Volume 127
Main Index

Issue 01

JACS Policy on Manuscript Processing Peter J. Stang, Editor p 1 DOI: 10.1021/ja040244+

Mixed Self-Assembled Monolayers of Alkanethiolates on Ultrasmooth Gold Do Not Exhibit Contact-Angle Hysteresis Pooja Gupta, Abraham Ulman, Stephanie Fanfan, Alexander Korniakov, and Katja Loos pp 4–5 DOI: 10.1021/ja044623e

Single Crystalline Magnetite Nanotubes Zuqin Liu, Daihua Zhang, Song Han, Chao Li, Bo Lei, Weigang Lu, Jiye Fang, and Chongwu Zhou pp 6–7 DOI: 10.1021/ja0445239 Supporting Info

Spontaneous Dissolution of a Single-Wall Carbon Nanotube Salt Alain Pénicaud, Philippe Poulin, Alain Derré, Eric Anglaret, and Pierre Petit pp 8–9 DOI: 10.1021/ja0443373 Supporting Info

Novel Substituent Effects on the Mechanism of the Thermal Denitrogenation of 2,3-Diazabicyclo[2.2.1]hept-2-ene Derivatives, Stepwise versus Concerted Manabu Abe, Chizuko Ishihara, Satoshi Kawanami, and Araki Masuyama pp 10–11 DOI: 10.1021/ja044269k Supporting Info

Glycosidic Linkage Rotations Determine Amylose Stretching Mechanism Michelle Kuttel and Kevin J. Naidoo pp 12–13 DOI: 10.1021/ja047138s Supporting Info

DNA-Directed Self-Assembling of Carbon Nanotubes Sinan Li, Pingang He, Jianhua Dong, Zhixin Guo, and Liming Dai pp 14–15 DOI: 10.1021/ja0446045

Resolving Conflicting Crystallographic and NMR Models for Solution-State DNA with Solution X-ray Diffraction Xiaobing Zuo and David M. Tiede pp 16–17 DOI: 10.1021/ja044533+ Supporting Info

Total Synthesis of Absinthin Weihe Zhang, Shengjun Luo, Fang Fang, Qingshou Chen, Hanwei Hu, Xueshun Jia, and Hongbin Zhai pp 18–19 DOI: 10.1021/ja0439219 Supporting Info

Are Stone−Wales Defect Sites Always More Reactive Than Perfect Sites in the Sidewalls of Single-Wall Carbon Nanotubes? Xin Lu, Zhongfang Chen, and Paul v. R. Schleyer pp 20–21 DOI: 10.1021/ja0447053 Supporting Info

A Needle-and-Thread Approach to Bilayer Transport:  Permeation of a Molecular Umbrella−Oligonucleotide Conjugate across a Phospholipid Membrane Vaclav Janout and Steven L. Regen pp 22–23 DOI: 10.1021/ja044257z Supporting Info

Minimalist Protein Design:  A β-Hairpin Peptide That Binds ssDNA Sara M. Butterfield, W. John Cooper, and Marcey L. Waters pp 24–25 DOI: 10.1021/ja045002o Supporting Info

Intense Near-Infrared Optical Absorbing Emerald Green [60]Fullerenes Taizoon Canteenwala, Prashant A. Padmawar, and Long Y. Chiang pp 26–27 DOI: 10.1021/ja044409q Supporting Info

Synthetic Control of Pt···Pt Separation and Photophysics of Binuclear Platinum Complexes Biwu Ma, Jian Li, Peter I. Djurovich, Muhammed Yousufuddin, Robert Bau, and Mark E. Thompson pp 28–29 DOI: 10.1021/ja044313w Supporting Info

Stepwise Molding of a Highly Selective Ribonucleopeptide Receptor Shin-ichi Sato, Masatora Fukuda, Masaki Hagihara, Yukiko Tanabe, Katsutoshi Ohkubo, and Takashi Morii pp 30–31 DOI: 10.1021/ja0445589 Supporting Info

Enantioselective Organocatalytic Hydride Reduction Stéphane G. Ouellet, Jamison B. Tuttle, and David W. C. MacMillan pp 32–33 DOI: 10.1021/ja043834g Supporting Info

Heterodimers of Nanoparticles:  Formation at a Liquid−Liquid Interface and Particle-Specific Surface Modification by Functional Molecules Hongwei Gu, Zhimou Yang, Jinhao Gao, C. K. Chang, and Bing Xu pp 34–35 DOI: 10.1021/ja045220h Supporting Info

Formation and Spatio-Temporal Evolution of Periodic Structures in Lipid Bilayers Sharon Rozovsky, Yoshihisa Kaizuka, and Jay T. Groves pp 36–37 DOI: 10.1021/ja046300o Supporting Info

Nanocrystal-Based Bioelectronic Coding of Single Nucleotide Polymorphisms Guodong Liu, Thomas M. H. Lee, and Joseph Wang pp 38–39 DOI: 10.1021/ja043780a Supporting Info

The Origin of Stark Splitting in the Initial Photoproduct State of MbCO Karin Nienhaus, John S. Olson, Stefan Franzen, and G. Ulrich Nienhaus pp 40–41 DOI: 10.1021/ja0466917 Supporting Info

Observation of Anomalous C−O Bond Weakening on Discandium and Activation Process to CO Dissociation Ling Jiang and Qiang Xu pp 42–43 DOI: 10.1021/ja0442421 Supporting Info

Efficient Generation of 2‘-Deoxyuridin-5-yl at 5‘-(G/C)AAXUXU-3‘ (X = Br, I) Sequences in Duplex DNA under UV Irradiation Takayoshi Watanabe, Toshikazu Bando, Yan Xu, Ryu Tashiro, and Hiroshi Sugiyama pp 44–45 DOI: 10.1021/ja0454743 Supporting Info

Aqueous Suspension Polymerization of Isobutene Initiated by 1,2-C6F4[B(C6F5)2]2 Stewart P. Lewis, Lee D. Henderson, Brett D. Chandler, Masood Parvez, Warren E. Piers, and Scott Collins pp 46–47 DOI: 10.1021/ja0445387 Supporting Info

Protection−Deprotection Chemistry to Control Styrene Self-Directed Line Growth on Hydrogen-Terminated Si(100) Jason L. Pitters and Robert A. Wolkow pp 48–49 DOI: 10.1021/ja045012p

Chiral Lewis Acid-Catalyzed Highly Enantioselective [4 + 3] Cycloaddition Reactions of Nitrogen-Stabilized Oxyallyl Cations Derived from Allenamides Jian Huang and Richard P. Hsung pp 50–51 DOI: 10.1021/ja044760b Supporting Info

Multipolymer Solution-Phase Reactions: Application to the Mitsunobu Reaction Andrew M. Harned, Helen Song He, Patrick H. Toy, Daniel L. Flynn, and Paul R. Hanson pp 52–53 DOI: 10.1021/ja045188r Supporting Info

Catalytic Asymmetric Arylative Cyclization of Alkynals:  Phosphine-Free Rhodium/Diene Complexes as Efficient Catalysts Ryo Shintani, Kazuhiro Okamoto, Yusuke Otomaru, Kazuhito Ueyama, and Tamio Hayashi pp 54–55 DOI: 10.1021/ja044021v Supporting Info

Unusual Ligand Discrimination by a Myoglobin Reconstituted with a Hydrophobic Domain-Linked Heme Hideaki Sato, Masahiro Watanabe, Yoshio Hisaeda, and Takashi Hayashi pp 56–57 DOI: 10.1021/ja044984u Supporting Info

Cationic Carbon Nanotubes Bind to CpG Oligodeoxynucleotides and Enhance Their Immunostimulatory Properties Alberto Bianco, Johan Hoebeke, Sylvie Godefroy, Olivier Chaloin, Davide Pantarotto, Jean-Paul Briand, Sylviane Muller, Maurizio Prato, and Charalambos D. Partidos pp 58–59 DOI: 10.1021/ja044293y Supporting Info

Periodic Mesoporous Organosilica with Large Heterocyclic Bridging Groups Oksana Olkhovyk and Mietek Jaroniec pp 60–61 DOI: 10.1021/ja043941a Supporting Info

Enantioselective Alkylations of Tributyltin Enolates Catalyzed by Cr(salen)Cl:  Access to Enantiomerically Enriched All-Carbon Quaternary Centers Abigail G. Doyle and Eric N. Jacobsen pp 62–63 DOI: 10.1021/ja043601p Supporting Info

Exploiting the Reaction Flexibility of a Type III Polyketide Synthase through in Vitro Pathway Manipulation Jae-Cheol Jeong, Aravind Srinivasan, Sabine Grüschow, Horacio Bach, David H. Sherman, and Jonathan S. Dordick pp 64–65 DOI: 10.1021/ja0441559 Supporting Info

Charge Transport Properties of Tris(8-hydroxyquinolinato)aluminum(III):  Why It Is an Electron Transporter Bo Chao Lin, Cheu P. Cheng, Zhi-Qiang You, and Chao-Ping Hsu pp 66–67 DOI: 10.1021/ja045087t Supporting Info

A Design of Fluorescent Probes for Superoxide Based on a Nonredox Mechanism Hatsuo Maeda, Kayoko Yamamoto, Yoko Nomura, Iho Kohno, Leila Hafsi, Noritsugu Ueda, Shoko Yoshida, Masako Fukuda, Yuka Fukuyasu, Yuji Yamauchi, and Norio Itoh pp 68–69 DOI: 10.1021/ja047018k Supporting Info

Synthesis of a Hafnocene Disilene Complex Roland Fischer, Michaela Zirngast, Michaela Flock, Judith Baumgartner, and Christoph Marschner pp 70–71 DOI: 10.1021/ja0464387 Supporting Info

Palladium-Catalyzed Intramolecular Coupling between Aryl Iodides and Allyl Moieties via Thermal and Microwave-Assisted Conditions Mark Lautens, Eiji Tayama, and Christelle Herse pp 72–73 DOI: 10.1021/ja043898r Supporting Info

An Extremely Stable and Orthogonal DNA Base Pair with a Simplified Three-Carbon Backbone Lilu Zhang and Eric Meggers pp 74–75 DOI: 10.1021/ja043904j Supporting Info

Studies on the Mechanism of the Photo-Induced DNA Damage in the Presence of Acridizinium SaltsInvolvement of Singlet Oxygen and an Unusual Source for Hydroxyl Radicals Cornelia Bohne, Katja Faulhaber, Bernd Giese, Angelika Häfner, Andrea Hofmann, Heiko Ihmels, Anne-Kathrin Köhler, Saana Perä, Friedemann Schneider, and Molina A. L. Sheepwash pp 76–85 DOI: 10.1021/ja046189m

The Electronic Spectrum of the UO2 Molecule Laura Gagliardi, Michael C. Heaven, Jesper Wisborg Krogh, and Björn O. Roos pp 86–91 DOI: 10.1021/ja044940l

EPR and Optical Spectroscopic Studies of Met80X Mutants of Yeast Ferricytochrome c. Models for Intermediates in the Alkaline Transition Gary G. Silkstone, Christopher E. Cooper, Dimitri Svistunenko, and Michael T. Wilson pp 92–99 DOI: 10.1021/ja045719b

A Quantitative Reconstruction of the Amide I Contour in the IR Spectra of Globular Proteins:  From Structure to Spectrum Joseph W. Brauner, Carol R. Flach, and Richard Mendelsohn pp 100–109 DOI: 10.1021/ja0400685

Polytheonamides A and B, Highly Cytotoxic, Linear Polypeptides with Unprecedented Structural Features, from the Marine Sponge, Theonella swinhoei Toshiyuki Hamada, Shigeki Matsunaga, Gen Yano, and Nobuhiro Fusetani pp 110–118 DOI: 10.1021/ja045749e Supporting Info

Enantio- and Diastereoselective Michael Reaction of 1,3-Dicarbonyl Compounds to Nitroolefins Catalyzed by a Bifunctional Thiourea Tomotaka Okino, Yasutaka Hoashi, Tomihiro Furukawa, Xuenong Xu, and Yoshiji Takemoto pp 119–125 DOI: 10.1021/ja044370p Supporting Info

Unusual Palladium-Catalyzed Silaboration of Allenes Using Organic Iodides as Initiators:  Mechanism and Application Kuo-Jui Chang, Dinesh Kumar Rayabarapu, Feng-Yu Yang, and Chien-Hong Cheng pp 126–131 DOI: 10.1021/ja044662q Supporting Info

Origin of Selectivity in the Antibody 20F10-Catalyzed Yang Cyclization Sigal Saphier, Yunfeng Hu, Subhash C. Sinha, K. N. Houk, and Ehud Keinan pp 132–145 DOI: 10.1021/ja045419u

Detecting Protein−Protein Interactions with a Green Fluorescent Protein Fragment Reassembly Trap:  Scope and Mechanism Thomas J. Magliery, Christopher G. M. Wilson, Weilan Pan, Dennis Mishler, Indraneel Ghosh, Andrew D. Hamilton, and Lynne Regan pp 146–157 DOI: 10.1021/ja046699g Supporting Info

Crystal Structures of Oxidized and Reduced Stellacyanin from Horseradish Roots Michael Koch, Milko Velarde, Mark D. Harrison, Steffi Echt, Markus Fischer, Albrecht Messerschmidt, and Christopher Dennison pp 158–166 DOI: 10.1021/ja046184p Supporting Info

Relationship between Side Chain Structure and 14-Helix Stability of β3-Peptides in Water Joshua A. Kritzer, Julian Tirado-Rives, Scott A. Hart, James D. Lear, William L. Jorgensen, and Alanna Schepartz pp 167–178 DOI: 10.1021/ja0459375

Phosphorescent Organogels via “Metallophilic” Interactions for Reversible RGB−Color Switching Akihiro Kishimura, Takashi Yamashita, and Takuzo Aida pp 179–183 DOI: 10.1021/ja0441007 Supporting Info

Rational Design of a Chromo- and Fluorogenic Hybrid Chemosensor Material for the Detection of Long-Chain Carboxylates Ana B. Descalzo, Knut Rurack, Hardy Weisshoff, Ramón Martínez-Máñez, M. Dolores Marcos, Pedro Amorós, Katrin Hoffmann, and Juan Soto pp 184–200 DOI: 10.1021/ja045683n Supporting Info

Nickel-Catalyzed Addition of Dimethylzinc to Aldehydes across Alkynes and 1,3-Butadiene:  An Efficient Four-Component Connection Reaction Masanari Kimura, Akihiro Ezoe, Masahiko Mori, and Yoshinao Tamaru pp 201–209 DOI: 10.1021/ja0469030 Supporting Info

Copper(I)-Catalyzed Synthesis of Azoles. DFT Study Predicts Unprecedented Reactivity and Intermediates Fahmi Himo, Timothy Lovell, Robert Hilgraf, Vsevolod V. Rostovtsev, Louis Noodleman, K. Barry Sharpless, and Valery V. Fokin pp 210–216 DOI: 10.1021/ja0471525 Supporting Info

ALARM NMR:  A Rapid and Robust Experimental Method To Detect Reactive False Positives in Biochemical Screens Jeffrey R. Huth, Renaldo Mendoza, Edward T. Olejniczak, Robert W. Johnson, Darlene A. Cothron, Yaya Liu, Claude G. Lerner, Jun Chen, and Philip J. Hajduk pp 217–224 DOI: 10.1021/ja0455547 Supporting Info

Asymmetric Total Syntheses of Tuberostemonine, Didehydrotuberostemonine, and 13-Epituberostemonine Peter Wipf and Stacey R. Spencer pp 225–235 DOI: 10.1021/ja044280k Supporting Info

Directly meso−meso Linked Porphyrin Rings:  Synthesis, Characterization, and Efficient Excitation Energy Hopping Yasuyuki Nakamura, In−Wook Hwang, Naoki Aratani, Tae Kyu Ahn, Dah Mee Ko, Akihiko Takagi, Tomoji Kawai, Takuya Matsumoto, Dongho Kim, and Atsuhiro Osuka pp 236–246 DOI: 10.1021/ja045254p Supporting Info

Highly Efficient Nickel-Catalyzed Cross-Coupling of Succinic and Glutaric Anhydrides with Organozinc Reagents Eric A. Bercot and Tomislav Rovis pp 247–254 DOI: 10.1021/ja044588b Supporting Info

Two-Photon Photosensitized Production of Singlet Oxygen in Water Peter K. Frederiksen, Sean P. McIlroy, Christian B. Nielsen, Lars Nikolajsen, Esben Skovsen, Mikkel Jørgensen, Kurt V. Mikkelsen, and Peter R. Ogilby pp 255–269 DOI: 10.1021/ja0452020 Supporting Info

Synthetic Architectures of TiO2/H2Ti5O11·H2O, ZnO/H2Ti5O11·H2O, ZnO/TiO2/H2Ti5O11·H2O, and ZnO/TiO2 Nanocomposites Hua Gui Yang and Hua Chun Zeng pp 270–278 DOI: 10.1021/ja045253x Supporting Info

Hydrogen for Fluorine Exchange in C6F6 and C6F5H by Monomeric [1,3,4-(Me3C)3C5H2]2CeH:  Experimental and Computational Studies Laurent Maron, Evan L. Werkema, Lionel Perrin, Odile Eisenstein, and Richard A. Andersen pp 279–292 DOI: 10.1021/ja0451012 Supporting Info

Selective Monoprotection of 1,n-Terminal Diols in Supercritical Carbon Dioxide:  A Striking Example of Solvent Tunable Desymmetrization Peter Licence, William K. Gray, Maia Sokolova, and Martyn Poliakoff pp 293–298 DOI: 10.1021/ja044814h

Helium Entry and Escape through a Chemically Opened Window in a Fullerene Christopher M. Stanisky, R. James Cross, Martin Saunders, Michihisa Murata, Yasujiro Murata, and Koichi Komatsu pp 299–302 DOI: 10.1021/ja045328x

Temperature Dependence of Three-Body Hydrophobic Interactions:  Potential of Mean Force, Enthalpy, Entropy, Heat Capacity, and Nonadditivity Maria Sabaye Moghaddam, Seishi Shimizu, and Hue Sun Chan pp 303–316 DOI: 10.1021/ja040165y

On the High-Temperature Phase Transition of Gd5Si2Ge2 Yurij Mozharivskyj, Alexandra O. Pecharsky, Vitalij K. Pecharsky, and Gordon J. Miller pp 317–324 DOI: 10.1021/ja048679k Supporting Info

Bifunctional Small Molecules Are Biomimetic Catalysts for Silica Synthesis at Neutral pH Kristian M. Roth, Yan Zhou, Wenjun Yang, and Daniel E. Morse pp 325–330 DOI: 10.1021/ja045308v

Design, Synthesis, and Chemistry of Sterically Nondemanding Primary Bisphosphines1 Nagavarakishore Pillarsetty, Kannan Raghuraman, Charles L. Barnes, and Kattesh V. Katti pp 331–336 DOI: 10.1021/ja047238y Supporting Info

Microscopic Description of the Polyamorphic Phases of Triphenyl Phosphite by Means of Multidimensional Solid-State NMR Spectroscopy Jürgen Senker, Jan Sehnert, and Sascha Correll pp 337–349 DOI: 10.1021/ja046602q

Using Physical Chemistry To Differentiate Nicotinic from Cholinergic Agonists at the Nicotinic Acetylcholine Receptor Amanda L. Cashin, E. James Petersson, Henry A. Lester, and Dennis A. Dougherty pp 350–356 DOI: 10.1021/ja0461771 Supporting Info

Thermodynamic Guidelines for the Design of Bimetallic Catalysts for Oxygen Electroreduction and Rapid Screening by Scanning Electrochemical Microscopy. M−Co (M:  Pd, Ag, Au) José L. Fernández, Darren A. Walsh, and Allen J. Bard pp 357–365 DOI: 10.1021/ja0449729

Self-Assembly and Luminescence of Oligo(p-phenylene vinylene) Amphiphiles James F. Hulvat, Marina Sofos, Keisuke Tajima, and Samuel I. Stupp pp 366–372 DOI: 10.1021/ja047210m Supporting Info

Energy and Electron Transfer in Bifunctional Non-Conjugated Dendrimers K. R. Justin Thomas, Alexis L. Thompson, Aathimanikandan V. Sivakumar, Christopher J. Bardeen, and S. Thayumanavan pp 373–383 DOI: 10.1021/ja044778m Supporting Info

Theoretical Investigations into the Intermediacy of Chlorinated Vinylcobalamins in the Reductive Dehalogenation of Chlorinated Ethylenes Derek A. Pratt and Wilfred A. van der Donk pp 384–396 DOI: 10.1021/ja047915o Supporting Info

13C CPMAS Spectroscopy of Deuterated Proteins:  CP Dynamics, Line Shapes, and T1 Relaxation Corey R. Morcombe, Vadim Gaponenko, R. Andrew Byrd, and Kurt W. Zilm pp 397–404 DOI: 10.1021/ja045581x

Polychromatic Selective Population Inversion for TROSY Experiments with Large Proteins Krystyna Bromek, Donghan Lee, Richard Hauhart, Malgorzata Krych-Goldberg, John P. Atkinson, Paul N. Barlow, and Konstantin Pervushin pp 405–411 DOI: 10.1021/ja0462326 Supporting Info

An Isosparteine Derivative for Stereochemical Assignment of Stereogenic (Chiral) Methyl Groups Using Tritium NMR:  Theory and Experiment Benjamin D. Allen, Jean-Christophe Cintrat, Nicolas Faucher, Patrick Berthault, Bernard Rousseau, and Daniel J. O'Leary pp 412–420 DOI: 10.1021/ja045265i Supporting Info

Polycyclooctatetraeneoxy Alkane Polyanionic Polyradicals Cheryl D. Stevenson, Richard C. Reiter, Lisa F. Szczepura, and Steven J. Peters pp 421–427 DOI: 10.1021/ja046312+ Supporting Info

Ice Surface Reconstruction as Antifreeze Protein-Induced Morphological Modification Mechanism Christina S. Strom, Xiang Yang Liu, and Zongchao Jia pp 428–440 DOI: 10.1021/ja047652y

Mechanism of the N-Cyclopropylimine-1-pyrroline Photorearrangement Diego Sampedro, Alberto Soldevilla, Miguel A. Rodríguez, Pedro J. Campos, and Massimo Olivucci pp 441–448 DOI: 10.1021/ja0467566 Supporting Info

Barrier to Enantiomerization of Unstabilized, Chelated, and Dipole-Stabilized 2-Lithiopyrrolidines Neil J. Ashweek, Peter Brandt, Iain Coldham, Samuel Dufour, Robert E. Gawley, Fredrik Hffner, Rosalyn Klein, and Graciela Sanchez-Jimenez pp 449–457 DOI: 10.1021/ja048090l Supporting Info

Supramolecular Helical Mesomorphic Polymers. Chiral Induction through H-Bonding Joaquín Barberá, Laura Puig, Pilar Romero, José Luis Serrano, and Teresa Sierra pp 458–464 DOI: 10.1021/ja046644e Supporting Info

The C−H Activation of Methane by Laser-Ablated Zirconium Atoms:  CH2ZrH2, the Simplest Carbene Hydride Complex, Agostic Bonding, and (CH3)2ZrH2 Han-Gook Cho, Xuefeng Wang, and Lester Andrews pp 465–473 DOI: 10.1021/ja0451259

A New Class of Foldamers Based on cis-γ-Amino-l-proline [J. Am. Chem. Soc. 2004, 126, 6048−6057]. Josep Farrera-Sinfreu, Laura Zaccaro, David Vidal, Xavier Salvatella, Ernest Giralt, Miquel Pons, Fernando Albericio, and Miriam Royo p 474 DOI: 10.1021/ja040826r

Issue 02

Mapping Long-Range Interactions in α-Synuclein using Spin-Label NMR and Ensemble Molecular Dynamics Simulations Matthew M. Dedmon, Kresten Lindorff-Larsen, John Christodoulou, Michele Vendruscolo, and Christopher M. Dobson pp 476–477 DOI: 10.1021/ja044834j Supporting Info

Controlling Both Ground- and Excited-State Thermal Barriers to Bergman Cyclization with Alkyne Termini Substitution Mahendra Nath, Maren Pink, and Jeffrey M. Zaleski pp 478–479 DOI: 10.1021/ja045979t Supporting Info

