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Volume 105
Main Index

Issue 1


Isomerization barriers and stabilities of C3H6+• isomers
Fred W. McLafferty, Michael P. Barbalas, and Frantisek Turecek
pp 1 - 3; DOI:
10.1021/ja00339a001
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Rydberg radicals. 1. Frozen-core model for Rydberg levels of the ammonium radical
S. Havriliak and Harry F. King
pp 4 - 12; DOI:
10.1021/ja00339a002
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Nuclear magnetic shielding in cyclopropane and cyclopropenyl cation
P. Lazzeretti, E. Rossi, and R. Zanasi
pp 12 - 15; DOI:
10.1021/ja00339a003
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Relative thermochemical stabilities of 1-methylsilaethylene and dimethylsilylene by ion cyclotron double resonance spectroscopy
C. F. Pau, W. J. Pietro, and W. J. Hehre
pp 16 - 18; DOI:
10.1021/ja00339a004
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Mechanism of Iron dissolution and passivation in an aqueous environment: Active and transition ranges
Alfred B. Anderson and N. C. Debnath
pp 18 - 22; DOI:
10.1021/ja00339a005
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Phosphorus NMR study of solid amorphous calcium phosphate
James Tropp, Norman C. Blumenthal, and John S. Waugh
pp 22 - 26; DOI:
10.1021/ja00339a006
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Electrochemical investigation of the energetics of particulate titanium dioxide photocatalysts. The methyl viologen-acetate system
Michael D. Ward, James R. White, and Allen J. Bard
pp 27 - 31; DOI:
10.1021/ja00339a007
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Theoretical models for solvation and catalysis in carbonyl addition
Ian H. Williams, Dale Spangler, Douglas A. Femec, Gerald M. Maggiora, and Richard L. Schowen
pp 31 - 40; DOI:
10.1021/ja00339a008
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Electronic interactions in mixed-valence molecules as mediated by organic bridging groups
David E. Richardson and Henry Taube
pp 40 - 51; DOI:
10.1021/ja00339a009
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Crystal structure of vacuum-dehydrated silver hydrogen zeolite A
L. R. Gellens, J. V. Smith, and J. J. Pluth
pp 51 - 55; DOI:
10.1021/ja00339a010
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Oxidation-reduction reactions of complexes with macrocyclic ligands. Kinetic and electrochemical studies of metal-ligand synergism
Jay A. Switzer, John F. Endicott, Mohamed A. Khalifa, Francois P. Rotzinger, and Krishan Kumar
pp 56 - 61; DOI:
10.1021/ja00339a011
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Kinetics, thermodynamics, and mechanism of the radical-chain process for ligand substitution of metal carbonyls
J. W. Hershberger, R. J. Klingler, and J. K. Kochi
pp 61 - 73; DOI:
10.1021/ja00339a012
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Intramolecular aminolysis of esters. Cyclization of esters of (o-aminophenyl)acetic acid
Thomas H. Fife and Neil W. Duddy
pp 74 - 79; DOI:
10.1021/ja00339a013
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Optical activity of β γ-enones: a quantitative chirality rule
P. H. Schippers and H. P. J. M. Dekkers
pp 79 - 84; DOI:
10.1021/ja00339a014
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Circular polarization in the fluorescence of β γ-enones: distortion in the 1nπ* state
P. H. Schippers, J. P. M. Van der Ploeg, and H. P. J. M. Dekkers
pp 84 - 89; DOI:
10.1021/ja00339a015
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Kinetics and mechanism of the C-alkylation of nitroalkane anions by 1-alkyl-2,4,6-triphenylpyridiniums: a nonchain reaction with radicaloid characteristics
Alan R. Katritzky, M. Akram Kashmiri, George Z. De Ville, and Ranjan C. Patel
pp 90 - 96; DOI:
10.1021/ja00339a016
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Thermochemical relationships between some bicyclohexenyl and benzenium cations
Ronald F. Childs and D. Lindsay Mulholland
pp 96 - 99; DOI:
10.1021/ja00339a017
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Tracer studies of the 1,5 sigmatropic hydrogen shifts in isodicyclopentadiene
Paul D. Bartlett and Chengjiu Wu
pp 100 - 104; DOI:
10.1021/ja00339a018
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Cyclic peptide disulfides. Solution and solid-state conformation of Boc-Cys-Pro-Aib-Cys-NHMe with a disulfide bridge from Cys to Cys, a disulfide-bridged peptide helix
A. Ravi, B. V. Venkataram Prasad, and P. Balaram
pp 105 - 109; DOI:
10.1021/ja00339a019
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Nitrogen-14 and proton ENDOR of nitrosylhemoglobin
Mathias Hoehn, Juergen Huettermann, James C. W. Chien, and L. Charles Dickinson
pp 109 - 115; DOI:
10.1021/ja00339a020
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Preparation of a mixture of nucleoside triphosphates from yeast RNA: use in enzymic synthesis requiring nucleoside triphosphate regeneration and conversion to nucleoside diphosphate sugars
Chi Huey Wong, Sharon L. Haynie, and George M. Whitesides
pp 115 - 117; DOI:
10.1021/ja00339a021
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Asymmetric alkylation of α-amino carbanions. An enantioselective synthesis of (S)-1-alkyl-1,2,3,4-tetrahydroisoquinolines
A. I. Meyers and Lelia M. Fuentes
pp 117 - 118; DOI:
10.1021/ja00339a022
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Molecular orbital study of the homocyclopropenylium cation
R. C. Haddon and K. Raghavachari
pp 118 - 120; DOI:
10.1021/ja00339a023
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π Complexing of chlorine atoms: is that all there is?
Charles K. Taylor and Philip S. Skell
pp 120 - 121; DOI:
10.1021/ja00339a024
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On the stability of early-transition-metal metallacyclobutadiene complexes
Bruce E. Bursten
pp 121 - 122; DOI:
10.1021/ja00339a025
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Pentalenene biosynthesis and the enzymic cyclization of farnesyl pyrophosphate
David E. Cane and Ann Marie Tillman
pp 122 - 124; DOI:
10.1021/ja00339a026
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Models for the photosynthetic water oxidizing enzyme. 1. A binuclear manganese(III)-β-cyclodextrin complex
Balachandran Unni Nair and G. Charles Dismukes
pp 124 - 125; DOI:
10.1021/ja00339a027
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Solution structure of thianthrene: dihedral angle between the benzene rings determined from the analysis of NMR spectra in nematic phase
Hideaki Fujiwara, Akio Kawamura, Tatsuya Takagi, and Yoshio Sasaki
pp 125 - 126; DOI:
10.1021/ja00339a028
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Formation of 1,2-oxathietanes and their formal [σ2s + σ2a]cycloreversion during the stereoelectronically controlled aqueous decomposition of sulfoxide-substituted nitrosoureas
J. William Lown and R. Rao Koganty
pp 126 - 127; DOI:
10.1021/ja00339a029
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Stereocontrolled osmylation of medium-ring alkenes: synthesis of a C1-C9 erythronolide fragment
E. Vedejs, J. M. Dolphin, and H. Mastalerz
pp 127 - 130; DOI:
10.1021/ja00339a030
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Additivity relation in the amplitudes of exciton-split circular dichroism curves arising from interactions between different chromophores and its application in structural studies
Richard J. Stonard, Diane A. Trainor, Munehiro Nakatani, and Koji Nakanishi
pp 130 - 131; DOI:
10.1021/ja00339a031
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Crown thiaether chemistry. Crystal structure of 1,4,7,10,13,16-hexathiacyclooctadecane, the hexathia analog of 18-crown-6
JudithAnn R. Hartman, Robert E. Wolf, Bruce M. Foxman, and Stephen R. Cooper
pp 131 - 132; DOI:
10.1021/ja00339a032
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Distribution of gauche bonds in crystalline n-heneicosane in phase II
Robert G. Snyder, Mark Maroncelli, Herbert L. Strauss, Carl A. Elliger, David G. Cameron, Hector L. Casal, and Henry H. Mantsch
pp 133 - 134; DOI:
10.1021/ja00339a033
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High-pressure studies. 24. cis-Azoalkanes. Mechanism of scission and isomerization
Robert C. Neuman and Glen A. Binegar
pp 134 - 135; DOI:
10.1021/ja00339a034
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An incremental approach to hosts that mimic serine proteases
Donald J. Cram and Howard Edan Katz
pp 135 - 137; DOI:
10.1021/ja00339a035
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Dimerization and cycloaddition reactions of a carbomethoxy-substituted cyclopropene
Albert Padwa, G. Davon Kennedy, George R. Newkome, and Frank R. Fronczek
pp 137 - 139; DOI:
10.1021/ja00339a036
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Reaction of MoS92- with bis(carboxymethyl)acetylene. The crystal and molecular structure of (Ph4P)2Mo[S2C2(COOMe)2]3: A Trigonal Prismatic Complex with a New Dithiolene Ligand
M. Draganjac and D. Coucouvanis
pp 139 - 140; DOI:
10.1021/ja00339a037
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Synthesis and reactivity of a semi-triply bridging methylidyne complex. Crystal structure of HOs3(CO)10(CH)
John R. Shapley, Michelle E. Cree-Uchiyama, and George M. St. George
pp 140 - 142; DOI:
10.1021/ja00339a038
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Biogenetic-type total synthesis of (.+-.)-aphidicolin
Eugene E. Van Tamelen, Steven R. Zawacky, Ronald K. Russell, and James G. Carlson
pp 142 - 143; DOI:
10.1021/ja00339a039
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Proton NMR studies of nitrogen-15-labeled Escherichia coli tRNAfMet. Assignments of imino resonances for uridine-related bases by proton-nitrogen-15 heteronuclear double resonance difference spectroscopy
Richard H. Griffey, C. Dale Poulter, Ziro Yamaizumi, Susumu Nishimura, and Bruce L. Hawkins
pp 143 - 145; DOI:
10.1021/ja00339a040
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Circular polarization of luminescence as a probe for intramolecular 1nπ* energy transfer in meso-diketones
P. H. Schippers and H. P. J. M. Dekkers
pp 145 - 146; DOI:
10.1021/ja00339a041
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Theoretical prescription for reductive coupling of carbonyl or isocyanide ligands
Roald Hoffmann, Charles N. Wilker, Stephen J. Lippard, Joseph L. Templeton, and Douglas C. Bower
pp 146 - 147; DOI:
10.1021/ja00339a042
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Palladium-catalyzed stereocontrolled cyclization of 1,3-diene monoepoxides and its application to the synthesis of 11-deoxy-PGE1
Takashi Takahashi, Hideaki Kataoka, and Jiro Tsuji
pp 147 - 149; DOI:
10.1021/ja00339a043
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Transition-metal insertion into naked metal cluster polyanions
Francesc Teixidor, Melvin L. Luetkens, and Ralph W. Rudolph
pp 149 - 150; DOI:
10.1021/ja00339a044
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Book Reviews

pp 150 - 152; DOI:
10.1021/ja00339a600
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Issue 2


Photoinduced electron-transfer reactions. The radical cations of methano-bridged paracyclophanes
Heinz D. Roth, Marcia L. Manion Schilling, Richard S. Hutton, and Elizabeth A. Truesdale
pp 153 - 157; DOI:
10.1021/ja00340a001
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Structure determination of gaseous norbornane by electron diffraction, microwave, Raman, and infrared spectroscopy. Molecular mechanics and ab initio calculations with complete geometry relaxation
L. Doms, L. Van den Enden, H. J. Geise, and C. Van Alsenoy
pp 158 - 162; DOI:
10.1021/ja00340a002
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Infrared spectra of two 1:1 complexes between hydrogen cyanide and hydrogen fluoride in solid argon at 12 K
Gary L. Johnson and Lester Andrews
pp 163 - 168; DOI:
10.1021/ja00340a003
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Dynamics of fatty acids in phospholipid vesicles using spin relaxation of proton-coupled carbon-13 spectra
M. M. Fuson and J. H. Prestegard
pp 168 - 176; DOI:
10.1021/ja00340a004
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Relationships between electron-transfer rate constants of bis(ligated)(octaethylporphinato)iron(III) perchlorate and the presence of a spin equilibrium
K. M. Kadish and C. H. Su
pp 177 - 180; DOI:
10.1021/ja00340a005
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A new ferrocenophane surface derivatizing reagent for the preparation of nearly reversible electrodes for horse heart ferri-/ferrocytochrome c: 2,3,4,5-tetramethyl-1-[(dichlorosilyl)methyl][2]ferrocenophane
Shuchi Chao, John L. Robbins, and Mark S. Wrighton
pp 181 - 188; DOI:
10.1021/ja00340a006
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Role of the interface in the extraction kinetics of zinc and nickel ions with alkyl-substituted dithizones
Hitoshi Watarai and Henry Freiser
pp 189 - 190; DOI:
10.1021/ja00340a007
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Effect of stirring on the distribution equilibriums of n-alkyl-substituted dithizones
Hitoshi Watarai and Henry Freiser
pp 191 - 194; DOI:
10.1021/ja00340a008
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The dimers of carbon monoxide and carbon monosulfide. Chemically bound triplet electronic ground states
Gwendolyn P. Raine, Henry F. Schaefer, and Robert C. Haddon
pp 194 - 198; DOI:
10.1021/ja00340a009
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Hypovalent radicals. 13. Gas-phase nucleophilic reactivities of phenylnitrene (PhN- •) and sulfur anion radicals (S-•) at sp3 and carbonyl carbon
Richard N. McDonald and A. Kasem Chowdhury
pp 198 - 207; DOI:
10.1021/ja00340a010
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Reductive electrochemistry of iron-carbene porphyrins
Jean Paul Battioni, Doris Lexa, Daniel Mansuy, and Jean Michel Saveant
pp 207 - 215; DOI:
10.1021/ja00340a011
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Dynamical effects of symmetry along a reaction path: mode specificity in the unimolecular dissociation of formaldehyde
William H. Miller
pp 216 - 220; DOI:
10.1021/ja00340a012
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Semiconductor electrodes. 48. Photooxidation of halides and water on n-silicon protected with silicide layers
Fu Ren F. Fan, R. Gerald Keil, and Allen J. Bard
pp 220 - 224; DOI:
10.1021/ja00340a013
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Kinetic studies on 1:1 electron-transfer reactions involving blue copper proteins. 4. Reactions of reduced Rhus vernicifera stellacyanin with Co(edta)-, Co(C2O4)33- and Ru(en)33+; reactivity patterns for stellacyanin
M. J. Sisley, M. G. Segal, C. S. Stanley, I. K. Adzamli, and A. G. Sykes
pp 225 - 228; DOI:
10.1021/ja00340a014
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Experimental observation of the tellurium(IV) bonding and lone-pair density in dimethyltellurium dichloride by x-ray diffraction techniques
Ronald F. Ziolo and Jan M. Troup
pp 229 - 235; DOI:
10.1021/ja00340a015
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Clusters in catalysis. High reactivity in an electron-rich cluster with weak metal-metal bonds. Facile, reversible addition of carbon monoxide to Os4(CO)123-S)2
Richard D. Adams and Li Wu Yang
pp 235 - 240; DOI:
10.1021/ja00340a016
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Total synthesis of a mycobactin: mycobactin S2
Peter J. Maurer and Marvin J. Miller
pp 240 - 245; DOI:
10.1021/ja00340a017
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Synthesis and x-ray structures of the conformational isomers of the mixed bimetal complex (t--BuNC)4Mo(μ-t-BuS)2CuBr
Nicholas C. Payne, Nobuyuki Okura, and Sei Otsuka
pp 245 - 251; DOI:
10.1021/ja00340a018
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Synthesis of 2,2-disubstituted oxetanes from ketones with S-methyl-S-(sodiomethyl)-N-(4-tolylsulfonyl)sulfoximine
Steven C. Welch, A. S. C. Prakasa Rao, John T. Lyon, and Jean Marie Assercq
pp 252 - 257; DOI:
10.1021/ja00340a019
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Synthesis, spectral characterization and alkylidene-transfer reactions of electrophilic iron carbene complexes Cp(CO)(L)Fe:CHR+ (L = CO, PPh3; R = Me, Et, CHMe2)
M. Brookhart, James R. Tucker, and G. Ronald Husk
pp 258 - 264; DOI:
10.1021/ja00340a020
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Elimination reactions of N-[2-(p-nitrophenyl)ethyl]alkylammonium ions by an E1cB mechanism
James R. Keeffe and William P. Jencks
pp 265 - 279; DOI:
10.1021/ja00340a021
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Cation-anion combination reactions. 22. Rate and equilibrium constants for reactions of pyronin and thiopyronin with nucleophiles
C. D. Ritchie, C. Kubisty, and G. Y. Ting
pp 279 - 284; DOI:
10.1021/ja00340a022
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Effects of through-bond and through-space interactions on singlet-triplet energy gaps in localized biradicals
Aaron H. Goldberg and Dennis A. Dougherty
pp 284 - 290; DOI:
10.1021/ja00340a023
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Substituent effects on tin-119 chemical shifts in 4-substituted bicyclo[2.2.2]octyl- and bicyclo[2.2.1]heptyl-1-(trimethyl)stannanes
William Adcock, Gaik B. Kok, Anil N. Abeywickrema, William Kitching, Gregory M. Drew, Henry A. Olszowy, and Inge Schott
pp 290 - 292; DOI:
10.1021/ja00340a024
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Oxidative-additions to (W.tplbond.W)6+ centers: the influence of Lewis base association reactions
Michael J. Chetcuti, Malcolm H. Chisholm, John C. Huffman, and Joseph Leonelli
pp 292 - 293; DOI:
10.1021/ja00340a025
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The effect of nickel(II) and cobalt(III) and other metal ions on the racemization of free and bound L-alanine
Grant Gill Smith, Awni Khatib, and G. Sudhakar Reddy
pp 293 - 295; DOI:
10.1021/ja00340a026
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Water-d2 effect on catalysis by triose phosphate isomerase requires isotope exchange on the enzyme
Irwin A. Rose and Radha Iyengar
pp 295 - 297; DOI:
10.1021/ja00340a027
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Crystal structure of a new type of two-dimensional organic metal, (C10H8S8)2(ClO4)(C2H3Cl3)0.5
Hayao Kobayashi, Akiko Kobayashi, Gunzi Saito, Toshiaki Enoki, and Hiroo Inokuchi
pp 297 - 298; DOI:
10.1021/ja00340a028
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A totally synthetic (nonporphyrin) iron(II) dioxygen carrier that is fully functional under ambient conditions
Norman Herron, James H. Cameron, Gary L. Neer, and Daryle H. Busch
pp 298 - 301; DOI:
10.1021/ja00340a029
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Oxidation-reduction catalytic activity of a pentaammineruthenium(III) derivative of sperm whale myoglobin
Ruth Margalit, Israel Pecht, and Harry B. Gray
pp 301 - 302; DOI:
10.1021/ja00340a030
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Structure and reactivity of sterically hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li{N(SiMe3)2}(OEt2)]2 and tetrakis(2,2,6,6-tetramethylpiperidinatolithium)
Michael F. Lappert, Martin J. Slade, Anirudh Singh, Jerry L. Atwood, Robin D. Rogers, and Riz Shakir
pp 302 - 304; DOI:
10.1021/ja00340a031
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Silane surface chemistry of palladium: synthesis of silaethylene, silacyclobutadiene and silabenzene
Thomas M. Gentle and E. L. Muetterties
pp 304 - 305; DOI:
10.1021/ja00340a032
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Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation
James R. Sweet and William A. G. Graham
pp 305 - 306; DOI:
10.1021/ja00340a033
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Protein structure by solid-state NMR
T. A. Cross and S. J. Opella
pp 306 - 308; DOI:
10.1021/ja00340a034
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Issue 3


Structures and stabilities of gas-phase C2H3O+ ions: an ab initio molecular orbital study
Ross H. Nobes, Willem J. Bouma, and Leo Radom
pp 309 - 314; DOI:
10.1021/ja00341a001
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Electron-transfer reactions and associated conformational changes. Studies of bianthrone reduction via homogeneous redox catalysis
Dennis H. Evans and Naixian Xie
pp 315 - 320; DOI:
10.1021/ja00341a002
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Intramolecular electron transfer and dehalogenation of nitroaromatic anion radicals
J. P. Bays, S. T. Blumer, S. Baral-Tosh, D. Behar, and P. Netav
pp 320 - 324; DOI:
10.1021/ja00341a003
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Heterojunction silicon/indium tin oxide photoelectrodes: development of stable systems in aqueous electrolytes and their applicability to solar energy conversion and storage
G. Hodes, L. Thompson, J. DuBow, and K. Rajeshwar
pp 324 - 330; DOI:
10.1021/ja00341a004
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Recoil tritium reactions with 1,2-difluoroethylenes
E. E. Siefert, D. D. Smith, R. E. Tricca, P. M. Ayoub, and Y. N. Tang
pp 330 - 336; DOI:
10.1021/ja00341a005
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Resonance Raman spectra and electronic structure of the .mu.-disulfur-bridged diruthenium complex [(H3N)5RuSSRu(NH3)5]4+ and related systems
Soonhee Kim, Elizabeth S. Otterbein, Richard P. Rava, Stephan S. Isied, and Joseph San Filippo
pp 336 - 339; DOI:
10.1021/ja00341a006
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Dipole-stabilized carbanions in the gas phase
John E. Bartmess, Gary Caldwell, and Melvin D. Rozeboom
pp 340 - 344; DOI:
10.1021/ja00341a007
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Low-pressure oxidation mechanism and reactivity of propylene on silver(110) and relation to gas-phase acidity
M. A. Barteau and R. J. Madix
pp 344 - 349; DOI:
10.1021/ja00341a008
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Theoretical study of gas-phase methylation and ethylation by diazonium ions and rationalization of some aspects of DNA reactivity
George P. Ford and John D. Scribner
pp 349 - 354; DOI:
10.1021/ja00341a009
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Interaction of methane and methanol with water
G. Bolis, E. Clementi, D. H. Wertz, H. A. Scheraga, and C. Tosi
pp 355 - 360; DOI:
10.1021/ja00341a010
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Microwave spectrum, dipole moment, and substitution structure of peroxyformic acid
M. Oldani, T. K. Ha, and A. Bauder
pp 360 - 365; DOI:
10.1021/ja00341a011
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Small-molecule chemisorption in nickel disilicide: implications for heterogeneous catalysts
L. H. Dubois and R. G. Nuzzo
pp 365 - 369; DOI:
10.1021/ja00341a012
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Photoinduced diffusion of methyl viologen across anionic surfactant vesicle bilayers
Lester Y. C. Lee, James K. Hurst, Mario Politi, Kazue Kurihara, and Janos H. Fendler
pp 370 - 373; DOI:
10.1021/ja00341a013
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A classical dynamics model of plasma desorption mass spectrometry experiments
Barbara J. Garrison
pp 373 - 378; DOI:
10.1021/ja00341a014
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Nature of .pi.-electron-transfer effects in organic systems with varying .pi.-electron demand
William F. Reynolds, Photis Dais, Douglas W. MacIntyre, Ronald D. Topsom, Stephen Marriott, Ellak Von Nagy-Felsobuki, and Robert W. Taft
pp 378 - 384; DOI:
10.1021/ja00341a015
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Structure and dynamics of phosphoranyl radicals. A single-crystal electron spin resonance study
J. H. H. Hamerlinck, P. Schipper, and H. M. Buck
pp 385 - 395; DOI:
10.1021/ja00341a016
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Ab initio study of the structures and vibrational spectra of the Hueckel 4n heterocycles azirine, oxirene and thiirene
P. Carsky, B. Andes Hess, and L. J. Schaad
pp 396 - 402; DOI:
10.1021/ja00341a017
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Location of cupric ions in X zeolites by electron spin echo spectrometry: contrast between sodium and potassium X zeolites
Tsuneki Ichikawa and Larry Kevan
pp 402 - 406; DOI:
10.1021/ja00341a018
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Coordination shifts in nitrogen-15 nuclear magnetic resonance spectra of glycinato and ethylenediamine ligands in cobalt(III) complexes
N. Juranic and R. L. Lichter
pp 406 - 410; DOI:
10.1021/ja00341a019
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Solution structure of tris[hydridotris(pyrazol-1-yl)borato]ytterbium(III); rare example of solution rigid lanthanide complex
Matthew V. R. Stainer and Josef Takats
pp 410 - 415; DOI:
10.1021/ja00341a020
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Formation, reactivities, and molecular structures of phosphine derivatives of titanocene. Isolation and characterization of a titanium monoolefin .pi. complex
Bruce H. Edwards, Robin D. Rogers, David J. Sikora, Jerry L. Atwood, and Marvin D. Rausch
pp 416 - 426; DOI:
10.1021/ja00341a021
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Ab initio electronic structures and reactivities of metal carbene complexes (CO)5Cr:CHOH and (CO)4Fe:CHOH
H. Nakatsuji, J. Ushio, S. Han, and T. Yonezawa
pp 426 - 434; DOI:
10.1021/ja00341a022
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Covalent bonding in trans-tetraamminedinitronickel(II) studied by x-ray diffraction at 110 K
B. N. Figgis, P. A. Reynolds, and S. Wright
pp 434 - 440; DOI:
10.1021/ja00341a023
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Covalent bonding in trans-tetraamminedinitronickel(II) studied by polarized neutron diffraction at 4.5 K
B. N. Figgis, P. A. Reynolds, and R. Mason
pp 440 - 443; DOI:
10.1021/ja00341a024
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An NMR and thermodynamic investigation of the reaction of square-planar rhodium(I) compounds with hydrogen
Russell S. Drago, James G. Miller, Mitchell A. Hoselton, and Richard D. Farris
pp 444 - 449; DOI:
10.1021/ja00341a025
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Pyridoxamine and 2-oxalopropionic acid in aqueous systems: conditional imine formation constants and rate constants of vitamin B6 catalyzed decarboxylation
Gregory Kubala and Arthur E. Martell
pp 449 - 455; DOI:
10.1021/ja00341a026
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Nitrosoalkane complexes of iron-porphyrins: analogy between the bonding properties of nitrosoalkanes and dioxygen
Daniel Mansuy, Pierrette Battioni, Jean Claude Chottard, Claude Riche, and Angele Chiaroni
pp 455 - 463; DOI:
10.1021/ja00341a027
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Synthesis and reaction chemistry of a new class of .mu.-alkylidene dicobalt complexes. Crystal and molecular structure of (.mu.-methylene)bis[.eta.5-(methylcyclopentadienyl)carbonylcobalt]
Klaus H. Theopold and Robert G. Bergman
pp 464 - 475; DOI:
10.1021/ja00341a028
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Single cubane-type MFe3S4 clusters (M = Mo, W): synthesis and properties of oxidized and reduced forms and the structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2C6H2O2)]
P. K. Mascharak, W. H. Armstrong, Y. Mizobe, and R. H. Holm
pp 475 - 483; DOI:
10.1021/ja00341a029
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Lithium-stabilized methanonium ions, CLi5-nHn+. A theoretical study
Paul v. R. Schleyer, Bruce Tidor, Eluvathingal D. Jemmis, Jayaraman Chandrasekhar, Ernst Ulrich Wuerthwein, Alexander J. Kos, Brian T. Luke, and John A. Pople
pp 484 - 488; DOI:
10.1021/ja00341a030
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Reaction of atomic carbon with ammonia. The mechanism of formation of amino acid precursors
Philip B. Shevlin, Daniel W. McPherson, and Paul Melius
pp 488 - 491; DOI:
10.1021/ja00341a031
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Substituent effects on chemical reactivity. Improved evaluation of field and resonance components
C. Gardner Swain, Stefan H. Unger, Niles R. Rosenquist, and Marguerite S. Swain
pp 492 - 502; DOI:
10.1021/ja00341a032
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Solvent effects on chemical reactivity. Evaluation of anion- and cation-solvation components
C. Gardner Swain, Marguerite S. Swain, Arnet L. Powell, and Sergio Alunni
pp 502 - 513; DOI:
10.1021/ja00341a033
PDF
Organic photochemistry with 6.7-eV photons: the photochemistry of bicyclo[4.1.0]hept-2-ene (2-norcarene)
William J. Leigh and R. Srinivasan
pp 514 - 519; DOI:
10.1021/ja00341a034
PDF
A practical method for using alkoxide-accelerated vinylcyclobutane ring expansions in the synthesis of six-membered rings. Unexpected orbital symmetry allowed and forbidden 1,3-sigmatropic rearrangements
Theodore Cohen, M. Bhupathy, and James R. Matz
pp 520 - 525; DOI:
10.1021/ja00341a035
PDF
Proximate charge effects. 3. Enthalpies of solvent transfer of reactants and transition states in the saponification of acetylcholine
Paul Haberfield and Jeffrey Pessin
pp 526 - 528; DOI:
10.1021/ja00341a036
PDF
Structural effects in solvolytic reactions. 43. Effect of increasing electron demand on the carbon-13 NMR shifts for 2-aryl-3-methyl-2-butyl cations. A static system becoming an equilibrating system with electron-withdrawing substituents
Herbert C. Brown and Mariappan Periasamy
pp 529 - 533; DOI:
10.1021/ja00341a037
PDF
Carbocationic rearrangements originating from the 2-tert-butyl-2-adamantyl system
James A. Saba and James L. Fry
pp 533 - 537; DOI:
10.1021/ja00341a038
PDF
Three-phase model of micellar reactions. Methylation of thymidine by (long-chain-alkyl)dimethylsulfonium iodides
Kiyoshi Yamauchi, Yorisato Hisanaga, and Masayoshi Kinoshita
pp 538 - 545; DOI:
10.1021/ja00341a039
PDF
Photocycloaddition of 9,10-dichloroanthracene to 1,3-cyclohexadiene
William K. Smothers, Marjorie C. Meyer, and Jack Saltiel
pp 545 - 555; DOI:
10.1021/ja00341a040
PDF
Template effects. 4. Ion pairing of aryloxide ions with alkali cations in 99% dimethylsulfoxide: influence on the rate of formation of benzo-18-crown-6 and of other Williamson-type reactions
Gabriello Illuminati, Luigi Mandolini, and Bernardo Masci
pp 555 - 563; DOI:
10.1021/ja00341a041
PDF
A short-step entry to (.+-.)-quadrone
Kei Takeda, Yukari Shimono, and Eiichi Yoshii
pp 563 - 568; DOI:
10.1021/ja00341a042
PDF
Palladium-assisted macrocyclization approach to cytochalasins: a synthesis of antibiotic A26771B
Barry M. Trost and Steven J. Brickner
pp 568 - 575; DOI:
10.1021/ja00341a043
PDF
Total synthesis of the paniculides
Amos B. Smith and Ruth E. Richmond
pp 575 - 585; DOI:
10.1021/ja00341a044
PDF
Crown cation complex effects. 20. Syntheses and cation binding properties of carbon-pivot lariat ethers
Dennis M. Dishong, Craig J. Diamond, Michael I. Cinoman, and George W. Gokel
pp 586 - 593; DOI:
10.1021/ja00341a045
PDF
Total synthesis of the hypocholesterolemic agent compactin
Chi Tung Hsu, Nai Yi Wang, Lee H. Latimer, and Charles J. Sih
pp 593 - 601; DOI:
10.1021/ja00341a046
PDF
Multinuclear NMR studies on aluminum(III) complexes of ATP and related compounds
S. J. Karlik, G. A. Elgavish, and G. L. Eichhorn
pp 602 - 609; DOI:
10.1021/ja00341a047
PDF
Simulation of reaction pathways in enzymic and nonenzymic hydrolysis of p-nitrophenyldeoxythymidine diphosphate
Joan A. Deiters and Robert R. Holmes
pp 609 - 615; DOI:
10.1021/ja00341a048
PDF
Collisionless photoinduced electron transfer from ruthenium tris(bipyridine)2+* homologs to methyl viologen (MV2+) in rigid glycerol solution
Tom Guarr, Mark McGuire, Steve Strauch, and George McLendon
pp 616 - 618; DOI:
10.1021/ja00341a049
PDF
Thermal fragmentation of silacyclobutane. Formation of silylene, methylsilylene, and silene
Robert T. Conlin and Russel S. Gill
pp 618 - 619; DOI:
10.1021/ja00341a050
PDF
Partial synthesis of (20R)-25-hydroxycholesterol involving a nickel(II)-promoted dienol rearrangement
Keith S. Kyler and David S. Watt
pp 619 - 621; DOI:
10.1021/ja00341a051
PDF
Total synthesis of methyl (+)-pseudomonate C from carbohydrates
Jean Marie Beau, Shimpei Aburaki, Jean Rene Pougny, and Pierre Sinay
pp 621 - 622; DOI:
10.1021/ja00341a052
PDF
Photochemistry. 138. Vinylcyclopropene triplet rearrangement mechanisms: mechanistic and exploratory organic photochemistry
Howard E. Zimmerman and Steven A. Fleming
pp 622 - 624; DOI:
10.1021/ja00341a053
PDF
Total synthesis of qinghaosu
G. Schmid and W. Hofheinz
pp 624 - 625; DOI:
10.1021/ja00341a054
PDF
Synthesis of the cytotoxic germacranolide eucannabinolide
W. Clark Still, Shizuaki Murata, Gilbert Revial, and Kazuo Yoshihara
pp 625 - 627; DOI:
10.1021/ja00341a055
PDF
Effect of intercalating drugs and temperature on the association of sodium ions with DNA: sodium-23 NMR studies
Yitbarek H. Mariam and W. David Wilson
pp 627 - 628; DOI:
10.1021/ja00341a056
PDF
Electron spin resonance spectroscopy of the triplet state of m-xylylene
Bradford B. Wright and Matthew S. Platz
pp 628 - 630; DOI:
10.1021/ja00341a057
PDF
Cyclotristannoxane (R2SnO)3 and cyclotristannane (R2Sn)3 systems. Synthesis and crystal structures
Satoru Masamune, Lawrence R. Sita, and David J. Williams
pp 630 - 631; DOI:
10.1021/ja00341a058
PDF
Isoquinolinium cycloadditions: total synthesis of (.+-.)-14-epicorynoline and O-methylarnottianamide
J. R. Falck, Sukumar Manna, and Charles Mioskowski
pp 631 - 633; DOI:
10.1021/ja00341a059
PDF
Cation radical catalyzed olefin cyclodimerization
Nathan L. Bauld and Raul Pabon
pp 633 - 634; DOI:
10.1021/ja00341a060
PDF
Red shifts in the optical spectra of porphyrin Schiff's bases upon protonation
Brian Ward, Patricia M. Callahan, Richard Young, Gerald T. Babcock, and C. K. Chang
pp 634 - 636; DOI:
10.1021/ja00341a061
PDF
Methylated bases stabilize short RNA duplexes
P. L. D'Andrea, D. Alkema, R. A. Bell, J. M. Coddington, P. A. Hader, D. W. Hughes, and T. Neilson
pp 636 - 638; DOI:
10.1021/ja00341a062
PDF
Interaction of phosphines containing cyclopropyl substituents with Group VIII metals
Wiley J. Youngs and James A. Ibers
pp 639 - 640; DOI:
10.1021/ja00341a063
PDF
Synthesis of carbene complexes of Group IV metals from alkylidene-bridged heterobimetallic precursors
Frederick W. Hartner, Jeffrey Schwartz, and Susan M. Clift
pp 640 - 641; DOI:
10.1021/ja00341a064
PDF
Solid-state rearrangement of (phenylazophenyl)palladium hexafluoroacetylacetonate
M. C. Etter and A. R. Siedle
pp 641 - 643; DOI:
10.1021/ja00341a065
PDF
Design of organic metals based on tetramethyltetraselenafulvalene: novel structural implications and predictions
Jack M. Williams, Mark A. Beno, James C. Sullivan, Lisa M. Banovetz, Julie M. Braam, Gregory S. Blackman, Clark D. Carlson, Deena L. Greer, and Diana M. Loesing
pp 643 - 645; DOI:
10.1021/ja00341a066
PDF
Characterization of the interchain selenium...selenium interaction in (TMTSF)2X by band electronic structure
Myung Hwan Whangbo, Jack M. Williams, Mark A. Beno, and Jay R. Dorfman
pp 645 - 646; DOI:
10.1021/ja00341a067
PDF
Bacteriorhodopsins containing cyanine dye chromophores. Support for the external point-charge model
Fadila Derguini, Charles G. Caldwell, Michael G. Motto, Valeria Balogh-Nair, and Koji Nakanishi
pp 646 - 648; DOI:
10.1021/ja00341a068
PDF
Symmetric charge distribution in the bacteriorhodopsin binding site
Toshiaki Kakitani, Hiroko Kakitani, Barry Honig, and Koji Nakanishi
pp 648 - 650; DOI:
10.1021/ja00341a069
PDF
Wittig olefination via reaction of fluorine-containing phosphoranium salts and F-acyl fluorides. A new approach to fluoroolefin synthesis
Donald J. Burton and Daryl G. Cox
pp 650 - 651; DOI:
10.1021/ja00341a070
PDF
Metal homoenolate chemistry. Isolation and reactions of titanium homoenolates of esters
Eiichi Nakamura and Isao Kuwajima
pp 651 - 652; DOI:
10.1021/ja00341a071
PDF
Photosensitized [4 + 2] cyclodimerization of 1,3-cyclohexadiene
Carol R. Jones, Brian J. Allman, Anne Mooring, and Bojana Spahic
pp 652 - 654; DOI:
10.1021/ja00341a072
PDF
Halonium-initiated cyclizations of allylic urethanes: stereo- and regioselectivity in functionalizing the olefinic bond
Kathlyn A. Parker and Robert O'Fee
pp 654 - 655; DOI:
10.1021/ja00341a073
PDF
Unusual ligand replacement: displacement of .eta.5-cyclopentadienyl by .eta.6-arenes in the syntheses of H3(.eta.6-X)RhOs3(CO)9 (X = C6H6, PhMe). Crystal and molecular structure of H3(.eta.6-PhMe)RhOs3(CO)9
Sheldon G. Shore, Wen Liang Hsu, Melvyn Rowen Churchill, and Clifford Bueno
pp 655 - 656; DOI:
10.1021/ja00341a074
PDF
Cryoresonance Raman spectroscopy of plastocyanin, azurin, and stellacyanin. A reevaluation of the identity of the resonance-enhanced modes
William H. Woodruff, Kenneth A. Norton, Basil I. Swanson, and Herbert A. Fry
pp 657 - 658; DOI:
10.1021/ja00341a075
PDF
Metal electrodes bonded on solid polymer electrolytes: platinum bonded on solid polymer electrolyte for electrooxidation of methanol in perchloric acid solution
Akiko Katayama-Aramata and Ryuichiro Ohnishi
pp 658 - 659; DOI:
10.1021/ja00341a076
PDF
A photochemical route to the formation of threo aldols
Stuart L. Schreiber, Amir H. Hoveyda, and Hsien Jen Wu
pp 660 - 661; DOI:
10.1021/ja00341a077
PDF
Hindered dialkylamino nucleoside phosphite reagents in the synthesis of two DNA 51-mers
Steven P. Adams, Kamila S. Kavka, Evan J. Wykes, Sarah B. Holder, and Gerald R. Galluppi
pp 661 - 663; DOI:
10.1021/ja00341a078
PDF
Formation of an ozonide by electron-transfer photooxygenation of tetraphenyloxirane. Cosensitization by 9,10-dicyanoanthracene and biphenyl
A. Paul Schaap, Luigi Lopez, and Steven D. Gagnon
pp 663 - 664; DOI:
10.1021/ja00341a079
PDF
Symmetry of a reactive intermediate from ring expansion of cyclobutylidenecarbene. Cyclopentyne
John C. Gilbert and M. E. Baze
pp 664 - 665; DOI:
10.1021/ja00341a080
PDF
Metal-metal-bonded zirconium-ruthenium and zirconium-iron complexes
Charles P. Casey, Richard F. Jordan, and Arnold L. Rheingold
pp 665 - 667; DOI:
10.1021/ja00341a081
PDF
Synthesis and thermal isomerization of trans-bicyclo[4.1.0]hept-3-ene
Paul G. Gassman and Steven M. Bonser
pp 667 - 669; DOI:
10.1021/ja00341a082
PDF
Stereochemistry of transmetalation in the palladium-catalyzed coupling of acid chlorides and organotins
Jeff W. Labadie and John K. Stille
pp 669 - 670; DOI:
10.1021/ja00341a083
PDF
Fast intramolecular electron transfer in radical ions over long distances across rigid saturated hydrocarbon spacers
L. T. Calcaterra, G. L. Closs, and John R. Miller
pp 670 - 672; DOI:
10.1021/ja00341a084
PDF
Highly reduced organometallics. 10. Synthesis and chemistry of the pentacarbonylmetallate(3-) ions of niobium and tantalum, M(CO)53-
Garry F. P. Warnock, Julian Sprague, Kristi L. Fjare, and John E. Ellis
pp 672 - 672; DOI:
10.1021/ja00341a085
PDF
Olefinic cyclizations promoted by Beckmann rearrangement of oxime sulfonate
Soichi Sakane, Yasushi Matsumura, Yoshihiro Yamamura, Yasuko Ishida, Keiji Maruoka, and Hisashi Yamamoto
pp 672 - 674; DOI:
10.1021/ja00341a086
PDF
A new approach to construction of artificial monolayer assemblies
Lucy Netzer and Jacob Sagiv
pp 674 - 676; DOI:
10.1021/ja00341a087
PDF
Bridging ligand effects in quadruply bonded dichromium(II) compounds
Randall A. Kok and Michael B. Hall
pp 676 - 677; DOI:
10.1021/ja00341a088
PDF
Low-temperature metallic conductivity in a metallomacrocyclic crystal: nickel phthalocyanine iodide
Jens Martinsen, Richard L. Greene, Sharon M. Palmer, and Brian M. Hoffman
pp 677 - 678; DOI:
10.1021/ja00341a089
PDF
Resonance Raman excitation of oxygen (O2) stretching vibrations of oxy(tetraphenylporphyrinato)cobalt(II) at 457.9 nm
K. Bajdor, K. Nakamoto, and J. Kincaid
pp 678 - 679; DOI:
10.1021/ja00341a090
PDF
Reaction of singlet oxygen with enol esters: a new path implicating a dipolar intermediate
Stephen L. Wilson and Gary B. Schuster
pp 679 - 681; DOI:
10.1021/ja00341a091
PDF
o-Iodosobenzoate: catalyst for the micellar cleavage of activated esters and phosphates
Robert A. Moss, K. W. Alwis, and George O. Bizzigotti
pp 681 - 682; DOI:
10.1021/ja00341a092
PDF
Rearrangement of an alkyl-substituted anthraquinone. A model for the biosynthetic rearrangement of the averufin side chain
Zareen Ahmed and M. P. Cava
pp 682 - 684; DOI:
10.1021/ja00341a093
PDF

Issue 4


Effects of electron exchange and single-file diffusion on charge propagation in Nafion films containing redox couples
Daniel A. Buttry and Fred C. Anson
pp 685 - 689; DOI:
10.1021/ja00342a001
PDF
Singlet cyclobutyne: a relative minimum on the C4H4 potential-energy hypersurface?
George Fitzgerald, Paul Saxe, and Henry F. Schaefer
pp 690 - 695; DOI:
10.1021/ja00342a002
PDF
Ab initio second-order Moller-Plesset calculation of the vibrational spectra of cyclobutadiene and its isotopic derivatives
B. Andes Hess, P. Carsky, and L. J. Schaad
pp 695 - 701; DOI:
10.1021/ja00342a003
PDF
Singlet energy transfer from the charge-transfer excited state of tris(2,2'-bipyridine)ruthenium(II) to laser dyes
Krishnagopal Mandal, T. D. L. Pearson, W. P. Krug, and J. N. Demas
pp 701 - 707; DOI:
10.1021/ja00342a004
PDF
Effects of cyclic 8π-electron conjugation in reductively silylated nitrogen heterocycles
Wolfgang Kaim
pp 707 - 713; DOI:
10.1021/ja00342a005
PDF
The azoalkane 7,8-benzo-2,3-diazatricyclo[4.3.0.04,9]nona-2,7-diene as spin state specific chemical titrant of singlet and triplet excitation generated in the thermolysis of dioxetanes
Waldemar Adam and Klaus Hannemann
pp 714 - 719; DOI:
10.1021/ja00342a006
PDF
Theoretical ab initio study of 1,3-dipolar cycloaddition of fulminic acid to acetylene. Support for Firestone's mechanism
Philippe C. Hiberty, G. Ohanessian, and H. Bernhard Schlegel
pp 719 - 723; DOI:
10.1021/ja00342a007
PDF
A Van der Waals model of chiral mixtures using a chiral Lennard-Jones potential. Applications to the Pasteur Experiment and phenomena in chiral solvents
Pieter E. Schipper and Peter R. Harrowell
pp 723 - 730; DOI:
10.1021/ja00342a008
PDF
Effects of carbon-bound deuterium on the affinities of acetaldehyde-1-d and N-methylformamide-1-d for solvent water
Richard Wolfenden and Sue Kirkman
pp 731 - 732; DOI:
10.1021/ja00342a009
PDF
Carbon-13 and proton NMR analysis of isotopically labeled benzo[a]pyrenes
Clifford J. Unkefer, Robert E. London, Thomas W. Whaley, and Guido H. Daub
pp 733 - 735; DOI:
10.1021/ja00342a010
PDF
Structural determination of NiCnH2n+ ions in the gas phase using Fourier-transform mass spectrometry collision-induced dissociation
D. B. Jacobson and B. S. Freiser
pp 736 - 742; DOI:
10.1021/ja00342a011
PDF
Structure and energetics of [4.4.4.4]fenestrane
Jerome M. Schulman, Michael L. Sabio, and Raymond L. Disch
pp 743 - 744; DOI:
10.1021/ja00342a012
PDF
Nitrogen-nitrogen bond in dinitrogen tetroxide
Charles W. Bauschlicher, Andrew Komornicki, and Bjorn Roos
pp 745 - 748; DOI:
10.1021/ja00342a013
PDF
Cyclenphosphine oxide. Anomalous member of a homologous series
Jack E. Richman and Joseph J. Kubale
pp 749 - 751; DOI:
10.1021/ja00342a014
PDF
Spin-conversion reaction of muonium with nickel cyclam
J. M. Stadlbauer, B. W. Ng, Y. C. Jean, and D. C. Walker
pp 752 - 755; DOI:
10.1021/ja00342a015
PDF
Vibrational spectrum of solid sodium hydrogen bis(formate). An unsymmetrical very short OH...O bond in a complex containing spectroscopically distinct formate ion and formic acid entities
E. Spinner
pp 756 - 761; DOI:
10.1021/ja00342a016
PDF
Correlation between anisotropic exchange and structure of di-μ-hydroxy bridged copper(II) complexes
L. Banci, A. Bencini, and D. Gatteschi
pp 761 - 764; DOI:
10.1021/ja00342a017
PDF
The comparative roles of the proton-acceptor properties of amide and carboxyl groups in influencing crystal packing patterns: doubly vs. singly hydrogen-bonded systems in N-acylamino acids and in other amide-acid crystals
Z. Berkovitch-Yellin, S. Ariel, and L. Leiserowitz
pp 765 - 767; DOI:
10.1021/ja00342a018
PDF
Quenching of triplet states of organic compounds by chromium(III) tris(hexafluoroacetylacetonate) in benzene solution as a result of energy and electron transfer
Frank Wilkinson and Chris Tsiamis
pp 767 - 774; DOI:
10.1021/ja00342a019
PDF
Correlation between metal stability, charge transfer, and Raman frequencies in metalloporphyrins and their π-π complexes
J. A. Shelnutt
pp 774 - 778; DOI:
10.1021/ja00342a020
PDF
Preparation and molecular stereochemistry of anionic difluoro(meso-tetraphenylporphinato)iron(III), a high-spin six-coordinate iron(III) porphyrinate with an unusually expanded core and a hydrogen-bonded "distal" imidazole
W. Robert Scheidt, Young Ja Lee, Shoko Tamai, and Keiichiro Hatano
pp 778 - 782; DOI:
10.1021/ja00342a021
PDF
Proton NMR characterization of the ferryl group in model heme complexes and hemoproteins: evidence for the FeIVO group in ferryl myoglobin and compound II of horseradish peroxidase
Gerd N. La Mar, Jeffrey S. De Ropp, Lechoslaw Latos-Grazynski, Alan L. Balch, R. B. Johnson, Kevin M. Smith, Daniel W. Parish, and Ru Jen Cheng
pp 782 - 787; DOI:
10.1021/ja00342a022
PDF
Cryochemical studies. 3. ESR studies of the reaction of Group IB metal atoms with acetylene and phenylacetylene in a rotating cryostat
J. H. B. Chenier, J. A. Howard, B. Mile, and R. Sutcliffe
pp 788 - 791; DOI:
10.1021/ja00342a023
PDF
Formation and reactivity of some heterobinuclear rhodium/platinum complexes with 2-(diphenylphosphino)pyridine as a bridging ligand
James P. Farr, Marilyn M. Olmstead, Fred Wood, and Alan L. Balch
pp 792 - 798; DOI:
10.1021/ja00342a024
PDF
X-ray absorption edge and EXAFS spectroscopic studies of molybdenum ions in aqueous solution
Stephen P. Cramer, P. K. Eidem, M. T. Paffett, Jay R. Winkler, Zvi Dori, and Harry B. Gray
pp 799 - 802; DOI:
10.1021/ja00342a025
PDF
Conformations of pyridoxal Schiff bases of amino acids. A circular dichroism study
Luigi Casella and Michele Gullotti
pp 803 - 809; DOI:
10.1021/ja00342a026
PDF
Coordination chemistry of microbial iron transport compounds. 24. Characterization of coprogen and ferricrocin, two ferric hydroxamate siderophores
Geoffrey B. Wong, Mary J. Kappel, Kenneth N. Raymond, B. Matzanke, and G. Winkelmann
pp 810 - 815; DOI:
10.1021/ja00342a027
PDF
UV photoelectron spectra and electronic structure of (η5-C5H5)(CO)2FeB2H5. Comparison of the iron-boron bonding with the iron-carbon bonding in (CO)4FeC2H4
Roger L. DeKock, Prabodh Deshmukh, Thomas P. Fehlner, Catherine E. Housecroft, Jeffrey S. Plotkin, and Sheldon G. Shore
pp 815 - 822; DOI:
10.1021/ja00342a028
PDF
Mechanisms of dirhenium decacarbonyl substitution reactions: crossover experiments with dirhenium-185 decacarbonyl and dirhenium-187 decacarbonyl
A. M. Stolzenberg and E. L. Muetterties
pp 822 - 827; DOI:
10.1021/ja00342a029
PDF
Synthesis, characterization, and conductivity of (μ-cyano)(phthalocyaninato)cobalt(III)
Josef Metz and Michael Hanack
pp 828 - 830; DOI:
10.1021/ja00342a030
PDF
Cluster syntheses. 2. The role of heteroatoms in the formation of high nuclearity transition-metal carbonyl cluster compounds. The condensation of small clusters
Richard D. Adams, Zain Dawoodi, Donald F. Foust, and Brigitte E. Segmueller
pp 831 - 838; DOI:
10.1021/ja00342a031
PDF
An experimental measure of cavity size in macrocyclic cyclophane-based host molecules
Barbara J. Whitlock and Howard W. Whitlock
pp 838 - 844; DOI:
10.1021/ja00342a032
PDF
Reactivity of coordinated disulfides. 1. Nucleophilic cleavage of the sulfur-sulfur bond
Akio Ichimura, Dennis L. Nosco, and Edward Deutsch
pp 844 - 850; DOI:
10.1021/ja00342a033
PDF
Kinetic study for reactions of phenylseleno radical with vinyl monomers
Osamu Ito
pp 850 - 853; DOI:
10.1021/ja00342a034
PDF
Enlarged deuterium isotope effects in oxyanion-catalyzed 1,3 proton transfer competing with 1,2 elimination as a probe of a common tightly hydrogen-bonded intermediate
Alf Thibblin
pp 853 - 858; DOI:
10.1021/ja00342a035
PDF
Low-temperature and time-resolved absorption spectral studies on the sp- and ap-2-(9-fluorenyl)phenylnitrenes generated from 1-azatriptycene and 2-(9-fluorenyl)phenyl azide
Tadashi Sugawara, Nobuaki Nakashima, Keitaro Yoshihara, and Hiizu Iwamura
pp 858 - 862; DOI:
10.1021/ja00342a036
PDF
Stereochemistry and Mechanism of π-Assisted Solvolysis of endo-Bicyclo[3.3.1]non-6-ene-3-methyl Tosylate
J. Eric Nordlander, Kirtivan D. Kotian, Dwight E. Raff, William P. Grohol, Vasanth M. Vishwanath, and Jeffry J. Winemiller
pp 863 - 867; DOI:
10.1021/ja00342a037
PDF
Equilibrium studies of water and thiol addition to ketones: substituent and solvent effects for methyl ketones
Theodore J. Burkey and Robert C. Fahey
pp 868 - 871; DOI:
10.1021/ja00342a038
PDF
Relationship between electron densities and chemical shifts. 3. para-Substituted benzoyl cations
Robert T. C. Brownlee and David J. Craik
pp 872 - 875; DOI:
10.1021/ja00342a039
PDF
Cyclization of 3-(arylchalcogeno)propenoyl chlorides. 1. 1,2-Oxatellurol-1-ium halides via ipso acylation
Michael R. Detty, Bruce J. Murray, Douglas L. Smith, and Nicholas Zumbulyadis
pp 875 - 882; DOI:
10.1021/ja00342a040
PDF
Cyclization of 3-(arylchalcogeno)propenoyl chlorides. 2. Chalcogen and substituent control in the regiochemistry of intramolecular acylation. Preparation of benzo[b]telluropyrones
Michael R. Detty and Bruce J. Murray
pp 883 - 890; DOI:
10.1021/ja00342a041
PDF
The totally degenerate (CH)9+ ion 9-barbaralyl cation studied by carbon-13 labeling and isotopic perturbation by eight deuteriums
Carin Engdahl, Goeran Jonsaell, and Per Ahlberg
pp 891 - 897; DOI:
10.1021/ja00342a042
PDF
Chemistry of heavy carbene analogs R2M (M = Si, Ge, Sn). 8. Germylenes: singlets or triplets? [2 + 4]Cheletropic cycloadditions of dimethylgermylene and diiodogermylene to conjugated dienes
Michael Schriewer and Wilhelm P. Neumann
pp 897 - 901; DOI:
10.1021/ja00342a043
PDF
A novel synthesis of peptides based on the photochemistry of 5-azido-1,3,4-oxadiazoles
Pat N. Confalone and Robert B. Woodward
pp 902 - 906; DOI:
10.1021/ja00342a044
PDF
Selenium dioxide oxidations in the indole area. Synthesis of β-carboline alkaloids
M. Cain, O. Campos, F. Guzman, and J. M. Cook
pp 907 - 913; DOI:
10.1021/ja00342a045
PDF
Nocardicin A: biosynthetic experiments with amino acid precursors
Craig A. Townsend and Alethia M. Brown
pp 913 - 918; DOI:
10.1021/ja00342a046
PDF
Nocardicin A: stereochemical and biomimetic studies of monocyclic β-lactam formation
Craig A. Townsend, Alethia M. Brown, and Loan T. Nguyen
pp 919 - 927; DOI:
10.1021/ja00342a047
PDF
Total synthesis of the marine natural product .DELTA.9(12)-capnellene. Reversal of regiochemistry in the intramolecular 1,3-diyl trapping reaction
R. Daniel Little, Gary L. Carroll, and Jeffrey L. Petersen
pp 928 - 932; DOI:
10.1021/ja00342a048
PDF
Intramolecular cycloaddition reactions of diazoalkenes. A theoretical prognosis of nitrene type behavior
Albert Padwa, Augusto Rodriguez, Mahrokh Tohidi, and Tadamichi Fukunaga
pp 933 - 943; DOI:
10.1021/ja00342a049
PDF
Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers
Charles E. Russell and Louis S. Hegedus
pp 943 - 949; DOI:
10.1021/ja00342a050
PDF
2-Norbornanediazonium ions revisited
Wolfgang Kirmse and Rainer Siegfried
pp 950 - 956; DOI:
10.1021/ja00342a051
PDF
Photoreaction of thymidine with alkylamines. Application to selective removal of thymine from DNA
Isao Saito, Hiroshi Sugiyama, and Teruo Matsuura
pp 956 - 962; DOI:
10.1021/ja00342a052
PDF
Novel photoadditions involving 1,4-transfer of cyano group. Photoreaction of 6-cyanouracils with alkenes and alkynes
Isao Saito, Koji Shimozono, and Teruo Matsuura
pp 963 - 970; DOI:
10.1021/ja00342a053
PDF
A method for the analysis of puckering disorder in five-membered rings: the relative mobilities of furanose and proline rings and their effects on polynucleotide and polypeptide backbone flexibility
E. Westhof and M. Sundaralingam
pp 970 - 976; DOI:
10.1021/ja00342a054
PDF
Ternary complexes as models for protein-metal-nucleic acid interactions: structure of palladium(II) complex with glycyl-L-tyrosine and cytidine
M. Sabat, K. A. Satyshur, and M. Sundaralingam
pp 976 - 980; DOI:
10.1021/ja00342a055
PDF
The bicarbonate proton in carbonic anhydrase catalysis
Y. Pocker and Thomas L. Deits
pp 980 - 986; DOI:
10.1021/ja00342a056
PDF
Flexibility of nucleic acid conformations. 1. Comparison of the intensities of the Raman-active backbone vibrations in double-helical nucleic acids and model double-helical dinucleotide crystals
Gerald A. Thomas and Warner L. Peticolas
pp 986 - 992; DOI:
10.1021/ja00342a057
PDF
Fluctuations in nucleic acid conformations. 2. Raman spectroscopic evidence of varying ring pucker in A-T polynucleotides
Gerald A. Thomas and Warner L. Peticolas
pp 993 - 996; DOI:
10.1021/ja00342a058
PDF
Molecular mechanics studies of enzyme-substrate interactions: the interaction of L- and D-N-acetyltryptophanamide with α-chymotrypsin
Georges Wipff, Andrew Dearing, Paul K. Weiner, Jeffrey M. Blaney, and Peter A. Kollman
pp 997 - 1005; DOI:
10.1021/ja00342a059
PDF
Products and mechanism of the oxyanion- and .beta.-lactamase-catalyzed hydrolyses of (phenoxymethyl)anhydropenicillin
R. F. Pratt, Yvonne S. Surh, and John J. Shaskus
pp 1006 - 1014; DOI:
10.1021/ja00342a060
PDF
Hydride vs. electron transfer in the reduction of flavin and flavin radical by 1,4-dihydropyridines
Michael F. Powell and Thomas C. Bruice
pp 1014 - 1021; DOI:
10.1021/ja00342a061
PDF
Nitrogen-15 nuclear magnetic resonance spectroscopy of neomycin B and related aminoglycosides
Robert E. Botto and Bruce Coxon
pp 1021 - 1028; DOI:
10.1021/ja00342a062
PDF
Affinities of phosphoric acids, esters, and amides for solvent water
Richard Wolfenden and Richard Williams
pp 1028 - 1031; DOI:
10.1021/ja00342a063
PDF
Cyclopeptide alkaloids. Conformational analysis of the dihydro-p-phencyclopeptine nucleus
J. Clark Lagarias, Wallace H. Yokoyama, Jon Bordner, Willy C. Shih, Melvin P. Klein, and Henry Rapoport
pp 1031 - 1040; DOI:
10.1021/ja00342a064
PDF
One-dimensional aromatic crystal in solution. 1. Synthesis, conformation, and spectroscopic properties of poly(L-1-naphthylalanine)
Masahiko Sisido, Syun Egusa, and Yukio Imanishi
pp 1041 - 1049; DOI:
10.1021/ja00342a065
PDF
Carbodications. V. Structures and energies of C6H62+ isomers. Fragmentation into C5H3+ and CH3+
Koop Lammertsma and Paul von Rague Schleyer
pp 1049 - 1051; DOI:
10.1021/ja00342a066
PDF
Bis(borane)-cyclenphosphorane: a stable adduct in which two phosphorus(V)-bonded nitrogen atoms display donor character
Jean Marc Dupart, Simonne Pace, and Jean G. Riess
pp 1051 - 1052; DOI:
10.1021/ja00342a067
PDF
1,1-Bis(benzenesulfonyl)cyclopropane: a synthon for a propylene 1,3-dipole
Barry M. Trost, Janine Cossy, and John Burks
pp 1052 - 1054; DOI:
10.1021/ja00342a068
PDF
Sulfur activation of azides toward addition of organometallics. Amination of aliphatic carbanions
Barry M. Trost and William H. Pearson
pp 1054 - 1056; DOI:
10.1021/ja00342a069
PDF
Syntheses, chemical properties, and x-ray crystal structures of rhenium formaldehyde and thioformaldehyde complexes
William E. Buhro, Alan T. Patton, Charles E. Strouse, J. A. Gladysz, Fred B. McCormick, and Margaret C. Etter
pp 1056 - 1058; DOI:
10.1021/ja00342a070
PDF
Total synthesis of (.+-.)-verrucarol
William R. Roush and Thomas E. D'Ambra
pp 1058 - 1060; DOI:
10.1021/ja00342a071
PDF
Incorporating metal-metal multiple bonds into heterometallic chains: bis[tris(trimethylstanyl)tin]tetrakis(dimethylamido)dimolybdenum and -ditungsten and related compounds
M. J. Chetcuti, M. H. Chisholm, H. T. Chiu, and J. C. Huffman
pp 1060 - 1061; DOI:
10.1021/ja00342a072
PDF
Stereochemistry of the electrophilic fragmentation-cyclization of allenic sulfones and sulfinates: stereoselective synthesis of chiral αβ-unsaturated γ-sultines
S. Braverman and Y. Duar
pp 1061 - 1063; DOI:
10.1021/ja00342a073
PDF
Mechanism of proton removal from intramolecularly hydrogen-bonded (phenylazo)resorcinol monoanions
Frank Hibbert and Gareth R. Simpson
pp 1063 - 1064; DOI:
10.1021/ja00342a074
PDF
Phosphorus donor-crown ether hybrid ligands as a route to carbonyl activation: phosphorus substituent effects and the importance of strong cation binding
John Powell, Michael Gregg, Anda Kuksis, and Patty Meindl
pp 1064 - 1065; DOI:
10.1021/ja00342a075
PDF
Low-temperature photochemistry of tetracarbonylethyleneiron and tetracarbonylpropyleneiron. Spectroscopic observation of catalytically significant intermediates
James C. Mitchener and Mark S. Wrighton
pp 1065 - 1067; DOI:
10.1021/ja00342a076
PDF
Raman spectroscopy of electronic excited organometallic complexes: a comparison of the metal to 2,2'-bipyridine charge-transfer state of fac-(2,2'-bipyridine)tricarbonylhalorhenium and tris(2,2'-bipyridine)ruthenium(II)
William K. Smothers and Mark S. Wrighton
pp 1067 - 1069; DOI:
10.1021/ja00342a077
PDF
Stable tungsten-iridium binuclear acyl hydride and carbene hydride complexes
Michael J. Breen, Gregory L. Geoffroy, Arnold L. Rheingold, and William C. Fultz
pp 1069 - 1070; DOI:
10.1021/ja00342a078
PDF
Chemical reactions of tetramesityldisilene
Mark J. Fink, Douglas J. De Young, Robert West, and Josef Michl
pp 1070 - 1071; DOI:
10.1021/ja00342a079
PDF
Stereocontrol in homogeneous catalytic hydrogenation via hydroxyl group coordination
Gilbert Stork and Daniel E. Kahne
pp 1072 - 1073; DOI:
10.1021/ja00342a080
PDF
2-Substituted tetrahydrofurans of known absolute stereochemistry by ScN' chirality transfer
Gilbert Stork and J. M. Poirier
pp 1073 - 1074; DOI:
10.1021/ja00342a081
PDF
Additions and Corrections - Tetraphenylarsonium 1,2,3,4,5-Pentakis(methylmercapto)cyclopentadienide
F. Wudl, D. Nalewajek, F. J. Rotella, and E. Gebert
pp 1074 - 1074; DOI:
10.1021/ja00342a600
PDF
Additions and Corrections - An Electron-Diffraction Investigation of the Molecular Structure of Gaseous 2,3-Butanedione (Biacetyl) at 228 and 525°C
Donald D. Danielson, and Kenneth Hedberg
pp 1074 - 1074; DOI:
10.1021/ja00342a601
PDF
Additions and Corrections - Intramolecular Type II "Metallo-Ene" Reactions of (2-Alkenylallyl)magnesium Chlorides: Regio- and Stereochemical Studies
Wolfgang Oppolzer, Rita Pitteloud, and Henrich F. Strauss
pp 1074 - 1074; DOI:
10.1021/ja00342a602
PDF
Additions and Corrections - Time Lags and V-V' Steady States in the Infrared Laser Induced Decomposition of CHCIF2 and CDCIF2 under Collisional Conditions
Ernest Grunwald, Shu-Huei Liu, and Charles M. Lonzetta
pp 1075 - 1075; DOI:
10.1021/ja00342a603
PDF
Additions and Corrections - β-Alkyl Transfer in the Lanthanide Model for Chain Termination
P. L. Watson, and D. C. Roe
pp 1075 - 1075; DOI:
10.1021/ja00342a604
PDF
Additions and Corrections - Ketonization of Enols. Enol Content and Acid Dissociation Constants of Simple Carbonyl Compounds.
Y. Chiang, A. J. Kresge, and P. A. Walsh
pp 1075 - 1075; DOI:
10.1021/ja00342a605
PDF
Book Reviews

pp 1075 - 1078; DOI:
10.1021/ja00342a606
PDF

Issue 5


Peierls distortions in two and three dimensions and the structures of AB solids
Jeremy K. Burdett and Stephen Lee
pp 1079 - 1083; DOI:
10.1021/ja00343a001
PDF
Vibrational frequencies for silaacetylene and its silylidene and vinylidene isomers
Mark R. Hoffmann, Yasunori Yoshioka, and Henry F. Schaefer
pp 1084 - 1088; DOI:
10.1021/ja00343a002
PDF
Coordination in benzene dimer cation radical
Sam A. Milosevich, Kathy Saichek, Laura Hinchey, Walter B. England, and Peter Kovacic
pp 1088 - 1090; DOI:
10.1021/ja00343a003
PDF
Thermal lensing study of singlet oxygen reactions
Kiyokazu Fuke, Masayasu Ueda, and Michiya Itoh
pp 1091 - 1096; DOI:
10.1021/ja00343a004
PDF
New model for the interior of polyelectrolyte coatings on electrode surfaces. Mechanisms of charge transport through protonated poly(L-lysine) films containing FeIII(edta)- and FeII(edta)2- as counterions
Fred C. Anson, Jean Michel Saveant, and Kiyotaka Shigehara
pp 1096 - 1106; DOI:
10.1021/ja00343a005
PDF
Transient spontaneous Raman study of photoionization kinetics at the hydrocarbon/water interface in micellar solutions
S. M. Beck and L. E. Brus
pp 1106 - 1111; DOI:
10.1021/ja00343a006
PDF
Heat capacities of solution for alcohols in polar solvents and the new view of hydrophobic effects
Dorla Mirejovsky and Edward M. Arnett
pp 1112 - 1117; DOI:
10.1021/ja00343a007
PDF
Novel photoreversible cyclization of acyl-substituted 2,4,6-triisopropylbenzophenones
Yoshikatsu Ito, Brij Pal Giri, Masaaki Nakasuji, Toshiya Hagiwara, and Teruo Matsuura
pp 1117 - 1122; DOI:
10.1021/ja00343a008
PDF
Aromatic substitution in the gas phase. Intramolecular selectivity of the reaction of aniline with charged electrophiles
Marina Attina and Fulvio Cacace
pp 1122 - 1126; DOI:
10.1021/ja00343a009
PDF
Infrared laser induced heterogeneous reactions: 2-propanol with cupric oxide
William D. Farneth, Patrick G. Zimmerman, Derk J. Hogenkamp, and Scott D. Kennedy
pp 1126 - 1129; DOI:
10.1021/ja00343a010
PDF
Polymeric surfactant vesicles. Synthesis and characterization by nuclear magnetic resonance spectroscopy and dynamic laser light scattering
Donald Kippenberger, Kenneth Rosenquist, Lars Odberg, Pietro Tundo, and Janos H. Fendler
pp 1129 - 1135; DOI:
10.1021/ja00343a011
PDF
Structure and reactivity of bis(pentamethylcyclopentadienyl)(ethylene)titanium(II), a simple olefin adduct of titanium
Steven A. Cohen, Pamela R. Auburn, and John E. Bercaw
pp 1136 - 1143; DOI:
10.1021/ja00343a012
PDF
Multiple-scattering effects in EXAFS spectroscopy of oxygen-bridged iron complexes. Possibility of angle determination of EXAFS analysis
Man Sung Co, Wayne A. Hendrickson, Keith O. Hodgson, and Sebastian Doniach
pp 1144 - 1150; DOI:
10.1021/ja00343a013
PDF
Molybdenum chalcogenides: clusters, chains, and extended solids. The approach to bonding in three dimensions
Timothy Hughbanks and Roald Hoffmann
pp 1150 - 1162; DOI:
10.1021/ja00343a014
PDF
1,2-Dibenzyl- and 1,2-diaryltetrakis(dimethylamido)dimolybdenum and -ditungsten compounds: M2R2(NMe2)4 (M.tplbond.M). Structural effects of Me2N-to-M .pi. bonding
M. J. Chetcuti, Malcolm H. Chisholm, K. Folting, D. A. Haitko, J. C. Huffman, and J. Janos
pp 1163 - 1170; DOI:
10.1021/ja00343a015
PDF
Protonation equilibria in excited-state tris(bipyrazine)ruthenium(II)
R. J. Crutchley, N. Kress, and A. B. P. Lever
pp 1170 - 1178; DOI:
10.1021/ja00343a016
PDF
Broensted acidities of carbonyl hydride complexes of iron, ruthenium, and osmium: pKa values and deprotonation rates in methanol solution
Howard W. Walker, Ralph G. Pearson, and Peter C. Ford
pp 1179 - 1186; DOI:
10.1021/ja00343a017
PDF
Crystal, molecular, and electronic structure of tetrasulfur dinitride, S4N2
T. Chivers, P. W. Codding, W. G. Laidlaw, S. W. Liblong, Richard T. Oakley, and M. Trsic
pp 1186 - 1192; DOI:
10.1021/ja00343a018
PDF
Crystal structure of dehydrated calcium-exchanged zeolite A. Absence of near-zero-coordinate calcium(2+) ion. Presence of aluminum complex
Joseph J. Pluth and Joseph V. Smith
pp 1192 - 1195; DOI:
10.1021/ja00343a019
PDF
Photoracemization of bis(oxalato)(1,10-phenanthroline)chromate(III): intensity and wavelength dependence evidence for both quartet and doublet pathways
Hiroaki Kido and Cooper H. Langford
pp 1196 - 1199; DOI:
10.1021/ja00343a020
PDF
Serial cyclization: studies in the mechanism and stereochemistry of peroxy radical cyclization
A. Nicholas Roe, Andrew T. McPhail, and Ned A. Porter
pp 1199 - 1203; DOI:
10.1021/ja00343a021
PDF
Exploratory and mechanistic aspects of the electron-transfer photochemistry of olefin-N-heteroaromatic cation systems
Ung Chan Yoon, Suzanne L. Quillen, Patrick S. Mariano, Rosemarie Swanson, Jerome L. Stavinoha, and Elliott Bay
pp 1204 - 1218; DOI:
10.1021/ja00343a022
PDF
Photochemical transformations. 32. Stereochemical course and stereochemical requirement for activation of photosolvolysis and photorearrangements in a chlorobenzobicyclo[2.2.2]octadienyl system
Stanley J. Cristol, Wayne A. Dickenson, and Marilyn K. Stanko
pp 1218 - 1220; DOI:
10.1021/ja00343a023
PDF
Substituent effects on benzyl radical ESR hyperfine coupling constants. The .sigma..alpha..cntdot. scale based upon spin delocalization
Julian M. Dust and Donald R. Arnold
pp 1221 - 1227; DOI:
10.1021/ja00343a024
PDF
Strain energies of small ring propellanes
Kenneth B. Wiberg
pp 1227 - 1233; DOI:
10.1021/ja00343a025
PDF
Carbon-carbon bond formation by condensation at metal-activated olefins. Regio- and stereoselectivity of cycloaddition reactions
P. Lennon and M. Rosenblum
pp 1233 - 1241; DOI:
10.1021/ja00343a026
PDF
Crystal structures of repeating peptides of elastin. 3. N-(tert-Butoxycarbonyl)-L-valyl-L-prolylglycyl-L-valine and its monohydrate crystal
Yoshiro Yagi, Isao Tanaka, Takashi Yamane, and Tamaichi Ashida
pp 1242 - 1246; DOI:
10.1021/ja00343a027
PDF
Crystal and molecular structure of benzo-13-crown-4 and its complex with lithium thiocyanate
G. Shoham, W. N. Lipscomb, and U. Olsher
pp 1247 - 1252; DOI:
10.1021/ja00343a028
PDF
Multifunctional micellar catalysis as a model of enzyme action
Yasuji Ihara, Mamoru Nango, Yoshiharu Kimura, and Nobuhiko Kuroki
pp 1252 - 1255; DOI:
10.1021/ja00343a029
PDF
Total syntheses of dl-gephyrotoxin and dl-dihydrogephyrotoxin
David J. Hart and Kenichi Kanai
pp 1255 - 1263; DOI:
10.1021/ja00343a030
PDF
Direct thermal and photochemical generation of silanones
Gregory Hussman, William D. Wulff, and Thomas J. Barton
pp 1263 - 1269; DOI:
10.1021/ja00343a031
PDF
Variations in mechanism for photoinduced valence isomerization of an electron-donor nonconjugated diene
Guilford Jones, William G. Becker, and Sheau Hwa Chiang
pp 1269 - 1276; DOI:
10.1021/ja00343a032
PDF
Photoisomerization of charge-transfer complexes of hexamethyl(Dewar benzene). Contrasting paths for rearrangement involving adiabatic reaction and ionic photodissociation
Guilford Jones and William G. Becker
pp 1276 - 1283; DOI:
10.1021/ja00343a033
PDF
Hydride-abstraction reactions from cycloheptatriene and 1-carbamoylcycloheptatriene. Effect of the CONH2 group orientation on the reactivity difference of the exo and endo hydrogen toward hydride abstraction. A quantum-chemical study
R. H. A. M. Brounts and H. M. Buck
pp 1284 - 1288; DOI:
10.1021/ja00343a034
PDF
Reactions of carbenes with acetone. Reversible thermal formation and fragmentation of carbonyl ylides and their cycloaddition to acetone
Michel Bekhazi and John Warkentin
pp 1289 - 1292; DOI:
10.1021/ja00343a035
PDF
Regiochemical control in intramolecular photochemical reactions of 1,5-hexadien-3-ones and 1-acyl-1,5-hexadienes
Steven Wolff and William C. Agosta
pp 1292 - 1299; DOI:
10.1021/ja00343a036
PDF
Intramolecular photochemical reactions of 2-acyl-1,5-hexadienes
Steven Wolff and William C. Agosta
pp 1299 - 1304; DOI:
10.1021/ja00343a037
PDF
Activation of carbon dioxide with aluminum porphyrin and reaction with epoxide. Studies on (tetraphenylporphinato)aluminum alkoxide having a long oxyalkylene chain as the alkoxide group
Takuzo Aida and Shohei Inoue
pp 1304 - 1309; DOI:
10.1021/ja00343a038
PDF
Photochemistry of diastereomeric 2,4-diphenylpentan-3-ones and related ketones in "super-cage" environments provided by micelles, porous glass, and porous silica: temperature and magnetic field effects
Bruce H. Baretz and Nicholas J. Turro
pp 1309 - 1316; DOI:
10.1021/ja00343a039
PDF
Cyclic and high polymeric nido-carboranylphosphazenes as ligands for transition metals
Harry R. Allcock, Angelo G. Scopelianos, Robert R. Whittle, and Norris M. Tollefson
pp 1316 - 1321; DOI:
10.1021/ja00343a040
PDF
Phosphorus-nitrogen ring systems and high polymers. Iron- and ruthenium-linked phosphazenes
Harry R. Allcock, Linda J. Wagner, and Michael L. Levin
pp 1321 - 1327; DOI:
10.1021/ja00343a041
PDF
Molecular structure, absolute stereochemistry, and interactions of nogalamycin, a DNA-binding anthracycline antitumor antibiotic
S. K. Arora
pp 1328 - 1332; DOI:
10.1021/ja00343a042
PDF
Detailed binding sites of the antibiotics vancomycin and ristocetin A: determination of intermolecular distances in antibiotic/substrate complexes by use of the time-dependent NOE
Dudley H. Williams, Michael P. Williamson, David W. Butcher, and Stephen J. Hammond
pp 1332 - 1339; DOI:
10.1021/ja00343a043
PDF
Solvent effects on equilibria of addition of nucleophiles to acetaldehyde and the hydrophilic character of diols
Roger Bone, Paul Cullis, and Richard Wolfenden
pp 1339 - 1343; DOI:
10.1021/ja00343a044
PDF
Solution forms of bouvardin and relatives from NMR studies. 6-O-Methylbouvardin
Robert B. Bates, Jack R. Cole, Joseph J. Hoffmann, George R. Kriek, Gary S. Linz, and Sterling J. Torrance
pp 1343 - 1347; DOI:
10.1021/ja00343a045
PDF
Thallium-205 as an NMR probe for the investigation of transferrin
I. Bertini, C. Luchinat, and L. Messori
pp 1347 - 1350; DOI:
10.1021/ja00343a046
PDF
Mechanism of T1 relaxation in 13CO complexed to an iron porphyrin: implications for CO bonding in heme proteins
T. Perkins, J. D. Satterlee, and J. H. Richards
pp 1350 - 1354; DOI:
10.1021/ja00343a047
PDF
Stereochemistry of gaseous anions: hydroxide ion negative chemical ionization of 17-.zeta.-R-5.alpha.,14.beta.-androstane-14,17.zeta.-diols
J. C. Beloeil, M. Bertranne, D. Stahl, and J. C. Tabet
pp 1355 - 1359; DOI:
10.1021/ja00343a048
PDF
Theory of magnetic susceptibilities and NMR chemical shifts in terms of localized quantities. 3. Application to hydrocarbons and other organic molecules
Michael Schindler and Werner Kutzelnigg
pp 1360 - 1370; DOI:
10.1021/ja00343a049
PDF
Conversion of alkyl acetates to (siloxymethylene)alkanes by dicobalt octacarbonyl-catalyzed reaction with a hydrosilane and carbon monoxide
Naoto Chatani, Shinji Murai, and Noboru Sonoda
pp 1370 - 1372; DOI:
10.1021/ja00343a050
PDF
Benz[b]homoheptalene. Consequences of ring fusion between benzene and a bridged [12]annulene
Lawrence T. Scott, Mark A. Kirms, Harald Guenther, and Henning Von Puttkamer
pp 1372 - 1373; DOI:
10.1021/ja00343a051
PDF
Emission spectroscopic properties of dioxorhenium(V) complexes in crystals and solutions
Jay R. Winkler and Harry B. Gray
pp 1373 - 1374; DOI:
10.1021/ja00343a052
PDF
Photochemical reactivity in organized assemblies. 33. Host-guest interactions in amylose inclusion complexes: photochemistry of surfactant stilbenes in helical cavities of amylose
Y. Hui, J. C. Russell, and D. G. Whitten
pp 1374 - 1376; DOI:
10.1021/ja00343a053
PDF
Synthesis and structure of 8-carboxy[6]paracyclophane
Yoshito Tobe, Kiyomi Kakiuchi, Yoshinobu Odaira, Tatusya Hosaki, Yasushi Kai, and Nobutami Kasai
pp 1376 - 1377; DOI:
10.1021/ja00343a054
PDF
Isolable species from nucleophilic attack at sulfinyl and sulfonyl sulfur: a sulfuran dioxide (10-S-5) salt and a sulfuran oxide (10-S-4) salt
C. W. Perkins and J. C. Martin
pp 1377 - 1379; DOI:
10.1021/ja00343a055
PDF
Unique stable organometallic nickel(III) complexes; syntheses and the molecular structure of [Ni[C6H3(CH2NMe2)2-2,6]I2]
David M. Grove, Gerard Van Koten, Rob Zoet, Nicholas W. Murrall, and Alan J. Welch
pp 1379 - 1380; DOI:
10.1021/ja00343a056
PDF
Formation of a .sigma.-bonded aryliron complex in the reaction of arylhydrazines with hemoglobin and myoglobin
Kent L. Kunze and Paul R. Ortiz de Montellano
pp 1380 - 1381; DOI:
10.1021/ja00343a057
PDF
Gas-phase NMR spectroscopy of cyclohexane: environmental effects on conformational isomerism
Brian D. Ross and Nancy S. True
pp 1382 - 1383; DOI:
10.1021/ja00343a058
PDF
Hydroalumination of 1-(trimethylsilyl-1,3-diynes). Syntheses of stereodefined enynes and dienes
Joseph A. Miller and George Zweifel
pp 1383 - 1384; DOI:
10.1021/ja00343a059
PDF
An unprecedented bis(carbyne) cluster rearrangement involving simultaneous coupling and decoupling of carbyne fragments: a new homogeneous model for carbon-carbon bond forming and bond breaking on surfaces
Neil T. Allison, John R. Fritch, K. Peter C. Vollhardt, and Eric C. Walborsky
pp 1384 - 1386; DOI:
10.1021/ja00343a060
PDF
Photosensitized electron-transfer reactions. Interception of the geminate radical ion pair
Susan L. Mattes and Samir Farid
pp 1386 - 1387; DOI:
10.1021/ja00343a061
PDF
Aggregation of the bacteriochlorophylls c, d, and e. Models for the antenna chlorophylls of green and brown photosynthetic bacteria
Kevin M. Smith, Lisa A. Kehres, and Jack Fajer
pp 1387 - 1389; DOI:
10.1021/ja00343a062
PDF
Transaminations by pyridoxamine selectively attached at C-3 in .beta.-cyclodextrin
Ronald Breslow and Anthony W. Czarnik
pp 1390 - 1391; DOI:
10.1021/ja00343a063
PDF
Stereochemistry at the chiral ruthenium atom in the reaction of diastereomeric (.eta.5-C5H5)RuCl[(R)-Ph2PCHMeCH2PPh2] with tin(II) chloride
Giambattista Consiglio, Franco Morandini, Gianfranco Ciani, Angelo Sironi, and Matthias Kretschmer
pp 1391 - 1392; DOI:
10.1021/ja00343a064
PDF
Formation and identification of methylene on ruthenium (001)
Patricia M. George, N. R. Avery, W. H. Weinberg, and F. N. Tebbe
pp 1393 - 1394; DOI:
10.1021/ja00343a065
PDF
Cryochemical studies. 4. ESR spectrum of matrix-isolated copper-silver-copper (CuAgCu)
J. A. Howard, R. Sutcliffe, and B. Mile
pp 1394 - 1395; DOI:
10.1021/ja00343a066
PDF
Free-radical rearrangement of a silyl radical via net 1,2-migration of an acetoxy group
James W. Wilt and Steven M. Keller
pp 1395 - 1396; DOI:
10.1021/ja00343a067
PDF
Total synthesis of eupolauramine
Jeremy I. Levin and Steven M. Weinreb
pp 1397 - 1398; DOI:
10.1021/ja00343a068
PDF
Free-radical chain-substitution reactions of alkylmercury halides
Glen A. Russell and Hasan Tashtoush
pp 1398 - 1399; DOI:
10.1021/ja00343a069
PDF
Iron porphyrin dependent oxidation of methyl- and phenylhydrazine: isolation of iron(II)-diazene and .sigma.-alkyliron(III) [or aryliron(III)] complexes. Relevance to the reactions of hemoproteins with hydrazines
P. Battioni, J. P. Mahy, G. Gillet, and D. Mansuy
pp 1399 - 1401; DOI:
10.1021/ja00343a070
PDF
Organolanthanide hydride chemistry. 3. Reactivity of low-valent samarium with unsaturated hydrocarbons leading to a structurally characterized samarium hydride complex
William J. Evans, Ira Bloom, William E. Hunter, and Jerry L. Atwood
pp 1401 - 1403; DOI:
10.1021/ja00343a071
PDF
Total synthesis of the hypocholesterolemic agent (+)-compactin
Paul A. Grieco, Robert E. Zelle, Randall Lis, and John Finn
pp 1403 - 1404; DOI:
10.1021/ja00343a072
PDF
Book Reviews

pp 1405 - 1406; DOI:
10.1021/ja00343a600
PDF

Issue 6


Quantum and statistical mechanical studies of liquids. 25. Solvation and conformation of methanol in water
William L. Jorgensen and Jeffry D. Madura
pp 1407 - 1413; DOI:
10.1021/ja00344a001
PDF
Absorption spectra and photochemical rearrangements of toluene, cycloheptatriene, and norbornadiene cations to methylenecyclohexadiene cation in solid argon
Benuel J. Kelsall and Lester Andrews
pp 1413 - 1419; DOI:
10.1021/ja00344a002
PDF
La coupe du roi and its relevance to stereochemistry. Combination of two homochiral molecules to give an achiral product
Frank A. L. Anet, Steve S. Miura, Jay Siegel, and Kurt Mislow
pp 1419 - 1426; DOI:
10.1021/ja00344a003
PDF
Conformational dynamics of propane, di-tert-butylmethane, and bis(9-triptycyl)methane. An analysis of the symmetry of two threefold rotors on a rigid frame in terms of nonrigid molecular structure and energy hypersurfaces
Hans Beat Buergi, W. Douglas Hounshell, Robert B. Nachbar, and Kurt Mislow
pp 1427 - 1438; DOI:
10.1021/ja00344a004
PDF
Dynamic gearing and residual stereoisomerism in labeled bis(9-triptycyl)methane and related molecules. Synthesis and stereochemistry of bis(2,3-dimethyl-9-triptycyl)methane, bis(2,3-dimethyl-9-triptycyl)carbinol, and bis(1,4-dimethyl-9-triptycyl)methane
Alberto Guenzi, Constance A. Johnson, Franco Cozzi, and Kurt Mislow
pp 1438 - 1448; DOI:
10.1021/ja00344a005
PDF
Correlated rotation in bis(9-triptycyl)methanes and bis(9-triptycyl) ethers. Separation and interconversion of the phase isomers of labeled bevel gears
Yuzo Kawada and Hiizu Iwamura
pp 1449 - 1459; DOI:
10.1021/ja00344a006
PDF
MCSCF/CI investigation of the low-lying potential energy surfaces of the formyloxyl radical, HCO2.cntdot.
David Feller, Earl S. Huyser, Weston Thatcher Borden, and Ernest R. Davidson
pp 1459 - 1466; DOI:
10.1021/ja00344a007
PDF
Flash EXAFS for structural analysis of transient species: rapidly melting aluminum
H. M. Epstein, R. E. Schwerzel, P. J. Mallozzi, and B. E. Campbell
pp 1466 - 1468; DOI:
10.1021/ja00344a008
PDF
On the thickness of hydrophobic bilayers
P. Covello, M. E. Marcondes Helene, and L. W. Reeves
pp 1469 - 1473; DOI:
10.1021/ja00344a009
PDF
Electron-transfer reactions and associated conformational changes. Electrochemical reduction of some vicinal dibromides
Kathleen M. O'Connell and Dennis H. Evans
pp 1473 - 1481; DOI:
10.1021/ja00344a010
PDF
Carbon-13 nuclear magnetic relaxation in carbon-13 uniformly enriched glycine and aspartic acid
H. Nery, D. Canet, F. Toma, and S. Fermandjian
pp 1482 - 1486; DOI:
10.1021/ja00344a011
PDF
Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning
Dean W. Sindorf and Gary E. Maciel
pp 1487 - 1493; DOI:
10.1021/ja00344a012
PDF
Nonlinear fluorescence quenching and the origin of positive curvature in Stern-Volmer plots
Joel Keizer
pp 1494 - 1498; DOI:
10.1021/ja00344a013
PDF
Spin trapping of peroxy radicals by phenyl N-(tert-butyl) nitrone and methyl N-duryl nitrone
Etsuo Niki, Seiichi Yokoi, Jyunichi Tsuchiya, and Yoshio Kamiya
pp 1498 - 1503; DOI:
10.1021/ja00344a014
PDF
Reversible nitrogen-nitrogen bond homolysis in tetrakis(trifluoromethylthio)hydrazine at room temperature. Electron spin resonance, thermodynamic, and kinetic results
K. Schlosser and S. Steenken
pp 1504 - 1506; DOI:
10.1021/ja00344a015
PDF
Laser photodissociation of nitrogenous bases from pentacoordinated cobalt(II) porphyrins
Catherine Tetreau, Daniel Lavalette, and Michel Momenteau
pp 1506 - 1509; DOI:
10.1021/ja00344a016
PDF
Tandem mass spectrometry: structural and stereochemical information from steroids
Michael T. Cheng, Michael P. Barbalas, Robert F. Pegues, and Fred W. McLafferty
pp 1510 - 1513; DOI:
10.1021/ja00344a017
PDF
Intramolecular electron transfer in a series of mixed-valence copper(II)-copper(I) complexes
Russell C. Long and David N. Hendrickson
pp 1513 - 1521; DOI:
10.1021/ja00344a018
PDF
Mechanisms of ligand binding to pentacoordinate protoheme
John S. Olson, Russell E. McKinnie, Martha P. Mims, and Dabney K. White
pp 1522 - 1527; DOI:
10.1021/ja00344a019
PDF
Applications of molybdenum-95 NMR spectroscopy. 7. Studies of metal-metal bonded systems including aqueous molybdenum(IV) and molybdenum(V). Crystal and molecular structure of Na2[Mo3O4((O2CCH2)2NCH3)3].7H2O
Stephen F. Gheller, Trevor W. Hambley, Robert T. C. Brownlee, Maxwell J. O'Connor, Michael R. Snow, and Anthony G. Wedd
pp 1527 - 1532; DOI:
10.1021/ja00344a020
PDF
Cluster synthesis. 1. The use of sulfido ligands in the synthesis of high nuclearity transition metal cluster compounds. The synthesis and crystal and molecular structures of Os6(CO)17(.mu.4-S)2 and Os6(CO)16(.mu.4-S)(.mu.3-S)
Richard D. Adams, Istvan T. Horvath, and Li Wu Yang
pp 1533 - 1538; DOI:
10.1021/ja00344a021
PDF
Cofacial assembly of partially oxidized metallamacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Chemical and architectural properties of the "face-to-face" polymers [M(phthalocyaninato)O]n, where M = Si, Ge, and Sn
Carl W. Dirk, Tamotsu Inabe, Karl F. Schoch, and Tobin J. Marks
pp 1539 - 1550; DOI:
10.1021/ja00344a022
PDF
Cofacial assembly of partially oxidized metallamacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Chemical, structural, oxidation state, transport, magnetic, and optical properties of halogen-doped [M(phthalocyaninato)O]n macromolecules, where M = Si, Ge, and Sn
Bruce N. Diel, Tamotsu Inabe, Joseph W. Lyding, Karl F. Schoch, Carl R. Kannewurf, and Tobin J. Marks
pp 1551 - 1567; DOI:
10.1021/ja00344a023
PDF
Kinetic features of an intraresin reaction
Bong Kim, Piotr Kirszensztejn, Durgadas Bolikal, and Steven L. Regen
pp 1567 - 1571; DOI:
10.1021/ja00344a024
PDF
Magnetic field and magnetic isotope effects on photoinduced emulsion polymerization
Nicholas J. Turro, Ming Fea Chow, Chao Jen Chung, and Chen Ho Tung
pp 1572 - 1577; DOI:
10.1021/ja00344a025
PDF
Optically active amines. 31. Spectral observations on the substituted benzene chromophore
Howard E. Smith, Jon R. Neergaard, Tomas De Paulis, and Fu Ming Chen
pp 1578 - 1584; DOI:
10.1021/ja00344a026
PDF
Molecular structure of acetylacetone. A crystallographic determination
Arthur Camerman, Donald Mastropaolo, and Norman Camerman
pp 1584 - 1586; DOI:
10.1021/ja00344a027
PDF
A new approach to asymmetric synthesis of polycycles on the basis of o-quinodimethane generation
Yoshihiko Ito, Yusuke Amino, Masashi Nakatsuka, and Takeo Saegusa
pp 1586 - 1590; DOI:
10.1021/ja00344a028
PDF
Photoinduced reaction. 142. Intramolecular hydrogen abstraction from triplet states of 2,4,6-triisopropylbenzophenones: importance of hindered rotation in excited states
Yoshikatsu Ito, Hiroaki Nishimura, Yasutoshi Umehara, Yutaka Yamada, Mutsuto Tone, and Teruo Matsuura
pp 1590 - 1597; DOI:
10.1021/ja00344a029
PDF
Tris(dialkylamino)sulfonium enolates. Synthesis, structure, and reactions
R. Noyori, I. Nishida, and J. Sakata
pp 1598 - 1608; DOI:
10.1021/ja00344a030
PDF
An improved route to 4-demethoxydaunomycinone. A-Ring functionalization and resolution studies of tetracyclic precursors
Domingo Dominguez, Robert J. Ardecky, and Michael P. Cava
pp 1608 - 1613; DOI:
10.1021/ja00344a031
PDF
Cyclic phosphonic-carboxylic imides and anhydrides as reactive intermediates. 1. Rearrangement and solvolysis of N-(amino(methyl)phosphinyl)-L-phenylalanine derivatives
Neil E. Jacobsen and Paul A. Bartlett
pp 1613 - 1619; DOI:
10.1021/ja00344a032
PDF
Cyclic phosphonic-carboxylic imides and anhydrides as reactive intermediates. 2. Solvolysis of N-(hydroxy(methyl)phosphinothioyl)-L-phenylalanine derivatives
Neil E. Jacobsen and Paul A. Bartlett
pp 1619 - 1626; DOI:
10.1021/ja00344a033
PDF
Thermal sigmatropic rearrangements of vinylallenes leading to 11-cis-retinoids and the novel properties of 9-cis,11-cis,13-cis-retinal and 11-cis,13-cis-retinal
Christopher G. Knudsen, Roshantha A. S. Chandraratna, Leslie P. Walkeapaa, Yeshpal S. Chauhan, Stephen C. Carey, Thomas M. Cooper, Robert R. Birge, and William H. Okamura
pp 1626 - 1631; DOI:
10.1021/ja00344a034
PDF
A cyclic phosphate: base and metal acetate catalyzed ring opening
William G. Wadsworth and William S. Wadsworth
pp 1631 - 1637; DOI:
10.1021/ja00344a035
PDF
Metal-ion catalysis of anhydride hydrolysis. Metal-ion-promoted water- and hydroxide-ion-catalyzed reactions of mixed cinnamic acid anhydrides
Thomas H. Fife and Theodore J. Przystas
pp 1638 - 1642; DOI:
10.1021/ja00344a036
PDF
Equilibration of 1-octanol with alcohol dehydrogenase. Evidence for horse liver alcohol dehydrogenase responsibility for exchange of the 1-pro-S hydrogen atom
Stuart Shapiro, Thangavel Arunachalam, and Eliahu Caspi
pp 1642 - 1646; DOI:
10.1021/ja00344a037
PDF
Oxygen-18 isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. 7. Hydrolysis of 2,2-dimethyloxirane in dilute acid and by microsomal epoxide hydratase
John M. Risley, Fengjiun Kuo, and Robert L. Van Etten
pp 1647 - 1652; DOI:
10.1021/ja00344a038
PDF
Sequential assignments for the hydrogen and phosphorus-31 atoms in the backbone of oligonucleotides by two-dimensional nuclear magnetic resonance
Arthur Pardi, Roger Walker, Henry Rapoport, Gerhard Wider, and Kurt Wuethrich
pp 1652 - 1653; DOI:
10.1021/ja00344a039
PDF
Tandem mass spectrometry of higher molecular weight compounds
I. J. Amster, M. A. Baldwin, M. T. Cheng, C. J. Proctor, and F. W. McLafferty
pp 1654 - 1655; DOI:
10.1021/ja00344a040
PDF
An unsymmetrically substituted diphosphene: NMR spectroscopic data pertinent to the phosphorus-phosphorus double bond
A. H. Cowley, J. E. Kilduff, M. Pakulski, and C. A. Stewart
pp 1655 - 1656; DOI:
10.1021/ja00344a041
PDF
Toward tricyclo[2.2.2.2]decane. 1. [n.2.2.2]Paddlane systems, n = 10-14
Philip E. Eaton and Bernard D. Leipzig
pp 1656 - 1658; DOI:
10.1021/ja00344a042
PDF
Photoreduction of keto carboxylic acid derivatives to oxyacid derivatives catalyzed by ZnTPPS[zinc tetraphenylporphyrintetrasulfonate]-quinolinium-3-carboxamide-CTAB micelle
Iwao Tabushi, Shinichi Kugimiya, and Tadashi Mizutani
pp 1658 - 1659; DOI:
10.1021/ja00344a043
PDF
Stereocontrolled synthesis of a cis-carbapenem antibiotic (-)-carpetimycin A
Takamasa Iimori, Yoshio Takahashi, Toshio Izawa, Susumu Kobayashi, and Masaji Ohno
pp 1659 - 1660; DOI:
10.1021/ja00344a044
PDF
Titanium-induced cyclization of keto esters: a new method of cycloalkanone synthesis
John E. McMurry and Dennis D. Miller
pp 1660 - 1661; DOI:
10.1021/ja00344a045
PDF
Rotational excitation in the carbon monoxide product of ketene photodissociation
Robert N. Rosenfeld and Blake I. Sonobe
pp 1661 - 1662; DOI:
10.1021/ja00344a046
PDF
Total synthesis of the major human urinary metabolite of prostaglandin D2, a key diagnostic indicator
E. J. Corey and Katsuichi Shimoji
pp 1662 - 1664; DOI:
10.1021/ja00344a047
PDF
Synthetic applications of titanocene methylene complexes: selective formation of ketone enolates and their reactions
John R. Stille and Robert H. Grubbs
pp 1664 - 1665; DOI:
10.1021/ja00344a048
PDF
Aryl isomerization during aliphatic carbon-hydrogen bond activation
Linda R. Chamberlain and Ian P. Rothwell
pp 1665 - 1666; DOI:
10.1021/ja00344a049
PDF
Acyclic stereoselection. 16. High diastereofacial selectivity in Lewis acid mediated additions of enol silanes to chiral aldehydes
Clayton H. Heathcock and Lee A. Flippin
pp 1667 - 1668; DOI:
10.1021/ja00344a050
PDF
Convenient direct synthesis of (SN)x films from S4N4 at lower temperatures
M. W. R. Witt, R. J. Lagow, and W. I. Bailey
pp 1668 - 1669; DOI:
10.1021/ja00344a051
PDF
Host recognition in parasitic angiosperms: use of correlation spectroscopy to identify long-range coupling in an haustorial inducer
John C. Steffens, James L. Roark, David G. Lynn, and James L. Riopel
pp 1669 - 1671; DOI:
10.1021/ja00344a052
PDF
Evidence for a silylenium ion in solution
Joseph B. Lambert and William J. Schulz
pp 1671 - 1672; DOI:
10.1021/ja00344a053
PDF
Crystal structure and solid-state reactivity of 4,4'-methylenediphenyl isocyanate (MDI)
Roxy B. Wilson, Yue Shen Chen, Iain C. Paul, and David Y. Curtin
pp 1672 - 1674; DOI:
10.1021/ja00344a054
PDF
Isolation and characterization of two new bacteriochlorophylls d bearing neopentyl substituents
Kevin M. Smith, Dane A. Goff, Jack Fajer, and Kathleen M. Barkigia
pp 1674 - 1676; DOI:
10.1021/ja00344a055
PDF
Synthesis, structure, and photochemistry of tetracarbonyl(fulvalene)diruthenium. Thermally reversible photoisomerization involving carbon-carbon bond activation at a dimetal center
K. Peter C. Vollhardt and Timothy W. Weidman
pp 1676 - 1677; DOI:
10.1021/ja00344a056
PDF
Phosphine ligands for the construction of polynuclear complexes. I. Bis(diphenylphosphinomethyl)phenylphosphine complexes of palladium(II) and rhodium(I)
Rosalvina R. Guimerans, Marilyn M. Olmstead, and Alan L. Balch
pp 1677 - 1679; DOI:
10.1021/ja00344a057
PDF
Preparation and reactivity of a dimeric ruthenium .mu.-methylene complex with no metal-metal bond: crystal and molecular structure of [(.eta.5-C5H5)Ru(CO)2]2(.mu.-CH2)
Y. C. Lin, J. C. Calabrese, and S. S. Wreford
pp 1679 - 1680; DOI:
10.1021/ja00344a058
PDF
Preparation and properties of molybdenum and tungsten dinitrogen complexes. 18. Preparation and characterization of novel .mu.3-dinitrogen mixed metal complexes
Tamotsu Takahashi, Teruyuki Kodama, Atsushi Watakabe, Yasuzo Uchida, and Masanobu Hidai
pp 1680 - 1682; DOI:
10.1021/ja00344a059
PDF
Unique high-spin-low-spin transition of the central ion in a linear, trinuclear iron(II) triazole compound
Ger Vos, Rob A. Le Febre, Rudolf A. G. De Graaff, Jaap G. Haasnoot, and Jan Reedijk
pp 1682 - 1683; DOI:
10.1021/ja00344a060
PDF
2,2-Dimethylpropanethial: a long-lived aliphatic thioaldehyde
E. Vedejs and D. A. Perry
pp 1683 - 1684; DOI:
10.1021/ja00344a061
PDF
Detection of a tetrahedral adduct in a trypsin-chloromethyl ketone specific inhibitor complex by carbon-13 NMR
J. Paul G. Malthouse, Neil E. Mackenzie, Alan S. F. Boyd, and A. Ian Scott
pp 1685 - 1686; DOI:
10.1021/ja00344a062
PDF
Stereospecific synthesis of racemic daunosamine. Diastereofacial selectivity in a nitrone cycloaddition
Philip DeShong and Joseph M. Leginus
pp 1686 - 1688; DOI:
10.1021/ja00344a063
PDF
Mechanistic studies of unimolecular ionic decompositions by deuterium and heavy-atom isotope effects. Concerted elimination of acetaldehyde from the benzyl ethyl ether radical cation
D. Stone, John Bowie, D. Underwood, K. Donchi, C. Allison, and P. Derrick
pp 1688 - 1689; DOI:
10.1021/ja00344a064
PDF
Highly reduced organometallics. 13. Synthesis and chemistry of the tricarbonylnitrosylmanganate(2-) ion, Mn(CO)3NO2-
Yu Sen Chen and John E. Ellis
pp 1689 - 1690; DOI:
10.1021/ja00344a065
PDF
Genesis, bonding mode and reaction with carbon monoxide of an oxymethylene unit bridging two metal atoms
S. Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
pp 1690 - 1691; DOI:
10.1021/ja00344a066
PDF
Evidence for a perepoxide intermediate in the 1,2-cycloaddition of singlet oxygen to adamantylideneadamantane: nucleophilic oxygen atom transfer to sulfoxides
A. Paul Schaap, Scott G. Recher, Gary R. Faler, and Steven R. Villasenor
pp 1691 - 1693; DOI:
10.1021/ja00344a067
PDF
Rearrangement of 4,4-diarylcyclohexadienones induced by attack of methyl metaphosphate at the carbonyl group
Kim C. Calvo, J. David Rozzell, and F. H. Westheimer
pp 1693 - 1694; DOI:
10.1021/ja00344a068
PDF
Intramolecular general base-acid catalysis in transaminations catalyzed by pyridoxamine enzyme analogs
Steven C. Zimmerman, Anthony W. Czarnik, and Ronald Breslow
pp 1694 - 1695; DOI:
10.1021/ja00344a069
PDF
Carbenes and the oxygen-hydrogen bond: 3-cyclopentenylidene. A novel approach to bis(homocyclopropenyl) cations
Wolfgang Kirmse, Van Chiem Pham, and Paul G. Henning
pp 1695 - 1696; DOI:
10.1021/ja00344a070
PDF
Total synthesis of (.+-.)-chaenorhine
Harry H. Wasserman, Ralph P. Robinson, and Charles G. Carter
pp 1697 - 1698; DOI:
10.1021/ja00344a071
PDF
Argon-matrix isolation of bis(trifluoromethyl)oxirene, perfluoromethylethyloxirene, and their isomeric ketocarbenes
M. Torres, J. L. Bourdelande, A. Clement, and O. P. Strausz
pp 1698 - 1700; DOI:
10.1021/ja00344a072
PDF
Heavy-atom tunneling as the dominant pathway in a solution-phase reaction? Bond shift in antiaromatic annulenes
Barry K. Carpenter
pp 1700 - 1701; DOI:
10.1021/ja00344a073
PDF
Novel reaction of metal-metal triple-bonded complexes and nitro compounds. Decarbonylation and the formation of high oxidation state molybdenum and tungsten complexes bearing bridging and terminal oxygen ligands
Howard Alper, Anthony C. Willis, Jean Francois Petrignani, and Frederick W. B. Einstein
pp 1701 - 1702; DOI:
10.1021/ja00344a074
PDF
Book Reviews

pp 1703 - 1704; DOI:
10.1021/ja00344a600
PDF

Issue 7


Theoretical study of thieno[3,4-c]thiophene, a nonclassical thiophene system
Kenneth J. Miller, Karl F. Moschner, and Kevin T. Potts
pp 1705 - 1712; DOI:
10.1021/ja00345a001
PDF
Theoretical study of the allyl radical: structure and vibrational analysis
T. Takada and M. Dupuis
pp 1713 - 1716; DOI:
10.1021/ja00345a002
PDF
Treatment of electrostatic effects within the molecular-mechanics method. 1
Ljiljana Dosen-Micovic, Dragoslav Jeremic, and Norman L. Allinger
pp 1716 - 1722; DOI:
10.1021/ja00345a003
PDF
Treatment of electrostatic effects within the molecular-mechanics method. 2
Ljiljana Dosen-Micovic, Dragoslav Jeremic, and Norman L. Allinger
pp 1723 - 1733; DOI:
10.1021/ja00345a004
PDF
Nuclear quadrupole interaction of excited nuclear state (19F*, I = 5/2) of fluorine in fluorobenzenes
K. Bonde Nielsen, B. Toft, K. C. Mishra, S. K. Mishra, K. J. Duff, and T. P. Das
pp 1734 - 1737; DOI:
10.1021/ja00345a005
PDF
Excited electronic states of optically active substituted ethylene oxides: (-)-(S)-2-methyloxirane and (-)-(S,S)-2,3-dimethyloxirane
D. Cohen, M. Levi, Harold Basch, and A. Gedanken
pp 1738 - 1742; DOI:
10.1021/ja00345a006
PDF
Unusual low-energy isomers of the ethanol and dimethyl ether radical cations
Willem J. Bouma, Ross H. Nobes, and Leo Radom
pp 1743 - 1746; DOI:
10.1021/ja00345a007
PDF
Theoretical aspects of the photochemistry of methanol, methylamine, and related materials
E. Kassab, J. T. Gleghorn, and E. M. Evleth
pp 1746 - 1753; DOI:
10.1021/ja00345a008
PDF
A theoretical study on the photochemical transposition reaction of oxazole
Hidetsugu Tanaka, Toshio Matsushita, and Kichisuke Nishimoto
pp 1753 - 1760; DOI:
10.1021/ja00345a009
PDF
Cyclic D6h hexaazabenzene - a relative minimum on the hexaazabenzene potential energy hypersurface?
Paul Saxe and Henry F. Schaefer
pp 1760 - 1764; DOI:
10.1021/ja00345a010
PDF
MNDO study of the mechanism of oxygen (O2(1.DELTA.)) formation by reaction of chlorine with basic hydrogen peroxide
Donn M. Storch, Chester J. Dymek, and Larry P. Davis
pp 1765 - 1769; DOI:
10.1021/ja00345a011
PDF
Hartree-Fock calculations on negative ion states of chromium hexacarbonyl
L. G. Vanquickenborne and J. Verhulst
pp 1769 - 1772; DOI:
10.1021/ja00345a012
PDF
Structural consequences of electron transfer reactions. 8. Elucidation of isomerization mechanism of the radical anion of (.eta.4-cyclooctatetraene)cyclopentadienylcobalt with FFT-Faradaic admittance measurements
Maria Grzeszczuk, Donald E. Smith, and William E. Geiger
pp 1772 - 1776; DOI:
10.1021/ja00345a013
PDF
Solar energy conversion through ligand photodissociation
Brian M. Hoffman and Paul D. Sima
pp 1776 - 1778; DOI:
10.1021/ja00345a014
PDF
Thermodynamics of homoantiaromaticity and homoaromaticity: homo[8]annulene and its dianion
Rosario Concepcion, Richard C. Reiter, and Gerald R. Stevenson
pp 1778 - 1782; DOI:
10.1021/ja00345a015
PDF
Selective M+-H+ coupled transport of cations through a liquid membrane by macrocyclic calixarene ligands
Reed M. Izatt, John D. Lamb, Richard T. Hawkins, Philip R. Brown, Steven R. Izatt, and James J. Christensen
pp 1782 - 1785; DOI:
10.1021/ja00345a016
PDF
Cation fluxes from binary Ag+-Mn+ mixtures in a water-trichloromethane-water liquid membrane system containing a series of macrocyclic ligand carriers
Reed M. Izatt, David V. Dearden, Philip R. Brown, Jerald S. Bradshaw, John D. Lamb, and James J. Christensen
pp 1785 - 1790; DOI:
10.1021/ja00345a017
PDF
Ab initio study of m-benzoquinodimethane
Shigeki Kato, Keiji Morokuma, David Feller, Ernest R. Davidson, and Weston Thatcher Borden
pp 1791 - 1795; DOI:
10.1021/ja00345a018
PDF
Luminescent iridium(I), rhodium(I), and platinum(II) dithiolate complexes
Curtis E. Johnson, Richard Eisenberg, Ted R. Evans, and Mitch S. Burberry
pp 1795 - 1802; DOI:
10.1021/ja00345a019
PDF
Vibrational spectroscopy of the electrode-solution interface. 2. Use of Fourier transform spectroscopy for recording infrared spectra of radical ion intermediates
Stanley Pons, T. Davidson, and A. Bewick
pp 1802 - 1805; DOI:
10.1021/ja00345a020
PDF
Electrochemical stability of catechols with a pyrene side chain strongly adsorbed on graphite electrodes for catalytic oxidation of dihydronicotinamide adenine dinucleotide
Hans Jaegfeldt, Theodore Kuwana, and Gillis Johansson
pp 1805 - 1814; DOI:
10.1021/ja00345a021
PDF
Solvation of hydrogen ions in mixed water-alcohol ion clusters
A. J. Stace and C. Moore
pp 1814 - 1819; DOI:
10.1021/ja00345a022
PDF
Picosecond emission spectroscopy of two predissociative isomeric methylenepyrazolines and product trimethylenemethane
D. F. Kelley and P. M. Rentzepis
pp 1820 - 1824; DOI:
10.1021/ja00345a023
PDF
Photoelectron-photoion coincidence spectroscopy as a sensitive probe for RRKM calculations: are the lowest energy fragmentation pathways of 1,3-butadiene cation in effective competition?
Rolf Bombach, Josef Dannacher, and Jean Pierre Stadelmann
pp 1824 - 1829; DOI:
10.1021/ja00345a024
PDF
Resonance Raman spectra of the nitrogen-bridged iron porphyrin dimer, (.mu.-nitrido)bis[(5,10,15,20-tetraphenylporphinato)iron]
G. Alan Schick and David F. Bocian
pp 1830 - 1838; DOI:
10.1021/ja00345a025
PDF
Chiroptical studies of labile or difficult-to-resolve molecules generated by chiral laser photochemistry. 2. Products and steric course of the phototransformation of the racemate
Maurizio Zandomeneghi, Marino Cavazza, Crescenzo Festa, and Francesco Pietra
pp 1839 - 1843; DOI:
10.1021/ja00345a026
PDF
Infrared photochemistry of bicyclopropyl
William E. Farneth and Marcus W. Thomsen
pp 1843 - 1848; DOI:
10.1021/ja00345a027
PDF
Carbon-13 CP/MAS NMR study of molecular motion in n-alkylsilane bonded to the silica surface
Dean W. Sindorf and Gary E. Maciel
pp 1848 - 1851; DOI:
10.1021/ja00345a028
PDF
Photoresponsive crown ethers. 8. Azobenzenophane-type switched-on crown ethers which exhibit an all-or-nothing change in ion-binding ability
Seiji Shinkai, Takahide Minami, Yumiko Kusano, and Osamu Manabe
pp 1851 - 1856; DOI:
10.1021/ja00345a029
PDF
Temperature dependence of the photochemistry of aryl alkyl ketones
M. V. Encina, E. A. Lissi, Else Lemp, A. Zanocco, and J. C. Scaiano
pp 1856 - 1860; DOI:
10.1021/ja00345a030
PDF
Micellar systems as supercages for reactions of geminate radical pairs. Magnetic effects
Nicholas J. Turro and Gregory C. Weed
pp 1861 - 1868; DOI:
10.1021/ja00345a031
PDF
Magnetic circular dichroism determination of zero-field splitting in chloro(meso-tetraphenylporphinato)iron(III)
W. R. Browett, A. F. Fucaloro, T. V. Morgan, and P. J. Stephens
pp 1868 - 1872; DOI:
10.1021/ja00345a032
PDF
Potassium-39 NMR study of the complexation kinetics of potassium(+) ion by 18-crown-6 in some nonaqueous solvents
Emmanuel Schmidt and Alexander I. Popov
pp 1873 - 1878; DOI:
10.1021/ja00345a033
PDF
Spectroscopic, electrochemical, and photochemical properties of molybdenum(II) and tungsten(II) halide clusters
Andrew W. Maverick, Jan S. Najdzionek, Douglas MacKenzie, Daniel G. Nocera, and Harry B. Gray
pp 1878 - 1882; DOI:
10.1021/ja00345a034
PDF
Stereochemical and electronic control of M-SO2 bonding geometry in d6 molybdenum and tungsten sulfur dioxide complexes: novel .eta.1 .tautm. .eta.2 sulfur dioxide linkage isomerization in Mo(CO)2(PPh3)2(CNR)(SO2) and structures of Mo(CO)3(P-iso-Pr3)2(SO2) and [Mo(CO)2(py)(PPh3)(.mu.-SO2)]2
Gregory J. Kubas, Gordon D. Jarvinen, and Robert R. Ryan
pp 1883 - 1891; DOI:
10.1021/ja00345a035
PDF
Active site of allantoic purple acid phosphatase and a model complex for strongly coupled diiron sites
Garry M. Mockler, John De Jersey, Burt Zerner, Charles J. O'Connor, and Ekk Sinn
pp 1891 - 1893; DOI:
10.1021/ja00345a036
PDF
Paramagnetic organometallic molecules. 13. Electron-transfer-catalyzed reactions of polynuclear metal carbonyls: reactions of R2C2Co2 (CO)6
Malini Arewgoda, Brian H. Robinson, and Jim Simpson
pp 1893 - 1903; DOI:
10.1021/ja00345a037
PDF
Electrochemical reduction of the gold cluster Au9(PPh3)83+. Evidence for an ErErCr mechanism. Formation of the paramagnetic gold cluster Au9(PPh3)82+
J. G. M. Van der Linden, M. L. H. Paulissen, and J. E. J. Schmitz
pp 1903 - 1907; DOI:
10.1021/ja00345a038
PDF
Cobalt metallacycles. 11. On the transformation of bis(acetylene)cobalt to cobaltacyclopentadiene
Yasuo Wakatsuki, Okio Nomura, Kazuo Kitaura, Keiji Morokuma, and Hiroshi Yamazaki
pp 1907 - 1912; DOI:
10.1021/ja00345a039
PDF
Dissociation and dioxygen formation in hydroxide solutions of tris(2,2'-bipyridyl)iron(III) and tris(1,10-phenanthroline)iron(III): rates and stoichiometry
G. Nord, B. Pedersen, and E. Bjergbakke
pp 1913 - 1919; DOI:
10.1021/ja00345a040
PDF
An x-ray absorption study of the binuclear iron center in deoxyhemerythrin
W. Timothy Elam, Edward A. Stern, John D. McCallum, and Joann Sanders-Loehr
pp 1919 - 1923; DOI:
10.1021/ja00345a041
PDF
Nature of the continuous high-spin (5T2) .dblharw. low-spin (1A1) transition in solid (dithiocyanato)bis(2,2'-bi(5-methyl-2-thiazoline))iron(II). Anomalous behavior of total effective thickness, quadrupole splitting, line widths, and lattice spacings employing Moessbauer effect and x-ray diffraction
E. Koenig, G. Ritter, S. K. Kulshreshtha, and S. M. Nelson
pp 1924 - 1929; DOI:
10.1021/ja00345a042
PDF
Use of kinetic isotope effects in mechanism studies. 4. Chlorine isotope effects associated with alkoxide-promoted dehydrochlorination reactions
Heinz F. Koch, Duncan J. McLennan, Judith G. Koch, William Tumas, Brian Dobson, and Nanci H. Koch
pp 1930 - 1937; DOI:
10.1021/ja00345a043
PDF
Kinetic study for spin-trapping reactions of thiyl radicals with nitroso compounds
Osamu Ito and Minoru Matsuda
pp 1937 - 1940; DOI:
10.1021/ja00345a044
PDF
Mechanistic investigation of the copper-catalyzed reactions of diphenyliodonium salts
Thomas P. Lockhart
pp 1940 - 1946; DOI:
10.1021/ja00345a045
PDF
.beta.-Deuterium and .beta.-tritium isotope effects on the distribution coefficient of carbonyl compounds for transfer from water to cyclohexane or chlorocyclohexane
Ildiko M. Kovach and Daniel M. Quinn
pp 1947 - 1950; DOI:
10.1021/ja00345a046
PDF
Simultaneous occurrence of solvent reorganization and heavy-atom reorganization in a transmethylation transition state
Osborne S. L. Wong and Richard L. Schowen
pp 1951 - 1954; DOI:
10.1021/ja00345a047
PDF
Competition between modes of solvolytic participation in 3-cyclopentenyl tosylate
Joseph B. Lambert and Rodney B. Finzel
pp 1954 - 1958; DOI:
10.1021/ja00345a048
PDF
Photochemical reactions of .alpha.-oxo amides. Norrish type II reactions via zwitterionic intermediates
Hiromu Aoyama, Masami Sakamoto, Keiko Kuwabara, Katsuhiko Yoshida, and Yoshimori Omote
pp 1958 - 1964; DOI:
10.1021/ja00345a049
PDF
Alkoxides as nucleophiles in (.pi.-allyl)palladium chemistry. Synthetic and mechanistic studies
Susan A. Stanton, Steven W. Felman, Carol S. Parkhurst, and Stephen A. Godleski
pp 1964 - 1969; DOI:
10.1021/ja00345a050
PDF
Hydrogen abstraction from amines: formation of aminyl vs. .alpha.-aminoalkyl radicals
A. S. Nazran and D. Griller
pp 1970 - 1971; DOI:
10.1021/ja00345a051
PDF
Ozonization of cholesterol
Jerzy Gumulka and Leland L. Smith
pp 1972 - 1979; DOI:
10.1021/ja00345a052
PDF
Topological charge stabilization
Benjamin M. Gimarc
pp 1979 - 1984; DOI:
10.1021/ja00345a053
PDF
Successive displacements of phenoxy by methoxy groups in triphenyl phosphite ozonide: mechanism of the accelerated singlet oxygen formation with pyridine and methanol
Paul D. Bartlett and Charles M. Lonzetta
pp 1984 - 1988; DOI:
10.1021/ja00345a054
PDF
The total synthesis of ionophore antibiotics. A convergent synthesis of lasalocid A (X537A)
Robert E. Ireland, Robert C. Anderson, Raphael Badoud, Brian J. Fitzsimmons, Glenn J. McGarvey, Suvit Thaisrivongs, and Craig S. Wilcox
pp 1988 - 2006; DOI:
10.1021/ja00345a055
PDF
Silacyclobutene synthesis via intramolecular cyclization of unsaturated silylenes
Gary T. Burns and Thomas J. Barton
pp 2006 - 2009; DOI:
10.1021/ja00345a056
PDF
Asymmetric synthesis of threonine and partial resolution and retroracemization of .alpha.-amino acids via copper(II) complexes of their Schiff bases with (S)-2-N-(N'-benzylprolyl)aminobenzaldehyde and (S)-2-N-(N'-benzylprolyl)aminoacetophenone. Crystal and molecular structure of a copper(II) complex of glycine Schiff base with (S)-2-N-(N'-benzylprolyl)aminoacetophenone
Yu. N. Belokon, I. E. Zel'tser, V. I. Bakhmutov, M. B. Saporovskaya, M. G. Ryzhov, A. I. Yanovskii, Yu. T. Struchkov, and V. M. Belikov
pp 2010 - 2017; DOI:
10.1021/ja00345a057
PDF
Selective syntheses using cyclodextrin as catalyst. 1. Control of orientation in the attack of dichlorocarbene at phenolates
Makoto Komiyama and Hidefumi Hirai
pp 2018 - 2021; DOI:
10.1021/ja00345a058
PDF
Short syntheses of furan and catechol derivatives. A synthesis of hydrourushiol
Ernest Wenkert, Miguel E. Alonso, Brian L. Buckwalter, and Eduardo L. Sanchez
pp 2021 - 2029; DOI:
10.1021/ja00345a059
PDF
Direct stereocontrolled synthesis of isocomene
Ernest Wenkert and Thomas S. Arrhenius
pp 2030 - 2033; DOI:
10.1021/ja00345a060
PDF
Synthesis of racemic frenolicin via organochromium and organopalladium intermediates
M. F. Semmelhack and A. Zask
pp 2034 - 2043; DOI:
10.1021/ja00345a061
PDF
Cyclic orthoester functions as new protecting groups in nucleosides
Mitsuo Sekine and Tsujiaki Hata
pp 2044 - 2049; DOI:
10.1021/ja00345a062
PDF
Studies of tautomers and protonation of adenine and its derivatives by nitrogen-15 nuclear magnetic resonance spectroscopy
Nina C. Gonnella, Hiroshi Nakanishi, Joseph B. Holtwick, David S. Horowitz, Keiko Kanamori, Nelson J. Leonard, and John D. Roberts
pp 2050 - 2055; DOI:
10.1021/ja00345a063
PDF
Estimation of the energy barrier to syn-anti interconversion in a pyrimidine nucleotide: ultrasonic investigation of syn-anti glycosyl isomerization in cytidine cyclic 2',3'-monophosphate with bound ethidium bromide
Frank Jordan, Paul Hemmes, Sadakatsu Nishikawa, and Mitsuo Mashima
pp 2055 - 2058; DOI:
10.1021/ja00345a064
PDF
Full structure of a mitomycin C dinucleoside phosphate adduct. Use of differential FT-IR spectroscopy in microscale structural studies
Maria Tomasz, Roselyn Lipman, John K. Snyder, and Koji Nakanishi
pp 2059 - 2063; DOI:
10.1021/ja00345a065
PDF
A catechol receptor model by macrocyclic polyamines
Eiichi Kimura, Asuka Watanabe, and Mutsuo Kodama
pp 2063 - 2066; DOI:
10.1021/ja00345a066
PDF
Coordination chemistry and catalytic properties of hydrido(phosphine)ruthenate complexes
Robert Wilczynski, William A. Fordyce, and Jack Halpern
pp 2066 - 2068; DOI:
10.1021/ja00345a067
PDF
Synthesis and structure of ketene complexes of permethylzirconocene and their hydrogenation to zirconium enolate hydrides
Eric J. Moore, Daniel A. Straus, Justine Armantrout, Bernard D. Santarsiero, Robert H. Grubbs, and John E. Bercaw
pp 2068 - 2070; DOI:
10.1021/ja00345a068
PDF
Standard enthalpies of sublimation and vaporization of 1,4,8,11-tetraazacyclotetradecane and 1,4,8,11-tetraazaundecane. Gas-phase macrocyclic enthalpy
R. M. Clay, S. Corr, G. Keenan, and W. V. Steele
pp 2070 - 2071; DOI:
10.1021/ja00345a069
PDF
Tropocoronands, a new class of metal-complexing macrocycles derived from aminotroponeiminates
Seichi Imajo, Koji Nakanishi, Michael Roberts, Stephen J. Lippard, and Tetsuo Nozoe
pp 2071 - 2073; DOI:
10.1021/ja00345a070
PDF
Activation and transfer of nitrogen from a nitridomanganese(V) porphyrin complex. Aza analog of epoxidation
John T. Groves and Tadashi Takahashi
pp 2073 - 2074; DOI:
10.1021/ja00345a071
PDF
Ring methyl to phosphorus hydrogen shifts in pentamethylcyclopentadienyl-substituted phosphorus cations: parallel between main-group and transition-metal chemistry
A. H. Cowley and S. K. Mehrotra
pp 2074 - 2075; DOI:
10.1021/ja00345a072
PDF
.beta.-Hydrogen effects in alkylalkoxides of dimolybdenum (M.tplbond.M)
Malcolm H. Chisholm, John C. Huffman, and Robert J. Tatz
pp 2075 - 2077; DOI:
10.1021/ja00345a073
PDF
Boronic ester homologation with 99% chiral selectivity and its use in syntheses of the insect pheromones (3S,4S)-4-methyl-3-heptanol and exo-brevicomin
Donald S. Matteson and Kizhakethil M. Sadhu
pp 2077 - 2078; DOI:
10.1021/ja00345a074
PDF
Light-induced reversible pH change
Masahiro Irie
pp 2078 - 2079; DOI:
10.1021/ja00345a075
PDF
Organotransition metal metallacarboranes. 3. The .eta.8 coordination of planar C8H82- to vanadium. Structural characterization of (.eta.8-C8H8)V(Et2C2B4H4)
Robert G. Swisher, Ekk Sinn, Greg A. Brewer, and Russell N. Grimes
pp 2079 - 2080; DOI:
10.1021/ja00345a076
PDF
Dipole-stabilized carbanions: evidence for a complex in the .alpha.'-lithiation of N,N-dimethyl-2,4,6-triisopropylbenzamide
Munther Al-Aseer, Peter Beak, David Hay, Dale J. Kempf, Sander Mills, and Stanley G. Smith
pp 2080 - 2082; DOI:
10.1021/ja00345a077
PDF
Initial complex and the role of solvent in metalations leading to dipole-stabilized anions
A. I. Meyers, William F. Rieker, and Lelia M. Fuentes
pp 2082 - 2083; DOI:
10.1021/ja00345a078
PDF
Tetralithiotetrahedrane: is it a minimum?
James P. Ritchie
pp 2083 - 2085; DOI:
10.1021/ja00345a079
PDF
Simple one-step route to a transition-metal complex containing a phosphorus-phosphorus double bond. Synthesis and x-ray crystal structure of {trans-bis[bis(trimethylsilyl)methyl]diphosphene}bis[tetracarbonyliron(0)]
Kathy M. Flynn, Marilyn M. Olmstead, and Philip P. Power
pp 2085 - 2086; DOI:
10.1021/ja00345a080
PDF
Synthesis of (.+-.)-kopsanone and (.+-.)-10,22-dioxokopsane, hetacyclic indole alkaloids
Timothy Gallagher and Philip Magnus
pp 2086 - 2087; DOI:
10.1021/ja00345a081
PDF
Asymmetric synthesis via acetal templates. 3. On the stereochemistry observed in the cyclization of chiral acetals of polyolefinic aldehydes; formation of optically active homoallylic alcohols
Paul A. Bartlett, William S. Johnson, and John D. Elliott
pp 2088 - 2089; DOI:
10.1021/ja00345a082
PDF
Simplest magnesium cluster Grignard. Theoretical evidence for strong metal-metal stabilization of RMg2X species
Paul G. Jasien and Clifford E. Dykstra
pp 2089 - 2090; DOI:
10.1021/ja00345a083
PDF
Gas-phase hydrolysis of phenyl acetate and phenyl benzoate by superoxide ion
Carolyn L. Johlman, Robert L. White, Donald T. Sawyer, and Charles L. Wilkins
pp 2091 - 2092; DOI:
10.1021/ja00345a084
PDF
Asymmetric carbon-carbon bond formation via .beta.-allyldiisopinocampheylborane. Simple synthesis of secondary homoallylic alcohols with excellent enantiomeric purities
Herbert C. Brown and Prabhakar K. Jadhav
pp 2092 - 2093; DOI:
10.1021/ja00345a085
PDF
Book Reviews

pp 2094 - 2098; DOI:
10.1021/ja00345a600
PDF

Issue 8


Assignment of hyperfine-shifted resonances in low-spin forms of cytochrome c peroxidase by reconstitutions with deuterated hemins
James D. Satterlee, James E. Erman, Gerd N. LaMar, Kevin M. Smith, and Kevin C. Langry
pp 2099 - 2104; DOI:
10.1021/ja00346a001
PDF
Multinuclear NMR study of the solvated electron in lithium-methylamine solutions
Dolores M. Holton, Peter P. Edwards, William McFarlane, and Brian Wood
pp 2104 - 2108; DOI:
10.1021/ja00346a002
PDF
Multiphoton ionization mass spectrometric studies of a bichromophoric molecule: 3-phenyl-1-(dimethylamino)propane
D. A. Lichtin, D. W. Squire, M. A. Winnik, and R. B. Bernstein
pp 2109 - 2117; DOI:
10.1021/ja00346a003
PDF
Nuclear magnetic resonance studies of inversion and diketonate R-group exchange in dialkoxybis(.beta.-diketonato)titanium(IV) complexes. Evidence for a twist mechanism
Robert C. Fay and Alan F. Lindmark
pp 2118 - 2127; DOI:
10.1021/ja00346a004
PDF
Crystal structure and solid-state NMR analysis of lactulose
G. A. Jeffrey, Richard A. Wood, Philip E. Pfeffer, and Kevin B. Hicks
pp 2128 - 2133; DOI:
10.1021/ja00346a005
PDF
Cross polarization and magic angle sample spinning NMR spectra of model organic compounds. 1. Highly protonated molecules
Lawrence B. Alemany, David M. Grant, Ronald J. Pugmire, Terry D. Alger, and Kurt W. Zilm
pp 2133 - 2141; DOI:
10.1021/ja00346a006
PDF
Cross polarization and magic angle sample spinning NMR spectra of model organic compounds. 2. Molecules of low or remote protonation
Lawrence B. Alemany, David M. Grant, Ronald J. Pugmire, Terry D. Alger, and Kurt W. Zilm
pp 2142 - 2147; DOI:
10.1021/ja00346a007
PDF
Metal-nitroxyl interactions. 30. Single-crystal EPR spectra of two spin-labeled copper porphyrins
Reddy Damoder, Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 2147 - 2154; DOI:
10.1021/ja00346a008
PDF
Intermolecular motional degrees of freedom of water and water-d2 isolated in solid gas matrices
Erich Knoezinger and Ruediger Wittenbeck
pp 2154 - 2158; DOI:
10.1021/ja00346a009
PDF
A simple relationship between empirical theories for predicting barrier heights of electron-, proton-, atom-, and group-transfer reactions
Joseph R. Murdoch
pp 2159 - 2164; DOI:
10.1021/ja00346a010
PDF
Paramagnetism and antiaromaticity: singlet-triplet equilibrium in doubly charged benzenoid polycyclic systems
Abraham Minsky, Amatzya Y. Meyer, Raphael Poupko, and Mordecai Rabinovitz
pp 2164 - 2172; DOI:
10.1021/ja00346a011
PDF
Intramolecular orbital interactions in triptycene studied by photoelectron spectroscopy
Tsunetoshi Kobayashi, Tanekazu Kubota, and Kiyoshi Ezumi
pp 2172 - 2174; DOI:
10.1021/ja00346a012
PDF
Boron aryls as electron donors: .pi.-complexes of arylboranes with tetracyanoethylene
John E. Frey and Elizabeth C. Kitchen
pp 2175 - 2178; DOI:
10.1021/ja00346a013
PDF
Conformational, bond-order, and substituent dependencies of ortho-benzylic coupling constants
M. Barfield, C. J. Fallick, K. Hata, S. Sternhell, and P. W. Westerman
pp 2178 - 2186; DOI:
10.1021/ja00346a014
PDF
Mechanism of carbon dioxide elimination from ionized methyl haloacetates in the gas phase. Formation of CH3XCH2+.cntdot. and CH3XCHX+.cntdot. (X = Cl, Br) halonium radical ions
Yitzhak Apeloig, Bernhard Ciommer, Gernot Frenking, Miriam Karni, Asher Mandelbaum, Helmut Schwarz, and Adrian Weisz
pp 2186 - 2193; DOI:
10.1021/ja00346a015
PDF
Gas-phase anionic oligomerization of methyl acrylate initiated by F3C-, NCCH2-, and allyl anions
Richard N. McDonald and A. Kasem Chowdhury
pp 2194 - 2203; DOI:
10.1021/ja00346a016
PDF
Gas-Phase Acidity of Aliphatic Alcohols
Genevieve Boand, Raymond Houriet, and Tino Gämann
pp 2203 - 2206; DOI:
10.1021/ja00346a600
PDF
Microwave structure measurements on the furan-argon complex
Stephen G. Kukolich
pp 2207 - 2210; DOI:
10.1021/ja00346a017
PDF
The pH jump: kinetic analysis and determination of the diffusion-controlled rate constants
Menachem Gutman, Esther Nachliel, Eli Gershon, Rina Giniger, and Ehud Pines
pp 2210 - 2216; DOI:
10.1021/ja00346a018
PDF
Chiral or achiral paths of steepest descent and transition states: a permutational approach
Jean Brocas and Rudolph Willem
pp 2217 - 2220; DOI:
10.1021/ja00346a019
PDF
Quantum chemical studies of a model for peptide bond formation. 2. Role of amine catalyst in formation of formamide and water from ammonia and formic acid
Tetsuro Oie, Gilda H. Loew, Stanley K. Burt, and Robert D. MacElroy
pp 2221 - 2227; DOI:
10.1021/ja00346a020
PDF
Methyl reorientation in polycrystalline amino acids and peptides: a deuteron NMR spin-lattice relaxation study
Lynne S. Batchelder, C. H. Niu, and D. A. Torchia
pp 2228 - 2231; DOI:
10.1021/ja00346a021
PDF
Side-chain rotational isomerization in proteins: a mechanism involving gating and transient packing defects
J. A. McCammon, C. Y. Lee, and S. H. Northrup
pp 2232 - 2237; DOI:
10.1021/ja00346a022
PDF
Peptide conformations. 20. Conformational analysis of proline rings from proton spin-spin coupling constants and force-field calculations: application to three cyclic tripeptides
Frank A. A. M. De Leeuw, Cornelis Altona, Horst Kessler, Wolfgang Bermel, Axel Friedrich, Gerhard Krack, and William E. Hull
pp 2237 - 2246; DOI:
10.1021/ja00346a023
PDF
Electrochemical characterization of p-type semiconducting tungsten disulfide photocathodes: efficient photoreduction processes at semiconductor/liquid electrolyte interfaces
Joseph A. Baglio, Gary S. Calabrese, D. Jed Harrison, Emil Kamieniecki, Antonio J. Ricco, Mark S. Wrighton, and Glenn D. Zoski
pp 2246 - 2256; DOI:
10.1021/ja00346a024
PDF
Non-Koopmans' theorem effects in the helium(I) photoelectron spectra of polyenes
T. Koenig, C. E. Klopfenstein, S. Southworth, J. A. Hoobler, R. A. Wielesek, T. Balle, W. Snell, and Daniel Imre
pp 2256 - 2259; DOI:
10.1021/ja00346a025
PDF
Electronegativity and bond energy
R. T. Sanderson
pp 2259 - 2261; DOI:
10.1021/ja00346a026
PDF
Incoherent inelastic neutron scattering, infrared, Raman, and x-ray diffraction studies of pentacarbonylmethylmanganese, Mn(CO)5Me
Mark A. Andrews, J. Eckert, J. A. Goldstone, Laurence Passell, and Basil Swanson
pp 2262 - 2269; DOI:
10.1021/ja00346a027
PDF
X-ray absorption spectra of ruthenium L edges in hexaammineruthenium trichloride
T. K. Sham
pp 2269 - 2273; DOI:
10.1021/ja00346a028
PDF
Photochemistry of mixed-metal bimetallic complexes containing pentacyanoferrate(II) or pentaammineruthenium(II) metal centers. Evidence for some intramolecular energy-transfer reactions
Kathy J. Moore, Liangshiu Lee, Joseph E. Figard, Janette A. Gelroth, Angela J. Stinson, H. David Wohlers, and John D. Petersen
pp 2274 - 2279; DOI:
10.1021/ja00346a029
PDF
Reaction paths of carbonyl insertion into the platinum(II)-methyl bond. An MO study
Shigeyoshi Sakaki, Kazuo Kitaura, Keiji Morokuma, and Katsutoshi Ohkubo
pp 2280 - 2286; DOI:
10.1021/ja00346a030
PDF
Synthesis, characterization, and chemical reactivity of soluble bimetallomers
Russell S. Drago, Michael J. Desmond, Barry B. Corden, and Karen A. Miller
pp 2287 - 2296; DOI:
10.1021/ja00346a031
PDF
Highly reduced organometallics. 9. Synthesis and characterization of the tetrasodium tetracarbonylmetalates(4-) of chromium, molybdenum, and tungsten, Na4M(CO)4: their reactions with weak acids to generate H2M2(CO)82-(M = Cr, Mo, and W)
Jiann T. Lin, Gary P. Hagen, and John E. Ellis
pp 2296 - 2303; DOI:
10.1021/ja00346a032
PDF
Synthesis, characterization, and chemistry of pentacarbonylnitrosylvanadium, V(CO)5NO, a remarkably reactive relative of hexacarbonylchromium
Kristi Lenz Fjare and John E. Ellis
pp 2303 - 2307; DOI:
10.1021/ja00346a033
PDF
The electronic structure of vanadium hexacarbonyl. Why it is black
Gary F. Holland, Mark C. Manning, Donald E. Ellis, and William C. Trogler
pp 2308 - 2314; DOI:
10.1021/ja00346a034
PDF
Palladium-mediated cycloaddition approach to cyclopentanoids. Introduction and initial studies
Barry M. Trost and Dominic M. T. Chan
pp 2315 - 2325; DOI:
10.1021/ja00346a035
PDF
Palladium-mediated cycloaddition approach to cyclopentanoids. Mechanistic studies
Barry M. Trost and Dominic M. T. Chan
pp 2326 - 2335; DOI:
10.1021/ja00346a036
PDF
Kinetics and thermodynamics of the structural transformations of thiamine in neutral and basic aqueous media. The UV spectrum of the tetrahedral pseudobase intermediate
Jean Michel El Hage Chahine and Jacques Emile Dubois
pp 2335 - 2340; DOI:
10.1021/ja00346a037
PDF
Hydroboration kinetics. 7. Kinetics and mechanism of the reduction of aldehydes and ketones with 9-borabicyclo[3.3.1]nonane dimer
Herbert C. Brown, Kung K. Wang, and J. Chandrasekharan
pp 2340 - 2343; DOI:
10.1021/ja00346a038
PDF
Solvolysis of 1-aryl-2,2,2-trifluoroethyl sulfonates. Kinetic and stereochemical effects in the generation of highly electron-deficient carbocations
Annette D. Allen, I. Christopher Ambidge, Claudius Che, Hany Micheal, Ronald J. Muir, and Thomas Tidwell
pp 2343 - 2350; DOI:
10.1021/ja00346a039
PDF
Stereochemistry of conformationally restricted analogs of the antitumor agent ICRF-159. 2. Structures of antimetastatically active and inactive isomers of a tricyclic analog
Andrew Hempel, Norman Camerman, and Arthur Camerman
pp 2350 - 2354; DOI:
10.1021/ja00346a040
PDF
Stereochemistry of the Sakurai reaction. Additions to cyclohexenones and cycloheptenones
Todd A. Blumenkopf and Clayton H. Heathcock
pp 2354 - 2358; DOI:
10.1021/ja00346a041
PDF
Can heteroatoms induce violations of orbital-symmetry control? Electrocyclic ring opening of oxirane
F. Volatron, Nguyen Trong Anh, and Y. Jean
pp 2359 - 2364; DOI:
10.1021/ja00346a042
PDF
A new route to functionalized trans-hydrindenones
Barry B. Snider and Thomas C. Kirk
pp 2364 - 2368; DOI:
10.1021/ja00346a043
PDF
Chromyl complexes in the direct epoxidation of alkenes
N. Miyaura and J. K. Kochi
pp 2368 - 2378; DOI:
10.1021/ja00346a044
PDF
Theory of cation-radical pericyclic reactions
Nathan L. Bauld, Dennis J. Bellville, Raul Pabon, Ron Chelsky, and Grant Green
pp 2378 - 2382; DOI:
10.1021/ja00346a045
PDF
Hydrolysis of imidazole-containing amide acetals
R. S. Brown and J. G. Ulan
pp 2382 - 2388; DOI:
10.1021/ja00346a046
PDF
Proton-transfer reactions. 3. Differences in the protonation of localized and delocalized carbanion intermediates
Heinz F. Koch, Judith G. Koch, Nanci H. Koch, and Andrew S. Koch
pp 2388 - 2393; DOI:
10.1021/ja00346a047
PDF
Proton-transfer reactions. 4. Near-unity kinetic isotope effects for hydron exchange and dehydrofluorination reactions
Heinz F. Koch, Donald B. Dahlberg, Gerrit Lodder, Karen S. Root, Nancy A. Touchette, Robert L. Solsky, Robin M. Zuck, Linda J. Wagner, Nanci H. Koch, and Michael A. Kuzemko
pp 2394 - 2398; DOI:
10.1021/ja00346a048
PDF
Organic photochemistry. 54. Photolytic cleavage of remote functional groups in polyfunctional molecules. Photolysis of exo- and endo-2-benzonorbornenyl chlorides and methanesulfonates
Harry Morrison, Alan Miller, and B. Bigot
pp 2398 - 2408; DOI:
10.1021/ja00346a049
PDF
Optical rotatory dispersion studies. 135. Synthesis and chiroptical properties of (S)- and (R)-(3-2H1)-2,2-dimethylcyclobutanone. Evidence for conformational effects in substituted cyclobutanones
R. N. Harris, P. Sundararaman, and C. Djerassi
pp 2408 - 2413; DOI:
10.1021/ja00346a050
PDF
Synthesis, x-ray analysis, and acidolysis of exo- and endo-1-methylindene ozonides
Masahiro Miura, Akio Ikegami, Masatomo Nojima, Shigekazu Kusabayashi, Kevin J. McCullough, and Shigeru Nagase
pp 2414 - 2426; DOI:
10.1021/ja00346a051
PDF
Synthesis, molecular structure and chemistry of p-[CoIII(tren)(2-(dihydroxymethyl)glycinato)]ZnCl4.2H2O
W. G. Jackson, G. M. McLaughlin, A. M. Sargeson, and A. D. Watson
pp 2426 - 2430; DOI:
10.1021/ja00346a052
PDF
A mild and general method for the synthesis of 0-glycosides
K. C. Nicolaou, S. P. Seitz, and D. P. Papahatjis
pp 2430 - 2434; DOI:
10.1021/ja00346a053
PDF
Iterative three-carbon annelation. A stereoselective total synthesis of (.+-.)-hirsutic acid C
Andrew E. Greene, Marie Jacqueline Luche, and Jean Pierre Depres
pp 2435 - 2439; DOI:
10.1021/ja00346a054
PDF
Transport of biological lipophiles: effect of lipophile structure
Henry J. Pownall, Diane L. Hickson, and Louis C. Smith
pp 2440 - 2445; DOI:
10.1021/ja00346a055
PDF
Correlative variations in enzyme-derived and substrate-derived structures of catalytic transition states. Implications for the catalytic strategy of acyl-transfer enzymes
Ross L. Stein, James P. Elrod, and Richard L. Schowen
pp 2446 - 2452; DOI:
10.1021/ja00346a056
PDF
Monooxygen donation potential of 4a-hydroperoxyflavins as compared with those of a percarboxylic acid and other hydroperoxides. Monooxygen donation to olefin, tertiary amine, alkyl sulfide, and iodide ion
Thomas C. Bruice, J. Barry Noar, Sheldon S. Ball, and U. V. Venkataram
pp 2452 - 2463; DOI:
10.1021/ja00346a057
PDF
Conformational energies of fenfluramine: graphical representation of energy as a function of four conformational variables
Mary Weir Creese and Gary L. Grunewald
pp 2463 - 2469; DOI:
10.1021/ja00346a058
PDF
High-resolution carbon-13 CP/MAS NMR spectra of solid cellulose oligomers and the structure of cellulose II
R. L. Dudley, C. A. Fyfe, P. J. Stephenson, Y. Deslandes, G. K. Hamer, and R. H. Marchessault
pp 2469 - 2472; DOI:
10.1021/ja00346a059
PDF
Ambident aniline reactivity in Meisenheimer complex formation
M. J. Strauss, R. A. Renfrow, and E. Buncel
pp 2473 - 2474; DOI:
10.1021/ja00346a060
PDF
Formation of the NH4- ion in the gas phase
Jan C. Kleingeld, Steen Ingemann, Jorma E. Jalonen, and Nico M. M. Nibbering
pp 2474 - 2475; DOI:
10.1021/ja00346a061
PDF
Double isotope fractionation: test for concertedness and for transition-state dominance
Joel G. Belasco, W. John Albery, and Jeremy R. Knowles
pp 2475 - 2477; DOI:
10.1021/ja00346a062
PDF
Stereoselectivity of intramolecular dicobalt octacarbonyl alkene-alkyne cyclizations: short synthesis of dl-coriolin
Christopher Exon and Philip Magnus
pp 2477 - 2478; DOI:
10.1021/ja00346a063
PDF
Phospholipids chiral at phosphorus. 4. Could membranes be chiral at phosphorus?
Ming Daw Tsai, Ru Tai Jiang, and Karol Bruzik
pp 2478 - 2480; DOI:
10.1021/ja00346a064
PDF
Chemically induced dynamic electron polarization (CIDEP) of some sulfur-containing cation radicals: evidence of the charge-transfer processes between quinone cation radicals and sulfur heterocyclic compounds
M. Catherine Depew, Liu Zhongli, and Jeffrey K. S. Wan
pp 2480 - 2481; DOI:
10.1021/ja00346a065
PDF
Absence of an .alpha.-effect in the gas-phase nucleophilic reactions of hydroperoxide ion
Charles H. DePuy, Ernest W. Della, Jonathan Filley, Joseph J. Grabowski, and Veronica M. Bierbaum
pp 2481 - 2482; DOI:
10.1021/ja00346a066
PDF
First in-plane coordination of a simple monoolefin in a square-planar complex. Molecular structure of .eta.3-methallyl(triphenylphosphine)(styrene)platinum(II) cation
Kunio Miki, Yasushi Kai, Nobutami Kasai, and Hideo Kurosawa
pp 2482 - 2483; DOI:
10.1021/ja00346a067
PDF
Observation of high-resolution oxygen-17 NMR spectra of inorganic solids
Suzanne Schramm, R. James Kirkpatrick, and Eric Oldfield
pp 2483 - 2485; DOI:
10.1021/ja00346a068
PDF
A metal formyl complex via hydride transfer from HRu(CO)4-: a model for catalytic hydrogenation of carbon monoxide
B. Duane Dombek and Arnold M. Harrison
pp 2485 - 2486; DOI:
10.1021/ja00346a069
PDF
Electrochemical routes to paramagnetic dinuclear and mononuclear palladium .pi. complexes stabilized by the pentaphenylcyclopentadienyl ligand
Karen Broadley, Gregg A. Lane, Neil G. Connelly, and William E. Geiger
pp 2486 - 2487; DOI:
10.1021/ja00346a070
PDF
A stereoselective synthesis of 1,3-diol derivatives and application to the ansa bridge of rifamycin S
W. Clark Still and Joel C. Barrish
pp 2487 - 2489; DOI:
10.1021/ja00346a071
PDF
Chemistry of carbynes: reaction of CF, CCl, and CBr with alkenes
B. P. Ruzsicska, A. Jodhan, H. K. J. Choi, O. P. Strausz, and T. N. Bell
pp 2489 - 2490; DOI:
10.1021/ja00346a072
PDF
Direct total synthesis of traditional sterols by tricyclization of polyunsaturated cyclohexene oxides
Eugene E. Van Tamelen and Jih Ru Hwu
pp 2490 - 2491; DOI:
10.1021/ja00346a073
PDF
Cumulene photochemistry: photorearrangement of 1,2-cyclononadiene to a bicyclic cyclopropene
Thomas J. Stierman and Richard P. Johnson
pp 2492 - 2493; DOI:
10.1021/ja00346a074
PDF
Biosynthesis of riboflavin. An unusual rearrangement in the formation of 6,7-dimethyl-8-ribityllumazine
Heinz G. Floss, Quang Le Van, Paul J. Keller, and Adelbert Bacher
pp 2493 - 2494; DOI:
10.1021/ja00346a075
PDF
Novel homo and heterometallic coordination macrocycles
P. Stricklen and J. Verkade
pp 2494 - 2495; DOI:
10.1021/ja00346a076
PDF
Isolation of some sterically protected unsymmetrical diphosphenes: nature of the phosphorus-phosphorus double bond
Masaaki Yoshifuji, Katsuhiro Shibayama, Naoki Inamoto, Toshio Matsushita, and Kichisuke Nishimoto
pp 2495 - 2497; DOI:
10.1021/ja00346a077
PDF
Nucleophile addition/carbonylation with .eta.4-dienetricarbonyliron(0) complexes
M. F. Semmelhack, James W. Herndon, and James P. Springer
pp 2497 - 2499; DOI:
10.1021/ja00346a078
PDF
Mechanism of ligand substitution in dimanganese decacarbonyl
N. J. Coville, A. M. Stolzenberg, and E. L. Muetterties
pp 2499 - 2500; DOI:
10.1021/ja00346a079
PDF
Systematic design of chemical oscillators. 17. Birhythmicity and compound oscillation in coupled chemical oscillators: chlorite-bromate-iodide system
Mohamed Alamgir and Irving R. Epstein
pp 2500 - 2502; DOI:
10.1021/ja00346a080
PDF
Carbon acidity. 64. First and second acidity constants for some indenyl and fluorenyl hydrocarbons: Coulombic effects in ion triplets
Andrew Streitwieser and Jon T. Swanson
pp 2502 - 2503; DOI:
10.1021/ja00346a081
PDF
Kinetics, thermodynamics and stereochemistry of the allyl sulfoxide-sulfenate and selenoxide-selenenate [2,3] sigmatropic rearrangements
Hans J. Reich, Kenneth E. Yelm, and Susan Wollowitz
pp 2503 - 2504; DOI:
10.1021/ja00346a082
PDF
Spectroscopic observation of the tautomer of 7-deoxydaunomycinone from elimination of daunosamine from daunomycin hydroquinone
Don L. Kleyer and Tad H. Koch
pp 2504 - 2505; DOI:
10.1021/ja00346a083
PDF
Biosynthesis of riboflavin. Analysis of biosynthetically carbon-13-labeled riboflavin by double-quantum and two-dimensional NMR
Paul J. Keller, Quang Le Van, Adelbert Bacher, John F. Kozlowski, and Heinz G. Floss
pp 2505 - 2507; DOI:
10.1021/ja00346a084
PDF
Mixed-valence pyrazine-bridged binuclear complexes of osmium ammines
Roy H. Magnuson, Peter A. Lay, and Henry Taube
pp 2507 - 2509; DOI:
10.1021/ja00346a085
PDF
Correction- Polymerized Phosphatidylcholine Vesciles. Synthesis and Characterization
Steven L. Regen, Alok Singh, Günther Oehme, and Manninder Singh
pp 2509 - 2509; DOI:
10.1021/ja00346a601
PDF
Corrections- Cyclohexaamylose Complexation with Organic Solvent Molecules
Robert I. Gelb, Lowell M. Schwartz, Michael Radeos, Robert B. Edmonds, and Daniel A. Laufer
pp 2509 - 2509; DOI:
10.1021/ja00346a602
PDF
Corrections- Reactive Intermediates. Volume 2

pp 2509 - 2509; DOI:
10.1021/ja00346a603
PDF
Corrections- Surface Photochemistry: Deviation of the Course of Reaction in Benzoin Ether Photolysis by Adsorption on Silica Gel
Paul de Mayo, Akira Nakamura, Peter W.K. Tsang, and S. King Wong
pp 2509 - 2509; DOI:
10.1021/ja00346a604
PDF
Corrections- Definitive Evidence for Cycloheptatetraene from Dehydrobromination of Bromocycloheptatrienes
James W. Harris, and W.M. Jones
pp 2509 - 2509; DOI:
10.1021/ja00346a605
PDF
Corrections- Iron(III)-Porphyrin π-Cation Radical Complexes. Molecular Structures and Magnetic Properties
Georges Buisson, Alain Deronzier, Emile Duee, Pierre Gans, Jean-Claude Marchon, and Jean-Rene Regnard
pp 2509 - 2509; DOI:
10.1021/ja00346a606
PDF
Corrections- Kinetics, Thermodynamics, and Mechanism of the Radical Chain Process for Ligand Substitution of Metal Carbonyls
J.W. Hershberger, R.J. Klingler, and J.K. Kochi
pp 2509 - 2509; DOI:
10.1021/ja00346a607
PDF
Corrections- Organic Electronic Spectral Data

pp 2509 - 2509; DOI:
10.1021/ja00346a608
PDF
Book Reviews

pp 2510 - 2522; DOI:
10.1021/ja00346a628
PDF

Issue 9


Reactions of atomic oxygen with ethene in solid argon. The infrared spectrum of vinyl alcohol
Michael Hawkins and Lester Andrews
pp 2523 - 2530; DOI:
10.1021/ja00347a001
PDF
Role of higher triplet states in the anthracene-sensitized photoisomerization of stilbene and 2,4-hexadiene
Jack Saltiel, David E. Townsend, and Alan Sykes
pp 2530 - 2538; DOI:
10.1021/ja00347a002
PDF
Carbon-13 and proton two-dimensional NMR study of the Ormosia alkaloids panamine, ormosanine, and ormosinine
N. S. Bhacca, M. F. Balandrin, A. D. Kinghorn, T. A. Frenkiel, R. Freeman, and G. A. Morris
pp 2538 - 2544; DOI:
10.1021/ja00347a003
PDF
Electrochemical studies of the reduction of fluorenone triphenylphosphazine. Formation of the stable dimeric dianion (FlN2)22-
Dale E. Herbranson, F. J. Theisen, M. Dale Hawley, and Richard N. McDonald
pp 2544 - 2549; DOI:
10.1021/ja00347a004
PDF
Structure and tunneling dynamics of malonaldehyde. A theoretical study
Jozef Bicerano, Henry F. Schaefer, and William H. Miller
pp 2550 - 2553; DOI:
10.1021/ja00347a005
PDF
Arene oxide-oxepin isomerization. Theoretical predictions and experimental evidence
Derek R. Boyd and Michael E. Stubbs
pp 2554 - 2559; DOI:
10.1021/ja00347a006
PDF
Conformational analysis of linear peptides. 4. Association properties of protected oligomers of .alpha.-aminoisobutyric acid in chloroform
Robert R. Wilkening, E. S. Stevens, G. M. Bonora, and C. Toniolo
pp 2560 - 2561; DOI:
10.1021/ja00347a007
PDF
Experimental investigation of gaseous ionic structures of interstellar importance: HCO+ and HOC+
A. J. Illies, M. F. Jarrold, and M. T. Bowers
pp 2562 - 2565; DOI:
10.1021/ja00347a008
PDF
Gas-phase hydrogen-deuterium exchange reactions of hydroxide and hydroxide-d ions with weakly acidic neutrals
Joseph J. Grabowski, Charles H. DePuy, and Veronica M. Bierbaum
pp 2565 - 2571; DOI:
10.1021/ja00347a009
PDF
Chemical oscillations and instabilities. 51. Gas evolution oscillators. 1. Some new experimental examples
Peter G. Bowers and Richard M. Noyes
pp 2572 - 2574; DOI:
10.1021/ja00347a010
PDF
Laser and pulse radiolytically induced colloidal gold formation in water and in water-in-oil microemulsions
Kazue Kurihara, Jerzy Kizling, Per Stenius, and Janos H. Fendler
pp 2574 - 2579; DOI:
10.1021/ja00347a011
PDF
Proton-exchange rates in solid tropolone as measured via carbon-13 CP/MAS NMR
Nikolaus M. Szeverenyi, Ad Bax, and Gary E. Maciel
pp 2579 - 2582; DOI:
10.1021/ja00347a012
PDF
Triple-decker complexes. 8. Triple-decker sandwiches. Syntheses, reactivity, electrochemistry, and x-ray crystal and electronic structures of bis(cyclopentadienylmetal)-.mu.-1,3-diborolenyl complexes with 29-34 valence electrons
Joseph Edwin, Manfred Bochmann, Michael C. Boehm, David E. Brennan, William E. Geiger, Carl Krueger, Juergen Pebler, Hans Pritzkow, Walter Siebert, and et al.
pp 2582 - 2598; DOI:
10.1021/ja00347a013
PDF
Synthesis and structure of a molybdenum dimer illustrating d.pi. orbital participation in .pi. donation, .pi. acceptance, and metal-metal bond formation
Richard S. Herrick, Sharon J. Nieter Burgmayer, and Joseph L. Templeton
pp 2599 - 2605; DOI:
10.1021/ja00347a014
PDF
Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 2. The d5-d5 Re2Cl4(PR3)4 compounds
Bruce E. Bursten, F. Albert Cotton, Phillip E. Fanwick, George G. Stanley, and Richard A. Walton
pp 2606 - 2611; DOI:
10.1021/ja00347a015
PDF
Conductive molecular crystals. Structural, magnetic, and charge-transport properties of partially oxidized (5,10,15,20-tetramethylporphyrinato)nickel(II)
Laurel J. Pace, Jens Martinsen, Abraham Ulman, Brian M. Hoffman, and James A. Ibers
pp 2612 - 2620; DOI:
10.1021/ja00347a016
PDF
Crystal structure of dehydrated rubidium-exchanged zeolite A. Absence of zero-coordinated rubidium. Preferential ion exchange of barium impurity
Joseph J. Pluth and Joseph V. Smith
pp 2621 - 2624; DOI:
10.1021/ja00347a017
PDF
Control of spin state in (porphinato)iron(III) complexes. An axial ligand orientation effect leading to an intermediate-spin complex. Molecular structure and physical characterization of the monoclinic form of bis(3-chloropyridine)(octaethylporphinato)iron(III) perchlorate
W. Robert Scheidt, David K. Geiger, Robert G. Hayes, and George Lang
pp 2625 - 2632; DOI:
10.1021/ja00347a018
PDF
Formation of paramagnetic adsorbed molecules on thermally activated magnesium and calcium oxides. Further studies of carbon monoxide
Russell M. Morris and Kenneth J. Klabunde
pp 2633 - 2639; DOI:
10.1021/ja00347a019
PDF
New type of oscillating reaction: air oxidation of benzaldehyde
James H. Jensen
pp 2639 - 2641; DOI:
10.1021/ja00347a020
PDF
Systematic design of chemical oscillators. 15. A new type of bromate oscillator: the bromate-iodide reaction in a stirred-flow reactor
Mohamed Alamgir, Patrick De Kepper, Miklos Orban, and Irving R. Epstein
pp 2641 - 2643; DOI:
10.1021/ja00347a021
PDF
Reduction of carbon monoxide by binuclear tantalum hydride complexes
Patricia A. Belmonte, F. Geoffrey N. Cloke, and Richard R. Schrock
pp 2643 - 2650; DOI:
10.1021/ja00347a022
PDF
Hydrogen-transfer reactions which generate new imine, imido, and trimethylenemethane complexes of tantalum
James M. Mayer, Calvin J. Curtis, and Johb E. Bercaw
pp 2651 - 2660; DOI:
10.1021/ja00347a023
PDF
Relationship between More O'Ferrall plots and Marcus rate theory. Overriding orbital-symmetry constraints on chemical reactions
Joseph R. Murdoch
pp 2660 - 2667; DOI:
10.1021/ja00347a024
PDF
Barrier heights and the position of stationary points along the reaction coordinate
Joseph R. Murdoch
pp 2667 - 2672; DOI:
10.1021/ja00347a025
PDF
Intrinsic barriers in nucleophilic displacements. A general model for intrinsic nucleophilicity toward methyl centers
Mark J. Pellerite and John I. Brauman
pp 2672 - 2680; DOI:
10.1021/ja00347a026
PDF
Orthoquinone complexes of vanadium and their reactions with molecular oxygen
Marion E. Cass, David L. Green, Robert M. Buchanan, and Cortlandt G. Pierpont
pp 2680 - 2686; DOI:
10.1021/ja00347a027
PDF
Metal-metal multiple bonds. 10. Electrophilic additions of halogens and hydrogen halides to the molybdenum-molybdenum triple bond in dicyclopentadienyldimolybdenum tetracarbonyl
M. David Curtis, Nicephoros A. Fotinos, Kyoung R. Han, and William M. Butler
pp 2686 - 2694; DOI:
10.1021/ja00347a028
PDF
Further studies of the dimeric .beta.-linked "face-to-face four" porphyrin: FTF4
James P. Collman, Fred C. Anson, Craig E. Barnes, C. Susana Bencosme, Thomas Geiger, Eric R. Evitt, Robert P. Kreh, Kurt Meier, and Roger B. Pettman
pp 2694 - 2699; DOI:
10.1021/ja00347a029
PDF
Mixed-metal face-to-face porphyrin dimers
James P. Collman, C. Susana Bencosme, Richard R. Durand, Robert P. Kreh, and Fred C. Anson
pp 2699 - 2703; DOI:
10.1021/ja00347a030
PDF
Two new members of the dimeric .beta.-linked face-to-face porphyrin family: FTF4* and FTF3
James P. Collman, C. Susana Bencosme, Craig E. Barnes, and Bryan D. Miller
pp 2704 - 2710; DOI:
10.1021/ja00347a031
PDF
Mechanistic aspects of the catalytic reduction of dioxygen by cofacial metalloporphyrins
Richard R. Durand, C. Susana Bencosme, James P. Collman, and Fred C. Anson
pp 2710 - 2718; DOI:
10.1021/ja00347a032
PDF
Structure-reactivity effects in the hydration of benzaldehydes
Robert A. McClelland and Margaret Coe
pp 2718 - 2725; DOI:
10.1021/ja00347a033
PDF
N,N'-Dinitrosation of platinum(IV)-coordinated 1,2-ethanediamine: crystal and molecular structure of chloronitro(bipyridyl)(N,N'-dinitroso-1,2-ethanediaminato)platinum(II) hemihydrate
Wade A. Freeman
pp 2725 - 2729; DOI:
10.1021/ja00347a034
PDF
Trefoil aromatics: a potentially new class of aromatic molecules
T. Fukunaga, H. E. Simmons, J. J. Wendoloski, and M. D. Gordon
pp 2729 - 2734; DOI:
10.1021/ja00347a035
PDF
Ester aminolysis: new reaction series for the quantitative measurement of steric effects
DeLos F. DeTar and Claire Delahunty
pp 2734 - 2739; DOI:
10.1021/ja00347a036
PDF
Optimization of metallocene substrates for .beta.-cyclodextrin reactions
Ronald Breslow, George Trainor, and Akihiko Ueno
pp 2739 - 2744; DOI:
10.1021/ja00347a037
PDF
Effect of pressure on two cyclodextrin-promoted ester hydrolyses
W. J. Le Noble, S. Srivastava, R. Breslow, and G. Trainor
pp 2745 - 2748; DOI:
10.1021/ja00347a038
PDF
New aspects of the telluroxide elimination: a facile elimination of sec-alkyl phenyl telluroxide leading to olefins, allylic alcohols, and allylic ethers
Sakae Uemura and Shinichi Fukuzawa
pp 2748 - 2752; DOI:
10.1021/ja00347a039
PDF
Stereopopulation control. VII. Rate enhancement in the lactonization of 3-(o-hydroxyphenyl)propionic acids: dependence on the size of aromatic ring substituents
Michael M. King and Louis A. Cohen
pp 2752 - 2760; DOI:
10.1021/ja00347a040
PDF
Stereopopulation control. VIII. Rate and equilibrium enhancement in the formation of homophthalic anhydrides
Paul S. Hillery and Louis A. Cohen
pp 2760 - 2770; DOI:
10.1021/ja00347a041
PDF
Oxyanionic substituent effect on the carbon-hydrogen insertion of carbenes. Reaction of alkoxides with dichlorocarbene and chlorophenylcarbene
Toshiro Harada, Eiji Akiba, and Akira Oku
pp 2771 - 2776; DOI:
10.1021/ja00347a042
PDF
Interdependence of carbon-nitrogen and carbon-oxygen bond lengths in urea structures and in ureido ring structures
Robert H. Blessing
pp 2776 - 2783; DOI:
10.1021/ja00347a043
PDF
Nucleophilic attacks on carbon-carbon double bonds. Part 29. Role of hyperconjugation in determining the stereochemistry of nucleophilic epoxidation and cyclopropanation of electrophilic olefins
Yitzhak Apeloig, Miriam Karni, and Zvi Rappoport
pp 2784 - 2793; DOI:
10.1021/ja00347a044
PDF
Adiabatic S1 9,10-dichloroanthracene formation from electronically excited 9,10-dichloroanthracene/1,3-cyclohexadiene photoadducts
William K. Smothers and Jack Saltiel
pp 2794 - 2799; DOI:
10.1021/ja00347a045
PDF
On the electronic character of progressively unsaturated [4.4.3]propellanyl cations under long- and short-life conditions
Leo A. Paquette, Katsuo Ohkata, Klaus Jelich, and William Kitching
pp 2800 - 2811; DOI:
10.1021/ja00347a046
PDF
Chemoselective behavior of enolate carbenes derived from dianions of enol thioacetals
Theodore Cohen and Lin Chen Yu
pp 2811 - 2813; DOI:
10.1021/ja00347a047
PDF
Phosphorus-nitrogen ring systems and high polymers. Mechanism of the reaction between alkyl or aryl Grignard reagents and hexachlorocyclotriphosphazene: an explanation of bicyclophosphazene formation
Harry R. Allcock, James L. Desorcie, and Paul J. Harris
pp 2814 - 2819; DOI:
10.1021/ja00347a048
PDF
Mechanism of gas-phase cyanation of alkenes and aromatics
Neil B. H. Henis and Larry L. Miller
pp 2820 - 2823; DOI:
10.1021/ja00347a049
PDF
Benzidine rearrangements. 18. Mechanism of the acid-catalyzed disproportionation of 4,4'-diiodohydrazobenzene. Application of heavy-atom kinetic isotope effects
Henry J. Shine, Jan Habdas, Harold Kwart, Martin Brechbiel, Ann Gafney Horgan, and Joseph San Filippo
pp 2823 - 2827; DOI:
10.1021/ja00347a050
PDF
Enol phosphates from the action of monomeric metaphosphate ion on ketones
Kim C. Calvo and F. H. Westheimer
pp 2827 - 2831; DOI:
10.1021/ja00347a051
PDF
Organoaluminum-promoted Beckmann rearrangement of oxime sulfonates
Keiji Maruoka, Tohru Miyazaki, Mamoru Ando, Yasushi Matsumura, Soichi Sakane, Kazunobu Hattori, and Hisashi Yamamoto
pp 2831 - 2843; DOI:
10.1021/ja00347a052
PDF
Molten salt catalysis. Selective bond cleavage reactions for some .alpha.,.omega.-diphenylalkanes in antimony trichloride melts
A. C. Buchanan, A. S. Dworkin, and G. P. Smith
pp 2843 - 2850; DOI:
10.1021/ja00347a053
PDF
Mesylate derivatives of .alpha.-hydroxy phosphonates. Formation of carbocations adjacent to the diethyl phosphonate group
Xavier Creary, Cristina C. Geiger, and Kathryn Hilton
pp 2851 - 2858; DOI:
10.1021/ja00347a054
PDF
Routes to mitomycins. New syntheses of the 2,3,5,8-tetrahydro-5,8-dioxo-1H-pyrrolo[1,2-a]indole ring system. An efficient synthesis of 7-methoxymitosene
Jay R. Luly and Henry Rapoport
pp 2859 - 2866; DOI:
10.1021/ja00347a055
PDF
Nitric oxide ferrohemes: kinetics of formation and photodissociation quantum yields
Emily J. Rose and Brian M. Hoffman
pp 2866 - 2873; DOI:
10.1021/ja00347a056
PDF
Total synthesis of (.+-.)-14-epicorynoline, (.+-.)-corynoline, and (.+-.)-6-oxocorynoline
Mark Cushman, Aziz Abbaspour, and Yash Pal Gupta
pp 2873 - 2879; DOI:
10.1021/ja00347a057
PDF
Studies on the catalyzed interconversions of vitamin A derivatives
Robert R. Rando and Andrew Chang
pp 2879 - 2882; DOI:
10.1021/ja00347a058
PDF
Detection of free radicals from low-temperature ozone-olefin reactions by ESR spin trapping: evidence that the radical precursor is a trioxide
William A. Pryor, Donald G. Prier, and Daniel F. Church
pp 2883 - 2888; DOI:
10.1021/ja00347a059
PDF
Stabilities of carbocations in solution. 14. An extended thermochemical scale of carbocation stabilities in a common superacid
Edward M. Arnett and Thomas C. Hofelich
pp 2889 - 2895; DOI:
10.1021/ja00347a060
PDF
Molecular structure of silicon dichloride and silicon dibromide from electron diffraction combined with mass spectrometry
Istvan Hargittai, Gyorgy Schultz, Janos Tremmel, N. D. Kagramanov, A. K. Maltsev, and O. M. Nefedov
pp 2895 - 2896; DOI:
10.1021/ja00347a061
PDF
Reaction of ethylene with trinuclear hydrido cluster complexes: formation and subsequent fragmentation of .mu.-acyl complexes
C. E. Kampe, N. M. Boag, and H. D. Kaesz
pp 2896 - 2897; DOI:
10.1021/ja00347a062
PDF
Dihydrogen evolution from aqueous vanadium(II)-cysteine solutions at pH 6.0-9.5
G. Kalatzis, J. Konstantatos, E. Vrachnou-Astra, and D. Katakis
pp 2897 - 2898; DOI:
10.1021/ja00347a063
PDF
Phenomenon of slowing down in the autocatalytic trypsinogen to trypsin conversion in a continuous-flow stirred-tank reactor
H. Lachmann and F. W. Schneider
pp 2898 - 2900; DOI:
10.1021/ja00347a064
PDF
Photochemistry of ketones in solution. 70. Stereospecific photodecarbonylation of cis- and trans-2,7-dimethyl-3,5-cycloheptadienone: observation of an apparent symmetry-forbidden concerted cheletropic fragmentation
David I. Schuster and Li Wang
pp 2900 - 2901; DOI:
10.1021/ja00347a065
PDF
Cooperative dioxygen binding by cobalt(II) gable porphyrin in homogeneous solution
Iwao Tabushi and Tomikazu Sasaki
pp 2901 - 2902; DOI:
10.1021/ja00347a066
PDF
Nanosecond time-resolved magnetic resonance of the primary radical pair state PF of bacterial photosynthesis
Michael R. Wasielewski, Christian H. Bock, Michael K. Bowman, and James R. Norris
pp 2903 - 2904; DOI:
10.1021/ja00347a067
PDF
Asymmetric synthesis via acetal templates. 4. Reactions with silylacetylenic compounds. Formation of chiral propargylic alcohols
William S. Johnson, Raymond Elliott, and John D. Elliott
pp 2904 - 2905; DOI:
10.1021/ja00347a068
PDF
.mu.-(.eta.5:.eta.5-Cyclooctatetraene)bis[(.eta.5-cyclopentadienyl)vanadium]: preparation, structure and ESR characterization of its radical anion
C. Elschenbroich, J. Heck, W. Massa, E. Nun, and R. Schmidt
pp 2905 - 2907; DOI:
10.1021/ja00347a069
PDF
Structures of betaenones A and B, novel phytotoxins from Phoma betae Fr.
Akitami Ichihara, Hideaki Oikawa, Kazuko Hayashi, Sadao Sakamura, Akio Furusaki, and Takeshi Matsumoto
pp 2907 - 2908; DOI:
10.1021/ja00347a070
PDF
Oxidatively assisted hydrolysis of allylic iodides to rearranged allylic alcohols. A new example of [2,3] sigmatropic rearrangement
Sadao Yamamoto, Hikaru Itani, Teruji Tsuji, and Wataru Nagata
pp 2908 - 2909; DOI:
10.1021/ja00347a071
PDF
Pentadienyl dithiocarbamate as a 1,5-dianion equivalent. Versatile reagent for polyene synthesis
Toshio Hayashi, Isaburo Hori, and Takeshi Oishi
pp 2909 - 2911; DOI:
10.1021/ja00347a072
PDF
Structure of dimesitylcarbene
A. S. Nazran, E. J. Gabe, Y. LePage, D. J. Northcott, J. M. Park, and D. Griller
pp 2912 - 2913; DOI:
10.1021/ja00347a073
PDF
Triacridine derivative: first DNA tris-intercalating ligand
Graham J. Atwell, Werner Leupin, Simon J. Twigden, and William A. Denny
pp 2913 - 2914; DOI:
10.1021/ja00347a074
PDF
Sequential resonance assignments in DNA proton NMR spectra by two-dimensional NOE spectroscopy
R. M. Scheek, N. Russo, R. Boelens, R. Kaptein, and J. H. Van Boom
pp 2914 - 2916; DOI:
10.1021/ja00347a075
PDF
Angle-resolved SIMS studies of organic monolayers on the silver (111) surface
D. W. Moon, R. J. Bleiler, E. J. Karwacki, and Nicholas Winograd
pp 2916 - 2917; DOI:
10.1021/ja00347a076
PDF
Redox properties of octacyano-substituted zinc phthalocyanine ((CN)8PcZn). New charge-transfer complex
A. Giraudeau, A. Louati, M. Gross, J. J. Andre, J. Simon, C. H. Su, and K. M. Kadish
pp 2917 - 2919; DOI:
10.1021/ja00347a077
PDF
Conversion of an .eta.5-C5H5 complex into a cyclopentadienylidene ketene complex
Charles P. Casey and Joseph M. O'Connor
pp 2919 - 2920; DOI:
10.1021/ja00347a078
PDF
Synthesis, characterization, and reaction chemistry of a bis(iodosylbenzene)metalloporphyrin complex, [PhI(OAc)O]2MnIVTPP. A complex possessing a five-electron oxidation capability
John A. Smegal and Craig L. Hill
pp 2920 - 2922; DOI:
10.1021/ja00347a079
PDF
New probes for electron-transfer processes. Evidence supporting the single-electron-transfer mechanism in additions of carbanions to dienones
Dennis Liotta, Manohar Saindane, and Liladhar Waykole
pp 2922 - 2923; DOI:
10.1021/ja00347a080
PDF
7-Cis,9-cis,11-cis-Retinal, all cis-vitamin A and 7-cis,9-cis,11-cis-12-fluororetinal. New geometric isomers of vitamin A and carotenoids. 12
Alfred E. Asato, Aravinda Kini, Marlene Denny, and R. S. H. Liu
pp 2923 - 2924; DOI:
10.1021/ja00347a081
PDF
Stereochemistry of the olefin metathesis reaction: theoretical extended Hueckel study of substituted metallacyclobutanes
B. Tinland, M. Leconte, and J. M. Basset
pp 2924 - 2925; DOI:
10.1021/ja00347a082
PDF
Surface acid site characterization by means of CP/MAS nitrogen-15 NMR
John A. Ripmeester
pp 2925 - 2927; DOI:
10.1021/ja00347a083
PDF
New class of .sigma.-bonded aliphatic aza-macrocyclic complexes of transition metals: synthesis and x-ray crystal structures of nitrogen-bridged [(TiN4C12H24)2] and the oxo-bridged species [(N4C12H25)TiOTi(N4C12H25)]
Marilyn M. Olmstead, Philip P. Power, and Michael Viggiano
pp 2927 - 2928; DOI:
10.1021/ja00347a084
PDF
Absorption and emission characteristics of merocyanine 540 in microemulsions
N. S. Dixit and R. A. Mackay
pp 2928 - 2929; DOI:
10.1021/ja00347a085
PDF
gem-Alkylcyclopentadienes. 2. Secondary deuterium kinetic isotope effect study of the cycloaddition of diphenylketene and 5,5-dimethylcyclopentadiene
Richard W. Holder, Norman A. Graf, Eileen Duesler, and Janine C. Moss
pp 2929 - 2931; DOI:
10.1021/ja00347a086
PDF
Book Reviews

pp 2931 - 2932; DOI:
10.1021/ja00347a600
PDF

Issue 10


Quartet vs. doublet excited-state reactivity in tris(2,2'-bipyridine)chromium(3+) ion. Temperature dependence of quenchable and unquenchable photoaquation
Mary A. Jamieson, Nick Serpone, and Morton Z. Hoffman
pp 2933 - 2937; DOI:
10.1021/ja00348a001
PDF
Matrix isolation study of iron-chromium (FeCr) molecules and SCF-X.alpha.-scattered wave molecular orbital calculations on iron-iron (Fe2) and iron-chromium (FeCr) diatomics
H. M. Nagarathna, Pedro A. Montano, and Vamun M. Naik
pp 2938 - 2943; DOI:
10.1021/ja00348a002
PDF
Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to Broensted acids from gas-phase fluoride exchange equilibrium measurements
J. W. Larson and T. B. McMahon
pp 2944 - 2950; DOI:
10.1021/ja00348a003
PDF
Reversible oxidation and rereduction of entire thin films of transition-metal phthalocyanines
J. Mark Green and Larry R. Faulkner
pp 2950 - 2955; DOI:
10.1021/ja00348a004
PDF
The ionic hydrogen bond. 1. Sterically hindered bonds. Solvation and clustering of protonated amines and pyridines
Michael Meot-Ner and L. Wayne Sieck
pp 2956 - 2961; DOI:
10.1021/ja00348a005
PDF
Evaluation of partition coefficients to micelles and cyclodextrins via planar chromatography
Daniel W. Armstrong and Gail Y. Stine
pp 2962 - 2964; DOI:
10.1021/ja00348a006
PDF
Steric forces in substituted aromatics: conformation of the hexahalobenzenes as determined by ab initio calculations
Jan Almloef and Knut Faegri
pp 2965 - 2969; DOI:
10.1021/ja00348a007
PDF
Photoelectron spectroscopy of the allenyl ion CH2=C=CH-
John M. Oakes and G. Barney Ellison
pp 2969 - 2975; DOI:
10.1021/ja00348a008
PDF
Dynamic and structural properties of polymerized phosphatidylcholine vesicle membranes
Akihiro Kusumi, Maninder Singh, David A. Tirrell, Gunther Oehme, Alok Singh, N. K. P. Samuel, James S. Hyde, and Steven L. Regen
pp 2975 - 2980; DOI:
10.1021/ja00348a009
PDF
Theory and application of photoelectron spectroscopy. 99. Low non-Koopmans' ion states of unsaturated hydrocarbons. Semiempirical PERTCI calculations
Reinhard Schulz, Armin Schweig, and Werner Zittlau
pp 2980 - 2984; DOI:
10.1021/ja00348a010
PDF
Reversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediate
Paul N. Becker and Robert G. Bergman
pp 2985 - 2995; DOI:
10.1021/ja00348a011
PDF
Charge density and bonding in (5,10,15,20-tetramethylporphyrinato)nickel(II): a combined experimental and theoretical study
F. W. Kutzler, P. N. Swepston, Ziva Berkovitch-Yellin, D. E. Ellis, and James A. Ibers
pp 2996 - 3004; DOI:
10.1021/ja00348a012
PDF
Molecular properties of 1,N6-ethenoadenosine in comparison with adenosine: self-association, protonation, metal ion complexation, and tryptophan-adduct formation. A study on .epsilon.-adenosine using proton nuclear magnetic resonance, ultraviolet spectrophotometry, and potentiometric pH titration
Kurt H. Scheller and Helmut Sigel
pp 3005 - 3014; DOI:
10.1021/ja00348a013
PDF
Preparation and properties of dinitrogen trimethylphosphine complexes of molybdenum and tungsten. 4. Synthesis, chemical properties, and x-ray structure of cis-[Mo(N2)2(PMe3)4]. The crystal and molecular structures of trans-[Mo(C2H4)2(PMe3)4] and trans,mer-[Mo(C2H4)2(CO)(PMe3)3]
Ernesto Carmona, Jose M. Marin, Manuel L. Poveda, Jerry L. Atwood, and Robin D. Rogers
pp 3014 - 3022; DOI:
10.1021/ja00348a014
PDF
Steric and electronic influences of methyl substitution on transition-metal complexes of tetrabenzo[b,f,j,n][1,5,9,13]tetraazacyclohexadecine
Alan J. Jircitano, Robert I. Sheldon, and Kristin Bowman Mertes
pp 3022 - 3027; DOI:
10.1021/ja00348a015
PDF
Methyl-substituted tribenzo[b,f,j][1,5,9]triazacycloduodecine with copper(II) ion: a dynamic Jahn-Teller effect
Robert I. Sheldon, Alan J. Jircitano, Mark A. Beno, Jack M. Williams, and Kristin Bowman Mertes
pp 3028 - 3031; DOI:
10.1021/ja00348a016
PDF
ESR studies of the redox orbitals in diimine complexes of iron(II) and ruthenium(II)
David E. Morris, Kenneth W. Hanck, and M. Keith DeArmond
pp 3032 - 3038; DOI:
10.1021/ja00348a017
PDF
Synthesis and characterization of the "pocket" porphyrins
James P. Collman, John I. Brauman, Terrence J. Collins, Brent L. Iverson, George Lang, Roger B. Pettman, Jonathan L. Sessler, and Marc A. Walters
pp 3038 - 3052; DOI:
10.1021/ja00348a018
PDF
Dioxygen and carbonyl binding to iron(II) porphyrins: a comparison of the "picket fence" and "pocket" porphyrins
James P. Collman, John I. Brauman, Brent L. Iverson, Jonathan L. Sessler, Roger M. Morris, and Quentin H. Gibson
pp 3052 - 3064; DOI:
10.1021/ja00348a019
PDF
Photochemistry of [W(CO)5{C(OMe)Ph}]. Formation of alkyne-carbene complexes and studies of their decomposition reactions
Henry C. Foley, Leslie M. Strubinger, Tom S. Targos, and Gregory L. Geoffroy
pp 3064 - 3073; DOI:
10.1021/ja00348a020
PDF
Surface organometallic chemistry: reactivity of silica-bound rhodium allyl complexes and the genesis of highly dispersed supported rhodium catalysts
H. C. Foley, S. J. DeCanio, K. D. Tau, K. J. Chao, J. H. Onuferko, Cecil Dybowski, and B. C. Gates
pp 3074 - 3082; DOI:
10.1021/ja00348a021
PDF
A molecular orbital calculation of the octachlorodirhenate(2-) ion by the relativistic SCF-X.alpha.-SW method. Redetermination and reassignment of the electronic absorption spectrum
Bruce E. Bursten, F. Albert Cotton, Phillip E. Fanwick, and George G. Stanley
pp 3082 - 3087; DOI:
10.1021/ja00348a022
PDF
Alcohol exchange and oxidation reactions of doubly bonded ditungsten(IV) complexes of the type W2Cl4(OR)4(ROH)2: the structural identification of novel hydrogen-bonded bridging systems
F. Albert Cotton, Larry R. Falvello, Michael F. Fredrich, David DeMarco, and Richard A. Walton
pp 3088 - 3097; DOI:
10.1021/ja00348a023
PDF
Oxidation of tris(1,10-phenanthroline)iron(II) by chlorine dioxide
Lynn A. Lednicky and David M. Stanbury
pp 3098 - 3101; DOI:
10.1021/ja00348a024
PDF
Vanadium(V) peroxy complexes. New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons
Hubert Mimoun, Lucien Saussine, Eric Daire, Michele Postel, Jean Fischer, and Raymond Weiss
pp 3101 - 3110; DOI:
10.1021/ja00348a025
PDF
Theoretical studies in the norbornadiene-quadricyclane system
Krishnan Raghavachari, Robert C. Haddon, and Heinz D. Roth
pp 3110 - 3114; DOI:
10.1021/ja00348a026
PDF
One-electron oxidation of tetrasubstituted hydrazides and dihydrazides
Stephen F. Nelsen, Silas C. Blackstock, and Daniel T. Rumack
pp 3115 - 3119; DOI:
10.1021/ja00348a027
PDF
Comparison of free energy changes for nitrogen inversion and electron loss for some amino nitrogen compounds
Stephen F. Nelsen, Glen T. Cunkle, Peter M. Gannett, Joseph T. Ippoliti, and Richard J. Qualy
pp 3119 - 3123; DOI:
10.1021/ja00348a028
PDF
Chemistry of oxaziridines. 4. Asymmetric epoxidation of unfunctionalized alkenes using chiral 2-sulfonyloxaziridines: evidence for a planar transition state geometry
Franklin A. Davis, Mark E. Harakal, and Sami B. Awad
pp 3123 - 3126; DOI:
10.1021/ja00348a029
PDF
Electronic control of stereoselectivity. 14. Long-range control by norbornane frameworks of cyclopentadienide reactivity. Stereoselective capture of electrophiles by tricyclo[5.2.1.02,6]deca-3,8-dienyl anions
Leo A. Paquette, Pana Charumilind, Tina M. Kravetz, Michael C. Boehm, and Rolf Gleiter
pp 3126 - 3135; DOI:
10.1021/ja00348a030
PDF
Electronic control of stereoselectivity. 15. Stereoselectivity of Diels-Alder cycloadditions to norbornyl- and norbornenyl-fused spirocyclic cyclopentadiene systems
Leo A. Paquette, Pana Charumilind, Michael C. Boehm, Rolf Gleiter, Lawrence S. Bass, and Jon Clardy
pp 3136 - 3147; DOI:
10.1021/ja00348a031
PDF
Electronic control of stereoselectivity. 16. Role of pendant methyl groups in controlling the rate and stereochemical outcome of Diels-Alder additions to tricyclo[5.2.1.02,6]decadienes and -trienes
Leo A. Paquette, Peter C. Hayes, Pana Charumilind, Michael C. Boehm, Rolf Gleiter, and John F. Blount
pp 3148 - 3161; DOI:
10.1021/ja00348a032
PDF
Ground states of molecules. 61. Relative stabilities of o-, m-, and p-benzyne
Michael J. S. Dewar, George P. Ford, and Charles H. Reynolds
pp 3162 - 3167; DOI:
10.1021/ja00348a033
PDF
Kinetics of breakdown of the tetrahedral intermediate of an O,S-acyl transfer reaction
Linda J. Santry and Robert A. McClelland
pp 3167 - 3172; DOI:
10.1021/ja00348a034
PDF
Structural studies of sodium channel neurotoxins. 2. Crystal structure and absolute configuration of veratridine perchlorate
Penelope W. Codding
pp 3172 - 3176; DOI:
10.1021/ja00348a035
PDF
Plant anticancer agents. 28. New antileukemic jatrophone derivatives from Jatropha gossypiifolia: structural and stereochemical assignment through nuclear magnetic resonance spectroscopy
Michael D. Taylor, Amos B. Smith, III, George T. Furst, Sarath P. Gunasekara, Carolyn A. Bevelle, Geoffrey A. Cordell, Norman R. Farnsworth, S. Morris Kupchan, Hsuo Uchida, and et al.
pp 3177 - 3183; DOI:
10.1021/ja00348a036
PDF
Mechanisms of elimination reactions. 36. Stereochemistry and transition-state structure in eliminations from primary alkyltrimethylammonium salts
Yu Tai Tao and William H. Saunders
pp 3183 - 3188; DOI:
10.1021/ja00348a037
PDF
Heterogeneous permanganate oxidations. 3. Mechanism of the oxidation of alcohols by hydrated copper permanganate
Donald G. Lee and N. A. Noureldin
pp 3188 - 3191; DOI:
10.1021/ja00348a038
PDF
Electron-transfer reactions in organic chemistry. 4. A mechanistic study of the oxidation of p-methoxytoluene by 12-tungstocobalt(III)ate ion
Lennart Eberson
pp 3192 - 3199; DOI:
10.1021/ja00348a039
PDF
Formation of superoxide ion via one-electron transfer from electron donors to singlet oxygen
Isao Saito, Teruo Matsuura, and Kenzo Inoue
pp 3200 - 3206; DOI:
10.1021/ja00348a040
PDF
Intermolecular interactions of the carbon-fluorine bond: the crystallographic environment of fluorinated carboxylic acids and related structures
Peter Murray-Rust, William C. Stallings, Claire T. Monti, Robert K. Preston, and Jenny P. Glusker
pp 3206 - 3214; DOI:
10.1021/ja00348a041
PDF
Regioselective functionalization of bicyclic piperazinedione bridgehead carbanions
Robert M. Williams, Jen Sen Dung, John Josey, Robert Armstrong, and Harold Meyers
pp 3214 - 3220; DOI:
10.1021/ja00348a042
PDF
Acid-catalyzed hydrolysis of 1,1-bis(methylthio)ethene. Buffer- and thiol-dependent changes in the rate-determining step
Tadashi Okuyama, Shoji Kawao, and Takayuki Fueno
pp 3220 - 3226; DOI:
10.1021/ja00348a043
PDF
Photochemical transformations. 33. Some studies of the photorearrangements of dibenzobarrelenes. A novel excitation-transfer relay mechanism
Stanley J. Cristol, Russell L. Kaufman, Sumittada Malasanta Opitz, Wojciech Szalecki, and Thomas H. Bindel
pp 3226 - 3234; DOI:
10.1021/ja00348a044
PDF
9a-Hydro-9a-methyl-9-anthracenone - a molecule with fused blocked aromatic rings
Bernard Miller and Ajit K. Bhattacharya
pp 3234 - 3242; DOI:
10.1021/ja00348a045
PDF
Rearrangement and fragmentation reactions of blocked aromatic alcohols
Ajit K. Bhattacharya and Bernard Miller
pp 3242 - 3247; DOI:
10.1021/ja00348a046
PDF
Synthesis of a cyclic analog of oxidized glutathione by an intersite reaction in a swollen polymer network
Kuldeep K. Bhargava, Virender K. Sarin, Nguyen Le Trang, Anthony Cerami, and R. B. Merrifield
pp 3247 - 3251; DOI:
10.1021/ja00348a047
PDF
Syntheses of chiral cyclohexylidenepropenes and cyclohexylideneacetaldehydes
M. Duraisamy and H. M. Walborsky
pp 3252 - 3264; DOI:
10.1021/ja00348a048
PDF
Chiroptical properties of planar acyclic 1,3-dienes and .alpha.,.beta.-unsaturated aldehydes: a planar diene rule
M. Duraisamy and H. M. Walborsky
pp 3264 - 3269; DOI:
10.1021/ja00348a049
PDF
Circular dichroism of isomeric 10,19-dihydrovitamin D
M. Duraisamy and H. M. Walborsky
pp 3270 - 3273; DOI:
10.1021/ja00348a050
PDF
A new 2-azatricyclo[4.4.0.02,8]decenone synthesis and ketene formation by retro-Diels-Alder reaction
Arthur G. Schultz, James P. Dittami, Sun Ok Myong, and Chin Kang Sha
pp 3273 - 3279; DOI:
10.1021/ja00348a051
PDF
Synthesis of a dodecahydro-18,21-dioxoniakekulene
Alan R. Katritzky and Charles M. Marson
pp 3279 - 3283; DOI:
10.1021/ja00348a052
PDF
Synthesis and photoreactivity of cholesteryl diazoacetate: a novel photolabeling reagent
Sue A. Keilbaugh and Edward R. Thornton
pp 3283 - 3286; DOI:
10.1021/ja00348a053
PDF
Symmetrical monothiopyrophosphate
David I. Loewus and Fritz Eckstein
pp 3287 - 3292; DOI:
10.1021/ja00348a054
PDF
Absolute rate constants for the addition of triethylsilyl radicals to various unsaturated compounds
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano
pp 3292 - 3296; DOI:
10.1021/ja00348a055
PDF
Models for compounds I of peroxidases: axial ligand effects
Ichiro Fujita, Louise Karle Hanson, F. Ann Walker, and Jack Fajer
pp 3296 - 3300; DOI:
10.1021/ja00348a056
PDF
Methylglyoxal synthase uses the trans isomer of triose-1,2-enediol 3-phosphate
Radha Iyengar and Irwin A. Rose
pp 3301 - 3303; DOI:
10.1021/ja00348a057
PDF
High- and low-potential flavin mimics (based on the pyrimidino[5,4-g]pteridine and imidazo[4,5-g]pteridine system). 1. General chemistry
Edward B. Skibo and Thomas C. Bruice
pp 3304 - 3315; DOI:
10.1021/ja00348a058
PDF
High- and low-potential flavin mimics. 2. 3,7,10-Trimethyl-(1H,3H,5H,7H,9H,10H)-pyrimido[5,4-g]pteridine-2,4,6,8-tetrone dianion reduction of carbonyl, nicotinamides, and alkyl disulfide functional groups
Edward B. Skibo and Thomas C. Bruice
pp 3316 - 3328; DOI:
10.1021/ja00348a059
PDF
Kinetic studies of intramolecular excimer formation in dipyrenylalkanes
M. J. Snare, P. J. Thistlethwaite, and K. P. Ghiggino
pp 3328 - 3332; DOI:
10.1021/ja00348a060
PDF
Low-temperature carbon-13 magnetic resonance in solids. 2. Six .pi.-electron ring systems: tropylium cation (C7H7+), benzene (C6H6) and cyclopentadienide anion (C5H5-)
Henri Strub, Alvin J. Beeler, David M. Grant, Josef Michl, Peter W. Cutts, and Kurt W. Zilm
pp 3333 - 3334; DOI:
10.1021/ja00348a061
PDF
Biosynthesis of mevinolin. Spectral assignment by double-quantum coherence NMR after high carbon-13 incorporation
Jean K. Chan, Richard N. Moore, Thomas T. Nakashima, and John C. Vederas
pp 3334 - 3336; DOI:
10.1021/ja00348a062
PDF
First synthesis of stannacyclobutanes
J. W. F. L. Seetz, G. Schat, O. S. Akkerman, and F. Bickelhaupt
pp 3336 - 3337; DOI:
10.1021/ja00348a063
PDF
Oxygenation of chloroalkenes by superoxide in aprotic media
Thomas S. Calderwood, Robert C. Neuman, and Donald T. Sawyer
pp 3337 - 3339; DOI:
10.1021/ja00348a064
PDF
Transient absorption study of the intramolecular excited-state and ground-state proton transfer in 3-hydroxyflavone and 3-hydroxychromone
Michiya Itoh, Yoshifumi Tanimoto, and Kunihiro Tokumura
pp 3339 - 3340; DOI:
10.1021/ja00348a065
PDF
Sequential mechanism in the oxidative demetalation of a trimethylenemethane-iron tricarbonyl complex, tricarbonyl[((1-3,6-.eta.)-2-methylenecyclopentane-1,3-diyl]iron
James A. Mondo and Jerome A. Berson
pp 3340 - 3341; DOI:
10.1021/ja00348a066
PDF
Platinum-195 NMR investigation of the head-to-head to head-to-tail isomerization of .alpha.-pyridonate-bridged ethylenediamineplatinum(II) dimer
Thomas V. O'Halloran and Stephen J. Lippard
pp 3341 - 3342; DOI:
10.1021/ja00348a067
PDF
On the stereo- and regioselectivity of molybdenum-catalyzed allylic alkylations. Stereocontrolled approach to quaternary carbons and tandem alkylation-cycloaddition
Barry M. Trost and Mark Lautens
pp 3343 - 3344; DOI:
10.1021/ja00348a068
PDF
Lewis acid catalysis of coumarin photodimerization
Frederick D. Lewis, Daniel K. Howard, and Joe D. Oxman
pp 3344 - 3345; DOI:
10.1021/ja00348a069
PDF
Total synthesis of racemic isochorismic acid
Frank R. Busch and Glenn A. Berchtold
pp 3346 - 3347; DOI:
10.1021/ja00348a070
PDF
When is allylic resonance unimportant?
David Feller, Ernest R. Davidson, and Weston Thatcher Borden
pp 3347 - 3348; DOI:
10.1021/ja00348a071
PDF
Practical method for .alpha.-alkenyl ketone synthesis based on a facile reductive rearrangement of alkynyl halohydrins
Paul A. Wender, Dennis A. Holt, and Scott M. Sieburth
pp 3348 - 3350; DOI:
10.1021/ja00348a072
PDF
Observation of a reversible adsorbed redox couple using surface-enhanced Raman scattering: pentaammine(pyridine)osmium(III)/(II) at silver electrodes
Stuart Farquharson, Michael J. Weaver, Peter A. Lay, Roy H. Magnuson, and Henry Taube
pp 3350 - 3351; DOI:
10.1021/ja00348a073
PDF
Circularly polarized fluorescence of aromatic poly(.alpha.-amino acids)
Masahiko Sisido, Syun Egusa, Akira Okamoto, and Yukio Imanishi
pp 3351 - 3352; DOI:
10.1021/ja00348a074
PDF
Fischer-Tropsch intermediates: tris[(.eta.2-formaldehyde)zirconocene] from the carbonylation of a zirconium hydride
Kurt Kropp, Volker Skibbe, Gerhard Erker, and Carl Krueger
pp 3353 - 3354; DOI:
10.1021/ja00348a075
PDF
Observation of coordinatively unsaturated intermediates following the pulsed UV photolysis of iron pentacarbonyl (Fe(CO)5)
A. J. Ouderkirk, Paul Wermer, N. L. Schultz, and Eric Weitz
pp 3354 - 3355; DOI:
10.1021/ja00348a076
PDF
Phosphoryl transfer between pyridines
Mark T. Skoog and William P. Jencks
pp 3356 - 3357; DOI:
10.1021/ja00348a077
PDF
The question of concerted or stepwise mechanisms in phosphoryl group (-PO32-) transfer to pyridines from isoquinolin-N-phosphonate
Nicholas Bourne and Andrew Williams
pp 3357 - 3358; DOI:
10.1021/ja00348a078
PDF
Preassociation concerted mechanism for sulfate group (-SO3-) transfer between isoquinoline-N-sulfonate and substituted pyridines
Andrew Hopkins, Nicholas Bourne, and Andrew Williams
pp 3358 - 3359; DOI:
10.1021/ja00348a079
PDF
Chemistry of organosilicon compounds. 167. 3,4,7,8-Tetrasilacycloocta-1,5-diyne, 3,6,7-trisilacyclohepta-1,4-diyne and related compounds. New class of cyclic compounds composed of polysilanes and acetylenes
Hideki Sakurai, Yasuhiro Nakadaira, Akira Hosomi, Yuichi Eriyama, and Chizuko Kabuto
pp 3359 - 3360; DOI:
10.1021/ja00348a080
PDF
A stereorational synthesis of optically active trans-cycloalkenes and [10.10]betweenanene
James A. Marshall and Katherine E. Flynn
pp 3360 - 3362; DOI:
10.1021/ja00348a081
PDF
Ruthenium and osmium thiolate compounds
Stephen A. Koch and Michelle Millar
pp 3362 - 3363; DOI:
10.1021/ja00348a082
PDF
Detection of hydrogen bonding in peptide by 13C[1H] nuclear Overhauser effect
M. Abu Khaled and Charles L. Watkins
pp 3363 - 3365; DOI:
10.1021/ja00348a083
PDF
Reaction of cis-[Mo(N2)2(PMe3)4] with carbon dioxide. Synthesis and characterization of products of disproportionation and the x-ray structure of a tetrametallic mixed-valence Mo(II)-Mo(V) carbonate with a novel mode of carbonate binding
Ernesto Carmona, Francisco Gonzalez, Manuel L. Poveda, Jose M. Marin, Jerry L. Atwood, and Robin D. Rogers
pp 3365 - 3366; DOI:
10.1021/ja00348a084
PDF
Anion ordering in mixed valence dicesium hexachloroantimonate (Cs2SbCl6) and related salts
Kosmos Prassides, Peter Day, and Anthony K. Cheetham
pp 3366 - 3368; DOI:
10.1021/ja00348a085
PDF
Syntheses and structures of anionic closo-rhodacarborane clusters that contain a formal rhodium(I) vertex
John A. Walker, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 3368 - 3369; DOI:
10.1021/ja00348a086
PDF
1,3-Dipolar cycloaddition reactions of low-valent metal-carbonyl complexes with arylnitrile N-oxides
John A. Walker, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 3370 - 3371; DOI:
10.1021/ja00348a087
PDF
Book Reviews

pp 3371 - 3374; DOI:
10.1021/ja00348a600
PDF

Issue 11


Applications of MCD spectroscopy: MO ordering and transannular interaction in 1,6-methano[10]annulenes from analysis of substituent effects
Kenneth A. Klingensmith, Wilhelm Puettmann, Emanuel Vogel, and Josef Michl
pp 3375 - 3380; DOI:
10.1021/ja00349a001
PDF
Cryochemical studies. 3. EPR studies of the reaction of group IB metal atoms with arenes at 77 K with a rotating cryostat
A. J. Buck, B. Mile, and J. A. Howard
pp 3381 - 3387; DOI:
10.1021/ja00349a002
PDF
CI study of geometrical relaxation in the ground and excited singlet and triplet states of unprotonated Schiff bases: allylidenimine and formaldimine
V. Bonacic-Koutecky and M. Persico
pp 3388 - 3395; DOI:
10.1021/ja00349a003
PDF
Haptotropic rearrangements of polyene-MLn complexes. 2. Bicyclic polyene-MCp, M(CO)3 systems
Thomas A. Albright, Peter Hofmann, Roald Hoffmann, C. Peter Lillya, and Paul A. Dobosh
pp 3396 - 3411; DOI:
10.1021/ja00349a004
PDF
Nuclear spin-spin coupling via nonbonded interactions. 5. The orientational dependence of .alpha.-substituent effects on vicinal carbon-13-carbon-13 coupling constants
M. Barfield, E. D. Canada, C. R. McDaniel, J. L. Marshall, and S. R. Walter
pp 3411 - 3417; DOI:
10.1021/ja00349a005
PDF
Site of protonation and conformational effects on gas-phase basicity in .beta.-amino alcohols. The nature of internal hydrogen bonding in .beta.-hydroxy ammonium ions
Raymond Houriet, Hermann Ruefenacht, Pierre Alain Carrupt, Pierre Vogel, and Milos Tichy
pp 3417 - 3422; DOI:
10.1021/ja00349a006
PDF
Chemistry of singlet oxygen. 42. Effect of solvent, solvent isotopic substitution, and temperature on the lifetime of singlet molecular oxygen (1.DELTA.g)
Peter R. Ogilby and Christopher S. Foote
pp 3423 - 3430; DOI:
10.1021/ja00349a007
PDF
Negative ion states of 3d metallocenes
Judith C. Giordan, John H. Moore, John A. Tossell, and Jacques Weber
pp 3431 - 3433; DOI:
10.1021/ja00349a008
PDF
A molecular orbital study of model cytochrome P450 oxidation of tetrachloromethane and trichloromethane
Andrew T. Pudzianowski, Gilda H. Loew, Bruce A. Mico, Richard V. Branchflower, and Lance R. Pohl
pp 3434 - 3438; DOI:
10.1021/ja00349a009
PDF
Ab initio studies of molecular geometries. 27. Optimized molecular structures and conformational analysis of N.alpha.-acetyl-N-methylalaninamide and comparison with peptide crystal data and empirical calculations
J. N. Scarsdale, C. Van Alsenoy, V. J. Klimkowski, Lothar Schaefer, and Frank A. Momany
pp 3438 - 3445; DOI:
10.1021/ja00349a010
PDF
Gas-phase derivatization for determination of the structures of C3H5+ ions
J. O. Lay and M. L. Gross
pp 3445 - 3451; DOI:
10.1021/ja00349a011
PDF
Energetics and structures of organosulfur ions: CH3SSCH3+, CH3SS+, C2H5S+, and CH2SH+
James J. Butler, Tomas Baer, and Slayton A. Evans
pp 3451 - 3455; DOI:
10.1021/ja00349a012
PDF
Kinetic parameters for a system at equilibrium from the time course of luminescence emission: a new probe of equilibrium dynamics. Excited-state europium(III) as a species label
William D. Horrocks, Valerie K. Arkle, Frank J. Liotta, and Daniel R. Sudnick
pp 3455 - 3459; DOI:
10.1021/ja00349a013
PDF
Curve crossing in the cyclic voltammetric oxidation of 2-phenylnorbornene. Evidence for an ECE reaction pathway
Marye Anne Fox and Ryoichi Akaba
pp 3460 - 3463; DOI:
10.1021/ja00349a014
PDF
Pulsed laser photoacoustic calorimetry of metastable species
Lewis J. Rothberg, John D. Simon, Mark Bernstein, and Kevin S. Peters
pp 3464 - 3468; DOI:
10.1021/ja00349a015
PDF
Adsorption and hydrogenation of acetylene on copper Cu(110) and Cu(110)-O surfaces
Duane A. Outka, C. M. Friend, Scott Jorgensen, and R. J. Madix
pp 3468 - 3472; DOI:
10.1021/ja00349a016
PDF
Role of triplet-triplet annihilation in anthracene dimerization
James L. Charlton, Reza Dabestani, and Jack Saltiel
pp 3473 - 3476; DOI:
10.1021/ja00349a017
PDF
Iron and molybdenum extended x-ray absorption fine structure studies of double-cubane clusters containing molybdenum iron sulfide (MoFe3S4) cores
Mark R. Antonio, Boon Keng Teo, Walter E. Cleland, and Bruce A. Averill
pp 3477 - 3484; DOI:
10.1021/ja00349a018
PDF
Energy disposal in the photofragmentation of pyruvic acid in the gas phase
Robert N. Rosenfeld and Brad Weiner
pp 3485 - 3488; DOI:
10.1021/ja00349a019
PDF
Raman and infrared spectra of binuclear platinum(II) and platinum(III) octaphosphite complexes. A characterization of the intermetallic bonding
Paul Stein, Mark K. Dickson, and D. Max Roundhill
pp 3489 - 3494; DOI:
10.1021/ja00349a020
PDF
Synthesis, structure, and platinum-195 NMR studies of binuclear complexes of cis-diammineplatinum(II) with bridging .alpha.-pyridonate ligands
L. Steven Hollis and Stephen J. Lippard
pp 3494 - 3503; DOI:
10.1021/ja00349a021
PDF
Concerning the structure and stability of a copper(I) alkoxy carbonyl
Rolf L. Geerts, John C. Huffman, Kirsten Folting, Timothy H. Lemmen, and Kenneth G. Caulton
pp 3503 - 3506; DOI:
10.1021/ja00349a022
PDF
A bis-pocket porphyrin
Kenneth S. Suslick and Mary M. Fox
pp 3507 - 3510; DOI:
10.1021/ja00349a023
PDF
Isolation, purification, and characterization of intermediate (iodosylbenzene)metalloporphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon functionalization system
John A. Smegal, Bruce C. Schardt, and Craig L. Hill
pp 3510 - 3515; DOI:
10.1021/ja00349a024
PDF
Hydrocarbon functionalization by the (iodosylbenzene)manganese(IV) porphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon oxidation system. Mechanism and reaction chemistry
John A. Smegal and Craig L. Hill
pp 3515 - 3521; DOI:
10.1021/ja00349a025
PDF
Copper(I)-olefin complexes. Support for the proposed role of copper in the ethylene effect in plants
Jeffery S. Thompson, Richard L. Harlow, and John F. Whitney
pp 3522 - 3527; DOI:
10.1021/ja00349a026
PDF
Chains of trans-edge-sharing molybdenum octahedra: metal-metal bonding in extended systems
Timothy Hughbanks and Roald Hoffmann
pp 3528 - 3537; DOI:
10.1021/ja00349a027
PDF
Specific oxidation of bis(chlorodicarbonylrhodium) by oxygen via the coordination of in situ generated hydrogen peroxide. Implications for the rhodium(III)/copper(III)-catalyzed oxygen oxidation of 1-alkenes to 2-ketones
Eric D. Nyberg, David C. Pribich, and Russell S. Drago
pp 3538 - 3544; DOI:
10.1021/ja00349a028
PDF
Activation of methane with metal atoms at 10 K without photolysis
Kenneth J. Klabunde and Yasutaka Tanaka
pp 3544 - 3546; DOI:
10.1021/ja00349a029
PDF
Coordinately unsaturated clusters. A novel catalytic reaction
R. R. Burch, A. J. Shusterman, E. L. Muetterties, R. G. Teller, and Jack M. Williams
pp 3546 - 3556; DOI:
10.1021/ja00349a030
PDF
Alicyclic reaction mechanisms. 6. Strain-reactivity relations as a tool for the localization of transition states. Equilibria, solvolysis, and redox reactions of substituted cycloalkanes
Hans Joerg Schneider, Guenther Schmidt, and Fred Thomas
pp 3556 - 3563; DOI:
10.1021/ja00349a031
PDF
Diazotetrakis(trifluoromethyl)cyclopentadiene and ylides of electronegative elements
Eugene P. Janulis and Anthony J. Arduengo
pp 3563 - 3567; DOI:
10.1021/ja00349a032
PDF
Theoretical studies of the tautomeric equilibriums and isomer energetics of 2-, 3-, and 4-hydroxypyridine
Martin J. Scanlan, Ian H. Hillier, and Alastair A. MacDowell
pp 3568 - 3571; DOI:
10.1021/ja00349a033
PDF
Isotopic perturbation effects on a single averaged NMR peak: norbornyl cation
Martin Saunders and Mandes R. Kates
pp 3571 - 3573; DOI:
10.1021/ja00349a034
PDF
Cation-anion combination reactions. 23. Solvent effects on rates and equilibria of reactions
Calvin D. Ritchie
pp 3573 - 3578; DOI:
10.1021/ja00349a035
PDF
Rate constants and Arrhenius parameters for the reaction of a primary alkyl radical with tributylgermanium hydride
J. Lusztyk, B. Maillard, D. A. Lindsay, and K. U. Ingold
pp 3578 - 3580; DOI:
10.1021/ja00349a036
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 41. Diethoxyphosphonyl radicals
M. Anpo, R. Sutcliffe, and K. U. Ingold
pp 3580 - 3583; DOI:
10.1021/ja00349a037
PDF
Theoretical analysis of selectivity in the cation radical Diels-Alder
Dennis J. Bellville, Nathan L. Bauld, Raul Pabon, and Steven A. Gardner
pp 3584 - 3588; DOI:
10.1021/ja00349a038
PDF
The 12-s-cis conformationally locked 11-cis-retinoids: a delineation of the thermal requirements for [1,5]-sigmatropic shifts and electrocyclizations in the vitamin A series and novel spectral properties
Roshantha A. S. Chandraratna, Ann L. Bayerque, and William H. Okamura
pp 3588 - 3594; DOI:
10.1021/ja00349a039
PDF
Unified stereochemical model of polyether antibiotic structure and biogenesis
David E. Cane, Walter D. Celmer, and John W. Westley
pp 3594 - 3600; DOI:
10.1021/ja00349a040
PDF
Dimerization mechanism of the 1-alkyl-4-phenylpyridinyl radicals generated from the photosensitive dimer as studied by kinetic ESR spectroscopy
Kimio Akiyama, Shozo Tero-Kubota, and Yusaku Ikegami
pp 3601 - 3604; DOI:
10.1021/ja00349a041
PDF
Triplet quenching by tert-butyl hydroperoxide
Laura C. Stewart, D. J. Carlsson, D. M. Wiles, and J. C. Scaiano
pp 3605 - 3609; DOI:
10.1021/ja00349a042
PDF
Phenyl radical kinetics
J. C. Scaiano and L. C. Stewart
pp 3609 - 3614; DOI:
10.1021/ja00349a043
PDF
Reaction of cumene with ozone to form cumyl hydrotrioxide and the kinetics of decomposition of cumyl hydrotrioxide
William A. Pryor, Norio Ohto, and Daniel F. Church
pp 3614 - 3622; DOI:
10.1021/ja00349a044
PDF
Uncatalyzed and general acid catalyzed decomposition of alkyl xanthates and monothiocarbonates in aqueous solutions
Robert J. Millican, Maria Angelopoulos, Anita Bose, Bram Riegel, Darlyne Robinson, and Carol K. Wagner
pp 3622 - 3630; DOI:
10.1021/ja00349a045
PDF
Stereochemical studies of the electrolytic reactions of organic compounds. 19. Electroorganic reactions on organic electrodes. 1. Asymmetric reduction of prochiral activated olefins on a poly-L-valine-coated graphite
Shigemitsu Abe, Tsutomu Nonaka, and Toshio Fuchigami
pp 3630 - 3632; DOI:
10.1021/ja00349a046
PDF
Isomerization of hexamethyl(Dewar benzene) to hexamethylbenzene catalyzed by electron acceptors. Thermal generation of an exciplex
Nancy J. Peacock and Gary B. Schuster
pp 3632 - 3638; DOI:
10.1021/ja00349a047
PDF
[2.1.1.]Propellane. Reaction of 1,4-diiodobicyclo[2.1.1]hexane with tert-butyllithium and with potassium atoms
Kenneth B. Wiberg, Frederick H. Walker, William E. Pratt, and Josef Michl
pp 3638 - 3641; DOI:
10.1021/ja00349a048
PDF
Electronic control of stereoselectivity. 19. Stereoselection in [4 + 2] cycloadditions to anti,anti-2,3-diethylidenenorbornane and -norbornene. Crystal structure analysis of double bond deformation in the adducts
Leo A. Paquette, Anthony G. Schaefer, and John F. Blount
pp 3642 - 3649; DOI:
10.1021/ja00349a049
PDF
A stable bromine(+) ion complex. A twisted bicyclo[2.2.2]octane derivative. Synthesis and structure of bis(quinuclidine)bromine(I) tetrafluoroborate
Larry K. Blair, Kevin D. Parris, Pwo Sen Hii, and Carolyn P. Brock
pp 3649 - 3653; DOI:
10.1021/ja00349a050
PDF
Synthesis of optically active pyrrolizidinediols: (+)-heliotridine
A. Richard Chamberlin and John Y. L. Chung
pp 3653 - 3656; DOI:
10.1021/ja00349a051
PDF
Total synthesis of leukotriene E4, a member of the SRS-A family
Michael Rosenberger, Christian Newkom, and Edward R. Aig
pp 3656 - 3661; DOI:
10.1021/ja00349a052
PDF
Enantiospecific syntheses of leukotrienes C4, D4, and E4, and [14,15-3H2]leukotriene E4 dimethyl ester
Noal Cohen, Bruce L. Banner, Rocco J. Lopresti, Frederick Wong, Michael Rosenberger, Yu Ying Liu, Edna Thom, and Arnold A. Liebman
pp 3661 - 3672; DOI:
10.1021/ja00349a053
PDF
Structure of the sodium and potassium ion activated adenosine triphosphatase inhibitor L-681,110
Otto D. Hensens, Richard L. Monaghan, Leeyuan Huang, and George Albers-Schonberg
pp 3672 - 3679; DOI:
10.1021/ja00349a054
PDF
The pH dependency of the zinc and cobalt carboxypeptidase catalyzed enolization of (R)-2-benzyl-3-(p-methoxybenzoyl)propionic acid
Thomas E. Spratt, Takuji Sugimoto, and E. T. Kaiser
pp 3679 - 3683; DOI:
10.1021/ja00349a055
PDF
Out-of-plane deformation modes in the resonance Raman spectra of metalloporphyrins and heme proteins
Sunhee Choi and Thomas G. Spiro
pp 3683 - 3692; DOI:
10.1021/ja00349a056
PDF
Resonance Raman and electronic spectra of heme a complexes and cytochrome oxidase
S. Choi, J. J. Lee, Y. H. Wei, and T. G. Spiro
pp 3692 - 3707; DOI:
10.1021/ja00349a057
PDF
Study of ion-pair return in 2-norbornyl brosylate by means of oxygen-17 NMR
Shoumo Chang and W. J. Le Noble
pp 3708 - 3709; DOI:
10.1021/ja00349a058
PDF
Total synthesis of (+)- and (-)-tryptoquivaline G by biomimetic double cyclization
Masako Nakagawa, Mikio Taniguchi, Mikiko Sodeoka, Manabu Ito, Keiichi Yamaguchi, and Tohru Hino
pp 3709 - 3710; DOI:
10.1021/ja00349a059
PDF
Homogeneous hydrogenolysis of carbon disulfide catalyzed by a molybdenum dimer with sulfido ligands
M. Rakowski DuBois
pp 3710 - 3711; DOI:
10.1021/ja00349a060
PDF
Isotopic multiplets in the proton-decoupled carbon-13 NMR spectra of carbohydrates with partially deuterated hydroxyls
Jacques Reuben
pp 3711 - 3713; DOI:
10.1021/ja00349a061
PDF
A 200% efficient electrolysis cell
Ray Jui Hsiang Chan, Chihiro Ueda, and Theodore Kuwana
pp 3713 - 3714; DOI:
10.1021/ja00349a062
PDF
Carbon-14 kinetic isotope effects and kinetic studies in the syn-elimination reactions of (2-phenylethyl)dimethylamine oxides
Daniel R. Wright, Leslie B. Sims, and Arthur Fry
pp 3714 - 3716; DOI:
10.1021/ja00349a063
PDF
Mild Lewis acid catalysis: tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium-mediated hetero-Diels-Alder reaction
M. Bednarski and S. Danishefsky
pp 3716 - 3717; DOI:
10.1021/ja00349a064
PDF
DNA major-minor groove binding specificity of daunorubicin: anthramycin-modified and T-4 bacteriophage DNA studies
Shau Fong Yen, Wayne Germon, and W. David Wilson
pp 3717 - 3719; DOI:
10.1021/ja00349a065
PDF
Diffuse reflectance infrared and photoluminescence spectra of surface vanadyl groups. Direct evidence for change of bond strength and electronic structure of metal-oxygen bond upon supporting oxide
Masakazu Iwamoto, Hiroshi Furukawa, Kazuto Matsukami, Toshihisa Takenaka, and Shuichi Kagawa
pp 3719 - 3720; DOI:
10.1021/ja00349a066
PDF
Vinyl radical cyclization. 2. Dicyclization via selective formation of unsaturated vinyl radicals by intramolecular addition to triple bonds. Applications to the synthesis of butenolides and furans
Gilbert Stork and Robert Mook
pp 3720 - 3722; DOI:
10.1021/ja00349a067
PDF
Design, preparation and ESR detection of a ground-state nonet hydrocarbon as a model for one-dimensional organic ferromagnets
Yoshio Teki, Takeji Takui, Koichi Itoh, Hiizu Iwamura, and Kazumasa Kobayashi
pp 3722 - 3723; DOI:
10.1021/ja00349a068
PDF
Contrasting ESR and UV spectroscopic properties and reactivities between the conformationally restricted o-(9-fluorenyl)phenylnitrenes at cryogenic temperatures
Shigeru Murata, Tadashi Sugawara, and Hiizu Iwamura
pp 3723 - 3724; DOI:
10.1021/ja00349a069
PDF
Migration of tricarbonylchromium groups in phenylanthracenes
Scott D. Cunningham, Karl Ofele, and Bennett R. Willeford
pp 3724 - 3725; DOI:
10.1021/ja00349a070
PDF
Stereochemistry of hydroboration of .alpha.-chiral olefins and reduction of .alpha.-chiral ketones. An unusual anti-Cram selectivity with dialkylboranes
M. Mark Midland and Young C. Kwon
pp 3725 - 3727; DOI:
10.1021/ja00349a071
PDF
Organometallic nitrosyl chemistry. 18. Electrophile-induced reduction of coordinated nitrogen monoxide. Sequential conversion of a .mu.3-nitrosyl group to .mu.3-hydroxylimido and .mu.3-imido ligands by protonic acids
Peter Legzdins, Charles R. Nurse, and Steven J. Rettig
pp 3727 - 3728; DOI:
10.1021/ja00349a072
PDF
Atomic fits to electron densities in polyatomic molecules. Correlation of atom size and charge
Robert F. Hout and Warren J. Hehre
pp 3728 - 3729; DOI:
10.1021/ja00349a073
PDF
Direct observation of radical-pair interaction and decay in anionic micelles. A time-resolved electron spin echo study
M. C. Thurnauer and D. Meisel
pp 3729 - 3731; DOI:
10.1021/ja00349a074
PDF
Carbon-13 NMR evidence of carbinolamine formation at the active site of an imine-forming aldolase
Bruce David Ray, Edwin T. Harper, and Wilmer K. Fife
pp 3731 - 3732; DOI:
10.1021/ja00349a075
PDF
Synthetic studies on the taxane diterpenes. Utility of the intramolecular Diels-Alder reaction for a single-step, stereocontrolled synthesis of a taxane model system
Kunio Sakan and Bryan M. Craven
pp 3732 - 3734; DOI:
10.1021/ja00349a076
PDF
Reactions of tert-butyl isocyanide with a binuclear niobium(III) compound
F. Albert Cotton and Wieslaw J. Roth
pp 3734 - 3735; DOI:
10.1021/ja00349a077
PDF
Nondegenerate mirror-image rearrangement semibullvalene in the solid state
V. Macho, R. D. Miller, and C. S. Yannoni
pp 3735 - 3737; DOI:
10.1021/ja00349a078
PDF
Synthesis and structure of an .eta.2-phosphaalkene nickel complex
A. H. Cowley, R. A. Jones, C. A. Stewart, A. L. Stuart, J. L. Atwood, W. E. Hunter, and H. M. Zhang
pp 3737 - 3738; DOI:
10.1021/ja00349a079
PDF
Crown thioether chemistry. The nickel(II) complex of 1,4,7,10,13,16-hexathiacyclooctadecane, the hexathia analogue of 18-crown-6
Eric J. Hintsa, JudithAnn R. Hartman, and Stephen R. Cooper
pp 3738 - 3739; DOI:
10.1021/ja00349a080
PDF
Sesbanimide, a potent antitumor substance from Sesbania drummondii seed
Richard G. Powell, Cecil R. Smith, David Weisleder, Gayle Matsumoto, Jon Clardy, and John Kozlowski
pp 3739 - 3741; DOI:
10.1021/ja00349a081
PDF
Free-radical cyclization of bromo acetals. Use in the construction of bicyclic acetals and lactones
Gilbert Stork, Robert Mook, Scott A. Biller, and Scott D. Rychnovsky
pp 3741 - 3742; DOI:
10.1021/ja00349a082
PDF
Alkaline earth metal-ammonia-anion radical complexes
Gerald R. Stevenson and Laurel E. Schock
pp 3742 - 3743; DOI:
10.1021/ja00349a083
PDF
2-Oxoazetidine-1-phosphonic acids: synthesis and transesterification
W. H. Koster, R. Zahler, H. W. Chang, C. M. Cimarusti, G. A. Jacobs, and M. Perri
pp 3743 - 3745; DOI:
10.1021/ja00349a084
PDF
Additions and Corrections - Effect of Particle Size on the Activity of Supported Palladium Catalysts
Yoshio Takasu, Tsutomu Akimaru, Kenji Kasahara, Yoshiharu Matsuda, Hiroyuki Miura, and Isamu Toyoshima
pp 3745 - 3745; DOI:
10.1021/ja00349a601
PDF
Additions and Corrections - Effect of Electron Correlation on Theoretical Equilibrium Geometries. 2. Comparison of Third-Order Perturbation and Configuration Interaction Results with Experiment
Douglas J. DeFrees, Krishnan Ragavachari, H. Bernard Schlegel, and John A. Pople
pp 3745 - 3745; DOI:
10.1021/ja00349a602
PDF
Additions and Corrections - Micellar Effects upon Spontaneous Hydrolyses and Their Relation to Mechanism
H. Al-Lohedan, C. A. Bunton, and M. Mhala
pp 3745 - 3745; DOI:
10.1021/ja00349a603
PDF
Additions and Corrections - A Systematic Investigation on the Structure and Stability of the Lowest Singlet and Triplet States of Si2H4 and SiH3SiH and the Analogous Carbon Compounds SiH2CH2, SiH3CH, Ch3SiH, C2H4, and CH3CH
Hans Joachim Kohler, and Hans Lischka
pp 3745 - 3745; DOI:
10.1021/ja00349a604
PDF
Additions and Corrections - Selective Coupling of [(Alkythio)allyl]titanium Reagent with Carbonyl Compounds. Facile Entry to Alkenyl Oxiranes and 2-(Arylthio)-1,3-butadienes
Yoshihiko Ikeda, Kyoji Furuta, Noriyuki Meguriya, Nobuo Ikeda, and Hisashi Yamamoto
pp 3745 - 3745; DOI:
10.1021/ja00349a605
PDF
Book Reviews

pp 3746 - 3750; DOI:
10.1021/ja00349a600
PDF

Issue 12


Molybdenum K-edge extended x-ray absorption fine structure studies of synthetic molybdenum-iron-sulfur clusters containing the MoS4 unit: development of a fine adjustment technique based on models
Boon Keng Teo, Mark R. Antonio, and Bruce A. Averill
pp 3751 - 3762; DOI:
10.1021/ja00350a001
PDF
Quantum effects of high-frequency modes in inorganic electron transfer: kinetic isotope effects in redox reactions of hexaaquairon(2+) ion ([Fe(H2O)6]2+, hexa(aqua-d2)iron(2+) ion ([Fe(D2O)6]2+), and hexa(aqua-18O)iron(2+) ion ([Fe(18OH2)6]2+)
Tom Guarr, Ephraim Buhks, and George McLendon
pp 3763 - 3767; DOI:
10.1021/ja00350a002
PDF
Solid-state NMR studies of the reactions of silica surfaces with polyfunctional chloromethylsilanes and ethoxymethylsilanes
Dean W. Sindorf and Gary E. Maciel
pp 3767 - 3776; DOI:
10.1021/ja00350a003
PDF
Intermolecular potentials for the water-benzene and the benzene-benzene systems calculated in an ab initio SCFCI approximation
G. Karlstroem, P. Linse, A. Wallqvist, and B. Joensson
pp 3777 - 3782; DOI:
10.1021/ja00350a004
PDF
Mechanism of the gas-phase reaction of the benzene radical cation and various alkyl iodides
D. L. Miller and Michael L. Gross
pp 3783 - 3788; DOI:
10.1021/ja00350a005
PDF
Molecular structure of dinitrogen pentoxide in the gas phase. Large amplitude motion in a system of coupled rotors
Bruce W. McClelland, Lise Hedberg, Kenneth Hedberg, and Kolbjoern Hagen
pp 3789 - 3793; DOI:
10.1021/ja00350a006
PDF
High-pressure collisional activation mass spectrometry
Karl Blom and Burnaby Munson
pp 3793 - 3799; DOI:
10.1021/ja00350a007
PDF
EPR evidence on molecular and electronic structure of nitrogen trifluoride radical cation
Alvin M. Maurice, R. Linn Belford, Ira B. Goldberg, and Karl O. Christe
pp 3799 - 3802; DOI:
10.1021/ja00350a008
PDF
Ab initio SCF study of hyperfine couplings, geometries, and inversion barriers in the isoelectronic radicals NF3+, CF3, and BF3-
M. A. Benzel, A. M. Maurice, R. L. Belford, and C. E. Dykstra
pp 3802 - 3805; DOI:
10.1021/ja00350a009
PDF
Molecular and electronic structure of phosphonium cyclopropylide: a theoretical study
Mark A. Vincent, Henry F. Schaefer, Annette Schier, and Hubert Schmidbaur
pp 3806 - 3811; DOI:
10.1021/ja00350a010
PDF
Ab initio study of the hydration of ketenimine (CH2:C:NH) by water and water dimer
Nguyen Minh Tho and Anthony Hegarty
pp 3811 - 3815; DOI:
10.1021/ja00350a011
PDF
Lipophilic lithium ion carriers
Abraham Shanzer, David Samuel, and Rafi Kornstein
pp 3815 - 3818; DOI:
10.1021/ja00350a012
PDF
Nonexponential fluorescence decay of tryptophan, tryptophylglycine, and glycyltryptophan
Mary C. Chang, Jacob W. Petrich, Daniel B. McDonald, and Graham R. Fleming
pp 3819 - 3824; DOI:
10.1021/ja00350a013
PDF
On the origin of nonexponential fluorescence decay in tryptophan and its derivatives
J. W. Petrich, M. C. Chang, D. B. McDonald, and G. R. Fleming
pp 3824 - 3832; DOI:
10.1021/ja00350a014
PDF
Novel example of simultaneous double nitrogen inversion in the solid state
M. Kaftory
pp 3832 - 3836; DOI:
10.1021/ja00350a015
PDF
Anion radicals of bacteriochlorophylls c, d, and e. Likely electron acceptors in the primary photochemistry of green and brown photosynthetic bacteria
J. Fajer, I. Fujita, A. Forman, L. K. Hanson, G. W. Craig, D. A. Goff, L. A. Kehres, and K. M. Smith
pp 3837 - 3843; DOI:
10.1021/ja00350a016
PDF
Spectroscopic evidence for proton transfer within the bimolecular complex hydrogen iodide-ammonia trapped in cryogenic matrixes
L. Schriver, A. Schriver, and J. P. Perchard
pp 3843 - 3848; DOI:
10.1021/ja00350a017
PDF
Carbon-13 NMR of arylgermanes and arylgermyl anions. Main-group elements as anionic .pi.-donor substituents. 2
Raymond J. Batchelor and Thomas Birchall
pp 3848 - 3852; DOI:
10.1021/ja00350a018
PDF
Temperature-dependent single vs. double ionization in the mass spectra of phthalocyanine and its metal(II) complexes
Steven M. Schildcrout
pp 3852 - 3855; DOI:
10.1021/ja00350a019
PDF
Electronic structure and orbital interactions in linear monocarbonylplatinum
Harold Basch and Drora Cohen
pp 3856 - 3860; DOI:
10.1021/ja00350a020
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Electronic structure of alkylated imidazoles and electronic spectra of tetrakis(imidazole)copper(II) complexes. Molecular structure of tetrakis(1,4,5-trimethylimidazole)copper(II) diperchlorate
Ernest Bernarducci, Parimal K. Bharadwaj, Karsten Krogh-Jespersen, Joseph A. Potenza, and Harvey J. Schugar
pp 3860 - 3866; DOI:
10.1021/ja00350a021
PDF
Computational design of polylactone macrocyclic ionophores
Shneior Lifson, Clifford E. Felder, and Abraham Shanzer
pp 3866 - 3875; DOI:
10.1021/ja00350a022
PDF
Electrochemically induced generation of catalytic species for olefin metathesis from molybdenum and tungsten chlorides
Michel Gilet, Andre Mortreux, Jean Claude Folest, and Francis Petit
pp 3876 - 3881; DOI:
10.1021/ja00350a023
PDF
Formation of [(diphenylphosphino)cyclopentadienyl]thallium and its utility in the synthesis of heterobimetallic titanium-manganese complexes: the molecular structure of (.eta.5-cyclopentadienyl)dicarbonyl[(.eta.5-cyclopentadienyl)[.eta.5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium-P]manganese
Marvin D. Rausch, Bruce H. Edwards, Robin D. Rogers, and Jerry L. Atwood
pp 3882 - 3886; DOI:
10.1021/ja00350a024
PDF
Carbon dioxide activation by lithium metal. 1. Infrared spectra of lithium carbon dioxide (Li+CO2-), lithium oxalate (Li+C2O4-), and lithium carbon dioxide (Li22+CO22-) in inert-gas matrices
Z. H. Kafafi, R. H. Hauge, W. E. Billups, and J. L. Margrave
pp 3886 - 3893; DOI:
10.1021/ja00350a025
PDF
Asymmetric synthesis of (+)-2,2,3-trimethylhex-4-enal via nucleophilic attack on .eta.3-1,3-dimethylallyl complexes of molybdenum
J. W. Faller and Kuo Hua Chao
pp 3893 - 3898; DOI:
10.1021/ja00350a026
PDF
Synthesis and decay kinetics of tricarbonyldinitrogennickel (Ni(CO)3N2) in liquid krypton: approximate determination of the nickel-dinitrogen (Ni-N2) bond dissociation energy
James J. Turner, Michael B. Simpson, Martyn Poliakoff, and William B. Maier
pp 3898 - 3904; DOI:
10.1021/ja00350a027
PDF
Synthetic routes to iron sulfide (Fe2S2, Fe3S4, Fe4S4, and Fe6S9), clusters from the common precursor tetrakis(ethanethiolate)ferrate(2-) ion ([Fe(SC2H5)4]2-): structures and properties of [Fe3S4(SR)4]3- and bis(ethanethiolate)nonathioxohexaferrate(4-) ion ([Fe6S9(SC2H5)2]4-), examples of the newest types of Fe-S-SR clusters
Karl S. Hagen, Alan D. Watson, and R. H. Holm
pp 3905 - 3913; DOI:
10.1021/ja00350a028
PDF
Mechanistic aspects of a homogeneous carbon monoxide hydrogenation catalyst - tetrairidium dodecacarbonyl in molten aluminum chloride-sodium chloride
James P. Collman, John I. Brauman, Gerald Tustin, and Grady S. Wann
pp 3913 - 3922; DOI:
10.1021/ja00350a029
PDF
Kinetics and mechanism of the formation of nitrosoalkane complexes by migratory insertion of coordinated nitric oxide into cobalt-carbon bonds
Wayne P. Weiner and Robert G. Bergman
pp 3922 - 3929; DOI:
10.1021/ja00350a030
PDF
Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
Andrew H. Janowicz and Robert G. Bergman
pp 3929 - 3939; DOI:
10.1021/ja00350a031
PDF
Crystal and molecular structure of biacetyl (2,3-butanedione), (H3CCO)2, at -12 and -100.degree.C
K. Eriks, T. D. Hayden, S. Hsi Yang, and I. Y. Chan
pp 3940 - 3942; DOI:
10.1021/ja00350a032
PDF
An experimental and ab initio study of the addition of atomic carbon to water
Sheikh N. Ahmed, Michael L. McKee, and Philip B. Shevlin
pp 3942 - 3947; DOI:
10.1021/ja00350a033
PDF
Microwave structures of cyanocyclopropane and cyclopropylacetylene. Effects of cyclopropyl .pi. conjugation on structure
Marlin D. Harmony, R. N. Nandi, James V. Tietz, Jong-In Choe, Stephen J. Getty, and Stuart W. Staley
pp 3947 - 3951; DOI:
10.1021/ja00350a034
PDF
Photochemical reactivity in organized assemblies. 32. Photoreactivity of surfactant ketones as a probe of the microenvironment of organized media
Joseph R. Winkle, Paul R. Worsham, Kirk S. Schanze, and David G. Whitten
pp 3951 - 3956; DOI:
10.1021/ja00350a035
PDF
Kinetics of hydrolysis of some sterically hindered ketene acetals
A. Jerry Kresge and Thomas S. Straub
pp 3957 - 3961; DOI:
10.1021/ja00350a036
PDF
Protonation of diazomethane in superacid media
John F. McGarrity and D. Phillip Cox
pp 3961 - 3966; DOI:
10.1021/ja00350a037
PDF
Heavy atom isotope effect studies of elimination reaction mechanisms. 1. A kinetic and carbon-14 kinetic isotope effect study of the base-promoted dehydrochlorination of substituted 1-phenylethyl-2-14C chlorides
Tayyaba Hasan, Leslie B. Sims, and Arthur Fry
pp 3967 - 3975; DOI:
10.1021/ja00350a038
PDF
Priority of aromatic delocalization: electron distributions, chemical stability, and .sigma.-framework in conjugated polycycles
Abraham Minsky, Amatzya Y. Meyer, Klaus Hafner, and Mordecai Rabinovitz
pp 3975 - 3981; DOI:
10.1021/ja00350a039
PDF
High-pressure studies. 25. One-bond azo initiators. Thermal decomposition of substituted (phenylazo)triphenylmethanes
R. C. Neuman and G. D. Lockyer
pp 3982 - 3987; DOI:
10.1021/ja00350a040
PDF
Effect of pressure on the rates of sigmatropic shifts. Volume as an indication of a wide mechanistic range
E. M. Schulman, A. E. Merbach, M. Turin, R. Wedinger, and W. J. Le Noble
pp 3988 - 3991; DOI:
10.1021/ja00350a041
PDF
Carbon-13 magnetic resonance of hydroaromatics. II. Conformation of Tetralin and tetrahydroanthracene and their methyl derivatives
Frederick G. Morin, W. James Horton, David M. Grant, Don K. Dalling, and Ronald J. Pugmire
pp 3992 - 3998; DOI:
10.1021/ja00350a042
PDF
Ground- and excited-state carboxylate radical chain carriers. Radical chain substitution reactions with acyl hypohalites
Philip S. Skell and Donald D. May
pp 3999 - 4008; DOI:
10.1021/ja00350a043
PDF
Vinyl cations. 40. .pi.- and .sigma.-Routes to vinyl cations. Solvolyses of 2-methylcyclohexenyl, cyclopentylideneethyl, hex-5-yn-1-yl, and related triflates
Michael Hanack, Karl Albrecht Fuchs, and Clair J. Collins
pp 4008 - 4017; DOI:
10.1021/ja00350a044
PDF
1-Benzyl-1,4-dihydronicotinamide as a reagent for replacing aliphatic nitro groups by hydrogen. An electron-transfer chain reaction
Noboro Ono, Rui Tamura, and Aritsune Kaji
pp 4017 - 4022; DOI:
10.1021/ja00350a045
PDF
Concerted fragmentation of N-chloro-.alpha.-amino acid anions
Vincent C. Hand, Martin P. Snyder, and Dale W. Margerum
pp 4022 - 4025; DOI:
10.1021/ja00350a046
PDF
Oxidation reactions of phosphaalkenes
T. A. Van der Knaap, T. C. Klebach, R. Lourens, M. Vos, and F. Bickelhaupt
pp 4026 - 4032; DOI:
10.1021/ja00350a047
PDF
Factors affecting the absorption maxima of polyene iminium systems: a model study for rhodopsin and bacteriorhodopsin
Mordechai Sheves and Koji Nakanishi
pp 4033 - 4039; DOI:
10.1021/ja00350a048
PDF
Formation of .alpha.-disulfoxides, sulfinic anhydrides, and sulfines during the m-chloroperoxybenzoic acid oxidation of symmetrical S-alkyl alkanethiosulfinates
Fillmore Freeman and Christos N. Angeletakis
pp 4039 - 4049; DOI:
10.1021/ja00350a049
PDF
Enantioselective synthesis of the carbocyclic nucleosides (-)-aristeromycin and (-)-neplanocin A by a chemicoenzymatic approach
Masafumi Arita, Kunitomo Adachi, Yukishige Ito, Hiroaki Sawai, and Masaji Ohno
pp 4049 - 4055; DOI:
10.1021/ja00350a050
PDF
3,10-Dihydro-1,4-dimethylazulene, a labile biosynthetic intermediate isolated from cultured cells of liverwort Calypogeia granulata Inoue
Reiji Takeda and Kenji Katoh
pp 4056 - 4058; DOI:
10.1021/ja00350a051
PDF
Nucleic acid related compounds. 42. A general procedure for the efficient deoxygenation of secondary alcohols. Regiospecific and stereoselective conversion of ribonucleosides to 2'-deoxynucleosides
Morris J. Robins, John S. Wilson, and Fritz Hansske
pp 4059 - 4065; DOI:
10.1021/ja00350a052
PDF
Multiple conformational states of a Pro-Pro peptide. Solid-state and solution conformations of Boc-Aib-Pro-Pro-NHMe
Hemalatha Balaram, B. V. Venkataram Prasad, and P. Balaram
pp 4065 - 4071; DOI:
10.1021/ja00350a053
PDF
Chromopeptides from phycoerythrins. Structure and linkage of a phycoerythrobilin tryptic tripeptide derived from a B-phycoerythrin
Robert W. Schoenleber, See Lap Leung, Daniel J. Lundell, Alexander N. Glazer, and Henry Rapoport
pp 4072 - 4076; DOI:
10.1021/ja00350a054
PDF
One-dimensional aromatic crystals in solution. 2. Synthesis, conformation, and spectroscopic properties of poly(L-2-naphthylalanine)
Masahiko Sisido, Syun Egusa, and Yukio Imanishi
pp 4077 - 4082; DOI:
10.1021/ja00350a055
PDF
Transimination kinetics of pyridoxal 5'-phosphate Schiff bases
Shu Huan Weng and Daniel L. Leussing
pp 4082 - 4090; DOI:
10.1021/ja00350a056
PDF
Ortho-metallation at a multiply bonded dirhenium center: the first such example occurring at a multiple bond of the M2L8 type
Timothy J. Barder, Stephen M. Tetrick, Richard A. Walton, F. Albert Cotton, and Gregory L. Powell
pp 4090 - 4091; DOI:
10.1021/ja00350a057
PDF
Photochemical synthesis of olefin-carbonylosmium complexes: serendipitous formation of a 1,2-diosmacyclobutane derivative
Michael R. Burke, Josef Takats, Friedrich Wilhelm Grevels, and Johannes G. A. Reuvers
pp 4092 - 4093; DOI:
10.1021/ja00350a058
PDF
Stereochemical course of 5-lipoxygenation of arachidonate by rat basophil leukemic cell (RBL-1) and potato enzymes
E. J. Corey and Peter T. Lansbury
pp 4093 - 4094; DOI:
10.1021/ja00350a059
PDF
Separate measurements of heteronuclear J coupling constants by manipulated polarization transfer in two-dimensional NMR
V. Rutar
pp 4095 - 4096; DOI:
10.1021/ja00350a060
PDF
Stereoselective total synthesis of pyrrolizidine alkaloid bases: (-)-rosmarinecine and (-)-isoretronecanol
Kuniaki Tatsuta, Hideaki Takahashi, Yoshiya Amemiya, and Mitsuhiro Kinoshita
pp 4096 - 4097; DOI:
10.1021/ja00350a061
PDF
Do complexes of composition MnLX2 (L = tertiary phosphine) really exist? Do they reversibly bind dioxygen?
H. D. Burkett, V. F. Newberry, W. E. Hill, and S. D. Worley
pp 4097 - 4099; DOI:
10.1021/ja00350a062
PDF
Control over site of alkylation in iron acylate complexes: general preparation and reactions of alkylidene-iron tetracarbonyl complexes
M. F. Semmelhack and Rui Tamura
pp 4099 - 4100; DOI:
10.1021/ja00350a063
PDF
Design of a peptide hormone: synthesis and characterization of a model peptide with calcitonin-like activity
Gregory R. Moe, Richard J. Miller, and E. T. Kaiser
pp 4100 - 4102; DOI:
10.1021/ja00350a064
PDF
Jump rope enantiomerization of 1,5-naphthalenophanes as a probe of polymethylene chain conformational dynamics
Moon Ho Chang and Dennis A. Dougherty
pp 4102 - 4103; DOI:
10.1021/ja00350a065
PDF
Interconversion of methylene and ketene ligands on a triosmium cluster. Crystal and molecular structure of the ketene complex dodecacarbonyl[.eta.2(C,C),.mu.-ketene]triosmium, [Os3(CO)12[.eta.2(C,C),.mu.-CH2CO]]
Eric D. Morrison, Guy R. Steinmetz, Gregory L. Geoffroy, William C. Fultz, and Arnold L. Rheingold
pp 4104 - 4105; DOI:
10.1021/ja00350a066
PDF
Studies concerning the mechanism of electrophilic substitution reactions of mitomycin C
Harold Kohn and Nada Zein
pp 4105 - 4106; DOI:
10.1021/ja00350a067
PDF
New stereoselective method for the preparation of vicinal diamines from olefins and cyanamide
Harold Kohn and Sang Hun Jung
pp 4106 - 4108; DOI:
10.1021/ja00350a068
PDF
Iron(II) octaethylchlorine: structure and ligand affinity comparison with its porphyrin and isobacteriochlorin homologs
Steven H. Strauss, Michael E. Silver, and James A. Ibers
pp 4108 - 4109; DOI:
10.1021/ja00350a069
PDF
Biosynthetic origin of the carbon skeleton and oxygen atoms of the avermectins
David E. Cane, Tzyy Chyau Liang, Louis Kaplan, Mary K. Nallin, Marvin D. Schulman, Otto D. Hensens, Alan W. Douglas, and Georg Albers-Schoenberg
pp 4110 - 4112; DOI:
10.1021/ja00350a070
PDF
A flexible new synthetic route to daunomycinone, adriamycinone, and their 6-deoxy analogs
Robert K. Boeckman and Seung Hoon Cheon
pp 4112 - 4113; DOI:
10.1021/ja00350a071
PDF
Short, stereocontrolled synthesis of [4]peristylane
Leo A. Paquette, Alan R. Browne, Christopher W. Doecke, and Richard V. Williams
pp 4113 - 4115; DOI:
10.1021/ja00350a072
PDF
Electrostatic control of regioselectivity in competing bimolecular eliminations
Edward J. Grubbs, Stephen P. Schmidt, Charles T. Wang, Marvin H. Goodrow, Robert M. Lewis, Larrie A. Deardurff, and Dewitt Coffey
pp 4115 - 4116; DOI:
10.1021/ja00350a073
PDF
Mechanism of formation of Weiss' endo- and exo-tetracyclo[5.5.1.02,6.010,13]tridecane-4,8,12-trione
Steven H. Bertz, Jay Kouba, and Norman E. Sharpless
pp 4116 - 4117; DOI:
10.1021/ja00350a074
PDF
Book Reviews

