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Volume 110
Main Index

Issue 1


Kinetic energy release distributions as a probe of transition-metal-mediated hydrogen-hydrogen, carbon-hydrogen, and carbon-carbon bond formation processes: reactions of cobalt and nickel ions with alkanes
Maureen A. Hanratty, J. L. Beauchamp, Andreas J. Illies, Petra Van Koppen, and M. T. Bowers
pp 1 - 14; DOI:
10.1021/ja00209a001
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Hydrocarbon activation by gas-phase lanthanide cations: interaction of praseodymium (Pr+), europium (Eu+), and gadolinium (Gd+) with small alkanes, cycloalkanes, and alkenes
J. Bruce Schilling and J. L. Beauchamp
pp 15 - 24; DOI:
10.1021/ja00209a002
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Thermochemistry of silaethylene and methylsilylene from experiment and theory
Seung Koo Shin, Karl K. Irikura, J. L. Beauchamp, and William A. Goddard
pp 24 - 30; DOI:
10.1021/ja00209a003
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Experimental determination of internal energy barriers in the gas-phase aromatic alkylation by dimethylchloronium ions
Maurizio Speranza and Giuseppe Laguzzi
pp 30 - 34; DOI:
10.1021/ja00209a004
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Gas-phase acid-induced nucleophilic displacement reactions. 7. Structural and stereochemical evidence for the existence and the relative stability of alkylenebenzenium ions in the gas phase
Simonetta Fornarini, Cinzia Sparapani, and Maurizio Speranza
pp 34 - 41; DOI:
10.1021/ja00209a005
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Gas-phase acid-induced nucleophilic displacement reactions. 8. Structural analysis of intermediate ions formed by the decomposition of .beta.-arylethyl onium ions
Simonetta Fornarini, Cinzia Sparapani, and Maurizio Speranza
pp 42 - 46; DOI:
10.1021/ja00209a006
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Effects of chemical environment on direct recoil ion fractions
J. N. Chen and J. W. Rabalais
pp 46 - 52; DOI:
10.1021/ja00209a007
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Interaction of formamide with the Ru(001) surface
J. E. Parmeter, U. Schwalke, and W. H. Weinberg
pp 53 - 62; DOI:
10.1021/ja00209a008
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Resonance Raman spectroscopic study of bilirubin hydrogen bonding in solutions and in the albumin complex
You Zung Hsieh and Michael D. Morris
pp 62 - 67; DOI:
10.1021/ja00209a009
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Manganese(I)-induced 1,6-demethanation across the carbon-carbon triple bond of linear alkynes in the gas phase. A case for the generation of manganese cycloalkynes?
Christian Schulze and Helmut Schwarz
pp 67 - 70; DOI:
10.1021/ja00209a010
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Chemisorption on size-selected metal clusters: activation barriers and chemical reactions for deuterium on aluminum cluster ions
Martin F. Jarrold and J. Eric Bower
pp 70 - 78; DOI:
10.1021/ja00209a011
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Ab initio structures of phosphorus acids and esters. 3. The phosphorus-oxygen-phosphorus bridged phosphinic compounds H4P2O2n-1 for n = 1 to 4
Carl S. Ewig and John R. Van Wazer
pp 79 - 86; DOI:
10.1021/ja00209a012
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Effect of cavity size on the charge distribution in carbido-metal carbonyl clusters and its possible catalytic implications
Jean Francois Halet, David G. Evans, and D. Michael P. Mingos
pp 87 - 90; DOI:
10.1021/ja00209a013
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Ab initio calculation of Broensted acidities
Michele R. F. Siggel, T. Darrah Thomas, and Leif J. Saethre
pp 91 - 96; DOI:
10.1021/ja00209a014
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Valency correlation diagrams
Prabha Siddarth and M. S. Gopinathan
pp 96 - 104; DOI:
10.1021/ja00209a015
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Band electronic structure study of the semimetallic properties and the anisotropic resistivity hump in zirconium tritelluride
Enric Canadell, Yves Mathey, and Myung Hwan Whangbo
pp 104 - 108; DOI:
10.1021/ja00209a016
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Silicon-carbon agostic interaction with titanium: origin of alkenyl group distortion in Ti[C(SiH2CH3):CH2]X2+. An ab initio MO study
Nobuaki Koga and Keiji Morokuma
pp 108 - 112; DOI:
10.1021/ja00209a017
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Environmental control of product states in the chemiluminescent electron transfer between rubrene radical ions
Joon Kim and Larry R. Faulkner
pp 112 - 119; DOI:
10.1021/ja00209a018
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Contrasting one- and two-cation binding behavior in syn- and anti-anthraquinone bibracchial podand (BiP) mono- and dianions assessed by cyclic voltammetry and electron paramagnetic resonance spectroscopy
Milagros Delgado, Deborah A. Gustowski, Hyunsook K. Yoo, Vincent J. Gatto, George W. Gokel, and Luis Echegoyen
pp 119 - 124; DOI:
10.1021/ja00209a019
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Structure and bonding in L2M(.mu.-CCR)2ML2 and L2M(.mu.-RC4R)ML2 (L2M = Cp2Zr, Cp2Ti, R2Al, R(NR3)Be, (tmpda)Li, H2B, and H2C+). A molecular orbital study
P. N. V. Pavan Kumar and Eluvathingal D. Jemmis
pp 125 - 131; DOI:
10.1021/ja00209a020
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Oxidation and reduction potentials of transient free radicals
D. D. M. Wayner, D. J. McPhee, and D. Griller
pp 132 - 137; DOI:
10.1021/ja00209a021
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Steric versus electronic effects on the tilt of the cyclopentadienyl rings in adducts of manganese dicyclopentadienide. Molecular and electronic structure of dicyclopentadienide manganese tetrahydrofuran
Frank Bottomley, Petra N. Keizer, and Peter S. White
pp 137 - 140; DOI:
10.1021/ja00209a022
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Synthetic, structural, and theoretical studies on the electron-deficient cubanes (RC5H4)4Ti4S4, (RC5H4)4V4S4, and [(RC5H4)4V4S4]+.
James Darkwa, John R. Lockemeyer, Peter D. W. Boyd, Thomas B. Rauchfuss, and Arnold L. Rheingold
pp 141 - 149; DOI:
10.1021/ja00209a023
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Homogeneous catalysis of mixed-metal systems. Highly regioselective hydroformylation-amidocarbonylation of a fluoro olefin catalyzed by cobalt-rhodium mixed-metal systems. Observation of CoRh(CO)7 catalysis
Iwao Ojima, Masami Okabe, Koji Kato, Hyok Boong Kwon, and Istvan T. Horvath
pp 150 - 157; DOI:
10.1021/ja00209a024
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Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 1. cis-Stilbene as a mechanistic probe
Angelo J. Castellino and Thomas C. Bruice
pp 158 - 162; DOI:
10.1021/ja00209a025
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Highly reduced organometallics. 20. The first general synthetic route to zerovalent titanium carbonyls; synthesis and properties of Ti(CO)5(Me2PCH2CH2PMe2)
Kai Ming Chi, Scott R. Frerichs, Beatrice Kelsey Stein, David W. Blackburn, and John E. Ellis
pp 163 - 171; DOI:
10.1021/ja00209a026
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Palladium(II) cage compounds based on diphenylglycoluril
Frank G. M. Niele and Roeland J. M. Nolte
pp 172 - 177; DOI:
10.1021/ja00209a027
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Selective molecular oxygen oxidation of thio ethers to sulfoxides catalyzed by cerium(IV)
Dennis P. Riley, M. R. Smith, and P. E. Correa
pp 177 - 180; DOI:
10.1021/ja00209a028
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Rates and mechanisms of hydrolysis of esters of phosphorous acid
F. H. Westheimer, Shaw Huang, and Frank Covitz
pp 181 - 185; DOI:
10.1021/ja00209a029
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Thin-layer phase-transfer catalysis in the reaction of alkyl chlorides and a solid formate salt
Onn Arrad and Yoel Sasson
pp 185 - 189; DOI:
10.1021/ja00209a030
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Regioselective trans-cis photoisomerization of m-styrylstilbenes
Yoshikatsu Ito, Yoshihiro Uozu, Toshimichi Dote, Masahiro Ueda, and Teruo Matsuura
pp 189 - 198; DOI:
10.1021/ja00209a031
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Intramolecular end-to-end reactions of photoactive terminal groups linked by polymethylene chains
Kazuo Ashikaga, Shinzaburo Ito, Masahide Yamamoto, and Yasunori Nishijima
pp 198 - 204; DOI:
10.1021/ja00209a032
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Binding sites of pyrene and related compounds and chiral excimer formation in the cavities of cyclodextrins and branched cyclodextrins
Koji Kano, Hitoshi Matsumoto, Yoshimichi Yoshimura, and Shizunobu Hashimoto
pp 204 - 209; DOI:
10.1021/ja00209a033
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Reaction of dicarbomethoxycarbene with acetaldehyde and simple ketones
Robert P. L'Esperance, Thomas M. Ford, and Maitland Jones
pp 209 - 213; DOI:
10.1021/ja00209a034
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Chemistry of hydrotrioxides. Preparation, characterization, and thermal decomposition of hydrotrioxides of alkyl .alpha.-methylbenzyl ethers and .alpha.-methylbenzyl alcohol. Attempted spin trapping of trioxyl radicals
Bozo Plesnicar, Franci Kovac, and Milan Schara
pp 214 - 222; DOI:
10.1021/ja00209a035
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Cobalt(III) complex promoted hydrolysis of phosphate diesters: change in rate-determining step with change in phosphate diester reactivity
Jik Chin and Xiang Zou
pp 223 - 225; DOI:
10.1021/ja00209a036
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Crystal structure of 1,2-diphenyl-3-nitrocyclopropene and ab initio calculations of 3-nitrocyclopropene
Clair J. Cheer, David Bernstein, Arthur Greenberg, and Ping Chiang Lyu
pp 226 - 230; DOI:
10.1021/ja00209a037
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An experimental and computational study of the formation of (.pi.-allyl) palladium complexes from olefins and palladium(II) salts
Douglas R. Chrisope, Peter Beak, and William H. Saunders
pp 230 - 238; DOI:
10.1021/ja00209a038
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Hydrogen bonding to the proximal imidazole in heme protein model compounds: effects upon oxygen binding and peroxidase activity
Teddy G. Traylor and Ronit Popovitz-Biro
pp 239 - 243; DOI:
10.1021/ja00209a039
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Photoreactivation of irreversibly inhibited serine proteinases
A. Denise Turner, S. V. Pizzo, George Rozakis, and Ned A. Porter
pp 244 - 250; DOI:
10.1021/ja00209a040
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Variable photon energy photoelectron spectroscopic studies of copper chlorides: an experimental probe of metal-ligand bonding and changes in electronic structure on ionization
Stephen V. Didziulis, Susan L. Cohen, Andrew A. Gewirth, and Edward I. Solomon
pp 250 - 268; DOI:
10.1021/ja00209a041
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Catalysis of the bromination of phenols and phenoxide ions in aqueous solution by .alpha.-cyclodextrin
Oswald S. Tee and Janice M. Bennett
pp 269 - 274; DOI:
10.1021/ja00209a042
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Hydrogenolysis and homologation of linear and branched pentenes on ruthenium/silica catalysts: implication in the mechanism of carbon-carbon bond formation and cleavage on metal surfaces
Eloy Rodriguez, Michel Leconte, Jean Marie Basset, Katsumi Tanaka, and Kenichi Tanaka
pp 275 - 278; DOI:
10.1021/ja00209a043
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Asymmetric synthesis with chiral .beta.-lactams. .alpha.-Substituted aromatic .alpha.-amino acids and their derivatives through highly stereoselective alkylations
Iwao Ojima, Hauh Jyun C. Chen, and Kazuaki Nakahashi
pp 278 - 281; DOI:
10.1021/ja00209a044
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Absolute rate constants for some intermolecular and intramolecular reactions of .alpha.-, .beta.-, and .gamma.-silicon-substituted radicals
James W. Wilt, J. Lusztyk, Mehoob Peeran, and K. U. Ingold
pp 281 - 287; DOI:
10.1021/ja00209a045
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Metalization of lipid vesicles via electroless plating
W. T. Ferrar, D. F. O'Brien, A. Warshawsky, and C. L. Voycheck
pp 288 - 289; DOI:
10.1021/ja00209a046
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Extremely short chiral synthesis of bicyclic alkaloids having a nitrogen atom ring juncture
Yoshimitsu Nagao, Wei Min Dai, Masahito Ochiai, Shigeru Tsukagoshi, and Eiichi Fujita
pp 289 - 291; DOI:
10.1021/ja00209a047
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Selective hydride-mediated conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds using [(Ph3P)CuH]6
Wayne S. Mahoney, Donna M. Brestensky, and Jeffrey M. Stryker
pp 291 - 293; DOI:
10.1021/ja00209a048
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Condensed-phase-facilitated transport of olefins through an ion-exchange membrane
Carl A. Koval and Terry Spontarelli
pp 293 - 295; DOI:
10.1021/ja00209a049
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Novel diamagnetic and paramagnetic hydrides of vanadium(II)
Bart Hessen, Fre Van Bolhuis, Jan H. Teuben, and Jeffrey L. Petersen
pp 295 - 296; DOI:
10.1021/ja00209a050
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Stereochemistry of the thermal isomerization of bicyclo[3.2.0]hept-2-ene to bicyclo[2.2.1]hept-2-ene
John E. Baldwin and Kevin D. Belfield
pp 296 - 297; DOI:
10.1021/ja00209a051
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Stereochemistry of the thermal rearrangement of bicyclo[3.2.0]hept-2-ene to bicyclo[2.2.1]hept-2-ene (norbornene). [1,3] Carbon migration with predominant inversion
Frank Gerrit Klaerner, Rolf Drewes, and Dieter Hasselmann
pp 297 - 298; DOI:
10.1021/ja00209a052
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Synthesis by spontaneous self-assembly of metal atom clusters of zirconium, niobium, and tantalum
F. Albert Cotton, Piotr A. Kibala, and Wieslaw J. Roth
pp 298 - 300; DOI:
10.1021/ja00209a053
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The ab initio energy difference favoring the nonclassical over the classical structure of the bicyclo[2.1.1]hexyl cation. Comparison of calculated (IGLO) and experimental 13C chemical shifts
Paul v. R. Schleyer, Keith Laidig, Kenneth B. Wiberg, Martin Saunders, and Michael Schindler
pp 300 - 301; DOI:
10.1021/ja00209a054
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Photoactivable fluorophores. 3. Synthesis and photoactivation of fluorogenic difunctionalized fluoresceins
Grant A. Krafft, W. Randall Sutton, and Richard T. Cummings
pp 301 - 303; DOI:
10.1021/ja00209a055
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Highly reduced organometallics. 23. Synthesis, isolation, and characterization of hexacarbonyltitanate(2-), (Ti(CO)62-). Titanium NMR spectra of carbonyltitanates
Kai Ming Chi, Scott R. Frerichs, Stephen B. Philson, and John E. Ellis
pp 303 - 304; DOI:
10.1021/ja00209a056
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Entrapment of an anionic, stable, moisture-resistant oxygen carrier in zeolite Y
Russell S. Drago, Iwona Bresinska, James E. George, Kenneth Balkus, and Robert J. Taylor
pp 304 - 305; DOI:
10.1021/ja00209a057
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Carlons. Organic oligomers from condensation of carbon dinucleophiles with difunctional derivatives of carboxylic acids
Lawrence B. Kool and George M. Whitesides
pp 306 - 307; DOI:
10.1021/ja00209a058
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Insertion reactions of chromium carbene complexes with organic nitriles and a diastereoselective alkylation of a resulting imino carbene complex
Dominic C. Yang, Vera Dragisich, William D. Wulff, and John C. Huffman
pp 307 - 309; DOI:
10.1021/ja00209a059
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Boron-11 nuclear magnetic resonance studies of the structure of the transition-state analog phenylboronic acid bound to chymotrypsin
Foluso Adebodun and Frank Jordan
pp 309 - 310; DOI:
10.1021/ja00209a060
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Asymmetric hetero-Diels-Alder reaction catalyzed by a chiral organoaluminum reagent
Keiji Maruoka, Takayuki Itoh, Tadashi Shirasaka, and Hisashi Yamamoto
pp 310 - 312; DOI:
10.1021/ja00209a061
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A potent new class of active-site-directed glycosidase inactivators
Michael K. Tong and Bruce Ganem
pp 312 - 313; DOI:
10.1021/ja00209a062
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Preparation of the first stable formylsilane, (Me3Si)3SiCHO, from a zirconium .eta.2-silaacyl complex
Frederick H. Elsner, Hee Gweon Woo, and T. Don Tilley
pp 313 - 314; DOI:
10.1021/ja00209a063
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Palladium-mediated biomimetic synthesis of narwedine
Robert A. Holton, Mukund P. Sibi, and William S. Murphy
pp 314 - 316; DOI:
10.1021/ja00209a064
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Comparison of stereochemistry of fatty acid and cladosporin biosynthesis in Cladosporium cladosporioides using deuterium-decoupled proton, carbon-13 NMR shift correlation
Paul B. Reese, Bernard J. Rawlings, Shawn E. Ramer, and John C. Vederas
pp 316 - 318; DOI:
10.1021/ja00209a065
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Stereochemical features of enoyl thiol ester reductase in averufin and fatty acid biosynthesis in Aspergillus parasiticus
Craig A. Townsend, Susan W. Brobst, Shawn E. Ramer, and John C. Vederas
pp 318 - 319; DOI:
10.1021/ja00209a066
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Tl2Pt(CN)4: a non-columnar, luminescent form of Pt(CN)42- containing platinum-thallium bonds
Jeffrey K. Nagle, Alan L. Balch, and Marilyn M. Olmstead
pp 319 - 321; DOI:
10.1021/ja00209a067
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Photoinitiated charge separation in a carotenoid-porphyrin-diquinone tetrad: enhanced quantum yields via multistep electron transfers
Devens Gust, Thomas A. Moore, Ana L. Moore, Donna Barrett, Larry O. Harding, Lewis R. Makings, Paul A. Liddell, F. C. De Schryver, M. Van der Auweraer, and et al.
pp 321 - 323; DOI:
10.1021/ja00209a068
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Evidence for the generation of .alpha.-carboxy-.alpha.-hydroxy-p-xylylene from p-(bromomethyl)mandelate by mandelate racemase
David T. Lin, Vincent M. Powers, Laure J. Reynolds, Christian P. Whitman, John W. Kozarich, and George L. Kenyon
pp 323 - 324; DOI:
10.1021/ja00209a069
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Computer Software Reviews

pp 324 - 325; DOI:
10.1021/ja00209a600
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Book Reviews

pp 325 - 326; DOI:
10.1021/ja00209a601
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Issue 2


High resolution ESR spectroscopy and structure of the acetaldehyde radical cation (CH3CHO+) in neon matrices at 4 K: comparison with results in freon matrices
Lon B. Knight, B. W. Gregory, S. T. Cobranchi, Ffrancon Williams, and Xue Zhi Qin
pp 327 - 336; DOI:
10.1021/ja00210a001
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High-resolution solid-state carbon-13 NMR spectra of porphine and 5,10,15-20-tetraalkylporphyrins: implications for the nitrogen-hydrogen tautomerization process
Lucio Frydman, Alejandro C. Olivieri, Luis E. Diaz, Benjamin Frydman, Frederick G. Morin, Charles L. Mayne, David M. Grant, and Alan D. Adler
pp 336 - 342; DOI:
10.1021/ja00210a002
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Karplus-type relationship for quadrupole coupling constants and asymmetry parameters for substituted acetic acids
Margo A. Jackisch, William L. Jarrett, Kermin Guo, Frank R. Fronczek, and Leslie G. Butler
pp 343 - 347; DOI:
10.1021/ja00210a003
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Dynamics of molecular hydrogen elimination from the methaniminium cation, [CH2NH2]+. Isotope effects, translational-energy release, and molecular-orbital calculations
Kevin F. Donchi, Bruce A. Rumpf, Gary D. Willett, John R. Christie, and Peter J. Derrick
pp 347 - 352; DOI:
10.1021/ja00210a004
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Structure and bonding in cycloalkanes and monosilacycloalkanes
Jerry A. Boatz, Mark S. Gordon, and Richard L. Hilderbrandt
pp 352 - 358; DOI:
10.1021/ja00210a005
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Band electronic structure of the lithium molybdenum purple bronze Li0.9Mo6O17
Myung Hwan Whangbo and Enric Canadell
pp 358 - 363; DOI:
10.1021/ja00210a006
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An ab initio study of diazoethene, a propadienone isoelectronic with a bent structure
Mark A. Murcko, Steven K. Pollack, and Paul M. Lahti
pp 364 - 368; DOI:
10.1021/ja00210a007
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Transferability of natural bond orbitals
J. E. Carpenter and Frank Weinhold
pp 368 - 372; DOI:
10.1021/ja00210a008
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Pseudopotential calculations on alkali silicide clusters with Si2 and tetrahedral Si4 backbones
A. Savin, K. Vogel, H. Preuss, H. Stoll, R. Nesper, and H. G. Von Schnering
pp 373 - 375; DOI:
10.1021/ja00210a009
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Characterization of the temporary anion states of metal carbonyl complexes: an MS-X.alpha. and ETS study of chromium hexacarbonyl and iron pentacarbonyl
Maurizio Guerra, Derek Jones, Giuseppe Distefano, Antonio Foffani, and Alberto Modelli
pp 375 - 379; DOI:
10.1021/ja00210a010
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Picosecond and nanosecond geminate recombination of myoglobin with carbon monoxide, oxygen, nitric oxide and isocyanides
Karen A. Jongeward, Douglas Magde, Douglas J. Taube, James C. Marsters, Teddy G. Traylor, and Vijay S. Sharma
pp 380 - 387; DOI:
10.1021/ja00210a011
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Gas-phase reactions of LaFe+ with alkanes
Yongqing Huang and Ben S. Freiser
pp 387 - 392; DOI:
10.1021/ja00210a012
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Interaction of adenosine 5'-triphosphate with Mg2+: vibrational study of coordination sites by use of 18O-labeled triphosphates
Hideo Takeuchi, Hiroshi Murata, and Issei Harada
pp 392 - 397; DOI:
10.1021/ja00210a013
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Active oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100)
Scott W. Jorgensen and Robert J. Madix
pp 397 - 400; DOI:
10.1021/ja00210a014
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Electron affinities of benzo-, naphtho-, and anthraquinones determined from gas-phase equilibria measurements
Thomas Heinis, Swapan Chowdhury, Susannah L. Scott, and Paul Kebarle
pp 400 - 407; DOI:
10.1021/ja00210a015
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Fluorescence-free scanning Raman spectroscopy
Donivan R. Porterfield and Alan Campion
pp 408 - 410; DOI:
10.1021/ja00210a016
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Electronic effects in C-H and C-C bond activation. State-specific reactions of FE+ (6D,4F) with methane, ethane, and propane
Richard H. Schultz, J. L. Elkind, and P. B. Armentrout
pp 411 - 423; DOI:
10.1021/ja00210a017
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Neutral square planar cobalt(III) complexes
John C. Brewer, Terrence J. Collins, Milton R. Smith, and Bernard D. Santarsiero
pp 423 - 428; DOI:
10.1021/ja00210a018
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Electron-transfer kinetics of zinc-substituted cytochrome c and its Ru(NH3)5(histidine-33) derivative
Horst Elias, Mei H. Chou, and Jay R. Winkler
pp 429 - 434; DOI:
10.1021/ja00210a019
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Distance dependence of photoinduced long-range electron transfer in zinc/ruthenium-modified myoglobins
Andrew W. Axup, Michael Albin, Stephen L. Mayo, Robert J. Crutchley, and Harry B. Gray
pp 435 - 439; DOI:
10.1021/ja00210a020
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Organolanthanide and organoyttrium hydride chemistry. 10. Reactivity of trimetallic organoyttrium hydride complexes. Synthesis of the alkoxy hydride anions [[(C5H5)2Y(.mu.-H)]x[(C5H5)2Y(.mu.-OCH3)]3-x(.mu.3-H)]- (x = 0-2), including the x-ray crystal structure of [[(C5H5)2Y(.mu.-OCH3)]3(.mu.3-H)]2[Li(THF)3]2
William J. Evans, Mark S. Sollberger, Saeed I. Khan, and Robert Bau
pp 439 - 446; DOI:
10.1021/ja00210a021
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Synthesis and spectroscopic and structural characterization of the novel lithium borylamide salts trans-[Li(Et2O)NHBMes2]2, a dimer, and the ion pair [Li(Et2O)3][Mes2BNBMes2] with a linear allene-like, [R2B = N = BR2]+ moiety
Ruth A. Bartlett, Hong Chen, H. V. Rasika Dias, Marilyn M. Olmstead, and Philip P. Power
pp 446 - 449; DOI:
10.1021/ja00210a022
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Transition-metal-promoted reactions of boron hydrides. 9. Cp*Ir-catalyzed reactions of polyhedral boranes and acetylenes
Mario G. L. Mirabelli and Larry G. Sneddon
pp 449 - 453; DOI:
10.1021/ja00210a023
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Oxidative additions and luminescence involving iridium-gold-iridium chains formed by binding of gold(I) to the metallamacrocycle Ir2Cl2(CO)2[.mu.-Ph2PCH2As(Ph)CH2PPh2]2
Alan L. Balch, Jeffrey K. Nagle, Douglas E. Oram, and Philip E. Reedy
pp 454 - 462; DOI:
10.1021/ja00210a024
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Arene synthesis by extrusion reaction. 12 Chemistry of dibenzo[2.2]paracyclophane and its related compounds. Evidence for the existence of a cyclophyne intermediate
Chin Wing Chan and Henry N. C. Wong
pp 462 - 469; DOI:
10.1021/ja00210a025
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Chemistry of F1,F0-ATPase inhibitors. Stereoselective total syntheses of (+)-citreoviral and (-)-citreoviridin
Hongsuk Suh and Craig S. Wilcox
pp 470 - 481; DOI:
10.1021/ja00210a026
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Asymmetric synthesis of .beta.-carboxyaspartic acid
Robert M. Williams, Peter J. Sinclair, and Weixu Zhai
pp 482 - 483; DOI:
10.1021/ja00210a027
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Asymmetric synthesis based on 1,3-oxathianes. 4. Mechanism of asymmetric induction in the reactions of oxathianyl ketones
Stephen V. Frye and Ernest L. Eliel
pp 484 - 489; DOI:
10.1021/ja00210a028
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Amphidinolide C: the first twenty-five membered macrocyclic lactone with potent antineoplastic activity from the cultured dinoflagellate Amphidinium sp
Junichi Kobayashi, Masami Ishibashi, Markus R. Walchli, Hideshi Nakamura, Yoshimasa Hirata, Takuma Sasaki, and Yasushi Ohizumi
pp 490 - 494; DOI:
10.1021/ja00210a029
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Reaction of singlet oxygen with thiirane: a peroxysulfenic acid intermediate as a new oxidizing species
Takeshi Akasaka, Masahiro Kako, Hideki Sonobe, and Wataru Ando
pp 494 - 496; DOI:
10.1021/ja00210a030
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Forfeiture of the aromaticity of a bridged [10]annulene by benzannelation
Richard K. Hill, Carolyn B. Giberson, and James V. Silverton
pp 497 - 500; DOI:
10.1021/ja00210a031
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Rearrangements of the isomeric tolylmethylenes
Orville L. Chapman, Jeffery W. Johnson, Robert J. McMahon, and Paul R. West
pp 501 - 509; DOI:
10.1021/ja00210a032
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Photochromism of salicylideneanilines incorporated in a Langmuir-Blodgett multilayer
Shinichi Kawamura, Tetsuo Tsutsui, Shogo Saito, Yuko Murao, and Kenyu Kina
pp 509 - 511; DOI:
10.1021/ja00210a033
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Use of a photoreversible fulgide as an actinometer in one- and two-laser experiments
Veronique Wintgens, Linda J. Johnston, and J. C. Scaiano
pp 511 - 517; DOI:
10.1021/ja00210a034
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Photochemistry of diphenylketyl radicals: spectroscopy, kinetics, and mechanisms
Linda J. Johnston, D. J. Lougnot, Veronique Wintgens, and J. C. Scaiano
pp 518 - 524; DOI:
10.1021/ja00210a035
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Structure sensitivity of the Marcus .lambda. for hydride transfer between NAD+ analogs
Maurice M. Kreevoy, Drazen Ostovic, In Sook Han Lee, David A. Binder, and Gary W. King
pp 524 - 530; DOI:
10.1021/ja00210a036
PDF
Molecular design of the electron-donating sidearm of lariat ethers: effective coordination of the quinoline moiety in complexation toward alkali-metal cations
Yohji Nakatsuji, Tetsuya Nakamura, Masayuki Yonetani, Hajime Yuya, and Mitsuo Okahara
pp 531 - 538; DOI:
10.1021/ja00210a037
PDF
Spectroscopic characterization of triplet 4,5-benzocycloheptatrienylidene
John E. Chateauneuf, Keith A. Horn, and Thomas G. Savino
pp 539 - 545; DOI:
10.1021/ja00210a038
PDF
Reversibility of bromonium ion formation and its effect on olefin reactivity in electrophilic bromination. New evidence from the 5H-dibenz[b,f]azepine system
Giuseppe Bellucci, Roberto Bianchini, Cinzia Chiappe, Franco Marioni, and Riccardo Spagna
pp 546 - 552; DOI:
10.1021/ja00210a039
PDF
Rapid, multistep rearrangements of hydrocarbon triplet biradicals at 4 K. A possible example of hot molecule effects in frozen organic solvents
Rakesh Jain, Lisa McElwee-White, and Dennis A. Dougherty
pp 552 - 560; DOI:
10.1021/ja00210a040
PDF
Total asymmetric transformations at interfaces with centrosymmetric crystals: role of hydrophobic and kinetic effects in the crystallization of the system glycine/.alpha.-amino acids
I. Weissbuch, L. Addadi, L. Leiserowitz, and M. Lahav
pp 561 - 567; DOI:
10.1021/ja00210a041
PDF
Thermochemical study of the addition of carbenium ions to alkenes
Christian Schade, Herbert Mayr, and Edward M. Arnett
pp 567 - 571; DOI:
10.1021/ja00210a042
PDF
Host-guest complexation. 45. A highly preorganized chromogenic spherand indicator system specific for sodium and lithium ions
Donald J. Cram, Richard A. Carmack, and Roger C. Helgeson
pp 571 - 577; DOI:
10.1021/ja00210a043
PDF
Enzymes in organic synthesis. 38. Preparations of enantiomerically pure chiral hydroxydecalones via stereospecific horse liver alcohol dehydrogenase catalyzed reductions of decalindiones
David R. Dodds and J. Bryan Jones
pp 577 - 583; DOI:
10.1021/ja00210a044
PDF
Protease-catalyzed regioselective esterification of sugars and related compounds in anhydrous dimethylformamide
Sergio Riva, Joel Chopineau, A. P. G. Kieboom, and Alexander M. Klibanov
pp 584 - 589; DOI:
10.1021/ja00210a045
PDF
Catalytic recruitment in the inactivation of acetylcholinesterase by Soman: temperature dependence of the solvent isotope effect
Ildiko M. Kovach, Joan Harmon-Ashley Huber, and Richard L. Schowen
pp 590 - 593; DOI:
10.1021/ja00210a046
PDF
Oxidation and reduction of hemoproteins by trioxodinitrate(II). The role of nitrosyl hydride and nitrite
Michael P. Doyle, Surendra N. Mahapatro, Richard D. Broene, and Judith K. Guy
pp 593 - 599; DOI:
10.1021/ja00210a047
PDF
Free energy dependence of the rate of long-range electron transfer in proteins. Reorganization energy in ruthenium-modified myoglobin
Jennifer L. Karas, Charles M. Lieber, and Harry B. Gray
pp 599 - 600; DOI:
10.1021/ja00210a048
PDF
Carbanion intermediates in the photodecarboxylation of benzannelated acetic acids in aqueous solution
Iain McAuley, Erik Krogh, and Peter Wan
pp 600 - 602; DOI:
10.1021/ja00210a049
PDF
A mixed-valence tetranuclear platinum(I,II) complex with a Pt(I)-Pt(I) bond
Peter Betz and Avi Bino
pp 602 - 603; DOI:
10.1021/ja00210a050
PDF
First x-ray crystal structure of a bis(monoazacrown ether) complex, a bis(crown ether) or a lariat ether?
Gong Xin He, Kiyoshi Kikukawa, Hiroshi Ohe, Mitsuo Machida, and Tsutomu Matsuda
pp 603 - 604; DOI:
10.1021/ja00210a051
PDF
Enantioselective enzymic sterol synthesis by ultrasonically stimulated bakers' yeast
Jorge Bujons, Richard Guajardo, and Keith S. Kyler
pp 604 - 606; DOI:
10.1021/ja00210a052
PDF
On the red shift of the bacteriochlorophyll-b dimer spectra
Mark A. Thompson and Michael C. Zerner
pp 606 - 607; DOI:
10.1021/ja00210a053
PDF
The existence of alkyl carbanions in the gas phase
Susan T. Graul and Robert R. Squires
pp 607 - 608; DOI:
10.1021/ja00210a054
PDF
C4O and C6O molecules
R. J. Van Zee, G. R. Smith, and W. Weltner
pp 609 - 610; DOI:
10.1021/ja00210a055
PDF
Intercalation of cationic, anionic, and molecular species by organic hosts. Preparation and crystal structure of [NH4]6[calix[4]arenesulfonate][MeOSO3].cntdot.(H2O)2
Simon G. Bott, Anthony W. Coleman, and Jerry L. Atwood
pp 610 - 611; DOI:
10.1021/ja00210a056
PDF
Effects of steric congestion on photochemistry: enol ether formation from .alpha.-mesityl ketones
Peter J. Wagner and Boli Zhou
pp 611 - 612; DOI:
10.1021/ja00210a057
PDF
Nucleophile-promoted electrophilic cyclization reactions of alkynes
Larry E. Overman and Matthew J. Sharp
pp 612 - 614; DOI:
10.1021/ja00210a058
PDF
Simulation of crystal structures by empirical atom-atom potentials. 2. The orthorhombic-to-tetragonal phase transition in the high-temperature (Tc > 90 K) superconductor yttrium barium copper oxide (YBa2Cu3O7-y)
Michel Evain, Myung Hwan Whangbo, Mark A. Beno, and Jack M. Williams
pp 614 - 616; DOI:
10.1021/ja00210a059
PDF
Natural abundance deuterium NMR as a novel probe of monoterpene biosynthesis: limonene
M. F. Leopold, William W. Epstein, and David M. Grant
pp 616 - 617; DOI:
10.1021/ja00210a060
PDF
Acyclic stereocontrol via and electron-transfer process. Remarkable stereochemical difference between one- and two-electron events
Yoshinori Yamamoto, Shinji Nishii, and Toshiro Ibuka
pp 617 - 618; DOI:
10.1021/ja00210a061
PDF
Inorganic analogs of Langmuir-Blodgett films: adsorption of ordered zirconium 1,10-decanebisphosphonate multilayers on silicon surfaces
Haiwon Lee, Larry J. Kepley, Hun Gi Hong, and Thomas E. Mallouk
pp 618 - 620; DOI:
10.1021/ja00210a062
PDF
Competitive .alpha.- and .beta.-elimination in an iridium alkyl
Mark J. Burk, Martin P. McGrath, and Robert H. Crabtree
pp 620 - 620; DOI:
10.1021/ja00210a063
PDF
Transition-metal-controlled synthesis of (.+-.)-aristeromycin and (.+-.)-2',3'-diepi-aristeromycin. An unusual directive effect in hydroxylations
Barry M. Trost, Gee Hong Kuo, and Torre Benneche
pp 621 - 622; DOI:
10.1021/ja00210a064
PDF
Hydrolysis mechanisms of alkynyl benzoates, tosylates, and phosphates
Annette D. Allen, Tsugio Kitamura, Kenneth A. Roberts, Peter J. Stang, and Thomas T. Tidwell
pp 622 - 624; DOI:
10.1021/ja00210a065
PDF
Reaction of phosphorus ylides with elemental selenium: generation of seleno aldehydes and selenium-catalyzed Ph3P:CHR cleavage to give RHC:CHR and triphenylphosphine
Gerhard Erker, Regina Hock, and Rainer Nolte
pp 624 - 625; DOI:
10.1021/ja00210a066
PDF
An unusually stable manganese(II)manganese(III) complex with novel EPR spectra: synthesis, structure, magnetism, and EPR analysis
Hsiu Rong Chang, Habibe Diril, Mark J. Nilges, Xiaohua Zhang, Joseph A. Potenza, Harvey J. Schugar, David N. Hendrickson, and Stephan S. Isied
pp 625 - 627; DOI:
10.1021/ja00210a067
PDF
Exclusion of a 1,4-cyclohexenediyl as a metastable intermediate in the [3,3] sigmatropic rearrangement of a 1-hexen-5-yne
Karen A. Owens and Jerome A. Berson
pp 627 - 628; DOI:
10.1021/ja00210a068
PDF
Tetrakis(1,3-dithiol-2-ylidene)cyclopentanone: a new electron donor with remarkably low oxidation potential
Toyonari Sugimoto, Yohji Misaki, Yoshihisa Arai, Yukishi Yamamoto, Zenichi Yoshida, Yasushi Kai, and Nobutami Kasai
pp 628 - 629; DOI:
10.1021/ja00210a069
PDF
Homogeneous asymmetric hydrogenation of functionalized ketones
Masato Kitamura, Takeshi Ohkuma, Shinichi Inoue, Noboru Sayo, Hidenori Kumobayashi, Susumu Akutagawa, Tetsuo Ohta, Hidemasa Takaya, and Ryoji Noyori
pp 629 - 631; DOI:
10.1021/ja00210a070
PDF
Synthesis of the bicyclic core of the esperamicin/calichemicin class of antitumor agents
Stuart L. Schreiber and Laura L. Kiessling
pp 631 - 633; DOI:
10.1021/ja00210a071
PDF
1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)tropylium ion: an all-hydrocarbon carbocation with extraordinary stability
Koichi Komatsu, Hidekazu Akamatsu, Yasuhisa Jinbu, and Kunio Okamoto
pp 633 - 634; DOI:
10.1021/ja00210a072
PDF
Polar host-guest interaction. Binding of nonionic polar compounds with a resorcinol-aldehyde cyclooligomer as a lipophilic polar host
Yasuhiro Aoyama, Yasutaka Tanaka, Hiroo Toi, and Hisanobu Ogoshi
pp 634 - 635; DOI:
10.1021/ja00210a073
PDF
The distance dependence of intramolecular electron-transfer rates: importance of the nuclear factor
Stephen S. Isied, Asbed Vassilian, James F. Wishart, Carol Creutz, Harold A. Schwarz, and Norman Sutin
pp 635 - 637; DOI:
10.1021/ja00210a074
PDF
A two-step chemistry for highlighting heteroatom species in petroleum materials using carbon-13 NMR spectroscopy
Kenneth D. Rose and M. A. Francisco
pp 637 - 638; DOI:
10.1021/ja00210a075
PDF
Triphenylphosphine oxide as a crystallization aid
Margaret C. Etter and Paul W. Baures
pp 639 - 640; DOI:
10.1021/ja00210a076
PDF
Spectroscopic evidence for the formation of singlet molecular oxygen (1.DELTA.gO2) upon irradiation of a solvent-oxygen (3.SIGMA.g-O2) cooperative absorption band
Rodger D. Scurlock and Peter R. Ogilby
pp 640 - 641; DOI:
10.1021/ja00210a077
PDF
Use of tetrairidium undecacarbonyl to measure the lengths of organic molecules with a scanning transmission electron microscope
Frederic R. Furuya, Larry L. Miller, J. F. Hainfeld, William C. Christopfel, and Peter W. Kenny
pp 641 - 643; DOI:
10.1021/ja00210a078
PDF
Equilibrium between [CpCr(CO)3]2 and CpCr(CO)3. Thermodynamics of chromium-chromium single-bond cleavage
Stephan J. McLain
pp 643 - 644; DOI:
10.1021/ja00210a079
PDF
DNA strand scission by (-)-epicatechin and procyanidin B2
Linda A. Chrisey, G. H. Shahidi Bonjar, and Sidney M. Hecht
pp 644 - 646; DOI:
10.1021/ja00210a080
PDF
Novel 1,2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with .alpha.-haloorganolithiums
Eiichi Negishi and Kazunari Akiyoshi
pp 646 - 647; DOI:
10.1021/ja00210a081
PDF
Synthesis and characterization of a silver(I) triflate sandwich complex of 1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne. The first example of a 12-membered macrocycle sandwich complex
Joseph D. Ferrara, Abdellah Djebli, Claire Tessier-Youngs, and Wiley J. Youngs
pp 647 - 649; DOI:
10.1021/ja00210a082
PDF
Total synthesis of (.+-.)-ginkgolide B
Elias J. Corey, Myung Chol Kang, Manoj C. Desai, Arun K. Ghosh, and Ioannis N. Houpis
pp 649 - 651; DOI:
10.1021/ja00210a083
PDF
Asymmetric synthesis on carbohydrate templates: stereoselective Ugi-synthesis of .alpha.-amino acid derivatives
Horst Kunz and Waldemar Pfrengle
pp 651 - 652; DOI:
10.1021/ja00210a084
PDF
Computer Software Reviews

pp 653 - 654; DOI:
10.1021/ja00210a600
PDF
Book Reviews

pp 654 - 656; DOI:
10.1021/ja00210a601
PDF

Issue 3


Excitation and dissociation of isolated ions derived from polycyclic aromatic hydrocarbons
Steven J. Pachuta, Hilkka I. Kenttamaa, Thomas M. Sack, Ronald L. Cerny, Kenneth B. Tomer, Michael L. Gross, Robin R. Pachuta, and R. Graham Cooks
pp 657 - 665; DOI:
10.1021/ja00211a001
PDF
A theoretical study of the Meyer-Schuster reaction mechanism: minimum-energy profile and properties of transition-state structure
J. Andres, R. Cardenas, E. Silla, and O. Tapia
pp 666 - 674; DOI:
10.1021/ja00211a002
PDF
Two-dimensional double-quantum NMR spectroscopy of isolated spin 3/2 systems: sodium-23 examples
William D. Rooney, Thomas M. Barbara, and Charles S. Springer
pp 674 - 681; DOI:
10.1021/ja00211a003
PDF
A highly active thermophilic semisynthetic flavoenzyme
Donald Hilvert, Yasumaru Hatanaka, and E. T. Kaiser
pp 682 - 689; DOI:
10.1021/ja00211a004
PDF
Vibrational circular dichroism in the carbon-hydrogen stretching region of (+)-3(R)-methylcyclohexanone and chiral deuteriated isotopomers
Teresa B. Freedman, James Kallmerten, Elmer D. Lipp, Daryl A. Young, and Laurence A. Nafie
pp 689 - 698; DOI:
10.1021/ja00211a005
PDF
Vicinal elimination from 2-fluoroisopropyl cation in the gas phase
Dion A. Stams, Kamalesh K. Johri, and Thomas Hellman Morton
pp 699 - 706; DOI:
10.1021/ja00211a006
PDF
Structure of triazadienyl fluoride, FN3, by microwave, infrared, and ab initio methods
Dines Christen, H. G. Mack, G. Schatte, and H. Willner
pp 707 - 712; DOI:
10.1021/ja00211a007
PDF
In situ FT-IR investigation of phospholipid monolayer phase transitions at the air water interface
Melody L. Mitchell and Richard A. Dluhy
pp 712 - 718; DOI:
10.1021/ja00211a008
PDF
Microwave, infrared, and Raman spectra, conformational stability, structure, dipole moment, and vibrational assignment for cyclopropyl isocyanate
J. R. Durig, R. J. Berry, and C. J. Wurrey
pp 718 - 726; DOI:
10.1021/ja00211a009
PDF
The continuously rotated cellular reactor
John B. Grutzner, Edward A. Patrick, Perry J. Pellechia, and Marisol Vera
pp 726 - 728; DOI:
10.1021/ja00211a010
PDF
Application of phosphorus-31 NMR chemical shift: gold affinity correlation to hemoglobin-gold binding and the first inter-protein gold transfer reaction
C. F. Shaw, M. T. Coffer, J. Klingbeil, and C. K. Mirabelli
pp 729 - 734; DOI:
10.1021/ja00211a011
PDF
The nigericin-mediated transport of sodium and potassium ions through phospholipid bilayers studied by sodium-23 and potassium-39 NMR spectroscopy
Frank G. Riddell, S. Arumugam, Peter J. Brophy, Brian G. Cox, Mary C. H. Payne, and Timothy E. Southon
pp 734 - 738; DOI:
10.1021/ja00211a012
PDF
Dramatic influence of the nature of the surfactant aggregate on the rate constant for hydrolysis of phosphinate esters in aqueous nematic lyotropic liquid crystals
V. Ramesh and M. M. Labes
pp 738 - 741; DOI:
10.1021/ja00211a013
PDF
Resonance Raman spectra of dioxygen adducts of cobalt picket fence porphyrins
J. Odo, H. Imai, E. Kyuno, and Kazuo Nakamoto
pp 742 - 748; DOI:
10.1021/ja00211a014
PDF
Bonding and coupling of C1 fragments on metal surfaces
Chong Zheng, Yitzhak Apeloig, and Roald Hoffmann
pp 749 - 774; DOI:
10.1021/ja00211a015
PDF
Energies of molecular interactions from Bragg diffraction data
M. A. Spackman, H. P. Weber, and Brian M. Craven
pp 775 - 782; DOI:
10.1021/ja00211a016
PDF
Magnetic ordering of manganese(II) copper(II) bimetallic chains; design of a molecular based ferromagnet
Olivier Kahn, Yu Pei, Michel Verdaguer, Jean Pierre Renard, and Jorunn Sletten
pp 782 - 789; DOI:
10.1021/ja00211a017
PDF
The generation, microwave spectrum, and structure of propadienethione, H2C:C:C:S
Ronald D. Brown, K. G. Dyall, P. S. Elmes, P. D. Godfrey, and D. McNaughton
pp 789 - 792; DOI:
10.1021/ja00211a018
PDF
Phase transition in the conductive molecular crystals bis(tetramethyltetraselenafulvalene)[bis(trifluoromethyl)ethylene]diselenolatonickel and -platinum, [TMTSF]2[M(tds)2), M = nickel, platinum. Relation to the copper analog
William B. Heuer, Philip J. Squattrito, Brian M. Hoffman, and James A. Ibers
pp 792 - 803; DOI:
10.1021/ja00211a019
PDF
Mechanism of acyl group isomerization in palladium(II) complexes. Development of a catalytic process for the isomerization of carboxylic acid chlorides
Jeffrey S. Brumbaugh and Ayusman Sen
pp 803 - 816; DOI:
10.1021/ja00211a020
PDF
Pyrazole derivatives of diborane(4)
C. P. Brock, M. K. Das, R. P. Minton, and Kurt Niedenzu
pp 817 - 822; DOI:
10.1021/ja00211a021
PDF
Nonanuclear oxide-bridged manganese complex. Preparation, structure, and magnetic properties of [Mn9O4(O2CPh)8(sal)4(salH)2(pyr)4] (salH2 = salicylic acid; pyr = pyridine)
Cheryl Christmas, John B. Vincent, Hsiu Rong Chang, John C. Huffman, George Christou, and David N. Hendrickson
pp 823 - 830; DOI:
10.1021/ja00211a022
PDF
Thermal decarbonylation of molybdenum(II) carbonyl-iodide complexes. Molecular and electronic structures of the mixed-valence trinuclear clusters Mo3HI7L3 (L = tetrahydrofuran, acetonitrile, benzonitrile) and molecular structures of MoI3(EtCN)3 and Mo2I4(PhCN)4
F. Albert Cotton and Rinaldo Poli
pp 830 - 841; DOI:
10.1021/ja00211a023
PDF
Physical properties and synthetic utility of .alpha.-alkoxyorganolithium species as studied through ligand selectivity in tin-lithium exchange
J. Scott Sawyer, Andrew Kucerovy, Timothy L. Macdonald, and Glenn J. McGarvey
pp 842 - 853; DOI:
10.1021/ja00211a024
PDF
3-Acyltetramic acid antibiotics. 2. Synthesis of (+)-streptolic acid
Robert E. Ireland and Michael G. Smith
pp 854 - 860; DOI:
10.1021/ja00211a025
PDF
Kinetic investigation of the type 2 intramolecular Diels-Alder cycloaddition
K. J. Shea, L. D. Burke, and W. P. England
pp 860 - 864; DOI:
10.1021/ja00211a026
PDF
Electrophilic reactions at single bonds. 22. Superacid-catalyzed electrophilic formylation of adamantane with carbon monoxide competing with Koch-Haaf carboxylation
Omar Farooq, Mike Marcelli, G. K. Surya Prakash, and George A. Olah
pp 864 - 867; DOI:
10.1021/ja00211a027
PDF
Twisting in alkyl-substituted olefin cation radicals
Timothy Clark and Stephen F. Nelsen
pp 868 - 870; DOI:
10.1021/ja00211a028
PDF
Y-conjugated dianions. A carbon-13 nuclear magnetic resonance study
Andrzej Rajca and Laren M. Tolbert
pp 871 - 876; DOI:
10.1021/ja00211a029
PDF
The chemistry and structure of a 10-Sn-4 system: Pseudo-trigonal-bipyramidal 4-coordinate, 10-electron tin centers
Gerhard Bettermann and Anthony J. Arduengo
pp 877 - 879; DOI:
10.1021/ja00211a030
PDF
Molecular recognition during 1,2-addition of chiral vinyl organometallics to chiral .beta.,.gamma.-unsaturated ketones. Case studies of three 7,7-disubstituted 2-norbornenones. Part 5
Leo A. Paquette, Keith S. Learn, Jeffrey L. Romine, and Ho Shen Lin
pp 879 - 890; DOI:
10.1021/ja00211a031
PDF
Kinetic resolution during condensation of chiral (racemic) cyclopentenyllithiums with (R)-(-)-isopiperitenone. A short route to optically active annulated germacranolides
Leo A. Paquette, Donald T. DeRussy, and Charles E. Cottrell
pp 890 - 896; DOI:
10.1021/ja00211a032
PDF
New oxyfunctionalization capabilities for .omega.-hydroxylases. Asymmetric aliphatic sulfoxidation and branched ether demethylation
Andreas G. Katopodis, Homer A. Smith, and Sheldon W. May
pp 897 - 899; DOI:
10.1021/ja00211a033
PDF
Diradical rearrangements. Part 211. An unusual 1,2-shift in a photochemically generated 1,3-diradical. Mechanistic and exploratory organic photochemistry. Part 151
Howard E. Zimmerman and Ajit P. Kamath
pp 900 - 911; DOI:
10.1021/ja00211a034
PDF
Nucleophilic attacks on carbon-carbon double bonds. 36. Stereochemistry of substitution of good nucleofuges at the stereoconvergence region as a tool for investigating the rapid step of nucleophilic vinylic substitution
Bianca Avramovitch and Zvi Rappoport
pp 911 - 922; DOI:
10.1021/ja00211a035
PDF
Convergent functional groups. 5. Ternary complexes in the molecular recognition of .beta.-arylethylamines
J. Rebek, B. Askew, P. Ballester, and A. Costero
pp 923 - 927; DOI:
10.1021/ja00211a036
PDF
UV-visible and carbon NMR studies of quinine binding to urohemin I chloride and uroporphyrin I in aqueous solution
I. Constantinidis and James D. Satterlee
pp 927 - 932; DOI:
10.1021/ja00211a037
PDF
Interactions between DNA and mono-, bis-, tris-, tetrakis-, and hexakis(aminoacridines). A linear and circular dichroism, electric orientation relaxation, viscometry, and equilibrium study
Michael Wirth, Ole Buchardt, Torben Koch, Peter E. Nielsen, and Bengt Norden
pp 932 - 939; DOI:
10.1021/ja00211a038
PDF
Biosynthesis of the toxic indolizidine alkaloids slaframine and swainsonine in Rhizoctonia leguminicola: metabolism of 1-hydroxyindolizidines
Constance M. Harris, Marilyn J. Schneider, Frank S. Ungemach, James E. Hill, and Thomas M. Harris
pp 940 - 949; DOI:
10.1021/ja00211a039
PDF
Synthesis and stereochemical analysis of exchange-inert chromium(III) complexes of adenosine 5'-O-(2-thiodiphosphate), adenosine 5'-O-(2-thiotriphosphate), and adenosine 5'-O-(3-thiotriphosphate). Generation of a new class of chiral enzyme active site probes
Irene Lin and Debra Dunaway-Mariano
pp 950 - 956; DOI:
10.1021/ja00211a040
PDF
Metalation of nonenolizable ketones and aldehydes by lithium dialkylamide bases
Christopher S. Shiner, Andrew H. Berks, and Allison M. Fisher
pp 957 - 958; DOI:
10.1021/ja00211a041
PDF
Asymmetric intramolecular Michael reaction. Construction of chiral building blocks for the synthesis of several alkaloids
Yoshiro Hirai, Takashi Terada, and Takao Yamazaki
pp 958 - 960; DOI:
10.1021/ja00211a042
PDF
The ring opening metathesis polymerization of 7-oxabicyclo[2.2.1]hept-5-ene derivatives: a new acyclic polymeric ionophore
Bruce M. Novak and Robert H. Grubbs
pp 960 - 961; DOI:
10.1021/ja00211a043
PDF
Activation of dihydrogen by organo-iridium-phosphido complexes. Evidence for .alpha.-hydrogen abstraction by a terminal phosphide ligand
Michael D. Fryzuk and Kiran Bhangu
pp 961 - 963; DOI:
10.1021/ja00211a044
PDF
Positive evidence for tetrahedral R'C(OR)3H+ intermediates in the gas phase
Simonetta Fornarini
pp 963 - 965; DOI:
10.1021/ja00211a045
PDF
Papuamine, an antifungal pentacyclic alkaloid from a marine sponge, Haliclona sp
Bill J. Baker, Paul J. Scheuer, and James N. Shoolery
pp 965 - 966; DOI:
10.1021/ja00211a046
PDF
Stereospecific replacement of sulfur from chiral .gamma.-(arylsulfanyl)butyrolactones. Synthesis of optically pure ring-fused .gamma.-butyrolactones
Joseph P. Marino, Edgardo Laborde, and Robert S. Paley
pp 966 - 968; DOI:
10.1021/ja00211a047
PDF
Regiocontrol in the intermolecular cobalt-catalyzed olefin-acetylene cycloaddition
Marie E. Krafft
pp 968 - 970; DOI:
10.1021/ja00211a048
PDF
A new method for the instant preparation of large unilamellar vesicles
D. D. Lasic, A. Belic, and T. Valentincic
pp 970 - 971; DOI:
10.1021/ja00211a049
PDF
Quinuclidine dimer cation radical
J. P. Dinnocenzo and T. E. Banach
pp 971 - 973; DOI:
10.1021/ja00211a050
PDF
A Study of the [1,7]-Sigmatropic shift of a 1-hydroxylated-3-desoxy previtamin D to vitamin D: observation of a modest primary deuterium kinetic isotope effect
William H. Okamura, Carl A. Hoeger, Kelli J. Miller, and Wolfgang Reischl
pp 973 - 974; DOI:
10.1021/ja00211a051
PDF
Dissociative versus molecular chemisorption of nitric oxide on small bare cationic cobalt clusters in the gas phase
J. J. Klaassen and D. B. Jacobson
pp 974 - 976; DOI:
10.1021/ja00211a052
PDF
Carbon-carbon bond activation via .beta.-alkyl elimination. Reversible branching of 1,4-pentadienes catalyzed by scandocene hydride derivatives
Emilio Bunel, Barbara J. Burger, and John E. Bercaw
pp 976 - 978; DOI:
10.1021/ja00211a053
PDF
Solid-state and solution structure of dilithium trimethyl[(phenylsulfonyl)methyl]silane, a true dilithiomethane derivative
Hans Joachim Gais, Juergen Vollhardt, Harald Guenther, Detlef Moskau, Hans J. Lindner, and Siegmar Braun
pp 978 - 980; DOI:
10.1021/ja00211a054
PDF
Electronic properties of phosphazene substituents on ferrocene
Reginaldo A. Saraceno, Geoffrey H. Riding, Harry R. Allcock, and Andrew G. Ewing
pp 980 - 982; DOI:
10.1021/ja00211a055
PDF
Laser-jet photochemistry: the photofragmentation of triplet 1,1,3,3-tetraarylpropan-1,3-diyls and their role in the photometathesis between diarylcarbenes and 1,1-diarylethylenes
R. Marshall Wilson and Karlyn A. Schnapp
pp 982 - 983; DOI:
10.1021/ja00211a056
PDF
Convergent functional groups: catalysis of hemiacetal cleavage in a synthetic molecular cleft
J. Wolfe, D. Nemeth, A. Costero, and Julius Rebek
pp 983 - 984; DOI:
10.1021/ja00211a057
PDF
On the Lewis-acid-induced addition of allylstannanes to aldehydes: a spectroscopic investigation
Scott E. Denmark, Thomas Wilson, and Timothy M. Willson
pp 984 - 986; DOI:
10.1021/ja00211a058
PDF
[Th(III)[.eta.5-C5H3(SiMe3)2]3], an actinide compound with a 6d1 ground state
Wing K. Kot, George V. Shalimoff, Norman M. Edelstein, Michael A. Edelman, and Michael F. Lappert
pp 986 - 987; DOI:
10.1021/ja00211a059
PDF
Enantioface differentiation in cis dihydroxylation of carbon-carbon double bonds by osmium tetroxide using a chiral diamine with D2 symmetry [Erratum to document cited in CA107(23):217321T]
Kiyoshi Tomioka, Makoto Nakajima, and Kenji Koga
pp 988 - 988; DOI:
10.1021/ja00211a060
PDF
Multisubstitution of Os(CO)5 by ethylene: isomeric Os(CO)2(C2H4)3 and a derivative of Os(CO)(C2H4)4 [Erratum to document cited in CA106(19):156661j]
Gong Yu Kiel, Josef Takats, and Friedrich Wielhelm Grevels
pp 988 - 988; DOI:
10.1021/ja00211a061
PDF
Computer Software Reviews

pp 988 - 988; DOI:
10.1021/ja00211a600
PDF

Issue 4


Application of carbon-13 NMR spectroscopy to acyclic conformational analysis
James K. Whitesell, Thomas LaCour, Randall L. Lovell, John Pojman, Pat Ryan, and Atsuko Yamada-Nosaka
pp 991 - 996; DOI:
10.1021/ja00212a001
PDF
Relaxation or fluctuation of the ionic atmosphere in charge-transfer reactions. An ab initio study of the charge transfer in the (H3O2)- and (FCH3F)- systems
Emili Carbonell, Jose L. Andres, Agusti Lledos, Miquel Duran, and Juan Bertran
pp 996 - 1001; DOI:
10.1021/ja00212a002
PDF
Broken symmetry analysis of spin coupling in iron-sulfur clusters
Louis Noodleman, David A. Case, and Arie Aizman
pp 1001 - 1005; DOI:
10.1021/ja00212a003
PDF
Ultraviolet resonance Raman excitation profiles of tyrosine: dependence of Raman cross sections on excited-state intermediates
Michael Ludwig and Sanford A. Asher
pp 1005 - 1011; DOI:
10.1021/ja00212a004
PDF
Semiconductor particles in bilayer lipid membranes. Formation, characterization, and photoelectrochemistry
Xiao Kang Zhao, Subhash Baral, Ranieri Rolandi, and Janos H. Fendler
pp 1012 - 1024; DOI:
10.1021/ja00212a005
PDF
Triplet ground-state benzoylphenylmethylene and its quintet ground-state triplet-triplet radical pair
H. Murai, I. Safarik, M. Torres, and Otto P. Strausz
pp 1025 - 1032; DOI:
10.1021/ja00212a006
PDF
Peptide conformations. 46. Conformational analysis of a superpotent cytoprotective cyclic somatostatin analog
Horst Kessler, Jan Willem Bats, Christian Griesinger, Sylvie Koll, Martin Will, and Klaus Wagner
pp 1033 - 1049; DOI:
10.1021/ja00212a007
PDF
Heteronuclear chemical-shift correlations of silanol groups studied by two-dimensional cross-polarization magic angle spinning NMR
Alexander J. Vega
pp 1049 - 1054; DOI:
10.1021/ja00212a008
PDF
The phosphorus-31 chemical shielding tensor in phospholipids
H. Hauser, C. Radloff, Richard R. Ernst, S. Sundell, and I. Pascher
pp 1054 - 1058; DOI:
10.1021/ja00212a009
PDF
High-field, high-resolution proton "magic-angle" sample-spinning nuclear magnetic resonance spectroscopic studies of gel and liquid crystalline lipid bilayers and the effects of cholesterol
Jeffrey Forbes, Cynthia Husted, and Eric Oldfield
pp 1059 - 1065; DOI:
10.1021/ja00212a010
PDF
Observation of a mobile molybdenum carbonyl fragment on .gamma.-alumina by solid-state carbon-13 nuclear magnetic resonance spectroscopy
Thomas H. Walter, Arthur Thompson, Max Keniry, Sumio Shinoda, Theodore L. Brown, H. S. Gutowsky, and Eric Oldfield
pp 1065 - 1068; DOI:
10.1021/ja00212a011
PDF
Electron spin-echo studies of the copper binding site in phenylalanine hydroxylase from Chromobacterium violaceum
John McCracken, Stephen Pember, Stephen J. Benkovic, Joseph J. Villafranca, Robert J. Miller, and Jack Peisach
pp 1069 - 1074; DOI:
10.1021/ja00212a012
PDF
Characterization of two dissimilatory sulfite reductases (desulforubidin and desulfoviridin) from the sulfate-reducing bacteria. Moessbauer and EPR studies
I. Moura, J. LeGall, A. R. Lino, H. D. Peck, G. Fauque, A. V. Xavier, D. V. DerVartanian, J. J. G. Moura, and B. H. Huynh
pp 1075 - 1082; DOI:
10.1021/ja00212a013
PDF
High-resolution silicon-29 nuclear magnetic resonance in the Y-Si-O-N system
R. Dupree, M. H. Lewis, and M. E. Smith
pp 1083 - 1087; DOI:
10.1021/ja00212a014
PDF
Equilibrium isotope effects on the hydration of gas-phase ions. The effect of hydrogen bond formation on deuterium isotopic fractionation factors for H3O+, H5O2+, F(H2O)-, and Cl(H2O)-
J. W. Larson and T. B. McMahon
pp 1087 - 1093; DOI:
10.1021/ja00212a015
PDF
Synchrotron radiation selected s-tetrazine ion chemistry
I. Nenner, O. Dutuit, M. Richard-Viard, P. Morin, and A. H. Zewail
pp 1093 - 1098; DOI:
10.1021/ja00212a016
PDF
Stereochemical effects in the gas-phase pinacol rearrangement. 2. Ring contraction versus methyl migration in cis- and trans-1,2-dimethylcyclohexane-1,2-diol
Giulia De Petris, Pierluigi Giacomello, Adriano Pizzabiocca, Gabriele Renzi, and Maurizio Speranza
pp 1098 - 1103; DOI:
10.1021/ja00212a017
PDF
Energy requirements for a chemical reaction. 2. Electron transfer to SbF5 and SnCl4
J. F. Hershberger, Y. D. Huh, J. J. McAndrew, R. J. Cross, and M. Saunders
pp 1104 - 1108; DOI:
10.1021/ja00212a018
PDF
Homotropenylium cation revisited: POAV and 3D-HMO analysis
R. C. Haddon
pp 1108 - 1112; DOI:
10.1021/ja00212a019
PDF
Elemental carbon cages
T. G. Schmalz, W. A. Seitz, D. J. Klein, and G. E. Hite
pp 1113 - 1127; DOI:
10.1021/ja00212a020
PDF
How is transition state looseness related to the reaction barrier?
Sason S. Shaik
pp 1127 - 1131; DOI:
10.1021/ja00212a021
PDF
Cluster framework structures and relationships. Two compounds with a new connectivity, K2Zr6Cl15B and K3Zr6Cl15Be
Robin P. Ziebarth and John D. Corbett
pp 1132 - 1139; DOI:
10.1021/ja00212a022
PDF
Combined single-crystal x-ray diffraction and magic angle spinning NMR study of .alpha.-CaZn2(PO4)2
R. J. B. Jakeman and Anthony K. Cheetham
pp 1140 - 1143; DOI:
10.1021/ja00212a023
PDF
Dinuclear formamidinato complexes of nickel and palladium
F. Albert Cotton, Marek Matusz, Rinaldo Poli, and Xuejun Feng
pp 1144 - 1154; DOI:
10.1021/ja00212a024
PDF
Translational symmetries in the linear-chain semiconductors K4[Pt2(P2O5H2)4X].cntdot.nH2O (X = Cl, Br, I)
Leslie G. Butler, Miriam Heinrichs Zietlow, Chi Ming Che, William P. Schaefer, S. Sridhar, Paula J. Grunthaner, Basil I. Swanson, Robin J. H. Clark, and Harry B. Gray
pp 1155 - 1162; DOI:
10.1021/ja00212a025
PDF
Kinetics, mechanism, and thermodynamic aspects of the interconversion of complexes of planar and nonplanar metallo-amido-N-groups
Terrence J. Collins and John T. Keech
pp 1162 - 1167; DOI:
10.1021/ja00212a026
PDF
Pentacoordinated molecules. 70. New five- and six-coordinated anionic tin(IV) complexes. Molecular structure of spirocyclic stannates with mixed ligands
Robert R. Holmes, Soheila Shafieezad, V. Chandrasekhar, Arjun C. Sau, Joan M. Holmes, and Roberta O. Day
pp 1168 - 1174; DOI:
10.1021/ja00212a027
PDF
Pentacoordinated molecules. 71. Hydrolysis reactions leading to ring-containing hexacoordinated distannoxanes. Tin-sulfur vs tin-oxygen bonding
Robert R. Holmes, Soheila Shafieezad, V. Chandrasekhar, Joan M. Holmes, and Roberta O. Day
pp 1174 - 1180; DOI:
10.1021/ja00212a028
PDF
Photoinduced intramolecular electron transfer in peptide-bridged molecules
Kirk S. Schanze and Kenneth Sauer
pp 1180 - 1186; DOI:
10.1021/ja00212a029
PDF
Biomimetic oxidation with molecular oxygen. Selective carbon-carbon bond cleavage of 1,2-diols by molecular oxygen and dihydropyridine in the presence of iron-porphyrin catalysts
Tadashi Okamoto, Ken Sasaki, and Shinzaburo Oka
pp 1187 - 1196; DOI:
10.1021/ja00212a030
PDF
Dioxygen-copper reactivity. Models for hemocyanin: Reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units
Kenneth D. Karlin, Michael S. Haka, Richard W. Cruse, Gerald J. Meyer, Amjad Farooq, Yilma Gultneh, Jon C. Hayes, and Jon Zubieta
pp 1196 - 1207; DOI:
10.1021/ja00212a031
PDF
A deoxymyoglobin model with a sterically unhindered axial imidazole
Michel Momenteau, W. Robert Scheidt, C. W. Eigenbrot, and Christopher A. Reed
pp 1207 - 1215; DOI:
10.1021/ja00212a032
PDF
Very efficient visible light energy harvesting and conversion by spectral sensitization of high surface area polycrystalline titanium dioxide films
Nick Vlachopoulos, Paul Liska, Jan Augustynski, and Michael Graetzel
pp 1216 - 1220; DOI:
10.1021/ja00212a033
PDF
Structural effect of gem-6 substitution on carbon, nitrogen, phosphorus, sulfur, and oxygen atoms: crystallographic data analysis of numerous C3CZCC3 fragments. Modelization of static and dynamic molecular states
Jacques Emile Dubois and Aliette Cosse-Barbi
pp 1220 - 1228; DOI:
10.1021/ja00212a034
PDF
Homolytic bond dissociation energies in solution from equilibrium acidity and electrochemical data
F. G. Bordwell, Jin Pei Cheng, and John A. Harrelson
pp 1229 - 1231; DOI:
10.1021/ja00212a035
PDF
Periselective intramolecular cycloaddition of allene-1,3-dicarboxylates. Unusual structural feature of [2 + 2] cycloadducts
Mitsutaka Yoshida, Yukari Hidaka, Yoshiharu Nawata, Jerzy M. Rudzinski, Eiji Osawa, and Ken Kanematsu
pp 1232 - 1238; DOI:
10.1021/ja00212a036
PDF
Asymmetric Diels-Alder cycloaddition reactions with chiral .alpha.,.beta.-unsaturated N-acyloxazolidinones
David A. Evans, K. T. Chapman, and J. Bisaha
pp 1238 - 1256; DOI:
10.1021/ja00212a037
PDF
Fundamental properties of Rose Bengal. 25. Bleaching studies of Rose Bengal onium salts
Shwn Meei Linden and D. C. Neckers
pp 1257 - 1260; DOI:
10.1021/ja00212a038
PDF
Lewis acid catalysis of photochemical reactions. 7. Photodimerization and cross-cycloaddition of cinnamic esters
Frederick D. Lewis, Suzanne L. Quillen, Paul D. Hale, and Joe D. Oxman
pp 1261 - 1267; DOI:
10.1021/ja00212a039
PDF
The quest for free metaphosphate in solution. Racemization at phosphorus in the transfer of the phospho group from aryl phosphate monoesters to tert-butyl alcohol in acetonitrile or in tert-butyl alcohol
Jonathan M. Friedman, Sally Freeman, and Jeremy R. Knowles
pp 1268 - 1275; DOI:
10.1021/ja00212a040
PDF
A theoretical treatment of nucleophilic reactivity in additions to carbonyl compounds. Role of the vertical ionization energy
Erwin Buncel, Sason S. Shaik, Ik Hwan Um, and Saul Wolfe
pp 1275 - 1279; DOI:
10.1021/ja00212a041
PDF
A new rigid sulfur-bridged dithiametacyclophane and its acyclic analogs: direct observation of the transannular bond formation between the three sulfur atoms and isolation of dicationic salts
Hisashi Fujihara, Jer Jye Chiu, and Naomichi Furukawa
pp 1280 - 1284; DOI:
10.1021/ja00212a042
PDF
Peroxide model reaction for placental aromatase
Philip A. Cole and Cecil H. Robinson
pp 1284 - 1285; DOI:
10.1021/ja00212a043
PDF
Rates of specific peptide binding to the glycopeptide antibiotics vancomycin, ristocetin, and avoparcin
Paul H. Popieniek and R. F. Pratt
pp 1285 - 1286; DOI:
10.1021/ja00212a044
PDF
Nickel(0)-promoted cyclization of enzymes with isocyanides: a new route to polycyclic cyclopentenone skeletons
Kohei Tamao, Kenji Kobayashi, and Yoshihiko Ito
pp 1286 - 1288; DOI:
10.1021/ja00212a045
PDF
Regioselective double vicinal carbon-carbon bond forming reactions of electron-deficient alkenes by use of allylic stannanes and organoiodo compounds
Kazuhiko Mizuno, Munehiro Ikeda, Susumu Toda, and Yoshio Otsuji
pp 1288 - 1290; DOI:
10.1021/ja00212a046
PDF
Metalation and alkylation of 4H-1,3-dioxin: a new .beta.-acyl vinyl anion equivalent
Raymond L. Funk and Gary L. Bolton
pp 1290 - 1292; DOI:
10.1021/ja00212a047
PDF
A general strategy for the chemical sequencing of polysaccharides
Chang Kiu Lee and Gary R. Gray
pp 1292 - 1293; DOI:
10.1021/ja00212a048
PDF
Photoinduced electron transfer in contact ion pairs
T. M. Bockman and Jay K. Kochi
pp 1294 - 1295; DOI:
10.1021/ja00212a049
PDF
An iron-activated alcohol dehydrogenase: metal dissociation constants and magnetic and spectroscopic properties
Peter Tse, Robert K. Scopes, Anthony G. Wedd, Eddy Bakshi, and Keith S. Murray
pp 1295 - 1297; DOI:
10.1021/ja00212a050
PDF
Carbocupration of cyclopropene. A novel synthon of cyclopropanone enolate and its application to [3 + 2] and [3 + 2 + 2] annulation
Eiichi Nakamura, Masahiko Isaka, and Satoshi Matsuzawa
pp 1297 - 1298; DOI:
10.1021/ja00212a051
PDF
Generation and trapping of an alkynyl cation
Giancarlo Angelini, Michael Hanack, Jan Vermehren, and Maurizio Speranza
pp 1298 - 1299; DOI:
10.1021/ja00212a052
PDF
A rigid and nonperturbing probe for duplex DNA motion
Andreas Spaltenstein, Bruce H. Robinson, and Paul B. Hopkins
pp 1299 - 1301; DOI:
10.1021/ja00212a053
PDF
Electronic absorptions in the high Tc superconductor YBa2Cu3Ox
William A. Little, James P. Collman, Gordon T. Yee, Matthew J. Holcomb, John T. McDevitt, and Gordon E. Brown
pp 1301 - 1302; DOI:
10.1021/ja00212a054
PDF
Chemical properties of dodecahedrane. Monofunctionalization reactions
Leo A. Paquette, Jeffrey C. Weber, and Tomoshige Kobayashi
pp 1303 - 1304; DOI:
10.1021/ja00212a055
PDF
Chemical properties of dodecahedrane. The dodecahedryl cation and 1,16-dodecahedryl dication. Regioselective difunctionalization of the sphere
George A. Olah, G. K. Surya Prakash, Tomoshige Kobayashi, and Leo A. Paquette
pp 1304 - 1305; DOI:
10.1021/ja00212a056
PDF
Cyclopropanation of spherical hydrocarbons without need for prior olefination. The synthesis of cyclopropadodecahedranes
Leo A. Paquette, Tomoshige Kobayashi, and Judith C. Gallucci
pp 1305 - 1307; DOI:
10.1021/ja00212a057
PDF
Selective binding of imidazoles and related organic molecules in an organic solvent
Jeremy D. Kilburn, A. Roderick MacKenzie, and W. Clark Still
pp 1307 - 1308; DOI:
10.1021/ja00212a058
PDF
Isolation and structure determination of the didemnenones, novel cytotoxic metabolites from tunicates
Niels Lindquist, William Fenical, David F. Sesin, Chris M. Ireland, Gregory D. Van Duyne, Craig J. Forsyth, and Jon Clardy
pp 1308 - 1309; DOI:
10.1021/ja00212a059
PDF
X-ray absorption study of octafluorodirhenate(III): EXAFS structures and resonance Raman spectroscopy of octahalodirhenates
Steven D. Conradson, Alfred P. Sattelberger, and William H. Woodruff
pp 1309 - 1311; DOI:
10.1021/ja00212a060
PDF
Organic reactions in liquid crystalline solvents. 6. Regiochemical control of bimolecular chemical reactivity in smectic and cholesteric liquid crystals
William J. Leigh and D. Scott Mitchell
pp 1311 - 1313; DOI:
10.1021/ja00212a061
PDF
Radical intermediates in the epoxidation of alkenes by cytochrome P-450 model systems. The design of a hypersensitive radical probe
Angelo J. Castellino and Thomas C. Bruice
pp 1313 - 1315; DOI:
10.1021/ja00212a062
PDF
Silacyclobutadienes: generation of 1-mesityl-2,3,4-tri-tert-butyl-1-silacyclobutadiene
Mark J. Fink, Dhananjay B. Puranik, and M. Pontier Johnson
pp 1315 - 1316; DOI:
10.1021/ja00212a063
PDF
A heteroaromatic trimethylenemethane
Fred Wudl, G. Srdanov, B. Rosenau, D. Wellman, K. Williams, and S. D. Cox
pp 1316 - 1318; DOI:
10.1021/ja00212a064
PDF
Molecular recognition of biologically interesting substrates: synthesis of an artificial receptor for barbiturates employing six hydrogen bonds
Suk Kyu Chang and Andrew D. Hamilton
pp 1318 - 1319; DOI:
10.1021/ja00212a065
PDF
Lewis acid-promoted carbon-carbon bond formation between bridging isocyanides
Jianxin Wu, Phillip E. Fanwick, and Clifford P. Kubiak
pp 1319 - 1321; DOI:
10.1021/ja00212a066
PDF
Total synthesis of (+)-CC-1065 and ent-(-)-CC-1065
Dale L. Boger and Robert S. Coleman
pp 1321 - 1323; DOI:
10.1021/ja00212a067
PDF
Remarkable effects of lone pair-lone pair interactions on the extremely stereoselective [2 + 2] cycloaddition of azidoketene to chiral 3-imino-.beta.-lactams [Erratum to document cited in CA106(19):156852x]
Iwao Ojima, Kazuaki Nakahashi, Stephan M. Brandstadter, and Naoto Hatanaka
pp 1323 - 1323; DOI:
10.1021/ja00212a068
PDF
Book Reviews

pp 1323 - 1324; DOI:
10.1021/ja00212a600
PDF

Issue 5


Evidence for static localization in the lowest optically excited states of ruthenium(II) diimine complexes: a solvent- and time-dependent photoselection study at 77 K
M. L. Myrick, R. L. Blakley, M. K. DeArmond, and M. L. Arthur
pp 1325 - 1336; DOI:
10.1021/ja00213a001
PDF
Primary ethynamines (HC.tplbond.CNH2, PhC.tplbond.CNH2), aminopropadienone (H2NCH:C:C:O), and imidoylketene (HN:CHCH:C:O). Preparation and identification of molecules of cosmochemical interest
Curt Wentrup, Horst Briehl, Primoz Lorencak, Uwe J. Vogelbacher, Hans Wilhelm Winter, Andre Maquestiau, and Robert Flammang
pp 1337 - 1343; DOI:
10.1021/ja00213a002
PDF
Ion/surface collisions for distinction of isomeric [C6H6].cntdot.+ and [C6H6]2+ ions
M. J. Hayward, M. A. Mabud, and R. G. Cooks
pp 1343 - 1346; DOI:
10.1021/ja00213a003
PDF
Time-resolved EPR studies of the properties of the triplet-state enols of intramolecularly hydrogen-bonded o-hydroxybenzaldehyde and related molecules
Seigo Yamauchi and Noboru Hirota
pp 1346 - 1351; DOI:
10.1021/ja00213a004
PDF
Time-resolved spectroscopy of tryptophan conformers in a supersonic jet
Laura A. Philips, S. P. Webb, Selso J. Martinez, G. R. Fleming, and Donald H. Levy
pp 1352 - 1355; DOI:
10.1021/ja00213a005
PDF
Cyclobutanediyls: a new class of localized biradicals. Synthesis and EPR spectroscopy
Rakesh Jain, Michael B. Sponsler, Frank D. Coms, and Dennis A. Dougherty
pp 1356 - 1366; DOI:
10.1021/ja00213a006
PDF
Characterization of hydrous species in minerals by high-speed proton MAS-NMR
James P. Yesinowski, Hellmut Eckert, and George R. Rossman
pp 1367 - 1375; DOI:
10.1021/ja00213a007
PDF
Theoretical study of .alpha.-lactone, acetoxyl diradical, and the gas-phase dissociation of the chloracetate anion
Danko Antolovic, Vernon J. Shiner, and Ernest R. Davidson
pp 1375 - 1381; DOI:
10.1021/ja00213a008
PDF
Magnetic and spectroscopic characterization of an iron porphyrin peroxide complex. Peroxoferrioctaethylporphyrin(1-)
Judith N. Burstyn, James A. Roe, Andrew R. Miksztal, Ben A. Shaevitz, George Lang, and Joan Selverstone Valentine
pp 1382 - 1388; DOI:
10.1021/ja00213a009
PDF
Second-order perturbation theory and configuration interaction theory applied to medium-sized molecules: cyclopropane, ethylenimine, ethylene oxide, fluoroethane, and acetaldehyde
Emmanuel D. Simandiras, Roger D. Amos, Nicholas C. Handy, Timothy J. Lee, Julia E. Rice, Richard B. Remington, and Henry F. Schaefer
pp 1388 - 1393; DOI:
10.1021/ja00213a010
PDF
Relative ineffectiveness of longicyclic three-ribbon interactions in dications. Rearrangement products of benzobarrelene dications: an MNDO and experimental study
Karl Schoetz, Timothy Clark, and Paul v. R. Schleyer
pp 1394 - 1405; DOI:
10.1021/ja00213a011
PDF
A quantum chemical study on the mechanism of cis-trans isomerization in retinal-like protonated Schiff bases
Guido J. M. Dormans, Gerrit C. Groenenboom, Wim C. A. Van Dorst, and Henk M. Buck
pp 1406 - 1415; DOI:
10.1021/ja00213a012
PDF
Jet-cooled exciplexes. 4. Diethyl ether and anisole with anthracene, perylene, and methyl-substituted anthracenes
Oded Anner and Yehuda Haas
pp 1416 - 1423; DOI:
10.1021/ja00213a013
PDF
Preparation and reactivity of several alkylidene complexes of the type W(CHR')(N-2,6-C6H3-iso-Pr2)(OR)2 and related tungstacyclobutane complexes. Controlling metathesis activity through the choice of alkoxide ligand
Richard R. Schrock, R. T. DePue, J. Feldman, C. J. Schaverien, J. C. Dewan, and A. H. Liu
pp 1423 - 1435; DOI:
10.1021/ja00213a014
PDF
Activation of the carbon-hydrogen bonds of benzene by reaction with [bis(dicyclohexylphosphino)ethane]platinum(0), generated by the thermolysis of cis-[bis(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)
Marifaith Hackett, James A. Ibers, and George M. Whitesides
pp 1436 - 1448; DOI:
10.1021/ja00213a015
PDF
[Bis(dicyclohexylphosphino)ethane]platinum(0). Reactions with alkyl, (trimethylsilyl)methyl, aryl, benzyl, and alkynyl carbon-hydrogen bonds
Marifaith Hackett and George M. Whitesides
pp 1449 - 1462; DOI:
10.1021/ja00213a016
PDF
Intramolecular coupling of .eta.2-iminoacyl groups at Group 4 metal centers: a kinetic study of the carbon-carbon double-bond-forming reaction
Loren D. Durfee, Anne K. McMullen, and Ian P. Rothwell
pp 1463 - 1467; DOI:
10.1021/ja00213a017
PDF
Topological kinetic effects: complexation of interlocked macrocyclic ligands by cationic species
Anne Marie Albrecht-Gary, Christiane Dietrich-Buchecker, Zeinab Saad, and Jean Pierre Sauvage
pp 1467 - 1472; DOI:
10.1021/ja00213a018
PDF
Ruthenium(IV)-oxo complexes: the novel utilization of tertiary pnicogen ligands
Mary E. Marmion and Kenneth J. Takeuchi
pp 1472 - 1480; DOI:
10.1021/ja00213a019
PDF
Molecular design based on inclusion chemistry. Synthesis, characterization, and crystal structures of a new family of lacunar Schiff base complexes with promise as broad-range host molecules
Dorai Ramprasad, Wang Kan Lin, Kenneth A. Goldsby, and Daryle H. Busch
pp 1480 - 1487; DOI:
10.1021/ja00213a020
PDF
Crystal and molecular structure of the tungsten-carbene complex [cyclic] W[C(CH2)3CH2](OCH2-tert-Bu)2Br2 and of its gallium tribromide adduct. A structural approach to the mechanism of olefin metathesis
M. T. Youinou, J. Kress, J. Fischer, A. Aguero, and John A. Osborn
pp 1488 - 1493; DOI:
10.1021/ja00213a021
PDF
Synthesis and molecular structure of [Al(CH3)3][12]aneS4: a novel example of an axially stabilized trigonal bipyramidal coordination of aluminum
Gregory H. Robinson and Samuel A. Sangokoya
pp 1494 - 1497; DOI:
10.1021/ja00213a022
PDF
Stable pentaammineruthenium(III) complexes of reductic acids: synthesis, linkage isomers, and autoxidation kinetics
D. M. Bryan, S. D. Pell, R. Kumar, Michael J. Clarke, V. Rodriguez, M. Sherban, and J. Charkoudian
pp 1498 - 1506; DOI:
10.1021/ja00213a023
PDF
Crystal chemistry of barium yttrium copper oxide (Ba2YCu3O7) and related compounds
Michael O'Keeffe and Staffan Hansen
pp 1506 - 1510; DOI:
10.1021/ja00213a024
PDF
Encapsulation of the transition metals chromium through cobalt in zirconium cluster iodides
Timothy Hughbanks, Guy Rosenthal, and John D. Corbett
pp 1511 - 1516; DOI:
10.1021/ja00213a025
PDF
Resolution of the paradox of ammonia and hydroxylamine as substrate analogs for the water-oxidation reaction catalyzed by photosystem II
Warren F. Beck and Gary W. Brudvig
pp 1517 - 1523; DOI:
10.1021/ja00213a026
PDF
Exciplexes of ruthenium(II) .alpha.-diimine complexes with silver(I)
N. P. Ayala, James N. Demas, and B. A. DeGraff
pp 1523 - 1529; DOI:
10.1021/ja00213a027
PDF
Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities
Herbert C. Brown, Raman K. Bakshi, and Bakthan Singaram
pp 1529 - 1534; DOI:
10.1021/ja00213a028
PDF
Chiral synthesis via organoboranes. 13. A highly diastereoselective and enantioselective addition of [(Z)-.gamma.-alkoxyallyl]diisopinocampheylboranes to aldehydes
Herbert C. Brown, Prabhakar K. Jadhav, and Krishna S. Bhat
pp 1535 - 1538; DOI:
10.1021/ja00213a029
PDF
Chiral synthesis via organoboranes. 14. Selective reductions. 41. Diisopinocampheylchloroborane, an exceptionally efficient chiral reducing agent
Herbert C. Brown, J. Chandrasekharan, and P. V. Ramachandran
pp 1539 - 1546; DOI:
10.1021/ja00213a030
PDF
Practical asymmetric syntheses of .alpha.-amino acids through carbon-carbon bond constructions on electrophilic glycine templates
Robert M. Williams, Peter J. Sinclair, Dongguan Zhai, and Daimo Chen
pp 1547 - 1557; DOI:
10.1021/ja00213a031
PDF
Palladium-catalyzed carbonylative coupling of aryl triflates with organostannanes
Antonio M. Echavarren and J. K. Stille
pp 1557 - 1565; DOI:
10.1021/ja00213a032
PDF
Chiral discrimination in the structures and energetics of association of stereoisomeric salts of mandelic acid with .alpha.-phenethylamine, ephedrine, and pseudoephedrine
S. P. Zingg, Edward M. Arnett, Andrew T. McPhail, Aksel A. Bothner-By, and W. R. Gilkerson
pp 1565 - 1580; DOI:
10.1021/ja00213a033
PDF
Atropisomerism in polymers. Screw-sense selective polymerization of isocyanides by inhibiting the growth of one enantiomer of a racemic pair of helices
Paul C. J. Kamer, Marco C. Cleij, Roeland J. M. Nolte, Tadao Harada, Alphons M. F. Hezemans, and Wiendelt Drenth
pp 1581 - 1587; DOI:
10.1021/ja00213a034
PDF
Membrane matrix for the hydrolysis of amino acid esters with marked enantioselectivity
Ryuichi Ueoka, Yoko Matsumoto, Robert A. Moss, Shanti Swarup, Atsushi Sugii, Kumiko Harada, Junichi Kikuchi, and Yukito Murakami
pp 1588 - 1595; DOI:
10.1021/ja00213a035
PDF
Dichotomous salt effects in the hydrophobic acceleration of the benzoin condensation
Eric T. Kool and Ronald Breslow
pp 1596 - 1597; DOI:
10.1021/ja00213a036
PDF
Unusual anthelminthic oxazoles from a marine sponge
Madeline Adamczeski, Emilio Quinoa, and Phillip Crews
pp 1598 - 1602; DOI:
10.1021/ja00213a037
PDF
2-[(Trimethylsilyl)methyl]-1-(trimethylsilyl)propen-3-yl carboxylates in cycloaddition. Novel approach for substitutive cyclopentannulation
Barry M. Trost, Serge M. Mignani, and Thomas N. Nanninga
pp 1602 - 1608; DOI:
10.1021/ja00213a038
PDF
Crystal structure, solid-state NMR spectra, and oxygen reactivity of five crystal forms of prednisolone tert-butylacetate
Stephen R. Byrn, Paul A. Sutton, Brian Tobias, James Frye, and Peter Main
pp 1609 - 1614; DOI:
10.1021/ja00213a039
PDF
Site-selective cleavage of RNA by a hybrid enzyme
Ronald N. Zuckermann, David R. Corey, and Peter G. Schultz
pp 1614 - 1615; DOI:
10.1021/ja00213a040
PDF
Difference in the methyl group conformational preferences of T1 and S1 acetophenone. A probe of the orbital character of excited electronic states
J. L. Tomer, L. H. Spangler, and David W. Pratt
pp 1615 - 1617; DOI:
10.1021/ja00213a041
PDF
Synthesis of cyclopentenyl sulfones via the [3 + 2] cyclization-elimination reaction of (phenylsulfonyl)allene
Albert Padwa and Philip E. Yeske
pp 1617 - 1618; DOI:
10.1021/ja00213a042
PDF
First simultaneous observation of the 133Cs NMR from Cs+, Cs-, and Cs+e- in a metal solution
A. S. Ellaboudy, N. C. Pyper, and Peter P. Edwards
pp 1618 - 1620; DOI:
10.1021/ja00213a043
PDF
The characterization of abasic sites in DNA heteroduplexes by site specific labeling with carbon-13
Muthiah Manoharan, Stephen C. Ransom, Abhijit Mazumder, John A. Gerlt, Joyce A. Wilde, Jane A. Withka, and Philip H. Bolton
pp 1620 - 1622; DOI:
10.1021/ja00213a044
PDF
FT ESR study of photoinduced electron transfer
T. Prisner, O. Dobbert, K. P. Dinse, and H. Van Willigen
pp 1622 - 1623; DOI:
10.1021/ja00213a045
PDF
Deoxygenation of phenolic natural products. Enzymic conversion of emodin to chrysophanol
John A. Anderson, Bor Kang Lin, Howard J. Williams, and A. Ian Scott
pp 1623 - 1624; DOI:
10.1021/ja00213a046
PDF
Total synthesis of (-)-botryococcene
James D. White, G. Nagabhushana Reddy, and Gary O. Spessard
pp 1624 - 1626; DOI:
10.1021/ja00213a047
PDF
A model for the proposed mechanism of action of the potent antitumor antibiotic esperamicin A1
Philip Magnus and Paul A. Carter
pp 1626 - 1628; DOI:
10.1021/ja00213a048
PDF
Does dehydroquinate synthase synthesize dehydroquinate?
Paul A. Bartlett and Kunio Satake
pp 1628 - 1630; DOI:
10.1021/ja00213a049
PDF
Convergent, enantiospecific total synthesis of the novel cyclodepsipeptide (+)-jasplakinolide (jaspamide)
Paul A. Grieco, Yung Son Hon, and Arturo Perez-Medrano
pp 1630 - 1631; DOI:
10.1021/ja00213a050
PDF
Bis(trimethylstannyl)benzopinacolate-mediated intermolecular free-radical carbon-carbon bond-forming reactions: a new one-carbon homologation
David J. Hart and Franklin L. Seely
pp 1631 - 1633; DOI:
10.1021/ja00213a051
PDF
Radical cyclization of oxime ethers
Paul A. Bartlett, Kevin L. McLaren, and Pauline C. Ting
pp 1633 - 1634; DOI:
10.1021/ja00213a052
PDF
Total synthesis of (.+-.)-pleurotin and (.+-.)-dihydropleurotin acid
David J. Hart and Horng Chih Huang
pp 1634 - 1635; DOI:
10.1021/ja00213a053
PDF
An unusual mechanism of a palladium-catalyzed intramolecular carbametalation. A novel palladium-catalyzed rearrangement
Barry M. Trost and Gerald J. Tanoury
pp 1636 - 1638; DOI:
10.1021/ja00213a054
PDF
Nonpeptide mimetics of .beta.-turns: a facile oxidative intramolecular cycloaddition of an azodicarbonyl system
Michael Kahn, Susanne Wilke, Barbara Chen, and Kagari Fujita
pp 1638 - 1639; DOI:
10.1021/ja00213a055
PDF
The .pi.-complex (benzene-ethylene) cation radical
Thomas Bally, Kuno Roth, and Rolf Straub
pp 1639 - 1641; DOI:
10.1021/ja00213a056
PDF
Synthetic and mechanistic features of dinuclear reductive elimination between Re2H8(PMe2Ph)4 and several tin(II) reagents
D. Eric Westerberg, Bruce R. Sutherland, John C. Huffman, and Kenneth G. Caulton
pp 1642 - 1643; DOI:
10.1021/ja00213a057
PDF
Titanium, zirconium, and hafnium tetrahydroborates as "tailored" CVD precursors for metal diboride thin films
James A. Jensen, John E. Gozum, Deborah M. Pollina, and Gregory S. Girolami
pp 1643 - 1644; DOI:
10.1021/ja00213a058
PDF
Resonance Raman spectroscopic investigation of axial coordination in M. thermoautotrophicum methyl reductase and its nickel tetrapyrrole cofactor F430
Andrew K. Shiemke, Robert A. Scott, and John A. Shelnutt
pp 1645 - 1646; DOI:
10.1021/ja00213a059
PDF
Synthesis of [Mo6S8(PEt3)6] by reductive dimerization of a trinuclear molybdenum chloro sulfido cluster complex coordinated with triethylphosphine and methanol: a molecular model for superconducting Chevrel phases
Taro Saito, Naohiro Yamamoto, Tsuneaki Yamagata, and Hideo Imoto
pp 1646 - 1647; DOI:
10.1021/ja00213a060
PDF
[(CH3)5C5]2Th(CH3)2 surface chemistry and catalysis. Direct NMR spectroscopic observation of surface alkylation and ethylene insertion/polymerization on MgCl2
David Hedden and Tobin J. Marks
pp 1647 - 1649; DOI:
10.1021/ja00213a061
PDF
Relative affinities of cation radicals and dications for nucleophiles and the super acid properties of dications in solution
Vernon D. Parker and Mats Tilset
pp 1649 - 1650; DOI:
10.1021/ja00213a062
PDF
Intermediacy of paramagnetic metal-hydrocarbyl species in organometallic reactions. Detection and characterization of a novel paramagnetic iron(II)-benzyl compound in the coupling of benzyl halides
Dale H. Hill and Ayusman Sen
pp 1650 - 1652; DOI:
10.1021/ja00213a063
PDF
Secohexaprismane - Correction
Goverdhan Mehta, and S. Padma
pp 1652 - 1652; DOI:
10.1021/ja00213a600
PDF
Computer Software Reviews

pp 1652 - 1654; DOI:
10.1021/ja00213a601
PDF
Book Reviews

pp 1654 - 1656; DOI:
10.1021/ja00213a602
PDF

Issue 6


The OPLS [optimized potentials for liquid simulations] potential functions for proteins, energy minimizations for crystals of cyclic peptides and crambin
William L. Jorgensen and Julian Tirado-Rives
pp 1657 - 1666; DOI:
10.1021/ja00214a001
PDF
Theoretical investigation of the thermal ring opening of bicyclobutane to butadiene. Evidence for a nonsynchronous process
Philip B. Shevlin and Michael L. McKee
pp 1666 - 1671; DOI:
10.1021/ja00214a002
PDF
Odd-electron .sigma. bonds
Timothy Clark
pp 1672 - 1678; DOI:
10.1021/ja00214a003
PDF
A novel optically active host: design, computer graphics, synthesis, and diastereomeric complex formation in aqueous solution
Ramalinga Dharanipragada, Stephen B. Ferguson, and Francois Diederich
pp 1679 - 1690; DOI:
10.1021/ja00214a004
PDF
Conformational stability of dimethyl phosphate anion in water: liquid-state free energy simulations
B. Jayaram, M. Mezei, and David L. Beveridge
pp 1691 - 1694; DOI:
10.1021/ja00214a005
PDF
Molecular and electronic structure of the low-lying electronic states of cycloalkenylidenes: cyclopropenylidene
Josep M. Bofill, Jaume Farras, Santiago Olivella, Albert Sole, and Jaume Vilarrasa
pp 1694 - 1700; DOI:
10.1021/ja00214a006
PDF
Reactivities of acrylic and methacrylic acids in a nucleophilic addition model of their biological activity
Roman Osman, Krishnan Namboodiri, Harel Weinstein, and James R. Rabinowitz
pp 1701 - 1707; DOI:
10.1021/ja00214a007
PDF
Molecular and macromolecular nonlinear optical materials. Probing architecture/electronic structure/frequency doubling relationships via an SCF-LCAO MECI .pi. electron formalism
De Quan Li, Mark A. Ratner, and Tobin J. Marks
pp 1707 - 1715; DOI:
10.1021/ja00214a008
PDF
Methyl radical formation over lithium-doped magnesium oxide. Molecular orbital theory
S. P. Mehandru, Alfred B. Anderson, and James F. Brazdil
pp 1715 - 1719; DOI:
10.1021/ja00214a009
PDF
Asymmetric nitrogen. 67. Geminal systems. 41. Chiroptical properties of N-chloro and N-bromo derivatives of three-membered nitrogen heterocycles: aziridines and diaziridines
G. V. Shustov, G. K. Kadorkina, R. G. Kostyanovskii, and A. Rauk
pp 1719 - 1726; DOI:
10.1021/ja00214a010
PDF
Excited-state behavior of tryptamine and related indoles. Remarkably efficient intramolecular proton-induced quenching
Haruo Shizuka, Manabu Serizawa, Hirokazu Kobayashi, Kosei Kameta, Hiroshi Sugiyama, Teruo Matsuura, and Isao Saito
pp 1726 - 1732; DOI:
10.1021/ja00214a011
PDF
Intramolecular photochemical electron transfer. 4. Singlet and triplet mechanisms of electron transfer in a covalently linked porphyrin-amide-quinone molecule
John A. Schmidt, Alan R. McIntosh, Alan C. Weedon, James R. Bolton, John S. Connolly, John K. Hurley, and Michael R. Wasielewski
pp 1733 - 1740; DOI:
10.1021/ja00214a012
PDF
Biosynthesis of triterpenes, ursolic acid and oleanolic acid in tissue cultures of Rabdosia japonica Hara fed [5-13C2H2]mevalonolactone and [2-13C2H3]acetate
Shujiro Seo, Yohko Yoshimura, Atsuko Uomori, Kenichi Takeda, Haruo Seto, Yutaka Ebizuka, and Ushio Sankawa
pp 1740 - 1745; DOI:
10.1021/ja00214a013
PDF
Orbital-overlap factor in electron transfer: sensitivity of homogeneous self-exchange kinetics for some metallocenes to electronic structure
Roger M. Nielson, M. Neal Golovin, George E. McManis, and Michael J. Weaver
pp 1745 - 1749; DOI:
10.1021/ja00214a014
PDF
Infrared vibrational circular dichroism in the amide III spectral region of peptides
G. M. Roberts, O. Lee, J. Calienni, and Max Diem
pp 1749 - 1752; DOI:
10.1021/ja00214a015
PDF
Structures and transformations of the bacteriochlorophylls e and their bacteriopheophorbides
Daniel J. Simpson and Kevin M. Smith
pp 1753 - 1758; DOI:
10.1021/ja00214a016
PDF
Rapid protein sequencing by the enzyme-thermospray liquid chromatographic/mass spectrometric method
Krystyna Stachowiak, Cheryl Wilder, Marvin L. Vestal, and Douglas F. Dyckes
pp 1758 - 1765; DOI:
10.1021/ja00214a017
PDF
Formation, reactivity, and proposed structures of gas-phase triosmium cluster ions: H2Os3(CO)10+ and its dimers, trimers, and fragments
Steven L. Mullen and Alan G. Marshall
pp 1766 - 1774; DOI:
10.1021/ja00214a018
PDF
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. A theoretical and experimental investigation of the electronic structure of Ru2(CO)4(R-DAB)(.mu.-CO) and Ru2(CO)4(R-DAB)(.mu.-HC.tplbond.CH)
Maurizio Casarin, Andrea Vittadini, Kees Vrieze, Fred Muller, Gaetano Granozzi, and Renzo Bertoncello
pp 1775 - 1781; DOI:
10.1021/ja00214a019
PDF
Structure and chemistry of chemisorbed phosphorus trifluoride, phosphorus difluoride and phosphorus monofluoride on nickel(111): electron stimulated desorption ion angular distribution study
Mark D. Alvey and John T. Yates
pp 1782 - 1786; DOI:
10.1021/ja00214a020
PDF
Upper electronic excited states of quadruply bonded M2X4(PMe3)4 complexes
Michael D. Hopkins, Vincent M. Miskowski, and Harry B. Gray
pp 1787 - 1793; DOI:
10.1021/ja00214a021
PDF
Electronic structure of tetrakis(isopropylthio)thieno[3,4-c]thiophene studied by photoelectron and electronic absorption spectroscopies combined with MO calculations
Tsunetoshi Kobayashi, Kenji Ozaki, and Shigeo Yoneda
pp 1793 - 1796; DOI:
10.1021/ja00214a022
PDF
Regarding the inherent dependence of resonance effects of strongly conjugated substituents on electron demand
R. W. Taft, J. L. M. Abboud, Frederick Anvia, Michel Berthelot, Mizue Fujio, Jean Francois Gal, Allan D. Headley, William G. Henderson, Ilmar Koppel, and et al.
pp 1797 - 1800; DOI:
10.1021/ja00214a023
PDF
Intrazeolite chemistry of nickel(0) complexes and Ni(0,II) clusters studied by EXAFS, solid-state NMR and FT-IR spectroscopy
Thomas Bein, Stephan J. McLain, David R. Corbin, Rodney D. Farlee, Karin Moller, Galen D. Stucky, Geoffrey Woolery, and Dale Sayers
pp 1801 - 1810; DOI:
10.1021/ja00214a024
PDF
Matrix photochemistry of (.eta.5-cyclopentadienyl)bis(ethene)rhodium and (.eta.5-cyclopentadienyl)(ethene)carbonylrhodium: a test-bed for intermediates in C-H activation
David M. Haddleton, Andrew McCamley, and Robin N. Perutz
pp 1810 - 1817; DOI:
10.1021/ja00214a025
PDF
Low-symmetry, mixed-valent, .mu.-oxo technetium complexes with pyridine and halide ligands
Michael J. Clarke, M. E. Kastner, L. A. Podbielski, P. H. Fackler, J. Schreifels, G. Meinken, and S. C. Srivastava
pp 1818 - 1827; DOI:
10.1021/ja00214a026
PDF
Cobalt and manganese complexes of a Schiff base biquinone radical ligand
Scott K. Larsen and Cortlandt G. Pierpont
pp 1827 - 1832; DOI:
10.1021/ja00214a027
PDF
A LAXS (large angle x-ray scattering) and EXAFS (extended x-ray absorption fine structure) investigation of conductive amorphous nickel tetrathiolato polymers
Thomas Vogt, Christophe Faulmann, Regis Soules, Pierre Lecante, Alain Mosset, Paule Castan, Patrick Cassoux, and Jean Galy
pp 1833 - 1840; DOI:
10.1021/ja00214a028
PDF
Synthesis and structure of the polymetallic yttrium alkoxide complex Y3(.mu.-OCMe3)(.mu.3-Cl)(.mu.-OCMe3)3(OCMe3)4(THF)2 and related complexes: Ln3(.mu.3-OR)(.mu.3-X)(.mu.-OR)3 building blocks in yttrium and lanthanide alkoxide chemistry
William J. Evans, Mark S. Sollberger, and Timothy P. Hanusa
pp 1841 - 1850; DOI:
10.1021/ja00214a029
PDF
Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution
R. N. Mukherjee, T. D. P. Stack, and R. H. Holm
pp 1850 - 1861; DOI:
10.1021/ja00214a030
PDF
Reaction of diphenylmethyl cations in a strong acid. Participation of carbodications with positive charge substantially delocalized over the aromatic rings
Tomohiko Ohwada and Koichi Shudo
pp 1862 - 1870; DOI:
10.1021/ja00214a031
PDF
Theoretical elucidation of the origin of the anomalously high acidity of Meldrum's acid
Xuebao Wang and K. N. Houk
pp 1870 - 1872; DOI:
10.1021/ja00214a032
PDF
Acidity of (Z)- and (E)-methyl acetates: relationship to Meldrum's acid
Kenneth B. Wiberg and Keith E. Laidig
pp 1872 - 1874; DOI:
10.1021/ja00214a033
PDF
Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis
Curt Wentrup, Rodney Blanch, Horst Briehl, and Gerhard Gross
pp 1874 - 1880; DOI:
10.1021/ja00214a034
PDF
Interrelationship between carboxyvinylketenes, methyleneketenes, vinylketenes, and hydroxyacetylenes
Curt Wentrup and Primoz Lorencak
pp 1880 - 1883; DOI:
10.1021/ja00214a035
PDF
Thermochemistry of the orthogonal butadienes (Z,Z)-3,4-dimethylhexa-2,4-diene and 2,3-di-tert-butylbuta-1,3-diene
Wolfgang R. Roth, Hans Werner Lennartz, William v. E. Doering, William R. Dolbier, and John C. Schmidhauser
pp 1883 - 1889; DOI:
10.1021/ja00214a036
PDF
A single transition state in the reaction of aryl diphenylphosphinate esters with phenolate ions in aqueous solution
Nicholas Bourne, Edwin Chrystiuk, Andrew M. Davis, and Andrew Williams
pp 1890 - 1895; DOI:
10.1021/ja00214a037
PDF
Equilibration of diastereomeric two-chain surfactants. Hydrophobic control of organic stereochemistry
Ned A. Porter, Dong Ok, Jeffrey B. Huff, Christopher M. Adams, Andrew T. McPhail, and Kwang Kim
pp 1896 - 1901; DOI:
10.1021/ja00214a038
PDF
A general approach to the stereoselective synthesis of spiroketals. A total synthesis of the pheromones of the olive fruit fly and related compounds
Philip DeShong, Robert E. Waltermire, and Herman L. Ammon
pp 1901 - 1910; DOI:
10.1021/ja00214a039
PDF
High-pressure study on intramolecular excimer formation of 1,3-di-1-pyrenylpropane in various solvents
Kimihiko Hara and Hiroyuki Yano
pp 1911 - 1915; DOI:
10.1021/ja00214a040
PDF
Chemically mediated fluorescence yield switching in nitroxide-fluorophore adducts: optical sensors of radical/redox reactions
Neil V. Blough and Daniel J. Simpson
pp 1915 - 1917; DOI:
10.1021/ja00214a041
PDF
Structure, resolution, and racemization of decakis(dichloromethyl)biphenyl
Silvio E. Biali, Bart Kahr, Yoshio Okamoto, Ryo Aburatani, and Kurt Mislow
pp 1917 - 1922; DOI:
10.1021/ja00214a042
PDF
Photoaddition and photoreduction of chloranil with arenes via singlet and triplet excited complexes. Effects of irradiation wavelength and radical-ion pair spin multiplicity
Guilford Jones, William A. Haney, and Xuan T. Phan
pp 1922 - 1929; DOI:
10.1021/ja00214a043
PDF
Fluorescence-quenching mechanism of tryptophan. Remarkably efficient internal proton-induced quenching and charge-transfer quenching
Haruo Shizuka, Manabu Serizawa, Tsutomu Shimo, Isao Saito, and Teruo Matsuura
pp 1930 - 1934; DOI:
10.1021/ja00214a044
PDF
Iron-57 hyperfine coupling tensors of the FeMo cluster in Azotobacter vinelandii MoFe protein: determination by polycrystalline ENDOR spectroscopy
Anne E. True, Mark J. Nelson, Ronald A. Venters, William H. Orme-Johnson, and Brian M. Hoffman
pp 1935 - 1943; DOI:
10.1021/ja00214a045
PDF
Analysis of NMR and absorption spectroscopic data in bacteriorhodopsin: models for protein-chromophore interactions
Hillary S. Rodman Gilson and Barry H. Honig
pp 1943 - 1950; DOI:
10.1021/ja00214a046
PDF
Bacterial organomercurial lyase: novel enzymic protonolysis of organostannanes
Alan E. Walts and Christopher T. Walsh
pp 1950 - 1953; DOI:
10.1021/ja00214a047
PDF
Model reactions related to cytochrome P-450. Effects of alkene structure on the rates of epoxide formation
Teddy G. Traylor and Feng Xu
pp 1953 - 1958; DOI:
10.1021/ja00214a048
PDF
Cyclic cystine peptides. Antiparallel .beta.-sheet conformation for the 20-membered ring in Boc-Cys-Val-Aib-Ala-Leu-Cys-NHMe
Isabella L. Karle, R. Kishore, S. Raghothama, and P. Balaram
pp 1958 - 1963; DOI:
10.1021/ja00214a049
PDF
Stereoselective total synthesis of (.+-.)-atisine via intramolecular double Michael reaction
Masataka Ihara, Makoto Suzuki, Keiichiro Fukumoto, Tetsuji Kametani, and Chizuko Kabuto
pp 1963 - 1964; DOI:
10.1021/ja00214a050
PDF
Negative hyperconjugation. The rotation-inversion barrier in .alpha.-fluoramines
M. Moklesur Rahman, David M. Lemal, and W. P. Dailey
pp 1964 - 1966; DOI:
10.1021/ja00214a051
PDF
Reactions of MCl5 (M = niobium or tantalum) with excess phenyllithium: structural characterization of bisbenzyne/polyphenyl derivatives of niobium and tantalum
Ruth A. Bartlett, Philip P. Power, and Steven C. Shoner
pp 1966 - 1968; DOI:
10.1021/ja00214a052
PDF
Asymmetric dihydroxylation via ligand-accelerated catalysis
Eric N. Jacobsen, Istvan Marko, William S. Mungall, Georg Schroeder, and K. Barry Sharpless
pp 1968 - 1970; DOI:
10.1021/ja00214a053
PDF
Probing ergot alkaloid biosynthesis: identification of advanced intermediates along the biosynthetic pathway
Alan P. Kozikowski, Jiang Ping Wu, Masaaki Shibuya, and Heinz G. Floss
pp 1970 - 1971; DOI:
10.1021/ja00214a054
PDF
Convenient preparation and structures of selenometalates MoSe42-, WSe42- and MoSe92- from polyselenide anions and metal carbonyls
Samuel O'Neal and Joseph W. Kolis
pp 1971 - 1973; DOI:
10.1021/ja00214a055
PDF
Intramolecular exchange effects in multiple quantum spectroscopy
Mark Rance
pp 1973 - 1974; DOI:
10.1021/ja00214a056
PDF
Radical cation cyclization of 1,5-hexadiene to cyclohexene via the cyclohexane-2,5-diyl radical cation intermediate
Qing Xiang Guo, Xue Zhi Qin, Jih Tzong Wang, and Ffrancon Williams
pp 1974 - 1976; DOI:
10.1021/ja00214a057
PDF
Direct conversion of aldehydes to seleno- and thioaldehydes
Masahito Segi, Tadashi Nakajima, Sohei Suga, Shinji Murai, Ilhyong Ryu, Akiya Ogawa, and Noboru Sonoda
pp 1976 - 1978; DOI:
10.1021/ja00214a058
PDF
Intrinsic fluorescence and HPLC measurement of the surface dynamics of lysozyme adsorbed on hydrophobic silica
Xiao Ming Lu, Alvaro Figueroa, and Barry L. Karger
pp 1978 - 1979; DOI:
10.1021/ja00214a059
PDF
Evidence for a cytochrome P-450-catalyzed allylic rearrangement with double-bond topomerization
Robert H. McClanahan, Alain C. Huitric, Paul G. Pearson, John C. Desper, and Sidney D. Nelson
pp 1979 - 1981; DOI:
10.1021/ja00214a060
PDF
The acidity of benzyl ketones in aqueous solution. Evaluation of the intrinsic acidifying effect of a phenyl group
Angela M. Ross, Dale L. Whalen, Sherif Eldin, and Ralph M. Pollack
pp 1981 - 1982; DOI:
10.1021/ja00214a061
PDF
The acidity of 2-indanone. The effect of a conjugated phenyl group on enolate stability
J. R. Keeffe, Alexander J. Kresge, and Y. Yin
pp 1982 - 1983; DOI:
10.1021/ja00214a062
PDF
Molecular recognition in aqueous media: donor-acceptor and ion-dipole interactions produce tight binding for highly soluble guests
Timothy J. Shepodd, Michael A. Petti, and Dennis A. Dougherty
pp 1983 - 1985; DOI:
10.1021/ja00214a063
PDF
Total synthesis of glycinoeclepin A
Akio Murai, Norihiko Tanimoto, Noriyasu Sakamoto, and Tadashi Masamune
pp 1985 - 1986; DOI:
10.1021/ja00214a064
PDF
Heterobimetallic complexes with (.mu.-phenoxo)bis(.mu.-carboxylato) cores
A. S. Borovik, Lawrence Que, Vasilios Papaefthymiou, Eckard Muenck, Lucille F. Taylor, and Oren P. Anderson
pp 1986 - 1988; DOI:
10.1021/ja00214a065
PDF
Metazidohemerythrin models featuring a bis-benzimidazole tripod ligand. Structure and spectroscopy of .mu.-oxobis(.mu.-benzoato)bis(bis(2-benzimidazolylmethyl)amine)diiron(III)
Pedro Gomez-Romero, Nieves Casan-Pastor, Ahmed Ben-Hussein, and Geoffrey B. Jameson
pp 1988 - 1990; DOI:
10.1021/ja00214a066
PDF
Unprecedented rearrangement of a diphosphene .eta.1.eta.2-bonded to iron. Synthesis and x-ray structure of Fe4 complexes containing either a .mu.4 spiro phosphorus atom or a 1, 1, 2 trimetalla diphosphorus ligand .scharw.P:P-
Serge Attali, Francoise Dahan, Rene Mathieu, Anne Marie Caminade, and Jean Pierre Majoral
pp 1990 - 1991; DOI:
10.1021/ja00214a067
PDF
Effect of molecular dimension on the rate of return electron transfer within photoproduced geminate radical ion pairs
Ian R. Gould, Jacques E. Moser, Deniz Ege, and Samir Farid
pp 1991 - 1993; DOI:
10.1021/ja00214a068
PDF
Generation of simple enols by photooxidation. Keto-enol equilibrium constants of some aliphatic systems in aqueous solution
J. R. Keeffe, A. J. Kresge, and N. P. Schepp
pp 1993 - 1995; DOI:
10.1021/ja00214a069
PDF
Detection of the Fe-O-O-Fe intermediate in the oxidation reaction of ferrous porphyrins by resonance Raman spectroscopy
Insook R. Paeng, Hideaki Shiwaku, and Kazuo Nakamoto
pp 1995 - 1996; DOI:
10.1021/ja00214a070
PDF
Characterization of a crystalline synthetic analog of copper(II)-bleomycin
Steven J. Brown, Douglas W. Stephan, and Pradip K. Mascharak
pp 1996 - 1997; DOI:
10.1021/ja00214a071
PDF
Evidence for a common batho intermediate of rhodopsin and isorhodopsin
S. J. Hug, J. W. Lewis, and D. S. Kliger
pp 1998 - 1999; DOI:
10.1021/ja00214a072
PDF
Enzymic synthesis of macrocyclic lactones
Zhi Wei Guo and Charles J. Sih
pp 1999 - 2001; DOI:
10.1021/ja00214a073
PDF
Laser induced triplet excitons in the columnar phases of an octasubstituted metal free phthalocyanine
Dimitra Markovitsi, Thu Hoa Tran Thi, Valerie Briois, Jacques Simon, and Kazuchita Ohta
pp 2001 - 2002; DOI:
10.1021/ja00214a074
PDF
Carboxylic acid complexation by a synthetic analog of the "carboxylate-binding pocket" of vancomycin
Nalin Pant and Andrew D. Hamilton
pp 2002 - 2003; DOI:
10.1021/ja00214a075
PDF
Transition-metal-mediated photochemical disproportionation of carbon dioxide
Kenneth A. Belmore, Richard A. Vanderpool, Jing Cherng Tsai, Masood A. Khan, and Kenneth M. Nicholas
pp 2004 - 2005; DOI:
10.1021/ja00214a076
PDF
Gas-phase chemistry of the silaacetylide anion, HCSi-
Robert Damrauer, Charles H. DePuy, Stephan E. Barlow, and Scott Gronert
pp 2005 - 2006; DOI:
10.1021/ja00214a077
PDF
Antineoplastic agents. 147. Isolation and structure of the powerful cell growth inhibitor cephalostatin 1
George R. Pettit, Masuo Inoue, Yoshiaki Kamano, Delbert L. Herald, Christoph Arm, Claude Dufresne, Nigel D. Christie, Jean M. Schmidt, Dennis L. Doubek, and Timothy S. Krupa
pp 2006 - 2007; DOI:
10.1021/ja00214a078
PDF
Degradation of DNA-RNA hybrids by bleomycin: evidence for DNA strand specificity and for possible structural modulation of chemical mechanism
C. R. Krishnamoorthy, Dana E. Vanderwall, John W. Kozarich, and JoAnne Stubbe
pp 2008 - 2009; DOI:
10.1021/ja00214a079
PDF
Electrochemistry at the water/air interface. Lateral electron transport in Langmuir monolayers
Cindra A. Widrig, Cary J. Miller, and Marcin Majda
pp 2009 - 2011; DOI:
10.1021/ja00214a080
PDF
Actinide bis(porphyrinate) .pi.-radical cations and dications, including the x-ray crystal structure of [(TPP)2Th][SbCl6]
Gregory S. Girolami, Stanley N. Milam, and Kenneth S. Suslick
pp 2011 - 2012; DOI:
10.1021/ja00214a081
PDF
Theory of vibrational circular dichroism: trans-2,3-dideuteriooxirane
K. J. Jalkanen, Philip J. Stephens, R. D. Amos, and N. C. Handy
pp 2012 - 2013; DOI:
10.1021/ja00214a082
PDF
A convenient method for the generation of o-quinodimethanes by proton induced 1,4-elimination of o-(1-hydroxyalkyl)benzyltributylstannanes
Hiroshi Sano, Hideki Ohtsuka, and Toshihiko Migita
pp 2014 - 2015; DOI:
10.1021/ja00214a083
PDF
Fingerprints of the carbon-nitrogen bond formation between ethylenediamine and an aldose on cobalt(III) complexes. Isotopic multiplets in the carbon-13 NMR spectra of cobalt(III) complexes with partially deuteriated coordinated amino groups
Katsuaki Ishida, Morio Yashiro, Shigenobu Yano, Masanbu Hidai, and Sadao Yoshikawa
pp 2015 - 2016; DOI:
10.1021/ja00214a084
PDF
Synthesis and polymerization of .gamma.-trichloroethyl-L-glutamate N-carboxyanhydride: a polypeptide that can be functionalized with a nucleophilic agent
Kazunori Ishikawa and Takeshi Endo
pp 2016 - 2017; DOI:
10.1021/ja00214a085
PDF
Corrections. Micellar Control of Organic Reactions: Propellane Substrates as Stereochemical Probes for Micellar Binding
Anand Natrajan, Joseph D. Ferrara, Wiley J. Youngs, and Chaim N. Sukenik
pp 2018 - 2018; DOI:
10.1021/ja00214a600
PDF
Correction. Isotopically Sensitive Branching and Its Effect on the Observed Intramolecular Isotope Effects in Cytochrome P-450 Catalyzed Reactions: A New Method for the Estimation of Intrinsic Isotope Effects
Jeffrey P. Jones, Kenneth R. Korzekwa, Allan E. Rettie, and William F. Trager
pp 2018 - 2018; DOI:
10.1021/ja00214a601
PDF
Corrections. The Separation of the Intramolecular Isotope Effect for the Cytochrome P-450 Catalyzed Hydroxylation of N-Octane int Its Primary and Secondary Components

pp 2018 - 2018; DOI:
10.1021/ja00214a602
PDF
Book Reviews

pp 2018 - 2022; DOI:
10.1021/ja00214a603
PDF

Issue 7


Proton NMR study of dehydration of the silica gel surface
Charles E. Bronnimann, Robert C. Zeigler, and Gary E. Maciel
pp 2023 - 2026; DOI:
10.1021/ja00215a001
PDF
Catecholate LMCT bands as probes for the active sites of nonheme iron oxygenases
D. D. Cox, S. J. Benkovic, L. M. Bloom, F. C. Bradley, M. J. Nelson, L. Que, and D. E. Wallick
pp 2026 - 2032; DOI:
10.1021/ja00215a002
PDF
The nature of the phosphorus-phosphorus double bond as studied by solid-state NMR
Kurt W. Zilm, Gretchen G. Webb, Alan H. Cowley, Marek Pakulski, and Anita Orendt
pp 2032 - 2038; DOI:
10.1021/ja00215a003
PDF
The reaction dimension in catalysis on dispersed metals
Dina Farin and David Avnir
pp 2039 - 2045; DOI:
10.1021/ja00215a004
PDF
SINDO1 study of the di-.pi.-methane photochemical reaction mechanism
Karl Jug, Ruediger Iffert, and Peter L. Mueller-Remmers
pp 2045 - 2049; DOI:
10.1021/ja00215a005
PDF
Molecular mechanics calculations on conjugated nitrogen-containing heterocycles
Julia C. Tai and Norman L. Allinger
pp 2050 - 2055; DOI:
10.1021/ja00215a006
PDF
Photophysical properties of fluorescent N-purin-6-ylpyridinium chloride
B. Skalski, R. P. Steer, and R. E. Verrall
pp 2055 - 2061; DOI:
10.1021/ja00215a007
PDF
HxMoO3 bronzes: structures, stabilities, and electronic properties
S. P. Mehandru and Alfred B. Anderson
pp 2061 - 2065; DOI:
10.1021/ja00215a008
PDF
Mechanism of base-induced gas-phase elimination reactions of cyclic thio ethers
Leo J. De Koning and Nico M. M. Nibbering
pp 2066 - 2073; DOI:
10.1021/ja00215a009
PDF
Rhodium-carbon monoxide surface chemistry: the involvement of surface hydroxyl groups on alumina and silica supports
P. Basu, D. Panayotov, and John T. Yates
pp 2074 - 2081; DOI:
10.1021/ja00215a010
PDF
Methoxyethylene ozonide: analysis of the structure and anomeric effect by microwave spectroscopy and ab initio techniques
Marabeth S. LaBarge, Helmut Keul, Robert L. Kuczkowski, Markus Wallasch, and Dieter Cremer
pp 2081 - 2089; DOI:
10.1021/ja00215a011
PDF
Transition structures for homodienyl 1,5-sigmatropic hydrogen shifts: origin of the high endo stereoselectivity
Richard J. Loncharich and K. N. Houk
pp 2089 - 2092; DOI:
10.1021/ja00215a012
PDF
Electronic spectra and chemical reactivity
Ralph G. Pearson
pp 2092 - 2097; DOI:
10.1021/ja00215a013
PDF
Recombination of Cr(CO)n with CO: kinetics and bond dissociation energies
T. Rick Fletcher and Robert N. Rosenfeld
pp 2097 - 2101; DOI:
10.1021/ja00215a014
PDF
Ab initio heats of formation of medium-sized hydrocarbons. 7. The [n]prismanes
Raymond L. Disch and Jerome M. Schulman
pp 2102 - 2105; DOI:
10.1021/ja00215a015
PDF
A comparison of the energies of double bonds of second-row elements with carbon and silicon
Paul v. R. Schleyer and Daniel Kost
pp 2105 - 2109; DOI:
10.1021/ja00215a016
PDF
An electrochemical study of the substitution and decomposition reactions of (arene)tricarbonylchromium radical cations
C. G. Zoski, D. A. Sweigart, N. J. Stone, P. H. Rieger, E. Mocellin, T. F. Mann, D. R. Mann, D. K. Gosser, M. M. Doeff, and A. M. Bond
pp 2109 - 2116; DOI:
10.1021/ja00215a017
PDF
A nickel(0) dimer/monomer system with facile and reversible carbon monoxide uptake: Ni2(CO)x(dppm)2 (x = 3, 4) and Ni(CO)3(.eta.1-dppm)
John A. Osborn, George G. Stanley, and Peter H. Bird
pp 2117 - 2122; DOI:
10.1021/ja00215a018
PDF
Evidence for the intermediacy of chromium-ketene complexes in the synthesis of .beta.-lactams by the photolytic reaction of chromium-carbene complexes with imines. Use in amino acid synthesis
Louis S. Hegedus, Guy De Weck, and Stan D'Andrea
pp 2122 - 2126; DOI:
10.1021/ja00215a019
PDF
Studies of silicoaluminophosphates with the sodalite structure
Dennis Hasha, Ligia Sierra de Saldarriaga, Carlos Saldarriaga, Paul E. Hathaway, David F. Cox, and Mark E. Davis
pp 2127 - 2135; DOI:
10.1021/ja00215a020
PDF
Fluorides and fluoro acids. Part 18. The system pyridine-hydrogen fluoride at low temperatures. Formation and crystal structures of solid complexes with very strong NHF and FHF hydrogen bonding
Dagmar Boenigk and Dietrich Mootz
pp 2135 - 2139; DOI:
10.1021/ja00215a021
PDF
Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: relevance to molybdoenzymes
John P. Caradonna, P. Rabindra Reddy, and R. H. Holm
pp 2139 - 2144; DOI:
10.1021/ja00215a022
PDF
Low-lying singlet and triplet electronic excited states of binuclear (d10-d10) palladium(0) and platinum(0) complexes
Pierre D. Harvey and Harry B. Gray
pp 2145 - 2147; DOI:
10.1021/ja00215a023
PDF
Cis and trans olefin radicals: equilibrium and photoisomerization
T. W. Ebbesen, R. Akaba, K. Tokumaru, M. Washio, S. Tagawa, and Y. Tabata
pp 2147 - 2151; DOI:
10.1021/ja00215a024
PDF
Carotenoid cation radicals: electrochemical, optical, and EPR study
Janice L. Grant, Vincent J. Kramer, Ruisong Ding, and Lowell D. Kispert
pp 2151 - 2157; DOI:
10.1021/ja00215a025
PDF
Photochemical generation of [4]paracyclophanes from 1,4-tetramethylene Dewar benzenes: their electronic absorption spectra and reactions with alcohols
Takashi Tsuji and Shinya Nishida
pp 2157 - 2164; DOI:
10.1021/ja00215a026
PDF
Direct and sensitized photoisomerization of 1,4-diphenylbutadienes
W. Atom Yee, Stephan J. Hug, and David S. Kliger
pp 2164 - 2169; DOI:
10.1021/ja00215a027
PDF
Liquid-crystalline solvents as mechanistic probes. 26. Norrish II photolyses and deuterium magnetic resonance studies on the solubilization sites and mobilities of 2- and sym-alkanones in interdigitated and bilayer gel phases of aqueous surfactants
Richard L. Treanor and Richard G. Weiss
pp 2170 - 2177; DOI:
10.1021/ja00215a028
PDF
Liquid-crystalline solvents as mechanistic probes. 29. Chiral discotic columnar mesophases from the .alpha. and .beta. anomers of penta-O-n-alkanoylglucopyranoses
Nancy L. Morris, Richard G. Zimmermann, Geoffrey B. Jameson, Adam W. Dalziel, P. Matthew Reuss, and Richard G. Weiss
pp 2177 - 2185; DOI:
10.1021/ja00215a029
PDF
Simultaneous 1,2-introduction of allylic and .alpha.,.beta.,.gamma.,.delta.-unsaturated acyl groups into isoquinoline systems and subsequent intramolecular Diels-Alder reactions
Ryohei Yamaguchi, Atsuo Otsuji, and Kiichiro Uchimoto
pp 2186 - 2187; DOI:
10.1021/ja00215a030
PDF
Reactivity of .alpha.-heteroatom-substituted alkyl radicals with nitrobenzenes in aqueous solution: an entropy controlled electron transfer/addition mechanism
V. Jagannadham and S. Steenken
pp 2188 - 2192; DOI:
10.1021/ja00215a031
PDF
Synthesis and properties of purinophanes. Relationship between the magnitude of hypochromism and stacking geometry of purine rings
F. Seyama, K. Akahori, Y. Sakata, S. Misumi, M. Aida, and C. Nagata
pp 2192 - 2201; DOI:
10.1021/ja00215a032
PDF
The first silylenium ions in solution
Joseph B. Lambert, William J. Schulz, JoAnn A. McConnell, and Wojciech Schilf
pp 2201 - 2210; DOI:
10.1021/ja00215a033
PDF
Intramolecular radical cyclization of phenolic enolates
Andrew S. Kende, Kevin Koch, and Cynthia A. Smith
pp 2210 - 2218; DOI:
10.1021/ja00215a034
PDF
Organobis(cuprates): a new class of reagents and method for spiroannelation
Paul A. Wender and Alan W. White
pp 2218 - 2223; DOI:
10.1021/ja00215a035
PDF
Comparison of the efficiencies of several natural and synthetic antioxidants in aqueous SDS [sodium dodecyl sulfate] micelle solutions
William A. Pryor, Theodore Strickland, and Daniel F. Church
pp 2224 - 2229; DOI:
10.1021/ja00215a036
PDF
Host-guest complexation. 46. Cavitands as open molecular vessels form solvates
Donald J. Cram, Stefan Karbach, Hye Eun Kim, Carolyn B. Knobler, Emily F. Maverick, John L. Ericson, and Roger C. Helgeson
pp 2229 - 2237; DOI:
10.1021/ja00215a037
PDF
Synthesis of optically pure .alpha.-amino acids via salts of .alpha.-amino-.beta.-propiolactone
Lee D. Arnold, Robert G. May, and John Christopher Vederas
pp 2237 - 2241; DOI:
10.1021/ja00215a038
PDF
Methods for indole alkaloid synthesis. A study of the compatibility of the indole-2,3-quinodimethane strategy for the synthesis of 16-methoxy-substituted aspidosperma-type alkaloids. Synthesis of (+)- and (-)-16-methoxytabersonine
Kevin Cardwell, Brian Hewitt, Mark Ladlow, and Philip Magnus
pp 2242 - 2248; DOI:
10.1021/ja00215a039
PDF
Total synthesis of (-)-laurenyne. Use of acetal-initiated cyclizations to prepare functionalized eight-membered cyclic ethers
Larry E. Overman and Andrew S. Thompson
pp 2248 - 2256; DOI:
10.1021/ja00215a040
PDF
Pyridine nucleotide chemistry. A new mechanism for the hydroxide-catalyzed hydrolysis of the nicotinamide-glycosyl bond
Randy W. Johnson, Thomas M. Marschner, and Norman J. Oppenheimer
pp 2257 - 2263; DOI:
10.1021/ja00215a041
PDF
Synthesis of the heme d prosthetic group of bacterial terminal oxidase
Chariklia Sotiriou and C. K. Chang
pp 2264 - 2270; DOI:
10.1021/ja00215a042
PDF
Multicomponent redox catalysts for reduction of large biological molecules using molecular hydrogen as the reductant
Shuchi Chao, Richard A. Simon, Thomas E. Mallouk, and Mark S. Wrighton
pp 2270 - 2276; DOI:
10.1021/ja00215a043
PDF
Solid-state conformation of anti-human immunodeficiency virus type-1 agents: Crystal structures of three 3'-azido-3'-deoxythymidine analogs
Patrick Van Roey, Jeffrey M. Salerno, William L. Duax, Chung K. Chu, Moon K. Ahn, and Raymond F. Schinazi
pp 2277 - 2282; DOI:
10.1021/ja00215a044
PDF
Antibody catalysis approaching the activity of enzymes
Alfonso Tramontano, Adrian A. Ammann, and Richard A. Lerner
pp 2282 - 2286; DOI:
10.1021/ja00215a045
PDF
Specific ring stacking interaction on the tryptophan-7-methylguanine system: comparative crystallographic studies of indole derivatives-7-methylguanine base, nucleoside, and nucleotide complexes
Toshimasa Ishida, Mitsunobu Doi, Hitoshi Ueda, Masatoshi Inoue, and George M. Scheldrick
pp 2286 - 2294; DOI:
10.1021/ja00215a046
PDF
Solid/liquid intermolecular transfer of dynamic nuclear polarization. Enhanced flowing fluid proton NMR signals via immobilized spin labels
R. Gitti, C. Wild, C. Tsiao, K. Zimmer, T. E. Glass, and Harry C. Dorn
pp 2294 - 2296; DOI:
10.1021/ja00215a047
PDF
Dependence of the lifetime of the twisted excited singlet state of tetraphenylethylene on solvent polarity
Charles L. Schilling and Edwin F. Hilinski
pp 2296 - 2298; DOI:
10.1021/ja00215a048
PDF
Ab initio calculations of the effects of substituents on the stabilization of silyl radicals versus methyl radicals
Michael B. Coolidge and Weston Thatcher Borden
pp 2298 - 2299; DOI:
10.1021/ja00215a049
PDF
Study of energy transfer from upper triplet states in solution using two-laser two-photon excitation
W. G. McGimpsey and J. C. Scaiano
pp 2299 - 2301; DOI:
10.1021/ja00215a050
PDF
A simple synthesis of dienones via isomerization of alkynones effected by palladium catalysts
Barry M. Trost and Thomas Schmidt
pp 2301 - 2303; DOI:
10.1021/ja00215a051
PDF
Trihydrogen complexes of iridium
D. Michael Heinekey, Neil G. Payne, and Gayle K. Schulte
pp 2303 - 2305; DOI:
10.1021/ja00215a052
PDF
Stereochemistry and mechanism of [4 + 2] photocycloaddition of Pummerer's ketone to furan
Mladen Mintas, David I. Schuster, and Paul G. Williard
pp 2305 - 2306; DOI:
10.1021/ja00215a053
PDF
Ionic strength dependence of intervalence transition bands in electron tunnelling processes
Nita A. Lewis and Yaw S. Obeng
pp 2306 - 2307; DOI:
10.1021/ja00215a054
PDF
Three-center binding of a nitroxyl free radical to copper(II) bromide
Andrea Caneschi, Andre Grand, Jean Laugier, Paul Rey, and Robert Subra
pp 2307 - 2309; DOI:
10.1021/ja00215a055
PDF
The electronic structures of trans- and cis-bicyclo[4.1.0]hept-3-ene. Evidence for a twist, bent .sigma. bond
David A. Dixon and Paul G. Gassman
pp 2309 - 2310; DOI:
10.1021/ja00215a056
PDF
Synthesis of main group heterocycles by metallacycle transfer from zirconium
Paul J. Fagan and William A. Nugent
pp 2310 - 2312; DOI:
10.1021/ja00215a057
PDF
An organochromium-mediated synthesis of 11-deoxydaunomycinone via a tandem benzannulation/Friedel-Crafts double cyclization
William D. Wulff and Yao Chang Xu
pp 2312 - 2314; DOI:
10.1021/ja00215a058
PDF
Transition structures for the Claisen rearrangement
Robert L. Vance, Nelson G. Rondan, K. N. Houk, Frank Jensen, Weston Thatcher Borden, Andrew Komornicki, and Erich Wimmer
pp 2314 - 2315; DOI:
10.1021/ja00215a059
PDF
The biosynthesis of sparsomycin. Elucidation of the origins of the carbon skeleton
Ronald J. Parry and Mary Elizabeth Eudy
pp 2316 - 2317; DOI:
10.1021/ja00215a060
PDF
Synthesis of inositol phosphates
James L. Meek, Fred Davidson, and Frank W. Hobbs
pp 2317 - 2318; DOI:
10.1021/ja00215a061
PDF
An exceptionally simple method of preparing matrix-isolated biradicals, biradicaloids, and carbenes
Karl Haider, Matthew S. Platz, Allan Despres, Violen Lejeune, Eva Migirdicyan, Thomas Bally, and Edwin Haselbach
pp 2318 - 2320; DOI:
10.1021/ja00215a062
PDF
Delineation of .alpha.-helical domains in deuteriated Staphylococcal nuclease by 2D NOE NMR spectroscopy
Dennis A. Torchia, Steven W. Sparks, and Ad Bax
pp 2320 - 2321; DOI:
10.1021/ja00215a063
PDF
Solid-state voltammetry of a protein in a polymer solvent
B. N. Oliver, J. O. Egekeze, and Royce W. Murray
pp 2321 - 2322; DOI:
10.1021/ja00215a064
PDF
Sensitive mass spectrometry of molecular adsorbates by stimulated desorption and single-photon ionization
U. Schuhle, J. B. Pallix, and C. H. Becker
pp 2323 - 2324; DOI:
10.1021/ja00215a065
PDF
Accelerating symmetry forbidden reactions: the vinylcyclopropane .fwdarw. cyclopentene cation radical rearrangement
J. P. Dinnocenzo and D. A. Conlon
pp 2324 - 2326; DOI:
10.1021/ja00215a066
PDF
Electron-transfer reactions in cyanine borate ion pairs: photopolymerization initiators sensitive to visible light
Subhankar Chatterjee, Peter Gottschalk, Paul D. Davis, and Gary B. Schuster
pp 2326 - 2328; DOI:
10.1021/ja00215a067
PDF
Palladium-catalyzed polyene cyclizations of dienyl aryl iodides
Matthew M. Abelman and Larry E. Overman
pp 2328 - 2329; DOI:
10.1021/ja00215a068
PDF
Microwave spectrum of uracil
Ronald D. Brown, Peter D. Godfrey, Donald McNaughton, and Anthony P. Pierlot
pp 2329 - 2330; DOI:
10.1021/ja00215a069
PDF
Structural characterization by EXAFS spectroscopy of the binuclear iron center in protein A of methane monooxygenase from Methylococcus capsulatus (Bath)
Agneta Ericson, Britt Hedman, Keith O. Hodgson, Jeffrey Green, Howard Dalton, James G. Bentsen, Robert H. Beer, and Stephen J. Lippard
pp 2330 - 2332; DOI:
10.1021/ja00215a070
PDF
Synthesis and structure of [CpRu(PPh3)2(SC2H4)]OSO2CF3. A transition-metal analog of an episulfonium salt
Jayantha Amarasekera, Thomas B. Rauchfuss, and Scott R. Wilson
pp 2332 - 2334; DOI:
10.1021/ja00215a071
PDF
Mechanism of formation of coordination polymers: a structural model for polymer chain growth
Thomas G. Richmond, Eric P. Kelson, Atta M. Arif, and Gene B. Carpenter
pp 2334 - 2335; DOI:
10.1021/ja00215a072
PDF
A model for the unsaturated intermediate in dissociative electron-transfer catalyzed substitution reactions of organometallic compounds
Bernadette T. Donovan and William E. Geiger
pp 2335 - 2337; DOI:
10.1021/ja00215a073
PDF
Diastereoselective reactions of chiral-at-iron carbene complexes C5H5(CO)(PR3)Fe:CHR+. Synclinal isomers are more reactive than anticlinal isomers
M. Brookhart, Yumin Liu, and Robert C. Buck
pp 2337 - 2339; DOI:
10.1021/ja00215a074
PDF
Isonitrile biosynthesis in the cyanophyte Hapalosiphon fontinalis
Volker Bornemann, Gregory M. L. Patterson, and Richard E. Moore
pp 2339 - 2340; DOI:
10.1021/ja00215a075
PDF
Synthesis via vinyl sulfones. 27. Total synthesis of cephalotaxine. The first example of an intramolecular [4 + 2] cycloaddition where the dienophile has been delivered from the face opposite to the tethering moiety
T. P. Burkholder and P. L. Fuchs
pp 2341 - 2342; DOI:
10.1021/ja00215a076
PDF
Poly(n-hexylsilyne): synthesis and properties of the first alkyl silicon [RSi]n network polymer
Patricia A. Bianconi and Timothy W. Weidman
pp 2342 - 2344; DOI:
10.1021/ja00215a077
PDF
New tetrodotoxin analogs from the newt Cynops ensicauda
Takeshi Yasumoto, Mari Yotsu, Michio Murata, and Hideo Naoki
pp 2344 - 2345; DOI:
10.1021/ja00215a078
PDF
Models for the iron(II)iron(III) and iron(II)iron(II) forms of iron-oxo proteins
A. S. Borovik and Lawrence Que
pp 2345 - 2347; DOI:
10.1021/ja00215a079
PDF
Alteration of bleomycin cleavage specificity in a platinated DNA oligomer of defined structure
Barry Gold, V. Dange, Mark A. Moore, Alan Eastman, Gijs A. Van der Marel, Jacques H. Van Boom, and Sidney M. Hecht
pp 2347 - 2349; DOI:
10.1021/ja00215a080
PDF
Determination of the absolute configurations of the isomers of triamminecobalt(III) adenosine triphosphate [Erratum to document cited in CA105(3):20891F]
David C. Speckhard, Vincent L. Pecoraro, Wilson B. Knight, and W. W. Cleland
pp 2349 - 2349; DOI:
10.1021/ja00215a081
PDF
Nitroethylene yields (N,N-dihydroxyiminium)methylium dication in trifluoromethanesulfonic acid. Dications stabilized by Y delocalization [Erratum to document cited in CA107(23):216993B]
Tomohiko Ohwada, Akiko Itai, Toshiharu Ohta, and Koichi Shudo
pp 2349 - 2349; DOI:
10.1021/ja00215a082
PDF
Book Reviews

pp 2350 - 2352; DOI:
10.1021/ja00215a600
PDF

Issue 8


Contributions from electron correlation to the relative stabilities of the tautomers of nucleic acid bases
Jozef S. Kwiatkowski, Rodney J. Bartlett, and Willis B. Person
pp 2353 - 2358; DOI:
10.1021/ja00216a001
PDF
Computational evidence for an unusual transition state in the fluxional behavior of the cyclopentadienyl ligand in chlorotris(cyclopentadienyl)titanium(IV)
Lillian M. Hansen and Dennis S. Marynick
pp 2358 - 2361; DOI:
10.1021/ja00216a002
PDF
Circular dichroism of the carbonyl n-.pi.* transition: an independent systems/perturbation approach
Alison Rodger and P. Mark Rodger
pp 2361 - 2368; DOI:
10.1021/ja00216a003
PDF
Reaction of singlet oxygen with organic sulfides. A theoretical study
Frank Jensen and Christopher S. Foote
pp 2368 - 2375; DOI:
10.1021/ja00216a004
PDF
Remarkable stabilities of the diatomic multiply charged cations SiHe.cntdot.3+ and SiHe4+
Ming Wah Wong and Leo Radom
pp 2375 - 2378; DOI:
10.1021/ja00216a005
PDF
Determination of 15N chemical shift tensor via 15N-2H dipolar coupling in Boc-glycylglycyl[15N glycine]benzyl ester
Yukio Hiyama, Chien Hua Niu, James V. Silverton, Alfonso Bavoso, and Dennis A. Torchia
pp 2378 - 2383; DOI:
10.1021/ja00216a006
PDF
Head-group orientation of a glycolipid analog from deuterium NMR data
Preetha Ram and J. H. Prestegard
pp 2383 - 2388; DOI:
10.1021/ja00216a007
PDF
Heteronuclear filters for two-dimensional proton NMR. Identification of the metal-bound amino acids in metallothionein and observation of small heteronuclear long-range couplings
Erich Woergoetter, Gerhard Wagner, Milan Vasak, Jeremias H. R. Kaegi, and Kurt Wuethrich
pp 2388 - 2393; DOI:
10.1021/ja00216a008
PDF
Chemical reactions of imidazole with metallic silver studied by the use of SERS and XPS techniques
Gi Xue, Quinpin Dai, and Shuangen Jiang
pp 2393 - 2395; DOI:
10.1021/ja00216a009
PDF
Gas-phase reactions of silicon ion (Si+ with ammonia and the amines (CH3)xNH3-x(X = 1-3): possible ion-molecule reaction pathways toward SiH, SiCH, SiNH, SiCH3, SiNCH3, and H2SiNH
S. Wlodek and Diethard K. Bohme
pp 2396 - 2399; DOI:
10.1021/ja00216a010
PDF
Cp2Zr(N=CPh2)2, an organometallic heteroallene-type Schiff base derivative relevant to describing sp2-hybridized nitrogen inversion
Gerhard Erker, Wolfgang Froemberg, Carl Krueger, and Eleonore Raabe
pp 2400 - 2405; DOI:
10.1021/ja00216a011
PDF
Substituent effects on the cleavage rates of titanocene metallacyclobutanes
William C. Finch, Eric V. Anslyn, and Robert H. Grubbs
pp 2406 - 2413; DOI:
10.1021/ja00216a012
PDF
Oxygen atom transfer reactions to metal carbonyls. Kinetics and mechanism of CO substitution reactions of M3(CO)12 (M = Fe, Ru, Os) in the presence of (CH3)3NO
Jiankun Shen, Yianlong Shi, Yici Gao, Qizhen Shi, and Fred Basolo
pp 2414 - 2418; DOI:
10.1021/ja00216a013
PDF
Intrinsic barriers to proton exchange between transition-metal centers: application of a weak-interaction model
Carol Creutz and Norman Sutin
pp 2418 - 2427; DOI:
10.1021/ja00216a014
PDF
Synthesis, structure, dynamic behavior, and reactivity of rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PR2): the gauche effect in transition-metal chemistry
William E. Buhro, Bill D. Zwick, Savas Georgiou, John P. Hutchinson, and J. A. Gladysz
pp 2427 - 2439; DOI:
10.1021/ja00216a015
PDF
Redox-promoted linkage isomerizations of aldehydes and ketones on pentaammineosmium
W. Dean Harman, Mikiya Sekine, and Henry Taube
pp 2439 - 2445; DOI:
10.1021/ja00216a016
PDF
Rubidium x-ray absorption (EXAFS and XANES) studies of Rb- and complexed Rb+ in alkalides and electrides
Odette Fussa-Rydel, James L. Dye, and Boon K. Teo
pp 2445 - 2451; DOI:
10.1021/ja00216a017
PDF
Singlet molecular oxygen: not a major product of the reaction between tris(2,2'-bipyridine)ruthenium(3+) and superoxide radical anions
Q. G. Mulazzani, M. Ciano, M. D'Angelantonio, M. Venturi, and M. A. J. Rodgers
pp 2451 - 2457; DOI:
10.1021/ja00216a018
PDF
Substituted complexes of enterobactin and synthetic analogs as probes of the ferric-enterobactin receptor in Escherichia coli
David J. Ecker, Lawrence D. Loomis, Marion E. Cass, and Kenneth N. Raymond
pp 2457 - 2464; DOI:
10.1021/ja00216a019
PDF
The formation, characterization, and reactivity of the oxene adduct of [tetrakis(2,6-dichlorophenyl)porphinato]iron(III) perchlorate in acetonitrile. Model for the reactive intermediate of cytochrome P-450
Hiroshi Sugimoto, Hui Chan Tung, and Donald T. Sawyer
pp 2465 - 2470; DOI:
10.1021/ja00216a020
PDF
Pressure effects on the intervalence-transfer band of salts of mixed-valence 1',1'''-disubstituted biferrocenium cations
Usha Sinha, Michael D. Lowery, Walter W. Ley, Harry G. Drickamer, and David N. Hendrickson
pp 2471 - 2477; DOI:
10.1021/ja00216a021
PDF
Stereochemistry of crown ethers and their complexes in the solid state. Carbon-13 CPMAS NMR and x-ray crystallographic studies of configurationally isomeric dicyclohexano-14-crown-4 ethers, dibenzo-14-crown-4 ether, and some lithium thiocyanate salts
G. W. Buchanan, R. A. Kirby, and J. P. Charland
pp 2477 - 2483; DOI:
10.1021/ja00216a022
PDF
Subsite-differentiated analogs of biological [4Fe-4S]2+ clusters: synthesis, solution and solid-state structures, and subsite-specific reactions
T. D. P. Stack and R. H. Holm
pp 2484 - 2494; DOI:
10.1021/ja00216a023
PDF
Functional capsule membranes. Part 31. Polymerizable lipid-corked capsule membranes. Polymerization at different positions of corking lipid bilayers on the capsule and effect of polymerization on permeation behavior
Yoshio Okahata, Katsuhiko Ariga, and Takahiro Seki
pp 2495 - 2500; DOI:
10.1021/ja00216a024
PDF
Alkynylation of mixed acetals with organotin acetylides
Dongguan Zhai, Weixu Zhai, and Robert M. Williams
pp 2501 - 2505; DOI:
10.1021/ja00216a025
PDF
The total synthesis of the polyether antibiotic X-206
David A. Evans, Steven L. Bender, and Joel Morris
pp 2506 - 2526; DOI:
10.1021/ja00216a026
PDF
1,4-Perinaphthadiyl. Singlet- and triplet-state reactivity of a conjugated hydrocarbon biradical
Michael N. Burnett, Richard Boothe, Ernest Clark, Markus Gisin, Hamdi M. Hassaneen, Richard M. Pagni, Gabriele Persy, Robert J. Smith, and Jakob Wirz
pp 2527 - 2538; DOI:
10.1021/ja00216a027
PDF
Acid-catalyzed nucleophilic aromatic photosubstitution. A reconsideration of protonation in excited states of nitrobenzenes
Gene G. Wubbels, Douglas P. Susens, and E. Bryan Coughlin
pp 2538 - 2542; DOI:
10.1021/ja00216a028
PDF
Hydrochloric acid-catalyzed photoreduction of 4-bromonitrobenzene as a concomitant of nucleophilic aromatic photosubstitution involving radical intermediates
Gene G. Wubbels, Eric J. Snyder, and E. Bryan Coughlin
pp 2543 - 2548; DOI:
10.1021/ja00216a029
PDF
Triene photophysics and photochemistry: previtamin D3
William G. Dauben, Paul E. Share, and Richard R. Ollmann
pp 2548 - 2554; DOI:
10.1021/ja00216a030
PDF
Host-guest complexation. 47. Carcerands and carcaplexes, the first closed molecular container compounds
Donald J. Cram, Stefan Karbach, Young Hwan Kim, Lubomir Baczynskyj, Kurt Marti, Russ M. Sampson, and Gregory W. Kalleymeyn
pp 2554 - 2560; DOI:
10.1021/ja00216a031
PDF
Friedel-Crafts chemistry. 11. Boron, aluminum, and gallium tris(trifluoromethanesulfonate) (triflate): effective new Friedel-Crafts catalysts
George A. Olah, Omar Farooq, S. M. F. Farnia, and Judith A. Olah
pp 2560 - 2565; DOI:
10.1021/ja00216a032
PDF
Rearrangement of suitably constituted aryl, alkyl, or vinyl radicals by acyl or cyano group migration
Athelstan L. J. Beckwith, D. M. O'Shea, and Steven W. Westwood
pp 2565 - 2575; DOI:
10.1021/ja00216a033
PDF
A general method for the preparation of carbonyl compounds and butenolides from organomanganese pentacarbonyl complexes
Philip DeShong, Daniel R. Sidler, Philip J. Rybczynski, Greg A. Slough, and Arnold L. Rheingold
pp 2575 - 2585; DOI:
10.1021/ja00216a034
PDF
Reactions of imidazole-2-thiones with molecular iodine and the structures of two crystalline modifications of the 1:1 1,3-dimethylimidazole-2-thione-diiodine charge-transfer complex (C5H8I2N2S)
Fillmore Freeman, Joseph W. Ziller, Henry N. Po, and Monica C. Keindl
pp 2586 - 2591; DOI:
10.1021/ja00216a035
PDF
Uni- and biparticulate electrophilic additions to conjugated bis(bicyclo[1.1.0]butanes)
Leo A. Paquette, Clifford J. Lau, and Robin D. Rogers
pp 2592 - 2600; DOI:
10.1021/ja00216a036
PDF
Diphenylacetaldehyde and its enol: determination of the keto-enol and hydration equilibrium constants and the pKa's of the aldehyde, enol, and hydrate. Comparison with sterically hindered systems
Y. Chiang, A. J. Kresge, and E. T. Krogh
pp 2600 - 2607; DOI:
10.1021/ja00216a037
PDF
Molecular and electronic structure of an isolated perfluorocarbanion. Crystal structure of tris(dimethylamino)sulfonium 1,3-bis(trifluoromethyl)-2,2,3,4,4-pentafluorocyclobutanide
William B. Farnham, David A. Dixon, and Joseph C. Calabrese
pp 2607 - 2611; DOI:
10.1021/ja00216a038
PDF
Kinetics and mechanisms of .alpha.- and .beta.-eliminations of alkoxysilanes from saturated and unsaturated carbon frameworks
Sukhamaya Bain, Sina Ijadi-Maghsoodi, and Thomas J. Barton
pp 2611 - 2614; DOI:
10.1021/ja00216a039
PDF
Direct electrical communication between chemically modified enzymes and metal electrodes. 2. Methods for bonding electron-transfer relays to glucose oxidase and D-amino-acid oxidase
Yinon Degani and Adam Heller
pp 2615 - 2620; DOI:
10.1021/ja00216a040
PDF
Biosynthesis of isoprenoid membranes in the methanogenic archaebacterium Methanospirillum hungatei
C. Dale Poulter, Tadashi Aoki, and Lacy Daniels
pp 2620 - 2624; DOI:
10.1021/ja00216a041
PDF
Model for the aspartate proteinases. Hydrolysis of a distorted amide catalyzed by dicarboxylic acids capable of forming cyclic anhydrides
V. Somayaji, Jeff Keillor, and R. S. Brown
pp 2625 - 2629; DOI:
10.1021/ja00216a042
PDF
Time-resolved proton-phospholipid interaction. Methodology and kinetic analysis
Esther Nachliel and Menachem Gutman
pp 2629 - 2635; DOI:
10.1021/ja00216a043
PDF
Time-resolved proton-protein interaction. Methodology and kinetic analysis
Ruth Yam, Esther Nachliel, and Menachem Gutman
pp 2636 - 2640; DOI:
10.1021/ja00216a044
PDF
In situ cuprate formation via transmetalation between vinylstannanes and higher order cyanocuprates
James R. Behling, Kevin A. Babiak, John S. Ng, Arthur L. Campbell, Robert Moretti, Mike Koerner, and Bruce H. Lipshutz
pp 2641 - 2643; DOI:
10.1021/ja00216a045
PDF
Semibullvalenes. IV. 2,6- and 2,8-Trapping of the bicyclo[3.3.0]octadienyl diradical with oxygen
R. Iyengar, R. Pina, K. Grohmann, and L. Todaro
pp 2643 - 2644; DOI:
10.1021/ja00216a046
PDF
Electrophilic activation of benzene in [Cr(.eta.4-C6H6)(CO)3]2-
Voon S. Leong and N. John Cooper
pp 2644 - 2646; DOI:
10.1021/ja00216a047
PDF
Highly oxidizing organometallics: preparation of magnetic charge-transfer salts derived from (MeCp)VCl3
David B. Morse, Thomas B. Rauchfuss, and Scott R. Wilson
pp 2646 - 2648; DOI:
10.1021/ja00216a048
PDF
Carbon-13 NMR and polarized IR spectra of vicinally labeled cyclobutadiene-13C2 in an argon matrix: interconversion of valence tautomers
Anita M. Orendt, Bradley R. Arnold, Juliusz G. Radziszewski, Julio C. Facelli, Klaus D. Malsch, Henri Strub, David M. Grant, and Josef Michl
pp 2648 - 2650; DOI:
10.1021/ja00216a049
PDF
Methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) as a protecting group for multifunctional molecules: synthetic utility in selective carbonyl reductions
Keiji Maruoka, Yoshitaka Araki, and Hisashi Yamamoto
pp 2650 - 2652; DOI:
10.1021/ja00216a050
PDF
Determination of long-distance intramolecular triplet energy-transfer rates. Quantitative comparison with electron transfer
Gerhard L. Closs, Piotr Piotrowiak, Jean M. MacInnis, and Graham R. Fleming
pp 2652 - 2653; DOI:
10.1021/ja00216a051
PDF
[2 + 1]- Versus [4 + 2]-cycloadditions of Fischer carbene complexes with 1,3-dienes. Evidence for a zwitterionic intermediate in a cyclopropanation reaction
William D. Wulff, Dominic C. Yang, and Christopher K. Murray
pp 2653 - 2655; DOI:
10.1021/ja00216a052
PDF
Bimetallic catalysis. A new method for the activation of chloroarenes toward palladium-catalyzed coupling with olefins
Joseph J. Bozell and Charles E. Vogt
pp 2655 - 2657; DOI:
10.1021/ja00216a053
PDF
The cage effect and apparent activation parameters for bond homolysis
T. Koenig and R. G. Finke
pp 2657 - 2658; DOI:
10.1021/ja00216a054
PDF
Lithium-6, carbon-13, and nitrogen-15 NMR spectroscopic studies of lithium dialkylamides. Solution structure of lithium isopropylcyclohexylamide (LICA) in tetrahydrofuran
Angela S. Galiano-Roth, Elias M. Michaelides, and David B. Collum
pp 2658 - 2660; DOI:
10.1021/ja00216a055
PDF
Interactions of dialkylmagnesium compounds with 15-crown-5: formation in solutions and solids of RMg(15-crown-5)+ and magnesiate ions
Anthony D. Pajerski, Masood Parvez, and Herman G. Richey
pp 2660 - 2662; DOI:
10.1021/ja00216a056
PDF
n-Pentenyl glycosides permit the chemospecific liberation of the anomeric center
David R. Mootoo, Vandana Date, and Bert Fraser-Reid
pp 2662 - 2663; DOI:
10.1021/ja00216a057
PDF
Synthesis and reactivity of a stable nitrile imine
Ghislaine Sicard, Antoine Baceiredo, and Guy Bertrand
pp 2663 - 2664; DOI:
10.1021/ja00216a058
PDF
Phosphonate-containing phospholipid analogs as tight-binding inhibitors of phospholipase-A2
Wei Yuan and Michael H. Gelb
pp 2665 - 2666; DOI:
10.1021/ja00216a059
PDF
Mechanism of the 1,5-sigmatropic hydrogen shift in 1,3-pentadiene
Michael J. S. Dewar, Eamonn F. Healy, and James M. Ruiz
pp 2666 - 2667; DOI:
10.1021/ja00216a060
PDF
Trajectories of proton transfer reactions. Experimental determination of the magnitude of primary deuterium isotope effects for proton-transfers occuring at acute angles
Dennis Liotta, Manohar Saindane, Liladhar Waykole, Julie Stephens, and Judy Grossman
pp 2667 - 2668; DOI:
10.1021/ja00216a061
PDF
Carbynes generated from metal carbonyl and isocyanide complexes; intermediates in the reductive coupling of carbonyl and CNR ligands
Raymond N. Vrtis, C. Pulla Rao, Steve Warner, and Stephen J. Lippard
pp 2669 - 2670; DOI:
10.1021/ja00216a062
PDF
Intramolecular excited-state electron transfer in a covalently linked porphyrin-viologen molecule: direct observation of the charge-separated intermediate by resonance Raman spectroscopy
Robert J. McMahon, R. Ken Force, Howard H. Patterson, and Mark S. Wrighton
pp 2670 - 2672; DOI:
10.1021/ja00216a063
PDF
A new class of stable head-to tail (Z-type) Langmuir Blodgett films. A second harmonic generation study
R. Popovitz-Biro, K. Hill, E. M. Landau, M. Lahav, L. Leiserowitz, J. Sagiv, H. Hsiung, G. R. Meredith, and H. Vanherzeele
pp 2672 - 2674; DOI:
10.1021/ja00216a064
PDF
Macroring contraction methodology. 4. A novel route to steroid A, B, C rings by the transannular Diels-Alder reaction of the 14-membered (E,E,E)-macrocyclic triene
Takashi Takahashi, Katsuya Shimizu, Takayuki Doi, Jiro Tsuji, and Yoshimasa Fukazawa
pp 2674 - 2676; DOI:
10.1021/ja00216a065
PDF
Fischer carbene-mediated conversions of enynes to bi- and tricyclic cyclopropane-containing carbon skeletons
Paul F. Korkowski, Thomas R. Hoye, and David B. Rydberg
pp 2676 - 2678; DOI:
10.1021/ja00216a066
PDF
Lithiothioacetals as carbenoids. Highly selective one-flask conversion of cyclohex-2-en-1-ones to lithium bicyclo[1.1.0]butan-2-olate intermediates
Keith Ramig, M. Bhupathy, and Theodore Cohen
pp 2678 - 2680; DOI:
10.1021/ja00216a067
PDF
Stereochemical course of the phospho group transfer catalyzed by cAMP-dependent protein kinase
Mengfei Ho, H. Neal Bramson, David E. Hansen, Jeremy R. Knowles, and E. T. Kaiser
pp 2680 - 2681; DOI:
10.1021/ja00216a068
PDF
The experimental heats of formation and kinetics of 1,3-biradicals using time-resolved photoacoustic calorimetry
Michael S. Herman and Joshua L. Goodman
pp 2681 - 2683; DOI:
10.1021/ja00216a069
PDF
Structure of the light emitter in krill (Euphausia pacifica) bioluminescence
Hideshi Nakamura, Branislav Musicki, Yoshito Kishi, and Osamu Shimomura
pp 2683 - 2685; DOI:
10.1021/ja00216a070
PDF
Preparation of rhenium(VII) monoimido alkylidyne complexes and metathesis of acetylenes via rhenacyclobutadiene intermediates
R. R. Schrock, I. A. Weinstock, A. D. Horton, A. H. Liu, and M. H. Schofield
pp 2686 - 2687; DOI:
10.1021/ja00216a071
PDF
First demonstration of high resolution laser desorption mass spectrometry of high mass organic ions
Carl F. Ijames and Charles L. Wilkins
pp 2687 - 2688; DOI:
10.1021/ja00216a072
PDF
"Tailored" organometallics as precursors for the chemical vapor deposition of high-purity palladium and platinum thin films
John E. Gozum, Deborah M. Pollina, James A. Jensen, and Gregory S. Girolami
pp 2688 - 2689; DOI:
10.1021/ja00216a073
PDF
Mechanism of UV endonuclease V cleavage of abasic sites in DNA determined by carbon-13 labeling
Muthiah Manoharan, Abhijit Mazumder, Stephen C. Ransom, John A. Gerlt, and Philip H. Bolton
pp 2690 - 2691; DOI:
10.1021/ja00216a074
PDF
The amido-ammine bridging ligand (H5N2-)
Ludwig Heck, Michael Ardon, Avi Bino, and Josef Zaap
pp 2691 - 2692; DOI:
10.1021/ja00216a075
PDF
Computer Software Reviews

pp 2692 - 2694; DOI:
10.1021/ja00216a600
PDF
Book Reviews

pp 2694 - 2698; DOI:
10.1021/ja00216a602
PDF

Issue 9


Study of the gas-phase basicity of 1-methylazaindole, 7-methyl-7H-pyrrolo[2,3-b]pyridine, and related compounds
J. Catalan, J. L. G. De Paz, M. Yanez, F. Amat-Guerri, R. Houriet, E. Rolli, R. Zehringer, P. Oelhafen, R. W. Taft, and et al.
pp 2699 - 2705; DOI:
10.1021/ja00217a001
PDF
Gas-phase Broensted versus Lewis acid-base reactions of 6,6-dimethylfulvene. A sensitive probe of the electronic structures of organic anions
Mark D. Brickhouse and Robert R. Squires
pp 2706 - 2714; DOI:
10.1021/ja00217a002
PDF
Mechanistic studies on gas-phase negative ion unimolecular decompositions. Alkoxide anions
William Tumas, Robert F. Foster, and John I. Brauman
pp 2714 - 2722; DOI:
10.1021/ja00217a003
PDF
Ionic structure and interactions in 1-methyl-3-ethylimidazolium chloride-aluminum chloride molten salts
Kenneth M. Dieter, Chester J. Dymek, Norman E. Heimer, John W. Rovang, and John S. Wilkes
pp 2722 - 2726; DOI:
10.1021/ja00217a004
PDF
Photodissociation of conjugated diene radical cations: methyl substituent band shifts
Robert C. Dunbar and Hun Young So
pp 2726 - 2730; DOI:
10.1021/ja00217a005
PDF
Application of photoelectron spectroscopy to molecular properties. Part 32. Ethenylphosphine. Synthesis by flash-vacuum thermolysis and characterization by photoelectron spectroscopy
Danielle Gonbeau, Sylvie Lacombe, Marie Claire Lasnes, Jean Louis Ripoll, and Genevieve Pfister-Guillouzo
pp 2730 - 2735; DOI:
10.1021/ja00217a006
PDF
Conformations of methyl 2'-deoxy-.alpha.-D-ribofuranoside and methyl 2'-deoxy-.beta.-D-ribofuranoside. A proton magnetic resonance spectroscopy and molecular mechanics study
J. Raap, J. H. Van Boom, H. C. Van Lieshout, and C. A. G. Haasnoot
pp 2736 - 2743; DOI:
10.1021/ja00217a007
PDF
Aqueous coordination and location of exchangeable copper(2+) cations in montmorillonite clay studied by electron spin resonance and electron spin echo modulation
David R. Brown and Larry Kevan
pp 2743 - 2748; DOI:
10.1021/ja00217a008
PDF
Theoretical and ESR/ENDOR single-crystal study of an azaallyl radical
Malledi V. V. S. Reddy, Alice Celalyan-Berthier, Michel Geoffroy, Pierre Y. Morgantini, Jacques Weber, and Gerald Bernardinelli
pp 2748 - 2753; DOI:
10.1021/ja00217a009
PDF
A time-resolved ESR study of the kinetics of spin trapping by nitromethane aci-anion
Keith P. Madden, Hitoshi Taniguchi, and Richard W. Fessenden
pp 2753 - 2758; DOI:
10.1021/ja00217a010
PDF
The r.alpha. structures of pyrazine and pyrimidine by the combined analysis of electron diffraction, liquid-crystal NMR, and rotational data
Stephen Cradock, Phillip B. Liescheski, David W. H. Rankin, and Heather E. Robertson
pp 2758 - 2763; DOI:
10.1021/ja00217a011
PDF
Effect of long-distance electron transfer on chemiluminescence efficiencies
Robert D. Mussell and Daniel G. Nocera
pp 2764 - 2772; DOI:
10.1021/ja00217a012
PDF
Insertion of two carbon monoxide moieties into an alkene double bond to form a RCH:C(O)C(O):CHR2- unit via organosamarium activation
William J. Evans and Donald K. Drummond
pp 2772 - 2774; DOI:
10.1021/ja00217a013
PDF
(Dialkylamino)phosphorus metal carbonyls. 5. Chemical reactivity of the phosphorus-bridging carbonyl group in carbonylbis[(diisopropylamino)phosphido]hexacarbonyldiiron
R. B. King, F. J. Wu, and E. M. Holt
pp 2775 - 2782; DOI:
10.1021/ja00217a014
PDF
Surface organometallic chemistry: hydrogenation of ethylene with Os3(CO)10(.mu.-H)(.mu.-OSi.rscharw.) and Os3(CO)10(.mu.-H)(.mu.-OPh). Evidence for cluster catalysis
Agnes Choplin, Bernard Besson, Lindora D'Ornelas, Roberto Sanchez-Delgado, and Jean Marie Basset
pp 2783 - 2787; DOI:
10.1021/ja00217a015
PDF
More rigid macrocyclic ligands that show metal ion size-based selectivity. Crystallographic, molecular mechanics, and formation constant study of the complexes of bridged cyclen
Robert D. Hancock, Susan M. Dobson, Ann Evers, Peter W. Wade, M. Patrick Ngwenya, Jan C. A. Boeyens, and Kevin P. Wainwright
pp 2788 - 2794; DOI:
10.1021/ja00217a016
PDF
Preparation, crystal structure, and magnetic properties of an oligonuclear complex with 12 coupled spins and an S = 12 ground state
Andrea Caneschi, Dante Gatteschi, Jean Laugier, Paul Rey, Roberta Sessoli, and Claudia Zanchini
pp 2795 - 2799; DOI:
10.1021/ja00217a017
PDF
Preparation of a thallium(I) diazotate. Structure, physicochemical characterization, and conversion to novel N-nitroso compounds
Larry K. Keefer, Shui Mei Wang, Takako Anjo, James C. Fanning, and Cynthia S. Day
pp 2800 - 2806; DOI:
10.1021/ja00217a018
PDF
Crystalline adducts of tetrakis(triphenylacetato)dichromium(II) with benzene, pyridine, and diethyl ether. Benzene as a multiple .pi. donor
F. Albert Cotton, Xuejun Feng, Piotr A. Kibala, and Marek Matusz
pp 2807 - 2815; DOI:
10.1021/ja00217a019
PDF
Mechanistic studies of the palladium-catalyzed reaction of methanol with bromobenzene and carbon monoxide to produce methyl benzoate. 1. Stoichiometric study
William R. Moser, Andrew W. Wang, and Nicholas K. Kildahl
pp 2816 - 2820; DOI:
10.1021/ja00217a020
PDF
Stereochemical mechanistic probe of substituted .alpha.-methylenetitanacyclobutane reactivity
Joel M. Hawkins and Robert H. Grubbs
pp 2821 - 2823; DOI:
10.1021/ja00217a021
PDF
Electronic structure of low-spin ferric porphyrins: single-crystal EPR evidence for pseudo-Jahn-Teller distortion in (tetraphenylporphinato)iron(III) bis(imidazole) cations
S. Michael Soltis and Charles E. Strouse
pp 2824 - 2829; DOI:
10.1021/ja00217a022
PDF
Carbon acidity. 73. Conductimetric study of lithium and cesium salts of hydrocarbon acids. A scale of free ion acidities in tetrahydrofuran. Revision of the ion pair scales
Michael J. Kaufman, Scott Gronert, and Andrew Streitwieser
pp 2829 - 2835; DOI:
10.1021/ja00217a023
PDF
Carbon acidity. 74. The effects of hetero-substituted pendant groups on carbanion reactivity. Solvent separated-contact ion pair equilibria and relative pKLi/THF's for 9-substituted fluorenyllithiums in tetrahydrofuran. The importance of internal chelation
Scott Gronert and Andrew Streitwieser
pp 2836 - 2842; DOI:
10.1021/ja00217a024
PDF
Carbon acidity. 75. The effects of hetero-substituted pendant groups on carbanion reactivity. Kinetic acidities of 9-substituted fluorenes in tetrahydrofuran. The importance of free ions in the reactions of delocalized carbanion salts
Scott Gronert and Andrew Streitwieser
pp 2843 - 2847; DOI:
10.1021/ja00217a025
PDF
Structures and interconversion of polymorphs of 2,3-dichloroquinizarin. Use of second harmonic generation to follow the change of a centrosymmetric to a polar structure
Robert C. Hall, Iain C. Paul, and David Y. Curtin
pp 2848 - 2854; DOI:
10.1021/ja00217a026
PDF
Ascorbic acid photoreductions of zinc(II) chlorophyll derivatives: access to metal-free isobacteriochlorins
Daniel J. Simpson and Kevin M. Smith
pp 2854 - 2861; DOI:
10.1021/ja00217a027
PDF
Lipid bilayer fibers from diastereomeric and enantiomeric N-octylaldonamides
Juergen Hinrich Fuhrhop, Peter Schnieder, Egbert Boekema, and Wolfgang Helfrich
pp 2861 - 2867; DOI:
10.1021/ja00217a028
PDF
Acidities of radical cations derived from remotely substituted and phenyl-substituted fluorenes
F. G. Bordwell, Jin Pei Cheng, and Mark J. Bausch
pp 2867 - 2872; DOI:
10.1021/ja00217a029
PDF
Acidities of radical cations derived from cyclopentadienes and 3-aryl-1,1,5,5-tetraphenyl-1,4-pentadienes
Frederick G. Bordwell, Jin Pei Cheng, and Mark J. Bausch
pp 2872 - 2877; DOI:
10.1021/ja00217a030
PDF
Spectroscopic and kinetic characteristics of aroyloxyl radicals. 1. The 4-methoxybenzoyloxyl radical
J. Chateauneuf, J. Lusztyk, and K. U. Ingold
pp 2877 - 2885; DOI:
10.1021/ja00217a031
PDF
Spectroscopic and kinetic characteristics of aroyloxyl radicals. 2. Benzoyloxyl and ring-substituted aroyloxyl radicals
J. Chateauneuf, J. Lusztyk, and Keith U. Ingold
pp 2886 - 2893; DOI:
10.1021/ja00217a032
PDF
Rhodium(II) acetate induced intramolecular dipolar cycloadditions of o-carboalkoxy-.alpha.-diazoacetophenone derivatives
Albert Padwa, Stephen P. Carter, Hildegard Nimmesgern, and Paul D. Stull
pp 2894 - 2900; DOI:
10.1021/ja00217a033
PDF
Free energies of transfer of carbon acids and their conjugate carbanions from water to dimethyl sulfoxide-water mixtures
Claude F. Bernasconi and Richard D. Bunnell
pp 2900 - 2903; DOI:
10.1021/ja00217a034
PDF
Electrostatic catalysis by ionic aggregates. 6. Modulation of proton-transfer equilibria by lithium perchlorate-diethyl ether clusters
Y. Pocker and James C. Ciula
pp 2904 - 2909; DOI:
10.1021/ja00217a035
PDF
Alkyl group effects on the rate constants and equilibrium constants for formation of cyclic tetrahedral intermediates
Linda J. Santry, Salwa Azer, and Robert A. McClelland
pp 2909 - 2914; DOI:
10.1021/ja00217a036
PDF
Reactivity control by microencapsulation in simple ammonium ion vesicles
Robert A. Moss, Shanti Swarup, and Hongmei Zhang
pp 2914 - 2919; DOI:
10.1021/ja00217a037
PDF
Regio- and stereospecific construction of anthracyclinones: total syntheses of (.+-.)-.gamma.-citromycinone, (.+-.)-dimethyl-6-deoxydaunomycinone, and (.+-.)-dimethyl-6-deoxyadriamycinone
Frank M. Hauser, Piyasena Hewawasam, and Dipakranjan Mal
pp 2919 - 2924; DOI:
10.1021/ja00217a038
PDF
Enantioselective synthesis of macrocyclic propargylic alcohols by [2,3] Wittig ring contraction. Synthesis of (+)-aristolactone and cembranoid precursors
James A. Marshall and Jacques Lebreton
pp 2925 - 2931; DOI:
10.1021/ja00217a039
PDF
A novel strategy for the stereoselective total synthesis of C-17 spiro steroids. Total synthesis of 19-norcanrenone - a formal total synthesis of 19-norspironolactone
Hideo Nemoto, Shigekazu Fujita, Mitsuo Nagai, Keiichiro Fukumoto, and Tetsuji Kametani
pp 2931 - 2938; DOI:
10.1021/ja00217a040
PDF
Biosynthesis and full NMR assignment of fungichromin, a polyene antibiotic from Streptomyces cellulose
Hiroshi Noguchi, Paul H. Harrison, Kunizo Arai, Thomas T. Nakashima, Laird A. Trimble, and John C. Vederas
pp 2938 - 2945; DOI:
10.1021/ja00217a041
PDF
Function of the amino sugar and N-terminal amino acid of the antibiotic vancomycin in its complexation with cell wall peptides
Rajamoorthi Kannan, Constance M. Harris, Thomas M. Harris, Jonathan P. Waltho, Nicholas J. Skelton, and Dudley H. Williams
pp 2946 - 2953; DOI:
10.1021/ja00217a042
PDF
Structure of the novel antibiotics boxazomycins A, B, and C
Takenori Kusumi, Takashi Ooi, Markus R. Walchli, and Hiroshi Kakisawa
pp 2954 - 2958; DOI:
10.1021/ja00217a043
PDF
L-Lactate dehydrogenase: substrate specificity and use as a catalyst in the synthesis of homochiral 2-hydroxy acids
Mahn Joo Kim and George M. Whitesides
pp 2959 - 2964; DOI:
10.1021/ja00217a044
PDF
Acidities of anilines in dimethyl sulfoxide solution
Frederick G. Bordwell and Donald J. Algrim
pp 2964 - 2968; DOI:
10.1021/ja00217a045
PDF
Free-radical reduction reactions of chiral dihydronicotinamides. Enantioselective hydrogen atom transfer and electron-transfer processes during the reduction of ketones
Dennis D. Tanner and Abdelmajid Kharrat
pp 2968 - 2970; DOI:
10.1021/ja00217a046
PDF
Synthesis, coloration, and crystal structure of the dibasic chromoacerand-piperazine 1:1 salt complex
Takahiro Kaneda, Yuka Ishizaki, Soichi Misumi, Yasushi Kai, Gen Hirao, and Nobutami Kasai
pp 2970 - 2972; DOI:
10.1021/ja00217a047
PDF
The aminolysis of methyl formate with aniline: evidence for catalysis by a trapping mechanism
Charles C. Yang and William P. Jencks
pp 2972 - 2973; DOI:
10.1021/ja00217a048
PDF
Strained rings as a source of unsaturation: polybenzvalene, a new soluble polyacetylene precursor
Timothy M. Swager, Dennis A. Dougherty, and Robert H. Grubbs
pp 2973 - 2974; DOI:
10.1021/ja00217a049
PDF
Highly effective mechanism-based inactivation of dopamine .beta.-hydroxylase by a novel ketene thioacetal
Thomas M. Bargar, Robert J. Broersma, Lawrence C. Creemer, James R. McCarthy, Jean Marie Hornsperger, Paul V. Attwood, and Michel J. Jung
pp 2975 - 2976; DOI:
10.1021/ja00217a050
PDF
A revision of the generally accepted hypothesis for the biosynthesis of the tropane moiety of cocaine
Edward Leete and Sung Hoon Kim
pp 2976 - 2978; DOI:
10.1021/ja00217a051
PDF
Enhanced kinetic resolution and enzyme-like shape selectivity
Paul R. Carlier, William S. Mungall, Georg Schroder, and K. Barry Sharpless
pp 2978 - 2979; DOI:
10.1021/ja00217a052
PDF
Synthesis of boroles and their use in low-temperature Diels-Alder reactions with unactivated alkenes
Paul J. Fagan, Elizabeth G. Burns, and Joseph C. Calabrese
pp 2979 - 2981; DOI:
10.1021/ja00217a053
PDF
Synthesis and unusual properties of a helically twisted multiply metalated rubrene derivative
Paul J. Fagan, Michael D. Ward, Jonathan V. Caspar, Joseph C. Calabrese, and Paul J. Krusic
pp 2981 - 2983; DOI:
10.1021/ja00217a054
PDF
Verification of the "cation-popping" doping mechanism of self doped polymers
Y. Ikenoue, J. Chiang, A. O. Patil, F. Wudl, and A. J. Heeger
pp 2983 - 2985; DOI:
10.1021/ja00217a055
PDF
Evidence for water coordinated to the active site iron in soybean lipoxygenase-1
Mark J. Nelson
pp 2985 - 2986; DOI:
10.1021/ja00217a056
PDF
Inclusion tuning of nonlinear optical materials: switching the SHG of p-nitroaniline and 2-methyl-p-nitroaniline with molecular sieve hosts
S. D. Cox, T. E. Gier, G. D. Stucky, and J. Bierlein
pp 2986 - 2987; DOI:
10.1021/ja00217a057
PDF
Direct .alpha.-phosphoryloxylation of ketones and (phosphoryloxy)lactonization of pentenoic acids with [hydroxy[(bis(phenyloxy)phosphoryl)oxy]iodo]benzene
Gerald F. Koser, Jayant S. Lodaya, Dale G. Ray, and Pandurang B. Kokil
pp 2987 - 2988; DOI:
10.1021/ja00217a058
PDF
Corner attack on cyclopropane by deuteron and mercuric ions: an example of stereospecific formation and capture of unsymmetrical corner-deuterated/mercurated cyclopropane intermediates
James M. Coxon, Peter J. Steel, Barry I. Whittington, and Merle A. Battiste
pp 2988 - 2990; DOI:
10.1021/ja00217a059
PDF
Evidence for a selenium anomeric effect? An unusual conformation of a selenium coronand
B. Mario Pinto, Raymond J. Batchelor, Blair D. Johnston, Frederick W. B. Einstein, and Ian D. Gay
pp 2990 - 2991; DOI:
10.1021/ja00217a060
PDF
A revised structure of sibiromycin
Jack D. Leber, John R. E. Hoover, Kenneth G. Holden, Randall K. Johnson, and Sidney M. Hecht
pp 2992 - 2993; DOI:
10.1021/ja00217a061
PDF
Rates and mechanisms of hydrolysis of esters of phosphorous acid [Erratum to document cited in CA108(3):21987r]
F. H. Westheimer, Shaw Huang, and Frank Covitz
pp 2993 - 2993; DOI:
10.1021/ja00217a062
PDF
Computer Software Reviews

pp 2994 - 2995; DOI:
10.1021/ja00217a600
PDF
Book Reviews

pp 2995 - 2998; DOI:
10.1021/ja00217a601
PDF

Issue 10


Macrochelate complexes of purine 5'-nucleotide triphosphates and monophosphates: definitive multinuclear NMR evidence supported by molecular mechanics calculations
Michael D. Reily, Trevor W. Hambley, and Luigi G. Marzilli
pp 2999 - 3007; DOI:
10.1021/ja00218a001
PDF
Comparison of variable-temperature proton NMR spectra of five-coordinate high-spin (S = 5/2) iron(III) porphyrins and chlorins
M. J. Pawlik, P. K. Miller, E. P. Sullivan, M. A. Levstik, D. A. Almond, and S. H. Strauss
pp 3007 - 3012; DOI:
10.1021/ja00218a002
PDF
Quantitative examination of the photoisomerization of retinal iminium salts by high-field proton NMR spectroscopy
Ronald F. Childs and Gary S. Shaw
pp 3013 - 3017; DOI:
10.1021/ja00218a003
PDF
A single-crystal ESR and quantum chemical study of electron-capture trialkylphosphine sulfide and selenide radical anions with a three-electron bond
Rene A. J. Janssen, Joost A. J. M. Kingma, and Henk M. Buck
pp 3018 - 3026; DOI:
10.1021/ja00218a004
PDF
Proton NMR characterization of the catalytically relevant proximal and distal hydrogen-bonding networks in ligated resting state horseradish peroxidase
V. Thanabal, Jeffrey S. De Ropp, and Gerd N. La Mar
pp 3027 - 3035; DOI:
10.1021/ja00218a005
PDF
Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy
R. Spindler and D. F. Shriver
pp 3036 - 3043; DOI:
10.1021/ja00218a006
PDF
Temperature-induced spontaneous emission of uranyl nitrate hexahydrate
H. D. Bist, T. Nishiya, M. Baba, and I. Hanazaki
pp 3043 - 3046; DOI:
10.1021/ja00218a007
PDF
Surface derivatization and isolation of semiconductor cluster molecules
M. L. Steigerwald, A. P. Alivisatos, J. M. Gibson, T. D. Harris, R. Kortan, A. J. Muller, A. M. Thayer, T. M. Duncan, D. C. Douglass, and L. E. Brus
pp 3046 - 3050; DOI:
10.1021/ja00218a008
PDF
MC-SCF study of the Diels-Alder reaction between ethylene and butadiene
Fernando Bernardi, Andrea Bottoni, Martin J. Field, Martin F. Guest, Ian H. Hillier, Michael A. Robb, and Alessandro Venturini
pp 3050 - 3055; DOI:
10.1021/ja00218a009
PDF
Theoretical study of the decomposition of five-coordinate silicon anions
Larry P. Davis, Larry W. Burggraf, and Mark S. Gordon
pp 3056 - 3062; DOI:
10.1021/ja00218a010
PDF
Do chemical reactions react along the reaction path?
B. Hartke and J. Manz
pp 3063 - 3068; DOI:
10.1021/ja00218a011
PDF
The coordination of bare iron(I) ion (Fe+) to aliphatic isonitriles differs from that of Fe+ and nitriles
Karsten Eller, Carlito B. Lebrilla, Thomas Drewello, and Helmut Schwarz
pp 3068 - 3071; DOI:
10.1021/ja00218a012
PDF
Models for strong interactions in proteins and enzymes. 1. Enhanced acidities of principal biological hydrogen donors
Michael Mautner
pp 3071 - 3075; DOI:
10.1021/ja00218a013
PDF
Models for strong interactions in proteins and enzymes. 2. Interactions of ions with the peptide link and with imidazole
Michael Mautner
pp 3075 - 3080; DOI:
10.1021/ja00218a014
PDF
Time-resolved slow dissociation of benzonitrile ions by trapped-ion ion cyclotron resonance photodissociation
Hun Young So and Robert C. Dunbar
pp 3080 - 3083; DOI:
10.1021/ja00218a015
PDF
Kinetics and thermochemistry of the tert-butyl radical. Study of the equilibrium tert-C4H9 + HBr .dblharw. iso-C4H10 + Br
John J. Russell, Jorma A. Seetula, Raimo S. Timonen, David Gutman, and David F. Nava
pp 3084 - 3091; DOI:
10.1021/ja00218a016
PDF
Kinetics and thermochemistry of methyl, ethyl, and isopropyl. Study of the equilibrium R + HBr .dblharw. R-H + Br
John J. Russell, Jorma A. Seetula, and David Gutman
pp 3092 - 3099; DOI:
10.1021/ja00218a017
PDF
The 2 + 1 REMPI spectra of cyclic ketones in a cold molecular beam. 2. The n .fwdarw. 3s Rydberg transition of methyl-substituted cyclohexanones and cyclopentanones
Timothy J. Cornish and Tomas Baer
pp 3099 - 3106; DOI:
10.1021/ja00218a018
PDF
Time-resolved resonance Raman spectroscopy and solution kinetics of photogenerated transients in the metal-carbene complex (OC)5W:C(OMe)Ph
Steven E. J. Bell, Keith C. Gordon, and John J. McGarvey
pp 3107 - 3112; DOI:
10.1021/ja00218a019
PDF
1,2-Migrations in free radicals related to coenzyme B12-dependent rearrangements
Susan Wollowitz and Jack Halpern
pp 3112 - 3120; DOI:
10.1021/ja00218a020
PDF
Thermal decomposition and cobalt-carbon bond dissociation energies of organocobalamins: neopentyl-, (cyclopentylmethyl)-, (cyclohexylmethyl)-, (tetrahydrofurfuryl)- and ((tetrahydro-2H-pyryl)methyl)cobalamin
Sook Hui Kim, Hui Lan Chen, Natalie Feilchenfeld, and Jack Halpern
pp 3120 - 3126; DOI:
10.1021/ja00218a021
PDF
Reduction of hydrogen peroxide by the ferrous iron chelate of diethylenetriamine-N,N,N',N",N"-pentaacetate
Siham Rahhal and Helen W. Richter
pp 3126 - 3133; DOI:
10.1021/ja00218a022
PDF
Kinetics and mechanism of the insertion of olefins into niobium- and tantalum-hydride bonds: a study of the competition between steric and electronic effects
Barbara J. Burger, Bernard D. Santarsiero, Mark S. Trimmer, and John E. Bercaw
pp 3134 - 3146; DOI:
10.1021/ja00218a023
PDF
Heterogeneous, platinum-catalyzed hydrogenation of (diolefin)dialkylplatinum(II) complexes: kinetics
Timothy M. Miller, Alan N. Izumi, Yen Shiang Shih, and George M. Whitesides
pp 3146 - 3156; DOI:
10.1021/ja00218a024
PDF
Deuterium-labeling experiments relevant to the mechanism of platinum-catalyzed hydrogenation of (diolefin)dialkylplatinum(II) complexes: evidence for isotopic exchange via platinum surface hydrogen. The stereochemistry of reduction
Timothy M. Miller, Thomas J. McCarthy, and George M. Whitesides
pp 3156 - 3163; DOI:
10.1021/ja00218a025
PDF
Isotopic exchange reactions occurring in the hydrogenation of (1,5-cyclooctadiene)dialkylplatinum(II) complexes over platinum black
Timothy M. Miller and George M. Whitesides
pp 3164 - 3170; DOI:
10.1021/ja00218a026
PDF
Kinetics and substituent effects in the formation of zirconocene thioaldehyde complexes: .beta.-hydride elimination versus cyclometalation
Stephen L. Buchwald and Ralph B. Nielsen
pp 3171 - 3175; DOI:
10.1021/ja00218a027
PDF
Synthesis and reactivity of binuclear tropocoronand and related organocopper(I) complexes. Catalytic enantioselective conjugate addition of Grignard reagents to 2-cyclohexen-1-one
Gilberto M. Villacorta, C. Pulla Rao, and Stephen J. Lippard
pp 3175 - 3182; DOI:
10.1021/ja00218a028
PDF
Aggregation of organometallic complex pillars in synthetic fluorhectorite and montmorillonite
Faina Tsvetkov and John White
pp 3183 - 3187; DOI:
10.1021/ja00218a029
PDF
Metal ion lability constant derived from a linear free energy relationship between ligand-substitution rates of tris(acetylacetonato) and aqua complexes of various tervalent metal ions
Hiroaki Kido and Kazuo Saito
pp 3187 - 3190; DOI:
10.1021/ja00218a030
PDF
Widely varying olefin rotation geometry in platinum(II)-olefin complexes containing the .eta.3-allyl ligand. Molecular structure, solution stability, and molecular orbital studies
Kunio Miki, Kazuhiko Yamatoya, Nobutami Kasai, Hideo Kurosawa, Akira Urabe, Mitsuhiro Emoto, Kazuyuki Tatsumi, and Akira Nakamura
pp 3191 - 3198; DOI:
10.1021/ja00218a031
PDF
Host-guest interactions: a fluorescence investigation of the solubilization of diphenylpolyene solute molecules in lipid bilayers
Mary T. Allen, Laerte Miola, and David G. Whitten
pp 3198 - 3206; DOI:
10.1021/ja00218a032
PDF
Carbon dioxide activation and catalytic lactone synthesis by telomerization of butadiene and carbon dioxide
Pierre Braunstein, Dominique Matt, and Dominique Nobel
pp 3207 - 3212; DOI:
10.1021/ja00218a033
PDF
Biologically useful chelators that release Ca2+ upon illumination
S. R. Adams, Joseph P. Y. Kao, G. Grynkiewicz, A. Minta, and R. Y. Tsien
pp 3212 - 3220; DOI:
10.1021/ja00218a034
PDF
Absolute rate constants for bromine abstraction from N-bromoimides and Br2 by alkyl radicals
James M. Tanko, Philip S. Skell, and Sri Seshadri
pp 3221 - 3225; DOI:
10.1021/ja00218a035
PDF
Catalysis of the debromination of 4-alkyl-4-bromo-2,5-cyclohexadienones in aqueous solution by .alpha.-cyclodextrin
Oswald S. Tee and Janice M. Bennett
pp 3226 - 3230; DOI:
10.1021/ja00218a036
PDF
Aluminum dichloride and dibromide. Preparation, spectroscopic (including matrix isolation) study, reactions, and role (together with alkyl(aryl)aluminum monohalides) in the preparation of organoaluminum compounds
George A. Olah, Omar Farooq, S. Morteza F. Farnia, Mark R. Bruce, Francoise L. Clouet, Peter R. Morton, G. K. Surya Prakash, Raymond C. Stevens, Robert Bau, and et al.
pp 3231 - 3238; DOI:
10.1021/ja00218a037
PDF
4-Oxazoline route to stabilized azomethine ylides. Controlled reduction of oxazolium salts
E. Vedejs and J. W. Grissom
pp 3238 - 3246; DOI:
10.1021/ja00218a038
PDF
The mechanism of the quinamine rearrangements
Bogdan Boduszek and Henry J. Shine
pp 3247 - 3252; DOI:
10.1021/ja00218a039
PDF
New conformation exhibiting near-threefold symmetry for uncomplexes valinomycin in crystals from dimethyl sulfoxide
Isabella L. Karle and Judith L. Flippen-Anderson
pp 3253 - 3257; DOI:
10.1021/ja00218a040
PDF
Diels-Alder reaction of dienes having stereogenic allylic substituents: control of diastereoface selectivity by the dienophile
R. Tripathy, R. W. Franck, and K. D. Onan
pp 3257 - 3262; DOI:
10.1021/ja00218a041
PDF
Several polycyclic valence isomers of dimethyl [14]annulene-1,8-dicarboxylate. Reactivity of a nonconjugated bis[bicyclo[1.1.0]butane]
Manfred Christl, Silke Freund, Helmut Henneberger, Arno Kraft, Juergen Hauck, and Hermann Irngartinger
pp 3263 - 3271; DOI:
10.1021/ja00218a042
PDF
Acetylenic esters. Preparation and characterization of alkynyl carboxylates via polyvalent iodonium species
Peter J. Stang, Manfred Boehshar, Horst Wingert, and Tsugio Kitamura
pp 3272 - 3278; DOI:
10.1021/ja00218a043
PDF
Reversibly and irreversibly formed products from the reactions of mercaptalbumin (AlbSH) with Et3PAuCN and of AlbSAuPEt3 with hydrocyanic acid
Anvarhusein A. Isab, Anne L. Hormann, Mary T. Coffer, and C. Frank Shaw
pp 3278 - 3284; DOI:
10.1021/ja00218a044
PDF
Evidence for an episulfonium ion intermediate in the formation of S-[2-(N7-guanyl)ethyl]glutathione in DNA
Lisa A. Peterson, Thomas M. Harris, and F. Peter Guengerich
pp 3284 - 3291; DOI:
10.1021/ja00218a045
PDF
Enzymochemical regioselective oxidation of steroids without oxidoreductase
Sergio Riva and Alexander M. Klibanov
pp 3291 - 3295; DOI:
10.1021/ja00218a046
PDF
The synthesis and structure determination from powder diffraction data of LaMo5O8, a new oxomolybdate containing Mo10 clusters
S. J. Hibble, A. K. Cheetham, A. R. L. Bogle, H. R. Wakerley, and D. E. Cox
pp 3295 - 3296; DOI:
10.1021/ja00218a047
PDF
Palladium-catalyzed arylation of siloxycyclopropanes with aryl triflates. Carbon chain elongation via catalytic carbon-carbon bond cleavage
Satoshi Aoki, Tsutomu Fujimura, Eiichi Nakamura, and Isao Kuwajima
pp 3296 - 3298; DOI:
10.1021/ja00218a048
PDF
A solution to the in,out-bicyclo[4.4.1]undecan-7-one problem inherent in ingenane total synthesis
Raymond L. Funk, Thomas A. Olmstead, and M. Parvez
pp 3298 - 3300; DOI:
10.1021/ja00218a049
PDF
Cyclopentane synthesis via free radical mediated addition of functionalized alkenes to substituted vinyl cyclopropanes
Ken S. Feldman, Anthony L. Romanelli, Robert E. Ruckle, and Raymond F. Miller
pp 3300 - 3302; DOI:
10.1021/ja00218a050
PDF
Electrophilic catalysis by vanadate of the dehydration of hydrated glyoxylate
Marcia M. Craig, Mario Baff, and Michael J. Gresser
pp 3302 - 3303; DOI:
10.1021/ja00218a051
PDF
Chemical potential driven contraction and relaxation by ionic strength modulation of an inverse temperature transition
D. W. Urry, R. D. Harris, and K. U. Prasad
pp 3303 - 3305; DOI:
10.1021/ja00218a052
PDF
Synthesis of boron carbide via poly(vinylpentaborane) precursors
Mario G. L. Mirabelli and Larry G. Sneddon
pp 3305 - 3307; DOI:
10.1021/ja00218a053
PDF
Diastereoselective synthesis of the first 2,3,4-trisubstituted platina(IV)cyclobutanes
W. D. Neilsen, R. D. Larsen, and P. W. Jennings
pp 3307 - 3308; DOI:
10.1021/ja00218a054
PDF
Luminescent organometallic compounds with relativistic metal-metal bonds. Synthesis and characterization of AuTl[Ph2P(CH2)S]2, a one-dimensional gold-thallium metal-metal bonded polymer in the solid state
Suning Wang, John P. Fackler, C. King, and J. C. Wang
pp 3308 - 3310; DOI:
10.1021/ja00218a055
PDF
Stereochemistry of the addition of diarylsilylenes to cis- and trans-2-butenes
Wataru Ando, Mikako Fujita, Hitoaki Yoshida, and Akira Sekiguchi
pp 3310 - 3311; DOI:
10.1021/ja00218a056
PDF
Preparation and catalytic activity of a new solid acid catalyst
R. S. Drago and E. E. Getty
pp 3311 - 3312; DOI:
10.1021/ja00218a057
PDF
Preparation and x-ray structure of a mixed-metal double cubane-type aqua ion, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9]8+
Takashi Shibahara, Haruo Akashi, and Hisao Kuroya
pp 3313 - 3314; DOI:
10.1021/ja00218a058
PDF
A new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula [M4(OR)12]
M. H. Chisholm, K. Folting, C. E. Hammond, and M. J. Hampden-Smith
pp 3314 - 3315; DOI:
10.1021/ja00218a059
PDF
Synthesis of bicyclic keto silanes by tandem rearrangement of silylacetylenic ketones
Andrew S. Kende, Paul Hebeisen, and Ronald C. Newbold
pp 3315 - 3317; DOI:
10.1021/ja00218a060
PDF
Properties of the Fe(II)-Fe(III) derivative of red kidney bean purple phosphatase. Evidence for a binuclear zinc-iron center in the native enzyme
Jennifer L. Beck, John De Jersey, Burt Zerner, Michael P. Hendrich, and Peter G. Debrunner
pp 3317 - 3318; DOI:
10.1021/ja00218a061
PDF
Silylation-mediated oxidation of 4-aza-3-ketosteroids with DDQ proceeds via DDQ-substrate adducts
Apurba Bhattacharya, Lisa M. DiMichele, Ulf H. Dolling, Alan W. Douglas, and Edward J. J. Grabowski
pp 3318 - 3319; DOI:
10.1021/ja00218a062
PDF
The role of nocardicin G in nocardicin A biosynthesis
Craig A. Townsend and Brenda A. Wilson
pp 3320 - 3321; DOI:
10.1021/ja00218a063
PDF
Preparation of polysilanes in the presence of ultrasound
H. K. Kim and K. Matyjaszewski
pp 3321 - 3323; DOI:
10.1021/ja00218a064
PDF
Mechanism of adenylate kinase. 3. Use of deuterium NMR to show lack of correlation between local substrate dynamics and local binding energy
Charles R. Sanders and Ming Daw Tsai
pp 3323 - 3324; DOI:
10.1021/ja00218a065
PDF
Synthesis and structural characterization of a thiolate coordination complex of a mixed-valence Mo(V)/Mo(VI) polyoxomolybdate, [Mo10O28(SCH2CH2O)2(HOCH3)2]4-, and of its decomposition product [Mo4O6(SCH2CH2O)5]2-
Shuncheng Liu, Xiao Sun, and Jon Zubieta
pp 3324 - 3326; DOI:
10.1021/ja00218a066
PDF
A novel n-doped metallomacrocyclic conductor
Joseph D. Ferrara, Claire Tessier-Youngs, and Wiley J. Youngs
pp 3326 - 3327; DOI:
10.1021/ja00218a067
PDF
Molecular recognition: hydrogen bonding and aromatic stacking converge to bind cytosine derivatives
K. S. Jeong and J. Rebek
pp 3327 - 3328; DOI:
10.1021/ja00218a068
PDF
Experimental tests of models to predict nucleophilic addition stereochemistries
Debabrata Mukherjee, Yun Dong Wu, Frank R. Fronczek, and K. N. Houk
pp 3328 - 3330; DOI:
10.1021/ja00218a069
PDF
Formation and autocatalytic destruction of the quinone methide from reductive cleavage of Menogaril
Marybeth Boldt, Giorgio Gaudiano, Makhluf J. Haddadin, and Tad H. Koch
pp 3330 - 3332; DOI:
10.1021/ja00218a070
PDF
High-resolution electrophoretic NMR
Timothy R. Saarinen and Charles S. Johnson
pp 3332 - 3333; DOI:
10.1021/ja00218a071
PDF
Phenoxazinone synthase: enzymatic catalysis of an aminophenol oxidative cascade
Clifton E. Barry, Parmesh G. Nayar, and Tadhg P. Begley
pp 3333 - 3334; DOI:
10.1021/ja00218a072
PDF
Cyclopentenones from the reaction of alkynes with cyclopropylcarbenechromium complexes
James W. Herndon, Seniz U. Tumer, and Wayne F. K. Schnatter
pp 3334 - 3335; DOI:
10.1021/ja00218a073
PDF
Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry [Erratum to document cited in CA99(11):87472W]
John D. Simon and Kevin S. Peters
pp 3336 - 3336; DOI:
10.1021/ja00218a074
PDF
Computer Software Reviews

pp 3336 - 3337; DOI:
10.1021/ja00218a600
PDF
Book Reviews

pp 3338 - 3344; DOI:
10.1021/ja00218a601
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Issue 11


Free energy effects on biological electron transfer: reactions of iron(IV) cytochrome c peroxidase (ES) with metallocytochromes c
Karen Taylor Conklin and George McLendon
pp 3345 - 3350; DOI:
10.1021/ja00219a001
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The conformational properties of the delta opioid peptide [cyclic] [D-pen2,D-pen5]enkephalin in aqueous solution determined by NMR and energy minimization calculations
Victor J. Hruby, Lung Fa Kao, B. Montgomery Pettitt, and Martin Karplus
pp 3351 - 3359; DOI:
10.1021/ja00219a002
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Side chain dynamics of crystalline L-[3,3-2H2]methionine studied by deuterium NMR spectroscopy
S. W. Sparks, N. Budhu, P. E. Young, and D. A. Torchia
pp 3359 - 3367; DOI:
10.1021/ja00219a003
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Sodium ion exchange reactions of monensin in methanol and methanol-water mixtures: a sodium-23 NMR study
E. Amat, B. G. Cox, J. Rzeszotarska, and H. Schneider
pp 3368 - 3372; DOI:
10.1021/ja00219a004
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Ultrahigh-resolution silicon-29 solid-state MAS NMR investigation of sorbate and temperature-induced changes in the lattice structure of zeolite ZSM-5
Colin A. Fyfe, Harald Strobl, George T. Kokotailo, Gordon J. Kennedy, and Gwyneth E. Barlow
pp 3373 - 3380; DOI:
10.1021/ja00219a005
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Intermolecular hydrogen-bonding effect on carbon-13 NMR chemical shifts of glycine residue carbonyl carbons of peptides in the solid state
Shinji Ando, Isao Ando, Akira Shoji, and Takuo Ozaki
pp 3380 - 3386; DOI:
10.1021/ja00219a006
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Low-temperature carbon-13 magnetic resonance. 8. Chemical shielding anisotropy of olefinic carbons
Anita M. Orendt, Julio C. Facelli, Alvin J. Beeler, Karl Reuter, W. J. Horton, Peter Cutts, David M. Grant, and Josef Michl
pp 3386 - 3392; DOI:
10.1021/ja00219a007
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Conformational dynamics detected by nuclear magnetic resonance NOE values and J coupling constants
Horst Kessler, Christian Griesinger, Joerg Lautz, Arndt Mueller, Wilfred F. Van Gunsteren, and Herman J. C. Berendsen
pp 3393 - 3396; DOI:
10.1021/ja00219a008
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Theoretical investigation of the anaerobic reduction of halogenated alkanes by cytochrome P-450. 2. Vertical electron affinities of chlorofluoromethanes as a measure of their activity
Brian T. Luke, Gilda H. Loew, and A. D. McLean
pp 3396 - 3400; DOI:
10.1021/ja00219a009
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High-spin carbenes
S. A. Alexander and D. J. Klein
pp 3401 - 3405; DOI:
10.1021/ja00219a010
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Ab initio calculations on the ring opening of cyclopropane radical cation. Trimethylene radical cation is not a stable intermediate
Ping Du, David A. Hrovat, and Weston Thatcher Borden
pp 3405 - 3412; DOI:
10.1021/ja00219a011
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Transition structures of pericyclic reactions. Electron correlation and basis set effects on the transition structure and activation energy of the electrocyclization of cyclobutene to butadiene
David C. Spellmeyer and K. N. Houk
pp 3412 - 3416; DOI:
10.1021/ja00219a012
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Rearrangement through Berry pseudorotation and olefin insertion of d8 five-coordinate Rh(H)(C2H4)(CO)2(PH3). An ab initio MO study
Nobuaki Koga, Su Qian Jin, and Keiji Morokuma
pp 3417 - 3425; DOI:
10.1021/ja00219a013
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Computational evaluation and comparison of some nitramine properties
Peter Politzer, Nagamani Sukumar, Keerthi Jayasuriya, and Shoba Ranganathan
pp 3425 - 3430; DOI:
10.1021/ja00219a014
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Band structures of polyfulvene and related polymers. A model for the effects of benzannelation on the band structures of polythiophene, polypyrrole, and polyfulvene
Julianto Pranata, Robert H. Grubbs, and Dennis A. Dougherty
pp 3430 - 3435; DOI:
10.1021/ja00219a015
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Do stable isomers of N3H3 exist?
David H. Magers, Edward A. Salter, Rodney J. Bartlett, Carl Salter, B. Andes Hess, and L. J. Schaad
pp 3435 - 3446; DOI:
10.1021/ja00219a016
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Protocol for determining enantioselective binding of chiral analytes on chiral chromatographic surfaces
Kenny B. Lipkowitz, David A. Demeter, Richard Zegarra, Raima Larter, and Thomas Darden
pp 3446 - 3452; DOI:
10.1021/ja00219a017
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Electron transfer versus energy transfer in the reactions of 2E Cr(bpy)33+ with organochromium and organocobalt complexes
Andreja Bakac and James H. Espenson
pp 3453 - 3457; DOI:
10.1021/ja00219a018
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Dinitrogen sulfide, N2S, revealed by photoelectron spectroscopy
Harald Bender, Frank Carnovale, J. Barrie Peel, and Curt Wentrup
pp 3458 - 3461; DOI:
10.1021/ja00219a019
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Novel chemical pathways and charge-transport dynamics of electrodes modified with electropolymerized layers of [Co(v-terpy)2]2+
A. R. Guadalupe, D. A. Usifer, K. T. Potts, H. C. Hurrell, A. E. Mogstad, and H. D. Abruna
pp 3462 - 3466; DOI:
10.1021/ja00219a020
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Reactions of nido-2,3-Et2C2B4H6 with triethylamine-alane: syntheses of new small aluminacarboranes
Jeffrey S. Beck and Larry G. Sneddon
pp 3467 - 3472; DOI:
10.1021/ja00219a021
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Magnetic field effects on the catalytic oxidation of 2,6-di-tert-butylphenol by CoSMDPT: Deuterium and oxygen-17 magnetic isotope effects
Richard P. Perito and Barry B. Corden
pp 3472 - 3477; DOI:
10.1021/ja00219a022
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Synthesis, characterization, and x-ray structure of the ruthenium picnic-basket porphyrins
James P. Collman, John I. Brauman, Jeffrey P. Fitzgerald, Philip D. Hampton, Yoshinori Naruta, John W. Sparapany, and James A. Ibers
pp 3477 - 3486; DOI:
10.1021/ja00219a023
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Reversible binding of dinitrogen and dioxygen by a ruthenium picnic-basket porphyrin
James P. Collman, John I. Brauman, Jeffrey P. Fitzgerald, John W. Sparapany, and James A. Ibers
pp 3486 - 3495; DOI:
10.1021/ja00219a024
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Proton exchange and NMR line broadening in aromatic nucleophilic addition and substitution
Radu Bacaloglu, Clifford A. Bunton, Giorgio Cerichelli, and Francisco Ortega
pp 3495 - 3503; DOI:
10.1021/ja00219a025
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Single-electron transfer in aromatic nucleophilic addition and substitution in aqueous media
Radu Bacaloglu, Clifford A. Bunton, and Francisco Ortega
pp 3503 - 3512; DOI:
10.1021/ja00219a026
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Single-electron transfer in aromatic nucleophilic substitution in reaction of 1-substituted 2,4-dinitronaphthalenes with hydroxide ion
Radu Bacaloglu, Clifford A. Bunton, and Francisco Ortega
pp 3512 - 3518; DOI:
10.1021/ja00219a027
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Kinetic analysis of alkane polychlorination with molecular chlorine. Chlorine atom/monochloride geminate pairs and the effect of reactive cage walls on the competition between monochloride rotation and chlorine atom escape
K. D. Raner, J. Lusztyk, and K. U. Ingold
pp 3519 - 3524; DOI:
10.1021/ja00219a028
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Competitive cage kinetics. Relative rates of complexation of chlorine atom by various arenes
James M. Tanko and Frank E. Anderson
pp 3525 - 3530; DOI:
10.1021/ja00219a029
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Reactions of alkylmercurials with heteroatom-centered acceptor radicals
Glen A. Russell, Preecha Ngoviwatchai, Hasan I. Tashtoush, Anna Pla-Dalmau, and Rajive K. Khanna
pp 3530 - 3538; DOI:
10.1021/ja00219a030
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Does formal intramolecular transfer of an acidic deuterium to a site of halogen-lithium exchange show that lithium-halogen exchange is faster than loss of the acidic deuterium? Evidence in favor of an alternative mechanism
Peter Beak, Timothy J. Musick, and Chin Wen Chen
pp 3538 - 3542; DOI:
10.1021/ja00219a031
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Heterogeneous catalytic hydrogenation of poly(vinylethylene)
J. H. Rosedale and F. S. Bates
pp 3542 - 3545; DOI:
10.1021/ja00219a032
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Lithium-6 and sodium-23 NMR spectroscopic studies of metalated hydrazone cryptates. Effects of ion triplet formation on the stereochemistry of alkylation
Angela S. Galiano-Roth and David B. Collum
pp 3546 - 3553; DOI:
10.1021/ja00219a033
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Free-radical macrocyclization-transannular cyclization
Ned A. Porter, Vincent H. T. Chang, David R. Magnin, and Bruce T. Wright
pp 3554 - 3560; DOI:
10.1021/ja00219a034
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Directed reduction of .beta.-hydroxy ketones employing tetramethylammonium triacetoxyborohydride
D. A. Evans, K. T. Chapman, and E. M. Carreira
pp 3560 - 3578; DOI:
10.1021/ja00219a035
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Synthesis and molecular structure of [7]circulene
Koji Yamamoto, Tadashi Harada, Yoshio Okamoto, Hiroaki Chikamatsu, Masao Nakazaki, Yasushi Kai, Takuo Nakao, Mitsuya Tanaka, Shigeharu Harada, and Nobutami Kasai
pp 3578 - 3584; DOI:
10.1021/ja00219a036
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Total synthesis of (-)-Specionin
James K. Whitesell and Diane E. Allen
pp 3585 - 3588; DOI:
10.1021/ja00219a037
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Amphiphilic reactions by means of exceptionally bulky organoaluminum reagents. Rational approach for obtaining unusual equatorial, anti-Cram, and 1,4 selectivity in carbonyl alkylation
Keiji Maruoka, Takayuki Itoh, Minoru Sakurai, Katsumasa Nonoshita, and Hisashi Yamamoto
pp 3588 - 3597; DOI:
10.1021/ja00219a038
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A model for the diastereofacial differentiation in the alkylation of endocyclic enolate
Kiyoshi Tomioka, Hisashi Kawasaki, Kosuke Yasuda, and Kenji Koga
pp 3597 - 3601; DOI:
10.1021/ja00219a039
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Arylcyclopropane photochemistry. Unusual aromatic substituent effects on the photochemical rearrangement of (2-arylcyclopropyl)methyl acetates to 1-arylhomoallyl acetates
Stephen S. Hixson, Lothar A. Franke, Jeffrey A. Gere, and Yi De Xing
pp 3601 - 3610; DOI:
10.1021/ja00219a040
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Photophysics of a cofacial porphyrin-quinone cage molecule and related compounds: fluorescence properties, flash transients, and electron-transfer reactions
Jonathan S. Lindsey, John K. Delaney, David C. Mauzerall, and Henry Linschitz
pp 3610 - 3621; DOI:
10.1021/ja00219a041
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Electrochemical reduction of ketones mediated by (dimethylpyrrolidinio)mercury. Reductive cyclization of unsaturated ketones and redox catalysis studies
James E. Swartz, Tendai J. Mahachi, and Essie Kariv-Miller
pp 3622 - 3628; DOI:
10.1021/ja00219a042
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An investigation of superoxide dismutase Lys-143, Ile-143, and Glu-143 mutants: Cu2Co2SOD derivatives
Lucia Banci, Ivano Bertini, Claudio Luchinat, and Robert A. Hallewell
pp 3629 - 3633; DOI:
10.1021/ja00219a043
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Temperature dependence and electronic transition energies in the magnetic circular dichroism spectrum of horeseradish peroxidase compound I
William R. Browett, Zbigniew Gasyna, and Martin J. Stillman
pp 3633 - 3640; DOI:
10.1021/ja00219a044
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Molecular recognition between oligopeptides and nucleic acids: influence of van der Waals contacts in determining the 3'-terminus of DNA sequences read by monocationic lexitropsins
Moses Lee, Krzysztof Krowicki, John A. Hartley, Richard T. Pon, and J. William Lown
pp 3641 - 3649; DOI:
10.1021/ja00219a045
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DNA strand scission by naturally occurring 5-alkylresorcinols
Ralph T. Scannell, John R. Barr, V. S. Murty, K. Sambi Reddy, and Sidney M. Hecht
pp 3650 - 3651; DOI:
10.1021/ja00219a046
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Biosynthesis of riboflavin. The structure of the four-carbon precursor
Rainer Volk and Adelbert Bacher
pp 3651 - 3653; DOI:
10.1021/ja00219a047
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Pillaring of layered double hydroxides (LDH's) by polyoxometalate anions
Taehyun Kwon, George A. Tsigdinos, and Thomas J. Pinnavaia
pp 3653 - 3654; DOI:
10.1021/ja00219a048
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.eta.1-Coordination versus .eta.2-coordination in transition-metal phosphinomethanide complexes: synthesis and x-ray structure of Cp2Zr(Cl)[C(PMe2)(SiMe3)2]
Hans H. Karsch, Brigitte Deubelly, Josef Hofmann, Ursula Pieper, and Gerhard Mueller
pp 3654 - 3656; DOI:
10.1021/ja00219a049
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Methyl viologen-mediated oxidation-reduction across dihexadecylphosphate vesicles involves transmembrane diffusion
Brian C. Patterson, David H. Thompson, and James K. Hurst
pp 3656 - 3657; DOI:
10.1021/ja00219a050
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Moderately strong intramolecular magnetic exchange interaction between the copper(II) ions separated by 11.25 .ANG. in [L2Cu2(OH2)2(.eta.-terephthalato)](ClO4)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
Phalguni Chaudhuri, Karen Oder, Karl Wieghardt, Stefan Gehring, Wolfgang Haase, Bernhard Nuber, and Johannes Weiss
pp 3657 - 3658; DOI:
10.1021/ja00219a051
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Quinone-substituted monometalated porphyrin dimers: models for photoinduced charge separation at fixed orientation and energy
Jonathan L. Sessler, Martin R. Johnson, Tzuhn Yuan Lin, and Stephen E. Creager
pp 3659 - 3661; DOI:
10.1021/ja00219a052
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Reinterpretation of the bicyclomycin-sodium methanethiolate reaction
Harold Kohn and Syed Abuzar
pp 3661 - 3663; DOI:
10.1021/ja00219a053
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The first cyclooctatetraene to which bond shifting is more accessible than ring inversion
Leo A. Paquette and Ting Zhong Wang
pp 3663 - 3665; DOI:
10.1021/ja00219a054
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Correlations between wettability and structure in monolayers of alkanethiols adsorbed on gold
Colin D. Bain and George M. Whitesides
pp 3665 - 3666; DOI:
10.1021/ja00219a055
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Novel triple-cubane type organometallic oxide clusters: [MCp*MoO4]4.nH2O (M = Rh and Ir; Cp* = C5Me5; n = 2 for Rh and 0 for Ir)
Yoshihito Hayashi, Koshiro Toriumi, and Kiyoshi Isobe
pp 3666 - 3668; DOI:
10.1021/ja00219a056
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The Gilman reagent Ph2CuLi and higher-order Ph3CuLi2: carbon-13 and lithium-6 NMR in dimethyl sulfide
Steven H. Bertz and Gary Dabbagh
pp 3668 - 3670; DOI:
10.1021/ja00219a057
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A total synthesis of (.+-.)-forskolin
Shunichi Hashimoto, Shinji Sakata, Motoharu Sonegawa, and Shiro Ikegami
pp 3670 - 3672; DOI:
10.1021/ja00219a058
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Total synthesis of (.+-.)-forskolin
E. J. Corey, Paul da Silva Jardine, and John C. Rohloff
pp 3672 - 3673; DOI:
10.1021/ja00219a059
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Hexagonal lattice hosts for urea. A new series of designed heterocyclic receptors
Thomas W. Bell and Jia Liu
pp 3673 - 3674; DOI:
10.1021/ja00219a060
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An induced barrier to rotation about the .eta.6-arene-metal bond in centrally bound bent-terphenylenechromium tricarbonyl. A gauge for aromatic character and bond localization?
Mitchell Nambu and Jay S. Siegel
pp 3675 - 3676; DOI:
10.1021/ja00219a061
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Evidence for a chair cyclohexane-1,4-radical cation intermediate in the single electron-transfer-induced Cope rearrangement of 2,5-diaryl-1,5-hexadienes
Tsutomu Miyashi, Akinori Konno, and Yasutake Takahashi
pp 3676 - 3677; DOI:
10.1021/ja00219a062
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Absence of a common ion effect on the hydrolysis of an .alpha.-azido ether of an aliphatic aldehyde
Tina L. Amyes and William P. Jencks
pp 3677 - 3679; DOI:
10.1021/ja00219a063
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The first fluorinated cyclams
Eiichi Kimura, Mitsuhiko Shionoya, Miho Okamoto, and Hiroko Nada
pp 3679 - 3680; DOI:
10.1021/ja00219a064
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Oxygen atom transfer from an iridium dioxygen complex: oxidation of carbon monoxide to carbonate
Holly J. Lawson and Jim D. Atwood
pp 3680 - 3682; DOI:
10.1021/ja00219a065
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Preparation and structure of [(C6H5)4P]3[NbTe10].cntdot.DMF: a soluble tellurium cluster containing an interstitial transition metal atom
Walter A. Flomer and Joseph W. Kolis
pp 3682 - 3683; DOI:
10.1021/ja00219a066
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Transition structures of aldol reactions
Yi Li, Michael N. Paddon-Row, and K. N. Houk
pp 3684 - 3686; DOI:
10.1021/ja00219a067
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cis-Diaquabis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) sensitizes wide band gap oxide semiconductors very efficiently over a broad spectral range in the visible
Paul Liska, Nick Vlachopoulos, Mohammad K. Nazeeruddin, Pascal Comte, and Michael Graetzel
pp 3686 - 3687; DOI:
10.1021/ja00219a068
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Criteria for concertedness in cycloadditions
Barry M. Trost and Maria L. Miller
pp 3687 - 3689; DOI:
10.1021/ja00219a069
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Reactions of 1,1-dimethylsilabutadiene. Stereospecific 4 + 2 and nonstereospecific 2 + 2 cycloadditions
Robert T. Conlin and Mohammad Namavari
pp 3689 - 3690; DOI:
10.1021/ja00219a070
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A copper-oxygen (Cu2-O2) complex. Crystal structure and characterization of a reversible dioxygen binding system
Richard R. Jacobson, Zoltan Tyeklar, Amjad Farooq, Kenneth D. Karlin, Shuncheng Liu, and Jon Zubieta
pp 3690 - 3692; DOI:
10.1021/ja00219a071
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Palladium-catalyzed regular insertion of isonitriles into silicon-silicon linkage of polysilane
Yoshihiko Ito, Takaharu Matsuura, and Masahiro Murakami
pp 3692 - 3693; DOI:
10.1021/ja00219a072
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Cycloaddition reactions of silyloxyacetylenes with ketenes: synthesis of cyclobutenones, resorcinols, and .DELTA.-6-tetrahydrocannabinol
Conrad J. Kowalski and G. Sankar Lal
pp 3693 - 3695; DOI:
10.1021/ja00219a073
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Hydride transfer catalyzed by lactate dehydrogenase displays absolute stereospecificity at C4 of the nicotinamide ring
V. E. Anderson and R. D. LaReau
pp 3695 - 3697; DOI:
10.1021/ja00219a074
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Direct evidence for both thermal and photochemical stepwise cleavage in a pair of isomeric azo compounds
D. E. Reedich and R. S. Sheridan
pp 3697 - 3698; DOI:
10.1021/ja00219a075
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Singlet oxygen production from the reaction of superoxide ion with halocarbons in acetonitrile
Jeffrey R. Kanofsky, Hiroshi Sugimoto, and Donald T. Sawyer
pp 3698 - 3699; DOI:
10.1021/ja00219a076
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Bimodal inclusion of nitroxide radicals by .beta.-cyclodextrin in water as detected by electron spin resonance
Yashige Kotake and Edward G. Janzen
pp 3699 - 3701; DOI:
10.1021/ja00219a077
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A symmetrically hydrogen-bonded binitrosamine cation produced on protonation of N-nitrosopyrrolidine
Larry K. Keefer, Joseph A. Hrabie, Lena Ohannesian, Judith L. Flippen-Anderson, and Clifford George
pp 3701 - 3702; DOI:
10.1021/ja00219a078
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Ligand-assisted nucleophilic additions. Control of site and face attack of nucleophiles on 4-oxido enones
Mark Solomon, W. Charles L. Jamison, Michael McCormick, Dennis Liotta, David A. Cherry, John E. Mills, Rekha D. Shah, James D. Rodgers, and Cynthia A. Maryanoff
pp 3702 - 3704; DOI:
10.1021/ja00219a079
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Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates
Darryl P. Klein, Jeffrey C. Hayes, and Robert G. Bergman
pp 3704 - 3706; DOI:
10.1021/ja00219a080
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Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex
Eric N. Jacobsen, Karen I. Goldberg, and Robert G. Bergman
pp 3706 - 3707; DOI:
10.1021/ja00219a081
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Alkyl diazonium ion pairs and deamination. Part 45. The preparation of carbonium ions and other high-energy alkylating agents under mild conditions
Emil H. White, Jeffrey T. DePinto, Albert J. Polito, Ines Bauer, and David F. Roswell
pp 3708 - 3709; DOI:
10.1021/ja00219a082
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Modification of proteases to esterases for peptide synthesis: methylchymotrypsin
J. Blair West, Jeff Scholten, N. J. Stolowich, John L. Hogg, A. I. Scott, and Chi Huey Wong
pp 3709 - 3710; DOI:
10.1021/ja00219a083
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Photoelectrochemical evolution of elemental fluorine at titanium dioxide electrodes in anhydrous hydrogen fluoride solutions
Chong Mou Wang, Qui Chee Mir, Simin Maleknia, and Thomas E. Mallouk
pp 3710 - 3712; DOI:
10.1021/ja00219a084
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Intramolecular hydrosilation of .alpha.-hydroxy enol ethers: a new highly stereoselective route to polyhydroxylated molecules
Kohei Tamao, Yoshiki Nakagawa, Hitoshi Arai, Noriko Higuchi, and Yoshihiko Ito
pp 3712 - 3714; DOI:
10.1021/ja00219a085
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Biosynthesis of ephedrine
Gunnar Grue-Sorensen and Ian D. Spenser
pp 3714 - 3715; DOI:
10.1021/ja00219a086
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Book Reviews

pp 3716 - 3722; DOI:
10.1021/ja00219a600
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Issue 12


Phosphoranes: multiple bonding and substituent effects
M. M. Francl, R. C. Pellow, and L. C. Allen
pp 3723 - 3728; DOI:
10.1021/ja00220a001
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Chemical origins of substituent effects in alkylpentacarbonylmanganese(I) group migration reactions
Frank U. Axe and Dennis S. Marynick
pp 3728 - 3734; DOI:
10.1021/ja00220a002
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Calculation of the free energy of association of nucleic acid bases in vacuo and water solution
Piotr Cieplak and Peter A. Kollman
pp 3734 - 3739; DOI:
10.1021/ja00220a003
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Molecular and electronic structure of the low-lying electronic states of cycloalkenylidenes. Cyclopentadienylidene
Josep M. Bofill, Nuria Bru, Jaume Farras, Santiago Olivella, Albert Sole, and Jaume Vilarrasa
pp 3740 - 3746; DOI:
10.1021/ja00220a004
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Five-fold diamond structure of adamantane-1,3,5,7-tetracarboxylic acid
Otto Ermer
pp 3747 - 3754; DOI:
10.1021/ja00220a005
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Homogeneous gas-phase formation and destruction of anthranil from o-nitrotoluene decomposition
Y. Z. He, J. P. Cui, W. G. Mallard, and W. Tsang
pp 3754 - 3759; DOI:
10.1021/ja00220a006
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Reversible one-electron generation of 4a,5-substituted flavin radical cations: models for a postulated key intermediate in bacterial bioluminescence
H. I. X. Mager, D. Sazou, Y. H. Liu, S. C. Tu, and K. M. Kadish
pp 3759 - 3762; DOI:
10.1021/ja00220a007
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Improved ab initio calculations of amplitude and phase functions for extended x-ray absorption fine structure spectroscopy
A. G. McKale, B. W. Veal, A. P. Paulikas, S. K. Chan, and G. S. Knapp
pp 3763 - 3768; DOI:
10.1021/ja00220a008
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Electron density analysis of the n .fwdarw. .pi.* transition of formaldehyde
Andrew Streitwieser and Boris Kohler
pp 3769 - 3772; DOI:
10.1021/ja00220a009
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Ab initio MO study of the full catalytic cycle of olefin hydrogenation by the Wilkinson catalyst RhCl(PR3)3
C. Daniel, N. Koga, J. Han, X. Y. Fu, and K. Morokuma
pp 3773 - 3787; DOI:
10.1021/ja00220a010
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A theoretical study of .alpha.-acylmethyl, oxiranyl, and acetyl carbocations
M. H. Lien and A. C. Hopkinson
pp 3788 - 3792; DOI:
10.1021/ja00220a011
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CASSCF and CCI study of the photochemistry of HCo(CO)4
Alain Veillard and Alain Strich
pp 3793 - 3797; DOI:
10.1021/ja00220a012
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New structural insights into the iron-molybdenum cofactor from Azotobacter vinelandii nitrogenase through sulfur K and molybdenum L x-ray absorption edge studies
Britt Hedman, Patrick Frank, Stephen F. Gheller, A. Lawrence Roe, William E. Newton, and Keith O. Hodgson
pp 3798 - 3805; DOI:
10.1021/ja00220a013
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NMR study of the conformations of free and lanthanide-complexed glutathione in aqueous solution
Benjamin Podanyi and R. Stephen Reid
pp 3805 - 3810; DOI:
10.1021/ja00220a014
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Electronic structure of plastocyanin: excited state spectral features
Andrew A. Gewirth and Edward I. Solomon
pp 3811 - 3819; DOI:
10.1021/ja00220a015
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Carbon-13 CP/MAS NMR studies of amylose inclusion complexes, cyclodextrins, and the amorphous phase of starch granules: relationships between glycosidic linkage conformation and solid-state carbon-13 chemical shifts
Michael J. Gidley and Stephen M. Bociek
pp 3820 - 3829; DOI:
10.1021/ja00220a016
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Structural factors controlling the aggregation of lithium phenolates in weakly polar aprotic solvents
Lloyd M. Jackman and B. D. Smith
pp 3829 - 3835; DOI:
10.1021/ja00220a017
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Low-spin cyanide adduct of transferrin
Susan K. Swope, N. Dennis Chasteen, Katherine E. Weber, and Daniel C. Harris
pp 3835 - 3840; DOI:
10.1021/ja00220a018
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Infrared spectra and structures of lithium-benzene and lithium-dibenzene complexes in solid argon
Laurent Manceron and Lester Andrews
pp 3840 - 3846; DOI:
10.1021/ja00220a019
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Determination of gas-phase ligand binding energies to magnesium(+) by FTMS techniques
Lorenza Operti, Edward C. Tews, and Ben S. Freiser
pp 3847 - 3853; DOI:
10.1021/ja00220a020
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Ionic hydrogen bond and ion solvation. 6. Interaction energies of the acetate ion with organic molecules. Comparison of CH3COO- with Cl-, CN-, and SH-
Michael Mautner
pp 3854 - 3858; DOI:
10.1021/ja00220a021
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The ionic hydrogen bond and ion solvation. 7. Interaction energies of carbanions with solvent molecules
Michael Meot-Ner
pp 3858 - 3862; DOI:
10.1021/ja00220a022
PDF
Distonic ions as reacting species
Thomas Bjoernholm, Steen Hammerum, and Dietmar Kuck
pp 3862 - 3869; DOI:
10.1021/ja00220a023
PDF
Secondary hydrogen isotope effects on simple cleavage reactions in the gas phase. The .alpha.-cleavage of tertiary amine cation radicals
Steen Ingemann, Steen Hammerum, and Peter J. Derrick
pp 3869 - 3873; DOI:
10.1021/ja00220a024
PDF
Substituent effects on solvent dependence of the band shape of charge-transfer transitions in N-pyridinium phenolates
A. M. Kjaer and J. Ulstrup
pp 3874 - 3879; DOI:
10.1021/ja00220a025
PDF
Reactions of metal-cluster carbonyls in pillared clay galleries: surface coordination chemistry and Fischer-Tropsch catalysis
Emmanuel P. Giannelis, Edward G. Rightor, and Thomas J. Pinnavaia
pp 3880 - 3885; DOI:
10.1021/ja00220a026
PDF
The influence of guest-host interactions on the excited-state properties of dioxorhenium(V) ions in intracrystalline environments of complex-layered oxides
Mark D. Newsham, Emmanuel P. Giannelis, Thomas J. Pinnavaia, and Daniel G. Nocera
pp 3885 - 3891; DOI:
10.1021/ja00220a027
PDF
Photophysical studies of XRe(CO)4L (X = Cl, I; L = CO, pip, PPh) complexes. Examples of ligand field luminescence from organometallic complexes in fluid solution
Marsha M. Glezen and Alistair J. Lees
pp 3892 - 3897; DOI:
10.1021/ja00220a028
PDF
Rupture and repair of the porphyrin inner core: carbon-nitrogen bond breaking and formation in ruthenium complexes of an N,N'-bridged porphyrin
Alan L. Balch, Yee Wai Chan, Marilyn M. Olmstead, Mark W. Renner, and Fred E. Wood
pp 3897 - 3902; DOI:
10.1021/ja00220a029
PDF
Formation and decomposition of iron-carbon .sigma.-bonds in the reaction of iron(II)-poly(amino carboxylate) complexes with CO2-free radicals. A pulse radiolysis study
Sara Goldstein, Gidon Czapski, Haim Cohen, and Dan Meyerstein
pp 3903 - 3907; DOI:
10.1021/ja00220a030
PDF
Anisotropic exchange in the cobalt-cobalt and cobalt-copper dinuclear EDTA hydrate (Co2(EDTA).cntdot.6H2O, CoCu(EDTA).cntdot.6H2O) bimetallic ordered chains. Low temperature investigation of the thermal and magnetic properties
E. Coronado, M. Drillon, P. R. Nugteren, L. J. De Jongh, and D. Beltran
pp 3907 - 3913; DOI:
10.1021/ja00220a031
PDF
Metal-assisted three-fragment demolition of the dithiocarbonate ligand: a new synthetic route to homo- and heterobinuclear bis(.mu.-sulfido)metal complexes. Chemical, electrochemical, and spectroscopic characterization of a family of complexes of iron, cobalt, rhodium, and platinum with bridging sulfido ligands
Claudio Bianchini, Andrea Meli, Franco Laschi, Alberto Vacca, and Piero Zanello
pp 3913 - 3919; DOI:
10.1021/ja00220a032
PDF
New crystalline phase of (octaethylporphinato)nickel(II): effects of .pi.-.pi. interactions on molecular structure and resonance Raman spectra
Theodore D. Brennan, W. Robert Scheidt, and John A. Shelnutt
pp 3919 - 3924; DOI:
10.1021/ja00220a033
PDF
Stereoselective reactions of alkenylpyranosides: the effect of double bond geometry on conformation
Michael P. DeNinno, Samuel J. Danishefsky, and Gayle Schulte
pp 3925 - 3929; DOI:
10.1021/ja00220a034
PDF
Stereoselective total syntheses of the naturally occurring enantiomers of N-acetylneuraminic acid and 3-deoxy-D-manno-2-octulosonic acid. A new and stereospecific approach to sialo and 3-deoxy-D-manno-2-octulosonic acid conjugates
Samuel J. Danishefsky, Michael P. DeNinno, and Shu Hui Chen
pp 3929 - 3940; DOI:
10.1021/ja00220a035
PDF
Substituent effects and the Wittig mechanism: the case of stereospecific oxaphosphetane decomposition
E. Vedejs, C. F. Marth, and R. Ruggeri
pp 3940 - 3948; DOI:
10.1021/ja00220a036
PDF
Mechanism of the Wittig reaction: the role of substituents at phosphorus
E. Vedejs and C. F. Marth
pp 3948 - 3958; DOI:
10.1021/ja00220a037
PDF
Braunicene. A novel cyclic C32 isoprenoid from Botryococcus braunii
Zheng Huang, C. Dale Poulter, Fred R. Wolf, Todd C. Somers, and James D. White
pp 3959 - 3964; DOI:
10.1021/ja00220a038
PDF
The stereochemistry of addition of trialkylammonium and pyridinium tetrafluoroborate salts to activated acetylenes. Preparation of novel dienophiles for Diels-Alder reactions
Michael E. Jung and Keith R. Buszek
pp 3965 - 3969; DOI:
10.1021/ja00220a039
PDF
Electron-rich hexasubstituted benzene derivatives and their oxidized cation radicals, dications with potential triplet ground states, and polycations
John Thomaides, Przemyslaw Maslak, and Ronald Breslow
pp 3970 - 3979; DOI:
10.1021/ja00220a040
PDF
N,N'-dibenzyl-N,N'-ethylenetartramide: a rationally designed chiral auxiliary for the allylboration reaction
William R. Roush and Luca Banfi
pp 3979 - 3982; DOI:
10.1021/ja00220a041
PDF
On the electron-proton-electron mechanism for 1-benzyl-1,4-dihydronicotinamide oxidations
Larry L. Miller and James R. Valentine
pp 3982 - 3989; DOI:
10.1021/ja00220a042
PDF
Marcus theory of hydride transfer from an anionic reduced deazaflavin to NAD+ analogs
In Sook Han Lee, Drazen Ostovic, and Maurice Kreevoy
pp 3989 - 3993; DOI:
10.1021/ja00220a043
PDF
Urea as the most reactive and versatile nitrogen nucleophile for the palladium(2+)-catalyzed cyclization of unsaturated amines
Yoshinao Tamaru, Makoto Hojo, Hideyuki Higashimura, and Zenichi Yoshida
pp 3994 - 4002; DOI:
10.1021/ja00220a044
PDF
Oxygen donation by an intermediate in the reaction of 3CF2 with oxygen
M. Rahman, Michael L. McKee, Philip B. Shevlin, and Renata Sztyribicka
pp 4002 - 4007; DOI:
10.1021/ja00220a045
PDF
Equilibrium and kinetic acidities of benzylic ketones. Application of the Marcus equation to the deprotonation of carbon acids
John W. Bunting and Dimitrios Stefanidis
pp 4008 - 4017; DOI:
10.1021/ja00220a046
PDF
2-Aza-2,4-cyclopentadienone. Existence and reactivity
F. Gavina, A. M. Costero, M. R. Andreu, M. Carda, and S. V. Luis
pp 4017 - 4018; DOI:
10.1021/ja00220a047
PDF
Structural effects on the transition states of imine-forming eliminations in N-substituted O-(arylsulfonyl)hydroxylamines
Robert V. Hoffman and Jean M. Shankweiler
pp 4019 - 4022; DOI:
10.1021/ja00220a048
PDF
Synthesis and identification of benzo[a]pyrene-guanine nucleoside adducts formed by electrochemical oxidation and by horseradish peroxidase catalyzed reaction of benzo[a]pyrene with DNA
E. G. Rogan, E. L. Cavalieri, S. R. Tibbels, P. Cremonesi, C. D. Warner, D. L. Nagel, K. B. Tomer, R. L. Cerny, and M. L. Gross
pp 4023 - 4029; DOI:
10.1021/ja00220a049
PDF
Molybdenum- and tungsten-substituted hemoproteins. Models for the high-valent iron porphyrin in myoglobin and horseradish peroxidase
Yoshitsugu Shiro, Motoru Takeda, and Isao Morishima
pp 4030 - 4035; DOI:
10.1021/ja00220a050
PDF
The biosynthesis of furanomycin. Mechanism of formation of the ether linkage
Ronald J. Parry, Rajesh Turakhia, and Buu Hanh Phuoc
pp 4035 - 4036; DOI:
10.1021/ja00220a051
PDF
Evolution of electronically excited triphenylmethyl radical. Picosecond preparation-pump-probe spectroscopic experiments
Jeffrey A. Schmidt and Edwin F. Hilinski
pp 4036 - 4038; DOI:
10.1021/ja00220a052
PDF
Gas-phase reactions of bis(.eta.5-cyclopentadienyl)methylzirconium1+ with dihydrogen, ethylene, and propylene
Charles S. Christ, John R. Eyler, and David E. Richardson
pp 4038 - 4039; DOI:
10.1021/ja00220a053
PDF
Palladium-catalyzed coupling of vinyl epoxides with organostannanes
Antonio M. Echavarren, David R. Tueting, and J. K. Stille
pp 4039 - 4041; DOI:
10.1021/ja00220a054
PDF
Total synthesis of (+)-18-deoxynargenicin A1
Daniel J. Plata and James Kallmerten
pp 4041 - 4042; DOI:
10.1021/ja00220a055
PDF
Irreversible inhibition of papain by epoxysuccinyl peptides. Carbon-13 NMR characterization of the site of alkylation
Yuichiro Yabe, Dominique Guillaume, and Daniel H. Rich
pp 4043 - 4044; DOI:
10.1021/ja00220a056
PDF
Formation of nitridoiron(V) porphyrins detected by resonance Raman spectroscopy
Wolf Dieter Wagner and Kazuo Nakamoto
pp 4044 - 4045; DOI:
10.1021/ja00220a057
PDF
Transition structure for hydride transfer to pyridinium cation from methanolate. Modeling of LADH catalyzed reaction
O. Tapia, R. Cardenas, J. Andres, and F. Colonna-Cesari
pp 4046 - 4047; DOI:
10.1021/ja00220a058
PDF
Electron transfer competes with proton transfer in gas-phase acid-base reactions
Chau Chung Han and John I. Brauman
pp 4048 - 4049; DOI:
10.1021/ja00220a059
PDF
Cyclodextrin sandwiched Fe4S4 cluster
Yasuhisa Kuroda, Yoro Sasaki, Yasushi Shiroiwa, and Iwao Tabushi
pp 4049 - 4050; DOI:
10.1021/ja00220a060
PDF
Absolute rates of dimerization and cycloaddition of 3,4-dimethylenefuran and 3,4-dimethylenethiophene by nanosecond time-resolved spectroscopy
J. C. Scaiano, Veronique Wintgens, Ann Bedell, and Jerome A. Berson
pp 4050 - 4051; DOI:
10.1021/ja00220a061
PDF
Total synthesis of amphimedine
Antonio M. Echavarren and J. K. Stille
pp 4051 - 4053; DOI:
10.1021/ja00220a062
PDF
Electronic emission from bis(bridging diphosphine) derivatives of Re2(CO)10.cntdot. Characterization of the emissive state as 3(d.sigma. .fwdarw. d.sigma.*)
A. E. Stiegman and Vincent M. Miskowski
pp 4053 - 4054; DOI:
10.1021/ja00220a063
PDF
Luminescence from a novel mixed-valence dirhodium fluorophosphine complex
Joel I. Dulebohn, Donald L. Ward, and Daniel G. Nocera
pp 4054 - 4056; DOI:
10.1021/ja00220a064
PDF
Stereochemical control of the exchange of hydrogen atoms between hydride and dihydrogen ligands in the complexes [M(.eta.2-H2)(H)(meso- or rac-tetraphos-1)]+, M = Fe, Os
Maria T. Bautista, Kelly A. Earl, Patricia A. Maltby, and Robert H. Morris
pp 4056 - 4057; DOI:
10.1021/ja00220a065
PDF
X-ray absorption of Azotobacter vinelandii vanadium nitrogenase
G. N. George, C. L. Coyle, B. J. Hales, and Steven P. Cramer
pp 4057 - 4059; DOI:
10.1021/ja00220a066
PDF
Effect of ion pairing on bond order and charge localization in alkyl phosphorothioates
Janina Baraniak and Perry A. Frey
pp 4059 - 4060; DOI:
10.1021/ja00220a067
PDF
Adenosine 5'-[.alpha.,.beta.-imido]triphosphate, a substrate for T7 RNA polymerase and rabbit muscle creatine kinase
Qi Feng Ma, Patricia C. Babbitt, and George L. Kenyon
pp 4060 - 4061; DOI:
10.1021/ja00220a068
PDF
A short enantioselective synthesis of (+)-sterpurene: complete intramolecular transfer of central to axial to central chiral elements
Richard A. Gibbs and William H. Okamura
pp 4062 - 4063; DOI:
10.1021/ja00220a069
PDF
Macromolecular stereochemistry: a cooperative deuterium isotope effect leading to a large optical rotation
Mark M. Green, Christopher Andreola, Beth Munoz, Michael P. Reidy, and Karl Zero
pp 4063 - 4065; DOI:
10.1021/ja00220a070
PDF
Intra- and intermolecular hetero-Diels-Alder reactions. 23. Intermolecular hetero-Diels-Alder reactions of enamino ketones at high pressure. The first significant pressure-induced diastereoselectivity in organic transformations
Lutz F. Tietze, Thomas Huebsch, Edgar Voss, Michael Buback, and Winfried Tost
pp 4065 - 4066; DOI:
10.1021/ja00220a071
PDF
Stereoselective synthesis of monosubstituted cis-aryldiazenes, NH:NR
Milton R. Smith and Gregory L. Hillhouse
pp 4066 - 4068; DOI:
10.1021/ja00220a072
PDF
Synthesis and structural characterization of platinum-silicon dimers with unusually short cross-ring silicon-silicon interactions
Eugene A. Zarate, Claire A. Tessier-Youngs, and Wiley J. Youngs
pp 4068 - 4070; DOI:
10.1021/ja00220a073
PDF
Diallyl- and bis(2-methylallyl)tetrakis(dimethylamino)ditungsten: W2(.mu.-.eta.3-C3H5)2(NMe2)4 and W2(.mu.1-C4H7)2(NMe2)4 (M.tplbond.M). Comments on ligand-metal .pi.-interactions at (W.tplbond.W)6+ centers
Malcolm H. Chisholm, M. J. Hampden-Smith, J. C. Huffman, and K. G. Moodley
pp 4070 - 4071; DOI:
10.1021/ja00220a074
PDF
Concave functionality: some exceptionally large binding constants of phenol sticky hosts
R. E. Sheridan and H. W. Whitlock
pp 4071 - 4073; DOI:
10.1021/ja00220a075
PDF
Enhanced formation of 8.pi.(4n) conjugated cyclic carbanions in the excited state: first example of photochemical C-H bond heterolysis in photoexcited suberene
Peter Wan, Erik Krogh, and Becky Chak
pp 4073 - 4074; DOI:
10.1021/ja00220a076
PDF
.pi.-Facial selectivity: heteroatom directed syn/anti stereoselection in Diels-Alder cycloadditions of plane-nonsymmetric cyclopentadienes
John B. Macaulay and Alex G. Fallis
pp 4074 - 4076; DOI:
10.1021/ja00220a077
PDF
Molecular recognition. 2. Molecular recognition of amino acids: two-point fixation of amino acids with bifunctional metalloporphyrin receptors
Yasuhiro Aoyama, Atsushi Yamagishi, Masumi Asagawa, Hiroo Toi, and Hisanobu Ogoshi
pp 4076 - 4077; DOI:
10.1021/ja00220a078
PDF
The carbon-carbon double bond of tetrafluoroethylene
Emily A. Carter and William A. Goddard
pp 4077 - 4079; DOI:
10.1021/ja00220a079
PDF
The synthesis, characterization, and reactivity of a novel nitroruthenium(III) complex
Randolph A. Leising and Kenneth J. Takeuchi
pp 4079 - 4080; DOI:
10.1021/ja00220a080
PDF
Pentalenene biosynthesis and the enzymatic cyclization of farnesyl pyrophosphate. Anti stereochemistry in a biological SE' reaction
David E. Cane, Christopher Abell, Rene Lattman, Charles T. Kane, Brian R. Hubbard, and Paul H. M. Harrison
pp 4081 - 4082; DOI:
10.1021/ja00220a081
PDF
Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+
Gerardo S. Bodner, Jesus M. Fernandez, Atta M. Arif, and J. A. Gladysz
pp 4082 - 4084; DOI:
10.1021/ja00220a082
PDF
Synthesis and confirmation of structure of the antheridium-inducing factor from the fern Anemia mexicana
Mark Furber and Lewis N. Mander
pp 4084 - 4085; DOI:
10.1021/ja00220a083
PDF
Isotope effects on isotope effects. Failure of the rule of the geometric mean as evidence for tunneling
Mohammed Amin, Robin C. Price, and William H. Saunders
pp 4085 - 4086; DOI:
10.1021/ja00220a084
PDF
Triticones A and B, novel phytotoxins from the plant pathogenic fungus Drechslera tritici-repentis
Fumio Sugawara, Nobutaka Takahashi, Gary A. Strobel, Scott A. Strobel, Helen S. M. Lu, and Jon Clardy
pp 4086 - 4087; DOI:
10.1021/ja00220a085
PDF
Catalysis of alkene oxidation by nickel salen complexes using sodium hypochlorite under phase-transfer conditions
Heungsik Yoon and Cynthia J. Burrows
pp 4087 - 4089; DOI:
10.1021/ja00220a086
PDF
Observations on the activation of bicyclomycin
Syed Abuzar and Harold Kohn
pp 4089 - 4090; DOI:
10.1021/ja00220a087
PDF
Oxygen-hydrogen bond dissociation energies in para-substituted phenols
P. Mulder, O. W. Saastad, and D. Griller
pp 4090 - 4092; DOI:
10.1021/ja00220a088
PDF
Synthesis, characterization, and x-ray crystal structure of a donor-stabilized bis(silylene)iron complex
Keiji Ueno, Hiromi Tobita, Mamoru Shimoi, and Hiroshi Ogino
pp 4092 - 4093; DOI:
10.1021/ja00220a089
PDF
Two-dimensional NMR strategies for carbon-carbon correlations and sequence-specific assignments in carbon-13 labeled proteins
William M. Westler, M. Kainosho, H. Nagao, N. Tomonaga, and John L. Markley
pp 4093 - 4095; DOI:
10.1021/ja00220a090
PDF
Detailed analysis of carbon-13 NMR spin systems in a uniformly carbon-13 enriched protein: flavodoxin from Anabaena 7120
Brian J. Stockman, William M. Westler, Prashanth Darba, and John L. Markley
pp 4095 - 4096; DOI:
10.1021/ja00220a091
PDF
First direct observation of pyridyne: matrix infrared study of the photolysis products of 3,4-pyridinedicarboxylic anhydride
H. H. Nam and G. E. Leroi
pp 4096 - 4097; DOI:
10.1021/ja00220a092
PDF
Computer Software Reviews

pp 4098 - 4100; DOI:
10.1021/ja00220a600
PDF
Book Reviews

pp 4101 - 4104; DOI:
10.1021/ja00220a601
PDF

Issue 13


Basicity and acidity of azoles: the annelation effect in azoles
Javier Catalan, Rosa Maria Claramunt, Jose Elguero, Jose Laynez, Margarita Menendez, Frederick Anvia, J. H. Quian, Mare Taagepera, and Robert W. Taft
pp 4105 - 4111; DOI:
10.1021/ja00221a001
PDF
In situ x-ray photoelectron spectroscopic studies of carbocations
Stephen A. Johnson and David T. Clark
pp 4112 - 4117; DOI:
10.1021/ja00221a002
PDF
Sigma/pi interactions in [2.2]paracyclophanes. PE investigations on octamethyltetrasila[2.2]paracyclophane and octamethyltetrasila[2.2](2,5)thiophenophane and -furanophane
Rolf Gleiter, Wolfgang Schaefer, Gerhard Krennrich, and Hideki Sakurai
pp 4117 - 4120; DOI:
10.1021/ja00221a003
PDF
High-molecular-weight boron oxides in the gas phase
Robert J. Doyle
pp 4120 - 4126; DOI:
10.1021/ja00221a004
PDF
An NMR method for distinguishing classical from nonclassical structures in transition metal polyhydrides
Douglas G. Hamilton and Robert H. Crabtree
pp 4126 - 4133; DOI:
10.1021/ja00221a005
PDF
Vibrational circular dichroism of optically active allenes. Experimental results
U. Narayanan, T. A. Keiderling, C. J. Elsevier, P. Vermeer, and W. Runge
pp 4133 - 4138; DOI:
10.1021/ja00221a006
PDF
Vibrational circular dichroism of optically active substituted allenes. Calculational results
Usha Narayanan and T. A. Keiderling
pp 4139 - 4144; DOI:
10.1021/ja00221a007
PDF
Experimental and theoretical study of the structures and optical rotations of chiral bicyclic ortho esters
A. E. Wroblewski, J. Applequist, A. Takaya, R. Honzatko, S. S. Kim, R. A. Jacobson, B. H. Reitsma, E. S. Yeung, and J. G. Verkade
pp 4144 - 4150; DOI:
10.1021/ja00221a008
PDF
Effects of solvents, axial ligation, and radical cation formation on the V:O stretching Raman frequency in vanadyl porphyrins. Implications for peroxidase intermediates
Y. Oliver Su, Roman S. Czernuszewicz, Lisa A. Miller, and Thomas G. Spiro
pp 4150 - 4157; DOI:
10.1021/ja00221a009
PDF
Oxomanganese(IV) porphyrins identified by resonance Raman and infrared spectroscopy. Weak bonds and the stability of the half-filled t2g subshell
Roman S. Czernuszewicz, Y. Oliver Su, Michael K. Stern, Kathleen A. Macor, Dongho Kim, John T. Groves, and Thomas G. Spiro
pp 4158 - 4165; DOI:
10.1021/ja00221a010
PDF
Differences between human and porcine insulin investigated by linear prediction carbon-13 NMR
Jens Jorgen Led, Henrik Gesmar, Kim R. Hejnaes, and Finn B. Hansen
pp 4165 - 4167; DOI:
10.1021/ja00221a011
PDF
Conformations of cyclic octapeptides. 5. Crystal structure of cyclo(Cys-Gly-Pro-Phe)2 and rotating frame relaxation (T1.rho.) NMR studies of internal mobility in cyclic octapeptides
Kenneth D. Kopple, Yu Sen Wang, Anita Go Cheng, and Krishna K. Bhandary
pp 4168 - 4176; DOI:
10.1021/ja00221a012
PDF
Proton NMR resonance assignment and dynamic analysis of phenylalanine CD1 in a low-spin ferric complex of sperm whale myoglobin
S. Donald Emerson, Juliette T. J. Lecomte, and Gerd N. La Mar
pp 4176 - 4182; DOI:
10.1021/ja00221a013
PDF
Atomic and group electronegativities from the electron-density distributions of molecules
Russell J. Boyd and Kenneth E. Edgecombe
pp 4182 - 4186; DOI:
10.1021/ja00221a014
PDF
Molecular modeling of the physical properties of alkanes
Diane E. Needham, I Chien Wei, and Paul G. Seybold
pp 4186 - 4194; DOI:
10.1021/ja00221a015
PDF
Hydrogen-bonded complexes involving benzene as an hydrogen acceptor
B. V. Cheney, M. W. Schulz, J. Cheney, and W. G. Richards
pp 4195 - 4198; DOI:
10.1021/ja00221a016
PDF
Molecular dynamics simulation of interfacial water structure and dynamics in a parvalbumin solution
Peter Ahlstroem, Olle Teleman, and Bo Joensson
pp 4198 - 4203; DOI:
10.1021/ja00221a017
PDF
Potentially aromatic metallocycles
Kim K. Baldridge and Mark S. Gordon
pp 4204 - 4208; DOI:
10.1021/ja00221a018
PDF
Ab initio study of coupled cages
Michael L. McKee
pp 4208 - 4212; DOI:
10.1021/ja00221a019
PDF
Cis-trans energy difference for the peptide bond in the gas phase and in aqueous solution
William L. Jorgensen and Jiali Gao
pp 4212 - 4216; DOI:
10.1021/ja00221a020
PDF
Cis-trans isomerization of epoxides catalyzed by ruthenium(II) porphyrins
John T. Groves, Kwang Hyun Ahn, and Robert Quinn
pp 4217 - 4220; DOI:
10.1021/ja00221a021
PDF
Synthesis and reactivity of a family of copper monooxygenase model systems
Luigi Casella, Michele Gullotti, Gianfranco Pallanza, and Luigi Rigoni
pp 4221 - 4227; DOI:
10.1021/ja00221a022
PDF
Organometallic synthesis of manganese telluride. Isolation and characterization of [(Et3P)2(CO)3MnTe]2
Michael L. Steigerwald and C. E. Rice
pp 4228 - 4231; DOI:
10.1021/ja00221a023
PDF
Mechanistic investigation of the ZrMe/PtMe exchange in Cp*ZrMe(.mu.-OCH2PPh2)2PtMe2
Steven M. Baxter, Gregory S. Ferguson, and Peter T. Wolczanski
pp 4231 - 4241; DOI:
10.1021/ja00221a024
PDF
Structure of the dicobalt "face-to-face" porphyrin with two four-atom amide bridges: Co2(FTF4).cntdot.CH3OH.cntdot.1.6CH2Cl2
Kimoon Kim, James P. Collman, and James A. Ibers
pp 4242 - 4246; DOI:
10.1021/ja00221a025
PDF
Synthesis of an (.eta.3-allyl)(hydrido)iridium complex and its reactions with arenes and alkanes. Sequential intermolecular carbon-hydrogen oxidative addition and hydride-to-alkene migratory insertion reactions
William D. McGhee and Robert G. Bergman
pp 4246 - 4262; DOI:
10.1021/ja00221a026
PDF
X-ray absorption studies of three-coordinate dicopper(I) complexes and their dioxygen adducts
Ninian J. Blackburn, Richard W. Strange, Amjad Farooq, Michael S. Haka, and Kenneth D. Karlin
pp 4263 - 4272; DOI:
10.1021/ja00221a027
PDF
Metal complexes with tetrapyrrole ligands. 50. Redox potentials of sandwichlike metal bis(octaethylporphyrinates) and their correlation with ring-ring distances
Johann W. Buchler and Bernd Scharbert
pp 4272 - 4276; DOI:
10.1021/ja00221a028
PDF
Oxygen transfer from percarboxylic acids and alkyl hydroperoxides to (meso-tetraphenylporphinato)iron(III) and -chromium(III)
William A. Lee, Lung Chi Yuan, and Thomas C. Bruice
pp 4277 - 4283; DOI:
10.1021/ja00221a029
PDF
Crown ether Grignard reagents; x-ray structure of 2-(bromomagnesio)-1,3-xylyl-15-crown-4
Peter R. Markies, Otto S. Akkerman, Friedrich Bickelhaupt, Wilberth J. J. Smeets, and Anthony L. Spek
pp 4284 - 4292; DOI:
10.1021/ja00221a030
PDF
Reactions of low-valent transition-metal complexes with hydrogen peroxide. Are they "Fenton-like" or not? 1. The case of Cu+aq and Cr2+aq
Mohamed Masarwa, Haim Cohen, Dan Meyerstein, David L. Hickman, Andreja Bakac, and James H. Espenson
pp 4293 - 4297; DOI:
10.1021/ja00221a031
PDF
Aroylnitrenes with singlet ground states: photochemistry of acetyl-substituted aroyl and aryloxycarbonyl azides
Michael E. Sigman, Tom Autrey, and Gary B. Schuster
pp 4297 - 4305; DOI:
10.1021/ja00221a032
PDF
Formation of hydrogen cyanide and acetylene oligomers by photolysis of ammonia in the presence of acetylene: applications to the atmospheric chemistry of Jupiter
James P. Ferris and Yoji Ishikawa
pp 4306 - 4312; DOI:
10.1021/ja00221a033
PDF
Additions of singlet oxygen to alkoxy-substituted dienes. The mechanism of the singlet oxygen 1,2-cycloaddition reaction
Edward L. Clennan and Krzysztof Nagraba
pp 4312 - 4318; DOI:
10.1021/ja00221a034
PDF
Relative yields of excited ketones from self-reactions of alkoxyl and alkylperoxyl radical pairs
S. H. Lee and G. D. Mendenhall
pp 4318 - 4323; DOI:
10.1021/ja00221a035
PDF
Association, photodimerization, and induced-fit types of host-guest complexation of anthracene-appended .gamma.-cyclodextrin derivatives
Akihiko Ueno, Fumio Moriwaki, Tetsuo Osa, Fumio Hamada, and Koichi Murai
pp 4323 - 4328; DOI:
10.1021/ja00221a036
PDF
Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions
E. Jon Jacobsen, Jeremy Levin, and Larry E. Overman
pp 4329 - 4336; DOI:
10.1021/ja00221a037
PDF
Structure and mechanism in the photo-retro-aldol type reactions of nitrobenzyl derivatives. Photochemical heterolytic cleavage of carbon-carbon bonds
Peter Wan and S. Muralidharan
pp 4336 - 4345; DOI:
10.1021/ja00221a038
PDF
Optically active arsenic macrocycles. Highly stereoselective syntheses of diastereomers and enantiomers of 14-membered macrocyclic dimers of (.+-.)-2,3-dihydro- and (.+-.)-2,3,4,5-tetrahydro-1-methyl-1,4-benzazarsepine
John W. L. Martin, Frederick S. Stephens, K. D. V. Weerasuria, and S. Bruce Wild
pp 4346 - 4356; DOI:
10.1021/ja00221a039
PDF
Total synthesis of linear polyprenoids. 3. Syntheses of ubiquinones via palladium-catalyzed oligomerization of monoterpene monomers
Doron Eren and Ehud Keinan
pp 4356 - 4362; DOI:
10.1021/ja00221a040
PDF
Bisection of an achiral molecule into homochiral halves. The first chemical analog of "la coupe du roi"
Mauro Cinquini, Franco Cozzi, Franco Sannicolo, and Angelo Sironi
pp 4363 - 4364; DOI:
10.1021/ja00221a041
PDF
Mycothiazole, a polyketide heterocycle from a marine sponge
Phillip Crews, Yao Kakou, and Emilio Quinoa
pp 4365 - 4368; DOI:
10.1021/ja00221a042
PDF
Total synthesis of zincophorin
Samuel J. Danishefsky, Harold G. Selnick, Robert E. Zelle, and Michael P. DeNinno
pp 4368 - 4378; DOI:
10.1021/ja00221a043
PDF
Crystal structures of inclusion complexes of .beta.-cyclodextrin with S-(+)- and (R)-(-)-fenoprofen
Jean A. Hamilton and Longyin Chen
pp 4379 - 4391; DOI:
10.1021/ja00221a044
PDF
UV-visible and carbon NMR studies of chloroquine binding to urohemin I chloride and uroporphyrin I in aqueous solutions
I. Constantinidis and James D. Satterlee
pp 4391 - 4395; DOI:
10.1021/ja00221a045
PDF
Monolayer properties of eight diastereomeric two-chain surfactants at the air/water interface: a resultant of intramolecular and intermolecular forces
Noel Harvey, Philip Rose, Ned A. Porter, Jeffrey B. Huff, and Edward M. Arnett
pp 4395 - 4399; DOI:
10.1021/ja00221a046
PDF
Evaluation of 1,3-diaxial steric hindrance to proton abstraction alpha to carbonyl groups
M. J. Gula, D. E. Vitale, J. M. Dostal, J. D. Trometer, and T. A. Spencer
pp 4400 - 4405; DOI:
10.1021/ja00221a047
PDF
Selective deuteriation as an aid in the assignment of proton NMR spectra of single-stranded oligodeoxynucleotides
Charles K. Brush, Michael P. Stone, and Thomas M. Harris
pp 4405 - 4408; DOI:
10.1021/ja00221a048
PDF
Enzymes in organic synthesis. 42. Investigation of the effects of the isozymal composition of pig liver esterase on its stereoselectivity in preparative-scale ester hydrolysis of asymmetric synthetic value
Lister K. P. Lam, Christine M. Brown, Bernard De Jeso, Laura Lym, Eric J. Toone, and J. Bryan Jones
pp 4409 - 4411; DOI:
10.1021/ja00221a049
PDF
Conformational properties of angiotensin II in aqueous solution and in a lipid environment: a Fourier transform infrared spectroscopic investigation
Witold K. Surewicz and Henry H. Mantsch
pp 4412 - 4414; DOI:
10.1021/ja00221a050
PDF
Generation of alkoxy radicals from N-alkoxypyridinethiones
Athelstan L. J. Beckwith and Benjamin P. Hay
pp 4415 - 4416; DOI:
10.1021/ja00221a051
PDF
The structure of liposidomycin B, an inhibitor of bacterial peptidoglycan synthesis
Makoto Ubukata, Kiyoshi Isono, Kenichi Kimura, Chad C. Nelson, and James A. McCloskey
pp 4416 - 4417; DOI:
10.1021/ja00221a052
PDF
Oxidative addition of halosilanes to zero-valent platinum complexes
Hiroshi Yamashita, Teruyuki Hayashi, Toshiaki Kobayashi, Masato Tanaka, and Midori Goto
pp 4417 - 4418; DOI:
10.1021/ja00221a053
PDF
Carbon acidity. 76. The remarkably low second pKa of 1-naphthylacetic acid. Lithium ion pair acidity in tetrahydrofuran
Scott Gronert and Andrew Streitwieser
pp 4418 - 4419; DOI:
10.1021/ja00221a054
PDF
Synthesis of (PCy3)2Cr(CO)3 and its reactions with hydrogen, nitrogen, and other ligands
Alberto A. Gonzalez, Shakti L. Mukerjee, Shou Jiau Chou, Zhang Kai, and Carl D. Hoff
pp 4419 - 4421; DOI:
10.1021/ja00221a055
PDF
.eta.2-(N,C)-pyridine and .mu.-.eta.2(1,2):.eta.2(4,5)-benzene complexes of (silox)3Ta (silox = t-Bu3SiO-)
David R. Neithamer, Laszlo Parkanyi, John F. Mitchell, and Peter T. Wolczanski
pp 4421 - 4423; DOI:
10.1021/ja00221a056
PDF
Time domain spectroscopic studies of mixed-valent perovskites
Russell S. Drago, Peter E. Doan, and Michael K. Kroeger
pp 4423 - 4424; DOI:
10.1021/ja00221a057
PDF
Preparation and isolation of polyenes containing up to 15 double bonds
Konrad Knoll, Steven A. Krouse, and Richard R. Schrock
pp 4424 - 4425; DOI:
10.1021/ja00221a058
PDF
Phosphorescence spectra of bacteriochlorophylls
Larry Takiff and Steven G. Boxer
pp 4425 - 4426; DOI:
10.1021/ja00221a059
PDF
Guanidyl groups: new metal-binding ligands in biomolecules. Reactions of chloro(2,2':6',2"-terpyridine)platinum(II) with arginine in two cytochromes c and with other guanidyl ligands
Eva Marie A. Ratilla and Nenad M. Kostic
pp 4427 - 4428; DOI:
10.1021/ja00221a060
PDF
Calculations of the geometric and electronic structure of trichloromethyltitanium: is there an agostic hydrogen interaction?
Rodney L. Williamson and Michael B. Hall
pp 4428 - 4429; DOI:
10.1021/ja00221a061
PDF
New inhibitors of cysteine proteinases. Peptidyl acyloxymethyl ketones and the quiescent nucleofuge strategy
Roger A. Smith, Leslie J. Copp, Peter J. Coles, Henry W. Pauls, Valerie J. Robinson, Robin W. Spencer, Stephen B. Heard, and Allen Krantz
pp 4429 - 4431; DOI:
10.1021/ja00221a062
PDF
Evidence for activation of the carbon-oxygen bond of methanol on the palladium(111) surface after low temperature adsorption
Robert J. Levis, Jiang Zhicheng, and Nicholas Winograd
pp 4431 - 4432; DOI:
10.1021/ja00221a063
PDF
Stereoselective alkylation of chiral .alpha.-nitro keto imine dianions. Observations on the role of amide bases
Scott E. Denmark and Jeffrey J. Ares
pp 4432 - 4434; DOI:
10.1021/ja00221a064
PDF
Doubly charged gas-phase heteronuclear cluster ions: synthesis and reaction of LaFe2+ with small hydrocarbons
Yongqing Huang and Ben S. Freiser
pp 4434 - 4435; DOI:
10.1021/ja00221a065
PDF
Studies on the biosynthesis of the meta-C7N unit in the antibiotics manumycin and asukamycin
John M. Beale, Richard E. Herrold, Heinz G. Floss, Ralf Thiericke, Axel Zeeck, Akira Nakagawa, and Satoshi Omura
pp 4435 - 4437; DOI:
10.1021/ja00221a066
PDF
Edge inversion barrier at a four-coordinate main group IV center
Anthony J. Arduengo, David A. Dixon, D. Christopher Roe, and Michael Kline
pp 4437 - 4438; DOI:
10.1021/ja00221a067
PDF
An allene adduct of ditungsten hexa-tert-butoxide: prediction of a stabilized .mu.-.eta.3-CH2CCH2 moiety
Roger H. Cayton, Malcolm H. Chisholm, and Mark J. Hampden-Smith
pp 4438 - 4440; DOI:
10.1021/ja00221a068
PDF
An unusual dinuclear cobalt dioxygen complex with a tetradentate thioether imidazole containing ligand. Structure of [Co2(bidhx)2(O2)(OH)](NO3)3
Elisabeth Bouwman and Willem L. Driessen
pp 4440 - 4441; DOI:
10.1021/ja00221a069
PDF
Benz[cd]indazole: infrared spectroscopic study
Akira Yabe, Koichi Honda, Hiroshi Nakanishi, Richard A. Hayes, and Orville L. Chapman
pp 4441 - 4443; DOI:
10.1021/ja00221a070
PDF
Dimethoxycarbene: direct observation of an archetypal nucleophilic carbene
Robert A. Moss, Marek Wlostowski, Shilan Shen, Karsten Krogh-Jespersen, and Alexander Matro
pp 4443 - 4444; DOI:
10.1021/ja00221a071
PDF
Organized monolayers of polycyclic aromatic quinones
P. W. Kenny, L. L. Miller, S. F. Rak, T. H. Jozefiak, W. C. Christopfel, J. H. Kim, and R. A. Uphaus
pp 4445 - 4446; DOI:
10.1021/ja00221a072
PDF
An ESR investigation of the structure and rearrangement of the hexamethyl(Dewar benzene) radical cation
Christopher J. Rhodes
pp 4446 - 4447; DOI:
10.1021/ja00221a073
PDF
Surface photochemistry: products retained on platinum(111) during photolysis of adsorbed methyl bromide
Y. Zhou, W. M. Feng, Michael A. Henderson, B. Roop, and J. M. White
pp 4447 - 4448; DOI:
10.1021/ja00221a074
PDF
Observation of a transition metal-enol complex and stereoselective keto-enol tautomerization in transition metal-acyl compounds
Joseph M. O'Connor and Roger Uhrhammer
pp 4448 - 4450; DOI:
10.1021/ja00221a075
PDF
Vanadium tetrahydroborates: preparation and characterization of V(.eta.2-BH4)3(PMe3)2 and the unusual unidentate BH4- complex V(.eta.1-BH4)2(dmpe)2
James A. Jensen and Gregory S. Girolami
pp 4450 - 4451; DOI:
10.1021/ja00221a076
PDF
Evidence for centrally directed bonds in trinuclear metal cluster compounds: the apparent free rotation of the Cr(CO)5 unit in (OC)5Cr[Os(CO)3(PMe3)]2
Harry B. Davis, Frederick W. B. Einstein, Victor J. Johnston, and Roland K. Pomeroy
pp 4451 - 4453; DOI:
10.1021/ja00221a077
PDF
The nontetrahedral structure and fluxional character of SiLi4. A violation of both van't Hoff and electrostatic bonding principles
Paul v. R. Schleyer and Alan E. Reed
pp 4453 - 4454; DOI:
10.1021/ja00221a078
PDF
Synthesis of naphthalene-bridged porphyrin dimers and their orientation-dependent exciton coupling
Atsuhiro Osuka and Kazuhiro Maruyama
pp 4454 - 4456; DOI:
10.1021/ja00221a079
PDF
A novel photorearrangement of 1-silyl 1,2-diones: generation of siloxyketenes
Bradford B. Wright
pp 4456 - 4457; DOI:
10.1021/ja00221a080
PDF
Dicarbollide complexes of samarium and ytterbium. Synthesis and structural characterization of the first closo-lanthanacarboranes
Mark J. Manning, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 4458 - 4459; DOI:
10.1021/ja00221a081
PDF
An extended x-ray absorption fine structure study on the morphology change of ruthenium catalyst by carbon monoxide adsorption
Takanori Mizushima, Kazuyuki Tohji, and Yasuo Udagawa
pp 4459 - 4460; DOI:
10.1021/ja00221a082
PDF
Chelation enhanced fluorescence in 9,10-bis[[(2-(dimethylamino)ethyl)methylamino]methyl]anthracene
Michael E. Huston, Karl W. Haider, and Anthony W. Czarnik
pp 4460 - 4462; DOI:
10.1021/ja00221a083
PDF
Electrocyclic reactions of 13-cis-retinal Schiff bases
William H. Okamura, Angel R. De Lera, and Wolfgang Reischl
pp 4462 - 4464; DOI:
10.1021/ja00221a084
PDF
Photophysics of metal complexes of spheroidal carbon shells
F. D. Weiss, J. L. Elkind, S. C. O'Brien, R. F. Curl, and R. E. Smalley
pp 4464 - 4465; DOI:
10.1021/ja00221a085
PDF
Probing metal cluster formation in NaY zeolite by xenon-129 NMR
B. F. Chmelka, R. Ryoo, S. B. Liu, L. C. De Menorval, C. J. Radke, E. E. Petersen, and A. Pines
pp 4465 - 4467; DOI:
10.1021/ja00221a086
PDF
Potential dependence of the conductivity of poly(3-methylthiophene) in liquid sulfur dioxide/electrolyte: a finite potential window of high conductivity
David Ofer and Mark S. Wrighton
pp 4467 - 4468; DOI:
10.1021/ja00221a087
PDF
Studies of phosphorylated sites in proteins using proton-phosphorus-31 two-dimensional NMR: further evidence for a phosphodiester link between a seryl and a threonyl residue in Azotobacter flavodoxin
David H. Live and Dale E. Edmondson
pp 4468 - 4470; DOI:
10.1021/ja00221a088
PDF
Cationic oligonucleotides
Robert L. Letsinger, Charles N. Singman, Gary Histand, and Manikrao Salunkhe
pp 4470 - 4471; DOI:
10.1021/ja00221a089
PDF
Tautomerization involving M-H-M and C-H-M interactions in capped trimetal clusters. Promotion of the C-H-M interaction in a mixed-metal cluster
Reynaldo D. Barreto and Thomas P. Fehlner
pp 4471 - 4472; DOI:
10.1021/ja00221a090
PDF
Allylic alcohols as synthons of allylic carbanions. Palladium-catalyzed carbonyl allylation by allylic alcohols with tin dichloride
Yoshiro Masuyama, Jun P. Takahara, and Yasuhiko Kurusu
pp 4473 - 4474; DOI:
10.1021/ja00221a091
PDF
Chair and boat transition states for the Cope rearrangement. A CASSCF study
Keiji Morokuma, Weston Thatcher Borden, and David A. Hrovat
pp 4474 - 4475; DOI:
10.1021/ja00221a092
PDF
Anti-Cram selective reduction of acyclic ketones via electron transfer initiated processes
Yoshinori Yamamoto, Koshin Matsuoka, and Hisao Nemoto
pp 4475 - 4476; DOI:
10.1021/ja00221a093
PDF
Computer Software Reviews

pp 4477 - 4477; DOI:
10.1021/ja00221a600
PDF
Book Reviews

pp 4478 - 4482; DOI:
10.1021/ja00221a601
PDF

Issue 14


1,2-Diphenylcycloalkenes: electronic and geometric structures in the gas phase, solution, and solid state
Georg Hohlneicher, Martin Mueller, Monika Demmer, Johann Lex, John H. Penn, Li Xian Gan, and Paul D. Loesel
pp 4483 - 4494; DOI:
10.1021/ja00222a001
PDF
Rate constants for reactions in viscous media: correlation between the viscosity of the solvent and the rate constant of the diffusion-controlled reactions
Andres F. Olea and J. K. Thomas
pp 4494 - 4502; DOI:
10.1021/ja00222a002
PDF
Metal-metal bonding in (C5H5V)2C8H8: a new interpretation of ab initio results
Pierre Mougenot, Jean Demuynck, Marc Benard, and Charles W. Bauschlicher
pp 4503 - 4505; DOI:
10.1021/ja00222a003
PDF
Bond-stretch isomerism in transition-metal complexes
Yves Jean, Agusti Lledos, Jeremy K. Burdett, and Roald Hoffmann
pp 4506 - 4516; DOI:
10.1021/ja00222a004
PDF
Comparison of direct and through-water binding of platinum ammines to the phosphate anion
Morris Krauss, Harold Basch, and K. J. Miller
pp 4517 - 4521; DOI:
10.1021/ja00222a005
PDF
Ground states and ionization energies of Si2H6, Si3H8, Si4H10, and Si5H12
J. V. Ortiz and J. W. Mintmire
pp 4522 - 4527; DOI:
10.1021/ja00222a006
PDF
Conformational studies by dynamic NMR. 35. Structure, conformation, and stereodynamics of hindered naphthylamines
D. Casarini, E. Foresti, Lodovico Lunazzi, and D. Macciantelli
pp 4527 - 4532; DOI:
10.1021/ja00222a007
PDF
Homoallylic chiral induction in the synthesis of 2,4-disubstituted tetrahydrofurans by iodoetherification. Synthetic scope and chiral induction mechanism
Marc Labelle, H. E. Morton, Y. Guindon, and J. P. Springer
pp 4533 - 4540; DOI:
10.1021/ja00222a008
PDF
Resonance Raman spectra of dioxygen adducts of cobalt porphyrins. Spectroscopic manifestation of vibrationally coupled dioxygen and energy matching of interactive modes
Leonard M. Proniewicz, Kazuo Nakamoto, and James R. Kincaid
pp 4541 - 4545; DOI:
10.1021/ja00222a009
PDF
Solid-state silicon-29 NMR and infrared studies of the reactions of mono- and polyfunctional silanes with zeolite Y surfaces
Thomas Bein, Robert F. Carver, Rodney D. Farlee, and Galen D. Stucky
pp 4546 - 4553; DOI:
10.1021/ja00222a010
PDF
Crystal structures of (MeC5H4)4U2(.mu.-NR)2. Unsymmetrical bridging, R = Ph, and symmetrical bridging, R = SiMe3, organoimide ligands in organoactinide compounds
John G. Brennan, Richard A. Andersen, and Allan Zalkin
pp 4554 - 4558; DOI:
10.1021/ja00222a011
PDF
Structure of the cobalt(II)-"capped" porphyrin, Co(C3-Cap).3CHCl3
John W. Sparapany, Maxwell J. Crossley, Jack E. Baldwin, and James A. Ibers
pp 4559 - 4564; DOI:
10.1021/ja00222a012
PDF
Valence trapping in mixed-valence manganese(II)-manganese(III) complexes of a macrocyclic binucleating ligand
Hsiu Rong Chang, Scott K. Larsen, Peter D. W. Boyd, Cortlandt G. Pierpont, and David N. Hendrickson
pp 4565 - 4576; DOI:
10.1021/ja00222a013
PDF
Acid-base properties of organic solvents
Alessandro Bagno and Gianfranco Scorrano
pp 4577 - 4582; DOI:
10.1021/ja00222a014
PDF
Borderline between E1cB and E2 mechanisms. Elimination of hydrogen chloride from fluorene derivatives
Alf Thibblin
pp 4582 - 4586; DOI:
10.1021/ja00222a015
PDF
Comparative study of E2 and SN2 reactions between ethyl halide and halide ion
Tsutomu Minato and Shinichi Yamabe
pp 4586 - 4593; DOI:
10.1021/ja00222a016
PDF
Chiroptical properties of chiral olefins
Aharon Gedanken, M. Duraisamy, Jiling Huang, J. Rachon, and Harry M. Walborsky
pp 4593 - 4599; DOI:
10.1021/ja00222a017
PDF
Chemistry of organosilicon compounds. 240. Pentacoordinate allylsilicates: characterization and highly stereoselective reaction with aldehydes
Mitsuo Kira, Kazuhiko Sato, and Hideki Sakurai
pp 4599 - 4602; DOI:
10.1021/ja00222a018
PDF
Modeling chemical reactivity. 9. The role of the metal in controlling the stereochemistry of nucleophilic additions of organometallic reagents
S. D. Kahn, K. D. Dobbs, and W. J. Hehre
pp 4602 - 4606; DOI:
10.1021/ja00222a019
PDF
Intramolecular hypervalent tin-oxygen interaction. The origin for fixation of six-membered carbocycles to the 1,3-diaxial conformer and for stereoselective osmylations
Masahito Ochiai, Shigeru Iwaki, Tatsuzo Ukita, Yoshiki Matsuura, Motoo Shiro, and Yoshimitsu Nagao
pp 4606 - 4610; DOI:
10.1021/ja00222a020
PDF
Asymmetric tandem addition to chiral 1- and 2-substituted naphthalenes. Application to the synthesis of (+)-phyltetralin
Albert I. Meyers, Gregory P. Roth, Denton Hoyer, Bruce A. Barner, and Dominique Laucher
pp 4611 - 4624; DOI:
10.1021/ja00222a021
PDF
Face selectivity in Diels-Alder reactions of chiral dienes containing allylic substituents
Matthew J. Fisher, Warren J. Hehre, Scott D. Kahn, and Larry E. Overman
pp 4625 - 4633; DOI:
10.1021/ja00222a022
PDF
The charge alternation concept. Application to cyclic conjugated doubly charged systems
Yoram Cohen, Joseph Klein, and Mordecai Rabinovitz
pp 4634 - 4640; DOI:
10.1021/ja00222a023
PDF
Electrophilic additions to 3-C-[(methoxycarbonyl)methyl]-3-deoxy-D-ribofuranose enolates: a case of unusually efficient nonchelate-enforced chirality transfer
Johann Mulzer, Ulrich Steffen, Ludwig Zorn, Christian Schneider, Elmar Weinhold, Winfried Muench, Rainer Rudert, Peter Luger, and Hans Hartl
pp 4640 - 4646; DOI:
10.1021/ja00222a024
PDF
Photolyses of organocobaloximes having aralkyl and (alkylthio)carbonyl groups on the .beta.-position. A radical reaction involving the thioester group
Masaru Tada, Tatsuya Nakamura, and Mitsuhiro Matsumoto
pp 4647 - 4652; DOI:
10.1021/ja00222a025
PDF
Highly diastereofacial selective chelation of a phosphite-containing .alpha.,.beta.-unsaturated ketone system to the Fe(CO)2 group
Wei Yuan Zhang, Dennis J. Jakiela, Andre Maul, Christopher Knors, Joseph W. Lauher, Paul Helquist, and Dieter Enders
pp 4652 - 4660; DOI:
10.1021/ja00222a026
PDF
Chemistry of amphotericin B. Degradation studies and preparation of amphoteronolide B
K. C. Nicolaou, T. K. Chakraborty, Y. Ogawa, R. A. Daines, N. S. Simpkins, and G. T. Furst
pp 4660 - 4672; DOI:
10.1021/ja00222a027
PDF
Total synthesis of amphoteronolide B and amphotericin B. 1. Strategy and stereocontrolled construction of key building blocks
Kyriacos C. Nicolaou, R. A. Daines, J. Uenishi, W. S. Li, D. P. Papahatjis, and T. K. Chakraborty
pp 4672 - 4685; DOI:
10.1021/ja00222a028
PDF
Total synthesis of amphoteronolide B and amphotericin B. 2. Total synthesis of amphoteronolide B
Kyriacos C. Nicolaou, R. A. Daines, T. K. Chakraborty, and Y. Ogawa
pp 4685 - 4696; DOI:
10.1021/ja00222a029
PDF
Total synthesis of amphotericin B. 3. The final stages
Kyriacos C. Nicolaou, R. A. Daines, Y. Ogawa, and T. K. Chakraborty
pp 4696 - 4705; DOI:
10.1021/ja00222a030
PDF
Organic ligand-receptor interactions between cucurbituril and alkylammonium ions
William L. Mock and Neng Yang Shih
pp 4706 - 4710; DOI:
10.1021/ja00222a031
PDF
Ab initio calculations of the olefin strain energies of some pyramidalized alkenes
David A. Hrovat and Weston Thatcher Borden
pp 4710 - 4718; DOI:
10.1021/ja00222a032
PDF
Prostaglandin synthesis. 16. The three-component coupling synthesis of prostaglandins
M. Suzuki, A. Yanagisawa, and Ryori Noyori
pp 4718 - 4726; DOI:
10.1021/ja00222a033
PDF
Triply convergent synthesis of (-)-prostaglandin E2 methyl ester
Carl R. Johnson and Thomas D. Penning
pp 4726 - 4735; DOI:
10.1021/ja00222a034
PDF
Enantioselective synthesis through microbial oxidation of arenes. 1. Efficient preparation of terpene and prostanoid synthons
Tomas Hudlicky, Hector Luna, Graciela Barbieri, and Lawrence D. Kwart
pp 4735 - 4741; DOI:
10.1021/ja00222a035
PDF
Enantioselective total synthesis of (+)-12,13-epoxytrichothec-9-ene and its antipode
Duy H. Hua, S. Venkataraman, Roch Yu King Chan, and Joseph V. Paukstelis
pp 4741 - 4748; DOI:
10.1021/ja00222a036
PDF
Gas-phase determination of the geometric requirements of the silicon .beta.-effect. Photoelectron and Penning ionization electron spectroscopic study of silylthiiranes and -oxiranes. Synthesis and chemistry of trans-2,3-bis(trimethylsilyl)thiirane
Eric Block, Andrew J. Yencha, Mohammad Aslam, Venkatachalam Eswarakrishnan, Jianzhi Luo, and Akinobu Sano
pp 4748 - 4753; DOI:
10.1021/ja00222a037
PDF
One-pot, four-component annulations: flexible and simple syntheses of unsaturated macrolides and of substituted aromatics and heteroaromatics
Gary H. Posner, Kevin S. Webb, Edward Asirvatham, Sang Sup Jew, and Alessandro Degl'Innocenti
pp 4754 - 4762; DOI:
10.1021/ja00222a038
PDF
Totally stereoselective additions to 2,6-disubstituted 1,3-dioxin-4-ones (chiral acetoacetic acid derivatives). Synthetic and mechanistic aspects of remote stereoselectivity
Dieter Seebach, Juerg Zimmermann, Urs Gysel, Regula Ziegler, and Tae Kyu Ha
pp 4763 - 4772; DOI:
10.1021/ja00222a039
PDF
Facilitation of electrochemical oxidation of dialkyl sulfides appended with neighboring carboxylate and alcohol groups
Richard S. Glass, Amorn Petsom, Massoud Hojjatie, Brian R. Coleman, John R. Duchek, Jacob Klug, and George S. Wilson
pp 4772 - 4778; DOI:
10.1021/ja00222a040
PDF
Chiral and achiral formamidines in synthesis. The first asymmetric route to (-)-yohimbine and an efficient total synthesis of (.+-.)-yohimbine
Albert I. Meyers, Donald B. Miller, and Franklin H. White
pp 4778 - 4787; DOI:
10.1021/ja00222a041
PDF
Vinyllithium cyclizations with unactivated alkenes as internal electrophiles: stereoselective formation of substituted methylenecyclopentanes
A. Richard Chamberlin, Steven H. Bloom, Laura A. Cervini, and Christopher H. Fotsch
pp 4788 - 4796; DOI:
10.1021/ja00222a042
PDF
Total synthesis of (.+-.)-N2-(phenylsulfonyl)-CPI, (.+-.)-CC-1065, (+)-CC-1065, ent-(-)-CC-1065, and the precise, functional agents (.+-.)-CPI-CDPI2, (+)-CPI-CDPI2, and (-)-CPI-CDPI2 [(.+-.)-(3bR*,4aS*)-, (+)-(3bR,4aS)-, and (-)-(3bS,4aR)-deoxy-CC-1065]
Dale L. Boger and Robert S. Coleman
pp 4796 - 4807; DOI:
10.1021/ja00222a043
PDF
Acromelic acids A and B. Potent neuroexcitatory amino acids isolated from Clitocybe acromelalga
Katsuhiro Konno, Kimiko Hashimoto, Yasufumi Ohfune, Haruhisa Shirahama, and Takeshi Matsumoto
pp 4807 - 4815; DOI:
10.1021/ja00222a044
PDF
A new route to the prostaglandin skeleton via radical alkylation. Synthesis of 6-oxoprostaglandin E1
Takeshi Toru, Yoshio Yamada, Toshio Ueno, Eturo Maekawa, and Yoshio Ueno
pp 4815 - 4817; DOI:
10.1021/ja00222a045
PDF
Enzymic cyclization of hydroxylated surrogate squalenoids with bakers' yeast
Julio C. Medina and Keith S. Kyler
pp 4818 - 4821; DOI:
10.1021/ja00222a046
PDF
A sulfur-mediated total synthesis of Zygosporin E
E. Vedejs, J. D. Rodgers, and S. J. Wittenberger
pp 4822 - 4823; DOI:
10.1021/ja00222a047
PDF
Highly efficient synthesis of a carbacyclin analog. Stereospecific synthesis of aryl-substituted exocyclic olefins
Mikiko Sodeoka, Shoji Satoh, and Masakatsu Shibasaki
pp 4823 - 4824; DOI:
10.1021/ja00222a048
PDF
Diastereoselective photodeconjugation of .alpha.,.beta.-unsaturated esters
Reza Mortezaei, Djamsah Awandi, Francoise Henin, Jacques Muzart, and Jean Pierre Pete
pp 4824 - 4826; DOI:
10.1021/ja00222a049
PDF
High diastereofacial selectivity in nucleophilic additions to chiral acylsilanes
Masahisa Nakada, Yasuharu Urano, Susumu Kobayashi, and Masaji Ohno
pp 4826 - 4827; DOI:
10.1021/ja00222a050
PDF
Pentacyclo[5.1.0.02,4.03,5.06,8]octane (octabisvalene)
Christoph Ruecker and Bjoern Trupp
pp 4828 - 4829; DOI:
10.1021/ja00222a051
PDF
Chlorine dioxide oxidation of amines: synthetic utility and a biomimetic synthesis of elaeocarpidine
Chien Kuang Chen, Alfred G. Hortmann, and Mohammad R. Marzabadi
pp 4829 - 4831; DOI:
10.1021/ja00222a052
PDF
A new method for the formation of nitrogen-containing ring systems via the intramolecular photocycloaddition of vinylogous amides. A synthesis of mesembrine
Jeffrey D. Winkler, Cheryl L. Muller, and Robert D. Scott
pp 4831 - 4832; DOI:
10.1021/ja00222a053
PDF
On the tautomerism of dihydropyrimidines: the influence of the 2- and 5-substituents on the observation of tautomers
Hidetsura Cho, Takashi Iwashita, Masaru Ueda, Akira Mizuno, Kosei Mizukawa, and Mikiko Hamaguchi
pp 4832 - 4834; DOI:
10.1021/ja00222a054
PDF
Effects of boron trifluoride etherate on higher order organocuprate reactions: substrate activation or cuprate modification?
Bruce H. Lipshutz, Edmund L. Ellsworth, and Teruna J. Siahaan
pp 4834 - 4835; DOI:
10.1021/ja00222a055
PDF
Antibody catalysis of bimolecular amide formation
K. D. Janda, R. A. Lerner, and Alfonso Tramontano
pp 4835 - 4837; DOI:
10.1021/ja00222a056
PDF
Ovothiols as biological antioxidants. The thiol groups of ovothiol and glutathione are chemically distinct
Tod P. Holler and Paul B. Hopkins
pp 4837 - 4838; DOI:
10.1021/ja00222a057
PDF
A versatile route to diastereomeric tungstenocene complexes containing chiral metal centers
John P. McNally, David Glueck, and N. John Cooper
pp 4838 - 4840; DOI:
10.1021/ja00222a058
PDF
Macrolide biosynthesis. 5. Intact incorporation of a chain-elongation intermediate into nargenicin
David E. Cane and Walter R. Ott
pp 4840 - 4841; DOI:
10.1021/ja00222a059
PDF
An antibody-catalyzed Claisen rearrangement
D. Y. Jackson, J. W. Jacobs, R. Sugasawara, S. H. Reich, P. A. Bartlett, and Peter G. Schultz
pp 4841 - 4842; DOI:
10.1021/ja00222a060
PDF
From twisted to folded ethylenes
Agha Zul Qarnain Khan and Jan Sandstroem
pp 4843 - 4844; DOI:
10.1021/ja00222a061
PDF
X-ray structures of threaded diethylmagnesium(18-crown-6) and diethylzinc(18-crown-6)
Anthony D. Pajerski, Gretchen L. BergStresser, Masood Parvez, and Herman G. Richey
pp 4844 - 4845; DOI:
10.1021/ja00222a062
PDF
X-ray structure of (1,3-xylyl-18-crown-5)diphenylmagnesium: an organometallic rotaxane
Peter R. Markies, Tateo Nomoto, Otto S. Akkerman, Friedrich Bickelhaupt, Wilberth J. J. Smeets, and Anthony L. Spek
pp 4845 - 4846; DOI:
10.1021/ja00222a063
PDF
Bis(2,3,4,6,7-.eta.5-bicyclo[3.2.2]nona-2,6,8-trien-4-yl)iron, a ferrocene analog with separated allyl and olefin systems
Janet Bluemel, Frank H. Koehler, and Gerhard Mueller
pp 4846 - 4848; DOI:
10.1021/ja00222a064
PDF
Modification of photochemical reactivity by zeolites: Norrish type I and type II reactions of benzoin derivatives
D. R. Corbin, D. F. Eaton, and V. Ramamurthy
pp 4848 - 4849; DOI:
10.1021/ja00222a065
PDF
(.mu.-NO)2[Co(.eta.5-C5H5)]2 is not paramagnetic
David J. Berg and Richard A. Andersen
pp 4849 - 4850; DOI:
10.1021/ja00222a066
PDF
Mycalamide A, an antiviral compound from a New Zealand sponge of the genus Mycale
Nigel B. Perry, John W. Blunt, Murray H. G. Munro, and Lewis K. Pannell
pp 4850 - 4851; DOI:
10.1021/ja00222a067
PDF
Isolation and structure elucidation of onnamide A, a new bioactive metabolite of a marine sponge, Theonella sp
Shinichi Sakemi, Toshio Ichiba, Shigeo Kohmoto, Gabriel Saucy, and Tatsuo Higa
pp 4851 - 4853; DOI:
10.1021/ja00222a068
PDF
Synthesis and physical properties of a dinuclear tantalum/cobalt radical with spin localized at one metal center
Karen I. Goldberg and Robert G. Bergman
pp 4853 - 4855; DOI:
10.1021/ja00222a069
PDF
A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2}
Adam K. List, Gregory L. Hillhouse, and Arnold L. Rheingold
pp 4855 - 4856; DOI:
10.1021/ja00222a070
PDF
Dercitine, a new biologically active acridine alkaloid from a deep water marine sponge, Dercitus sp
Geewananda P. Gunawardana, Shigeo Kohmoto, Sarath P. Gunasekera, Oliver J. McConnell, and Frank E. Koehn
pp 4856 - 4858; DOI:
10.1021/ja00222a071
PDF
Synthetic studies on arene-olefin cycloadditions. 10. A concise, stereocontrolled total synthesis of (.+-.)-laurenene
Paul A. Wender, Thomas W. Von Geldern, and Barry H. Levine
pp 4858 - 4860; DOI:
10.1021/ja00222a072
PDF
An ethylene complex of vanadium: synthesis, structure, and reactivity of cyclopentadienylbis(trimethylphosphine)(ethylene)vanadium(I)
Bart Hessen, Auke Meetsma, and Jan H. Teuben
pp 4860 - 4861; DOI:
10.1021/ja00222a073
PDF
Stereochemistry of the biosynthesis of sn-2,3-O-diphytanyl glycerol, membrane lipid of archaebacteria Halobacterium halobium
Katsumi Kakinuma, Masahiro Yamagishi, Yoshinori Fujimoto, Tairo Oshima, and Nobuo Ikekawa
pp 4861 - 4863; DOI:
10.1021/ja00222a074
PDF
[S4Cd17(SPh)28]2-, the first member of a third series of tetrahedral [SWMX(SR)y]z- clusters
Garry S. H. Lee, Don C. Craig, Ida Ma, Marcia L. Scudder, Trevor D. Bailey, and Ian G. Dance
pp 4863 - 4864; DOI:
10.1021/ja00222a075
PDF
A novel mechanism of glycoside anomerization
Leise A. Berven, David H. Dolphin, and Stephen G. Withers
pp 4864 - 4866; DOI:
10.1021/ja00222a076
PDF
Cyclic conjugated enediynes related to calicheamicins and esperamicins: calculations, synthesis, and properties
K. C. Nicolaou, Y. Ogawa, G. Zuccarello, E. J. Schweiger, and T. Kumazawa
pp 4866 - 4868; DOI:
10.1021/ja00222a077
PDF
Novel chemistry of dithiatopazine
K. C. Nicolaou, C. K. Hwang, S. DeFrees, and N. A. Stylianides
pp 4868 - 4869; DOI:
10.1021/ja00222a078
PDF
Carbon dioxide activation: thermodynamics of carbon dioxide binding and the involvement of two cobalt centers in the reduction of carbon dioxide by a cobalt(I) macrocycle
Etsuko Fujita, David J. Szalda, Carol Creutz, and Norman Sutin
pp 4870 - 4871; DOI:
10.1021/ja00222a079
PDF
A novel molybdenum(0) dinitrogen complex containing crown thio ether as the sole auxiliary ligand: trans-Mo(N2)2Me8[16]aneS4 (Me8[16]aneS4 = 3,3,7,7,11,11,15,15-octamethyl-1,5,9,13-tetrathiacyclohexadecane)
Toshikatsu Yoshida, Tomohiro Adachi, Manabu Kaminaka, Tatsuo Ueda, and Taiichi Higuchi
pp 4872 - 4873; DOI:
10.1021/ja00222a080
PDF
The origin of proximity effects on reactivity: a modified MM2 model for the rates of acid-catalyzed lactonizations of hydroxy acids [Erratum to document cited in CA107(1):6606b]
Andrea E. Dorigo and K. N. Houk
pp 4874 - 4874; DOI:
10.1021/ja00222a081
PDF
Book Reviews

pp 4874 - 4876; DOI:
10.1021/ja00222a600
PDF

Issue 15


Fluoride affinities of perfluorobenzenes C6F5X. Meisenheimer complexes in the gas phase and solution
Glen W. Dillow and Paul Kebarle
pp 4877 - 4882; DOI:
10.1021/ja00223a001
PDF
Growth of silver halides from the molecule to the crystal. A pulse radiolysis study
K. H. Schmidt, R. Patel, and Dan Meisel
pp 4882 - 4884; DOI:
10.1021/ja00223a002
PDF
Adsorbed thiophenol and related compounds studied at platinum(111) electrodes by EELS, Auger spectroscopy, and cyclic voltammetry
Donald A. Stern, Edna Wellner, Ghaleb N. Salaita, Laarni Laguren-Davidson, Frank Lu, Nikola Batina, Douglas G. Frank, Donald C. Zapien, Nicholas Walton, and Arthur T. Hubbard
pp 4885 - 4893; DOI:
10.1021/ja00223a003
PDF
Spectroscopic investigations of the electron self-exchange reaction of the perchlorate salt of [1,7-bis(5-methylimidazol-4-yl)-2,6-dithiaheptane]copper(n+) (n = 1, 2)
C. M. Groeneveld, J. Van Rijn, J. Reedijk, and G. W. Canters
pp 4893 - 4900; DOI:
10.1021/ja00223a004
PDF
Torsional angles in vinylarenes determined by high-field NMR spectroscopy
Kevin L. Facchine, Stuart W. Staley, Peter C. M. Van Zijl, Prasanna K. Mishra, and Aksel A. Bothner-By
pp 4900 - 4905; DOI:
10.1021/ja00223a005
PDF
Electrocatalysis at a novel electrode coating of nonstoichiometric tungsten(VI,V) oxide aggregates
Pawel J. Kulesza and Larry R. Faulkner
pp 4905 - 4913; DOI:
10.1021/ja00223a006
PDF
Evidence for adduct formation at the semiconductor-gas interface. Photoluminescent properties of cadmium selenide in the presence of amines
Gerald J. Meyer, George C. Lisensky, and Arthur B. Ellis
pp 4914 - 4918; DOI:
10.1021/ja00223a007
PDF
Topological aspects of conformational coupling in 8,8-dimethyl-1,4-diheterospiro[4.5]decanes: a molecular mechanics study
P. Iratcabal and D. Liotard
pp 4919 - 4926; DOI:
10.1021/ja00223a008
PDF
MBPT and coupled-cluster investigation of isomerization reactions: HCN .ltbbrac. = .rtbbrac. HNC, BH3CN- .ltbbrac. = .rtbbrac. BH3NC-, and HCNBH3 .ltbbrac. = .rtbbrac. HNCBH3
Miroslav Urban and Rodney J. Bartlett
pp 4926 - 4931; DOI:
10.1021/ja00223a009
PDF
Structures and stabilities of singly charged three-electron hemibonded systems and their hydrogen-bonded isomers
Peter M. W. Gill and Leo Radom
pp 4931 - 4941; DOI:
10.1021/ja00223a010
PDF
Theoretical study of bimolecular nucleophilic substitution at four, five-, and six-coordinate metal carbonyl radicals
Michael J. Therien and William C. Trogler
pp 4942 - 4953; DOI:
10.1021/ja00223a011
PDF
Empirical potential energy surfaces relating structure and activation energy. 1. Metallacyclopentene ring inversion in (s-cis-.eta.4-butadiene)metallocene complexes and related compounds
Hans Beat Buergi and Katharina C. Dubler-Steudle
pp 4953 - 4957; DOI:
10.1021/ja00223a012
PDF
Reactions of iron(II) nitrilotriacetate and iron(II) ethylenediamine-N,N'-diacetate complexes with hydrogen peroxide
J. D. Rush and W. H. Koppenol
pp 4957 - 4963; DOI:
10.1021/ja00223a013
PDF
Preparation and reactions of tantalum alkylidene complexes containing bulky phenoxide or thiolate ligands. Controlling ring-opening metathesis polymerization activity and mechanism through choice of anionic ligand
Kevin C. Wallace, Andy H. Liu, John C. Dewan, and Richard R. Schrock
pp 4964 - 4977; DOI:
10.1021/ja00223a014
PDF
Titanium(III) tetrahydroborates. Preparation and crystal structure of Ti(BH4)3(PMe3)2 containing an unusual Ti.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.B agostic interaction
James A. Jensen, Scott R. Wilson, and Gregory S. Girolami
pp 4977 - 4982; DOI:
10.1021/ja00223a015
PDF
Synthetic, structural, and reactivity studies of the reduction and carbon monoxide derivatization of azobenzene mediated by divalent lanthanide complexes
William J. Evans, Donald K. Drummond, L. R. Chamberlain, Robert J. Doedens, Simon G. Bott, Hongming Zhang, and Jerry L. Atwood
pp 4983 - 4994; DOI:
10.1021/ja00223a016
PDF
Cocomplexation of neutral guests and electrophilic metal cations in synthetic macrocyclic hosts
Catherina J. Van Staveren, Johan Van Eerden, Frank C. J. M. Van Veggel, Sybolt Harkema, and David N. Reinhoudt
pp 4994 - 5008; DOI:
10.1021/ja00223a017
PDF
Synthesis and catalysis of novel mono- and bis(diene) complexes of niobium and x-ray structures of binuclear [Nb(.mu.-Cl)(C5H5)(s-cis-butadiene)]2 and mononuclear Nb(C5H5)(s-cis-2,3-dimethylbutadiene)2
Takuji Okamoto, Hajime Yasuda, Akira Nakamura, Yasushi Kai, Nobuko Kanehisa, and Nobutami Kasai
pp 5008 - 5017; DOI:
10.1021/ja00223a018
PDF
Bis(platinum) complexes containing two platinum cis-diammine units. Synthesis and initial DNA-binding studies
Nicholas P. Farrell, Sergio G. De Almeida, and Kirsten A. Skov
pp 5018 - 5019; DOI:
10.1021/ja00223a019
PDF
Copper-mediated hydroxylation of an arene: kinetics and mechanism of the reaction of a dicopper(II) m-xylyl-containing complex with H2O2 to yield a phenoxodicopper(II) complex
Richard W. Cruse, Susan Kaderli, Charles J. Meyer, Andreas D. Zuberbuehler, and Kenneth D. Karlin
pp 5020 - 5024; DOI:
10.1021/ja00223a020
PDF
Isomerization in metal-metal bonded M2L10 systems involving cis and trans sets of bis(diphenylphosphino)methane ligands
Ann R. Cutler, Daniel R. Derringer, Phillip E. Fanwick, and Richard A. Walton
pp 5024 - 5034; DOI:
10.1021/ja00223a021
PDF
The origin of the directing effect in hydrogen addition to square-planar d8 complexes
Mark J. Burk, Martin P. McGrath, Ralph Wheeler, and Robert H. Crabtree
pp 5034 - 5039; DOI:
10.1021/ja00223a022
PDF
Decamethylrhenocene, (.eta.5-C5Me5)2Re
Judith A. Bandy, F. Geoffrey N. Cloke, Glyn Copper, Jeremy P. Day, Reuben B. Girling, Robin G. Graham, Jennifer C. Green, Roger Grinter, and Robin N. Perutz
pp 5039 - 5050; DOI:
10.1021/ja00223a023
PDF
Inter- and intramolecular excited-state interactions of surfactant-active rhenium(I) photosensitizers
G. A. Reitz, James N. Demas, B. A. DeGraff, and Eileen M. Stephens
pp 5051 - 5059; DOI:
10.1021/ja00223a024
PDF
Reactions of polypyridylchromium(II) ions with oxygen: determination of the self-exchange rate constant of oxygen O2/O2-
Khurram Zahir, James H. Espenson, and Andreja Bakac
pp 5059 - 5063; DOI:
10.1021/ja00223a025
PDF
A samarium(II) iodide promoted tandem radical cyclization. The total synthesis of (.+-.)-hypnophilin and the formal synthesis of (.+-.)-coriolin
Thomas L. Fevig, Richard L. Elliott, and Dennis P. Curran
pp 5064 - 5067; DOI:
10.1021/ja00223a026
PDF
Kinetics and mechanism of solvolysis of Precocene I 3,4-oxide: change in rate-determining step and trapping of an intermediate in an epoxide solvolysis reaction
Jane M. Sayer, S. J. Grossman, K. S. Adusei-Poku, and D. M. Jerina
pp 5068 - 5074; DOI:
10.1021/ja00223a027
PDF
Elimination reactions of .beta.-cyano thioethers: evidence for a carbanion intermediate and a change in rate-limiting step
James C. Fishbein and William P. Jencks
pp 5075 - 5086; DOI:
10.1021/ja00223a028
PDF
Elimination reactions of .beta.-cyano thioethers: internal return and the lifetime of the carbanion intermediate
James C. Fishbein and William P. Jencks
pp 5087 - 5095; DOI:
10.1021/ja00223a029
PDF
The mechanism of rearrangement of 6-halopenicilloates to 2,3-dihydro-1,4-thiazines
Rex F. Pratt and David J. Cahn
pp 5096 - 5104; DOI:
10.1021/ja00223a030
PDF
Charge description of base-catalyzed alcoholysis of aryl phosphodiesters: a ribonuclease model
Andrew M. Davis, Adrian D. Hall, and Andrew Williams
pp 5105 - 5108; DOI:
10.1021/ja00223a031
PDF
Unusual stability of an alkyllithium dimer. Preparation, properties, and decomposition mechanism of tert-butyllithium dietherate dimer
Tim F. Bates, Matthew T. Clarke, and Ruthanne D. Thomas
pp 5109 - 5112; DOI:
10.1021/ja00223a032
PDF
Homoaromatic delocalization in the transition state for norcaradiene formation
Achim Bertsch, Wolfram Grimme, Gerd Reinhardt, Hermann Rose, and Philip M. Warner
pp 5112 - 5117; DOI:
10.1021/ja00223a033
PDF
Structure-reactivity effects in the breakdown of hemiacetals of .alpha.-bromoacetophenone. Change in rate-limiting step for base catalysis
Poul E. Soerensen, K. J. Pedersen, P. R. Pedersen, V. M. Kanagasabapathy, and Robert A. McClelland
pp 5118 - 5123; DOI:
10.1021/ja00223a034
PDF
Kinetics of amphiphilic ketone epimerizations in cleavable surfactant hosts
David A. Jaeger, Phillip K. Chou, Durgadas Bolikal, Dong Ok, Kwang Yoo Kim, Jeffrey B. Huff, Eun Yi, and Ned A. Porter
pp 5123 - 5129; DOI:
10.1021/ja00223a035
PDF
Electron-transfer-induced reorganization of bicyclo[6.1.0]nonatriene and derivatives
Heinz D. Roth, Marcia L. Schilling, Christopher J. Abelt, Tsutomu Miyashi, Yasutake Takahashi, Akinori Konno, and Toshio Mukai
pp 5130 - 5136; DOI:
10.1021/ja00223a036
PDF
Micelle-mimetic ionene polyelectrolytes
Valdir Soldi, Norma de Magalhaes Erismann, and Frank H. Quina
pp 5137 - 5143; DOI:
10.1021/ja00223a037
PDF
Simple enols. 5. (Z)- and (E)-1-Hydroxy-1,3-butadiene
Brian Capon and Bozhang Guo
pp 5144 - 5147; DOI:
10.1021/ja00223a038
PDF
Shape-specific weak interactions related to a phenyl group: determination of their enthalpies by gas-liquid partition chromatography
Masato M. Ito, Junichi Kato, Shiro Takagi, Emi Nakashiro, Tsunenobu Sato, Yoshinori Yamada, Hiroko Saito, Takao Namiki, Ichiro Takamura, and et al.
pp 5147 - 5152; DOI:
10.1021/ja00223a039
PDF
Crystal structures of two simple N-substituted dihydronicotinamides: possible implications for stereoelectronic arguments in enzymology
Arthur Glasfeld, Peter Zbinden, Max Dobler, Steven A. Benner, and Jack D. Dunitz
pp 5152 - 5157; DOI:
10.1021/ja00223a040
PDF
Crystal structure of cyclo(Gly1-L-Pro2-D-Phe3-L-Ala4-L-Pro5): a cyclic pentapeptide with a Gly-L-Pro .delta. turn
A. N. Stroup, A. L. Rockwell, A. L. Rheingold, and Lila M. Gierasch
pp 5157 - 5161; DOI:
10.1021/ja00223a041
PDF
A search for peptide ligase: cosolvent-mediated conversion of proteases to esterases for irreversible synthesis of peptides
Carlos F. Barbas, Jose R. Matos, J. Blair West, and Chi Huey Wong
pp 5162 - 5166; DOI:
10.1021/ja00223a042
PDF
A new class of phospholipase A2 substrates: kinetics of the phospholipase A2 catalyzed hydrolysis of 3-(acyloxy)-4-nitrobenzoic acids
Wonhwa Cho, Michael A. Markowitz, and Ferenc J. Kezdy
pp 5166 - 5171; DOI:
10.1021/ja00223a043
PDF
Phospholipase A2 inhibition and modification by manoalogue
Laure J. Reynolds, Bradley P. Morgan, Gary A. Hite, Edward D. Mihelich, and Edward A. Dennis
pp 5172 - 5177; DOI:
10.1021/ja00223a044
PDF
G(syn).cntdot.A(anti) mismatch formation in DNA dodecamers at acidic pH: pH-dependent conformational transition of G.cntdot.A mispairs detected by proton NMR
Xiaolian Gao and Dinshaw J. Patel
pp 5178 - 5182; DOI:
10.1021/ja00223a045
PDF
Molecular mechanics simulations of thermodynamic functions and infrared spectra of alkanes
Yoshihisa Miwa and Katsunosuke Machida
pp 5183 - 5189; DOI:
10.1021/ja00223a046
PDF
Reactivities of ester radical anions
John Masnovi and Jeanne Maticic
pp 5189 - 5191; DOI:
10.1021/ja00223a047
PDF
Configuration-dependent photoisomerization of (E)-cinnamamides
Frederick D. Lewis, Jeffrey E. Elbert, Alana L. Upthagrove, and Paul D. Hale
pp 5191 - 5192; DOI:
10.1021/ja00223a048
PDF
A new class of chelating agents
L. Marshall, K. Parris, Julius Rebek, S. V. Luis, and M. I. Burguete
pp 5192 - 5193; DOI:
10.1021/ja00223a049
PDF
Oxygenation of hexafluorobenzene by superoxide ion
Hiroshi Sugimoto, Shigenobu Matsumoto, Donald T. Sawyer, Jeffrey R. Kanofsky, A. Kasem Chowdhury, and Charles L. Wilkins
pp 5193 - 5195; DOI:
10.1021/ja00223a050
PDF
A simple, divergent, asymmetric synthesis of all members of the 2,3,6-trideoxy-3-aminohexose family
Lixin Dai, Boliang Lou, and Yinzhi Zhang
pp 5195 - 5196; DOI:
10.1021/ja00223a051
PDF
Stereocontrolled total synthesis of (.+-.)-quinocarcin
Toru Fukuyama and Joseph J. Nunes
pp 5196 - 5198; DOI:
10.1021/ja00223a052
PDF
Synthetic studies in the brefeldin series: asymmetric enamine-enal cycloaddition and intramolecular Nozaki reactions
Stuart L. Schreiber and Harold V. Meyers
pp 5198 - 5200; DOI:
10.1021/ja00223a053
PDF
Determination of the structural and the electronic properties of surfaces using scanning tunneling microscopy coupled with chemical modifications
Xian Liang Wu and Charles M. Lieber
pp 5200 - 5201; DOI:
10.1021/ja00223a054
PDF
A novel chiral route to substituted tetrahydrofurans. Total synthesis of (+)-verrucosidin and formal synthesis of (-)-citreoviridin
Susumi Hatakeyama, Kuniya Sakurai, Hirotoshi Numata, Noriko Ochi, and Seiichi Takano
pp 5201 - 5203; DOI:
10.1021/ja00223a055
PDF
The water content of micelles: infrared spectroscopic studies
H. L. Casal
pp 5203 - 5205; DOI:
10.1021/ja00223a056
PDF
The influence of a carboxylate group on the rate of O-acylation of 2-hydroxymethylimidazoles by a strained amide
K. I. Skorey, V. Somayaji, and R. S. Brown
pp 5205 - 5206; DOI:
10.1021/ja00223a057
PDF
Solvent-induced mechanism change in charge-transfer molecules. Inversion versus rotation paths for the Z .fwdarw. E isomerization of donor-acceptor substituted azobenzenes
Dong Myung Shin and David G. Whitten
pp 5206 - 5208; DOI:
10.1021/ja00223a058
PDF
Synthesis and crystal structure of the first stannacyclopropene derivative
Lawrence R. Sita and Richard D. Bickerstaff
pp 5208 - 5209; DOI:
10.1021/ja00223a059
PDF
A new strategy for 1,4- and 1,4,7-polycarbonyl compounds
Tsuneo Sato, Hiroshi Okazaki, Junzo Otera, and Hitosi Nozaki
pp 5209 - 5211; DOI:
10.1021/ja00223a060
PDF
Molecular yardsticks. Synthesis of extended equilibrium transfer alkylating cross-link reagents and their use in the formation of macrocycles
Stephen J. Brocchini, Martin Eberle, and Richard G. Lawton
pp 5211 - 5212; DOI:
10.1021/ja00223a061
PDF
The total synthesis of robustadial A and B dimethyl ethers
Robert G. Salomon, Kasturi Lal, Samuel M. Mazza, Eugene A. Zarate, and Wiley J. Youngs
pp 5213 - 5214; DOI:
10.1021/ja00223a062
PDF
Low-temperature synthesis of superconducting La2-xMxCuO4: direct precipitation from NaOH/KOH melts
William K. Ham, Gary F. Holland, and Angelica M. Stacy
pp 5214 - 5215; DOI:
10.1021/ja00223a063
PDF
Diastereoselectivity control elements. Acyclic diastereocontrol in formation and reactions of .gamma.-hydroxy sulfones
Barry M. Trost and Craig A. Merlic
pp 5216 - 5218; DOI:
10.1021/ja00223a064
PDF
A folded metallacyclopentatriene and a bicapped-tetrahedral M2C4 cluster obtained from coupling of alkyne ligands. Structures of CpMoCl(C4Ph4) and (CpMoCl)2(.mu.,.eta.4-C5Ar4) (Ar = p-tolyl)
Wakgari Hirpo and M. David Curtis
pp 5218 - 5219; DOI:
10.1021/ja00223a065
PDF
Synthesis and characterization of 12-vertex dinuclear cobaltaborane complexes containing the Co2(CO)5 moiety and SEt2 cage substituents
David M. Schubert, Carolyn B. Knobler, Patrick A. Wegner, and M. Frederick Hawthorne
pp 5219 - 5221; DOI:
10.1021/ja00223a066
PDF
Use of a polymeric counter ion to induce bilayer formation from a single-chain surfactant
Masaaki Wakita, Katherine A. Edwards, Steven L. Regen, David Turner, and Sol M. Gruner
pp 5221 - 5222; DOI:
10.1021/ja00223a067
PDF
A model for the chromophoric site of purple acid phosphatases
Shiping Yan, Lawrence Que, Lucille F. Taylor, and Oren P. Anderson
pp 5222 - 5224; DOI:
10.1021/ja00223a068
PDF
Diastereofacialselectivity in intramolecular Pauson-Khand cycloaddition. Highly stereoselective synthesis of pentalenene
Neil E. Schore and Elizabeth G. Rowley
pp 5224 - 5225; DOI:
10.1021/ja00223a069
PDF
[n]Staffanes: a molecular-size "Tinkertoy" construction set for nanotechnology. Preparation of end-functionalized telomers and a polymer of [1.1.1]propellane
Piotr Kaszynski and Josef Michl
pp 5225 - 5226; DOI:
10.1021/ja00223a070
PDF
The role of oxygen in the partial oxidation of methane over a samarium oxide catalyst
Alfred Ekstrom and Jacek A. Lapszewicz
pp 5226 - 5228; DOI:
10.1021/ja00223a071
PDF
Carbon monoxide and carbon dioxide carbon-metal bond insertion chemistry of alkyliron(III) porphyrin complexes
Isam M. Arafa, Koo Shin, and Harold M. Goff
pp 5228 - 5229; DOI:
10.1021/ja00223a072
PDF
Preparation of complex aminoglycosides: a new strategy
Brian J. Fitzsimmons, Yves Leblanc, Nicolas Chan, and Joshua Rokach
pp 5229 - 5231; DOI:
10.1021/ja00223a073
PDF
A metal-catalyzed cyclization of enallenes
Barry M. Trost and James M. Tour
pp 5231 - 5233; DOI:
10.1021/ja00223a074
PDF
A biomimetic synthesis of (.+-.)-petiodial. A novel palladium-catalyzed enallene cyclization
Barry M. Trost and Koyo Matsuda
pp 5233 - 5235; DOI:
10.1021/ja00223a075
PDF
Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n: resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n
Philip C. Andrews, David R. Armstrong, Robert E. Mulvey, and David Reed
pp 5235 - 5236; DOI:
10.1021/ja00223a076
PDF
Tritriptycene: a D3h C62 hydrocarbon with three U-shaped cavities [Erratum to document cited in CA105(25):225994P]
Abdollah Bashir-Hashemi, Harold Hart, and Donald L. Ward
pp 5237 - 5237; DOI:
10.1021/ja00223a077
PDF
Computer Software Reviews

pp 5237 - 5238; DOI:
10.1021/ja00223a600
PDF
Book Reviews

pp 5238 - 5238; DOI:
10.1021/ja00223a601
PDF

Issue 16


Structures and energies of disilicon dicarbide, C2Si2
Koop Lammertsma and Osman F. Guner
pp 5239 - 5245; DOI:
10.1021/ja00224a001
PDF
Molecular association in ethanol-water mixtures studied by mass spectrometric analysis of clusters generated through adiabatic expansion of liquid jets
Nobuyuki Nishi, Kunimasa Koga, Chikako Ohshima, Kazunori Yamamoto, Umpei Nagashima, and Kenzo Nagami
pp 5246 - 5255; DOI:
10.1021/ja00224a002
PDF
Carbonaceous solids as a model for adsorption by dispersion forces
Edward M. Arnett, Brenda J. Hutchinson, and Marguerite H. Healy
pp 5255 - 5260; DOI:
10.1021/ja00224a003
PDF
Gas-phase reactions. 66. Gas-phase pyrolyses of alkyl azides: experimental evidence for chemical activation
Hans Bock and Ralph Dammel
pp 5261 - 5269; DOI:
10.1021/ja00224a004
PDF
Oscillations and mechanism: catalyzed oxygen oxidation of cyclohexanone
J. D. Druliner and E. Wasserman
pp 5270 - 5275; DOI:
10.1021/ja00224a005
PDF
Picosecond absorption studies on the excited state of (.mu.-oxo)-bis[(tetraphenylporphinato)iron(III)]
C. R. Guest, K. D. Straub, J. A. Hutchinson, and Peter M. Rentzepis
pp 5276 - 5280; DOI:
10.1021/ja00224a006
PDF
Trends in the optical signatures for transition-metal oxide carbonyl complexes. Evaluation of transition-metal carbonyl, M(CO)x, binding energies
M. J. McQuaid, K. Morris, and James L. Gole
pp 5280 - 5285; DOI:
10.1021/ja00224a007
PDF
Structural isomers of C2N+: a selected-ion flow tube study
J. S. Knight, S. A. H. Petrie, C. G. Freeman, Murray J. McEwan, A. D. McLean, and D. J. DeFrees
pp 5286 - 5290; DOI:
10.1021/ja00224a008
PDF
Reaction of ground-state aluminum atoms with propene: electron paramagnetic resonance spectroscopic evidence for a .pi.-allylmetal hydride
M. Histed, J. A. Howard, H. Morris, and B. Mile
pp 5290 - 5292; DOI:
10.1021/ja00224a009
PDF
Electrochemical generation of soluble and reactive cadmium, lead, and thallium cations in noncoordinating solvents. Relative strengths of perchlorate, tetrafluoroborate, and hexafluorophosphate ligation in dichloromethane and benzene
Alan M. Bond, S. Richard Ellis, and Anthony F. Hollenkamp
pp 5293 - 5297; DOI:
10.1021/ja00224a010
PDF
Simulation of free energy relationships and dynamics of SN2 reactions in aqueous solution
Jenn Kang Hwang, Gregory King, S. Creighton, and Arieh Warshel
pp 5297 - 5311; DOI:
10.1021/ja00224a011
PDF
How does a dication lose a proton?
Peter M. W. Gill and Leo Radom
pp 5311 - 5314; DOI:
10.1021/ja00224a012
PDF
Location of the transition structure for a concerted pathway in the methylenecyclopropane rearrangement
Anne Skancke, L. J. Schaad, and B. Andes Hess
pp 5315 - 5316; DOI:
10.1021/ja00224a013
PDF
Ab initio study of the mechanisms of rearrangements in C2B4H6 and C2B5H7
Michael L. McKee
pp 5317 - 5321; DOI:
10.1021/ja00224a014
PDF
Electron density study of thiotrithiazyl chloride, S4N3Cl
Helge Johansen
pp 5322 - 5323; DOI:
10.1021/ja00224a015
PDF
Characterization of interstitial hydrogen within metal clusters in Zr6Cl12H and ZrClOxHy by solid-state nuclear magnetic resonance
P. J. Chu, R. P. Ziebarth, J. D. Corbett, and B. C. Gerstein
pp 5324 - 5329; DOI:
10.1021/ja00224a016
PDF
Spectroscopic studies on ferrous nonheme iron active sites: magnetic circular dichroism of mononuclear iron sites in superoxide dismutase and lipoxygenase
James W. Whittaker and Edward I. Solomon
pp 5329 - 5339; DOI:
10.1021/ja00224a017
PDF
Guyanin, a novel tetranortriterpenoid: structural characterization by 2D NMR spectroscopy and x-ray crystallography
Stewart McLean, Marion Perpick-Dumont, William F. Reynolds, Jeffery F. Sawyer, Helen Jacobs, and Frank Ramdayal
pp 5339 - 5344; DOI:
10.1021/ja00224a018
PDF
Interaction of iron with boron in metal-rich metallaboranes resulting in large deshielding and rapid relaxation processes of the boron-11 nucleus
Nigam P. Rath and Thomas P. Fehlner
pp 5345 - 5349; DOI:
10.1021/ja00224a019
PDF
Infrared spectroscopy of half-methemocyanin cyanide. Evidence for two nonequivalently bound cyanides
Mark A. Pavlosky and James A. Larrabee
pp 5349 - 5353; DOI:
10.1021/ja00224a020
PDF
Trapping of three-center Ir-Sn-X intermediates in the reaction of IrI[C6H4(CH2NMe2)-2](COD) with organotin(IV) halides. X-ray structure of [2-(Me2NCH2)C6H4](COD)Ir(Br)SnMe2Br
Adolphus A. H. Van der Zeijden, Gerard Van Koten, Jacqueline M. A. Wouters, Willem F. A. Wijsmuller, David M. Grove, Wilberth J. J. Smeets, and Anthony L. Spek
pp 5354 - 5361; DOI:
10.1021/ja00224a021
PDF
Defect patterns in perovskites
Jeremy K. Burdett and Gururaj V. Kulkarni
pp 5361 - 5368; DOI:
10.1021/ja00224a022
PDF
Evidence for the lability of a bridging phosphido ligand under hydrogen atmosphere. Reactions of the cluster complex Ru3(.mu.3-P(C6H5)(C5H4N))(.mu.-P(C6H5)2)(CO)8
Noel Lugan, Guy Lavigne, Jean Jacques Bonnet, Regis Reau, Denis Neibecker, and Igor Tkatchenko
pp 5369 - 5376; DOI:
10.1021/ja00224a023
PDF
Pentacoordinated molecules. 74. Distortion coordinate for five-coordinated tin. A model for nucleophilic substitution. Synthesis and structure of hypervalent anionic (cyanoethylenedithiolato)stannates
Roberta O. Day, Joan M. Holmes, Sohelia Shafieezad, V. Chandrasekhar, and Robert R. Holmes
pp 5377 - 5383; DOI:
10.1021/ja00224a024
PDF
Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism
Eiichi Negishi, Larry D. Boardman, Hiroyuki Sawada, Vahid Bagheri, A. Timothy Stoll, James M. Tour, and Cynthia L. Rand
pp 5383 - 5396; DOI:
10.1021/ja00224a025
PDF
Reactions of the nickel(I) octaethylisobacteriochlorin anion with alkyl halides
Alan M. Stolzenberg and Matthew T. Stershic
pp 5397 - 5403; DOI:
10.1021/ja00224a026
PDF
Redox-coupled linkage isomerizations with .eta.2-coordinated anilines
W. Dean Harman and Henry Taube
pp 5403 - 5407; DOI:
10.1021/ja00224a027
PDF
Photochemistry of diplatinum(III,III) pyrophosphite complexes. Efficient photochemical reduction of [Pt2(pop)4X2]4- to [Pt2(pop)4]4- in methanol
Chi Ming Che, Wai Man Lee, and Kar Cheong Cho
pp 5407 - 5411; DOI:
10.1021/ja00224a028
PDF
Aprotic conjugate addition of allyllithium reagents bearing polar groups to cyclic enones. 1. 3-Alkylallyl systems
Malcolm R. Binns, Richard K. Haynes, Andrew G. Katsifis, Paul A. Schober, and Simone C. Vonwiller
pp 5411 - 5423; DOI:
10.1021/ja00224a029
PDF
Aprotic conjugate addition of allyllithium reagents bearing polar groups to cyclic enones. 2. 2-Alkyl-, 2,3-dialkyl- and 1,3-dialkylallyl systems
Richard K. Haynes, Andrew G. Katsifis, Simone C. Vonwiller, and Trevor W. Hambley
pp 5423 - 5433; DOI:
10.1021/ja00224a030
PDF
3-Methyl-.gamma.-butyrolactones as templates for the synthesis of polypropionates: the basic strategy
Frederick E. Ziegler, Alyssa Kneisley, John K. Thottathil, and Ronald T. Wester
pp 5434 - 5442; DOI:
10.1021/ja00224a031
PDF
Applications of the 3-methyl-.gamma.-butyrolactone strategy to the synthesis of polypropionates: the Prelog-Djerassi lactonic ester, ent-invictolide, and the C19-C27 fragment of rifamycin S
Frederick E. Ziegler, William T. Cain, Alyssa Kneisley, Eugene P. Stirchak, and Ronald T. Wester
pp 5442 - 5452; DOI:
10.1021/ja00224a032
PDF
Diastereoselectivity in the Diels-Alder reactions of thio aldehydes
Edwin Vedejs, J. S. Stults, and R. G. Wilde
pp 5452 - 5460; DOI:
10.1021/ja00224a033
PDF
Homogeneous catalytic photochemical functionalization of alkanes by .alpha.-dodecatungstophosphate. Rate behavior, energetics, and general characteristics of the processes
Roman F. Renneke and Craig L. Hill
pp 5461 - 5470; DOI:
10.1021/ja00224a034
PDF
Catalytic photochemical oxidation of organic substrates by polyoxometalates. Picosecond spectroscopy, photochemistry, and structural properties of charge-transfer complexes between heteropolytungstic acids and dipolar organic compounds
Craig L. Hill, Donald A. Bouchard, Miryam Kadkhodayan, Michael M. Williamson, Jeffrey A. Schmidt, and Edwin F. Hilinski
pp 5471 - 5479; DOI:
10.1021/ja00224a035
PDF
Through-bond interaction via cyclobutane relay orbitals as a means of extending conjugation. Synthesis of tricyclo[5.5.0.02,8]dodecatetraene, tricyclo[5.3.0.02,8]deca-3,5,9-triene, and 9,10-dimethylenetricyclo[5.3.0.02,8]deca-3,5-diene
Juergen Dressel, Kent L. Chasey, and Leo A. Paquette
pp 5479 - 5489; DOI:
10.1021/ja00224a036
PDF
Photoelectron spectroscopic analysis of through-bond interaction via cyclobutane relay orbitals. Evidence for strong relay conjugation in tricyclo[5.5.0.02,8]dodecatetraene
Rolf Gleiter, Azumao Toyota, Peter Bischof, Gerhard Krennrich, Juergen Dressel, Paul D. Pansegrau, and Leo A. Paquette
pp 5490 - 5497; DOI:
10.1021/ja00224a037
PDF
Intermediates in nucleophilic aromatic substitution. Part 23. Kinetics of spiro meisenheimer complex formation from 3,6-dimethylcatechol 2,4,6-trinitrophenyl ether. Competition between a trapping and a preassociation mechanism
Claude F. Bernasconi and Douglas E. Fairchild
pp 5498 - 5505; DOI:
10.1021/ja00224a038
PDF
Ketonization of acetophenone enol in aqueous buffer solutions. Rate-equilibrium relations and mechanism of the uncatalyzed reaction
Y. Chiang, Alexander J. Kresge, J. A. Santaballa, and J. Wirz
pp 5506 - 5510; DOI:
10.1021/ja00224a039
PDF
Detection of hyperconjugative effects in experimentally determined structures of neutral molecules
Thomas Laube and Tae Kyu Ha
pp 5511 - 5517; DOI:
10.1021/ja00224a040
PDF
Structure and reactivity of lithium amides. Lithium-6, carbon-13, and nitrogen-15 NMR spectroscopic studies and colligative measurements of lithium diphenylamide and lithium diphenylamide-lithium bromide complex solvated by tetrahydrofuran
Jeffrey S. DePue and David B. Collum
pp 5518 - 5524; DOI:
10.1021/ja00224a041
PDF
Structure and reactivity of lithium diphenylamide. Role of aggregates, mixed aggregates, monomers, and free ions on the rates and selectivities of N-alkylation and E2 elimination
Jeffrey S. DePue and David B. Collum
pp 5524 - 5533; DOI:
10.1021/ja00224a042
PDF
Exploratory studies of the transition metal catalyzed intramolecular cyclization of unsaturated .alpha.,.alpha.-dichloro esters, acids, and nitriles
Thomas K. Hayes, Rosanna Villani, and Steven M. Weinreb
pp 5533 - 5543; DOI:
10.1021/ja00224a043
PDF
Stereochemical controls on exciplex reactions. Excited state proton transfer
Yuan L. Chow, Zheng Zhi Wu, M. L. W. Thewalt, and T. W. Steiner
pp 5543 - 5547; DOI:
10.1021/ja00224a044
PDF
Intramolecular 2 + 2 photocycloadditions of 4-(3'-alkenyl)- and 4-(3'-pentynyl)-2,5-cyclohexadien-1-ones
Arthur G. Schultz, Mark Plummer, Arthur G. Taveras, and Rudolph K. Kullnig
pp 5547 - 5555; DOI:
10.1021/ja00224a045
PDF
Stereochemical profile of the dehydrogenases of Drosophila melanogaster
Rudolf K. Allemann, Rebecca Hung, and Steven A. Benner
pp 5555 - 5560; DOI:
10.1021/ja00224a046
PDF
Comparison of carboxypeptidase A and thermolysin: inhibition by phosphonamidates
David W. Christianson and William N. Lipscomb
pp 5560 - 5565; DOI:
10.1021/ja00224a047
PDF
Simultaneous observation of oxygen-oxygen and iron-oxygen stretching vibrations of Fe(TPP)O2 in dioxygen matrixes by resonance Raman spectroscopy
Wolf Dieter Wagner, Insook Rhee Paeng, and Kazuo Nakamoto
pp 5565 - 5567; DOI:
10.1021/ja00224a048
PDF
Synthesis of 2-functionalized 1,1-diiodo-1-alkenes. Generation and reactions of 1-iodo-1-lithio-1-alkenes and 1,1-dilithio-1-alkenes
Jose Barluenga, Miguel A. Rodriguez, Pedro J. Campos, and Gregorio Asensio
pp 5567 - 5568; DOI:
10.1021/ja00224a049
PDF
Total synthesis of a highly oxygenated quassinoid, (.+-.)-klaineanone
Paul A. Grieco, David T. Parker, and Ravi P. Nargund
pp 5568 - 5569; DOI:
10.1021/ja00224a050
PDF
Spin echo NMR of cobalt zeolite catalysts. Control of particle size and structure
Zongchao Zhang, Steven L. Suib, Y. D. Zhang, W. A. Hines, and J. I. Budnick
pp 5569 - 5571; DOI:
10.1021/ja00224a051
PDF
Ene diimidazoles: ligands for biomimetic chemistry
Teddy G. Traylor, Kenneth W. Hill, Zong Qiang Tian, Arnold L. Rheingold, Jack Peisach, and John McCracken
pp 5571 - 5573; DOI:
10.1021/ja00224a052
PDF
The [MoFe6S6(CO)16]2- ion: a new model for the FeMo-cofactor of nitrogenase
Patricia A. Eldredge, Robert F. Bryan, Ekkehard Sinn, and Bruce A. Averill
pp 5573 - 5575; DOI:
10.1021/ja00224a053
PDF
Catalysis and thermodynamics of the phosphoenolpyruvate/phosphonopyruvate rearrangement. Entry into the phosphonate class of naturally occurring organophosphorus compounds
Elise Bowman, Michael McQueney, Robert J. Barry, and Debra Dunaway-Mariano
pp 5575 - 5576; DOI:
10.1021/ja00224a054
PDF
First experimental evaluation of hypervalent nitrogen-sulfur-nitrogen bond energy from the restricted rotation of pyrimidine ring in 10-S-3 sulfuranes
Kinya Akiba, Minoru Ohsugi, Hideharu Iwasaki, and Katsuo Ohkata
pp 5576 - 5578; DOI:
10.1021/ja00224a055
PDF
A diastereoselective synthesis of (E)-alkene-1,3-diols via the reaction of 3-borolenes with aldehydes
George Zweifel and Timothy M. Shoup
pp 5578 - 5579; DOI:
10.1021/ja00224a056
PDF
Palladium-catalyzed asymmetric 1,4-disilylation of .alpha.,.beta.-unsaturated ketones: catalytic asymmetric synthesis of .beta.-hydroxy ketones
Tamio Hayashi, Yonetatsu Matsumoto, and Yoshihiko Ito
pp 5579 - 5581; DOI:
10.1021/ja00224a057
PDF
Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM
Neil R. Bastian, Gabriele Diekert, Eric C. Niederhoffer, Boon Keng Teo, Christopher T. Walsh, and William H. Orme-Johnson
pp 5581 - 5582; DOI:
10.1021/ja00224a058
PDF
Reversible photodissociation and thermal binding of carbon dioxide in oxo-bridged copper dimers
Maher Henary and Jeffrey I. Zink
pp 5582 - 5583; DOI:
10.1021/ja00224a059
PDF
Armed and disarmed n-pentenyl glycosides in saccharide couplings leading to oligosaccharides
D. R. Mootoo, Peter Konradsson, Uko Udodong, and Bert Fraser-Reid
pp 5583 - 5584; DOI:
10.1021/ja00224a060
PDF
A new class of binucleating tetratertiaryphosphine ligands. The synthesis and crystallographic characterization of the chiral diastereomer of a rhodium(I) dimer: Rh2Cl2(CO)2(eLTTP) (eLTTP = (Et2PCH2CH2)(Ph)PCH2P(Ph)(CH2CH2PEt2))
Scott A. Laneman, Frank R. Fronczek, and George G. Stanley
pp 5585 - 5586; DOI:
10.1021/ja00224a061
PDF
An "expanded porphyrin": the synthesis and structure of a new aromatic pentadentate ligand
Jonathan L. Sessler, Toshiaki Murai, Vincent Lynch, and Michael Cyr
pp 5586 - 5588; DOI:
10.1021/ja00224a062
PDF
8,8'-Bis[tetracyclo[5.1.0.01,6.02,7]octane], a coupled [1.1.1]propellane: synthesis and structure
Georg Kottirsch, Kurt Polborn, and Guenter Szeimies
pp 5588 - 5590; DOI:
10.1021/ja00224a063
PDF
Neutron spectroscopic evidence for adsorbed hydroxyl species on platinum black
T. J. Udovic, R. R. Cavanagh, and J. J. Rush
pp 5590 - 5591; DOI:
10.1021/ja00224a064
PDF
The generation of 1,4-biradicals in rigid media: crystal structure-solid state reactivity correlations
Sara Ariel, Stephen V. Evans, Miguel Garcia-Garibay, Brian R. Harkness, Nalamasu Omkaram, John R. Scheffer, and James Trotter
pp 5591 - 5592; DOI:
10.1021/ja00224a065
PDF
Stereospecific Claisen rearrangement catalyzed by an antibody
Donald Hilvert and Karen D. Nared
pp 5593 - 5594; DOI:
10.1021/ja00224a066
PDF
Local structure evaluation in solid organophosphorus compounds by double cross polarization carbon-13 nuclear magnetic resonance spectroscopy
Edward W. Hagaman
pp 5594 - 5595; DOI:
10.1021/ja00224a067
PDF
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis
James E. Jackson, N. Soundararajan, Matthew S. Platz, and Michael T. H. Liu
pp 5595 - 5596; DOI:
10.1021/ja00224a068
PDF
Study of chlorine atom abstraction reactions of phenylchlorocarbene by laser flash photolysis
Michelle B. Jones, James E. Jackson, N. Soundararajan, and Matthew S. Platz
pp 5597 - 5597; DOI:
10.1021/ja00224a069
PDF
Theory of vibrational circular dichroism: trans-2,3-dideuteriooxirane [Erratum to document cited in CA108(17):149832d]
K. J. Jalkanen, Philip J. Stephens, R. D. Amos, and N. C. Handy
pp 5598 - 5598; DOI:
10.1021/ja00224a070
PDF
Computer Software Reviews

pp 5598 - 5599; DOI:
10.1021/ja00224a600
PDF
Book Reviews

pp 5599 - 5604; DOI:
10.1021/ja00224a601
PDF

Issue 17


Matrix reactions of oxygen atoms with P4. Infrared spectra of P4O, P2O, PO and PO2
Lester Andrews and Robert Withnall
pp 5605 - 5611; DOI:
10.1021/ja00225a001
PDF
Carbon and proton basicity
John I. Brauman and Chau Chung Han
pp 5611 - 5613; DOI:
10.1021/ja00225a002
PDF
Diels-Alder reactions in nonaqueous polar solvents. Kinetic effects of chaotropic and antichaotropic agents and of .beta.-cyclodextrin
Ronald Breslow and Tao Guo
pp 5613 - 5617; DOI:
10.1021/ja00225a003
PDF
Remarkable effects of a pentafluorophenyl group on the stereoselective reactions of a chiral iron acyl complex
Iwao Ojima and Hyok Boong Kwon
pp 5617 - 5621; DOI:
10.1021/ja00225a004
PDF
Orbital interactions in a dimethylbicycloalkadiene series studied by photoelectron spectroscopy. Avoided crossing between two HOMO levels
Tsunetoshi Kobayashi, Sadao Miki, Zenichi Yoshida, Yoshinobu Asako, and Chikara Kajimoto
pp 5622 - 5624; DOI:
10.1021/ja00225a005
PDF
Broad-band two-dimensional Fourier transform ion cyclotron resonance
Peter Pfaendler, Geoffrey Bodenhausen, Jacques Rapin, Marc Etienne Walser, and Tino Gaeumann
pp 5625 - 5628; DOI:
10.1021/ja00225a006
PDF
Unusual spectroscopic features in the emission and absorption spectra of single-crystal potassium tetrachloroplatinate(II) (K2[PtCl4]) caused by multiple-mode excited-state distortions
D. M. Preston, Wolfgang Guentner, Alfred Lechner, Guenter Gliemann, and Jeffrey I. Zink
pp 5628 - 5633; DOI:
10.1021/ja00225a007
PDF
Gas-phase heats of formation of C7H7+ isomers: m-tolyl, p-tolyl, and benzyl ions
Tomas Baer, J. C. Morrow, Jian Dong Shao, and Susan Olesik
pp 5633 - 5638; DOI:
10.1021/ja00225a008
PDF
Intramolecular determinants of conformation and mobility within the antibiotic vancomycin
Jonathan P. Waltho, Dudley H. Williams, David J. M. Stone, and Nicholas J. Skelton
pp 5638 - 5643; DOI:
10.1021/ja00225a009
PDF
The electronic structure of highly anisotropic low-spin ferric porphyrin complexes based on single-crystal EPR measurements
Daryl Inniss, S. Michael Soltis, and Charles E. Strouse
pp 5644 - 5650; DOI:
10.1021/ja00225a010
PDF
A variable-temperature solid-state carbon-13 CPMAS NMR analysis of meso-tetrapropylporphyrin and of octaethylporphyrin
Lucio Frydman, Alejandro C. Olivieri, Luis E. Diaz, Aldonia Valasinas, and Benjamin Frydman
pp 5651 - 5661; DOI:
10.1021/ja00225a011
PDF
Indirect two-dimensional heteronuclear NMR spectroscopy. Phosphorus-31 and iron-57 spectra of organoiron complexes
Reinhard Benn, Herbert Brenneke, Albert Frings, Herbert Lehmkuhl, Gerlinde Mehler, Anna Rufinska, and Thomas Wildt
pp 5661 - 5668; DOI:
10.1021/ja00225a012
PDF
Observation of molecular reorientation in ice by proton and deuterium magnetic resonance
R. J. Wittebort, M. G. Usha, D. J. Ruben, D. E. Wemmer, and A. Pines
pp 5668 - 5671; DOI:
10.1021/ja00225a013
PDF
Quantum chemical studies of the products of decomposition of anticancer (2-haloethyl)nitrosoureas under physiological conditions
Anne Marie Sapse, Evelyn B. Allen, and J. William Lown
pp 5671 - 5675; DOI:
10.1021/ja00225a014
PDF
Ab initio calculation of the ferromagnetic interaction in a copper-vanadyl oxide (CuIIVIIO) heterodinuclear system
Philippe De Loth, Padeleimon Karafiloglou, Jean Pierre Daudey, and Olivier Kahn
pp 5676 - 5680; DOI:
10.1021/ja00225a015
PDF
Quenching of lithium by nitrogen. A dual theoretical MO-CI and VB investigation of the role of ionic and covalent surfaces
Alain Sevin, Patrick Chaquin, Louis Hamon, and Philippe C. Hiberty
pp 5681 - 5686; DOI:
10.1021/ja00225a016
PDF
Molecules for memory, logic, and amplification
Ari Aviram
pp 5687 - 5692; DOI:
10.1021/ja00225a017
PDF
Experimental and theoretical study of excimer formation in 1-azabicyclo[l.m.n]alkanes: interpretation of binding energies using a 3-electron-bond model
Christopher J. Ruggles and Arthur M. Halpern
pp 5692 - 5698; DOI:
10.1021/ja00225a018
PDF
The rapid hydration of the acetyl radical. A pulse radiolysis study of acetaldehyde in aqueous solution.
Man Nien Schuchmann and Clemens Von Sonntag
pp 5698 - 5701; DOI:
10.1021/ja00225a019
PDF
Electrochemical behavior of lithium dialkylamides: the effect of aggregation
Philippe Renaud and Marye Anne Fox
pp 5702 - 5705; DOI:
10.1021/ja00225a020
PDF
An electrochemical characterization of dianions: dilithiated carboxylic acids
Philippe Renaud and Marye Anne Fox
pp 5705 - 5709; DOI:
10.1021/ja00225a021
PDF
Laser-induced fluorescence, far-infrared spectroscopy, and luminescence quenching of europium zeolite Y: site-selective probes of extraframework cations
M. D. Baker, G. A. Ozin, and Michael M. Olken
pp 5709 - 5714; DOI:
10.1021/ja00225a022
PDF
Synthesis and electrochemistry of (CO)2(PMe3)Fe(.mu.2-tert-Bu2P)(.mu.2-CO)Rh(PMe3)L(Fe-Rh) (L = CO, PMe3). Digital simulation of modified ECE mechanism. X-ray crystal structures of (CO)2(PMe3)Fe(.mu.2-tert-Bu2P)(.mu.2-CO)Rh(PMe3)2 and [Me3PO.cntdot.Na(15-crown-5)]+[(CO)3Fe(.mu.2-tert-Bu2P)Rh(PMe3)(CO)]-
Roger D. Moulton, Don J. Chandler, Atta M. Arif, Richard A. Jones, and Allen J. Bard
pp 5714 - 5725; DOI:
10.1021/ja00225a023
PDF
Substituent effects on .eta.2-coordinated arene complexes of pentaammineosmium(II)
W. Dean Harman, Mikiya Sekine, and Henry Taube
pp 5725 - 5731; DOI:
10.1021/ja00225a024
PDF
Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study
Page O. Stoutland and Robert G. Bergman
pp 5732 - 5744; DOI:
10.1021/ja00225a025
PDF
Synthesis and reactions of dinuclear palladium complexes containing methyls and hydride on adjacent palladium centers: Reductive elimination and carbonylation reactions
S. J. Young, B. Kellenberger, Joseph H. Reibenspies, S. E. Himmel, M. Manning, Oren P. Anderson, and J. K. Stille
pp 5744 - 5753; DOI:
10.1021/ja00225a026
PDF
Intramolecular long-range electron transfer in the .alpha.-hemoglobin subunit
M. Faraggi and Michael H. Klapper
pp 5753 - 5756; DOI:
10.1021/ja00225a027
PDF
Oxoferryl complexes of the halogenated (porphinato)iron catalyst [tetrakis(2,6-dichlorophenyl)porphinato]iron
A. Gold, K. Jayaraj, P. Doppelt, R. Weiss, G. Chottard, E. Bill, X. Ding, and A. X. Trautwein
pp 5756 - 5761; DOI:
10.1021/ja00225a028
PDF
Preparation and molecular and electronic structures of a diamagnetic diruthenium(II) compound, Ru2[(p-CH3C6H4)NNN(p-CH3C6H4)]4
F. A. Cotton and Mark Matusz
pp 5761 - 5764; DOI:
10.1021/ja00225a029
PDF
An unusually facile formation of substituted 1,2-dihydropyridine derivatives: the reversible condensation of pyridines with reactive carbonyl groups
Joseph A. King
pp 5764 - 5767; DOI:
10.1021/ja00225a030
PDF
An approach to the total synthesis of aplysiatoxin
Robert E. Ireland, Suvit Thaisrivongs, and Patrick H. Dussault
pp 5768 - 5779; DOI:
10.1021/ja00225a031
PDF
Synthesis of chirally deuteriated phthalimido-propanols and evaluation of their absolute stereochemistry
P. C. Prabhakaran, Steven J. Gould, Gary R. Orr, and James K. Coward
pp 5779 - 5784; DOI:
10.1021/ja00225a032
PDF
Biosynthesis of blasticidin S from L-.alpha.-arginine. Stereochemistry in the arginine-2,3-aminomutase reaction
P. C. Prabhakaran, Nam Tae Woo, Peter S. Yorgey, and Steven J. Gould
pp 5785 - 5791; DOI:
10.1021/ja00225a033
PDF
Synthesis of chirally deuteriated (S-adenosyl-S-methylsulfonio)propylamines and spermidines. Elucidation of the stereochemical course of putrescine aminopropyltransferase (spermidine synthase)
Gary R. Orr, Deborah W. Danz, Gabriele Pontoni, P. C. Prabhakaran, Steven J. Gould, and James K. Coward
pp 5791 - 5799; DOI:
10.1021/ja00225a034
PDF
Biosynthesis of the modified peptide antibiotic nosiheptide in Streptomyces actuosus
David R. Houck, Li Chun Chen, Paul J. Keller, John M. Beale, and Heinz G. Floss
pp 5800 - 5806; DOI:
10.1021/ja00225a035
PDF
A convergent synthesis of triquinane sesterterpenes. Enantioselective synthesis of (-)-retigeranic acid A
Jonathan Wright, Gary J. Drtina, Richard A. Roberts, and Leo A. Paquette
pp 5806 - 5817; DOI:
10.1021/ja00225a036
PDF
Sequential annulation approach to sterpuric acid and sterpurene-3,12,14-triol, metabolites of the silver leaf fungus Stereum purpureum
Leo A. Paquette, Ho Shen Lin, Bruce P. Gunn, and Michael J. Coghlan
pp 5818 - 5826; DOI:
10.1021/ja00225a037
PDF
The stable singlet ground state dication of hexaiodobenzene: possibly a .sigma.-delocalized dication
D. J. Sagl and J. C. Martin
pp 5827 - 5833; DOI:
10.1021/ja00225a038
PDF
Crystal structure of an inclusion complex of .beta.-cyclodextrin with racemic fenoprofen: direct evidence for chiral recognition
Jean A. Hamilton and Longyin Chen
pp 5833 - 5841; DOI:
10.1021/ja00225a039
PDF
Group transfer polymerization with polyunsaturated esters and silyl polyenolates
Walter R. Hertler, T. V. RajanBabu, Derick W. Ovenall, Gade S. Reddy, and Dotsevi Y. Sogah
pp 5841 - 5853; DOI:
10.1021/ja00225a040
PDF
Highly enantioselective and substrate-selective polymers obtained by molecular imprinting utilizing noncovalent interactions. NMR and chromatographic studies on the nature of recognition
Boerje Sellergren, Matti Lepistoe, and Klaus Mosbach
pp 5853 - 5860; DOI:
10.1021/ja00225a041
PDF
Radiation chemical production, lifetimes, and structure-activity relations for .alpha.-dialkoxyalkyl carbocations in aqueous solutions: Importance of solvation for cation reactivity
Robert A. McClelland and Steen Steenken
pp 5860 - 5866; DOI:
10.1021/ja00225a042
PDF
Mechanisms of decarboxylation of carboxybiotin
Peter A. Tipton and W. W. Cleland
pp 5866 - 5869; DOI:
10.1021/ja00225a043
PDF
Interaction of vanadate with uridine and adenosine monophosphate. Formation of ADP and ATP analogs
Alan S. Tracey, Michael J. Gresser, and Susana Liu
pp 5869 - 5874; DOI:
10.1021/ja00225a044
PDF
Conformational mimicry. 1. 1,5-Disubstituted tetrazole ring as a surrogate for the cis amide bond
Janusz Zabrocki, G. David Smith, James B. Dunbar, Hiroshi Iijima, and Garland R. Marshall
pp 5875 - 5880; DOI:
10.1021/ja00225a045
PDF
Preparation and characterization of two His-59 ruthenium-modified algal plastocyanins and an unusually small rate constant for ruthenium(II) .fwdarw. copper(II) intramolecular electron transfer over.apprx.12 .ANG.
M. P. Jackman, J. McGinnis, R. Powls, G. A. Salmon, and A. G. Sykes
pp 5880 - 5887; DOI:
10.1021/ja00225a046
PDF
Enzyme-catalyzed organic syntheses: transesterification reactions of chlorophyll a, bacteriochlorophyll a, and derivatives with chlorophyllase
T. J. Michalski, J. E. Hunt, C. Bradshaw, A. M. Wagner, J. R. Norris, and J. J. Katz
pp 5888 - 5891; DOI:
10.1021/ja00225a047
PDF
Isolation and characterization of a major adduct between mitomycin C and DNA
Maria Tomasz, Roselyn Lipman, Brian F. McGuinness, and Koji Nakanishi
pp 5892 - 5896; DOI:
10.1021/ja00225a048
PDF
1,3-Bis(m-nitrophenyl)urea: an exceptionally good complexing agent for proton acceptors
Margaret C. Etter and Thomas W. Panunto
pp 5896 - 5897; DOI:
10.1021/ja00225a049
PDF
Depth sensitivity of wetting: monolayers of .omega.-mercapto ethers on gold
Colin D. Bain and George M. Whitesides
pp 5897 - 5898; DOI:
10.1021/ja00225a050
PDF
Concerning the catalytic site of porphobilinogen deaminase
A. I. Scott, N. J. Stolowich, H. J. Williams, M. D. Gonzalez, C. A. Roessner, S. K. Grant, and C. Pichon
pp 5898 - 5900; DOI:
10.1021/ja00225a051
PDF
Translocation of radical sites by intramolecular 1,5-hydrogen atom transfer
Dennis P. Curran, Dooseop Kim, Hong Tao Liu, and Wang Shen
pp 5900 - 5902; DOI:
10.1021/ja00225a052
PDF
Cationic chromium(III) alkyls as olefin polymerization catalysts
Barbara J. Thomas and Klaus H. Theopold
pp 5902 - 5903; DOI:
10.1021/ja00225a053
PDF
The relative ease of removing a proton, a hydrogen atom, or an electron from carboxamides versus thiocarboxamides
F. G. Bordwell, Donald J. Algrim, and John A. Harrelson
pp 5903 - 5904; DOI:
10.1021/ja00225a054
PDF
Nickel-catalyzed intramolecular [4+4] cycloadditions. 4. Enantioselective total synthesis of (+)-asteriscanolide
Paul A. Wender, Nathan C. Ihle, and Carlos R. D. Correia
pp 5904 - 5906; DOI:
10.1021/ja00225a055
PDF
Stereoelectronic effects at carboxylate: a syn-oriented model for the histidine-aspartate couple in enzymes
Steven C. Zimmerman and Katherine D. Cramer
pp 5906 - 5908; DOI:
10.1021/ja00225a056
PDF
Stereoelectronic effects and the active site of the serine proteases
Jeffrey B. Huff, Ben Askew, Robert J. Duff, and Julius Rebek
pp 5908 - 5909; DOI:
10.1021/ja00225a057
PDF
The effects of pressure on porphyrin c-cytochrome b5 complex formation
Jack A. Kornblatt, Gaston Hui Bon Hoa, Lindsay Eltis, and A. Grant Mauk
pp 5909 - 5911; DOI:
10.1021/ja00225a058
PDF
Total synthesis of (+)-didemnenones A and B. Absolute configurations of the didemnenones
Craig J. Forsyth and Jon Clardy
pp 5911 - 5912; DOI:
10.1021/ja00225a059
PDF
Origin of the cyanamide carbon of the kinamycin antibiotics
Pamela J. Seaton and Steven J. Gould
pp 5912 - 5914; DOI:
10.1021/ja00225a060
PDF
Crossed-beam study of HX elimination reactions
Y. D. Huh, R. J. Cross, and M. Saunders
pp 5914 - 5915; DOI:
10.1021/ja00225a061
PDF
The necessity of an intact polyene for the biological isomerization of vitamin A
Wing C. Law, Robert R. Rando, Stefano Canonica, Fadila Derguini, and Koji Nakanishi
pp 5915 - 5917; DOI:
10.1021/ja00225a062
PDF
Highly efficient, practical approach to natural taxol
Jean Noel Denis, Andrew E. Greene, Daniel Guenard, Francoise Gueritte-Voegelein, Lydie Mangatal, and Pierre Potier
pp 5917 - 5919; DOI:
10.1021/ja00225a063
PDF
Adiabatic photochemistry of o,o'-dibenzenes
Nienchu C. Yang, Taehee Noh, Hong Gan, Sherin Halfon, and Bruce J. Hrnjez
pp 5919 - 5920; DOI:
10.1021/ja00225a064
PDF
Tellurapyrylium dyes as photochemotherapeutic agents. Surprising tellurium atom effects for the generation of rates of reaction with singlet oxygen
Michael R. Detty, Paul B. Merkel, and Stephen K. Powers
pp 5920 - 5922; DOI:
10.1021/ja00225a065
PDF
Pentalenene biosynthesis and the enzymic cyclization of farnesyl pyrophosphate. Inversion at C-1 during 11-membered-ring formation
Paul H. M. Harrison, John S. Oliver, and David E. Cane
pp 5922 - 5923; DOI:
10.1021/ja00225a066
PDF
Uranium alkoxide chemistry. 1. Synthesis and the novel dimeric structure of the first homoleptic uranium(III) aryloxide complex
W. G. Van der Sluys, C. J. Burns, J. C. Huffman, and A. P. Sattelberger
pp 5924 - 5925; DOI:
10.1021/ja00225a067
PDF
A concise strategy for the syntheses of indole alkaloids of the heteroyohimboid and corynantheioid families. Total syntheses of (.+-.)-tetrahydroalstonine, (.+-.)-cathenamine and (.+-.)-geissoschizine
Stephen F. Martin, Brigitte Benage, and James E. Hunter
pp 5925 - 5927; DOI:
10.1021/ja00225a068
PDF
Facial selectivity of the intramolecular SN2' cyclization: stereocontrolled total synthesis of brevianamide B
Robert M. Williams, Tomasz Glinka, and Ewa Kwast
pp 5927 - 5929; DOI:
10.1021/ja00225a069
PDF
First EPR spectroscopic detection of photochemically generated carbonyloxyl radicals in solution under steady-state conditions
H. G. Korth, J. Chateauneuf, J. Lusztyk, and K. U. Ingold
pp 5929 - 5931; DOI:
10.1021/ja00225a070
PDF
Luminescent exciplex formation involving tetrakis(.mu.-diphosphito)diplatinate(II) and -thallium(I) in aqueous solution
Jeffrey K. Nagle and Bridget A. Brennan
pp 5931 - 5932; DOI:
10.1021/ja00225a071
PDF
A stereoselective synthesis of functionalized cyclopentenes via base-induced ring contraction of thiocarbonyl Diels-Alder adducts
Scott D. Larsen
pp 5932 - 5934; DOI:
10.1021/ja00225a072
PDF
Structure and conformation of two coprogen-type siderophores. Neocoprogen I and neocoprogen II [Erratum to document cited in CA107(13):115410D]
M. B. Hossain, M. A. F. Jalal, B. A. Benson, C. L. Barnes, and D. Van der Helm
pp 5934 - 5934; DOI:
10.1021/ja00225a073
PDF
Nucleophile-promoted electrophilic cyclization reactions of alkynes [Erratum to document cited in CA108(7):55853J]
Larry E. Overman and Matthew J. Sharp
pp 5934 - 5934; DOI:
10.1021/ja00225a074
PDF
Book Reviews

pp 5935 - 5936; DOI:
10.1021/ja00225a600
PDF

Issue 18


Carbon acidities of aromatic compounds. 2. Ionic probes of aromaticity in annelated rings
Michael Meot-Ner, Joel F. Liebman, and Sherif A. Kafafi
pp 5937 - 5941; DOI:
10.1021/ja00226a001
PDF
Circular dichroism of oxiranes: an independent systems/perturbation approach
Alison Rodger
pp 5941 - 5945; DOI:
10.1021/ja00226a002
PDF
The 5-hydroxy-1,2,3-oxadiazolinium ion: neighboring group interaction between N-nitroso and aldehyde carbonyl
Richard N. Loeppky, Eugene D. Fleischmann, John E. Adams, Witold Tomasik, Elmer O. Schlemper, and Tuck C. Wong
pp 5946 - 5951; DOI:
10.1021/ja00226a003
PDF
An EXAFS study of cobalt-manganese/silica bimetallic solvated metal atom dispersed (SMAD) catalysts
Beng Jit Tan, Kenneth J. Klabunde, Tsunehiro Tanaka, Hiroyoshi Kanai, and Satohiro Yoshida
pp 5951 - 5958; DOI:
10.1021/ja00226a004
PDF
Comparative molecular field analysis (CoMFA). 1. Effect of shape on binding of steroids to carrier proteins
Richard D. Cramer, David E. Patterson, and Jeffrey D. Bunce
pp 5959 - 5967; DOI:
10.1021/ja00226a005
PDF
Infrared, resonance Raman, and excitation profile studies of Os2(O2CCH3)4Cl2 and Os2(O2CCD3)4Cl2. The assignment of the osmium-osmium stretching vibration for a complex involving an osmium-osmium multiple bond
Robin J. H. Clark, Andrew J. Hempleman, and Derek A. Tocher
pp 5968 - 5972; DOI:
10.1021/ja00226a006
PDF
A symmetry-based procedure for the determination of molecular geometry changes following electronic excitation. 1. Outline of the qualitative method
V. Bachler and O. E. Polansky
pp 5972 - 5977; DOI:
10.1021/ja00226a007
PDF
A symmetry-based procedure for the determination of molecular geometry changes following electronic excitation. 2. Relaxation pathways for the excited states of ethylene, acetone, butadiene, and methylenimine
V. Bachler
pp 5977 - 5981; DOI:
10.1021/ja00226a008
PDF
Excess free energy of liquids from molecular dynamics simulations. Application to water models
Jan Hermans, Ahammadunny Pathiaseril, and Amil Anderson
pp 5982 - 5986; DOI:
10.1021/ja00226a009
PDF
Iron(I)-induced demethanation of tert-butyl-substituted nitriles in the gas phase. A case of remote functionalization of carbon-carbon bonds
Tilmann Pruesse, Carlito B. Lebrilla, Thomas Drewello, and Helmut Schwarz
pp 5986 - 5993; DOI:
10.1021/ja00226a010
PDF
Do supra-antara paths really exist for 2 + 2 cycloaddition reactions? Analytical computation of the MC-SCF Hessians for transition states of ethylene with ethylene, singlet oxygen, and ketene
Fernando Bernardi, Andrea Bottoni, Massimo Olivucci, Michael A. Robb, H. Bernard Schlegel, and Glauco Tonachini
pp 5993 - 5995; DOI:
10.1021/ja00226a011
PDF
Pseudorotation in pentacoordinated phosphorus compounds. The influence of the conformational transmission effect on the barriers to pseudorotation in cyclic alkoxyphosphoranes
A. E. H. De Keijzer, L. H. Koole, and Hendrick M. Buck
pp 5995 - 6001; DOI:
10.1021/ja00226a012
PDF
A single-crystal ESR study on radicals derived from rac- and meso-1,2-dimethyl-1,2-diphenyldiphosphine disulfide: stereochemical selection in radical formation
Rene A. J. Janssen, Mark J. Van der Woerd, Olav M. Aagaard, and Henk M. Buck
pp 6001 - 6006; DOI:
10.1021/ja00226a013
PDF
Resonance Raman studies of dioxygen adducts of cobalt-substituted heme proteins and model compounds. Vibrationally coupled dioxygen and the issues of multiple structures and distal side hydrogen bonding
Alan Bruha and James R. Kincaid
pp 6006 - 6014; DOI:
10.1021/ja00226a014
PDF
Crystal structure, CP/MAS xeon-129 and carbon-13 NMR of local ordering in Dianin's compound clathrates
F. Lee, E. Gabe, J. S. Tse, and J. A. Ripmeester
pp 6014 - 6019; DOI:
10.1021/ja00226a015
PDF
Separation by sodium-23 NMR of the unimolecular and bimolecular components of the dissociation kinetics of 18-crown-6-Na+ in some nonaqueous solvents
Helen P. Graves and Christian Detellier
pp 6019 - 6024; DOI:
10.1021/ja00226a016
PDF
Is bound carbonyl linear or bent in heme proteins? Evidence from resonance Raman and infrared spectroscopic data
Xiao Yuan Li and Thomas G. Spiro
pp 6024 - 6033; DOI:
10.1021/ja00226a017
PDF
The reaction of n-butyllithium with diphenylacetylene: structure elucidation of the mono- and dilithio product by one- and two-dimensional NMR spectroscopy, x-ray analysis, and MNDO calculations. Agostic activation by lithium
Walter Bauer, Martin Feigel, Gerhard Mueller, and Paul v. R. Schleyer
pp 6033 - 6046; DOI:
10.1021/ja00226a018
PDF
Zigzag collapse of four-membered rings generated by additions of halonium ions to cyclopropanes
Shinichi Yamabe, Tsutomu Minato, Masahiro Seki, and Satoshi Inagaki
pp 6047 - 6053; DOI:
10.1021/ja00226a019
PDF
Superacid solutions in hydrogen fluoride
Ronald J. Gillespie and Jack Liang
pp 6053 - 6057; DOI:
10.1021/ja00226a020
PDF
Structures of lithium salts of 2,3,3-trimethylindolenine and its 5-methoxy derivative in solution and the solid state
L. M. Jackman, L. M. Scarmoutzos, B. D. Smith, and Paul G. Williard
pp 6058 - 6063; DOI:
10.1021/ja00226a021
PDF
Thermodynamic studies of competitive adduct formation: single- and double-insertion reactions of carbon monoxide with rhodium octaethylporphyrin dimer
Virginia L. Coffin, W. Brennen, and Bradford B. Wayland
pp 6063 - 6069; DOI:
10.1021/ja00226a022
PDF
Formation of bridging acylium and nitrilium complexes by reaction of carbon monoxide and tert-butyl isocyanide with a bridging diiron methylidyne complex. Evidence for strong electron donation from the Fe2C core onto the .mu.-CHC.tplbond.O and .mu.-CHC.tplbond.NR ligands
Charles P. Casey, Mark Crocker, Gerald P. Niccolai, Paul J. Fagan, and Mark S. Konings
pp 6070 - 6076; DOI:
10.1021/ja00226a023
PDF
IR flash kinetic spectroscopy of transients generated by irradiation of cyclopentadienylcobalt dicarbonyl in the gas phase and in solution
Eric P. Wasserman, Robert G. Bergman, and C. Bradley Moore
pp 6076 - 6084; DOI:
10.1021/ja00226a024
PDF
Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors
M. J. Carney, G. C. Papaefthymiou, K. Spartalian, R. B. Frankel, and Richard H. Holm
pp 6084 - 6095; DOI:
10.1021/ja00226a025
PDF
Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nucleophilic attack
Dwayne R. Senn, Andrew Wong, Alan T. Patton, Marianne Marsi, Charles E. Strouse, and J. A. Gladysz
pp 6096 - 6109; DOI:
10.1021/ja00226a026
PDF
Divergent kinetic and thermodynamic acidity in organotransition-metal hydride complexes: synthesis, structure, and reactivity of the rhenium anion of Li+ [(.eta.-C5H5)Re(NO)(PPh3)]-
Guy L. Crocco and John A. Gladysz
pp 6110 - 6118; DOI:
10.1021/ja00226a027
PDF
Hole delocalization in oxidized cerium(IV) porphyrin sandwich complexes
Robert J. Donohoe, John K. Duchowski, and David F. Bocian
pp 6119 - 6124; DOI:
10.1021/ja00226a028
PDF
Mechanistic studies of alkene epoxidation catalyzed by nickel(II) cyclam complexes. Oxygen-18 labeling and substituent effects
Joanne F. Kinneary, Jeffrey S. Albert, and Cynthia J. Burrows
pp 6124 - 6129; DOI:
10.1021/ja00226a029
PDF
Preparation, electrochemical oxidation, and XPS studies of unsymmetrical ruthenocenes bearing the pentamethylcyclopentadienyl ligand
Paul G. Gassman and Charles H. Winter
pp 6130 - 6135; DOI:
10.1021/ja00226a030
PDF
Incorporation of phenoxy groups in self-assembled monolayers of trichlorosilane derivatives. Effects on film thickness, wettability, and molecular orientation
Nolan Tillman, Abraham Ulman, Jay S. Schildkraut, and Thomas L. Penner
pp 6136 - 6144; DOI:
10.1021/ja00226a031
PDF
Eliminations from (E)-O-Arylbenzaldoximes promoted by tertiary amines in acetonitrile. Effects of aryl substituents, base strength, and leaving group upon the nitrile-forming transition state
Bong Rae Cho, Kee Dong Kim, Jong Chan Lee, and Nam Soon Cho
pp 6145 - 6148; DOI:
10.1021/ja00226a032
PDF
Comparison of free energy changes for nitrogen inversion and electron loss. 2. 8-Azabicyclo[3.2.1]octyl and 7-azabicyclo[2.2.1]heptyl systems
Stephen F. Nelsen, Silas C. Blackstock, Daniel J. Steffek, Glen T. Cunkle, and Mitchell L. Kurtzweil
pp 6149 - 6153; DOI:
10.1021/ja00226a033
PDF
Calixarenes. 22. Synthesis, properties, and metal complexation of aminocalixarenes
C. David Gutsche and Kye Chun Nam
pp 6153 - 6162; DOI:
10.1021/ja00226a034
PDF
The tunichromes. A class of reducing blood pigments from sea squirts: isolation, structures, and vanadium chemistry
Eugene M. Oltz, Reimar C. Bruening, Mitchell J. Smith, Kenneth Kustin, and Koji Nakanishi
pp 6162 - 6172; DOI:
10.1021/ja00226a035
PDF
Biomimetic syntheses of pretetramides. 1. Synthesis of pretetramide by tandem extension of a polyketide chain
S. Gordon Gilbreath, Constance M. Harris, and Thomas M. Harris
pp 6172 - 6179; DOI:
10.1021/ja00226a036
PDF
Biomimetic syntheses of pretetramides. 2. A synthetic route based on a preformed D ring
Thomas M. Harris, Constance M. Harris, Timothy A. Oster, Larry E. Brown, and John Y. C. Lee
pp 6180 - 6186; DOI:
10.1021/ja00226a037
PDF
Biomimetic syntheses of pretetramides. 3. Synthesis of 6-methylpretetramides using a preassembled D ring template
Thomas M. Harris, Constance M. Harris, Peter C. Kuzma, John Y. C. Lee, Sankaran Mahalingam, and S. Gordon Gilbreath
pp 6186 - 6192; DOI:
10.1021/ja00226a038
PDF
Stereocontrolled construction of an ingenol prototype having a complete array of oxygenated and unsaturated centers
Leo A. Paquette, Robert J. Ross, and James P. Springer
pp 6192 - 6204; DOI:
10.1021/ja00226a039
PDF
Molecular recognition in aqueous media. Conformationally restricted water-soluble cyclophanes derived from 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
Marlon D. Cowart, Irving Sucholeiki, Rudolf R. Bukownik, and Craig S. Wilcox
pp 6204 - 6210; DOI:
10.1021/ja00226a040
PDF
Structural and synthetic studies of the spore germination autoinhibitor, gloeosporone
Stuart L. Schreiber, Sarah E. Kelly, John A. Porco, Tarek Sammakia, and Edward M. Suh
pp 6210 - 6218; DOI:
10.1021/ja00226a041
PDF
Conformational analysis of lipophilic antifolates: crystal structure of piritrexim and a theoretical evaluation of its binding to dihydrofolate reductase
Paul A. Sutton and Vivian Cody
pp 6219 - 6224; DOI:
10.1021/ja00226a042
PDF
Kinetic solvation pressure: a measure of environmental effects on reaction rates. 1. Application to hydrophobic systems
Julio F. Mata-Segreda
pp 6224 - 6230; DOI:
10.1021/ja00226a043
PDF
Thiamin diphosphate catalysis. Mechanistic divergence as a probe of substrate activation of pyruvate decarboxylase
Gerald Gish, Timothy Smyth, and Ronald Kluger
pp 6230 - 6234; DOI:
10.1021/ja00226a044
PDF
Effect of heme orientation on the reduction potential of cytochrome b5
F. Ann Walker, David Emrick, Jenny E. Rivera, Bernard J. Hanquet, and Daniel H. Buttlaire
pp 6234 - 6240; DOI:
10.1021/ja00226a045
PDF
The reaction of dimethylsilylene with carbon monoxide in low-temperature matrices
C. A. Arrington, J. T. Petty, S. E. Payne, and W. C. K. Haskins
pp 6240 - 6241; DOI:
10.1021/ja00226a046
PDF
Ligand field transitions and the origin of zero field splitting in [PPh4][FeCl4] and [NEt4][Fe(SR)4] (R = 2,3,5,6-Me4C6H): a model for the high-spin Fe(III) site in rubredoxin
Joseph C. Deaton, Matthew S. Gebhard, Stephen A. Koch, Michelle Millar, and Edward I. Solomon
pp 6241 - 6243; DOI:
10.1021/ja00226a047
PDF
Nonequilibrated multiple luminescence from CpRe(CO)2(4-Phpy) in 293 K solution
Marsha M. Glezen and Alistair J. Lees
pp 6243 - 6244; DOI:
10.1021/ja00226a048
PDF
Permethylmanganates. Synthesis and characterization of divalent [MnMe42-], trivalent [MnMe52-], and tetravalent [MnMe62-]
Robert J. Morris and Gregory S. Girolami
pp 6245 - 6246; DOI:
10.1021/ja00226a049
PDF
Enantioselective ring cleavage of meso-epoxides with B-halodiisopinocampheylboranes
N. N. Joshi, M. Srebnik, and Herbert C. Brown
pp 6246 - 6248; DOI:
10.1021/ja00226a050
PDF
Organometallic chemical vapor deposition of III/V compound semiconductors with novel organometallic precursors
Alan H. Cowley, Brian L. Benac, John G. Ekerdt, Richard A. Jones, Kenneth B. Kidd, James Y. Lee, and James E. Miller
pp 6248 - 6249; DOI:
10.1021/ja00226a051
PDF
Novel synthesis of tetrahydrofurans via a synthetic equivalent to a carbonyl ylide
Russell J. Linderman and Alex Godfrey
pp 6249 - 6251; DOI:
10.1021/ja00226a052
PDF
Bis(.mu.-acetato)(.mu.-oxo)-bis(tris(pyridine)ruthenium(III)) ion: a ruthenium analog of the hemerythrin active center
Yoichi Sasaki, Masakazu Suzuki, Ayako Tokiwa, Masahiro Ebihara, Tadashi Yamaguchi, Chizuko Kabuto, and Tasuku Ito
pp 6251 - 6252; DOI:
10.1021/ja00226a053
PDF
Boratirane: preparation and characterization of trans-1,1,2,3-tetraphenylboratirane
Michael Kropp, Kaumudi Bhamidapaty, and Gary B. Schuster
pp 6252 - 6254; DOI:
10.1021/ja00226a054
PDF
Acyloxyborane: an activating device for carboxylic acids
Kyoji Furuta, Yoshikazu Miwa, Kiyoshi Iwanaga, and Hisashi Yamamoto
pp 6254 - 6255; DOI:
10.1021/ja00226a055
PDF
Syndiospecific propylene polymerizations with Group IVB metallocenes
John A. Ewen, Robert L. Jones, A. Razavi, and Joseph D. Ferrara
pp 6255 - 6256; DOI:
10.1021/ja00226a056
PDF
Correlation of carbon-13 and nitrogen-15 chemical shifts in selectively and uniformly labeled proteins by heteronuclear two-dimensional NMR spectroscopy
William M. Westler, Brian J. Stockman, Yoshiko Hosoya, Yoko Miyake, Masatsune Kainosho, and John L. Markley
pp 6256 - 6258; DOI:
10.1021/ja00226a057
PDF
Mass measurements using isotopically labeled solvents reveal the extent of solvent transport during redox in thin films on electrodes
Steven J. Lasky and Daniel A. Buttry
pp 6258 - 6260; DOI:
10.1021/ja00226a058
PDF
Facile cleavage of C-H bonds. Reaction of trimethylaluminum with bis(diphenylphosphinoyl)methane. Synthesis and molecular structure of [Al(CH3)][(C6H5)2P(O)CP(O)(C6H5)2]2[Al(CH3)2]2
Gregory H. Robinson, Baosheng Lee, William T. Pennington, and Samuel A. Sangokoya
pp 6260 - 6261; DOI:
10.1021/ja00226a059
PDF
The x-ray structure of flavohemoglobin. A semisynthetic hydroxylase
John Kuriyan, Arno Pahler, Reyna J. Simon, Toshio Kokubo, and E. T. Kaiser
pp 6261 - 6263; DOI:
10.1021/ja00226a060
PDF
Ring enlargement of boracyclanes via sequential one carbon homologation. The first synthesis of boracyclanes in the strained medium ring range
Herbert C. Brown, Avinash S. Phadke, and Milind V. Rangaishenvi
pp 6263 - 6264; DOI:
10.1021/ja00226a061
PDF
Total synthesis of (.+-.)-punctaporonin B
Andrew S. Kende, Istvan Kaldor, and Robert Aslanian
pp 6265 - 6266; DOI:
10.1021/ja00226a062
PDF
The peptide way to macrocyclic bifunctional chelating agents: synthesis of 2-(p-nitrobenzyl)-1,4,7,10-tetraazacyclododecane-N,N',N",N'''-tetraacetic acid and study of its yttrium(III) complex
Min K. Moi, Claude F. Meares, and Sally J. DeNardo
pp 6266 - 6267; DOI:
10.1021/ja00226a063
PDF
Highly sensitive flash photolysis with optical waveguides: photodeposition of silver onto particulate TiO2 from solution
Kiminori Ito and Akira Fujishima
pp 6267 - 6269; DOI:
10.1021/ja00226a064
PDF
Observation of a local minimum on the S1 surface of cis-stilbene solvated in inert gas clusters
Hrvoje Petek, Yoshihisa Fujiwara, Dongho Kim, and Keitaro Yoshihara
pp 6269 - 6270; DOI:
10.1021/ja00226a065
PDF
Reaction of dimesitylsilylene in a cryogenic oxygen matrix. IR spectroscopic observation of a silylene-oxygen adduct
Takeshi Akasaka, Shigeru Nagase, Akira Yabe, and Wataru Ando
pp 6270 - 6272; DOI:
10.1021/ja00226a066
PDF
Unusually lower barrier to reductive elimination in an 18-electron .eta.3-allyl(organo)nickel(II) complex than those for the 16-electron .eta.3-allyl counterpart and its 16-electron .eta.1-allyl isomer
Hideo Kurosawa, Hiroaki Ohnishi, Mitsuhiro Emoto, Yoshikane Kawasaki, and Shinji Murai
pp 6272 - 6273; DOI:
10.1021/ja00226a067
PDF
Optically active 2-ethenyl-1,3-dioxolanones as 3-carbon synthons. Allylnickel derivatives as homoenolate equivalents
Damian J. Krysan and Peter B. Mackenzie
pp 6273 - 6274; DOI:
10.1021/ja00226a068
PDF
Directed Arbuzov-type reactions of 2-cyano-1,1-dimethylethyl deoxynucleoside phosphites
John Nielsen and Marvin H. Caruthers
pp 6275 - 6276; DOI:
10.1021/ja00226a069
PDF
The resolution of racemic hydroperoxides: the preparation of optically pure hydroperoxide natural products
Patrick Dussault and Ned A. Porter
pp 6276 - 6277; DOI:
10.1021/ja00226a070
PDF
Principal component self-modeling analysis applied to conformational equilibration of 1,3-butadiene vapor. UV spectra and thermodynamic parameters of the two conformers
Ya-Ping Sun, D. F. Sears, and J. Saltiel
pp 6277 - 6278; DOI:
10.1021/ja00226a071
PDF
Computer Software Reviews

pp 6279 - 6280; DOI:
10.1021/ja00226a600
PDF
Book Reviews

pp 6280 - 6286; DOI:
10.1021/ja00226a601
PDF

Issue 19


An experimental link between the carbon-13 NMR chemical shift of carbonyl carbons and the energy shifts observed in the n .fwdarw. 3s optical transition of cyclic ketones
Timothy J. Cornish and Tomas Baer
pp 6287 - 6291; DOI:
10.1021/ja00227a001
PDF
Combined deuterium and oxygen-18 isotope effects in support of a concerted, synchronous elimination of acetaldehyde from a bis(benzyl ethyl ether) radical cation
Colin E. Allison, Michael B. Stringer, John H. Bowie, and Peter J. Derrick
pp 6291 - 6297; DOI:
10.1021/ja00227a002
PDF
Carbon acidities of aromatic compounds. 1. Effects of in-ring aza and external electron-withdrawing groups
Michael Meot-Ner and Sherif A. Kafafi
pp 6297 - 6303; DOI:
10.1021/ja00227a003
PDF
Proton affinities and pKa values of tetraalkylhydrazines
Stephen F. Nelsen, Daniel T. Rumack, L. Wayne Sieck, and M. Meot-Ner (Mautner)
pp 6303 - 6308; DOI:
10.1021/ja00227a004
PDF
An ab initio investigation of the stabilization of selected .beta.-substituted ethyl cations and .alpha.-substituted methyl cations
Julia C. White, Robert J. Cave, and Ernest R. Davidson
pp 6308 - 6314; DOI:
10.1021/ja00227a005
PDF
Conformational analysis of the pyrrolizidine alkaloid senecionine using molecular mechanics
Bryan A. Hanson and James D. White
pp 6314 - 6318; DOI:
10.1021/ja00227a006
PDF
Vibronic coupling model for the calculation of mixed-valence line shapes: the interdependence of vibronic and MO effects
Susan B. Piepho
pp 6319 - 6326; DOI:
10.1021/ja00227a007
PDF
Infrared spectrum of F.hivin..cntdot.H2O
Brian F. Yates, Henry F. Schaefer, Timothy J. Lee, and Julia E. Rice
pp 6327 - 6332; DOI:
10.1021/ja00227a008
PDF
A theoretical study of the reaction of ketene radical cation with ethylene: nucleophilic addition or concerted [2 + 1] cycloaddition?
Nikolaus Heinrich, Wolfram Koch, J. C. Morrow, and Helmut Schwarz
pp 6332 - 6336; DOI:
10.1021/ja00227a009
PDF
Reactivity of biologically important reduced pyridines. 2. Oxidation of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP). MNDO study
Marcus E. Brewster, James J. Kaminski, and Nicholas Bodor
pp 6337 - 6341; DOI:
10.1021/ja00227a010
PDF
Resonance Raman studies of myoglobin single crystals
Dimitrios Morikis, J. Timothy Sage, Apostolos K. Rizos, and Paul M. Champion
pp 6341 - 6342; DOI:
10.1021/ja00227a011
PDF
ENDOR-determined molecular geometries of spin-labeled fluoroanilides in frozen solution
Gregg B. Wells and Marvin W. Makinen
pp 6343 - 6352; DOI:
10.1021/ja00227a012
PDF
Nuclear magnetic resonance study of the molecular and electronic structure of the stable green sulfhemin prosthetic groups extracted from sulfmyoglobin
Mariann J. Chatfield, Gerd N. La Mar, W. O. Parker, Kevin M. Smith, Hiu Kwong Leung, and Ian K. Morris
pp 6352 - 6358; DOI:
10.1021/ja00227a013
PDF
Nuclear magnetic resonance studies of the solution chemistry of metal complexes. 25. Hg(thiol)3 complexes and HG(II)-thiol ligand exchange kinetics
Bruce V. Cheesman, Alan P. Arnold, and Dallas L. Rabenstein
pp 6359 - 6364; DOI:
10.1021/ja00227a014
PDF
Chlorine NMR studies of ionized and associated silyl perchlorates
Joseph B. Lambert and Wojciech Schilif
pp 6364 - 6367; DOI:
10.1021/ja00227a015
PDF
Solid-state deuterium NMR investigation of internal motion in 2'-deoxythymidine
Agustin Kintanar, Todd M. Alam, Wen Chang Huang, Deborah C. Schindele, David E. Wemmer, and Gary Drobny
pp 6367 - 6372; DOI:
10.1021/ja00227a016
PDF
The oxygen-18 isotope shift in carbon-13 nuclear magnetic resonance spectroscopy. 12. Position of bond cleavage in the acid-catalyzed hydrolysis of sucrose
Tony L. Mega and Robert L. Van Etten
pp 6372 - 6376; DOI:
10.1021/ja00227a017
PDF
The radical anions of [2.2]metaparacyclophane and some derivatives. A comprehensive ESR, ENDOR, and TRIPLE resonance study of unstable paramagnetic species in solution
Juerg Bruhin, Fabian Gerson, Wiliam B. Martin, and Hynek Novotny
pp 6377 - 6384; DOI:
10.1021/ja00227a018
PDF
Identification of high-valent fluoroiron porphyrin intermediates associated with the electrocatalytic functionalization of hydrocarbons
David L. Hickman, Alaganandan Nanthakumar, and Harold M. Goff
pp 6384 - 6390; DOI:
10.1021/ja00227a019
PDF
Reductive chemistry of nickel hydroporphyrins. Evidence for a biologically significant difference between porphyrins, hydroporphyrins, and other tetrapyrroles
Alan M. Stolzenberg and Matthew T. Stershic
pp 6391 - 6402; DOI:
10.1021/ja00227a020
PDF
Electron mediation through the thiocyanate bridge: mono- and dinuclear ruthenium diimine complexes and their mixed-valence properties
Vaithianathan Palaniappan, Sokki Sathaiah, Hari Dutt Bist, and Umesh Chandra Agarwala
pp 6403 - 6410; DOI:
10.1021/ja00227a021
PDF
Rhodium complexes with tripodal polyphosphines as excellent precursors to systems for the activation of H-H and C-H bonds
Claudio Bianchini, Dante Masi, Andrea Meli, Maurizio Peruzzini, and Fabrizio Zanobini
pp 6411 - 6423; DOI:
10.1021/ja00227a022
PDF
Reactivity of trimethylaluminum with (C5Me5)2Sm(THF)2: synthesis, structure, and reactivity of the samarium methyl complexes (C5Me5)2Sm[(.mu.-Me)AlMe2(.mu.-Me)]2Sm(C5Me5)2 and (C5Me5)2SmMe(THF)
William J. Evans, L. R. Chamberlain, Tamara A. Ulibarri, and Joseph W. Ziller
pp 6423 - 6432; DOI:
10.1021/ja00227a023
PDF
Stereochemistry of vinylallene cycloadditions
Hans J. Reich, Eric K. Eisenhart, Wesley L. Whipple, and Martha J. Kelly
pp 6432 - 6442; DOI:
10.1021/ja00227a024
PDF
Host-guest chemistry. 14. Solvent and salt effects on binding constants of organic substrates in macrocyclic host compounds. A general equation measuring hydrophobic binding contributions
Hans Joerg Schneider, Ruediger Kramer, Svetlana Simova, and Ulrich Schneider
pp 6442 - 6448; DOI:
10.1021/ja00227a025
PDF
Host-guest chemistry. 15. Host-guest complexes with water-soluble macrocyclic polyphenolates including induced fit and simple elements of a proton pump
Hans Joerg Schneider, Detlev Guettes, and Ulrich Schneider
pp 6449 - 6454; DOI:
10.1021/ja00227a026
PDF
First example of a trimeric metalloporphyrin. Synthesis, electrochemical, and spectroelectrochemical studies of [(P)Th(OH)2]3 where P is the dianion of octaethyl- or tetraphenylporphyrin. Crystal structure of a dihydrated trinuclear complex of dihydroxy(5,10,15,20-tetraphenylporphinato)thorium(IV) heptane solvate
K. M. Kadish, Y. H. Liu, J. E. Anderson, P. Charpin, G. Chevrier, M. Lance, M. Nierlich, D. Vigner, A. Dormond, and et al.
pp 6455 - 6462; DOI:
10.1021/ja00227a027
PDF
Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene
Alain Igau, Hansjorg Grutzmacher, Antoine Baceiredo, and Guy Bertrand
pp 6463 - 6466; DOI:
10.1021/ja00227a028
PDF
Enantioselective synthesis of (-)-kainic acid
Seiichi Takano, Takumichi Sugihara, Shigeki Satoh, and Kunio Ogasawara
pp 6467 - 6471; DOI:
10.1021/ja00227a029
PDF
Synthesis of (.+-.)-fredericamycin A
T. Ross Kelly, Stephen H. Bell, Naohito Ohashi, and Rosemary J. Armstrong-Chong
pp 6471 - 6480; DOI:
10.1021/ja00227a030
PDF
Enzymes in carbohydrate synthesis: N-acetylneuraminic acid aldolase catalyzed reactions and preparation of N-acetyl-2-deoxy-D-neuraminic acid derivatives
Mahn Joo Kim, William J. Hennen, H. Marcel Sweers, and Chi Huey Wong
pp 6481 - 6486; DOI:
10.1021/ja00227a031
PDF
A mechanistic study of the Mitsunobu esterification reaction
D. L. Hughes, R. A. Reamer, J. J. Bergan, and E. J. J. Grabowski
pp 6487 - 6491; DOI:
10.1021/ja00227a032
PDF
Epoxides in vicinal diol dehydration. 7. A mechanistic characterization of the spontaneous ring opening process of epoxides in aqueous solution: kinetic and product studies
Y. Pocker, B. P. Ronald, and K. W. Anderson
pp 6492 - 6497; DOI:
10.1021/ja00227a033
PDF
Crystal structures of D-(+)- and meso-hydrobenzoin. Absolute direction of the dipole moment of D- and L-hydrobenzoin in the crystal and correlation with crystal morphology, pyroelectric effect, and absolute configuration
William T. Pennington, Sumita Chakraborty, Iain C. Paul, and D. Y. Curtin
pp 6498 - 6504; DOI:
10.1021/ja00227a034
PDF
Intramolecular nucleophilic addition of phenolate oxygen to double bonds activated by carboxyl and carboxylate groups. Relative reactivity, stereochemistry, and mechanism
Tina L. Amyes and Anthony J. Kirby
pp 6505 - 6514; DOI:
10.1021/ja00227a035
PDF
Rate and equilibrium constants of ionization of (.alpha.-cyanodiphenylmethane)bis[tricarbonylchromium(0)] in dimethyl sulfoxide-water mixtures. Unusual solvent effect on the intrinsic rate constant
Claude F. Bernasconi, Richard D. Bunnell, and Francois Terrier
pp 6514 - 6521; DOI:
10.1021/ja00227a036
PDF
Capacity of quadricyclane frameworks related to syn-sesquinorbornatriene for excited-state rearrangement
Leo A. Paquette, Hermann Kuenzer, and Mark A. Kesselmayer
pp 6521 - 6527; DOI:
10.1021/ja00227a037
PDF
A mechanistic probe study of potential electron-transfer reactions of lithium dialkylamides
Martin Newcomb, Michael T. Burchill, and Thomas M. Deeb
pp 6528 - 6535; DOI:
10.1021/ja00227a038
PDF
EPR spectroscopy of triplet aryl nitrenes covalently bound to .alpha.-chymotrypsin. Application of low-temperature methods to photoaffinity labeling
K. Kanakarajan, Raymond Goodrich, Mary J. T. Young, Soundara Soundararajan, and Matthew S. Platz
pp 6536 - 6541; DOI:
10.1021/ja00227a039
PDF
Observation of secondary bonding in solution: synthesis, NMR studies, and the crystal structure of TeVI[OTeIV(C8H8)(S2P(OEt)2)]6
Dainis Dakternieks, Robert Di Giacomo, Robert W. Gable, and Bernard F. Hoskins
pp 6541 - 6546; DOI:
10.1021/ja00227a040
PDF
Sterically congested molecules: synthesis, characterization, and unique spectral characteristics of hexa-tert-butyl-substituted biaryl bis(1,3,2-oxazaphospholidines)
Stephen D. Pastor, James L. Hyun, Paul A. Odorisio, and Ronald K. Rodebaugh
pp 6547 - 6555; DOI:
10.1021/ja00227a041
PDF
Cyclization terminators. Vinylcyclopropanol as a composite functional group
Barry M. Trost and Donna C. Lee
pp 6556 - 6558; DOI:
10.1021/ja00227a042
PDF
A synthesis of taxusin
Robert A. Holton, R. R. Juo, Hyeong B. Kim, Andrew D. Williams, Shinya Harusawa, Richard E. Lowenthal, and Sadamu Yogai
pp 6558 - 6560; DOI:
10.1021/ja00227a043
PDF
Formation of two-component surfaces by the spontaneous assembly of monolayers on gold from solutions containing mixtures of organic thiols
Colin D. Bain and George M. Whitesides
pp 6560 - 6561; DOI:
10.1021/ja00227a044
PDF
Aromatic-aromatic interactions in molecular recognition: a family of artificial receptors for thymine that shows both face-to-face and edge-to-face orientations
Alexander V. Muehldorf, Donna Van Engen, John C. Warner, and Andrew D. Hamilton
pp 6561 - 6562; DOI:
10.1021/ja00227a045
PDF
.sigma.-Delocalization induced stereoselectivity in the capture of cumyl cations and failure of stabilizing substituents to suppress it
M. H. Lin, C. K. Cheung, and W. J. Le Noble
pp 6562 - 6563; DOI:
10.1021/ja00227a046
PDF
Unbridged and bridged isomers of W2(PCy2)2(NMe2)4: preparations, characterizations, and comments on thermodynamic and activation parameters for the closing of phosphido bridges in d3-d3 dinuclear compounds
William E. Buhro, Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, James D. Martin, and William E. Streib
pp 6563 - 6565; DOI:
10.1021/ja00227a047
PDF
Hypervalent alkenyliodonium tetrafluoroborates. Evidence for generation of alkylidenecarbenes via base-induced .alpha.-elimination
Masahito Ochiai, Yoshikazu Takaoka, and Yoshimitsu Nagao
pp 6565 - 6566; DOI:
10.1021/ja00227a048
PDF
Experimental support for Asp-52's importance in lysozyme using a carbohydrate-based enzyme model. Acetal hydrolysis catalyzed by a "stereoelectronically correct" carboxylate group
Xavier M. Cherian, Scott A. Van Arman, and Anthony W. Czarnik
pp 6566 - 6568; DOI:
10.1021/ja00227a049
PDF
The degenerate 21-homododecahedryl cation
Leo A. Paquette, Tomoshige Kobayashi, and Mark A. Kesselmayer
pp 6568 - 6569; DOI:
10.1021/ja00227a050
PDF
Optical memory in copper(1+)-doped .beta."-alumina
Gary Hollingsworth, James D. Barrie, Bruce Dunn, and Jeffrey I. Zink
pp 6569 - 6570; DOI:
10.1021/ja00227a051
PDF
Sequence-specific scission of RNA by 1,10-phenanthroline-copper linked to deoxyoligonucleotides
Chi Hong B. Chen and David S. Sigman
pp 6570 - 6572; DOI:
10.1021/ja00227a052
PDF
Regio- and stereoselective reduction of N(21),N(22)-bridged porphyrin hydroperchlorates to stable 5H-phlorins
Junichiro Setsune, Mitsuhiro Ikeda, Toshiya Iida, and Teijiro Kitao
pp 6572 - 6574; DOI:
10.1021/ja00227a053
PDF
Cupped- and cappedophanes, two new general classes of compounds with molecular cavities
Thottumkara K. Vinod and Harold Hart
pp 6574 - 6575; DOI:
10.1021/ja00227a054
PDF
Molecular recognition: multipoint contacts with new sizes and shapes
Jonathan S. Lindsey, Patrick C. Kearney, Robert J. Duff, P. Tjama Tjivikua, and Julius Rebek
pp 6575 - 6577; DOI:
10.1021/ja00227a055
PDF
Isolation and structural elucidation of the tetrahedral intermediate in the EPSP synthase enzymic pathway
Karen S. Anderson, James A. Sikorski, Alan J. Benesi, and Kenneth A. Johnson
pp 6577 - 6579; DOI:
10.1021/ja00227a056
PDF
Observation of reactive o-quinodimethanes by flow NMR
Walter S. Trahanovsky, C. H. Chou, D. R. Fischer, and B. C. Gerstein
pp 6579 - 6581; DOI:
10.1021/ja00227a057
PDF
Oxygen isotope exchange between water and semiquinones
Gerald R. Stevenson, Zhong Yi Wang, Richard C. Reiter, and Steven J. Peters
pp 6581 - 6582; DOI:
10.1021/ja00227a058
PDF
Chemistry of singlet oxygen. 50. Hydroperoxide intermediates in the photooxygenation of ascorbic acid
Byoung Mog Kwon and Christopher S. Foote
pp 6582 - 6583; DOI:
10.1021/ja00227a059
PDF
Intermediate in the ene reaction of singlet oxygen with 1,4-diphenyl-cis-2-butene and 2-butene
Michael Orfanopoulos and Christopher S. Foote
pp 6583 - 6584; DOI:
10.1021/ja00227a060
PDF
Novel rates and mechanisms of CO substitution of similar 17- and 18-electron metal carbonyls
Noel C. Hallinan, Giancarlo Morelli, and Fred Basolo
pp 6585 - 6586; DOI:
10.1021/ja00227a061
PDF
Direct observation of superoxide electron transfer with viologens by immobilization in zeolite
K. B. Yoon and J. K. Kochi
pp 6586 - 6588; DOI:
10.1021/ja00227a062
PDF
Rhodopsin activation: a novel view suggested by in vivo Chlamydomonas experiments
Kenneth W. Foster, Jureepan Saranak, Fadila Derguini, V. Jayathirtha Rao, Gerald R. Zarrilli, Masami Okabe, Jim Min Fang, Nobuko Shimizu, and Koji Nakanishi
pp 6588 - 6589; DOI:
10.1021/ja00227a063
PDF
[Na2Fe18S30]8-. A high-nuclearity cyclic cluster generated solely by iron-sulfur bridge bonding
Jing Feng You, Barry S. Snyder, and R. H. Holm
pp 6589 - 6591; DOI:
10.1021/ja00227a064
PDF
Heterobimetallic catalysts for the oxidation of alcohols. [Os(N)R2(CrO4)]- (R = Me, CH2SiMe3)
Naijie Zhang, Charles M. Mann, and Patricia A. Shapley
pp 6591 - 6592; DOI:
10.1021/ja00227a065
PDF
A hybrid sequence-selective ribonuclease S
Ronald N. Zuckermann and Peter G. Schultz
pp 6592 - 6594; DOI:
10.1021/ja00227a066
PDF
New channel type inclusion compound of steroidal bile acid. Structure of 1:1 complex between cholic acid and acetophenone
Kunio Miki, Akihiko Masui, Nobutami Kasai, Mikiji Miyata, Motonari Shibakami, and Kiichi Takemoto
pp 6594 - 6596; DOI:
10.1021/ja00227a067
PDF
Bis[(pentamethylcyclopentadienyl)metal]pentalenes. A new class of highly delocalized, fused metallocenes
Emilio E. Bunel, Luis Valle, Nancy L. Jones, Patrick J. Carroll, Cecilia Barra, Myriam Gonzalez, Nancy Munoz, Giovanni Visconti, Arie Aizman, and Juan M. Manriquez
pp 6596 - 6598; DOI:
10.1021/ja00227a068
PDF
3,4-Di-tert-butylthiophene 1,1-dioxide, a convenient precursor of o-Di-tert-butylbenzene and its derivatives
Juzo Nakayama, Shoji Yamaoka, Tomoko Nakanishi, and Masamatsu Hoshino
pp 6598 - 6599; DOI:
10.1021/ja00227a069
PDF
1-Methyl-4,5-cyclopentenoborepin: a neutral boron analog of tropylium [Erratum to document cited in CA106(21):176450T]
Arthur J. Ashe and Frederick J. Drone
pp 6599 - 6599; DOI:
10.1021/ja00227a070
PDF
Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy [Erratum to document cited in CA108(22):187565B]
R. Spindler and D. F. Shriver
pp 6599 - 6599; DOI:
10.1021/ja00227a071
PDF
Book Reviews

pp 6600 - 6600; DOI:
10.1021/ja00227a600
PDF

Issue 20


Gas-phase and computational studies of pentacoordinate silicon
Robert Damrauer, Larry W. Burggraf, Larry P. Davis, and Mark S. Gordon
pp 6601 - 6606; DOI:
10.1021/ja00228a001
PDF
Gas-phase chemistry of transition metal-imido and -nitrene ion complexes. Oxidative addition of nitrogen-hydrogen bonds in ammonia and transfer of NH from a metal center to an alkene
Steven W. Buckner, James R. Gord, and Ben S. Freiser
pp 6606 - 6612; DOI:
10.1021/ja00228a002
PDF
Surface-enhanced Raman study of the effect of electrode potential and solution pH upon the interfacial behavior of 4-pyridinecarboxaldehyde
Mark R. Anderson and Dennis H. Evans
pp 6612 - 6617; DOI:
10.1021/ja00228a003
PDF
Resonance Raman studies of hydrogenase-catalyzed reduction of cytochrome c3 by hydrogenation. Evidence for heme-heme interactions
A. L. Verma, K. Kimura, A. Nakamura, T. Yagi, H. Inokuchi, and T. Kitagawa
pp 6617 - 6623; DOI:
10.1021/ja00228a004
PDF
Magnetic properties in terms of localized quantities. 9. The DNA bases, and the protonation of adenine
Michael Schindler
pp 6623 - 6630; DOI:
10.1021/ja00228a005
PDF
Geometry of the transition state of the decarbonylation of bicyclo[2.2.1]hepta-2,5-dien-7-one. Experimental and ab initio theoretical studies
David M. Birney, Kenneth B. Wiberg, and Jerome A. Berson
pp 6631 - 6642; DOI:
10.1021/ja00228a006
PDF
Rotational barriers in aldehydes and ketones coordinated to neutral Lewis acids
Teresa J. LePage and Kenneth B. Wiberg
pp 6642 - 6650; DOI:
10.1021/ja00228a007
PDF
The nickel-carbonyl binding energy in Ni(CO)x (x = 1-4). A theoretical investigation
Margareta R. A. Blomberg, Ulf B. Brandemark, Per E. M. Siegbahn, Jan Wennerberg, and Charles W. Bauschlicher
pp 6650 - 6655; DOI:
10.1021/ja00228a008
PDF
Protein fluctuations, distributed coupling, and the binding of ligands to heme proteins
V. Srajer, L. Reinisch, and P. M. Champion
pp 6656 - 6670; DOI:
10.1021/ja00228a009
PDF
Determination of the central bond length in hexaarylethanes by nutation NMR spectroscopy
Nino Yannoni, Bart Kahr, and Kurt Mislow
pp 6670 - 6672; DOI:
10.1021/ja00228a010
PDF
Intramolecular electron transfer in linked tris(2,2'-bipyridine)ruthenium(II)/diquat complexes
Laura F. Cooley, Christine E. L. Headford, C. Michael Elliott, and David F. Kelley
pp 6673 - 6682; DOI:
10.1021/ja00228a011
PDF
Appearance potentials of CnH2n+2N+ ions (n = 1-3)
S. W. Sigsworth, R. G. Keesee, and A. W. Castleman
pp 6682 - 6684; DOI:
10.1021/ja00228a012
PDF
Quantitative studies of the effect of added acid and base on the sputtering of organic amines and acids from dilute glycerol solution
Woodfin V. Ligon and Steven B. Dorn
pp 6684 - 6688; DOI:
10.1021/ja00228a013
PDF
The photochemistry of matrix-isolated di-tert-butyldiazidosilane. Observation of di-tert-butylsilylene and N,N'-di-tert-butylsilanediimine
Kevin M. Welsh, Josef Michl, and Robert West
pp 6689 - 6696; DOI:
10.1021/ja00228a014
PDF
Electronic structure of dicyanobarrelenes studied by integration of photoelectron spectroscopy, cyclic voltammetry, electronic spectroscopy, molecular orbital theory, and composite molecule theory
Tsunetoshi Kobayashi, Hideki Yamochi, Kazuhiro Nakasuji, and Ichiro Murata
pp 6696 - 6701; DOI:
10.1021/ja00228a015
PDF
Isomerization of the dimethyl sulfoxide radical cation and the possible analogies to the neutral species
Lars Carlsen and Helge Egsgaard
pp 6701 - 6705; DOI:
10.1021/ja00228a016
PDF
Chemisorption on the microsurface of metal clusters: activation barriers and chemical reactions for carbon monoxide, nitrogen, oxygen, and methane on aluminum cluster
Martin F. Jarrold and J. Eric Bower
pp 6706 - 6716; DOI:
10.1021/ja00228a017
PDF
Metal ion substitution chemistry in the yttrium barium copper oxide system as a probe of the superexchange pathway
Ruth Jones, Peter P. Edwards, Martin R. Harrison, Thitinant Thanyasiri, and Ekkehard Sinn
pp 6716 - 6720; DOI:
10.1021/ja00228a018
PDF
Inversion of the oxiranyl radical occurs by quantum-mechanical tunneling
S. Deycard, J. Lusztyk, Kieth U. Ingold, F. Zerbetto, M. Z. Zgierski, and W. Siebrand
pp 6721 - 6726; DOI:
10.1021/ja00228a019
PDF
First spectroscopic and absolute kinetic studies on (alkoxycarbonyl)oxyl radicals and an unsuccessful attempt to observe carbamoyloxyl radicals
J. Chateauneuf, J. Lusztyk, B. Maillard, and Kieth U. Ingold
pp 6727 - 6731; DOI:
10.1021/ja00228a020
PDF
Nearly linear rhodium(I) aggregates. Chemical and spectroscopic behavior of [Rh3(CNCH3)6{.mu.-(Ph2PCH2)2PPH}2]3+ and its oxidation products
Alan L. Balch, L. Alan Fossett, Jeffrey K. Nagle, and Marilyn M. Olmstead
pp 6732 - 6738; DOI:
10.1021/ja00228a021
PDF
Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activation
Albert L. Casalnuovo, Joseph C. Calabrese, and David Milstein
pp 6738 - 6744; DOI:
10.1021/ja00228a022
PDF
Mechanism of the oxidation of carbon monoxide by tetrachloroplatinate(2-). An investigation into the nature of the intermediates by isotopic labeling
K. S. Sun and C. H. Cheng
pp 6744 - 6748; DOI:
10.1021/ja00228a023
PDF
Nitrogen atom activation: the influence of porphyrin ring structure on the kinetics of the reaction of trifluoroacetic anhydride with nitrido manganese(V) porphyrins
Lawrence A. Bottomley and Frank L. Neely
pp 6748 - 6752; DOI:
10.1021/ja00228a024
PDF
Synthesis, NMR spectroscopic investigation, and crystal structures of 1,3-dihydro-2.lambda.4-benzotellurole-2,2-diyl bis(diethyldithiocarbamate), C8H8Te[S2CNEt2]2; S,S'-1,3-dihydro-2.lambda.4-benzotellurole-2,2-diyl O,O,O',O'-tetraethyl bis(dithiophosphate), C8H8Te[S2P(OEt)2]2; and 1,3-dihydro-2.lambda.4-benzotellurole-2,2-diyl bis(O-ethyl xanthate), C8H8Te[S2COEt]2
Dainis Dakternieks, Robert Di Giacomo, Robert W. Gable, and Bernard F. Hoskins
pp 6753 - 6761; DOI:
10.1021/ja00228a025
PDF
Synthesis, NMR study, and crystal structures of bis(diethyldithiocarbamato)-(O,O'-diethyl dithiophosphato)phenyltellurium(IV), PhTe(S2CNEt2)2[S2P(OEt)2], and bis(diethyldithiocarbamato)iodomethyltellurium(IV), MeTe(I)(S2CNEt2)2
Dainis Dakternieks, Robert Di Giacomo, Robert W. Gable, and Bernard F. Hoskins
pp 6762 - 6768; DOI:
10.1021/ja00228a026
PDF
Dioxygen-copper reactivity: generation, characterization, and reactivity of a hydroperoxodicopper(II) complex
Kenneth D. Karlin, Phalguni Ghosh, Richard W. Cruse, Amjad Farooq, Yilma Gultneh, Richard R. Jacobson, Ninian J. Blackburn, Richard W. Strange, and Jon Zubieta
pp 6769 - 6780; DOI:
10.1021/ja00228a027
PDF
Cobalt(II)-facilitated transport of dioxygen in a polystyrene membrane
M. J. Barnes, R. S. Drago, and K. J. Balkus
pp 6780 - 6785; DOI:
10.1021/ja00228a028
PDF
Some thermal and photochemical reactions of [4.4.4.5]fenestranes
Steven Wolff, Bhaskar Rao Venepalli, Clifford F. George, and William C. Agosta
pp 6785 - 6790; DOI:
10.1021/ja00228a029
PDF
Two triplets mediating intramolecular photochemical abstraction of hydrogen by nitrogen in 4-acyl-6-alkylpyrimidines
Martha A. Brumfield and William C. Agosta
pp 6790 - 6794; DOI:
10.1021/ja00228a030
PDF
Fast hydrolysis of an aliphatic amide at neutral pH and ambient temperature. A peptidase model
F. M. Menger and M. Ladika
pp 6794 - 6796; DOI:
10.1021/ja00228a031
PDF
Chain-substituted lipids in monolayer films. A study of molecular packing
F. M. Menger, M. G. Wood, S. Richardson, Q. Zhou, A. R. Elrington, and M. J. Sherrod
pp 6797 - 6803; DOI:
10.1021/ja00228a032
PDF
Thermotropic properties of synthetic chain-substituted phosphatidylcholines: effect of substituent size, polarity, number, and location on molecular packing in bilayers
F. M. Menger, M. G. Wood, Q. Z. Zhou, H. P. Hopkins, and J. Fumero
pp 6804 - 6810; DOI:
10.1021/ja00228a033
PDF
A series of calix[4]arenes, having two opposite para positions connected by an aliphatic chain
Helmut Goldmann, Walter Vogt, Erich Paulus, and Volker Boehmer
pp 6811 - 6817; DOI:
10.1021/ja00228a034
PDF
Screw sense selective polymerization of achiral isocyanides catalyzed by optically active nickel(II) complexes
Paul C. J. Kamer, Roeland J. M. Nolte, and Wiendelt Drenth
pp 6818 - 6825; DOI:
10.1021/ja00228a035
PDF
"Hydrophobic" binding of water-soluble guests by high-symmetry, chiral hosts. An electron-rich receptor site with a general affinity for quaternary ammonium compounds and electron-deficient .pi. systems
Michael A. Petti, Timothy J. Shepodd, Richard E. Barrans, and Dennis A. Dougherty
pp 6825 - 6840; DOI:
10.1021/ja00228a036
PDF
A macrocyclic tetraether bolaamphiphile and an oligoamino .alpha.,.omega.-dicarboxylate combine to form monolayered, porous vesicle membranes, which are reversibly sealed by EDTA and other bulky anions
Juergen Hinrich Fuhrhop, Ulrich Liman, and Volker Koesling
pp 6840 - 6845; DOI:
10.1021/ja00228a037
PDF
A fresh look at electron transfer in the reactions of Grignard reagents
Cheves Walling
pp 6846 - 6850; DOI:
10.1021/ja00228a038
PDF
Evidence from isotope labeling studies for a sequential mechanism for dissimilatory nitrite reduction
Els Weeg-Aerssens, James M. Tiedje, and Bruce A. Averill
pp 6851 - 6856; DOI:
10.1021/ja00228a039
PDF
Comparison of the metal ion coordinating properties of tubercidin 5'-monophosphate (7-deaza-AMP) with those of adenosine 5'-monophosphate (AMP) and 1,N6-ethenoadenosine 5'-monophosphate (.epsilon.-AMP). Definite evidence for metal ion-base-backbinding to N-7 and extent of macrochelate formation in M(AMP) and M(.epsilon.-AMP)
Helmut Sigel, Salah S. Massoud, and Roger Tribolet
pp 6857 - 6865; DOI:
10.1021/ja00228a040
PDF
Trichodiene biosynthesis and the role of nerolidyl pyrophosphate in the enzymic cyclization of farnesyl pyrophosphate
David E. Cane and Hyun Joon Ha
pp 6865 - 6870; DOI:
10.1021/ja00228a041
PDF
Molecular pathways in the cyclotrimerization of ethyne on palladium: role of the C4 intermediate
Charles H. Patterson and Richard M. Lambert
pp 6871 - 6877; DOI:
10.1021/ja00228a042
PDF
Isolation and x-ray crystal structure of the first dinitrogen complex of an f-element metal, [(C5Me5)2Sm]2N2
William J. Evans, Tamara A. Ulibarri, and Joseph W. Ziller
pp 6877 - 6879; DOI:
10.1021/ja00228a043
PDF
.beta.-Lactams from ester enolates and silylimines. Enantioselective synthesis of (+)-PS-5
Gianfranco Cainelli, Mauro Panunzio, Daria Giacomini, Giorgio Martelli, and Giuseppe Spunta
pp 6879 - 6880; DOI:
10.1021/ja00228a044
PDF
Basic polypeptides accelerate the hydrolysis of ribonucleic acids
Bernard Barbier and Andre Brack
pp 6880 - 6882; DOI:
10.1021/ja00228a045
PDF
Kinetic and thermodynamic studies on the reaction of oxygen with two dinuclear copper(I) complexes
Richard W. Cruse, Susan Kaderli, Kenneth D. Karlin, and Andreas D. Zuberbuehler
pp 6882 - 6883; DOI:
10.1021/ja00228a046
PDF
Formation of complexed nitrosamines by oxidation of coordinated ammonia in the presence of secondary amines
Matthew T. Stershic, Larry K. Keefer, B. Patrick Sullivan, and Thomas J. Meyer
pp 6884 - 6885; DOI:
10.1021/ja00228a047
PDF
One dimensional nuclear Overhauser effect with two dimensional heteronuclear multiple quantum coherence detection: proton-proton nitrogen-15 correlation in T4 lysozyme
David F. Lowry, Alfred G. Redfield, Lawrence P. McIntosh, and Frederick W. Dahlquist
pp 6885 - 6886; DOI:
10.1021/ja00228a048
PDF
Lewis basicity of the "noncoordinating" common solvent 1,2-dichloroethane: strong RCl.fwdarw.silver bonding in AgOTeF5(1,2-C2H4Cl2)+
Mark R. Colsman, Mark D. Noirot, M. M. Miller, Oren P. Anderson, and Steven H. Strauss
pp 6886 - 6888; DOI:
10.1021/ja00228a049
PDF
The Al(2P){SiH4} complex and the photoreversible oxidative addition/reductive-elimination reaction: Al(2P){SiH4} .dblarw. H3SiAlH
Michael A. Lefcourt and Geoffrey A. Ozin
pp 6888 - 6890; DOI:
10.1021/ja00228a050
PDF
Concise route to the calichemicin-esperamicin series: the crystal structure of an aglycone prototype
Samuel J. Danishefsky, Nathan B. Mantlo, Dennis S. Yamashita, and Gayle Schulte
pp 6890 - 6891; DOI:
10.1021/ja00228a051
PDF
Dependence of disulfide vibrational frequencies on internal rotation geometry: an ab initio and normal mode study of dimethyl disulfide
W. Zhao, J. Bandekar, and Samuel Krimm
pp 6891 - 6892; DOI:
10.1021/ja00228a052
PDF
The enzymatic Baeyer-Villiger oxidation: enantioselective synthesis of lactones from mesomeric cyclohexanones
Michael J. Taschner and Donald J. Black
pp 6892 - 6893; DOI:
10.1021/ja00228a053
PDF
Reversible metal-metal bond cleavage accompanied by the facile reversible addition of hydrogen to a Ru3 cluster. Synthesis and x-ray structures of Ru3(CO)8(.mu.-H)2(.mu.-tert-Bu2P)2 and Ru3(CO)8(.mu.-H)2(H)2(.mu.-tert-Bu2P)2
Atta M. Arif, Theresa A. Bright, Richard A. Jones, and Christine M. Nunn
pp 6894 - 6895; DOI:
10.1021/ja00228a054
PDF
Biosynthesis of marine lipids. 19. Dealkylation of the sterol side chain in sponges
Sohail Malik, Russell G. Kerr, and Carl Djerassi
pp 6895 - 6897; DOI:
10.1021/ja00228a055
PDF
Internal electron transfer in a quinone adduct of a nickel(II)-catecholate complex
Cristiano Benelli, Andrea Dei, Dante Gatteschi, and Luca Pardi
pp 6897 - 6898; DOI:
10.1021/ja00228a056
PDF
Modeling the dinuclear sites of iron biomolecules: synthesis and properties of Fe2O(OAc)2Cl2(bipy)2 and its use as an alkane activation catalyst
John B. Vincent, John C. Huffman, G. Christou, Qiaoying Li, Mark A. Nanny, David N. Hendrickson, Raymond H. Fong, and Richard H. Fish
pp 6898 - 6900; DOI:
10.1021/ja00228a057
PDF
Novel type of selectivity in anionotropic rearrangements
Vittorio Lucchini, Giorgio Modena, and Lucia Pasquato
pp 6900 - 6901; DOI:
10.1021/ja00228a058
PDF
Viable geometries for T1-S0ISC in alkene triplets
Richard A. Caldwell, L. Carlacci, C. E. Doubleday, T. R. Furlani, H. F. King, and J. W. McIver
pp 6901 - 6903; DOI:
10.1021/ja00228a059
PDF
Transition metal based reagents for molecular recognition: hydrogen bonding properties of tungsten(II) cis-amino halides
Carolyn E. Osterberg, Atta M. Arif, and Thomas G. Richmond
pp 6903 - 6904; DOI:
10.1021/ja00228a060
PDF
Photochemical activation of carbon dioxide. Transient absorbance kinetic studies of the addition of carbon dioxide to a metal-to-bridging ligand charge-transfer state of a binuclear nickel(0) complex
Frederick R. Lemke, Dru L. DeLaet, Jiali Gao, and Clifford P. Kubiak
pp 6904 - 6906; DOI:
10.1021/ja00228a061
PDF
Transition state geometry in epoxidation by iron-oxo porphyrin at the compound I oxidation level. Epoxidation of alkenes catalyzed by a sterically hindered meso-tetrakis(2,6-dibromophenyl)porphinato iron(III) chloride
Drazen Ostovic and Thomas C. Bruice
pp 6906 - 6908; DOI:
10.1021/ja00228a062
PDF
Photo-Arbuzov rearrangements of benzyl phosphites
Jan Omelanzcuk, Alan E. Sopchik, Sueg Geun Lee, Kunihiko Akutagawa, S. Matthew Cairns, and Wesley G. Bentrude
pp 6908 - 6909; DOI:
10.1021/ja00228a063
PDF
Synthesis of (R)-(+)- and (S)-(-)-.alpha.-damascone by tandem Grignard reaction-enantioselective protonation: evidence for the intermediacy of a chiral complex
Charles Fehr and Jose Galindo
pp 6909 - 6911; DOI:
10.1021/ja00228a064
PDF
Allylic radicals in cyclization reactions
Gilbert Stork and Mark E. Reynolds
pp 6911 - 6913; DOI:
10.1021/ja00228a065
PDF
Nanosecond laser flash photolytic generation and lifetimes in solvolytic media of diarylmethyl and p-methoxyphenethyl cations
Robert A. McClelland, V. M. Kanagasabapathy, and Steen Steenken
pp 6913 - 6914; DOI:
10.1021/ja00228a066
PDF
Total synthesis of both (+)-compactin and (+)-mevinolin. A general strategy based on the use of a special TiCl3/C8K mixture for dicarbonyl coupling
Derrick L. J. Clive, K. S. Keshava Murthy, Andrew G. H. Wee, J. Siva Prasad, Gil V. J. Da Silva, Marek Majewski, Paul C. Anderson, Richard D. Haugen, and Louis D. Heerze
pp 6914 - 6916; DOI:
10.1021/ja00228a067
PDF
Rhodium(I)-catalyzed hydroboration of olefins. The documentation of regio- and stereochemical control in cyclic and acyclic systems
David A. Evans, Gregory C. Fu, and Amir H. Hoveyda
pp 6917 - 6918; DOI:
10.1021/ja00228a068
PDF
The preparation and structure of a dinuclear .eta.2-H2 complex (P-N)(.eta.2-H2)Ru(.mu.-Cl)2(.mu.-H)Ru(H)(PPh3)2, P-N = Fe[.eta.-C5H3(CHMeNMe2){P(iso-Pr)2}-1,2](.eta.-C5H5)
Cashman Hampton, William R. Cullen, Brian R. James, and Jean Pierre Charland
pp 6918 - 6919; DOI:
10.1021/ja00228a069
PDF
Biosynthesis of pyrroloquinoline quinone. 1. Identification of biosynthetic precursors using carbon-13 labeling and NMR spectroscopy
David R. Houck, John L. Hanners, and Clifford J. Unkefer
pp 6920 - 6921; DOI:
10.1021/ja00228a070
PDF
Synthesis of a remarkably stable bicyclo[7.3.1]diynene esperamicin A1/calicheamicin .gamma. system. Structural requirements for facile formation of a 1,4-diyl
Philip Magnus, Richard T. Lewis, and John C. Huffman
pp 6921 - 6923; DOI:
10.1021/ja00228a071
PDF
Oxygen-17 and molybdenum-95 coupling in spectroscopic models of molybdoenzymes
Graham L. Wilson, Michael Kony, Edward R. T. Tiekink, John R. Pilbrow, Jack T. Spence, and Anthony G. Wedd
pp 6923 - 6925; DOI:
10.1021/ja00228a072
PDF
X-ray structure determination of [1-cyano-2,.2-dimtheylcyclopropyllithium.cntdot.tetrahydrofuran].infin.: a tetrahedral anionic .alpha.-cyano carbon atom
Gernot Boche, Klaus Harms, and Michael Marsch
pp 6925 - 6926; DOI:
10.1021/ja00228a073
PDF
Effect of long-distance electron transfer on chemiluminescence efficiencies [Erratum to document cited in CA108(21):186021j]
Robert D. Mussell and Daniel G. Nocera
pp 6926 - 6926; DOI:
10.1021/ja00228a074
PDF
Synthesis and reactivity of binuclear tropocoronand and related organocopper(I) complexes. Catalytic enantioselective conjugate addition of Grignard reagents to 2-cyclohexen-1-one [Erratum to document cited in CA108(21):186196v]
Gilberto M. Villacorta, C. Pulla Rao, and Stephen J. Lippard
pp 6926 - 6926; DOI:
10.1021/ja00228a075
PDF
A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2} [Erratum to document cited in CA109(9):73587a]
Adam K. List, Gregory L. Hillhouse, and Arnold L. Rheingold
pp 6926 - 6926; DOI:
10.1021/ja00228a076
PDF
Book Reviews

pp 6927 - 6930; DOI:
10.1021/ja00228a600
PDF

Issue 21


Linkage position in oligosaccharides by fast atom bombardment ionization, collision-activated dissociation, tandem mass spectrometry and molecular modeling. L-Fucosylp-(.alpha.1.fwdarw.X)-D-N-acetyl-D-glucosaminylp-(.beta.1.fwdarw.3)-D-galactosylp-(.beta.1-O-methyl) where X = 3, 4, or 6
Roger A. Laine, Krishna M. Pamidimukkala, Alfred D. French, Randall W. Hall, Saeed A. Abbas, Rakesh K. Jain, and Khushi L. Matta
pp 6931 - 6939; DOI:
10.1021/ja00229a001
PDF
Adsorption and decomposition of dimethyl methylphosphonate on platinum(111).
Michael A. Henderson and J. M. White
pp 6939 - 6947; DOI:
10.1021/ja00229a002
PDF
Molecular orbital approach to substituent effects in amine-CO2 interactions
A. K. Chakraborty, K. B. Bischoff, G. Astarita, and J. R. Damewood
pp 6947 - 6954; DOI:
10.1021/ja00229a003
PDF
On the dynamic character of "ordered" structure in polymer latex suspensions
K. Ito, H. Nakamura, H. Yoshida, and Norio Ise
pp 6955 - 6963; DOI:
10.1021/ja00229a004
PDF
Application of photoelectron spectroscopy to molecular properties. Part 34. Phosphaethene. Synthesis by vacuum gas-solid reaction (VGSR) and characterization by photoelectron spectroscopy
Sylvie Lacombe, Danielle Gonbeau, Jean Luc Cabioch, Bruno Pellerin, Jean Marc Denis, and Genevieve Pfister-Guillouzo
pp 6964 - 6967; DOI:
10.1021/ja00229a005
PDF
Infrared vibrational circular dichroism of alanine in the mid-infrared region: isotopic effects
Max Diem
pp 6967 - 6970; DOI:
10.1021/ja00229a006
PDF
Vibrational circular dichroism in the methine bending modes of amino acids and dipeptides
Teresa B. Freedman, Anita C. Chernovitz, William M. Zuk, M. Germana Paterlini, and Laurence A. Nafie
pp 6970 - 6974; DOI:
10.1021/ja00229a007
PDF
Principal component-three component self-modeling analysis applied to trans-1,2-di(2-naphthyl)ethene fluorescence
Ya Ping Sun, Donald F. Sears, Jack Saltiel, Frank B. Mallory, Clelia W. Mallory, and Carolyn A. Buser
pp 6974 - 6984; DOI:
10.1021/ja00229a008
PDF
Many-body potential for molecular interactions
Allison E. Howard, U. Chandra Singh, Martin Billeter, and Peter A. Kollman
pp 6984 - 6991; DOI:
10.1021/ja00229a009
PDF
Molecular dynamics study of ion capture from water by a model ionophore, tetraprotonated cryptand SC24
Brian Owenson, Robert D. MacElroy, and Andrew Pohorille
pp 6992 - 7000; DOI:
10.1021/ja00229a010
PDF
Theoretical studies of the structure of the benzene-hydrogen fluoride complex
J. L. Bredas and G. B. Street
pp 7001 - 7005; DOI:
10.1021/ja00229a011
PDF
Electron diffraction and Monte Carlo studies of liquids. 3. Supercooled benzene
Lawrence S. Bartell, Leo R. Sharkey, and Xianqian Shi
pp 7006 - 7013; DOI:
10.1021/ja00229a012
PDF
A solid-state nitrogen-15 CPMAS NMR study of dye tautomerism in glassy polystyrene: site dependence of double minimum potentials and their motional averaging
Bernd Wehrle, Herbert Zimmermann, and Hans Heinrich Limbach
pp 7014 - 7024; DOI:
10.1021/ja00229a013
PDF
Cobalt-59 NMR of cobalt(III) porphyrin complexes. 2. Electric field gradients, d-orbital populations, and hydrogen bonding
Karen I. Hagen, Catherine M. Schwab, John O. Edwards, John G. Jones, Ronald G. Lawler, and Dwight A. Sweigart
pp 7024 - 7031; DOI:
10.1021/ja00229a014
PDF
Estimation of the hydrogen-hydrogen distances of .eta.2-dihydrogen ligands in the complexes trans-[M(.eta.2-H2)(H)(PR2CH2CH2PR2)2]+ [M = iron, ruthenium, R = Ph, M = osmium, R = Et] by solution NMR methods
Maria T. Bautista, Kelly A. Earl, Patricia A. Maltby, Robert H. Morris, Caroline T. Schweitzer, and Andrea Sella
pp 7031 - 7036; DOI:
10.1021/ja00229a015
PDF
Optical determination of magnetization behavior: a study of unstable metallocenes by magnetic circular dichroism
Robin G. Graham, Roger Grinter, and Robin N. Perutz
pp 7036 - 7042; DOI:
10.1021/ja00229a016
PDF
Stacked complexes of iridium and a novel form of charge compensation
Paul G. Rasmussen, J. Bruce Kolowich, and Juan Carlos Bayon
pp 7042 - 7049; DOI:
10.1021/ja00229a017
PDF
Generation and characterization of highly reactive oxo-transfer intermediates and related species derived from (tetraarylporphinato)manganese(III) complexes
Kenton R. Rodgers and Harold M. Goff
pp 7049 - 7060; DOI:
10.1021/ja00229a018
PDF
Organotin clusters. 4. Cubic, butterfly, and oxygen-capped clusters of n-butyloxotin phosphinates. A new class of organotin compounds
Robert R. Holmes, K. C. Kumara Swamy, Charles G. Schmid, and Roberta O. Day
pp 7060 - 7066; DOI:
10.1021/ja00229a019
PDF
Organotin clusters. 5. Crown and extended organooxotin compounds formed with phosphinate ligands. A new class of tetranuclear tin clusters
K. C. Kumara Swamy, Charles G. Schmid, Roberta O. Day, and Robert R. Holmes
pp 7067 - 7076; DOI:
10.1021/ja00229a020
PDF
Experimental and theoretical studies of the copper(I) and silver(I) dinuclear N,N'-di-p-tolylformamidinato complexes
F. Albert Cotton, Xuejun Feng, Marek Matusz, and Rinaldo Poli
pp 7077 - 7083; DOI:
10.1021/ja00229a021
PDF
Trinuclear, mixed Pt2Pd-1-methyluracil and -1-methylthymine blues with +2.33 average metal oxidation state. Preparation, crystal structures, and solution studies
Wolfgang Micklitz, Gerhard Mueller, Brigitte Huber, Juergen Riede, Farouk Rashwan, Juergen Heinze, and Bernhard Lippert
pp 7084 - 7092; DOI:
10.1021/ja00229a022
PDF
Pentadienyl ligands in cluster complexes. Synthesis and structural characterization of Ru5(CO)12(.mu.4-S)(.mu.-H)(.mu.-1,5-Me2C5H5) and Ru6(CO)15(.mu.4-S)(.mu.-H)(.mu.-1,5-Me2C5H5)
Richard D. Adams, J. E. Babin, M. Tasi, and T. A. Wolfe
pp 7093 - 7097; DOI:
10.1021/ja00229a023
PDF
Synthesis, x-ray structural analysis, and thermal decomposition of the platinum(II) carboxylic acid (hydroxycarbonyl) trans-Pt(CO2H)(C6H5)(PEt3)2. Formation of a diplatinum(II) complex containing carbon dioxide
Martin A. Bennett, Glen B. Robertson, Andrzej Rokicki, and Wasantha A. Wickramasinghe
pp 7098 - 7105; DOI:
10.1021/ja00229a024
PDF
Photochemical reactions of diiron .mu.-alkenylidene complexes with hydrogen, trialkylsilanes, and diazo compounds: cleavage to alkenes, vinylsilanes and allenes
Charles P. Casey and Edwin A. Austin
pp 7106 - 7113; DOI:
10.1021/ja00229a025
PDF
Preparation, characterization, and intramolecular rate constant for ruthenium(II) .fwdarw. iron(II) electron transfer in the pentaammineruthenium histidine modified cytochrome c551 from Pseudomonas stutzeri
Peter Osvath, G. Arthur Salmon, and A. Geoffrey Sykes
pp 7114 - 7118; DOI:
10.1021/ja00229a026
PDF
Conformations of saturated six-membered ring phosphorus heterocycles. 2-Aryl-1,3,2-.lambda.5-oxazaphosphorinanes
Wesley G. Bentrude, William N. Setzer, Alan E. Sopchik, Subramanian Chandrasekaran, and Michael T. Ashby
pp 7119 - 7127; DOI:
10.1021/ja00229a027
PDF
Stereoselective cyclization of enynes mediated by metallocene reagents
T. V. RajanBabu, William A. Nugent, Douglass F. Taber, and Paul J. Fagan
pp 7128 - 7135; DOI:
10.1021/ja00229a028
PDF
The mechanism of trimerization of bicyclo[2.2.2]alkynes
Khalil Shahlai and Harold Hart
pp 7136 - 7140; DOI:
10.1021/ja00229a029
PDF
Allosteric cooperativity and transport: studies in a circulating system
F. Gavina, S. V. Luis, A. M. Costero, M. I. Burguete, and J. Rebek
pp 7140 - 7143; DOI:
10.1021/ja00229a030
PDF
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities
N. Soundararajan, Matthew S. Platz, James E. Jackson, Michael P. Doyle, Su Min Oon, Michael T. H. Liu, and Surinder M. Anand
pp 7143 - 7152; DOI:
10.1021/ja00229a031
PDF
Claisen rearrangement of allyl phenyl ether: heavy-atom kinetic isotope effects and bond orders in the transition structure
Lidia Kupczyk-Subotkowska, William H. Saunders, and Henry J. Shine
pp 7153 - 7159; DOI:
10.1021/ja00229a032
PDF
Synthesis of CMP-NeuAc from N-acetylglucosamine: generation of CTP from CMP using adenylate kinase
Ethan S. Simon, Mark D. Bednarski, and George M. Whitesides
pp 7159 - 7163; DOI:
10.1021/ja00229a033
PDF
Photophysics, photochemistry, and theoretical calculations of some benz[a]anthracene-3,4-diones and their significance
Ralph S. Becker, L. V. Natarajan, Christian Lenoble, and Ronald G. Harvey
pp 7163 - 7167; DOI:
10.1021/ja00229a034
PDF
Chemistry of singlet oxygen. 51. Zwitterionic intermediates from 2,4-hexadienes
Kevin E. O'Shea and Christopher S. Foote
pp 7167 - 7170; DOI:
10.1021/ja00229a035
PDF
Photolabile 1-(2-nitrophenyl)ethyl phosphate esters of adenine nucleotide analogs. Synthesis and mechanism of photolysis
Jeffery W. Walker, Gordon P. Reid, James A. McCray, and David R. Trentham
pp 7170 - 7177; DOI:
10.1021/ja00229a036
PDF
The oxazoline-benzyne route to 1,2,3-trisubstituted benzenes. Tandem addition of organolithiums, organocuprates, and .alpha.-lithionitriles to benzynes
Paul D. Pansegrau, William F. Rieker, and A. I. Meyers
pp 7178 - 7184; DOI:
10.1021/ja00229a037
PDF
Asymmetric synthesis of functionalized cyclopropanes via .beta.-lithiation-cyclization of N-monosubstituted 3-(phenylthio)-2-[(phenylthio)methyl]propanamides
Kazuhiko Tanaka, Ikuo Funaki, Aritsune Kaji, Keizaburo Minami, Masami Sawada, and Takanori Tanaka
pp 7185 - 7188; DOI:
10.1021/ja00229a038
PDF
Five-membered aromatic heterocycles as dienophiles in Diels-Alder reactions. Furan, pyrrole, and indole
Ernest Wenkert, Peter D. R. Moeller, and Serge R. Piettre
pp 7188 - 7194; DOI:
10.1021/ja00229a039
PDF
OH- versus SH- nucleophilic attack on amides: dramatically different gas-phase and solvation energetics
Allison E. Howard and Peter A. Kollman
pp 7195 - 7200; DOI:
10.1021/ja00229a040
PDF
Lipase-catalyzed irreversible transesterifications using enol esters as acylating reagents: preparative enantio- and regioselective syntheses of alcohols, glycerol derivatives, sugars and organometallics
Yi Fong Wang, James J. Lalonde, Milagros Momongan, David E. Bergbreiter, and Chi Huey Wong
pp 7200 - 7205; DOI:
10.1021/ja00229a041
PDF
Dynamics of proton translocation in the primary process of vision
Oscar J. Riveros and D. J. Diestler
pp 7206 - 7208; DOI:
10.1021/ja00229a042
PDF
Poly-1,2-azepines by the photopolymerization of phenyl azides. Precursors for conducting polymer films
E. W. Meijer, S. Nijhuis, and F. C. B. M. Van Vroonhoven
pp 7209 - 7210; DOI:
10.1021/ja00229a043
PDF
Ruthenium(II)-polypyridine cage complexes: luminescence and photochemical properties
Luisa De Cola, Francesco Barigelletti, Vincenzo Balzani, Peter Belser, Alex Von Zelewsky, Fritz Voegtle, Frank Ebmeyer, and Smaragda Grammenudi
pp 7210 - 7212; DOI:
10.1021/ja00229a044
PDF
Stereochemical assignment of neocarzinostatin chromophore. Structures of neocarzinostatin chromophore-methyl thioglycolate adducts
Andrew G. Myers, Philip J. Proteau, and Tracy M. Handel
pp 7212 - 7214; DOI:
10.1021/ja00229a045
PDF
NMR determination of association constants for calixarene complexes. Evidence for the formation of a 1:2 complex with calix[8]arene
Seiji Shinkai, Koji Araki, and Osamu Manabe
pp 7214 - 7215; DOI:
10.1021/ja00229a046
PDF
Oxygen-atom transfer from nitrous oxide. Synthesis and structure of a zirconocene oxametallacyclobutene complex
G. Alan Vaughan, Gregory L. Hillhouse, Robert T. Lum, Stephen L. Buchwald, and Arnold L. Rheingold
pp 7215 - 7217; DOI:
10.1021/ja00229a047
PDF
Synthesis of (-)-oxetanocin
Daniel W. Norbeck and James B. Kramer
pp 7217 - 7218; DOI:
10.1021/ja00229a048
PDF
The structure of 1,4-cyclohexadiene at 153 K
George A. Jeffrey, Juergen Buschmann, Christian W. Lehmann, and Peter Luger
pp 7218 - 7219; DOI:
10.1021/ja00229a049
PDF
Achieving high quantum yield charge separation in porphyrin-containing donor-acceptor molecules at 10 K
Michael R. Wasielewski, Douglas G. Johnson, Walter A. Svec, Kristin M. Kersey, and David W. Minsek
pp 7219 - 7221; DOI:
10.1021/ja00229a050
PDF
Solid-state NMR detection of proton exchange between the bacteriorhodopsin Schiff base and bulk water
Gerard S. Harbison, James E. Roberts, Judith Herzfeld, and Robert G. Griffin
pp 7221 - 7223; DOI:
10.1021/ja00229a051
PDF
FTIR evidence for tryptophan perturbations during the bacteriorhodopsin photocycle
P. Roepe, D. Gray, J. Lugtenburg, E. M. M. Van den Berg, J. Herzfeld, and K. J. Rothschild
pp 7223 - 7224; DOI:
10.1021/ja00229a052
PDF
Evidence for a cyclic form of the azide anion
Rujiang Tian, V. Balaji, and Josef Michl
pp 7225 - 7226; DOI:
10.1021/ja00229a053
PDF
Structure and reactivity of novel lithium di-tert-butylphosphido(alkyl)cuprates
Stephen F. Martin, Jeffrey R. Fishpaugh, John M. Power, Dean M. Giolando, Richard A. Jones, Christine M. Nunn, and Alan H. Cowley
pp 7226 - 7228; DOI:
10.1021/ja00229a054
PDF
The reactions of diorganosilylenes with carbon monoxide
Mary Ann Pearsall and Robert West
pp 7228 - 7229; DOI:
10.1021/ja00229a055
PDF
Synthesis of homocub-4(5)-ene: confirmation of a computational prediction
David A. Hrovat and Weston Thatcher Borden
pp 7229 - 7230; DOI:
10.1021/ja00229a056
PDF
Cubene (1,2-dehydrocubane)
Philip E. Eaton and Michele Maggini
pp 7230 - 7232; DOI:
10.1021/ja00229a057
PDF
X-ray structures of cubylcubane and 2-tert-butylcubylcubane: short cage-cage bonds
Richard Gilardi, Michele Maggini, and Philip E. Eaton
pp 7232 - 7234; DOI:
10.1021/ja00229a058
PDF
New developments in cubane chemistry: phenylcubanes
A. Bashir-Hashemi
pp 7234 - 7235; DOI:
10.1021/ja00229a059
PDF
Oxidative ring expansion of 1-(tert-butylamino)indolines to 1,4-dihydrocinnolines. Novel neophyl rearrangement of hydrazyl radicals
S. F. Wang, L. Mathew, and J. Warkentin
pp 7235 - 7236; DOI:
10.1021/ja00229a060
PDF
Control of enzyme enantioselectivity by the reaction medium
Takayasu Sakurai, Alexey L. Margolin, Alan J. Russell, and Alexander M. Klibanov
pp 7236 - 7237; DOI:
10.1021/ja00229a061
PDF
Nucleophilic substitution within the photoionized van der Waals complex: generation of C6H5NH3+ from C6H5Cl-NH3
Toshihiko Maeyama and Naohiko Mikami
pp 7238 - 7239; DOI:
10.1021/ja00229a062
PDF
Reductive coupling of nitriles via formal [2 + 2] cycloadditions to the titanium-carbon double bond
Kenneth M. Doxsee and Judah B. Farahi
pp 7239 - 7240; DOI:
10.1021/ja00229a063
PDF
The gas phase displacement reaction of chloride ion with methyl chloride as a function of kinetic energy
Stephan E. Barlow, Jane M. Van Doren, and Veronica M. Bierbaum
pp 7240 - 7242; DOI:
10.1021/ja00229a064
PDF
Electron-transfer reactions in the Marcus inverted region: differences in solvation and electronic coupling between excited charge-transfer complexes and geminate radical ion pairs
Ian R. Gould, Roger Moody, and Samir Farid
pp 7242 - 7244; DOI:
10.1021/ja00229a065
PDF
Homoaromaticity in a cyclic polyacetylene
Lawrence T. Scott, Mark J. Cooney, Donald W. Rogers, and Kosol Dejroongruang
pp 7244 - 7245; DOI:
10.1021/ja00229a066
PDF
A novel asymmetric synthesis of substituted cyclopropanes
Albert I. Meyers, Jeffrey L. Romine, and Steven A. Fleming
pp 7245 - 7247; DOI:
10.1021/ja00229a067
PDF
DNA cleavage by a synthetic mimic of the calicheamicin-esperamicin class of antibiotics
K. C. Nicolaou, Y. Ogawa, G. Zuccarello, and H. Kataoka
pp 7247 - 7248; DOI:
10.1021/ja00229a068
PDF
Siastatin B, a potent neuraminidase inhibitor: the total synthesis and absolute configuration
Yoshio Nishimura, Wenmei Wang, Shinichi Kondo, Takaaki Aoyagi, and Hamao Umezawa
pp 7249 - 7250; DOI:
10.1021/ja00229a069
PDF
Observation and substituent control of medium-dependent hot-molecule reactions in low-temperature matrixes
Brian F. LeBlanc and Robert S. Sheridan
pp 7250 - 7252; DOI:
10.1021/ja00229a070
PDF
Counterattack reagent hexamethyldisilane in the direct conversion of aldehydes, ketones, and allyl alcohols to allyltrimethylsilanes
Jih Ru Hwu, Lung Ching Lin, and Ben Ruey Liaw
pp 7252 - 7254; DOI:
10.1021/ja00229a071
PDF
Electronic properties and redox conduction of ferrocene-substituted high polymeric phosphazenes
Reginaldo A. Saraceno, Geoffrey H. Riding, Harry R. Allcock, and Andrew G. Ewing
pp 7254 - 7255; DOI:
10.1021/ja00229a072
PDF
A catalytic reductive cyclization of 1,6-diynes
Barry M. Trost and Donna C. Lee
pp 7255 - 7258; DOI:
10.1021/ja00229a073
PDF
Polymerization of .alpha.,.alpha.'-bis(dialkylsulfonio)-p-xylene dihalides via p-xylylene intermediates: evidence for a nonradical mechanism
Paul M. Lahti, David A. Modarelli, Frank R. Denton, Robert W. Lenz, and Frank E. Karasz
pp 7258 - 7259; DOI:
10.1021/ja00229a074
PDF
Table of marks and double cosets in isomer counting [Erratum to document cited in CA106(16):126207y]
C. Alden Mead
pp 7260 - 7260; DOI:
10.1021/ja00229a075
PDF
Magnetic and spectroscopic characterization of an iron porphyrin peroxide complex. Peroxoferrioctaethylporphyrin(1-) [Erratum to document cited in CA108(12):105249q]
Judith N. Burstyn, James A. Roe, Andrew R. Miksztal, Ben A. Shaevitz, George Lang, and Joan Selverstone Valentine
pp 7260 - 7260; DOI:
10.1021/ja00229a076
PDF
Transition structures of aldol reactions [Erratum to document cited in CA109(7):54051e]
Yi Li, Michael N. Paddon-Row, and K. N. Houk
pp 7260 - 7260; DOI:
10.1021/ja00229a077
PDF
Computer Software Reviews

pp 7260 - 7261; DOI:
10.1021/ja00229a600
PDF
Book Reviews

pp 7262 - 7268; DOI:
10.1021/ja00229a601
PDF

Issue 22


Stereodynamics of N-ethyl-N-methyl-2-aminobutane
Charles T. Danehey, Gilbert L. Grady, Philippe R. Bonneau, and C. Hackett Bushweller
pp 7269 - 7279; DOI:
10.1021/ja00230a001
PDF
Intermolecular electronic interactions in the primary charge separation in bacterial photosynthesis
M. Plato, K. Moebius, M. E. Michel-Beyerle, M. Bixon, and Joshua Jortner
pp 7279 - 7285; DOI:
10.1021/ja00230a002
PDF
MM2/MOMM force-field parameters for azoalkanes
J. Kao and D. Leister
pp 7286 - 7291; DOI:
10.1021/ja00230a003
PDF
Empirical potential energy surfaces relating structure and activation energy. 2. Determination of transition-state structure for the spontaneous hydrolysis of axial tetrahydropyranyl acetals
Hans Beat Buergi and Katharina C. Dubler-Steudle
pp 7291 - 7299; DOI:
10.1021/ja00230a004
PDF
Sulfur-sulfur bond lengths, or can a bond length be estimated from a single parameter?
Osvald Knop, Russell J. Boyd, and S. C. Choi
pp 7299 - 7301; DOI:
10.1021/ja00230a005
PDF
A reciprocal space approach to the orbitals of truncated crystals
Ralph A. Wheeler, Lucjan Piela, and Roald Hoffmann
pp 7302 - 7315; DOI:
10.1021/ja00230a006
PDF
Trans-edge-sharing molybdenum octahedra: a reciprocal space approach to metal-metal bonding in finite chains
Ralph A. Wheeler and Roald Hoffmann
pp 7315 - 7325; DOI:
10.1021/ja00230a007
PDF
The C4H7+ cation. A theoretical investigation
Wolfram Koch, Bowen Liu, and Douglas J. DeFrees
pp 7325 - 7328; DOI:
10.1021/ja00230a008
PDF
A physical basis for the VSEPR model of molecular geometry
Richard F. W. Bader, Ronald J. Gillespie, and Preston J. MacDougall
pp 7329 - 7336; DOI:
10.1021/ja00230a009
PDF
Relative energies of silaethylene and methylsilylene
Roger S. Grev, Gustavo E. Scuseria, Andrew C. Scheiner, Henry F. Schaefer, and Mark S. Gordon
pp 7337 - 7339; DOI:
10.1021/ja00230a010
PDF
Heats of formation of alkyl radicals from appearance energies
John L. Holmes, F. P. Lossing, and Allan Maccoll
pp 7339 - 7342; DOI:
10.1021/ja00230a011
PDF
Heats of formation and bond dissociation energies in halogen-substituted methyl and ethyl radicals
John L. Holmes and F. P. Lossing
pp 7343 - 7345; DOI:
10.1021/ja00230a012
PDF
Fragmentation of the enolate ions of some cycloalkanones. A comparison of high-energy and low-energy collisional activation
Swapan Chowdhury and Alex G. Harrison
pp 7345 - 7349; DOI:
10.1021/ja00230a013
PDF
Electronic spectroscopy of small tryptophan peptides in supersonic molecular beams
J. R. Cable, Michael J. Tubergen, and Donald H. Levy
pp 7349 - 7355; DOI:
10.1021/ja00230a014
PDF
Nitrogen quadrupole coupling in cyclopentadienyl nickel nitrosyl
S. G. Kukolich, J. V. Rund, D. J. Pauley, and R. E. Bumgarner
pp 7356 - 7357; DOI:
10.1021/ja00230a015
PDF
Multiple electron oxidation of phenols by an oxo complex of ruthenium(IV)
Won K. Seok and Thomas J. Meyer
pp 7358 - 7367; DOI:
10.1021/ja00230a016
PDF
Crystal and molecular structure of cis-[Pt(NH3)2[d(pGpG)]], the principal adduct formed by cis-diamminedichloroplatinum(II) with DNA
Suzanne E. Sherman, Dan Gibson, Andrew H. J. Wang, and Stephen J. Lippard
pp 7368 - 7381; DOI:
10.1021/ja00230a017
PDF
Ruthenium(II) 2,2'-bipyridine complexes containing methyl isocyanide ligands. Extreme effects of nonchromophoric ligands on excited-state properties
Maria Teresa Indelli, Carlo Alberto Bignozzi, Anna Marconi, and Franco Scandola
pp 7381 - 7386; DOI:
10.1021/ja00230a018
PDF
Activation of a metal axial ligand bond in aluminum porphyrin by visible light
Yasuhiro Hirai, Hideki Murayama, Takuzo Aida, and Shohei Inoue
pp 7387 - 7390; DOI:
10.1021/ja00230a019
PDF
Thermochromism in copper(II) halide salts. 4. Bis(diethylammonium)tetrachlorocuprate(II), structure of the high-temperature phase and physical characterization of its two phases
Darrell R. Bloomquist, Mark R. Pressprich, and Roger D. Willett
pp 7391 - 7398; DOI:
10.1021/ja00230a020
PDF
Synthesis, crystal structures, reactivity, and magnetochemistry of a series of binuclear complexes of manganese(II), -(III), and -(IV) of biological relevance. The crystal structure of [L'MnIV(.mu.-O)3MnIVL'](PF6)2.H2O containing an unprecedented short Mn.cntdot..cntdot..cntdot.Mn distance of 2.296 .ANG.
Karl Wieghardt, Ursula Bossek, Bernhard Nuber, Johannes Weiss, J. Bonvoisin, M. Corbella, S. E. Vitols, and J. J. Girerd
pp 7398 - 7411; DOI:
10.1021/ja00230a021
PDF
The dynamics of reaction of a water-soluble and non-.mu.-oxo dimer forming iron(III) porphyrin with tert-butyl hydroperoxide in aqueous solution. 1. Studies using a trap for immediate oxidation products
John R. Lindsay Smith, P. N. Balasubramanian, and Thomas C. Bruice
pp 7411 - 7418; DOI:
10.1021/ja00230a022
PDF
Two regiocomplementary approaches to angular furanocoumarins with chromium carbene complexes: synthesis of sphondin, thiosphondin, heratomin, and angelicin
William D. Wulff, J. Stuart McCallum, and Fen Ann Kunng
pp 7419 - 7434; DOI:
10.1021/ja00230a023
PDF
Total synthesis of octosyl acid A. Intramolecular Williamson reaction via a cyclic stannylene derivative
Samuel J. Danishefsky, Randall Hungate, and Gayle Schulte
pp 7434 - 7440; DOI:
10.1021/ja00230a024
PDF
Kinetics of the anion-catalyzed Michael reaction of silyl ketene acetals. Initiation and propagation steps of group transfer polymerization
William J. Brittain
pp 7440 - 7444; DOI:
10.1021/ja00230a025
PDF
A highly stereocontrolled, four-step synthesis of (.+-.)-lasubine II
Jack D. Brown, Michael A. Foley, and Daniel L. Comins
pp 7445 - 7447; DOI:
10.1021/ja00230a026
PDF
.alpha.-Amino acids as chiral educts for asymmetric products. Alkylation of N-phenylfluorenyl .alpha.-amino ketones. Synthesis of optically pure .alpha.-alkyl carboxylic acids
William D. Lubell and Henry Rapoport
pp 7447 - 7455; DOI:
10.1021/ja00230a027
PDF
H+-induced release of contents of phosphatidylcholine vesicles bearing surface-bound polyelectrolyte chains
Mizuo Maeda, Atsushi Kumano, and David A. Tirrell
pp 7455 - 7459; DOI:
10.1021/ja00230a028
PDF
Nitrogen protonation of N-nitrosodimethylamine
Larry K. Keefer, Joseph A. Hrabie, Bruce D. Hilton, and David Wilbur
pp 7459 - 7462; DOI:
10.1021/ja00230a029
PDF
Permeability characteristics of lipid bilayers from lipoic acid-derived phosphatidylcholines. Comparison of monomeric, crosslinked and noncrosslinked polymerized membranes
James Stefely, Michael A. Markowitz, and Steven L. Regen
pp 7463 - 7469; DOI:
10.1021/ja00230a030
PDF
Does a stilbazolium cation adsorbing poly(styrenesulfonate) anion form micellelike clusters?
Katsuhiko Takagi, Haruhiko Fukaya, and Yasuhiko Sawaki
pp 7469 - 7472; DOI:
10.1021/ja00230a031
PDF
Mechanism of aromatic hydroxylation in the Fenton and related reactions. One-electron oxidation and the NIH shift
Tsunehiko Kurata, Yasumasa Watanabe, Makoto Katoh, and Yasuhiko Sawaki
pp 7472 - 7478; DOI:
10.1021/ja00230a032
PDF
Formation of cyclohexadienyl-type radicals in the photoreduction of xanthone as studied by a laser photolysis-ESR technique
Yoshio Sakaguchi, Hisaharu Hayashi, Hisao Murai, and Yasumasa J. Ihaya
pp 7479 - 7484; DOI:
10.1021/ja00230a033
PDF
Protonation of 1,3,5-triaminobenzenes in aqueous solutions. Thermodynamics and kinetics of the formation of stable .sigma.-complexes
Wilhelm Knoche, Wolfgang W. Schoeller, Reinhard Schomaecker, and Siegmund Vogel
pp 7484 - 7489; DOI:
10.1021/ja00230a034
PDF
Nucleophilic attacks on low LUMO compounds. Part 5. Radical-anionic nature of the transition state in the Michael addition reaction
Zeev Gross and Shmaryahu Hoz
pp 7489 - 7493; DOI:
10.1021/ja00230a035
PDF
Cycloalkylmethyl radicals. 6. The unexpectedly high barrier to the rotation of axial CH2.cntdot. groups in cyclohexylmethyl radicals
L. Hughes, K. U. Ingold, and J. C. Walton
pp 7494 - 7499; DOI:
10.1021/ja00230a036
PDF
Chemical reactivity of the three-sulfur ring in norbornanetrithiolanes. The S3 transfer reaction
Tirthankar Ghosh and Paul D. Bartlett
pp 7499 - 7506; DOI:
10.1021/ja00230a037
PDF
Nucleophilic addition to olefins. Part 23. High intrinsic rate constant and large imbalances in the thiolate ion addition to substituted .alpha.-nitrostilbenes
Claude F. Bernasconi and Robert B. Killion
pp 7506 - 7512; DOI:
10.1021/ja00230a038
PDF
Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 2. Use of the trans-2,trans-3-diphenylcyclopropyl substituent in a search for radical intermediates
Angelo J. Castellino and Thomas C. Bruice
pp 7512 - 7519; DOI:
10.1021/ja00230a039
PDF
Structure-activity relations of (2-chloroethyl)nitrosoureas. 2. Kinetic evidence of a novel mechanism for the cytotoxically important DNA cross-linking reactions of (2-chloroethyl)nitrosoureas
Neil Buckley and Thomas P. Brent
pp 7520 - 7529; DOI:
10.1021/ja00230a040
PDF
Hydrolysis of a peptide bond in neutral water
Daniel Kahne and W. Clark Still
pp 7529 - 7534; DOI:
10.1021/ja00230a041
PDF
Carbon dioxide-laser desorption and multiphoton ionization of tris(2,2'-bipyridyl)ruthenium
Ronald Beavis, Josef Lindner, Juergen Grotemeyer, Ian M. Atkinson, F. Richard Keene, and Alan E. W. Knight
pp 7534 - 7535; DOI:
10.1021/ja00230a042
PDF
Photooxidation of (.eta.5-C5H5)[P(OMe)3]2Mo.tplbond.CPh in CHCl3. Intermediacy of a 17-electron cationic metal carbyne
Carolyn J. Leep, Kevin B. Kingsbury, and Lisa McElwee-White
pp 7535 - 7536; DOI:
10.1021/ja00230a043
PDF
Atom-transfer annulations in heterocycle synthesis. An efficient synthesis of (-)-trachelanthamidine and related ring systems
Ravinder S. Jolly and Tom Livinghouse
pp 7536 - 7538; DOI:
10.1021/ja00230a044
PDF
Vicinal diol cyclic sulfates. Like epoxides only more reactive
Yun Gao and K. Barry Sharpless
pp 7538 - 7539; DOI:
10.1021/ja00230a045
PDF
C-H bond activation in Cp2ZrIIICH2PPh2: evidence for an unexpected mechanistic pathway
Claudine Blandy, Susan A. Locke, Steven J. Young, and Neil E. Schore
pp 7540 - 7542; DOI:
10.1021/ja00230a046
PDF
Catalytic organometallic chemistry in water: the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives
Bruce M. Novak and Robert H. Grubbs
pp 7542 - 7543; DOI:
10.1021/ja00230a047
PDF
A new structural form of tin as a double cube. A heptanuclear tin-sulfur cluster
K. C. Kumara Swamy, Roberta O. Day, and Robert R. Holmes
pp 7543 - 7544; DOI:
10.1021/ja00230a048
PDF
Perforated monolayers: porous and cohesive monolayers from mercurated calix[6]arenes
Michael A. Markowitz, Roman Bielski, and Steven L. Regen
pp 7545 - 7546; DOI:
10.1021/ja00230a049
PDF
The preparation and crystal structures of new platinum/phosphonate complexes
Robert Bau, Sharon K. S. Huang, Jin An Feng, and Charles E. McKenna
pp 7546 - 7547; DOI:
10.1021/ja00230a050
PDF
Synthesis of the transient formyl complex [CH3N(PF2)2]3Co2(CO)(CHO)- and observation of facile formyl decomposition to give the mixed-valence complex [CH3N(PF2)2]3Co2(CO)2.cntdot.-
David S. Dumond and Michael G. Richmond
pp 7547 - 7549; DOI:
10.1021/ja00230a051
PDF
Dioxetane formation at a double bond adjacent to bridgehead nitrogen: rapid reaction between neostrychnine and singlet oxygen in a polar protic medium. Evidence against the intermediacy of an open zwitterion
N. M. Curtis, A. A. Gorman, and A. L. Prescott
pp 7549 - 7550; DOI:
10.1021/ja00230a052
PDF
A new model for the oxygen-evolving complex in photosynthesis. A trinuclear .mu.3-oxomanganese(III) complex which contains a .mu.-peroxo group
Rajumati Bhula, Graeme J. Gainsford, and David C. Weatherburn
pp 7550 - 7552; DOI:
10.1021/ja00230a053
PDF
Effect of pressure on the proton-proton vicinal coupling constants in 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane-1-13C. A new approach to high-pressure study of molecular conformations
H. Yamada, T. Kazuoka, and A. Sera
pp 7552 - 7553; DOI:
10.1021/ja00230a054
PDF
EPR spectral evidence for a dinuclear active site in the Lactobacillus plantarum manganese catalase
Richard M. Fronko, James E. Penner-Hahn, and Christopher J. Bender
pp 7554 - 7555; DOI:
10.1021/ja00230a055
PDF
.pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines
W. Dean Harman and Henry Taube
pp 7555 - 7557; DOI:
10.1021/ja00230a056
PDF
Measurement of 13C relaxation times in proteins by two-dimensional heteronuclear 1H-13C correlation spectroscopy
N. R. Nirmala and Gerhard Wagner
pp 7557 - 7558; DOI:
10.1021/ja00230a057
PDF
Preparation, isolation, and characterization of transition-metal .eta.2-silene complexes. X-ray crystal structure of (.eta.5-C5Me5)[P(iso-Pr)3]Ru(H)(.eta.2-CH2SiPh2)
Brian K. Campion, Richard H. Heyn, and T. Don Tilley
pp 7558 - 7560; DOI:
10.1021/ja00230a058
PDF
Facile stereoselective allylic hydroxylation by dopamine .beta.-monooxygenase
Sarath R. Sirimanne and Sheldon W. May
pp 7560 - 7561; DOI:
10.1021/ja00230a059
PDF
Proton transfer reactions of sulfonium ylides: unit Broensted slopes do not require diffusion-controlled proton transfer
Christopher J. Murray and William P. Jencks
pp 7561 - 7563; DOI:
10.1021/ja00230a060
PDF
Direct observational studies of a singlet alkylcarbene: methylmethoxycarbene, a remarkably selective nucleophile
R. S. Sheridan, R. A. Moss, B. K. Wilk, S. Shen, M. Wlostowski, M. A. Kesselmayer, R. Subramanian, G. Kmiecik-Lawrynowicz, and K. Krogh-Jespersen
pp 7563 - 7564; DOI:
10.1021/ja00230a061
PDF
Synthesis and stabilization of tantalum-coordinated dihydroxyacetylene from two reductively coupled carbon monoxide ligands
Raymond N. Vrtis, C. Pulla Rao, Simon G. Bott, and Stephen J. Lippard
pp 7564 - 7566; DOI:
10.1021/ja00230a062
PDF
Structural and theoretical models of photosynthetic chromophores. Implications for redox, light-absorption properties and vectorial electron flow
K. M. Barkigia, L. Chantranupong, K. M. Smith, and J. Fajer
pp 7566 - 7567; DOI:
10.1021/ja00230a063
PDF
A carotenoid-diporphyrin-quinone model for photosynthetic multistep electron and energy transfer
Devens Gust, Thomas A. Moore, Ana L. Moore, Lewis R. Makings, Gilbert R. Seely, Xiaochun Ma, Todd T. Trier, and Feng Gao
pp 7567 - 7569; DOI:
10.1021/ja00230a064
PDF
2,5,7,7-Tetraphenyl-7-boratabicyclo[4.1.0]hepta-2,4-diene: the first isolation and characterization of a boratanorcaradiene
John D. Wilkey and Gary B. Schuster
pp 7569 - 7571; DOI:
10.1021/ja00230a065
PDF
Free standing polydiacetylene films cast from bilayer membranes
Thauming Kuo and David F. O'Brien
pp 7571 - 7572; DOI:
10.1021/ja00230a066
PDF
Design and chemical synthesis of a sequence-specific DNA-cleaving protein
David P. Mack, Brent L. Iverson, and Peter B. Dervan
pp 7572 - 7574; DOI:
10.1021/ja00230a067
PDF
Ab initio calculations of the geometries and IR spectra of two derivatives of tetramethyleneethane
Yeong Choi, Kenneth D. Jordan, Yi Hyon Paik, Wonghil Chang, and Paul Dowd
pp 7575 - 7576; DOI:
10.1021/ja00230a068
PDF
Book Reviews

pp 7577 - 7582; DOI:
10.1021/ja00230a600
PDF

Issue 23


The interaction of formamide with hydrogen-presaturated Ru(001): conversion of .eta.1(O)-NH2CHO to .eta.2(C,O)-bonded species
J. E. Parmeter and W. Henry Weinberg
pp 7583 - 7590; DOI:
10.1021/ja00231a001
PDF
Methyl cation affinities
Terrance B. McMahon, Thomas Heinis, Gordon Nicol, Jamey K. Hovey, and Paul Kebarle
pp 7591 - 7598; DOI:
10.1021/ja00231a002
PDF
Carbene-like character of gaseous ions. An ion cyclotron resonance and ab initio investigation of the reactions of difluoronitrenium ion with methane
J. J. Fisher and T. B. McMahon
pp 7599 - 7604; DOI:
10.1021/ja00231a003
PDF
Gas-phase Lewis acid-base interactions. An experimental determination of cyanide binding energies from ion cyclotron resonance and high-pressure mass spectrometric equilibrium measurements
J. W. Larson, J. E. Szulejko, and T. B. McMahon
pp 7604 - 7609; DOI:
10.1021/ja00231a004
PDF
Excited states of titanium(2+): sharp-band and broad-band near-infrared luminescence from titanium(2+) in magnesium chloride and magnesium bromide
Stuart M. Jacobsen, Hans U. Guedel, and Claude A. Daul
pp 7610 - 7616; DOI:
10.1021/ja00231a005
PDF
Single electron transfer and nucleophilic substitution. Reaction of alkyl bromides with aromatic anion radicals and low-oxidation-state iron porphyrins
Doris Lexa, Jean Michel Saveant, Su Khac Binh, and Dan Li Wang
pp 7617 - 7625; DOI:
10.1021/ja00231a006
PDF
Silicon naphthalocyanine triplet state and oxygen. A reversible energy-transfer reaction
Patricia A. Firey, William E. Ford, James R. Sounik, Malcolm E. Kenney, and Michael A. J. Rodgers
pp 7626 - 7630; DOI:
10.1021/ja00231a007
PDF
Photoelectrochemistry of strained-layer and lattice-matched superlattice electrodes: effects due to buffer layers
Arthur J. Nozik, B. R. Thacker, J. A. Turner, and M. W. Peterson
pp 7630 - 7637; DOI:
10.1021/ja00231a008
PDF
Direct observation of intermediate ligation states of hemoglobin
Gerard Simonneaux, Arnaud Bondon, Christian Brunel, and Patrick Sodano
pp 7637 - 7640; DOI:
10.1021/ja00231a009
PDF
NMR studies of nucleic acids. Deuterium isotope effects on carbon-13 chemical shifts in hydrogen-bonded complexes of pyrimidines and purines
William H. Gmeiner and C. Dale Poulter
pp 7640 - 7647; DOI:
10.1021/ja00231a010
PDF
Solid-state carbon-13 NMR characterization of polyanilines
S. Kaplan, E. M. Conwell, A. F. Richter, and A. G. MacDiarmid
pp 7647 - 7651; DOI:
10.1021/ja00231a011
PDF
Structures, energies, and modes of interconversion of C4H7+ ions
Martin Saunders, Keith E. Laidig, Kenneth B. Wiberg, and Paul v. R. Schleyer
pp 7652 - 7659; DOI:
10.1021/ja00231a012
PDF
Nonlinear optical properties of organic molecules. 7. Calculated hyperpolarizabilities of azulenes and sesquifulvalene
John O. Morley
pp 7660 - 7663; DOI:
10.1021/ja00231a013
PDF
Ab initio quantum chemical study of the .pi.-electron spectrum of the cytosine molecule
J. Mauricio O. Matos and Bjoern O. Roos
pp 7664 - 7671; DOI:
10.1021/ja00231a014
PDF
Fluorine and chlorine apicophilicities in five-coordinated phosphorus and silicon compounds via molecular orbital calculations. A model for nucleophilic substitution
Joan A. Deiters, Robert R. Holmes, and Joan M. Holmes
pp 7672 - 7681; DOI:
10.1021/ja00231a015
PDF
Ab initio heats of formation of medium-sized hydrocarbons. 8. On the homoaromatic character of triquinacene
Mitchell A. Miller, Jerome M. Schulman, and Raymond L. Disch
pp 7681 - 7684; DOI:
10.1021/ja00231a016
PDF
Chemical hardness and bond dissociation energies
Ralph G. Pearson
pp 7684 - 7690; DOI:
10.1021/ja00231a017
PDF
Dynamics of ligand escape from the heme pocket of myoglobin
J. Kottalam and David A. Case
pp 7690 - 7697; DOI:
10.1021/ja00231a018
PDF
Ring currents in wholly inorganic heteropoly blue complexes. Evaluation by a modification of Evans' susceptibility method
Mariusz Kozik, Nieves Casan-Pastor, Charles F. Hammer, and Louis C. W. Baker
pp 7697 - 7701; DOI:
10.1021/ja00231a019
PDF
Organometallic thermochemistry. Metal hydrocarbyl, hydride, halide, carbonyl, amide, and alkoxide bond enthalpy relationships and their implications in pentamethylcyclopentadienyl and cyclopentadienyl complexes of zirconium and hafnium
Laurel E. Schock and Tobin J. Marks
pp 7701 - 7715; DOI:
10.1021/ja00231a020
PDF
Dicobalt-O-BISTREN cryptate as a reversible dioxygen carrier for oxygen separation and transport
Ramunas J. Motekaitis and Arthur E. Martell
pp 7715 - 7719; DOI:
10.1021/ja00231a021
PDF
A discrete tetranuclear complex of niobium, Nb4Cl10(PMe3)6, related to the local structure in CsNb4Cl11
F. Albert Cotton and Maoyu Shang
pp 7719 - 7722; DOI:
10.1021/ja00231a022
PDF
[Fp-.eta.1-(1-polycycloalkyl)methylidene]+ to [Fp-.eta.2-(1-homopolycycloalkene)]+ rearrangement. Carbon migration in iron(II) alkylidenes. A new route to stabilized bridgehead olefins
Robert S. Bly, Ruta K. Bly, Mahmun M. Hossain, Lukasz Lebioda, and Muthukrishna Raja
pp 7723 - 7730; DOI:
10.1021/ja00231a023
PDF
[Fp-.eta.1-1-norbornylmethylidene)+ to [Fp-.eta.2-(2-bicyclo[3.2.1]octene)]+ rearrangement. Iron(II) alkylidene to iron(II) alkylidene isomerization via ligand rearrangement
Robert S. Bly, Gary S. Silverman, and Ruta K. Bly
pp 7730 - 7737; DOI:
10.1021/ja00231a024
PDF
Organosulfur chemistry. Part 55. Fluorodestannylation. A powerful technique to liberate anions of oxygen, sulfur, selenium, and carbon
David N. Harpp and Marc Gingras
pp 7737 - 7745; DOI:
10.1021/ja00231a025
PDF
Extended x-ray absorption fine structure (EXAFS) of poly[.mu.-hexakis(2-methylimidazolato-N,N')triiron(II)]: implications for metalloprotein studies
M. C. Feiters, S. Navaratnam, M. Al-Hakim, J. C. Allen, A. L. Spek, G. A. Veldink, and J. F. G. Vliegenthart
pp 7746 - 7750; DOI:
10.1021/ja00231a026
PDF
Synthetic design of MLCT excited states. Ligand-substituted, mono-2,2'-bipyridine complexes of ruthenium(II)
Khaled R. Bargawi, Antoni Llobet, and Thomas J. Meyer
pp 7751 - 7759; DOI:
10.1021/ja00231a027
PDF
Adiabatic and charge-transfer pathways in the photocleavage of dimers and cycloadducts of some aromatic molecules
A. Albini and E. Fasani
pp 7760 - 7763; DOI:
10.1021/ja00231a028
PDF
Stable carbocations. 273. [1.1.1.1]- and [2.2.1.1]Pagodane dications: frozen two-electron Woodward-Hoffmann transition-state models
G. K. Surya Prakash, V. V. Krishnamurthy, Rainer Herges, Robert Bau, Hanna Yuan, George A. Olah, Wolf Dieter Fessner, and Horst Prinzbach
pp 7764 - 7772; DOI:
10.1021/ja00231a029
PDF
Transient effects in diffusion controlled reactions. 6. Intermolecular pyrene excimer formation in end-labeled polystyrene of MW 7800: role of the mutual diffusion coefficient
Jose M. G. Martinho, Krzysztof Sienicki, Douglas Blue, and Mitchell A. Winnik
pp 7773 - 7777; DOI:
10.1021/ja00231a030
PDF
Kinetics and thermodynamics of phenolate silylation and alkylation
Joe Carey Ellington and E. M. Arnett
pp 7778 - 7785; DOI:
10.1021/ja00231a031
PDF
Rates of hydroxyl radical reactions. 17. Rate and mechanism of the reaction of hydroxyl radicals with formic and deuteriated formic acids
Donald L. Singleton, George Paraskevopoulos, Robert S. Irwin, Gurvinder S. Jolly, and Donald J. McKenney
pp 7786 - 7790; DOI:
10.1021/ja00231a032
PDF
Divalent metal ion catalysis in the hydrolysis of phosphomonoesters. Hydrolysis of 2-(1,10-phenanthrolyl) phosphate
Thomas H. Fife and Mahesh P. Pujari
pp 7790 - 7797; DOI:
10.1021/ja00231a033
PDF
Semifluorinated hydrocarbons: primitive surfactant molecules
Michael P. Turberg and James E. Brady
pp 7797 - 7801; DOI:
10.1021/ja00231a034
PDF
Planar tetracoordinate carbon atoms hidden in the tetrameric aggregate of (2,6-dimethoxyphenyl)lithium
Sjoerd Harder, Jaap Boersma, Lambert Brandsma, Albert Van Heteren, Jan A. Kanters, Walter Bauer, and Paul v. R. Schleyer
pp 7802 - 7806; DOI:
10.1021/ja00231a035
PDF
Polycyclooctatetraene (polyacetylene): synthesis and properties
Floyd L. Klavetter and Robert H. Grubbs
pp 7807 - 7813; DOI:
10.1021/ja00231a036
PDF
Lipoxygenase inhibitors from the essential oil of garlic. Markovnikov addition of the allyldithio radical to olefins
Eric Block, Rajeshwari Iyer, Serge Grisoni, Chantu Saha, Sidney Belman, and Fred P. Lossing
pp 7813 - 7827; DOI:
10.1021/ja00231a037
PDF
An enantioselective method for reductive alkylation of aromatic carboxylic acid derivatives. Examination of the factors that provide stereoselectivity
Arthur G. Schultz, Mark Macielag, Padmanabhan Sundararaman, Arthur G. Taveras, and Martha Welch
pp 7828 - 7841; DOI:
10.1021/ja00231a038
PDF
Synthesis and conformation of 1,1,10,10-tetramethyl[3.3]metacyclophane
Yoshimasa Fukazawa, Yoshiya Takeda, Shuji Usui, and Mitsuaki Kodama
pp 7842 - 7847; DOI:
10.1021/ja00231a039
PDF
Solid-phase synthesis of porcine cardiodilatin 88
Kiyoshi Nokihara and Toshihiko Semba
pp 7847 - 7854; DOI:
10.1021/ja00231a040
PDF
Asymmetric total synthesis of (-)-podophyllotoxin
Robert C. Andrews, Simon J. Teague, and Albert I. Meyers
pp 7854 - 7858; DOI:
10.1021/ja00231a041
PDF
Conformational analysis of 14-membered macrolides using x-ray crystallography and molecular mechanics calculations
Thomas H. Keller, Edward G. Neeland, Steven Rettig, James Trotter, and Larry Weiler
pp 7858 - 7868; DOI:
10.1021/ja00231a042
PDF
Synthesis of Os2(CO)8(.mu.-CHCH3) from a geminal ditriflate and its reversible carbonylation to a ketene-bridged diosmacycle
R. Morris Bullock, Robert T. Hembre, and Jack R. Norton
pp 7868 - 7870; DOI:
10.1021/ja00231a043
PDF
Clean TOCSY for proton spin system identification in macromolecules
C. Griesinger, G. Otting, K. Wuethrich, and Richard R. Ernst
pp 7870 - 7872; DOI:
10.1021/ja00231a044
PDF
(Mercury)18-metallothionein
Wuhua Cai and Martin J. Stillman
pp 7872 - 7873; DOI:
10.1021/ja00231a045
PDF
Enantioselective synthesis of dihydropyridine sulfones
Roman Davis, John R. Kern, Lilia J. Kurz, and Jurg R. Pfister
pp 7873 - 7874; DOI:
10.1021/ja00231a046
PDF
Are the halogenations of simple enols in aqueous solution really diffusion-controlled reactions?
Remo Hochstrasser, A. Jerry Kresge, Norman P. Schepp, and Jakob Wirz
pp 7875 - 7876; DOI:
10.1021/ja00231a047
PDF
Prorocentrolide, a toxic nitrogenous macrocycle from a marine dinoflagellate, Prorocentrum lima
Koichiro Torigoe, Michio Murata, Takeshi Yasumoto, and Takashi Iwashita
pp 7876 - 7877; DOI:
10.1021/ja00231a048
PDF
Asymmetric amplifying phenomena in enantioselective addition of diethylzinc to benzaldehyde
N. Oguni, Y. Matsuda, and T. Kaneko
pp 7877 - 7878; DOI:
10.1021/ja00231a049
PDF
Stereochemistry of enzymic formation of the berberine bridge in protoberberine alkaloids
Thomas Frenzel, John M. Beale, Motomasa Kobayashi, Meinhart H. Zenk, and Heinz G. Floss
pp 7878 - 7880; DOI:
10.1021/ja00231a050
PDF
The reaction of 2,3-diazabicyclo[2.2.2]oct-2-ene with stable cation radical salts
Paul S. Engel, A. K. M. M. Hoque, John N. Scholz, Henry J. Shine, and Kenton H. Whitmire
pp 7880 - 7882; DOI:
10.1021/ja00231a051
PDF
Hyperconjugation as a factor in face selectivity during cycloaddition
Wen Sheng Chung, N. J. Turro, Sushil Srivastava, Haifang Li, and W. J. Le Noble
pp 7882 - 7883; DOI:
10.1021/ja00231a052
PDF
Specific deuterium isotope effects on the rates of electron transfer within geminate radical-ion pairs
Ian R. Gould and Samir Farid
pp 7883 - 7885; DOI:
10.1021/ja00231a053
PDF
Onium ions. 37. Hydrogen-deuterium exchange of diborane in superacid solution through diboranonium (B2H7+) and diboranium (B2H5+) ions
George A. Olah, Robert Aniszfeld, G. K. Surya Prakash, Robert E. Williams, Koop Lammertsma, and Osman F. Guner
pp 7885 - 7886; DOI:
10.1021/ja00231a054
PDF
ESR study of the 2,3-diazabicyclo[2.2.2]oct-2-ene radical cation in Freon matrixes
Ffrancon Williams, Qing Xiang Guo, Peter A. Petillo, and Stephen F. Nelsen
pp 7887 - 7888; DOI:
10.1021/ja00231a055
PDF
Photosensitized cleavage of a thymine dimer by an antibody
Andrea G. Cochran, Renee Sugasawara, and Peter G. Schultz
pp 7888 - 7890; DOI:
10.1021/ja00231a056
PDF
The mechanism of hydroperoxide oxygen-oxygen bond scission on reaction of hydroperoxides with iron(III) porphyrins
Thomas C. Bruice, P. N. Balasubramanian, R. W. Lee, and J. R. Lindsay Smith
pp 7890 - 7892; DOI:
10.1021/ja00231a057
PDF
Rate-limiting phosphorus-oxygen fission in the self-stimulated inactivation of acetylcholinesterase by 4-nitrophenyl 2-propyl methylphosphonate
Andrew J. Bennet, Ildiko M. Kovach, and Richard L. Schowen
pp 7892 - 7893; DOI:
10.1021/ja00231a058
PDF
Biosynthesis of 3,6-dideoxy hexoses: C-3 deoxygenation may proceed via a radical mechanism
Oksoo Han and Hung Wen Liu
pp 7893 - 7894; DOI:
10.1021/ja00231a059
PDF
Polyaza cavity shaped molecules. 15. Stereocontrol in the formation of binuclear complexes
Randolph P. Thummel, Christophe Hery, Darwin Williamson, and Francois Lefoulon
pp 7894 - 7896; DOI:
10.1021/ja00231a060
PDF
M43 antibiotics: methylated vancomycins and unrearranged CDP-I analogs
Ramakrishnan Nagarajan, Kurt E. Merkel, Karl H. Michel, Harvey M. Higgins, Marvin M. Hoehn, Ann H. Hunt, Noel D. Jones, John L. Occolowitz, Amelia A. Schabel, and John K. Swartzendruber
pp 7896 - 7897; DOI:
10.1021/ja00231a061
PDF
Proton NMR evidence for a non-chair conformation for the six-membered ring attached apical equatorial to pentacovalent phosphorus. Potential implications for enzyme-catalyzed reactions of cyclic nucleotides
Jaehoon H. Yu and Wesley G. Bentrude
pp 7897 - 7899; DOI:
10.1021/ja00231a062
PDF
The bicyclobutyl anion: an alkyl carbanion
Steven R. Kass and Phillip K. Chou
pp 7899 - 7900; DOI:
10.1021/ja00231a063
PDF
Evidence for free monomeric thiometaphosphate anion in aqueous solution
J. Burgess, N. Blundell, Paul M. Cullis, C. D. Hubbard, and R. Misra
pp 7900 - 7901; DOI:
10.1021/ja00231a064
PDF
Remarkably similar solution and solid-state structures for two divergently reactive lithium enolates derived from vinylogous urethanes
Paul G. Williard, James R. Tata, Richard H. Schlessinger, Alan D. Adams, and Edwin J. Iwanowicz
pp 7901 - 7903; DOI:
10.1021/ja00231a065
PDF
Synthesis of bis(2,5-dimethylpyrrolo[3,4-d])-tetrathiafulvalene, an annelated TTF derivative with good electron donor properties
Wha Chen, Michael P. Cava, Mohammad A. Takassi, and Robert M. Metzger
pp 7903 - 7904; DOI:
10.1021/ja00231a066
PDF
Monomeric metaphosphate formation during radical-based dephosphorylation
L. Z. Avila and John W. Frost
pp 7904 - 7906; DOI:
10.1021/ja00231a067
PDF
The selective hydrogenation of benzene to cyclohexene on pentaammineosmium(II)
W. Dean Harman and Henry Taube
pp 7906 - 7907; DOI:
10.1021/ja00231a068
PDF
Transition-state structural features for the thermolysin-catalyzed hydrolysis of N-(3-[2-furyl]acryloyl)-Gly-LeuNH2
Ross L. Stein
pp 7907 - 7908; DOI:
10.1021/ja00231a069
PDF
Direct observation of multiple environments for the H.delta. but not the H.epsilon. proton of a histidine residue in Staphylococcal nuclease
Susan M. Stanczyk, Philip H. Bolton, Mark Dell'Acqua, Tayebeh Pourmotabbed, and John A. Gerlt
pp 7908 - 7910; DOI:
10.1021/ja00231a070
PDF
A practical and enantioselective synthesis of glycosphingolipids and related compounds. Total synthesis of globotriaosylceramide (Gb3)
K. C. Nicolaou, T. Caulfield, H. Kataoka, and T. Kumazawa
pp 7910 - 7912; DOI:
10.1021/ja00231a071
PDF
ENDOR detection of diastereomers formed by inclusion of a prochiral spin probe into .beta.-cyclodextrin
Edward G. Janzen and Yashige Kotake
pp 7912 - 7913; DOI:
10.1021/ja00231a072
PDF
The resonance Raman spectrum of horseradish peroxidase compound I
Ki Jung Paeng and James R. Kincaid
pp 7913 - 7915; DOI:
10.1021/ja00231a073
PDF
Activation of methane by the reactive intermediate tris(trimethylphosphine)osmium(0)
T. Gregory P. Harper, Ronald S. Shinomoto, Mark A. Deming, and Thomas C. Flood
pp 7915 - 7916; DOI:
10.1021/ja00231a074
PDF
New strategies for annulations: a highly convergent and stereoselective synthesis of an octahydronaphthalene synthon for dihydrocompactin
J. P. Marino and Jeffrey K. Long
pp 7916 - 7917; DOI:
10.1021/ja00231a075
PDF
The effect of substitution and stereochemistry on ion binding in the polyether ionophore monensin
Paul W. Smith and W. Clark Still
pp 7917 - 7919; DOI:
10.1021/ja00231a076
PDF
Patellazole C: a novel cytotoxic macrolide from Lissoclinum patella
T. Mark Zabriskie, Charles L. Mayne, and Chris M. Ireland
pp 7919 - 7920; DOI:
10.1021/ja00231a077
PDF
Patellazole B: a novel cytotoxic thiazole-containing macrolide from the marine tunicate Lissoclinum patella
David G. Corley, Richard E. Moore, and Valerie J. Paul
pp 7920 - 7922; DOI:
10.1021/ja00231a078
PDF
Unprecedented stereochemical control in the Claisen rearrangement of allyl vinyl ethers using organoaluminum reagents
Keiji Maruoka, Katsumasa Nonoshita, Hiroshi Banno, and Hisashi Yamamoto
pp 7922 - 7924; DOI:
10.1021/ja00231a079
PDF
Evidence for dipolar cross-correlation from triple-quantum-filtered two-dimensional exchange NMR spectroscopy
Claudio Dalvit and Geoffrey Bodenhausen
pp 7924 - 7926; DOI:
10.1021/ja00231a080
PDF
Long range heteronuclear correlation. A powerful tool for the NMR analysis of medium-size proteins
Ad Bax, Steven W. Sparks, and Dennis A. Torchia
pp 7926 - 7927; DOI:
10.1021/ja00231a081
PDF
Double strand cleavage of genomic DNA at a single site by triple helix formation
Scott A. Strobel, Heinz E. Moser, and Peter B. Dervan
pp 7927 - 7929; DOI:
10.1021/ja00231a082
PDF
Preparation of the 8,9-epoxide of the mycotoxin aflatoxin B1: the ultimate carcinogenic species
Steven W. Baertschi, Kevin D. Raney, Michael P. Stone, and Thomas M. Harris
pp 7929 - 7931; DOI:
10.1021/ja00231a083
PDF
Stereoselective 3 + 2 and stereospecific 2 + 2 cycloaddition reactions of alkenes and quinones
Thomas A. Engler, Keith D. Combrink, and James E. Ray
pp 7931 - 7933; DOI:
10.1021/ja00231a084
PDF
A stereoselective contrasteric conversion of epoxides to cis-oxazolidin-2-ones
Barry M. Trost and Anantha R. Sudhakar
pp 7933 - 7935; DOI:
10.1021/ja00231a085
PDF
Book Reviews

pp 7936 - 7944; DOI:
10.1021/ja00231a600
PDF

Issue 24


Gas-phase electron-transfer equilibrium studies on tetraalkylhydrazines: geometry effects on ionization thermochemistry, relaxation energies, and ion solvation energies
Stephen F. Nelsen, Daniel T. Rumack, and Michael Meot-Ner
pp 7945 - 7952; DOI:
10.1021/ja00232a001
PDF
The chemistry of acetylene on the ruthenium(001)-p(2X2)0 and ruthenium(001)-p(1X2)0 surfaces
J. E. Parmeter, M. M. Hills, and W. H. Weinberg
pp 7952 - 7961; DOI:
10.1021/ja00232a002
PDF
XPS valence band study of zeolites and related systems. 1. General chemistry and structure
Tery L. Barr, Li Mei Chen, Mehran Mohsenian, and Marie A. Lishka
pp 7962 - 7975; DOI:
10.1021/ja00232a003
PDF
Characterization and novel low-temperature reactions of FeCH2 and N2FeCH2
Sou Chan Chang, Robert H. Hauge, Zakya H. Kafafi, John L. Margrave, and W. E. Billups
pp 7975 - 7980; DOI:
10.1021/ja00232a004
PDF
Association of dimethyl sulfide radical cation with dimethyl sulfide. Strength of a two-center three-electron bond
A. J. Illies, P. Livant, and M. L. McKee
pp 7980 - 7984; DOI:
10.1021/ja00232a005
PDF
Unstable enols in the gas phase. Preparation ionization, energies, and heats of formation of (E)- and (Z)-2-buten-2-ol, 2-methyl-1-propen-1-ol, and 3-methyl-2-buten-2-ol
Frantisek Turecek, Libor Brabec, and Jorma Korvola
pp 7984 - 7990; DOI:
10.1021/ja00232a006
PDF
The ozonolysis of ethylene. Microwave spectrum, molecular structure, and dipole moment of ethylene primary ozonide (1,2,3-trioxolane)
J. Z. Gillies, Charles W. Gillies, R. D. Suenram, and F. J. Lovas
pp 7991 - 7999; DOI:
10.1021/ja00232a007
PDF
The MPS3 coloring problem
Stephen Lee
pp 8000 - 8006; DOI:
10.1021/ja00232a008
PDF
Stabilities and nature of the attractive interactions in HeBeO, NeBeO, and ArBeO and a comparison with analogs NGLiF, NGBN, and NGLiH (NG = He, Ar). A theoretical investigation
Gernot Frenking, Wolfram Koch, Juergen Gauss, and Dieter Cremer
pp 8007 - 8016; DOI:
10.1021/ja00232a009
PDF
A theoretical investigation of the ground and a few excited states of the lithium cobalt-Schiff base complexes
Renato Colle, Alessandro Fortunelli, Nazzareno Re, and Oriano Salvetti
pp 8016 - 8022; DOI:
10.1021/ja00232a010
PDF
The role of resonance and inductive effects in the acidity of carboxylic acids
Michele R. F. Siggel, Andrew Streitwieser, and T. Darrah Thomas
pp 8022 - 8028; DOI:
10.1021/ja00232a011
PDF
Rotational barriers. 2. Energies of alkane rotamers. An examination of gauche interactions
Kenneth B. Wiberg and Mark A. Murcko
pp 8029 - 8038; DOI:
10.1021/ja00232a012
PDF
Application of modern tritium NMR techniques to analysis of complex isotopic products from a hydrogenation reaction
Philip G. Williams, Hiromi Morimoto, and David E. Wemmer
pp 8038 - 8044; DOI:
10.1021/ja00232a013
PDF
Electron spin resonance and electron spin echo spectroscopic studies of catalytic dimerization of ethylene on palladium-exchanged Na-X and Ca-X zeolites. Proposed reaction mechanism for ethylene dimerization
Ashim K. Ghosh and Larry Kevan
pp 8044 - 8050; DOI:
10.1021/ja00232a014
PDF
Nonplanarity of the methylcyclobutyl cation
Martin Saunders and Norbert Krause
pp 8050 - 8052; DOI:
10.1021/ja00232a015
PDF
Identification of both preequilibrium and diffusion limits for reaction of singlet oxygen, O2(1.DELTA.g), with both physical and chemical quenchers: variable-temperature, time-resolved infrared luminescence studies
A. A. Gorman, I. Hamblett, C. Lambert, B. Spencer, and M. C. Standen
pp 8053 - 8059; DOI:
10.1021/ja00232a016
PDF
Formation and degradation of an oxalato- and peroxo-bridged dicobalt BISDIEN dioxygen complex: binuclear complexes as hosts for the activation of two coordinated guests
Arthur E. Martell and Ramunas J. Motekaitis
pp 8059 - 8064; DOI:
10.1021/ja00232a017
PDF
Low-temperature neutron powder diffraction study of chromium dioxide and the validity of the Jahn-Teller viewpoint
Jeremy K. Burdett, Gordon J. Miller, James W. Richardson, and Joseph V. Smith
pp 8064 - 8071; DOI:
10.1021/ja00232a018
PDF
Vanadium nitride linear chain polymers and monomers. Synthesis and structures of [V(.mu.-N)Cl2(py)2].infin. and V(N)Cl2(quin)2
Susan C. Critchlow, Megan E. Lerchen, Randal C. Smith, and Nancy M. Doherty
pp 8071 - 8075; DOI:
10.1021/ja00232a019
PDF
Bis(dioxolene)(bipyridine)ruthenium redox series
A. B. P. Lever, Pamela R. Auburn, Elaine S. Dodsworth, Masa Aki Haga, Wei Liu, Milan Melnik, and W. Andrew Nevin
pp 8076 - 8084; DOI:
10.1021/ja00232a020
PDF
Functional models for catechol 1,2-dioxygenase. The role of the iron(III) center
David D. Cox and Lawrence Que
pp 8085 - 8092; DOI:
10.1021/ja00232a021
PDF
1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods
Yu Zhuo Li, John P. Kirby, Michael W. George, Martyn Poliakoff, and Gary B. Schuster
pp 8092 - 8098; DOI:
10.1021/ja00232a022
PDF
Electron-transfer-induced photoadditions of the silyl amine, Et2NCH2SiMe3, to .alpha.,.beta.-unsaturated cyclohexenones. Dual reaction pathways based on ion pair-selective cation-radical chemistry
Eietsu Hasegawa, Wei Xu, Patrick S. Mariano, Ung Chan Yoon, and Jin Uk Kim
pp 8099 - 8111; DOI:
10.1021/ja00232a023
PDF
A strategy for intermolecular Diels-Alder cycloaddition to enamides
Nathan L. Bauld, Bijan Harirchian, Dan W. Reynolds, and John C. White
pp 8111 - 8117; DOI:
10.1021/ja00232a024
PDF
Biosynthetic studies of marine lipids. 17. The course of chain elongation and desaturation in long-chain fatty acids of marine sponges
Soonkap Hahn, Ivan L. Stoilov, T. B. Tam Ha, Daniel Raederstorff, George A. Doss, Hui Ting Li, and Carl Djerassi
pp 8117 - 8124; DOI:
10.1021/ja00232a025
PDF
Sterols in marine invertebrates. 60. Isolation and structure elucidation of four new steroidal cyclopropenes from the sponge Calyx podatypa
George A. Doss and Carl Djerassi
pp 8124 - 8128; DOI:
10.1021/ja00232a026
PDF
Total synthesis of (.+-.)-heptelidic acid
Samuel J. Danishefsky and Nathan Mantlo
pp 8129 - 8133; DOI:
10.1021/ja00232a027
PDF
Synthetic molecular receptors for urea. Macrocyclic ligands with intraannular acidic groups and the complexes with urea
Catherina J. Van Staveren, Veronika M. L. J. Aarts, Peter D. J. Grootenhuis, Wichert J. H. Droppers, Johan Van Eerden, Sybolt Harkema, and David N. Reinhoudt
pp 8134 - 8144; DOI:
10.1021/ja00232a028
PDF
Complex-induced proximity effects and dipole-stabilized carbanions: kinetic evidence for the role of complexes in the .alpha.'-lithiations of carboxamides
David R. Hay, Zhiguo Song, Stanley G. Smith, and Peter Beak
pp 8145 - 8153; DOI:
10.1021/ja00232a029
PDF
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst
Tamio Hayashi, Keiichi Hayashizaki, Takao Kiyoi, and Yoshihiko Ito
pp 8153 - 8156; DOI:
10.1021/ja00232a030
PDF
Metal ion effects in intramolecular reactions. Effects of divalent metal ions on intramolecular acetamido group participation in ester hydrolysis
Thomas H. Fife, Theodore J. Przystas, and Mahesh P. Pujari
pp 8157 - 8163; DOI:
10.1021/ja00232a031
PDF
Radical stabilization energies of disubstituted methyl radicals. A detailed theoretical analysis of the captodative effect
Daniel J. Pasto
pp 8164 - 8175; DOI:
10.1021/ja00232a032
PDF
Influencing reactivity by monolayer compression: an alcohol dehydration
Jamil Ahmad and K. Brian Astin
pp 8175 - 8178; DOI:
10.1021/ja00232a033
PDF
Properties of anions, radicals, and radical cations derived from 9-(dialkylamino)fluorenes
Frederick G. Bordwell, Jin Pei Cheng, S. E. Seyedrezai, and Craig A. Wilson
pp 8178 - 8183; DOI:
10.1021/ja00232a034
PDF
Competing reactions of the acetone cation radical: RRKM-QET calculations on an ab initio potential-energy surface
Nikolaus Heinrich, Frank Louage, Chava Lifshitz, and Helmut Schwarz
pp 8183 - 8192; DOI:
10.1021/ja00232a035
PDF
Dynamic behavior of 1,2-annulated cyclooctatetraenes. Kinetic analysis of transition-state steric congestion involving neighboring alicyclic substituents
Leo A. Paquette and Ting Zhong Wang
pp 8192 - 8197; DOI:
10.1021/ja00232a036
PDF
Dynamic properties of chiral cyclooctatetraenes. Total inhibition of the racemization process by 1,4-annulation
Leo A. Paquette and Michael P. Trova
pp 8197 - 8201; DOI:
10.1021/ja00232a037
PDF
2-Indanone and its enol. The effect of a conjugated phenyl group on enol and enolate stability
James R. Keeffe, A. J. Kresge, and Y. Yin
pp 8201 - 8206; DOI:
10.1021/ja00232a038
PDF
Electron-transfer activation in the thermal and photochemical osmylations of aromatic electron donor-acceptor complexes with osmium(VIII) tetroxide
J. M. Wallis and Jay K. Kochi
pp 8207 - 8223; DOI:
10.1021/ja00232a039
PDF
Primary deuterium kinetic isotope effects for the thermal [1,7] sigmatropic rearrangement of 7-methylocta-1,3(Z),5(Z)-triene
John E. Baldwin and V. Prakash Reddy
pp 8223 - 8228; DOI:
10.1021/ja00232a040
PDF
Biosynthesis of the unusual amino acid, 5-hydroxy-4-oxonorvaline
Robert L. White, Alphonse C. DeMarco, and Kevin C. Smith
pp 8228 - 8229; DOI:
10.1021/ja00232a041
PDF
Direct measurement of deuterium-deuterium dipolar coupling and analysis of the ordering of a specifically deuterated diunsaturated lipid
John E. Baenziger, Ian C. P. Smith, Robin J. Hill, and Harold C. Jarrell
pp 8229 - 8231; DOI:
10.1021/ja00232a042
PDF
Ordered DNA-polypeptide complexes of extreme chirality: effects of polypeptide handedness on DNA long-range asymmetry
Sarah Weinberger, Craig Berman, and Abraham Minsky
pp 8231 - 8232; DOI:
10.1021/ja00232a043
PDF
Long-lived light-induced charge separation in a zeolite L-based molecular triad
Jonathan S. Krueger, James E. Mayer, and Thomas E. Mallouk
pp 8232 - 8234; DOI:
10.1021/ja00232a044
PDF
Organometallic dioxygen activation: formation of (pentamethylcyclopentadienyl)chromyl dibromide
David B. Morse, Thomas B. Rauchfuss, and Scott R. Wilson
pp 8234 - 8235; DOI:
10.1021/ja00232a045
PDF
Synthesis and structure of a tungstacyclopentatriene
Judith L. Kerschner, Phillip E. Fanwick, and Ian P. Rothwell
pp 8235 - 8238; DOI:
10.1021/ja00232a046
PDF
Cell-free biosynthesis of nocardicin A from nocardicin E and S-adenosylmethionine
Brenda A. Wilson, Shanta Bantia, Gino M. Salituro, Anne M. Reeve, and Craig A. Townsend
pp 8238 - 8239; DOI:
10.1021/ja00232a047
PDF
Metal-catalyzed cyclization via isomerization of .alpha.-dienyl-.omega.-allyl acetates
Barry M. Trost and Juan I. Luengo
pp 8239 - 8241; DOI:
10.1021/ja00232a048
PDF
Does the conformation of hydrocarbon chains depend on solvation?
F. M. Menger and L. L. D'Angelo
pp 8241 - 8242; DOI:
10.1021/ja00232a049
PDF
Structure of aranorosin, a new antibiotic of a novel skeletal type
H. W. Fehlhaber, H. Kogler, Triptikumar Mukhopadhyay, E. K. S. Vijayakumar, and B. N. Ganguli
pp 8242 - 8244; DOI:
10.1021/ja00232a050
PDF
A stable, simple enol: ketonization of 2-methylprop-1-en-1-ol in nonaqueous solvents
Chong Shik Chin, Sun Yeol Lee, Jeonghan Park, and Sangtae Kim
pp 8244 - 8245; DOI:
10.1021/ja00232a051
PDF
Thermodynamics of kinetically irreversible organometallic processes. Metal-metal bonds
J. Richard Pugh and Thomas J. Meyer
pp 8245 - 8246; DOI:
10.1021/ja00232a052
PDF
Methyl chymotrypsin catalyzed hydrolyses of specific substrate esters indicate multiple proton catalysis is possible with a modified charge relay triad
Jeffrey D. Scholten, John L. Hogg, and Frank M. Raushel
pp 8246 - 8247; DOI:
10.1021/ja00232a053
PDF
Spectroscopic and structural investigation of the unbridged dirhodium cation [Rh2(CH3CN)10]4+
Kim R. Dunbar
pp 8247 - 8249; DOI:
10.1021/ja00232a054
PDF
Modeling the ammoxidation of propylene to acrylonitrile: the conversion of an allylimido(2-) ligand to an allylideneamido(1-) ligand
Eric A. Maatta and Yuhua Du
pp 8249 - 8250; DOI:
10.1021/ja00232a055
PDF
Synthetic studies of the cyclopropyl iminium ion rearrangement. 3. Application of the cyclopropyl acyliminium ion rearrangement to a concise and highly convergent synthesis of (.+-.)-lycorine
Robert K. Boeckman, Steven W. Goldstein, and Michael A. Walters
pp 8250 - 8252; DOI:
10.1021/ja00232a056
PDF
Thermal encapsulation and photochemical deencapsulation of silver(I) by [Ir2(dimen)4](PF6)2 (dimen = 1,8-diisocyanomenthane). X-ray crystal structure of [AgIr2(dimen)4](PF6)3.cntdot.2DMSO
Andrew Sykes and Kent R. Mann
pp 8252 - 8253; DOI:
10.1021/ja00232a057
PDF
Dioxygen-derived peroxo-alkyl complexes of permethyltantalocene. Structural characterization of (.eta.5-C5Me5)2Ta(.eta.2-O2)(CH2C6H5) and acid-catalyzed rearrangement to oxo-alkoxide derivatives
Allan Van Asselt, Mark S. Trimmer, Larry M. Henling, and John E. Bercaw
pp 8254 - 8255; DOI:
10.1021/ja00232a058
PDF
Intramolecular charge-transfer transition in benzanilides and its dielectric medium modulation
Jozef Heldt, David Gormin, and Michael Kasha
pp 8255 - 8256; DOI:
10.1021/ja00232a059
PDF
Ruthenium-catalyzed cytochrome P-450 type oxidation of tertiary amines with alkyl hydroperoxides
Shunichi Murahashi, Takeshi Naota, and Koichi Yonemura
pp 8256 - 8258; DOI:
10.1021/ja00232a060
PDF
Generalized valence bond description of multiple bonds
Peter A. Schultz and Richard P. Messmer
pp 8258 - 8259; DOI:
10.1021/ja00232a061
PDF
ESR investigation of carbon-carbon bond cleavage in radical cations
Przemyslaw Maslak and Stacey L. Asel
pp 8260 - 8261; DOI:
10.1021/ja00232a062
PDF
Are triplet exciplexes involved in [2 + 2] photocycloaddition of cyclic enones to alkenes?
David I. Schuster, George E. Heibel, Pamela B. Brown, Nicholas J. Turro, and Challa V. Kumar
pp 8261 - 8263; DOI:
10.1021/ja00232a063
PDF
Phosphine complexes of yttrium(III). Synthesis, reactivity and fluxional behavior of YCl[N(SiMe2CH2PMe2)2]2
Michael D. Fryzuk and T. S. Haddad
pp 8263 - 8265; DOI:
10.1021/ja00232a064
PDF
Proton transfer is not rate-limiting in buffer-induced non-enzymic glucation of hemoglobin
Herminia Gil, Julio F. Mata-Segreda, and Richard L. Schowen
pp 8265 - 8266; DOI:
10.1021/ja00232a065
PDF
Bismethyleneborane [B(CH2)2]- and trismethyleneborane [B(CH2)3]- anions. Do they exist in the gas phase?
John C. Sheldon, Graeme J. Currie, and John H. Bowie
pp 8266 - 8267; DOI:
10.1021/ja00232a066
PDF
Gated electron transfer: when are observed rates controlled by conformational interconversion? [Erratum to document cited in CA107(19):175241j]
Brian M. Hoffman and Mark A. Ratner
pp 8267 - 8267; DOI:
10.1021/ja00232a067
PDF
Adenosine 5'-[.alpha.,.beta.-imido]triphosphate, a substrate for T7 RNA polymerase and rabbit muscle creatine kinase [Erratum to document cited in CA109(1):6886j]
Qi Feng Ma, Patricia C. Babbitt, and George L. Kenyon
pp 8267 - 8267; DOI:
10.1021/ja00232a068
PDF
Computer Software Review

pp 8268 - 8268; DOI:
10.1021/ja00232a600
PDF
Book Reviews

pp 8268 - 8274; DOI:
10.1021/ja00232a601
PDF

Issue 25


The use of lanthanides for solution structure determination of biomolecules by NMR. Evaluation of the methodology with EDTA derivatives as model systems
Marvin D. Kemple, Bruce D. Ray, Kenny B. Lipkowitz, Franklyn G. Prendergast, and B. D. Nageswara Rao
pp 8275 - 8287; DOI:
10.1021/ja00233a001
PDF
Kinetics of degenerate rearrangements in nortricyclyl cation
Ronald M. Jarret, Joseph C. Veniero, Timothy P. Byrne, Martin Saunders, and Keith E. Laidig
pp 8287 - 8291; DOI:
10.1021/ja00233a002
PDF
Binding of unfused aromatic cations to DNA. The influence of molecular twist on intercalation
W. David Wilson, Lucjan Strekowski, Farial A. Tanious, Rebecca A. Watson, Jerzy L. Mokrosz, Alewtina Strekowska, Gordon D. Webster, and Stephen Neidle
pp 8292 - 8299; DOI:
10.1021/ja00233a003
PDF
Time-resolved observation of excitation hopping between two identical chromophores attached to both ends of alkanes
Tomiki Ikeda, Bong Lee, Seiji Kurihara, Shigeo Tazuke, Shinzaburo Ito, and Masahide Yamamoto
pp 8299 - 8304; DOI:
10.1021/ja00233a004
PDF
Hydrogenolysis of ethane, propane, n-butane, and neopentane on the (111) and (110)-(1.times.2) surfaces of iridium
J. R. Engstrom, D. W. Goodman, and W. H. Weinberg
pp 8305 - 8319; DOI:
10.1021/ja00233a005
PDF
Matrix isolation infrared studies of nucleic acid constituents. 5. Experimental matrix-isolation and theoretical ab initio SCF molecular orbital studies of the infrared spectra of cytosine monomers
M. Szczesniak, K. Szczepaniak, J. S. Kwiatkowski, K. KuBulat, and W. B. Person
pp 8319 - 8330; DOI:
10.1021/ja00233a006
PDF
Experimental evidence for the existence of ionized and neutral fluorohydroxymethylene (FCOH) in the gas phase
Detlev Suelzle, Thomas Drewello, Ben L. M. Van Baar, and Helmut Schwarz
pp 8330 - 8333; DOI:
10.1021/ja00233a007
PDF
Quantitative measure of .alpha.-silyl carbanion stabilization. The electron affinity of (trimethylsilyl)methyl radical
Donna M. Wetzel and John I. Brauman
pp 8333 - 8336; DOI:
10.1021/ja00233a008
PDF
Hydrogen atom tunneling in the thermal tautomerism of porphine imbedded in a n-hexane matrix
Thomas J. Butenhoff and C. Bradley Moore
pp 8336 - 8341; DOI:
10.1021/ja00233a009
PDF
Nephelauxetic effect in paramagnetic shielding of transition metal nuclei in octahedral d6 complexes
Nenad Juranic
pp 8341 - 8343; DOI:
10.1021/ja00233a010
PDF
Electron transfer via dithiaspiroalkane linkages. Nature of long-range through-bond electronic coupling in disulfoxide radical cations and bis(metal) complexes and implications for the characterization of the sulfoxide bond
Alistair P. L. Rendell, George B. Bacskay, and Noel S. Hush
pp 8343 - 8354; DOI:
10.1021/ja00233a011
PDF
Evaluation of the rate constant for the SN2 reaction fluoromethane + hydride .fwdarw. methane + fluoride in the gas phase
Angela Merkel, Zdenek Havlas, and Rudolf Zahradnik
pp 8355 - 8359; DOI:
10.1021/ja00233a012
PDF
Theoretical studies on the lithiation of enamines
G. Stork, R. L. Polt, Yi Li, and Kendall N. Houk
pp 8360 - 8367; DOI:
10.1021/ja00233a013
PDF
Computational studies of the interactions of chiral molecules: complexes of methyl N-(2-naphthyl)alaninate with N-(3,5-dinitrobenzoyl)leucine n-propylamide as a model for chiral stationary-phase interactions
Sid Topiol, Michael Sabio, June Moroz, and Walton B. Caldwell
pp 8367 - 8376; DOI:
10.1021/ja00233a014
PDF
Dimensionality and metal-metal and metal-oxygen bonding in the sodium niobate (NaNb3O6) structure
Maria Jose Calhorda and Roald Hoffmann
pp 8376 - 8385; DOI:
10.1021/ja00233a015
PDF
A new technique to calculate low-energy conformations of cyclic molecules utilizing the ellipsoid algorithm and molecular dynamics: application to 18-crown-6
Martin Billeter, Allison E. Howard, Irwin D. Kuntz, and Peter A. Kollman
pp 8385 - 8391; DOI:
10.1021/ja00233a016
PDF
Spectroscopic, structural, electrochemical, and kinetic studies of ligand substitution in the 33e dinuclear radical Fe2(CO)7(.mu.-PPh2) and the 34e analogs [Fe2(CO)7(.mu.-PPh2)]- and FeCo(CO)7(.mu.-PPh2)
R. T. Baker, J. C. Calabrese, P. J. Krusic, M. J. Therien, and W. C. Trogler
pp 8392 - 8412; DOI:
10.1021/ja00233a017
PDF
Chromium-53 nuclear magnetic resonance studies of pentacarbonylchromium carbene complexes
Andreas Hafner, Louis S. Hegedus, Guy DeWeck, Bruce Hawkins, and Karl H. Doetz
pp 8413 - 8421; DOI:
10.1021/ja00233a018
PDF
Two approaches to the synthesis of bimetallic cage complexes of the tetraoxatetraphosphorinane [RPO]4 ring
Edward H. Wong, Mark M. Turnbull, Kirk D. Hutchinson, Carmen Valdez, Eric J. Gabe, Florence L. Lee, and Yvon Le Page
pp 8422 - 8428; DOI:
10.1021/ja00233a019
PDF
Carbon-hydrogen oxidative addition and reductive elimination reactions in a dinuclear iridium complex
William D. McGhee, Frederick J. Hollander, and Robert G. Bergman
pp 8428 - 8443; DOI:
10.1021/ja00233a020
PDF
Reactive iron porphyrin derivatives related to the catalytic cycles of cytochrome P-450 and peroxidase. Studies of the mechanism of oxygen activation
John T. Groves and Yoshihito Watanabe
pp 8443 - 8452; DOI:
10.1021/ja00233a021
PDF
Novel fluorine-bridged polyfluorinated iodine structures. The presence of fluorine as the central atom in a five-center, six-electron bond
William B. Farnham, David A. Dixon, and Joseph C. Calabrese
pp 8453 - 8461; DOI:
10.1021/ja00233a022
PDF
Monooxygenase-like oxidation of hydrocarbons by hydrogen peroxide catalyzed by manganese porphyrins and imidazole: selection of the best catalytic system and nature of the active oxygen species
P. Battioni, J. P. Renaud, J. F. Bartoli, M. Reina-Artiles, M. Fort, and Daniel Mansuy
pp 8462 - 8470; DOI:
10.1021/ja00233a023
PDF
Metal-ion recognition. 2. Structural dislocation behavior in the interaction of zinc(II) and cadmium(II) with a series of O2N3-donor macrocycles
Kenneth R. Adam, Keith P. Dancey, Anthony J. Leong, Leonard F. Lindoy, Brian J. McCool, Mary McPartlin, and Peter A. Tasker
pp 8471 - 8477; DOI:
10.1021/ja00233a024
PDF
Chemistry of oxaziridines. 11. (Camphorylsulfonyl)oxaziridine: synthesis and properties
Franklin A. Davis, James C. Towson, Michael C. Weismiller, Sankar Lal, and Patrick J. Carroll
pp 8477 - 8482; DOI:
10.1021/ja00233a025
PDF
Total synthesis of (+)-halenaquinol and (+)-halenaquinone. Experimental proof of their absolute stereostructures theoretically determined
Nobuyuki Harada, Tatsuo Sugioka, Yusuke Ando, Hisashi Uda, and Takeo Kuriki
pp 8483 - 8487; DOI:
10.1021/ja00233a026
PDF
Charge density distribution in tetrasulfur tetraimide (S4(NH)4)
David Gregson, Gerhard Klebe, and Hartmut Fuess
pp 8488 - 8493; DOI:
10.1021/ja00233a027
PDF
A new approach to the construction of radialenes by the nickel-catalyzed cyclooligomerization of [3]cumulenes (butatrienes)
Masahiko Iyoda, Shigeyoshi Tanaka, Hiroyuki Otani, Masanori Nose, and Masaji Oda
pp 8494 - 8500; DOI:
10.1021/ja00233a028
PDF
Static structure of a regular intermediate controls the course of the thermal 1,3-sigmatropic rearrangement of 6-methylenebicyclo[3.1.0]hex-2-enyl derivatives
Steven Pikulin and Jerome A. Berson
pp 8500 - 8512; DOI:
10.1021/ja00233a029
PDF
Stereoelectronic effects in sulfate diesters and sulfuric acid
Gordon Lowe, Gregory R. J. Thatcher, James C. G. Turner, Anne Waller, and David J. Watkin
pp 8512 - 8520; DOI:
10.1021/ja00233a030
PDF
Acidities of glycine Schiff bases and alkylation of their conjugate bases
Martin J. O'Donnell, William D. Bennett, William A. Bruder, William N. Jacobsen, Keith Knuth, Brigitte LeClef, Robin L. Polt, Frederick G. Bordwell, Susan R. Mrozack, and Thomas A. Cripe
pp 8520 - 8525; DOI:
10.1021/ja00233a031
PDF
Formation of peptide amides by peptidylglycine .alpha.-amidating monooxygenase: a new assay and stereochemistry of hydrogen loss
Shawn E. Ramer, Hengmiao Cheng, Monica M. Palcic, and John C. Vederas
pp 8526 - 8532; DOI:
10.1021/ja00233a032
PDF
A reversible photoconversion between the carbon monoxide-induced axial 2.06 and the rhombic 2.10 ESR signals of the periplasmic hydrogenase from Desulfovibrio vulgaris
Daulat S. Patil, Huynh Boi Hanh, Shao H. He, Harry D. Peck Jr., Daniel V. DerVartanian, and Jean LeGall
pp 8533 - 8534; DOI:
10.1021/ja00233a033
PDF
A general treatment of hydrogen bond complexation constants in tetrachloromethane
Michael H. Abraham, Priscilla L. Grellier, David V. Prior, Robert W. Taft, Jeffrey J. Morris, Peter J. Taylor, Christian Laurence, Michel Berthelot, Ruth M. Doherty, and et al.
pp 8534 - 8536; DOI:
10.1021/ja00233a034
PDF
Direct electrochemistry of the undecapeptide from cytochrome c (microperoxidase) at a glassy carbon electrode
Roberto Santucci, Hans Reinhard, and Maurizio Brunori
pp 8536 - 8537; DOI:
10.1021/ja00233a035
PDF
Potential building blocks for molecular ferromagnets: [Mn12O12(O2CPh)16(H2O)4] with a S = 14 ground state
Peter D. W. Boyd, Qiaoying Li, John B. Vincent, Kirsten Folting, Hsiu Rong Chang, William E. Streib, John C. Huffman, George Christou, and David N. Hendrickson
pp 8537 - 8539; DOI:
10.1021/ja00233a036
PDF
Antineoplastic agents. 160. Isolation and structure of combretastatin D-1: a cell growth inhibitory macrocyclic lactone from Combretum caffrum
George R. Pettit, Sheo Bux Singh, and Margaret L. Niven
pp 8539 - 8540; DOI:
10.1021/ja00233a037
PDF
Epoxidation of olefins on silver: conversion of norbornene to norbornene oxide by atomic oxygen on silver(110)
Jeffrey T. Roberts and Robert J. Madix
pp 8540 - 8541; DOI:
10.1021/ja00233a038
PDF
Observation and geometry assignment of conformations of styrenes in the ground and first excited singlet state
Jeffrey I. Seeman, V. H. Grassian, and E. R. Bernstein
pp 8542 - 8543; DOI:
10.1021/ja00233a039
PDF
Synthesis and chemistry of a dinuclear iridium bis-.mu.-oxo complex. Observation of oxygen transfer and phosphorus-carbon bond cleavage
William D. McGhee, Thomas Foo, Frederick J. Hollander, and Robert G. Bergman
pp 8543 - 8545; DOI:
10.1021/ja00233a040
PDF
Tubular silicate-layered silicate intercalation compounds: a new family of pillared clays
Ivy D. Johnson, Todd A. Werpy, and Thomas J. Pinnavaia
pp 8545 - 8547; DOI:
10.1021/ja00233a041
PDF
Assignment of a new conformation-sensitive UV resonance Raman band in peptides and proteins
Sunho Song, Sanford A. Asher, Samuel Krimm, and Jagdeesh Bandekar
pp 8547 - 8548; DOI:
10.1021/ja00233a042
PDF
A reversible photoredox reaction. Electron-transfer photoreduction of .beta.-lapachone by triethylamine
Xiaohong Ci, Rosaly S. Da Silva, Joshua L. Goodman, David E. Nicodem, and David G. Whitten
pp 8548 - 8550; DOI:
10.1021/ja00233a043
PDF
Cross polarization magic angle spinning proton NMR spectroscopy of solids
Richard C. Crosby, Ronnie L. Reese, and James F. Haw
pp 8550 - 8551; DOI:
10.1021/ja00233a044
PDF
Identification of a covalent .alpha.-D-glucopyranosyl enzyme intermediate formed on a .beta.-glucosidase
Stephen G. Withers and Ian P. Street
pp 8551 - 8553; DOI:
10.1021/ja00233a045
PDF
Synthesis and reactivity of cobalt(III) complexes bearing primary- and secondary-side cyclodextrin binding sites. A tale of two CD's
Engin U. Akkaya and Anthony W. Czarnik
pp 8553 - 8554; DOI:
10.1021/ja00233a046
PDF
Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cis-hexatriene to 1,3-cyclohexadiene
John E. Baldwin, V. Prakash Reddy, B. A. Hess, and L. J. Schaad
pp 8554 - 8555; DOI:
10.1021/ja00233a047
PDF
Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene
John E. Baldwin, V. Prakash Reddy, L. J. Schaad, and B. A. Hess
pp 8555 - 8556; DOI:
10.1021/ja00233a048
PDF
Nodularin, microcystin, and the configuration of Adda
Kenneth L. Rinehart, Kenichi Harada, Michio Namikoshi, Choryu Chen, Carl A. Harvis, Murray H. G. Munro, John W. Blunt, Paul E. Mulligan, Val R. Beasley, and et al.
pp 8557 - 8558; DOI:
10.1021/ja00233a049
PDF
DNA promotes the reaction of cis-diamminedichloroplatinum(II) with the exocyclic amino groups of ethidium bromide
Wesley I. Sundquist, Daniel P. Bancroft, Laurent Chassot, and Stephen J. Lippard
pp 8559 - 8560; DOI:
10.1021/ja00233a050
PDF
Transition-metal-centered radicals in organic synthesis. Titanium(III)-induced cyclization of epoxy olefins
William A. Nugent and T. V. RajanBabu
pp 8561 - 8562; DOI:
10.1021/ja00233a051
PDF
Electrosynthesis of porphyrins from a,c-biladienes
D. Jeyakumar, Kevin M. Snow, and Kevin M. Smith
pp 8562 - 8564; DOI:
10.1021/ja00233a052
PDF
Para hydrogen induced polarization in hydrogenation reactions catalyzed by ruthenium phosphine complexes
Rein U. Kirss, Thomas C. Eisenschmid, and Richard Eisenberg
pp 8564 - 8566; DOI:
10.1021/ja00233a053
PDF
Anion radicals of porphycenes: first ESR and ENDOR characterization
Jenny Schluepmann, Martina Huber, Moshe Toporowicz, Matthias Koecher, Emanuel Vogel, Haim Levanon, and Klaus Moebius
pp 8566 - 8567; DOI:
10.1021/ja00233a054
PDF
ESR evidence for the 2A1 state of the hexamethyl (Dewar) benzene radical cation
Christopher J. Rhodes
pp 8567 - 8568; DOI:
10.1021/ja00233a055
PDF
Substitution competes with elimination in a gas-phase anion-molecule reaction
Rachel C. Lum and Joseph J. Grabowski
pp 8568 - 8570; DOI:
10.1021/ja00233a056
PDF
Nickel(0)-catalyzed reaction of diynes with aldehydes
Tetsuo Tsuda, Takao Kiyoi, Toshiki Miyane, and Takeo Saegusa
pp 8570 - 8572; DOI:
10.1021/ja00233a057
PDF
pH dependence of the mechanism of hydrolysis of benzo[a]pyrene-cis-7,8-diol 9,10-epoxide catalyzed by DNA, poly(G), and poly(A) [Erratum to document cited in CA106(15):114999v]
Nafisa B. Islam, Dale L. Whalen, H. Yagi, and Donald M. Jerina
pp 8572 - 8572; DOI:
10.1021/ja00233a058
PDF
Reaction of dinitrogen pentoxide with fluoranthene [Erratum to document cited in CA105(3):23766e]
Barbara Zielinska, Janet Arey, Roger Atkinson, Thomas Ramdahl, Arthur M. Winer, and James N. Pitts
pp 8572 - 8572; DOI:
10.1021/ja00233a059
PDF
Computer Software Reviews

pp 8572 - 8573; DOI:
10.1021/ja00233a600
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Book Reviews

pp 8573 - 8578; DOI:
10.1021/ja00233a601
PDF

Issue 26


The fate of thermally produced cyclohexyloxyl radicals as determined by mass spectrometry
Charles N. McEwen and J. Douglas Druliner
pp 8579 - 8583; DOI:
10.1021/ja00234a001
PDF
Tellurium-125 solid-state NMR spectra and secondary bonding arrangements for some salts of the trimethyltelluronium and triphenyltelluronium cations
Michael J. Collins, John A. Ripmeester, and Jeffery F. Sawyer
pp 8583 - 8590; DOI:
10.1021/ja00234a002
PDF
Dodecahedrane. Improved synthetic access to, and monofunctionalization of, the spherical hydrocarbon. Spectral properties of the derivatives
Leo A. Paquette, Jeffrey C. Weber, Tomoshige Kobayashi, and Yuji Miyahara
pp 8591 - 8599; DOI:
10.1021/ja00234a003
PDF
Stable carbocations. Part 275. The dodecahedryl cation and 1,16-dodecahedryl dication. Proton and carbon-13 NMR spectroscopic studies and theoretical investigations
George A. Olah, G. K. Surya Prakash, Wolf Dieter Fessner, Tomoshige Kobayashi, and Leo A. Paquette
pp 8599 - 8605; DOI:
10.1021/ja00234a004
PDF
Docking calculations on ferrocene complexation with cyclodextrins
F. M. Menger and M. J. Sherrod
pp 8606 - 8611; DOI:
10.1021/ja00234a005
PDF
Molecular modeling calculations on the acylation of .beta.-cyclodextrin by ferrocenylacrylate esters
Hans Jurgen Thiem, Michael Brandl, and Ronald Breslow
pp 8612 - 8616; DOI:
10.1021/ja00234a006
PDF
The shape of a three-dimensional binding site of rhodopsin based on molecular modeling analysis of isomeric and other visual pigment analogs. Bioorganic studies of visual pigments. 11
Robert S. H. Liu and Taraneh Mirzadegan
pp 8617 - 8623; DOI:
10.1021/ja00234a007
PDF
Amplified mass immunosorbent assay with a quartz crystal microbalance
Richard C. Ebersole and Michael D. Ward
pp 8623 - 8628; DOI:
10.1021/ja00234a008
PDF
Synthesis, characterization, and reactivity of oxomanganese(IV) porphyrin complexes
John T. Groves and Michael K. Stern
pp 8628 - 8638; DOI:
10.1021/ja00234a009
PDF
Crystal structures of three new copper(II) halide layered perovskites: structural, crystallographic, and magnetic correlations
Roger Willett, Helen Place, and Michael Middleton
pp 8639 - 8650; DOI:
10.1021/ja00234a010
PDF
Structural aspects of metal ion carboxylate interactions
Christopher J. Carrell, H. L. Carrell, Jonah Erlebacher, and Jenny P. Glusker
pp 8651 - 8656; DOI:
10.1021/ja00234a011
PDF
Platina(IV)cyclopentanes. Stereoselective synthesis and structural characterization of trisubstituted platinacyclopentanes
W. D. Neilsen, R. D. Larsen, and P. W. Jennings
pp 8657 - 8659; DOI:
10.1021/ja00234a012
PDF
Photodimerization of singlet trans- and cis-anethole. Concerted or stepwise?
Frederick D. Lewis and Masanobu Kojima
pp 8660 - 8664; DOI:
10.1021/ja00234a013
PDF
Electron-transfer-induced photoisomerization, dimerization, and oxygenation of trans- and cis-anethole. The role of monomer and dimer cation radicals
Frederick D. Lewis and Masanobu Kojima
pp 8664 - 8670; DOI:
10.1021/ja00234a014
PDF
Synthesis and cycloaddition reactivity of selenoaldehydes
Peter T. Meinke and Grant A. Krafft
pp 8671 - 8679; DOI:
10.1021/ja00234a015
PDF
Preparation and cycloaddition reactions of selenoketones
Peter T. Meinke and Grant A. Krafft
pp 8679 - 8685; DOI:
10.1021/ja00234a016
PDF
Design and synthesis of new ferroelectric liquid crystals. 5. Properties of some chiral fluorinated FLCs: a direct connection between macroscopic properties and absolute configuration in a fluid phase
David M. Walba, Homaune A. Razavi, Noel A. Clark, and Devendra S. Parmar
pp 8686 - 8691; DOI:
10.1021/ja00234a017
PDF
Conformational analysis by the ring-current method. The structure of 2,2,12,12-tetramethyl[4.4]metacyclophane
Yoshimasa Fukazawa, Koji Ogata, and Shuji Usui
pp 8692 - 8693; DOI:
10.1021/ja00234a018
PDF
Orientation dependence of 2H NMR spin-lattice relaxation rates for cholesterol in macroscopically oriented multibilayers
Jean Marc Bonmatin, Ian C. P. Smith, Harold C. Jarrell, and David J. Siminovitch
pp 8693 - 8695; DOI:
10.1021/ja00234a019
PDF
Unsaturated transition-metal complexes in solution: naked Cr(CO)5 in cyclohexane solution observed by picosecond IR transient absorption
Liang Wang, Xinming Zhu, and Kenneth G. Spears
pp 8695 - 8696; DOI:
10.1021/ja00234a020
PDF
Stereoselective synthesis of (.+-.)-indolizidines 167B, 205A, and 207A. Enantioselective synthesis of (-)-indolizidine 209B
Adrian L. Smith, Simon F. Williams, Andrew B. Holmes, Leslie R. Hughes, Colin Swithenbank, and Zev Lidert
pp 8696 - 8698; DOI:
10.1021/ja00234a021
PDF
Intramolecular reactions of 2-O-organosilyl glycosides. Highly stereoselective synthesis of C-furanosides
Olivier R. Martin, S. Prahlada Rao, Kenneth G. Kurz, and Hamdy A. El-Shenawy
pp 8698 - 8700; DOI:
10.1021/ja00234a022
PDF
Photochemical azo metathesis by tungsten carbene (OC)5W:C(OCH3)CH3. Isolation of a of a zwitterionic intermediate
Hanadi F. Sleiman and Lisa McElwee-White
pp 8700 - 8701; DOI:
10.1021/ja00234a023
PDF
First-principle calculations of the ionization potentials and electron affinities of the spheroidal molecules carbon (C60) and lanthanum carbude (LaC60)
Arne Rosen and Bo Waestberg
pp 8701 - 8703; DOI:
10.1021/ja00234a024
PDF
Pentadienyl chemistry of niobium and tantalum. Surprising differences and new diene and dienyl coordination patterns
Enrique Melendez, Atta M. Arif, Arnold L. Rheingold, and Richard D. Ernst
pp 8703 - 8704; DOI:
10.1021/ja00234a025
PDF
Synthesis and structure of closo-Sn9Cr(CO)34-: The first member in a new class of polyhedral clusters
Bryan W. Eichhorn, Robert C. Haushalter, and William T. Pennington
pp 8704 - 8706; DOI:
10.1021/ja00234a026
PDF
Synthesis and reactivity of silyliron porphyrin complexes
Yunghee Oh Kim and Harold M. Goff
pp 8706 - 8707; DOI:
10.1021/ja00234a027
PDF
Transient formation of hydrogen tetraoxide [HOOOOH] from the dimerization of perhydroxyl (HOO.cntdot.): concerted homolytic dissociation to singlet oxygen(1O2) and hydrogen peroxide
Hiroshi Sugimoto, Donald T. Sawyer, and Jeffrey R. Kanofsky
pp 8707 - 8708; DOI:
10.1021/ja00234a028
PDF
Surface photochemistry. 4. Quenching of methyl iodide on platinum(111)
Z. M. Liu, S. Akhter, B. Roop, and J. M. White
pp 8708 - 8710; DOI:
10.1021/ja00234a029
PDF
Kinetic studies of the sphere-rod transition of micelles
Shoji Harada, Nobuya Fujita, and Takayuki Sano
pp 8710 - 8711; DOI:
10.1021/ja00234a030
PDF
Solution study and molecular structure of a [3]-catenand. Intramolecular interaction between the two peripheral rings
Jean Guilhem, Claudine Pascard, Jean Pierre Sauvage, and Jean Weiss
pp 8711 - 8713; DOI:
10.1021/ja00234a031
PDF
Antibody catalysis in reverse micelles
Charles N. Durfor, Richard J. Bolin, Renee J. Sugasawara, Richard J. Massey, Jeffrey Jacobs, and Peter G. Schultz
pp 8713 - 8714; DOI:
10.1021/ja00234a032
PDF
Heme model studies related to cytochrome P-450 reactions: preparation of iron porphyrin complexes with carbenes bearing a .beta.-oxygen atom and their transformation into iron-N-alkylporphyrins and iron-metallacyclic complexes
Isabelle Artaud, Nathalie Gregoire, Jean Paul Battioni, Daniel Dupre, and Daniel Mansuy
pp 8714 - 8716; DOI:
10.1021/ja00234a033
PDF
The use of alkoxy-substituted anomeric radicals for the construction of .beta.-glycosides
Daniel Kahne, Dan Yang, Jung Jin Lim, Raymond Miller, and Eduardo Paguaga
pp 8716 - 8717; DOI:
10.1021/ja00234a034
PDF
The anthranilate amide of "polyethylene carboxylic acid" shows an exceptionally large change with pH in its wettability by water
Mark D. Wilson and George M. Whitesides
pp 8718 - 8719; DOI:
10.1021/ja00234a035
PDF
Comparison of migratory aptitudes of hydride and alkyl groups in .beta.-migratory insertion reactions of Cp*(P(OMe)3)Rh(C2H4)R+ (R = H, CH2CH3)
M. Brookhart and D. M. Lincoln
pp 8719 - 8720; DOI:
10.1021/ja00234a036
PDF
Chiral lithium: conformation and dynamic behavior of monomeric neopentyllithium-N,N,N',N',N''-pentamethyldiethylenetriamine complex
Gideon Fraenkel and William R. Winchester
pp 8720 - 8721; DOI:
10.1021/ja00234a037
PDF
Structure of the 3 iron-4 sulfur cluster in Desulfovibrio gigas ferredoxin II
Charles R. Kissinger, Elinor T. Adman, Larry C. Sieker, and Lyle H. Jensen
pp 8721 - 8723; DOI:
10.1021/ja00234a038
PDF
An ionic system with critical point at 44.degree.C
Rajiv R. Singh and Kenneth S. Pitzer
pp 8723 - 8724; DOI:
10.1021/ja00234a039
PDF
XPS data for linear three-center, four-electron bonding in sulfur species
Paul G. Gassman, Matthew R. Callstrom, J. C. Martin, and Joseph C. Rongione
pp 8724 - 8725; DOI:
10.1021/ja00234a040
PDF
A stable .eta.2-dihydrogen complex of cobalt. Role of the hydrogen-hydrogen interaction in hydrogen transfer from metal to alkene
Claudio Bianchini, Carlo Mealli, Andrea Meli, Maurizio Peruzzini, and Fabrizio Zanobini
pp 8725 - 8726; DOI:
10.1021/ja00234a041
PDF
The chromium and tungsten pentacarbonyl groups as reactivity auxiliaries in [2 + 2] cycloadditions
Katherine L. Faron and William D. Wulff
pp 8727 - 8729; DOI:
10.1021/ja00234a042
PDF
Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes
Patrick J. Walsh, Frederick J. Hollander, and Robert G. Bergman
pp 8729 - 8731; DOI:
10.1021/ja00234a043
PDF
Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3
Christopher C. Cummins, Steven M. Baxter, and Peter T. Wolczanski
pp 8731 - 8733; DOI:
10.1021/ja00234a044
PDF
Isolation and structure of the novel dihydroxamate siderophore alcaligin
Takayuki Nishio, Nobuo Tanaka, Jun Hiratake, Yukiteru Katsube, Yuzaburo Ishida, and Junichi Oda
pp 8733 - 8734; DOI:
10.1021/ja00234a045
PDF
Total synthesis of (.+-.)-methyl homosecodaphniphyllate. A remarkable new tetracyclization reaction
Roger B. Ruggeri, Marvin M. Hansen, and Clayton H. Heathcock
pp 8734 - 8736; DOI:
10.1021/ja00234a046
PDF
A new and practical method of decarboxylation: photosensitized decarboxylation of N-acyloxyphthalimides via electron-transfer mechanism
Keiji Okada, Kazushige Okamoto, and Masaji Oda
pp 8736 - 8738; DOI:
10.1021/ja00234a047
PDF
Computer Software Reviews

pp 8738 - 8740; DOI:
10.1021/ja00234a600
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Book Reviews

pp 8741 - 8744; DOI:
10.1021/ja00234a601
PDF