Scaling of Folding Times with Protein Size Athi N. Naganathan and Victor Muñoz pp 480–481 DOI: 10.1021/ja044449u

α,β,γ-Trifluoroalkanes:  A Stereoselective Synthesis Placing Three Vicinal Fluorines along a Hydrocarbon Chain Marcello Nicoletti, David O'Hagan, and Alexandra M. Z. Slawin pp 482–483 DOI: 10.1021/ja045299q Supporting Info

A Supramolecular Triarm Star Polymer from a Homotritopic Tris(Crown Ether) Host and a Complementary Monotopic Paraquat-Terminated Polystyrene Guest by a Supramolecular Coupling Method Feihe Huang, Devdatt S. Nagvekar, Carla Slebodnick, and Harry W. Gibson pp 484–485 DOI: 10.1021/ja0438516 Supporting Info

Transnitrosation of Nitrosothiols:  Characterization of an Elusive Intermediate Laura L. Perissinotti, Adrián G. Turjanski, Darío A. Estrin, and Fabio Doctorovich pp 486–487 DOI: 10.1021/ja044056v Supporting Info

New Rhenium−Tin Cluster Adds Palladium Phosphine Groups across Re−Sn Bonds Richard D. Adams, Burjor Captain, Mikael Johansson, and Jack L. Smith, Jr. pp 488–489 DOI: 10.1021/ja0443169 Supporting Info

Reversible Photoelectronic Signal Conversion Based on Photoisomerization-Controlled Coordination Change of Azobenzene-bipyridine Ligands to Copper Shoko Kume, Masaki Murata, Tomoji Ozeki, and Hiroshi Nishihara pp 490–491 DOI: 10.1021/ja045093p Supporting Info

Evidence Against the Hopping Mechanism as an Important Electron Transfer Pathway for Conformationally Constrained Oligopeptides Federico Polo, Sabrina Antonello, Fernando Formaggio, Claudio Toniolo, and Flavio Maran pp 492–493 DOI: 10.1021/ja043607e Supporting Info

Direct Observation of Growth Defects in Zeolite Beta Paul A. Wright, Wuzong Zhou, Joaquin Pérez-Pariente, and Mar Arranz pp 494–495 DOI: 10.1021/ja043948s Supporting Info

Bioaffinity Sensing Using Biologically Functionalized Conducting-Polymer Nanowire Kumaran Ramanathan, Mangesh A. Bangar, Minhee Yun, Wilfred Chen, Nosang V. Myung, and Ashok Mulchandani pp 496–497 DOI: 10.1021/ja044486l Supporting Info

Single-Crystalline Vanadium Dioxide Nanowires with Rectangular Cross Sections Beth S. Guiton, Qian Gu, Amy L. Prieto, Mark S. Gudiksen, and Hongkun Park pp 498–499 DOI: 10.1021/ja045976g Supporting Info

Cleavage of Hydrazine and 1,1-Dimethylhydrazine by Dinuclear Tantalum Hydrides:  Formation of Imides, Nitrides, and N,N-Dimethylamine Michael P. Shaver and Michael D. Fryzuk pp 500–501 DOI: 10.1021/ja043732q Supporting Info

17O ESEEM Evidence for Exchange of the Axial Oxo Ligand in the Molybdenum Center of the High pH Form of Sulfite Oxidase Andrei V. Astashkin, Changjian Feng, Arnold M. Raitsimring, and John H. Enemark pp 502–503 DOI: 10.1021/ja0461466 Supporting Info

Dendrimeric Gadolinium Chelate with Fast Water Exchange and High Relaxivity at High Magnetic Field Strength Valérie C. Pierre, Mauro Botta, and Kenneth N. Raymond pp 504–505 DOI: 10.1021/ja045263y Supporting Info

Glyco- and Peptidomimetics from Three-Component Joullié−Ugi Coupling Show Selective Antiviral Activity Timothy M. Chapman, Ieuan G. Davies, Baohua Gu, Timothy M. Block, David I. C. Scopes, Philip A. Hay, Stephen M. Courtney, Luke A. McNeill, Christopher J. Schofield, and Benjamin G. Davis pp 506–507 DOI: 10.1021/ja043924l Supporting Info

Efficient Synthesis of 1,2,4-Dithiazolidine-3,5-diones [Dithiasuccinoyl-Amines] from Bis(chlorocarbonyl)disulfane Plus Bis(trimethylsilyl)amines Michael J. Barany, Robert P. Hammer, R. B. Merrifield, and George Barany pp 508–509 DOI: 10.1021/ja0455446 Supporting Info

Stille Cross-Couplings of Unactivated Secondary Alkyl Halides Using Monoorganotin Reagents David A. Powell, Toshihide Maki, and Gregory C. Fu pp 510–511 DOI: 10.1021/ja0436300 Supporting Info

Direct Evidence for Highly Organized Networks of Circular Surface Micelles of Surfactant at the Air−Water Interface Philippe Fontaine, Michel Goldmann, Pierre Muller, Marie-Claude Fauré, Oleg Konovalov, and Marie Pierre Krafft pp 512–513 DOI: 10.1021/ja044779e

Catalytic Enantioselective Conjugate Addition of Cyanide to α,β-Unsaturated N-Acylpyrroles Tsuyoshi Mita, Kazuki Sasaki, Motomu Kanai, and Masakatsu Shibasaki pp 514–515 DOI: 10.1021/ja043424s Supporting Info

Enantioselective Tandem Michael Addition/H2-Hydrogenation Catalyzed by Ruthenium Hydride Borohydride Complexes Containing β-aminophosphine Ligands1 Rongwei Guo, Robert H. Morris, and Datong Song pp 516–517 DOI: 10.1021/ja043782v Supporting Info

Site-Selective RNA Cleavage by DNA Bearing a Base Pair-Mimic Nucleoside Shu-ichi Nakano, Yuuki Uotani, Kazuya Uenishi, Masayuki Fujii, and Naoki Sugimoto pp 518–519 DOI: 10.1021/ja045445s Supporting Info

Changing Selectivity of DNA Oxidation from Deoxyribose to Guanine by Ligand Design and a New Binuclear Copper Complex Lei Li, Kenneth D. Karlin, and Steven E. Rokita pp 520–521 DOI: 10.1021/ja044209e Supporting Info

Consecutive Elongation of Alanine Oligopeptides at the Second Time Range under Hydrothermal Conditions Using a Microflow Reactor System Kunio Kawamura, Teruyuki Nishi, and Tomofumi Sakiyama pp 522–523 DOI: 10.1021/ja0447917 Supporting Info

Dramatic Increases in the Lifetime of the Er3+ Ion in a Molecular Complex Using a Perfluorinated Imidodiphosphinate Sensitizing Ligand Gaetano Mancino, Andrew J. Ferguson, Andrew Beeby, Nicholas J. Long, and Tim S. Jones pp 524–525 DOI: 10.1021/ja0441864 Supporting Info

Mirror “Base-off” Conformation of Coenzyme B12 in Human Adenosyltransferase and Its Downstream Target, Methylmalonyl-CoA Mutase Mamoru Yamanishi, Tetyana Labunska, and Ruma Banerjee pp 526–527 DOI: 10.1021/ja044365l

Rational Synthesis of Contra-Thermodynamic Spiroacetals by Reductive Cyclizations Leo R. Takaoka, Alexandre J. Buckmelter, Thomas E. LaCruz, and Scott D. Rychnovsky pp 528–529 DOI: 10.1021/ja044642o Supporting Info

Peroxotungstate Immobilized on Ionic Liquid-Modified Silica as a Heterogeneous Epoxidation Catalyst with Hydrogen Peroxide Kazuya Yamaguchi, Chie Yoshida, Sayaka Uchida, and Noritaka Mizuno pp 530–531 DOI: 10.1021/ja043688e Supporting Info

Biosynthesis of Iso-Fatty Acids in Myxobacteria:  Iso-Even Fatty Acids Are Derived by α-Oxidation from Iso-Odd Fatty Acids Helge B. Bode, Jeroen S. Dickschat, Reiner M. Kroppenstedt, Stefan Schulz, and Rolf Müller pp 532–533 DOI: 10.1021/ja043570y Supporting Info

Helicity Induction and Two-Photon Absorbance Enhancement in Zinc(II) Meso−Meso Linked Porphyrin Oligomers via Intermolecular Hydrogen Bonding Interactions Chusaku Ikeda, Zin Seok Yoon, Mira Park, Hidenari Inoue, Dongho Kim, and Atsuhiro Osuka pp 534–535 DOI: 10.1021/ja043428x Supporting Info

A Crystallographic Investigation of Phosphoantigen Binding to Isopentenyl Pyrophosphate/Dimethylallyl Pyrophosphate Isomerase Johan Wouters, Fenglin Yin, Yongcheng Song, Yonghui Zhang, Yamina Oudjama, Victor Stalon, Louis Droogmans, Craig T. Morita, and Eric Oldfield pp 536–537 DOI: 10.1021/ja040207i Supporting Info

A Dimerization “Switch” in the Internalization Mechanism of a Cell-Penetrating Peptide Jason A. Moss, Antonietta Lillo, Young Soo Kim, Changshou Gao, Henrik Ditzel, and Kim D. Janda pp 538–539 DOI: 10.1021/ja0443171 Supporting Info

Ca2+- and Ba2+-Selective Receptors Based on Site-Selective Transmetalation of Multinuclear Polyoxime−Zinc(II) Complexes Shigehisa Akine, Takanori Taniguchi, Toshiyuki Saiki, and Tatsuya Nabeshima pp 540–541 DOI: 10.1021/ja046790k Supporting Info

Symmetry-Based 29Si Dipolar Recoupling Magic Angle Spinning NMR Spectroscopy:  A New Method for Investigating Three-Dimensional Structures of Zeolite Frameworks Darren H. Brouwer, Per Eugen Kristiansen, Colin A. Fyfe, and Malcolm H. Levitt pp 542–543 DOI: 10.1021/ja043228l Supporting Info

Synthesis and Characterization of Co/CdSe Core/Shell Nanocomposites:  Bifunctional Magnetic-Optical Nanocrystals Hyungrak Kim, Marc Achermann, Laurent P. Balet, Jennifer A. Hollingsworth, and Victor I. Klimov pp 544–546 DOI: 10.1021/ja047107x

Chain-Length-Dependent Helical Motifs and Self-Association of β-Peptides with Constrained Side Chains Anasztázia Hetényi, István M. Mándity, Tamás A. Martinek, Gábor K. Tóth, and Ferenc Fülöp pp 547–553 DOI: 10.1021/ja0475095 Supporting Info

Synthesis of Postulated Molecular Probes:  Stereoselective Free-Radical-Mediated C-Glycosylation in Tandem with Hydrogen Transfer Yvan Guindon, Mohammed Bencheqroun, and Abderrahim Bouzide pp 554–558 DOI: 10.1021/ja046389y Supporting Info

Synthesis and Characterization of Dimaleimide Fluorogens Designed for Specific Labeling of Proteins Stéphane Girouard, Marie-Hélène Houle, Alain Grandbois, Jeffrey W. Keillor, and Stephen W. Michnick pp 559–566 DOI: 10.1021/ja045742x Supporting Info

Interaction between the Type-3 Copper Protein Tyrosinase and the Substrate Analogue p-Nitrophenol Studied by NMR Armand W. J. W. Tepper, Luigi Bubacco, and Gerard W. Canters pp 567–575 DOI: 10.1021/ja0454687 Supporting Info

Structural and Oxidation-State Changes at Its Nonstandard Ni−Fe Site during Activation of the NAD-Reducing Hydrogenase from Ralstonia eutropha Detected by X-ray Absorption, EPR, and FTIR Spectroscopy Tanja Burgdorf, Simone Löscher, Peter Liebisch, Eddy Van der Linden, Marcus Galander, Friedhelm Lendzian, Wolfram Meyer-Klaucke, Simon P. J. Albracht, Bärbel Friedrich, Holger Dau, and Michael Haumann pp 576–592 DOI: 10.1021/ja0461926

Structure and Properties of High Stability Geminal Dicationic Ionic Liquids Jared L. Anderson, Rongfang Ding, Arkady Ellern, and Daniel W. Armstrong pp 593–604 DOI: 10.1021/ja046521u Supporting Info

Cp*RuCl-Catalyzed [2 + 2 + 2] Cycloadditions of α,ω-Diynes with Electron-Deficient Carbon−Heteroatom Multiple Bonds Leading to Heterocycles Yoshihiko Yamamoto, Keisuke Kinpara, Tomoaki Saigoku, Hideyuki Takagishi, Satoshi Okuda, Hisao Nishiyama, and Kenji Itoh pp 605–613 DOI: 10.1021/ja045694g Supporting Info

Indolo[3,2-b]carbazole-Based Thin-Film Transistors with High Mobility and Stability Yiliang Wu, Yuning Li, Sandra Gardner, and Beng S. Ong pp 614–618 DOI: 10.1021/ja0456149 Supporting Info

Discotic Liquid Crystalline Poly(propylene imine) Dendrimers Based on Triphenylene Mark D. McKenna, Joaquín Barberá, Mercedes Marcos, and José Luis Serrano pp 619–625 DOI: 10.1021/ja0455906 Supporting Info

Kinetics of Acid-Induced Spectral Changes in the GFPmut2 Chromophore Stefania Abbruzzetti, Elena Grandi, Cristiano Viappiani, Sara Bologna, Barbara Campanini, Samanta Raboni, Stefano Bettati, and Andrea Mozzarelli pp 626–635 DOI: 10.1021/ja045400r

Dynamic Assessment of Bilayer Thickness by Varying Phospholipid and Hydraphile Synthetic Channel Chain Lengths Michelle E. Weber, Paul H. Schlesinger, and George W. Gokel pp 636–642 DOI: 10.1021/ja044936+

Synthesis and Characterization of Scandium Silyl Complexes of the Type Cp*2ScSiHRR‘. σ-Bond Metathesis Reactions and Catalytic Dehydrogenative Silation of Hydrocarbons Aaron D. Sadow and T. Don Tilley pp 643–656 DOI: 10.1021/ja040141r Supporting Info

Supramolecular Aggregates Constructed from Gold Nanoparticles and l-Try-CD Polypseudorotaxanes as Captors for Fullerenes Yu Liu, Hao Wang, Yong Chen, Chen-Feng Ke, and Min Liu pp 657–666 DOI: 10.1021/ja046294w Supporting Info

Metal and Ligand K-Edge XAS of Organotitanium Complexes:  Metal 4p and 3d Contributions to Pre-edge Intensity and Their Contributions to Bonding Serena DeBeer George, Patrick Brant, and Edward I. Solomon pp 667–674 DOI: 10.1021/ja044827v Supporting Info

Effect of Explicit Cationic Size and Valence Constraints on the Phase Stability of 1:2 B-Site-Ordered Perovskite Ruthenates Job T. Rijssenbeek, Takashi Saito, Sylvie Malo, Masaki Azuma, Mikio Takano, and Kenneth R. Poeppelmeier pp 675–681 DOI: 10.1021/ja044797w

Molecular Spectroscopy of Uranium(IV) Bis(ketimido) Complexes. Rare Observation of Resonance-Enhanced Raman Scattering from Organoactinide Complexes and Evidence for Broken-Symmetry Excited States Ryan E. Da Re, Kimberly C. Jantunen, Jeffrey T. Golden, Jaqueline L. Kiplinger, and David E. Morris pp 682–689 DOI: 10.1021/ja044315g

Trimer Based Polarization as a Multibody Molecular Model. Application to Hydrogen Fluoride Scott J. Wierzchowski and David A. Kofke pp 690–698 DOI: 10.1021/ja031877b

Valence and Dipole-Bound Anions of the Most Stable Tautomers of Guanine Maciej Haranczyk and Maciej Gutowski pp 699–706 DOI: 10.1021/ja046622s Supporting Info

Intrinsic Folding of Small Peptide Chains:  Spectroscopic Evidence for the Formation of β-Turns in the Gas Phase Wutharath Chin, Jean-Pierre Dognon, François Piuzzi, Benjamin Tardivel, Iliana Dimicoli, and Michel Mons pp 707–712 DOI: 10.1021/ja045251c Supporting Info

Off-Resonance R1ρ NMR Studies of Exchange Dynamics in Proteins with Low Spin-Lock Fields:  An Application to a Fyn SH3 Domain Dmitry M. Korzhnev, Vladislav Yu. Orekhov, and Lewis E. Kay pp 713–721 DOI: 10.1021/ja0446855

Mechanism of Aerobic Decomposition of Angeli's Salt (Sodium Trioxodinitrate) at Physiological pH Katrina M. Miranda, Andrew S. Dutton, Lisa A. Ridnour, Christian A. Foreman, Eleonora Ford, Nazareno Paolocci, Tatsuo Katori, Carlo G. Tocchetti, Daniele Mancardi, Douglas D. Thomas, Michael G. Espey, K. N. Houk, Jon M. Fukuto, and David A. Wink pp 722–731 DOI: 10.1021/ja045480z

Relationship between Charge-Transfer Interactions, Redox Potentials, and Catalysis for Different Forms of the Flavoprotein Component of p-Cresol Methylhydroxylase Igor Efimov and William S. McIntire pp 732–741 DOI: 10.1021/ja047409z

Extending the Language of DNA Molecular Recognition by Polyamides:  Unexpected Influence of Imidazole and Pyrrole Arrangement on Binding Affinity and Specificity Karen L. Buchmueller, Andrew M. Staples, Cameron M. Howard, Sarah M. Horick, Peter B. Uthe, N. Minh Le, Kari K. Cox, Binh Nguyen, Kimberly A. O. Pacheco, W. David Wilson, and Moses Lee pp 742–750 DOI: 10.1021/ja044359p

Ionic Liquid-Promoted, Highly Regioselective Heck Arylation of Electron-Rich Olefins by Aryl Halides Jun Mo, Lijin Xu, and Jianliang Xiao pp 751–760 DOI: 10.1021/ja0450861 Supporting Info

Catalytic [4+1] Cycloaddition of α,β-Unsaturated Carbonyl Compounds with Isocyanides Masayuki Oshita, Kohei Yamashita, Mamoru Tobisu, and Naoto Chatani pp 761–766 DOI: 10.1021/ja0450206 Supporting Info

Catalytic Hydroxylation of Polypropylenes Chulsung Bae, John F. Hartwig, Nicole K. Boaen Harris, Rachael O. Long, Kelly S. Anderson, and Marc A. Hillmyer pp 767–776 DOI: 10.1021/ja044440s Supporting Info

Probing the Molecular Orbitals and Charge Redistribution in Organometallic (PP)Pd(XX) Complexes. A Pd K-Edge XANES Study Moniek Tromp, Jeroen A. van Bokhoven, Gino P. F. van Strijdonck, Piet W. N. M. van Leeuwen, Diek C. Koningsberger, and David E. Ramaker pp 777–789 DOI: 10.1021/ja048225n Supporting Info

Bifunctional Hybrid Mesoporous Organoaluminosilicates with Molecularly Ordered Ethylene Groups Yongde Xia, Wenxin Wang, and Robert Mokaya pp 790–798 DOI: 10.1021/ja0453230

Water-Soluble Gadofullerenes:  Toward High-Relaxivity, pH-Responsive MRI Contrast Agents Éva Tóth, Robert D. Bolskar, Alain Borel, Gabriel González, Lothar Helm, André E. Merbach, Balaji Sitharaman, and Lon J. Wilson pp 799–805 DOI: 10.1021/ja044688h Supporting Info

Comprehensive Chemical Kinetics. Volume 39. Unimolecular Kinetics, Part 1:  The Reaction Step Edited by Nicholas J. B. Green (King's College London). Elsevier B. V.:  Amsterdam. 2003. xiv + 248 pp. $155.00. ISBN 0-444-50893-7. Edwin L. Sibert III p 806 DOI: 10.1021/ja0409053

Issue 03

A High Molar Extinction Coefficient Sensitizer for Stable Dye-Sensitized Solar Cells Peng Wang, Cédric Klein, Robin Humphry-Baker, Shaik M. Zakeeruddin, and Michael Grätzel pp 808–809 DOI: 10.1021/ja0436190 Supporting Info

Complementary Quadruple Hydrogen Bonding in Supramolecular Copolymers G. B. W. L. Ligthart, Haruki Ohkawa, Rint P. Sijbesma, and E. W. Meijer pp 810–811 DOI: 10.1021/ja043555t Supporting Info

Near-IR Luminescence of Monolayer-Protected Metal Clusters Gangli Wang, Tao Huang, Royce W. Murray, Laurent Menard, and Ralph G. Nuzzo pp 812–813 DOI: 10.1021/ja0452471

Bonding in HNO-Myoglobin as Characterized by X-ray Absorption and Resonance Raman Spectroscopies Chad E. Immoos, Filip Sulc, Patrick J. Farmer, Kazimierz Czarnecki, David F. Bocian, Aviva Levina, Jade B. Aitken, Robert S. Armstrong, and Peter A. Lay pp 814–815 DOI: 10.1021/ja0433727 Supporting Info

Guanidinium Ion as a Symmetrical Template in the Formation of Cubic Hydrogen-Bonded Borate Networks with the Boracite Topology Brendan F. Abrahams, Marissa G. Haywood, and Richard Robson pp 816–817 DOI: 10.1021/ja044200c Supporting Info

Design and Synthesis of Zinc-Selective Chelators for Extracellular Applications Eri Kawabata, Kazuya Kikuchi, Yasuteru Urano, Hirotatsu Kojima, Akira Odani, and Tetsuo Nagano pp 818–819 DOI: 10.1021/ja044697q Supporting Info

Water-Soluble [2.2]Paracyclophane Chromophores with Large Two-Photon Action Cross Sections Han Young Woo, Janice W. Hong, Bin Liu, Alexander Mikhailovsky, Dmitry Korystov, and Guillermo C. Bazan pp 820–821 DOI: 10.1021/ja0440811 Supporting Info

Light Regulation of Aptamer Activity:  An Anti-Thrombin Aptamer with Caged Thymidine Nucleobases Alexander Heckel and Günter Mayer pp 822–823 DOI: 10.1021/ja043285e Supporting Info

A Nuclear Isotope Effect for Interfacial Electron Transfer:  Excited-State Electron Injection from Ru Ammine Compounds to Nanocrystalline TiO2 Feng Liu and Gerald J. Meyer pp 824–825 DOI: 10.1021/ja045266a Supporting Info

Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins Xi Zhang, Hideki Furutachi, Shuhei Fujinami, Shigenori Nagatomo, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa, and Masatatsu Suzuki pp 826–827 DOI: 10.1021/ja045594a Supporting Info

Changes in Calmodulin Main-Chain Dynamics upon Ligand Binding Revealed by Cross-Correlated NMR Relaxation Measurements Tianzhi Wang, Kendra King Frederick, Tatyana I. Igumenova, A. Joshua Wand, and Erik R. P. Zuiderweg pp 828–829 DOI: 10.1021/ja045743p Supporting Info

Preparation of Superconducting Nax(H2O)yCoO2 using NaMnO4 as the Deintercalation and Oxidation Agent Chia-Jyi Liu, Wen-Chin Hung, Jung-Sheng Wang, and Chia-Jung Charlie Liu pp 830–831 DOI: 10.1021/ja043828k Supporting Info

Direct Observation of the Participation of Flavin in Product Formation by thyX-Encoded Thymidylate Synthase Samuel G. Gattis and Bruce A. Palfey pp 832–833 DOI: 10.1021/ja0432214

Unique Oxidation Reaction of Amides with Pyridine-N-oxide Catalyzed by Ruthenium Porphyrin:  Direct Oxidative Conversion of N-Acyl-l-proline to N-Acyl-l-glutamate Rina Ito, Naoki Umezawa, and Tsunehiko Higuchi pp 834–835 DOI: 10.1021/ja045603f Supporting Info

One-Step Synthesis of Labeled Sugar Nucleotides for Protein O-GlcNAc Modification Studies by Chemical Function Analysis of an Archaeal Protein Rahman M. Mizanur, Firoz A. Jaipuri, and Nicola L. Pohl pp 836–837 DOI: 10.1021/ja044117p Supporting Info

14-Azacamptothecin:  A Potent Water-Soluble Topoisomerase I Poison Kejun Cheng, Nicolas J. Rahier, Brian M. Eisenhauer, Rong Gao, S. J. Thomas, and Sidney M. Hecht pp 838–839 DOI: 10.1021/ja0442769 Supporting Info

The Pyridine Ring of NAD Is Formed by a Nonenzymatic Pericyclic Reaction Keri L. Colabroy and Tadhg P. Begley pp 840–841 DOI: 10.1021/ja0446395 Supporting Info

Resist-Free Patterning of Surface Architectures in Polymer-Based Microanalytical Devices Robin L. McCarley, Bikas Vaidya, Suying Wei, Alison F. Smith, Ami B. Patel, Juan Feng, Michael C. Murphy, and Steven A. Soper pp 842–843 DOI: 10.1021/ja0454135 Supporting Info

Reduction of Trichloroethylene by Outer-Sphere Electron-Transfer Agents Angela D. Follett and Kristopher McNeill pp 844–845 DOI: 10.1021/ja043569z Supporting Info

Caged Phosphoproteins Deborah M. Rothman, E. James Petersson, M. Eugenio Vázquez, Gabriel S. Brandt, Dennis A. Dougherty, and Barbara Imperiali pp 846–847 DOI: 10.1021/ja043875c Supporting Info

The Total Synthesis of Gambierol Henry W. B. Johnson, Utpal Majumder, and Jon D. Rainier pp 848–849 DOI: 10.1021/ja043396d Supporting Info

Dihydrogen Complexes of Electrophilic Metal Centers:  Observation of Cr(CO)5(H2), W(CO)5(H2) and [Re(CO)5(H2)]+ Steven L. Matthews, Vincent Pons, and D. Michael Heinekey pp 850–851 DOI: 10.1021/ja0433370

A Family of Alkynylgold(III) Complexes [AuI(μ-{CH2}2PPh2)2AuIII(CCR)2] (R = Ph, tBu, Me3Si):  Facile and Reversible Comproportionation of Gold(I)/Gold(III) to Digold(II) Luis A. Méndez, Josefina Jiménez, Elena Cerrada, Fabian Mohr, and Mariano Laguna pp 852–853 DOI: 10.1021/ja043401d Supporting Info

Approaching Zero:  Using Fractured Crystals in Metrology for Replica Molding Qiaobing Xu, Brian T. Mayers, Michal Lahav, Dmitri V. Vezenov, and George M. Whitesides pp 854–855 DOI: 10.1021/ja043436d Supporting Info

Heterogeneous Binding of Lipoteichoic Acid to the Surface of Titanium Dioxide as Determined with 31P Solid-State NMR Spectroscopy Charles V. Rice and Jason R. Wickham pp 856–857 DOI: 10.1021/ja043195+ Supporting Info

Mechanism of Inactivation of Inducible Nitric Oxide Synthase by Amidines. Irreversible Enzyme Inactivation without Inactivator Modification Yaoqiu Zhu, Dejan Nikolic, Richard B. Van Breemen, and Richard B. Silverman pp 858–868 DOI: 10.1021/ja0445645 Supporting Info

Highly Efficient, Nonpeptidic Oligoguanidinium Vectors that Selectively Internalize into Mitochondria Jimena Fernández-Carneado, Michiel Van Gool, Vera Martos, Susanna Castel, Pilar Prados, Javier de Mendoza, and Ernest Giralt pp 869–874 DOI: 10.1021/ja044006q Supporting Info

Relation between Pore Sizes of Protein Crystals and Anisotropic Solute Diffusivities Aleksandar Cvetkovic, Cristian Picioreanu, Adrie J. J. Straathof, Rajamani Krishna, and Luuk A. M. van der Wielen pp 875–879 DOI: 10.1021/ja0440708

Demonstration of an Alternative Mechanism for G-to-G Cross-Link Formation Ming Qian and Rainer Glaser pp 880–887 DOI: 10.1021/ja045108j Supporting Info

Molecular Control of Macroscopic Cubic, Columnar, and Lamellar Organizations in Luminescent Lanthanide-Containing Thermotropic Liquid Crystals Emmanuel Terazzi, Stéphane Torelli, Gérald Bernardinelli, Jean-Pierre Rivera, Jean-Marc Bénech, Cyril Bourgogne, Bertrand Donnio, Daniel Guillon, Daniel Imbert, Jean-Claude G. Bünzli, André Pinto, Damien Jeannerat, and Claude Piguet pp 888–903 DOI: 10.1021/ja0446101 Supporting Info

Nanomolar Protein Sensing with Embedded Receptor Molecules Reza Zadmard and Thomas Schrader pp 904–915 DOI: 10.1021/ja045785d

Direct Observation of Ligand Binding to Membrane Proteins in Living Cells by a Saturation Transfer Double Difference (STDD) NMR Spectroscopy Method Shows a Significantly Higher Affinity of Integrin αIIbβ3 in Native Platelets than in Liposomes Birgit Claasen, Marco Axmann, Robert Meinecke, and Bernd Meyer pp 916–919 DOI: 10.1021/ja044434w Supporting Info

Pseudo-para-dinitro[2.2]paracyclophane Radical Anion, a Mixed-Valence System Poised on the Class II/Class III Borderline Stephen F. Nelsen, Asgeir E. Konradsson, and João P. Telo pp 920–925 DOI: 10.1021/ja0441920

Phase Stabilization through Electronic Tuning:  Electron-Poorer Alkali-Metal−Indium Compounds with Unprecedented In/Li Clusters Bin Li and John D. Corbett pp 926–932 DOI: 10.1021/ja0402046 Supporting Info

Synthesis of Dicyclopenta[a,e]pentalenes via a Molybdenum Carbonyl Mediated Tandem Allenic Pauson−Khand Reaction and the X-ray Crystal Structure of a Planar Dicyclopenta[a,e]pentalene Hui Cao, Scott G. Van Ornum, Jeffery Deschamps, Judith Flippen-Anderson, Frank Laib, and James M. Cook pp 933–943 DOI: 10.1021/ja040120x Supporting Info

Solvent-Assisted New Reaction Pathways for the (THF)W(CO)5-Promoted endo- and exo-Cycloisomerization of 4-Pentyn-1-ol:  A Theoretical Investigation Tomás Sordo, Pablo Campomanes, Alejandro Diéguez, Félix Rodríguez, and Francisco J. Fañanás pp 944–952 DOI: 10.1021/ja045567k Supporting Info

Reactivity of Peroxo Forms of the Vanadium Haloperoxidase Cofactor. A DFT Investigation Giuseppe Zampella, Piercarlo Fantucci, Vincent L. Pecoraro, and Luca De Gioia pp 953–960 DOI: 10.1021/ja046016x

Single-Site Anionic Polymerization. Monomeric Ester Enolaluminate Propagator Synthesis, Molecular Structure, and Polymerization Mechanism Antonio Rodriguez-Delgado and Eugene Y.-X. Chen pp 961–974 DOI: 10.1021/ja044671z Supporting Info

On the Origin of Optical Activity in Tris-diamine Complexes of Co(III) and Rh(III):  A Simple Model Based on Time-Dependent Density Function Theory Francisco Elias Jorge, Jochen Autschbach, and Tom Ziegler pp 975–985 DOI: 10.1021/ja047670f

Silicon−Nitrogen Bonding in Silatranes:  Assignment of Photoelectron Spectra A. B. Trofimov, V. G. Zakrzewski, O. Dolgounitcheva, J. V. Ortiz, V. F. Sidorkin, E. F. Belogolova, M. Belogolov, and V. A. Pestunovich pp 986–995 DOI: 10.1021/ja045667q

Interaction Of The Human Prion PrP(106−126) Sequence With Copper(II), Manganese(II), And Zinc(II):  NMR and EPR Studies Elena Gaggelli, Francesca Bernardi, Elena Molteni, Rebecca Pogni, Daniela Valensin, Gianni Valensin, Maurizio Remelli, Marek Luczkowski, and Henryk Kozlowski pp 996–1006 DOI: 10.1021/ja045958z

High Nuclearity Iridium−Platinum Clusters:  Synthesis, Structures, Bonding, and Reactivity Richard D. Adams, Burjor Captain, Michael B. Hall, Jack L. Smith, Jr., and Charles Edwin Webster pp 1007–1014 DOI: 10.1021/ja0443777 Supporting Info

Synthesis, Characterization, and Structure-Selective Extraction of 1−3-nm Diameter AuAg Dendrimer-Encapsulated Bimetallic Nanoparticles Orla M. Wilson, Robert W. J. Scott, Joaquin C. Garcia-Martinez, and Richard M. Crooks pp 1015–1024 DOI: 10.1021/ja045224m Supporting Info

Substrate Hydroxylation in Methane Monooxygenase:  Quantitative Modeling via Mixed Quantum Mechanics/Molecular Mechanics Techniques Benjamin F. Gherman, Stephen J. Lippard, and Richard A. Friesner pp 1025–1037 DOI: 10.1021/ja049847b Supporting Info

Application of Molecular Absorption Properties of Horseradish Peroxidase for Self-Indicating Enzymatic Interactions and Analytical Methods Vanesa Sanz, Susana de Marcos, Juan R. Castillo, and Javier Galbán pp 1038–1048 DOI: 10.1021/ja046830k

Where Does the Planar-to-Nonplanar Turnover Occur in Small Gold Clusters? Ryan M. Olson, Sergey Varganov, Mark S. Gordon, Horia Metiu, Steeve Chretien, Piotr Piecuch, Karol Kowalski, Stanislaw A. Kucharski, and Monika Musial pp 1049–1052 DOI: 10.1021/ja040197l

Glycosidic Bond Cleavage of Pyrimidine Nucleosides by Low-Energy Electrons:  A Theoretical Rationale Jiande Gu, Yaoming Xie, and Henry F. Schaefer III pp 1053–1057 DOI: 10.1021/ja0400990

Ellipsometric Approach for the Real-Time Detection of Label-Free Protein Adsorption by Second Harmonic Generation  [J. Am. Chem. Soc. 2004, 126, 5001−5007]. Mark A. Polizzi, Ryan M. Plocinik, and Garth J. Simpson p 1058 DOI: 10.1021/ja042833l

Elemental Sulfur and Sulfur-Rich Compounds I. Topics in Current Chemistry, 230 Edited by Ralf Steudel (Technische Universität Berlin). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 202 pp. $189.00. ISBN 3-540-40191-1. Thomas B. Rauchfuss p 1059 DOI: 10.1021/ja040908f

Trends in Molecular Electrochemistry Edited by Armando J. L. Pombeiro (Instituto Superior Técnico, Lisboa, Portugal) and Christian Amatore (Ecole Normale Supérieure, Paris). Marcel Dekker, Inc. and FontisMedia, S. A.:  New York and Lausanne, respectively. 2004. xvi + 552 pp. $185.00. ISBN 0-8247-5352-6. p 1059 DOI: 10.1021/ja040993r

Azeotropic Data, Second, Completely Revised and Extended Edition, Parts I−III By Jürgen Gmehling (Carl Ossietzky Universität, Oldenburg, Germany), Jochen Menke (DDBST GmbH, Oldenburg), Jörg Krafczyk (DDBST GmbH, Oldenburg), and Kai Fischer (Lab for Thermophysical Properties (LTP GmbH, Oldenburg)). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. 1992 pp. $910.00. ISBN 3-527-30833-4. p 1059 DOI: 10.1021/ja0410035

Highlights in Bioorganic Chemistry:  Methods and Applications Edited by Carsten Schmuck (University of Würzburg) and Helma Wennemers (University of Basel). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xxviii + 572pp. $125.00. ISBN 3-527-30656-0. Danith H. Ly pp 1059–1060 DOI: 10.1021/ja040953n

Progress in Colloid and Polymer Science, Volume 124:  Aqueous Polymer Dispersions Edited by Klaus Tauer (Max Planck Institute of Colloid and Interfaces, Golm, Germany). Springer-Verlag:  Berlin, Heidelberg. 2004. viii + 170 pp. $159.00. ISBN 3-540-00578-1. p 1060 DOI: 10.1021/ja040994j

Progress in Colloid and Polymer Science, Volume 123. Trends in Colloid and Interface Science XVI Edited by Maria da Graça Miguel and Hugh D. Burrows (Universidade de Coimbra, Portugal). Springer-Verlag:  Berlin, Heidelberg. 2004. x + 288 pp. $189.00. ISBN 3-540-00553-6. p 1060 DOI: 10.1021/ja040995b

Oligonucleotide Synthesis:  Methods and Applications. Methods in Molecular Biology, Volume 288 Edited by Piet Herdewijn (Katholieke Universiteit Leuven, Belgium). Humana Press:  Totowa, NJ. 2005. xvi + 436 pp. $125.00. ISBN 1-58829-233-9. p 1060 DOI: 10.1021/ja040997w

Organosilanes in Radical Chemistry:  Principles, Methods and Applications By Chryssostomos Chatgilialoglu (Consiglio Nazionale delle Ricerche, Bologna, Italy). John Wiley & Sons:  Chichester, U.K. 2004. xii + 228 pp. $265.00. ISBN 0-471-49870-X. Eric Block pp 1060–1061 DOI: 10.1021/ja0409513

Spin Crossover in Transition Metal Compounds I. Topics in Current Chemistry, 233 Edited by Philipp Gütlich (Johannes-Gutenberg-University of Mainz) and Harold A. Goodwin (University of New South Wales). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xiv + 342 pp. $289.00. ISBN 3-540-40394-9. Catalina Achim p 1061 DOI: 10.1021/ja0409715

Annual Review of Biophysics and Biomolecular Structure, Volume 33 Edited by Douglas C. Rees (California Institute of Technology), Michael P. Sheetz (Columbia University), and James R. Williamson (The Scripps Research Institute). Annual Reviews:  Palo Alto, CA. 2004. xiv + 520 pp. $84.00 (print and online for individuals). ISBN 0-8243-1833-1. James W. Whittaker pp 1061–1062 DOI: 10.1021/ja040969d

Protein NMR Techniques, 2nd ed. Methods in Molecular Biology, Volume 278 Edited by A. Kristina Downing (University of Oxford). Humana Press:  Totowa, NJ. 2004. xii + 488 pp. $115.00. ISBN 1-58829-246-0. p 1062 DOI: 10.1021/ja0409863

Issue 04

Solvent Deuterium Isotope Effects on Phosphodiester Cleavage Catalyzed by an Extraordinarily Active Zn(II) Complex Meng-Yin Yang, Olga Iranzo, John P. Richard, and Janet R. Morrow pp 1064–1065 DOI: 10.1021/ja044617i Supporting Info

Asymmetric [2,3]-Rearrangement of Glycine-Derived Allyl Ammonium Ylids James A. Workman, Neil P. Garrido, Julien Sançon, Edward Roberts, Hans Peter Wessel, and J. B. Sweeney pp 1066–1067 DOI: 10.1021/ja043768i Supporting Info

Formation of a Bridging Planar Trimethylenemethane Dianion from a Neopentyl Precursor via Sequential β-Alkyl Elimination and C−H Activation William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller pp 1068–1069 DOI: 10.1021/ja044529y Supporting Info

Platinum-Catalyzed Intramolecular Hydroamination of Unactivated Olefins with Secondary Alkylamines Christopher F. Bender and Ross A. Widenhoefer pp 1070–1071 DOI: 10.1021/ja043278q Supporting Info

Highly Porous Uranyl Selenate Nanotubules Sergey V. Krivovichev, Volker Kahlenberg, Ivan G. Tananaev, Reinhard Kaindl, Edgar Mersdorf, and Boris F. Myasoedov pp 1072–1073 DOI: 10.1021/ja0436289 Supporting Info

Photoinduced Switch of a DNA/RNA Inactive Molecule into a Classical Intercalator Kristina Starević, Grace Karminski-Zamola, Ivo Piantanida, Mladen Žinić, Lidija Šuman, and Marijeta Kralj pp 1074–1075 DOI: 10.1021/ja0438866 Supporting Info

Cubic Phases and Cubic Phase Dispersions in a Phospholipid-Based System Markus Johnsson, Justas Barauskas, and Fredrik Tiberg pp 1076–1077 DOI: 10.1021/ja043331a Supporting Info

Stable Polythiophene Semiconductors Incorporating Thieno[2,3-b]thiophene Martin Heeney, Clare Bailey, Kristijonas Genevicius, Maxim Shkunov, David Sparrowe, Steve Tierney, and Iain McCulloch pp 1078–1079 DOI: 10.1021/ja043112p Supporting Info

Brønsted Acid Catalysis of Achiral Enamine for Regio- and Enantioselective Nitroso Aldol Synthesis Norie Momiyama and Hisashi Yamamoto pp 1080–1081 DOI: 10.1021/ja0444637 Supporting Info

A Chromium Catalyst for the Polymerization of Ethylene as a Homogeneous Model for the Phillips Catalyst Leonard A. MacAdams, Gerald P. Buffone, Christopher D. Incarvito, Arnold L. Rheingold, and Klaus H. Theopold pp 1082–1083 DOI: 10.1021/ja043877x Supporting Info

The Phenylnitrene Rearrangement in the Inner Phase of a Hemicarcerand Ralf Warmuth and Slawomir Makowiec pp 1084–1085 DOI: 10.1021/ja044557g Supporting Info

Dynamics of Hyaluronan Oligosaccharides Revealed by 15N Relaxation Andrew Almond, Paul L. DeAngelis, and Charles D. Blundell pp 1086–1087 DOI: 10.1021/ja043526i Supporting Info

Reactive Cysteine Is Protonated in the Triplet Excited State of the LOV2 Domain in Adiantum Phytochrome3 Yoshiaki Sato, Tatsuya Iwata, Satoru Tokutomi, and Hideki Kandori pp 1088–1089 DOI: 10.1021/ja0436897

Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant Alexander T. Radosevich, Christine Musich, and F. Dean Toste pp 1090–1091 DOI: 10.1021/ja0433424 Supporting Info

Diastereoselective and Enantioselective Rh(I)-Catalyzed Additions of Arylboronic Acids to N-tert-Butanesulfinyl and N-Diphenylphosphinoyl Aldimines Daniel J. Weix, Yili Shi, and Jonathan A. Ellman pp 1092–1093 DOI: 10.1021/ja044003d Supporting Info

Rhodium-Catalyzed Cyclization of 1,6-Enynes Triggered by Addition of Arylboronic Acids Tomoya Miura, Masahiko Shimada, and Masahiro Murakami pp 1094–1095 DOI: 10.1021/ja0435079 Supporting Info

Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon Jan Roggenbuck and Michael Tiemann pp 1096–1097 DOI: 10.1021/ja043605u Supporting Info

Amorphous Se:  A New Platform for Synthesizing Superparamagnetic Colloids with Controllable Surfaces Unyong Jeong, Thurston Herricks, Edan Shahar, and Younan Xia pp 1098–1099 DOI: 10.1021/ja043847u Supporting Info

Structural Trends in Transition Metal Cation−Acetylene Complexes Revealed through the C−H Stretching Fundamentals Richard S. Walters, Paul v. R. Schleyer, Clemence Corminboeuf, and Michael A. Duncan pp 1100–1101 DOI: 10.1021/ja043766y

The Interaction of 1,1‘-Diisocyanoferrocene with Gold:  Formation of Monolayers and Supramolecular Polymerization of an Aurophilic Ferrocenophane Ulrich Siemeling, Dag Rother, Clemens Bruhn, Heinrich Fink, Tobias Weidner, Frank Träger, Alexander Rothenberger, Dieter Fenske, Andreas Priebe, Jörg Maurer, and Rainer Winter pp 1102–1103 DOI: 10.1021/ja0436244 Supporting Info

Role of Ion Ligands in the Attachment of Poly(ethylene oxide) to a Charged Surface Liraz Chai and Jacob Klein pp 1104–1105 DOI: 10.1021/ja043963x

Single-Feature Inking and Stamping:  A Versatile Approach to Molecular Patterning Jonathon D. Gerding, Dale M. Willard, and Alan Van Orden pp 1106–1107 DOI: 10.1021/ja045737t Supporting Info

Rotational Spectrum and Hydrogen Bonding of the H2O−HO Radical Complex Yasuhiro Ohshima, Kazuya Sato, Yoshihiro Sumiyoshi, and Yasuki Endo pp 1108–1109 DOI: 10.1021/ja0442973

Reaction Mechanism of cis-1,3-Butadiene Addition to the Si(100)-2 × 1 Surface Peter Minary and Mark E. Tuckerman pp 1110–1111 DOI: 10.1021/ja046934v Supporting Info

Magnetic Deformation of Self-Assembled Sexithiophene Spherical Nanocapsules Igor O. Shklyarevskiy, Pascal Jonkheijm, Peter C. M. Christianen, Albertus P. H. J. Schenning, E. W. Meijer, Oliver Henze, Andreas F. M. Kilbinger, W. James Feast, André Del Guerzo, Jean-Pierre Desvergne, and J. C. Maan pp 1112–1113 DOI: 10.1021/ja0431096 Supporting Info

Anionic Fullerenes, Calixarenes, Coronenes, and Pyrenes as Activators of Oligo/Polyarginines in Model Membranes and Live Cells Florent Perret, Masamichi Nishihara, Toshihide Takeuchi, Shiroh Futaki, Adina N. Lazar, Anthony W. Coleman, Naomi Sakai, and Stefan Matile pp 1114–1115 DOI: 10.1021/ja043633c Supporting Info

A New Polymorph of 5-Fluorouracil Found Following Computational Crystal Structure Predictions Ashley T. Hulme, Sarah L. Price, and Derek A. Tocher pp 1116–1117 DOI: 10.1021/ja044336a Supporting Info

The Second Cyclopropannulene:  Cycloprop-[8]annulene Matthew K. Kiesewetter, Richard C. Reiter, and Cheryl D. Stevenson pp 1118–1119 DOI: 10.1021/ja044278t Supporting Info

Field Emission Properties of Large-Area Nanowires of Organic Charge-Transfer Complexes Huibiao Liu, Qing Zhao, Yuliang Li, Yang Liu, Fushen Lu, Junpeng Zhuang, Shu Wang, Lei Jiang, Daoben Zhu, Dapeng Yu, and Lifeng Chi pp 1120–1121 DOI: 10.1021/ja0438359 Supporting Info

Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from Preformed Complexes [(TMS)2N]3Ln(μ-Cl)Li(THF)3 (Ln = Pr, Nd, Sm; (TMS)2N = Bis(trimethylsilyl)amide) Hong-Xi Li, Zhi-Gang Ren, Yong Zhang, Wen-Hua Zhang, Jian-Ping Lang, and Qi Shen pp 1122–1123 DOI: 10.1021/ja043415j Supporting Info

Generation of a Chiral Mesophase by Achiral Molecules:  Absolute Chiral Induction in the Smectic C Phase of 4-Octyloxyphenyl 4-Octyloxybenzoate Takashi Kajitani, Hyuma Masu, Shigeo Kohmoto, Makoto Yamamoto, Kentaro Yamaguchi, and Keiki Kishikawa pp 1124–1125 DOI: 10.1021/ja0438664 Supporting Info

Properties and Reactivity of Chlorovinylcobalamin and Vinylcobalamin and Their Implications for Vitamin B12-Catalyzed Reductive Dechlorination of Chlorinated Alkenes Kevin M. McCauley, Derek A. Pratt, Scott R. Wilson, Justin Shey, Theodore J. Burkey, and Wilfred A. van der Donk pp 1126–1136 DOI: 10.1021/ja048573p Supporting Info

Ferrioxamine B Analogues:  Targeting the FoxA Uptake System in the Pathogenic Yersinia enterocolitica Hagit Kornreich-Leshem, Carmit Ziv, Elzbieta Gumienna-Kontecka, Rina Arad-Yellin, Yona Chen, Mourad Elhabiri, Anne-Marie Albrecht-Gary, Yitzhak Hadar, and Abraham Shanzer pp 1137–1145 DOI: 10.1021/ja035182m Supporting Info

Decomposition of Triacetone Triperoxide Is an Entropic Explosion Faina Dubnikova, Ronnie Kosloff, Joseph Almog, Yehuda Zeiri, Roland Boese, Harel Itzhaky, Aaron Alt, and Ehud Keinan pp 1146–1159 DOI: 10.1021/ja0464903 Supporting Info

Duplex-Promoted Platination of Adenine-N3 in the Minor Groove of DNA:  Challenging a Longstanding Bioinorganic Paradigm Colin G. Barry, Cynthia S. Day, and Ulrich Bierbach pp 1160–1169 DOI: 10.1021/ja0451620 Supporting Info

Polymer−DNA Hybrids as Electrochemical Probes for the Detection of DNA Julianne M. Gibbs, So-Jung Park, Donde R. Anderson, Keith J. Watson, Chad A. Mirkin, and SonBinh T. Nguyen pp 1170–1178 DOI: 10.1021/ja046931i Supporting Info

Energetics and Structural Consequences of Axial Ligand Coordination in Nonplanar Nickel Porphyrins Yujiang Song, Raid E. Haddad, Song-Ling Jia, Saphon Hok, Marilyn M. Olmstead, Daniel J. Nurco, Neal E. Schore, Jun Zhang, Jian-Guo Ma, Kevin M. Smith, Stéphanie Gazeau, Jacques Pécaut, Jean-Claude Marchon, Craig J. Medforth, and John A. Shelnutt pp 1179–1192 DOI: 10.1021/ja045309n Supporting Info

Coassembly of Amphiphiles with Opposite Peptide Polarities into Nanofibers Heather A. Behanna, Jack J. J. M. Donners, Alex C. Gordon, and Samuel I. Stupp pp 1193–1200 DOI: 10.1021/ja044863u Supporting Info

Intramolecular [2 + 2] Photocycloaddition/Thermal Fragmentation:  Formally “Allowed” and “Forbidden” Pathways toward 5−8−5 Ring Systems Scott J. Bader and Marc L. Snapper pp 1201–1205 DOI: 10.1021/ja044542i Supporting Info

Bifunctional Lewis Acid-Nucleophile-Based Asymmetric Catalysis:  Mechanistic Evidence for Imine Activation Working in Tandem with Chiral Enolate Formation in the Synthesis of β-Lactams Stefan France, Meha H. Shah, Anthony Weatherwax, Harald Wack, Justine P. Roth, and Thomas Lectka pp 1206–1215 DOI: 10.1021/ja044179f Supporting Info

Photovoltaic Cells Using Composite Nanoclusters of Porphyrins and Fullerenes with Gold Nanoparticles Taku Hasobe, Hiroshi Imahori, Prashant V. Kamat, Tae Kyu Ahn, Seong Keun Kim, Dongho Kim, Atsushi Fujimoto, Tsutomu Hirakawa, and Shunichi Fukuzumi pp 1216–1228 DOI: 10.1021/ja047768u Supporting Info

Ground- and Excited-State Electronic Structure of an Emissive Pyrazine-Bridged Ruthenium(II) Dinuclear Complex Wesley R. Browne, Noel M. O'Boyle, William Henry, Adrian L. Guckian, Sabine Horn, Thomas Fett, Christine M. O'Connor, Marco Duati, Luisa De Cola, Colin G. Coates, Kate L. Ronayne, John J. McGarvey, and Johannes G. Vos pp 1229–1241 DOI: 10.1021/ja046034e Supporting Info

Can Luminescent Quantum Dots Be Efficient Energy Acceptors with Organic Dye Donors? Aaron R. Clapp, Igor L. Medintz, Brent R. Fisher, George P. Anderson, and Hedi Mattoussi pp 1242–1250 DOI: 10.1021/ja045676z

Fluid Mixing in Growing Microscale Vesicles Conjugated by Surfactant Nanotubes Max Davidson, Paul Dommersnes, Martin Markström, Jean-Francois Joanny, Mattias Karlsson, and Owe Orwar pp 1251–1257 DOI: 10.1021/ja0451113

Confinement of Transmembrane Cell Receptors in Tunable Stripe Micropatterns Oliver Purrucker, Anton Förtig, Karin Lüdtke, Rainer Jordan, and Motomu Tanaka pp 1258–1264 DOI: 10.1021/ja045713m Supporting Info

The Mechanism of the Self-Initiated Thermal Polymerization of Styrene. Theoretical Solution of a Classic Problem Kelli S. Khuong, Walter H. Jones, William A. Pryor, and K. N. Houk pp 1265–1277 DOI: 10.1021/ja0448667 Supporting Info

Transition Metal Complexes of Cyclic and Open Ozone and Thiozone Beate Flemmig, Peter T. Wolczanski, and Roald Hoffmann pp 1278–1285 DOI: 10.1021/ja044809d

Mechanism of Ligand Exchange Studied Using Transition Path Sampling Preston T. Snee, Jennifer Shanoski, and Charles B. Harris pp 1286–1290 DOI: 10.1021/ja044807t

Conformational Dynamics of the Nicotinic Acetylcholine Receptor Channel:  A 35-ns Molecular Dynamics Simulation Study Yechun Xu, Francisco J. Barrantes, Xiaomin Luo, Kaixian Chen, Jianhua Shen, and Hualiang Jiang pp 1291–1299 DOI: 10.1021/ja044577i Supporting Info

Photophysics and Biological Applications of the Environment-Sensitive Fluorophore 6-N,N-Dimethylamino-2,3-naphthalimide M. Eugenio Vázquez, Juan B. Blanco, and B. Imperiali pp 1300–1306 DOI: 10.1021/ja0449168 Supporting Info

Positional Ordering of Reacting Groups Contributes Significantly to the Efficiency of Proton Transfer at an Antibody Active Site Florian P. Seebeck and Donald Hilvert pp 1307–1312 DOI: 10.1021/ja044647l

Highly Enantioselective Conjugate Additions to α,β-Unsaturated Ketones Catalyzed by a (Salen)Al Complex Mark S. Taylor, David N. Zalatan, Andreas M. Lerchner, and Eric N. Jacobsen pp 1313–1317 DOI: 10.1021/ja044999s Supporting Info

Vapor−Solid Growth and Characterization of Aluminum Nitride Nanocones Chun Liu, Zheng Hu, Qiang Wu, Xizhang Wang, Yi Chen, Hai Sang, Jianmin Zhu, Shaozhi Deng, and Ningsheng Xu pp 1318–1322 DOI: 10.1021/ja045682v Supporting Info

Inframolecular Protonation Process of Norbadione A:  Influence of the Ionic Environment and Stereochemical Consequences Paul Kuad, Michal Borkovec, Marine Desage-El Murr, Thierry Le Gall, Charles Mioskowski, and Bernard Spiess pp 1323–1333 DOI: 10.1021/ja0483185 Supporting Info

A Biomimetic Approach to the Rocaglamides Employing Photogeneration of Oxidopyryliums Derived from 3-Hydroxyflavones  [J. Am. Chem. Soc. 2004, 126, 13620−13621].  Baudouin Gerard, Guilford Jones, II, and John A. Porco, Jr. p 1334 DOI: 10.1021/ja042481i

Issue 05

Axially Chiral Biaryl Diols Catalyze Highly Enantioselective Hetero-Diels−Alder Reactions through Hydrogen Bonding Aditya K. Unni, Norito Takenaka, Hisashi Yamamoto, and Viresh H. Rawal pp 1336–1337 DOI: 10.1021/ja044076x Supporting Info

A New Mode of Reactivity for Pyridine N-Oxide:  C−H Activation with Uranium(IV) and Thorium(IV) Bis(alkyl) Complexes Jaime A. Pool, Brian L. Scott, and Jaqueline L. Kiplinger pp 1338–1339 DOI: 10.1021/ja044153o Supporting Info

A Role for Fucose α(1−2) Galactose Carbohydrates in Neuronal Growth Stacey A. Kalovidouris, Cristal I. Gama, Lori W. Lee, and Linda C. Hsieh-Wilson pp 1340–1341 DOI: 10.1021/ja044631v Supporting Info

Metal Carbene-Promoted Sequential Transformations for the Enantioselective Synthesis of Highly Functionalized Cycloheptadienes Liang Deng, Anthony J. Giessert, Oksana O. Gerlitz, Xing Dai, Steven T. Diver, and Huw M. L. Davies pp 1342–1343 DOI: 10.1021/ja045173t Supporting Info

Assembly and Charge Transfer in Hybrid TiO2 Architectures Using Biotin−Avidin as a Connector Nada M. Dimitrijevic, Zoran V. Saponjic, Bryan M. Rabatic, and Tijana Rajh pp 1344–1345 DOI: 10.1021/ja0458118 Supporting Info

Computational De Novo Design and Characterization of a Four-Helix Bundle Protein that Selectively Binds a Nonbiological Cofactor Frank V. Cochran, Sophia P. Wu, Wei Wang, Vikas Nanda, Jeffery G. Saven, Michael J. Therien, and William F. DeGrado pp 1346–1347 DOI: 10.1021/ja044129a Supporting Info

Organic Thin-Film Transistors Based on Carbonyl-Functionalized Quaterthiophenes:  High Mobility N-Channel Semiconductors and Ambipolar Transport Myung-Han Yoon, Sara A. DiBenedetto, Antonio Facchetti, and Tobin J. Marks pp 1348–1349 DOI: 10.1021/ja045124g Supporting Info

Site-Specific Polymer Attachment to a CCL-5 (RANTES) Analogue by Oxime Exchange Haiyan Shao, Milan M. Crnogorac, Ting Kong, Shiah-Yun Chen, Jason M. Williams, Janette M. Tack, Vincent Gueriguian, E. Neil Cagle, Maia Carnevali, David Tumelty, Xavier Paliard, Les P. Miranda, James A. Bradburne, and Gerd G. Kochendoerfer pp 1350–1351 DOI: 10.1021/ja043096w Supporting Info

The Azaacepentalenide Anion:  A New Aromatic, Bowl-Shaped Heterocycle Mark Mascal and Jordi Cerón Bertran pp 1352–1353 DOI: 10.1021/ja043593c Supporting Info

Brønsted Acid-Promoted Olefin Aziridination and Formal anti-Aminohydroxylation Joseph M. Mahoney, Colin R. Smith, and Jeffrey N. Johnston pp 1354–1355 DOI: 10.1021/ja045608c Supporting Info

General Method for Modification of Liposomes for Encoded Assembly on Supported Bilayers Chiaki Yoshina-Ishii, Gregory P. Miller, Mary L. Kraft, Eric T. Kool, and Steven G. Boxer pp 1356–1357 DOI: 10.1021/ja043299k Supporting Info

ATP as Building Blocks for the Self-Assembly of Excitonic Nanowires Masa-aki Morikawa, Masakuni Yoshihara, Takeshi Endo, and Nobuo Kimizuka pp 1358–1359 DOI: 10.1021/ja043844h Supporting Info

Blue Alkali Dinitrosomethanides:  Synthesis, Structure, and Bonding Harald Brand, Peter Mayer, Kurt Polborn, Axel Schulz, and Jan J. Weigand pp 1360–1361 DOI: 10.1021/ja042877u Supporting Info

A Plant Type III Polyketide Synthase that Produces Pentaketide Chromone Ikuro Abe, Yoriko Utsumi, Satoshi Oguro, Hiroyuki Morita, Yukie Sano, and Hiroshi Noguchi pp 1362–1363 DOI: 10.1021/ja0431206 Supporting Info

Face-Integrated Fukui Function:  Understanding Wettability Anisotropy of Molecular Crystals from Density Functional Theory Tonglei Li, Shubin Liu, Shaoxin Feng, and Clare E. Aubrey pp 1364–1365 DOI: 10.1021/ja0476009 Supporting Info

Contrasteric Stereochemical Dictation of the Cyclobutene Ring-Opening Reaction by a Vacant Boron p Orbital Masahiro Murakami, Ippei Usui, Munehiro Hasegawa, and Takanori Matsuda pp 1366–1367 DOI: 10.1021/ja043979n Supporting Info

Ab Initio Calculation of Optical Rotation in (P)-(+)-[4]Triangulane T. Daniel Crawford, Lesley S. Owens, Mary C. Tam, Peter R. Schreiner, and Henrik Koch pp 1368–1369 DOI: 10.1021/ja042787p

Simple and Efficient Fabrication of Room Temperature Stable Electride:  Melt-Solidification and Glass Ceramics SungWng Kim, Masashi Miyakawa, Katsuro Hayashi, Takashi Sakai, Masahiro Hirano, and Hideo Hosono pp 1370–1371 DOI: 10.1021/ja043990n

Remarkable Effect of Silyl Groups on Asymmetric Induction in a Conjugate Addition Reaction with O-Methylnorephedrine-Based N-Silylamidocuprates1 Steven H. Bertz, Craig A. Ogle, and Abhinav Rastogi pp 1372–1373 DOI: 10.1021/ja0455805 Supporting Info

Cinchona Alkaloid/Sulfinyl Chloride Combinations:  Enantioselective Sulfinylating Agents of Alcohols Norio Shibata, Mitsuharu Matsunaga, Masaya Nakagawa, Takeo Fukuzumi, Shuichi Nakamura, and Takeshi Toru pp 1374–1375 DOI: 10.1021/ja0430189 Supporting Info

P450/NADPH/O2- and P450/PhIO-Catalyzed N-Dealkylations Are Mechanistically Distinct Mehul N. Bhakta, Paul F. Hollenberg, and Kandatege Wimalasena pp 1376–1377 DOI: 10.1021/ja0436143 Supporting Info

Surface Molecularly Imprinted Nanowires for Biorecognition Huang-Hao Yang, Shu-Qiong Zhang, Fang Tan, Zhi-Xia Zhuang, and Xiao-Ru Wang pp 1378–1379 DOI: 10.1021/ja0467622 Supporting Info

Titania-Supported PdAu Bimetallic Catalysts Prepared from Dendrimer-Encapsulated Nanoparticle Precursors Robert W. J. Scott, Chinta Sivadinarayana, Orla M. Wilson, Zhen Yan, D. Wayne Goodman, and Richard M. Crooks pp 1380–1381 DOI: 10.1021/ja044446h Supporting Info

Rational Design of Platinum(IV) Compounds to Overcome Glutathione-S-Transferase Mediated Drug Resistance Wee Han Ang, Isam Khalaila, Claire S. Allardyce, Lucienne Juillerat-Jeanneret, and Paul J. Dyson pp 1382–1383 DOI: 10.1021/ja0432618 Supporting Info

Electronic Decay Constant of Carotenoid Polyenes from Single-Molecule Measurements Jin He, Fan Chen, Jun Li, Otto F. Sankey, Yuichi Terazono, Christian Herrero, Devens Gust, Thomas A. Moore, Ana L. Moore, and Stuart M. Lindsay pp 1384–1385 DOI: 10.1021/ja043279i Supporting Info

Heterodinuclear Bridged Borylene Complexes Holger Braunschweig, Krzysztof Radacki, Daniela Rais, Fabian Seeler, and Katharina Uttinger pp 1386–1387 DOI: 10.1021/ja0426746 Supporting Info

Spectroscopic Evidence for Gas-Phase Formation of Successive β-Turns in a Three-Residue Peptide Chain Wutharath Chin, Isabelle Compagnon, Jean-Pierre Dognon, Clélia Canuel, François Piuzzi, Iliana Dimicoli, Gert von Helden, Gerard Meijer, and Michel Mons pp 1388–1389 DOI: 10.1021/ja042860b Supporting Info

Ketone Synthesis by Intramolecular Acylation of Organorhodium(I) with Ester Tomoya Miura, Taisuke Sasaki, Hiroki Nakazawa, and Masahiro Murakami pp 1390–1391 DOI: 10.1021/ja043123i Supporting Info

Building Addressable Libraries:  The Use of Electrochemistry for Spatially Isolating a Heck Reaction on a Chip Jun Tian, Karl Maurer, Eden Tesfu, and Kevin D. Moeller pp 1392–1393 DOI: 10.1021/ja042448w Supporting Info

Selective Oxidation of Methane by the Bis(μ-oxo)dicopper Core Stabilized on ZSM-5 and Mordenite Zeolites Marijke H. Groothaert, Pieter J. Smeets, Bert F. Sels, Pierre A. Jacobs, and Robert A. Schoonheydt pp 1394–1395 DOI: 10.1021/ja047158u Supporting Info

Helix-Forming Properties of Size-Expanded DNA, an Alternative Four-Base Genetic Form Haibo Liu, Jianmin Gao, and Eric T. Kool pp 1396–1402 DOI: 10.1021/ja046305l Supporting Info

Substrate Modulation of the Properties and Reactivity of the Oxy-Ferrous and Hydroperoxo-Ferric Intermediates of Cytochrome P450cam As Shown by Cryoreduction-EPR/ENDOR Spectroscopy Roman Davydov, Roshan Perera, Shengxi Jin, Tran-Chin Yang, Thomas A. Bryson, Masanori Sono, John H. Dawson, and Brian M. Hoffman pp 1403–1413 DOI: 10.1021/ja045351i Supporting Info

Structure, Assembly, and Topology of the G185R Mutant of the Fourth Transmembrane Domain of Divalent Metal Transporter Fei Li, Hongyan Li, Lihong Hu, Miufan Kwan, Guanhua Chen, Qing-Yu He, and Hongzhe Sun pp 1414–1423 DOI: 10.1021/ja047148t Supporting Info

Crystal Structure of a Partly Self-Complementary Peptide Nucleic Acid (PNA) Oligomer Showing a Duplex−Triplex Network Britt Petersson, Bettina Bryde Nielsen, Hanne Rasmussen, Ingrid Kjøller Larsen, Michael Gajhede, Peter E. Nielsen, and Jette Sandholm Kastrup pp 1424–1430 DOI: 10.1021/ja0458726

Inactivation of Horseradish Peroxidase by Phenoxyl Radical Attack Qing Huang, Qingguo Huang, Roger A. Pinto, Kai Griebenow, Reinhard Schweitzer-Stenner, and Walter J. Weber, Jr. pp 1431–1437 DOI: 10.1021/ja045986h

Spectroscopy and Quantum Chemical Modeling Reveal a Predominant Contribution of Excitonic Interactions to the Bathochromic Shift in α-Crustacyanin, the Blue Carotenoprotein in the Carapace of the Lobster Homarus gammarus Arjan A. C. van Wijk, Arnold Spaans, Natallia Uzunbajakava, Cees Otto, Huub J. M. de Groot, Johan Lugtenburg, and Francesco Buda pp 1438–1445 DOI: 10.1021/ja045049+ Supporting Info

Reactivity and Stability of Organocopper(I), Silver(I), and Gold(I) Ate Compounds and Their Trivalent Derivatives Waka Nakanishi, Masahiro Yamanaka, and Eiichi Nakamura pp 1446–1453 DOI: 10.1021/ja045659+ Supporting Info

Wavelength-Dependent Electron and Energy Transfer Pathways in a Side-to-Face Ruthenium Porphyrin/Perylene Bisimide Assembly Anna Prodi, Claudio Chiorboli, Franco Scandola, Elisabetta Iengo, Enzo Alessio, Rainer Dobrawa, and Frank Würthner pp 1454–1462 DOI: 10.1021/ja045379u

Ultrafast Time-Resolved Study of Photophysical Processes Involved in the Photodeprotection of p-Hydroxyphenacyl Caged Phototrigger Compounds Chensheng Ma, Wai Ming Kwok, Wing Sum Chan, Peng Zuo, Jovi Tze Wai Kan, Patrick H. Toy, and David Lee Phillips pp 1463–1472 DOI: 10.1021/ja0458524 Supporting Info

Total Synthesis of the Tricyclic Marine Alkaloids (−)-Lepadiformine, (+)-Cylindricine C, and (−)-Fasicularin via a Common Intermediate Formed by Formic Acid-Induced Intramolecular Conjugate Azaspirocyclization Hideki Abe, Sakae Aoyagi, and Chihiro Kibayashi pp 1473–1480 DOI: 10.1021/ja040213e Supporting Info

A Catalytic Asymmetric Bioorganic Route to Enantioenriched Tetrahydro- and Dihydropyranones Charles Baker-Glenn, Neil Hodnett, Maud Reiter, Sandrine Ropp, Rachael Ancliff, and Véronique Gouverneur pp 1481–1486 DOI: 10.1021/ja043925d Supporting Info

Highly Ordered Arrays of Metal/Semiconductor Core−Shell Nanoparticles with Tunable Nanostructures and Photoluminescence Yong Lei and Wai-Kin Chim pp 1487–1492 DOI: 10.1021/ja043969m Supporting Info

Oligomeric Rods of Alkyl- and Hydridogallium Imides Bethany L. Kormos, Jolin A. Jegier, Paul C. Ewbank, Udo Pernisz, Victor G. Young, Jr., Christopher J. Cramer, and Wayne L. Gladfelter pp 1493–1503 DOI: 10.1021/ja045149f Supporting Info

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units Nathaniel L. Rosi, Jaheon Kim, Mohamed Eddaoudi, Banglin Chen, Michael O'Keeffe, and Omar M. Yaghi pp 1504–1518 DOI: 10.1021/ja045123o Supporting Info

Mediator−Template Assembly of Nanoparticles Mathew M. Maye, I-Im S. Lim, Jin Luo, Zia Rab, Daniel Rabinovich, Tianbo Liu, and Chuan-Jian Zhong pp 1519–1529 DOI: 10.1021/ja044408y

Three-Site Model for Hydrogen Adsorption on Supported Platinum Particles:  Influence of Support Ionicity and Particle Size on the Hydrogen Coverage Michiel K. Oudenhuijzen, Jeroen A. van Bokhoven, Jeffrey T. Miller, David E. Ramaker, and Diederik C. Koningsberger pp 1530–1540 DOI: 10.1021/ja045286c Supporting Info

Controlled Oxidative Cutting of Single-Walled Carbon Nanotubes Kirk J. Ziegler, Zhenning Gu, Haiqing Peng, Erica L. Flor, Robert H. Hauge, and Richard E. Smalley pp 1541–1547 DOI: 10.1021/ja044537e Supporting Info

New Insights into the Stereoselectivity of the Aryl Zinc Addition to Aldehydes Jens Rudolph, Carsten Bolm, and Per-Ola Norrby pp 1548–1552 DOI: 10.1021/ja046254s Supporting Info

How Does the cAMP-Dependent Protein Kinase Catalyze the Phosphorylation Reaction:  An ab Initio QM/MM Study Yuhui Cheng, Yingkai Zhang, and J. Andrew McCammon pp 1553–1562 DOI: 10.1021/ja0464084

Structures and Properties of Self-Assembled Monolayers of Bistable [2]Rotaxanes on Au (111) Surfaces from Molecular Dynamics Simulations Validated with Experiment Seung Soon Jang, Yun Hee Jang, Yong-Hoon Kim, William A. Goddard III, Amar H. Flood, Bo W. Laursen, Hsian-Rong Tseng, J. Fraser Stoddart, Jan O. Jeppesen, Jang Wook Choi, David W. Steuerman, Erica DeIonno, and James R. Heath pp 1563–1575 DOI: 10.1021/ja044530x

Packing and Viscoelasticity of Polyunsaturated ω-3 and ω-6 Lipid Bilayers as Seen by 2H NMR and X-ray Diffraction Kannan Rajamoorthi, Horia I. Petrache, Thomas J. McIntosh, and Michael F. Brown pp 1576–1588 DOI: 10.1021/ja046453b

Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis. Topics in Organometallic Chemistry, 7 Edited by E. Peter Kündig (University of Geneva). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. viii + 232 pp. $269.00. ISBN 3-540-01604-X. Roy A. Periana p 1589 DOI: 10.1021/ja040984i

Crystallography of Modular Materials. IUCr Monographs on Crystallography, 15 By Giovanni Ferraris (University of Turin), Emil Makovicky (University of Copenhagen), and Stefano Merlino (University of Pisa). Oxford University Press:  Oxford. 2004. x + 370 pp. $144.50. ISBN 0-19-852664-4. T. Stanley Cameron pp 1589–1590 DOI: 10.1021/ja040958k

Reflexive Polymers and Hydrogels:  Understanding and Designing Fast Responsive Polymeric Systems Edited by Nobuhiko Yui (Japan Advanced Institute of Science and Technology, Ishikawa), Randall J. Mrsny (Welsh School of Pharmacy, Cardiff), and Kinam Park (Purdue University). CRC Press LLC:  Boca Raton, FL. 2004. xvi + 452 pp. $179.95. ISBN 0-8493-1487-9. Christopher S. Brazel p 1590 DOI: 10.1021/ja040974h

Issue 06

Swelling-Based Method for Preparing Stable, Functionalized Polymer Colloids Anthony J. Kim, Vinothan N. Manoharan, and John C. Crocker pp 1592–1593 DOI: 10.1021/ja0450051

Reversible Binding of Multivalent Ions by Surfactant Self-Assembly Johan P. A. Custers, Peter Kelemen, Leo J. P. van den Broeke, Martien A. Cohen Stuart, and Jos T. F. Keurentjes pp 1594–1595 DOI: 10.1021/ja0432362 Supporting Info

Paralog-Selective Ligands for Bcl-2 Proteins Anja C. Gemperli, Stacey E. Rutledge, Abby Maranda, and Alanna Schepartz pp 1596–1597 DOI: 10.1021/ja0441211 Supporting Info

Biocompatible Micropatterning of Two Different Cell Types Carlos C. Co, Yu-Chi Wang, and Chia-Chi Ho pp 1598–1599 DOI: 10.1021/ja044382a Supporting Info

Identification of a Molecular Recognition Role for the Activation Loop Phosphotyrosine of the Src Tyrosine Kinase Elizabeth J. Videlock, Victor K. Chung, Justin M. Hall, John Hines, Christina M. Agapakis, and David J. Austin pp 1600–1601 DOI: 10.1021/ja047957c Supporting Info

Diastereoselective Intermolecular Rhodium-Catalyzed [4 + 2 + 2] Carbocyclization Reactions:  Computational and Experimental Evidence for the Intermediacy of an Alternative Metallacycle Intermediate Mu-Hyun Baik, Erich W. Baum, Matthew C. Burland, and P. Andrew Evans pp 1602–1603 DOI: 10.1021/ja043521l Supporting Info

The Role of F-Centers in Catalysis by Au Supported on MgO Zhen Yan, Sivadinarayana Chinta, Ahmed A. Mohamed, John P. Fackler, Jr., and D. Wayne Goodman pp 1604–1605 DOI: 10.1021/ja043652m

ESR Investigation of a Stable Trapped Hydrogen Atom in X-ray-Irradiated β-Tricalcium Phosphate at Room Temperature Kouichi Nakashima and Jun Yamauchi pp 1606–1607 DOI: 10.1021/ja043084a

Reactivity of Secondary Metal−Alkyls in Catalytic Propene Polymerization:  How Dormant Are “Dormant Chains”? Vincenzo Busico, Roberta Cipullo, Valeria Romanelli, Sara Ronca, and Maria Togrou pp 1608–1609 DOI: 10.1021/ja042839a Supporting Info

Photochemical CO2 Splitting by Metal-to-Metal Charge-Transfer Excitation in Mesoporous ZrCu(I)-MCM-41 Silicate Sieve Wenyong Lin and Heinz Frei pp 1610–1611 DOI: 10.1021/ja040162l Supporting Info

Ratiometric Displacement Approach to Cu(II) Sensing by Fluorescence Maksim Royzen, Zhaohua Dai, and James W. Canary pp 1612–1613 DOI: 10.1021/ja0431051

Efficient Electrogenerated Chemiluminescence from Cyclometalated Iridium(III) Complexes Jae Il Kim, Ik-Soo Shin, Hasuck Kim, and Jin-Kyu Lee pp 1614–1615 DOI: 10.1021/ja043721x Supporting Info

Carboxylate−Imidazole Cooperativity in Dipeptide-Functionalized Gold Nanoparticles with Esterase-like Activity Paolo Pengo, Stefano Polizzi, Lucia Pasquato, and Paolo Scrimin pp 1616–1617 DOI: 10.1021/ja043547c Supporting Info

Determination of the Structural Environment of the Tyrosyl Radical in Prostaglandin H2 Synthase-1:  A High Frequency ENDOR/EPR Study John C. Wilson, Gang Wu, Ah-lim Tsai, and Gary J. Gerfen pp 1618–1619 DOI: 10.1021/ja043853q Supporting Info

Bond-Coupled Electron Transfer Processes:  Cleavage of Si−Si Bonds in Disilanes Rabih O. Al-Kaysi and Joshua L. Goodman pp 1620–1621 DOI: 10.1021/ja0432564 Supporting Info

Migrastatin and Dorrigocins Are Shunt Metabolites of Iso-Migrastatin Jianhua Ju, Si-Kyu Lim, Hui Jiang, and Ben Shen pp 1622–1623 DOI: 10.1021/ja043808i Supporting Info

Lactosylated Poly(ethylene glycol)-siRNA Conjugate through Acid-Labile β-Thiopropionate Linkage to Construct pH-Sensitive Polyion Complex Micelles Achieving Enhanced Gene Silencing in Hepatoma Cells Motoi Oishi, Yukio Nagasaki, Keiji Itaka, Nobuhiro Nishiyama, and Kazunori Kataoka pp 1624–1625 DOI: 10.1021/ja044941d Supporting Info

Delivery Platform for Hydrophobic Drugs:  Prodrug Approach Combined with Self-Assembled Multilayers Benjamin Thierry, Piotr Kujawa, Cathy Tkaczyk, Françoise M. Winnik, Luc Bilodeau, and Maryam Tabrizian pp 1626–1627 DOI: 10.1021/ja045077s Supporting Info

Catalytic Asymmetric Synthesis of a Potent Thiomarinol Antibiotic Xuri Gao and Dennis G. Hall pp 1628–1629 DOI: 10.1021/ja042827p Supporting Info

Efficient Stereoselective Synthesis of γ-N-Glycosyl Asparagines by N-Glycosylation of Primary Amide Groups Hiroshi Tanaka, Yuki Iwata, Daisuke Takahashi, Masaatsu Adachi, and Takashi Takahashi pp 1630–1631 DOI: 10.1021/ja0450298 Supporting Info

Interfacial pH at an Isolated Silica−Water Surface Josephine P. O'Reilly, Craig P. Butts, Ian A. I'Anson, and Andrew M. Shaw pp 1632–1633 DOI: 10.1021/ja0443326

Band Gap Engineering of CdTe Nanocrystals through Chemical Surface Modification Kensuke Akamatsu, Takaaki Tsuruoka, and Hidemi Nawafune pp 1634–1635 DOI: 10.1021/ja044150b Supporting Info

Particle Arrays with Patterned Pores by Nanomachining with Colloidal Masks Dae-Geun Choi, Sarah Kim, Eeunsug Lee, and Seung-Man Yang pp 1636–1637 DOI: 10.1021/ja044578a

Ladder Oligo(p-phenylenevinylene)s with Silicon and Carbon Bridges Caihong Xu, Atsushi Wakamiya, and Shigehiro Yamaguchi pp 1638–1639 DOI: 10.1021/ja042964m Supporting Info

Single-Walled Carbon Nanotube-Templated Crystallization of H2SO4:  Direct Evidence for Protonation Wei Zhou, Paul A. Heiney, Hua Fan, Richard E. Smalley, and John E. Fischer pp 1640–1641 DOI: 10.1021/ja043131z

Synthesis and Applications of Chiral Organoboranes Generated from Sulfonium Ylides Varinder K. Aggarwal, Guang Yu Fang, and Andreas T. Schmidt pp 1642–1643 DOI: 10.1021/ja043632k Supporting Info

Signal Amplification and Detection via a Supramolecular Allosteric Catalyst Nathan C. Gianneschi, SonBinh T. Nguyen, and Chad A. Mirkin pp 1644–1645 DOI: 10.1021/ja0437306 Supporting Info

Postsynthetic Modification at the Focal Point of a Hyperbranched Polymer Peter J. Gittins and Lance J. Twyman pp 1646–1647 DOI: 10.1021/ja043909g Supporting Info

A Parallel Electromagnetic Molecular Logic Gate Oded Hod, Roi Baer, and Eran Rabani pp 1648–1649 DOI: 10.1021/ja043366a

Preparation of Poly(phenyl)acetylenes Having Diazo Groups and Magnetic Characterization of Poly(carbene) Tetsuji Itoh, Yoshinobu Jinbo, Katsuyuki Hirai, and Hideo Tomioka pp 1650–1651 DOI: 10.1021/ja0455345 Supporting Info

Latent Fluorophore Based on the Trimethyl Lock Sunil S. Chandran, Kimberly A. Dickson, and Ronald T. Raines pp 1652–1653 DOI: 10.1021/ja043736v Supporting Info

Thiazolylalanine-Derived Catalysts for Enantioselective Intermolecular Aldehyde−Imine Cross-Couplings Steven M. Mennen, John D. Gipson, Yoona R. Kim, and Scott J. Miller pp 1654–1655 DOI: 10.1021/ja042650z Supporting Info

Synthesis of Water-Dispersible Fluorescent, Radio-Opaque, and Paramagnetic CdS:Mn/ZnS Quantum Dots:  A Multifunctional Probe for Bioimaging Swadeshmukul Santra, Heesun Yang, Paul H. Holloway, Jessie T. Stanley, and Robert A. Mericle pp 1656–1657 DOI: 10.1021/ja0464140 Supporting Info

Origins of the Activity of PAL and LAP Enzyme Inhibitors:  Toward Ab Initio Binding Affinity Prediction Edyta Dyguda, Jolanta Grembecka, W. Andrzej Sokalski, and Jerzy Leszczyński pp 1658–1659 DOI: 10.1021/ja042691v Supporting Info

DNA-Templated Functional Group Transformations Enable Sequence-Programmed Synthesis Using Small-Molecule Reagents Kaori Sakurai, Thomas M. Snyder, and David R. Liu pp 1660–1661 DOI: 10.1021/ja0432315 Supporting Info

An Affinity Probe for Isolation of Abscisic Acid-Binding Proteins James M. Nyangulu, Marek M. Galka, Ashok Jadhav, Yuanzhu Gai, Cindy M. Graham, Ken M. Nelson, Adrian J. Cutler, David C. Taylor, Gary M. Banowetz, and Suzanne R. Abrams pp 1662–1664 DOI: 10.1021/ja0429059 Supporting Info

Protein NMR Recall, Precision, and F-measure Scores (RPF Scores):  Structure Quality Assessment Measures Based on Information Retrieval Statistics Yuanpeng J. Huang, Robert Powers, and Gaetano T. Montelione pp 1665–1674 DOI: 10.1021/ja047109h Supporting Info

Synthesis, Structure Determination, and Spectroscopic/Computational Characterization of a Series of Fe(II)−Thiolate Model Complexes:  Implications for Fe−S Bonding in Superoxide Reductases Adam T. Fiedler, Heather L. Halfen, Jason A. Halfen, and Thomas C. Brunold pp 1675–1689 DOI: 10.1021/ja046939s Supporting Info

Water-Solubilized, Cap-Stabilized, Helical Polyalanines:  Calibration Standards for NMR and CD Analyses Björn Heitmann, Gabriel E. Job, Robert J. Kennedy, Sharon M. Walker, and Daniel S. Kemp pp 1690–1704 DOI: 10.1021/ja0457462 Supporting Info

Synergistic Stabilization of Nucleic Acid Assembly by Oligo-N3‘→P5‘ Phosphoramidate Modification and Additions of Comb-type Cationic Copolymers Hidetaka Torigoe and Atushi Maruyama pp 1705–1710 DOI: 10.1021/ja044964s Supporting Info

A New Family of Glucose-1-phosphate/Glucosamine-1-phosphate Nucleotidylyltransferase in the Biosynthetic Pathways for Antibiotics Fumitaka Kudo, Kenichi Kawabe, Hisako Kuriki, Tadashi Eguchi, and Katsumi Kakinuma pp 1711–1718 DOI: 10.1021/ja044921b

Duplex Molecular Strands Based on the 3,6-Diaminopyridazine Hydrogen Bonding Motif:  Amplifying Small-Molecule Self-Assembly Preferences through Preorganization and Iterative Arrangement of Binding Residues Hegui Gong and Michael J. Krische pp 1719–1725 DOI: 10.1021/ja044566p Supporting Info

Membrane Dynamics of the Amphiphilic Siderophore, Acinetoferrin Minkui Luo, Evgeny A. Fadeev, and John T. Groves pp 1726–1736 DOI: 10.1021/ja044230f Supporting Info

Structural and Thermodynamic Studies on Cation−Π Interactions in Lectin−Ligand Complexes:  High-Affinity Galectin-3 Inhibitors through Fine-Tuning of an Arginine−Arene Interaction Pernilla Sörme, Pascal Arnoux, Barbro Kahl-Knutsson, Hakon Leffler, James M. Rini, and Ulf J. Nilsson pp 1737–1743 DOI: 10.1021/ja043475p Supporting Info

Thiophene Dendron Jacketed Poly(amidoamine) Dendrimers:  Nanoparticle Synthesis and Adsorption on Graphite Suxiang Deng, Jason Locklin, Derek Patton, Akira Baba, and Rigoberto C. Advincula pp 1744–1751 DOI: 10.1021/ja046144l

Rearrangements and Stereomutations of Metallacycles Derived from Allenes and Imidozirconium Complexes Forrest E. Michael, Andrew P. Duncan, Zachary K. Sweeney, and Robert G. Bergman pp 1752–1764 DOI: 10.1021/ja045607k Supporting Info

Highly Metallized Polymers:  Synthesis, Characterization, and Lithographic Patterning of Polyferrocenylsilanes with Pendant Cobalt, Molybdenum, and Nickel Cluster Substituents Wing Yan Chan, Scott B. Clendenning, Andrea Berenbaum, Alan J. Lough, Stephane Aouba, Harry E. Ruda, and Ian Manners pp 1765–1772 DOI: 10.1021/ja045386i Supporting Info

Oxidation of Guanosine Derivatives by a Platinum(IV) Complex:  Internal Electron Transfer through Cyclization Sunhee Choi, Richard B. Cooley, Adelina Voutchkova, Chin Hin Leung, Livia Vastag, and Darcy E. Knowles pp 1773–1781 DOI: 10.1021/ja045194n

Dynamics of Photoinduced Processes in Adenine and Thymine Base Pairs E. Samoylova, H. Lippert, S. Ullrich, I. V. Hertel, W. Radloff, and T. Schultz pp 1782–1786 DOI: 10.1021/ja044369q

Palladium Pincer Complex Catalyzed Stannyl and Silyl Transfer to Propargylic Substrates:  Synthetic Scope and Mechanism Johan Kjellgren, Henrik Sundén, and Kálmán J. Szabó pp 1787–1796 DOI: 10.1021/ja043951b Supporting Info

“Separated” versus “Contact” Ion-Pair Structures in Solution from Their Crystalline States:  Dynamic Effects on Dinitrobenzenide as a Mixed-Valence Anion Jian-Ming Lü, Sergiy V. Rosokha, Sergey V. Lindeman, Ivan S. Neretin, and Jay K. Kochi pp 1797–1809 DOI: 10.1021/ja043998x Supporting Info

Structural Design Criteria for Anion Hosts:  Strategies for Achieving Anion Shape Recognition through the Complementary Placement of Urea Donor Groups Benjamin P. Hay, Timothy K. Firman, and Bruce A. Moyer pp 1810–1819 DOI: 10.1021/ja043995k Supporting Info

Triplet-State Formation along the Ultrafast Decay of Excited Singlet Cytosine Manuela Merchán, Luis Serrano-Andrés, Michael A. Robb, and Lluís Blancafort pp 1820–1825 DOI: 10.1021/ja044371h Supporting Info

Phosphodiester Cleavage of Guanylyl-(3‘,3‘)-(2‘-amino-2‘-deoxyuridine):  Rate Acceleration by the 2‘-Amino Function Mikko Ora, Heidi Linjalahti, and Harri Lönnberg pp 1826–1832 DOI: 10.1021/ja045060+

Mechanism and Scope of the Cyanide-Catalyzed Cross Silyl Benzoin Reaction Xin Linghu, Cory C. Bausch, and Jeffrey S. Johnson pp 1833–1840 DOI: 10.1021/ja044086y Supporting Info

Acrylonitrile Insertion Reactions of Cationic Palladium Alkyl Complexes Fan Wu, Stephen R. Foley, Christopher T. Burns, and Richard F. Jordan pp 1841–1853 DOI: 10.1021/ja044122t

Insertion of Acrylonitrile into Palladium Methyl Bonds in Neutral and Anionic Pd(II) Complexes Laurent F. Groux, Thomas Weiss, Dastigiri N. Reddy, Preston A. Chase, Warren E. Piers, Tom Ziegler, Masood Parvez, and Jordi Benet-Buchholz pp 1854–1869 DOI: 10.1021/ja044119+ Supporting Info

A Succession of Isomers of Ruthenium Dihydride Complexes. Which One Is the Ketone Hydrogenation Catalyst? Robert Abbel, Kamaluddin Abdur-Rashid, Michael Faatz, Alen Hadzovic, Alan J. Lough, and Robert H. Morris pp 1870–1882 DOI: 10.1021/ja039396f Supporting Info

Isomerization and Deuterium Scrambling Evidence for a Change in the Rate-Limiting Step during Imine Hydrogenation by Shvo's Hydroxycyclopentadienyl Ruthenium Hydride Charles P. Casey and Jeffrey B. Johnson pp 1883–1894 DOI: 10.1021/ja044450t Supporting Info

IrII(ethene):  Metal or Carbon Radical? Dennis G. H. Hetterscheid, Jasper Kaiser, Eduard Reijerse, Theo P. J. Peters, Simone Thewissen, Arno N. J. Blok, Jan M. M. Smits, René de Gelder, and Bas de Bruin pp 1895–1905 DOI: 10.1021/ja0439470 Supporting Info

Application of the Generalized 2D Correlation Analysis to Dynamic Near-Edge X-ray Absorption Spectroscopy Data Peter Haider, Yuan Chen, Sangyun Lim, Gary L. Haller, Lisa Pfefferle, and Dragos Ciuparu pp 1906–1912 DOI: 10.1021/ja045391m

Ground-State Singlet L3Fe-(μ-N)-FeL3 and L3Fe(NR) Complexes Featuring Pseudotetrahedral Fe(II) Centers Steven D. Brown and Jonas C. Peters pp 1913–1923 DOI: 10.1021/ja0453073 Supporting Info

Controlled Polymerization in Mesoporous Silica toward the Design of Organic−Inorganic Composite Nanoporous Materials Minkee Choi, Freddy Kleitz, Dinan Liu, Hee Yoon Lee, Wha-Seung Ahn, and Ryong Ryoo pp 1924–1932 DOI: 10.1021/ja044907z Supporting Info

On [Fe4S4]2+−(μ2-SR)−MII Bridge Formation in the Synthesis of an A-Cluster Analogue of Carbon Monoxide Dehydrogenase/Acetylcoenzyme A Synthase P. Venkateswara Rao, Sumit Bhaduri, Jianfeng Jiang, Daewon Hong, and R. H. Holm pp 1933–1945 DOI: 10.1021/ja040222n Supporting Info

Dynamic and Electrostatic Effects in Enzymatic Processes. An Analysis of the Nucleophilic Substitution Reaction in Haloalkane Dehalogenase Alejandro Soriano, Estanislao Silla, Iñaki Tuñón, and Manuel F. Ruiz-López pp 1946–1957 DOI: 10.1021/ja046553h

Introducing Krypton NMR Spectroscopy as a Probe of Void Space in Solids Charlene F. Horton-Garcia, Galina E. Pavlovskaya, and Thomas Meersmann pp 1958–1962 DOI: 10.1021/ja045636v

Redox Potentials of Chlorophylls and β-Carotene in the Antenna Complexes of Photosystem II Hiroshi Ishikita and Ernst-Walter Knapp pp 1963–1968 DOI: 10.1021/ja045058i Supporting Info

Phosphorylation Effects on cis/trans Isomerization and the Backbone Conformation of Serine−Proline Motifs:  Accelerated Molecular Dynamics Analysis Donald Hamelberg, Tongye Shen, and J. Andrew McCammon pp 1969–1974 DOI: 10.1021/ja0446707

Understanding the Barriers to Crystal Growth:  Dynamical Simulation of the Dissolution and Growth of Urea from Aqueous Solution Stefano Piana and Julian D. Gale pp 1975–1982 DOI: 10.1021/ja043395l

Radical Cation of a Trimethylenemethane with a Nondegenerate Ground State Thomas Bally, Alexander Maltsev, Fabian Gerson, Daniel Frank, and A. de Meijere pp 1983–1988 DOI: 10.1021/ja046961l Supporting Info

Sequence-Specific, Self-Reporting Hairpin Inversion Probes Kenneth A. Browne pp 1989–1994 DOI: 10.1021/ja046369w

Limited Variations in 15N CSA Magnitudes and Orientations in Ubiquitin Are Revealed by Joint Analysis of Longitudinal and Transverse NMR Relaxation Peter Damberg, Jüri Jarvet, and Astrid Gräslund pp 1995–2005 DOI: 10.1021/ja045956e Supporting Info

Selective Anion Sensing by a Tris-Amide CTV Derivative:  1H NMR Titration, Self-Assembled Monolayers, and Impedance Spectroscopy Sheng Zhang and Luis Echegoyen pp 2006–2011 DOI: 10.1021/ja044411h

Molecular Clusters of the Main Group Elements Edited by Matthias Driess (Ruhr-Universität Bochum) and Heinrich Nöth (Ludwig-Maximilians Universität-München). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xvi + 444 pp. $150.00. ISBN 3-527-30654-4. Russell N. Grimes pp 2012–2013 DOI: 10.1021/ja0409558

Organometallics in Process Chemistry. Topics in Organometallic Chemistry, 6 Edited by Robert D. Larsen. Merck and Co., Inc.:  Rahway, NJ. Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 296 pp. $229.00. ISBN 3-540-01603-1. Kim Albizati p 2013 DOI: 10.1021/ja040983q

Fundamental Electron Interactions with Plasma Processing Gases By Loucas G. Christophorou (National Institute of Standards and Technology, Gaithersburg and Academy of Athens, Greece) and James K. Olthoff (National Institute of Standards and Technology, Gaithersburg). Kluwer Academic/Plenum Publishers:  New York. 2004. xvi + 783 pp. $199.00. ISBN 0-306-48037-9. C. William McCurdy pp 2013–2014 DOI: 10.1021/ja040964g

Ruthenium Catalysts and Fine Chemistry. Topics in Organometallic Chemistry, 11 Edited by Christian Bruneau and Pierre H. Dixneuf (Université de Rennes 1). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 347 pp. $329.00. ISBN 3-540-20543-8. Philip Magnus p 2014 DOI: 10.1021/ja040987v

Organic Chemistry in Photography By Shinsaku Fujita (Kyoto Institute of Technology). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xx + 588 pp. $249.00. ISBN 3-540-20988-3. Bruce E. Kahn pp 2014–2015 DOI: 10.1021/ja040975+

New Synthetic Methods. Advances in Polymer Science, 167 With contributions by Owen W. Webster (Chadds Ford, PA), Jean Jacques Robin (Ecole Nationale Supérieure de Chimie Montpellier), Takashi Uemura, Kensuke Naka, Yoshiki Chujo (Kyoto University), Younghwan Kwon (Daegu University), and Rudolf Faust (University of Massachusetts, Lowell). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 156 pp. $179.00. ISBN 3-540-00544-7. Jacques Penelle p 2015 DOI: 10.1021/ja040962w

Electrogenerated Chemiluminescence Edited by Allen J. Bard (University of Texas at Austin). Marcel Dekker, Inc.:  New York. 2004. viii + 540 pp. $165.00. ISBN 0-8247-5347-X. Nicholas Leventis pp 2015–2016 DOI: 10.1021/ja040978m

Issue 07

Controlling Protein Orientation at Interfaces Using Histidine Tags:  An Alternative to Ni/NTA Daniel L. Johnson and Lisandra L. Martin pp 2018–2019 DOI: 10.1021/ja045084g Supporting Info

Probing Every Layer in Dendrons Kulandaivelu Sivanandan, Sivakumar V. Aathimanikandan, Christopher G. Arges, Christopher J. Bardeen, and S. Thayumanavan pp 2020–2021 DOI: 10.1021/ja043356+ Supporting Info

Using a Deoxyribozyme Ligase and Rolling Circle Amplification To Detect a Non-nucleic Acid Analyte, ATP Eun Jeong Cho, Litao Yang, Matthew Levy, and Andrew D. Ellington pp 2022–2023 DOI: 10.1021/ja043490u Supporting Info

Oxytocin-Receptor Binding:  Why Divalent Metals Are Essential Dengfeng Liu, Alexandra B. Seuthe, Oli T. Ehrler, Xiaohua Zhang, Thomas Wyttenbach, Jeffrey F. Hsu, and Michael T. Bowers pp 2024–2025 DOI: 10.1021/ja046042v Supporting Info

Reversible Inside−Out Micellization of pH-responsive and Water-Soluble Vesicles Based on Polypeptide Diblock Copolymers Juan Rodríguez-Hernández and Sébastien Lecommandoux pp 2026–2027 DOI: 10.1021/ja043920g Supporting Info

Assignment and NOE Analysis of 2‘-Hydroxyl Protons in RNA:  Implications for Stabilization of RNA A-Form Duplexes Mirko Hennig, Jörg Fohrer, and Teresa Carlomagno pp 2028–2029 DOI: 10.1021/ja043390o Supporting Info

A Highly Emissive Cu2N2 Diamond Core Complex Supported by a [PNP]- Ligand Seth B. Harkins and Jonas C. Peters pp 2030–2031 DOI: 10.1021/ja043092r Supporting Info

1,5-Diamino-4-methyltetrazolium Dinitramide Thomas M. Klapötke, Peter Mayer, Axel Schulz, and Jan J. Weigand pp 2032–2033 DOI: 10.1021/ja042596m Supporting Info

A [2]Rotaxane Capped by a Cyclodextrin and a Guest:  Formation of Supramolecular [2]Rotaxane Polymer Masahiko Miyauchi, Taiki Hoshino, Hiroyasu Yamaguchi, Shigehiro Kamitori, and Akira Harada pp 2034–2035 DOI: 10.1021/ja042840+ Supporting Info

Turn and Helical Peptide Handedness Governed Exclusively by Side-Chain Chiral Centers Soledad Royo, Wim M. De Borggraeve, Cristina Peggion, Fernando Formaggio, Marco Crisma, Ana I. Jiménez, Carlos Cativiela, and Claudio Toniolo pp 2036–2037 DOI: 10.1021/ja043116u Supporting Info

Highly Efficient One-Pot Synthesis of N-Sulfonylamidines by Cu-Catalyzed Three-Component Coupling of Sulfonyl Azide, Alkyne, and Amine Imhyuck Bae, Hoon Han, and Sukbok Chang pp 2038–2039 DOI: 10.1021/ja0432968 Supporting Info

Escherichia coli O86 O-Antigen Biosynthetic Gene Cluster and Stepwise Enzymatic Synthesis of Human Blood Group B Antigen Tetrasaccharide Wen Yi, Jun Shao, Lizhi Zhu, Mei Li, Mamata Singh, Yuquan Lu, Steven Lin, Hanfen Li, Kang Ryu, Jie Shen, Hongjie Guo, Qingjia Yao, C. Allen Bush, and Peng G. Wang pp 2040–2041 DOI: 10.1021/ja045021y Supporting Info

Calcium-Mediated Intramolecular Hydroamination Catalysis Mark R. Crimmin, Ian J. Casely, and Michael S. Hill pp 2042–2043 DOI: 10.1021/ja043576n Supporting Info

Protein Heterodimerization through Ligand-Bridged Multivalent Pre-organization:  Enhancing Ligand Binding toward Both Protein Targets Jiyun Liu, Zhongsheng Zhang, Xiaojian Tan, Wim G. J. Hol, Christophe L. M. J. Verlinde, and Erkang Fan pp 2044–2045 DOI: 10.1021/ja043817r Supporting Info

Silylene Transfer to Carbonyl Compounds and Subsequent Ireland−Claisen Rearrangements to Control Formation of Quaternary Carbon Stereocenters Stacie A. Calad and K. A. Woerpel pp 2046–2047 DOI: 10.1021/ja042893r Supporting Info

Energy and Electron Transfers in Photosensitive Chitosan Shuizhu Wu, Fang Zeng, Hongping Zhu, and Zhen Tong pp 2048–2049 DOI: 10.1021/ja045356f Supporting Info

Anhydrous Tetrabutylammonium Fluoride Haoran Sun and Stephen G. DiMagno pp 2050–2051 DOI: 10.1021/ja0440497 Supporting Info

Influence of Structure on Binding of Chlorophylls to Peptide Ligands Min Chen, Laura L. Eggink, J. Kenneth Hoober, and Anthony W. D. Larkum pp 2052–2053 DOI: 10.1021/ja043462b

Synthesis of Nanoscale NbSe2 Materials from Molecular Precursors Perumal Sekar, Eric C. Greyson, Jeremy E. Barton, and Teri W. Odom pp 2054–2055 DOI: 10.1021/ja0428006 Supporting Info

Activation for Catalysis of Penicillin-Binding Protein 2a from Methicillin-Resistant Staphylococcus aureus by Bacterial Cell Wall Cosimo Fuda, Dusan Hesek, Mijoon Lee, Ken-ichiro Morio, Thomas Nowak, and Shahriar Mobashery pp 2056–2057 DOI: 10.1021/ja0434376 Supporting Info

Electrochemical Sensing Platform Based on the Carbon Nanotubes/Redox Mediators-Biopolymer System Maogen Zhang and Waldemar Gorski pp 2058–2059 DOI: 10.1021/ja044764g Supporting Info

A New Approach to Highly Electrooptically Active Materials Using Cross-Linkable, Hyperbranched Chromophore-Containing Oligomers as a Macromolecular Dopant Yaowen Bai, Naiheng Song, Jian Ping Gao, Xun Sun, Xiaomei Wang, Guomin Yu, and Zhi Yuan Wang pp 2060–2061 DOI: 10.1021/ja042854f Supporting Info

Establishing the Kinetic Competency of the Cationic Imine Intermediate in Nitroalkane Oxidase Michael P. Valley, Shane E. Tichy, and Paul F. Fitzpatrick pp 2062–2066 DOI: 10.1021/ja043542f

On the Catalytic Mechanism of Choline Oxidase Fan Fan and Giovanni Gadda pp 2067–2074 DOI: 10.1021/ja044541q Supporting Info

Amyloid β-Protein:  Monomer Structure and Early Aggregation States of Aβ42 and Its Pro19 Alloform Summer L. Bernstein, Thomas Wyttenbach, Andrij Baumketner, Joan-Emma Shea, Gal Bitan, David B. Teplow, and Michael T. Bowers pp 2075–2084 DOI: 10.1021/ja044531p Supporting Info

Design of a Calcium-Binding Protein with Desired Structure in a Cell Adhesion Molecule Wei Yang, Anna L. Wilkins, Yiming Ye, Zhi-ren Liu, Shun-yi Li, Jeffrey L. Urbauer, Homme W. Hellinga, Alice Kearney, P. Anton van der Merwe, and Jenny J. Yang pp 2085–2093 DOI: 10.1021/ja0431307 Supporting Info

Biomolecule-Based Switching Devices that Respond Inversely to Thermal Stimuli Ryu Tashiro and Hiroshi Sugiyama pp 2094–2097 DOI: 10.1021/ja044138j Supporting Info

Electron Transfer Reaction in a Single Protein Molecule Observed by Total Internal Reflection Fluorescence Microscopy Yoshiaki Furukawa, Tadato Ban, Daizo Hamada, Koichiro Ishimori, Yuji Goto, and Isao Morishima pp 2098–2103 DOI: 10.1021/ja0478173

Subtilisin-Catalyzed Resolution of N-Acyl Arylsulfinamides Christopher K. Savile, Vladimir P. Magloire, and Romas J. Kazlauskas pp 2104–2113 DOI: 10.1021/ja045397b Supporting Info

Photochemistry of 5-Phenyl-1-pentene in the Gas Phase Chang-Dar D. Ho and Harry Morrison pp 2114–2124 DOI: 10.1021/ja044504z Supporting Info

Formation of Nanoarchitectures Including Subnanometer Palladium Clusters and Their Use as Highly Active Catalysts Kuniaki Okamoto, Ryo Akiyama, Hisao Yoshida, Tomoko Yoshida, and Shū Kobayashi pp 2125–2135 DOI: 10.1021/ja047095f

Chiroptical Switching Polyguanidine Synthesized by Helix-Sense-Selective Polymerization Using [(R)-3,3‘-Dibromo-2,2‘-binaphthoxy](di-tert-butoxy)titanium(IV) Catalyst Hong-Zhi Tang, Paul D. Boyle, and Bruce M. Novak pp 2136–2142 DOI: 10.1021/ja0453533 Supporting Info

Chemical Reactivities of the Cation and Anion of M@C82 (M = Y, La, and Ce) Yutaka Maeda, Jun Miyashita, Tadashi Hasegawa, Takatsugu Wakahara, Takahiro Tsuchiya, Lai Feng, Yongfu Lian, Takeshi Akasaka, Kaoru Kobayashi, Shigeru Nagase, Masahiro Kako, Kazunori Yamamoto, and Karl M. Kadish pp 2143–2146 DOI: 10.1021/ja043986b

Dynamic Ligand Exchange of the Lanthanide Complex Leading to Structural and Functional Transformation:  One-Pot Sequential Catalytic Asymmetric Epoxidation-Regioselective Epoxide-Opening Process Shin-ya Tosaki, Riichiro Tsuji, Takashi Ohshima, and Masakatsu Shibasaki pp 2147–2155 DOI: 10.1021/ja043770+ Supporting Info

N,N‘-Linked Oligoureas as Foldamers: Chain Length Requirements for Helix Formation in Protic Solvent Investigated by Circular Dichroism, NMR Spectroscopy, and Molecular Dynamics Aude Violette, Marie Christine Averlant-Petit, Vincent Semetey, Christine Hemmerlin, Richard Casimir, Roland Graff, Michel Marraud, Jean-Paul Briand, Didier Rognan, and Gilles Guichard pp 2156–2164 DOI: 10.1021/ja044392b Supporting Info

Light-Harvesting and Photoisomerization in Benzophenone and Norbornadiene-Labeled Poly(aryl ether) Dendrimers via Intramolecular Triplet Energy Transfer Jinping Chen, Shayu Li, Lu Zhang, Baining Liu, Yongbin Han, Guoqiang Yang, and Yi Li pp 2165–2171 DOI: 10.1021/ja044800b Supporting Info

Thiol-Functionalized, 1.5-nm Gold Nanoparticles through Ligand Exchange Reactions:  Scope and Mechanism of Ligand Exchange Gerd H. Woehrle, Leif O. Brown, and James E. Hutchison pp 2172–2183 DOI: 10.1021/ja0457718 Supporting Info

Solutes Probe Hydration in Specific Association of Cyclodextrin and Adamantane Daniel Harries, Donald C. Rau, and V. Adrian Parsegian pp 2184–2190 DOI: 10.1021/ja045541t

Combination of Nitrogen Dioxide Radicals with 8-Oxo-7,8-dihydroguanine and Guanine Radicals in DNA:  Oxidation and Nitration End-Products Richard Misiaszek, Conor Crean, Nicholas E. Geacintov, and Vladimir Shafirovich pp 2191–2200 DOI: 10.1021/ja044390r Supporting Info

Coordination Assembled Rings of Ferrocene-Bridged Trisporphyrin with Flexible Hinge-like Motion:  Selective Dimer Ring Formation, Its Transformation to Larger Rings, and Vice Versa Osami Shoji, Saori Okada, Akiharu Satake, and Yoshiaki Kobuke pp 2201–2210 DOI: 10.1021/ja0445746 Supporting Info

Metal-Free Catalysts for the Hydrolysis of RNA Derived from Guanidines, 2-Aminopyridines, and 2-Aminobenzimidazoles Ute Scheffer, Andreas Strick, Verena Ludwig, Sascha Peter, Elisabeth Kalden, and Michael W. Göbel pp 2211–2217 DOI: 10.1021/ja0443934 Supporting Info

Correlations between 31P Chemical Shift Anisotropy and Molecular Structure in Polycrystalline O,O‘-Dialkyldithiophosphate Zinc(II) and Nickel(II) Complexes:  31P CP/MAS NMR and Ab Initio Quantum Mechanical Calculation Studies Anna-Carin Larsson, Alexander V. Ivanov, Willis Forsling, Oleg N. Antzutkin, Anu E. Abraham, and Angel C. de Dios pp 2218–2230 DOI: 10.1021/ja0306112 Supporting Info

Photoinduced Electroreduction of Chlorophyllide on Alkanethiol-Coated Mercury Francesco Tadini Buoninsegni, Maria Rosa Moncelli, Giovanni Aloisi, Angela Agostiano, and Rolando Guidelli pp 2231–2237 DOI: 10.1021/ja045527g

Interaction with Glycine Increases Stability of a Mutagenic Tautomer of Uracil. A Density Functional Theory Study Iwona Dbkowska, Maciej Gutowski, and Janusz Rak pp 2238–2248 DOI: 10.1021/ja048730k Supporting Info

A Computational Study of the Effect of Bending on Secondary Kinetic Isotope Effects in SN2 Transition States Faraj Hasanayn, Andrew Streitwieser, and Rasha Al-Rifai pp 2249–2255 DOI: 10.1021/ja0487978 Supporting Info

Stereoisomers of 1,3,5,7-Tetrahydroxy-1,3,5,7-tetraisopropylcyclotetrasiloxane:  Synthesis and Structures in the Crystal Masafumi Unno, Yasuaki Kawaguchi, Yukiko Kishimoto, and Hideyuki Matsumoto pp 2256–2263 DOI: 10.1021/ja043894m Supporting Info

Detection of a Biomarker for Alzheimer's Disease from Synthetic and Clinical Samples Using a Nanoscale Optical Biosensor Amanda J. Haes, Lei Chang, William L. Klein, and Richard P. Van Duyne pp 2264–2271 DOI: 10.1021/ja044087q

Physisorption of Hydroxide Ions from Aqueous Solution to a Hydrophobic Surface Ronen Zangi and Jan B. F. N. Engberts pp 2272–2276 DOI: 10.1021/ja044426f

Bonding and Oxidation State of a Transition Metal Atom Encapsulated in an Isolated Octahedral Cluster Cation of Main Group Elements:  Synthesis, Crystal Structure, and Electronic Structure of Pt2In14Ga3O8F15 Containing Highly Positive 18-Electron Complex [PtIn6]10+ and Low-Valent In+ Ions Jürgen Köhler, Jen-Hui Chang, and Myung-Hwan Whangbo pp 2277–2284 DOI: 10.1021/ja044389s Supporting Info

Silver(I)−Imidazole Cyclophane gem-Diol Complexes Encapsulated by Electrospun Tecophilic Nanofibers:  Formation of Nanosilver Particles and Antimicrobial Activity Abdulkareem Melaiye, Zhaohui Sun, Khadijah Hindi, Amy Milsted, Daniel Ely, Darrell H. Reneker, Claire A. Tessier, and Wiley J. Youngs pp 2285–2291 DOI: 10.1021/ja040226s Supporting Info

Anion-Templated Assembly of Pseudorotaxanes:  Importance of Anion Template, Strength of Ion-Pair Thread Association, and Macrocycle Ring Size Mark R. Sambrook, Paul D. Beer, James A. Wisner, Rowena L. Paul, Andrew R. Cowley, Fridrich Szemes, and Michael G. B. Drew pp 2292–2302 DOI: 10.1021/ja046278z Supporting Info

Formation of Third Generation Poly(pyrazolyl)borate Ligands from Alkyne Coupling Reactions of Fe[(p-IC6H4)B(3-Rpz)3]2 (R = H, Me; pz = Pyrazolyl):  Pathways toward Controlling an Iron(II) Electronic Spin-State Crossover Daniel L. Reger, James R Gardinier, William R. Gemmill, Mark D. Smith, Ahmed M. Shahin, Gary J. Long, Leila Rebbouh, and Fernande Grandjean pp 2303–2316 DOI: 10.1021/ja044900h Supporting Info

Synthesis of a Regioregular Zwitterionic Conjugated Oligoelectrolyte, Usable as an Optical Probe for Detection of Amyloid Fibril Formation at Acidic pH Anna Herland, K. Peter R. Nilsson, Johan D. M. Olsson, Per Hammarström, Peter Konradsson, and Olle Inganäs pp 2317–2323 DOI: 10.1021/ja045835e Supporting Info

Identity Hydride-Ion Transfer from C−H Donors to C Acceptor Sites. Enthalpies of Hydride Addition and Enthalpies of Activation. Comparison with C···H···C Proton Transfer. An ab Initio Study Scott Gronert and James R. Keeffe pp 2324–2333 DOI: 10.1021/ja044002l Supporting Info

Structures and Energies of Isolobal (BCO)n and (CH)n Cages Hai-Shun Wu, Xiao-Fang Qin, Xiao-Hong Xu, Haijun Jiao, and Paul v. R. Schleyer pp 2334–2338 DOI: 10.1021/ja046740f Supporting Info

Hopping Transport in Conductive Heterocyclic Oligomers:  Reorganization Energies and Substituent Effects Geoffrey R. Hutchison, Mark A. Ratner, and Tobin J. Marks pp 2339–2350 DOI: 10.1021/ja0461421

Energetically Driven Reorganization of a Modified Catalytic Surface under Reaction Conditions Andrea Locatelli, Carlo Sbraccia, Stefan Heun, Stefano Baroni, and Maya Kiskinova pp 2351–2357 DOI: 10.1021/ja045285k Supporting Info

Spontaneous Immobilization of Liposomes on Electron-Beam Exposed Resist Surfaces Jong Min Kim, Ho Sup Jung, Jong Wan Park, Tetsuo Yukimasa, Hiroaki Oka, Hea Yeon Lee, and Tomoji Kawai pp 2358–2362 DOI: 10.1021/ja046169k Supporting Info

A Catalytic [4 + 1] Cycloaddition of α, β-Unsaturated Carbonyl Compounds with Isocyanides [J. Am. Chem. Soc. 2005, 127, 761−766]. Masayuki Oshita, Kohei Yamashita, Mamoru Tobisu, and Naoto Chatani p 2363 DOI: 10.1021/ja042540s

Temperature Dependence of Three-Body Hydrophobic Interactions:  Potential of Mean Force, Enthalpy, Entropy, Heat Capacity, and Nonadditivity [J. Am. Chem. Soc. 2005, 127, 303−316]. Maria Sabaye Moghaddam, Seishi Shimizu, and Hue Sun Chan p 2363 DOI: 10.1021/ja050266b

Publicon. Wolfram Research, Inc 100 Trade Center Drive, Champaign, IL 61820-7237. http://www.wolfram. com/products/publicon. $149.00 (in the United States and Canada). Outside the United States and Canada, contact http://www.wolfram.com/international for pricing. Chris Pursell and Susan Oxley p 2364 DOI: 10.1021/ja040985a

Pseudo-Peptides in Drug Discovery Edited by Peter E. Nielsen (University of Copenhagen). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xii + 244 pp. $125.00. ISBN 3-527-30633-1. Kevin Burgess p 2365 DOI: 10.1021/ja0409964

Chemometrics:  From Basics to Wavelet Transform. Chemical Analysis, Volume 164 By Foo-Tim Chau (Hong Kong Polytechnic University), Yi-Zeng Liang (Central South University), Junbin Gao (University of New England), and Xue-Guang Shao (University of Science and Technology of China). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xiv + 316 pp. $99.95. ISBN 0-471-20242-8. Barry K. Lavine pp 2365–2366 DOI: 10.1021/ja040937q

Issue 08

Sonochemical Preparation of Hollow Nanospheres and Hollow Nanocrystals N. Arul Dhas and Kenneth S. Suslick pp 2368–2369 DOI: 10.1021/ja049494g Supporting Info

67Zn NMR Chemical Shifts and Electric Field Gradients in Zinc Complexes:  A Quantum Chemical Investigation Yong Zhang, Sujoy Mukherjee, and Eric Oldfield pp 2370–2371 DOI: 10.1021/ja040242p Supporting Info

Searching for DDAH Inhibitors:  S-Nitroso-l-homocysteine Is a Chemical Lead Markus Knipp, Oliver Braun, and Milan Vašák pp 2372–2373 DOI: 10.1021/ja0430200 Supporting Info

Microhydration of Guanine Base Pairs Ali Abo-Riziq, Bridgit Crews, Louis Grace, and Mattanjah S. de Vries pp 2374–2375 DOI: 10.1021/ja043000y

Selective Small Molecules Blocking HIV-1 Tat and Coactivator PCAF Association Lei Zeng, Jiaming Li, Michaela Muller, Sherry Yan, Shiraz Mujtaba, Chongfeng Pan, Zhiyong Wang, and Ming-Ming Zhou pp 2376–2377 DOI: 10.1021/ja044885g Supporting Info

A General Low-Temperature Route for Large-Scale Fabrication of Highly Oriented ZnO Nanorod/Nanotube Arrays Haidong Yu, Zhongping Zhang, Mingyong Han, Xiaotao Hao, and Furong Zhu pp 2378–2379 DOI: 10.1021/ja043121y Supporting Info

Unusually High Performance Photovoltaic Cell Based on a [60]Fullerene Metal Cluster−Porphyrin Dyad SAM on an ITO Electrode Youn-Jaung Cho, Tae Kyu Ahn, Hyunjoon Song, Kil Suk Kim, Chang Yeon Lee, Won Seok Seo, Kwangyeol Lee, Seong Keun Kim, Dongho Kim, and Joon T. Park pp 2380–2381 DOI: 10.1021/ja044847x Supporting Info

Mixed Valence Isomers J. Catherine Salsman and Clifford P. KubiakTasuku Ito pp 2382–2383 DOI: 10.1021/ja042351+

Can Block Copolymers Be Synthesized by a Single-Step Chemoenzymatic Route in Supercritical Carbon Dioxide? Christopher J. Duxbury, Wenxin Wang, Matthijs de Geus, Andreas Heise, and Steven M. Howdle pp 2384–2385 DOI: 10.1021/ja042903o

Large Gate Modulation in the Current of a Room Temperature Single Molecule Transistor Bingqian Xu, Xiaoyin Xiao, Xiaomei Yang, Ling Zang, and Nongjian Tao pp 2386–2387 DOI: 10.1021/ja042385h Supporting Info

Synthesis of Planar Chiral Phosphapalladacycles by Highly Enantioselective Transcyclopalladation Francesc X. Roca, Majid Motevalli, and Christopher J. Richards pp 2388–2389 DOI: 10.1021/ja042930e Supporting Info

Enantioselective Radical Addition/Trapping Reactions with α,β-Disubstituted Unsaturated Imides. Synthesis of anti-Propionate Aldols Mukund P. Sibi, Goran Petrovic, and Jake Zimmerman pp 2390–2391 DOI: 10.1021/ja043371e Supporting Info

55Mn Pulse ENDOR at 34 GHz of the S0 and S2 States of the Oxygen-Evolving Complex in Photosystem II Leonid V. Kulik, Boris Epel, Wolfgang Lubitz, and Johannes Messinger pp 2392–2393 DOI: 10.1021/ja043012j

Terminal Phosphate-Labeled Nucleotides with Improved Substrate Properties for Homogeneous Nucleic Acid Assays Anup Sood, Shiv Kumar, Satyam Nampalli, John R. Nelson, John Macklin, and Carl W. Fuller pp 2394–2395 DOI: 10.1021/ja043595x Supporting Info

Peptide-Cleaving Catalyst Selective for Peptide Deformylase Pil Seok Chae, Myoung-soon Kim, Chul-Seung Jeung, Seong Du Lee, Hwangseo Park, Sangyoub Lee, and Junghun Suh pp 2396–2397 DOI: 10.1021/ja044043h Supporting Info

Room Temperature Ionic Liquids from 20 Natural Amino Acids Kenta Fukumoto, Masahiro Yoshizawa, and Hiroyuki Ohno pp 2398–2399 DOI: 10.1021/ja043451i Supporting Info

Folding Directed N-Oxidation of Oligopyridine−Dicarboxamide Strands and Hybridization of Oxidized Oligomers Christel Dolain, Chuanlang Zhan, Jean-Michel Léger, Lee Daniels, and Ivan Huc pp 2400–2401 DOI: 10.1021/ja0424631 Supporting Info

Photoinduced Deformation of Amphiphilic Azo Polymer Colloidal Spheres Yaobang Li, Yaning He, Xiaolan Tong, and Xiaogong Wang pp 2402–2403 DOI: 10.1021/ja0424981 Supporting Info

New Aspects of Diphenylbutadiene Photochemistry. Regiospecific Hula-Twist Photoisomerization Lan-ying Yang, Robert S. H. Liu, Kelly J. Boarman, Natalie L. Wendt, and Jin Liu pp 2404–2405 DOI: 10.1021/ja043193p Supporting Info

High-Performance, Stable Organic Thin-Film Field-Effect Transistors Based on Bis-5‘-alkylthiophen-2‘-yl-2,6-anthracene Semiconductors Hong Meng, Fangping Sun, Marc B. Goldfinger, Gary D. Jaycox, Zhigang Li, Will J. Marshall, and Gregory S. Blackman pp 2406–2407 DOI: 10.1021/ja043189d Supporting Info

Unprecedented Chemistry of an Aryloxychlorodiazirine:  Generation of a Dihalodiazirine and Diazirinone Robert A. Moss, Gaosheng Chu, and Ronald R. Sauers pp 2408–2409 DOI: 10.1021/ja050103n Supporting Info

A Lipophilic Hexaporphyrin Assembly Supported on a Stannoxane Core Vadapalli Chandrasekhar, Selvarajan Nagendran, Ramachandran Azhakar, Murugaeson Ravi Kumar, Alagar Srinivasan, Kallol Ray, Tavarekere K. Chandrashekar, C. Madhavaiah, Sandeep Verma, U. Deva Priyakumar, and G. Narahari Sastry pp 2410–2411 DOI: 10.1021/ja043748g Supporting Info

The Synthesis of (−)-Isodomoic Acid C Jonathan Clayden, Faye E. Knowles, and Ian R. Baldwin pp 2412–2413 DOI: 10.1021/ja042415g Supporting Info

Structure-Dependent Modulation of a Pathogen Response in Plants by Synthetic O-Antigen Polysaccharides Emiliano Bedini, Cristina De Castro, Gitte Erbs, Lorenzo Mangoni, J. Maxwell Dow, Mari-Anne Newman, Michelangelo Parrilli, and Carlo Unverzagt pp 2414–2416 DOI: 10.1021/ja0452166 Supporting Info

Simultaneous Binding of meso-Tetrakis(N-methylpyridinium-4-yl)porphyrin and 4‘,6-Diamidino-2-phenylindole at the Minor Grooves of Poly(dA)·poly(dT) and Poly[d(A−T)2]:  Fluorescence Resonance Energy Transfer between DNA Bound Drugs Biao Jin, Hyun Mee Lee, Young-Ae Lee, Jae Hong Ko, Cheol Kim, and Seog K. Kim pp 2417–2424 DOI: 10.1021/ja044555w

Investigation of a Putative Möbius Aromatic Hydrocarbon. The Effect of Benzannelation on Möbius [4n]Annulene Aromaticity Claire Castro, Zhongfang Chen, Chaitanya S. Wannere, Haijun Jiao, William L. Karney, Michael Mauksch, Ralph Puchta, Nico J. R. van Eikema Hommes, and Paul von Ragué Schleyer pp 2425–2432 DOI: 10.1021/ja0458165 Supporting Info

Photoisomerization Mechanism of 11-cis-Locked Artificial Retinal Chromophores:  Acceleration and Primary Photoproduct Assignment Luca De Vico, Marco Garavelli, Fernando Bernardi, and Massimo Olivucci pp 2433–2442 DOI: 10.1021/ja045747u Supporting Info

Base-Catalyzed Hydrogenation:  Rationalizing the Effects of Catalyst and Substrate Structures and Solvation Bun Chan and Leo Radom pp 2443–2454 DOI: 10.1021/ja0450253 Supporting Info

Optical Activity Induced by Helical Arrangements of Tryptamine and 4-Chlorobenzoic Acid in Their Cocrystal Hideko Koshima, Masaki Nagano, and Toru Asahi pp 2455–2463 DOI: 10.1021/ja044472f Supporting Info

Structure−Property Relationships of Donor/Acceptor-Functionalized Tetrakis(phenylethynyl)benzenes and Bis(dehydrobenzoannuleno)benzenes Jeremiah A. Marsden, Jeremie J. Miller, Laura D. Shirtcliff, and Michael M. Haley pp 2464–2476 DOI: 10.1021/ja044175a Supporting Info

Fluorescent Cocaine Probes:  A Tool for the Selection and Engineering of Therapeutic Antibodies Michael M. Meijler, Gunnar F. Kaufmann, Longwu Qi, Jenny M. Mee, Avery R. Coyle, Jason A. Moss, Peter Wirsching, Masayuki Matsushita, and Kim D. Janda pp 2477–2484 DOI: 10.1021/ja043935e Supporting Info

Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC):  A Detailed Study on Their Interaction with Ni(CO)4 Reto Dorta, Edwin D. Stevens, Natalie M. Scott, Chiara Costabile, Luigi Cavallo, Carl D. Hoff, and Steven P. Nolan pp 2485–2495 DOI: 10.1021/ja0438821 Supporting Info

Size-Dependent Dissociation pH of Thiolate Ligands from Cadmium Chalcogenide Nanocrystals Jose Aldana, Natasha Lavelle, Yunjun Wang, and Xiaogang Peng pp 2496–2504 DOI: 10.1021/ja047000+ Supporting Info

Catalytically Active μ-Oxodiiron(IV) Oxidants from Iron(III) and Dioxygen Anindya Ghosh, Filipe Tiago de Oliveira, Toshihiro Yano, Takanori Nishioka, Evan S. Beach, Isamu Kinoshita, Eckard Münck, Alexander D. Ryabov, Colin P. Horwitz, and Terrence J. Collins pp 2505–2513 DOI: 10.1021/ja0460458 Supporting Info

Covalently Attached Monolayers on Crystalline Hydrogen-Terminated Silicon:  Extremely Mild Attachment by Visible Light Qiao-Yu Sun, Louis C. P. M. de Smet, Barend van Lagen, Marcel Giesbers, Peter C. Thüne, Johan van Engelenburg, Frits A. de Wolf, Han Zuilhof, and Ernst J. R. Sudhölter pp 2514–2523 DOI: 10.1021/ja045359s Supporting Info

Amine-Assisted Facetted Etching of CdSe Nanocrystals Rongfu Li, Jeunghoon Lee, Baocheng Yang, David N. Horspool, Mark Aindow, and Fotios Papadimitrakopoulos pp 2524–2532 DOI: 10.1021/ja0465404 Supporting Info

Nanoscale Vibrational Analysis of Single-Walled Carbon Nanotubes Neil Anderson, Achim Hartschuh, Steve Cronin, and Lukas Novotny pp 2533–2537 DOI: 10.1021/ja045190i

Rhodium Boryl Complexes in the Catalytic, Terminal Functionalization of Alkanes John F. Hartwig, Kevin S. Cook, Marko Hapke, Christopher D. Incarvito, Yubo Fan, Charles Edwin Webster, and Michael B. Hall pp 2538–2552 DOI: 10.1021/ja045090c Supporting Info

Temperature-Induced Switching of the Mechanism for Intramolecular Energy Transfer in a 2,2‘:6‘,2‘ ‘-Terpyridine-Based Ru(II)−Os(II) Trinuclear Array Andrew C. Benniston, Anthony Harriman, Peiyi Li, and Craig A. Sams pp 2553–2564 DOI: 10.1021/ja044097r Supporting Info

A Ferroelectrically Switchable Columnar Liquid Crystal Phase with Achiral Molecules:  Superstructures and Properties of Liquid Crystalline Ureas Keiki Kishikawa, Shoichiro Nakahara, Yohei Nishikawa, Shigeo Kohmoto, and Makoto Yamamoto pp 2565–2571 DOI: 10.1021/ja046100c Supporting Info

Shape of 4(S)- and 4(R)-Hydroxyproline in Gas Phase Alberto Lesarri, Emilio J. Cocinero, Juan C. López, and José L. Alonso pp 2572–2579 DOI: 10.1021/ja045955m Supporting Info

Simulation of the Embryonic Stage of ZnS Formation from Aqueous Solution Said Hamad, Sylvain Cristol, and C. Richard A. Catlow pp 2580–2590 DOI: 10.1021/ja045274r Supporting Info

Understanding Structure and Bonding in Early Actinide 6d05f0 MX6q (M = Th−Np; X = H, F) Complexes in Comparison with Their Transition Metal 5d0 Analogues Michal Straka, Peter Hrobárik, and Martin Kaupp pp 2591–2599 DOI: 10.1021/ja044982+ Supporting Info

Flexible Docking in Solution Using Metadynamics Francesco Luigi Gervasio, Alessandro Laio, and Michele Parrinello pp 2600–2607 DOI: 10.1021/ja0445950 Supporting Info

Balancing Dynamic and Nondynamic Correlation for Diradical and Aromatic Transition States:  A Renormalized Coupled-Cluster Study of the Cope Rearrangement of 1,5-Hexadiene Michael J. McGuire and Piotr Piecuch pp 2608–2614 DOI: 10.1021/ja044734d Supporting Info

Unexpectedly Strong Energy Stabilization Inside the Hydrophobic Core of Small Protein Rubredoxin Mediated by Aromatic Residues:  Correlated Ab Initio Quantum Chemical Calculations Jiří Vondrášek, Lada Bendová, Vojtěch Klusák, and Pavel Hobza pp 2615–2619 DOI: 10.1021/ja044607h Supporting Info

New Selective Haloform-type Reaction Yielding 3-Hydroxy-2,2-difluoroacids:  Theoretical Study of the Mechanism Santiago Olivella, Albert Solé, Óscar Jiménez, M. Pilar Bosch, and Angel Guerrero pp 2620–2627 DOI: 10.1021/ja043522d Supporting Info

Photochemistry of 2-(1-Naphthyl)-2H-azirines in Matrixes and in Solutions:  Wavelength-Dependent C−C and C−N Bond Cleavage of the Azirine Ring Hiroshi Inui and Shigeru Murata pp 2628–2636 DOI: 10.1021/ja040109x Supporting Info

Altering the Folding Patterns of Naphthyl Trimers Gregory J. Gabriel, Steven Sorey, and Brent L. Iverson pp 2637–2640 DOI: 10.1021/ja046722y Supporting Info

Kinetics of the Reactions of Halide Anions with Carbocations:  Quantitative Energy Profiles for SN1 Reactions Shinya Minegishi, Robert Loos, Shinjiro Kobayashi, and Herbert Mayr pp 2641–2649 DOI: 10.1021/ja045562n Supporting Info

Enantioselective, Chirally Templated Sol−Gel Thin Films Sharon Fireman-Shoresh, Inna Popov, David Avnir, and Sharon Marx pp 2650–2655 DOI: 10.1021/ja0454384 Supporting Info

Multiply Doped Nanostructured Silicate Sol−Gel Thin Films:  Spatial Segregation of Dopants, Energy Transfer, and Distance Measurements Payam N. Minoofar, Bruce S. Dunn, and Jeffrey I. Zink pp 2656–2665 DOI: 10.1021/ja045185e

Polyynes as a Model for Carbyne:  Synthesis, Physical Properties, and Nonlinear Optical Response Sara Eisler, Aaron D. Slepkov, Erin Elliott, Thanh Luu, Robert McDonald, Frank A. Hegmann, and Rik R. Tykwinski pp 2666–2676 DOI: 10.1021/ja044526l Supporting Info

Elucidation of the Thermochemical Properties of Triphenyl- or Tributyl-Substituted Si-, Ge-, and Sn-Centered Radicals by Means of Electrochemical Approaches and Computations Allan Hjarbæk Holm, Tore Brinck, and Kim Daasbjerg pp 2677–2685 DOI: 10.1021/ja044687p Supporting Info

Mechanistic Investigation of the Staudinger Ligation Fiona L. Lin, Helen M. Hoyt, Herman van Halbeek, Robert G. Bergman, and Carolyn R. Bertozzi pp 2686–2695 DOI: 10.1021/ja044461m Supporting Info

Determination of N−NO Bond Dissociation Energies of N-Methyl-N-nitrosobenzenesulfonamides in Acetonitrile and Application in the Mechanism Analyses on NO Transfer Xiao-Qing Zhu, Wei-Fang Hao, Hui Tang, Chun-Hua Wang, and Jin-Pei Cheng pp 2696–2708 DOI: 10.1021/ja0443676 Supporting Info

Generation and Reaction of Tungsten-Containing Carbonyl Ylides:  [3 + 2]-Cycloaddition Reaction with Electron-Rich Alkenes Hiroyuki Kusama, Hideaki Funami, Masahide Shido, Yoshihiro Hara, Jun Takaya, and Nobuharu Iwasawa pp 2709–2716 DOI: 10.1021/ja044194k Supporting Info

Photochromic Control of Photoinduced Electron Transfer. Molecular Double-Throw Switch Stephen D. Straight, Joakim Andréasson, Gerdenis Kodis, Ana L. Moore, Thomas A. Moore, and Devens Gust pp 2717–2724 DOI: 10.1021/ja044128i

Asymmetric Synthesis of Dihydrofurans via a Formal Retro-Claisen Photorearrangement Wujiong Xia, Chao Yang, Brian O. Patrick, John R. Scheffer, and Carl Scott pp 2725–2730 DOI: 10.1021/ja043254j Supporting Info

Probing the Local Environments of Phosphorus in Aluminophosphate-Based Mesostructured Lamellar Materials by Solid-State NMR Spectroscopy Yining Huang and Zhimin Yan pp 2731–2740 DOI: 10.1021/ja040167i Supporting Info

Development of a Technique to Determine Bicyclomycin-Rho Binding and Stoichiometry by Isothermal Titration Calorimetry and Mass Spectrometry Andrew P. Brogan, William R. Widger, Dalila Bensadek, Isabel Riba-Garcia, Simon J. Gaskell, and Harold Kohn pp 2741–2751 DOI: 10.1021/ja046441q Supporting Info

Does Core Size Matter in the Kinetics of Ligand Exchanges of Monolayer-Protected Au Clusters? Rui Guo, Yang Song, Gangli Wang, and Royce W. Murray pp 2752–2757 DOI: 10.1021/ja044638c Supporting Info

Systematic Study of the Structure−Property Relationship of a Series of Ferrocenyl Nonlinear Optical Chromophores Yi Liao, Bruce E. Eichinger, Kimberly A. Firestone, Marnie Haller, Jingdong Luo, Werner Kaminsky, Jason B. Benedict, Philip J. Reid, Alex K-Y Jen, Larry R. Dalton, and Bruce H. Robinson pp 2758–2766 DOI: 10.1021/ja0449123 Supporting Info

High-Resolution Four-Dimensional 1H−13C NOE Spectroscopy using Methyl-TROSY, Sparse Data Acquisition, and Multidimensional Decomposition Vitali Tugarinov, Lewis E. Kay, Ilghiz Ibraghimov, and Vladislav Yu. Orekhov pp 2767–2775 DOI: 10.1021/ja044032o

A Quantum Chemical Study of the Reaction Mechanism of Acetyl-Coenzyme A Synthase Patricia Amara, Anne Volbeda, Juan Carlos Fontecilla-Camps, and Martin J. Field pp 2776–2784 DOI: 10.1021/ja0439221

Intramolecular Migration of Amide Hydrogens in Protonated Peptides upon Collisional Activation Thomas J. D. Jørgensen, Henrik Gårdsvoll, Michael Ploug, and Peter Roepstorff pp 2785–2793 DOI: 10.1021/ja043789c

Polymers and Light. Advances in Polymer Science, 168 Edited by Thomas K. Lippert (Paul Scherrer Institut, Switzerland). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xii + 360 pp. $299.00. ISBN 3-540-40471-6. Charles E. Hoyle p 2794 DOI: 10.1021/ja040963o

Sax's Dangerous Properties of Industrial Materials, 11th Edition By Richard J. Lewis, Sr. (Lewis Information Systems, Inc.). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. $595.00 print set (other pricings available for CD-ROM and online versions). ISBN 0-471-47662-5 for print set. p 2794 DOI: 10.1021/ja041002c

Issue 09

Discovery of and Mechanistic Insight into a Ligand-Modulated Palladium-Catalyzed Wacker Oxidation of Styrenes Using TBHP Candace N. Cornell and Matthew S. Sigman pp 2796–2797 DOI: 10.1021/ja043203m Supporting Info

Endohedral Clusterization of Ten Water Molecules into a “Molecular Ice” within the Hydrophobic Pocket of a Self-Assembled Cage Michito Yoshizawa, Takahiro Kusukawa, Masaki Kawano, Takashi Ohhara, Ichiro Tanaka, Kazuo Kurihara, Nobuo Niimura, and Makoto Fujita pp 2798–2799 DOI: 10.1021/ja043953w Supporting Info

A Self-Assembling Protein Template for Constrained Synthesis and Patterning of Nanoparticle Arrays R. Andrew McMillan, Jeanie Howard, Nestor J. Zaluzec, Hiromi K. Kagawa, Rakesh Mogul, Yi-Fen Li, Chad D. Paavola, and Jonathan D. Trent pp 2800–2801 DOI: 10.1021/ja043827s Supporting Info

An in Vitro Selection System for TNA Justin K. Ichida, Keyong Zou, Allen Horhota, Biao Yu, Larry W. McLaughlin, and Jack W. Szostak pp 2802–2803 DOI: 10.1021/ja045364w Supporting Info

A Self-Assembled Nano Optical Switch and Transistor Based on a Rigid Conjugated Polymer, Thioacetyl-End-Functionalized Poly(para-phenylene ethynylene) Wenping Hu, Hiroshi Nakashima, Kazuaki Furukawa, Yoshiaki Kashimura, Katsuhiro Ajito, Yunqi Liu, Daoben Zhu, and Keiichi Torimitsu pp 2804–2805 DOI: 10.1021/ja0433929 Supporting Info

Selective Detection of 2-Deoxyribonolactone in DNA Kousuke Sato and Marc M. Greenberg pp 2806–2807 DOI: 10.1021/ja0426185 Supporting Info

Deblurred Observation of the Molecular Structure of an Oil−Water Interface Henry S. Ashbaugh, Lawrence R. Pratt, Michael E. Paulaitis, Jason Clohecy, and Thomas L. Beck pp 2808–2809 DOI: 10.1021/ja042600u

PEGylated Polyplex Micelles from Triblock Catiomers with Spatially Ordered Layering of Condensed pDNA and Buffering Units for Enhanced Intracellular Gene Delivery Shigeto Fukushima, Kanjiro Miyata, Nobuhiro Nishiyama, Naoki Kanayama, Yuichi Yamasaki, and Kazunori Kataoka pp 2810–2811 DOI: 10.1021/ja0440506 Supporting Info

Structure and Magnetism of VnBzn+1 Sandwich Clusters Jinlan Wang, Paulo H. Acioli, and Julius Jellinek pp 2812–2813 DOI: 10.1021/ja043807q

Calcium Oxalate Monohydrate Precipitation at Membrane Lipid Rafts Isa O. Benítez and Daniel R. Talham pp 2814–2815 DOI: 10.1021/ja042937w Supporting Info

Patterns Formed by Droplet Evaporation from a Restricted Geometry Zhiqun Lin and Steve Granick pp 2816–2817 DOI: 10.1021/ja044792z

The Dichotomy of Dimetallocenes:  Coaxial versus Perpendicular Dimetal Units in Sandwich Compounds Yaoming Xie, Henry F. Schaefer III, and R. Bruce King* pp 2818–2819 DOI: 10.1021/ja042754+

Molecular Sensing with Ultrafine Silver Crystals on Hexagonal Aluminum Nitride Nanorod Templates Surojit Chattopadhyay, Shih Chen Shi, Zon Huang Lan, Chia Fu Chen, Kuei-Hsien Chen, and Li-Chyong Chen pp 2820–2821 DOI: 10.1021/ja042954l Supporting Info

Large-Scale Fabrication of Flexible Silver/Cross-Linked Poly(vinyl alcohol) Coaxial Nanocables by a Facile Solution Approach Lin-Bao Luo, Shu-Hong Yu, Hai-Sheng Qian, and Tao Zhou pp 2822–2823 DOI: 10.1021/ja0428154 Supporting Info

Allele-Specific Inhibitors of Protein Tyrosine Phosphatases Hillary E. Hoffman, Elizabeth R. Blair, James E. Johndrow, and Anthony C. Bishop pp 2824–2825 DOI: 10.1021/ja043378w Supporting Info

Lipid Mobility and Molecular Binding in Fluid Lipid Membranes Victoria Yamazaki, Oksana Sirenko, Robert J. Schafer, and Jay T. Groves pp 2826–2827 DOI: 10.1021/ja042430l Supporting Info

DNA-Templated Three-Branched Nanostructures for Nanoelectronic Devices Héctor A. Becerril, Randall M. Stoltenberg, Dean R. Wheeler, Robert C. Davis, John N. Harb, and Adam T. Woolley pp 2828–2829 DOI: 10.1021/ja043314l Supporting Info

Temperature Dependence of Carbon-13 Kinetic Isotope Effects of Importance to Global Climate Change Hai Lin, Yan Zhao, Benjamin A. Ellingson, Jingzhi Pu, and Donald G. Truhlar pp 2830–2831 DOI: 10.1021/ja0434026 Supporting Info

Alkane Oxidation by Osmium Tetroxide Brian C. Bales, Peter Brown, Ahmad Dehestani, and James M. Mayer pp 2832–2833 DOI: 10.1021/ja044273w

Imaging Chirality with Surface Second Harmonic Generation Microscopy Matthew A. Kriech and John C. Conboy pp 2834–2835 DOI: 10.1021/ja0430649 Supporting Info

Multicomponent Cycloadditions:  The Four-Component [5+1+2+1] Cycloaddition of Vinylcyclopropanes, Alkynes, and CO Paul A. Wender, Gabriel G. Gamber, Robert D. Hubbard, Son M. Pham, and Lei Zhang pp 2836–2837 DOI: 10.1021/ja042728b Supporting Info

All-Catalytic, Efficient, and Asymmetric Synthesis of α,ω-Diheterofunctional Reduced Polypropionates via “One-Pot” Zr-Catalyzed Asymmetric Carboalumination−Pd-Catalyzed Cross-Coupling Tandem Process Tibor Novak, Ze Tan, Bo Liang, and Ei-ichi Negishi pp 2838–2839 DOI: 10.1021/ja043534z Supporting Info

UV Raman Examination of α-Helical Peptide Water Hydrogen Bonding Konstantin V. Pimenov, Sergei V. Bykov, Aleksandr V. Mikhonin, and Sanford A. Asher pp 2840–2841 DOI: 10.1021/ja044708f

Highly Selective 1,3-Isomerization of Allylic Alcohols via Rhenium Oxo Catalysis Christie Morrill and Robert H. Grubbs pp 2842–2843 DOI: 10.1021/ja044054a Supporting Info

Total Synthesis of (+)-Allocyathin B2 Barry M. Trost, Li Dong, and Gretchen M. Schroeder pp 2844–2845 DOI: 10.1021/ja0435586 Supporting Info

Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation of Ketones through Allyl Enol Carbonates Barry M. Trost and Jiayi Xu pp 2846–2847 DOI: 10.1021/ja043472c Supporting Info

Development of an Electrolytic System Using Solid-Supported Bases for in Situ Generation of a Supporting Electrolyte from Methanol as a Solvent Toshiki Tajima and Toshio Fuchigami pp 2848–2849 DOI: 10.1021/ja0423062 Supporting Info

Alternating Isotactic Ethylene−Cyclopentene Copolymer:  A Crystalline Engineering Plastomer Including High Amounts of Structural Disorder Finizia Auriemma, Claudio De Rosa, Simona Esposito, Geoffrey W. Coates, and Masayuki Fujita pp 2850–2851 DOI: 10.1021/ja042357z Supporting Info

Room-Temperature Catalytic Hydrodefluorination of C(sp3)−F Bonds Valerie J. Scott, Remle Çelenligil-Çetin, and Oleg V. Ozerov pp 2852–2853 DOI: 10.1021/ja0426138 Supporting Info

Ti-Crossed-Claisen Condensation between Carboxylic Esters and Acid Chlorides or Acids:  A Highly Selective and General Method for the Preparation of Various β-Keto Esters Tomonori Misaki, Ryohei Nagase, Kunshi Matsumoto, and Yoo Tanabe pp 2854–2855 DOI: 10.1021/ja043833o Supporting Info

Syntheses of Metallabenzynes from an Allenylcarbene Complex Ting Bin Wen, Wai Yiu Hung, Herman H. Y. Sung, Ian D. Williams, and Guochen Jia pp 2856–2857 DOI: 10.1021/ja0429061 Supporting Info

Enantioselective Friedel−Crafts Alkylations with Benzoylhydrazones Promoted by a Simple Strained Silacycle Reagent Seiji Shirakawa, Richard Berger, and James L. Leighton pp 2858–2859 DOI: 10.1021/ja042522a Supporting Info

Mechanistic Investigations of Lipoic Acid Biosynthesis in Escherichia coli:  Both Sulfur Atoms in Lipoic Acid are Contributed by the Same Lipoyl Synthase Polypeptide Robert M. Cicchillo and Squire J. Booker pp 2860–2861 DOI: 10.1021/ja042428u

Single-Crystalline LaB6 Nanowires Han Zhang, Qi Zhang, Jie Tang, and Lu-Chang Qin pp 2862–2863 DOI: 10.1021/ja043512c

Observation of Excited-State Proton Transfer in Green Fluorescent Protein using Ultrafast Vibrational Spectroscopy Deborah Stoner-Ma, Andrew A. Jaye, Pavel Matousek, Michael Towrie, Stephen R. Meech, and Peter J. Tonge pp 2864–2865 DOI: 10.1021/ja042466d

Catalytic Asymmetric Synthesis of Chiral Allylic Esters Stefan F. Kirsch and Larry E. Overman pp 2866–2867 DOI: 10.1021/ja0425583 Supporting Info

Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium Jodie L. Brice, Jenna E. Harang, Vitaliy I. Timokhin, Natia R. Anastasi, and Shannon S. Stahl pp 2868–2869 DOI: 10.1021/ja0433020 Supporting Info

Biomimetic Synthesis and Structure Elucidation of Rubicordifolin, a Cytotoxic Natural Product from Rubia cordifolia Jean-Philip Lumb and Dirk Trauner pp 2870–2871 DOI: 10.1021/ja042375g Supporting Info

Rhodium-Catalyzed Isomerization of α-Arylpropargyl Alcohols to Indanones:  Involvement of an Unexpected Reaction Cascade Ryo Shintani, Kazuhiro Okamoto, and Tamio Hayashi pp 2872–2873 DOI: 10.1021/ja042582g Supporting Info

Benzene-Free Synthesis of Catechol:  Interfacing Microbial and Chemical Catalysis Wensheng Li, Dongming Xie, and J. W. Frost pp 2874–2882 DOI: 10.1021/ja045148n Supporting Info

Albumin-Conjugated Corrole Metal Complexes:  Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems Atif Mahammed and Zeev Gross pp 2883–2887 DOI: 10.1021/ja045372c

Isotope Effects, Dynamics, and the Mechanism of Solvolysis of Aryldiazonium Cations in Water Bryson R. Ussing and Daniel A. Singleton pp 2888–2899 DOI: 10.1021/ja043918p Supporting Info

A Deoxyribozyme that Forms a Three-Helix-Junction Complex with its RNA Substrates and has General RNA Branch-Forming Activity Rebecca L. Coppins and Scott K. Silverman pp 2900–2907 DOI: 10.1021/ja044881b Supporting Info

Investigating Cellular Signaling Reactions in Single Attoliter Vesicles Horst Pick, Evelyne L. Schmid, Ana-Paula Tairi, Erwin Ilegems, Ruud Hovius, and Horst Vogel pp 2908–2912 DOI: 10.1021/ja044605x

High Molecular Weight Supramolecular Polymers Containing Both Terpyridine Metal Complexes and Ureidopyrimidinone Quadruple Hydrogen-Bonding Units in the Main Chain Harald Hofmeier, Richard Hoogenboom, Marielle E. L. Wouters, and Ulrich S. Schubert pp 2913–2921 DOI: 10.1021/ja042919e

Molecular Recognition of Trigonal Oxyanions Using a Ditopic Salt Receptor:  Evidence for Anisotropic Shielding Surface around Nitrate Anion Joseph M. Mahoney, Kenneth A. Stucker, Hua Jiang, Ian Carmichael, Nicole R. Brinkmann, Alicia M. Beatty, Bruce C. Noll, and Bradley D. Smith pp 2922–2928 DOI: 10.1021/ja0440295 Supporting Info

A Photoinducible β-Hairpin Andreas Aemissegger, Vincent Kräutler, Wilfred F. van Gunsteren, and Donald Hilvert pp 2929–2936 DOI: 10.1021/ja0442567 Supporting Info

Reinforced HNA Backbone Hydration in the Crystal Structure of a Decameric HNA/RNA Hybrid Timm Maier, Ingo Przylas, Norbert Strater, Piet Herdewijn, and Wolfram Saenger pp 2937–2943 DOI: 10.1021/ja045843v Supporting Info

Design and Synthesis of an Expanded Porphyrin That Has Selectivity for the c-MYC G-Quadruplex Structure Jeyaprakashnarayanan Seenisamy, Sridevi Bashyam, Vijay Gokhale, Hariprasad Vankayalapati, Daekyu Sun, Adam Siddiqui-Jain, Nicole Streiner, Kazuo Shin-ya, Elizabeth White, W. David Wilson, and Laurence H. Hurley pp 2944–2959 DOI: 10.1021/ja0444482 Supporting Info

Enantioselective Esterification of Prochiral Phosphonate Pendants of a Polyphenylacetylene Assisted by Macromolecular Helicity:  Storage of a Dynamic Macromolecular Helicity Memory Hisanari Onouchi, Toyoharu Miyagawa, Akira Furuko, Katsuhiro Maeda, and Eiji Yashima pp 2960–2965 DOI: 10.1021/ja042806v Supporting Info

Design and Synthesis of N-Maleimido-Functionalized Hydrophilic Polymers via Copper-Mediated Living Radical Polymerization:  A Suitable Alternative to PEGylation Chemistry Giuseppe Mantovani, François Lecolley, Lei Tao, David M. Haddleton, Joost Clerx, Jeroen J. L. M. Cornelissen, and Kelly Velonia pp 2966–2973 DOI: 10.1021/ja0430999 Supporting Info

Single Turn Peptide Alpha Helices with Exceptional Stability in Water Nicholas E. Shepherd, Huy N. Hoang, Giovanni Abbenante, and David P. Fairlie pp 2974–2983 DOI: 10.1021/ja0456003 Supporting Info

Chiral Supramolecular Polymers Formed by Host−Guest Interactions Masahiko Miyauchi, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 2984–2989 DOI: 10.1021/ja043289j Supporting Info

Molecular Containers Based on Amphiphilic PS-b-PMVE Dendrigraft Copolymers:  Topology, Organization, and Aqueous Solution Properties Michel Schappacher, Jean Luc Putaux, Christelle Lefebvre, and Alain Deffieux pp 2990–2998 DOI: 10.1021/ja0440203

Molecular Recognition in a Thermoplastic Elastomer Rolf A. Koevoets, Ron M. Versteegen, Huub Kooijman, Anthony L. Spek, Rint P. Sijbesma, and E. W. Meijer pp 2999–3003 DOI: 10.1021/ja0451160 Supporting Info

Hydroxyl Stereochemistry and Amine Number within Poly(glycoamidoamine)s Affect Intracellular DNA Delivery Yemin Liu and Theresa M. Reineke pp 3004–3015 DOI: 10.1021/ja0436446

β-Sheet Ligands in Action:  KLVFF Recognition by Aminopyrazole Hybrid Receptors in Water Petra Rzepecki and Thomas Schrader pp 3016–3025 DOI: 10.1021/ja045558b Supporting Info

Photoswitching of Single Association Force between a Pair of Photoionizable Spirobenzopyrans Shinpei Kado, Kaname Yamada, Tomoo Murakami, and Keiichi Kimura pp 3026–3030 DOI: 10.1021/ja0443474

Bimetallic Anilido-Aldimine Zinc Complexes for Epoxide/CO2 Copolymerization Bun Yeoul Lee, Heon Yong Kwon, Su Yeon Lee, Sung Jae Na, Song-i Han, Hoseop Yun, Hyosun Lee, and Young-Whan Park pp 3031–3037 DOI: 10.1021/ja0435135 Supporting Info

High-Pressure Dissociation of Crystalline para-Diiodobenzene:  Optical Experiments and Car−Parrinello Calculations Aldo Brillante, Raffaele G. Della Valle, Luca Farina, Elisabetta Venuti, Carlo Cavazzoni, Andrew P. J. Emerson, and Karl Syassen pp 3038–3043 DOI: 10.1021/ja0432416

Transmutation of Fullerenes R. James Cross and Martin Saunders pp 3044–3047 DOI: 10.1021/ja045521r

Surface-Catalyzed Growth of Polymethylene-Rich Copolymer Films on Gold Dongshun Bai and G. Kane Jennings pp 3048–3056 DOI: 10.1021/ja043609z

Solid-State NMR Study of MCM-41-type Mesoporous Silica Nanoparticles Julien Trébosc, Jerzy W. Wiench, Seong Huh, Victor S.-Y. Lin, and Marek Pruski pp 3057–3068 DOI: 10.1021/ja043567e Supporting Info

Pentacene Disproportionation during Sublimation for Field-Effect Transistors Luke B. Roberson, Janusz Kowalik, Laren M. Tolbert, Christian Kloc, Roswitha Zeis, Xiaoliu Chi, Richard Fleming, and Charles Wilkins pp 3069–3075 DOI: 10.1021/ja044586r Supporting Info

Formation and Characterization of the Hexanuclear Platinum Cluster [Pt6(μ-PBut2)4(CO)6](CF3SO3)2 through Structural, Electrochemical, and Computational Analyses Fabrizia Fabrizi de Biani, Andrea Ienco, Franco Laschi, Piero Leoni, Fabio Marchetti, Lorella Marchetti, Carlo Mealli, and Piero Zanello pp 3076–3089 DOI: 10.1021/ja043626o Supporting Info

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground State Marilena Ferbinteanu, Hitoshi Miyasaka, Wolfgang Wernsdorfer, Kazuya Nakata, Ken-ichi Sugiura, Masahiro Yamashita, Claude Coulon, and Rodolphe Clérac pp 3090–3099 DOI: 10.1021/ja0468123 Supporting Info

Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride:  Study of Hydrogen Activation in a Ligand−Metal Bifunctional Hydrogenation Catalyst Charles P. Casey, Jeffrey B. Johnson, Steven W. Singer, and Qiang Cui pp 3100–3109 DOI: 10.1021/ja043460r Supporting Info

Inducing Spin Crossover in Metallo-supramolecular Polyelectrolytes through an Amphiphilic Phase Transition Yves Bodenthin, Ullrich Pietsch, Helmuth Möhwald, and Dirk G. Kurth pp 3110–3114 DOI: 10.1021/ja0447210

Nanometal Surface Energy Transfer in Optical Rulers, Breaking the FRET Barrier C. S. Yun, A. Javier, T. Jennings, M. Fisher, S. Hira, S. Peterson, B. Hopkins, N. O. Reich, and G. F. Strouse pp 3115–3119 DOI: 10.1021/ja043940i Supporting Info

Self-Assembly of Diorganotin(IV) Oxides (R = Me, nBu, Ph) and 2,5-Pyridinedicarboxylic Acid to Polymeric and Trinuclear Macrocyclic Hybrids with Porous Solid-State Structures:  Influence of Substituents and Solvent on the Supramolecular Structure Reyes García-Zarracino and Herbert Höpfl pp 3120–3130 DOI: 10.1021/ja0437095 Supporting Info

Cycloaddition of Benzene on Si(100) and Its Surface Conversions Yousung Jung and Mark S. Gordon pp 3131–3139 DOI: 10.1021/ja0402093 Supporting Info

Chemical Behavior of the Biradicaloid (HO···ONO) Singlet States of Peroxynitrous Acid. The Oxidation of Hydrocarbons, Sulfides, and Selenides Robert D. Bach, Olga Dmitrenko, and Carlos M. Estévez pp 3140–3155 DOI: 10.1021/ja044245d Supporting Info

Selective Calcium Ion Sensing with a Bichromophoric Squaraine Foldamer Easwaran Arunkumar, Ayyappanpillai Ajayaghosh, and Jörg Daub pp 3156–3164 DOI: 10.1021/ja045760e Supporting Info

Nonequilibrium Capillary Electrophoresis of Equilibrium Mixtures: A Universal Tool for Development of Aptamers Maxim Berezovski, Andrei Drabovich, Svetlana M. Krylova, Michael Musheev, Victor Okhonin, Alexander Petrov, and Sergey N. Krylov pp 3165–3171 DOI: 10.1021/ja042394q Supporting Info

High-Performance Hole-Transport Layers for Polymer Light-Emitting Diodes. Implementation of Organosiloxane Cross-Linking Chemistry in Polymeric Electroluminescent Devices He Yan, Paul Lee, Neal R. Armstrong, Amy Graham, Guennadi A. Evmenenko, Pulak Dutta, and Tobin J. Marks pp 3172–3183 DOI: 10.1021/ja044455q

The Nature of the Supramolecular Association of 1,2,5-Chalcogenadiazoles Anthony F. Cozzolino, Ignacio Vargas-Baca, Sarah Mansour, and Amir H. Mahmoudkhani pp 3184–3190 DOI: 10.1021/ja044005y Supporting Info

Origin of Tight Binding of a Near-Perfect Transition-State Analogue by Cytidine Deaminase:  Implications for Enzyme Catalysis Haobo Guo, Niny Rao, Qin Xu, and Hong Guo pp 3191–3197 DOI: 10.1021/ja0439625

Dimensional Effects on the LO−TO Splitting in CF4:  First-Principles and Infrared Absorption Studies Wai-Leung Yim, Oleg Byl, John T. Yates, Jr., and J. Karl Johnson pp 3198–3206 DOI: 10.1021/ja043540v

π-Stacking in Thiophene Oligomers as the Driving Force for Electroactive Materials and Devices Damian A. Scherlis and Nicola Marzari pp 3207–3212 DOI: 10.1021/ja043557d

Selective Chemical Shift Assignment of B800 and B850 Bacteriochlorophylls in Uniformly [13C,15N]-Labeled Light-Harvesting Complexes by Solid-State NMR Spectroscopy at Ultra-High Magnetic Field Adriaan J. van Gammeren, Francesco Buda, Frans B. Hulsbergen, Suzanne Kiihne, Johan G. Hollander, Tatjana A. Egorova-Zachernyuk, Niall J. Fraser, Richard J. Cogdell, and Huub J. M. de Groot pp 3213–3219 DOI: 10.1021/ja044215a

A New Spin Probe of Protein Dynamics:  Nitrogen Relaxation in 15N−2H Amide Groups Jun Xu, Oscar Millet, Lewis E. Kay, and Nikolai R. Skrynnikov pp 3220–3229 DOI: 10.1021/ja040215z Supporting Info

Biliverdin Reduction by Cyanobacterial Phycocyanobilin:Ferredoxin Oxidoreductase (PcyA) Proceeds via Linear Tetrapyrrole Radical Intermediates [J. Am. Chem. Soc. 2004, 126, 8682−8693]. Shih-Long Tu, Alexander Gunn, Michael D. Toney, R. David Britt, and J. Clark Lagarias pp 3230–3231 DOI: 10.1021/ja059902w

ACD/HNMR Predictor and ACD/CNMR Predictor Advanced Chemistry Development, Inc. (ACD/Labs), 90 Adelaide Street West, Suite 600, Toronto, ON M5H 2V9, Canada. www.acdlabs.com. See Web site for pricing information. Brian Pagenkopf p 3232 DOI: 10.1021/ja040946z

Reviews in Computational Chemistry, Volume 20 Edited by Kenny B. Lipkowitz (North Dakota State University), Raima Larter (Indiana University-Purdue University), Thomas R. Cundari (University of North Texas), and Donald B. Boyd, Editor Emeritus (Indiana University−Purdue University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xxvi + 458 pp. $150.00. ISBN 0-471-44525-8. James W. Gauld p 3233 DOI: 10.1021/ja040980d

Progress in Colloid and Polymer Science, Volume 125:  From Colloids to Nanotechnology Edited by Miklós Zrínyi and Zoltán Hórvölgyi (Budapest University of Technology and Economics). Springer-Verlag:  Berlin, Heidelberg. 2004. viii + 226 pp. $189.00 ISBN 3-540-40658-1. p 3233 DOI: 10.1021/ja0410082

Well Architectured Fluoropolymers:  Synthesis, Properties and Applications By Bruno Améduri and Bernard Boutevin (Ecole Nationale Supérieure de Chemie de Montpellier). Elsevier Ltd:  Oxford. 2004. xviii + 481 pp. $189.00. ISBN 0-08-044388-5. Patrick E. Cassidy pp 3233–3234 DOI: 10.1021/ja040989f

Name Reactions in Heterocyclic Chemistry Edited by Jie-Jack Li (Pfizer Global Research and Development). Scientific Editor:  E. J. Corey (Harvard University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xx + 558 pp. $125.00. ISBN 0-471-30215-5. p 3234 DOI: 10.1021/ja041001k

DNA-Based Molecular Electronics. International Symposium on DNA-Based Molecular Electronics, Jena, Germany, May 13−15, 2004. AIP Conference Proceeding, Volume 725 Edited by Wolfgang Fritzsche (IPHT, Jena, Germany). American Institute of Physics:  Melville, NY. 2004. x + 116 pp. $98.00. ISBN 0-7354-0206-X. p 3234 DOI: 10.1021/ja041004x

Issue 10

Hydrogen Transfer Reaction on the Surface of an Oxide Catalyst Marcus Knapp, Daniela Crihan, Ari P. Seitsonen, and Herbert Over pp 3236–3237 DOI: 10.1021/ja043355h

Remarkable Supramolecular Catalysis of Glycoside Hydrolysis by a Cyclodextrin Cyanohydrin Fernando Ortega-Caballero, Cyril Rousseau, Brian Christensen, Torben Ellebæk Petersen, and Mikael Bols pp 3238–3239 DOI: 10.1021/ja042678a Supporting Info

Enantioselective Organocatalytic Cyclopropanations. The Identification of a New Class of Iminium Catalyst Based upon Directed Electrostatic Activation Roxanne K. Kunz and David W. C. MacMillan pp 3240–3241 DOI: 10.1021/ja042774b Supporting Info

A Simple Organic Reaction Mediates the Crystallization of the Inorganic Nanocluster [Ga13(μ3-OH)6(μ2-OH)18(H2O)24](NO3)15 Elisabeth Rather, Jason T. Gatlin, Paul G. Nixon, Takuji Tsukamoto, Victor Kravtsov, and Darren W. Johnson pp 3242–3243 DOI: 10.1021/ja043520t Supporting Info

Ligand-Catalyzed Asymmetric Alkynylboration of Enones:  A New Paradigm for Asymmetric Synthesis Using Organoboranes T. Robert Wu and J. Michael Chong pp 3244–3245 DOI: 10.1021/ja043001q Supporting Info

Nonclassical Crystallization:  Mesocrystals and Morphology Change of CaCO3 Crystals in the Presence of a Polyelectrolyte Additive Tongxin Wang, Helmut Cölfen, and Markus Antonietti pp 3246–3247 DOI: 10.1021/ja045331g Supporting Info

Rh(I)-Catalyzed Cyclization of 1-Arylprop-2-yn-1-ol Derivatives Utilizing Rhodium 1,4-Migration Hokuto Yamabe, Akio Mizuno, Hiroyuki Kusama, and Nobuharu Iwasawa pp 3248–3249 DOI: 10.1021/ja042581o Supporting Info

Differential Inhibition of Staphylococcus aureus PBP2 by Glycopeptide Antibiotics Catherine Leimkuhler, Lan Chen, Dianah Barrett, Gianbattista Panzone, Binyuan Sun, Brian Falcone, Markus Oberthür, Stefano Donadio, Suzanne Walker, and Daniel Kahne pp 3250–3251 DOI: 10.1021/ja043849e Supporting Info

Synthesis of β,β-Disubstituted Vinyl Boronates via the Ruthenium-Catalyzed Alder Ene Reaction of Borylated Alkynes and Alkenes Eric C. Hansen and Daesung Lee pp 3252–3253 DOI: 10.1021/ja0424629 Supporting Info

In Situ XAFS and NMR Study of Rhodium-Catalyzed Dehydrogenation of Dimethylamine Borane Yongsheng Chen, John L. Fulton, John C. Linehan, and Tom Autrey pp 3254–3255 DOI: 10.1021/ja0437050 Supporting Info

Synthesis of the Potent Immunostimulatory Adjuvant QS-21A Pengfei Wang, Yong-Jae Kim, Mauricio Navarro-Villalobos, Bridget D. Rohde, and David Y. Gin pp 3256–3257 DOI: 10.1021/ja0422007 Supporting Info

Nitrogen Atom Transfer between Manganese Complexes of Salen, Porphyrin, and Corrole and Characterization of a (Nitrido)manganese(VI) Corrole Galina Golubkov and Zeev Gross pp 3258–3259 DOI: 10.1021/ja043683h

Single-Crystalline and Monodisperse LaF3 Triangular Nanoplates from a Single-Source Precursor Ya-Wen Zhang, Xiao Sun, Rui Si, Li-Ping You, and Chun-Hua Yan pp 3260–3261 DOI: 10.1021/ja042801y Supporting Info

Crystal Structure of BRL 42715, C6-(N1-Methyl-1,2,3-triazolylmethylene)penem, in Complex with Enterobacter cloacae 908R β-Lactamase:  Evidence for a Stereoselective Mechanism from Docking Studies Catherine Michaux, Paulette Charlier, Jean-Marie Frère, and Johan Wouters pp 3262–3263 DOI: 10.1021/ja0426241 Supporting Info

Ordering of Vacancies in Type-I Tin Clathrate:  Superstructure of Rb8Sn44□2 Franck Dubois and Thomas F. Fässler pp 3264–3265 DOI: 10.1021/ja043500r Supporting Info

Facile Synthesis of Silver Nanoparticles Useful for Fabrication of High-Conductivity Elements for Printed Electronics Yuning Li, Yiliang Wu, and Beng S. Ong pp 3266–3267 DOI: 10.1021/ja043425k Supporting Info

Fabrication of Colloidal Crystals with Tubular-like Packings Feng Li, Xavier Badel, Jan Linnros, and John B. Wiley pp 3268–3269 DOI: 10.1021/ja042928n Supporting Info

Inhibition Assay of Biomolecules based on Fluorescence Resonance Energy Transfer (FRET) between Quantum Dots and Gold Nanoparticles Eunkeu Oh, Mi-Young Hong, Dohoon Lee, Sung-Hun Nam, Hyun C. Yoon, and Hak-Sung Kim pp 3270–3271 DOI: 10.1021/ja0433323 Supporting Info

Atomic XAFS as a Tool to Probe the Electronic Properties of Supported Noble Metal Nanoclusters Ad M. J. van der Eerden, Tom Visser, T. Alexander Nijhuis, Yasuo Ikeda, Muriel Lepage, Diek C. Koningsberger, and Bert M. Weckhuysen pp 3272–3273 DOI: 10.1021/ja043107l Supporting Info

Enantioselective Synthesis of Near Enantiopure Compound by Asymmetric Autocatalysis Triggered by Asymmetric Photolysis with Circularly Polarized Light Tsuneomi Kawasaki, Mirai Sato, Saori Ishiguro, Takahiro Saito, Yosuke Morishita, Itaru Sato, Hideo Nishino, Yoshihisa Inoue, and Kenso Soai pp 3274–3275 DOI: 10.1021/ja0422108 Supporting Info

Enzymatic Clipping of DNA Wires Coated with Magnetic Nanoparticles Joseph M. Kinsella and Albena Ivanisevic pp 3276–3277 DOI: 10.1021/ja043865b Supporting Info

A Facile Synthesis and Properties of Multicarbazole Molecules Containing Multiple Vinylene Bridges Jia-Xiang Yang, Xu-Tang Tao, