ball, and Thomas C. Bruice
pp 2797 - 2802; DOI:
10.1021/ja00400a051
PDF
Experimental and theoretical investigation of the mechanism of deoxygenation of carbonyl compounds by atomic carbon
Michael J. S. Dewar, Donna J. Nelson, Philip B. Shevlin, and Keith A. Biesiada
pp 2802 - 2807; DOI:
10.1021/ja00400a052
PDF
Thermal rearrangements of propargylic trichloroacetimidates. Synthesis of (trichloroacetamido)-1,3-dienes and -1,2-dienes
Larry E. Overman, Lane A. Clizbe, Robert L. Freerks, and Charles K. Marlowe
pp 2807 - 2815; DOI:
10.1021/ja00400a053
PDF
Diels-Alder reactions of 1-(acylamino)-1,3-dienes
Larry E. Overman, Robert L. Freerks, C. Bruce Petty, Lane A. Clizbe, Robert K. Ono, Garry F. Taylor, and Peter J. Jessup
pp 2816 - 2822; DOI:
10.1021/ja00400a054
PDF
Low-temperature characterization of the intermediates in the Wittig reaction
E. Vedejs, G. P. Meier, and K. A. J. Snoble
pp 2823 - 2831; DOI:
10.1021/ja00400a055
PDF
Electron spin resonance characterization of radicals from 3,4-dihydroxyphenylalanine: semiquinone anions and their metal chelates
C. C. Felix and R. C. Sealy
pp 2831 - 2836; DOI:
10.1021/ja00400a056
PDF
Nuclear magnetic resonance studies of the complexation of trimethyllead by glutathione in aqueous solution and in intact human erythrocytes
Dallas L. Rabenstein, Stanley J. Backs, and Anvarhusein A. Isab
pp 2836 - 2841; DOI:
10.1021/ja00400a057
PDF
Magnetic resonance studies of cyanide and fluoride binding to galactose oxidase copper(II): evidence for two exogenous ligand sites
Beverly J. Marwedel, Daniel J. Kosman, Robert D. Bereman, and Robert J. Kurland
pp 2842 - 2847; DOI:
10.1021/ja00400a058
PDF
Electron paramagnetic resonance study of nitrosylhemoglobin and its chemistry in single crystals
D. C. Doetschman and S. G. Utterback
pp 2847 - 2852; DOI:
10.1021/ja00400a059
PDF
Simple molecular orbital explanation for "bay-region" carcinogenic reactivity
John P. Lowe and B. D. Silverman
pp 2852 - 2855; DOI:
10.1021/ja00400a060
PDF
Lanthanide ion luminescence probes. Measurement of distance between intrinsic protein fluorophores and bound metal ions: quantitation of energy transfer between tryptophan and terbium(III) or europium(III) in the calcium-binding protein parvalbumin
William DeW. Horrocks and William E. Collier
pp 2856 - 2862; DOI:
10.1021/ja00400a061
PDF
Crystallographic assessment of absolute configuration in 2'-deoxyadenosine cyclic 3',5'-(Rp)-phosphoranilidate. Direct phosphorus-31-nitrogen-15 spin-spin coupling as a probe for configurational assessment
Zbigniew J. Lesnikowski, Wojciech J. Stec, Wojciech S. Zielinski, Dorota Adamiak, and Wolfram Saenger
pp 2862 - 2863; DOI:
10.1021/ja00400a062
PDF
Molecular structure of 10-bromo-1,6-methano-2-aza[10]annulene
Riccardo Destro, Massimo Simonetta, and Emanuel Vogel
pp 2863 - 2865; DOI:
10.1021/ja00400a063
PDF
Definitive theoretical evidence for the nonplanarity of the hydronium ion (H3O+)
William R. Rodwell and Leo Radom
pp 2865 - 2866; DOI:
10.1021/ja00400a064
PDF
Triplet GpCpA forms a stable RNA duplex
D. Alkema, R. A. Bell, P. A. Hader, and T. Neilson
pp 2866 - 2868; DOI:
10.1021/ja00400a065
PDF
Synthesis of a thiacyclopentyne
John M. Bolster and Richard M. Kellogg
pp 2868 - 2869; DOI:
10.1021/ja00400a066
PDF
One-electron electrochemical reduction of a ferrous porphyrin dioxygen complex
Curtis H. Welborn, David Dolphin, and Brian R. James
pp 2869 - 2871; DOI:
10.1021/ja00400a067
PDF
Biosynthesis of streptothricin F. 1. Observing the interaction of primary and secondary metabolism with [1,2-13C2]acetate
Steven J. Gould, Kazys J. Martinkus, and Chou-Hong Tann
pp 2871 - 2872; DOI:
10.1021/ja00400a068
PDF
Biosynthetic studies of nocardicin A
Craig A. Townsend and Alethia M. Brown
pp 2873 - 2874; DOI:
10.1021/ja00400a069
PDF
Trapping and chirality as evidence for an allene structure for 2,3,6-bicyclo[3.2.1]octatriene
Metin Balci and William M. Jones
pp 2874 - 2876; DOI:
10.1021/ja00400a070
PDF
Enantioselective aldol condensations. 3. Erythro-selective condensations via zirconium enolates
D. A. Evans and L. R. McGee
pp 2876 - 2878; DOI:
10.1021/ja00400a071
PDF
Electronic states of 2-methylenecyclopentane-1,3-diyl and trimethylenemethane
David A. Dixon, Thom H. Dunning, Robert A. Eades, and Daniel A. Kleier
pp 2878 - 2880; DOI:
10.1021/ja00400a072
PDF
Metal-metal bonded complexes of the early transition metals. 2. Synthesis of quadruply bonded tungsten(II) trifluoroacetate complexes
A. P. Sattelberger, K. W. McLaughlin, and John C. Huffman
pp 2880 - 2882; DOI:
10.1021/ja00400a073
PDF
Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes
Hajime Matsushita and Eiichi Negishi
pp 2882 - 2884; DOI:
10.1021/ja00400a074
PDF
High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450
John T. Groves, Robert C. Haushalter, Mikio Nakamura, Thomas E. Nemo, and B. J. Evans
pp 2884 - 2886; DOI:
10.1021/ja00400a075
PDF
High asymmetric induction during organometallic .beta.-addition to .alpha.,.beta.-ethylenic sulfoxides. Synthesis of optically active .beta.-alkylcarboxylic acids, .beta.-substituted cyclopentanones, and steroidal 11-oxoequilenin methyl ether
Gary H. Posner, John P. Mallamo, and Kyo Miura
pp 2886 - 2888; DOI:
10.1021/ja00400a076
PDF
Electronic states of iron oxyporphyrin and verdohemochrome obtained by coupled oxidation of iron porphyrin
Seiyo Sano, Yukio Sugiura, Yutaka Maeda, Satoshi Ogawa, and Isao Morishima
pp 2888 - 2890; DOI:
10.1021/ja00400a077
PDF
First total synthesis of (+)-chenodeoxycholic acid
Tetsuji Kametani, Koji Suzuki, and Hideo Nemoto
pp 2890 - 2891; DOI:
10.1021/ja00400a078
PDF
Transition state of oxidative addition reaction: Pt(PH3)2 + H2 .fwdarw. Pt(H)2(PH3)2
Kazuo Kitaura, Shigeru Obara, and Keiji Morokuma
pp 2891 - 2892; DOI:
10.1021/ja00400a079
PDF
Chemical modification of deoxyribonucleic acids: a direct study by NMR spectroscopy
Ching-Jer Chang, Jose DaSilva Gomes, and Stephen R. Byrn
pp 2892 - 2894; DOI:
10.1021/ja00400a080
PDF
Transition-metal nitro-nitrosyl redox couple: catalytic oxidation of olefins to ketones
Mark A. Andrews and Kevin P. Kelly
pp 2894 - 2896; DOI:
10.1021/ja00400a081
PDF
Thermochemistry and unimolecular reactions of ionized 1,2-dimesityl-2-phenylethanone and 2,2-dimesityl-1-phenylethanone and their enols and enol acetates in the gas phase
Silvio E. Biali, Chava Lifshitz, Zvi Rappoport, Miriam Karni, and Asher Mandelbaum
pp 2896 - 2897; DOI:
10.1021/ja00400a082
PDF
Proton-coupled electron transfer between [Ru(bpy)2(py)OH2]2+ and [Ru(bpy)2(py)O]2+. A solvent isotope effect (kH2O/kD2O) of 16.1
Robert A. Binstead, Bruce A. Moyer, George J. Samuels, and Thomas J. Meyer
pp 2897 - 2899; DOI:
10.1021/ja00400a083
PDF
An iron(III)-porphyrin complex with a vinylidene group inserted into an iron-nitrogen bond: relevance to the structure of the active oxygen complex of catalase
Bernard Chevrier, Raymond Weiss, Marc Lange, Jean Claude Chottard, and Daniel Mansuy
pp 2899 - 2901; DOI:
10.1021/ja00400a084
PDF
Site symmetry and the framework group
R. L. Flurry
pp 2901 - 2902; DOI:
10.1021/ja00400a085
PDF
Radical anion of 1,1-difluoroethylene. EPR evidence for a perpendicular geometry
Jih Tzong Wang and Ffrancon Williams
pp 2902 - 2904; DOI:
10.1021/ja00400a086
PDF
Condensation of enolates with hexachlorobutadiene
Andrew S. Kende, Pawel Fludzinski, and John H. Hill
pp 2904 - 2905; DOI:
10.1021/ja00400a087
PDF
Selective functionalization of doubly coordinated flexible chains
Ronald Breslow, Raghavan Rajagopalan, and Joshua Schwarz
pp 2905 - 2907; DOI:
10.1021/ja00400a088
PDF
New stereospecific approach to steroid side chains: conversion of dehydroepiandrosterone to cholesterol, isocholesterol, and their 15.beta.-hydroxy derivatives
J. P. Marino and Hiroyuki Abe
pp 2907 - 2909; DOI:
10.1021/ja00400a089
PDF
Additions and Corrections - Studies on the Reaction Mechanism of the Photocyclization of N-Aryl Enamines. Dependence of Quantum Yields on Back and Side Reacitons
Thomas Wolff, and Reinhart Waffenschmidt
pp 2909 - 2909; DOI:
10.1021/ja00400a600
PDF
Additions and Corrections - Synthesis of β-Lactams from Substituted Hydroxamic Acids
M. J. Miller, P. G. Mattingly, M. A, Morrison, and J. F. Kerwin, Jr.
pp 2909 - 2909; DOI:
10.1021/ja00400a601
PDF
Additions and Corrections - 15N Nuclear Magnetic Resonance Spectroscopy. Products and Rearrangements in the Reaction of p-Toluenesulfonyl Azide-3-15N with the Sodium Salt of p-Toluenesulfonamide. An in Situ 15N
Carla Casewit, and J. D. Roberts
pp 2909 - 2909; DOI:
10.1021/ja00400a602
PDF
Additions and Corrections - A C11H11 Cation of Unusual Structure
M. J. Goldstein, and Stanley A. Kline
pp 2910 - 2910; DOI:
10.1021/ja00400a603
PDF
Additions and Corrections - Electronic Control of Stereoselectivity. 4. Effects of Neighboring Fused Bicyclic Frameworks on the Stereochemical Outcome of Diels-Alder Cycloadditions to Cyclopentadiene Rings
Michael C. Bohm, Richard V. C. Carr, Rolf Gleiter, and Leo A. Paquette
pp 2910 - 2910; DOI:
10.1021/ja00400a604
PDF
Book Reviews

pp 2910 - 2912; DOI:
10.1021/ja00400a605
PDF

Issue 11


Carbon-13 dipolar spectroscopy of small organic molecules in argon matrixes
Kurt W. Zilm and David M. Grant
pp 2913 - 2922; DOI:
10.1021/ja00401a001
PDF
Ultrafine and specific catalysts affording efficient hydrogen evolution from water under visible light illumination
Pierre Alain Brugger, Pierre Cuendet, and Michael Graetzel
pp 2923 - 2927; DOI:
10.1021/ja00401a002
PDF
Effects of outer-sphere electron transfer on the vibrational spectrum of dicesium antimony hexachloride
H. W. Clark and Basil I. Swanson
pp 2928 - 2933; DOI:
10.1021/ja00401a003
PDF
Temperature effect on the vapor phase fluorescence in cyano-substituted anthracenes. Reconsideration of the S1-Tn energy gap
Satoshi Hirayama
pp 2934 - 2938; DOI:
10.1021/ja00401a004
PDF
Relative stability of multiple bonds to silicon: an ab initio study of C2SiH4 isomers
Mark S. Gordon and Robert D. Koob
pp 2939 - 2944; DOI:
10.1021/ja00401a005
PDF
Structure and stability of a silicon-carbon triple bond
Mark S. Gordon and John A. Pople
pp 2945 - 2947; DOI:
10.1021/ja00401a006
PDF
Sensitivity of polypeptide conformation to geometry. Theoretical conformational analysis of oligomers of .alpha.-aminoisobutyric acid
Yvonne Paterson, Shirley M. Rumsey, Ettore Benedetti, George Nemethy, and Harold A. Scheraga
pp 2947 - 2955; DOI:
10.1021/ja00401a007
PDF
Theoretical calculations on proton-transfer energetics: studies of methanol, imidazole, formic acid, and methaneethiol as models for the serine and cysteine proteases
Peter A. Kollman and David M. Hayes
pp 2955 - 2961; DOI:
10.1021/ja00401a008
PDF
Complete microwave structure and electron distribution for spiro[2.4]hepta-4,6-diene
Marlin D. Harmony, S. N. Mathur, Jong-In Choe, Mano Kattija-Ari, Allison E. Howard, and Stuart W. Staley
pp 2961 - 2966; DOI:
10.1021/ja00401a009
PDF
Phase separation in metal solutions and expanded fluid metals
Peter P. Edwards and M. J. Sienko
pp 2967 - 2971; DOI:
10.1021/ja00401a010
PDF
Chemical reaction paths. 7. Pathways for SN2 and SN3 substitution at tin(IV)
Doyle Britton and Jack D. Dunitz
pp 2971 - 2979; DOI:
10.1021/ja00401a011
PDF
X-ray crystallographic, chemical, and spectroscopic studies of the palladium dichloride complexes of cyclonona-1,5-diene, cycloocta-1,5-diene, cycloocta-1,4-diene, and cyclohepta-1,4-diene
Michael F. Rettig, Richard M. Wing, and George R. Wiger
pp 2980 - 2986; DOI:
10.1021/ja00401a012
PDF
[2.2.2]paracyclophane, a novel type of metal cation complexing agent (.pi.-prismand)
Jean Louis Pierre, Paul Baret, Pierre Chautemps, and Michel Armand
pp 2986 - 2988; DOI:
10.1021/ja00401a013
PDF
Dynamic FTNMR studies of hindered metal-cage rotation in twelve-vertex closo-phosphinometallacarborane complexes
Todd B. Marder, R. Thomas Baker, Judith A. Long, James A. Doi, and M. Frederick Hawthorne
pp 2988 - 2994; DOI:
10.1021/ja00401a014
PDF
Trifluoromethyl group 2B compounds: bis(trifluoromethyl)cadmium.base. New, more powerful ligand-exchange reagents and low-temperature difluorocarbene sources
L. J. Krause and J. A. Morrison
pp 2995 - 3001; DOI:
10.1021/ja00401a015
PDF
Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenylphosphine)nickel. A cis insertion that leads to trans kinetic products
John M. Huggins and Robert G. Bergman
pp 3002 - 3011; DOI:
10.1021/ja00401a016
PDF
A novel molybdenum thiolato compound, tetrakis(tert-butylthiolato)molybdenum(IV). Preparation and crystal and molecular structure
Sei Otsuka, Masato Kamata, Ken Hirotsu, and Taiichi Higuchi
pp 3011 - 3014; DOI:
10.1021/ja00401a017
PDF
Structures, spectroscopy, and a mechanism of formation of linked-norbornadiene complexes of ruthenium(II). Interaction of ruthenium(II) with alicyclic hydrogen atoms
Kenji Itoh, Noriaki Oshima, Geoffrey B. Jameson, Huntley C. Lewis, and James A. Ibers
pp 3014 - 3023; DOI:
10.1021/ja00401a018
PDF
Clustering of metal atoms in organic media. 8. Low-temperature cleavage of alkanes by small nickel particles resulting in stable nickel-organic composites with unusual magnetic and chemical properties
Stephen C. Davis, Sarah J. Severson, and Kenneth J. Klabunde
pp 3024 - 3029; DOI:
10.1021/ja00401a019
PDF
Degenerative chemistry of malondialdehyde. Structure, stereochemistry, and kinetics of formation of enaminals from reaction with amino acids
Vasu Nair, David E. Vietti, and Curt S. Cooper
pp 3030 - 3036; DOI:
10.1021/ja00401a020
PDF
Amination of .pi.-allylpalladium chloride complexes. A mechanistic study
Bjorn Aakermark, Gunilla Aakermark, Louis S. Hegedus, and Krister Zetterberg
pp 3037 - 3040; DOI:
10.1021/ja00401a021
PDF
Macromonocyclic polyamines as specific receptors for tricarboxylate-cycle anions
Eiichi Kimura, Atsuko Sakonaka, Takashi Yatsunami, and Mutsuo Kodama
pp 3041 - 3045; DOI:
10.1021/ja00401a022
PDF
Isomer distribution ratios of phenols in aromatic hydroxylation with the hydroxyl radical generated from .alpha.-azohydroperoxide in anhydrous organic media. Comparison with Fenton's reagent
Takahiro Tezuka, Nozomu Narita, Wataru Ando, and Shigeru Oae
pp 3045 - 3049; DOI:
10.1021/ja00401a023
PDF
The permethylcyclosilanes (Me2Si)5 through (Me2Si)35
Lawrence F. Brough and Robert West
pp 3049 - 3056; DOI:
10.1021/ja00401a024
PDF
Photochemistry of cyclopropene derivatives. 20. Deuterium isotope effects in the triplet-induced photochemistry of tetrasubstituted cyclopropenes
Albert Padwa, Chuen S. Chou, Robert J. Rosenthal, and Byron Rubin
pp 3057 - 3068; DOI:
10.1021/ja00401a025
PDF
Chemiluminescence of secondary peroxy esters
Brian G. Dixon and Gary B. Schuster
pp 3068 - 3077; DOI:
10.1021/ja00401a026
PDF
Reactions of phenols with photoexcited benzophenones. A CIDNP study
Marcia L. Manion Schilling
pp 3077 - 3081; DOI:
10.1021/ja00401a027
PDF
Enantioselective alkylation of ketones via chiral, nonracemic lithioenamines. An asymmetric synthesis of .alpha.-alkyl and .alpha.,.alpha.'-dialkyl cyclic ketones
A. I. Meyers, Donald R. Williams, Gary W. Erickson, Steven White, and Melvin Druelinger
pp 3081 - 3087; DOI:
10.1021/ja00401a028
PDF
An asymmetric synthesis of acyclic and macrocyclic .alpha.-alkyl ketones. The role of (e)- and (z)-lithioenamines
A. I. Meyers, Donald R. Williams, Steven White, and Gary W. Erickson
pp 3088 - 3093; DOI:
10.1021/ja00401a029
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 37. The reaction of bis(trifluoromethyl)nitroxide with toluene. Evidence for quantum-mechanical tunneling in an intermolecular hydrogen-atom abstraction
V. Malatesta and K. U. Ingold
pp 3094 - 3098; DOI:
10.1021/ja00401a030
PDF
Stereoselective aldol condensations via boron enolates
D. A. Evans, J. V. Nelson, E. Vogel, and T. R. Taber
pp 3099 - 3111; DOI:
10.1021/ja00401a031
PDF
Selenium-stabilized anions. Preparation of .alpha.,.beta.-unsaturated carbonyl compounds using propargyl selenides. Synthesis of (.+-.)-7-hydroxymyoporone
Hans J. Reich, Shrenik K. Shah, Paul M. Gold, and Richard E. Olson
pp 3112 - 3120; DOI:
10.1021/ja00401a032
PDF
Frontier-controlled pericyclic reactions of cyclooctatetraene with cyclopentadienones. First example of exo [4 + 6].pi. cycloadduct by effective secondary orbital control and its molecular structure
Masami Yasuda, Kazunobu Harano, and Ken Kanematsu
pp 3120 - 3126; DOI:
10.1021/ja00401a033
PDF
Hydrogen isotope exchange between fluoroform (CF3H) and water. 1. Catalysis by hydroxide ion
E. Allan Symons and Michel J. Clermont
pp 3127 - 3130; DOI:
10.1021/ja00401a034
PDF
Hydrogen isotope exchange between fluoroform (CF3H) and water. 2. Catalysis by hydroxide ion in the presence of added dimethyl sulfoxide
E. Allan Symons, Michel J. Clermont, and Lorraine A. Coderre
pp 3131 - 3135; DOI:
10.1021/ja00401a035
PDF
Electron-transfer photochemistry of iminium salts. Olefin photoadditions to 2-phenyl-1-pyrrolinium perchlorate
Jerome L. Stavinoha and Patrick S. Mariano
pp 3136 - 3148; DOI:
10.1021/ja00401a036
PDF
Photocyclizations of N-allyliminium salts leading to the production of substituted pyrrolidines
Jerome L. Stavinoha, Patrick S. Mariano, Andrea Leone-Bay, Rosemarie Swanson, and Christopher Bracken
pp 3148 - 3160; DOI:
10.1021/ja00401a037
PDF
Mechanism of oxidative cleavage of organocobalt(III) macrocycles. Application of electrochemical techniques to irreversible electron-transfer processes
W. H. Tamblyn, R. J. Klingler, W. S. Hwang, and J. K. Kochi
pp 3161 - 3172; DOI:
10.1021/ja00401a038
PDF
Alkaloid synthesis via intramolecular ene reactions. 1. Application to (.+-.)-crinane
Gary E. Keck and Robert R. Webb
pp 3173 - 3177; DOI:
10.1021/ja00401a039
PDF
Total solid-phase synthesis of porcine gut gastrin releasing peptide (GRP), a mammalian bombesin
W. Maerki, J. Spiess, Y. Tache, M. Brown, and J. E. Rivier
pp 3178 - 3185; DOI:
10.1021/ja00401a040
PDF
Synthesis of deoxyoligonucleotides on a polymer support
M. D. Matteucci and M. H. Caruthers
pp 3185 - 3191; DOI:
10.1021/ja00401a041
PDF
5-Nitro-2'-deoxyuridine 5'-phosphate: a mechanism-based inhibitor of thymidylate synthetase
Linda Maggiora, Charles C. T. C. Chang, Paul F. Torrence, and Mathias P. Mertes
pp 3192 - 3198; DOI:
10.1021/ja00401a042
PDF
Reaction of carbon disulfide with metal cluster carbonyls of the iron triad: synthesis and x-ray structure of [Fe5(CO)13S2(CS)] containing a six-electron-donor thiocarbonyl group
Peter V. Broadhurst, Brian F. G. Johnson, Jack Lewis, and Paul R. Raithby
pp 3198 - 3200; DOI:
10.1021/ja00401a043
PDF
Copper site of deoxyhemocyanin. Structural evidence from x-ray absorption spectroscopy
Man Sung Co and Keith O. Hodgson
pp 3200 - 3201; DOI:
10.1021/ja00401a044
PDF
Magnetic circular dichroism studies. 59. Substituent-induced sign variation in the magnetic circular dichroism spectra of chlorins
Joseph D. Keegan, Alan M. Stolzenberg, Yu-Cheng Lu, Robert E. Linder, Guenter Barth, Edward Bunnenberg, Carl Djerassi, and Albert Moscowitz
pp 3201 - 3203; DOI:
10.1021/ja00401a045
PDF
Photosensitized electron-transfer reactions in colloidal silicon dioxide systems: charge separation at a solid-aqueous interface
Itamar Willner, John W. Otvos, and Melvin Calvin
pp 3203 - 3205; DOI:
10.1021/ja00401a046
PDF
3-Acyltetramic acid antibiotics. 1. Synthesis of tirandamycic acid
Robert E. Ireland, Peter G. M. Wuts, and Beat Ernst
pp 3205 - 3207; DOI:
10.1021/ja00401a047
PDF
Biosynthesis of retronecine
Gunnar Grue-Soerensen and Ian D. Spenser
pp 3208 - 3210; DOI:
10.1021/ja00401a048
PDF
Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction
R. B. Woodward, E. Logusch, K. P. Nambiar, K. Sakan, D. E. Ward, B. W. Au-Yeung, P. Balaram, L. J. Browne, P. J. Card, and C. H. Chen
pp 3210 - 3213; DOI:
10.1021/ja00401a049
PDF
Asymmetric total synthesis of erythromycin. 2. Synthesis of an erythronolide A lactone system
R. B. Woodward, B. W. Au-Yeung, P. Balaram, L. J. Browne, D. E. Ward, B. W. Au-Yeung, P. Balaram, L. J. Browne, P. J. Card, and C. H. Chen
pp 3213 - 3215; DOI:
10.1021/ja00401a050
PDF
Asymmetric total synthesis of erythromycin. 3. Total synthesis of erythromycin
R. B. Woodward, E. Logusch, K. P. Nambiar, K. Sakan, D. E. Ward, B. W. Au-Yeung, P. Balaram, L. J. Browne, P. J. Card, and C. H. Chen
pp 3215 - 3217; DOI:
10.1021/ja00401a051
PDF
Measurements of degenerate radical ion-neutral molecule electron exchange by microsecond time-resolved CIDNP. Determination of relative hyperfine coupling constants of radical cations of chlorophylls and derivatives
G. L. Closs and E. V. Sitzmann
pp 3217 - 3219; DOI:
10.1021/ja00401a052
PDF
Hydrophobic-hydrophilic interactions in sodium dodecyl sulfate micelles. Stilbene-viologen complex formation as a probe of the micelle interior
John C. Russell, David G. Whitten, and Andre M. Braun
pp 3219 - 3220; DOI:
10.1021/ja00401a053
PDF
Substrate-induced inactivation of aromatase by allenic and acetylenic steroids
B. W. Metcalf, C. L. Wright, J. P. Burkhart, and J. O. Johnston
pp 3221 - 3222; DOI:
10.1021/ja00401a054
PDF
Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction
Donald J. Darensbourg, Andrzej Rokicki, and Marcetta Y. Darensbourg
pp 3223 - 3224; DOI:
10.1021/ja00401a055
PDF
Diels-Alder reactions involving cross-conjugated dienones. Effects of substitution on reactivity
Dennis Liotta, Manohar Saindane, and Christopher Barnum
pp 3224 - 3226; DOI:
10.1021/ja00401a056
PDF
A novel synthesis of (.+-.)-cinnamodial
Lester P. J. Burton and James D. White
pp 3226 - 3228; DOI:
10.1021/ja00401a057
PDF
A monohydroxobridged, strongly antiferromagnetically coupled dicopper(II) center in a binucleating macrocycle. Comparisons with binuclear copper sites in biology
Peter K. Coughlin and Stephen J. Lippard
pp 3228 - 3229; DOI:
10.1021/ja00401a058
PDF
.alpha.-Silyl- or -stannyl-substituted crotyl-9-borabicyclo[3.3.1]nonane as a new reagent for the stereoregulated synthesis of acrylic systems
Yoshinori Yamamoto, Hidetaka Yatagai, and Kazuhiro Maruyama
pp 3229 - 3231; DOI:
10.1021/ja00401a059
PDF
Absolute rate constants for some reactions involving triethylsilyl radicals in solution
C. Chatgilialoglu, K. U. Ingold, J. C. Scaiano, and H. Woynar
pp 3231 - 3232; DOI:
10.1021/ja00401a060
PDF
Unusual equilibrium between 1,4- and 1,6-di-tert-butylcyclooctatetraenes
Matthew H. Lyttle, Andrew Streitwieser, and Robert Q. Kluttz
pp 3232 - 3233; DOI:
10.1021/ja00401a061
PDF
Catalysis of ester aminolysis by divalent metal ions
Robert M. Propst and Larry S. Trzupek
pp 3233 - 3235; DOI:
10.1021/ja00401a062
PDF
Homogeneous asymmetric catalysis: structural studies of catalytic intermediates using extended x-ray absorption fine structure
B. Ray Stults, Robert Mark Friedman, Karl Koenig, William Knowles, Robert B. Greegor, and Farrel W. Lytle
pp 3235 - 3237; DOI:
10.1021/ja00401a063
PDF
Tetraanion of 1,1-dimethyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene
Daniel H. O'Brien and David L. Breeden
pp 3237 - 3239; DOI:
10.1021/ja00401a064
PDF
Book reviews

pp 3239 - 3240; DOI:
10.1021/ja00401a600
PDF

Issue 12


Barriers to ring rotation in 1,1',4,4'-tetra-tert-butyluranocene and 1,1',3,3'-tetra-tert-butylferrocene
Wayne D. Luke and Andrew Streitwieser
pp 3241 - 3243; DOI:
10.1021/ja00402a001
PDF
The sudden polarization effect: MC-SCF calculations on planar and 90.degree. twisted methylenecyclopropene
Richard P. Johnson and Michael W. Schmidt
pp 3244 - 3249; DOI:
10.1021/ja00402a002
PDF
Quantitative prediction and analysis of enthalpies for the interaction of gas-phase ion-ion, gas-phase ion-molecule, and molecule-molecule Lewis acid-base system
Michael K. Kroeger and Russell S. Drago
pp 3250 - 3262; DOI:
10.1021/ja00402a003
PDF
Study of methanesulfonates and trifluoromethanesulfonates. Evidence for hydrogen bonding to the trifluoro group
O. D. Bonner
pp 3262 - 3265; DOI:
10.1021/ja00402a004
PDF
Intramolecular electron delocalization: a four-site model
Jan Linderberg and Mark A. Ratner
pp 3265 - 3271; DOI:
10.1021/ja00402a005
PDF
Electronic relaxation of intra- and intermolecular exciplexes in the vapor phase
Michiya Itoh, Takayuki Kotani, and Yukio Hanashima
pp 3271 - 3275; DOI:
10.1021/ja00402a006
PDF
Theoretical investigation of the structure and rotational barriers of peroxyformimidic acid. The mechanism of stereomutation at the carbon-nitrogen double bond
Timothy J. Lang, Gregory J. Wolber, and Robert D. Bach
pp 3275 - 3282; DOI:
10.1021/ja00402a007
PDF
Principal components of the cadmium-113 shielding tensors in cadmium sulfate hydrates: a nuclear magnetic resonance study of cadmium coordinated with oxygen
P. DuBois Murphy and B. C. Gerstein
pp 3282 - 3286; DOI:
10.1021/ja00402a008
PDF
UPE studies of conjugation involving Group 5A elements. 1. Phenylphosphines
Diane E. Cabelli, Alan H. Cowley, and Michael J. S. Dewar
pp 3286 - 3289; DOI:
10.1021/ja00402a009
PDF
UPE studies of conjugation involving Group 5A elements. 2. Substituted tert-butylacetylenes
Diane E. Cabelli, Alan H. Cowley, and Michael J. S. Dewar
pp 3290 - 3292; DOI:
10.1021/ja00402a010
PDF
Slow multiphoton excitation as a probe of bimolecular and unimolecular reaction energetics. Multiphoton dissociation of proton-bound alcohol dimers
D. S. Bomse and J. L. Beauchamp
pp 3292 - 3296; DOI:
10.1021/ja00402a011
PDF
Theoretical studies of dodecahedrane. 3. Ab initio studies of dodecahedrane and its inclusion compounds
Raymond L. Disch and Jerome M. Schulman
pp 3297 - 3300; DOI:
10.1021/ja00402a012
PDF
Conformational interconversions in pentaalkylhydrazine cation tetrafluoroborates
Stephen F. Nelsen and Peter M. Gannett
pp 3300 - 3304; DOI:
10.1021/ja00402a013
PDF
Fluoromethyl formate. Synthesis, microwave spectrum, structure, dipole moment, and anomeric effect
Alexander D. Lopata and Robert L. Kuczkowski
pp 3304 - 3309; DOI:
10.1021/ja00402a014
PDF
Crystal structure and conformation of cyclo-(glycyl-D-leucyl-L-leucyl)2
Kottayil I. Varughese, Gopinath Kartha, and Kenneth D. Kopple
pp 3310 - 3313; DOI:
10.1021/ja00402a015
PDF
The nature of the 1n.pi.* .rarw. S0 transition. 4. The first excited singlet state of acetaldehyde
Lynn M. Hubbard, David F. Bocian, and Robert R. Birge
pp 3313 - 3320; DOI:
10.1021/ja00402a016
PDF
Organocobalt cluster complexes. 23. Novel chemistry of (acylmethylidyne)- and (aroylmethylidyne)tricobalt-nonacarbonyl complexes
Dietmar Seyferth and Mara Ozolins Nestle
pp 3320 - 3328; DOI:
10.1021/ja00402a017
PDF
Metalloporphyrins with unusual geometries. 1. Mono-, di-, triatom-bridged porphyrin dimers
Kazuyuki Tatsumi and Roald Hoffmann
pp 3328 - 3341; DOI:
10.1021/ja00402a018
PDF
Specific sequestering agents for the actinides. 6. Synthetic and structural chemistry of tetrakis(N-alkylalkanehydroxamato)thorium(IV) complexes
William L. Smith and Kenneth N. Raymond
pp 3341 - 3349; DOI:
10.1021/ja00402a019
PDF
Tetrahedral complexes containing the Fe(II)S4 core. The syntheses, ground-state electronic structures and crystal and molecular structures of the bis(tetraphenylphosphonium) tetrakis (thiophenolato)ferrate (II) and bis (tetrapheny lphosphonium) bis(dithiosquarato)ferrate (II) complexes. An analog for the active site in reducd rubredoxins (Rdred)
D. Coucouvanis, D. Swenson, N. C. Baenziger, C. Murphy, D. G. Holah, N. Sfarnas, A. Simopoulos, and A. Kostikas
pp 3350 - 3362; DOI:
10.1021/ja00402a020
PDF
Generation of rhodium(II) and rhodium(I) from the one-electron reduction of tris(2,2'-bipyridine)rhodium(III) ion in aqueous solution
Quinto G. Mulazzani, Silvano Emmi, Morton Z. Hoffman, and Margherita Venturi
pp 3362 - 3370; DOI:
10.1021/ja00402a021
PDF
The nonadiabaticity problem of outer-sphere electron-transfer reactions. Reduction and oxidation of europium ions
V. Balzani, F. Scandola, G. Orlandi, N. Sabbatini, and M. T. Indelli
pp 3370 - 3378; DOI:
10.1021/ja00402a022
PDF
Intramolecular electron-transfer reactions in bridged binuclear ruthenium(II)-cobalt(III) molecules
Susan K. S. Zawacky and Henry Taube
pp 3379 - 3387; DOI:
10.1021/ja00402a023
PDF
Conversion of coordinated carbon monoxide into carbon dioxide via oxygen-atom transfer from coordinated nitrite: thermolysis of bis(nitrito)dicarbonylbis(triphenylphosphine)ruthenium
David T. Doughty, Robert P. Stewart, and Gilbert Gordon
pp 3388 - 3395; DOI:
10.1021/ja00402a024
PDF
Mechanisms of thermal decomposition of diethylbis(triethylphosphine)platinum(II)
Thomas J. McCarthy, Ralph G. Nuzzo, and George M. Whitesides
pp 3396 - 3403; DOI:
10.1021/ja00402a025
PDF
Thermal decomposition of di(cycloalkyl)bis(triethylphosphine)platinum(II) complexes
Ralph G. Nuzzo, Thomas J. McCarthy, and George M. Whitesides
pp 3404 - 3410; DOI:
10.1021/ja00402a026
PDF
Activation of water molecule. 5. Rhodium(I) hydride catalyzed water gas shift reaction. Identification of the elemental reactions comprising the catalytic cycles
T. Yoshida, T. Okano, Y. Ueda, and S. Otsuka
pp 3411 - 3422; DOI:
10.1021/ja00402a027
PDF
Palladium(II) complexes with trans bis-(carbon-metal) bonds. Ligand syntheses, complexation, x-ray analysis, and biochemical activity with supercoiled DNA
George R. Newkome, Toshio Kawato, Dalip K. Kohli, Wallace E. Puckett, Brian D. Olivier, Giacomo Chiari, Frank R. Fronczek, and Walter A. Deutsch
pp 3423 - 3429; DOI:
10.1021/ja00402a028
PDF
Kinetic studies and a molecular orbital interpretation of reactions at bridging sulfur ligands in dimeric molybdenum complexes
D. L. DuBois, W. K. Miller, and M. Rakowski DuBois
pp 3429 - 3436; DOI:
10.1021/ja00402a029
PDF
The F3NO- radical anion. ESR spectra, structure, and its dissociation to F2NO
A. Hasegawa, R. L. Hudson, O. Kikuchi, K. Nishikida, and F. Williams
pp 3436 - 3440; DOI:
10.1021/ja00402a030
PDF
Crystal structure of vacuum-dehydrated fully ammonium-exchanged zeolite A
Lynne B. McCusker and Karl Seff
pp 3441 - 3446; DOI:
10.1021/ja00402a031
PDF
Characterization of apical copper(II)-thioether bonding. Structure and electronic spectra of bis(2,2-bis(5-phenyl-2-imidazolyl)propane)copper(II) diperchlorate and bis(1,3-bis(5-phenyl-2-imidazolyl)-2-thiapropane)copper(II) diperchlorate
Hans J. Prochaska, William F. Schwindinger, Michael Schwartz, Mark J. Burk, Ernest Bernarducci, Roger A. Lalancette, Joseph A. Potenza, and Harvey J. Schugar
pp 3446 - 3455; DOI:
10.1021/ja00402a032
PDF
Characterization of particulate titanium dioxide photocatalysts by photoelectrophoretic and electrochemical measurements
Wendell W. Dunn, Yosihiro Aikawa, and Allen J. Bard
pp 3456 - 3459; DOI:
10.1021/ja00402a033
PDF
Stereospecific total syntheses of dl-coriolin and dl-coriolin B
Samuel Danishefsky, Robert Zamboni, Michael Kahn, and Sarah Jane Etheredge
pp 3460 - 3467; DOI:
10.1021/ja00402a034
PDF
Total synthesis of sarracenin
James K. Whitesell, Randall S. Matthews, Mark A. Minton, and Andre M. Helbling
pp 3468 - 3472; DOI:
10.1021/ja00402a035
PDF
Synthesis of (5Z)- and (5E)-6,9-thiaprostacyclins
K. C. Nicolaou, W. E. Barnette, and R. L. Magolda
pp 3472 - 3480; DOI:
10.1021/ja00402a036
PDF
Organoselenium-based synthesis of oxygen-containing prostacyclins
K. C. Nicolaou, W. E. Barnette, and R. L. Magolda
pp 3480 - 3485; DOI:
10.1021/ja00402a037
PDF
Organoselenium-based synthesis of sulfur-containing prostacyclins
K. C. Nicolaou, W. E. Barnette, and R. L. Magolda
pp 3486 - 3497; DOI:
10.1021/ja00402a038
PDF
New synthesis of aflatoxin M1
George Buechi, Manuel A. Francisco, Jerrold M. Liesch, and Paul F. Schuda
pp 3497 - 3501; DOI:
10.1021/ja00402a039
PDF
Complete retention in substitution and stereospecificity in transannular reactions of cis- and trans-3-tert-butylcyclooctyl tosylates
Hans Joerg Schneider and Dieter Heiske
pp 3501 - 3505; DOI:
10.1021/ja00402a040
PDF
Neighboring group participation in solvolyses. 11. Kinetic isotope effect study of the solvolysis of neophyl arenesulfonates
Takashi Ando, Seung-Geon Kim, Kenichi Matsuda, Hiroshi Yamataka, Yasuhide Yukawa, Arthur Fry, David E. Lewis, Leslie B. Sims, and Joe C. Wilson
pp 3505 - 3516; DOI:
10.1021/ja00402a041
PDF
Mechanism of the disproportionation of ascorbate radicals
Benon H. J. Bielski, Augustine O. Allen, and Harold A. Schwarz
pp 3516 - 3518; DOI:
10.1021/ja00402a042
PDF
Mechanisms of elimination reactions. 33. Carbon isotope effects in E2 reactions of (2-phenylethyl-2-14C)trimethylammonium ion. The role of tunneling
David J. Miller, R. Subramanian, and William H. Saunders
pp 3519 - 3522; DOI:
10.1021/ja00402a043
PDF
Activation of cobalt-nitro complexes by Lewis acids: catalytic oxidation of alcohols by molecular oxygen
Benjamin S. Tovrog, Steven E. Diamond, Frank Mares, and Andrew Szalkiewicz
pp 3522 - 3526; DOI:
10.1021/ja00402a044
PDF
Gas-phase reactions of O(3P) atoms with methanethiol, ethanethiol, methyl sulfide, and dimethyl disulfide. 1. Rate constants and Arrhenius parameters
W. S. Nip, D. L. Singleton, and R. J. Cvetanovic
pp 3526 - 3530; DOI:
10.1021/ja00402a045
PDF
Gas-phase reactions of O(3P) atoms with methanethiol, ethanethiol, methyl sulfide, and dimethyl disulfide. 2. Reaction products and mechanisms
R. J. Cvetanovic, D. L. Singleton, and R. S. Irwin
pp 3530 - 3539; DOI:
10.1021/ja00402a046
PDF
Carbon-13-proton coupling constants in carbocations. 3. Variation of .DELTA.J with electron demand in aryldialkyl carbocations
David P. Kelly, Graeme J. Farquharson, Joseph J Giansiracusa, Wendy A. Jensen, Helmut M. Huegel, Anne P. Porter, Ian J. Rainbow, and Pamela H. Timewell
pp 3539 - 3543; DOI:
10.1021/ja00402a047
PDF
Transport of photoproduced ions in water in oil microemulsions: movement of ions from one water pool to another
S. S. Atik and J. K. Thomas
pp 3543 - 3550; DOI:
10.1021/ja00402a048
PDF
Photoinduced electron transfer in organized assemblies
S. S. Atik and J. K. Thomas
pp 3550 - 3555; DOI:
10.1021/ja00402a049
PDF
Hydrolysis of 3-(m-nitrophenyl)-3-methoxyphthalide
Daniel P. Weeks and Donald B. Whitney
pp 3555 - 3558; DOI:
10.1021/ja00402a050
PDF
Reactivity of coordinated nitriles
I. I. Creaser, J. M. B. Harrowfield, F. R. Keene, and A. M. Sargeson
pp 3559 - 3564; DOI:
10.1021/ja00402a051
PDF
Crystal structure and chelate ring pucker of bidentate (pyrophosphato)tetraaquochromium(III) trihydrate, a model for metal-ADP coordination
E. A. Merritt, M. Sundaralingam, and D. Dunaway-Mariano
pp 3565 - 3567; DOI:
10.1021/ja00402a052
PDF
Proton nuclear magnetic resonance study of the relaxation behavior and kinetic lability of exchangeable protons in the heme pocket of cyanometmyoglobin
John D. Cutnell, Gerd N. La Mar, and Stephen B. Kong
pp 3567 - 3572; DOI:
10.1021/ja00402a053
PDF
Versatility of tetrakis(tert-butylthiolato)molybdenum. Selective formation of a series of thiolato-molybdenum(I), -molybdenum(II), and -molybdenum(IV) compounds
Masato Kamata, Toshikatsu Yoshida, Sei Otsuka, Ken Hirotsu, and Taiichi Higuchi
pp 3572 - 3574; DOI:
10.1021/ja00402a054
PDF
Photochemistry of stilbene-capped cyclodextrins. Exclusive ring closure of cis cap and direct evidence for trans A,D structure
Iwao Tabushi and Lung Chi Yuan
pp 3574 - 3575; DOI:
10.1021/ja00402a055
PDF
Carbon monoxide activation by organoactinides. Catalytic hydrogenation of inserted carbon monoxide
Eric A. Maatta and Tobin J. Marks
pp 3576 - 3578; DOI:
10.1021/ja00402a056
PDF
High-resolution NMR spectra in inhomogeneous magnetic fields: application of total spin coherence transfer echoes
D. P. Weitekamp, J. R. Garbow, J. B. Murdoch, and A. Pines
pp 3578 - 3579; DOI:
10.1021/ja00402a057
PDF
6-Silafulvene via silylcarbene rearrangement from diazo-2-silacyclohexa-3,5-diene
Akira Sekiguchi and Wataru Ando
pp 3579 - 3580; DOI:
10.1021/ja00402a058
PDF
Bifunctional chiral synthons via microbiological methods. 1. Optically active 2,4-dimethylglutaric acid monomethyl esters
Ching-Shih Chen, Yoshinori Fujimoto, and Charles J. Sih
pp 3580 - 3582; DOI:
10.1021/ja00402a059
PDF
Cleavage of DNA by the 1,10-phenanthroline-copper ion complex. Superoxide mediates the reaction dependent on NADH and hydrogen peroxide
Karl A. Reich, Laura E. Marshall, Daniel R. Graham, and David S. Sigman
pp 3582 - 3584; DOI:
10.1021/ja00402a060
PDF
Ketene dithio acetals as synthetic intermediates. Synthesis of unsaturated 1,5-diketones
Kevin T. Potts, Michael Cipullo, Philip Ralli, and George Theodoridis
pp 3584 - 3585; DOI:
10.1021/ja00402a061
PDF
Ketenedithioacetals as synthetic intermediates. A versatile synthesis of pyridenes, polypyridinyls, and pyrylium salts
Kevin T. Potts, Michael J. Cipullo, Philip Ralli, and George Theodoridis
pp 3585 - 3586; DOI:
10.1021/ja00402a062
PDF
Laser flash photolysis with NMR detection. Submicrosecond time-resolved CIDNP: kinetics of triplet states and biradicals
G. L. Closs and R. J. Miller
pp 3586 - 3588; DOI:
10.1021/ja00402a063
PDF
Selective isomerization of butadiene-cyclobutene systems via infrared multiphoton excitation
James L. Buechele, Eric Weitz, and Frederick D. Lewis
pp 3588 - 3589; DOI:
10.1021/ja00402a064
PDF
A uranium-carbon multiple bond. Crystal and molecular structure of (.eta.5-C5H5)3UCHP(CH3)2(C6H5)
Roger E. Cramer, Richard B. Maynard, Josephine C. Paw, and John W. Gilje
pp 3589 - 3590; DOI:
10.1021/ja00402a065
PDF
Electron spin resonance study of electronic and geometrical structures of C2H6+ and other simple alkane cations at 4.2 K: possible evidence for Jahn-Teller distortion
Machio Iwasaki, Kazumi Toriyama, and Keichi Nunome
pp 3591 - 3592; DOI:
10.1021/ja00402a066
PDF
Hybrid multidentate ligands. Tridentate amidophosphine complexes of nickel(II) and palladium(II)
Michael D. Fryzuk and Patricia A. MacNeil
pp 3592 - 3593; DOI:
10.1021/ja00402a067
PDF
Lifetimes of some styrene triplets in fluid solution. Triplet geometries and the effect of alkylation
Richard A. Caldwell and Chi Van Cao
pp 3594 - 3595; DOI:
10.1021/ja00402a068
PDF
Fast oxidants for NADH and electrochemical discrimination between ascorbic acid and NADH
Akira Kitani and Larry L. Miller
pp 3595 - 3597; DOI:
10.1021/ja00402a069
PDF
Reactivity of the [(.eta.5-C5H5)Ti(Mo5O18)]3- anion: synthesis and structure of MoO2Cl+ and Mn(CO)3+ adducts
V. W. Day, M. F. Fredrich, M. R. Thompson, W. G. Klemperer, R. S. Liu, and W. Shum
pp 3597 - 3599; DOI:
10.1021/ja00402a070
PDF
The first general index of molecular complexity
Steven H. Bertz
pp 3599 - 3601; DOI:
10.1021/ja00402a071
PDF
Selective epoxidation of olefins by molybdenum porphyrin catalyzed peroxy-bond heterolysis
Henry J. Ledon, Patrick Durbut, and Francois Varescon
pp 3601 - 3603; DOI:
10.1021/ja00402a072
PDF
Electron spin resonance and electron spin echo studies of photoproduced tetramethylbenzidine cation radical in frozen aqueous micellar solutions: cation surroundings and retention of micellar structure in frozen solutions
P. A. Narayana, A. S. W. Li, and Larry Kevan
pp 3603 - 3604; DOI:
10.1021/ja00402a073
PDF
The cycloheptatrienylidene-cycloheptatetraene problem. A MNDO investigation
Edward E. Waali
pp 3604 - 3606; DOI:
10.1021/ja00402a074
PDF
Minor and trace sterols in marine invertebrates. 23. Xestospongesterol and isoxestospongesterol - first examples of quadruple biomethylation of the sterol side chain
Lian Niang Li and Carl Djerassi
pp 3606 - 3608; DOI:
10.1021/ja00402a075
PDF
Silver(I) photocatalyzed addition of acetonitrile to norbornene
Joseph W. Bruno, Tobin J. Marks, and Frederick D. Lewis
pp 3608 - 3609; DOI:
10.1021/ja00402a076
PDF
Purported Fischer-Tropsch alkylation of benzene: Reaction of benzene with aluminum trichloride revisited
Linda S. Benner, Yee-Hing Lai, and K. Peter C. Vollhardt
pp 3609 - 3611; DOI:
10.1021/ja00402a077
PDF
Carboxypeptidase A catalysis of an .alpha.,.beta.-elimination reaction
N. T. Nashed and E. T. Kaiser
pp 3611 - 3612; DOI:
10.1021/ja00402a078
PDF
Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex
Wayne P. Weiner, Mary Ann White, and Robert G. Bergman
pp 3612 - 3614; DOI:
10.1021/ja00402a079
PDF
Additions and Corrections - Stereochemistry of an Enzymatic Baeyer-Villiger Reaction. Application of Deuterium NMR
John M. Schwab
pp 3614 - 3614; DOI:
10.1021/ja00402a601
PDF
Additions and Corrections - Conformations of Six N-Methylated Diketopiperazines in Solution
W. Radding, B. Donzel, N. Ueyama, and M. Goodman
pp 3614 - 3614; DOI:
10.1021/ja00402a602
PDF
Additions and Corrections - The Solution Conformational Preferences of the Sugar and Sugar Phosphate Constituents of RNA and DNA
John A. Gerlt, and A. Virginia Youngblood
pp 3614 - 3614; DOI:
10.1021/ja00402a603
PDF
Additions and Corrections - Effect of Photoelectrode Crystal Structure on Output Stability of Cd(Se,Te)/Polysulfide Photoelectrochemical Cells
Gary Hodes, Joost Manassen, and David Cahen
pp 3614 - 3614; DOI:
10.1021/ja00402a604
PDF
Book Reviews