pp 4118 - 4128; DOI:
10.1021/ja00350a600
PDF

Issue 13


Singlet oxygen generation for solution kinetics: clean and simple
W. Robert Midden and Shih Yi Wang
pp 4129 - 4135; DOI:
10.1021/ja00351a001
PDF
Relative conjugative abilities of three-membered-ring heterocycles with benzene based on carbon-13 and nitrogen-15 NMR
DeLanson R. Crist, Guy J. Jordan, Donald W. Moore, Joseph A. Hashmall, Arnold P. Borsetti, and Saleh A. Turujman
pp 4136 - 4142; DOI:
10.1021/ja00351a002
PDF
Lone-pair electronic effects on the calculated ab initio SCF-MO electric potential and the crystal structures of azabenzenes
Donald E. Williams and Robert R. Weller
pp 4143 - 4148; DOI:
10.1021/ja00351a003
PDF
Vibrational frequencies of the cyanocarbene (HCCN) molecule. A near degeneracy between bent cyanocarbene and linear allene-related geometries
Kwang S. Kim, Henry F. Schaefer, Leo Radom, John A. Pople, and J. Stephen Binkley
pp 4148 - 4154; DOI:
10.1021/ja00351a004
PDF
Polarized emission of tris(2,2'-bipyridine)ruthenium bis(hexafluorophosphate) ([Ru(bpy)3](PF6)2) single crystals
H. Yersin, E. Gallhuber, A. Vogler, and H. Kunkely
pp 4155 - 4156; DOI:
10.1021/ja00351a005
PDF
Acid-base thermochemistry at elevated temperatures
David L. Hughes and Edward M. Arnett
pp 4157 - 4163; DOI:
10.1021/ja00351a006
PDF
Cadmium-113 shielding tensors of cadmium-oxo compounds. I. Single-crystal studies on cadmium nitrate tetrahydrate (Cd(NO3)2.4H2O) and cadmium sulfate octahydrate (3CdSO4.8H2O)
Robert S. Honkonen, F. David Doty, and Paul D. Ellis
pp 4163 - 4168; DOI:
10.1021/ja00351a007
PDF
The interaction of lanthanide shift reagents with cationic sites: a proton and carbon-13 NMR study of the solution geometry of nicotine N-methiodide
Ronald L. Bassfield
pp 4168 - 4172; DOI:
10.1021/ja00351a008
PDF
Lanthanide-induced shift and relaxation-rate studies of aqueous L-proline solutions
Mangal Singh, Joe J. Reynolds, and A. Dean Sherry
pp 4172 - 4177; DOI:
10.1021/ja00351a009
PDF
Aggregation of lithium phenolates in weakly polar aprotic solvents
Lloyd M. Jackman and C. W. DeBrosse
pp 4177 - 4184; DOI:
10.1021/ja00351a010
PDF
Experimental and theoretical studies of carbon-13-carbon-13 coupling constants. 1. Conformational and substituent dependencies of long range coupling constants 4J(13C-13C)
Steven R. Walter, James L. Marshall, Cato R. McDaniel, Edward D. Canada, and Michael Barfield
pp 4185 - 4190; DOI:
10.1021/ja00351a011
PDF
Experimental and theoretical studies of carbon-13-carbon-13 coupling constants. 2. Conformational and substituent dependencies of geminal coupling constants 2J(13C-13C)
Michael Barfield and Steven R. Walter
pp 4191 - 4195; DOI:
10.1021/ja00351a012
PDF
Side-chain vs. main-chain conformational flexibility in aromatic dipeptides
Vincenzo Rizzo and Hans Jaeckle
pp 4195 - 4205; DOI:
10.1021/ja00351a013
PDF
Energy and time dependence of the decay processes of toluene molecular cations
Rolf Bombach, Josef Dannacher, and Jean Pierre Stadelmann
pp 4205 - 4211; DOI:
10.1021/ja00351a014
PDF
Characterization of intrinsic amorphous hydrogenated silicon as a thin-film photocathode material. Efficient photoreduction processes in aqueous solution
D. Jed Harrison, Gary S. Calabrese, Antonio J. Ricco, Joseph Dresner, and Mark S. Wrighton
pp 4212 - 4219; DOI:
10.1021/ja00351a015
PDF
Investigation of the dynamic processes of the excited states of o-hydroxybenzaldehyde and o-hydroxyacetophenone by emission and picosecond spectroscopy
Shinichi Nagaoka, Noboru Hirota, Minoru Sumitani, and Keitaro Yoshihara
pp 4220 - 4226; DOI:
10.1021/ja00351a016
PDF
Effect of solvation on the acid/base properties of glycine
Michael J. Locke and Robert T. McIver
pp 4226 - 4232; DOI:
10.1021/ja00351a017
PDF
ENDOR study of vanadyl(2+) ion (VO2+) adsorbed on Y zeolite
Hans Van Willigen and T. K. Chandrashekar
pp 4232 - 4235; DOI:
10.1021/ja00351a018
PDF
Angular distribution parameter as a function of photon energy for some mono- and diazabenzenes and its use for orbital assignment
M. N. Piancastelli, P. R. Keller, and J. W. Taylor
pp 4235 - 4239; DOI:
10.1021/ja00351a019
PDF
Chemical properties of the gas-phase benzvalene radical cation
D. L. Miller and M. L. Gross
pp 4239 - 4243; DOI:
10.1021/ja00351a020
PDF
Gas-phase chemistry of H2P-
David Richard Anderson, Veronica M. Bierbaum, and Charles H. DePuy
pp 4244 - 4248; DOI:
10.1021/ja00351a021
PDF
Association of methyl viologen and its cation radical with dihexadecyl phosphate vesicles
Sava Lukac and John R. Harbour
pp 4248 - 4250; DOI:
10.1021/ja00351a022
PDF
A new probe of solvent accessibility of bound photosensitizers. 1. Ruthenium(II) and osmium(II) photosensitizers in sodium lauryl sulfate micelles
B. L. Hauenstein, W. J. Dressick, S. L. Buell, J. N. Demas, and B. A. DeGraff
pp 4251 - 4255; DOI:
10.1021/ja00351a023
PDF
Photophysics of bis(chlorophyll)cyclophanes: models of photosynthetic reaction centers
Robert E. Overfield, Avigdor Scherz, Kenneth J. Kaufmann, and Michael R. Wasielewski
pp 4256 - 4260; DOI:
10.1021/ja00351a024
PDF
Transition-metal host complexes designed for critical-locus accommodation of organic guest molecules-an approach to a new kind of coordination catalysts patterned after enzymes
Kenneth J. Takeuchi, Daryle H. Busch, and Nathanial Alcock
pp 4261 - 4270; DOI:
10.1021/ja00351a025
PDF
Interaction of saturated hydrocarbons with transition-metal films: molecular orbital calculations
R. C. Baetzold
pp 4271 - 4276; DOI:
10.1021/ja00351a026
PDF
Single-crystal EPR of the oxygen-17-enriched dioxygen adduct of vitamin B12r: reversible oxygen bonding, electronic and geometric structure and molecular dynamics
E. Joerin, A. Schweiger, and H. H. Guenthard
pp 4277 - 4286; DOI:
10.1021/ja00351a027
PDF
Mixed-valence chemistry of adjacent vanadium centers in heteropolytungstate anions. I. Synthesis and electronic structures of mono-, di-, and trisubstituted derivatives of .alpha.-octadecatungstodiphosphate(6-) ion (.alpha.-[P2W18O62]6-)
Subhash P. Harmalker, Michele A. Leparulo, and Michael T. Pope
pp 4286 - 4292; DOI:
10.1021/ja00351a028
PDF
Aqueous chemistry of (2,2',2"-terpyridine)gold(III). Preparation and structures of chloro(2,2',2"-terpyridine)gold dichloride trihydrate ([Au(terpy)Cl]Cl2.3H2O) and the mixed valence gold(I)-gold(III) salt bis[chloro(2,2',2"-terpyridine)gold] tris(dichloroaurate) tetrachloroaurate ([Au(terpy)Cl]2[AuCl2]3[AuCl4])
L. Steven Hollis and Stephen J. Lippard
pp 4293 - 4299; DOI:
10.1021/ja00351a029
PDF
Studies in aromatic nitration. 2. Nitrogen-14 NMR study of the nitric acid/nitronium ion equilibrium in aqueous sulfuric acid
David S. Ross, Karl F. Kuhlmann, and Ripudaman Malhotra
pp 4299 - 4302; DOI:
10.1021/ja00351a030
PDF
Electronic structure in the intervalence transfer absorption band of a mixed-valence dimer
Edward M. Kober, Kenneth A. Goldsby, D. N. S. Narayana, and Thomas J. Meyer
pp 4303 - 4309; DOI:
10.1021/ja00351a031
PDF
Reactivity properties of single molybdenum iron sulfide (MoFe3S4) cubane-type clusters: synthesis, structure, and ligand substitution reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2-
R. E. Palermo and R. H. Holm
pp 4310 - 4318; DOI:
10.1021/ja00351a032
PDF
Positively charged ligands. The synthesis, structure, and bonding of sulfonium ion complexes of transition metals and evidence for a metal-induced acceleration of their dealkylation
Richard D. Adams, Craig Blankenship, Brigitte E. Segmueller, and Mahmoud Shiralian
pp 4319 - 4326; DOI:
10.1021/ja00351a033
PDF
The role of the tosyl group in the coordination ability of N-protected amino acids. 1. Solid-state behavior of (N-tosylglycinato)copper(II) complexes: crystal and molecular structures of (N-tosylglycinato)triaquacopper(II) and dipotassium bis(N-tosylglycinato)cuprate(II) complexes
L. Antolini, L. P. Battaglia, G. Battistuzzi Gavioli, A. Bonamartini Corradi, G. Grandi, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 4327 - 4332; DOI:
10.1021/ja00351a034
PDF
The role of the tosyl group in the coordination ability of N-protected amino acids. 2. Behavior of the copper(II) ion-N-tosylglycinate system in aqueous solution
L. Antolini, L. P. Battaglia, G. Battistuzzi Gavioli, A. Bonamartini Corradi, G. Grandi, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 4333 - 4337; DOI:
10.1021/ja00351a035
PDF
Formation constants of complexes between crown ethers and alkali picrates in apolar solvents. Application of crown ether network polymers
Roger Sinta, Peter S. Rose, and Johannes Smid
pp 4337 - 4343; DOI:
10.1021/ja00351a036
PDF
Rates of deprotonation of (4-nitrophenyl)acetonitrile and (2,4-dinitrophenyl)acetonitrile in 50% dimethyl sulfoxide-50% water
Claude F. Bernasconi and Sharon A. Hibdon
pp 4343 - 4348; DOI:
10.1021/ja00351a037
PDF
Nucleophilic addition to olefins. 8. Addition of piperidine, morpholine, and n-butylamine to .alpha.-cyano-4-nitrostilbene and .alpha.-cyano-2,4-dinitrostilbene. Kinetics and equilibria in 50% dimethyl sulfoxide-50% water
Claude F. Bernasconi, Christopher J. Murray, John P. Fox, and David J. Carre
pp 4349 - 4359; DOI:
10.1021/ja00351a038
PDF
The .alpha.- and .beta.-carbon substituent effect on SN2 reactivity. A valence-bond approach
Sason S. Shaik
pp 4359 - 4367; DOI:
10.1021/ja00351a039
PDF
Photochemistry of .beta.,.gamma.-enones. 7. Intramolecular competition between di-.pi.-methane and oxa-di-.pi.-methane rearrangements. On the intermediary of charge-transfer complexes and zwitterions in the di-.pi.-methane rearrangements
Reinout H. Van der Veen, Cornelis Kruk, and Hans Cerfontain
pp 4367 - 4374; DOI:
10.1021/ja00351a040
PDF
Four-at-once dedeuteration of cyclopentanone-2,2,5,5-d4
Jack Hine, David E. Miles, and James P. Zeigler
pp 4374 - 4379; DOI:
10.1021/ja00351a041
PDF
Pattern of hydroxyl radical addition to cytosine and 1-, 3-, 5-, and 6-substituted cytosines. Electron transfer and dehydration reactions of the hydroxyl adducts
D. K. Hazra and S. Steenken
pp 4380 - 4386; DOI:
10.1021/ja00351a042
PDF
Imidazole-promoted hydrolysis of oxaphospholene esters. Nucleophilic vs. general base catalysis
Roger S. Macomber
pp 4386 - 4389; DOI:
10.1021/ja00351a043
PDF
Acid-catalyzed hydrolysis of a phenylketene dithioacetal. Reversible protonation of the carbon-carbon double bond
Tadashi Okuyama and Takayuki Fueno
pp 4390 - 4395; DOI:
10.1021/ja00351a044
PDF
Factors controlling regioselectivity in deprotonations of unsymmetrical ketimines
J. Kirk Smith, David E. Bergbreiter, and Martin Newcomb
pp 4396 - 4400; DOI:
10.1021/ja00351a045
PDF
Cyclopropylidene rearrangement in the reduction of 1,2:3,4-bis(dihalomethano)-1,2,3,4-tetrahydropolymethylnaphthalenes by naphthalenides
Akira Oku, Ken Harada, Tohru Yagi, and Yasushi Shirahase
pp 4400 - 4407; DOI:
10.1021/ja00351a046
PDF
Acid-catalyzed and photochemical isomerization of steroidal cyclopropenes
Toshihiro Itoh and Carl Djerassi
pp 4407 - 4416; DOI:
10.1021/ja00351a047
PDF
Poly(1,6-heptadiyne), a free-standing polymer film dopable to high electrical conductivity
Harry W. Gibson, F. C. Bailey, Arthur J. Epstein, Heiko Rommelmann, Samuel Kaplan, John Harbour, Xiao Quing Yang, David B. Tanner, and John M. Pochan
pp 4417 - 4431; DOI:
10.1021/ja00351a048
PDF
Chemical properties of phenanthrolinequinones and the mechanism of amine oxidation by o-quinones of medium redox potentials
Timothy S. Eckert and Thomas C. Bruice
pp 4431 - 4441; DOI:
10.1021/ja00351a049
PDF
Structure of caesalpinine A: a novel spermidine alkaloid from Caesalpinia digyna Rottl
S. B. Mahato, N. P. Sahu, and P. Luger
pp 4441 - 4445; DOI:
10.1021/ja00351a050
PDF
Synthesis of the benzotricyclo[3.2.0.02,7]heptene ring system via the intramolecular [2 + 2]-cycloaddition reaction of some cyclopropene derivatives
Albert Padwa, William F. Rieker, and Robert J. Rosenthal
pp 4446 - 4456; DOI:
10.1021/ja00351a051
PDF
Conformational analysis by NMR spectrometry of the highly substituted cyclic tetrapeptides, chlamydocin and Ala4-chlamydocin. Evidence for a unique amide bond sequence in dimethyl sulfoxide-d6
Megumi Kawai, Ronald D. Jasensky, and Daniel H. Rich
pp 4456 - 4462; DOI:
10.1021/ja00351a052
PDF
Structure of the pseudoaglycon of A35512B
Ann H. Hunt
pp 4463 - 4468; DOI:
10.1021/ja00351a053
PDF
Strategic design of organic conductors. Structure of a prototypical molecule
James Y. Becker, Joel Bernstein, Shmuel Bittner, Nurit Levi, and Sason S. Shaik
pp 4468 - 4469; DOI:
10.1021/ja00351a054
PDF
Isotope effects of benzylic deuterons on chemical shifts of ortho carbons. Correlation with .pi. bond orders as an indication of a hyperconjugative contribution
Ludger Ernst, Henning Hopf, and Dieter Wullbrandt
pp 4469 - 4470; DOI:
10.1021/ja00351a055
PDF
Electron transfer at crystallographically known long distances (25 .ANG.) in [ZnII,FeIII] hybrid hemoglobin
Jacqueline L. McGourty, Neil V. Blough, and Brian M. Hoffman
pp 4470 - 4472; DOI:
10.1021/ja00351a056
PDF
Total synthesis of the trichothecene mycotoxin anguidine
Dee W. Brooks, Paul G. Grothaus, and Hormoz Mazdiyasni
pp 4472 - 4473; DOI:
10.1021/ja00351a057
PDF
Development of low-valent tantalum chemistry: syntheses and x-ray structures of dichlorotetrakis(trimethylphosphine)tantalum [TaCl2(PMe3)4], dichlorodihydrotetrakis(trimethylphosphine)tantalum [TaCl2H2(PMe3)4] and chlorodihydrotetrakis(trimethylphosphine)tantalum [TaClH2(PMe3)4]
M. L. Luetkens, J. C. Huffman, and A. P. Sattelberger
pp 4474 - 4475; DOI:
10.1021/ja00351a058
PDF
Reaction of acyl halides with organotin hydrides. Mechanism of aldehyde formation
J. Lusztyk, E. Lusztyk, B. Maillard, L. Lunazzi, and K. U. Ingold
pp 4475 - 4477; DOI:
10.1021/ja00351a059
PDF
Rapid incorporation of copper(II) in porphyrin derivatives
G. Mattney Cole, Daniel W. Doll, and Smith L. Holt
pp 4477 - 4478; DOI:
10.1021/ja00351a060
PDF
Metal-metal multiple bonds. 16. Synthesis, structure, and reactivity of a dimetallacyclopropene, Cp2Mo2(CO)4(.mu.-C13H8)(Mo:Mo)
John J. D'Errico and M. David Curtis
pp 4479 - 4480; DOI:
10.1021/ja00351a061
PDF
Prelunularic acid, a probable immediate precursor of lunularic acid. First example of a "prearomatic" intermediate in the phenylpropanoid-polymalonate pathway
Y. Ohta, S. Abe, H. Komura, and M. Kobayashi
pp 4480 - 4481; DOI:
10.1021/ja00351a062
PDF
Adsorption of bifunctional organic disulfides on gold surfaces
Ralph G. Nuzzo and David L. Allara
pp 4481 - 4483; DOI:
10.1021/ja00351a063
PDF
Organoiron complexes in organic synthesis. 30. Approach to stereochemically defined cycloheptadiene derivatives using organoiron chemistry
Anthony J. Pearson, Sandra H. Kole, and Bruce Chen
pp 4483 - 4484; DOI:
10.1021/ja00351a064
PDF
2-Indanol formation from photocyclization of .alpha.-arylacetophenones
Michael A. Meador and Peter J. Wagner
pp 4484 - 4486; DOI:
10.1021/ja00351a065
PDF
Resonance Raman spectra of the ground and excited states of specifically deuterated tris(2,2'-bipyridine)ruthenium(II)
Stephen McClanahan, Thomas Hayes, and James Kincaid
pp 4486 - 4487; DOI:
10.1021/ja00351a066
PDF
Structure and bonding of the first .eta.2-coordinated tetraphosphido ligand: molecular structure of trans-chlorobis(triphenylphosphine)tetraphosphidorhodium-bis(dichloromethane) (trans-[Rh(P4)(PPh3)2Cl].2CH2Cl2) at 185 K
W. Edward Lindsell, Kevin J. McCullough, and Alan J. Welch
pp 4487 - 4489; DOI:
10.1021/ja00351a067
PDF
Oxygen activation by metalloporphyrins. Formation and decomposition of an acylperoxymanganese(III) complex
John T. Groves, Yoshihito Watanabe, and Thomas J. McMurry
pp 4489 - 4490; DOI:
10.1021/ja00351a068
PDF
Transition-metal-catalyzed silylmetalation of acetylenes and its application to the stereoselective synthesis of steroidal side chains
Hiroshi Hayami, Mitsuyoshi Sato, Shigekazu Kanemoto, Yoshitomi Morizawa, Koichiro Oshima, and Hitosi Nozaki
pp 4491 - 4492; DOI:
10.1021/ja00351a069
PDF
Nitroxyl-mediated electrooxidation of alcohols to aldehydes and ketones
M. F. Semmelhack, Chuen S. Chou, and David A. Cortes
pp 4492 - 4494; DOI:
10.1021/ja00351a070
PDF
Tris(trimethylsilyl)aluminum and transition-metal catalysts. Silylation of allyl acetates
Barry M. Trost, Junichi Yoshida, and Mark Lautens
pp 4494 - 4496; DOI:
10.1021/ja00351a071
PDF
Indirect measurement of scalar spin-spin coupling between chemically equivalent hydrogen nuclei
V. Rutar
pp 4496 - 4497; DOI:
10.1021/ja00351a072
PDF
Photocatalytic formylation of primary and secondary amines on irradiated semiconductor powders
Marye Anne Fox and Ming Jang Chen
pp 4497 - 4499; DOI:
10.1021/ja00351a073
PDF
Stereospecific synthesis of acyclic unsaturated amino alcohols. A new approach to threo and erythro sphingosine
Ravi S. Garigipati and Steven M. Weinreb
pp 4499 - 4501; DOI:
10.1021/ja00351a074
PDF
Additions and Corrections - The Mechanism of Hemiacetal Decomposition. Substituent Effects in Breakdown of Substituted Benzaldehyde Ethyl Hemiacetals
Theodore J. Przystas, and Thomas H. Fife
pp 4501 - 4501; DOI:
10.1021/ja00351a601
PDF
Additions and Corrections - Ene Reaction of Singlet Oxygen: An Entropy-Controlled Process Determines the Reaction Rate.
John R. Hurst, and Gary B. Schuster
pp 4501 - 4501; DOI:
10.1021/ja00351a602
PDF
Additions and Corrections - Synthesis of (Trifluoromethansulfonato)pentaammineosmium(III): Osmium(III) Pentaammine Complexes
Peter A. Lay, Roy H. Magnuson, J. Sen, and Henry Taube
pp 4501 - 4501; DOI:
10.1021/ja00351a603
PDF
Additions and Corrections - An Unprecedented Bis(carbyne) Cluster Rearrangement Involving Simultaneous Coupling and Decoupling of Carbyne Fragments: A New Homogenous Model for C-C Bond Forming and Bond Breaking on Surfaces
Neil T. Allison, John R. Fritch, K. Peter C. Vollhardt, and Eric Walborsky
pp 4501 - 4501; DOI:
10.1021/ja00351a604
PDF
Additions and Corrections - Bacteriorhodopsins Containing Cyanine Dye Chromophores. Support for the External Point-Charge Model
F. Derguini, C. G. Caldwell, M. G .Motto, V. Balogh-Nair, and K. Nakanishi
pp 4501 - 4501; DOI:
10.1021/ja00351a605
PDF
Additions and Corrections - New Model for the Interior of Polyelectrolyte Coatings on Electrode Surfaces. Mechanisms of Charge Transport through Protonated Poly(L-lysine) Films Containing FeIII(edta)- and FeII-(edta)2- as Counterions
Fred C. Anson, Jean-Michel Saveant, and Kiyotaka Shigehara
pp 4501 - 4501; DOI:
10.1021/ja00351a606
PDF
Book Reviews

pp 4502 - 4506; DOI:
10.1021/ja00351a600
PDF

Issue 14


Polymerized vesicles derived from an isocyano amphiphile. Electron microscopic evidence of the polymerized state
M. F. M. Roks, H. G. J. Visser, J. W. Zwikker, A. J. Verkley, and R. J. M. Nolte
pp 4507 - 4510; DOI:
10.1021/ja00352a001
PDF
Redox conduction in mixed-valent polymers
P. G. Pickup and Royce W. Murray
pp 4510 - 4514; DOI:
10.1021/ja00352a002
PDF
Photoinduced reactions in polymerized microemulsions
S. Atik and J. K. Thomas
pp 4515 - 4519; DOI:
10.1021/ja00352a003
PDF
Theory and application of photoelectron spectroscopy. 100. Variable-temperature photoelectron spectral study of 1,3-dithiol-2-one and 4,5-disubstituted 1,3-dithiol-2-ones. Thermal generation of 1,2-dithiete, 3,4-disubstituted 1,2-dithietes, and dialkyl tetrathiooxalates
Reinhard Schulz, Armin Schweig, Klaus Hartke, and Joachim Koester
pp 4519 - 4528; DOI:
10.1021/ja00352a004
PDF
High pressure NMR kinetics. 19. Variable pressure and temperature nuclear magnetic resonance and visible spectrophotometric studies of lanthanide ions in dimethylformamide: solvation and solvent exchange dynamics
Dino L. Pisaniello, Lothar Helm, Pierre Meier, and Andre E. Merbach
pp 4528 - 4536; DOI:
10.1021/ja00352a005
PDF
Surface spectroscopic studies of polymer surfaces and interfaces: poly(tetramethyl-p-silphenylenesiloxane)
Joseph A. Gardella, J. S. Chen, J. H. Magill, and David M. Hercules
pp 4536 - 4541; DOI:
10.1021/ja00352a006
PDF
Symmetry rules for the determination of the intercalation geometry of host/systems using circular dichroism: a symmetry-adapted coupled-oscillator model
Pieter E. Schipper and Alison Rodger
pp 4541 - 4550; DOI:
10.1021/ja00352a007
PDF
Conformational mobility in the trans-cycloheptene-copper(I) triflate complex
Gregory M. Wallraff, Richard H. Boyd, and Josef Michl
pp 4550 - 4555; DOI:
10.1021/ja00352a008
PDF
Study of electron distributions of molecular orbitals by Penning ionization electron spectroscopy
Koichi Ohno, Hideki Mutoh, and Yoshiya Harada
pp 4555 - 4561; DOI:
10.1021/ja00352a009
PDF
Chiral discrimination in crystalline tri-o-thymotide clathrate inclusion complexes. Chemical and crystallographic studies
Rina Arad-Yellin, Bernard S. Green, Marcel Knossow, and Georges Tsoucaris
pp 4561 - 4571; DOI:
10.1021/ja00352a010
PDF
Electronic absorption and emission spectra of binuclear platinum(II) complexes. Characterization of the lowest singlet and triplet excited states of tetrakis(diphosphonato)diplatinate(4-) anion (Pt2(H2P2O5)44-)
Steven F. Rice and Harry B. Gray
pp 4571 - 4575; DOI:
10.1021/ja00352a011
PDF
Determination by proton NMR of the orientation of modified hemes incorporated into horseradish peroxidase. Evidence for steric clamping of a vinyl group by the protein
Gerd N. La Mar, Jeffrey S. De Ropp, Kevin M. Smith, and Kevin C. Langry
pp 4576 - 4580; DOI:
10.1021/ja00352a012
PDF
Chemistry, spectroscopy, and isotope-selective infrared photochemistry of a volatile uranium compound tailored for 10-.mu. absorption: uranium hexamethoxide (U(OCH3)6)
Edward A. Cuellar, Steven S. Miller, Tobin J. Marks, and Eric Weitz
pp 4580 - 4589; DOI:
10.1021/ja00352a013
PDF
Detailed absorption, reflectance, and UV photoelectron spectroscopic and theoretical studies of the charge-transfer transitions of tetrachlorocuprate(2-) ion: correlation of the square-planar and the tetrahedral limits
Sylvie R. Desjardins, Kevin W. Penfield, Susan L. Cohen, Ronald L. Musselman, and Edward I. Solomon
pp 4590 - 4603; DOI:
10.1021/ja00352a014
PDF
Binuclear platinum diphosphite complexes. Crystal structures of tetrapotassium bromotetrakis(diphosphito)diplatinate trihydrate (K4[Pt2(pop)4Br].3H2O), a new linear chain semiconductor, and tetrapotassium dichlorotetrakis(diphosphito)diplatinate dihydrate (K4[Pt2(pop)4Cl2].2H2O)
Chi Ming Che, Frank H. Herbstein, William P. Schaefer, Richard E. Marsh, and Harry B. Gray
pp 4604 - 4607; DOI:
10.1021/ja00352a015
PDF
Crystal structure and excited triplet-state electron paramagnetic resonance of the .SIGMA.-bonded TCNQ dimer in bis(2,9-dimethyl-1,10-phenanthroline)copper(I) tetracyanoquinodimethane dimer [Cu(DMP)2]2[TCNQ]2
Stanislaw K. Hoffmann, Peter J. Corvan, Phirtu Singh, C. N. Sethulekshmi, Robert M. Metzger, and William E. Hatfield
pp 4608 - 4617; DOI:
10.1021/ja00352a016
PDF
Coordination chemistry of microbial iron transport compounds. 22. pH-dependent Moessbauer spectroscopy of ferric enterobactin and synthetic analogues
Vincent L. Pecoraro, Geoffrey B. Wong, Thomas A. Kent, and Kenneth N. Raymond
pp 4617 - 4623; DOI:
10.1021/ja00352a017
PDF
Coordination chemistry of microbial iron transport compounds. 23. Fourier transform infrared spectroscopy of ferric catechoylamide analogues of enterobactin
Vincent L. Pecoraro, Wesley R. Harris, Geoffrey B. Wong, Carl J. Carrano, and Kenneth N. Raymond
pp 4623 - 4633; DOI:
10.1021/ja00352a018
PDF
gem-(Difluoroallyl)lithium: Preparation by lithium-halogen exchange and utilization in organosilicon and organic synthesis
Dietmar Seyferth, Robert M. Simon, Dennis J. Sepelak, and Helmut A. Klein
pp 4634 - 4639; DOI:
10.1021/ja00352a019
PDF
Comparison of radiationless decay processes in osmium and platinum porphyrins
Glauco Ponterini, Nick Serpone, Michael A. Bergkamp, and Thomas L. Netzel
pp 4639 - 4645; DOI:
10.1021/ja00352a020
PDF
Ligand design and metal-ion recognition. Interaction of nickel(II) with 17- to 19-membered macrocycles containing O2N3 and O3N2 donor sets and the x-ray structure of the parent 17-membered macrocyclic ligand
Kenneth R. Adam, Anthony J. Leong, Leonard F. Lindoy, Hyacinth C. Lip, Brian W. Skelton, and Allan H. White
pp 4645 - 4651; DOI:
10.1021/ja00352a021
PDF
Macrobicyclic (hexaamine)platinum(IV) complexes: synthesis, characterization, and electrochemistry
Heather A. Boucher, Geoffrey A. Lawrance, Peter A. Lay, Alan M. Sargeson, Alan M. Bond, David F. Sangster, and James C. Sullivan
pp 4652 - 4661; DOI:
10.1021/ja00352a022
PDF
(Trimethylphosphine)cobalt(I) complexes. 2. Reactivity with diphenylacetylene: chemical and structural evidence for alkyne ligand as variable-electron donor in tris(trimethylphosphine)(diphenylacetylene)(acetonitrile)cobalt tetraphenylborate and tris(trimethylphosphine)(diphenylacetylene)cobalt tetraphenylborate
Brigitte Capelle, Michele Dartiguenave, Yves Dartiguenave, and Andre L. Beauchamp
pp 4662 - 4670; DOI:
10.1021/ja00352a023
PDF
Mugineic acid-iron(III) complex and its structurally analogous cobalt(III) complex: characterization and implication for absorption and transport of iron in gramineous plants
Yoshiki Mino, Toshimasa Ishida, Nagayo Ota, Masatoshi Inoue, Kyosuke Nomoto, Tsunematsu Takemoto, Hisashi Tanaka, and Yukio Sugiura
pp 4671 - 4676; DOI:
10.1021/ja00352a024
PDF
Protonation and alkylation of ambident (9-anthryl)arylmethyl anions
Masato Takagi, Masatomo Nojima, and Shigekazu Kusabayashi
pp 4676 - 4684; DOI:
10.1021/ja00352a025
PDF
Synergistic effect of iodine and neighboring amine groups on thioester deacylation
Joyce Takahashi Doi, Tracy Louise Carpenter, Marilyn M. Olmstead, and W. Kenneth Musker
pp 4684 - 4689; DOI:
10.1021/ja00352a026
PDF
Intermediates in nucleophilic aromatic substitution. 22. Kinetics of acid-catalyzed breakdown of spiro Meisenheimer complexes
Claude F. Bernasconi and Keith A. Howard
pp 4690 - 4697; DOI:
10.1021/ja00352a027
PDF
A nitrogen-15 NMR study of the barriers to isomerization about guanidinium and guanidino carbon-nitrogen bonds in L-arginine
Keiko Kanamori and John D. Roberts
pp 4698 - 4701; DOI:
10.1021/ja00352a028
PDF
Heats of formation and ionization potentials of some .alpha.-aminoalkyl radicals
T. J. Burkey, A. L. Castelhano, D. Griller, and F. P. Lossing
pp 4701 - 4703; DOI:
10.1021/ja00352a029
PDF
Mechanism of the ozonolysis of propene in the liquid phase
Jong In Choe, M. Srinivasan, and R. L. Kuczkowski
pp 4703 - 4707; DOI:
10.1021/ja00352a030
PDF
Chemistry of singlet oxygen. 43. Quenching by conjugated olefins
Lewis E. Manring, Richard C. Kanner, and Christopher S. Foote
pp 4707 - 4710; DOI:
10.1021/ja00352a031
PDF
Chemistry of singlet oxygen. 44. Mechanism of photooxidation of 2,5-dimethylhexa-2,4-diene and 2-methyl-2-pentene
Lewis E. Manring and Christopher S. Foote
pp 4710 - 4717; DOI:
10.1021/ja00352a032
PDF
Chemistry of singlet oxygen. 45. Mechanism of the photooxidation of sulfides
J. J. Liang, C. L. Gu, M. L. Kacher, and Christopher S. Foote
pp 4717 - 4721; DOI:
10.1021/ja00352a033
PDF
Photoreduction of alkyl halides by an NADH model compound. An electron-transfer chain mechanism
Shunichi Fukuzumi, Katsuhiko Hironaka, and Toshio Tanaka
pp 4722 - 4727; DOI:
10.1021/ja00352a034
PDF
Optically active phosphines. Facile preparation of the optically active propylmethylbenzyl- and methylphenylbenzylphosphine oxides as precursors to the corresponding tertiary phosphines
Masaru Moriyama and Wesley G. Bentrude
pp 4727 - 4733; DOI:
10.1021/ja00352a035
PDF
Synthesis of difunctionalized iceane derivatives: 3,13-dimethylene-8-oxapentacyclo[8.3.1.12,6.04,12.06,10]pentadecane
Paul R. Spurr and David P. G. Hamon
pp 4734 - 4739; DOI:
10.1021/ja00352a036
PDF
Indole-2,3-quinodimethanes: a new strategy for the synthesis of tetracyclic systems of indole alkaloids
Christopher Exon, Timothy Gallagher, and Philip Magnus
pp 4739 - 4749; DOI:
10.1021/ja00352a037
PDF
Pentacyclic systems of indole alkaloids. Formation of the C11-C12 bond. Two syntheses of (.+-.)-aspidospermidine
Timothy Gallagher, Philip Magnus, and John C. Huffman
pp 4750 - 4757; DOI:
10.1021/ja00352a038
PDF
Cationic cyclocodimerization. 1. Novel synthesis of [3.3]paracyclophane skeleton from 1,3-bis(p-vinylphenyl)propane
Jun Nishimura, Kazumasa Hashimoto, Tomohisa Okuda, Hiroshi Hayami, Yoshihiko Mukai, and Akira Oku
pp 4758 - 4767; DOI:
10.1021/ja00352a039
PDF
Rate-controlling two-proton transfer coupled with heavy-atom motion in the 2-pyridinone-catalyzed mutarotation of tetramethylglucose. Experimental and calculated deuterium isotope effects
Kjell Aake Engdahl, Haakan Bivehed, Per Ahlberg, and William H. Saunders
pp 4767 - 4774; DOI:
10.1021/ja00352a040
PDF
In situ generation of 1,5-dipoles by concerted [1,6] hydrogen transfer. Stereoselective thermal rearrangement of 1-(1-pyrrolidinyl)-1,3-butadienes to pyrrolizines
David N. Reinhoudt, Germ W. Visser, Willem Verboom, Piet H. Benders, and Marcel L. M. Pennings
pp 4775 - 4781; DOI:
10.1021/ja00352a041
PDF
Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation
Yitzhak Apeloig, Miriam Karni, Peter J. Stang, and Dennis P. Fox
pp 4781 - 4792; DOI:
10.1021/ja00352a042
PDF
Dynamics at the active site of bis(4-fluorophenyl)carbamoyl-.alpha.-chymotrypsin
M. Cairi and J. T. Gerig
pp 4793 - 4800; DOI:
10.1021/ja00352a043
PDF
Cyclohexanone oxygenase: stereochemistry, enantioselectivity, and regioselectivity of an enzyme-catalyzed Baeyer-Villiger reaction
John M. Schwab, Wubo Li, and Lawrence P. Thomas
pp 4800 - 4808; DOI:
10.1021/ja00352a044
PDF
Synthesis and study of a 6-amino-5-oxo-3H,5H-uracil and derivatives. The structure of an intermediate proposed in mechanisms of flavin and pterin oxygenases
Albert Wessiak and Thomas C. Bruice
pp 4809 - 4825; DOI:
10.1021/ja00352a045
PDF
Novel mode of reduction of phosphido-bridged, metal-metal-bonded binuclear complexes. Synthesis and reactivity of an unsymmetrical anion from bis(.mu.-diphenylphosphido)hexacarbonyldiiron [Fe2(CO)6(.mu.-PPh2)2]
Yuan Fu Yu, Judith Gallucci, and Andrew Wojcicki
pp 4826 - 4828; DOI:
10.1021/ja00352a046
PDF
Transient absorption and two-step laser excitation fluorescence spectra of the excited-state and ground-state proton transfer in 7-hydroxyquinoline
Michiya Itoh, Tomoko Adachi, and Kunihiro Tokumura
pp 4828 - 4829; DOI:
10.1021/ja00352a047
PDF
Medium and substituent directed stereoselective photoisomerization of polyenes in the vitamin A series. Application of the Dellinger-Kasha model
R. S. H. Liu, A. E. Asato, and M. Denny
pp 4829 - 4830; DOI:
10.1021/ja00352a048
PDF
Hypothetical metallic allotrope of carbon
Roald Hoffmann, Timothy Hughbanks, Miklos Kertesz, and Peter H. Bird
pp 4831 - 4832; DOI:
10.1021/ja00352a049
PDF
Mechanisms of water oxidation to oxygen: cobalt(IV) as an intermediate in the aquocobalt(II)-catalyzed reaction
Bruce S. Brunschwig, Mei H. Chou, Carol Creutz, Pushpito Ghosh, and Norman Sutin
pp 4832 - 4833; DOI:
10.1021/ja00352a050
PDF
1,3-Asymmetric induction in addition reactions of chiral .beta.-alkoxy aldehydes: efficient chelation control via Lewis acidic titanium reagents
M. T. Reetz and A. Jung
pp 4833 - 4835; DOI:
10.1021/ja00352a051
PDF
Amphimedine, new aromatic alkaloid from a pacific sponge, Amphimedon sp. Carbon connectivity determination from natural abundance carbon-13-carbon-13 coupling constants
Francis J. Schmitz, Santosh K. Agarwal, Sarath P. Gunasekera, Paul G. Schmidt, and James N. Shoolery
pp 4835 - 4836; DOI:
10.1021/ja00352a052
PDF
(.mu.-Oxo)bis(.mu.-acetato)bis(tri-1-pyrazolylborato)diiron(III), [(HBpz3)FeO(CH3CO2)2Fe(HBpz3)]: model for the binuclear iron center of hemerythrin
William H. Armstrong and Stephen J. Lippard
pp 4837 - 4838; DOI:
10.1021/ja00352a053
PDF
Location of internal hydrogen atoms in the paradodecatungstate polyanion by neutron diffraction
Howard T. Evans and Edward Prince
pp 4838 - 4839; DOI:
10.1021/ja00352a054
PDF
Formation of ozonides: a kinetic secondary isotope effect for the carbonyl oxide
Jong In Choe and Robert L. Kuczkowski
pp 4839 - 4841; DOI:
10.1021/ja00352a055
PDF
Deuterium NMR study of organic molecules absorbed by zeolites
R. Eckman and A. J. Vega
pp 4841 - 4842; DOI:
10.1021/ja00352a056
PDF
Electrocatalytic oxidation of chloride to chlorine based on polypyridine complexes of ruthenium
Charles D. Ellis, John A. Gilbert, W. Rorer Murphy, and Thomas J. Meyer
pp 4842 - 4843; DOI:
10.1021/ja00352a057
PDF
On the nature of the bicyclo[3.2.1]octa-3,6-dien-2-yl anion. A carbon-13 NMR spectroscopic study
Manfred Christl, Hartmut Leininger, and Dieter Brueckner
pp 4843 - 4844; DOI:
10.1021/ja00352a058
PDF
Electrophilic additions to diphosphenes (RP:PR)
A. H. Cowley, J. E. Kilduff, N. C. Norman, J. L. Atwood, M. Pakulski, and W. E. Hunter
pp 4845 - 4846; DOI:
10.1021/ja00352a059
PDF
Vinyl hydrogen activation in mono- and dinuclear (.eta.5-cyclopentadienyl)(hexatriene)cobalt complexes. Thermal and photochemical hydrogen shifts of complementary stereochemistry
Joseph A. King and K. Peter C. Vollhardt
pp 4846 - 4848; DOI:
10.1021/ja00352a060
PDF
Phosphorus-31 shielding tensor of deoxycytidine 5'-monophosphate
P. Tutunjian, J. Tropp, and John S. Waugh
pp 4848 - 4849; DOI:
10.1021/ja00352a061
PDF
Cyclocontraction - spiroannulation: a stereoselective approach to spirocycles
Barry M. Trost and Bruce R. Adams
pp 4849 - 4850; DOI:
10.1021/ja00352a062
PDF
Book Reviews

pp 4850 - 4854; DOI:
10.1021/ja00352a600
PDF

Issue 15


A large nylon capsule coated with a synthetic bilayer membrane. Permeability control of sodium chloride by phase transition of the dialkylammonium bilayer coating
Yoshio Okahata, Han Jin Lim, Genichi Nakamura, and Satoshi Hachiya
pp 4855 - 4859; DOI:
10.1021/ja00353a001
PDF
Theory of the chemical bond. 6. Accurate relationship between bond energies and electronegativity differences
Robert L. Matcha
pp 4859 - 4862; DOI:
10.1021/ja00353a002
PDF
Conformation and dynamics of carcinogenic N-substituted 2-aminofluorene compounds studied by NMR.
Frederick E. Evans and Dwight W. Miller
pp 4863 - 4868; DOI:
10.1021/ja00353a003
PDF
On the structure of anions derived from cycloheptatriene in the gas phase
Robert L. White, Charles L. Wilkins, Jennifer J. Heitkamp, and Stuart W. Staley
pp 4868 - 4870; DOI:
10.1021/ja00353a004
PDF
NMR spectroscopy of cyclohexane. Gas-phase conformational kinetics
Brian D. Ross and Nancy S. True
pp 4871 - 4875; DOI:
10.1021/ja00353a005
PDF
Sodium(+) ion and lithium(+) ion effects on the photoreduction of benzophenone: a picosecond absorption study
John D. Simon and Kevin S. Peters
pp 4875 - 4882; DOI:
10.1021/ja00353a006
PDF
Kinetics of electron-transfer cross-reactions within redox polymers. Coatings of a protonated polylysine copolymer with incorporated electroactive anions
Fred C. Anson, Takeo Ohsaka, and Jean Michel Saveant
pp 4883 - 4890; DOI:
10.1021/ja00353a007
PDF
Electrochemical modulation of fluorescence from zinc tetraphenylporphyrin on electrode surfaces
Julie S. Pflug, Larry R. Faulkner, and W. R. Seitz
pp 4890 - 4896; DOI:
10.1021/ja00353a008
PDF
Porphyrins. 44. Electronic states of cobalt, nickel, rhodium, and palladium complexes
Artemis Antipas and Martin Gouterman
pp 4896 - 4901; DOI:
10.1021/ja00353a009
PDF
Interactions of the aluminum(III) ion in a model membrane system
Alan S. Tracey and Taryn L. Boivin
pp 4901 - 4905; DOI:
10.1021/ja00353a010
PDF
The ionic hydrogen bond. 2. Intramolecular and partial bonds. Protonation of polyethers, crown ethers, and diketones
Michael Meot-Ner
pp 4906 - 4911; DOI:
10.1021/ja00353a011
PDF
The ionic hydrogen bond. 3. Multiple imidogen(1+)-oxygen (NH+...O) and methylidyne(.delta.+)-oxygen (CH.delta.+...O) bonds. Complexes of ammonium ions with polyethers and crown ethers
Michael Meot-Ner
pp 4912 - 4915; DOI:
10.1021/ja00353a012
PDF
Low-spin ferric porphyrin complexes: analysis of the electronic structure based on single-crystal electron spin resonance measurements
Marianne P. Byrn, Bradley A. Katz, Nancy L. Keder, Keith R. Levan, Charles J. Magurany, Kathleen M. Miller, Jeffrey W. Pritt, and Charles E. Strouse
pp 4916 - 4922; DOI:
10.1021/ja00353a013
PDF
Oxygen-17 NMR as a tool for studying oxygenated transition-metal derivatives: first direct oxygen-17 NMR observations of transition-metal-bonded peroxidic oxygen atoms. Evidence for the absence of oxo-peroxo oxygen exchange in molybdenum(VI) compounds
Michele Postel, Christian Brevard, Henri Arzoumanian, and Jean G. Riess
pp 4922 - 4926; DOI:
10.1021/ja00353a014
PDF
EPR evidence on the structure of the copper(II)-bacitracin A complex
Edmund G. Seebauer, Edward P. Duliba, Duane A. Scogin, Robert B. Gennis, and R. L. Belford
pp 4926 - 4929; DOI:
10.1021/ja00353a015
PDF
Interruption of conjugation in polyenes bound to transition-metal fragments
John W. Chinn and Michael B. Hall
pp 4930 - 4941; DOI:
10.1021/ja00353a016
PDF
Alkylidene hydride complexes of tantalum and the polymerization of ethylene by diiodotris(trimethylphosphine)hydroneopentylidenetantalum [Ta(CHCMe3)(H)(PMe3)3I2]
H. W. Turner, R. R. Schrock, J. D. Fellmann, and S. J. Holmes
pp 4942 - 4950; DOI:
10.1021/ja00353a017
PDF
Synthesis and structural characterization of bis[bis(dimethylphenylphosphine)dichlororhenium](n+) ion (n = 0-2): a series of complexes processing metal-metal bond orders of 4, 3.5, and 3 and the dependence of bond length upon bond order
F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Milagros Tomas, and Richard A. Walton
pp 4950 - 4954; DOI:
10.1021/ja00353a018
PDF
Novel products in the carbonylation of the triply bonded ditungsten hexaisopropoxide dipyridine adduct. 1. Synthesis and structure of the carbonylated triply bonded ditungsten hexaisopropoxide dipyridine adduct [(iso-PrO)3W(.mu.-CO)(.mu.-O-iso-Pr)W(O-iso-Pr)2py]2
F. Albert Cotton and Willi Schwotzer
pp 4955 - 4957; DOI:
10.1021/ja00353a019
PDF
Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction
William A. Kiel, Gong Yu Lin, Gerardo S. Bodner, and J. A. Gladysz
pp 4958 - 4972; DOI:
10.1021/ja00353a020
PDF
Are the silacyclopentadienyl anion and the silacyclopropenyl cation aromatic?
Mark S. Gordon, Philip Boudjouk, and Freidun Anwari
pp 4972 - 4976; DOI:
10.1021/ja00353a021
PDF
Kinetics and mechanism of oxidative addition and reductive elimination of hydrogen on triruthenium clusters
Lynn M. Bavaro, Paolo Montangero, and Jerome B. Keister
pp 4977 - 4981; DOI:
10.1021/ja00353a022
PDF
Formation of a carbinolamine intermediate in the tertiary amine catalyzed enolization of oxaloacetic acid. An alternative mechanism for enolization
Paula Yurkanis Bruice
pp 4982 - 4996; DOI:
10.1021/ja00353a023
PDF
Directionality of proton transfer in solution. Three systems of known angularity
F. M. Menger, J. F. Chow, H. Kaiserman, and P. C. Vasquez
pp 4996 - 5002; DOI:
10.1021/ja00353a024
PDF
Catalytic alkyl group exchange reaction of primary and secondary amines
Shunichi Murahashi, Noriaki Yoshimura, Tatsuo Tsumiyama, and Takeyuki Kojima
pp 5002 - 5011; DOI:
10.1021/ja00353a025
PDF
Enzyme-catalyzed organic synthesis: regeneration of deuterated nicotinamide cofactors for use in large-scale enzymatic synthesis of deuterated substances
Chi Huey Wong and George M. Whitesides
pp 5012 - 5014; DOI:
10.1021/ja00353a026
PDF
Total synthesis of (-)-maysine
A. I. Meyers, K. A. Babiak, Arthur L. Campbell, Daniel L. Comins, Michael P. Fleming, Rainer Henning, Manfred Heuschmann, James P. Hudspeth, John M. Kane, and et al.
pp 5015 - 5024; DOI:
10.1021/ja00353a027
PDF
Reversible tautomerization of radical cations. Photoionization of 2-methoxyethanol and 3-methoxy-1-propanol
H. W. Biermann and Thomas Hellman Morton
pp 5025 - 5030; DOI:
10.1021/ja00353a028
PDF
A product study of 1-adamantyl and 1-bicyclo[2.2.2]octyl radicals in hydrocarbon solvents. An unusually large hydrogen isotope effect
Paul S. Engel, Woo Ki Chae, Sharon A. Baughman, Gregor E. Marschke, Edward S. Lewis, Jack W. Timberlake, and Alan E. Luedtke
pp 5030 - 5034; DOI:
10.1021/ja00353a029
PDF
Mechanism of carbon-carbon cleavage of cyclic 1,2-diketones with alkaline hydrogen peroxide. The acyclic mechanism and its application to the basic autoxidation of pyrogallol
Yasuhiko Sawaki and Christopher S. Foote
pp 5035 - 5040; DOI:
10.1021/ja00353a030
PDF
Photochemical and thermal stereomutations of 3-aryl-2-propenylideniminium salts
Ronald F. Childs and Brian D. Dickie
pp 5041 - 5046; DOI:
10.1021/ja00353a031
PDF
Ozonolysis of 1,1-difluoroethylene, trifluoroethylene, and perfluoroethylene: mechanism of ozonide, epoxide, and cyclopropane formation
John W. Agopovich and Charles W. Gillies
pp 5047 - 5053; DOI:
10.1021/ja00353a032
PDF
Solid-state chemistry, kinetics, and spectroscopy of 1,2-diphenylpropylidene
Hideo Tomioka, Norihiro Hayashi, Yasuji Izawa, V. P. Senthilnathan, and Matthew S. Platz
pp 5053 - 5057; DOI:
10.1021/ja00353a033
PDF
Local conformer control in medium-ring olefin epoxidation and osmylation
E. Vedejs and D. M. Gapinski
pp 5058 - 5061; DOI:
10.1021/ja00353a034
PDF
Description of conjugation and hyperconjugation in terms of electron distributions
R. F. W. Bader, T. S. Slee, D. Cremer, and E. Kraka
pp 5061 - 5068; DOI:
10.1021/ja00353a035
PDF
Description of homoaromaticity in terms of electron distributions
D. Cremer, E. Kraka, T. S. Slee, R. F. W. Bader, C. D. H. Lau, T. T. Nguyen Dang, and P. J. MacDougall
pp 5069 - 5075; DOI:
10.1021/ja00353a036
PDF
Enol thioethers as enol substitutes. An alkylation sequence
Barry M. Trost and Alvin C. Lavoie
pp 5075 - 5090; DOI:
10.1021/ja00353a037
PDF
Stereoelectronic control of intramolecular Michael addition reactions
Graham W. L. Ellis, C. David Johnson, and David N. Rogers
pp 5090 - 5095; DOI:
10.1021/ja00353a038
PDF
Rate constants for the reactions of free radicals with oxygen in solution
B. Maillard, K. U. Ingold, and J. C. Scaiano
pp 5095 - 5099; DOI:
10.1021/ja00353a039
PDF
Secondary isotope multiplet NMR spectroscopy of partially labeled entities. Carbon-13 SIMPLE NMR of carbohydrates
John C. Christofides and David B. Davies
pp 5099 - 5105; DOI:
10.1021/ja00353a040
PDF
Biosynthesis of antibiotics of the virginiamycin family. 3. Biosynthesis of virginiamycin M1
David G. I. Kingston, Michael X. Kolpak, Joseph W. LeFevre, and Ingrid Borup-Grochtmann
pp 5106 - 5110; DOI:
10.1021/ja00353a041
PDF
Catalysis by human leukocyte elastase: substrate structural dependence of rate-limiting protolytic catalysis and operation of the charge relay system
Ross L. Stein
pp 5111 - 5116; DOI:
10.1021/ja00353a042
PDF
Equilibrium species in cobalt(II) carbonic anhydrase
Ivano Bertini, G. Lanini, and C. Luchinat
pp 5116 - 5118; DOI:
10.1021/ja00353a043
PDF
Radical chain carriers in N-bromosuccinimide brominations
Cheves Walling, Gamil M. El-Taliawi, and Chengxue Zhao
pp 5119 - 5124; DOI:
10.1021/ja00353a044
PDF
Selectivities of .pi.- and .sigma.-succinimidyl radicals in substitution and addition reactions. Response to Walling, El-Taliawi and Zhao
P. S. Skell, R. L. Tlumak, and S. Seshadri
pp 5125 - 5131; DOI:
10.1021/ja00353a045
PDF
Facile synthesis of substituted brendanes via spirocyclopropane participation
Waldemar Adam, Nestor Carballeira, Eva Maria Peters, Karl Peters, and Hans Georg Von Schnering
pp 5132 - 5133; DOI:
10.1021/ja00353a046
PDF
Proton-transfer spectroscopy of 3-hydroxychromones. Extreme sensitivity to hydrogen-bonding perturbations
Dale McMorrow and Michael Kasha
pp 5133 - 5134; DOI:
10.1021/ja00353a047
PDF
2-Oxabicyclo[2.2.0]hexene/3-oxatricyclo[3.1.0.02,6]hexane isomerization
Philipp Eisenbarth, Gerhard Maas, and Manfred Regitz
pp 5134 - 5135; DOI:
10.1021/ja00353a048
PDF
Design and synthesis of a highly amphoteric condensed hydrocarbon with the highest reduction potential. Pentaleno[1,2,3-cd:4,5,6-c'd']diphenalene
Kazuhiro Nakasuji, Keiji Yoshida, and Ichiro Murata
pp 5136 - 5137; DOI:
10.1021/ja00353a049
PDF
An unprecedented ligand set and coordination geometry for copper(I)
Larry F. Rhodes, John C. Huffman, and Kenneth G. Caulton
pp 5137 - 5138; DOI:
10.1021/ja00353a050
PDF
Effect of a polar substituent on olefin triplet lifetime
Richard A. Caldwell and Major Singh
pp 5139 - 5140; DOI:
10.1021/ja00353a051
PDF
Azo precursors to a putative biradical in arene metal photoadditions: evidence for a novel concerted nitrogen expulsion
Robert S. Sheridan
pp 5140 - 5142; DOI:
10.1021/ja00353a052
PDF
Conductivity measurement of x-ray absorption spectrum: rhenium LIII near-edge structure of dirhenium decacarbonyl in 2,2,4-trimethylpentane
T. K. Sham and S. M. Heald
pp 5142 - 5143; DOI:
10.1021/ja00353a053
PDF
Triplet excitation transfer to carotenoids from biradical intermediates in Norrish type II photoreactions of o-alkyl-substituted aromatic carbonyl compounds
C. V. Kumar, S. K. Chattopadhyay, and P. K. Das
pp 5143 - 5144; DOI:
10.1021/ja00353a054
PDF
Quintet ground state of a non-Kekule tetraradical 3,6-dimethyleneanthracenyl-1,7-dioxy
David E. Seeger and Jerome A. Berson
pp 5144 - 5146; DOI:
10.1021/ja00353a055
PDF
2,6-Dimethyleneanthracenyl-4,8-dioxy. High-spin ground state of a disjoint biradical that has no Hueckel NBMO degeneracy
David E. Seeger and Jerome A. Berson
pp 5146 - 5147; DOI:
10.1021/ja00353a056
PDF
Electric field gradient at iron in dicarbonyl complexes of (tetraphenylporphyrinato)- and (octamethyltetrabenzoporphyrinato)iron(II)
Kenneth J. Reimer, Craig A. Sibley, and John R. Sams
pp 5147 - 5149; DOI:
10.1021/ja00353a057
PDF
Stereoselective formation of cis-stilbene ozonide from the cosensitized electron-transfer photooxygenation of cis- and trans-2,3-diphenyloxiranes
A. Paul Schaap, Shahabuddin Siddiqui, Steven D. Gagnon, and Luigi Lopez
pp 5149 - 5150; DOI:
10.1021/ja00353a058
PDF
Syn and anti stereochemistry in elimination reactions producing acyclic conjugated thioesters
Jerry R. Mohrig, Steve C. Schultz, and Gregg Morin
pp 5150 - 5151; DOI:
10.1021/ja00353a059
PDF
Optical resolution of 3-methylcycloalkanones and 5-methyl-.gamma.-butyrolactone by complexation with optically active 1,6-bis(o-halophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol
Fumio Toda, Koichi Tanaka, Tetsuo Omata, Kazuyoshi Nakamura, and Tokio Oshima
pp 5151 - 5152; DOI:
10.1021/ja00353a060
PDF
Crystal and molecular structures of 2,11-dithia- and 1,3,10,12-tetrathia[3.3](2,6)-pyridinophanes
George R. Newkome, Sebastiano Pappalardo, and Frank R. Fronczek
pp 5152 - 5153; DOI:
10.1021/ja00353a061
PDF
Electrophilic trapping of the tautomer of 7-deoxydaunomycinone. A possible mechanism for covalent binding of daunomycin to DNA
Don L. Kleyer and Tad H. Koch
pp 5154 - 5155; DOI:
10.1021/ja00353a062
PDF
Photodecomposition of alkanones in urea inclusion compounds
H. L. Casal, P. De Mayo, J. F. Miranda, and J. C. Scaiano
pp 5155 - 5156; DOI:
10.1021/ja00353a063
PDF
Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry
John D. Simon and Kevin S. Peters
pp 5156 - 5158; DOI:
10.1021/ja00353a064
PDF
Cation radical Diels-Alder reactions of electron-rich dienophiles
Raul A. Pabon, Dennis J. Bellville, and Nathan L. Bauld
pp 5158 - 5159; DOI:
10.1021/ja00353a065
PDF
Taft-Kamlet .pi.* solvatochromic polarity parameters of solid compounds
Richard Fuchs and W. Kirk Stephenson
pp 5159 - 5160; DOI:
10.1021/ja00353a066
PDF
Photoaffinity labeling of bacteriorhodopsin with 3-([1-14C]diazoacetoxy)-trans-retinal
Ranjan Sen, Theodore S. Widlanski, Valeria Balogh-Nair, and Koji Nakanishi
pp 5160 - 5162; DOI:
10.1021/ja00353a067
PDF
Evidence for the necessity of double bond (13-ene) isomerization in the proton pumping of bacteriorhodopsin
Jim Min Fang, John D. Carriker, Valeria Balogh-Nair, and Koji Nakanishi
pp 5162 - 5164; DOI:
10.1021/ja00353a068
PDF
Structure and synthesis of 3-deoxy-D-glycero-pentos-2-ulose, an unusual sugar produced enzymatically from (ADP-ribosyl)histone H2B
Hajime Komura, Takashi Iwashita, Hideo Naoki, Koji Nakanishi, Jun Oka, Kunihiro Ueda, and Osamu Hayaishi
pp 5164 - 5165; DOI:
10.1021/ja00353a069
PDF
Hydrogen-bond stabilization of oxygen in hemoprotein models
Joel Mispelter, Michel Momenteau, Daniel Lavalette, and Jean Marc Lhoste
pp 5165 - 5166; DOI:
10.1021/ja00353a070
PDF
Heteronuclear 2D-NOE spectroscopy
Peter L. Rinaldi
pp 5167 - 5168; DOI:
10.1021/ja00353a071
PDF
Additions and Corrections - Low-Valent Molybdenum Porphyrin Derivatives: Synthesis and Structure of a π-Bonded Adduct of Molbdenum(II) (meso-Tetra-p-tolylporphyrin)
Andre De Cian, Jocelyne Colin, Michel Schappacher, Louis Ricard, and Raymond Weiss
pp 5168 - 5168; DOI:
10.1021/ja00353a601
PDF
Additions and Corrections - Fast Hydrolysis of Alkyl Radicals with Leaving Groups in the β Position
G. Koltzenburg, G. Behrens, and D. Shulte-Frohlinde
pp 5168 - 5168; DOI:
10.1021/ja00353a602
PDF
Book reviews

pp 5169 - 5184; DOI:
10.1021/ja00353a600
PDF

Issue 16


Multiple proton transfers within long-lived ion-molecule complexes
Robert R. Squires, Veronica M. Bierbaum, Joseph J. Grabowski, and Charles H. DePuy
pp 5185 - 5192; DOI:
10.1021/ja00354a001
PDF
Transient species in electron transfer: reactions of chloranil with donor aromatic compounds
E. F. Hilinski, S. V. Milton, and P. M. Rentzepis
pp 5193 - 5196; DOI:
10.1021/ja00354a002
PDF
Studies of the reactions of Group VIII transition-metal ions [iron(+), cobalt(+), and nickel(+)] with linear alkanes. Determination of reaction mechanisms and MCnH2n+ ion structures using Fourier transform mass spectrometry collision-induced dissociation
D. B. Jacobson and B. S. Freiser
pp 5197 - 5206; DOI:
10.1021/ja00354a003
PDF
Picosecond laser photolysis studies of deactivation processes of excited hydrogen bonding complexes. 3. Detection of the nonfluorescent charge-transfer state in the excited 1-aminopyrene-pyridine hydrogen bonded pair and related systems
Noriaki Ikeda, Hiroshi Miyasaka, Tadashi Okada, and Noboru Mataga
pp 5206 - 5211; DOI:
10.1021/ja00354a004
PDF
Electron spin resonance studies of 1,4-disilacyclohexa-2,5-diene free radical reactions
Jonathan D. Rich and Robert West
pp 5211 - 5215; DOI:
10.1021/ja00354a005
PDF
Molecular quadrupole moments, magnetic anisotropies, and charge distributions of ferrocene and ruthenocene
Geoffrey L. D. Ritchie, Mervyn K. Cooper, Robert L. Calvert, Gary R. Dennis, Leonidas Phillips, and Julian Vrbancich
pp 5215 - 5219; DOI:
10.1021/ja00354a006
PDF
The calculation of molecular volumes and the use of volume analysis in the investigation of structured media and of solid-state organic reactivity
A. Gavezzotti
pp 5220 - 5225; DOI:
10.1021/ja00354a007
PDF
Bifurcated vs. linear hydrogen bonds: dimethyl phosphate and formate anion interactions with water
Giuliano Alagona, Caterino Ghio, and Peter Kollman
pp 5226 - 5230; DOI:
10.1021/ja00354a008
PDF
Luminescence quenching studies in NaLS micellar systems at 77 K
S. Hashimoto and J. K. Thomas
pp 5230 - 5237; DOI:
10.1021/ja00354a009
PDF
Photoinduced reactions. 143. Spin inversion in the 1,4-diradical derived from 2,4,6-triisopropylbenzophenone: importance of lone-pair orbital rotation
Yoshikatsu Ito and Teruo Matsuura
pp 5237 - 5244; DOI:
10.1021/ja00354a010
PDF
Looking at chemistry as a spin ordering problem
D. Maynau, M. Said, and J. P. Malrieu
pp 5244 - 5252; DOI:
10.1021/ja00354a011
PDF
Carbodications. 6. The ethylene dication: a theoretical study of the ethylene dication (C2H42+) potential-energy surface
Koop Lammertsma, Mario Barzaghi, George A. Olah, John A. Pople, Alexander J. Kos, and Paul v. R. Schleyer
pp 5252 - 5257; DOI:
10.1021/ja00354a012
PDF
Carbodications. 7. Structure and stability of diprotonated methane, CH62+
Koop Lammertsma, Mario Barzaghi, George A. Olah, John A. Pople, P. V. R. Schleyer, and Massimo Simonetta
pp 5258 - 5263; DOI:
10.1021/ja00354a013
PDF
CASSCF study of reaction of singlet molecular oxygen with ethylene. Reaction paths with C2v and Cs symmetries
M. Hotokka, B. Roos, and P. Siegbahn
pp 5263 - 5269; DOI:
10.1021/ja00354a014
PDF
Clustering of hydrophobic ions in the presence and absence of the polysoap poly(vinylbenzo-18-crown-6)
Bruno Roland and Johannes Smid
pp 5269 - 5271; DOI:
10.1021/ja00354a015
PDF
Electrochemical behavior of a dopamine polymer. Dopamine release as a primitive analog of a synapse
Aldrich N. K. Lau and Larry L. Miller
pp 5271 - 5277; DOI:
10.1021/ja00354a016
PDF
Release of the neurotransmitters glutamate and .gamma.-aminobutyric acid from an electrode. Catalysis of slow redox propagation through a polymer film
Aldrich N. K. Lau, Larry L. Miller, and Baruch Zinger
pp 5278 - 5284; DOI:
10.1021/ja00354a017
PDF
Metallacyclobutane rearrangements
Charles N. Wilker and Roald Hoffmann
pp 5285 - 5290; DOI:
10.1021/ja00354a018
PDF
The mechanism of iron EDTA catalyzed superoxide dismutation
Christopher Bull, Gregory J. McClune, and James A. Fee
pp 5290 - 5300; DOI:
10.1021/ja00354a019
PDF
Charge-transfer perturbations of the electronic contributions to bimolecular reactions. Nonadiabatic effects observed in energy-transfer and electron-transfer reactions
John F. Endicott, T. Ramasami, Dennis C. Gaswick, R. Tamilarasan, Mary Jane Heeg, George R. Brubaker, and Stephen C. Pyke
pp 5301 - 5310; DOI:
10.1021/ja00354a020
PDF
Electronic absorption and emission spectra of complexes containing dichromium, dimolybdenum, and ditungsten quadruple bonds
Mark C. Manning and William C. Trogler
pp 5311 - 5320; DOI:
10.1021/ja00354a021
PDF
Isolation and crystal structures of the halide-free and halide-rich phenyllithium etherate complexes [(PhLi.Et2O)4] and [(PhLi.Et2O)3.LiBr]
Haakon Hope and Philip P. Power
pp 5320 - 5324; DOI:
10.1021/ja00354a022
PDF
(.eta.5-Cyclopentadienyl)- and (.eta.5-pentamethylcyclopentadienyl)copper compounds containing phosphine, carbonyl, and .eta.2-acetylenic ligands
David W. Macomber and Marvin D. Rausch
pp 5325 - 5329; DOI:
10.1021/ja00354a023
PDF
Synthesis of inequivalently bridged cyclopentadienyl dimers of molybdenum and a comparison of their reactivities with unsaturated molecules and with hydrogen
Maryanne McKenna, Laura L. Wright, Douglas J. Miller, Linnea Tanner, R. C. Haltiwanger, and M. Rakowski DuBois
pp 5329 - 5337; DOI:
10.1021/ja00354a024
PDF
Synthesis of some polyimidazole ligands related to zinc enzymes
Ronald Breslow, John T. Hunt, Richard Smiley, and Thomas Tarnowski
pp 5337 - 5342; DOI:
10.1021/ja00354a025
PDF
Synthesis, x-ray crystal structure, and study of dynamic behavior of [dihydrobis(3,5-dimethyl-1-pyrazolyl)borato]chlorotrimethyltantalum(V), a molecule with a strong 3-center, 2-electron bond
Daniel L. Reger, Cornelius A. Swift, and Lukasz Lebioda
pp 5343 - 5347; DOI:
10.1021/ja00354a026
PDF
Synthesis, linkage isomerism, and ligand reactivity of (urea)pentaamminerhodium(III) complexes
Neville J. Curtis, Nicholas E. Dixon, and Alan M. Sargeson
pp 5347 - 5353; DOI:
10.1021/ja00354a027
PDF
Crystal lattice control of unimolecular photorearrangements. Medium-dependent photochemistry of cyclohexenones
Wolfgang K. Appel, Z. Q. Jiang, John R. Scheffer, and Leueen Walsh
pp 5354 - 5363; DOI:
10.1021/ja00354a028
PDF
The 7-norbornyl cation. Structure and interactions
Dionis E. Sunko, Hrvoj Vancik, Vjera Deljac, and Milorad Milun
pp 5364 - 5368; DOI:
10.1021/ja00354a029
PDF
Chiral deuterium labeling: new method for determination of rotational propensities
William Von Eggers Doering and Yoshiro Yamashita
pp 5368 - 5372; DOI:
10.1021/ja00354a030
PDF
Synthetic applications of N-acylamino-1,3-dienes. 10. Importance of allylic interactions and stereoelectronic effects in dictating the steric course of the reaction of iminium ions with nucleophiles. An efficient total synthesis of (.+-.)-gephyrotoxin
Larry E. Overman, Dominique Lesuisse, and Mitsunori Hashimoto
pp 5373 - 5379; DOI:
10.1021/ja00354a031
PDF
Base-catalyzed hydrogen exchange of phenylacetylene and chloroform. Broensted relations and normal acid behavior
A. C. Lin, Y. Chiang, D. B. Dahlberg, and A. J. Kresge
pp 5380 - 5386; DOI:
10.1021/ja00354a032
PDF
Electrostatic catalysis of proton-transfer reactions: hydrogen exchange in chloroform and ionization of 2-nitropropane
D. B. Dahlberg, M. A. Kuzemko, Y. Chiang, A. J. Kresge, and M. F. Powell
pp 5387 - 5390; DOI:
10.1021/ja00354a033
PDF
Alkylation of amino acids without loss of the optical activity: preparation of .alpha.-substituted proline derivatives. A case of self-reproduction of chirality
Dieter Seebach, Michael Boes, Reto Naef, and W. Bernd Schweizer
pp 5390 - 5398; DOI:
10.1021/ja00354a034
PDF
Structure and conformation of 5-methylarabinosylcytosine, a potential antiviral nucleoside
George I. Birnbaum and Glenn A. Gentry
pp 5398 - 5402; DOI:
10.1021/ja00354a035
PDF
Desulfurization of the epidithiopiperazinedione sirodesmin PL with triphenylphosphine: retention of configuration at the bridgehead carbon atoms
Jean Pierre Ferezou, Annik Quesneau-Thierry, Michele Cesario, Claudine Pascard, and Michel Barbier
pp 5402 - 5406; DOI:
10.1021/ja00354a036
PDF
Conformational analysis of functionalized sultines by nuclear magnetic resonance and x-ray crystallography. Application of a generalized Karplus equation
C. A. G. Haasnoot, R. M. J. Liskamp, P. A. W. Van Dael, J. H. Noordik, and H. C. J. Ottenheijm
pp 5406 - 5414; DOI:
10.1021/ja00354a037
PDF
Volumetric study on the 1,3-dipolar cycloaddition reaction. 2. .alpha.-Benzoyl-N-phenylnitrone with several olefins
Y. Yoshimura, J. Osugi, and M. Nakahara
pp 5414 - 5418; DOI:
10.1021/ja00354a038
PDF
Reactions with aromatic compounds of recoiling bromine atoms formed from the krypton-76,77 .fwdarw. bromine-76,77 transformations. Liquid-phase reactions
Stephen M. Moerlein, Michael J. Welch, and Alfred P. Wolf
pp 5418 - 5428; DOI:
10.1021/ja00354a039
PDF
Reaction selectivity of translationally and electronically excited carbon-11 atoms with ethylene
Richard A. Ferrieri, Alfred P. Wolf, and Yi Noo Tang
pp 5428 - 5433; DOI:
10.1021/ja00354a040
PDF
Mechanism of the oxidation of dopamine by the hydroxyl radical in aqueous solution
Helen W. Richter and Walter H. Waddell
pp 5434 - 5440; DOI:
10.1021/ja00354a041
PDF
Total synthesis of a monosubstituted dodecahedrane. The methyl derivative
Leo A. Paquette, Robert J. Ternansky, Douglas W. Balogh, and William J. Taylor
pp 5441 - 5446; DOI:
10.1021/ja00354a042
PDF
Total synthesis of dodecahedrane
Leo A. Paquette, Robert J. Ternansky, Douglas W. Balogh, and Gary Kentgen
pp 5446 - 5450; DOI:
10.1021/ja00354a043
PDF
MNDO calculation of kinetic isotope effects in model cytochrome P-450 oxidations
J. Paul Shea, Sidney D. Nelson, and George P. Ford
pp 5451 - 5454; DOI:
10.1021/ja00354a044
PDF
Effects of oxygen-17 and oxygen-18 on phosphorus-31 NMR: further investigation and applications
R. Douglas Sammons, Perry A. Frey, Karol Bruzik, and Ming Daw Tsai
pp 5455 - 5461; DOI:
10.1021/ja00354a045
PDF
Stereochemistry of lysine 2,3-aminomutase isolated from Clostridium subterminale strain SB4
D. John Aberhart, Steven J. Gould, Horng Jau Lin, T. K. Thiruvengadam, and Bruce H. Weiller
pp 5461 - 5470; DOI:
10.1021/ja00354a046
PDF
Biosynthesis of streptothricin F. 5. Formation of .beta.-lysine by Streptomyces L-1689-23
T. K. Thiruvengadam, Steven J. Gould, D. John Aberhart, and Horng Jau Lin
pp 5470 - 5476; DOI:
10.1021/ja00354a047
PDF
Novel alkyne reactions with binuclear molybdenum-sulfur complexes: structure of the dimethyl acetylenedicarboxylate adduct of dioxobis(dithioxo)di-.mu.-thiodimolybdate(2-) ion ([Mo2O2(.mu.-S)2(S2)2]2-)
Thomas R. Halbert, Wie Hin Pan, and Edward I. Stiefel
pp 5476 - 5477; DOI:
10.1021/ja00354a048
PDF
Novel approach to vicinal stereocontrol during carbon-carbon bond formation. Stereocontrolled synthesis of (.+-.)-threo-juvabione
D. J. Morgans and Gregg B. Feigelson
pp 5477 - 5479; DOI:
10.1021/ja00354a049
PDF
The first triple-decker sandwich with a bridging benzene ring
Alan W. Duff, Klaus Jonas, Richard Goddard, Hans Juergen Kraus, and Carl Krueger
pp 5479 - 5480; DOI:
10.1021/ja00354a050
PDF
Metal-bridging benzene in a binuclear hydridovanadium complex
Klaus Jonas, Volker Wiskamp, Yi Hung Tsay, and Carl Krueger
pp 5480 - 5481; DOI:
10.1021/ja00354a051
PDF
Carbene chemistry of cations: the chemistry of the carbene cation :C3H+ in the gas phase
Diethard K. Bohme, Asit B. Raksit, and Arnold Fox
pp 5481 - 5483; DOI:
10.1021/ja00354a052
PDF
Nuclear Overhauser effect measurements involving the imino protons of yeast tRNAPhe using two-dimensional proton NMR spectroscopy
C. A. G. Haasnoot, A. Heerschap, and C. W. Hilbers
pp 5483 - 5484; DOI:
10.1021/ja00354a053
PDF
Methyleneoxonium and hydroxymethylene dications: dicationic analogs of ethylene and acetylene
Willem J. Bouma and Leo Radom
pp 5484 - 5486; DOI:
10.1021/ja00354a054
PDF
Location of double-bond position in unsaturated fatty acids by negative ion MS/MS
Kenneth B. Tomer, Frank W. Crow, and Michael L. Gross
pp 5487 - 5488; DOI:
10.1021/ja00354a055
PDF
Preparation and structural characterization of acetylene(2,2'-dipyridylamine)copper(I) tetrafluoroborate
Jeffery S. Thompson and John F. Whitney
pp 5488 - 5490; DOI:
10.1021/ja00354a056
PDF
A titanium vinylidene route to substituted allenes
Stephen L. Buchwald and Robert H. Grubbs
pp 5490 - 5491; DOI:
10.1021/ja00354a057
PDF
Carbon-13 CP-MAS NMR spectra of paramagnetic solids
V. P. Chacko, S. Ganapathy, and R. G. Bryant
pp 5491 - 5492; DOI:
10.1021/ja00354a058
PDF
Metal-metal interactions in binuclear platinum(II) diphosphite complexes. Resonance Raman spectra of the 1A1g(d.sigma.*)2 and 3A2u(d.sigma.*p.sigma.) electronic states of tetrakis(diphosphonato)diplatinate(4-) ion (Pt2(P2O5H2)44-)
Chi Ming Che, Leslie G. Butler, Harry B. Gray, R. M. Crooks, and William H. Woodruff
pp 5492 - 5494; DOI:
10.1021/ja00354a059
PDF
Synthesis of conduritol a from benzoquinone using 9-benzyloxymethoxyanthracene as a protecting and directing group
Spencer Knapp, Raphael M. Ornaf, and Karen E. Rodriques
pp 5494 - 5495; DOI:
10.1021/ja00354a060
PDF
Two-photon excitation of d .fwdarw. d* transitions in a rhodium(III) complex
M. Johnson Hassinger and F. E. Lytle
pp 5495 - 5496; DOI:
10.1021/ja00354a061
PDF
Static distortion of 2E molecular cations of cyclobutane at 4.2 K giving 2B2 with C2v symmetry and its dynamic average at >77 K: ESR evidence
Kiminori Ushida, Tadamasa Shida, Machio Iwasaki, Kazumi Toriyama, and Keichi Nunome
pp 5496 - 5497; DOI:
10.1021/ja00354a062
PDF
Recognition of the phase relationship between remote substituents in 9,10-bis(3-chloro-9-triptycyloxy)triptycene molecules undergoing rapid internal rotation cooperatively
Noboru Koga, Yuzo Kawada, and Hiizu Iwamura
pp 5498 - 5499; DOI:
10.1021/ja00354a063
PDF
Photoinitiated chain decomposition of phenyl isocyanate via its reaction with phenylnitrene
Walter H. Waddell and Natalie B. Feilchenfeld
pp 5499 - 5500; DOI:
10.1021/ja00354a064
PDF
Testing theoretical models of micelles. The acetylenic probe
F. M. Menger and J. F. Chow
pp 5501 - 5502; DOI:
10.1021/ja00354a065
PDF
Chemical reactivity of the zirconium hydride complex [(.eta.5-C5H4Me)2ZrH(.mu.-H)]2. ESR evidence for the formation and participation of paramagnetic zirconocene complexes
S. Bart Jones and Jeffrey L. Petersen
pp 5502 - 5503; DOI:
10.1021/ja00354a066
PDF
Synthesis and properties of macrobicyclic amine complexes of rhodium(III) and iridium(III)
Jack M. Harrowfield, Anthony J. Herlt, Peter A. Lay, Alan M. Sargeson, Alan M. Bond, William A. Mulac, and James C. Sullivan
pp 5503 - 5505; DOI:
10.1021/ja00354a067
PDF
Octahedral metal carbonyls. 54. Rates of chelate ring closure in five-coordinate metal carbonyl intermediates
Gerard R. Dobson, Saber E. Mansour, D. Eric Halverson, and Erika S. Erikson
pp 5505 - 5506; DOI:
10.1021/ja00354a068
PDF
Synthesis and structure of a diarsene: the first compound with an unsupported arsenic-arsenic double bond
A. H. Cowley, J. G. Lasch, N. C. Norman, and M. Pakulski
pp 5506 - 5507; DOI:
10.1021/ja00354a069
PDF
Elemental sulfur- and selenium-induced intramolecular carbyne-carbyne coupling in trinuclear bis(carbyne) cobalt clusters. A novel entry into metalladithiolenes and metalladiselenolenes
K. Peter C. Vollhardt and Eric C. Walborsky
pp 5507 - 5509; DOI:
10.1021/ja00354a070
PDF
Nucleophilic displacement with a selectively solvated nucleophile: the system hydrated hydroxide ion (OH-.cntdot.H2O) + bromomethane at 300 K
Michael Henchman, John F. Paulson, and Peter M. Hierl
pp 5509 - 5510; DOI:
10.1021/ja00354a071
PDF
A simplified total synthesis of cytochalasins via an intramolecular Diels-Alder reaction
Gilbert Stork and Eiichi Nakamura
pp 5510 - 5512; DOI:
10.1021/ja00354a072
PDF
Book Reviews

pp 5512 - 5528; DOI:
10.1021/ja00354a600
PDF

Issue 17


NMR studies of pyridine on silica-alumina
Gary E. Maciel, James F. Haw, I. Ssuer Chuang, Bruce L. Hawkins, Thomas A. Early, Dale R. McKay, and Leon Petrakis
pp 5529 - 5535; DOI:
10.1021/ja00355a001
PDF
X.alpha. calculations of the EPR parameters of pseudotetrahedral copper(II) complexes
Alessandro Bencini and Dante Gatteschi
pp 5535 - 5541; DOI:
10.1021/ja00355a002
PDF
The 1,2 hydrogen shift as an accompaniment to ring closure and opening: ab initio MO study of thermal rearrangements on the C2H3N potential energy hypersurface
L. L. Lohr, M. Hanamura, and K. Morokuma
pp 5541 - 5547; DOI:
10.1021/ja00355a003
PDF
Ab initio CI study of chemical reactions of singlet and triplet imidogen (NH) radicals
Takayuki Fueno, Vlasta Bonacic-Koutecky, and Jaroslav Koutecky
pp 5547 - 5557; DOI:
10.1021/ja00355a004
PDF
Theoretical investigation of the elimination and addition reactions of methane and ethane with nickel
Margareta R. A. Blomberg, Ulf Brandemark, and Per E. M. Siegbahn
pp 5557 - 5563; DOI:
10.1021/ja00355a005
PDF
Ionization potentials, electron affinities, and molecular orbitals of 2-substituted norbornadienes. Theory of 1,2 and homo-1,4 carbene cycloaddition selectivities
K. N. Houk, Nelson G. Rondan, Michael N. Paddon-Row, Charles W. Jefford, Thanh Huy Phan, Paul D. Burrow, and K. D. Jordan
pp 5563 - 5569; DOI:
10.1021/ja00355a006
PDF
Magnetic susceptibility anisotropy, molecular g values, and other molecular properties of cyclopropane as determined from rotational Zeeman studies of the cyclopropane-hydrochloric-35Cl acid and cyclopropane-hydrocyanic-15N acid complexes
P. D. Aldrich, S. G. Kukolich, E. J. Campbell, and W. G. Read
pp 5569 - 5576; DOI:
10.1021/ja00355a007
PDF
Phosphorescence and triplet-state optically detected magnetic resonance studies of acetylacetonates of the ammonium and some group 2 metal ions
J. J. Sahbari, K. D. Bomben, and D. S. Tinti
pp 5577 - 5583; DOI:
10.1021/ja00355a008
PDF
Photochemistry of tris(2,2'-bipyridine)ruthenium(2+) ion (Ru(bpy)32+). Solvent effects
Jonathan V. Caspar and Thomas J. Meyer
pp 5583 - 5590; DOI:
10.1021/ja00355a009
PDF
Distribution of site reactivities in photoreactive amorphous solids
Eric Pitts and Arnost Reiser
pp 5590 - 5593; DOI:
10.1021/ja00355a010
PDF
Mediated electrochemical reduction of oxygen to hydrogen peroxide via a surface-confined naphthoquinone reagent and the mediated electrochemical reduction of a naphthoquinone redox reagent anchored to high surface area oxides
Gary S. Calabrese, Robert M. Buchanan, and Mark S. Wrighton
pp 5594 - 5600; DOI:
10.1021/ja00355a011
PDF
Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins
K. A. Macor and T. G. Spiro
pp 5601 - 5607; DOI:
10.1021/ja00355a012
PDF
Bioorganic applications of mass spectrometry. 3. Fast-atom-bombardment-induced zwitterionic oligonucleotide quasimolecular ions sequenced by MS/MS
Maria Panico, Giovanni Sindona, and Nicola Uccella
pp 5607 - 5610; DOI:
10.1021/ja00355a013
PDF
Electrochemical and spectral characterization of iron mono- and dinitrosyl porphyrins
D. Lancon and K. M. Kadish
pp 5610 - 5617; DOI:
10.1021/ja00355a014
PDF
Reduction potentials for 2,2'-bipyridine and 1,10-phenanthroline couples in aqueous solutions
C. V. Krishnan, Carol Creutz, Harold A. Schwarz, and Norman Sutin
pp 5617 - 5623; DOI:
10.1021/ja00355a015
PDF
Kinetic studies of metal-metal bonded species: protonation of octachlorodimolybdate(4-) ion and hydrogen evolution from octachlorohydrodimolybdate(3-) ion
Steven S. Miller and Albert Haim
pp 5624 - 5626; DOI:
10.1021/ja00355a016
PDF
Two-dimensional dynamical Jahn-Teller effects in a mixed-valence benzotriazolato copper cluster, Cu5(BTA)6(RNC)4
G. F. Kokoszka, J. Baranowski, C. Goldstein, J. Orsini, A. D. Mighell, V. L. Himes, and A. R. Siedle
pp 5627 - 5633; DOI:
10.1021/ja00355a017
PDF
Vibrational broadening in fluorine 1s hole states and the 8a1g valence orbital of xenon hexafluoride: structure of xenon hexafluoride and heats of formation of unusual cations
D. J. Bristow and G. M. Bancroft
pp 5634 - 5638; DOI:
10.1021/ja00355a018
PDF
Novel products in the carbonylation of the triply bonded ditungsten hexaisopropoxide dipyridine adduct. 2. Preparation and structure of tetracarbonylhexakis(isopropanolato)ditungsten (W2(O-iso-Pr)6(CO)4), molecule containing two atoms of the same metallic element with oxidation numbers differing by six units
F. Albert Cotton and Willi Schwotzer
pp 5639 - 5641; DOI:
10.1021/ja00355a019
PDF
Mechanisms of A-frame inversion for binuclear platinum(II) complexes with bis(diphenylphosphino)methane ligands
Richard J. Puddephatt, Kazi A. Azam, Ross H. Hill, Michael P. Brown, Charles D. Nelson, Roger P. Moulding, Kenneth R. Seddon, and Martin C. Grossel
pp 5642 - 5646; DOI:
10.1021/ja00355a020
PDF
Silver(I) chemistry in aqueous alkaline media. 2. Study of the interaction of silver(I) with .beta.-disulfone carbanions in aqueous alkaline media
John R. DeMember, Hilton F. Evans, Fredrick A. Wallace, and Patricia A. Tariverdian
pp 5647 - 5652; DOI:
10.1021/ja00355a021
PDF
Photochemistry of acetone in surfactant solutions
W. J. Leigh and J. C. Scaiano
pp 5652 - 5657; DOI:
10.1021/ja00355a022
PDF
Onium ions. 26. Aminodiazonium ions: preparation, proton, carbon-13, and nitrogen-15 NMR structural studies, and electrophilic amination of aromatics
George A. Olah
pp 5657 - 5660; DOI:
10.1021/ja00355a023
PDF
Piperidino and pyrrolidino demethoxylation of 4-methoxy-1-methyl-2,6-diphenylpyridinium ion. Rate parameters and base catalysis
Raffaele Aveta, Giancarlo Doddi, and Gabriello Illuminati
pp 5661 - 5664; DOI:
10.1021/ja00355a024
PDF
Reduction of halosilanes by organotin hydrides
James W. Wilt, Frank G. Belmonte, and Paul A. Zieske
pp 5665 - 5675; DOI:
10.1021/ja00355a025
PDF
Generation and chemical properties of dicyclopropylcarbene. Ring expansion, chlorine abstraction, carbon-hydrogen bond insertion, and alkene addition reactions
Michel Bekhazi, Prabhakar A. Risbood, and John Warkentin
pp 5675 - 5679; DOI:
10.1021/ja00355a026
PDF
Total synthesis of (.+-.)-spiniferin-1, a naturally occurring 1,6-methano[10]annulene
James A. Marshall and Raymond E. Conrow
pp 5679 - 5688; DOI:
10.1021/ja00355a027
PDF
Total synthesis of 11-deoxydaunomycinone
Frank M. Hauser and Dipakranjan Mal
pp 5688 - 5690; DOI:
10.1021/ja00355a028
PDF
Stereochemical studies of the electrolytic reactions of organic compounds. Part 22. Electroorganic reactions on organic electrodes. 3. Electrochemical asymmetric oxidation of phenyl cyclohexyl sulfide on poly(L-valine)-coated platinum electrodes
Tetsuo Komori and Tsutomu Nonaka
pp 5690 - 5691; DOI:
10.1021/ja00355a029
PDF
Clay-modified electrodes
Pushpito K. Ghosh and Allen J. Bard
pp 5691 - 5693; DOI:
10.1021/ja00355a030
PDF
Dicopper complexes of a macrocyclic ligand as models for type 3 copper proteins
S. Martin Nelson, Ferida Esho, Aidan Lavery, and Michael G. B. Drew
pp 5693 - 5695; DOI:
10.1021/ja00355a031
PDF
Photochemical hydrogen generation by visible light. Sensitization of titanium dioxide particles by surface complexation with 8-hydroxyquinoline
V. H. Houlding and M. Gratzel
pp 5695 - 5696; DOI:
10.1021/ja00355a032
PDF
Carbon monoxide activation by organoactinides. .eta.2-Acyl-carbon monoxide coupling and the formation of metal-bound ketenes
Kenneth G. Moloy, Tobin J. Marks, and Victor W. Day
pp 5696 - 5698; DOI:
10.1021/ja00355a033
PDF
The transannular ozonide of 9-tert-butyl-10-methylanthracene
Yoshikatsu Ito, Akira Matsuura, Ryohei Otani, Teruo Matsuura, Keiichi Fukuyama, and Yukiteru Katsube
pp 5699 - 5700; DOI:
10.1021/ja00355a034
PDF
Bilayer induced diastereomeric kinetic differentiation
Russell C. Petter, John C. Mitchell, William J. Brittain, Thomas J. McIntosh, and Ned A. Porter
pp 5700 - 5701; DOI:
10.1021/ja00355a035
PDF
Proton NMR study of the mechanism of the heme-apoprotein reaction for myoglobin
T. Jue, R. Krishnamoorthi, and Gerd N. La Mar
pp 5701 - 5703; DOI:
10.1021/ja00355a036
PDF
Chemoselective desilylation of silyl enol ethers with tributyltin fluoride catalyzed by palladium
Hirokazu Urabe, Yasunobu Takano, and Isao Kuwajima
pp 5703 - 5704; DOI:
10.1021/ja00355a037
PDF
Reaction-coordinate tunneling in hydride-transfer reactions
W. Phillip Huskey and Richard L. Schowen
pp 5704 - 5706; DOI:
10.1021/ja00355a038
PDF
Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiators
O. W. Webster, W. R. Hertler, D. Y. Sogah, W. B. Farnham, and T. V. RajanBabu
pp 5706 - 5708; DOI:
10.1021/ja00355a039
PDF
Picosecond observation of kinetic vs. thermodynamic hydrogen atom transfer
Lewis E. Manring and Kevin S. Peters
pp 5708 - 5709; DOI:
10.1021/ja00355a040
PDF
Solvolytic hydroperoxide rearrangements. A new ring expansion reaction
Robert C. Ronald and Thomas S. Lillie
pp 5709 - 5710; DOI:
10.1021/ja00355a041
PDF
The cis addition of hydride to .eta.2-alkyne complexes by initial reaction at an .eta.5-cyclopentadienyl (.eta.5-C5H5) ring. Crystal and molecular structure of the carbonyl-.eta.5-cyclopentadienyliron complex (.eta.5-C5H5)FeCO(PPh3)[.eta.1-E-C(CO2Et):CHMe]
Daniel L. Reger, Kenneth A. Belmore, Jerry L. Atwood, and William E. Hunter
pp 5710 - 5711; DOI:
10.1021/ja00355a042
PDF
Contribution of intrinsic volume change of the reactants to the pressure effect on outer-sphere and intramolecular electron-transfer reactions involving cobalt(III) to cobalt(II) reduction
Masatoshi Kanesato, Masahiro Ebihara, Yoichi Sasaki, and Kazuo Saito
pp 5711 - 5713; DOI:
10.1021/ja00355a043
PDF
Carbon-13 NMR study of liquid crystal solutions. Chemical shift tensors in benzonitrile
B. M. Fung
pp 5713 - 5714; DOI:
10.1021/ja00355a044
PDF
Homopolyatomic anions. The synthesis and characterization of the novel paramagnetic nonastannide(3-) anion Sn93-, a D3h cluster with 21 skeletal electrons
Susan C. Critchlow and John D. Corbett
pp 5715 - 5716; DOI:
10.1021/ja00355a045
PDF

Issue 18


Carbon-13 NMR of crystalline morphine
J. G. Hexem, M. H. Frey, and S. J. Opella
pp 5717 - 5719; DOI:
10.1021/ja00356a001
PDF
Structure and reactivity of gas-phase ions: C4H4.bul.+
Winfried Wagner-Redeker, Andreas J. Illies, Paul R. Kemper, and Michael T. Bowers
pp 5719 - 5724; DOI:
10.1021/ja00356a002
PDF
Electrocyclic ring opening of 1-phenylcyclobutene and 3-phenylcyclobutene radical cations
Chhabil Dass and M. L. Gross
pp 5724 - 5729; DOI:
10.1021/ja00356a003
PDF
Solvation of organic oxyanions studied by oxygen-17 NMR
Lars Baltzer and Edwin D. Becker
pp 5730 - 5733; DOI:
10.1021/ja00356a004
PDF
NMR spectra of porphyrins. 21. Applications of the ring-current model to porphyrin and chlorophyll aggregation
Raymond J. Abraham and Kevin M. Smith
pp 5734 - 5741; DOI:
10.1021/ja00356a005
PDF
Argon matrix investigation of the 1:1 molecular complexes of silicon tetrafluoride with water, methanol, and dimethyl ether
Bruce S. Ault
pp 5742 - 5746; DOI:
10.1021/ja00356a006
PDF
Photoinduced electron-transfer reactions in a chlorophyllide-pheophorbide cyclophane. A model for photosynthetic reaction centers
Robert E. Overfield, Avigdor Scherz, Kenneth J. Kaufmann, and Michael R. Wasielewski
pp 5747 - 5752; DOI:
10.1021/ja00356a007
PDF
Optical absorption, electron spin resonance, and electron spin echo studies of the photoionization of tetramethylbenzidine in cationic and anionic synthetic vesicles: comparison with analogous micellar systems
A. S. W. Li and Larry Kevan
pp 5752 - 5755; DOI:
10.1021/ja00356a008
PDF
Nonradiative relaxation of singlet oxygen in solution
John R. Hurst and Gary B. Schuster
pp 5756 - 5760; DOI:
10.1021/ja00356a009
PDF
Geometry of the imino-carbonyl (N-H...O:C) hydrogen bond. 1. Lone-pair directionality
Robin Taylor, Olga Kennard, and Werner Versichel
pp 5761 - 5766; DOI:
10.1021/ja00356a010
PDF
EXAFS model for the iron-molybdenum cofactor of nitrogenase: molybdenum, tungsten, and iron EXAFS of the [Cl2FeS2MS2FeCl2]2- (M = molybdenum or tungsten) dianions. A comparison with the Mo EXAFS of nitrogenase
Boon K. Teo, Mark R. Antonio, D. Coucouvanis, E. D. Simhon, and P. P. Stremple
pp 5767 - 5770; DOI:
10.1021/ja00356a011
PDF
Ab initio studies of abstraction reactions XHn + hydrogen (H2) .fwdarw. XHn+1 + hydrogen (H) (X = carbon, nitrogen, silicon, or phosphorus)
Mark S. Gordon, David R. Gano, and Jerry A. Boatz
pp 5771 - 5775; DOI:
10.1021/ja00356a012
PDF
Experimental and theoretical investigations of the unimolecular dissociation of nascent ion-molecule clusters: diaquahydrogen(1+) ion (H2O.H3O+), diamminehydrogen(1+) ion (NH3.NH4+), and carbon oxide(1+) ion (CO2.CO2+)
A. J. Illies, M. F. Jarrold, L. M. Bass, and M. T. Bowers
pp 5775 - 5781; DOI:
10.1021/ja00356a013
PDF
Sonochemistry and sonocatalysis of metal carbonyls
Kenneth S. Suslick, James W. Goodale, Paul F. Schubert, and Hau H. Wang
pp 5781 - 5785; DOI:
10.1021/ja00356a014
PDF
Epoxidation reactions catalyzed by iron porphyrins. Oxygen transfer from iodosylbenzene
John T. Groves and Thomas E. Nemo
pp 5786 - 5791; DOI:
10.1021/ja00356a015
PDF
Catalytic asymmetric epoxidations with chiral iron porphyrins
John T. Groves and Richard S. Myers
pp 5791 - 5796; DOI:
10.1021/ja00356a016
PDF
Mechanism and energetics of the ligand-induced reductive elimination of hydrogen from a binuclear platinum hydride
Ross H. Hill and Richard J. Puddephatt
pp 5797 - 5804; DOI:
10.1021/ja00356a017
PDF
Syntheses, properties, and x-ray crystal structures of stable methylidene complexes of the formula [(.eta.-C5Me5)Re(NO)(L)(:CH2)]+ PF6-
Alan T. Patton, Charles E. Strouse, Carolyn B. Knobler, and J. A. Gladysz
pp 5804 - 5811; DOI:
10.1021/ja00356a018
PDF
Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition
James H. Merrifield, Gong Yu Lin, William A. Kiel, and J. A. Gladysz
pp 5811 - 5819; DOI:
10.1021/ja00356a019
PDF
Iodocyclization of allylic alcohol derivatives containing internal nucleophiles. Control of stereoselectivity by substituents in the acyclic precursors
A. Richard Chamberlin, Milana Dezube, Patrick Dussault, and Mark C. McMills
pp 5819 - 5825; DOI:
10.1021/ja00356a020
PDF
Reduction of .DELTA.2-isoxazolines. 3. Raney nickel catalyzed formation of .beta.-hydroxy ketones
Dennis P. Curran
pp 5826 - 5833; DOI:
10.1021/ja00356a021
PDF
Synthesis, crystal and molecular structure, and reactions of a benzodicobaltacyclohexene, a thermally derived mononuclear o-xylylene complex, and an unsymmetrical phosphine-derived dinuclear complex
William H. Hersh, Frederick J. Hollander, and Robert G. Bergman
pp 5834 - 5846; DOI:
10.1021/ja00356a022
PDF
Kinetics and mechanism of decomposition of a benzodicobaltacyclohexene: reversible dinuclear elimination of o-xylylene via a dimetalla-Diels-Alder reaction
William H. Hersh and Robert G. Bergman
pp 5846 - 5859; DOI:
10.1021/ja00356a023
PDF
Accessibility of triplet indenylidene in solution
Robert A. Moss and Claire M. Young
pp 5859 - 5865; DOI:
10.1021/ja00356a024
PDF
X-ray and theoretical analysis of the relationship between substituent steric effects and the structure of bicyclo[1.1.0]butane. The unexpected flexibility of the bicyclo[1.1.0]butane skeleton
Paul G. Gassman, Mark L. Greenlee, David A. Dixon, Steven Richtsmeier, and J. Zanos Gougoutas
pp 5865 - 5874; DOI:
10.1021/ja00356a025
PDF
Annulated pyranosides. 4. Routes to cyclohexano and cyclopentano pyranosides from carbohydrate .alpha.-enones
J. L. Primeau, R. C. Anderson, and Bert Fraser-Reid
pp 5874 - 5879; DOI:
10.1021/ja00356a026
PDF
Oxygen chiral phosphate in uridylyl(3'.fwdarw.5')adenosine by oxidation of a phosphite intermediate: synthesis and absolute configuration
Frank Seela, Johann Ott, and Barry V. L. Potter
pp 5879 - 5886; DOI:
10.1021/ja00356a027
PDF
A mechanistic basis for the stereoselectivity of enzymic transfer of hydrogen from nicotinamide cofactors
Krishnan P. Nambiar, Dora M. Stauffer, Peter A. Kolodziej, and Steven A. Benner
pp 5886 - 5890; DOI:
10.1021/ja00356a028
PDF
A proton nuclear magnetic resonance study of purine and pyrimidine nucleoside 5'-diphosphates. Extent of macrochelate formation in monomeric metal ion complexes and promotion of self-stacking by metal ions
Kurt H. Scheller and Helmut Sigel
pp 5891 - 5900; DOI:
10.1021/ja00356a029
PDF
Oxygen-17 NMR of nucleosides. 2. Hydration and self-association of uridine derivatives
Herbert M. Schwartz, Malcolm MacCoss, and Steven S. Danyluk
pp 5901 - 5911; DOI:
10.1021/ja00356a030
PDF
7-Deoxydaunomycinone, a catalyst for achieving a two electron reduction with a one electron reducing agent
Don L. Kleyer and Tad H. Koch
pp 5911 - 5912; DOI:
10.1021/ja00356a031
PDF
Novel synthesis and reactivity of 4-azahomoadamant-3-ene and 4-aza-4-homobrend-3-enes via intramolecular aza-Wittig reactions
Tadashi Sasaki, Shoji Eguchi, and Takashi Okano
pp 5912 - 5913; DOI:
10.1021/ja00356a032
PDF
Carbon dioxide coordination chemistry. 5. The preparation and structure of the rhodium complex Rh(.eta.1-CO2)(Cl)(diars)2
J. C. Calabrese, T. Herskovitz, and J. B. Kinney
pp 5914 - 5915; DOI:
10.1021/ja00356a033
PDF
Effects of electron correlation on the energies of 2-norbornyl cation structures. Evaluation of the nonclassical stabilization energy
Krishnan Raghavachari, Robert C. Haddon, Paul v. R. Schleyer, and Henry F. Schaefer
pp 5915 - 5917; DOI:
10.1021/ja00356a034
PDF
Theoretical structure of the heptahydrodiborate(1-) (B2H7-) anion
Krishnan Raghavachari, Paul von Rague Schleyer, and Guenther W. Spitznagel
pp 5917 - 5918; DOI:
10.1021/ja00356a035
PDF
Dynamic NMR study of conjugation in tert-butyl thiolformate
Eric A. Noe, Thomas Sanders, Felicia Badelle, and Liselle Douyon
pp 5918 - 5920; DOI:
10.1021/ja00356a036
PDF
Isotopic perturbation of resonance in benzylic cations
David A. Forsyth and Matthew M. MacConnell
pp 5920 - 5921; DOI:
10.1021/ja00356a037
PDF
Metallacumulenes: a diruthenium vinylidene-alkylidene complex from the apparent dimerization of cyclopentadienylbis(triphenylphosphine)(3-methyl-1,2-butadienylidene)ruthenium hexafluorophosphate ([CpRu(C:C:CMe2)(PPh3)2][PF6])
John P. Selegue
pp 5921 - 5923; DOI:
10.1021/ja00356a038
PDF
Insertion of boron into an osmium-carbonyl bond. Preparation and structure of the carbonyl borylidyne (.mu.-H)3(CO)9Os3BCO
Sheldon G. Shore, Deng Yang Jan, Leh Yeh Hsu, Wen Liang Hsu, S. Kennedy, and J. Huffman
pp 5923 - 5924; DOI:
10.1021/ja00356a039
PDF
Hexakis(2,4,6-trimethylbenzenethiolato)dimolybdenum (Mo2(SC6H2Me3)6). The first example of a compound containing a molybdenum-molybdenum triple bond supported by six mercaptido ligands
Malcolm H. Chisholm, James F. Corning, and John C. Huffman
pp 5924 - 5925; DOI:
10.1021/ja00356a040
PDF
Stereochemical control of yeast reductions. 1. Asymmetric synthesis of L-carnitine
Bing Nan Zhou, Aravamudan S. Gopalan, Frank VanMiddlesworth, Woan Ru Shieh, and Charles J. Sih
pp 5925 - 5926; DOI:
10.1021/ja00356a041
PDF
Formation of a stable (.eta.2-C,C) ketene compound dicarbonyl(cyclopentadienyl)keteneiron hexafluorophosphate [(C5H5)Fe(CO)2(CH2CO)+ PF6-] by carbonylation of an iron-methylidene complex. A novel entry into carbonyl-derived C2 chemistry
T. W. Bodnar and A. R. Cutler
pp 5926 - 5928; DOI:
10.1021/ja00356a042
PDF
Measurement of the rotational barrier of a tetraalkylhydrazine radical cation
Stephen F. Nelsen, Glen T. Cunkle, Dennis H. Evans, and Timothy Clark
pp 5928 - 5929; DOI:
10.1021/ja00356a043
PDF
Structure of an electronically stabilized carbonyl ylide
Eugene P. Janulis and Anthony J. Arduengo
pp 5929 - 5930; DOI:
10.1021/ja00356a044
PDF
Effectively hypervalent molecules. 2. Lithium carbide (CLi5), lithium carbide (CLi6), and the related effectively hypervalent first row molecules, CLi5-nHn and CLi6-nHn
Paul v. R. Schleyer, Ernst Ulrich Wuerthwein, Elmar Kaufmann, Timothy Clark, and John A. Pople
pp 5930 - 5932; DOI:
10.1021/ja00356a045
PDF
Addition of singlet oxygen to conjugated dienes. The mechanism of endoperoxide formation
Edward L. Clennan and M. E. Mehrsheikh-Mohammadi
pp 5932 - 5933; DOI:
10.1021/ja00356a046
PDF
Relative importance of metal-metal bond scission and loss of carbon monoxide from photoexcited dimanganese decacarbonyl: spectroscopic detection of a coordinatively unsaturated, carbonyl-bridged dinuclear species in low-temperature alkane matrices
Aloysius F. Hepp and Mark S. Wrighton
pp 5934 - 5935; DOI:
10.1021/ja00356a047
PDF
Enantioselective carbocyclization: a facile route to chiral cyclopentanes
Douglass F. Taber and Krishna Raman
pp 5935 - 5937; DOI:
10.1021/ja00356a048
PDF
Homogeneous catalysts for carbon dioxide/hydrogen activation. Alkyl formate production using anionic ruthenium carbonyl clusters as catalysts
Donald J. Darensbourg, Cesar Ovalles, and Magdalena Pala
pp 5937 - 5939; DOI:
10.1021/ja00356a049
PDF
A mononuclear, low-valent, electron-rich osmium methylene complex
Anthony F. Hill, Warren R. Roper, Joyce M. Waters, and Anthony H. Wright
pp 5939 - 5940; DOI:
10.1021/ja00356a050
PDF
Macrolide formation via an isomerization reaction. An unusual dependence on nucleophile
Barry M. Trost and Robert W. Warner
pp 5940 - 5942; DOI:
10.1021/ja00356a051
PDF
.alpha.-Elimination of .alpha.-acetoxysilanes induced by palladium: evidence for the intermediacy of a vinylcarbene-palladium complex
Barry M. Trost and Christopher R. Self
pp 5942 - 5944; DOI:
10.1021/ja00356a052
PDF
Syntheses and structures of the tetrakis(benzenethiolato)ferrate(1-) ([FeIII(SPh)4]-) and tetrakis(ethanethiolato)ferrate(1-) ([FeIII(SEt)4]-) anions. A general route to iron(III) tetrathiolate complexes
Stephen A. Koch, Lynn E. Maelia, and Michelle Millar
pp 5944 - 5945; DOI:
10.1021/ja00356a053
PDF
Application for proton NMR spectral editing techniques for selective observation of nitrogen-hydrogen (N-H) protons in an actinomycin D complex with a tetranucleotide duplex
David G. Reid, David M. Doddrell, Keith R. Fox, Stephen A. Salisbury, and Dudley H. Williams
pp 5945 - 5946; DOI:
10.1021/ja00356a054
PDF
Stereochemical control in the addition of isothiocyanatoacetate esters to boron trifluoride activated 3-thiazolines. A novel synthesis of d-biotin
Robert A. Volkmann, Jeffery T. Davis, and Clifford N. Meltz
pp 5946 - 5948; DOI:
10.1021/ja00356a055
PDF
Hydrogen bond length and proton NMR chemical shifts in proteins
Gerhard Wagner, Arthur Pardi, and Kurt Wuethrich
pp 5948 - 5949; DOI:
10.1021/ja00356a056
PDF
Antioxidant activity of phenols related to vitamin E. Are there chain-breaking antioxidants better than .alpha.-tocopherol?
Graham W. Burton, Lise Hughes, and Keith U. Ingold
pp 5950 - 5951; DOI:
10.1021/ja00356a057
PDF
Organometallic electron reservoirs. 10. Dramatic salt effect on the basic and nucleophilic properties of the superoxide radical anion generated from oxygen (O2) and iron(I) electron-reservoir complexes
Jean Rene Hamon and Didier Astruc
pp 5951 - 5952; DOI:
10.1021/ja00356a058
PDF
Multiple-state emission and intramolecular electron-transfer quenching in rhenium(I) bipyridine based chromophore-quencher complexes
T. David Westmoreland, Hubert Le Bozec, Royce W. Murray, and Thomas J. Meyer
pp 5952 - 5954; DOI:
10.1021/ja00356a059
PDF
Alkyl, hydride, and dinitrogen 1,2-bis(dimethylphosphino)ethane complexes of chromium. Crystal structures of Me2Cr(dmpe)2, CrH4(dmpe)2, and Cr(N2)2(dmpe)2
Gregory S. Girolami, Julian E. Salt, Geoffrey Wilkinson, Mark Thornton-Pett, and Michael B. Hursthouse
pp 5954 - 5956; DOI:
10.1021/ja00356a060
PDF
18[Hexa(2,6)pyridinocoronand-6]: "Sexipyridine"
George R. Newkome and H. W. Lee
pp 5956 - 5957; DOI:
10.1021/ja00356a061
PDF
Reaction of Au(NO3)PPh3 with cationic polyhydride cluster complexes of iridium(III). Structures of [AuIr3H6(NO3)(dppe)3]BF4 and [Au3Ir(NO3)(PPh3)5]PF6
A. L. Casalnuovo, L. H. Pignolet, J. W. A. Van der Velden, J. J. Bour, and J. J. Steggerda
pp 5957 - 5958; DOI:
10.1021/ja00356a062
PDF
Synthesis and transilience of a 1,3-diazabiphenylene
Marc d'Alarcao and Nelson J. Leonard
pp 5958 - 5960; DOI:
10.1021/ja00356a063
PDF
1-Phenylphosphonin oxide as an unstable valence tautomer of 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene 9-oxide
Nandakumar S. Rao and Louis D. Quin
pp 5960 - 5961; DOI:
10.1021/ja00356a064
PDF
Doubly destabilized carbocations. Unexpectedly high reactivity in formation of carbocation intermediates with two destabilizing substituents
Annette D. Allen, V. M. Kanagasabapathy, and Thomas T. Tidwell
pp 5961 - 5962; DOI:
10.1021/ja00356a065
PDF
Book Reviewa

pp 5962 - 5966; DOI:
10.1021/ja00356a600
PDF

Issue 19


Spontaneous oscillation of pH and electrical potential in an oil-water system
K. Yoshikawa and Y. Matsubara
pp 5967 - 5969; DOI:
10.1021/ja00357a001
PDF
Matrix isolation studies of nucleic acid constituents. 1. Infrared spectra of uracil monomers
M. Szczesniak, M. J. Nowak, H. Rostkowska, K. Szczepaniak, W. B. Person, and D. Shugar
pp 5969 - 5976; DOI:
10.1021/ja00357a002
PDF
Ionized oxycarbenes: hydroxymethylidyne cation ([COH]+), hydroxymethylene cation ([HCOH]+.bul.), dihydroxymethylene cation ([C(OH)2]+.bul.), formoxylium cation ([HCO2]+) and carboxyl cation ([COOH]+), their generation, identification, heat of formation, and dissociation characteristics
Peter C. Burgers, Alexander A. Mommers, and J. L. Holmes
pp 5976 - 5979; DOI:
10.1021/ja00357a003
PDF
Electronic origins and consequences of pyramidalization of asymmetric alkenes in ground and triplet excited states
K. N. Houk, Nelson G. Rondan, Frank K. Brown, William L. Jorgensen, Jeffry D. Madura, and David C. Spellmeyer
pp 5980 - 5988; DOI:
10.1021/ja00357a004
PDF
Intramolecular excimer emission of poly(N-vinylcarbazole) and rac- and meso-2,4-di-N-carbazolylpentane. Model substances for its syndiotactic and isotactic dyads
F. Evers, K. Kobs, R. Memming, and D. R. Terrell
pp 5988 - 5995; DOI:
10.1021/ja00357a005
PDF
Structural and conformational study of repanduline using long-range nuclear Overhauser effect difference spectroscopy
David Neuhaus, Richard N. Sheppard, and I. Ralph C. Bick
pp 5996 - 6002; DOI:
10.1021/ja00357a006
PDF
Electrode kinetics of the hexacyanoferrate(4-/3-) ion (Fe(CN)64-/3-) and pentacyanoferrate(3-/2-) ion (Fe(CN)53-/2-) complexes confined to polymer film on graphite surfaces
Noboru Oyama, Takeo Ohsaka, Michito Kaneko, Keiichi Sato, and Hiroaki Matsuda
pp 6003 - 6008; DOI:
10.1021/ja00357a007
PDF
Preparation and crystal and molecular structure of tetrasulfur tetranitride-tetrafluoroboric acid salt (S4N4H+BF4-). Molecular orbital study of the protonation of tetrasulfur tetranitride
A. W. Cordes, C. G. Marcellus, M. C. Noble, R. T. Oakley, and W. T. Pennington
pp 6008 - 6012; DOI:
10.1021/ja00357a008
PDF
Synthesis, structure, and reactivity of monomeric two-coordinate copper(I) complexes
Thomas N. Sorrell and Donald L. Jameson
pp 6013 - 6018; DOI:
10.1021/ja00357a009
PDF
Mechanisms of the photoreactions of Cp2Fe2(CO)4 with phosphines and chlorocarbons
David R. Tyler, Maryke A. Schmidt, and Harry B. Gray
pp 6018 - 6021; DOI:
10.1021/ja00357a010
PDF
Effects of phenoxide ligation on iron-sulfur clusters. Preparation and properties of [Fe4S4(OAr)4]2- ions and the structure of bis(tetraethylammonium) tetrakis(phenolatosulfidoferrate) ([(C2H5)4N]2[Fe4S4(OC6H5)4])
W. E. Cleland, D. A. Holtman, M. Sabat, James A. Ibers, G. C. DeFotis, and B. A. Averill
pp 6021 - 6031; DOI:
10.1021/ja00357a011
PDF
Mechanism of the low-energy photochemical disproportionation reactions of bis(.eta.5-cyclopentadienyl)dimolybdenum hexacarbonyl [(.eta.5-C5H5)2Mo2(CO)6]
Albert E. Stiegman, Marc Stieglitz, and David R. Tyler
pp 6032 - 6037; DOI:
10.1021/ja00357a012
PDF
Mechanistic photochemistry of transition-metal .beta.-diketonate complexes. 4. A photochemical investigation of trans-tris(1,1,1-trifluoro-2,4-pentanedionato)rhodium(III) in the gas phase
Xiucen Yang and Charles Kutal
pp 6038 - 6041; DOI:
10.1021/ja00357a013
PDF
Sonochemistry of dimanganese decacarbonyl (Mn2(CO)10) and dirhenium decacarbonyl (Re2(CO)10)
Kenneth S. Suslick and Paul F. Schubert
pp 6042 - 6044; DOI:
10.1021/ja00357a014
PDF
Stereochemistry of metallacycle formation in the double alkylation of bis(triphenylphosphine)nitrogen(1+) bis(.eta.5-cyclopentadienyl)-di-.mu.-carbonyldicobaltate with .alpha.,.gamma.-diiodoalkanes
Gilbert K. Yang and Robert G. Bergman
pp 6045 - 6052; DOI:
10.1021/ja00357a015
PDF
The reactions of ethoxy radicals with optically active tertiary phosphines. Stereochemistry of the substitution process and the question of permutation modes for the possible phosphoranyl radical intermediates
Wesley G. Bentrude, Masaru Moriyama, Hans Dieter Mueller, and Alan E. Sopchik
pp 6053 - 6061; DOI:
10.1021/ja00357a016
PDF
Sulfate group transfer between nitrogen and oxygen: evidence consistent with an open "exploded" transition state
Andrew Hopkins, Richard A. Day, and Andrew Williams
pp 6062 - 6070; DOI:
10.1021/ja00357a017
PDF
Phase separation and reactivity changes of phenyl ester substrate and imidazole catalyst in the dialkylammonium bilayer membrane
Toyoki Kunitake, Hirotaka Ihara, and Yoshio Okahata
pp 6070 - 6078; DOI:
10.1021/ja00357a018
PDF
An azocine anion radical and heats of formation of azocine dianions
Gerald R. Stevenson, Laurel E. Schock, Richard C. Reiter, and John F. Hansen
pp 6078 - 6082; DOI:
10.1021/ja00357a019
PDF
Azide-water competition in solvolysis reactions. A revisit of the reactivity-selectivity relationship
Rachel Ta-Shma and Zvi Rappoport
pp 6082 - 6095; DOI:
10.1021/ja00357a020
PDF
Chemistry of 8-substituted 1-naphthylmethylenes and 2-substituted benzylidenes. A simple entry to 1H-cyclobuta[de]naphthalenes
R. J. Bailey, P. Card, and H. Shechter
pp 6096 - 6103; DOI:
10.1021/ja00357a021
PDF
Synthesis and chemistry of 1H-cyclobuta[de]naphthalenes, 1-alkylidene-1H-cyclobuta[de]naphthalenes, and 1H-cyclobuta[de]naphthalen-1-one
P. J. Card, F. E. Friedli, and H. Shechter
pp 6104 - 6114; DOI:
10.1021/ja00357a022
PDF
Anti and syn eliminations from 2,3-dihalo-2,3-dihydrobenzofurans. The role of the substrate structure and the base-solvent system on the reaction mechanism
Enrico Baciocchi, Renzo Ruzziconi, and Giovanni V. Sebastiani
pp 6114 - 6120; DOI:
10.1021/ja00357a023
PDF
Absolute rate constants for reactions of cumyloxy in solution
A. Baignee, J. A. Howard, J. C. Scaiano, and L. C. Stewart
pp 6120 - 6123; DOI:
10.1021/ja00357a024
PDF
Electronic absorption and circular dichroism spectra of the perturbed coplanar cis-diene chromophore in deuterium- and methyl-substituted 7,7-dimethylbicyclo[4.1.1]octa-2,4-dienes
Alan R. Browne, Francis R. Kearney, Stephen F. Mason, Leo A. Paquette, and Alex F. Drake
pp 6123 - 6129; DOI:
10.1021/ja00357a025
PDF
Mechanisms of the palladium-catalyzed couplings of acid chlorides with organotin reagents
Jeff W. Labadie and J. K. Stille
pp 6129 - 6137; DOI:
10.1021/ja00357a026
PDF
Orientation effects on the rate and equilibrium constants for formation and decomposition of tetrahedral intermediates
Linda J. Santry and Robert A. McClelland
pp 6138 - 6141; DOI:
10.1021/ja00357a027
PDF
Reluctant azoalkanes: the photochemical behavior of acyclic, bridgehead-centered azoalkanes on 185- and 350-nm irradiation
Waldemar Adam, Francois Mazenod, Yoshinori Nishizawa, Paul S. Engel, Sharon A. Baughman, Woo-Ki Chae, Douglas W. Horsey, Helmut Quast, and Bernhard Seiferling
pp 6141 - 6145; DOI:
10.1021/ja00357a028
PDF
Template effects. 5. Model system for the template effect of alkali and alkaline-earth metal ions on the formation of benzo-18-crown-6 in methanol solution
Gianfranco Ercolani, Luigi Mandolini, and Bernardo Masci
pp 6146 - 6149; DOI:
10.1021/ja00357a029
PDF
Polyvalent porphyrins. 1. Properties of tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin (1-P) and its iron(III) and zinc(II) derivatives
T. G. Traylor, Kevin B. Nolan, and Robert Hildreth
pp 6149 - 6151; DOI:
10.1021/ja00357a030
PDF
Thioxyallyl ion from allene episulfide with acid
Wataru Ando, Yukio Hanyu, Toshiyata Furuhata, and Toshikazu Takata
pp 6151 - 6152; DOI:
10.1021/ja00357a031
PDF
Electron-transfer catalysis by surfactant vesicle stabilized colloidal platinum
Kazue Kurihara and Janos H. Fendler
pp 6152 - 6153; DOI:
10.1021/ja00357a032
PDF
Chiral leaving group. Biogenetic-type asymmetric synthesis of limonene and bisabolenes
Soichi Sakane, Junya Fujiwara, Keiji Maruoka, and Hisashi Yamamoto
pp 6154 - 6155; DOI:
10.1021/ja00357a033
PDF
In situ trapping of ortho lithiated benzenes containing electrophilic directing groups
Timothy D. Krizan and J. C. Martin
pp 6155 - 6157; DOI:
10.1021/ja00357a034
PDF
Synthesis and chemistry of chiral vinylrhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(CH:CHR'). Stereoselective reactions with electrophiles and a spontaneous alkylidene to olefin rearrangement
William G. Hatton and J. A. Gladysz
pp 6157 - 6158; DOI:
10.1021/ja00357a035
PDF
Observation of 2-azabicyclo[3.2.1]oct-1-ene, highly reactive bridgehead imine
Robert S. Sheridan and George A. Ganzer
pp 6158 - 6160; DOI:
10.1021/ja00357a036
PDF
Sequential electron-transfer-desilylation pathways for C-vinylazomethine ylide formation in the photochemistry of [1-(triethylsilyl)allyl]iminium salts
Shyh Fong Chen, John W. Ullrich, and Patrick S. Mariano
pp 6160 - 6162; DOI:
10.1021/ja00357a037
PDF
Reactions of M-M triple bonds with carbon-nitrogen triple bonds: adduct formation (M = molybdenum) and metathesis (M = tungsten) as seen in the reactions between dimethylcyanamide and hexaalkoxides of dimolybdenum and ditungsten
Malcolm H. Chisholm, John C. Huffman, and Nancy L. Marchant
pp 6162 - 6163; DOI:
10.1021/ja00357a038
PDF
A bimetallic vanadium(I) polyhydride
Rick L. Bansemer, John C. Huffman, and Kenneth G. Caulton
pp 6163 - 6164; DOI:
10.1021/ja00357a039
PDF
Organosulfur compounds in organic synthesis. 1. Bromomethanesulfonyl bromide in organic synthesis. Formation and base-induced reactions of .alpha.,.beta.-unsaturated halomethyl sulfones
Eric Block and Mohammad Aslam
pp 6164 - 6165; DOI:
10.1021/ja00357a040
PDF
Bromomethanesulfonyl bromide in organic synthesis. A useful new 1,3-diene synthesis
Eric Block, Mohammad Aslam, Venkatachalam Eswarakrishnan, and Alan Wall
pp 6165 - 6167; DOI:
10.1021/ja00357a041
PDF
Charge-transfer excitation of electron donor-acceptor complexes. Direct observation of ion pairs by time-resolved (picosecond) spectroscopy
E. F. Hilinski, J. M. Masnovi, C. Amatore, J. K. Kochi, and P. M. Rentzepis
pp 6167 - 6168; DOI:
10.1021/ja00357a042
PDF
NMR studies of ruthenium(II) porphyrin .pi.-cation radicals with relevance to horseradish peroxidase compound I
Isao Morishima, Yoshitsugu Shiro, and Yasuhiko Takamuki
pp 6168 - 6170; DOI:
10.1021/ja00357a043
PDF
(Benzene)vanadium, (C6H6)V: a half-sandwich with an .eta.6-benzene ligand
Mark P. Andrews, Helmut X. Huber, Saba M. Mattar, Douglas F. McIntosh, and Geoffrey A. Ozin
pp 6170 - 6172; DOI:
10.1021/ja00357a044
PDF
Direct heterolysis of a very weak carbon-carbon bond to a carbocation and carbanion
Edward M. Arnett, E. B. Troughton, Andrew T. McPhail, and Kent E. Molter
pp 6172 - 6173; DOI:
10.1021/ja00357a045
PDF
Electronic ground state of iron(II) phthalocyanine as determined from accurate diffraction data
Philip Coppens, Liang Li, and Nai Jui Zhu
pp 6173 - 6174; DOI:
10.1021/ja00357a046
PDF
Hydrogen bonding in optically active and racemic 2-butanol
William C. Herndon and Steven P. Vincenti
pp 6174 - 6175; DOI:
10.1021/ja00357a047
PDF
On the proposed thermal interconversion of matrix-isolated dimethylsilylene and 1-methylsilene: their reactions with oxygen atom donors
Charles A. Arrington, Robert West, and Josef Michl
pp 6176 - 6177; DOI:
10.1021/ja00357a048
PDF
Halenaquinone, a pentacyclic polyketide from a marine sponge
Deborah M. Roll, Paul J. Scheuer, Gayle K. Matsumoto, and Jon Clardy
pp 6177 - 6178; DOI:
10.1021/ja00357a049
PDF
Biosynthesis of polyprenols in higher plants. The elimination of the pro-4S hydrogen atom of mevalonic acid during the formation of their (Z)-isoprene chain
Takayuki Suga, Toshifumi Hirata, Tadashi Aoki, and Tsuyoshi Shishibori
pp 6178 - 6179; DOI:
10.1021/ja00357a050
PDF
The synthesis and structure of tetrasodium tetramethoxyoctamolybdate-methanol complex (Na4[Mo8O24(OCH3)4].8MeOH): a novel isopolymolybdate that decomposes with the loss of formaldehyde
E. M. McCarron and R. L. Harlow
pp 6179 - 6181; DOI:
10.1021/ja00357a051
PDF
Detection by carbon-13 CPMAS NMR of molecules photochemically generated in organic glasses at low temperature
C. S. Yannoni, H. P. Reisenauer, and G. Maier
pp 6181 - 6182; DOI:
10.1021/ja00357a052
PDF
Coordination and scission of alkynes on a tungsten-triosmium framework
Joon T. Park, John R. Shapley, Melvyn Rowen Churchill, and Clifford Bueno
pp 6182 - 6184; DOI:
10.1021/ja00357a053
PDF
Synthesis and x-ray crystal structure of Mo2(.mu.-t-Bu2P)2(t-Bu2P)2(Mo-Mo); the first structurally characterized binary transition-metal phosphide
Richard A. Jones, Jon G. Lasch, Nicholas C. Norman, Bruce R. Whittlesey, and Thomas C. Wright
pp 6184 - 6185; DOI:
10.1021/ja00357a054
PDF
Electron correlation and basis set effects on the relative stabilities of classical and nonclassical structures of the 2-norbornyl cation
M. Yoshimine, A. D. McLean, B. Liu, D. J. DeFrees, and J. S. Binkley
pp 6185 - 6186; DOI:
10.1021/ja00357a055
PDF
Transition metal heterocyclic chemistry. 7. Stabilization of an .alpha.-diazo thioketone (a new class of compound) by a unique linear triiron cluster
Keith H. Pannell, Armin J. Mayr, and Don VanDerveer
pp 6186 - 6188; DOI:
10.1021/ja00357a056
PDF
Methyl effects on the basicities of cyclopentadienide and indenide ions and on the chemistry of their transition metal complexes
Frederick G. Bordwell and Mark J. Bausch
pp 6188 - 6189; DOI:
10.1021/ja00357a057
PDF
Long-range proton-nitrogen spin coupling constants via polarization-enhanced two-dimensional nitrogen-15 NMR
Donald G. Davis, William C. Agosta, and David Cowburn
pp 6189 - 6190; DOI:
10.1021/ja00357a058
PDF
Vibrational circular dichroism in (S)-(-)-epoxypropane. Measurement in vapor phase and verification of the perturbed degenerate mode theory
P. L. Polavarapu and D. F. Michalska
pp 6190 - 6191; DOI:
10.1021/ja00357a059
PDF
Fluorine-19 MAS-NMR of fluoridated hydroxyapatite surfaces
James P. Yesinowski and Michael J. Mobley
pp 6191 - 6193; DOI:
10.1021/ja00357a060
PDF
Thioether trans-crosslinking reaction of phalloidin
Theodor Wieland, Michael Nassal, Tamiko Miura, and Christa Goetzendoerfer
pp 6193 - 6195; DOI:
10.1021/ja00357a061
PDF
Additions and Corrections - Elimination Reactions of N-(2-p-Nitrophenyl)ethyl) alkyl-ammonium Ions by an E1cB Mechanism
James R. Keefe, and William P. Jencks
pp 6195 - 6195; DOI:
10.1021/ja00357a601
PDF
Additions and Corrections - Boronic Ester Homologation with 99% Chiral Selectivity and Its Use in Syntheses of the Insect Pheromones (3S, 4S)-4-Methyl-3-heptanol and exo-Brevicomin
Donald S. Matteson, and Kizhakethil M. Sadhu
pp 6195 - 6195; DOI:
10.1021/ja00357a602
PDF
Additions and Corrections - Double Isotope Fractionation: Test for Concertedness and for Transition State Dominance.
Joel G. Belasco, W. John Albery, and Jeremy R. Knowles
pp 6195 - 6195; DOI:
10.1021/ja00357a603
PDF
Additions and Corrections - Detection of Free Radicals from Low-Temperature Ozone-Olefin Reactions by ESR Spin Trapping: Evidence That the Radical Precursor Is a Trioxide
William A. Pryor, Donald G. Prier, and Daniel F. Church
pp 6195 - 6195; DOI:
10.1021/ja00357a604
PDF
Book Reviews

pp 6195 - 6200; DOI:
10.1021/ja00357a600
PDF

Issue 20


Solvent-induced deactivation of singlet oxygen: additivity relationships in nonaromatic solvents
Michael A. J. Rodgers
pp 6201 - 6205; DOI:
10.1021/ja00358a001
PDF
Photoprocesses in diphenylpolyenes. 2. Excited-state interactions with stable free radicals
S. K. Chattopadhyay, P. K. Das, and G. L. Hug
pp 6205 - 6210; DOI:
10.1021/ja00358a002
PDF
Excited singlet states of "hairpin" polyenes
Wolfgang Froelich, Harry J. Dewey, Hans Deger, Bernhard Dick, Kenneth A. Klingensmith, Wilhelm Puettmann, Emanuel Vogel, Georg Hohlneicher, and Josef Michl
pp 6211 - 6220; DOI:
10.1021/ja00358a003
PDF
Evaluation and perturbation of micelle-solute interactions
Daniel W. Armstrong and Gail Y. Stine
pp 6220 - 6223; DOI:
10.1021/ja00358a004
PDF
Solvent and pH dependence of absorption and fluorescence spectra of 5-aminoindazole: biprotonic phototautomerism of singly protonated species
M. Swaminathan and S. K. Dogra
pp 6223 - 6228; DOI:
10.1021/ja00358a005
PDF
Photoinduced hydrogen evolution by a zwitterionic diquat electron acceptor. The functions of silicon dioxide colloid in controlling the electron-transfer process
Yinon Degani and Itamar Willner
pp 6228 - 6233; DOI:
10.1021/ja00358a006
PDF
Photofragmentation of acrylic acid and methacrylic acid in the gas phase
Robert N. Rosenfeld and Brad R. Weiner
pp 6233 - 6236; DOI:
10.1021/ja00358a007
PDF
Intramolecular donor-acceptor systems. 10. Multiple fluorescences from 8-(N-phenylamino)-1-naphthalenesulfonates
Edward M. Kosower and Hannah Kanety
pp 6236 - 6243; DOI:
10.1021/ja00358a008
PDF
Aliphatic hydroxylation catalyzed by iron porphyrin complexes
John T. Groves and Thomas E. Nemo
pp 6243 - 6248; DOI:
10.1021/ja00358a009
PDF
Laser photolysis study of the photosubstitution in dimanganese decacarbonyl
Hiroshi Yesaka, Takayoshi Kobayashi, Katsutoshi Yasufuku, and Saburo Nagakura
pp 6249 - 6252; DOI:
10.1021/ja00358a010
PDF
Highly reduced organometallics. 15. Coordinatively unsaturated tetranuclear hydrido carbonyl clusters of molybdenum and tungsten. Structural characterization of tetrakis(tetrapropylammonium) tetrakis(tricarbonylhydromolybdate) ([(n-C3H7)4N]4[HMo(CO)3]4)
Jiann T'suen Lin and John E. Ellis
pp 6252 - 6258; DOI:
10.1021/ja00358a011
PDF
A very long cobalt to nitrogen bond in a coenzyme B12 model. Relevance to the role of the 5,6-dimethylbenzimidazole in cobalt-carbon bond cleavage in coenzyme B12
Michael F. Summers, Paul J. Toscano, Nevenka Bresciani-Pahor, Giorgio Nardin, Lucio Randaccio, and Luigi G. Marzilli
pp 6259 - 6263; DOI:
10.1021/ja00358a012
PDF
Improved synthesis of racemic chorismic acid. Claisen rearrangement of 4-epi-chorismic acid and dimethyl 4-epi-chorismate
John H. Hoare, Peter P. Policastro, and Glenn A. Berchtold
pp 6264 - 6267; DOI:
10.1021/ja00358a013
PDF
On the photochemical synthesis of N,N'-dimethylindolo[2,3-c]carbazole and the mechanism of its formation from N,N'-dimethyl-N,N'-diphenyl-1,4-phenylenediamine
Horst Weller and Karl Heinz Grellmann
pp 6268 - 6273; DOI:
10.1021/ja00358a014
PDF
Reactions of dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III) with alkynes. Formation of tris(triisopropylphosphine)(diphenylacetylene)carbonatodihydrodirhodium [Rh2H2(OCO2)(PhC.tplbond.CPh)[P(CHMe2)3]3] and the stereoselective hydrogenation of alkynes to trans olefins
T. Yoshida, Wiley J. Youngs, T. Sakaeda, T. Ueda, S. Otsuka, and James A. Ibers
pp 6273 - 6278; DOI:
10.1021/ja00358a015
PDF
Synthesis and decomposition of E- and Z-3,3,5-trisubstituted 1,2-dioxolanes
Masaya Yoshida, Masahiro Miura, Masatomo Nojima, and Shigekazu Kusabayashi
pp 6279 - 6285; DOI:
10.1021/ja00358a016
PDF
Organoboranes. 32. Homologation of alkylboronic esters with methoxy(phenylthio)methyllithium: regio- and stereocontrolled aldehyde synthesis from olefins via hydroboration
Herbert C. Brown and Toshiro Imai
pp 6285 - 6289; DOI:
10.1021/ja00358a017
PDF
Carbanions. 23. Cleavages of 1,2-diphenylethane and derivatives by cesium-potassium-sodium alloy. Competitive rates of bond scission
Erling Grovenstein, Amjad M. Bhatti, Dean E. Quest, Dibyendu Sengupta, and Don VanDerveer
pp 6290 - 6299; DOI:
10.1021/ja00358a018
PDF
Structural effects in solvolytic reactions. 45. Carbon-13 NMR studies of carbocations. 9. Variation of the cationic carbon chemical shifts with increasing electron demand in 1,1-diaryl-1-ethyl carbocations. Importance of the inductive localized .pi.-polarization effect in causing deviations from linearity
Herbert C. Brown, Mariappan Periasamy, P. Thirumalai Perumal, David P. Kelly, and Joseph J. Giansiracusa
pp 6300 - 6305; DOI:
10.1021/ja00358a019
PDF
Solid- and solvated-state conformation of the free tetrapeptide glycyl-L-prolyl-D-leucylglycine by x-ray and proton nuclear magnetic resonance spectroscopy
Thierry Prange, Constantin Sakarellos, Flavio Toma, Clauding Pascard, and Serge Fermandjian
pp 6306 - 6309; DOI:
10.1021/ja00358a020
PDF
Cyclopropabenzynes: generation and trapping
Brian Halton and Clifford J. Randall
pp 6310 - 6311; DOI:
10.1021/ja00358a021
PDF
Structure of carzinophilin. 3. Structure elucidation by nuclear magnetic resonance spectroscopy. 1
Masayuki Onda, Yaeko Konda, Akiko Hatano, Toju Hata, and Satoshi Omura
pp 6311 - 6312; DOI:
10.1021/ja00358a022
PDF
Carbon-carbon bond formation by selective coupling of enol silyl ethers with oxime sulfonates
Yasushi Matsumura, Junya Fujiwara, Keiji Maruoka, and Hisashi Yamamoto
pp 6312 - 6314; DOI:
10.1021/ja00358a023
PDF
A novel (.eta.5-cyclohexadienyl)tricarbonylchromium anion: the reaction between the dianion of (.eta.6-naphthalene)tricarbonylchromium and a proton source
William P. Henry and Reuben D. Rieke
pp 6314 - 6316; DOI:
10.1021/ja00358a024
PDF
Extraordinary photorearrangement of silylfurans and subsequent thermal rearrangements
Thomas J. Barton and Greg Hussmann
pp 6316 - 6318; DOI:
10.1021/ja00358a025
PDF
Supported palladium catalysts for the reduction of sodium bicarbonate to sodium formate in aqueous solution at room temperature and one atmosphere of hydrogen
Charles J. Stalder, Shuchi Chao, David P. Summers, and Mark S. Wrighton
pp 6318 - 6320; DOI:
10.1021/ja00358a026
PDF
Gas-phase reactions of Group VIII metal hydride ions (FeD+, CoD+, and NiD+) with hydrocarbons
T. J. Carlin, L. Sallans, C. J. Cassady, D. B. Jacobson, and B. S. Freiser
pp 6320 - 6321; DOI:
10.1021/ja00358a027
PDF
Synthesis and structures of the vanadium sulfide cluster compounds (iso-PrC5H4)2V2S4 and (C5H5)2V2S2[S2C2(CF3)2]: the influence of .pi.-bonding on the geometry of the .mu.-disulfido ligand
C. Mark Bolinger, Thomas B. Rauchfuss, and Arnold L. Rheingold
pp 6321 - 6323; DOI:
10.1021/ja00358a028
PDF
ESR study of cation-crown ether induced dimerization of a water-soluble porphyrin
T. K. Chandrashekar and Hans Van Willigen
pp 6323 - 6324; DOI:
10.1021/ja00358a029
PDF
Structure and stereochemistry of tetrahedral inhibitor complexes of papain by direct NMR observation
Michael P. Gamcsik, J. Paul G. Malthouse, William U. Primrose, Neil E. Mackenzie, Alan S. F. Boyd, Richard A. Russell, and A. Ian Scott
pp 6324 - 6325; DOI:
10.1021/ja00358a030
PDF
Photoreduction of thioindigo: photoinitiated two-electron transfer within a substrate-quencher pair
Kirk S. Schanze, Charles Giannotti, and David G. Whitten
pp 6326 - 6327; DOI:
10.1021/ja00358a031
PDF
Two novel examples of hydroxylation of aromatic rings in coordination chemistry
Pinaki Bandyopadhyay, Debkumar Bandyopadhyay, Animesh Chakravorty, F. Albert Cotton, Larry R. Falvello, and Scott Han
pp 6327 - 6329; DOI:
10.1021/ja00358a032
PDF
Mechanism of an oscillating organic reaction: oxidation of benzaldehyde with oxygen catalyzed by cobalt/bromine
Mark G. Roelofs, E. Wasserman, James H. Jensen, and Allan E. Nader
pp 6329 - 6330; DOI:
10.1021/ja00358a033
PDF
Syntheses and structures of a novel series of tetrathiolene clusters: (.eta.5-C5H5)2Fe2(C10Cl4S4)(C10Cl4S3), (.eta.5-C5H5)2Co2(C10Cl4S4), and (.eta.5-C5H5)2Ni2(C10Cl4S4)
Boon K. Teo, V. Bakirtzis, and P. A. Snyder-Robinson
pp 6330 - 6332; DOI:
10.1021/ja00358a034
PDF
Phosphine ligands for the construction of polynuclear complexes. 2. 2,6-Bis(diphenylphosphino)pyridine complexes of palladium(II) and rhodium(I)
Fred Wood, Marilyn M. Olmstead, and Alan L. Balch
pp 6332 - 6334; DOI:
10.1021/ja00358a035
PDF
Reactions of coordinated dinitrogen. 13. A bis(dinitrogen) complex of molybdenum: a chemical resemblance to nitrogenase?
T. Adrian George and Lenore M. Koczon
pp 6334 - 6335; DOI:
10.1021/ja00358a036
PDF
Preparation and Diels-Alder reactions of 1,3-dienes containing both sulfur and nitrogen substituents. Complete orientational control by the acylamino group
Larry E. Overman, Charles B. Petty, Takashi Ban, and Glenn T. Huang
pp 6335 - 6337; DOI:
10.1021/ja00358a037
PDF
Stereochemical course of thermal cycloreversion of [3.2.1]propellanes to 1,3-dialkenylcyclohexanes
Michael A. Blaustein and Jerome A. Berson
pp 6337 - 6338; DOI:
10.1021/ja00358a038
PDF
Chalcogenides as ligands of complexes. 3. Synthesis and structure of [PPN]2[(.mu.2-CO)3(CO)9Cr3(.mu.4-S)Cr(CO)5], a chromium cluster
M. Hoefler, K. F. Tebbe, H. Veit, and N. E. Weiler
pp 6338 - 6339; DOI:
10.1021/ja00358a039
PDF
Effective route to azetidines from azetidin-2-ones with the use of hydroalanes as specific reducing agents
Mitsuo Yamashita and Iwao Ojima
pp 6339 - 6342; DOI:
10.1021/ja00358a040
PDF
Organic thermal reaction. 56. Intramolecular 1,1-cycloaddition reaction of allyldiazomethanes: electrophilic nature of the terminal nitrogen of diazomethane and geometrical requirement
Tsutomu Miyashi, Katsuyoshi Yamakawa, Masaki Kamata, and Toshio Mukai
pp 6342 - 6343; DOI:
10.1021/ja00358a041
PDF
Stereospecificity in the biosynthesis of phytosterol side chains: carbon-13 NMR signal assignments of C-26 and C-27
Shujiro Seo, Atsuko Uomori, Yohko Yoshimura, and Kenichi Takeda
pp 6343 - 6344; DOI:
10.1021/ja00358a042
PDF
Novel silicon-promoted cycloalkylation of alkenylmetal derivatives
Eiichi Negishi, Larry D. Boardman, James M. Tour, Hiroyuki Sawada, and Cynthia L. Rand
pp 6344 - 6346; DOI:
10.1021/ja00358a043
PDF
Tungsten carbene complexes in olefin metathesis: a cationic and chiral active species
Jacky Kress and John A. Osborn
pp 6346 - 6347; DOI:
10.1021/ja00358a044
PDF
Dynamics of micellized radical pairs. Measurement of micellar exit rates of benzylic radicals
Nicholas J. Turro, Matthew B. Zimmt, and Ian R. Gould
pp 6347 - 6349; DOI:
10.1021/ja00358a045
PDF
Thermal isomerizations of 2,2,3,3-tetrafluorobicyclopentanes. The kinetic effect of fluorine substituents on cyclobutane bond homolysis
William R. Dolbier and Dheya M. Al-Fekri
pp 6349 - 6350; DOI:
10.1021/ja00358a046
PDF
Dominance of the proximity effect of complexation over resonance and inductive effects in directing a metalation: regiospecific .beta. lithiation of N,N-diisopropylcyclohex-3-enecarboxamide and of N,N-diisopropyl-2-methylpent-3-enecarboxamide
Peter Beak, James E. Hunter, and Young M. Jun
pp 6350 - 6351; DOI:
10.1021/ja00358a047
PDF
Novel chain mechanism for the formyl-metal to hydrido-metal conversion. Free radical, photochemical and electrochemical methods of initiation
B. A. Narayanan, C. Amatore, C. P. Casey, and J. K. Kochi
pp 6351 - 6352; DOI:
10.1021/ja00358a048
PDF
Preparation and reactions of chromium(1-) ion. The chromium-hydrogen bond strength
Larry Sallans, Kelley Lane, Robert R. Squires, and Ben S. Freiser
pp 6352 - 6354; DOI:
10.1021/ja00358a049
PDF
Polymerized-depolymerized vesicles. A reversible phosphatidylcholine-based membrane
Steven L. Regen, Kazuo Yamaguchi, N. K. P. Samuel, and Maninder Singh
pp 6354 - 6355; DOI:
10.1021/ja00358a050
PDF
Organometallic crown ethers. 1. Metal-acyl binding to a crown ether-held cation
S. J. McLain
pp 6355 - 6357; DOI:
10.1021/ja00358a051
PDF
Oxygen-17 NMR as a probe of nucleic acid dynamics
Matthew Petersheim, Virginia W. Miner, John A. Gerlt, and James H. Prestegard
pp 6357 - 6358; DOI:
10.1021/ja00358a052
PDF
The photofragmentation dynamics of chromium hexacarbonyl in the gas phase
T. Rick Fletcher and Robert N. Rosenfeld
pp 6358 - 6359; DOI:
10.1021/ja00358a053
PDF
Evidence for rapid pseudorotation in triphenylcyclopropenyl anion
Hans Gunter Koser, George E. Renzoni, and Weston Thatcher Borden
pp 6359 - 6360; DOI:
10.1021/ja00358a054
PDF
Formation of photoactive charge-transfer complexes between methyl viologen and sacrifical electron donors. EDTA and triethanolamine
Morton Z. Hoffman, D. R. Prasad, Guilford Jones, and Vincent Malba
pp 6360 - 6362; DOI:
10.1021/ja00358a055
PDF
Book Reviews

pp 6362 - 6370; DOI:
10.1021/ja00358a600
PDF

Issue 21


Nuclear spin polarization effects in systems with large hyperfine couplings. Limitations of Kaptein's rules
Richard S. Hutton, Heinz D. Roth, and Steven H. Bertz
pp 6371 - 6377; DOI:
10.1021/ja00359a001
PDF
Automerization of gaseous phenylium ions. Direct evidence from the phenylation of methyl halides
Maurizio Speranza, Yeghis Keheyan, and Giancarlo Angelini
pp 6377 - 6380; DOI:
10.1021/ja00359a002
PDF
High resolution electron energy loss vibrational studies of carbon monoxide coordination to the (10.hivin.10) surface of zinc oxide
K. L. D'Amico, F. R. McFeely, and Edward I. Solomon
pp 6380 - 6383; DOI:
10.1021/ja00359a003
PDF
Photophysics of polycyclic aromatic molecules on semiconductor powders
K. Chandrasekaran and J. K. Thomas
pp 6383 - 6389; DOI:
10.1021/ja00359a004
PDF
Comprehensive theoretical study of isomers and rearrangement barriers of even-electron polyatomic molecules HmABHn (A, B = carbon, nitrogen, oxygen, and fluorine)
John A. Pople, Krishnan Raghavachari, Michael J. Frisch, J. Stephen Binkley, and Paul V. R. Schleyer
pp 6389 - 6399; DOI:
10.1021/ja00359a005
PDF
Dioxygen activation by photoexcited copper atoms
Geoffrey A. Ozin, Steven A. Mitchell, and Jamie Garcia-Prieto
pp 6399 - 6406; DOI:
10.1021/ja00359a006
PDF
Coupled oscillator interpretation of the vibrational circular dichroism of several dicarbonyl-containing steroids
Usha Narayanan and T. A. Keiderling
pp 6406 - 6411; DOI:
10.1021/ja00359a007
PDF
Optical and neutron inelastic scattering study of norbornane: a new assignment of vibrational frequences
Yvon Brunel, Christian Coulombeau, Christian Coulombeau, Michel Moutin, and Herve Jobic
pp 6411 - 6416; DOI:
10.1021/ja00359a008
PDF
Effect of crystal packing on the solid-state spectral properties of vicinal diketones
John I. Crowley, Richard D. Balanson, and James J. Mayerle
pp 6416 - 6423; DOI:
10.1021/ja00359a009
PDF
Measurements of molecular g values, magnetic susceptibility anisotropies, and quadrupole moments for the acetylene-hydrochloric acid complex
S. G. Kukolich, E. J. Campbell, W. G. Read, and J. A. Shea
pp 6423 - 6426; DOI:
10.1021/ja00359a010
PDF
Rotational barriers in diphenylmethyl anions stabilized by trimethylsilyl and tricarbonylchromium(0) moieties
Siden Top, Gerard Jaouen, Brian G. Sayer, and Michael J. McGlinchey
pp 6426 - 6429; DOI:
10.1021/ja00359a011
PDF
Sapphyrins: novel aromatic pentapyrrolic macrocycles
Victor J. Bauer, Derrick L. J. Clive, David Dolphin, John B. Paine, Francis L. Harris, Michael M. King, John Loder, Shen Wei Chien Wang, and Robert Burns Woodward
pp 6429 - 6436; DOI:
10.1021/ja00359a012
PDF
Chemistry of organosilicon compounds. 178. Electron spin resonance and chemical studies on the 6-(trimethylsilyl)cyclohexadienyl and related radicals
Mitsuo Kira, Hisashi Sugiyama, and Hideki Sakurai
pp 6436 - 6442; DOI:
10.1021/ja00359a013
PDF
An SN2 deprotection of synthetic peptides with a low concentration of hydrofluoric acid in dimethyl sulfide: evidence and application in peptide synthesis
James P. Tam, William F. Heath, and R. B. Merrifield
pp 6442 - 6455; DOI:
10.1021/ja00359a014
PDF
Resonance Raman spectra of rubredoxin, desulforedoxin, and the synthetic analog Fe(S2-o-xyl)2: conformational effects
Vittal K. Yachandra, Jeffrey Hare, I. Moura, and Thomas G. Spiro
pp 6455 - 6462; DOI:
10.1021/ja00359a015
PDF
Resonance Raman spectra of spinach ferredoxin and adrenodoxin and of analog complexes
Vittal K. Yachandra, Jeffrey Hare, Andrew Gewirth, Roman S. Czernuszewicz, T. Kimura, Richard H. Holm, and Thomas G. Spiro
pp 6462 - 6469; DOI:
10.1021/ja00359a016
PDF
Oxygen-17 NMR spectral properties of pyrophosphate, simple phosphonates, and thiophosphate and phosphonate analogues of ATP
John A. Gerlt, Mark A. Reynolds, Peter C. Demou, and George L. Kenyon
pp 6469 - 6475; DOI:
10.1021/ja00359a017
PDF
Nitrogen-15 and oxygen-17 NMR studies of the proton binding sites in imidodiphosphate, tetraethyl imidodiphosphate, and adenylyl imidodiphosphate
Mark A. Reynolds, John A. Gerlt, Peter C. Demou, Norman J. Oppenheimer, and George L. Kenyon
pp 6475 - 6481; DOI:
10.1021/ja00359a018
PDF
Electron paramagnetic crystallography of cobalt(II) and copper(II) carboxypeptidase A
L. Charles Dickinson and J. C. W. Chien
pp 6481 - 6487; DOI:
10.1021/ja00359a019
PDF
Reaction of (ethoxycarbonyl)carbene with o-carborane
Guoxiu Zheng and Maitland Jones
pp 6487 - 6488; DOI:
10.1021/ja00359a020
PDF
The possible involvement of excited singlet methylene in the deoxygenation of formaldehyde by atomic carbon
Sheikh N. Ahmed and Philip B. Shevlin
pp 6488 - 6490; DOI:
10.1021/ja00359a021
PDF
Cesium 18-crown-6 compounds. A crystalline ceside and a crystalline electride
Ahmed Ellaboudy, James L. Dye, and Patrick B. Smith
pp 6490 - 6491; DOI:
10.1021/ja00359a022
PDF
Methane exchange reactions of lanthanide and early-transition-metal methyl complexes
Patricia L. Watson
pp 6491 - 6493; DOI:
10.1021/ja00359a023
PDF
An experimental and theoretical evaluation of the mechanism of hydrocyanic acid formation in the reaction between atomic carbon and ammonia
Daniel W. McPherson, Michael L. McKee, and Philip B. Shevlin
pp 6493 - 6495; DOI:
10.1021/ja00359a024
PDF
Valence electronic structures of the organouranium dicyclopentadienyl complexes (.eta.5-C5H5)2UX2 (X = chlorine or methyl)
Bruce E. Bursten and Anne Fang
pp 6495 - 6496; DOI:
10.1021/ja00359a025
PDF
Tricarbon monoxide
Ronald D. Brown, Frank W. Eastwood, Patricia S. Elmes, and Peter D. Godfrey
pp 6496 - 6497; DOI:
10.1021/ja00359a026
PDF
Reaction of bicyclic endo peroxides with carbonyl compounds. A new approach to 1,2,4-trioxanes
Charles W. Jefford, Danielle Jaggi, John Boukouvalas, and Shigeo Kohmoto
pp 6497 - 6498; DOI:
10.1021/ja00359a027
PDF
Reaction of singlet oxygen with enol ethers in the presence of acetaldehyde. Formation of 1,2,4-trioxanes
Charles W. Jefford, Shigeo Kohmoto, John Boukouvalas, and Ulrich Burger
pp 6498 - 6499; DOI:
10.1021/ja00359a028
PDF
Characterization and evidence for alkylation of hydridodicarbonylcyclopentadienylrhenate(1-) ion [CpRe(CO)2H-] in the conversion of dihydrodicarbonylcyclopentadienylrhenium [CpRe(CO)2H2] to CpRe(CO)2R2. Synthesis of a rhenacyclopentane and its thermolysis to methylcyclopropane
Gilbert K. Yang and Robert G. Bergman
pp 6500 - 6501; DOI:
10.1021/ja00359a029
PDF
Correlation between thiophene hydrodesulfurization activity and the number of first sulfur neighbors as determined by EXAFS in sulfided .gamma.-alumina-supported cobalt-molybdenum (CoMo/.gamma.-Al2O3) samples
Michel Boudart, Jorge Sanchez Arrieta, and Ralph Dalla Betta
pp 6501 - 6502; DOI:
10.1021/ja00359a030
PDF
Perfect enzymes: is the equilibrium constant between the enzyme's bound species unity?
Jik Chin
pp 6502 - 6503; DOI:
10.1021/ja00359a031
PDF
Photochemical reactions in organized assemblies. 36. Solubilization in detergent micelles: interactive nature of the solubilization process as indicated by a study of intermolecular charge-transfer complexes
Joseph P. Otruba and David G. Whitten
pp 6503 - 6505; DOI:
10.1021/ja00359a032
PDF
EPR spectra of some .alpha.-tocopherol model compounds. Polar and conformational effects and their relation to antioxidant activities
T. Doba, G. W. Burton, and K. U. Ingold
pp 6505 - 6506; DOI:
10.1021/ja00359a033
PDF
A remakable reversal in the direction of boron migration in the thermal isomerization of organoboranes derived from 2-methyl-2-butene
Herbert C. Brown and Uday S. Racherla
pp 6506 - 6508; DOI:
10.1021/ja00359a034
PDF
Stepwise assembly of heterometallic M4S4 clusters. The structure of bis[(methylcyclopentadienyl)vanadium] bis(nitrosyliron) sulfide [(MeCp)2V2Fe2(NO)2S4], a 58e cubane
Thomas B. Rauchfuss, Timothy D. Weatherill, Scott R. Wilson, and Jeffery P. Zebrowski
pp 6508 - 6510; DOI:
10.1021/ja00359a035
PDF
Electron-imbalanced metallocenophanes. Synthesis and molecular structure of 1,3-(.eta.5,.eta.5-dicyclopentadienyl)propane-3,5-dichloropyridinemanganese(II)
J. Tracy Weed, Michael F. Rettig, and Richard M. Wing
pp 6510 - 6511; DOI:
10.1021/ja00359a036
PDF
Trimethylenemethane cation radical: photosensitized (electron-transfer) generation and reactivity
Yasutake Takahashi, Tsutomu Miyashi, and Toshio Mukai
pp 6511 - 6513; DOI:
10.1021/ja00359a037
PDF
Exchange reactions of halodiazirines. Synthesis of fluorodiazirines
D. Phillip Cox, Robert A. Moss, and Jacek Terpinski
pp 6513 - 6514; DOI:
10.1021/ja00359a038
PDF
Combined oxygen-17 NMR spectra and oxygen-18 isotope effects in carbon-13 NMR spectra for oxygen labeling studies. Carbon .fwdarw. sulfur oxygen migration in the aqueous chlorination of mercapto alcohols
J. F. King, S. Skonieczny, K. C. Khemani, and J. B. Stothers
pp 6514 - 6515; DOI:
10.1021/ja00359a039
PDF
Perannulanes. A new class of fused polycyclic compounds
James A. Marshall, James C. Peterson, and Lukasz Lebioda
pp 6515 - 6517; DOI:
10.1021/ja00359a040
PDF
Stereocontrolled synthesis of the C(1)-C(17) half of boromycin
James D. White, Mitchell A. Avery, Satish C. Choudhry, Om P. Dhingra, Myung Chol Kang, and Alan J. Whittle
pp 6517 - 6518; DOI:
10.1021/ja00359a041
PDF
New mechanism based serine protease inhibitors: inhibition of human leukocyte elastase, porcine pancreatic elastase, human leukocyte cathepsin G, and chymotrypsin by 3-chloroisocoumarin and 3,3-dichlorophthalide
J. Wade Harper, Keiji Hemmi, and James C. Powers
pp 6518 - 6520; DOI:
10.1021/ja00359a042
PDF
Chemiluminescence from hyponitrite esters. Excited triplet states from dismutation of geminate alkoxyl radical pairs
E. M. Y. Quinga and G. D. Mendenhall
pp 6520 - 6521; DOI:
10.1021/ja00359a043
PDF
Thermal generation of the [16]annulene anion radical from the [8]annulene anion radical
Gerald R. Stevenson, Richard C. Reiter, and James B. Sedgwick
pp 6521 - 6522; DOI:
10.1021/ja00359a044
PDF
Spatially isolated redox orbitals: evidence from low-temperature voltammetry
Yasuhiko Ohsawa, M. Keith DeArmond, Kenneth W. Hanck, David E. Morris, David G. Whitten, and Paul E. Neveux
pp 6522 - 6524; DOI:
10.1021/ja00359a045
PDF
Hexaalkylcyclotrisilanes (R2Si)3: hexakis(1-ethylpropyl) and hexaisopropyl derivatives
Satoru Masamune, Hiromi Tobita, and Shu Murakami
pp 6524 - 6525; DOI:
10.1021/ja00359a046
PDF
Methods for indole alkaloid synthesis: an exceptionally mild procedure for introducing the 6,7 double bond into Aspidosperma alkaloids via thiolactams
Philip Magnus and Paul Pappalardo
pp 6525 - 6526; DOI:
10.1021/ja00359a047
PDF
Hydrogen atom transfer reactions: the nature of the transition state as delineated from the temperature dependence of the primary KIE
Henry L. Strong, Marilyn L. Brownawell, and Joseph San Filippo
pp 6526 - 6528; DOI:
10.1021/ja00359a048
PDF
Excited-state porphyrin-quinone interactions at 10 .ANG. separation
Jonathan S. Lindsey, David C. Mauzerall, and Henry Linschitz
pp 6528 - 6529; DOI:
10.1021/ja00359a049
PDF
Electrophilic reactions at single bonds. 18. Heterogeneous gas phase ethylation of methane with ethylene over solid superacids. A carbon-13 isotope tracer study
George A. Olah, Jeff D. Felberg, and Koop Lammertsma
pp 6529 - 6531; DOI:
10.1021/ja00359a050
PDF
Additions and Corrections - Studies of the Tautomerism of Purine and the Protonation of Purine and Its 7- and 9-Methyl Derivatives by Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy
Nina C. Gonnella, and John D. Roberts
pp 6531 - 6531; DOI:
10.1021/ja00359a601
PDF
Additions and Corrections - Two Syntheses of d,l-Aplysistatin
T. R. Hoye, A. J. Caruso, J. F. Dellaria, Jr., and M. J. Kurth
pp 6531 - 6531; DOI:
10.1021/ja00359a602
PDF
Additions and Corrections - Poly(1,6-heptadiyane), a Free-Standing Polymer Film Dopable to High Electrical Conductivity
Harry W. Gibson, F. C. Bailey, Arthur J. Epstein, Heiko Rommelmann, Samuel Kaplan, John Harbour, Xiao-Quing Yang, David B. Tanner, and John M. Pochan
pp 6531 - 6531; DOI:
10.1021/ja00359a603
PDF
Additions and Corrections - Substituent Effects on Benzyl Radical ESR Hyperfine Coupling Constants. The σα· Scale Based upon Spin Delocalization
J. M. Dust, and D. R .Arnold
pp 6531 - 6531; DOI:
10.1021/ja00359a604
PDF
Book Reviews

pp 6532 - 6540; DOI:
10.1021/ja00359a600
PDF

Issue 22


Anion states of para-disubstituted benzenes: p-Di-tert-butylbenzene and related group 4 molecules: p-bis[trimethyl(silyl, germyl, and stannyl)]benzene
Judith C. Giordan and John H. Moore
pp 6541 - 6544; DOI:
10.1021/ja00360a001
PDF
Negative ions: effect of .alpha.- vs. .beta.-silyl substitution on the negative ion states of .pi. systems
Judith C. Giordan
pp 6544 - 6546; DOI:
10.1021/ja00360a002
PDF
Light-induced electron transfer in colloidal semiconductor dispersions: single vs. dielectronic reduction of acceptors by conduction-band electrons
Jacques Moser and Michael Graetzel
pp 6547 - 6555; DOI:
10.1021/ja00360a003
PDF
Chain-length dependence of electronic and electrochemical properties of conjugated systems: polyacetylene, polyphenylene, polythiophene, and polypyrrole
J. L. Bredas, R. Silbey, D. S. Boudreaux, and R. R. Chance
pp 6555 - 6559; DOI:
10.1021/ja00360a004
PDF
Use of the ESR half-field transition to determine the interspin distance and the orientation of the interspin vector in systems with two unpaired electrons
Sandra S. Eaton, Kundalika M. More, Bhimrao M. Sawant, and Gareth R. Eaton
pp 6560 - 6567; DOI:
10.1021/ja00360a005
PDF
Host-guest complexes of 18-crown-6 with neutral molecules possessing the structure element XH2 (X = oxygen, nitrogen, or carbon)
A. Elbasyouny, H. J. Bruegge, K. Von Deuten, M. Dickel, A. Knochel, K. U. Koch, J. Kopf, D. Melzer, and G. Rudolph
pp 6568 - 6577; DOI:
10.1021/ja00360a006
PDF
Polymer-immobilized complexes of platinum(II): their precursors and preparation studied by high-resolution solid-state phosphorus-31 NMR using magic-angle spinning techniques
C. A. Fyfe, J. A. Davies, H. C. Clark, P. J. Hayes, and R. E. Wasylishen
pp 6577 - 6584; DOI:
10.1021/ja00360a007
PDF
Synthesis and characterization of some reversible iron(II) dioxygen carriers of lacunar macrobicyclic ligands and their reactivities with dioxygen
Norman Herron, L. Lawrence Zimmer, Joseph J. Grzybowski, Dennis J. Olszanski, Susan C. Jackels, Robert W. Callahan, James H. Cameron, Gary G. Christoph, and Daryle H. Busch
pp 6585 - 6596; DOI:
10.1021/ja00360a008
PDF
X-ray absorption spectra and the coordination number of zinc and cobalt carbonic anhydrase as a function of pH and inhibitor binding
Vittal Yachandra, Linda Powers, and Thomas G. Spiro
pp 6596 - 6604; DOI:
10.1021/ja00360a009
PDF
Stereochemical course of phosphoanhydride synthesis
John P. Richard and Perry A. Frey
pp 6605 - 6609; DOI:
10.1021/ja00360a010
PDF
Crystal structures, molecular conformations, infrared spectra, and carbon-13 NMR spectra of methylproline peptides in the solid state
Judith L. Flippen-Anderson, Richard Gilardi, Isabella L. Karle, Michael H. Frey, Stanley J. Opella, Lila M. Gierasch, Murray Goodman, Vincent Madison, and Norma G. Delaney
pp 6609 - 6614; DOI:
10.1021/ja00360a011
PDF
Centrosymmetric crystals for the direct assignment of the absolute configuration of chiral molecules. Application to the .alpha.-amino acids by their effect on glycine crystals
I. Weissbuch, L. Addadi, Z. Berkovitch-Yellin, E. Gati, S. Weinstein, M. Lahav, and L. Leiserowitz
pp 6615 - 6621; DOI:
10.1021/ja00360a012
PDF
Synthesis applications of aza-Cope rearrangements. 11. Carbon-carbon bond formation under mild conditions via tandem cationic aza-Cope rearrangement-Mannich reactions. A convenient synthesis of polysubstituted pyrrolidines
Larry E. Overman, Masaaki Kakimoto, Mark E. Okazaki, and G. Patrick Meier
pp 6622 - 6629; DOI:
10.1021/ja00360a013
PDF
Synthesis applications of aza-Cope rearrangements. 12. Applications of cationic aza-Cope rearrangements for alkaloid synthesis. Stereoselective preparation of cis-3a-aryloctahydroindoles and a new short route to Amaryllidaceae alkaloids
Larry E. Overman, Leah T. Mendelson, and E. Jon Jacobsen
pp 6629 - 6637; DOI:
10.1021/ja00360a014
PDF
Manipulation of vinyl groups in protoporphyrin IX: introduction of deuterium and carbon-13 labels for spectroscopic studies
Kevin M. Smith, Eugene M. Fujinari, Kevin C. Langry, Daniel W. Parish, and Hani D. Tabba
pp 6638 - 6646; DOI:
10.1021/ja00360a015
PDF
Ab initio investigation on the lowest singlet and triplet state of disilyne (Si2H2)
Hans Lischka and Hans Joachim Koehler
pp 6646 - 6649; DOI:
10.1021/ja00360a016
PDF
Metacyclophanes and related compounds. 6. Reduction of [2.2]metaparacyclophanequinone
Masashi Tashiro, Keizo Koya, and Takehito Yamato
pp 6650 - 6653; DOI:
10.1021/ja00360a017
PDF
Termination of biomimetic cyclizations by the allylsilane function. Formation of the steroid nucleus in one step from an acyclic polyenic chain
William S. Johnson, Yu Qun Chen, and Michael S. Kellogg
pp 6653 - 6656; DOI:
10.1021/ja00360a018
PDF
Discrimination between exo- and endo-3,2-methyl shifts in substituted 2-norbornyl cations on the (+)-camphenilone route to (-)-albene
John E. Baldwin and Timothy C. Barden
pp 6656 - 6662; DOI:
10.1021/ja00360a019
PDF
Enzyme-catalyzed positional isotope exchange by phosphorus-31 nuclear magnetic resonance spectroscopy using either oxygen-18- or oxygen-17-.beta.,.gamma.-bridge-labeled adenosine 5'-triphosphate
Mark A. Reynolds, Norman J. Oppenheimer, and George L. Kenyon
pp 6663 - 6667; DOI:
10.1021/ja00360a020
PDF
Allosteric effects: an on-off switch
J. Rebek and L. Marshall
pp 6668 - 6670; DOI:
10.1021/ja00360a021
PDF
Resonance Raman spectroscopic evidence for a common [3-iron-4-sulfur] structure among proteins containing three-iron centers
Michael K. Johnson, Roman S. Czernuszewicz, Thomas G. Spiro, James A. Fee, and William V. Sweeney
pp 6671 - 6678; DOI:
10.1021/ja00360a022
PDF
The chemistry of 1,5-diblocked flavin. 1. Interconversion of the reduced, radical, and oxidized forms of 1,10-ethano-5-ethyllumiflavin
Gert Eberlein and Thomas C. Bruice
pp 6679 - 6684; DOI:
10.1021/ja00360a023
PDF
The chemistry of a 1,5-diblocked flavin. 2. Proton and electron transfer steps in the reaction of dihydroflavins with oxygen
Gert Eberlein and Thomas C. Bruice
pp 6685 - 6697; DOI:
10.1021/ja00360a024
PDF
Cross polarization and magic angle sample spinning NMR spectra of model organic compounds. 3. Effect of the carbon-13-proton dipolar interaction on cross polarization and carbon-proton dephasing
Lawrence B. Alemany, David M. Grant, Terry D. Alger, and Ronald J. Pugmire
pp 6697 - 6704; DOI:
10.1021/ja00360a025
PDF
Acetylene and ethylene complexes of gold atoms: matrix isolation ESR study
Paul H. Kasai
pp 6704 - 6710; DOI:
10.1021/ja00360a026
PDF
Practical, cobalt-mediated, diastereoselective synthesis of the 11-(trimethylsilyl)-3-methoxyestra-1,3,5(10),8(14),9(11)-pentaene nucleus: a novel steroid intermediate. First observation of hindered rotation in a vinyltrimethylsilane
Jean Claude Clinet, Elisabet Dunach, and K. Peter C. Vollhardt
pp 6710 - 6712; DOI:
10.1021/ja00360a027
PDF
Synthesis and reactivity of compounds with cyclobutane ring(s). 19. Intramolecular thermal cyclization reactions of N,N-diacryloylamines
Alex Alder and Daniel Bellus
pp 6712 - 6714; DOI:
10.1021/ja00360a028
PDF
Intramolecular [8+2] cycloadditions of alkenylheptafulvenes
Ching Yang Liu, Jiri Mareda, K. N. Houk, and Frank R. Fronczek
pp 6714 - 6715; DOI:
10.1021/ja00360a029
PDF
A totally synthetic route to lincosamine
Eric R. Larson and Samuel Danishefsky
pp 6715 - 6716; DOI:
10.1021/ja00360a030
PDF
Unequivocal evidence for sidearm participation in crystalline lariat ether complexes
Frank R. Fronczek, Vincent J. Gatto, Rose Ann Schultz, Steven J. Jungk, William J. Colucci, Richard D. Gandour, and George W. Gokel
pp 6717 - 6718; DOI:
10.1021/ja00360a031
PDF
6-Cyanotricyclo[5.5.0.02,5]dodeca-3,6,8,10,12-pentaene (cyano-Dewar heptalene). Synthesis and isomerizations in ground and excited states
Yoshikazu Sugihara, Shigeharu Wakabayashi, and Ichiro Murata
pp 6718 - 6719; DOI:
10.1021/ja00360a032
PDF
Photoaddition of alkyl halides to olefins catalyzed by copper(I) complexes
Michiharu Mitani, Isao Kato, and Kikuhiko Koyama
pp 6719 - 6721; DOI:
10.1021/ja00360a033
PDF
Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFeSC)- and (RFeSC)-(C5H5)(CO)(Ph2R*P)Fe:CHCH3+ (R* = (S)-2-methylbutyl). Role of metal vs. ligand chirality in the optical induction
M. Brookhart, D. Timmers, J. R. Tucker, G. D. Williams, G. Ronald Husk, Henri Brunner, and Benedikt Hammer
pp 6721 - 6723; DOI:
10.1021/ja00360a034
PDF
Application of the furan carbonyl photocycloaddition reaction to the synthesis of the bis(tetrahydrofuran) moiety of asteltoxin
Stuart L. Schreiber and Kunio Satake
pp 6723 - 6724; DOI:
10.1021/ja00360a035
PDF
Silene stereochemistry. 3. The configurational stability of 1-methyl-1-phenyl-2-neopentylsilene
Paul Ronald Jones and Myong Euy Lee
pp 6725 - 6726; DOI:
10.1021/ja00360a036
PDF
Diels-Alder reactions of Fischer carbene complexes
William D. Wulff and Dominic C. Yang
pp 6726 - 6727; DOI:
10.1021/ja00360a037
PDF
Chemistry of the tropane alkaloids. 33. 2-Carbomethoxy-3-tropinone: an advanced intermediate in the biosynthesis of cocaine
Edward Leete
pp 6727 - 6728; DOI:
10.1021/ja00360a038
PDF
Intramolecular nitrene carbon-hydrogen insertions mediated by transition-metal complexes as nitrogen analogs of cytochrome P-450 reactions
Ronald Breslow and Samuel H. Gellman
pp 6728 - 6729; DOI:
10.1021/ja00360a039
PDF
Multiple metal-carbon bonds. 34. Why terminal alkynes cannot be metathesized. Preparation and crystal structure of a deprotonated tungstacyclobutadiene complex, W(.eta.5-C5H5)[C3(CMe3)2]Cl
Laughlin G. McCullough, Mark L. Listemann, Richard R. Schrock, Melvyn Rowen Churchill, and Joseph W. Ziller
pp 6729 - 6730; DOI:
10.1021/ja00360a040
PDF
Derivatives of tetrathiovanadate(V): synthesis of the linear heterometallic Fe(.mu.2-S)2V(.mu.2-S)2Fe core and the structures of tetrathiovanadate(3-) ion ([VS4]3-) and tetrachlorotetrathiodiferratevanadate(3-) ion ([VFe2S4Cl4]3-)
Y. Do, E. D. Simhon, and R. H. Holm
pp 6731 - 6732; DOI:
10.1021/ja00360a041
PDF
Nitroxyl-mediated electro-oxidation of amines to nitriles and carbonyl compounds
M. F. Semmelhack and Christopher R. Schmid
pp 6732 - 6734; DOI:
10.1021/ja00360a042
PDF
Solubilization in surfactant media: the use of an isomerizable solute-probe to determine microheterogeneity in microemulsions
Kirk S. Schanze and David G. Whitten
pp 6734 - 6735; DOI:
10.1021/ja00360a043
PDF
Nucleic acid related compounds. 45. A deoxygenative [1,2]-hydride shift rearrangement converting cyclic cis-diol monotosylates to inverted secondary alcohols
Fritz Hansske and Morris J. Robins
pp 6736 - 6737; DOI:
10.1021/ja00360a044
PDF
Regiospecific metal-catalyzed ring expansion of aziridines to .beta.-lactams
Howard Alper, Fabio Urso, and David J. H. Smith
pp 6737 - 6738; DOI:
10.1021/ja00360a045
PDF
Photophysics of the second excited singlet states of xanthione and related thiones in perfluoroalkane solvents
A. Maciejewski and R. P. Steer
pp 6738 - 6740; DOI:
10.1021/ja00360a046
PDF
Radiation-induced reduction of thymidine in aqueous solution: isolation and characterization of a novel dimeric product
Seiichi Nishimoto, Hiroshi Ide, Kikumi Nakamichi, and Tsutomu Kagiya
pp 6740 - 6741; DOI:
10.1021/ja00360a047
PDF
Linear solvation energy relationships. 26. Some measures of relative self-association of alcohols and water
Mortimer J. Kamlet, Ruth Doherty, R. W. Taft, and Michael H. Abraham
pp 6741 - 6743; DOI:
10.1021/ja00360a048
PDF
Models for nitrite reductases. Redox chemistry of iron-nitrosyl porphyrins, chlorins, and isobacteriochlorins and .pi. cation radicals of cobalt-nitrosyl isobacteriochlorins
Etsuko Fujita and Jack Fajer
pp 6743 - 6745; DOI:
10.1021/ja00360a049
PDF
Dependence on anomeric configuration of the temperature dependence of the chemical shifts of exchangeable protons of pyranoses and pyranosides
Lynn Buffington, John Crusius, Mark Nachbor, and Linda Reven
pp 6745 - 6747; DOI:
10.1021/ja00360a050
PDF
Enforced deformation of porphyrins by short-strap bridging
Tilak P. Wijesekera, John B. Paine, David Dolphin, Frederick W. B. Einstein, and Terry Jones
pp 6747 - 6749; DOI:
10.1021/ja00360a051
PDF
Uranium-carbon multiple bond chemistry. 2. Coupling of bridging and terminal carbonyls in the formation of an iron .eta.1:.eta.3-allyl complex
Roger E. Cramer, Kelvin T. Higa, Steven L. Pruskin, and John W. Gilje
pp 6749 - 6750; DOI:
10.1021/ja00360a052
PDF
Coupling of alkenes with Fischer-type alkylidene complexes of iron
M. F. Semmelhack and Rui Tamura
pp 6750 - 6752; DOI:
10.1021/ja00360a053
PDF
Hydrido, alkyl, and ethylene 1,2-bis(dimethylphosphino)ethane complexes of manganese and the crystal structures of MnBr2(dmpe)2, [Mn(AlH4)(dmpe)2]2 and MnMe2(dmpe)2
Gregory S. Girolami, Geoffrey Wilkinson, Mark Thornton-Pett, and Michael B. Hursthouse
pp 6752 - 6753; DOI:
10.1021/ja00360a054
PDF
.alpha.-Substitution-spiroannulation of saturated ketones
Barry M. Trost and Michael K. T. Mao
pp 6753 - 6755; DOI:
10.1021/ja00360a055
PDF
A biomimetic approach to plumericin
Barry M. Trost, James M. Balkovec, and Michael K. T. Mao
pp 6755 - 6757; DOI:
10.1021/ja00360a056
PDF
An umpolung of allyl bis(silanes). Tandem [6.5] annulations via a biallyl equivalent
Barry M. Trost and Makoto Shimizu
pp 6757 - 6759; DOI:
10.1021/ja00360a057
PDF
Allosteric effects: structural and thermodynamic origins of binding in cooperativity in a subunit model
K. Onan, J. Rebek, T. Costello, and L. Marshall
pp 6759 - 6760; DOI:
10.1021/ja00360a058
PDF
Proton transfer dynamics involving the intramolecular charge transfer state of photoexcited 1-(p-aminophenyl)pyrene
Sair Hagopian and Lawrence A. Singer
pp 6760 - 6761; DOI:
10.1021/ja00360a059
PDF
Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes
Eiichi Negishi and Joseph A. Miller
pp 6761 - 6763; DOI:
10.1021/ja00360a060
PDF
Synthesis and molecular structures of homoleptic dicyclohexylphosphide complexes of the early transition metals
R. T. Baker, P. J. Krusic, T. H. Tulip, J. C. Calabrese, and S. S. Wreford
pp 6763 - 6765; DOI:
10.1021/ja00360a061
PDF
Regiospecific trapping of radicals from cyclization reactions. Cyclic nitriles via isocyanide trapping
G. Stork and Philip Michael Sher
pp 6765 - 6766; DOI:
10.1021/ja00360a062
PDF
Catalytic chemistry of palladium surfaces under ultrahigh-vacuum conditions
T. M. Gentle, V. H. Grassian, D. G. Klarup, and E. L. Muetterties
pp 6766 - 6767; DOI:
10.1021/ja00360a063
PDF
Dynamic behavior of a two-site vesicular reaction
Robert A. Moss and Ronald P. Schreck
pp 6767 - 6768; DOI:
10.1021/ja00360a064
PDF
Additions and Corrections - Toward Tricyclo[2.2.2.2.]decane. 1. [n.2.2.2.]Paddlane Systems, n = 10-14
Philip E. Eaton, and Bernard D. Leipzig
pp 6768 - 6768; DOI:
10.1021/ja00360a601
PDF
Additions and Corrections - Polar Radicals. 17. On the Mechanism of Iodine Atom Transfer. A 9-1-2 Intermediate.
Dennis D. Tanner, Darwin W. Reed, and B. P. Setiloane
pp 6768 - 6768; DOI:
10.1021/ja00360a602
PDF
Additions and Corrections - Measurement of Nonsynergistic Anion Binding to Transferrin by EPR Difference Spectroscopy.
Donald A. Folajtar, and N. Dennis Chasteen
pp 6768 - 6768; DOI:
10.1021/ja00360a603
PDF
Book Reviews

pp 6769 - 6774; DOI:
10.1021/ja00360a600
PDF

Issue 23


A simple model for the interaction potentials in electron-transfer reactions: application to the molecular hydrogen ion/molecular molecular (H2+H2) system
Chyuan Yih Lee and Andrew E. DePristo
pp 6775 - 6781; DOI:
10.1021/ja00361a001
PDF
Effect of pressure on the rate of alkaline fading of triphenylmethane dyes in cationic micelles
Yoshihiro Taniguchi and Akira Iguchi
pp 6782 - 6786; DOI:
10.1021/ja00361a002
PDF
Clarification of the hole-size cation-diameter relationship in crown ethers and a new method for determining calcium cation homogeneous equilibrium binding constants
George W. Gokel, Deepa M. Goli, Carlo Minganti, and Luis Echegoyen
pp 6786 - 6788; DOI:
10.1021/ja00361a003
PDF
Indentification of the gas-phase trimer methyl sulfide-hydrofluoric acid complex [Me2S.cntdot.(HF)2] by photoelectron spectroscopy
Frank Carnovale, Michelle K. Livett, and J. Barrie Peel
pp 6788 - 6790; DOI:
10.1021/ja00361a004
PDF
EPR and ODMR studies of the lowest excited triplet states of two tautomers of indazole in a benzoic acid host crystal
Masayo Noda and Noboru Hirota
pp 6790 - 6794; DOI:
10.1021/ja00361a005
PDF
A correlation of carbon-13 NMR and electrochemical data for benzyllithium
Ronald Breslow and Joshua Schwarz
pp 6795 - 6796; DOI:
10.1021/ja00361a006
PDF
Solubility properties in polymers and biological media. 1. Correlations in various media of the solubilities of gaseous anesthetics and other solutes with a number of solute parameters
Michael H. Abraham, Mortimer J. Kamlet, R. W. Taft, and Paul K. Weathersby
pp 6797 - 6801; DOI:
10.1021/ja00361a007
PDF
Charge reversal of the conjugate bases of acetonitrile and nitromethane
Maurice M. Bursey, Donald J. Harvan, Carol E. Parker, and J. Ronald Hass
pp 6801 - 6804; DOI:
10.1021/ja00361a008
PDF
Radical cations of tetraalkylcyclopropanes. The cyclopropane moiety as an electron donor
H. D. Roth and M. L. M. Schilling
pp 6805 - 6808; DOI:
10.1021/ja00361a009
PDF
Multiphoton dissociation of transition-metal carbonyl complexes: a novel route to gas-phase metal clusters
D. G. Leopold and V. Vaida
pp 6809 - 6811; DOI:
10.1021/ja00361a010
PDF
Inclusion complex formation by transition-metal complexes containing a void in proximity to a site that can be made catalytically active
Kenneth J. Takeuchi and Daryle H. Busch
pp 6812 - 6816; DOI:
10.1021/ja00361a011
PDF
Electron delocalization in mixed-valence tungsten polyanions
C. Sanchez, J. Livage, J. P. Launay, and M. Fournier
pp 6817 - 6823; DOI:
10.1021/ja00361a012
PDF
Organo-f-element thermochemistry. Metal-ligand bond dissociation enthalpies in (pentamethylcyclopentadienyl)thorium hydrocarbyls, metallacycles, hydrides, and dialkylamides
Joseph W. Bruno, Tobin J. Marks, and Lester R. Morss
pp 6824 - 6832; DOI:
10.1021/ja00361a013
PDF
Chemical and physical properties of fluorenylidene: equilibration of the singlet and triplet carbenes
Peter B. Grasse, Beth Ellen Brauer, Joseph J. Zupancic, Kenneth J. Kaufmann, and Gary B. Schuster
pp 6833 - 6845; DOI:
10.1021/ja00361a014
PDF
Kinetics and mechanism of the interaction of potassium peroxydisulfate and 18-crown-6 in aqueous media
Jerald K. Rasmussen, Steven M. Heilmann, Paul E. Toren, Alphonsus V. Pocius, and Thomas A. Kotnour
pp 6845 - 6849; DOI:
10.1021/ja00361a015
PDF
Thermolysis of acyclic azoalkanes: simultaneous or stepwise carbon-nitrogen homolysis?
Paul S. Engel and Dale B. Gerth
pp 6849 - 6851; DOI:
10.1021/ja00361a016
PDF
Hydrolysis of ortho esters: further investigation of the factors that control the rate-determining step
Y. Chiang, A. J. Kresge, M. O. Lahti, and D. P. Weeks
pp 6852 - 6855; DOI:
10.1021/ja00361a017
PDF
The strain energy of diphenylcyclopropenone: a reexamination
Arthur Greenberg, Reginald P. T. Tomkins, Mark Dobrovolny, and Joel F. Liebman
pp 6855 - 6858; DOI:
10.1021/ja00361a018
PDF
Kinetics of ozonation. 1. Electron-deficient alkenes
William A. Pryor, David Giamalva, and Daniel F. Church
pp 6858 - 6861; DOI:
10.1021/ja00361a019
PDF
Semibullvalenes. 2. A MNDO theoretical study of the rearrangements of semibullvalene and several of its derivatives
L. S. Miller, K. Grohmann, and J. J. Dannenberg
pp 6862 - 6865; DOI:
10.1021/ja00361a020
PDF
Selective ring-opening polymerization of di-O-methylated and di-O-benzylated 1,4-anhydro-.alpha.-D-ribopyranoses and structure proof of synthetic cellulose-type polysaccharide (1 .fwdarw. 4)-.beta.-D-ribopyranan and (1 .fwdarw. 5)-.alpha.-D-ribofuranan
Toshiyuki Uryu, Junichi Yamanouchi, Takashi Kato, Shinya Higuchi, and Kei Matsuzaki
pp 6865 - 6871; DOI:
10.1021/ja00361a021
PDF
Proton [1,5] shifts in P-unsubstituted 1H-phospholes. Synthesis and chemistry of 2H-phosphole dimers
Claude Charrier, Hubert Bonnard, Guillaume De Lauzon, and Francois Mathey
pp 6871 - 6877; DOI:
10.1021/ja00361a022
PDF
Palladium-catalyzed oxidation of amino alkenes to cyclic imines or enamines and amino ketones
B. Pugin and L. M. Venanzi
pp 6877 - 6881; DOI:
10.1021/ja00361a023
PDF
Mercury(II)-mediated opening of cyclopropanes. Effects of proximate internal nucleophiles on stereo- and regioselectivity
David B. Collum, Fariborz Mohamadi, and John S. Hallock
pp 6882 - 6889; DOI:
10.1021/ja00361a024
PDF
Methano-bridged compounds. 1. Correlation of the carbon-13 nuclear magnetic shift average and shift of the bridge carbon with the average .pi.-electron density of methano-bridged and homoaromatic compounds
Ronald J. Hunadi
pp 6889 - 6895; DOI:
10.1021/ja00361a025
PDF
Thioacylium ions. Gas-phase ion-molecule reactions of thioic and dithioic acid derivatives
Marjorie C. Caserio and Jhong K. Kim
pp 6896 - 6902; DOI:
10.1021/ja00361a026
PDF
Studies on the photochemical reactions of .alpha.,.beta.-acetylenic ketones with tetramethylethylene
Shahrokh Saba, Steven Wolff, Clemens Schroeder, Paul Margaretha, and William C. Agosta
pp 6902 - 6907; DOI:
10.1021/ja00361a027
PDF
Photochemistry of alkyl halides. 10. Vinyl halides and vinylidene dihalides
Paul J. Kropp, Steven A. McNeely, and Robert Drummond Davis
pp 6907 - 6915; DOI:
10.1021/ja00361a028
PDF
Vancomycin: structure and transformation to CDP-I
Constance M. Harris, Hana Kopecka, and Thomas M. Harris
pp 6915 - 6922; DOI:
10.1021/ja00361a029
PDF
Models of the cytochromes b. 4. Effects of axial ligand plane orientation on the proton NMR spectra of symmetrically substituted low-spin iron(III) porphyrins
F. Ann Walker, Joanne Buchler, Joyce T. West, and John L. Hinds
pp 6923 - 6929; DOI:
10.1021/ja00361a030
PDF
Proton nuclear magnetic resonance investigation of the active site fragment of splenin, an immunoregulatory polypeptide
N. Rama Krishna, George A. Heavner, and Joseph B. Vaughn
pp 6930 - 6934; DOI:
10.1021/ja00361a031
PDF
Permeable membrane/mass spectrometric measurement of an enzymatic kinetic isotope effect: .alpha.-chymotrypsin-catalyzed transesterification
K. C. Calvo, C. R. Weisenberger, L. B. Anderson, and Michael H. Klapper
pp 6935 - 6941; DOI:
10.1021/ja00361a032
PDF
Stereochemistry of the phosphorylation reaction of .alpha.-chymotrypsin by a cyclic phosphate triester
Dinesh O. Shah, Deborah Kallick, Robert Rowell, Rouhlwai Chen, and David G. Gorenstein
pp 6942 - 6943; DOI:
10.1021/ja00361a033
PDF
Peptide conformations. 28. Relayed heteronuclear correlation spectroscopy and conformational analysis of cyclic hexapeptides containing the active sequence of somatostatin
H. Kessler, M. Bernd, H. Kogler, J. Zarbock, O. W. Soerensen, G. Bodenhausen, and R. R. Ernst
pp 6944 - 6952; DOI:
10.1021/ja00361a034
PDF
Kinetics of the scrambling reaction between dimanganese and dirhenium decacarbonyl
Antonio Marcomini and Anthony Poe
pp 6952 - 6958; DOI:
10.1021/ja00361a035
PDF
Norrish type II reaction in the solid state: involvement of a boatlike reactant conformation
Sara Ariel, V. Ramamurthy, John R. Scheffer, and James Trotter
pp 6959 - 6960; DOI:
10.1021/ja00361a036
PDF
Kinetics of free radical brominations. Effect of ring substitution on the strength of benzyl carbon-hydrogen bonds
Andreas A. Zavitsas, Gerald Fogel, Kamal E. Halwagi, and Patricia A. Donnaruma Legotte
pp 6960 - 6962; DOI:
10.1021/ja00361a037
PDF
Regioselectivity in the addition of carbanions to (1,4-dimethoxynaphthalene)tricarbonylchromium. A new entry into anthracyclinone synthesis
E. Peter Kuendig, Vincent Desobry, and Dana P. Simmons
pp 6962 - 6963; DOI:
10.1021/ja00361a038
PDF
Organometallic high-pressure reactions. 2. Aldol reaction of silyl enol ethers with aldehydes under neutral conditions
Yoshinori Yamamoto, Kazuhiro Maruyama, and Kiyoshi Matsumoto
pp 6963 - 6965; DOI:
10.1021/ja00361a039
PDF
First example of an isolable .sigma.-sulfurane with an apical alkyl group effected by transannular bond formation between the amino and the sulfonio groups
Kinya Akiba, Kohichi Takee, Katsuo Ohkata, and Fujiko Iwasaki
pp 6965 - 6966; DOI:
10.1021/ja00361a040
PDF
Optical activity due to exciton interaction between 1B transitions of benzene chromophores
Keiji Shingu, Seiichi Imajo, Hiroko Kuritani, Sanji Hagishita, and Kaoru Kuriyama
pp 6966 - 6967; DOI:
10.1021/ja00361a041
PDF
On the interactivity of chiral auxiliaries with chiral catalysts in the hetero Diels-Alder reaction: a new route to L-glycolipids
Mark Bednarski and Samuel Danishefsky
pp 6968 - 6969; DOI:
10.1021/ja00361a042
PDF
Double oxidative addition of beta or gamma methyl groups of coordinated Fischer-type carbenes on a tri-ruthenium cluster; synthesis of Ru3{.mu.-H2,.eta.2,.mu.3-C(OEt):C(H)}(CO)9 and Ru3{.mu.-H2,.eta.2,.mu.3-C(OEt)N(Me)C(H)}(CO)9
C. M. Jensen and H. D. Kaesz
pp 6969 - 6970; DOI:
10.1021/ja00361a043
PDF
Multichannel resonance Raman experiments on carboxypeptidase A catalyzed ester hydrolysis under cryoenzymological conditions
Stephen J. Hoffman, Samuel S. T. Chu, Ho Hi Lee, E. T. Kaiser, and P. R. Carey
pp 6971 - 6973; DOI:
10.1021/ja00361a044
PDF
Selective DEPT pulse sequence. A rapid one-dimensional experiment for the simultaneous determination of carbon-proton chemical-shift correlations and CHn multiplicities
David M. Doddrell, William Brooks, James Field, and Ruth Lynden-Bell
pp 6973 - 6975; DOI:
10.1021/ja00361a045
PDF
Synthesis of the alleged structure of senoxydene, the triquinane sesquiterpene derived from Senecio oxyodontus
Leo A. Paquette, Robert A. Galemmo, and James P. Springer
pp 6975 - 6976; DOI:
10.1021/ja00361a046
PDF
Asymmetric induction in the intramolecular 1,3-diyl trapping reaction. Chirality on the linking chain
R. Daniel Little and Keith J. Stone
pp 6976 - 6978; DOI:
10.1021/ja00361a047
PDF
Control of stereochemistry in potassium alkoxide accelerated [1,3] sigmatropic rearrangements by the use of a crown ether for the apparent destruction of ion pairs. Evidence for a fragmentation mechanism in a vinylcyclobutane rearrangement
M. Bhupathy and Theodore Cohen
pp 6978 - 6979; DOI:
10.1021/ja00361a048
PDF
The anion assisted transfer of a sterically constrained proton: molecular structure of bis[1,2-ethanediylbis(diphenylphosphine)]dicarbonylhydridomolybdenum tetrachloroaluminate [HMo(CO)2(Ph2PCH2CH2PPh2)2+ AlCl4-]
John M. Hanckel and Marcetta Y. Darensbourg
pp 6979 - 6980; DOI:
10.1021/ja00361a049
PDF
Ethylene and acetylene complexes of the silver atom
Drora Cohen and Harold Basch
pp 6980 - 6982; DOI:
10.1021/ja00361a050
PDF
syn-1,6:8,13-Diimino[14]annulene
E. Vogel, F. Kuebart, J. A. Marco, R. Andree, H. Guenther, and R. Aydin
pp 6982 - 6983; DOI:
10.1021/ja00361a051
PDF
Chemistry of organosilicon compounds. 185. ESR study of twisting of trimethylsilyl-substituted alkene cation radicals
Mitsuo Kira, Hiroko Nakazawa, and Hideki Sakurai
pp 6983 - 6984; DOI:
10.1021/ja00361a052
PDF
Bromocyclization of unsaturated thiocarbamidates. Synthesis of (.+-.)-sporamine
Spencer Knapp and Dinesh V. Patel
pp 6985 - 6986; DOI:
10.1021/ja00361a053
PDF
Rupture and realignment of the bridging phosphine framework in the reactions of polynuclear rhodium complexes of 2,6-bis(diphenylphosphino)pyridine
Fred E. Wood, Jan Hvoslef, and Alan L. Balch
pp 6986 - 6987; DOI:
10.1021/ja00361a054
PDF
Biosynthesis of estrogens: the steric mode of the initial C-19 hydroxylation of androgens by human placental aromatase
Eliahu Caspi, Thangavel Arunachalam, and Peter A. Nelson
pp 6987 - 6989; DOI:
10.1021/ja00361a055
PDF
Photoinduced reactions. 151. Isolation and characterization of a thymine-lysine adduct in UV-irradiated nuclei. The role of thymine-lysine photoaddition in photo-cross-linking of proteins to DNA
Isao Saito, Hiroshi Sugiyama, and Teruo Matsuura
pp 6989 - 6991; DOI:
10.1021/ja00361a056
PDF
Cobalt-catalyzed cocyclizations of isocyanato alkynes: a regiocontrolled entry into 5-indolizinones. Application to the total synthesis of camptothecin
Richard A. Earl and K. Peter C. Vollhardt
pp 6991 - 6993; DOI:
10.1021/ja00361a057
PDF
Iminium ion and acyl iminium ion initiated cyclizations of vinylsilanes. Regiocontrolled construction of unsaturated azacyclics
Larry E. Overman, Thomas C. Malone, and G. Patrick Meier
pp 6993 - 6994; DOI:
10.1021/ja00361a058
PDF
Solvent and intramolecular proton dipolar relaxation of the three phosphates of ATP: a heteronuclear 2D NOE study
Chin Yu and George C. Levy
pp 6994 - 6996; DOI:
10.1021/ja00361a059
PDF
Selective intramolecular [6 + 4] cycloadditions of aminodienylfulvenes
Tse Chong Wu, Jiri Mareda, Y. N. Gupta, and K. N. Houk
pp 6996 - 6997; DOI:
10.1021/ja00361a060
PDF
Transition structure for the reaction of a carbenoid, (fluoromethyl)lithium, with ethylene
Jiri Mareda, Nelson G. Rondan, K. N. Houk, Timothy Clark, and Paul V. R. Schleyer
pp 6997 - 6999; DOI:
10.1021/ja00361a061
PDF
Regiochemistry in thiocarbonyl Diels-Alder additions: reversal of selectivity by substituent effects in thioaldehydes
E. Vedejs, D. A. Perry, K. N. Houk, and Nelson G. Rondan
pp 6999 - 7001; DOI:
10.1021/ja00361a062
PDF
Hematin-catalyzed rearrangement of hydroperoxylinoleic acid to epoxy alcohols via an oxygen rebound
Thomas A. Dix and Lawrence J. Marnett
pp 7001 - 7002; DOI:
10.1021/ja00361a063
PDF
Integrated chemical systems: photocatalysis at semiconductors incorporated into polymer (Nafion)/mediator systems
M. Krishnan, James R. White, Marye Anne Fox, and Allen J. Bard
pp 7002 - 7003; DOI:
10.1021/ja00361a064
PDF
Additions and Corrections - Preparation and Properties of Dinitrogen Trimethylphosphine Complexes of Molybdenum and Tungsten. 4. Synthesis, Chemical Properties, and X-ray Structure of cis-[Mo(N2)2(PMe3)4]. The Crystal and Molecular Structure of trans-[Mo(C2H4)2(PMe3)4] and trans, mer-[Mo(C2H4)2(CO)(PMe3)3]
Ernesto Carmona, Jose M. Marin, Manuel L. Poveda, Jerry L. Atwood, and Robin D. Rogers
pp 7004 - 7004; DOI:
10.1021/ja00361a600
PDF
Additions and Corrections - Chemistry of Singlet Oxygen. 44. Mechanism of Photooxidation of 2,5-Dimethylhexa-2,4-diene and 2-Methyl-2-pentene
Lewis E. Manring, and Christopher S. Foote
pp 7004 - 7004; DOI:
10.1021/ja00361a601
PDF
Book Reviews

pp 7004 - 7010; DOI:
10.1021/ja00361a602
PDF

Issue 24


Generalized valence bond description of simple ylides
David A. Dixon, Thom H. Dunning, Robert A. Eades, and Paul G. Gassman
pp 7011 - 7017; DOI:
10.1021/ja00362a001
PDF
Radical anions and radical trianions of tetracyanoarenoquinodimethanes. An ESR and ENDOR study
Fabian Gerson, Rene Heckendorn, Dwaine O. Cowan, Arawinda M. Kini, and McRae Maxfield
pp 7017 - 7023; DOI:
10.1021/ja00362a002
PDF
Ion-molecule association reactions: reaction sequences initiated by protonated methanol (MeOH2+) in methanol; experiment and theory
Lewis M. Bass, R. Dwight Cates, Martin F. Jarrold, Nicolas Kirchner, and Michael T. Bowers
pp 7024 - 7033; DOI:
10.1021/ja00362a003
PDF
Nature of the frontier orbitals in phosphine, trimethylphosphine, and trifluorophosphine
Shenxiu Xiao, William C. Trogler, D. E. Ellis, and Ziva Berkovitch-Yellin
pp 7033 - 7037; DOI:
10.1021/ja00362a004
PDF
Combination of theoretical ab initio and experimental information to obtain reliable harmonic force constants. Scaled quantum mechanical (QM) force fields for glyoxal, acrolein, butadiene, formaldehyde, and ethylene
Peter Pulay, Geza Fogarasi, Gabor Pongor, James E. Boggs, and Anna Vargha
pp 7037 - 7047; DOI:
10.1021/ja00362a005
PDF
Photoredox behavior of zinc(II) porphyrins in vesicle assemblies
James K. Hurst, Lester Y. C. Lee, and Michael Graetzel
pp 7048 - 7056; DOI:
10.1021/ja00362a006
PDF
The absence of bonding electron density in certain covalent bonds as revealed by x-ray analysis
Jack D. Dunitz and Paul Seiler
pp 7056 - 7058; DOI:
10.1021/ja00362a007
PDF
Tungsten-183 NMR: a complete and unequivocal assignment of the tungsten-tungsten connectivities in heteropolytungstates via two-dimensional tungsten-183 NMR techniques
C. Brevard, R. Schimpf, G. Tourne, and C. M. Tourne
pp 7059 - 7063; DOI:
10.1021/ja00362a008
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Dependence of the rate advantage for the inner-sphere electron-transfer pathway on electronic structure for low-spin cobalt(III)-(II), nickel(III)-(II), and copper(III)-(II) couples
Krishan Kumar, Francois P. Rotzinger, and John F. Endicott
pp 7064 - 7074; DOI:
10.1021/ja00362a009
PDF
Investigations of the nature of dehydrogenation of the .alpha.-carbon atom in the oxidation of amines coordinated to ruthenium
F. Richard Keene, Michael J. Ridd, and Michael R. Snow
pp 7075 - 7081; DOI:
10.1021/ja00362a010
PDF
Chemical reaction paths. 9. Conformational interconversions of Wilkinson's catalyst and of related square-planar XM(PR3)3 compounds as determined from systematic analysis of solid-state structural data
K. Chandrasekhar and Hans Beat Buergi
pp 7081 - 7093; DOI:
10.1021/ja00362a011
PDF
Models for the photosynthetic water oxidizing enzyme. 2. Electronic, magnetic, and EPR characterization of a binuclear manganese(II) semiquinone complex
P. Mathur and G. C. Dismukes
pp 7093 - 7098; DOI:
10.1021/ja00362a012
PDF
Positive shift of redox potential of [Fe4S4(Z-cys-Gly-Ala-OMe)4]2- in dichloromethane
Norikazu Ueyama, Toshitsugu Terakawa, Michio Nakata, and Akira Nakamura
pp 7098 - 7102; DOI:
10.1021/ja00362a013
PDF
Thermolysis of azoalkanes containing the 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) skeleton
Paul S. Engel, Chrostopher J. Nalepa, Douglas W. Horsey, Dalen E. Keys, and Robert T. Grow
pp 7102 - 7107; DOI:
10.1021/ja00362a014
PDF
Photolysis of reluctant azoalkanes. Effect of structure on photochemical loss of nitrogen from 2,3-diazabicyclo[2.2.2]oct-2-ene derivatives
Paul S. Engel, Christopher J. Nalepa, Luis R. Soltero, Douglas W. Horsey, and Dalen E. Keys
pp 7108 - 7114; DOI:
10.1021/ja00362a015
PDF
Reaction of nucleophiles with electron acceptors by SN2 or electron transfer (ET) mechanisms: tert-butyl peroxybenzoate/dimethyl sulfide and benzoyl peroxide/N,N-dimethylaniline systems
William A. Pryor and William H. Hendrickson
pp 7114 - 7122; DOI:
10.1021/ja00362a016
PDF
Solvolyses of .alpha.-keto norbornyl trifluoroacetates and triflates. Discrete .alpha.-keto cations vs .sigma.-assisted (K.DELTA.) processes
Xavier Creary and Cristina C. Geiger
pp 7123 - 7129; DOI:
10.1021/ja00362a017
PDF
Reagents for organic synthesis. Part 3. Tin-mediated esterification in macrolide synthesis
Kosta Steliou and Marc Andre Poupart
pp 7130 - 7138; DOI:
10.1021/ja00362a018
PDF
Effect of isotope scrambling and tunneling on the kinetic and product isotope effects for reduced nicotinamide adenine dinucleotide model hydride transfer reactions
Michael F. Powell and Thomas C. Bruice
pp 7139 - 7149; DOI:
10.1021/ja00362a019
PDF
Effects of hydration on the dynamics of deoxyribonucleic acid
Michael Thang Mai, David E. Wemmer, and Oleg Jardetzky
pp 7149 - 7152; DOI:
10.1021/ja00362a020
PDF
Ground states of molecules. 62. MINDO/3 and MNDO studies of some cheletropic reactions
Michael J. S. Dewar and Lek Chantranupong
pp 7152 - 7161; DOI:
10.1021/ja00362a021
PDF
Ground states of molecules. 63. Reverse cheletropic reactions in polycyclic systems
Michael J. S. Dewar and Lek Chantranupong
pp 7161 - 7168; DOI:
10.1021/ja00362a022
PDF
Enhanced sodium cation binding by electrochemically reduced nitrobenzene-substituted lariat ethers
Angel Kaifer, Luis Echegoyen, Deborah A. Gustowski, Deepa M. Goli, and George W. Gokel
pp 7168 - 7169; DOI:
10.1021/ja00362a023
PDF
Glutathiohydroxyacetone: proton NMR determination of the stereochemistry of proton exchange by glyoxalase I. Evidence for a cis-enediol intermediate based on mirror-image catalysis
Ravi V. J. Chari and John W. Kozarich
pp 7169 - 7171; DOI:
10.1021/ja00362a024
PDF
Synthesis and characterization of [7]circulene
Koji Yamamoto, Tadashi Harada, Masao Nakazaki, Takuo Naka, Yasushi Kai, Shigeharu Harada, and Nobutami Kasai
pp 7171 - 7172; DOI:
10.1021/ja00362a025
PDF
A stable sulfenic acid, 9-triptycenesulfenic acid: its isolation and characterization
Nobuo Nakamura
pp 7172 - 7173; DOI:
10.1021/ja00362a026
PDF
Palladium-catalyzed cross-coupling of allyl halides with organotins
Forrest K. Sheffy and J. K. Stille
pp 7173 - 7175; DOI:
10.1021/ja00362a027
PDF
Direct conversion of organic halides to aldehydes with carbon monoxide and tin hydride catalyzed by palladium
Victor P. Baillargeon and J. K. Stille
pp 7175 - 7176; DOI:
10.1021/ja00362a028
PDF
Aqueous tungsten(VI) alkyl chemistry
Irene Feinstein-Jaffe, Steven F. Pedersen, and Richard R. Schrock
pp 7176 - 7177; DOI:
10.1021/ja00362a029
PDF
Nucleophilic aromatic substitution by organoaluminum reagents. Application to the synthesis of indoles
Junya Fujiwara, Yoshimi Fukutani, Hiromi Sano, Keiji Maruoka, and Hisashi Yamamoto
pp 7177 - 7179; DOI:
10.1021/ja00362a030
PDF
Photoreduction of methylviologen sensitized by dihydroxytin(IV) uroporphyrin
J. A. Shelnutt
pp 7179 - 7180; DOI:
10.1021/ja00362a031
PDF
Photocatalytic conversion of primary amines to secondary amines and cyclization of polymethylene-.alpha.,.omega.-diamines by an aqueous suspension of titanium(IV) oxide/platinum
Seiichi Nishimoto, Bunsho Ohtani, Tadao Yoshikawa, and Tsutomu Kagiya
pp 7180 - 7182; DOI:
10.1021/ja00362a032
PDF
Homoenolate dianions. Intramolecular rearrangements of 1,4-dilithio-N-phenyl amides
Ramanuj Goswami and Daniel E. Corcoran
pp 7182 - 7183; DOI:
10.1021/ja00362a033
PDF
Orientation of complex molecules chemisorbed on metal surfaces: near-edge x-ray absorption
Allen L. Johnson and E. L. Muetterties
pp 7183 - 7185; DOI:
10.1021/ja00362a034
PDF
Ab initio study of the transition structure of the [1,5]-sigmatropic hydrogen transfer in cis-1,3-pentadiene
B. Andes Hess and L. J. Schaad
pp 7185 - 7186; DOI:
10.1021/ja00362a035
PDF
Stereocontrolled synthesis of an ene-carbapenem antibiotic (-)-asparenomycin C
Kazuo Okano, Yoshinori Kyotani, Hiroshi Ishihama, Susumu Kobayashi, and Masaji Ohno
pp 7186 - 7187; DOI:
10.1021/ja00362a036
PDF
Nucleophilic trapping of 7,11-dideoxyanthracyclinone quinone methides
K. Ramakrishnan and Jed Fisher
pp 7187 - 7188; DOI:
10.1021/ja00362a037
PDF
Sensitivity-enhanced correlation of nitrogen-15 and proton chemical shifts in natural-abundance samples via multiple quantum coherence
Ad Bax, Richard H. Griffey, and Bruce L. Hawkins
pp 7188 - 7190; DOI:
10.1021/ja00362a038
PDF
Activation of methane by iridium complexes
James K. Hoyano, Alexander D. McMaster, and William A. G. Graham
pp 7190 - 7191; DOI:
10.1021/ja00362a039
PDF
Dicycloocta[1,2,3,4-def:1',2',3',4'-jkl]biphenylene. Benzenoid atropism in a highly antiaromatic polycycle
Charles F. Wilcox and Erik N. Farley
pp 7191 - 7192; DOI:
10.1021/ja00362a040
PDF
A .beta.-metal ketone strategy. Reactions of siloxycyclopropanes with silver(I) tetrafluoroborate and copper(II) tetrafluoroborate leading to 1,6-diketones
Ilhyong Ryu, Masato Ando, Akiya Ogawa, Shinji Murai, and Noboru Sonoda
pp 7192 - 7194; DOI:
10.1021/ja00362a041
PDF
(Iminomethylidene)phosphines (RP:C:NR)
Curt Wentrup, Horst Briehl, Gerd Becker, Gudrun Uhl, Hans Juergen Wessely, Andre Maquestiau, and Robert Flammang
pp 7194 - 7195; DOI:
10.1021/ja00362a042
PDF
Enzyme system generation of singlet (1.DELTA.g) molecular oxygen observed directly by 1.0-1.8-.mu. luminescence spectroscopy
Ahsan U. Khan
pp 7195 - 7197; DOI:
10.1021/ja00362a043
PDF
Rearrangement of bridging alkylidyneiron complexes to bridging alkenyliron complexes
Charles P. Casey, Seth R. Marder, and Paul J. Fagan
pp 7197 - 7198; DOI:
10.1021/ja00362a044
PDF
Artificial transaminase carrying a synthetic macrocyclic binding group
Jeffrey Winkler, Evdoxia Coutouli-Argyropoulou, Reinhard Leppkes, and Ronald Breslow
pp 7198 - 7199; DOI:
10.1021/ja00362a045
PDF
Revised absolute configuration of mitomycin C. X-ray analysis of 1-N-(p-bromobenzoyl)mitomycin C
Kunikatsu Shirahata and Noriaki Hirayama
pp 7199 - 7200; DOI:
10.1021/ja00362a046
PDF
Synthesis and reactions of porphine-type metal complexes. 15. Carbon-carbon bond formation by light assisted B12-catalysis. Nucleophilic acylation of Michael olefins
Rolf Scheffold and Ryszard Orlinski
pp 7200 - 7202; DOI:
10.1021/ja00362a047
PDF
Cluster compounds with unusual reactivity. The syntheses and crystal and molecular structures of the electron-rich osmium-tungsten cluster with carbonyl, dimethylphenylphosphine, and sulfido ligands Os3W(CO)12(PMe2Ph)(.mu.3-S)2 and its dimethylphenylphosphine adduct
Richard D. Adams, Istvan T. Horvath, and Pradeep Mathur
pp 7202 - 7203; DOI:
10.1021/ja00362a048
PDF
The chemistry of the dianions of 3-heteroatom-substituted cyclopent-2-en-1-ones: an expedient route to dl-coriolin
Masato Koreeda and Suresh G. Mislankar
pp 7203 - 7205; DOI:
10.1021/ja00362a049
PDF
A method of assigning functionally relevant amino acid residue resonances in paramagnetic hemoproteins using proton NOE measurements
Robert D. Johnson, S. Ramaprasad, and Gerd N. La Mar
pp 7205 - 7206; DOI:
10.1021/ja00362a050
PDF
Surface titration of silica-alumina monitored by nitrogen-15 NMR with cross polarization and magic-angle spinning
James F. Haw, I Ssuer Chuang, Bruce L. Hawkins, and Gary E. Maciel
pp 7206 - 7207; DOI:
10.1021/ja00362a051
PDF
Ethylene biosynthesis. 2. Stereochemistry of ripening, stress, and model reactions
Michael C. Pirrung
pp 7207 - 7209; DOI:
10.1021/ja00362a052
PDF
Far-UV (185-nm) photochemistry of allenes: photoisomerization and cycloreversion reactions of vinylidenecyclobutane
Mark G. Steinmetz, Edmund J. Stark, Yao Pin Yen, Richard T. Mayes, and R. Srinivasan
pp 7209 - 7210; DOI:
10.1021/ja00362a053
PDF
Additions and Corrections - Dynamics at the Active Site of Bis(4-fluorophenyl)carbamoyl-α-chymotrysin
M. Cairi, and J. T. Gerig
pp 7210 - 7210; DOI:
10.1021/ja00362a601
PDF
Additions and Corrections - Organoaluminum-Promoted Beckmann Rearrangement of Oxime Sulfonates
Keiji Maruoka, Tohru Miyazaki, Mamoru Ando, Yasushi Matsumura, Soichi Sakane, Kazunobu Hattori, and Hisashi Yamamoto
pp 7210 - 7210; DOI:
10.1021/ja00362a602
PDF
Additions and Corrections - Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II), Structural and Spectroscopic Evidence for Molybdenum-to-Bipyridyl π* Bonding
M. H. Chisholm, J. C. Huffman, I. R. Rothwell, P. G. Bradley, N. Kress, and W. H. Woodruff
pp 7210 - 7210; DOI:
10.1021/ja00362a603
PDF
Book Reviews

pp 7211 - 7214; DOI:
10.1021/ja00362a600
PDF

Issue 25


Intramolecular Photochemical Electron Transfer. 1. EPR and Optical Absorption Evidence for Stabilized Charge Separation in Linked Porphyrin-Quinone Molecules
Alan R. McIntosh, Aleksander Siemiarczuk, James R. Bolton, Martin J. Stillman, Te Fu Ho, and Alan C. Weedon
pp 7215 - 7223; DOI:
10.1021/ja00363a001
PDF
Intramolecular photochemical electron transfer. 2. Fluorescence studies of linked porphyrin-quinone compounds
Aleksander Siemiarczuk, Alan R. McIntosh, Te Fu Ho, Martin J. Stillman, Kenneth J. Roach, Alan C. Weedon, James R. Bolton, and John S. Connolly
pp 7224 - 7230; DOI:
10.1021/ja00363a002
PDF
Gas-phase NMR investigation of structural exchange in sulfur tetrafluoride. Evidence for nonstatistical intramolecular vibrational redistribution
Cheryl A. Spring and Nancy S. True
pp 7231 - 7236; DOI:
10.1021/ja00363a003
PDF
Quasirelativistic SCF-X.alpha. scattered-wave study of uranocene, thorocene, and cerocene
Notker Roesch and Andrew Streitwieser
pp 7237 - 7240; DOI:
10.1021/ja00363a004
PDF
Alternating current electrolysis of transition-metal carbonyl complexes: electrochemically induced photochemistry
Horst Kunkely, Andreas Merz, and Arnd Vogler
pp 7241 - 7243; DOI:
10.1021/ja00363a005
PDF
Metalloporphyrin gas and condensed-phase resonance Raman studies: the role of vibrational anharmonicities as determinants of Raman frequencies
Sanford A. Asher and James Murtaugh
pp 7244 - 7251; DOI:
10.1021/ja00363a006
PDF
Stereochemistry in trivalent nitrogen compounds. 39. Configurational biasing of tertiary amide ionophores by alkali metal chelation
Leslie H. Craine, Jeremy Greenblatt, Sarah Woodson, Edwin Hortelano, and Morton Raban
pp 7252 - 7255; DOI:
10.1021/ja00363a007
PDF
Absorption spectra and dynamics of some excited and ionic dicarbazolyl compounds with specific geometrical structures
Hiroshi Masuhara, Naoto Tamai, Noboru Mataga, Frans C. De Schryver, and Jan Vandendriessche
pp 7256 - 7262; DOI:
10.1021/ja00363a008
PDF
Proton nuclear magnetic relaxation of nitrogen-15-labeled nucleic acids via dipolar coupling and chemical shift anisotropy
M. Gueron, J. L. Leroy, and R. H. Griffey
pp 7262 - 7266; DOI:
10.1021/ja00363a009
PDF
Nucleophilic reactions of trifluoromethyl ion (F3C-) at sp2 and sp3 carbon in the gas phase. Characterization of carbonyl addition adducts
Richard N. McDonald and A. Kasem Chowdhury
pp 7267 - 7271; DOI:
10.1021/ja00363a010
PDF
Interactions of benzoquinone with a model membrane bilayer as reported by a positronium probe
Y. Y. Wang, A. J. Hancock, and Y. C. Jean
pp 7272 - 7276; DOI:
10.1021/ja00363a011
PDF
Mechanisms of the dismutation of superoxide catalyzed by the copper(II) phenanthroline complex and of the oxidation of the copper(I) phenanthroline complex by oxygen in aqueous solution
Sara Goldstein and Gidon Czapski
pp 7276 - 7280; DOI:
10.1021/ja00363a012
PDF
Effects of secondary bonding interactions on the iron-sulfur cubane-type [Fe4S4]2+ core of ferredoxin site analogs: [Fe4S4(SC6H4-o-OH)4]2-, a distorted cubane-type cluster with one five-coordinate iron atom
R. E. Johnson, G. C. Papaefthymiou, R. B. Frankel, and R. H. Holm
pp 7280 - 7287; DOI:
10.1021/ja00363a013
PDF
A silica-supported rhodium hydroformylation catalyst: evidence for dinuclear elimination
James P. Collman, James A. Belmont, and John I. Brauman
pp 7288 - 7294; DOI:
10.1021/ja00363a014
PDF
Cyclopentadienyldichlorotitanium(III): a free-radical-like reagent for reducing azo (N:N) multiple bonds in azo and diazo compounds
S. Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
pp 7295 - 7301; DOI:
10.1021/ja00363a015
PDF
Bidodecahedral coordination geometry in a dimolybdenum tetrahydride containing three fluoride bridges: crystal and molecular structure of .mu.-trifluoro-bis[tris(methyldiphenylphosphine)dihydromolybdenum] tetrafluoroborate ([((PMePh2)3H2Mo)2(.mu.-F)3]BF4)
Robert H. Crabtree, Gregory G. Hlatky, and Elizabeth M. Holt
pp 7302 - 7306; DOI:
10.1021/ja00363a016
PDF
Synthesis, x-ray crystal structure, and chemistry of a metal cluster ketenylidene, [Fe3(CO)9(CCO)]2-, with carbide-like reactivity
Joseph W. Kolis, Elizabeth M. Holt, and Duward F. Shriver
pp 7307 - 7313; DOI:
10.1021/ja00363a017
PDF
Cation-anion combination reactions. 24. Ionization potentials, solvation energies, and reactivities of nucleophiles in water
Calvin D. Ritchie
pp 7313 - 7318; DOI:
10.1021/ja00363a018
PDF
Induction of the cholesteric mesophase in nematic liquid crystals: mechanism and application to the determination of bridged biaryl configurations
Giovanni Gottarelli, Marcel Hibert, Bruno Samori, Guy Solladie, Gian P. Spada, and Richard Zimmermann
pp 7318 - 7321; DOI:
10.1021/ja00363a019
PDF
Electrocyclic ring opening of a .beta.-lithiocyclopropyloxirane. Generation and trapping of (2Z,4E)-cyclohepta-2,4-dienol
Robert M. Coates and Larry A. Last
pp 7322 - 7326; DOI:
10.1021/ja00363a020
PDF
Hydrolysis of phosphate esters bound to cobalt(III). Kinetics and mechanism of intramolecular attack of hydroxide on coordinated 4-nitrophenyl phosphate
David R. Jones, Leonard F. Lindoy, and Alan M. Sargeson
pp 7327 - 7336; DOI:
10.1021/ja00363a021
PDF
Photochemical transformations. 35. Stereochemistry of electron transfer from photoexcited aromatic rings to carbon-chlorine bonds. Syn stereochemistry of migration in photo-Wagner-Meerwein rearrangements
Stanley J. Cristol, Dave G. Seapy, and Ellen O. Aeling
pp 7337 - 7345; DOI:
10.1021/ja00363a022
PDF
Synthesis of .beta.-lactam antibiotics by the sulfeno-cycloamination
Masataka Ihara, Yo Haga, Mariko Yonekura, Tatsushi Ohsawa, Keiichiro Fukumoto, and Tetsuii Kametani
pp 7345 - 7352; DOI:
10.1021/ja00363a023
PDF
Triquinane sesquiterpenes. An iterative, highly stereocontrolled synthesis of (.+-.)-silphinene
Leo A. Paquette and Andrea Leone-Bay
pp 7352 - 7358; DOI:
10.1021/ja00363a024
PDF
Total synthesis of (.+-.)-pentalenene, the least oxidized neutral triquinane metabolite of Streptomyces griseochromogenes
Leo A. Paquette and Gary D. Annis
pp 7358 - 7363; DOI:
10.1021/ja00363a025
PDF
Silanes in organic synthesis. 20. Regio- and stereochemical definition of silatropic migration within trimethylsilyl-substituted isodicyclopentadienes
Leo A. Paquette, Pana Charumilind, and Judith C. Gallucci
pp 7364 - 7375; DOI:
10.1021/ja00363a026
PDF
Syntheses and ENDOR investigations of carbon-13-labeled and deuterated phenalenyls. Rearrangement reactions
C. Hass, B. Kirste, H. Kurreck, and G. Schloemp
pp 7375 - 7383; DOI:
10.1021/ja00363a027
PDF
A study of the syntheses and properties of [22](1,6)cyclooctatetraenyl(1,4)cyclophane and [24](1,2,5,6)cyclooctatetraenyl(1,2,4,5)cyclophane
James E. Garbe and V. Boekelheide
pp 7384 - 7388; DOI:
10.1021/ja00363a028
PDF
The bond between inverted carbon atoms. Synthesis and chemistry of 2,4-methano-2,4-didehydroadamantane: a highly reactive [3.1.1]propellane
Katica Mlinaric-Majerski and Zdendo Majerski
pp 7389 - 7395; DOI:
10.1021/ja00363a029
PDF
Structures of kelletinins I and II, antibacterial metabolites of the marine mollusk Kelletia kelletii
Adrienne A. Tymiak and Kenneth L. Rinehart
pp 7396 - 7401; DOI:
10.1021/ja00363a030
PDF
Deuterium nuclear magnetic resonance spectroscopy as a probe of the stereochemistry of biosynthetic reactions: the biosynthesis of retronecine
Gunnar Grue-Sorensen and Ian D. Spenser
pp 7401 - 7404; DOI:
10.1021/ja00363a031
PDF
Thermal isomerization of quadricyclane to norbornadiene catalyzed by copper(II) and tin(II) salts
D. J. Fife, K. W. Morse, and W. M. Moore
pp 7404 - 7407; DOI:
10.1021/ja00363a032
PDF
Diastereoselective benzyloxymercuration/demercuration of derivatives of .gamma.-alkyl-.delta.-hydroxy-.alpha.,.beta.-unsaturated esters. A new strategy for the synthesis of aldol-type products
Suvit Thaisrivongs and Dieter Seebach
pp 7407 - 7413; DOI:
10.1021/ja00363a033
PDF
The denticulatins, two polypropionate metabolites from the pulmonate Siphonaria denticulata
Jill E. Hochlowski, D. John Faulkner, Gayle K. Matsumoto, and Jon Clardy
pp 7413 - 7415; DOI:
10.1021/ja00363a034
PDF
Structural studies of a new antitumor agent: tiazofurin and its inactive analogs
Barry M. Goldstein, Fusao Takusagawa, Helen M. Berman, Prem C. Srivastava, and Roland K. Robins
pp 7416 - 7422; DOI:
10.1021/ja00363a035
PDF
Nuclear Overhauser effects and circular dichroism as probes of .beta.-turn conformations in acyclic and cyclic peptides with pro-X sequences
B. N. Narasinga Rao, Anil Kumar, Hemalatha Balaram, A. Ravi, and P. Balaram
pp 7423 - 7428; DOI:
10.1021/ja00363a036
PDF
Practical synthesis of 5-phospho-D-ribosyl .alpha.-1-pyrophosphate (PRPP): enzymatic routes from ribose 5-phosphate or ribose
Akiva Gross, Obsidiana Abril, Jerome M. Lewis, Shimona Geresh, and George M. Whitesides
pp 7428 - 7435; DOI:
10.1021/ja00363a037
PDF
Side chain conformations of oxytocin and vasopressin studied by NMR observation of isotopic isomers
David Cowburn, David H. Live, Alan J. Fischman, and William C. Agosta
pp 7435 - 7442; DOI:
10.1021/ja00363a038
PDF
Phosphenium ions as dienophiles
Carlton K. SooHoo and S. G. Baxter
pp 7443 - 7444; DOI:
10.1021/ja00363a039
PDF
Reaction of phosphenium ions with 1,3-dienes: a rapid synthesis of phosphorus-containing five-membered rings
A. H. Cowley, R. A. Kemp, J. G. Lasch, N. C. Norman, and C. A. Stewart
pp 7444 - 7445; DOI:
10.1021/ja00363a040
PDF
Electron spin echo modulation demonstrates P-450scc complexation
Susan E. Groh, Atsushi Nagahisa, Swee Lian Tan, and William H. Orme-Johnson
pp 7445 - 7446; DOI:
10.1021/ja00363a041
PDF
Investigations of the biosynthesis of furanomycin. Unexpected derivation from acetate and propionate
Ronald J. Parry and H. P. Buu
pp 7446 - 7447; DOI:
10.1021/ja00363a042
PDF
Transmission of magnetic interactions in a molecular metal oxide cluster
A. R. Siedle, J. Barandwski, C. Goldstein, M. DeAngelo, G. F. Kokoszka, L. Azevedo, E. L. Venturini, and F. Padula
pp 7447 - 7448; DOI:
10.1021/ja00363a043
PDF
Vibrational circular dichroism in amino acids and peptides. 8. A chirality rule for methine C*.alpha.-H stretching modes
Laurence A. Nafie, M. Reza Oboodi, and Teresa B. Freedman
pp 7449 - 7450; DOI:
10.1021/ja00363a044
PDF
First experimental demonstration of chemical resonance in an open system
F. Buchholtz and F. W. Schneider
pp 7450 - 7452; DOI:
10.1021/ja00363a045
PDF
Reaction of fluorine atoms with alkyl iodides: a possible observation of the Walden inversion in the gas phase
T. V. Venkitachalam, P. Das, and R. Bersohn
pp 7452 - 7453; DOI:
10.1021/ja00363a046
PDF
Oxidation of NADH by ferrocenium salts. Rate-limiting one-electron transfer
Brian W. Carlson and Larry L. Miller
pp 7453 - 7454; DOI:
10.1021/ja00363a047
PDF
Neutralization-reionization mass spectrometry (NRMS)
Paul O. Danis, Chrysostomos Wesdemiotis, and Fred W. McLafferty
pp 7454 - 7456; DOI:
10.1021/ja00363a048
PDF
Electrocatalytic oxidation of carbon monoxide in a carbon monoxide/oxygen fuel cell
Jianxin Wu and Clifford P. Kubiak
pp 7456 - 7457; DOI:
10.1021/ja00363a049
PDF
Photochemistry of perfluoro-3-diazo-2-butanone
E. D. Laganis, D. S. Janik, T. J. Curphey, and D. M. Lemal
pp 7457 - 7459; DOI:
10.1021/ja00363a050
PDF
Isolation and x-ray structure of bis[(tetrahydrofuran)(.mu.2-di-tert-butylphosphido)(.mu.3-di-tert-butylphosphido)dilithium] ([Li2(.mu.3-tert-Bu2P)(.mu.2-tert-Bu2P)(C4H8O)]2) containing a staggered, planar lithium (Li4) unit. The first structurally characterized alkali metal diorganophosphide
Richard A. Jones, Anthony L. Stuart, and Thomas C. Wright
pp 7459 - 7460; DOI:
10.1021/ja00363a051
PDF
Interaction of phosphorous bis(trimethylsilyl)amide dichloride with carbonylmetalate dianions of iron and chromium: syntheses and x-ray crystal structures of new transition metal complexes involving phosphorus and arsenic in multiple bonding
Kathy M. Flynn, Brendan D. Murray, Marilyn M. Olmstead, and Philip P. Power
pp 7460 - 7461; DOI:
10.1021/ja00363a052
PDF
Retention of chirality during thermal automerization of methyl 1,2-diphenylcyclopentane-1-carboxylate
W. von E. Doering and Ludmila Birladeanu
pp 7461 - 7462; DOI:
10.1021/ja00363a053
PDF
Surface-enhanced Raman scattering study of bipyridyl-modified silver electrodes
Therese M. Cotton, Dwarakannath Kaddi, and Dan Iorga
pp 7462 - 7464; DOI:
10.1021/ja00363a054
PDF
Isotope effects as a mechanistic probe of unimolecular ion decompositions. tert-Butoxide anion
William Tumas, Robert F. Foster, Mark J. Pellerite, and John I. Brauman
pp 7464 - 7465; DOI:
10.1021/ja00363a055
PDF
Rose bengal and nonpolar derivatives
Joseph J. M. Lamberts and D. C. Neckers
pp 7465 - 7467; DOI:
10.1021/ja00363a056
PDF
On the stability of the polygonal Hn systems. Simple models of aromaticity and antiaromaticity
Hiroshi Ichikawa
pp 7467 - 7468; DOI:
10.1021/ja00363a057
PDF
Photochemistry of dibenzo-1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene and the germanium analog. Exclusive extrusion of the divalent species
Mitsuo Kira, Kenkichi Sakamoto, and Hideki Sakurai
pp 7469 - 7470; DOI:
10.1021/ja00363a058
PDF
A novel molybdenum-iron thiolato complex: octacarbonyltetrakis(.mu.-tert-butylthiolato)-molybdenum-iron complex (MoFe2(.mu.-tert-BuS)4(CO)8)
Shiwei Lu, Nobuyuki Okura, Toshikatsu Yoshida, Sei Otsuka, Ken Hirotsu, and Taiichi Higuchi
pp 7470 - 7471; DOI:
10.1021/ja00363a059
PDF
Nitrogen-15 spin exchange in a protein
T. A. Cross, M. H. Frey, and S. J. Opella
pp 7471 - 7473; DOI:
10.1021/ja00363a060
PDF
Poly[1-(trimethylsilyl)-1-propyne]: a new high polymer synthesized with transition-metal catalysts and characterized by extremely high gas permeability
Toshio Masuda, Eiji Isobe, Toshinobu Higashimura, and Koichi Takada
pp 7473 - 7474; DOI:
10.1021/ja00363a061
PDF
Additions and Corrections - Structure and Tunneling Dynamics of Malonaldehyde. A Theoretical Study.
Jozef Bicerano, Henry F. Schaefer III, and William H. Miller
pp 7474 - 7474; DOI:
10.1021/ja00363a601
PDF
Additions and Corrections - Migration of Tricarbonylchromium Groups in Phenylanthracenes.
Scott D. Cunningham, Karl Ofele, and Bennett R. Willeford
pp 7474 - 7475; DOI:
10.1021/ja00363a602
PDF
Additions and Corrections - Dynamics of Micellized Radical Pairs. Measurement of Micellar Exit Rates of Benzylic Radicals by Time-Resolved Flash CIDNP and Optical Spectroscopy.
Nicholas J. Turro, Matthew B. Zimmt, and Ian R. Gould
pp 7475 - 7475; DOI:
10.1021/ja00363a603
PDF
Book Reviews

pp 7475 - 7478; DOI:
10.1021/ja00363a600
PDF

Issue 26


Polarized nonvertical excited states: FORS MCSCF and CI study of torsion and bending in allene
Brenda Lam and Richard P. Johnson
pp 7479 - 7483; DOI:
10.1021/ja00364a001
PDF
Reactions of iron(1+) ion and (olefin)iron(1+) ion complexes with alkenes in the gas phase using Fourier transform mass spectrometry
D. B. Jacobson and B. S. Freiser
pp 7484 - 7491; DOI:
10.1021/ja00364a002
PDF
Reactions of Group 8 transition-metal ions (iron(1+), cobalt(1+), and nickel(1+)) with cyclic hydrocarbons in the gas phase
D. B. Jacobson and B. S. Freiser
pp 7492 - 7500; DOI:
10.1021/ja00364a003
PDF
Ab Initio Calculation of Resonance Energies. Benzene and Cyclobutadiene
B.A. Hess, Jr., and L.J. Schaad
pp 7500 - 7505; DOI:
10.1021/ja00364a600
PDF
Analytic energy second derivatives for two-configuration self-consistent-field wave functions. Application to twisted ethylene and to the trimethylene diradical
Yukio Yamaguchi, Yoshihiro Osamura, and Henry F. Schaefer
pp 7506 - 7511; DOI:
10.1021/ja00364a004
PDF
Absolute hardness: companion parameter to absolute electronegativity
Robert G. Parr and Ralph G. Pearson
pp 7512 - 7516; DOI:
10.1021/ja00364a005
PDF
ESR study of the electronic structure and dynamic Jahn-Teller effect in nickelocenium cation
M. V. Rajasekharan, R. Bucher, E. Deiss, L. Zoller, A. K. Salzer, E. Moser, J. Weber, and J. H. Ammeter
pp 7516 - 7522; DOI:
10.1021/ja00364a006
PDF
Carbon-13{deuteron} polarization transfer studies: new NMR methods for isotopic labeling studies
Peter L. Rinaldi and Nicholas J. Baldwin
pp 7523 - 7527; DOI:
10.1021/ja00364a007
PDF
Energy disposal in the photofragmentation of ketene
Blake I. Sonobe and Robert N. Rosenfeld
pp 7528 - 7530; DOI:
10.1021/ja00364a008
PDF
Photoionization study of hydrogen sulfide ((H2S)2 and (H2S)3)
H. F. Prest, W. B. Tzeng, J. M. Brom, and C. Y. Ng
pp 7531 - 7536; DOI:
10.1021/ja00364a009
PDF
Analysis of fully anisotropic overall molecular tumbling with group internal rotation: steroid examples
George C. Levy, Anil Kumar, and Dehua Wang
pp 7536 - 7540; DOI:
10.1021/ja00364a010
PDF
Mechanism for forming sodium pyrosulfate from sodium chloride, sulfur dioxide, and oxygen
Alfred B. Anderson and S. C. Hung
pp 7541 - 7543; DOI:
10.1021/ja00364a011
PDF
Theoretical study of the triple metal bond in d3-d3 binuclear complexes of chromium, molybdenum, tungsten by the Hartree-Fock-Slater transition state method
Tom Ziegler
pp 7543 - 7549; DOI:
10.1021/ja00364a012
PDF
Anion coordination chemistry. Chlorine-35 NMR studies of chloride anion cryptates
Jean Pierre Kintzinger, Jean Marie Lehn, Elizabeth Kauffmann, James L. Dye, and Alexander I. Popov
pp 7549 - 7553; DOI:
10.1021/ja00364a013
PDF
Origin of asymmetry in nitrogen hyperfine interactions in metmyoglobin
K. C. Mishra, Santosh K. Mishra, C. P. Scholes, and T. P. Das
pp 7553 - 7556; DOI:
10.1021/ja00364a014
PDF
Alterdentate ligands: determination of the energy barrier for intramolecular metal ion exchange in complexes of ninhydrin and alloxan radical ions with zinc(2+), magnesium(2+), cadmium(2+), and yttrium(3+)
C. Daul, E. Deiss, J. N. Gex, D. Perret, D. Schaller, and A. Von Zelewsky
pp 7556 - 7563; DOI:
10.1021/ja00364a015
PDF
Nuclear magnetic resonance and calorimetric studies on the solvation of cryptand C221 and its sodium(+) and potassium(+) ion complexes in nonaqueous solvents
Emmanuel Schmidt, Alexander I. Popov, Jean Pierre Kintzinger, and Jean-Michel Tremillon
pp 7563 - 7566; DOI:
10.1021/ja00364a016
PDF
Imidazole complexes of low-spin iron(III) porphyrin .pi.-cation radical species. Models for the compound I .pi.-cation radical state of peroxidases
Harold M. Goff and Martin A. Phillippi
pp 7567 - 7571; DOI:
10.1021/ja00364a017
PDF
Thermochemical splitting of sulfur dioxide with cerium(IV) oxide
E. J. Peterson, E. M. Foltyn, and E. I. Onstott
pp 7572 - 7573; DOI:
10.1021/ja00364a018
PDF
Synthesis of molybdenum-rhodium and molybdenum-iridium compounds linked by a heterodifunctional ligand and formation of molybdenum-iridium dihydrides by reaction with molecular hydrogen
Charles P. Casey, R. Morris Bullock, and Francois Nief
pp 7574 - 7580; DOI:
10.1021/ja00364a019
PDF
A reversible chemical reaction in a single crystal. The dimerization of .eta.5-cyclopentadienyl(o-dithiobenzene)cobalt [CpCo(S2C6H4-o)]
Edward J. Miller, Thomas B. Brill, Arnold L. Rheingold, and William C. Fultz
pp 7580 - 7584; DOI:
10.1021/ja00364a020
PDF
Symmetry of the magnetic orbitals and exchange interaction in copper iron (CuIIFeIII) and copper chromium (CuIICrIII) heterobinuclear complexes. Crystal structure of CuFe[(fsa)2en]Cl(H2O)(CH3OH).CH3OH
Yves Journaux, Olivier Kahn, Jacqueline Zarembowitch, Jean Galy, and Joel Jaud
pp 7585 - 7591; DOI:
10.1021/ja00364a021
PDF
Model studies of coenzyme B12 dependent diol dehydratase. 1. Synthetic, physical property, and product studies of two key, cobalt-bound, putative diol dehydratase intermediates
Richard G. Finke, William P. McKenna, David A. Schiraldi, Brad L. Smith, and Cortlandt Pierpont
pp 7592 - 7604; DOI:
10.1021/ja00364a022
PDF
Model studies of coenzyme B12 dependent diol dehydratase. 2. A kinetic and mechanistic study focusing upon the cobalt participation or nonparticipation question
Richard G. Finke and David A. Schiraldi
pp 7605 - 7617; DOI:
10.1021/ja00364a023
PDF
On the structure and stability of 1,3-dilithiopropanes and other .alpha.,.omega.-dilithioalkanes. The importance of lithium hydride complexes as structural alternatives and reaction intermediates
Paul v. R. Schleyer, Alexander J. Kos, and Elmar Kaufmann
pp 7617 - 7623; DOI:
10.1021/ja00364a024
PDF
Kinetics of the superoxide radical oxidation of [cobalt sepulchrate](2+) ion. A flash photolytic study
Andreja Bakac, James H. Espenson, Inge I. Creaser, and Alan M. Sargeson
pp 7624 - 7628; DOI:
10.1021/ja00364a025
PDF
Isotope effects on hydride transfer between NAD+ analogs
Drazen Ostovic, Roger M. G. Roberts, and Maurice M. Kreevoy
pp 7629 - 7631; DOI:
10.1021/ja00364a026
PDF
Energetics of twisting in the lowest stilbene triplet state
Jack Saltiel, Alan D. Rousseau, and Babu Thomas
pp 7631 - 7637; DOI:
10.1021/ja00364a027
PDF
Synthesis of sinefungin and its C-6' epimer
M. Geze, P. Blanchard, J. L. Fourrey, and M. Robert-Gero
pp 7638 - 7640; DOI:
10.1021/ja00364a028
PDF
Total synthesis of (.+-.)-elwesine, (.+-.)-epielwesine, and (.+-.)-oxocrinine
Ignacio H. Sanchez, Francisco J. Lopez, Jose J. Soria, Maria Isabel Larraza, and Humberto J. Flores
pp 7640 - 7643; DOI:
10.1021/ja00364a029
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Bond fixation in annulenes. 15. A titanium(0)-mediated synthesis of a cyclooctatetraene. Probe of the relative size of the interstitial phenyl substituent in 1,3-dimethyl-2-phenylcyclooctatetraene by means of racemization kinetics
Leo A. Paquette, John M. Gardlik, Kevin J. McCullough, and Yuji Hanzawa
pp 7644 - 7648; DOI:
10.1021/ja00364a030
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Bond fixation in annulenes. 16. Synthesis of the 1,2-dimethyl-3-phenylcyclooctatetraene .dblarw. 1,8-dimethyl-2-phenylcyclooctatetraene bond shift isomer pair. Probe of the relative size of a flanking phenyl substituent by means of racemization kinetics
Leo A. Paquette, John M. Gardlik, Kevin J. McCullough, Rodney Samodral, George DeLucca, and Robert J. Ouellette
pp 7649 - 7655; DOI:
10.1021/ja00364a031
PDF
Chemiluminescence mechanism of cyclic hydrazides such as luminol in aqueous solutions
J. Lind, G. Merenyi, and T. E. Eriksen
pp 7655 - 7661; DOI:
10.1021/ja00364a032
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A plausible mechanism for the chemiexcitation of cyclic hydrazides. The "double-crossing" model
S. Ljunggren, G. Merenyi, and J. Lind
pp 7662 - 7666; DOI:
10.1021/ja00364a033
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Carbon-14 kinetic isotope effects and mechanisms of addition of 2,4-dinitrobenzenesulfenyl chloride to substituted styrenes-1-14C and styrenes-2-14C
Marianna Kanska and Arthur Fry
pp 7666 - 7672; DOI:
10.1021/ja00364a034
PDF
Mechanisms of epoxidations and chlorinations of hydrocarbons by inorganic hypochlorite in the presence of a phase-transfer catalyst
Hossein E. Fonouni, S. Krishnan, David G. Kuhn, and Gordon A. Hamilton
pp 7672 - 7676; DOI:
10.1021/ja00364a035
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Pressure effect on tunneling of the proton- and deuteron-transfer reaction of 2,4,6-trinitrotoluene with 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile
Naoki Sugimoto, Muneo Sasaki, and Jiro Osugi
pp 7676 - 7680; DOI:
10.1021/ja00364a036
PDF
Gas-phase reactions. 36. Pyrolysis of vinyl azide
Hans Bock, Ralph Dammel, and Sitki Aygen
pp 7681 - 7685; DOI:
10.1021/ja00364a037
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Cyclobutane-bicyclobutane systems. 5. Zwitterionic bicyclobutane: an intermediate in the course of nucleophilic vinylic-like substitution reaction on 3-halobicyclobutanecarbonitrile
Shmaryahu Hoz and Doron Aurbach
pp 7685 - 7690; DOI:
10.1021/ja00364a038
PDF
Oxygenation by superoxide ion of tetrachloromethane, trichlorofluoromethane, trichloromethane, p,p'-DDT and related trichloromethyl substrates (RCCl3) in aprotic solvents
Julian L. Roberts, Thomas S. Calderwood, and Donald T. Sawyer
pp 7691 - 7696; DOI:
10.1021/ja00364a039
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Diels-Alder reactions of 1-azadienes
Yea Shun Cheng, Andrew T. Lupo, and Frank W. Fowler
pp 7696 - 7703; DOI:
10.1021/ja00364a040
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Heterocycles as masked diamide/dipeptide equivalents. Formation and reactions of substituted 5-(acylamino)oxazoles as intermediates en route to the cyclopeptide alkaloids
Bruce H. Lipshutz, Randall W. Hungate, and Keith E. McCarthy
pp 7703 - 7713; DOI:
10.1021/ja00364a041
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Camphorae: chiral intermediates for the enantiospecific total synthesis of steroids. 1
Robert V. Stevens, Fred C. A. Gaeta, and David S. Lawrence
pp 7713 - 7719; DOI:
10.1021/ja00364a042
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Studies on the synthesis of vitamin B-12. 3
Robert V. Stevens, Jun H. Chang, Richard Lapalme, Steven Schow, Markus G. Schlageter, Rafael Shapiro, and Harold N. Weller
pp 7719 - 7729; DOI:
10.1021/ja00364a043
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Electronic structure of ferricytochrome c and associated hyperfine interactions
K. C. Mishra, Santosh K. Mishra, and T. P. Das
pp 7729 - 7735; DOI:
10.1021/ja00364a044
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Antifungal peroxide-containing acids from two Caribbean sponges
Douglas W. Phillipson and Kenneth L. Rinehart
pp 7735 - 7736; DOI:
10.1021/ja00364a045
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Molecular and crystal structure of O4-methyluridine. Reaction coordinates for an incipient nucleophilic attack seen by short intermolecular sugar-base interactions
Richard G. Brennan, Gilbert G. Prive, Wayne J. P. Blonski, Frank E. Hruska, and Muttaiya Sundaralingam
pp 7737 - 7742; DOI:
10.1021/ja00364a046
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An examination of relaxation reagents for conformational analysis of peptides in aqueous solution
Kenneth D. Kopple and Peng Peng Zhu
pp 7742 - 7746; DOI:
10.1021/ja00364a047
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Hydrogen oxide bridging ligands in a classical coordination compound
Michael Ardon and Avi Bino
pp 7747 - 7748; DOI:
10.1021/ja00364a048
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Sequence-specific double-strand cleavage of DNA by bis(EDTA-distamycin.iron(II)) and EDTA-bis(distamycin).iron(II)
P. G. Schultz and P. B. Dervan
pp 7748 - 7750; DOI:
10.1021/ja00364a049
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Syntheses and x-ray crystal structures of two new transition metal complexes having diphosphene ligands in novel bonding modes
Kathy M. Flynn, Hakon Hope, Brendan D. Murray, Marilyn M. Olmstead, and Philip P. Power
pp 7750 - 7751; DOI:
10.1021/ja00364a050
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Reactivity of diphosphenes and phosphaarsenes toward metal carbonyls
A. H. Cowley, J. E. Kilduff, J. G. Lasch, N. C. Norman, M. Pakulski, F. Ando, and T. C. Wright
pp 7751 - 7752; DOI:
10.1021/ja00364a051
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Six-membered ring phosphites in twist conformations. The methyl and phenyl trans-3',5'-cyclic phosphites of thymidine
Keith A. Nelson, Alan E. Sopchik, and Wesley G. Bentrude
pp 7752 - 7754; DOI:
10.1021/ja00364a052
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Chiral 1,4-dihydropyridine equivalents: a new approach to the asymmetric synthesis of alkaloids. The enantiospecific synthesis of (+)- and (-)-coniine and dihydropinidine
Luc Guerrier, Jacques Royer, David S. Grierson, and Henri Philippe Husson
pp 7754 - 7755; DOI:
10.1021/ja00364a053
PDF
Oxidation of organic compounds by zinc permanganate
Saul Wolfe and Christopher F. Ingold
pp 7755 - 7757; DOI:
10.1021/ja00364a054
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Tungsten-catalyzed allylic alkylations. New avenues for selectivity
Barry M. Trost and Ming Hong Hung
pp 7757 - 7759; DOI:
10.1021/ja00364a055
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Cyclization of the N-butyl-5-methyl-1-hex-4-enaminyl radical and the use of N-lithio-N-butyl-5-methyl-1-hex-4-enamine as a mechanistic probe for electron-transfer processes
Martin Newcomb and Michael T. Burchill
pp 7759 - 7760; DOI:
10.1021/ja00364a056
PDF
Decamethyl[5]pericyclyne. A novel homoconjugated cyclic polyacetylene
L. T. Scott, G. J. DeCicco, J. L. Hyun, and G. Reinhardt
pp 7760 - 7761; DOI:
10.1021/ja00364a057
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Confirmation of the Mayo mechanism for the initiation of the thermal polymerization of styrene
Yen K. Chong, Ezio Rizzardo, and David H. Solomon
pp 7761 - 7762; DOI:
10.1021/ja00364a058
PDF
Experimental evidence for a high barrier to internal rotation in hexaisopropylbenzene
Jay Siegel and Kurt Mislow
pp 7763 - 7764; DOI:
10.1021/ja00364a059
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Photochemical and chemical reduction of vicinal dibromides via phase transfer of 4,4'-bipyridinium radical: the role of radical disproportionation
Zafrir Goren and Itamar Willner
pp 7764 - 7765; DOI:
10.1021/ja00364a060
PDF
Kinetics of long-distance ruthenium-to-copper electron transfer in [pentaammineruthenium histidine-83]azurin
Nenad M. Kostic, Ruth Margalit, Chi Ming Che, and Harry B. Gray
pp 7765 - 7767; DOI:
10.1021/ja00364a061
PDF
Stereochemistry of oxidative addition of an optically active allyl acetate to a palladium(0) complex
Tamio Hayashi, Toshiya Hagihara, Mitsuo Konishi, and Makoto Kumada
pp 7767 - 7768; DOI:
10.1021/ja00364a062
PDF
Low-temperature photochemistry of (.eta.5-C5R5)W(CO)3CH2SiMe2H: loss of carbon monoxide followed by .beta.-hydrogen transfer
Claudia Lewis and Mark S. Wrighton
pp 7768 - 7770; DOI:
10.1021/ja00364a063
PDF
Mechanistic investigation of olefin insertion into the rhodium-hydrogen bond
D. Christopher Roe
pp 7770 - 7771; DOI:
10.1021/ja00364a064
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A new model for the study of multistep electron transfer in photosynthesis
Shinji Nishitani, Nobuyuki Kurata, Yoshiteru Sakata, Soichi Misumi, Akiya Karen, Tadashi Okada, and Noboru Mataga
pp 7771 - 7772; DOI:
10.1021/ja00364a065
PDF
Stereoselectivity and kinetic control of hydrogen oxidative addition to iridium(I) complexes
Curtis E. Johnson, Barbara J. Fisher, and Richard Eisenberg
pp 7772 - 7774; DOI:
10.1021/ja00364a066
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Cleavage of carbon monoxide by mononuclear zirconium dialkyls: formation of a (.mu.-oxo)dialkyl and an enolate
Roy P. Planalp and Richard A. Andersen
pp 7774 - 7775; DOI:
10.1021/ja00364a067
PDF
Photoisomerization of trimesitylvinyl alcohol. Indirect evidence for the keto form
Harold Hart and Raymond J. Giguere
pp 7775 - 7776; DOI:
10.1021/ja00364a068
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1,1,2,2-Tetrakis(2,6-dimethylphenyl)-1,2-disilacyclopropane
Satoru Masamune, Shu Murakami, Hiromi Tobita, and David J. Williams
pp 7776 - 7778; DOI:
10.1021/ja00364a069
PDF
Crystal structure of 1,3,5-triphenyl-2,4,6-trithia-1,3,5-tristannaadamantane
Andre L. Beauchamp, Stephan Latour, Marc J. Olivier, and James D. Wuest
pp 7778 - 7780; DOI:
10.1021/ja00364a070
PDF
Cooperativity in oxygen binding to Lingula reevii hemerythrin: spectroscopic comparison to the sipunculid hemerythrin coupled binuclear iron active site
David E. Richardson, Richard C. Reem, and Edward I. Solomon
pp 7780 - 7781; DOI:
10.1021/ja00364a071
PDF
Iron-histidine stretching Raman lines of the aa3-type cytochrome oxidases
Takashi Ogura, Koyu Honnami, Tairo Oshima, Shinya Yoshikawa, and Teizo Kitagawa
pp 7781 - 7783; DOI:
10.1021/ja00364a072
PDF
Facile syntheses of bridge-oxygen-labeled pyrophosphates: The preparation of adenosine 5'-[.beta..gamma.-18O]triphosphate
Paul M. Cullis
pp 7783 - 7784; DOI:
10.1021/ja00364a073
PDF
Soluble metal sulfides. Synthesis and structures of [M6S17]4- (M = niobium or tantalum): icosahedral-fragment cages containing four types of coordinated sulfide
Joan Sola, Youngkyu Do, Jeremy M. Berg, and R. H. Holm
pp 7784 - 7786; DOI:
10.1021/ja00364a074
PDF
Photochemical Wolff rearrangement of a triplet ground state carbene
Richard A. Hayes, Thomas C. Hess, Robert J. McMahon, and Orville L. Chapman
pp 7786 - 7787; DOI:
10.1021/ja00364a075
PDF
Mechanism of Ziegler-Natta polymerization of acetylene: a nutation NMR study
T. C. Clarke, C. S. Yannoni, and T. J. Katz
pp 7787 - 7789; DOI:
10.1021/ja00364a076
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Tungsten vinylidenes and carbynes from terminal alkyne reagents
K. R. Birdwhistell, S. J. Nieter Burgmayer, and J. L. Templeton
pp 7789 - 7790; DOI:
10.1021/ja00364a077
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Ortho lithiation of monosubstituted benzenes: a quantitative determination of pKa values in tetrahydrofuran
Robert R. Fraser, Monique Bresse, and Tarek S. Mansour
pp 7790 - 7791; DOI:
10.1021/ja00364a078
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Pyridinium salts structurally related to NAD(P)+ as enolate transferring agents
Sabir H. Mashraqui and Richard M. Kellogg
pp 7792 - 7793; DOI:
10.1021/ja00364a079
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Additions and Corrections - Selectivities of π -and σ-Succinimidyl Radicals in Substitution and Addition Reactions. Appendix: Response to Walling, El-Taliawi, and Zhao.
P. S. Skell, R. L. Tlumak, and S. Seshadri
pp 7793 - 7793; DOI:
10.1021/ja00364a601
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Book Reviews

pp 7793 - 7800; DOI:
10.1021/ja00364a602
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