pp 3615 - 3618; DOI:
10.1021/ja00402a600
PDF

Issue 13


Theoretical determination of molecular structure and conformation. 7. Stereoselectivity of the ozonolysis reaction
Dieter Cremer
pp 3619 - 3626; DOI:
10.1021/ja00403a001
PDF
Theoretical determination of molecular structure and conformation. 8. Energetics of the ozonolysis reaction. Primary ozonide vs. carbonyl oxide control of stereochemistry
Dieter Cremer
pp 3627 - 3633; DOI:
10.1021/ja00403a002
PDF
Theoretical determination of molecular structure and conformation. 9. Ozonolysis of fluoroalkenes
Dieter Cremer
pp 3633 - 3638; DOI:
10.1021/ja00403a003
PDF
Negative-ion states of terminal methyl-substituted butadienes. Evidence for through-space interactions involving methyl groups
Stuart W. Staley, Judith C. Giordan, and John H. Moore
pp 3638 - 3641; DOI:
10.1021/ja00403a004
PDF
Thermoneutral isotope-exchange reactions of cations in the gas phase
P. Ausloos and S. G. Lias
pp 3641 - 3647; DOI:
10.1021/ja00403a005
PDF
Absolute heats of formation for gas-phase cations
John C. Traeger and Russell G. McLoughlin
pp 3647 - 3652; DOI:
10.1021/ja00403a006
PDF
Calculation of the nuclear spin-spin coupling constants. 3. .sigma.- and .pi.-Electron contributions in some simple unsaturated hydrocarbons
H. Fukui, T. Tsuji, and K. Miura
pp 3652 - 3653; DOI:
10.1021/ja00403a007
PDF
Buildup rates of the nuclear Overhauser effect measured by two-dimensional proton magnetic resonance spectroscopy: implications for studies of protein conformation
Anil Kumar, Gerhard Wagner, Richard R. Ernst, and Kurt Wuethrich
pp 3654 - 3658; DOI:
10.1021/ja00403a008
PDF
Cadmium-113 nuclear magnetic resonance studies of cadmium-ethylenediaminetetraacetic acid complexes
Claus F. Jensen, Sudha Deshmukh, Hans J. Jakobsen, Ruth R. Inners, and Paul D. Ellis
pp 3659 - 3666; DOI:
10.1021/ja00403a009
PDF
NMR and conductometric studies of 2-pyridyl-substituted carbanions. 2. Effects of cation size and coordination
Thieo E. Hogen-Esch and Waylon L. Jenkins
pp 3666 - 3672; DOI:
10.1021/ja00403a010
PDF
X-ray photoemission from the Creutz-Taube mixed valence complex: a reassessment
P. H. Citrin and A. P. Ginsbeg
pp 3673 - 3679; DOI:
10.1021/ja00403a011
PDF
Conformational analysis of polysubstituted ethanes
Giorgio Favini, Massimo Simonetta, and Roberto Todeschini
pp 3679 - 3682; DOI:
10.1021/ja00403a012
PDF
The relationship between nuclear quadrupole coupling constants and the asymmetry parameter. The interplay of theory and experiment
Jill E. Gready
pp 3682 - 3691; DOI:
10.1021/ja00403a013
PDF
What happens to molecules as they react? A valence bond approach to reactivity
Sason S. Shaik
pp 3692 - 3701; DOI:
10.1021/ja00403a014
PDF
Reactivity-selectivity relationships. A quantum-mechanical approach to transition-state structure. Application to the SN2 reaction of benzyl derivatives
Addy Pross and Sason S. Shaik
pp 3702 - 3709; DOI:
10.1021/ja00403a015
PDF
The pH jump: a rapid modulation of pH of aqueous solutions by a laser pulse
Menachem Gutman, Dan Huppert, and Ehud Pines
pp 3709 - 3713; DOI:
10.1021/ja00403a016
PDF
Iron(III) porphyrin-imidazole complexes. Analysis of carbon-13 nuclear magnetic resonance isotropic shifts and unpaired spin delocalization
Harold M. Goff
pp 3714 - 3722; DOI:
10.1021/ja00403a017
PDF
Oscillations and bistability in hydrogen-platinum-oxyhalogen systems
Miklos Orban and Irving R. Epstein
pp 3723 - 3727; DOI:
10.1021/ja00403a018
PDF
Formation of gas-phase .pi.-allyl radicals from propylene over bismuth oxide and .gamma.-bismuth molybdate catalysts
Wilson Martir and Jack H. Lunsford
pp 3728 - 3732; DOI:
10.1021/ja00403a019
PDF
Solute-solvent interactions in perfluorocarbon solutions of oxygen. An NMR study
M'Hamed Ali Hamza, Guy Serratrice, Marie Jose Stebe, and Jean Jacques Delpuech
pp 3733 - 3738; DOI:
10.1021/ja00403a020
PDF
Nitrogen-15 magnetic resonance spectroscopy of trioxodinitrate: N-protonation of an oxoanion
Francis T. Bonner, Hadassa Degani, and Mohammad Javaid Akhtar
pp 3739 - 3742; DOI:
10.1021/ja00403a021
PDF
Seven-coordinate dicarbonyltriphenylphosphinebis(N,N-dialkyldithiocarbamato)tungsten(II) complexes. Molecular structure and dynamic properties
Joseph L. Templeton and Bennett C. Ward
pp 3743 - 3753; DOI:
10.1021/ja00403a022
PDF
Electrochemistry of titanium(IV) in basic butylpyridinium chloride aluminum chloride in the presence of oxide
Hogne Linga, Z. Stojek, and R. A. Osteryoung
pp 3754 - 3760; DOI:
10.1021/ja00403a023
PDF
Photochemical reactivity in organized assemblies. 18. Light-induced electron-transfer processes in anionic micelles: specific electrolyte effects on the quenching process
Russell H. Schmehl, Leonard G. Whitesell, and David G. Whitten
pp 3761 - 3764; DOI:
10.1021/ja00403a024
PDF
Organo halide addition to tris(bis(diphenylphosphino)methane)dipalladium. Preparation of novel methylene- and phenylene-bridged complexes by two-center, three-fragment oxidative addition
Alan L. Balch, Catherine T. Hunt, Chung-Li Lee, Marilyn M. Olmstead, and James P. Farr
pp 3764 - 3772; DOI:
10.1021/ja00403a025
PDF
Nuclear magnetic resonance studies of some sodium ion complexes with crown ethers and [2]-cryptands in various solvents
Jy Dale Lin and Alexander I. Popov
pp 3773 - 3777; DOI:
10.1021/ja00403a026
PDF
Ab initio modeling of substituent effects in Hammett correlations
Erich R. Vorpagel, Andrew Streitwieser, and Spiro D. Alexandratos
pp 3777 - 3781; DOI:
10.1021/ja00403a027
PDF
Calixarenes. 4. The synthesis, characterization, and properties of the calixarenes from p-tert-butylphenol
C. David Gutsche, Balram Dhawan, Kwang Hyun No, and Ramamurthi Muthukrishnan
pp 3782 - 3792; DOI:
10.1021/ja00403a028
PDF
Gas-phase acid-induced nucleophilic displacement reactions. 4. A stereochemical probe for the existence and the relative stability of cyclic halonium ions in the gas phase
Giancarlo Angelini and Maurizio Speranza
pp 3792 - 3799; DOI:
10.1021/ja00403a029
PDF
Gas-phase acid-induced nucleophilic displacement reactions. 5. Quantitative evaluation of neighboring-group participation in bifunctional compounds
Giancarlo Angelini and Maurizio Speranza
pp 3800 - 3806; DOI:
10.1021/ja00403a030
PDF
The mechanism of ozone-alkene reactions in the gas phase. A mass spectrometric study of the reactions of eight linear and branched-chain alkenes
Richard I. Martinez, John T. Herron, and Robert E. Huie
pp 3807 - 3820; DOI:
10.1021/ja00403a031
PDF
Mechanisms of polymer-supported catalysis. 1. Reaction of 1-bromooctane with aqueous sodium cyanide catalyzed by polystyrene-bound benzyltri-n-butylphosphonium ion
M. Tomoi and Warren T. Ford
pp 3821 - 3828; DOI:
10.1021/ja00403a032
PDF
Mechanisms of polymer-supported catalysis. 2. Reaction of benzyl bromide with aqueous sodium cyanide catalyzed by polystyrene-bound onium ions
M. Tomoi and Warren T. Ford
pp 3828 - 3832; DOI:
10.1021/ja00403a033
PDF
Reactivity of carbonyl oxides. Characteristic nucleophilic oxygen atom transfer from R2COO beside electrophilic and radical reactions
Yasuhiko Sawaki, Hiroshi Kato, and Yoshiro Ogata
pp 3832 - 3837; DOI:
10.1021/ja00403a034
PDF
Monoradical rearrangements of the 1,4-biradicals involved in Norrish type II photoreactions
Peter J. Wagner, Kou-Chang Liu, and Y. Noguchi
pp 3837 - 3841; DOI:
10.1021/ja00403a035
PDF
Photochemistry of .delta.-haloketones: anchimeric assistance in triplet-state .gamma.-hydrogen abstraction and .beta.-elimination of halogen atoms from the resulting diradicals
Peter J. Wagner, Michael J. Lindstrom, James H. Sedon, and Donald R. Ward
pp 3842 - 3849; DOI:
10.1021/ja00403a036
PDF
Excited-state prototropism in esters of o-hydroxy-2-naphthoic acids
G. J. Woolfe and P. J. Thistlethwaite
pp 3849 - 3854; DOI:
10.1021/ja00403a037
PDF
General acid catalysis of alcohol heterolysis
Clifford A. Bunton, Faegh Davoudazedeh, and William E. Watts
pp 3855 - 3858; DOI:
10.1021/ja00403a038
PDF
Photocycloaddition in liquid ethyl cinnamate and in ethyl cinnamate glasses. The photoreaction as a probe into the micromorphology of the solid
P. L. Egerton, E. M. Hyde, J. Trigg, A. Payne, P. Beynon, M. V. Mijovic, and A. Reiser
pp 3859 - 3863; DOI:
10.1021/ja00403a039
PDF
Solvolysis of 2-(trifluoromethyl)-2-propyl trifluoromethanesulfonate. Solvent, salt, and .beta.-deuterium isotope effects. Substituent effect of a strongly deactivating group and rate-limiting solvent-assisted elimination
Michael P. Jansen, Kalavelil M. Koshy, Nevindra N. Mangru, and Thomas T. Tidwell
pp 3863 - 3867; DOI:
10.1021/ja00403a040
PDF
Tetradentate 14-membered tert-phosphino-containing macrocycles
Evan P. Kyba, Raymond E. Davis, Carl W. Hudson, A. Meredith John, S. Bruce Brown, Michael J. McPhaul, Ling-Kang Liu, and Ann C. Glover
pp 3868 - 3875; DOI:
10.1021/ja00403a041
PDF
Reaction of benzene radical cation with water. Evidence for the reversibility of hydroxyl radical addition to benzene
Manfred K. Eberhardt
pp 3876 - 3878; DOI:
10.1021/ja00403a042
PDF
Thermolysis of .alpha.-azido sulfides, sulfoxides, and sulfones: dependence of mechanism on oxidation state of sulfur
Bruce B. Jarvis, Paul E. Nicholas, and Jacob O. Midiwo
pp 3878 - 3882; DOI:
10.1021/ja00403a043
PDF
Oxygenation with molecular oxygen. Thermal and photochemical epoxidation of propylene in the presence of sulfur dioxide in acetonitrile at ambient temperature
Tadahiro Sasaki
pp 3882 - 3886; DOI:
10.1021/ja00403a044
PDF
Magnetic and micellar effects on photoreactions. 1. Carbon-13 isotopic enrichment of dibenzyl ketone via photolysis in aqueous detergent solution
Nicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, and Bernhard Kraeutler
pp 3886 - 3891; DOI:
10.1021/ja00403a045
PDF
Magnetic and micellar effects on photoreactions. 2. Magnetic isotope effects on quantum yields and magnetic field effects on separation efficiency. Correlation of carbon-13 enrichment parameters with quantum yield measurements
Nicholas J. Turro, David R. Anderson, Ming-Fea Chow, Chao-Jen Chung, and Bernhard Kraeutler
pp 3892 - 3896; DOI:
10.1021/ja00403a046
PDF
Reductive cleavage of 9,9-diarylfluorenes by potassium in 1,2-dimethoxyethane
Thomas D. Walsh and Tommy L. Megremis
pp 3897 - 3898; DOI:
10.1021/ja00403a047
PDF
Conformationally 'concerted' changes in nucleotide structures. A new description using circular correlation and regression analyses
Kunihiro Kitamura, Akio Wakahara, Hiroshi Mizuno, Yasumasa Baba, and Kenichi Tomita
pp 3899 - 3904; DOI:
10.1021/ja00403a048
PDF
Mechanism of the reduction and oxidation reaction of cytochrome c at a modified gold electrode
W. John Albery, Mark J. Eddowes, H. Allen O. Hill, and A. Robert Hillman
pp 3904 - 3910; DOI:
10.1021/ja00403a049
PDF
Model studies for a molecular mechanism of action of oral anticoagulants
Richard B. Silverman
pp 3910 - 3915; DOI:
10.1021/ja00403a050
PDF
Anatomy of a complex mutarotation. Kinetics of tautomerization of .alpha.-D-galactopyranose and .beta.-D-galactopyranose in water
Philip W. Wertz, John C. Garver, and Laurens Anderson
pp 3916 - 3922; DOI:
10.1021/ja00403a051
PDF
Total synthesis of the C-nucleoside dl-showdomycin by a Diels-Alder, retrograde Dieckmann strategy
Alan P. Kozikowski and Anthony Ames
pp 3923 - 3924; DOI:
10.1021/ja00403a052
PDF
Oxo-peroxo oxygen exchange in peroxovanadium(V) and peroxomolybdenum(VI) compounds
Olga Bortolini, Fulvio Di Furia, and Giorgio Modena
pp 3924 - 3926; DOI:
10.1021/ja00403a053
PDF
Farnesylpyrophosphate synthetase. A stepwise mechanism for the 1'-4 condensation reaction
C. Dale Poulter, Paul L. Wiggins, and Anthony T. Le
pp 3926 - 3927; DOI:
10.1021/ja00403a054
PDF
Farnesylpyrophosphate synthetase. Evidence for a rigid geranyl cation-pyrophosphate anion pair
Eugene A. Mash, George M. Gurria, and C. Dale Poulter
pp 3927 - 3929; DOI:
10.1021/ja00403a055
PDF
Synthesis and complexing properties of chiral macrocycles containing enforced cavities
Roger C. Helgeson, Jean Paul Mazaleyrat, and Donald J. Cram
pp 3929 - 3931; DOI:
10.1021/ja00403a056
PDF
Structure of C4H4+ produced in the unimolecular fragmentation of C6H6+ and C5H5N+
Pierre Ausloos
pp 3931 - 3932; DOI:
10.1021/ja00403a057
PDF
Metathesis of acetylenes by tungsten(VI)-alkylidyne complexes
Jeffrey H. Wengrovius, Jose Sancho, and Richard R. Schrock
pp 3932 - 3934; DOI:
10.1021/ja00403a058
PDF
Thermoneutral dyotropic transfer of hydrogen in a hydrocarbon
Jean Pierre Hagenbuch, Brigitte Stampfli, and Pierre Vogel
pp 3934 - 3935; DOI:
10.1021/ja00403a059
PDF
The new amino acid .beta.-carboxyaspartic acid (asa). Laboratory synthesis and identification in the ribosomal proteins of E. coli
M. Robert Christy, Robert M. Barkley, Tad H. Koch, John J. Van Buskirk, and Wolff M. Kirsch
pp 3935 - 3937; DOI:
10.1021/ja00403a060
PDF
Polymer films on electrodes. 6. Bioconductive polymers produced by incorporation of tetrathiafulvalenium in a polyelectrolyte (Nafion) matrix
Timothy P. Henning, Henry S. White, and Allen J. Bard
pp 3937 - 3938; DOI:
10.1021/ja00403a061
PDF
Kijanimicin. 1. Structures of the individual sugar components
Alan K. Mallams, Mohindar S. Puar, and Randall R. Rossman
pp 3938 - 3940; DOI:
10.1021/ja00403a062
PDF
Kijanimicin. 2. Structure and absolute stereochemistry of kijanimicin
Alan K. Mallams, Mohindar S. Puar, Randall R. Rossman, Andrew T. McPhail, and Ronald D. Macfarlane
pp 3940 - 3943; DOI:
10.1021/ja00403a063
PDF
Electron-impact-induced fragmentation of quaternary ammonium cations
Mamoru Ohashi, Robert P. Barron, and Walter R. Benson
pp 3943 - 3945; DOI:
10.1021/ja00403a064
PDF
Nickel-promoted cyclization/carbonylation in the preparation of .alpha.-methylene-.gamma.lactones. Stereospecific synthesis of (.+-.)-frullanolide
M. F. Semmelhack and Steven J. Brickner
pp 3945 - 3947; DOI:
10.1021/ja00403a065
PDF
Dioxygenase model studies: reaction of oxygen with iron catecholates
Randall B. Lauffer, Robert H. Heistand, and Lawrence Que
pp 3947 - 3949; DOI:
10.1021/ja00403a066
PDF
Observation of a novel effect on the anionic inhibition of carbonic anhydrase: implications for enzymic catalysis
Y. Pocker and Thomas L. Deits
pp 3949 - 3951; DOI:
10.1021/ja00403a067
PDF
Novel substrate-binding property of synthetic membrane vesicles involving an amino acid residue as a molecular component
Yukito Murakami, Yasuhiro Aoyama, Akio Nakano, Toshito Tada, and Kiyoshi Fukuya
pp 3951 - 3953; DOI:
10.1021/ja00403a068
PDF
Quadruply bonded tetramethyltetrakis(trialkylphosphine)dimolybdenum compounds: phosphine exchange kinetics, acetone formation with carbon monoxide and crystal structure of Mo2Me4(PMe3)4
Gregory S. Girolami, Vera V. Mainz, Richard A. Andersen, Sara H. Vollmer, and Victor W. Day
pp 3953 - 3955; DOI:
10.1021/ja00403a069
PDF
Sulfenium ion addition to hexamethyl (Dewar benzene). A case for a hypervalent sulfonium ion intermediate
J. M. Bolster, H. Hogeveen, R. M. Kellogg, and L. Zwart
pp 3955 - 3956; DOI:
10.1021/ja00403a070
PDF
A chiral synthesis of L-acosamine and L-daunosamine via an enantioselective intramolecular[3 + 2]cycloaddition
Peter M. Wovkulich and Milan R. Uskokovic
pp 3956 - 3958; DOI:
10.1021/ja00403a071
PDF
Tetrakis(trifluoromethyl)semibullvalenes. Could Cope degeneration be frozen out?
Yoshiro Kobayashi, Akira Ando, Kosuke Kawada, and Itsumaro Kumadaki
pp 3958 - 3959; DOI:
10.1021/ja00403a072
PDF
Ethylene glycol from synthesis gas via ruthenium melt catalysis
John F. Knifton
pp 3959 - 3961; DOI:
10.1021/ja00403a073
PDF
Ligand-induced valence tautomerism in manganese-quinone complexes
Michael W. Lynch, David N. Hendrickson, Brian J. Fitzgerald, and Cortlandt G. Pierpont
pp 3961 - 3963; DOI:
10.1021/ja00403a074
PDF
Stereocontrolled synthesis of cis-2,5-disubstituted tetrahydrofurans and cis- and trans-linalyl oxides
Scott D. Rychnovsky and Paul A. Bartlett
pp 3963 - 3964; DOI:
10.1021/ja00403a075
PDF
A widely useful chiral stationary phase for the high-performance liquid chromatography separation of enantiomers
William H. Pirkle, John M. Finn, James L. Schreiner, and Bruce C. Hamper
pp 3964 - 3966; DOI:
10.1021/ja00403a076
PDF

Issue 14


Energetics of the rearrangement of neutral and ionized perfluorocyclopropane to perfluoropropylene. Use of infrared multiphoton dissociation spectra to identify structural isomers of molecular ions
D. S. Bomse, D. Wayne Berman, and J. L. Beauchamp
pp 3967 - 3971; DOI:
10.1021/ja00404a001
PDF
Propensity rules for vibration-induced electron detachment of anions
Jack Simons
pp 3971 - 3976; DOI:
10.1021/ja00404a002
PDF
Structures and properties of organic liquids: n-alkyl ethers and their conformational equilibriums
William L. Jorgensen and Mustafa Ibrahim
pp 3976 - 3985; DOI:
10.1021/ja00404a003
PDF
Geometry and electronic structure of (CO)3NiCH2. A model transition-metal carbene
Dale Spangler, John J. Wendoloski, Michel Dupuis, Maynard M. L. Chen, and Henry F. Schaefer
pp 3985 - 3990; DOI:
10.1021/ja00404a004
PDF
Novel method for angle determinations by EXAFS via a new multiple-scattering formalism
Boon-Keng Teo
pp 3990 - 4001; DOI:
10.1021/ja00404a005
PDF
Infrared multiphoton photochemistry of vinylcyclopropane. Variation of yield and branching ratio with experimental parameters
William E. Farneth, Marcus W. Thomsen, Nancy L. Schultz, and Mark A. Davies
pp 4001 - 4006; DOI:
10.1021/ja00404a006
PDF
Ab initio direct calculation of the singlet-triplet separation in cupric acetate hydrate dimer
P. De Loth, P. Cassoux, J. P. Daudey, and J. P. Malrieu
pp 4007 - 4016; DOI:
10.1021/ja00404a007
PDF
Effects of the acidities of phenols from specific substituent-solvent interactions. Inherent substituent parameters from gas-phase acidities
M. Fujio, R. T. McIver, and R. W. Taft
pp 4017 - 4029; DOI:
10.1021/ja00404a008
PDF
High-resolution carbon-13 NMR study of solid .pi.-.pi. molecular complexes using "magic angle" spinning techniques
William G. Blann, Colin A. Fyfe, James R. Lyerla, and Costantino S. Yannoni
pp 4030 - 4033; DOI:
10.1021/ja00404a009
PDF
Electron transfer in chemical and biological systems. Orbital rules for nonadiabatic transfer
Sven Larsson
pp 4034 - 4040; DOI:
10.1021/ja00404a010
PDF
Molecular and electronic structures of two quadruply bonded ditungsten compounds and a dimolybdenum homolog
F. Albert Cotton, Michael W. Extine, Timothy R. Felthouse, Brian W. S. Kolthammer, and Dennis G. Lay
pp 4040 - 4045; DOI:
10.1021/ja00404a011
PDF
Preparation and characterization of 1,2-dialkyl compounds of dimolybdenum and ditungsten of formula M2R2(NMe2)4 (M.tplbond.M)
M. H. Chisholm, D. A. Haitko, K. Folting, and J. C. Huffman
pp 4046 - 4053; DOI:
10.1021/ja00404a012
PDF
Definition of reaction sequences resulting in self-assembly of [Fe4S4(SR)4]2- clusters from simple reactants
Karl S. Hagen, John G. Reynolds, and R. H. Holm
pp 4054 - 4063; DOI:
10.1021/ja00404a013
PDF
Actinide-carbon bonds: insertion reactions of carbon monoxide, tert-butyl isocyanide, and tert-butyl cyanide into [(Me3Si)2N]2MCH2Si(Me)2NSiMe3
Stephen J. Simpson and Richard A. Andersen
pp 4063 - 4066; DOI:
10.1021/ja00404a014
PDF
Syntheses of Halogensulfuranes with a five-membered ring bonded to sulfur via oxygen and nitrogen
Kiyoshi Tanaka and Jean'ne M. Shreeve
pp 4067 - 4069; DOI:
10.1021/ja00404a015
PDF
(.eta.2-Olefin)tetracarbonylruthenium complexes: photochemical syntheses from dodecacarbonyltriruthenium and quantum yield determinations
Friedrich Wilhelm Grevels, Johannes G. A. Reuvers, and Josef Takats
pp 4069 - 4073; DOI:
10.1021/ja00404a016
PDF
The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent copper(I)copper(II) complex
R. R. Gagne, C. L. Spiro, T. J. Smith, C. A. Hamann, W. R. Thies, and A. D. Shiemke
pp 4073 - 4081; DOI:
10.1021/ja00404a017
PDF
Kinetic evidence for the formation of discrete 1,4-dehydrobenzene intermediates. Trapping by inter- and intramolecular hydrogen atom transfer and observation of high-temperature CIDNP
Thomas P. Lockhart, Paul B. Comita, and Robert G. Bergman
pp 4082 - 4090; DOI:
10.1021/ja00404a018
PDF
Evidence for the reactive spin state of 1,4-dehydrobenzenes
Thomas P. Lockhart and Robert G. Bergman
pp 4091 - 4096; DOI:
10.1021/ja00404a019
PDF
Binding and transport of alkali and alkaline earth metal ions by synthetic macrolides containing tetrahydropyran rings
Ichiro Tajima, Masahiko Okada, and Hiroshi Sumitomo
pp 4096 - 4100; DOI:
10.1021/ja00404a020
PDF
Molecular orbital correlations of chlorine atom abstraction from heteroarylmethyl chlorides by triphenyltin radical
Helene Soppe-Mbang and Gerald Jay Gleicher
pp 4100 - 4104; DOI:
10.1021/ja00404a021
PDF
Flash photolytic triplet sensitization and the mechanism of carbonylferroporphyrin photodissociation
Marlene A. Stanford and Brian M. Hoffman
pp 4104 - 4113; DOI:
10.1021/ja00404a022
PDF
Total synthesis of Lauraceae lactones: obtusilactones, litsenolides, and mahubanolides
Susan Wells Rollinson, Richard A. Amos, and John A. Katzenellenbogen
pp 4114 - 4125; DOI:
10.1021/ja00404a023
PDF
Synthesis of tetraphenylstannacyclopentadienes (stannoles). 1. Alkylation of 1,1-dihalostannoles leading to lithium 1,1-bis-(.eta.1-cyclopentadienyl)-1-halo-2,3,4,5-tetraphenylstannole, an [R4SnX]- anion, with pseudorotating axial- and equatorial-fluxional .eta.1-cyclopentadienyl groups
W. A. Gustavson, L. M. Principe, W. Z. Min Rhee, and J. J. Zuckerman
pp 4126 - 4131; DOI:
10.1021/ja00404a024
PDF
Synthesis and carbon-13 nuclear magnetic resonance studies of some bridgehead fluorides: carbon-fluorine coupling constants
Ernest W. Della, Evangelo Cotsaris, and Philip T. Hine
pp 4131 - 4135; DOI:
10.1021/ja00404a025
PDF
Total synthesis of dl-quadrone
Samuel Danishefsky, Kenward Vaughan, Robert Gadwood, and Kazuo Tsuzuki
pp 4136 - 4141; DOI:
10.1021/ja00404a026
PDF
Ring-closure reactions. 19. Kinetics of formation of benzo-crown ethers by intramolecular nucleophilic substitution. A comparison between polyoxyethylene and polymethylene chains
Gabriello Illuminati, Luigi Mandolini, and Bernardo Masci
pp 4142 - 4145; DOI:
10.1021/ja00404a027
PDF
Degenerate thermal rearrangement of 1,3-dimethylenecyclopentane. Evidence for partially stereospecific biradical formation and closure in a 1,3 shift
Joseph J. Gajewski and Jose Del C. Salazar
pp 4145 - 4154; DOI:
10.1021/ja00404a028
PDF
Laser flash photolysis study of the reactions of carbonyl triplets with phenols and photochemistry of p-hydroxypropiophenone
P. K. Das, M. V. Encinas, and J. C. Scaiano
pp 4154 - 4162; DOI:
10.1021/ja00404a029
PDF
Reaction of tert-butoxy radicals with phenols. Comparison with the reactions of carbonyl triplets
P. K. Das, M. V. Encinas, S. Steenken, and J. C. Scaiano
pp 4162 - 4166; DOI:
10.1021/ja00404a030
PDF
Reactions of coordinated molecules. 30. Carbon-carbon bond formation between adjacent acyl ligands: transannular coupling across a metalla-.beta.-diketonate ring
C. M. Lukehart and K. Srinivasan
pp 4166 - 4170; DOI:
10.1021/ja00404a031
PDF
Photolysis of organopolysilanes. Reaction of trimethylsilylphenylsilylene with functional-group-substituted olefins
Mitsuo Ishikawa, Kenichi Nakagawa, Seiji Katayama, and Makoto Kumada
pp 4170 - 4174; DOI:
10.1021/ja00404a032
PDF
Mechanisms of 1,1-reductive elimination from palladium: coupling of styrylmethylpalladium complexes
Marilyn K. Loar and J. K. Stille
pp 4174 - 4181; DOI:
10.1021/ja00404a033
PDF
Mechanisms of 1,1-reductive elimination from palladium: elimination of ethane from dimethylpalladium(II) and trimethylpalladium(IV)
A. Moravskiy and J. K. Stille
pp 4182 - 4186; DOI:
10.1021/ja00404a034
PDF
Regioselective carbonyl amination using diisobutylaluminum hydride
Hisashi Yamamoto and Keiji Maruoka
pp 4186 - 4194; DOI:
10.1021/ja00404a035
PDF
Effect of nucleophile basicity on intramolecular nucleophilic aminolysis reactions of carbonate diesters
Thomas H. Fife and J. E. C. Hutchins
pp 4194 - 4199; DOI:
10.1021/ja00404a036
PDF
Photochemistry of some deoxybenzoins in micellar solutions. Cage effects, isotope effects, and magnetic field effects
Nicholas J. Turro and Jochen Mattay
pp 4200 - 4204; DOI:
10.1021/ja00404a037
PDF
Cyanation of aromatic compounds in a gaseous plasma
Y. H. So and Larry L. Miller
pp 4204 - 4209; DOI:
10.1021/ja00404a038
PDF
High resolution, zero quantum transition (two-dimensional) nuclear magnetic resonance spectroscopy: spectral analysis
G. Pouzard, S. Sukumar, and L. D. Hall
pp 4209 - 4215; DOI:
10.1021/ja00404a039
PDF
Avermectins. Structure determination
G. Albers-Schoenberg, B. H. Arison, J. C. Chabala, A. W. Douglas, P. Eskola, M. H. Fisher, A. Lusi, H. Mrozik, J. L. Smith, and R. L. Tolman
pp 4216 - 4221; DOI:
10.1021/ja00404a040
PDF
The absolute stereochemistry and conformation of avermectin B2a aglycone and avermectin B1a
James P. Springer, Byron H. Arison, Jordan M. Hirshfield, and Karst Hoogsteen
pp 4221 - 4224; DOI:
10.1021/ja00404a041
PDF
N-Methylprotoporphyrin IX. Identification by NMR of the nitrogen alkylated in each of the four isomers
Kent L. Kunze and Paul R. Ortiz de Montellano
pp 4225 - 4230; DOI:
10.1021/ja00404a042
PDF
Active-site-directed inhibition of .alpha.-chymotrypsin by deaminatively produced carbonium ions: an example of suicide or enzyme-activated-substrate inhibition
Emil H. White, Lynn W. Jelinski, Ieva R. Politzer, Bruce R. Branchini, and David F. Roswell
pp 4231 - 4239; DOI:
10.1021/ja00404a043
PDF
Micellar solubilization of biopolymers in organic solvents. 5. Activity and conformation of .alpha.-chymotrypsin in isooctane-AOT reverse micelles
Slobodan Barbaric and Pier Luigi Luisi
pp 4239 - 4244; DOI:
10.1021/ja00404a044
PDF
Addition of alkynes to hexaalkoxydimolybdenum (M.ident.M) compounds and structure of .mu.-ethyne-hexaisopropoxydipyridinodimolybdenum
Malcolm H. Chisholm, John C. Huffman, and Ian P. Rothwell
pp 4245 - 4246; DOI:
10.1021/ja00404a045
PDF
A stereospecific total synthesis of aklavinone
Andrew S. Kende and James P. Rizzi
pp 4247 - 4248; DOI:
10.1021/ja00404a046
PDF
Practical total synthesis of (.+-.)-aklavinone and total synthesis of aklavin
B. A. Pearlman, J. M. McNamara, I. Hasan, S. Hatakeyama, H. Sekizaki, and Y. Kishi
pp 4248 - 4251; DOI:
10.1021/ja00404a047
PDF
Total stereospecific synthesis of (.+-.)-aklavinone
Pat N. Confalone and Giacomo Pizzolato
pp 4251 - 4254; DOI:
10.1021/ja00404a048
PDF
A study of the rate of intervalence electron transfer by using time domain reflectometry
Bruce C. Bunker, Michael K. Kroeger, Robert M. Richman, and Russell S. Drago
pp 4254 - 4255; DOI:
10.1021/ja00404a049
PDF
Synthesis, structural characterization, and molecular orbital calculations for a titanium Lewis acid-carbonyl adduct
David M. Hamilton, William S. Willis, and Galen D. Stucky
pp 4255 - 4256; DOI:
10.1021/ja00404a050
PDF
Gas phase hydrogen-deuterium exchange reactions in carbanions: exchange of vinyl and aryl protons by water-d2
Robert R. Squires, C. H. DePuy, and Veronica M. Bierbaum
pp 4256 - 4258; DOI:
10.1021/ja00404a051
PDF
Dication ethers, R+-O-R+, conjugated cations with remarkably low rotation barriers. Theoretical investigation
Yitzhak Apeloig and Dorit Arad
pp 4258 - 4260; DOI:
10.1021/ja00404a052
PDF
Gas chromatographic separation and identification of the four stereoisomers of 1,2,2-trimethylpropyl methylphosphonofluoridate (soman). Stereospecificity of in vitro detoxification reactions
Hendrik P. Benschop, Cornelis A. G. Konings, and Leo P. A. De Jong
pp 4260 - 4262; DOI:
10.1021/ja00404a053
PDF
Heats of formation of tert-butyl and ethyl radicals
A. L. Castelhano, P. R. Marriott, and D. Griller
pp 4262 - 4263; DOI:
10.1021/ja00404a054
PDF
Silicon-29 CP/MAS NMR studies of methylchlorosilane reactions on silica gel
Dean W. Sindorf and Gary E. Maciel
pp 4263 - 4265; DOI:
10.1021/ja00404a055
PDF
Derivatives of heteropolyanions. 3. O-alkylation of Mo12PO403- and W12PO403-
W. H. Knoth and R. L. Harlow
pp 4265 - 4266; DOI:
10.1021/ja00404a056
PDF
Synthesis and ammonium cryptates of triply bridged cylindrical macrotetracycles
Florence Kotzyba-Hibert, Jean Marie Lehn, and Kazuhiko Saigo
pp 4266 - 4268; DOI:
10.1021/ja00404a057
PDF
Oxygen activation by radical coupling between superoxide ion and reduced methyl viologen
Edward J. Nanni, Charles T. Angelis, Jon Dickson, and Donald T. Sawyer
pp 4268 - 4270; DOI:
10.1021/ja00404a058
PDF
Reversible migration of an axial carbene ligand into an iron-nitrogen bond on a porphyrin. Implications for high oxidation states of heme enzymes and heme catabolism
L. Latos-Grazynski, Ru-Jen Cheng, Gerd N. La Mar, and Alan L. Balch
pp 4270 - 4272; DOI:
10.1021/ja00404a059
PDF
Synthesis and molecular structure of an aminophosphoranide transition-metal adduct. First transition-metal derivative having a cyclic N-P(V)-M arrangement
Francois Jeanneaux, Andre Grand, and Jean G. Riess
pp 4272 - 4273; DOI:
10.1021/ja00404a060
PDF
Organometallic photochemistry at the solid/gas interface. Photochemistry of surface-confined cobalt tetracarbonyl monitored by Fourier transform infrared photoacoustic spectroscopy
John B. Kinney, Ralph H. Staley, Carol L. Reichel, and Mark S. Wrighton
pp 4273 - 4275; DOI:
10.1021/ja00404a061
PDF
Structure of molecular complexes of copper uroporphyrin with aromatic heterocycles
J. A. Shelnutt
pp 4275 - 4277; DOI:
10.1021/ja00404a062
PDF
New bonding mode for a bridging dioxygen ligand: Crystal and molecular structure of [K.dibenzo-18-crown-6] [Al2(CH3)6O2].1.5C6H6
Duane C. Hrncir, Robin D. Rogers, and Jerry L. Atwood
pp 4277 - 4278; DOI:
10.1021/ja00404a063
PDF
Enantioselective aldol reactions with high threo or erythro selectivity using boron azaenolates
A. I. Meyers and Yukio Yamamoto
pp 4278 - 4279; DOI:
10.1021/ja00404a064
PDF
Polymerized microemulsions
S. S. Atik and J. K. Thomas
pp 4279 - 4280; DOI:
10.1021/ja00404a065
PDF

Issue 15


MNDO molecular orbital study of nitrenium ions derived from carcinogenic aromatic amines and amides
George P. Ford and John D. Scribner
pp 4281 - 4291; DOI:
10.1021/ja00405a001
PDF
Charge-transfer band of 7-norbornenone. Circular dichroism of (1R)-2-deuteriobicyclo[2.2.1]hept-2-en-7-one and (1R)-2-methylbicyclo[2.2.1]hept-2-en-7-one
David A. Lightner, Jacek K. Gawronski, Aage E. Hansen, and Thomas D. Bouman
pp 4291 - 4296; DOI:
10.1021/ja00405a002
PDF
Mechanism of bond rotation in 9-(1-naphthyl)methylenecyclooctatrienyl anions
Stuart W. Staley and Charles K. Dustman
pp 4297 - 4302; DOI:
10.1021/ja00405a003
PDF
Proton localization in an asymmetric double-minimum potential: 2-methyl-9-hydroxyphenalenone
R. Rossetti, R. Rayford, R. C. Haddon, and L. E. Brus
pp 4303 - 4307; DOI:
10.1021/ja00405a004
PDF
Transition-metal complexed olefins: how their reactivity toward a nucleophile relates to their electronic structure
Odile Eisenstein and Roald Hoffmann
pp 4308 - 4320; DOI:
10.1021/ja00405a005
PDF
Deformations from octahedral geometry in d4 transition-metal complexes
Pavel Kubacek and Roald Hoffmann
pp 4320 - 4332; DOI:
10.1021/ja00405a006
PDF
Reactions of recoil bromine formed by the 76,77Kr .fwdarw. 76,77Br systems with simple hydrocarbons. Solid-phase reactions
James J. Frost, Stephen M. Moerlein, and Michael J. Welch
pp 4332 - 4337; DOI:
10.1021/ja00405a007
PDF
Reactions of recoil bromine formed by the 76,77Kr .fwdarw. 76,77Br systems with simple hydrocarbons
James J. Frost, Stephen M. Moerlein, and Michael J. Welch
pp 4337 - 4343; DOI:
10.1021/ja00405a008
PDF
Radical trapping in a mass spectrometer ion source. 1
C. N. McEwen and M. A. Rudat
pp 4343 - 4349; DOI:
10.1021/ja00405a009
PDF
Gas-phase radical structures. Radical trapping. 2
M. A. Rudat and C. N. McEwen
pp 4349 - 4354; DOI:
10.1021/ja00405a010
PDF
Isomerization of gas-phase hydrocarbon ions. Radical trapping. 3
C. N. McEwen and M. A. Rudat
pp 4355 - 4359; DOI:
10.1021/ja00405a011
PDF
Gas-phase reactions of iron(1+) with ketones and ethers
R. C. Burnier, G. D. Byrd, and B. S. Freiser
pp 4360 - 4367; DOI:
10.1021/ja00405a012
PDF
Photoprocesses in cationic microemulsion systems
S. S. Atik and J. K. Thomas
pp 4367 - 4371; DOI:
10.1021/ja00405a013
PDF
Highly conducting linear stacked polymers: iodine-doped fluoroaluminum and fluorogallium phthalocyanines
Ronald S. Nohr, Paul M. Kuznesof, Kenneth J. Wynne, Malcolm E. Kenney, and P. G. Siebenman
pp 4371 - 4377; DOI:
10.1021/ja00405a014
PDF
Low-temperature EPR studies of highly anisotropic low-spin (protoporphyrinato)iron(III) complexes
Catharina T. Migita and Masamoto Iwaizumi
pp 4378 - 4381; DOI:
10.1021/ja00405a015
PDF
Spectroscopic studies on plastocyanin single crystals: a detailed electronic structure determination of the blue copper active site
K. W. Penfield, R. R. Gay, R. S. Himmelwright, N. C. Eickman, V. A. Norris, H. C. Freeman, and E. I. Solomon
pp 4382 - 4388; DOI:
10.1021/ja00405a016
PDF
Oxygen-18 isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. 4. Oxygen exchange of [1-13C,18O2]acetic acid in dilute acid
John M. Risley and Robert L. Van Etten
pp 4389 - 4392; DOI:
10.1021/ja00405a017
PDF
Structures and properties of organic liquids: n-butane and 1,2-dichloroethane and their conformation equilibriums
William L. Jorgensen, Robert C. Binning, and Bernard Bigot
pp 4393 - 4399; DOI:
10.1021/ja00405a018
PDF
High-resolution cadmium-113 NMR of solids. Correlation of spectra with the molecular structure of a decanuclear cadmium(II) complex
P. DuBois Murphy, W. C. Stevens, T. T. P. Cheung, S. Lacelle, B. C. Gerstein, and D. M. Kurtz
pp 4400 - 4405; DOI:
10.1021/ja00405a019
PDF
Analysis of field-dependent relaxation data and hyperfine shifts of cytochrome c' from Rhodospirillum rubrum in terms of the high-spin iron ligation states
Gerd N. La Mar, J. Timothy Jackson, and R. G. Bartsch
pp 4405 - 4410; DOI:
10.1021/ja00405a020
PDF
Stereochemistry at manganese of the carbon monoxide insertion in pentacarbonylmethylmanganese(I). The geometry of the intermediate
Thomas C. Flood, John E. Jensen, and John A. Statler
pp 4410 - 4414; DOI:
10.1021/ja00405a021
PDF
Comparative reactivities of two isoelectronic transition-metal hydrides with transition-metal carbonyls and alkyls
William D. Jones, John M. Huggins, and Robert G. Bergman
pp 4415 - 4423; DOI:
10.1021/ja00405a022
PDF
Preparation and helium (He I) photoelectron spectra of the halogen thiocyanates, XSCN (X = chlorine and bromine)
D. C. Frost, C. B. MacDonald, C. A. McDowell, and N. P. C. Westwood
pp 4423 - 4427; DOI:
10.1021/ja00405a023
PDF
Preparation and helium (He I) photoelectron spectra of the dihaloboranes, HBX2 (X = chlorine and bromine)
D. C. Frost, C. Kirby, C. A. McDowell, and N. P. C. Westwood
pp 4428 - 4432; DOI:
10.1021/ja00405a024
PDF
Phosphorus-containing cyclohexanes. Nuclear magnetic resonance studies and conformational analysis of 1,3,2-dithiaphosphorinanes
Bruce E. Maryanoff, Andrew T. McPhail, and Robert O. Hutchins
pp 4432 - 4445; DOI:
10.1021/ja00405a025
PDF
Crystal and molecular structure of the ternary complex bis[(adenosine 5'-triphosphato)(2,2'-bipyridine)zinc(II)] tetrahydrate
P. Orioli, R. Cini, D. Donati, and S. Mangani
pp 4446 - 4452; DOI:
10.1021/ja00405a026
PDF
Highly selective re-additions to a masked oxaloacetate. Absolute configurations of fluorocitric acids
Svante Brandaenge, Olof Dahlman, and Lars Moerch
pp 4452 - 4458; DOI:
10.1021/ja00405a027
PDF
How many rings can share a quaternary atom?
Peter Gund and Tamara M. Gund
pp 4458 - 4465; DOI:
10.1021/ja00405a028
PDF
Electron transfer in nickel-catalyzed addition reactions of organozirconium compounds to unsaturated ketones
Fabian M. Dayrit and Jeffrey Schwartz
pp 4466 - 4473; DOI:
10.1021/ja00405a029
PDF
Thermochemical studies of carbonyl reactions. 2. Steric effects in acetal and ketal hydrolysis
Kenneth B. Wiberg and Robert R. Squires
pp 4473 - 4478; DOI:
10.1021/ja00405a030
PDF
Association constants and reaction dynamics of metal ions bound to anionic micelles
Henry Ziemiecki and W. R. Cherry
pp 4479 - 4483; DOI:
10.1021/ja00405a031
PDF
[1-2H]-Allyl radical: barrier to rotation and allyl delocalization energy
Hans-Gert Korth, Heinrich Trill, and Reiner Sustmann
pp 4483 - 4489; DOI:
10.1021/ja00405a032
PDF
Steric effects in the intramolecular carboxyl-catalyzed hydrolysis of sulfonamides. Ab initio quantum chemical studies of the pentacoordinated sulfur intermediate
Teun Graafland, Wim C. Nieuwpoort, and Jan B. F. N. Engberts
pp 4490 - 4494; DOI:
10.1021/ja00405a033
PDF
Methylation of lithioisobutyrophenone in weakly polar aprotic solvents. The effect of aggregation
L. M. Jackman and B. C. Lange
pp 4494 - 4499; DOI:
10.1021/ja00405a034
PDF
Redox-photosensitized reactions. 7. Aromatic hydrocarbon-photosensitized electron-transfer reactions of furan, methylated furans, 1,1-diphenylethylene, and indene with p-dicyanobenzene
Tetsuro Majima, Chyongjin Pac, Akira Nakasone, and Hiroshi Sakurai
pp 4499 - 4508; DOI:
10.1021/ja00405a035
PDF
Mechanism of hydrolysis of N-(1-aminoalkyl)amides
G. Marc Loudon, Merrick Almond, and James N. Jacob
pp 4508 - 4515; DOI:
10.1021/ja00405a036
PDF
Perchlorate esters. 4. Kinetics and mechanism of the reactions of alkyl perchlorates with N,N-dimethylanilines in benzene
Dennis N. Kevill and Betty W. Shen
pp 4515 - 4521; DOI:
10.1021/ja00405a037
PDF
Structural aspects and low-temperature photochemistry of the monothioacetylacetone system
Jerzy Gebicki and Allen Krantz
pp 4521 - 4526; DOI:
10.1021/ja00405a038
PDF
Structure, reactivity, and biological activity of strained bicyclic .beta.-lactams
H. R. Pfaendler, J. Gosteli, R. B. Woodward, and G. Rihs
pp 4526 - 4531; DOI:
10.1021/ja00405a039
PDF
Oxyphosphoranes with an oxaphospholene ring: analysis of the activation barriers of the isomerization process
G. Buono and J. R. Llinas
pp 4532 - 4540; DOI:
10.1021/ja00405a040
PDF
Stereochemistry of nucleophilic addition to cyclohexanone. The importance of two-electron stabilizing interactions
Andrzej Stanislaw Cieplak
pp 4540 - 4552; DOI:
10.1021/ja00405a041
PDF
Lifetimes and energies of the relaxed triplet states of cyclopentadiene and tetramethylbutadiene. A pulse radiolysis and pulsed laser study
A. A. Gorman, I. R. Gould, and I. Hamblett
pp 4553 - 4558; DOI:
10.1021/ja00405a042
PDF
Aryloxenium ions. Generation from N-(aryloxy)pyridinium tetrafluoroborates and reaction with anisole and benzonitrile
Rudolph A. Abramovitch, Gerard Alvernhe, Romuald Bartnik, Nissanke L. Dassanayake, Mutiah N. Inbasekaran, and Shiego Kato
pp 4558 - 4565; DOI:
10.1021/ja00405a043
PDF
Biosynthesis of the boron-containing macrolide antibiotic aplasmomycin by Streptomyces griseus
Tom S. S. Chen, Ching-Jer Chang, and Heinz G. Floss
pp 4565 - 4568; DOI:
10.1021/ja00405a044
PDF
Transient phenomena in the pulse radiolysis of retinyl polyenes. 1. Radical anions
N. V. Raghavan, P. K. Das, and K. Bobrowski
pp 4569 - 4573; DOI:
10.1021/ja00405a045
PDF
Time-resolved laser flash spectroscopic study of benzyl radical pairs in micelle cages
Nicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, Yoshifumi Tanimoto, and Gregory Weed
pp 4574 - 4576; DOI:
10.1021/ja00405a046
PDF
Polymerization of acetylenes, 1,3-dienes and allyl halides on active uranium powder
T. C. Wen, C. C. Chang, Y. D. Chuang, C. P. Cheng, J. P. Chiu, and C. T. Chang
pp 4576 - 4578; DOI:
10.1021/ja00405a047
PDF
Reaction of primary amines with the dichlorocarbene complex of iron(II) tetraphenylporphyrin [FeIITPP(CCl2)]
Thomas C. Bruice, Peter G. Furter, and Sheldon S. Ball
pp 4578 - 4580; DOI:
10.1021/ja00405a048
PDF
A novel P-450 model system for the N-dealkylation reaction
Patrick Shannon and Thomas C. Bruice
pp 4580 - 4582; DOI:
10.1021/ja00405a049
PDF
Asymmetric, biogenetically modeled synthesis of (-)-3-aminonocardicinic acid
Craig A. Townsend and Loan T. Nguyen
pp 4582 - 4583; DOI:
10.1021/ja00405a050
PDF
Excited-state energetics and dynamics of magnesium tetraphenylporphyrin cooled in supersonic expansions
Uzi Even, Yaacov Magen, Joshua Jortner, and Haim Levanon
pp 4583 - 4585; DOI:
10.1021/ja00405a051
PDF
Chiral catalysis of additions of alkyllithiums to aldehydes
Jean Paul Mazaleyrat and Donald J. Cram
pp 4585 - 4586; DOI:
10.1021/ja00405a052
PDF
Aromatic polycyclic benzenoid tetraanions: pyrene and perylene anions revisited
Abraham Minsky, Joseph Klein, and Mordecai Rabinovitz
pp 4586 - 4587; DOI:
10.1021/ja00405a053
PDF
Synthesis and structure of bis(2,4,6-tri-tert-butylphenyl)diphosphene: isolation of a true phosphobenzene
M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, and T. Higuchi
pp 4587 - 4589; DOI:
10.1021/ja00405a054
PDF
Tungston-183 NMR spectroscopy: 2Jw-w coupling. Structural application to 1-12 heteropolytungstates
J. Lefebvre, F. Chauveau, P. Doppelt, and C. Brevard
pp 4589 - 4591; DOI:
10.1021/ja00405a055
PDF
Rotational diffusion of rose bengal in aqueous micelles: evidence for extensive exposure of the hydrocarbon chains
Wayne Reed, Mario J. Politi, and Janos H. Fendler
pp 4591 - 4593; DOI:
10.1021/ja00405a056
PDF
Fluoromethylglyoxal: synthesis and glyoxalase I catalyzed product partitioning via a presumed enediol intermediate
John W. Kozarich, Ravi V. J. Chari, John C. Wu, and Timothy L. Lawrence
pp 4593 - 4595; DOI:
10.1021/ja00405a057
PDF
Dicoordinated 2H-phospholes as transient intermediates in the reactions of tervalent phospholes at high temperature. One-step syntheses of 1-phosphanorbornadienes and phosphorins from phospholes
Francois Mathey, Francois Mercier, Claude Charrier, Jean Fischer, and Andre Mitschler
pp 4595 - 4597; DOI:
10.1021/ja00405a058
PDF
Synthesis of thromboxane A2 analogs: DL-9,11:11,12-dideoxa-9,11:11,12-diepithiothromboxane A2
Shuichi Ohuchida, Nobuyuki Hamanaka, and Masaki Hayashi
pp 4597 - 4599; DOI:
10.1021/ja00405a059
PDF
A tungsten T-shaped methylene complex and related methylidyne hydride complexes
Steven J. Holmes and Richard R. Schrock
pp 4599 - 4600; DOI:
10.1021/ja00405a060
PDF
Coordination unsaturation in the iron tetrahiometalate complexes. Synthesis and structural characterization of the [Fe(WS4)2(HCON(CH3)2)2]2- complex anion
P. Stremple, N. C. Baenziger, and D. Coucouvanis
pp 4601 - 4603; DOI:
10.1021/ja00405a061
PDF
Editing of carbon-13 NMR spectra. 1. A pulse sequence for the generation of subspectra
M. R. Bendall, D. M. Doddrell, and D. T. Pegg
pp 4603 - 4605; DOI:
10.1021/ja00405a062
PDF
Novel addition reaction of thebaine with acetylenic dienophiles: construction of a new morphine skeleton
Kenji Hayakawa, Shigenori Motohiro, Ikuo Fujii, and Ken Kanematsu
pp 4605 - 4606; DOI:
10.1021/ja00405a063
PDF
Generation and recycle use of selenenylating reagents in electrochemical oxyselenenylation-deselenenylation of olefins
Sigeru Torii, Kenji Uneyama, Michio Ono, and Tadashi Bannou
pp 4606 - 4608; DOI:
10.1021/ja00405a064
PDF
Stereomutation at pentacoordinate silicon by intramolecular ligand exchange
William B. Farnham and Richard L. Harlow
pp 4608 - 4610; DOI:
10.1021/ja00405a065
PDF
Alkylation and oxidative dimerization of enolate anions by radical chain processes
Glen A. Russell, Boguslaw Mudryk, and Mikolaj Jawdosiuk
pp 4610 - 4611; DOI:
10.1021/ja00405a066
PDF
Bis heteroannulation. 3. Facile synthesis of (.+-.)-ligularone and (.+-.)-petasalbine
Peter A. Jacobi and Donald G. Walker
pp 4611 - 4613; DOI:
10.1021/ja00405a067
PDF
High enantioselectivity in reductions with a chiral bis(NADH) model compound
Masahiko Seki, Naomichi Baba, Junichi Oda, and Yuzo Inouye
pp 4613 - 4615; DOI:
10.1021/ja00405a068
PDF
Total synthesis of (.+-.)-maritimol
Eugene E. Van Tamelen, James G. Carlson, Ronald K. Russell, and Steven R. Zawacky
pp 4615 - 4616; DOI:
10.1021/ja00405a069
PDF
A short, economical, and stereoselective route to prostaglandins by vicinal alkylation of cyclopentadiene
S. Goldstein, P. Vannes, C. Houge, A. M. Frisque-Hesbain, C. Wiaux-Zamar, L. Ghosez, G. Germain, J. P. Declercq, M. Van Meerssche, and J. M. Arrieta
pp 4616 - 4618; DOI:
10.1021/ja00405a070
PDF
Stereospecific total synthesis of 11(R)-HETE (2), lipoxygenation product of arachidonic acid via the prostaglandin pathway
E. J. Corey and Jahyo Kang
pp 4618 - 4619; DOI:
10.1021/ja00405a071
PDF
Carbon-13 magic angle NMR study of the isomerization of cis- to trans-polyacetylene
Harry W. Gibson, John M. Pochan, and Samuel Kaplan
pp 4619 - 4620; DOI:
10.1021/ja00405a072
PDF
cis-Diamminedichloroplatinum(II) binds in a unique manner to oligo(dG).oligo(dC) sequences in DNA - a new assay using exonuclease III
Thomas D. Tullius and Stephen J. Lippard
pp 4620 - 4622; DOI:
10.1021/ja00405a073
PDF
Stereoelectronic properties of photosynthetic and related systems. 10. Quantum mechanical characterization of the excited states of ethyl chlorophyllide a enol
J. D. Petke, Lester L. Shipman, Gerald M. Maggiora, and Ralph E. Christoffersen
pp 4622 - 4623; DOI:
10.1021/ja00405a074
PDF
A primary carbon-13 equilibrium isotope effect. 13C NMR spectrum of 2,3-dimethyl-2-[2-13C]butylium ion
Martin Saunders, Mandes R. Kates, and Gary E. Walker
pp 4623 - 4624; DOI:
10.1021/ja00405a075
PDF
Photosolvolysis of (iodomethyl)naphthalene. Laser spectrophotometric analysis of the mechanism
Gregory H. Slocum, Kenneth Kaufmann, and Gary B. Schuster
pp 4625 - 4627; DOI:
10.1021/ja00405a076
PDF
Catalysis by solvated transition-metal cations. Novel catalytic transformations of alkenes by tetrakis(acetonitrile)palladium ditetrafluoroborate. Evidence for the formation of incipient carbonium ions as intermediates
Ayusman Sen and Ta-Wang Lai
pp 4627 - 4629; DOI:
10.1021/ja00405a077
PDF
Planar, pleated, and saddle-shaped structures of the phthalocyanine dianion in two novel multidentate oxygen-donor complexes of dipotassium phthalocyanine
R. F. Ziolo, W. H. H. Guenther, and J. M. Troup
pp 4629 - 4630; DOI:
10.1021/ja00405a078
PDF
Wavelength and solvent effects on ionic photodissociation of charge-transfer complexes. The hexamethyl (Dewar benzene) system
Guilford Jones and William G. Becker
pp 4630 - 4632; DOI:
10.1021/ja00405a079
PDF
Production of acrylonitrile and other unsaturated nitriles from hydrocarbons using a plasma
Neil B. H. Henis, Ying-Hung So, and Larry L. Miller
pp 4632 - 4633; DOI:
10.1021/ja00405a080
PDF
Structure of koumine
Chu-Tsin Liu, Qi-Wen Wang, and Chi-Hao Wang
pp 4634 - 4635; DOI:
10.1021/ja00405a081
PDF
In vivo liquid solution ENDOR and TRIPLE resonance of bacterial photosynthetic reaction centers of Rhodopseudomonas sphaeroides R-26
F. Lendzian, W. Lubitz, H. Scheer, C. Bubenzer, and K. Moebius
pp 4635 - 4637; DOI:
10.1021/ja00405a082
PDF
Stereospecific hydrogen-deuterium exchange via an enolate ion
Robert D. Guthrie and Edgar C. Nicolas
pp 4637 - 4638; DOI:
10.1021/ja00405a083
PDF
Dimethylpentatetraenylidene
W. J. Le Noble, Sanjay Basak, and Sushil Srivastava
pp 4638 - 4639; DOI:
10.1021/ja00405a084
PDF
Studies of nitrogen metabolism using carbon-13 NMR spectroscopy. 2. Incorporation of L-[guanido-13C,15N2]arginine and DL-[guanido-13C,2-15N]arginine into streptothricin F
Steven J. Gould, Kazys J. Martinkus, and Chou-Hong Tann
pp 4639 - 4640; DOI:
10.1021/ja00405a085
PDF
Optical resolution of metal chelates by use of adsorption on a colloidal clay
Akihiko Yamagishi and Mitsuyuki Soma
pp 4640 - 4642; DOI:
10.1021/ja00405a086
PDF
Diphenylselenium bistrifluoroacetate: a new reagent for biomimetic oxidations of amines and amino acids
Joseph P. Marino and Robert D. Larsen
pp 4642 - 4643; DOI:
10.1021/ja00405a087
PDF
Efficient and stereoselective synthesis of 2,3-dihydroindoles via 1,5-electrocyclization
W. Nico Speckamp, Siem J. Veenstra, Jan Dijkink, and Rik Fortgens
pp 4643 - 4645; DOI:
10.1021/ja00405a088
PDF
A stereoselective synthesis of indole alkaloid intermediates via N-acyliminium cyclizations
Siem J. Veenstra and W. Nico Speckamp
pp 4645 - 4646; DOI:
10.1021/ja00405a089
PDF
The spiro[2.5]oct-4-yl cation, a long-lived secondary cyclohexyl cation
George A. Olah, Alexander P. Fung, Tarik N. Rawdah, and G. K. Surya Prakash
pp 4646 - 4647; DOI:
10.1021/ja00405a090
PDF
Preparation of lactone systems. Total synthesis of (.+-.)-quadrone
Walter K. Bornack, Shripad S. Bhagwat, John Ponton, and Paul Helquist
pp 4647 - 4648; DOI:
10.1021/ja00405a091
PDF
Evidence for migratory insertion of a methylidene ligand into a transition-metal-methyl bond
Jeffrey C. Hayes, Gregory D. N. Pearson, and N. John Cooper
pp 4648 - 4650; DOI:
10.1021/ja00405a092
PDF
Role of solvent in the mechanism of amine oxide thermolysis elucidated by the temperature dependence of a kinetic isotope effect
Harold Kwart and Martin Brechbiel
pp 4650 - 4652; DOI:
10.1021/ja00405a093
PDF
Additions and Corrections - Isolation and Characterization of the First Host Recognition Substance for Parasitic Angiosperms
David G. Lynn, John C. Steffens, Vinayak S. Kamat, David W. Graden, Jeffrey Shabanowitz, and James L. Riopel
pp 4652 - 4652; DOI:
10.1021/ja00405a600
PDF
Additions and Corrections - Competitive Condensation and Proton-Transfer Processes in the Reaction of t-C4H9+ Ions with Ammonia in Gaseous Systems at Atmospheric Pressure
M. Attina, Fulvio Cacace, P. Giacomello, and M. Speranza
pp 4652 - 4652; DOI:
10.1021/ja00405a601
PDF
Additions and Corrections - A Strategy for the Total Synthesis of Jatrophone: Synthesis of Normethyljatrophone
A. B. Smith, III, M. A. Guaciaro, S. R. Schow, P. M. Wovkulich, B. H. Toder, and T. W. Hall
pp 4652 - 4652; DOI:
10.1021/ja00405a602
PDF
Additions and Corrections - Interaction of Pyruvate-Thiamin Diphosphate Adducts with Pyruvate Decarboxylase. Catalysis through "Closed" Transition States
Ronald Kluger, and Timothy Smith
pp 4652 - 4652; DOI:
10.1021/ja00405a603
PDF
Book Reviews

pp 4653 - 4656; DOI:
10.1021/ja00405a604
PDF

Issue 16


Electronic and geometric structural properties of the bare silver (Ag3) cluster and ions
Harold Basch
pp 4657 - 4663; DOI:
10.1021/ja00406a001
PDF
Calculations of ground- and excited-state potential surfaces for conjugated heteroatomic molecules
A. Warshel and A. Lappicirella
pp 4664 - 4673; DOI:
10.1021/ja00406a002
PDF
Study of additivity of correlation and polarization effects in relative energies
Michael L. McKee and William N. Lipscomb
pp 4673 - 4676; DOI:
10.1021/ja00406a003
PDF
Molecular Orbital Calculations on Carbyne Complexes CpMn(CO)2CR+ and (CO)5CrCNEt2+. Frontier-Controlled Nucleophilic Addition to Metal-Carbon Triple Bond
Nenad M. Kostic, and Richard F. Fenske
pp 4677 - 4685; DOI:
10.1021/ja00406a600
PDF
Dynamics of light-induced water cleavage in colloidal systems
Dung Duonghong, Enrico Borgarello, and Michael Graetzel
pp 4685 - 4690; DOI:
10.1021/ja00406a004
PDF
NMR studies of base-catalyzed proton exchange in amides
Charles L. Perrin, Eric R. Johnston, Charles Peter Lollo, and Paul A. Kobrin
pp 4691 - 4696; DOI:
10.1021/ja00406a005
PDF
Mechanisms of acid-catalyzed proton exchange in amides
Charles L. Perrin and Eric R. Johnston
pp 4697 - 4703; DOI:
10.1021/ja00406a006
PDF
Experimental chemical shift correlation maps from heteronuclear two-dimensional NMR spectroscopy. 1. Carbon-13 and proton chemical shifts of raffinose and its subunits
Gareth A. Morris and Laurence D. Hall
pp 4703 - 4711; DOI:
10.1021/ja00406a007
PDF
Does the cyclohexyl cation exist in the dilute gas state? Direct evidence from a radiolytic study
Marina Attina, Fulvio Cacace, and Pierluigi Giacomello
pp 4711 - 4714; DOI:
10.1021/ja00406a008
PDF
Picosecond laser spectroscopy of intramolecular heteroexcimer systems. Time-resolved absorption studies of p-(CH3)2NC6H4(CH2)n-1-pyrenyl and 9-anthryl systems
Tadashi Okada, Masahito Migita, Noboru Mataga, Yoshiteru Sakata, and Soichi Misumi
pp 4715 - 4720; DOI:
10.1021/ja00406a009
PDF
Pressure dependence of the structure and properties of liquid n-butane
William L. Jorgensen
pp 4721 - 4726; DOI:
10.1021/ja00406a010
PDF
Unidirectional current flow and charge state trapping at redox polymer interfaces on bilayer electrodes: principles, experimental demonstration, and theory
P. Denisevich, K. W. Willman, and Royce W. Murray
pp 4727 - 4737; DOI:
10.1021/ja00406a011
PDF
Conformational study of the tetrapeptide Boc-Arg-Ala-Gly-Glu-NHEt. A .beta. turn locked by a salt bridge
Roger Mayer and Gerard Lancelot
pp 4738 - 4742; DOI:
10.1021/ja00406a012
PDF
Volumes of complexation of cryptands with mono- and divalent cations in water and in methanol
Nicole Morel-Desrosiers and Jean Pierre Morel
pp 4743 - 4746; DOI:
10.1021/ja00406a013
PDF
Elimination, fragmentation, and proton transfer in 1,3-dithianes and 1,3-dithiolanes in the gas phase
John E. Bartmess, Robert L. Hays, Hiralal N. Khatri, Raj N. Misra, and Stephen R. Wilson
pp 4746 - 4751; DOI:
10.1021/ja00406a014
PDF
Nitrogen-15 chemical shift tensors in L-histidine hydrochloride monohydrate
G. Harbison, J. Herzfeld, and R. G. Griffin
pp 4752 - 4754; DOI:
10.1021/ja00406a015
PDF
Photoelectron spectroscopy of f-element organometallic complexes. 4. Comparative studies of bis(pentamethylcyclopentadienyl) dichloride and dimethyl complexes of uranium(IV), thorium(IV), and zirconium(IV)
Enrico Ciliberto, Giuseppe Condorelli, Paul J. Fagan, Juan M. Manriquez, Ignazio Fragala, and Tobin J. Marks
pp 4755 - 4759; DOI:
10.1021/ja00406a016
PDF
The ambidentate thiocyanate ligand. Niobium-93 nuclear magnetic resonance detection of (thiocyanato)- and (isothiocyanato)niobium(V) complexes
R. G. Kidd and H. G. Spinney
pp 4759 - 4763; DOI:
10.1021/ja00406a017
PDF
Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: means of formation and spectroscopic and redox properties
Alan M. Stolzenberg, Steven H. Strauss, and R. H. Holm
pp 4763 - 4778; DOI:
10.1021/ja00406a018
PDF
Structural consequences of electron-transfer reactions. 5. Electrochemically induced isomerizations of (cyclooctadiene)- and (cyclooctatetraene)cobalt compounds
Jerome Moraczewski and William E. Geiger
pp 4779 - 4787; DOI:
10.1021/ja00406a019
PDF
Structural consequences of electron-transfer reactions. VI. Electronic structures and structural preferences of cyclooctatetraene- and cyclooctadiene- iron and cobalt compounds and their radical anions
Thomas A. Albright, William E. Geiger, Jerry Moraczewski, and Bunchai Tulyathan
pp 4787 - 4794; DOI:
10.1021/ja00406a020
PDF
1-Alkyl-2-(carbomethoxy)pyridinyl radicals: monomers and dimers defined through chemical and photochemical properties and electron paramagnetic resonance
Joshua Hermolin, Menachem Levin, Yusaku Ikegami, Masako Sawayanagi, and Edward M. Kosower
pp 4795 - 4800; DOI:
10.1021/ja00406a021
PDF
Thin-film optical spectroscopic investigations of 1-alkyl-2-(carbomethoxy)- and 2-acetylpyridinyl radical monomers and dimers
Joshua Hermolin, Menachem Levin, and Edward M. Kosower
pp 4801 - 4807; DOI:
10.1021/ja00406a022
PDF
Stable free radicals. 12. New aspects of the behavior of 1-alkyl-4-(carboalkoxy)- and 1-alkyl-4-carbamidopyridinyl radicals in solution and in thin films
Joshua Hermolin, Menachem Levin, and Edward M. Kosower
pp 4808 - 4813; DOI:
10.1021/ja00406a023
PDF
Stable free radicals. 13. Reinvestigation of the pyridinyl diradical, 1,1'-trimethylenebis(4-(carbomethoxy)pyridinyl)
Joshua Hermolin and Edward M. Kosower
pp 4813 - 4816; DOI:
10.1021/ja00406a024
PDF
Solution and solid carbon-13 magnetic resonance study of the conformation of 9,10-dihydroanthracene and its 9,10-methylated derivatives
Don K. Dalling, Kurt W. Zilm, David M. Grant, William A. Heeschen, W. James Horton, and Ronald J. Pugmire
pp 4817 - 4824; DOI:
10.1021/ja00406a025
PDF
Decomposition and isomerization of bridgehead cis 1,2-diazenes (azoalkanes)
Woo-Ki Chae, Sharon A. Baughman, Paul S. Engel, Manfred Bruch, Cenan Ozmeral, Sandor Szilagyi, and Jack W. Timberlake
pp 4824 - 4833; DOI:
10.1021/ja00406a026
PDF
"Spontaneous" formation of radicals from nitroso compounds. Inadvertent photolysis vs. molecule assisted homolysis
C. Chatgilialoglu and K. U. Ingold
pp 4833 - 4837; DOI:
10.1021/ja00406a027
PDF
Dication ether salts, R+-O-R+.2CF3SO3-, from the reaction of trifluoromethanesulfonic anhydride with activated ketones
Peter J. Stang, Gerhard Maas, David L. Smith, and James A. McCloskey
pp 4837 - 4845; DOI:
10.1021/ja00406a028
PDF
Aluminum chloride catalyzed skeletal rearrangement of permethylated acyclic polysilanes
Mitsuo Ishikawa, Jun Iyoda, Haruhiko Ikeda, Kazunori Kotake, Toshio Hashimoto, and Makoto Kumada
pp 4845 - 4850; DOI:
10.1021/ja00406a029
PDF
Nucleophilic addition to olefins. 5. Reaction of 1,1-dinitro-2,2-diphenylethylene with water and hydroxide ion in 50% dimethyl sulfoxide-50% water. Complete kinetic analysis of hydrolytic cleavage of the C:C double bond in acidic and basic solution
Claude F. Bernasconi, David J. Carre, and Anastassia Kanavarioti
pp 4850 - 4860; DOI:
10.1021/ja00406a030
PDF
Differing behavior of pyrrolidine and piperidine as nucleophiles toward 2,4-dinitrophenyl and 2,4-dinitro-6-methylphenyl phenyl ethers
Joseph F. Bunnett and Artemio V. Cartano
pp 4861 - 4865; DOI:
10.1021/ja00406a031
PDF
Kinetics of reactions of cyclic secondary amines with 2,4-dinitro-1-naphthyl ethyl ether in dimethyl sulfoxide solution. Spectacular difference between the behavior of pyrrolidine and piperidine
Joseph F. Bunnett, Shizen Sekiguchi, and Lewis A. Smith
pp 4865 - 4871; DOI:
10.1021/ja00406a032
PDF
Reactions of secondary amines with their N-(2,4-dinitro-1-naphthyl) derivatives to form Jackson-Meisenheimer adducts. Substantial difference in reaction rates between pyrrolidine and piperidine
Shizen Sekiguchi and J. F. Bunnett
pp 4871 - 4874; DOI:
10.1021/ja00406a033
PDF
Acid-catalyzed hydrolyses of acylpyrroles and acylindoles. Noninvolvement of protonated substrates
Antonio Cipiciani, Paolo Linda, Gianfranco Savelli, and Clifford A. Bunton
pp 4874 - 4879; DOI:
10.1021/ja00406a034
PDF
Tridentate to bidentate in a platinum(II) chelate: a 90.degree. anthranilaldehyde rotation
Alan J. Jircitano, William G. Rohly, and Kristin Bowman Mertes
pp 4879 - 4883; DOI:
10.1021/ja00406a035
PDF
The mechanism of hemiacetal decomposition. Substituent effects in breakdown of substituted benzaldehyde ethyl hemiacetals
Theodore J. Przystas and Thomas H. Fife
pp 4884 - 4890; DOI:
10.1021/ja00406a036
PDF
Enzyme-catalyzed organic synthesis: NAD(P)H cofactor regeneration by using glucose-6-phosphate and the glucose-5-phosphate dehydrogenase from Leuconostoc mesenteroides
Chi-Huey Wong and George M. Whitesides
pp 4890 - 4899; DOI:
10.1021/ja00406a037
PDF
Preparation and reactivity of model compounds related to oligomers from thiamin. A mechanism for oligomerization
John A. Zoltewicz, Georg Uray, and Glenn M. Kauffman
pp 4900 - 4904; DOI:
10.1021/ja00406a038
PDF
Synthesis and characterization of a novel cholesterol nitroxide spin label. Application to the molecular organization of human high-density lipoprotein
John F. W. Keana, Toshinari Tamura, Debra A. McMillen, and Patricia C. Jost
pp 4904 - 4912; DOI:
10.1021/ja00406a039
PDF
Comparative NMR studies of cytochrome c and its active site octapeptide
Michele Smith and George McLendon
pp 4912 - 4921; DOI:
10.1021/ja00406a040
PDF
Stereochemical analysis of .gamma.-replacement and .gamma.-elimination processes catalyzed by a pyridoxal phosphate dependent enzyme
Michael N. T. Chang and Christopher T. Walsh
pp 4921 - 4927; DOI:
10.1021/ja00406a041
PDF
Temperature-dependent spin-state equilibrium in aquo and hydroxo ferric heme octapeptide complexes. Model systems for the spin equilibrium of ferric hemoproteins
Ya-Ping Huang and Richard J. Kassner
pp 4927 - 4932; DOI:
10.1021/ja00406a042
PDF
Electronic effects on the binding of dioxygen and carbon monoxide to hemes
T. G. Traylor, Dabney K. White, Dwane H. Campbell, and Albin P. Berzinis
pp 4932 - 4936; DOI:
10.1021/ja00406a043
PDF
Fluorescence detected circular dichroism of proteins with single fluorescent tryptophans
Eric W. Lobenstine, William C. Schaefer, and Douglas H. Turner
pp 4936 - 4940; DOI:
10.1021/ja00406a044
PDF
Synthesis of bridging vinylideneiron dimers using 1,1-dichlorocyclopropanes. Cyclopropenes as intermediates
David F. Marten, Eckehard V. Dehmlow, David J. Hanlon, M. Bilayet Hossain, and Dick Van der Helm
pp 4940 - 4941; DOI:
10.1021/ja00406a045
PDF
End-to-end cyclization of hydrocarbon chains. Photochemical and computer simulation studies
Andrew Mar, Simon Fraser, and Mitchell A. Winnik
pp 4941 - 4943; DOI:
10.1021/ja00406a046
PDF
Gold-197 Moessbauer spectroscopic data for antiarthritic drugs and related gold(I) thiol derivatives
Karen Brown, R. V. Parish, and Charles A. McAuliffe
pp 4943 - 4945; DOI:
10.1021/ja00406a047
PDF
Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II). Structural and spectroscopic evidence for molybdenum-to-bipyridyl .pi.* bonding
M. H. Chisholm, J. C. Huffman, I. P. Rothwell, P. G. Bradley, N. Kress, and W. H. Woodruff
pp 4945 - 4947; DOI:
10.1021/ja00406a048
PDF
A semichelating metal-.beta.-diketonate complex
A. R. Siedle, L. H. Pignolet, and R. A. Newmark
pp 4947 - 4948; DOI:
10.1021/ja00406a049
PDF
New route to 11-oxygenated steroids
Gilbert Stork, G. Clark, and Christopher S. Shiner
pp 4948 - 4949; DOI:
10.1021/ja00406a050
PDF
Photosensitized oxygenation of .alpha.-diazoquinone
Wataru Ando, Hajime Miyazaki, Katsuhiko Ueno, Hachiro Nakanishi, Tosio Sakurai, and Kimiko Kobayashi
pp 4949 - 4950; DOI:
10.1021/ja00406a051
PDF
Dye-sensitized photooxygenation of 4,6-di-tert-butyl-2-diazo-1,2-benzoquinone
Hong-Son Ryang and Christopher S. Foote
pp 4951 - 4952; DOI:
10.1021/ja00406a052
PDF
Dinucleating octaaza macrocyclic ligands from simple imine condensations
Keith P. Dancey, Anne Dell, Kim Henrick, Patricia M. Judd, Philip G. Owston, Roger Peters, Peter A. Tasker, and Ralph W. Turner
pp 4952 - 4954; DOI:
10.1021/ja00406a053
PDF
Assignment of the nitrogen-15 nuclear magnetic resonances of biotin and unequivocal synthesis of (+)-[1-15N]biotin
Amy Abe, Michael Nee, John D. Roberts, Wayne L. Wittenberg, and Nelson J. Leonard
pp 4954 - 4956; DOI:
10.1021/ja00406a054
PDF
Rearrangement of vobasine to ervatamine-type alkaloids catalyzed by liver microsomes
C. Thal, M. Dufour, P. Potier, M. Jaouen, and D. Mansuy
pp 4956 - 4957; DOI:
10.1021/ja00406a055
PDF
Effect of molecular structure on mesomorphism. 12. Flexible-center Siamese-twin liquid crystalline diesters - a "prepolymer" model
Anselm C. Griffin and Thomas R. Britt
pp 4957 - 4959; DOI:
10.1021/ja00406a056
PDF
Stereocontrolled trans and cis nucleophilic attack by acetate on .pi.-allylpalladium complexes. Applications to stereoselective palladium-catalyzed 1,4-diacetoxylation of cyclic 1,3-dienes
Jan E. Baeckvall and Ruth E. Nordberg
pp 4959 - 4960; DOI:
10.1021/ja00406a057
PDF
The binary metal hydrido anion hexahydroferrate(4-). X-ray structural characterization
Robert Bau, Douglas M. Ho, and Sidney G. Gibbins
pp 4960 - 4962; DOI:
10.1021/ja00406a058
PDF
Carbenoid insertion reactions: formation of [4.1.1]propellane
David P. G. Hamon and V. Craige Trenerry
pp 4962 - 4965; DOI:
10.1021/ja00406a059
PDF
Search for singlet oxygen in the disproportionation of superoxide anion
J. M. Aubry, J. Rigaudy, C. Ferradini, and J. Pucheault
pp 4965 - 4966; DOI:
10.1021/ja00406a060
PDF
Rhodium(I)-copper(II) catalyzed oxidation of 1-hexene by oxygen using immobilized, site-separated organosulfide complexes
Eric D. Nyberg and Russell S. Drago
pp 4966 - 4968; DOI:
10.1021/ja00406a061
PDF
Synthesis and molecular structure of .mu.4-carbido-.mu.2-carbonyl-dodecacarbonyltetrairon, a neutral iron butterfly cluster bearing an exposed carbon atom
John S. Bradley, Gerald B. Ansell, Michael E. Leonowicz, and Ernestine W. Hill
pp 4968 - 4970; DOI:
10.1021/ja00406a062
PDF
Novel bay-region diol epoxides from benzo[c]phenanthrene
Jane M. Sayer, Haruhiko Yagi, Martine Croisy-Delcey, and Donald M. Jerina
pp 4970 - 4972; DOI:
10.1021/ja00406a063
PDF
Acyclic stereoselection. 14. O-alkyllactic acid esters: reagents for the stereoselective construction of erythro- and threo-.alpha.-methyl-.alpha.,.beta.-dihydroxy carbonyl compounds
Clayton H. Heathcock, James P. Hagen, Esa T. Jarvi, Michael C. Pirrung, and Steven D. Young
pp 4972 - 4974; DOI:
10.1021/ja00406a064
PDF
Nitrone cycloaddition. New approach to .beta.-lactams
Albert Padwa, Konrad Koehler, and Augusto Rodriguez
pp 4974 - 4975; DOI:
10.1021/ja00406a065
PDF
Regiocontrolled hydration of 2-butyne-1,4-diol derivatives to give 4,5-dihydro-3(2H)-furanones. Practical synthesis of bullatenone and geiparvarin
Hiroyuki Saimoto, Tamejiro Hiyama, and Hitosi Nozaki
pp 4975 - 4977; DOI:
10.1021/ja00406a066
PDF
Photoexcitation of nonconjugated, strained, saturated hydrocarbons. Relationship between ease of oxidation and the quenching of naphthalene fluorescence by saturated hydrocarbons
Paul G. Gassman, Kurt D. Olson, Lee Walter, and Ryohei Yamaguchi
pp 4977 - 4979; DOI:
10.1021/ja00406a067
PDF
Synthesis and characterization of "long-chain" alkylidene-bridged hetero bimetallic complexes
Frederick W. Hartner and Jeffrey Schwartz
pp 4979 - 4981; DOI:
10.1021/ja00406a068
PDF
Bis(triphenylphosphine) iminium nitrite, mild, versatile nitrosylating reagent
Robert E. Stevens, Timothy J. Yanta, and Wayne L. Gladfelter
pp 4981 - 4982; DOI:
10.1021/ja00406a069
PDF
Direct evidence supporting a single electron transfer pathway in the reduction of ketones by primary, secondary, and tertiary Grignard reagents
E. C. Ashby and A. B. Goel
pp 4983 - 4985; DOI:
10.1021/ja00406a070
PDF
Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination
Tadao Yoshida and Eiichi Negishi
pp 4985 - 4987; DOI:
10.1021/ja00406a071
PDF
Book Reviews

pp 4987 - 4988; DOI:
10.1021/ja00406a601
PDF

Issue 17


Structure of spiropentane: an NMR study
William Bechtold and J. H. Goldstein
pp 4989 - 4991; DOI:
10.1021/ja00407a001
PDF
Investigation of the structure of zeolites by solid-state high-resolution silicon-29 NMR spectroscopy
E. Lippmaa, M. Maegi, A. Samoson, M. Tarmak, and G. Engelhardt
pp 4992 - 4996; DOI:
10.1021/ja00407a002
PDF
1,2-Dilithioethane. A molecular orbital study
Alexander J. Kos, Eluvathingal D. Jemmis, Paul von Rague Schleyer, Rolf Gleiter, Ursula Fischbach, and John A. Pople
pp 4996 - 5002; DOI:
10.1021/ja00407a003
PDF
Theoretical study of the core binding energies of ozone and oxygen difluoride
C. S. Ewig, R. D. Mathews, and M. S. Banna
pp 5002 - 5004; DOI:
10.1021/ja00407a004
PDF
Optical rotatory dispersion studies. 134. Absolute configuration and circular dichroism spectrum of (R)-[2-2H1]cyclopentanone. Demonstration of a conformational isotope effect
P. Sundararaman, Guenter Barth, and Carl Djerassi
pp 5004 - 5007; DOI:
10.1021/ja00407a005
PDF
Polymer films on electrodes. 5. Electrochemistry and chemiluminescence at Nafion-coated electrodes
Israel Rubinstein and Allen J. Bard
pp 5007 - 5013; DOI:
10.1021/ja00407a006
PDF
Empirical force field calculations. 10. Conformational analysis of cis-decalin
Jan M. A. Baas, Bastiaan Van de Graaf, Dirk Tavernier, and Paul Vanhee
pp 5014 - 5021; DOI:
10.1021/ja00407a007
PDF
Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability
Christian Amatore and Jean Michel Saveant
pp 5021 - 5023; DOI:
10.1021/ja00407a008
PDF
Theory of proton hyperfine interaction in high-spin five- and six-liganded iron and manganese heme systems
S. K. Mun, Mahendra K. Mallick, Shantilata Mishra, Jane C. Chang, and T. P. Das
pp 5024 - 5031; DOI:
10.1021/ja00407a009
PDF
Gas-phase chemiionization reactions of antimony pentafluoride
L. Lee, J. Russell, R. T. M. Su, R. J. Cross, and M. Saunders
pp 5031 - 5034; DOI:
10.1021/ja00407a010
PDF
Gas-phase elimination reactions of ethers induced by amide and hydroxide ions
C. H. DePuy and Veronica M. Bierbaum
pp 5034 - 5038; DOI:
10.1021/ja00407a011
PDF
Phenylalanine ring dynamics by solid-state deuterium NMR
C. M. Gall, J. A. DiVerdi, and S. J. Opella
pp 5039 - 5043; DOI:
10.1021/ja00407a012
PDF
Mechanism of photooxygenation reactions. Computational evidence against the diradical mechanism of singlet oxygen ene reactions
K. Yamaguchi, S. Yabushita, T. Fueno, and K. N. Houk
pp 5043 - 5046; DOI:
10.1021/ja00407a013
PDF
Origin of the pyramidalization of the tert-butyl radical
Michael N. Paddon-Row and K. N. Houk
pp 5046 - 5049; DOI:
10.1021/ja00407a014
PDF
Carbene singlet-triplet gaps. Linear correlations with substituent .pi.-donation
Paul H. Mueller, Nelson G. Rondan, K. N. Houk, James F. Harrison, Dwight Hooper, Barry H. Willen, and Joel F. Liebman
pp 5049 - 5052; DOI:
10.1021/ja00407a015
PDF
Delocalized dicarbanions and higher delocalized carbanions
Robert B. Bates, B. Andes Hess, Craig A. Ogle, and L. J. Schaad
pp 5052 - 5058; DOI:
10.1021/ja00407a016
PDF
Isotope selective soft multiphoton ionization and fragmentation of polyatomic molecules
U. Boesl, H. J. Neusser, and E. W. Schlag
pp 5058 - 5060; DOI:
10.1021/ja00407a017
PDF
Substituent effect on the fifth overtones of the aryl carbon-hydrogen stretching vibrations in disubstituted benzenes
Yoshihiro Mizugai, Mikio Katayama, and Naoya Nakagawa
pp 5061 - 5063; DOI:
10.1021/ja00407a018
PDF
The absorption and circular dichroism spectra of chiral triquinacenes
Leo A. Paquette, Francis R. Kearney, Alex F. Drake, and Stephen F. Mason
pp 5064 - 5069; DOI:
10.1021/ja00407a019
PDF
Resonance Raman spectra of excited triplet state all-trans-retinal
G. H. Atkinson, J. B. Pallix, T. B. Freedman, D. A. Gilmore, and R. Wilbrandt
pp 5069 - 5072; DOI:
10.1021/ja00407a020
PDF
Applications of magnetic circular dichroism spectroscopy: excited states of oxocarbon dianions
Robert West, John W. Downing, Satoshi Inagaki, and Josef Michl
pp 5073 - 5078; DOI:
10.1021/ja00407a021
PDF
Experimental and theoretical evidence for double bonds between metal atoms. Dinuclear alkoxo-bridged ditungsten(IV,IV) complexes W2Cl4(OR)4(ROH)2
Lori Beth Anderson, F. Albert Cotton, David DeMarco, Anne Fang, William H. Ilsley, Brian W. S. Kolthammer, and Richard A. Walton
pp 5078 - 5086; DOI:
10.1021/ja00407a022
PDF
Electronic structure of metalloporphyrins. 1. Experimental electron density distribution of (meso-tetraphenylporphinato)cobalt(II)
Edwin D. Stevens
pp 5087 - 5095; DOI:
10.1021/ja00407a023
PDF
Polystyrene-bearing cyclopentadienyl metal catalysts: copolymerization of a styrene monomer containing cyclopentadiene synthons
Akira Sekiya and J. K. Stille
pp 5096 - 5100; DOI:
10.1021/ja00407a024
PDF
Alkylation of tin by alkylcobalamins. Kinetics and mechanism
Y. T. Fanchiang and J. M. Wood
pp 5100 - 5103; DOI:
10.1021/ja00407a025
PDF
Novel boron-to-sulfur alkyl group transfer in reactions of lithium triethylborohydride-derived bis(.mu.-thiolato)bis(tricarbonyliron) dianion with mercuric chloride and alkylmercuric chlorides
Dietmar Seyferth, Li-Cheng Song, and Richard S. Henderson
pp 5103 - 5107; DOI:
10.1021/ja00407a026
PDF
Synthesis and characterization of a novel family of dimeric nickel(II) complexes - bimetallic species separated by a persistent void
Daryle H. Busch, Gary G. Christoph, L. Lawrence Zimmer, Susan C. Jackels, Joseph J. Grzybowski, Robert C. Callahan, Massaki Kojima, Katherine Anne Holter, Jan Mocak, and et al.
pp 5107 - 5114; DOI:
10.1021/ja00407a027
PDF
Complexes of functional phosphines. 4. Coordination properties of (diphenylphosphino)acetonitrile, ethyl (diphenylphosphino)acetate and corresponding carbanions. Characterization of a new facile reversible carbon dioxide insertion into palladium(II) complexes
Pierre Braunstein, Dominique Matt, Yves Dusausoy, Jean Fischer, Andre Mitschler, and Louis Ricard
pp 5115 - 5125; DOI:
10.1021/ja00407a028
PDF
Preparation, hydrogen-1 NMR spectrum and structure of cis-diamminebis(1-methylcytosine)platinum(II) nitrate-1-methylcytosine. Cis steric effects in pyrimidine ring-bound cis-bis(nucleic acid base)platinum(II) compounds
John D. Orbell, Luigi G. Marzilli, and Thomas J. Kistenmacher
pp 5126 - 5133; DOI:
10.1021/ja00407a029
PDF
Ferric ion-specific sequestering agents. 7. Synthesis, iron-exchange kinetics, and stability constants of N-substituted, sulfonated catechoylamide analogs of enterobactin
Vincent L. Pecoraro, Frederick L. Weit, and Kenneth N. Raymond
pp 5133 - 5140; DOI:
10.1021/ja00407a030
PDF
High-resolution solid-state carbon-13 NMR. Conformational studies of NADH and NAD+ model systems
Gary R. Hays, Rob Huis, Brian Coleman, Derek Clague, Jan W. Verhoeven, and Frank Rob
pp 5140 - 5146; DOI:
10.1021/ja00407a031
PDF
Geometric isomerism in quinolylmethylenes
Richard S. Hutton, Heinz D. Roth, Marcia L. Manion Schilling, and J. William Suggs
pp 5147 - 5151; DOI:
10.1021/ja00407a032
PDF
Radiolysis of water vapor and a surface-catalyzed isotope-exchange reaction
Helen W. Richter and R. F. Firestone
pp 5152 - 5160; DOI:
10.1021/ja00407a033
PDF
Temperature and pressure dependences of thermal cis-to-trans isomerization of azobenzenes which evidence an inversion mechanism
Tsutomu Asano, Toshio Okada, Seiji Shinkai, Kazuyoshi Shigematsu, Yumiko Kusano, and Osamu Manabe
pp 5161 - 5165; DOI:
10.1021/ja00407a034
PDF
Neutron and x-ray diffraction studies of tris(methyldiphenylphosphine)[tetrahydroborato(1-)]copper, Cu[P(C6H5)2CH3]3(BH4). The first accurate characterization of an unsupported metal-hydrogen-boron bridge bond
Fusao Takusagawa, Alessandro Fumagalli, Thomas F. Koetzle, Sheldon G. Shore, Thomas Schmitkons, Albert V. Fratini, Karen W. Morse, Chiau-Yu Wei, and Robert Bau
pp 5165 - 5171; DOI:
10.1021/ja00407a035
PDF
Three-electron oxidations. 18. Carbon-13 and deuterium isotope effects in the cooxidation of 2-hydroxy-2-methylbutyric acid and 2-propanol. Evidence for a two-step mechanism
S. Ramesh, Surendra N. Mahapatra, Juei H. Liu, and Jan Rocek
pp 5172 - 5175; DOI:
10.1021/ja00407a036
PDF
Intramolecular electron transfer and SN2 reactions in the radical anions of 1-(4-biphenylyl)-.omega.-haloalkane studied by pulse radiolysis
Hitoshi Kigawa, Setsuo Takamuku, Susumu Toki, Norio Kimura, Seishi Takeda, Kunihiko Tsumori, Hiroshi Sakurai, and Hiroshi Sakurai
pp 5176 - 5179; DOI:
10.1021/ja00407a037
PDF
Oxidative carbon-carbon bond cleavage of 1,2-diols by silver(II)
Anil Kumar
pp 5179 - 5182; DOI:
10.1021/ja00407a038
PDF
Preparation of macrocyclic lactones by ring closure of cesium carboxylates
Wim H. Kruizinga and Richard M. Kellogg
pp 5183 - 5189; DOI:
10.1021/ja00407a039
PDF
Cyclopentadienylidene. A matrix isolation study exploiting photolysis with unpolarized and plane-polarized light
Mark S. Baird, Ian R. Dunkin, Nigel Hacker, Martyn Poliakoff, and James J. Turner
pp 5190 - 5195; DOI:
10.1021/ja00407a040
PDF
Oxidative cyclization of some .gamma.- and .delta.-hydroxy olefins induced by tellurium dioxide
Jan Bergman and Lars Engman
pp 5196 - 5200; DOI:
10.1021/ja00407a041
PDF
Studies on the total synthesis of chlorothricolide: stereochemical aspects of the intramolecular Diels-Alder reactions of methyl undeca-2,8,10-trienoates
William R. Roush and Steven E. Hall
pp 5200 - 5211; DOI:
10.1021/ja00407a042
PDF
Reagent design and study of p-benzoquinone derivatives as highly reactive electron-attracting dienophiles. A promising class of reagents (synthons) for cycloaddition
Ken Kanematsu, Shiro Morita, Sunao Fukushima, and Eiji Osawa
pp 5211 - 5215; DOI:
10.1021/ja00407a043
PDF
Homoazulene
Lawrence T. Scott, William R. Brunsvold, Mark A. Kirms, and Ihsan Erden
pp 5216 - 5220; DOI:
10.1021/ja00407a044
PDF
Binding of manganese(II) by tetracycline. Carbon-13 NMR spin-lattice relaxation study
Jean Y. Lee and Grover W. Everett
pp 5221 - 5225; DOI:
10.1021/ja00407a045
PDF
Electronic structure of transition-metal nitrosyls. X.alpha.-SW and configuration interaction calculations of the valence ionization potentials of tricarbonylnitrosylcobalt and tetracarbonylnitrosylmanganese
Bruce E. Bursten, J. Robert Jensen, Douglas J. Gordon, Paul M. Treichel, and Richard F. Fenske
pp 5226 - 5231; DOI:
10.1021/ja00407a046
PDF
Sch 18640. A new thiostrepton-type antibiotic
M. S. Puar, A. K. Ganguly, A. Afonso, R. Brambilla, P. Mangiaracina, O. Sarre, and R. D. MacFarlane
pp 5231 - 5233; DOI:
10.1021/ja00407a047
PDF
Cyclophane hemes. 4. Steric effects on dioxygen and carbon monoxide binding to hemes and heme proteins
T. G. Traylor, M. J. Mitchell, S. Tsuchiya, D. H. Campbell, D. V. Stynes, and N. Koga
pp 5234 - 5236; DOI:
10.1021/ja00407a048
PDF
Nonbonding steric effect on carbon monoxide and oxygen binding to hemes. Kinetics of ligand binding in iron-copper cofacial diporphyrins and strapped hemes
Brian Ward, Ching-Bore Wang, and C. K. Chang
pp 5236 - 5238; DOI:
10.1021/ja00407a049
PDF
New mechanism for photosubstitution of organometallic complexes. Generation of substitutionally labile oxidation states by excited-state electron transfer in the presence of ligands
David P. Summers, John C. Luong, and Mark S. Wrighton
pp 5238 - 5241; DOI:
10.1021/ja00407a050
PDF
R-1-Acetamido-2-phenylethaneboronic acid. A specific transition-state analog for chymotrypsin
Donald S. Matteson, Kizhakethil M. Sadhu, and Gustav E. Lienhard
pp 5241 - 5242; DOI:
10.1021/ja00407a051
PDF
Flavoprotein monooxygenases: a chemical model
John W. Frost and William H. Rastetter
pp 5242 - 5245; DOI:
10.1021/ja00407a052
PDF
Laser synthesis of metal clusters from metal carbonyl microcrystals
M. A. Duncan, T. G. Dietz, and R. E. Smalley
pp 5245 - 5246; DOI:
10.1021/ja00407a053
PDF
New layered compounds with transition-metal oxide layers separated by covalently bound organic ligands. Molybdenum and tungsten trioxide-pyridine
Jack W. Johnson, A. J. Jacobson, S. M. Rich, and J. F. Brody
pp 5246 - 5247; DOI:
10.1021/ja00407a054
PDF
Kinetics of an intraresin reaction
Steven L. Regen and Durgadas Bolikal
pp 5248 - 5249; DOI:
10.1021/ja00407a055
PDF
Tris[phenyl(difluorophosphino)amino]phosphine (P[N(C6H5)PF2]3), a novel tridentate strong .pi.-acceptor ligand forming cage chelates. Crystal structure of the chelate complex P[N(C6H5)PF2]3Mo(CO)3
George M. Brown, J. E. Finholt, R. B. King, and T. W. Lee
pp 5249 - 5250; DOI:
10.1021/ja00407a056
PDF
Synthesis of nitrogen-containing polycycles on the basis of a new method of o-quinonemethide imine generation
Yoshihiko Ito, Satoru Miyata, Masashi Nakatsuka, and Takeo Saegusa
pp 5250 - 5251; DOI:
10.1021/ja00407a057
PDF
Effect of the silicon site on the cyclization of sila-5-hexen-1-yl radicals. The unusual effect of .alpha.-silicon
James W. Wilt
pp 5251 - 5253; DOI:
10.1021/ja00407a058
PDF
Silica-bound rhodium hydride catalysts for arene hydrogenation
Michael D. Ward and Jeffrey Schwartz
pp 5253 - 5255; DOI:
10.1021/ja00407a059
PDF
A novel mode of protein-protein interaction. Water bridged cation-cation interaction in trypsin-inhibitor complex
Iwao Tabushi, Yoichi Kiyosuke, and Kazuo Yamamura
pp 5255 - 5257; DOI:
10.1021/ja00407a060
PDF
Optically detected magnetic resonance evidence for carcinogen-nucleic acid interaction in the tetrahydro-9,10-epoxy benzo(e)pyrene-DNA adduct
Steven M. Lefkowitz and Henry C. Brenner
pp 5257 - 5259; DOI:
10.1021/ja00407a061
PDF
Stereoselective synthesis of steroid side chains: a route to de-AB-cholestan-9-one
Takashi Takahashi, Haruo Yamada, and Jiro Tsuji
pp 5259 - 5261; DOI:
10.1021/ja00407a062
PDF
Simple synthesis of de-AB-cholesta-8(14),22-dien-9-one by highly stereoselective double Michael addition involving alkenylcopper-phosphine complex, vinyl ketone, and 2-methyl-2-cyclopentenone followed by Claisen rearrangement and rhodium-promoted decarbonylation
Takashi Takahashi, Yoichiro Naito, and Jiro Tsuji
pp 5261 - 5263; DOI:
10.1021/ja00407a063
PDF
A novel methoxy-directed ketal hydrolysis and its application to a convergent, regiospecific synthesis of (.+-.)-daunomycinone
Mark G. Dolson, Bertrand L. Chenard, and John S. Swenton
pp 5263 - 5264; DOI:
10.1021/ja00407a064
PDF
Phosphonium fluoride salts
Jack E. Richman and Robert B. Flay
pp 5265 - 5265; DOI:
10.1021/ja00407a065
PDF
Gas-phase nitration of aromatic radical cations
Robert J. Schmitt, D. S. Ross, and S. E. Buttrill
pp 5265 - 5267; DOI:
10.1021/ja00407a066
PDF
Reversibility of .eta.4-cyclobutadiene metal formation from complexed alkynes: unimolecular isomerization of labeled racemic and enantiomerically enriched .eta.5-cyclopentadienyl-.eta.4-cyclobutadiene-cobalt complexes
G. Ville, K. Peter C. Vollhardt, and Mark J. Winter
pp 5267 - 5269; DOI:
10.1021/ja00407a067
PDF
A new geometrical form of silicon. Synthesis and structure of tetraethylammonium bis(1,2-benzenediolato)fluorosilicate(IV)
John J. Harland, Roberta O. Day, Jean F. Vollano, Arjun C. Sau, and Robert R. Holmes
pp 5269 - 5270; DOI:
10.1021/ja00407a068
PDF

Issue 18


Theoretical ab initio study of nucleophilic substitution reactions involving radical anion intermediates
B. Bigot, D. Roux, and L. Salem
pp 5271 - 5276; DOI:
10.1021/ja00408a001
PDF
Finite perturbation-configuration interaction calculations of nuclear spin-spin coupling constants for some monosubstituted methanes
A. Laaksonen and J. Kowalewski
pp 5277 - 5283; DOI:
10.1021/ja00408a002
PDF
Ion-molecule radiative association reactions. A statistical phase-space theory model
Lewis M. Bass, Paul R. Kemper, Vincent G. Anicich, and Michael T. Bowers
pp 5283 - 5292; DOI:
10.1021/ja00408a003
PDF
Ground states of molecules. 58. The C4H4 potential surface
Herbert Kollmar, Francisco Carrion, Michael J. S. Dewar, and Richard C. Bingham
pp 5292 - 5303; DOI:
10.1021/ja00408a004
PDF
The nature of organosilane to silica-surface bonding
Thomas G. Waddell, Donald E. Leyden, and Mary T. DeBello
pp 5303 - 5307; DOI:
10.1021/ja00408a005
PDF
Watson-Crick base pairing between guanosine and cytidine studied by carbon-13 nuclear magnetic resonance spectroscopy
Steffen B. Petersen and Jens J. Led
pp 5308 - 5313; DOI:
10.1021/ja00408a006
PDF
Dissymmetric chromophores. 7. Optical activity of conjugated cisoid dienes: experimental-theoretical study of 5-alkyl-1,3-cyclohexadienes
David A. Lightner, Thomas D. Bouman, Jacek K. Gawronski, Krystyna Gawronska, Jacques L. Chappuis, B. Vincent Crist, and Aage E. Hansen
pp 5314 - 5327; DOI:
10.1021/ja00408a007
PDF
Carbon-13 exchange maps for the elucidation of chemical exchange networks
Y. Huang, S. Macura, and R. R. Ernst
pp 5327 - 5333; DOI:
10.1021/ja00408a008
PDF
The importance of hydrophobic-hydrophilic factors in binding of charged substrates to micelles: use of extramicellar probe luminescence to monitor association of cations to the micelle
Thomas K. Foreman, Warren M. Sobol, and David G. Whitten
pp 5333 - 5336; DOI:
10.1021/ja00408a009
PDF
Catalytic water reduction at colloidal metal "microelectrodes". 2. Theory and experiment
Deborah S. Miller, Allen J. Bard, George McLendon, and J. Ferguson
pp 5336 - 5341; DOI:
10.1021/ja00408a010
PDF
Ionization of normal alkanes: enthalpy, entropy, structural and isotope effects
M. Meot-Ner, L. W. Sieck, and P. Ausloos
pp 5342 - 5348; DOI:
10.1021/ja00408a011
PDF
Optical activity due to isotopic substitution. Vibrational circular dichroism and the absolute configurations of .alpha.-deuterated cyclohexanones
Prasad L. Polavarapu, Laurence A. Nafie, Steven A. Benner, and Thomas Hellman Morton
pp 5349 - 5354; DOI:
10.1021/ja00408a012
PDF
Structural studies of copper-exchanged A zeolites by electron spin echo spectrometry: absorbate interactions
Tsuneki Ichikawa and Larry Kevan
pp 5355 - 5359; DOI:
10.1021/ja00408a013
PDF
Molecular structure of gaseous cyclobutane-1,2-dione by electron diffraction
Kolbjorn Hagen and Kenneth Hedberg
pp 5360 - 5363; DOI:
10.1021/ja00408a014
PDF
Conformational studies of dihydrotetraphenylmethanes. I. X-ray crystallographic and solution hydrogen-1 NMR studies of trans-1,4-dihydro-4-tritylbiphenyl and its 4'-bromo derivatives: boat-boat inversion in a congested cyclohexa-1,4-diene
Anthony K. Cheetham, Martin C. Grossel, and John M. Newsam
pp 5363 - 5372; DOI:
10.1021/ja00408a015
PDF
Electronic structure of vinylamine. Proton affinity and conformational analysis
Robert A. Eades, David A. Weil, Mark R. Ellenberger, William E. Farneth, David A. Dixon, and Charles H. Douglass
pp 5372 - 5377; DOI:
10.1021/ja00408a016
PDF
Proton affinities and the site of protonation of enamines in the gas phase
Mark R. Ellenberger, David A. Dixon, and William E. Farneth
pp 5377 - 5382; DOI:
10.1021/ja00408a017
PDF
NMR studies of low-spin ferric complexes of natural porphyrin derivatives. 4. Proton relaxation characterization of the dimer structure of dicyanohemin in aqueous solution
Gerd N. La Mar, M. J. Minch, and J. S. Frye
pp 5383 - 5388; DOI:
10.1021/ja00408a018
PDF
Substituent dependence of the selectivity in alkene bromination through bromocarbenium ions
Elisabeth Bienvenue-Goetz and Jacques Emile Dubois
pp 5388 - 5392; DOI:
10.1021/ja00408a019
PDF
Kinetics and thermodynamics of keto-enol tautomerism of simple carbonyl compounds: an approach based on a kinetic study of halogenation at low halogen concentrations
Jacques Emile Dubois, Mohiedine El-Alaoui, and Jean Toullec
pp 5393 - 5401; DOI:
10.1021/ja00408a020
PDF
Formation of stable bilayer assemblies in water from single-chain amphiphiles. Relationship between the amphiphile structure and the aggregate morphology
Toyoki Kunitake, Yoshio Okahata, Masatsugu Shimomura, Shoichiro Yasunami, and Kunihide Takarabe
pp 5401 - 5413; DOI:
10.1021/ja00408a021
PDF
Flash vacuum thermolysis of 1,3-dioxolan-4-ones
Tim B. Cameron, Fiesal M. El-Kabbani, and Harold W. Pinnick
pp 5414 - 5417; DOI:
10.1021/ja00408a022
PDF
Proton-transfer reactions. I. Partitioning of carbanion intermediates generated by reactions of alkenes with alkoxide ions in alcohol
H. F. Koch, J. G. Koch, D. B. Donovan, A. G. Toczko, and A. J. Kielbania
pp 5417 - 5423; DOI:
10.1021/ja00408a023
PDF
Proton-transfer reactions. II. Effects of internal return on reactivity difference between alkoxide-promoted eliminations in tert-butyl alcohol and ethyl alcohol
H. F. Koch, W. Tumas, and R. Knoll
pp 5423 - 5429; DOI:
10.1021/ja00408a024
PDF
Extended unsaturated carbenes. Novel silicon, germanium, and tin-functionalized cumulenes, R2C:C:C:CHMR'3 via insertion of alkadienylidenecarbenes into Group (IV) hydrides
Peter J. Stang and Mitchell R. White
pp 5429 - 5433; DOI:
10.1021/ja00408a025
PDF
Photochemical reactivity of the di-tert-butyl nitroxide .pi.,.pi.* state and di-tert-butyl nitroxide halocarbon charge-transfer excited states
Joseph S. Keute, David Richard Anderson, and Tad H. Koch
pp 5434 - 5439; DOI:
10.1021/ja00408a026
PDF
Reactivity control in micelles and surfactant vesicles. Kinetics and mechanism of base-catalyzed hydrolysis of 5,5'-dithiobis(2-nitrobenzoic acid) in water, hexadecyltrimethylammonium bromide micelles, and dioctadecyldimethylammonium chloride surfactant vesicles
Janos H. Fendler and Willie L. Hinze
pp 5439 - 5447; DOI:
10.1021/ja00408a027
PDF
Oxonium ions. Solvation by single acetonitrile molecules in the gas phase and by bulk solvents
J. Bromilow, J. L. M. Abboud, C. B. Lebrilla, R. W. Taft, G. Scorrano, and V. Lucchini
pp 5448 - 5453; DOI:
10.1021/ja00408a028
PDF
Lanthanoids in organic synthesis. 6. Reduction of .alpha.-enones by sodium borohydride in the presence of lanthanoid chlorides: synthetic and mechanistic aspects
Andre L. Gemal and Jean Louis Luche
pp 5454 - 5459; DOI:
10.1021/ja00408a029
PDF
Synthesis of halo enol lactones. Mechanism-based inactivators of serine proteases
Grant A. Krafft and John A. Katzenellenbogen
pp 5459 - 5466; DOI:
10.1021/ja00408a030
PDF
The SN2-SN1 spectrum. 3. Solvolyses of secondary and tertiary alkyl sulfonates in fluorinated alcohols. Further evidence for the SN2 (intermediate) mechanism
T. William Bentley, Christine T. Bowen, David H. Morten, and Paul von Rague Schleyer
pp 5466 - 5475; DOI:
10.1021/ja00408a031
PDF
Mechanism of formation of Grignard reagents. Rate of reaction of cyclopentyl bromide with a rotating disk of magnesium
Karen S. Root, John Deutch, and George M. Whitesides
pp 5475 - 5479; DOI:
10.1021/ja00408a032
PDF
Chiral discrimination in fluorescence quenching
Takehiko Yorozu, Koichiro Hayashi, and Masahiro Irie
pp 5480 - 5484; DOI:
10.1021/ja00408a033
PDF
Determination of rate constants for electron transfer from radical anions of aromatic compounds to diaryl disulfides
Hideyuki Tagaya, Tamotsu Aruga, Osamu Ito, and Minoru Matsuda
pp 5484 - 5489; DOI:
10.1021/ja00408a034
PDF
Dissociation of O6-(p-methoxybenzyl)guanosine in aqueous solution to yield guanosine, p-methoxybenzylguanosines, and 4-(p-methoxybenzyl)-5-guanidino-1-.beta.-D-ribofuranosylimidazole
Robert C. Moschel, W. Robert Hudgins, and Anthony Dipple
pp 5489 - 5494; DOI:
10.1021/ja00408a035
PDF
Chemistry of 1-carba-1-deaza-N5-ethyl-N3-methyllumiflavins. Influence of the N1 upon the reactivity of flavin 4a-hydroperoxides
Sheldon Ball and Thomas C. Bruice
pp 5494 - 5503; DOI:
10.1021/ja00408a036
PDF
Conformational barriers in triplet 1- and 2-naphthylcarbene. 2. Absolute rate of decay of arylcarbenes by electron spin resonance spectroscopy
V. P. Senthilnathan and Matthew S. Platz
pp 5503 - 5511; DOI:
10.1021/ja00408a037
PDF
Magnetic studies and the crystal and molecular structure of [enH2][V(hedta-H)]2.cntdot.2H2O: a novel di-.mu.-alcoxy-bridged dimer of seven-coordinate vanadium(III)
Rex E. Shepherd, William E. Hatfield, Debashis Ghosh, C. David Stout, Frank J. Kristine, and J. R. Ruble
pp 5511 - 5517; DOI:
10.1021/ja00408a038
PDF
Reaction of carbon monoxide with the coordinately unsaturated metal dimer (.mu.-H)2Rh2[P(O-i-C3H7)3]4 with retention of dimeric form. Crystal and molecular structure of Rh2(.mu.-CO)2[P(O-i-C3H7)3]4
R. R. Burch, E. L. Muetterties, A. J. Schultz, E. G. Gebert, and Jack M. Williams
pp 5517 - 5522; DOI:
10.1021/ja00408a039
PDF
The reaction between sulfur dioxide and hexamethyldisilazane. 3. Characterization of ammonium (trimethylsilyl)sulfite
D. W. Bennett and L. D. Spicer
pp 5522 - 5526; DOI:
10.1021/ja00408a040
PDF
Resonance Raman studies of ferric NADH transients
O. Siiman and R. Callaghan
pp 5526 - 5529; DOI:
10.1021/ja00408a041
PDF
State of manganese in the photosynthetic apparatus. 1. Extended x-ray absorption fine structure studies on chloroplasts and di-.mu.-oxo-bridged dimanganese model compounds
J. A. Kirby, A. S. Robertson, J. P. Smith, A. C. Thompson, S. R. Cooper, and M. P. Klein
pp 5529 - 5537; DOI:
10.1021/ja00408a042
PDF
State of manganese in the photosynthetic apparatus. 2. X-ray absorption edge studies on manganese in photosynthetic membrane
J. A. Kirby, D. B. Goodin, T. Wydrzynski, A. S. Robertson, and M. P. Klein
pp 5537 - 5542; DOI:
10.1021/ja00408a043
PDF
Kinetic studies on reactions of iron-sulfur proteins. 4. Redox reactions of Chromatium vinosum HIPIP with Co(4,7-DPSphen)33-, Mn(CyDTA)(H2O)- and Fe(CN)63- (oxidants) and Fe(CN)64- (reductant)
I. Kofi Adzamli, D. Martin Davies, Carmel S. Stanley, and A. Geoffrey Sykes
pp 5543 - 5547; DOI:
10.1021/ja00408a044
PDF
The 310 helical conformation of the amino terminal decapeptide of suzukacillin. 270 MHz hydrogen-1 NMR evidence for eight intramolecular hydrogen bonds
M. Iqbal and P. Balaram
pp 5548 - 5552; DOI:
10.1021/ja00408a045
PDF
Circular dichroism of rifamycin S
P. Salvadori, C. Bertucci, C. Rosini, M. Zandomeneghi, G. G. Gallo, E. Martinelli, and P. Ferrari
pp 5553 - 5557; DOI:
10.1021/ja00408a046
PDF
Coenzyme B12 model studies: an electrochemical comparison of both alkylcobaloxime and nonalkyl cobaloxime and Co[C2(DO)(DOH)pn] complexes to coenzyme B12
C. Michael Elliott, E. Hershenhart, R. G. Finke, and B. L. Smith
pp 5558 - 5566; DOI:
10.1021/ja00408a047
PDF
Nitrogen-14 and hydrogen-1 ENDOR and TRIPLE resonance experiments of flavin and thiaflavin radical cations in liquid solution
M. Bock, W. Lubitz, H. Kurreck, H. Fenner, and R. Grauert
pp 5567 - 5568; DOI:
10.1021/ja00408a048
PDF
Stereoselective carbonyl-olefination via organosilicon compounds
Y. Yamakado, M. Ishiguro, N. Ikeda, and H. Yamamoto
pp 5568 - 5570; DOI:
10.1021/ja00408a049
PDF
Photoinduced alkylation of five-membered heteroaromatic compounds via electron-transfer reaction: heterodimer cation radical intermediacy
Kazuhiko Mizuno, Masao Ishii, and Yoshio Otsuji
pp 5570 - 5572; DOI:
10.1021/ja00408a050
PDF
Pentamethylcyclopentadienyl-substituted phosphorus and arsenic cations: evidence for multihapto bonding between Group 5A elements and carbocyclic ligands
S. G. Baxter, A. H. Cowley, and S. K. Mehrotra
pp 5572 - 5573; DOI:
10.1021/ja00408a051
PDF
Isomerization of silene to ketene in the photolysis of pentamethyldisilanyldiazoacetate
Wataru Ando, Akira Sekiguchi, and Takashi Sato
pp 5573 - 5574; DOI:
10.1021/ja00408a052
PDF
Observation of a very large orbital interaction through four bonds. An alternative model of orbital interactions through bonds
Michael N. Paddon-Row, Harish K. Patney, R. S. Brown, and K. N. Houk
pp 5575 - 5577; DOI:
10.1021/ja00408a053
PDF
Oxidation of coordinated ammonia to nitrate
Mark S. Thompson and Thomas J. Meyer
pp 5577 - 5579; DOI:
10.1021/ja00408a054
PDF
Synthesis applications of aza-Cope rearrangements. Stereoselective synthesis of cis-3a-aryloctahydroindoles and a new short entry to Amaryllidaceae alkaloids
Larry E. Overman and Leah T. Mendelson
pp 5579 - 5581; DOI:
10.1021/ja00408a055
PDF
Synthesis and structure of the distorted tetrahedral cluster [(.eta.5-C5H5)4Cr4O4], the third member of the [(.eta.5-C5H5)mMmOn] series where n and m satisfy Euler's theorem
Frank Bottomley, Daniel E. Paez, and Peter S. White
pp 5581 - 5582; DOI:
10.1021/ja00408a056
PDF
Some geometrical and electronic features of the intermediate stages of olefin metathesis
Odile Eisenstein, Roald Hoffmann, and Angelo R. Rossi
pp 5582 - 5584; DOI:
10.1021/ja00408a057
PDF
Substituent effects in metallacyclobutenes. Contributions from a metal-methylene-acetylene adduct form
R. J. McKinney, T. H. Tulip, D. L. Thorn, T. S. Coolbaugh, and F. N. Tebbe
pp 5584 - 5586; DOI:
10.1021/ja00408a058
PDF
Efficient upper excited-state ligand photochemistry in pentammineruthenium(II)-acylpyridine complexes
Peter J. Wagner and Rosemary Bartoszek-Loza
pp 5587 - 5588; DOI:
10.1021/ja00408a059
PDF
Reaction of (CH3)3SnM and Ph3SnM (M = lithium, sodium, potassium) with optically active 2-octyl tosylate, chloride, and bromide
Joseph San Filippo and Joseph Silbermann
pp 5588 - 5590; DOI:
10.1021/ja00408a060
PDF
A chiroptical method for determining the absolute configuration of allylic alcohols
Nobuyuki Harada, Jun Iwabuchi, Yoichi Yokota, Hisashi Uda, and Koji Nakanishi
pp 5590 - 5591; DOI:
10.1021/ja00408a061
PDF
Additivity relation found in the amplitudes of exciton-split circular dichroism curves of pyranose benzoates
Hung-Wen Liu and Koji Nakanishi
pp 5591 - 5593; DOI:
10.1021/ja00408a062
PDF
Allylic rearrangements in the thermal decarbonylation of (2-cyclopropene-1-carbonyl)rhenium compounds; nonfluxional .eta.1-cyclopropenylrhenium compounds
Peter J. Desrosiers and Russel P. Hughes
pp 5593 - 5594; DOI:
10.1021/ja00408a063
PDF
Spherands, the first ligand systems fully organized during synthesis rather than during complexation
Kenneth N. Trueblood, Carolyn B. Knobler, Emily Maverick, Roger C. Helgeson, S. Bruce Brown, and Donald J. Cram
pp 5594 - 5596; DOI:
10.1021/ja00408a064
PDF
Transition-metal-mediated hydrogenation of carbon monoxide to olefins: intermediacy of coordinated carbenes
John A. Marsella, Kirsten Folting, John C. Huffman, and Kenneth G. Caulton
pp 5596 - 5598; DOI:
10.1021/ja00408a065
PDF
Perfluoroallyl fluorosulfate, a reactive new perfluoroallylating agent
Carl G. Krespan and David V. England
pp 5598 - 5599; DOI:
10.1021/ja00408a066
PDF
Total synthesis of the quinonoid alcohol dehydrogenase coenzyme (1) of methylotrophic bacteria
E. J. Corey and Alfonso Tramontano
pp 5599 - 5600; DOI:
10.1021/ja00408a067
PDF
Oxidative addition of allyl acetate to palladium(0) complexes
Takakazu Yamamoto, Osamu Saito, and Akio Yamamoto
pp 5600 - 5602; DOI:
10.1021/ja00408a068
PDF
Ultra-high field NMR spectroscopy: observation of proton-proton dipolar coupling in paramagnetic bis[tolyltris(pyrazolyl)borato]cobalt(II)
Aksel A. Bothner-By, Peter J. Domaille, and C. Gayathri
pp 5602 - 5603; DOI:
10.1021/ja00408a069
PDF
Reduction of bis(cyclooctatetraene)uranium
F. Billiau, G. Folcher, H. Marquet-Ellis, P. Rigny, and E. Saito
pp 5603 - 5604; DOI:
10.1021/ja00408a070
PDF
Ptilocaulin and isoptilocaulin, antimicrobial and cytotoxic cyclic guanidines from the Caribbean sponge Ptilocaulis aff. P. spiculifer (Lamarck, 1814)
Gary C. Harbour, Adrienne A. Tymiak, Kenneth L. Rinehart, Paul D. Shaw, Robert Hughes, Stephen A. Mizsak, John H. Coats, Gary E. Zurenko, Li H. Li, and Sandra L. Kuentzel
pp 5604 - 5606; DOI:
10.1021/ja00408a071
PDF
Palladium(0) catalyzed reaction of 1,4-epiperoxides. Conversion of a prostaglandin endoperoxide to primary prostaglandins
M. Suzuki, R. Noyori, and N. Hamanaka
pp 5606 - 5607; DOI:
10.1021/ja00408a072
PDF
Three rational syntheses of new stable metal .alpha.-hydroxyalkyl complexes
George D. Vaughn and J. A. Gladysz
pp 5608 - 5609; DOI:
10.1021/ja00408a073
PDF
Efficient and accurate calculation of anion proton affinities
Jayaraman Chandrasekhar, Juan G. Andrade, and Paul von Rague Schleyer
pp 5609 - 5612; DOI:
10.1021/ja00408a074
PDF
Thermodynamic stability of carbonyl anions, R-.hivin.C:O. A molecular orbital examination
Jayaraman Chandrasekhar, Juan G. Andrade, and Paul von Rague Schleyer
pp 5612 - 5614; DOI:
10.1021/ja00408a075
PDF
Stereochemistry of ribostamycin biosynthesis. Application of hydrogen-2 NMR spectroscopy
Katsumi Kakinuma, Yasuaki Ogawa, Tohru Sasaki, Haruo Seto, and Noboru Otake
pp 5614 - 5616; DOI:
10.1021/ja00408a076
PDF
N21,N22 Cis-bridged tetraarylporphyrins from oxidation of tetraarylporphinatoiron(II)-carbene complexes
Thomas J. Wisnieff, Avram Gold, and Slayton A. Evans
pp 5616 - 5618; DOI:
10.1021/ja00408a077
PDF
Symmetry in synthesis. Preparation and methylation of spiro dilactones
Thomas R. Hoye, David R. Peck, and Peter K. Trumper
pp 5618 - 5620; DOI:
10.1021/ja00408a078
PDF
Synthesis and characterization of a cyclic bimetallic complex of the trisulfide ion
C. Mark Bolinger, Thomas B. Rauchfuss, and Scott R. Wilson
pp 5620 - 5621; DOI:
10.1021/ja00408a079
PDF
Synthesis of the left-hand segment of the antitumor agent CC-1065
Wendell Wierenga
pp 5621 - 5623; DOI:
10.1021/ja00408a080
PDF
Additions and Corrections - Photochemistry of Cis-Fused Bicyclo[4.n.0]-2,4-dienes. Ground State Conformational Control
William G. Dauben, and Michael S. Kellogg
pp 5623 - 5623; DOI:
10.1021/ja00408a600
PDF
Additions and Corrections - Crystal and Molecular Structure of Cofacial Dicopper Hexyldiporphyrin-7
Marcos H. Hatada, A. Tulinsky, and C. K. Chang
pp 5623 - 5623; DOI:
10.1021/ja00408a601
PDF
Additions and Corrections - Pauling "3-Electron Bonds", "Increased-Valence", and 6-Electron 4-Center Bonding
Richard D. Harcourt
pp 5623 - 5623; DOI:
10.1021/ja00408a602
PDF
Additions and Corrections - Evidence for an Electron-Transfer Mechanism in the Reduction of Ketones by Main Group Metal Hydrides.
Eugene C. Ashby, Anil B. Goel, and Robert N. DePriest
pp 5623 - 5623; DOI:
10.1021/ja00408a603
PDF
Additions and Corrections - Accurate and Sensitive Determination, by a New Cobalt-59 Nuclear Magnetic Resonance Method, of Electron Acceptance and Hydrogen Bond Donation by Protic Solvents
Pierre Laszlo, and Armel Stockis
pp 5623 - 5623; DOI:
10.1021/ja00408a604
PDF
Additions and Corrections - Deactivation of the Fluorescent State of 9-tert-Butylanthracene. 9-tert-Butyl-9,10-(Dewar anthracene)
H. Gusten, M. Mintas, and L. Klasinc
pp 5624 - 5624; DOI:
10.1021/ja00408a605
PDF
Additions and Corrections - Dianions of 2-Methyl-2-butene: Evidence for the Stability of a "Y-Aromatic" Species
Nancy S. Mills, James Shapiro, and Mark Hollingsworth
pp 5624 - 5624; DOI:
10.1021/ja00408a606
PDF
Additions and Corrections - Binuclear Copper Complexes: An Open and Shut Case. A Strong Antiferromagnetically Coupled μ-Monohydroxo Bridged Complex
Patrick L. Burk, John A. Osborn, Marie-Thérèse Youinou, Yvette Agnus, Rémy Louis, and Raymond Weiss
pp 5624 - 5624; DOI:
10.1021/ja00408a607
PDF
Additions and Corrections - Carbon-Phosphorous Heterocycles. Synthesis of Phosphorus-Containing Cannabinoid Precursors and a Single-Crystal Analysis of 1,2,3,4-Tetrahydro-10-hydroxy-8-n-pentyl-5H-phosphorino-[3,4-c[1])benzopyran-5-one-3-Oxide
Jang B. Rampal, K. Danell Berlin, Nantelle S. Pantales, Ann McGuffy, and Dick Van Der Helm
pp 5624 - 5624; DOI:
10.1021/ja00408a608
PDF
Additions and Corrections - Synthesis and Reactions of a Binuclear Cobalt Bridging Methylene (μ-CH2) Complex. Conversion to μ-CH2 Rh/Co and Rh/Rh Complexes and Methylene Transfer to Ethylene Involving Activation by a Second Metal Complex
Klaus H. Theopold, and Robert G. Bergman
pp 5624 - 5624; DOI:
10.1021/ja00408a609
PDF
Book Reviews

pp 5624 - 5628; DOI:
10.1021/ja00408a610
PDF

Issue 19


Natural-abundance nitrogen-15 nuclear magnetic resonance spectroscopy. Chemical shifts of methyl-substituted trans-decahydroquinolines.
Friedrich W. Vierhapper, George T. Furst, Robert L. Lichter, Samuel N. Y. Fanso-Free, and Ernest L. Eliel
pp 5629 - 5632; DOI:
10.1021/ja00409a001
PDF
Oxygen-18 isotope-induced shifts in nitrogen-15 nuclear magnetic resonance spectroscopy. 1. Isotope shift in nitrite and its application to the study of oxygen exchange of sodium [15N,18O2]nitrite
Robert L. Van Etten and John M. Risley
pp 5633 - 5636; DOI:
10.1021/ja00409a002
PDF
Use of magnetic circular dichroism to determine axial ligation for some sterically encumbered iron(II) porphyrin complexes
James P. Collman, Fred Basolo, Edward Bunnenberg, Terrence J. Collins, John H. Dawson, Paul E. Ellis, Matthew L. Marrocco, Albert Moscowitz, Jonathan L. Sessler, and Thomas Szymanski
pp 5636 - 5648; DOI:
10.1021/ja00409a003
PDF
Molecular orbital theory of the electronic structure of organic molecules. 40. Structures and energies of C1-C3 carbocations including effects of electron correlation
Krishnan Raghavachari, Robert A. Whiteside, John A. Pople, and Paul V. R. Schleyer
pp 5649 - 5657; DOI:
10.1021/ja00409a004
PDF
First determination of the structure of an ion-paired species in nonpolar media: hydrogen-1, carbon-13, lithium-7 NMR spectra of peralkylcyclohexadienyl lithium compounds
Gideon Fraenkel and Michael P. Hallden-Abberton
pp 5657 - 5664; DOI:
10.1021/ja00409a005
PDF
Structure of moderately strong acids in aqueous solution
Robert I. Gelb, Lowell M. Schwartz, and Daniel A. Laufer
pp 5664 - 5673; DOI:
10.1021/ja00409a006
PDF
Formation and structure of C2H4N+. Effect of pressure and reaction exothermicity on collision-induced dissociation spectra
A. J. Illies, Shuying Liu, and M. T. Bowers
pp 5674 - 5676; DOI:
10.1021/ja00409a007
PDF
Diborane(4) (B2H4): the boron hydride analog of ethylene
Mark A. Vincent and Henry F. Schaefer
pp 5677 - 5680; DOI:
10.1021/ja00409a008
PDF
Bis(cyclobutadiene)nickel: geometrical and electronic structure
Russell M. Pitzer, John D. Goddard, and Henry F. Schaefer
pp 5681 - 5685; DOI:
10.1021/ja00409a009
PDF
Comparison of equilibrium constants in gas and liquid phases
S. E. Stein
pp 5685 - 5690; DOI:
10.1021/ja00409a010
PDF
Effects of N7 platinum binding on the hydrogen-bonding behavior of 9-ethylguanine
Bernhard Lippert
pp 5691 - 5697; DOI:
10.1021/ja00409a011
PDF
Binding site of the antibiotic vancomycin for a cell-wall peptide analog
Dudley H. Williams and David W. Butcher
pp 5697 - 5700; DOI:
10.1021/ja00409a012
PDF
Fast atom bombardment mass spectrometry: a powerful technique for the study of polar molecules
Dudley H. Williams, Carol Bradley, Gustav Bojesen, Sitthivet Santikarn, and Lester C. E. Taylor
pp 5700 - 5704; DOI:
10.1021/ja00409a013
PDF
Unified theory of aromaticity and London diamagnetism
Junichi Aihara
pp 5704 - 5706; DOI:
10.1021/ja00409a014
PDF
Isotopic shifts in chemical exchange systems. I. Large isotope effects in the complexation of sodium(1+) isotopes by macrocyclic polyethers
Arndt Knoechel and Rolf Dieter Wilken
pp 5707 - 5711; DOI:
10.1021/ja00409a015
PDF
Microwave spectrum and unusual geometry of propadienone (methylene ketene)
Ronald D. Brown, Peter D. Godfrey, Robert Champion, and Donald McNaughton
pp 5711 - 5715; DOI:
10.1021/ja00409a016
PDF
Spectroscopic studies on the interaction of the antibiotic lasalocid A (X537A) with lanthanide(III) ions in methanol
Frederick S. Richardson and Anupam Das Gupta
pp 5716 - 5725; DOI:
10.1021/ja00409a017
PDF
The potential surface for the cyclobutadiene radical cation
Weston Thatcher Borden, Ernest R. Davidson, and David Feller
pp 5725 - 5729; DOI:
10.1021/ja00409a018
PDF
Location and relative orientation of methanol adsorbate molecules in A, X, and Y zeolites from electron spin-echo studies
M. Narayana and Larry Kevan
pp 5729 - 5733; DOI:
10.1021/ja00409a019
PDF
Mechanism of oxidation of an amine coordinated to ruthenium
Michael J. Ridd and F. Richard Keene
pp 5733 - 5740; DOI:
10.1021/ja00409a020
PDF
Mechanism and kinetics of the homogeneous gas-phase thermal decomposition of methylgermane
J. Dzarnoski, H. E. O'Neal, and M. A. Ring
pp 5740 - 5746; DOI:
10.1021/ja00409a021
PDF
Structural correlation and metal ion movement in stable pentaammineruthenium(III)-hypoxanthine complexes
M. E. Kastner, K. F. Coffey, M. J. Clarke, S. E. Edmonds, and K. Eriks
pp 5747 - 5752; DOI:
10.1021/ja00409a022
PDF
Trigonal-bipyramidal bis(neopentylidene), neopentylidene/ethylene, and bis(ethylene) complexes of tantalum and how they react with ethylene. A catalyst for rapidly dimerizing ethylene to 1-butene
J. D. Fellmann, R. R. Schrock, and G. A. Rupprecht
pp 5752 - 5758; DOI:
10.1021/ja00409a023
PDF
Thioether ligation in iron-porphyrin complexes: models for cytochrome c
Toshio Mashiko, Christopher A. Reed, Kenneth J. Haller, Margaret E. Kastner, and W. Robert Scheidt
pp 5758 - 5767; DOI:
10.1021/ja00409a024
PDF
Calorimetric study of the oxidative addition of acyl chlorides to iridium(I) complexes in solution, the standard state and the gas phase
Gerald Yoneda, Szu-Min Lin, Lou-Pin Wang, and Daniel M. Blake
pp 5768 - 5771; DOI:
10.1021/ja00409a025
PDF
A highly distorted octahedral d4 compound, cis-Mo(tert-BuS)2(tert-BuNC)4
Masato Kamata, Ken Hirotsu, Taiichi Higuchi, Kazuyuki Tatsumi, Roald Hoffmann, Toshikatsu Yoshida, and Sei Otsuka
pp 5772 - 5778; DOI:
10.1021/ja00409a026
PDF
Trinuclear molybdenum-molybdenum-bonded cluster cation with one oxygen atom cap and one ethylidyne cap
Avi Bino, F. Albert Cotton, Zvi Dori, and Brian W. S. Kolthammer
pp 5779 - 5784; DOI:
10.1021/ja00409a027
PDF
Micellar catalysis of dephosphorylation by benzimidazolide and naphth-2,3-imidazolide ions
Clifford A. Bunton, Young S. Hong, Laurence S. Romsted, and Clifford Quan
pp 5784 - 5788; DOI:
10.1021/ja00409a028
PDF
Catalysis by hydrophobic tetraalkylammonium ions. Dephosphorylation of p-nitrophenyl diphenyl phosphate
Clifford A. Bunton, Young S. Hong, Laurence S. Romsted, and Clifford Quan
pp 5788 - 5794; DOI:
10.1021/ja00409a029
PDF
Copper(II)-induced oxidations of aromatic substrates: catalytic conversion of catechols to o-benzoquinones. Copper phenoxides as intermediates in the oxidation of phenol, and a single-step conversion of phenol, ammonia, and oxygen into muconic acid mononitrile
Timothy R. Demmin, Michael D. Swerdloff, and Milorad M. Rogic
pp 5795 - 5804; DOI:
10.1021/ja00409a030
PDF
Crystalline state reaction of cobaloxime complexes by x-ray exposure. 1. Direct observation of cobalt-carbon bond cleavage in [(R)-1-cyanoethyl][(S)-(-)-.alpha.-methylbenzylamine]bis(dimethylglyoximato)cobalt(III)
Yuji Ohashi, Kazunori Yanagi, Toshiharu Kurihara, Yoshio Sasada, and Yoshiaki Ohgo
pp 5805 - 5812; DOI:
10.1021/ja00409a031
PDF
Convergent total synthesis of (.+-.)-colchicine and (.+-.)-desacetamidoisocolchicine
D. A. Evans, S. P. Tanis, and D. J. Hart
pp 5813 - 5821; DOI:
10.1021/ja00409a032
PDF
Synthesis of the endoperoxide anti-7,8-dioxatricyclo[4.2.2.02,5]deca-3,9-diene via singlet oxygenation of the bicyclic valence tautomer of cyclooctatetraene and its transformations
Waldemar Adam, Omar Cueto, Ottorino De Lucchi, Karl Peters, Eva-Maria Peters, and Hans Georg Von Schnering
pp 5822 - 5828; DOI:
10.1021/ja00409a033
PDF
Mechanisms of the .pi.-electron steric effect
Joseph B. Lambert and Kalulu M. Taba
pp 5828 - 5832; DOI:
10.1021/ja00409a034
PDF
Stereochemistry and mechanisms of reactions of dioxygen complexes with organic electrophiles as studied by use of chiral reagents and isotopic labeling
Y. Tatsuno and Sei Otsuka
pp 5832 - 5839; DOI:
10.1021/ja00409a035
PDF
Activation barriers for heterogeneous and homogeneous electron transfer. Experimental tests for Marcus theory in the oxidation of organometallic complexes
R. J. Klingler and J. K. Kochi
pp 5839 - 5848; DOI:
10.1021/ja00409a036
PDF
Comparative study of the cosolvent effect in tert-butyl alcohol-water solutions: the solvolyses of adamantyl bromide and cyclohexyl bromide
Yu-Chu Yang and Thomas F. Fagley
pp 5849 - 5854; DOI:
10.1021/ja00409a037
PDF
Dimers of 5,15-dioxoporphodimethenes with direct links between methine bridge carbon atoms
Juergen Hinrich Fuhrhop, Ehrenfried Baumgartner, and Hans Bauer
pp 5854 - 5861; DOI:
10.1021/ja00409a038
PDF
Substituent rate effects on the thermal isomerizations of bicyclo[3.2.0]hepta-2,6-diene
Eric W. Otterbacher and Joseph J. Gajewski
pp 5862 - 5866; DOI:
10.1021/ja00409a039
PDF
Studies on peptides. 103. Chemical synthesis of a crystalline protein with the full enzymic activity of ribonuclease A
Haruaki Yajima and Nobutaka Fujii
pp 5867 - 5871; DOI:
10.1021/ja00409a040
PDF
Evaluation of addition rates of thiyl radicals to vinyl monomers by flash photolysis. 3. Polar effect in addition reactions of substituted benzenethiyl radicals
Osamu Ito and Minoru Matsuda
pp 5871 - 5874; DOI:
10.1021/ja00409a041
PDF
Azulene thermal rearrangements. Carbon-13 labeling studies of automerization and isomerization to naphthalene
Lawrence T. Scott and Mark A. Kirms
pp 5875 - 5879; DOI:
10.1021/ja00409a042
PDF
Crystal structure of valinomycin potassium picrate: anion effects on valinomycin cation complexes
J. A. Hamilton, M. N. Sabesan, and L. K. Steinrauf
pp 5880 - 5885; DOI:
10.1021/ja00409a043
PDF
Tetraphenylarsonium 1,2,3,4,5-pentakis(methylmercapto)cyclopentadienide
F. Wudl, D. Nalewajek, F. J. Rotella, and E. Gebert
pp 5885 - 5890; DOI:
10.1021/ja00409a044
PDF
Crystal and molecular structure of methyl bacteriopheophorbide a. A model for a primary electron acceptor in bacterial photosynthesis
K. M. Barkigia, J. Fajer, K. M. Smith, and G. J. B. Williams
pp 5890 - 5893; DOI:
10.1021/ja00409a045
PDF
Multiple structure-reactivity correlations in the hydrolysis of epimeric 2-aryloxy-2-oxy-dioxaphosphorinanes. Stereoelectronic effects
Robert Rowell and David G. Gorenstein
pp 5894 - 5902; DOI:
10.1021/ja00409a046
PDF
Crystal structures of repeating peptides of elastin. 1. N-(tert-Butoxycarbonyl)-L-valyl-L-prolylglycyl-L-valylglycine
Hiroshi Ayato, Isao Tanaka, and Tamaichi Ashida
pp 5902 - 5905; DOI:
10.1021/ja00409a047
PDF
Photostudies of 2,2'-bipyridine bis(triphenylphosphine)copper(1+), 1,10-phenanthroline bis(triphenylphosphine)copper(1+), and 2,9-dimethyl-1,10-phenanthroline bis(triphenylphosphine)copper(1+) in solution and in rigid, low-temperature glasses. Simultaneous multiple emissions from intraligand and charge-transfer states
Rosemary A. Rader, David R. McMillin, Michael T. Buckner, Thomas G. Matthews, Dominick J. Casadonte, Russell K. Lengel, Steven B. Whittaker, Lola M. Darmon, and Fred E. Lytle
pp 5906 - 5912; DOI:
10.1021/ja00409a048
PDF
Circular dichroism of (C3)-cyclotriveratrylene-d9: an example of exciton optical activity due to isotopic substitution
Andre Collet and Giovanni Gottarelli
pp 5912 - 5913; DOI:
10.1021/ja00409a049
PDF
Alternate synthetic routes to the pentacarbonylhydrides of chromium, molybdenum, and tungsten
Marcetta Y. Darensbourg and Sydney Slater
pp 5914 - 5915; DOI:
10.1021/ja00409a050
PDF
Transition-state variation in the Menshutkin reaction
J. Milton Harris, M. Steven Paley, and Thomas W. Prasthofer
pp 5915 - 5916; DOI:
10.1021/ja00409a051
PDF
Highly regiocontrolled and rapid lithiation of 3-methyl-4H-5,6-dihydro-1,2-oxazine: elaboration for .alpha.-methylene ketone synthesis
Ramy Lidor and Shimon Shatzmiller
pp 5916 - 5917; DOI:
10.1021/ja00409a052
PDF
Transition-metal-catalyzed rearrangements of oxocyclopropanes to vinyl ethers. Activation by vicinal carboalkoxy substituents
Michael P. Doyle and Daan Van Leusen
pp 5917 - 5919; DOI:
10.1021/ja00409a053
PDF
syn- and anti-Norcaradieneiron tricarbonyl
Wolfram Grimme and Hans Guenter Koeser
pp 5919 - 5920; DOI:
10.1021/ja00409a054
PDF
High-field oxygen-17 NMR spectroscopy: solution structures and dynamics of oxygen-17 enriched dodecacarbonyltetracobalt and dodecacarbonylhydroiron dicobaltate
S. Aime, D. Osella, L. Milone, G. E. Hawkes, and E. W. Randall
pp 5920 - 5922; DOI:
10.1021/ja00409a055
PDF
1,3-Dimetallacyclobutanes in metal-methylidene dimerization reactions
Kevin C. Ott and Robert H. Grubbs
pp 5922 - 5923; DOI:
10.1021/ja00409a056
PDF
Some observations concerning the temperature dependence of the reaction of ammonia with water
Michael Jesse Blandamer, Ross Elmore Robertson, John Marshall William Scott, and Peter David Golding
pp 5923 - 5925; DOI:
10.1021/ja00409a057
PDF
Nonequivalence of phosphorus-31 NMR chemical shifts of RNA complexes
James L. Alderfer and Geraldine L. Hazel
pp 5925 - 5926; DOI:
10.1021/ja00409a058
PDF
Reaction between hydroperoxo radicals and chlorine in aqueous solution
E. Bjergbakke, S. Navaratnam, B. J. Parsons, and A. J. Swallow
pp 5926 - 5928; DOI:
10.1021/ja00409a059
PDF
Resonance Raman evidence of iron pentacoordination in high-spin ferric cytochrome P-450. A comparison with model compound, iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate
Pavel Anzenbacher, Zdenek Sipal, Bohuslav Strauch, Jacek Twardowski, and Leonard M. Proniewicz
pp 5928 - 5929; DOI:
10.1021/ja00409a060
PDF
Organosilicon polymer that is derived from a mineral and is at least partly ladder-like and inherently fibrous
Jesse Hefter and Malcolm E. Kenney
pp 5929 - 5930; DOI:
10.1021/ja00409a061
PDF
Photo-CIDNP study of adenosine 5'-monophosphate. Pair-substitution effects due to cation radical deprotonation
R. M. Scheek, S. Stob, T. Schleich, N. C. M. Alma, C. W. Hilbers, and R. Kaptein
pp 5930 - 5932; DOI:
10.1021/ja00409a062
PDF
Addition of diphenylphosphine oxide to arenesulfonylhydrazones: novel adducts from tosylhydrazones and a new synthesis of alkyldiphenylphosphine oxides from trisylhydrazones
Steven H. Bertz and Gary Dabbagh
pp 5932 - 5934; DOI:
10.1021/ja00409a063
PDF
Radical-like reactions of singlet fluorenylidene. Hydrogen and halogen abstraction
P. C. Wong, D. Griller, and J. C. Scaiano
pp 5934 - 5935; DOI:
10.1021/ja00409a064
PDF
Carbenes and the oxygen-hydrogen bond: cyclopentadienylidene and cycloheptatrienylidene
Wolfgang Kirmse, Karin Loosen, and Heinz Dieter Sluma
pp 5935 - 5937; DOI:
10.1021/ja00409a065
PDF
Catalysis of the hydrolysis of ethyl benzoate by inverted micelles adsorbed on platinum
Thomas C. Franklin and Maurice Iwunze
pp 5937 - 5938; DOI:
10.1021/ja00409a066
PDF
Hexapus, a new complexing agent for organic molecules
F. M. Menger, M. Takeshita, and J. F. Chow
pp 5938 - 5939; DOI:
10.1021/ja00409a067
PDF
Chemical model studies for the mechanism of vitamin K epoxide reductase
Richard B. Silverman
pp 5939 - 5941; DOI:
10.1021/ja00409a068
PDF
Chelating phosphinite complexes of Group 6 metal carbonyls with crown-ether-type characteristics. Effect of preferential cation binding on the reactivity of coordinated carbon monoxide
John Powell, Anda Kuksis, Christopher J. May, Stanley C. Nyburg, and Stuart J. Smith
pp 5941 - 5943; DOI:
10.1021/ja00409a069
PDF
Autorecycling oxidation of alcohols catalyzed by pyridodipyrimidines as an NAD(P)+ model
Fumio Yoneda, Hirotake Yamato, and Masami Ono
pp 5943 - 5945; DOI:
10.1021/ja00409a070
PDF
Vesicles of polymeric bilayer and monolayer membranes
T. Kunitake, N. Nakashima, K. Takarabe, M. Nagai, A. Tsuge, and H. Yanagi
pp 5945 - 5947; DOI:
10.1021/ja00409a071
PDF
Nucleophilic oxygen atom transfer reactions by persulfoxide and persulfone
Yasuhiko Sawaki and Yoshiro Ogata
pp 5947 - 5948; DOI:
10.1021/ja00409a072
PDF
Chemistry of singlet oxygen. 35. Nature of intermediates in the photooxygenation of sulfides
Chee-Liang Gu, Christopher S. Foote, and Mark L. Kacher
pp 5949 - 5951; DOI:
10.1021/ja00409a073
PDF
Observations on the nature of polylithium organic compounds and their rearrangements
Lawrence A. Shimp, John A. Morrison, John A. Gurak, John W. Chinn, and Richard J. Lagow
pp 5951 - 5953; DOI:
10.1021/ja00409a074
PDF
Biosynthesis of macrolides. 5. Regiochemistry of the labeling of lasalocid A by [13C,18O]-labeled precursors
C. Richard Hutchinson, Mary M. Sherman, John C. Vederas, and Thomas T. Nakashima
pp 5953 - 5956; DOI:
10.1021/ja00409a075
PDF
Biosynthesis of macrolides. 6. Mechanism of stereocontrol during the formation of lasalocid A
C. Richard Hutchinson, Mary M. Sherman, A. Gavin McInnes, John A. Walter, and John C. Vederas
pp 5956 - 5959; DOI:
10.1021/ja00409a076
PDF
Macrolide biosynthesis. Origin of the oxygen atoms in the erythromycins
David E. Cane, Heinz Hasler, and Tzyy-Chyau Liang
pp 5960 - 5962; DOI:
10.1021/ja00409a077
PDF
Polyether biosynthesis. Origin of the oxygen atoms of monensin A
David E. Cane, Tzyy-Chyau Liang, and Heinz Hasler
pp 5962 - 5965; DOI:
10.1021/ja00409a078
PDF
Reaction of alkoxides with phenylthiocarbene: a novel oxy-anionic substituent effect on the carbon-hydrogen insertion of carbenes
Toshiro Harada and Akira Oku
pp 5965 - 5967; DOI:
10.1021/ja00409a079
PDF
Oxotrimolybdenum(IV) alkoxides: Mo3(.mu.3-O)(.mu.3-OR)(.mu.2-OR)3(OR)6, where R = isopropyl and neopentyl. Synthetic considerations
M. H. Chisholm, K. Folting, J. C. Huffman, and C. C. Kirkpatrick
pp 5967 - 5968; DOI:
10.1021/ja00409a080
PDF
Raman spectroscopy of excited electronic states of photoactive metal complexes. 1. Nitroprusside ion
John W. Schindler and Jeffrey I. Zink
pp 5968 - 5969; DOI:
10.1021/ja00409a081
PDF
Neutral alkylations via palladium(0) catalysis
Barry M. Trost and Gary A. Molander
pp 5969 - 5972; DOI:
10.1021/ja00409a082
PDF
Regiochemistry of the cycloaddition of a substituted trimethylenemethanepalladium complex
Barry M. Trost and Dominic M. T. Chan
pp 5972 - 5974; DOI:
10.1021/ja00409a083
PDF
Molecular orbital study of substituted trimethylenemethane-bis(phosphine)palladium complexes
Douglas J. Gordon, Richard F. Fenske, Thomas N. Nanninga, and Barry M. Trost
pp 5974 - 5976; DOI:
10.1021/ja00409a084
PDF
Novel reaction course of oxosulfonium ylides to sulfurane oxides
Kentaro Okuma, Yoshihiko Tanaka, and Hiroshi Ohta
pp 5976 - 5977; DOI:
10.1021/ja00409a085
PDF
Vibronic spectra of naphthalene and naphthalene-d8 cations in solid argon
Lester Andrews and Terry A. Blankenship
pp 5977 - 5979; DOI:
10.1021/ja00409a086
PDF
High-resolution NMR spectra of quadrupole nuclei in solution using multiple quantum coherence
V. W. Miner and J. H. Prestegard
pp 5979 - 5981; DOI:
10.1021/ja00409a087
PDF
A ferrous, high-spin heme a model for cytochrome a3 in the dioxygen reducing site of cytochrome oxidase
Julie Van Steelandt-Frentrup, Irving Salmeen, and Gerald T. Babcock
pp 5981 - 5982; DOI:
10.1021/ja00409a088
PDF
Correlation of nonadditive kinetic effects with MINDO/3-derived molecular geometries
Jeffrey I. Seeman, Roseanne Galzerano, Keith Curtis, John C. Schug, and Jimmy W. Viers
pp 5982 - 5984; DOI:
10.1021/ja00409a089
PDF
Formation of an iridium ethyl complex by methyl migration to a coordinated methylene group
D. L. Thorn and T. H. Tulip
pp 5984 - 5986; DOI:
10.1021/ja00409a090
PDF
Book Reviews

pp 5986 - 5990; DOI:
10.1021/ja00409a600
PDF

Issue 20


Cobalt-59 NMR as a sensitive probe into hydrophobic effects
Alfred Delville, Pierre Laszlo, and Armel Stockis
pp 5991 - 5998; DOI:
10.1021/ja00410a001
PDF
NMR relaxation parameters in molecules with internal motion: exact Langevin trajectory results compared with simplified relaxation models
Ronald M. Levy, Martin Karplus, and Peter G. Wolynes
pp 5998 - 6011; DOI:
10.1021/ja00410a002
PDF
Paramagnetic doping as an aid in obtaining high-resolution carbon-13 NMR spectra of biomolecules in the solid state
S. Ganapathy, A. Naito, and C. A. McDowell
pp 6011 - 6015; DOI:
10.1021/ja00410a003
PDF
S-adenosyl-L-methionine and S-adenosyl-L-homocysteine, an NMR study
Mark L. Stolowitz and M. J. Minch
pp 6015 - 6019; DOI:
10.1021/ja00410a004
PDF
Characterization of bacteriochlorophyll interactions in vitro by resonance Raman spectroscopy
Therese M. Cotton and Richard P. Van Duyne
pp 6020 - 6026; DOI:
10.1021/ja00410a005
PDF
Secondary ion mass spectrometry of small-molecule solids at cryogenic temperatures. 2. Rare gas solids
Robert G. Orth, Harry T. Jonkman, David H. Powell, and Josef Michl
pp 6026 - 6030; DOI:
10.1021/ja00410a006
PDF
Disilver: spectroscopy and photoprocesses in rare-gas matrixes
Steven A. Mitchell, Geraldine A. Kenney-Wallace, and Geoffrey A. Ozin
pp 6030 - 6035; DOI:
10.1021/ja00410a007
PDF
Classical electrical contributions to solvent polarity scales
S. Ehrenson
pp 6036 - 6043; DOI:
10.1021/ja00410a008
PDF
Proton cryptates. Kinetics and thermodynamics of protonation of the [1.1.1] macrobicyclic cryptand
Patrick B. Smith, James L. Dye, John Cheney, and Jean Marie Lehn
pp 6044 - 6048; DOI:
10.1021/ja00410a009
PDF
Effect of substituents on the structure of reaction complexes
Addy Pross and Leo Radom
pp 6049 - 6053; DOI:
10.1021/ja00410a010
PDF
Why uranyl ion(2+) is linear and isoelectronic thorium dioxide is bent
Willard R. Wadt
pp 6053 - 6057; DOI:
10.1021/ja00410a011
PDF
Polyacene dianion crystal lattice energies and thermodynamic stabilities: the quantitative effect of aromaticity
Gerald R. Stevenson, Steven S. Zigler, and Richard C. Reiter
pp 6057 - 6061; DOI:
10.1021/ja00410a012
PDF
Linear solvation energy relationships. 13. Relationship between the Hildebrand solubility parameter, .delta.H, and the solvatochromic parameter, .pi.*
Mortimer J. Kamlet, Peter W. Carr, R. W. Taft, and Michael H. Abraham
pp 6062 - 6066; DOI:
10.1021/ja00410a013
PDF
Electronic structure of free-base and transition-metal tetraazaporphyrins
Ziva Berkovitch-Yellin and D. E. Ellis
pp 6066 - 6073; DOI:
10.1021/ja00410a014
PDF
Static and dynamic stereochemistry of hexaethylbenzene and of its tricarbonylchromium, tricarbonylmolybdenum, and dicarbonyl(triphenylphosphine)chromium complexes
Daniel J. Iverson, Geoffrey Hunter, John F. Blount, James R. Damewood, and Kurt Mislow
pp 6073 - 6083; DOI:
10.1021/ja00410a015
PDF
Single-crystal polarized x-ray absorption spectroscopy. Observation and theory for thiomolybdate(2-)
Frank W. Kutzler, R. A. Scott, Jeremy M. Berg, Keith O. Hodgson, S. Doniach, S. P. Cramer, and C. H. Chang
pp 6083 - 6088; DOI:
10.1021/ja00410a016
PDF
Flash photolysis study of the metal-metal bond homolysis in dimanganese decacarbonyl and dirhenium decacarbonyl
R. W. Wegman, R. J. Olsen, D. R. Gard, L. R. Faulkner, and Theodore L. Brown
pp 6089 - 6092; DOI:
10.1021/ja00410a017
PDF
Metal alkoxides - models for metal oxides. 1. Preparations and structures of hexadecaalkoxytetratungsten compounds, W4(OR)16, where R = Me and Et, and octaoxotetraisopropoxytetrapyridinotetramolybdenum, Mo4(O)4(.mu.-O)2(.mu.3-O)2(O-i-Pr)2(.mu.-O-i-Pr)2(py)4
M. H. Chisholm, J. C. Huffman, C. C. Kirkpatrick, J. Leonelli, and K. Folting
pp 6093 - 6099; DOI:
10.1021/ja00410a018
PDF
Highly reduced organometallics. 4. Syntheses and chemistry of pentacarbonylvanadate(3-) ion, V(CO)53-
John E. Ellis, Kristi Lenz Fjare, and Thomas G. Hay
pp 6100 - 6106; DOI:
10.1021/ja00410a019
PDF
Highly reduced organometallics. 5. Synthesis, properties, and the molecular structure of (Ph3PAu)3V(CO)5, a gold-vanadium cluster
John E. Ellis
pp 6106 - 6110; DOI:
10.1021/ja00410a020
PDF
Evidence for the localized iron(III)/iron(II) oxidation state configuration as an intrinsic property of [Fe2S2(SR)4]3- clusters
P. K. Mascharak, G. C. Papaefthymiou, R. B. Frankel, and R. H. Holm
pp 6110 - 6116; DOI:
10.1021/ja00410a021
PDF
Chemisorption of halogen on copper and silver clusters
R. C. Baetzold
pp 6116 - 6120; DOI:
10.1021/ja00410a022
PDF
Bistability in the oxidation of arsenite by iodate in a stirred flow reactor
Patrick De Kepper, Irving R. Epstein, and Kenneth Kustin
pp 6121 - 6127; DOI:
10.1021/ja00410a023
PDF
Synthesis and characterization of the major component of alamethicin
T. M. Balasubramanian, Nancy C. E. Kendrick, Melissa Taylor, Garland R. Marshall, James E. Hall, Igor Vodyanoy, and Fritz Reusser
pp 6127 - 6132; DOI:
10.1021/ja00410a024
PDF
Total synthesis of (.+-.)-celacinnine, (.+-.)-celallocinnine, (.+-.)-celafurine, and (.+-.)-celabenzine
Hisashi Yamamoto and Keiji Maruoka
pp 6133 - 6136; DOI:
10.1021/ja00410a025
PDF
Proton affinities and ionization energies of bicyclic amines and diamines. Effects of ring strain and of 3-electron .sigma. bonding
Roger W. Alder, Richard J. Arrowsmith, Alan Casson, Richard B. Sessions, Edgar Heilbronner, Branka Kovac, Hanspeter Huber, and Mare Taagepera
pp 6137 - 6142; DOI:
10.1021/ja00410a026
PDF
The first bis gem donor-acceptor substituted allene: synthesis, geometry, and electronic structure
Robert Weiss, Hilmar Wolf, Ulrich Schubert, and Timothy Clark
pp 6142 - 6147; DOI:
10.1021/ja00410a027
PDF
Morpholino demethoxylation on pyrylium and pyridinium rings: rate parameters and base catalysis
Raffaele Aveta, Giancarlo Doddi, Gabriello Illuminati, and Franco Stegel
pp 6148 - 6151; DOI:
10.1021/ja00410a028
PDF
Lipophilic diammonium cation having a rigid structure complementary to pyrophosphate dianions of nucleotides. Selective extraction and transport of nucleotides
Iwao Tabushi, Yoshiaki Kobuke, and Junichi Imuta
pp 6152 - 6157; DOI:
10.1021/ja00410a029
PDF
.alpha.-Amino acids as chiral educts for asymmetric products. Amino acylation with N-acylamino acids
Thomas F. Buckley and Henry Rapoport
pp 6157 - 6163; DOI:
10.1021/ja00410a030
PDF
Selectivity of (trifluoromethyl)chlorocarbene
Robert A. Moss, Wenjeng Guo, Dorothy Z. Denney, K. N. Houk, and Nelson G. Rondan
pp 6164 - 6169; DOI:
10.1021/ja00410a031
PDF
Acyl substituent effects on rates of acyl transfer to thiolate, hydroxide, and oxy dianions
Spencer L. Shames and Larry D. Byers
pp 6170 - 6177; DOI:
10.1021/ja00410a032
PDF
Effect of phosphono substituents on acyl transfer reactions
Spencer L. Shames and Larry D. Byers
pp 6177 - 6184; DOI:
10.1021/ja00410a033
PDF
Carbon-13 nuclear magnetic resonance study of the biosynthesis of cycloheximide. Stereospecific incorporation of malonate into the glutarimide ring
Peter W. Jeffs and David McWilliams
pp 6185 - 6192; DOI:
10.1021/ja00410a034
PDF
Catalytic mechanisms of acyl transfer reactions in dipolar aprotic media. 2. Electrophilic activation of the carbonyl group by quaternary alkylammonium and imidazolium functions
Joseph Hajdu and Georgianna M. Smith
pp 6192 - 6197; DOI:
10.1021/ja00410a035
PDF
Reaction kinetics and equilibriums of .beta.-elimination of some Schiff base complexes
Kuniyasu Tatsumoto, Arthur E. Martell, and Ramunas J. Motekaitis
pp 6197 - 6203; DOI:
10.1021/ja00410a036
PDF
Pyridoxal- and metal-catalyzed .beta.-elimination, decarboxylation, and dealdolation reactions of .beta.-hydroxyglutamic acid
Kuniyasu Tatsumoto and Arthur E. Martell
pp 6203 - 6208; DOI:
10.1021/ja00410a037
PDF
A stereocontrolled synthesis of antineoplastic podophyllum lignans
D. Rajapaksa and R. Rodrigo
pp 6208 - 6209; DOI:
10.1021/ja00410a038
PDF
Photoassisted reduction of molecular oxygen to hydrogen peroxide catalyzed by oxoalkoxomolybdenum(V) porphyrin
Henry J. Ledon, Michel Bonnet, and Daniel Galland
pp 6209 - 6211; DOI:
10.1021/ja00410a039
PDF
Semisynthetic enzymes: synthesis of a new flavopapain with high catalytic efficiency
James T. Slama, Subba Rao Oruganti, and E. T. Kaiser
pp 6211 - 6213; DOI:
10.1021/ja00410a040
PDF
Strategy for the synthesis of cylindrical macropolycyclic hosts with hydrophilic interior surfaces: crown ether rings fused by the tetrahydroxymethylethylene (THYME) unit
David M. Walba, Rodney M. Richards, Steven P. Sherwood, and R. Curtis Haltiwanger
pp 6213 - 6215; DOI:
10.1021/ja00410a041
PDF
Facile carbon-carbon bond rotation in azaallyllithium reagents
John Y. Lee, Thomas J. Lynch, David T. Mao, David E. Bergbreiter, and M. Newcomb
pp 6215 - 6217; DOI:
10.1021/ja00410a042
PDF
[(Trimethylsilyl)acetyl]trimethylsilane, a versatile synthon for stereoselective syntheses of functionalized trisubstituted olefins
Joseph A. Miller and George Zweifel
pp 6217 - 6219; DOI:
10.1021/ja00410a043
PDF
Cyclopentadienylbis(ligand)nickel(I): synthesis and characterization, including the x-ray structure of .eta.5-cyclopentadienyl-1,1'-bipyridylnickel(I). Observations on the mechanism of substitution of nickelocene
E. Kent Barefield, D. A. Krost, D. S. Edwards, D. G. Van Derveer, R. L. Trytko, S. P. O'Rear, and Alex N. Williamson
pp 6219 - 6222; DOI:
10.1021/ja00410a044
PDF
Photolysis of bis(triphenylphosphine)dioxygenplatinum. Generation of singlet oxygen
Arnd Vogler and Horst Kunkely
pp 6222 - 6223; DOI:
10.1021/ja00410a045
PDF
Structures of the C2H4O+.cntdot. gas-phase isomers. Evidence for the formation of the CH2OCH2+.cntdot. ion from ethylene carbonate
Bruno C. Baumann and John K. MacLeod
pp 6223 - 6224; DOI:
10.1021/ja00410a046
PDF
Reactions of nitroimidazoles. Nucleophilic substitution of the nitro group
P. Goldman and James D. Wuest
pp 6224 - 6226; DOI:
10.1021/ja00410a047
PDF
Cryochemical studies. 1. ESR spectrum of silver(Ag3)
J. A. Howard, K. F. Preston, and B. Mile
pp 6226 - 6227; DOI:
10.1021/ja00410a048
PDF
Enzyme-catalyzed organic synthesis: NAD(P)H regeneration using dihydrogen and the hydrogenase from Methanobacterium thermoautotrophicum
Chi-Huey Wong, Lacy Daniels, William H. Orme-Johnson, and George M. Whitesides
pp 6227 - 6228; DOI:
10.1021/ja00410a049
PDF
Augmented and diminished spherands and scales of binding
Donald J. Cram, George M. Lein, Takahiro Kaneda, Roger C. Helgeson, Carolyn B. Knobler, Emily Maverick, and Kenneth N. Trueblood
pp 6228 - 6232; DOI:
10.1021/ja00410a050
PDF
α-Disulfoxide and sulfinic anhydride in the peroxy acid oxidation of 2-methyl-2-propyl 2-methyl-2-propanethiosulfinate
Fillmore Freeman, Christos N. Angeletakis, and Tom J. Maricich
pp 6232 - 6235; DOI:
10.1021/ja00410a051
PDF
Mild base-promoted conversion of tertiary cis,cis-2,4-cyclononadienols to bicyclo[4.3.1]nona-2,4-dienes. Antarafacial cyclization of coiled 8.pi.-7C conjugated anions
Leo A. Paquette and Gary D. Crouse
pp 6235 - 6236; DOI:
10.1021/ja00410a052
PDF
Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?
Victor S. Martin, Scott S. Woodard, Tsutomu Katsuki, Yasuhiro Yamada, Masonari Ikeda, and K. Barry Sharpless
pp 6237 - 6240; DOI:
10.1021/ja00410a053
PDF
Restricted gearing and residual stereoisomerism in bis(1,4-dimethyl-9-triptycyl)methane
Constance A. Johnson, Alberto Guenzi, and Kurt Mislow
pp 6240 - 6242; DOI:
10.1021/ja00410a054
PDF
Fractionation factor for hydrogen isotopes at the aqueous ligand of cobalt in cobalt(II)-substituted bovine carbonic anhydrase
David N. Silverman
pp 6242 - 6243; DOI:
10.1021/ja00410a055
PDF
Total synthesis and stereochemical identity of the C18H32O5 degradation product from boromycin
Stephen Hanessian, Peter C. Tyler, Gilles Demailly, and Yves Chapleur
pp 6243 - 6246; DOI:
10.1021/ja00410a056
PDF
Synthesis and structure of a new type of molybdenum-iron-sulfur double-cubane cluster and evidence for formation of magnetically uncoupled S = 3/2 MoFe3S4 subclusters
William H. Armstrong and R. H. Holm
pp 6246 - 6248; DOI:
10.1021/ja00410a057
PDF
Isotope scrambling with nitrogen-15-labeled azide ion and p-toluenesulfonyl azide
Carla Casewit, J. Wenninger, and John D. Roberts
pp 6248 - 6249; DOI:
10.1021/ja00410a058
PDF
Semibullvalenes. 1. Synthesis and crystal structure of 1,5-dimethyl-2,4,6,8-tetrakis(carbomethoxy)tricyclo[3.3.0.02,8]octa-3,6-diene a donor-acceptor-substituted semibullvalene
L. S. Miller, K. Grohmann, J. J. Dannenberg, and L. Todaro
pp 6249 - 6251; DOI:
10.1021/ja00410a059
PDF
.alpha.-Silyl aldehydes: preparation and use as stereoselective vinyl cation equivalents
Paul F. Hudrlik and Ashok K. Kulkarni
pp 6251 - 6253; DOI:
10.1021/ja00410a060
PDF
Pulsed infrared laser-induced reaction of cyclobutyl acetate. Laser synthesis of a thermally labile compound by a rapid heating-quenching process
Hanh H. Nguyen and Wayne C. Danen
pp 6253 - 6255; DOI:
10.1021/ja00410a061
PDF
Observation of the 1,4 biradical in the Paterno-Buchi reaction
Steven C. Freilich and Kevin S. Peters
pp 6255 - 6257; DOI:
10.1021/ja00410a062
PDF
Reaction of bicyclo[1.1.0]butanes with platinum(II) complexes. Isolation and characterization of new platinacycle compounds
Akira Miyashita, Mikio Takahashi, and Hidemasa Takaya
pp 6257 - 6259; DOI:
10.1021/ja00410a063
PDF
Mechanism of the Reppe cyclooctatetraene synthesis from ethyne: a labeling experiment
Robert E. Colborn and K. Peter C. Vollhardt
pp 6259 - 6261; DOI:
10.1021/ja00410a064
PDF
2,3,4,4a,5,6,7,7a-Octahydro-1H-benzofuro[3,2-e]isoquinoline: a new morphine fragment
Engelbert Ciganek
pp 6261 - 6262; DOI:
10.1021/ja00410a065
PDF
Experimental measurement of the electron affinity of the hydroperoxy radical
Veronica M. Bierbaum, Robert J. Schmitt, C. H. DePuy, Roy D. Mead, Peter A. Schulz, and W. C. Lineberger
pp 6262 - 6263; DOI:
10.1021/ja00410a066
PDF
Preparative hydroxylation of aromatic compounds catalyzed by peroxidase
Alexander M. Klibanov, Zina Berman, and Barbara N. Alberti
pp 6263 - 6264; DOI:
10.1021/ja00410a067
PDF
Anomalous dipole moments of photoreactive triplet states
Irwin C. Winkler and David M. Hanson
pp 6264 - 6265; DOI:
10.1021/ja00410a068
PDF
High-resolution NMR spectroscopy of solids and surface-adsorbed species in colloidal suspension: phosphorus-31 NMR spectra of hydroxyapatite and diphosphonates
J. P. Yesinowski
pp 6266 - 6267; DOI:
10.1021/ja00410a069
PDF
Effect of DNA molecular weight, temperature, and magnetic field strength on the phosphorus-31 NMR results of DNA complexed with ethidium
W. David Wilson, Rebecca A. Keel, and Yitbarek H. Mariam
pp 6267 - 6269; DOI:
10.1021/ja00410a070
PDF
A hexanuclear iron-sulfide-thiolate cluster: assembly and properties of [Fe6S9(S-tert-C4H9)2]4- containing three types of bridging sulfur atoms
G. Christou, R. H. Holm, M. Sabat, and James A. Ibers
pp 6269 - 6271; DOI:
10.1021/ja00410a071
PDF
Book Reviews

pp 6271 - 6272; DOI:
10.1021/ja00410a600
PDF

Issue 21


Photoelectrochemical oxidation of sulfur dioxide in strong acid solution: iodide-mediated oxidation at illuminated metal dichalcogenide electrodes
Gary S. Calabrese and Mark S. Wrighton
pp 6273 - 6280; DOI:
10.1021/ja00411a001
PDF
Hydrogen-1 and carbon-13 ENDOR investigations of sterically hindered galvinoxyl radicals
B. Kirste, W. Harrer, H. Kurreck, K. Schubert, H. Bauer, and W. Gierke
pp 6280 - 6286; DOI:
10.1021/ja00411a002
PDF
Local order study of zinc bromide solutions in ethyl acetate by EXAFS
A. Sadoc, A. Fontaine, P. Lagarde, and D. Raoux
pp 6287 - 6290; DOI:
10.1021/ja00411a003
PDF
Protonation and site of protonation of anilines. Hydration and site of protonation after hydration
Y. K. Lau, K. Nishizawa, A. Tse, R. S. Brown, and P. Kebarle
pp 6291 - 6295; DOI:
10.1021/ja00411a004
PDF
Microwave spectroscopic study of malonaldehyde (3-hydroxy-2-propenal). 2. Structure, dipole moment, and tunneling
Steven L. Baughcum, Richard W. Duerst, Walter F. Rowe, Zuzana Smith, and E. Bright Wilson
pp 6296 - 6303; DOI:
10.1021/ja00411a005
PDF
Spectroscopy and decay dynamics of several methyl- and fluorine-substituted benzene radical cations
V. E. Bondybey, C. Vaughn, Terry A. Miller, J. H. English, and R. H. Shiley
pp 6303 - 6307; DOI:
10.1021/ja00411a006
PDF
Determination of the heats of formation of the isomeric xylylenes by ion cyclotron double-resonance spectroscopy
Steven K. Pollack, Brian C. Raine, and Warren J. Hehre
pp 6308 - 6313; DOI:
10.1021/ja00411a007
PDF
Silabutadienes and their silylene isomers. An ab initio study
Georges Trinquier and Jean Paul Malrieu
pp 6313 - 6319; DOI:
10.1021/ja00411a008
PDF
Multiconformational synthetic polypeptides
Andre Brack and Gerard Spach
pp 6319 - 6323; DOI:
10.1021/ja00411a009
PDF
Sustained water cleavage by visible light
Enrico Borgarello, J. Kiwi, Ezio Pelizzetti, Mario Visca, and Michael Graetzel
pp 6324 - 6329; DOI:
10.1021/ja00411a010
PDF
Ultraviolet photoelectron studies of methyl-substituted benz[a]anthracenes
I. Akiyama, P. R. LeBreton, and R. G. Harvey
pp 6330 - 6332; DOI:
10.1021/ja00411a011
PDF
Molecular beam chemistry. Formation of phenyl cations from C6H5X molecules
S. A. Safron, G. A. King, and R. C. Horvat
pp 6333 - 6337; DOI:
10.1021/ja00411a012
PDF
Coordination modes of histidine. 2. Stereochemistry of the reaction between histidine derivatives and pyridoxal analogs conformational properties of zinc(II) complexes of histidine Schiff bases
Luigi Casella and Michele Gullotti
pp 6338 - 6347; DOI:
10.1021/ja00411a013
PDF
Angular distortions at the carbon bound to cobalt in coenzyme B12 models. Implications with regard to cobalt-carbon bond cleavage in coenzyme B12 and other alkylcobalamins
Lucio Randaccio, Nevenka Bresciani-Pahor, Paul J. Toscano, and Luigi G. Marzilli
pp 6347 - 6351; DOI:
10.1021/ja00411a014
PDF
Photochemical substitution reactions of iron tricarbonyl 1,4-dimethyltetraazadiene and related complexes. Behavior consistent with the strong coupling limit
Curtis E. Johnson and William C. Trogler
pp 6352 - 6358; DOI:
10.1021/ja00411a015
PDF
NMR spectroscopy on paramagnetic complexes. 23. Vanadium-carbon bonds in paramagnetic bent vanadocene derivatives
Frank H. Koehler, Peter Hofmann, and Wolfram Proessdorf
pp 6359 - 6367; DOI:
10.1021/ja00411a016
PDF
Synthesis of [1.1]ferrocenophanes via 1,1'-bis(6-fulvenyl)ferrocene
A. Cassens, P. Eilbracht, A. Nazzal, W. Proessdorf, and U. T. Mueller-Westerhoff
pp 6367 - 6372; DOI:
10.1021/ja00411a017
PDF
Synthesis of the major component of alamethicin
B. F. Gisin, D. G. Davis, Z. K. Borowska, J. E. Hall, and S. Kobayashi
pp 6373 - 6377; DOI:
10.1021/ja00411a018
PDF
Total syntheses of (.+-.)-duanomycinone. Regiospecific preparations of (.+-.)-7,9-dideoxydaunomycinone and 6,11-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,9,12-trione
Frank M. Hauser and Subbarao Prasanna
pp 6378 - 6386; DOI:
10.1021/ja00411a019
PDF
Synthesis of indolizidine alkaloids via the intramolecular imino Diels-Alder reaction
Nazir A. Khatri, Hans F. Schmitthenner, Jayant Shringarpure, and Steven M. Weinreb
pp 6387 - 6393; DOI:
10.1021/ja00411a020
PDF
Reaction of benzophenone triplets with allylic hydrogens. Laser flash photolysis study
M. V. Encinas and J. C. Scaiano
pp 6393 - 6397; DOI:
10.1021/ja00411a021
PDF
Generality of the temperature dependence of carbon-13 shieldings as a probe for conformational or structural equilibriums
Joseph B. Lambert, Adelia R. Vagenas, and Sujata Somani
pp 6398 - 6402; DOI:
10.1021/ja00411a022
PDF
Solvent effects on the picosecond dynamics of the photoreduction of benzophenone by aromatic amines
John D. Simon and Kevin S. Peters
pp 6403 - 6406; DOI:
10.1021/ja00411a023
PDF
Thermolysis and photolysis of the azoalkane 2,3-diazatricyclo[4.3.0.04,9]non-2-ene: generation and transformation of the bicyclo[2.2.1]heptane-2,7-diyl diradical
Waldemar Adam, Nestor Carballeira, and Ottorino De Lucchi
pp 6406 - 6409; DOI:
10.1021/ja00411a024
PDF
Photocontrol of polypeptide helix sense by cis-trans isomerism of side-chain azobenzene moieties
Akihiko Ueno, Keiko Takahashi, Junichi Anzai, and Tetsuo Osa
pp 6410 - 6415; DOI:
10.1021/ja00411a025
PDF
Absorption spectra and photochemical rearrangements in phenylalkene cations in solid argon
Lester Andrews, James A. Harvey, Benuel J. Kelsall, and Donald C. Duffey
pp 6415 - 6422; DOI:
10.1021/ja00411a026
PDF
Perfluoroacetylmethylmethylene and its quintet radical pair: isolation and ESR detection
H. Murai, J. Ribo, M. Torres, and O. P. Strausz
pp 6422 - 6426; DOI:
10.1021/ja00411a027
PDF
Equilibrium [10]annulene .dblarw. bisnorcaradiene. X-ray study of the .beta. form of 11-methyltricyclo[4.4.1.01,6]undeca-2,4,7,9-tetraene-11-carbonitrile at two temperatures
Riccardo Bianchi, Tullio Pilati, and Massimo Simonetta
pp 6426 - 6431; DOI:
10.1021/ja00411a028
PDF
Hydrolysis of spirobicyclic oxyphosphoranes. Associative and dissociative reactions
Robert A. McClelland, Geeta Patel, and Corrado Cirinna
pp 6432 - 6436; DOI:
10.1021/ja00411a029
PDF
Unsaturated carbenes. 16. Extended unsaturated carbenes. Generation, nature, and chemistry of alkatetraenylidenecarbenes, R2C:C:C:C:C:C:
Peter J. Stang and Mladen Ladika
pp 6437 - 6443; DOI:
10.1021/ja00411a030
PDF
Carbon acidity. 58. Hydrogen isotope exchange kinetics of propylene with lithium cyclohexylamide
Donald W. Boerth and Andrew Streitwieser
pp 6443 - 6447; DOI:
10.1021/ja00411a031
PDF
Unified mechanism for polyunsaturated fatty acid autoxidation. Competition of peroxy radical hydrogen atom abstraction, .beta.-scission, and cyclization
Ned A. Porter, Laura S. Lehman, Bruce A. Weber, and Karl J. Smith
pp 6447 - 6455; DOI:
10.1021/ja00411a032
PDF
Mechanism of the photoepoxidation with and photodecarboxylation of .alpha.-keto acids
Yasuhiko Sawaki and Yoshiro Ogata
pp 6455 - 6460; DOI:
10.1021/ja00411a033
PDF
Reaction of aryl and vinyl halides with zerovalent nickel - preparative aspects and the synthesis of alnusone
M. F. Semmelhack, Paul Helquist, L. D. Jones, Leonard Keller, L. Mendelson, Laurine Speltz Ryono, Janice Gorzynski Smith, and R. D. Stauffer
pp 6460 - 6471; DOI:
10.1021/ja00411a034
PDF
Autoxidation of biological molecules. 1. Antioxidant activity of vitamin E and related chain-breaking phenolic antioxidants in vitro
G. W. Burton and K. U. Ingold
pp 6472 - 6477; DOI:
10.1021/ja00411a035
PDF
Autoxidation of biological molecules. 2. Autoxidation of a model membrane. Comparison of the autoxidation of egg lecithin phosphatidylcholine in water and in chlorobenzene
L. R. C. Barclay and K. U. Ingold
pp 6478 - 6485; DOI:
10.1021/ja00411a036
PDF
Substrate specificity in ester hydrolysis by a new water-soluble heterocyclophane
Iwao Tabushi, Yoshio Kimura, and Kazuo Yamamura
pp 6486 - 6492; DOI:
10.1021/ja00411a037
PDF
[2,3]-Wittig rearrangement of unsymmetrical bis-allylic ethers. Facile method for regio- and stereoselective synthesis of 1,5-dien-3-ols
T. Nakai, K. Mikami, S. Taya, and Y. Fujita
pp 6492 - 6494; DOI:
10.1021/ja00411a038
PDF
Oxidation of isopropylamine coordinated to ruthenium
Peter A. Adcock and F. Richard Keene
pp 6494 - 6495; DOI:
10.1021/ja00411a039
PDF
Tris(2,2'-bipyridine)ruthenium(2+)-mediated photoreduction of olefins with 1-benzyl-1,4-dihydronicotinamide: a mechanistic probe for electron-transfer reactions of NAD(P)H-model compounds
Chyongjin Pac, Mikio Ihama, Masahide Yasuda, Yoji Miyauchi, and Hiroshi Sakurai
pp 6495 - 6497; DOI:
10.1021/ja00411a040
PDF
Photochemical additions of alkenes to N-methylphthalimides. Effect of aryl substituents on the direction of addition
P. H. Mazzocchi, F. Khachik, P. Wilson, and R. Highet
pp 6498 - 6499; DOI:
10.1021/ja00411a041
PDF
Infrared spectra of gas-phase ions and their use in elucidating reaction mechanisms. Identification of C7H7- structural isomers by multiphoton electron detachment using a low-power infrared laser
Charles A. Wight and J. L. Beauchamp
pp 6499 - 6501; DOI:
10.1021/ja00411a042
PDF
Periodic trends in transition metal-hydrogen, metal-carbon, and metal-oxygen bond dissociation energies. Correlation with reactivity and electronic structure
P. B. Armentrout, L. F. Halle, and J. L. Beauchamp
pp 6501 - 6502; DOI:
10.1021/ja00411a043
PDF
Synthesis of 11.alpha.,9.alpha.-epoxymethanothromboxane A2: a stable, optically active TxA2 agonist
Thomas K. Schaaf, Donald L. Bussolotti, M. John Parry, and E. J. Corey
pp 6502 - 6505; DOI:
10.1021/ja00411a044
PDF
Discrimination of C3H3+ structures on the basis of chemical reactivity
Pierre Ausloos and Sharon G. Lias
pp 6505 - 6507; DOI:
10.1021/ja00411a045
PDF
Synthesis and x-ray crystal structure of a soluble divalent organosamarium complex
William J. Evans, Ira Bloom, William E. Hunter, and Jerry L. Atwood
pp 6507 - 6508; DOI:
10.1021/ja00411a046
PDF
Novel catalytic system for homogeneous hydrogenation of carbon monoxide: ruthenium complexes in the presence of iodide promoters
B. Duane Dombek
pp 6508 - 6510; DOI:
10.1021/ja00411a047
PDF
Importance of trinuclear coordination in the activation and desulfurization of a thioformamido ligand by a triosmium cluster
Richard D. Adams and Zain Dawoodi
pp 6510 - 6512; DOI:
10.1021/ja00411a048
PDF
Fully functionalized thiol vesicles: structure and esterolytic properties
Robert A. Moss and George O. Bizziogtti
pp 6512 - 6514; DOI:
10.1021/ja00411a049
PDF
Iron and ruthenium carbonyl catalyzed reductive carbonylation of nitro compounds by sodium methoxide. A significant effect of the metal on the reaction course
Howard Alper and Khaled E. Hashem
pp 6514 - 6515; DOI:
10.1021/ja00411a050
PDF
Direct spectral evidence of the generation of singlet molecular oxygen (1.DELTA.g) in the reaction of potassium superoxide with water
Ahsan U. Khan
pp 6516 - 6517; DOI:
10.1021/ja00411a051
PDF
Structures of eleven zervamicin and two emerimicin peptide antibiotics studied by fast atom bombardment mass spectrometry
Kenneth L. Rinehart, Larry A. Gaudioso, Michael L. Moore, Ramesh C. Pandey, J. Carter Cook, Michael Barber, R. Donald Sedgwick, Robert S. Bordoli, Andrew N. Tyler, and Brian N. Green
pp 6517 - 6520; DOI:
10.1021/ja00411a052
PDF
Hydrogenation on the hindered face of syn-sesquinorbornene photosensitized by acetone
Paul D. Bartlett, Antonius A. M. Roof, and William J. Winter
pp 6520 - 6522; DOI:
10.1021/ja00411a053
PDF
Avoparcin and epiavoparcin
G. A. Ellestad, R. A. Leese, G. O. Morton, F. Barbatschi, W. Gore, W. J. McGahren, and I. M. Armitage
pp 6522 - 6524; DOI:
10.1021/ja00411a054
PDF
Optically active radical complexes. ESR-HPLC-OR study of the carbonyl(quinone)rhenium-(+)- and (-)-DIOP radical complexes
Tong Ing Ho, K. A. M. Creber, and J. K. S. Wan
pp 6524 - 6526; DOI:
10.1021/ja00411a055
PDF
Total synthesis of (.+-.)-pentalenolactone E methyl ester
Leo A. Paquette, Heinrich Schostarez, and Gary D. Annis
pp 6526 - 6527; DOI:
10.1021/ja00411a056
PDF
12-s-Cis - a novel conformation of retinoids
Anita H. Lewin, F. Ivy Carroll, and Charles G. Moreland
pp 6527 - 6529; DOI:
10.1021/ja00411a057
PDF
Dimethylmethylthiosulfonium fluoroborate. A chemoselective initiator for thionium ion induced cyclizations
Barry M. Trost and Eigoro Murayama
pp 6529 - 6530; DOI:
10.1021/ja00411a058
PDF
Automerization of C11H11 chlorides and stability of their cations
M. J. Goldstein, S. Tomoda, E. J. Pressman, and J. A. Dodd
pp 6530 - 6532; DOI:
10.1021/ja00411a059
PDF
An equilibrium deuterium isotope effect of surprising magnitude
M. J. Goldstein and E. J. Pressman
pp 6533 - 6534; DOI:
10.1021/ja00411a060
PDF
Formation of N-phenylheme in the hemolytic reaction of phenylhydrazine with hemoglobin
Paul R. Ortiz de Montellano and Kent L. Kunze
pp 6534 - 6536; DOI:
10.1021/ja00411a061
PDF
Structure revision of 37 lycoctonine-related diterpenoid alkaloids
S. William Pelletier, Naresh V. Mody, Kottayil I. Varughese, Joseph A. Maddry, and Haridutt K. Desai
pp 6536 - 6538; DOI:
10.1021/ja00411a062
PDF
Total synthesis of (+)-compactin (ML-236B)
Nai Yi Wang, Chi Tung Hsu, and Charles J. Sih
pp 6538 - 6539; DOI:
10.1021/ja00411a063
PDF
Book Reviews

pp 6540 - 6540; DOI:
10.1021/ja00411a600
PDF

Issue 22


Nuclear quadrupole coupling constants and hydrogen bonding. Molecular orbital study of oxygen-17 and deuterium field gradients in formaldehyde-water hydrogen bonding
Leslie G. Butler and Theodore L. Brown
pp 6541 - 6549; DOI:
10.1021/ja00412a001
PDF
Hydride-donation reaction of reduced nicotinamide adenine dinucleotide. 1. MINDO/3 and STO-3G calculations on analog reactions with cyclopropene, tropylidene, and 1,4-dihydropyridine as hydride donors and the cyclopropenium cation as acceptor
M. C. A. Donkersloot and H. M. Buck
pp 6549 - 6554; DOI:
10.1021/ja00412a002
PDF
The hydride-donation reaction of reduced nicotinamide adenine dinucleotide. 2. MINDO/3 and STO-3G calculations on the role of the carbamoyl group in enzymic reactions
M. C. A. Donkersloot and H. M. Buck
pp 6554 - 6558; DOI:
10.1021/ja00412a003
PDF
Enthalpy of steric inhibition to solvation due to tert-butyl groups on an anion radical
Gerald R. Stevenson, Jeanette D. Kokosinski, and Yoh-Tz Chang
pp 6558 - 6562; DOI:
10.1021/ja00412a004
PDF
Enthalpies of hydration of alkenes. 1. The n-hexenes
Kenneth B. Wiberg and David J. Wasserman
pp 6563 - 6566; DOI:
10.1021/ja00412a005
PDF
Study of increasingly crowded phenylethanes by carbon-13 spectroscopy and molecular mechanics calculations
Michael I. Watkins and George A. Olah
pp 6566 - 6574; DOI:
10.1021/ja00412a006
PDF
Proton nuclear Overhauser effects and protein dynamics
E. T. Olejniczak, F. M. Poulsen, and C. M. Dobson
pp 6574 - 6580; DOI:
10.1021/ja00412a007
PDF
Structure revision of the antibiotic vancomycin. Use of nuclear Overhauser effect difference spectroscopy
Michael P. Williamson and Dudley H. Williams
pp 6580 - 6585; DOI:
10.1021/ja00412a008
PDF
Model calculations of potential surfaces of van der Waals complexes containing large aromatic molecules
Mary Jo Ondrechen, Ziva Berkovitch-Yellin, and Joshua Jortner
pp 6586 - 6592; DOI:
10.1021/ja00412a009
PDF
Resonance Raman excitation profiles for the permanganate ion: calculation of Franck-Condon scattering contributions for the totally symmetric fundamental and its overtones and of the equilibrium manganese oxide (MnO) bond length in the first 1T2 excited state
Robin J. H. Clark and Brian Stewart
pp 6593 - 6599; DOI:
10.1021/ja00412a010
PDF
Gas-phase generation of phenylnitrene anion radical - proton affinity and .DELTA.Hf.degree. of phN-.cntdot. and its clustering with ROH molecules
Richard N. McDonald, A. Kasem Chowdhury, and D. W. Setser
pp 6599 - 6603; DOI:
10.1021/ja00412a011
PDF
Carbon-13 hyperfine splittings and geometry at the radical center in bicyclo[2.2.1]hept-2-yl radicals
Angelo Alberti, Maurizio Guerra, and Gian Franco Pedulli
pp 6604 - 6606; DOI:
10.1021/ja00412a012
PDF
Threshold intensities and kinetics of sonoreaction of thymine in aqueous solutions at low ultrasonic intensities
Chandra M. Sehgal and Shih Yi Wang
pp 6606 - 6611; DOI:
10.1021/ja00412a013
PDF
Reactions of copper(I) with micellar porphyrins and hemes. Spectroscopic evidence for copper(I)-heme binuclear ion formation
Eugene A. Deardorff, Paulette A. G. Carr, and James K. Hurst
pp 6611 - 6616; DOI:
10.1021/ja00412a014
PDF
Coordination chemistry of microbial iron transport compounds. 21. Kinetics and mechanism of iron exchange in hydroxamate siderophore complexes
Thomas P. Tufano and Kenneth N. Raymond
pp 6617 - 6624; DOI:
10.1021/ja00412a015
PDF
Ion-beam studies of the reactions of atomic cobalt ions with alkenes
P. B. Armentrout, L. F. Halle, and J. L. Beauchamp
pp 6624 - 6628; DOI:
10.1021/ja00412a016
PDF
Ion-beam studies of the reactions of atomic cobalt ions with cycloalkanes in the gas phase. Formation and decomposition of chemically activated metallacycles
P. B. Armentrout and J. L. Beauchamp
pp 6628 - 6632; DOI:
10.1021/ja00412a017
PDF
Negative ion states of d6 transition-metal hexacarbonyls
Judith C. Giordan, John H. Moore, and John A. Tossell
pp 6632 - 6636; DOI:
10.1021/ja00412a018
PDF
Phosphorus-31 NMR spectra of chelated diphosphine rhodium complexes in solution
O. Richard Hughes and D. A. Young
pp 6636 - 6642; DOI:
10.1021/ja00412a019
PDF
Thallium-205 nuclear magnetic resonance study of thallium(III) halide complexes in aqueous solutions
Julius Glaser and Ulf Henriksson
pp 6642 - 6649; DOI:
10.1021/ja00412a020
PDF
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
Paul J. Fagan, Juan M. Manriquez, Eric A. Maatta, Afif M. Seyam, and Tobin J. Marks
pp 6650 - 6667; DOI:
10.1021/ja00412a021
PDF
Effects of ligand substituents on excited-state reactivity and overall photoredox behavior for (polypyridyl)ruthenium(II) complexes. Laser flash study with potential reductive quenchers
Keith Monserrat, Thomas K. Foreman, Michael Graetzel, and David G. Whitten
pp 6667 - 6672; DOI:
10.1021/ja00412a022
PDF
Reactivity of lanthanide metals with unsaturated hydrocarbons: terminal alkyne reactions
William J. Evans, Steven C. Engerer, and Kraig M. Coleson
pp 6672 - 6677; DOI:
10.1021/ja00412a023
PDF
Use of silyloxydienes in synthesis. Total syntheses of the sesquiterpene (.+-.)-seychellene
Michael E. Jung, Charles A. McCombs, Yukiko Takeda, and Yuh-Guo Pan
pp 6677 - 6685; DOI:
10.1021/ja00412a024
PDF
Organoiron complexes in organic synthesis. Part 19. Trichothecene analogs. Total synthesis of 12,13-epoxy-14-methoxytrichothecene via organoiron complexes
Anthony J. Pearson and Chi Wi Ong
pp 6686 - 6690; DOI:
10.1021/ja00412a025
PDF
Preparation of 2,3-dimethylene-2,3-dihydrofurans by the flash vacuum pyrolysis of substituted furylmethyl esters
Walter S. Trahanovsky, Timothy J. Cassady, and Treacy L. Woods
pp 6691 - 6695; DOI:
10.1021/ja00412a026
PDF
Intramolecular Diels-Alder reactions: the angularly methylated trans-perhydroindan ring system
William R. Roush and Steven M. Peseckis
pp 6696 - 6704; DOI:
10.1021/ja00412a027
PDF
Conformation of progesterone side chain: conflict between x-ray data and force-field calculations
William L. Duax, Jane F. Griffin, and Douglas C. Rohrer
pp 6705 - 6712; DOI:
10.1021/ja00412a028
PDF
Stereoelectronic control in the gas-phase ionization of cyclic ortho esters
Marjorie C. Caserio, Yoshie Souma, and Jhong K. Kim
pp 6712 - 6716; DOI:
10.1021/ja00412a029
PDF
Alkyl group stabilization of monoolefin radical cations. ESR, ENDOR, and cyclic voltammetry study
Fabian Gerson, Javier Lopez, Ryoichi Akaba, and Stephen F. Nelsen
pp 6716 - 6722; DOI:
10.1021/ja00412a030
PDF
Kinetics of gas phase tetramethyldioxetane decomposition and chemiluminescence
B. D. Cannon and F. F. Crim
pp 6722 - 6726; DOI:
10.1021/ja00412a031
PDF
Plasticity of the DNA double helix
C. K. Mitra, M. H. Sarma, and Ramaswamy H. Sarma
pp 6727 - 6737; DOI:
10.1021/ja00412a032
PDF
Valence isomer of 4-methoxyazulene. Synthesis of 6-methoxytetracyclo[5.3.0.02,4.03,5]deca-6,8,10-triene
Yoshikazu Sugihara, Takashi Sugimura, and Ichiro Murata
pp 6738 - 6739; DOI:
10.1021/ja00412a033
PDF
Chirally selective synthesis of sugar moiety of nucleosides by chemicoenzymatic approach: L- and D-riboses, showdomycin, and cordycepin
Yukishige Ito, Tomoyuki Shibata, Masafumi Arita, Hiroaki Sawai, and Masaji Ohno
pp 6739 - 6741; DOI:
10.1021/ja00412a034
PDF
A new bridging ligand, the hydrogen oxide ion (H3O2-)
Avi Bino and Dan Gibson
pp 6741 - 6742; DOI:
10.1021/ja00412a035
PDF
Relationship between solution entropies and gas phase entropies of nonelectrolytes
Michael H. Abraham
pp 6742 - 6744; DOI:
10.1021/ja00412a036
PDF
Free radical epoxidation of 7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene by hematin and polyunsaturated fatty acid hydroperoxides
Thomas A. Dix and Lawrence J. Marnett
pp 6744 - 6746; DOI:
10.1021/ja00412a037
PDF
Silver-109 and rhodium-103 NMR spectroscopy with proton polarization transfer
Christian Brevard, Gerard C. Van Stein, and Gerard Van Koten
pp 6746 - 6748; DOI:
10.1021/ja00412a038
PDF
Structural and dynamic information about double-stranded DNA from nitrogen-15 NMR spectroscopy
Thomas L. James, Jacqueline L. James, and Aviva Lapidot
pp 6748 - 6750; DOI:
10.1021/ja00412a039
PDF
Stereochemistry of lysine 2,3-aminomutase
D. John Aberhart, Horng Jau Lin, and Bruce H. Weiller
pp 6750 - 6752; DOI:
10.1021/ja00412a040
PDF
Studies of nitrogen metabolism using C-13 NMR spectroscopy. 3. Synthesis of DL-[3-13C,2-15N]lysine and its incorporation into streptothricin F1
Steven J. Gould and T. K. Thiruvengadam
pp 6752 - 6754; DOI:
10.1021/ja00412a041
PDF
(.mu.-H)Fe4(CO)12(.eta.2-COH): evidence for a protonated .eta.2-CO complex as an intermediate in the proton-induced reduction of carbon monoxide
K. H. Whitmire and D. F. Shriver
pp 6754 - 6755; DOI:
10.1021/ja00412a042
PDF
Photocatalytic oxidations of lactams and N-acylamines
James W. Pavlik and Supawan Tantayanon
pp 6755 - 6757; DOI:
10.1021/ja00412a043
PDF
Mechanistic features of the semiconductor photocatalyzed olefin-to-carbonyl oxidative cleavage
Marye Anne Fox and C. C. Chen
pp 6757 - 6759; DOI:
10.1021/ja00412a044
PDF
Time-resolved determinations of deuterium isotope effects on O2(1.DELTA.g) lifetimes in solution
G. Peters and M. A. J. Rodgers
pp 6759 - 6761; DOI:
10.1021/ja00412a045
PDF
Synthesis, structure, and electrochemical behavior of cis-diammine-platinum(III) dimers with bridging .alpha.-pyridonate ligands
L. Steven Hollis and Stephen J. Lippard
pp 6761 - 6763; DOI:
10.1021/ja00412a046
PDF
Biosynthesis of dibromotyrosine-derived antimicrobial compounds by the marine sponge Aplysina fistularis (Verongia aurea)
Adrienne A. Tymiak and Kenneth L. Rinehart
pp 6763 - 6765; DOI:
10.1021/ja00412a047
PDF
Stereospecific conversion of penicillin to thienamycin
Sandor Karady, Joseph S. Amato, Robert A. Reamer, and Leonard M. Weinstock
pp 6765 - 6767; DOI:
10.1021/ja00412a048
PDF
Internal reactions of tetraalkylstannanes with carbon-centered electrophiles
Timothy L. Macdonald, Sankaran Mahalingam, and Dale E. O'Dell
pp 6767 - 6769; DOI:
10.1021/ja00412a049
PDF
Synthesis and structure of a "dicuprophane", a dicopper(I) complex derived from [o-(diphenylphosphino)benzoyl]pinacolone
Thomas B. Rauchfuss, Scott R. Wilson, and Debra A. Wrobleski
pp 6769 - 6770; DOI:
10.1021/ja00412a050
PDF
Synthesis of [(C6H5NH)PNC6H5]3: a participant in a phosphorus(III)-nitrogen compound trimer-dimer interconversion reaction
Martin L. Thompson, Abbas Tarassoli, R. Curtis Haltiwanger, and Arlan D. Norman
pp 6770 - 6772; DOI:
10.1021/ja00412a051
PDF
Sceptrin, an antimicrobial agent from the sponge Agelas sceptrum
Roger P. Walker, D. John Faulkner, Donna Van Engen, and Jon Clardy
pp 6772 - 6773; DOI:
10.1021/ja00412a052
PDF
Isolation and structure of brevetoxin B from the "red tide" dinoflagellate Ptychodiscus brevis (Gymnodinium breve)
Yong-Yeng Lin, Martin Risk, Sammy M. Ray, Donna Van Engen, Jon Clardy, Jerzy Golik, John C. James, and Koji Nakanishi
pp 6773 - 6775; DOI:
10.1021/ja00412a053
PDF
High-energy fragmentation of chlorophyll a and its fully deuterated analog by californium-252 plasma desorption mass spectrometry
Jerry E. Hunt, Ronald D. Macfarlane, Joseph J. Katz, and Ralph C. Dougherty
pp 6775 - 6778; DOI:
10.1021/ja00412a054
PDF
Infrared spectroscopy of oxidized metalloporphyrins: detection of a band diagnostic of porphyrin-centered oxidation
Eric T. Shimomura, Martin A. Phillippi, Harold M. Goff, William F. Scholz, and Christopher A. Reed
pp 6778 - 6780; DOI:
10.1021/ja00412a055
PDF
Carbon-13 cross-polarization magic-angle-spinning NMR study of butylamine adsorbed on .gamma.-alumina: characterization of surface acid sites
William H. Dawson, Steve W. Kaiser, Paul D. Ellis, and Ruth R. Inners
pp 6780 - 6781; DOI:
10.1021/ja00412a056
PDF
Laser photochemical production of vitamin D
V. Malatesta, C. Willis, and P. A. Hackett
pp 6781 - 6783; DOI:
10.1021/ja00412a057
PDF
Spinning near the magic angle: a means of obtaining first-order dipolar NMR spectra of molecules dissolved in nematic liquid crystals
Jacques Courtieu, D. W. Alderman, and David M. Grant
pp 6783 - 6784; DOI:
10.1021/ja00412a058
PDF
Synthetic model approach to the active site structure of cytochrome oxidase. Novel porphyrin-containing heterobinuclear iron(III)-copper(II) complexes
Maxwell J. Gunter, Lewis N. Mander, Keith S. Murray, and Paul E. Clark
pp 6784 - 6787; DOI:
10.1021/ja00412a059
PDF
Novel linear aluminum-hydrogen-aluminum electron-deficient bond in Na[(CH3)3Al-H-Al(CH3)3]
Jerry L. Atwood, Duane C. Hrncir, Robin D. Rogers, and Judith A. K. Howard
pp 6787 - 6788; DOI:
10.1021/ja00412a060
PDF
A rearrangement-elimination sequence to 1-silatoluene
Thomas J. Barton and Michael Vuper
pp 6788 - 6789; DOI:
10.1021/ja00412a061
PDF
Book Reviews

pp 6790 - 6790; DOI:
10.1021/ja00412a600
PDF

Issue 23


Quantitative electrochemical kinetics studies of "microelectrodes": catalytic water reduction by methyl viologen/colloidal platinum
Deborah S. Miller and George McLendon
pp 6791 - 6796; DOI:
10.1021/ja00413a001
PDF
Association of spin-labeled substrate molecules with poly(sodium 10-undecenoate) and the sodium 10-undecenoate micelle
Estel D. Sprague, David C. Duecker, and C. E. Larrabee
pp 6797 - 6800; DOI:
10.1021/ja00413a002
PDF
Charge-transfer spectra of metallophthalocyanines: correlation with electrode potentials
A. B. P. Lever, S. R. Pickens, P. C. Minor, S. Licoccia, B. S. Ramaswamy, and K. Magnell
pp 6800 - 6806; DOI:
10.1021/ja00413a003
PDF
Electroreductive alkylation of iron in porphyrin complexes. Electrochemical and spectral characteristics of .sigma.-alkylironporphyrins
Doris Lexa, Joel Mispelter, and Jean Michel Saveant
pp 6806 - 6812; DOI:
10.1021/ja00413a004
PDF
Infrared multiphoton decomposition of monosilane
P. A. Longeway and F. W. Lampe
pp 6813 - 6818; DOI:
10.1021/ja00413a005
PDF
Induced optical activity and liquid crystal linear dichroism of 9,9'-spiro-bi[9H-fluorene]
P. Palmieri and B. Samori
pp 6818 - 6823; DOI:
10.1021/ja00413a006
PDF
Reversible wavelength shifts of chlorophyll induced by a point charge
R. C. Davis, S. L. Ditson, A. F. Fentiman, and R. M. Pearlstein
pp 6823 - 6826; DOI:
10.1021/ja00413a007
PDF
Electrochemical investigations of compounds having isomeric forms with similar standard redox potentials: oxidation of bis(tri-n-butylphosphine)molybdenum tetracarbonyl and related complexes
A. M. Bond, D. J. Darensbourg, E. Mocellin, and B. J. Stewart
pp 6827 - 6832; DOI:
10.1021/ja00413a008
PDF
Equilibriums in solutions of nucleosides, 5'-nucleotides, and diethylenetriaminepalladium(2+)
Kurt H. Scheller, Verena Scheller-Krattiger, and R. Bruce Martin
pp 6833 - 6839; DOI:
10.1021/ja00413a009
PDF
Effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. Core and valence ionizations of methylated tricarbonyl(.eta.5-cyclopentadienyl)metal complexes
David C. Calabro, John L. Hubbard, Charles H. Blevins, Andrew C. Campbell, and Dennis L. Lichtenberger
pp 6839 - 6846; DOI:
10.1021/ja00413a010
PDF
Valence ionizations of olefins coordinated to metals. Olefin dicarbonyl[.eta.5-(methyl- and pentamethyl)cyclopentadienyl]manganese complexes
David C. Calabro and Dennis L. Lichtenberger
pp 6846 - 6852; DOI:
10.1021/ja00413a011
PDF
Valence electronic structure of bridging methylenes: UV photoelectron spectroscopy of .mu.-methylene-bis[dicarbonyl(.eta.5-cyclopentadienyl)manganese]
David C. Calabro, Dennis L. Lichtenberger, and Wolfgang A. Herrmann
pp 6852 - 6855; DOI:
10.1021/ja00413a012
PDF
Thallium in organic synthesis. 61. Intramolecular capture of radical cations from thallium(III) trifluoroacetate oxidation of arylalkanoic acids and arylalkanols. New routes to oxygen heterocycles
Edward C. Taylor, Juan G. Andrade, Gerhardus J. H. Rall, Ignatius J. Turchi, Kosta Steliou, G. Erik Jagdmann, and Alexander McKillop
pp 6856 - 6863; DOI:
10.1021/ja00413a013
PDF
Interaction of nickel(0) complexes with allyl carboxylates, allyl ethers, allylic alcohols, and vinyl acetate. .pi.-Complex formation and oxidative addition to nickel involving cleavage of the alkenyl-oxygen bond
Takakazu Yamamoto, Junichi Ishizu, and Akio Yamamoto
pp 6863 - 6869; DOI:
10.1021/ja00413a014
PDF
Crystal structures of repeating peptides of elastin. 2. N-(tert-Butoxycarbonyl)-L-valyl-L-prolylglycylglycine benzyl ester
Hiroshi Ayato, Isao Tanaka, and Tamaichi Ashida
pp 6869 - 6873; DOI:
10.1021/ja00413a015
PDF
Study of the synthesis and properties of [25](1,2,3,4,5)cyclophane
Paulo F. T. Schirch and V. Boekelheide
pp 6873 - 6878; DOI:
10.1021/ja00413a016
PDF
Formation of [9]- and [10]paracyclophane derivatives in cycloaddition reactions
Fumio Kataoka, Shinya Nishida, Takashi Tsuji, and Masashi Murakami
pp 6878 - 6884; DOI:
10.1021/ja00413a017
PDF
Methoxymethyl-directed aryl metalation. Total synthesis of (.+-.)-averufin
Craig A. Townsend, Steven G. Davis, Siegfried B. Christensen, John C. Link, and Charles P. Lewis
pp 6885 - 6888; DOI:
10.1021/ja00413a018
PDF
Photochemical formation of dihydrocarbazoles from diphenylamines and their thermal rearrangement and disproportionation reactions
Karl Heinz Grellmann, Wolfgang Kuehnle, Horst Weller, and Thomas Wolff
pp 6889 - 6893; DOI:
10.1021/ja00413a019
PDF
Heterogeneous photosynthetic production of amino acids at platinum/titanium dioxide suspensions by near ultraviolet light
Wendell W. Dunn, Yosihiro Aikawa, and Allen J. Bard
pp 6893 - 6897; DOI:
10.1021/ja00413a020
PDF
Semiconductor electrodes. 40. Photoassisted hydrogen evolution at poly(benzyl viologen)-coated p-type silicon electrodes
Hector D. Abruna and Allen J. Bard
pp 6898 - 6901; DOI:
10.1021/ja00413a021
PDF
Photocatalysis. 6. Mechanism of the cyclotrimerization of trans-cycloheptene, catalyzed by copper(I) triflate
Ton Spee and Adri Mackor
pp 6901 - 6904; DOI:
10.1021/ja00413a022
PDF
Locally excited triplet state production from excited charge-transfer complexes
Bobby K. Adams and William R. Cherry
pp 6904 - 6907; DOI:
10.1021/ja00413a023
PDF
Kinetics and mechanism of the hydrolysis of anilide acetals
Robert A. McClelland and Geeta Patel
pp 6908 - 6911; DOI:
10.1021/ja00413a024
PDF
Rate and equilibrium constants for the formation and decomposition of the tetrahedral intermediate of the methanolysis of methyl benzoates
Robert A. McClelland and Geeta Patel
pp 6912 - 6915; DOI:
10.1021/ja00413a025
PDF
Direct observation of excited state intramolecular proton transfer kinetics in 3-hydroxyflavone
G. J. Woolfe and P. J. Thistlethwaite
pp 6916 - 6923; DOI:
10.1021/ja00413a026
PDF
Use of carbon-13 substituent chemical shifts to scale nonhydrogen-bonding dipolar interactions of protonic solvents
B. Chawla, S. K. Pollack, C. B. Lebrilla, M. J. Kamlet, and R. W. Taft
pp 6924 - 6930; DOI:
10.1021/ja00413a027
PDF
Electron-transfer-induced reactions. Termination steps and efficiency of the chain process in SRN1 aromatic substitutions
Christian Amatore, Jean Pinson, Jean Michel Saveant, and Andre Thiebault
pp 6930 - 6937; DOI:
10.1021/ja00413a028
PDF
Low-temperature fluorination of aerosol suspensions of hydrocarbons utilizing elemental fluorine
James L. Adcock, Kiyoshi Horita, and Ehrengard B. Renk
pp 6937 - 6947; DOI:
10.1021/ja00413a029
PDF
Crystal and molecular structure of [tris(4,5-diisopropylimidazol-2-yl)phosphine]dichlorozinc(II)-bis[N,N-dimethylformamide]
Randy J. Read and Michael N. G. James
pp 6947 - 6952; DOI:
10.1021/ja00413a030
PDF
Tris(4,5-diisopropylimidazol-2-yl)phosphine:zinc(2+). A catalytically active model for carbonic anhydrase
R. S. Brown, N. J. Curtis, and J. Huguet
pp 6953 - 6959; DOI:
10.1021/ja00413a031
PDF
Carbon monoxide activation by organoactinides. Migratory carbon monoxide insertion into metal-hydrogen bonds to produce mononuclear formyls
Paul J. Fagan, Kenneth G. Moloy, and Tobin J. Marks
pp 6959 - 6962; DOI:
10.1021/ja00413a032
PDF
Formation constants of ion pair-ligand complexes. Application of crown ether network polymers
Roger Sinta and Johannes Smid
pp 6962 - 6963; DOI:
10.1021/ja00413a033
PDF
Efficient electron channel through self-aggregation of cytochrome c3 on an artificial membrane
Iwao Tabushi, Takako Nishiya, Tatsuhiko Yagi, and Hiroo Inokuchi
pp 6963 - 6965; DOI:
10.1021/ja00413a034
PDF
Design and synthesis of a model peptide with .beta.-endorphin-like properties
John W. Taylor, David G. Osterman, Richard J. Miller, and E. T. Kaiser
pp 6965 - 6966; DOI:
10.1021/ja00413a035
PDF
Total synthesis of ionophore antibiotic X-14547A. 1. Enantioselective synthesis of the tetrahydropyran and tetrahydroindan building blocks
K. C. Nicolaou, D. P. Papahatjis, D. A. Claremon, and R. E. Dolle
pp 6967 - 6969; DOI:
10.1021/ja00413a036
PDF
Total synthesis of ionophore antibiotic X-14547A. 2. Coupling of the tetrahydropyran and tetrahydroindan systems and construction of the butadienyl and ketopyrrole moieties
K. C. Nicolaou, D. A. Claremon, D. P. Papahatjis, and R. L. Magolda
pp 6969 - 6971; DOI:
10.1021/ja00413a037
PDF
Novel packing material for optical resolution: (+)-poly(triphenylmethyl methacrylate) coated on macroporous silica gel
Yoshio Okamoto, Shiro Honda, Ichiro Okamoto, Heimei Yuki, Shizuaki Murata, Ryoji Noyori, and Hidemasa Takaya
pp 6971 - 6973; DOI:
10.1021/ja00413a038
PDF
Solvation of ion pairs. Solvation complexes between the ion-paired 9-fluorenone anion radical and dipolar aprotic solvents
Kazuo Nakamura
pp 6973 - 6974; DOI:
10.1021/ja00413a039
PDF
24(S),25-Epoxycholesterol is a natural product of mammalian steroid biosynthesis
James A. Nelson, Sharon R. Steckbeck, and Thomas A. Spencer
pp 6974 - 6975; DOI:
10.1021/ja00413a040
PDF
Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3)
John R. Shapley, Allen C. Sievert, Melvyn Rowen Churchill, and Harvey J. Wasserman
pp 6975 - 6977; DOI:
10.1021/ja00413a041
PDF
Structures of two novel toxins from Protogonyaulax
Carol Fix Wichmann, Walter P. Niemczura, Heinrich K. Schnoes, Sherwood Hall, Paul B. Reichardt, and Stephen D. Darling
pp 6977 - 6978; DOI:
10.1021/ja00413a042
PDF
Structure, properties, and transport mechanism of iron(III) complex of mugineic acid, a possible phytosiderophore
Yukio Sugiura, Hisashi Tanaka, Yoshiki Mino, Toshimasa Ishida, Nagayo Ota, Masatoshi Inoue, Kyosuke Nomoto, Himeko Yoshioka, and Tsunematsu Takemoto
pp 6979 - 6982; DOI:
10.1021/ja00413a043
PDF
Picosecond laser study of the adiabatic photodissociation of an endoperoxide
S. Y. Hou, C. G. Dupuy, M. J. McAuliffe, D. A. Hrovat, and K. B. Eisenthal
pp 6982 - 6983; DOI:
10.1021/ja00413a044
PDF
Substituent effects on the aliphatic Claisen rearrangement. 1. Synthesis and rearrangement of cyano-substituted allyl vinyl ethers
Cynthia J. Burrows and Barry K. Carpenter
pp 6983 - 6984; DOI:
10.1021/ja00413a045
PDF
Substituent effects on the aliphatic Claisen rearrangements. 2. Theoretical analysis
Cynthia Burrows and Barry K. Carpenter
pp 6984 - 6986; DOI:
10.1021/ja00413a046
PDF
Transition-metal binding site of bleomycin. A synthetic analog capable of binding iron(II) to yield an oxygen-sensitive complex
Masami Otsuka, Makoto Yoshida, Susumu Kobayashi, Masaji Ohno, Yukio Sugiura, Tomohisa Takita, and Hamao Umezawa
pp 6986 - 6988; DOI:
10.1021/ja00413a047
PDF
Use of spy nuclei for relaxation studies in nuclear magnetic resonance
Y. Huang, G. Bodenhausen, and R. R. Ernst
pp 6988 - 6989; DOI:
10.1021/ja00413a048
PDF
Novel photoisomerization of 1-acylindoles to 3-acylindolenines. General entry to the total synthesis of Strychnos and Aspidosperma alkaloids
Yoshio Ban, Kiyoshi Yoshida, Jiro Goto, and Takeshi Oishi
pp 6990 - 6992; DOI:
10.1021/ja00413a049
PDF
Synthesis and reactions of a dimetallacyclohexene. Thermal conversion to an o-xylylene complex and phosphine-induced conversion to free o-xylylene and a new reactive dinuclear cobalt complex
William H. Hersh and Robert G. Bergman
pp 6992 - 6994; DOI:
10.1021/ja00413a050
PDF
ESR detection of the dimethyl ether radical cation
Jih Tzong Wang and Ffrancon Williams
pp 6994 - 6996; DOI:
10.1021/ja00413a051
PDF
Nature of the intermediate between 4a-hydroperoxyflavin and 4a-hydroxyflavin in the hydroxylation reaction of p-hydroxybenzoate hydroxylase. Synthesis of 6-aminopyrimidine-2,4,5(3H)-triones and the mechanism of aromatic hydroxylation by flavin monooxygenases
A. Wessiak and T. C. Bruice
pp 6996 - 6998; DOI:
10.1021/ja00413a052
PDF
Intercalation of potentially reactive transition-metal complexes in the lamellar manganese phosphide sulfide host lattice
Rene Clement
pp 6998 - 7000; DOI:
10.1021/ja00413a053
PDF
Copper(II) hemocyanin models
Vickie McKee, Jeffrey V. Dagdigian, Robert Bau, and Christopher A. Reed
pp 7000 - 7001; DOI:
10.1021/ja00413a054
PDF
Competitive inhibitor binding to the binuclear copper active site in tyrosinase
Marjorie E. Winkler, Konrad Lerch, and Edward I. Solomon
pp 7001 - 7003; DOI:
10.1021/ja00413a055
PDF
Novel intramolecular photorearrangement of alkane nitronate anions
K. Yamada, T. Kanekiyo, S. Tanaka, K. Naruchi, and M. Yamamoto
pp 7003 - 7005; DOI:
10.1021/ja00413a056
PDF
A micromethod for determining the branching points in oligosaccharides based on circular dichroism
Hung Wen Liu and Koji Nakanishi
pp 7005 - 7006; DOI:
10.1021/ja00413a057
PDF
Amino acids in the hydrolysis products of the reaction of carbon vapor with ammonia
Philip B. Shevlin, Daniel W. McPherson, and Paul Melius
pp 7006 - 7007; DOI:
10.1021/ja00413a058
PDF
Facile regio- and stereoselective total synthesis of racemic aklavinone
Tsung Tee Li and Yu Lin Wu
pp 7007 - 7009; DOI:
10.1021/ja00413a059
PDF
Unusual sesterterpenoids from the secretion of Ceroplastes floridensis (Coccidae), an orchard pest. Application of the allylic benzoate method for determination of absolute configuration
Yoko Naya, Kazuo Yoshihara, Takashi Iwashita, Hajime Komura, Koji Nakanishi, and Yasuo Hata
pp 7009 - 7011; DOI:
10.1021/ja00413a060
PDF
Thermal rearrangement of an allenic diazoalkane and intermolecular capture of a diazoethene by a cyclopropene to give a common dihydropyridazine product
Paul M. Lahti and Jerome A. Berson
pp 7011 - 7012; DOI:
10.1021/ja00413a061
PDF
Kinetic bistability in the permanganate oxidation of oxalate
John S. Reckley and Kenneth Showalter
pp 7012 - 7013; DOI:
10.1021/ja00413a062
PDF
Chemical and spectroscopic properties of the binuclear copper active site in Rhus laccase: direct confirmation of a reduced binuclear type 3 copper site in type 2 depleted laccase and intramolecular coupling of the type 3 to the type 1 and type 2 copper sites
C. D. LuBien, M. E. Winkler, T. J. Thamann, R. A. Scott, M. S. Co, K. O. Hodgson, and E. I. Solomon
pp 7014 - 7016; DOI:
10.1021/ja00413a063
PDF
Chemistry of sulfenic acids. 4. The first direct evidence for the involvement of sulfenic acids in the oxidation of thiols
Franklin A. Davis and Robert L. Billmers
pp 7016 - 7018; DOI:
10.1021/ja00413a064
PDF
Oxygen chiral phosphodiesters. 5. Stereochemical course of the hydrolysis of thymidine 3'-[(4-nitrophenyl)[17O,18O]phosphate] in water (oxygen-16) catalyzed by the exonuclease from bovine spleen
Shujaath Mehdi and John A. Gerlt
pp 7018 - 7020; DOI:
10.1021/ja00413a065
PDF
Comparison of the capacities of the perhydroxyl and the superoxide radicals to initiate chain oxidation of linoleic acid
Janusz M. Gebicki and Benon H. J. Bielski
pp 7020 - 7022; DOI:
10.1021/ja00413a066
PDF
Production of gas-phase bare transition metal clusters by laser photodissociation of organometallic cluster compounds
V. Vaida, N. J. Cooper, R. J. Hemley, and D. G. Leopold
pp 7022 - 7023; DOI:
10.1021/ja00413a067
PDF
Cobalt(III)-mediated peptide synthesis. 1. Cobalt(III)-activated amino acid methyl esters and the synthesis of dipeptides
C. R. Clark, R. F. Tasker, D. A. Buckingham, D. R. Knighton, D. R. K. Harding, and W. S. Hancock
pp 7023 - 7025; DOI:
10.1021/ja00413a068
PDF
Cobalt(III)-mediated peptide synthesis. 2. Synthesis of tetrapeptides and [leu5]-enkephalin
D. R. Knighton, D. R. K. Harding, M. J. Friar, W. S. Hancock, G. D. Reynolds, C. R. Clark, C. R. Clark, R. F. Tasker, and D. A. Buckingham
pp 7025 - 7026; DOI:
10.1021/ja00413a069
PDF
Total synthesis of FK-156 isolated from a Streptomyces as an immunostimulating peptide: application of a novel copper chelate amino protection
Keiji Hemmi, Hidekazu Takeno, Satoshi Okada, Osamu Nakaguchi, Yoshihiko Kitaura, and Masashi Hashimoto
pp 7026 - 7028; DOI:
10.1021/ja00413a070
PDF
Direct evidence for solvent coordination in migratory carbon monoxide insertion
Michael J. Wax and Robert G. Bergman
pp 7028 - 7030; DOI:
10.1021/ja00413a071
PDF
Binuclear ruthenium(II) porphyrins: reinvestigation of their preparation, characterization, and interactions with molecular oxygen
James P. Collman, Craig E. Barnes, Terrence J. Collins, Penelope J. Brothers, Judith Gallucci, and James A. Ibers
pp 7030 - 7032; DOI:
10.1021/ja00413a072
PDF
Diazomethane and thiobenzophenone: mechanistic elucidation of the Schoenberg reaction
Ivars Kalwinsch, Li Xingya, Joerg Gottstein, and Rolf Huisgen
pp 7032 - 7033; DOI:
10.1021/ja00413a073
PDF
Acenaphthyne
O. L. Chapman, J. Gano, P. R. West, M. Regitz, and G. Maas
pp 7033 - 7036; DOI:
10.1021/ja00413a074
PDF
Additions and Corrections - Radical Anion and Radical Trianion of 1,4-Bis(dimethyl-phosphino)benzene
W. Kaim, and H. Bock
pp 7036 - 7036; DOI:
10.1021/ja00413a600
PDF
Additions and Corrections - Isolation and Structure Elucidation of 22(S),23(S)-Methylene-Cholesterol. Evidence for Direct Bioalkylation of 22-Dehydrocholesterol
Pierre-Alain Blanc, and Carl Djerassi
pp 7036 - 7036; DOI:
10.1021/ja00413a601
PDF
Additions and Corrections - Complete Thermodynamic Analysis of the Hydration of Thirteen Pyridines and Pyridium Ions. The Special Case Of 2,6-Di-tert-butylpyridine
Edward M. Arnett, and B. Chawla
pp 7036 - 7036; DOI:
10.1021/ja00413a602
PDF
Additions and Corrections - Chiral Perturbation of Olefins by Deuterium Substitution. The Optical Activity and Circular Dichroism Behavior of (1S)·[2-2H]Norbornene and Deuterated Apoboronenes
Leo A. Paquette, Christopher W. Doecke, Francis R. Kearney, Alex F. Drake, and Stephen F. Mason
pp 7036 - 7037; DOI:
10.1021/ja00413a603
PDF
Additions and Corrections - Reversed Micelles of Aerosol-OT in Benzene. 3. Dynamics of the Solubilization of Picric Acid.
Kiyoshi Tamura, and Z. A. Schelly
pp 7037 - 7037; DOI:
10.1021/ja00413a604
PDF
Additions and Corrections - Evaluation and Prediction of the Stability of Bridgehead Olefins.
Wilehlm F. Maier, and Paul von Rague Schleyer
pp 7037 - 7037; DOI:
10.1021/ja00413a605
PDF
Additions and Corrections - Pentaprismane
Philip E. Eaton, Yat Sun Or, and Stephen J. Branca
pp 7037 - 7037; DOI:
10.1021/ja00413a606
PDF
Additions and Corrections - Structure and Properties of Transition-Metal Ylide Complexes. 2. Organometallic Complexes of Gold(III)
Judtih Stein, John P. Fackler, Jr., C. Paparizos, and H. W. Chen
pp 7037 - 7037; DOI:
10.1021/ja00413a607
PDF
Additions and Corrections - Spectroscopic Studies on Plastocyanin Single Crystals: A Detailed Electronic Structure Detemination of the Blue Copper Active Site
K. W. Penfield, R. R. Gay, R. S. Himmelwright, N. C .Eickman, V. A. Norris, H. C. Freeman, and E. I. Solomon
pp 7037 - 7037; DOI:
10.1021/ja00413a608
PDF
Additions and Corrections - Chelation of the Sodium Cation by Polyamines: A Novel Approach to Preferential Solvation, and to the Understanding of Sodium-23 Chemical Shifts and Quadrupolar Coupling Constants.
Alfred Delville, Christian Detellier, Andre Gerstmans, and Pierre Laszlo
pp 7037 - 7037; DOI:
10.1021/ja00413a609
PDF
Additions and Corrections - On the Question of Ground-State Perpendicular Olefins. Rehybridization of Twisted Olefins.
Philip Warner, and Richard F. Palmer
pp 7037 - 7037; DOI:
10.1021/ja00413a610
PDF
Additions and Corrections - Absorption and Circular Dichroism Spectra of Chiral Triquinacenes
L. A. Paquette, F. R. Kearney, A. F. Drake, and S. F. Mason
pp 7037 - 7037; DOI:
10.1021/ja00413a611
PDF
Additions and Corrections - Synthesis of the Left-Hand Segment of the Antitumor Agent CC-1065
Wendell Wierenga
pp 7037 - 7037; DOI:
10.1021/ja00413a612
PDF
Additions and Corrections - Carbon-Phosphorus Heterocycles. Synthesis of Phosphorus-Containing Cannabinoid Precursors and a Single-Crystal Analysis of 1,2,3,4-Tetrahydro-10-hydroxy-8-n-pentyl-5H-phosphorus-[3,4-c[I]]benzopyran-5-one-3-Oxide
Jang B. Rampal, K. Darrell Berlin, Nantelle S. Pantaleo, Ann McGuffy, and Dick van der helm
pp 7037 - 7037; DOI:
10.1021/ja00413a613
PDF
Book Reviews

pp 7038 - 7040; DOI:
10.1021/ja00413a614
PDF

Issue 24


Rates of conformational changes in the anion radicals of bianthrones
P. Neta and Dennis H. Evans
pp 7041 - 7045; DOI:
10.1021/ja00414a001
PDF
Comparison of proton- and electron-transfer equilibriums and rates for tetraalkylhydrazines
Stephen F. Nelsen, Patrick J. Kinlen, and Dennis H. Evans
pp 7045 - 7050; DOI:
10.1021/ja00414a002
PDF
ESR spectra and structure of the perchloryl fluoride radical anion (FClO3-): a 33 valence electron radical with C3v symmetry
A. Hasegawa and Ffrancon Williams
pp 7051 - 7054; DOI:
10.1021/ja00414a003
PDF
Selenium-77 NMR studies of some organoselenium compounds containing-selenium double bonds
Edward R. Cullen, Frank S. Guziec, Christopher J. Murphy, Tuck C. Wong, and Kenneth K. Andersen
pp 7055 - 7057; DOI:
10.1021/ja00414a004
PDF
Negative ion states of cyclopentadiene derivatives
Stuart W. Staley, Mark D. Bjorke, Judith C. Giordan, Michael R. McMillan, and John H. Moore
pp 7057 - 7061; DOI:
10.1021/ja00414a005
PDF
Electronic spectroscopy of a diplatinum(II) octaphosphite complex
W. A. Fordyce, J. G. Brummer, and G. A. Crosby
pp 7061 - 7064; DOI:
10.1021/ja00414a006
PDF
Three-dimensional structure of the superconductor (TMTSF)2AsF6 and the spin-charge separation hypothesis
F. Wudl
pp 7064 - 7069; DOI:
10.1021/ja00414a007
PDF
Neophyl rearrangements in crystalline bis(3,3,3-triphenylpropanoyl) peroxide. 1. Dynamic studies by EPR
Donald W. Walter and J. Michael McBride
pp 7069 - 7073; DOI:
10.1021/ja00414a008
PDF
Neophyl rearrangements in crystalline bis(3,3,3-triphenylpropanoyl) peroxide. 2. Structural studies by x-ray and EPR. Mechanistic role of inert molecules
Donald W. Walter and J. Michael McBride
pp 7074 - 7084; DOI:
10.1021/ja00414a009
PDF
Mercaptide-chelated protoheme. A synthetic model compound for cytochrome P-450
T. G. Traylor, Terry C. Mincey, and Albin P. Berzinis
pp 7084 - 7089; DOI:
10.1021/ja00414a010
PDF
A new mechanism involving cyclic tautomers for the reaction with nucleophiles of the water-soluble peptide coupling reagent 1-ethyl-3-(3'-(dimethylamino)propyl)carbodiimide (EDC)
Andrew Williams and Ibrahim T. Ibrahim
pp 7090 - 7095; DOI:
10.1021/ja00414a011
PDF
Formation and reactions of dithiodicarbenium salts
Ronald L. Blankespoor, Michael P. Doyle, William H. Hedstrand, William H. Tamblyn, and David A. Van Dyke
pp 7096 - 7101; DOI:
10.1021/ja00414a012
PDF
Absolute rate constants for hydrocarbon autoxidation. 31. Autoxidation of cumene in the presence of tertiary amines
J. A. Howard and T. Yamada
pp 7102 - 7106; DOI:
10.1021/ja00414a013
PDF
Electronic control of stereoselectivity. 8. The stereochemical course of electrophilic additions to aryl-substituted 9-isopropylidenebenzonorbornenes
Leo A. Paquette, Larry W. Hertel, Rolf Gleiter, Michael C. Boehm, Mark A. Beno, and Gary G. Christoph
pp 7106 - 7121; DOI:
10.1021/ja00414a014
PDF
Electronic control of stereoselectivity. 9. The stereochemical course of electrophilic additions to aryl-substituted benzobicyclo[2.2.2]octadienes
Leo A. Paquette, Francois Bellamy, Gregory J. Wells, Michael C. Boehm, and Rolf Gleiter
pp 7122 - 7133; DOI:
10.1021/ja00414a015
PDF
Gas-phase reactions of negative ions with alkyl nitrites
Gary K. King, M. Matti Maricq, Veronica M. Bierbaum, and C. H. DePuy
pp 7133 - 7140; DOI:
10.1021/ja00414a016
PDF
Nucleophile competition in aromatic SRN1 reactions. Evaluation of nucleophilic reactivities and evidence of reaction mechanism
Carlo Galli and Joseph F. Bunnett
pp 7140 - 7147; DOI:
10.1021/ja00414a017
PDF
Aluminum-27 nuclear magnetic resonance study of the room-temperature melt aluminum trichloride butylpyridinium chloride
Joel L. Gray and Gary E. Maciel
pp 7147 - 7151; DOI:
10.1021/ja00414a018
PDF
Phytochrome models. 6. Conformation control by membrane of biliverdin dimethyl ester incorporated into lipid vesicles
Inga Mai Tegmo-Larsson, Silvia E. Braslavsky, Stephen Culshaw, Raymond M. Ellul, Claude Nicolau, and Kurt Schaffner
pp 7152 - 7158; DOI:
10.1021/ja00414a019
PDF
Spin-statistical factor in the triplet-triplet annihilation of anthracene triplets
Jack Saltiel, Gary R. March, William K. Smothers, Susan A. Stout, and James L. Charlton
pp 7159 - 7164; DOI:
10.1021/ja00414a020
PDF
Analysis of the decay of 1-phenyl-2-(2-naphthyl)ethene triplets. A nanosecond laser pulse study
Helmut Goerner, David Eaker, and Jack Saltiel
pp 7164 - 7169; DOI:
10.1021/ja00414a021
PDF
Liquid crystalline solvents as mechanistic probes. 6. Dynamic quenching of pyrene fluorescence by 5.alpha.-cholestan-3.beta.-yldimethylamine in the liquid crystalline and isotropic phases of a cholesteric solvent
Valerie C. Anderson, Bruce B. Craig, and Richard G. Weiss
pp 7169 - 7176; DOI:
10.1021/ja00414a022
PDF
Photochemistry of the tetranuclear clusters tridecacarbonyldihydrotetraruthenium, tridecacarbonyldihydroirontriruthenium, and tridecacarbonyldihydroirontriosmium
Henry C. Foley and Gregory L. Geoffroy
pp 7176 - 7180; DOI:
10.1021/ja00414a023
PDF
Photochemistry of surface-confined organometallics: photochemical release of a surface-confined cobalt carbonyl catalyst
Carol L. Reichel and Mark S. Wrighton
pp 7180 - 7189; DOI:
10.1021/ja00414a024
PDF
Synthetic applications of conjugated azocarbinols. Radical chain hydrophenylation and hydrocyclohexenylation of haloethenes
Yau-Min Chang, Ralph Profetto, and John Warkentin
pp 7189 - 7195; DOI:
10.1021/ja00414a025
PDF
Synthesis and properties of 12-fluororetinal and 12-fluororhodopsin. Model system for fluorine-19 NMR studies of visual pigments
Robert S. H. Liu, Hiroyuki Matsumoto, Alfred E. Asato, Marlene Denny, Yoshinori Shichida, Toru Yoshizawa, and F. W. Dahlquist
pp 7195 - 7201; DOI:
10.1021/ja00414a026
PDF
Photochemical transformations of small ring compounds. 116. Photochemistry of cyclopropene derivatives. Synthesis of the tricyclo[2.2.0.02,6]hexane ring system via a photosensitized [2 + 2] cycloaddition reaction
Albert Padwa, Thomas J. Blacklock, Diana M. Cordova, and Roman Loza
pp 7202 - 7210; DOI:
10.1021/ja00414a027
PDF
Nuclear spin polarization effects in radical ion pair reactions. Comparison between triplet state and radical ion reactivity
Heinz D. Roth and Marcia L. Manion Schilling
pp 7210 - 7217; DOI:
10.1021/ja00414a028
PDF
Mechanism of thermolysis of endoperoxides of aromatic compounds. Activation parameters, magnetic field, and magnetic isotope effects
Nicholas J. Turro and Ming Fea Chow
pp 7218 - 7224; DOI:
10.1021/ja00414a029
PDF
Micellar microviscosity of ionic surfactants under high pressure
Nicholas J. Turro and Tsuneo Okubo
pp 7224 - 7228; DOI:
10.1021/ja00414a030
PDF
Singlet electronic energy transfer to azoalkanes: separation of collisional and long-range mechanisms by steric and solvent-viscosity effects
Carl C. Wamser, Lillian Lou, Jeannette Mendoza, and Eric Olson
pp 7228 - 7232; DOI:
10.1021/ja00414a031
PDF
Type II photoelimination from .alpha.-cycloalkylacetophenones and a polystyrene-bound analog
Carl C. Wamser and William R. Wagner
pp 7232 - 7234; DOI:
10.1021/ja00414a032
PDF
Quenching of singlet excited states of electron-deficient anthracenes by allyl- and benzyltrialkylstannanes
David F. Eaton
pp 7235 - 7239; DOI:
10.1021/ja00414a033
PDF
Electrophilic aromatic substitution. Charge-transfer excited states and the nature of the activated complex
S. Fukuzumi and J. K. Kochi
pp 7240 - 7252; DOI:
10.1021/ja00414a034
PDF
Rate constants for the reaction of singlet oxygen with conjugated dienes
Bruce M. Monroe
pp 7253 - 7256; DOI:
10.1021/ja00414a035
PDF
Photochemical methoxide exchange in some nitromethoxybenzenes. Role of the nitro group in SN2 Ar reactions
H. C. H. A. Van Riel, G. Lodder, and E. Havinga
pp 7257 - 7262; DOI:
10.1021/ja00414a036
PDF
Photochemistry of the phenanthrene-stilbene system. Cycloaddition and singlet-sensitized isomerization
Richard A. Caldwell, Kazuhiko Mizuno, P. E. Hansen, L. P. Vo, M. Frentrup, and C. D. Ho
pp 7263 - 7269; DOI:
10.1021/ja00414a037
PDF
Photoelectrochemical cells based on hydrogen-atom abstraction and electron-transfer reactions in solution: systems based on benzophenone, 2-propanol, trialkylamines, and methylviologen
K. Chandrasekaran and David G. Whitten
pp 7270 - 7275; DOI:
10.1021/ja00414a038
PDF
Infrared multiple-photon absorption in polyatomic molecules: silicon tetrafluoride, cyclobutanone, ammonia, and hexafluorobenzene
Vladimir Starov, Nur Selamoglu, and Colin Steel
pp 7276 - 7281; DOI:
10.1021/ja00414a039
PDF
Infrared multiphoton absorption by medium-sized molecules in the gas phase. Hexafluorobenzene and 2,3-dihydropyran
Michael T. Duignan, Dana Garcia, and Ernest Grunwald
pp 7281 - 7287; DOI:
10.1021/ja00414a040
PDF
Photochemical transformations. 30. Photosolvolysis of benzyl chlorides in tert-butyl alcohol. 2. Nature of excited states
Stanley J. Cristol and Thomas H. Bindel
pp 7287 - 7293; DOI:
10.1021/ja00414a041
PDF
Photochemistry of alkenes. 8. Sterically congested alkenes
Paul J. Kropp and Frank P. Tise
pp 7293 - 7298; DOI:
10.1021/ja00414a042
PDF
Organic photochemistry with 6.7-eV photons: 1,4-cyclohexadiene and 1,4-cyclohexadiene-3,3,6,6-d4
R. Srinivasan, Lloyd S. White, Angelo R. Rossi, and Gary A. Epling
pp 7299 - 7304; DOI:
10.1021/ja00414a043
PDF
Kinetic scheme for intramolecular excimer formation in bis(.alpha.-naphthylmethyl)ether, involving different starting conformations
R. Todesco, J. Gelan, H. Martens, J. Put, and F. C. De Schryver
pp 7304 - 7312; DOI:
10.1021/ja00414a044
PDF
Photochemical processes of benzophenone in microheterogeneous systems
Andre M. Braun, Marianne Krieg, Nicholas J. Turro, M. Aikawa, I. R. Gould, G. A. Graf, and Plato Chun Chih Lee
pp 7312 - 7316; DOI:
10.1021/ja00414a045
PDF
Solution-phase photodecarbonylation of the bicyclo[3.1.0]hexan-3-one system
Robert S. Cooke and Gregory D. Lyon
pp 7317 - 7322; DOI:
10.1021/ja00414a046
PDF
Quenching, radical formation, and disproportionation in the photoreduction of 4-carboxybenzophenone by 4-carboxybenzhydrol, hydrazine, and hydrazinium ion
Shai Inbar, Henry Linschitz, and Saul G. Cohen
pp 7323 - 7328; DOI:
10.1021/ja00414a047
PDF
Deactivation of triplet phenyl alkyl ketones by conjugatively electron-withdrawing substituents
Peter J. Wagner and Elizabeth J. Siebert
pp 7329 - 7335; DOI:
10.1021/ja00414a048
PDF
Regioelectronic control of intramolecular charge-transfer quenching in excited triplet p-acylbenzoate esters
Peter J. Wagner and Elizabeth J. Siebert
pp 7335 - 7337; DOI:
10.1021/ja00414a049
PDF
Photoinduced elimination of hydrogen from [Pt2H3(dppm)2]PF6 and [Pt2H2Cl(dppm)2]PF6
Robert H. Morris, Henry C. Foley, Tom S. Targos, and Gregory L. Geoffroy
pp 7337 - 7339; DOI:
10.1021/ja00414a050
PDF
A novel series of macrocyclic lactones
Abraham Shanzer, Jacqueline Libman, and Felix Frolow
pp 7339 - 7340; DOI:
10.1021/ja00414a051
PDF
Synthesis of the first homoleptic trifluorosilyl .sigma.-bonded metal compounds by cocondensation of metal vapor with trifluorosilyl radicals
Thomas R. Bierschenk, T. J. Juhlke, and Richard J. Lagow
pp 7340 - 7341; DOI:
10.1021/ja00414a052
PDF
1-Deoxy-D-threo-2-pentulose: the precursor of the five-carbon chain of the thiazole of thiamine
Serge David, Bernard Estramareix, Jean Claude Fischer, and Michel Therisod
pp 7341 - 7342; DOI:
10.1021/ja00414a053
PDF
Sonochemistry and sonocatalysis of iron carbonyls
Kenneth S. Suslick, Paul F. Schubert, and James W. Goodale
pp 7342 - 7344; DOI:
10.1021/ja00414a054
PDF
1-Silacyclopent-3-en-1-ylidene, a cyclic silylene from the reactions of silicon atoms and a silicon atom synthon
Peter P. Gaspar, Yue Shen Chen, Adam P. Helfer, Stanislaw Konieczny, Eric C. L. Ma, and Siu Hong Mo
pp 7344 - 7345; DOI:
10.1021/ja00414a055
PDF
Lewis acid enhancement of photochemical trans .fwdarw. cis isomerization of .alpha.,.beta.-unsaturated esters
Frederick D. Lewis and Joe D. Oxman
pp 7345 - 7347; DOI:
10.1021/ja00414a056
PDF
Formation of aminyl vs. aminoalkyl radicals in the photooxidation of diethylamine
Frederick D. Lewis and Paul E. Correa
pp 7347 - 7349; DOI:
10.1021/ja00414a057
PDF
Electron-transfer chemistry of the luminescent excited state of octachlorodirhenate(III)
Daniel G. Nocera and Harry B. Gray
pp 7349 - 7350; DOI:
10.1021/ja00414a058
PDF
Stable simple enols. 2. Correlated rotation in two .beta..beta.-dimesityl-.alpha.-arylethenols. A probable example of a three-ring flip
Silvio E. Biali and Zvi Rappoport
pp 7350 - 7351; DOI:
10.1021/ja00414a059
PDF
Kinetics of the reaction of cis-diammineplatinum dichloride Pt(NH3)2Cl2 with DNAs of different G-C content
N. P. Johnson and J. L. Butour
pp 7351 - 7352; DOI:
10.1021/ja00414a060
PDF
Phenylmethylpolysilanes: formable silane copolymers with potential semiconducting properties
Robert West, Lawrence D. David, Peter I. Djurovich, Kimberly L. Stearley, K. S. V. Srinivasan, and Hyuk Yu
pp 7352 - 7354; DOI:
10.1021/ja00414a061
PDF
Soluble copper hydrides: solution behavior and reactions related to carbon monoxide hydrogenation
Gary V. Goeden and Kenneth G. Caulton
pp 7354 - 7355; DOI:
10.1021/ja00414a062
PDF
Severe steric hindrance: hydrogen bonding and the consequences of its inhibition. Equilibrium hydrogen isotope effects
Jack C. Day
pp 7355 - 7357; DOI:
10.1021/ja00414a063
PDF
Stereospecific total syntheses of the natural antitumor agent, (.alpha.S, 5S)-.alpha.-amino-3-chloro-4,5-dihydro-5-isoxazoleacetic acid, and its unnatural C-5 epimer
Richard B. Silverman and Mark W. Holladay
pp 7357 - 7358; DOI:
10.1021/ja00414a064
PDF
Structures of titanacyclobutanes
J. Bosco Lee, Gregory J. Gajda, William P. Schaefer, Thomas R. Howard, Takao Ikariya, Daniel A. Straus, and Robert H. Grubbs
pp 7358 - 7361; DOI:
10.1021/ja00414a065
PDF
Reactivity of distorted C5H5Fe(CO)2 (olefin) cations toward nucleophilic attack
T. C. T. Chang, Bruce M. Foxman, M. Rosenblum, and C. Stockman
pp 7361 - 7362; DOI:
10.1021/ja00414a066
PDF
Identification of three alkylated nucleotide adducts from the reaction of guanosine 5'-monophosphate with phosphoramide mustard
Vanessa T. Vu, Catherine C. Fenselau, and O. Michael Colvin
pp 7362 - 7364; DOI:
10.1021/ja00414a067
PDF
A bacteriorhodopsin analog containing the retinal nitroxide free radical
Rosalie K. Crouch, Thomas G. Ebrey, and Rajni Govindjee
pp 7364 - 7366; DOI:
10.1021/ja00414a068
PDF
Theoretical studies of the 1,2-hydrogen shift. 11. Controversial barrier height between silaethylene and methylsilylene
Yasunori Yoshioka and Henry E. Schaefer
pp 7366 - 7367; DOI:
10.1021/ja00414a069
PDF
Cucurbituril
W. A. Freeman, W. L. Mock, and N. Y. Shih
pp 7367 - 7368; DOI:
10.1021/ja00414a070
PDF
Successive Beckmann rearrangement-alkylation sequence by organoaluminum reagents. Simple route to dl-pumiliotoxin C
Kazunobu Hattori, Yasushi Matsumura, Tohru Miyazaki, Keiji Maruoka, and Hisashi Yamamoto
pp 7368 - 7370; DOI:
10.1021/ja00414a071
PDF
Oscillatory behavior in fluorescence intensity from irradiated sodium dodecyl sulfate micellar solutions of zinc porphyrin
Shinji Tsuchiya, Hiroyuki Kanai, and Manabu Seno
pp 7370 - 7371; DOI:
10.1021/ja00414a072
PDF
P-450-tpye dioxygen activation using hydrogen/colloidal platinum as an effective electron donor
Iwao Tabushi and Akira Yazaki
pp 7371 - 7373; DOI:
10.1021/ja00414a073
PDF
Ordered magnetic bimetallic chains: a novel class of one-dimensional compounds
Alain Gleizes and Michel Verdaguer
pp 7373 - 7374; DOI:
10.1021/ja00414a074
PDF
Synthesis of macrocyclic peptide thiolactones as models of the metastable binding sites of .alpha.2-macroglobulin and complement protein C3b
Shabbir A. Khan and Bruce W. Erickson
pp 7374 - 7376; DOI:
10.1021/ja00414a075
PDF
Encircling of water by crown compounds
George R. Newkome, Hellen C. R. Taylor, Frank R. Fronczek, Terry J. Delord, Dalip K. Kohli, and Fritz Voegtle
pp 7376 - 7378; DOI:
10.1021/ja00414a076
PDF
Experimental evidence for the absence of bonding electron density between inverted carbon atoms
Pinakpani Chakrabarti, Paul Seiler, Jack D. Dunitz, Arnulf Dieter Schluter, and Guenter Szeimies
pp 7378 - 7380; DOI:
10.1021/ja00414a077
PDF
Synthesis of dl-coriolin
Barry M. Trost and Dennis P. Curran
pp 7380 - 7381; DOI:
10.1021/ja00414a078
PDF
Hopping and delocalized electrons in class II mixed-valence oxovanadates
Subhash P. Harmalker and Michael T. Pope
pp 7381 - 7383; DOI:
10.1021/ja00414a079
PDF
Bimetallic catalysts from pseudotetrahedral iridium-tungsten clusters. Synthesis and crystal structures of (.eta.5-C5H5)WIr3(CO)11 and (.eta.5-C5H5)2W2Ir2(CO)10
John R. Shapley, Steven J. Hardwick, Daniel S. Foose, Galen D. Stucky, Melvyn Rowen Churchill, Clifford Bueno, and John P. Hutchinson
pp 7383 - 7385; DOI:
10.1021/ja00414a080
PDF
Remarkably facile osmium-osmium bond cleavage in the reaction of H2Os3(CO)10 with a tungsten carbyne. Crystal structures of CpWOs3(CO)11[C(O)CH2C6H4Me] and Cp2W2Os(CO)7[C2(C6H4Me)2]
John R. Shapley, Joon Taik Park, Melvyn Rowen Churchill, Clifford Bueno, and Harvey J. Wasserman
pp 7385 - 7387; DOI:
10.1021/ja00414a081
PDF
Reaction of Os3(CO)9(C2Ph2) with diazomethane. Photoinduced loss of dinitrogen and thermally activated coupling of methylene and diphenylacetylene on the triosmium framework
Allen D. Clauss, John R. Shapley, and Scott R. Wilson
pp 7387 - 7388; DOI:
10.1021/ja00414a082
PDF
Activation barriers for the trans .fwdarw. cis photoisomerization of all-trans-retinal
Walter H. Waddell and Kohji Chihara
pp 7389 - 7390; DOI:
10.1021/ja00414a083
PDF
Stereoselective ion-pair formation between the tris(ethylenediamine)cobalt(III) ion and the glycinatobis(oxalato)cobaltate(III) ion
Akira Tatehata, Mikio Iiyoshi, and Keiya Kotsuji
pp 7391 - 7392; DOI:
10.1021/ja00414a084
PDF
Side-chain conformational changes of some amino acids and dipeptides having aromatic side chains induced by complexation with cycloamyloses
Yoshio Inoue, Takehiro Okuda, and Yoshiaki Miyata
pp 7393 - 7394; DOI:
10.1021/ja00414a085
PDF
Selectivity in binding a phenanthridinium-dinucleotide derivative to homopolynucleotides
Robert L. Letsinger and Margaret E. Schott
pp 7394 - 7396; DOI:
10.1021/ja00414a086
PDF
Preparation and spectral properties of lipophilic fluorescein derivatives: application to plasma low-density lipoprotein
J. R. Falck, Monty Krieger, J. L. Goldstein, and M. S. Brown
pp 7396 - 7398; DOI:
10.1021/ja00414a087
PDF
A stereospecific synthesis of highly substituted tetrahydrofurans
David R. Williams, James G. Phillips, and Bruce A. Barner
pp 7398 - 7399; DOI:
10.1021/ja00414a088
PDF
Book Reviews

pp 7400 - 7402; DOI:
10.1021/ja00414a600
PDF

Issue 25


Photochemical studies of an oleate oil in water microemulsion
S. S. Atik and J. K. Thomas
pp 7403 - 7406; DOI:
10.1021/ja00415a001
PDF
Electronic structure of the phosphenium ions PH2+, HPF+, and PF2+
James F. Harrison
pp 7406 - 7413; DOI:
10.1021/ja00415a002
PDF
Theoretical study of the role of valence and Rydberg states in the photochemistry of ethylene
E. M. Evleth and A. Sevin
pp 7414 - 7422; DOI:
10.1021/ja00415a003
PDF
Kinetics of outer-sphere electron transfers between metal complexes in solutions and polymeric films on modified electrodes
Tokuji Ikeda, C. R. Leidner, and Royce W. Murray
pp 7422 - 7425; DOI:
10.1021/ja00415a004
PDF
Molecules in an electric field. Model for molecular geometry
Hiroshi Nakatsuji, Toshiaki Hayakawa, and Teijiro Yonezawa
pp 7426 - 7432; DOI:
10.1021/ja00415a005
PDF
Vibrational spectroscopy of the electronically excited state. 4. Nanosecond and picosecond time-resolved resonance Raman spectroscopy of carotenoid excited states
Richard F. Dallinger, Stuart Farquharson, William H. Woodruff, and Michael A. J. Rodgers
pp 7433 - 7440; DOI:
10.1021/ja00415a006
PDF
Vibrational spectroscopy of the electronically excited state. 5. Time-resolved resonance Raman study of tris(bipyridine)ruthenium(II) and related complexes. Definitive evidence for the "localized" MLCT state
Paul G. Bradley, Nurit Kress, Boyce A. Hornberger, Richard F. Dallinger, and William H. Woodruff
pp 7441 - 7446; DOI:
10.1021/ja00415a007
PDF
Experimental study of the n-silicon/acetonitrile interface: Fermi level pinning and surface states investigation
J. N. Chazalviel and T. B. Truong
pp 7447 - 7451; DOI:
10.1021/ja00415a008
PDF
Coupled fragment molecular orbital method for interacting systems
Hiroshi Fujimoto, Nobuaki Koga, and Kenichi Fukui
pp 7452 - 7457; DOI:
10.1021/ja00415a009
PDF
Localized molecular orbital studies of three-, four-, five-, and six-membered ring molecules and ions formed from sulfur and nitrogen
A. A. Bhattacharyya, A. Bhattacharyya, R. R. Adkins, and A. G. Turner
pp 7458 - 7465; DOI:
10.1021/ja00415a010
PDF
Kinetic and thermodynamic contributions to energy barriers and energy wells: application to proton-bound dimers in gas-phase proton-transfer reactions
Douglas E. Magnoli and Joseph R. Murdoch
pp 7465 - 7469; DOI:
10.1021/ja00415a011
PDF
Ab initio studies of (1,2)-hydrogen migrations in open-shell hydrocarbons: vinyl radical, ethyl radical, and triplet methylcarbene
Lawrence B. Harding
pp 7469 - 7475; DOI:
10.1021/ja00415a012
PDF
The central bond length in hexaphenylethane and hexakis(2,6-di-tert-butyl-4-biphenylyl)ethane
Eiji Osawa, Yoshiaki Onuki, and Kurt Mislow
pp 7475 - 7479; DOI:
10.1021/ja00415a013
PDF
Selectivity and directed charge transfer through an electroactive metallopolymer film
Charles D. Ellis, W. Rorer Murphy, and Thomas J. Meyer
pp 7480 - 7483; DOI:
10.1021/ja00415a014
PDF
Association of alkali and alkaline earth cations with benzo-18-crown-6 and its neutral and negatively charged acyclic analogs in methanol solution
Gianfranco Ercolani, Luigi Mandolini, and Bernardo Masci
pp 7484 - 7489; DOI:
10.1021/ja00415a015
PDF
Homogeneous catalysis of the electrochemical reduction of dioxygen by a macrocyclic cobalt(III) complex
Thomas Geiger and Fred C. Anson
pp 7489 - 7496; DOI:
10.1021/ja00415a016
PDF
Molecular generality of surface-enhanced Raman spectroscopy (SERS). A detailed investigation of the hexacyanoruthenate ion adsorbed on silver and copper electrodes
Craig S. Allen and Richard P. Van Duyne
pp 7497 - 7501; DOI:
10.1021/ja00415a017
PDF
Organometallic electron reservoirs. 5. Novel mode of carbon-hydrogen activation using dioxygen via superoxide radical anion in solution and in the solid state with C5R5FeIC6R'6. Subsequent bond formation with carbon, silicon, phosphorus, manganese, iron, chromium, and molybdenum
Didier Astruc, Jean Rene Hamon, Enrique Roman, and Pascal Michaud
pp 7502 - 7514; DOI:
10.1021/ja00415a018
PDF
Synthesis and characterization of the pentacarbonylmanganese(0) radical, Mn(CO)5, in low-temperature matrixes
Stephen P. Church, Martyn Poliakoff, John A. Timney, and James J. Turner
pp 7515 - 7520; DOI:
10.1021/ja00415a019
PDF
Palladium-catalyzed cyclocarbonylation of acetylenic alcohols to methylene lactones. Scope and synthesis of appropriate substrates
Timothy F. Murray, Edward G. Samsel, Vijaya Varma, and Jack R. Norton
pp 7520 - 7528; DOI:
10.1021/ja00415a020
PDF
Anionic metal hydride catalysts. 1. Synthesis of potassium hydrido(phosphine)ruthenate complexes
Guido P. Pez, Roger A. Grey, and Jeff Corsi
pp 7528 - 7535; DOI:
10.1021/ja00415a021
PDF
Anionic metal hydride catalysts. 2. Application to the hydrogenation of ketones, aldehydes, carboxylic acid esters, and nitriles
Roger A. Grey, Guido P. Pez, and Andrea Wallo
pp 7536 - 7542; DOI:
10.1021/ja00415a022
PDF
Cobalt(III) complex of pseudotetrapeptide A of bleomycin
J. C. Dabrowiak and M. Tsukayama
pp 7543 - 7550; DOI:
10.1021/ja00415a023
PDF
Palladium-catalyzed 1,3-oxygen-to-carbon alkyl shifts. Basic studies
Barry M. Trost and Thomas A. Runge
pp 7550 - 7559; DOI:
10.1021/ja00415a024
PDF
Palladium-catalyzed 1,3-oxygen-to-carbon alkyl shifts. A cyclopentanone synthesis
Barry M. Trost and Thomas A. Runge
pp 7559 - 7572; DOI:
10.1021/ja00415a025
PDF
Stereochemical studies on the intramolecular imino Diels-Alder reaction
Bassam Nader, Thomas R. Bailey, Richard W. Franck, and Steven M. Weinreb
pp 7573 - 7580; DOI:
10.1021/ja00415a026
PDF
Activation of molecular oxygen. Kinetic studies of the oxidation of hindered phenols with cobalt-dioxygen complexes
Alan Zombeck, Russell S. Drago, Barry B. Corden, and John H. Gaul
pp 7580 - 7585; DOI:
10.1021/ja00415a027
PDF
Gas-phase ion-molecule reactions of cyclopentadienyl anion (c-C5H5-)
Richard N. McDonald, A. Kasem Chowdhury, and D. W. Setser
pp 7586 - 7589; DOI:
10.1021/ja00415a028
PDF
Photochemical hydroformylation of olefins with cobalt catalysts. 1. Neutral cobalt carbonyls
Manfred J. Mirbach, Marlis F. Mirbach, Alfons Saus, Nikolaos Topalsavoglou, and Tuyet Nhu Phu
pp 7590 - 7594; DOI:
10.1021/ja00415a029
PDF
Photochemical hydroformylation of olefins with cobalt catalysts. 2. Ionic cobalt carbonyls
Manfred J. Mirbach, Marlis F. Mirbach, Alfons Saus, Nikolaos Topalsavoglou, and Tuyet Nhu Phu
pp 7594 - 7601; DOI:
10.1021/ja00415a030
PDF
Novel thermal-catalyzed isomerization of certain substituted 1,2,6-triphenyl-4-phosphorinanones. Stereochemical and conformational analysis of substituted 1,2,6-triphenyl-4-phosphorinanones and 2,6-diphenyl-4-thianones via ultraviolet spectrometry, carbon-13 NMR spectroscopy, and liquid crystal circular dichroism spectropolarimetry
Jang B. Rampal, Nagichettiar Satyamurthy, John M. Bowen, Neil Purdie, and K. Darrell Berlin
pp 7602 - 7609; DOI:
10.1021/ja00415a031
PDF
Nuclear magnetic resonance investigation of the spontaneous decarboxylation of 2-oxalopropionic acid. 2. Species in solution
Gregory Kubala and A. E. Martell
pp 7609 - 7615; DOI:
10.1021/ja00415a032
PDF
Synthesis of 3,6-disulfonated 4-aminonaphthalimides
Walter W. Stewart
pp 7615 - 7620; DOI:
10.1021/ja00415a033
PDF
"Wolf and Lamb" reactions equilibrium and kinetic effects in multipolymer systems
B. J. Cohen, M. A. Kraus, and A. Patchornik
pp 7620 - 7629; DOI:
10.1021/ja00415a034
PDF
The structure of CC-1065, a potent antitumor agent and its binding to DNA
C. G. Chidester, W. C. Krueger, S. A. Mizsak, D. J. Duchamp, and D. G. Martin
pp 7629 - 7635; DOI:
10.1021/ja00415a035
PDF
Electrochemical study of the kinetics of NADH being oxidized by diimines derived from diaminobenzenes and diaminopyrimidines
Akira Kitani, Ying Hung So, and Larry L. Miller
pp 7636 - 7641; DOI:
10.1021/ja00415a036
PDF
13-(Trifluoromethyl)retinal forms an active and far-red-shifted chromophore in bacteriorhodopsin
Wolfgang Gaertner, Dieter Oesterhelt, Paul Towner, Henning Hopf, and Ludger Ernst
pp 7642 - 7643; DOI:
10.1021/ja00415a037
PDF
Synthesis of stabilized phenyltin(II) compounds: inhibition of the conversion to tin(IV) by substitution
M. P. Bigwood, P. J. Corvan, and J. J. Zuckerman
pp 7643 - 7646; DOI:
10.1021/ja00415a038
PDF
Models for the coordination site of iron in cytochrome P-450. Synthesis and spectroscopic properties of a dioxygen adduct of (2,3,5,6-tetrafluorophenylthiolato)iron(II) tetraphenylpivalcylporphyrin
M. Schappacher, L. Ricard, R. Weiss, R. Montiel-Montoya, E. Bill, U. Gonser, and A. Trautwein
pp 7646 - 7648; DOI:
10.1021/ja00415a039
PDF
Synthesis and structure of triphenylphosphinegold-dodecacarbonyltricobaltiron ([FeCo3(CO)12AuPPh3]): a trimetallic trigonal-bipyramidal cluster. Gold derivatives as structural analogs of hydrides
Joseph W. Lauher and Kenneth Wald
pp 7648 - 7650; DOI:
10.1021/ja00415a040
PDF
Cell-free biosynthesis of penicillins. Conversion of peptides into new .beta.-lactam antibiotics
Gulam A. Bahadur, Jack E. Baldwin, John J. Usher, Edward P. Abraham, Gamini S. Jayatilake, and Robert L. White
pp 7650 - 7651; DOI:
10.1021/ja00415a041
PDF
Deuterium isotope effects on methyl transfer to alcohols. Possible asynchronous solvent repolarization and internal structural changes
Joseph L. Kurz, Jasun Lee, and Susan Rhodes
pp 7651 - 7653; DOI:
10.1021/ja00415a042
PDF
Homolytic substitution at carbon: 1,3- and 1,5-ring closures in organotin-substituted radicals
Dennis D. Davis and Fahim U. Ahmed
pp 7653 - 7654; DOI:
10.1021/ja00415a043
PDF
Oxygen-17 ENDOR of horseradish peroxidase compound I
James E. Roberts, Brian M. Hoffman, Rick Rutter, and Lowell P. Hager
pp 7654 - 7656; DOI:
10.1021/ja00415a044
PDF
Heterogeneous one-electron reduction of metal-containing biological molecules using molecular hydrogen as the reductant: synthesis and use of a surface-confined viologen redox mediator that equilibrates with hydrogen
Dana C. Bookbinder, Nathan S. Lewis, and Mark S. Wrighton
pp 7656 - 7659; DOI:
10.1021/ja00415a045
PDF
Formation of monocyclic and bicyclic aza-.beta.-lactams and other novel heterocycles from 1-(diphenylmethylene)-3-oxo-1,2-diazetidinium inner salt
Edward C. Taylor, Robert J. Clemens, Huw M. L. Davies, and Neil F. Haley
pp 7659 - 7660; DOI:
10.1021/ja00415a046
PDF
3-Oxo-1,2-diazetidinium tosylate
Edward C. Taylor, Huw M. L. Davies, Robert J. Clemens, Hiroaki Yanagisawa, and Neil F. Haley
pp 7660 - 7661; DOI:
10.1021/ja00415a047
PDF
Stereochemistry of an alkoxide-accelerated [1,3] migration
Mary Therese Zoeckler and Barry K. Carpenter
pp 7661 - 7663; DOI:
10.1021/ja00415a048
PDF
Photoinduced ESR signals from the primary electron donors in deuterated highly carbon-13 enriched photosynthetic bacteria and algae
Michael R. Wasielewski, James R. Norris, Henry L. Crespi, and Joan Harper
pp 7664 - 7665; DOI:
10.1021/ja00415a049
PDF
Heteropolypentatungstobisphosphonates. Cyclopentane-like pseudorotation of an oxometalate structure
P. R. Sethuraman, M. A. Leparulo, M. T. Pope, F. Zonnevijlle, C. Brevard, and J. Lemerle
pp 7665 - 7666; DOI:
10.1021/ja00415a050
PDF
Substituent control of the poly(C)-directed oligomerization of guanosine 5'-phosphoroimidazolide
Tan Inoue and Leslie E. Orgel
pp 7666 - 7667; DOI:
10.1021/ja00415a051
PDF
Ketone methylenation with optical resolution. Total synthesis of the ginseng sesquiterpene (-)-.beta.-panasinsene and its enantiomer
Carl R. Johnson and Nicholas A. Meanwell
pp 7667 - 7669; DOI:
10.1021/ja00415a052
PDF
Base catalysis in a photochemical Smiles rearrangement. A case of general base catalysis of a photoreaction
Gene G. Wubbels and Daniel W. Celander
pp 7669 - 7670; DOI:
10.1021/ja00415a053
PDF
Identification and structure of the benzene-hydrogen chloride complex from microwave spectroscopy
W. G. Read, E. J. Campbell, Giles Henderson, and W. H. Flygare
pp 7670 - 7672; DOI:
10.1021/ja00415a054
PDF
Chemistry of higher order, mixed organocuprates. 1. Substitution reactions at unactivated secondary centers
Bruce H. Lipshutz, Robert S. Wilhelm, and David M. Floyd
pp 7672 - 7674; DOI:
10.1021/ja00415a055
PDF
Racemization - free photochemical coupling of peptide segments
Sh. Pass, B. Amit, and A. Patchornik
pp 7674 - 7675; DOI:
10.1021/ja00415a056
PDF
A unique stereospecific [.pi.2s + .sigma.2a] cycloaddition of tetracyanoethylene to substituted cyclopropanone acetals
Petrus G. Wiering, Jan W. Verhoeven, and Herbert Steinberg
pp 7675 - 7676; DOI:
10.1021/ja00415a057
PDF
Regiochemistry of the reaction of chromium-carbene complexes with acetylenes
William D. Wulff, Peng Cho Tang, and J. Stuart McCallum
pp 7677 - 7678; DOI:
10.1021/ja00415a058
PDF
First evidence for the existence of intramolecular carbon-hydrogen-carbon hydrogen bonds: carbanions of [1.1]ferrocenophane, 1-methyl-[1.1]ferrocenophane, and 1,12-dimethyl-[1.1]ferrocenophane
Ulrich T. Mueller-Westerhoff, Adel Nazzal, and Wolfram Proessdorf
pp 7678 - 7681; DOI:
10.1021/ja00415a059
PDF
Oxygen-atom-transfer reactions from a carbonyl oxide (produced from a 1,2,3-trioxolane) to electron-deficient unsaturated compounds
William A. Pryor and C. K. Govindan
pp 7681 - 7682; DOI:
10.1021/ja00415a060
PDF
Stable glucopyranosylpalladium compound with a cis .beta.-hydrogen
Isamu Arai and G. Doyle Daves
pp 7683 - 7683; DOI:
10.1021/ja00415a061
PDF
Selective symmetric and asymmetric palladium-catalyzed dimerizations of pyrimidinylmercuric salts
Isamu Arai, Robert Hanna, and G. Doyle Daves
pp 7684 - 7685; DOI:
10.1021/ja00415a062
PDF
N-alkylformamidyl radicals. Identification and electronic structure
R. Sutcliffe, K. U. Ingold, and J. Lessard
pp 7685 - 7686; DOI:
10.1021/ja00415a063
PDF
Cis-Alkylcarbamoyl radicals. The overlooked conformer
R. Sutcliffe and K. U. Ingold
pp 7686 - 7687; DOI:
10.1021/ja00415a064
PDF
Stereospecific reactions of dichloroketene with vinyl sulfoxides: a new type of polar cycloaddition
J. P. Marino and Mark Neisser
pp 7687 - 7689; DOI:
10.1021/ja00415a065
PDF
Azocyclopropane
Paul S. Engel and Dale B. Gerth
pp 7689 - 7690; DOI:
10.1021/ja00415a066
PDF
Vanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed transition-state model
Edward D. Mihelich, Karen Daniels, and David J. Eickhoff
pp 7690 - 7692; DOI:
10.1021/ja00415a067
PDF
Theoretical studies of SN2 transition states. 1. Geometries
Saul Wolfe, David John Mitchell, and H. Bernhard Schlegel
pp 7692 - 7694; DOI:
10.1021/ja00415a068
PDF
Theoretical studies of SN2 transition states. 2. Intrinsic barriers, rate-equilibrium relationships, and the Marcus equation
Saul Wolfe, David John Mitchell, and H. Bernhard Schlegel
pp 7694 - 7696; DOI:
10.1021/ja00415a069
PDF
Nucleophilic activation of carbon monoxide for reduction by hydrogen
Kenneth M. Doxsee and Robert H. Grubbs
pp 7696 - 7698; DOI:
10.1021/ja00415a070
PDF
Book Reviews

pp 7698 - 7700; DOI:
10.1021/ja00415a600
PDF

Issue 26


Calculation of proton-transfer energies and electrostatic lattice energies of various amino acids and peptides using CNDO/2 and ab initio SCF methods
J. Voogd, J. L. Derissen, and F. B. Van Duijneveldt
pp 7701 - 7706; DOI:
10.1021/ja00416a001
PDF
Rotational jumps of the tyrosine side chain in crystalline enkephalin. Hydrogen-2 NMR line shapes for aromatic ring motions in solids
David M. Rice, Richard J. Wittebort, Robert G. Griffin, Eva Meirovitch, Evelyn R. Stimson, Yvonne C. Meinwald, Jack H. Freed, and Harold A. Scheraga
pp 7707 - 7710; DOI:
10.1021/ja00416a002
PDF
Noncompeting metastable losses of methyl and ethylene from gaseous butanoic acid ions due to isomerization prior to methyl loss
David J. McAdoo and Charles E. Hudson
pp 7710 - 7713; DOI:
10.1021/ja00416a003
PDF
Role of ligand .pi.-donation in electron-deficient organometallic Group VIB complexes
Joseph L. Templeton, Paul B. Winston, and Bennett C. Ward
pp 7713 - 7721; DOI:
10.1021/ja00416a004
PDF
Molybdenum sites of sulfite oxidase and xanthine dehydrogenase. A comparison by EXAFS
S. P. Cramer, R. Wahl, and K. V. Rajagopalan
pp 7721 - 7727; DOI:
10.1021/ja00416a005
PDF
Hydrogen-1 NMR rate constants and mercury-199 FT NMR equilibrium constants involved in disulfide cleavage by methylmercury
Robert D. Bach, Sundar J. Rajan, Harsha B. Vardhan, Timothy J. Lang, and Norman G. Albrecht
pp 7727 - 7734; DOI:
10.1021/ja00416a006
PDF
Xenon-nitrogen bonds. The synthesis and characterization of [imidobis(sulfuryl fluoride)]xenon(II) derivatives Xe[N(SO2F)2]2, FXeN(SO2F)2 and [(FSO2)2NXe]2F+AsF6- and the radical .cntdot.N(SO2F)2
Darryl D. DesMarteau, Robert D. LeBlond, S. Fazley Hossain, and Dietrich Nothe
pp 7734 - 7739; DOI:
10.1021/ja00416a007
PDF
Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydride
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano
pp 7739 - 7742; DOI:
10.1021/ja00416a008
PDF
Synthesis and properties of 3-oxo-1,2-diazetidinium ylides
Edward C. Taylor, Neil F. Haley, and Robert J. Clemens
pp 7743 - 7752; DOI:
10.1021/ja00416a009
PDF
Response of acidity and magnetic resonance properties to aryl substitution in carbon acids and derived carbanions: 1-aryl-4-phenylcyclopenta-1,3 dienes. Dependence of ionic structure on aryl substitution
Linda G. Greifenstein, Joseph B. Lambert, Ronald J. Nienhuis, George E. Drucker, and Giorgio A. Pagani
pp 7753 - 7761; DOI:
10.1021/ja00416a010
PDF
Homolytic addition to benzene. Rate constants for the formation and decay of some substituted cyclohexadienyl radicals
P. C. Wong, P. R. Marriott, D. Griller, D. C. Nonhebel, and M. J. Perkins
pp 7761 - 7763; DOI:
10.1021/ja00416a011
PDF
The 2-butyl cation in trifluoroacetic acid. A hydrogen-bridged carbonium ion
J. J. Dannenberg, B. J. Goldberg, J. K. Barton, K. Dill, D. H. Weinwurzel, and M. O. Longas
pp 7764 - 7768; DOI:
10.1021/ja00416a012
PDF
The surface of silica as a medium for the radical and ionic decomposition of diacyl peroxides
J. E. Leffler and J. T. Barbas
pp 7768 - 7773; DOI:
10.1021/ja00416a013
PDF
Sequence-specific osmium reagents for polynucleotides. 2. A method for thymine-cytosine pairs
H. Ford, C. H. Chang, and E. J. Behrman
pp 7773 - 7779; DOI:
10.1021/ja00416a014
PDF
Binding sites of anions in superoxide dismutase
Ivano Bertini, Elena Borghi, Claudio Luchinat, and Andrea Scozzafava
pp 7779 - 7783; DOI:
10.1021/ja00416a015
PDF
Hydrogen-1 NMR spectra of the coordination sphere of cobalt-substituted carbonic anhydrase
Ivano Bertini, Giorgio Canti, Claudio Luchinat, and Fabrizio Mani
pp 7784 - 7788; DOI:
10.1021/ja00416a016
PDF
Effective enhancement of valinomycin-mediated potassium uptake in organic phase by uncouplers of oxidative phosphorylation detected by proton NMR
Kenichi Yoshikawa and Hiroshi Terada
pp 7788 - 7790; DOI:
10.1021/ja00416a017
PDF
Photolysis of two tricyclic nonenediones. Direct observation of norcaradiene
Mordecai B. Rubin
pp 7791 - 7792; DOI:
10.1021/ja00416a018
PDF
Tertiary phosphine derivatives of the f-block metals. Preparation of X4M(Me2PCH2CH2PMe2)2, where X is halide, methyl or phenoxy and M is thorium or uranium. Crystal structure of tetraphenoxybis[bis(1,2-dimethylphosphino)ethane]uranium(IV)
Peter G. Edwards, Richard A. Andersen, and Allan Zalkin
pp 7792 - 7794; DOI:
10.1021/ja00416a019
PDF
Kinetics of the anaerobic reduction of ferricytochrome cd1 by Fe(EDTA)2-. Evidence for bimolecular and intramolecular electron transfers to the d1 hemes
Steven A. Schichman and Harry B. Gray
pp 7794 - 7795; DOI:
10.1021/ja00416a020
PDF
Spectroscopic properties and redox chemistry of the phosphorescent excited state of octahydrotetrakis(phosphorus pentoxide)diplatinate(4-) ion (Pt2(P2O5)4H84-)
Chi Ming Che, Leslie G. Butler, and Harry B. Gray
pp 7796 - 7797; DOI:
10.1021/ja00416a021
PDF
Additions and Corrections - On the Nonconcertedness of Allylic Cation Promoted π-Cyclization Reactions
Mladen Ladika, Ivo Bregovec, and Dionis E. Sunko
pp 7797 - 7797; DOI:
10.1021/ja00416a601
PDF
Additions and Corrections - Stereochemical Analysis of γ-Replacement and γ-Elimination Processes Catalyzed by a Pyridoxal Phosphate Dependent Enzyme
Michael N. T. Chang, and Christopher T. Walsh
pp 7797 - 7797; DOI:
10.1021/ja00416a602
PDF
Additions and Corrections - Synthesis, Structure, and Stability of (i,o)-Bicyclo(6.2.2)dodeca-9,11-dienes. Generation of Unusually Expanded Carbon-Carbon-Carbon Bond Angles.
Paul S. Gassman, and Rebecca C. Hoye
pp 7797 - 7797; DOI:
10.1021/ja00416a603
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Additions and Corrections - α-Disulfoxide and Sulfinic Anhydride in the Peroxy Acid Oxidation of 2-Methyl-2-propyl 2-methyl-2-propanethiosulfinate
Fillmore Freeman, and Christos N. Angeletakis
pp 7797 - 7797; DOI:
10.1021/ja00416a604
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Book Reviews

pp 7798 - 7807; DOI:
10.1021/ja00416a600
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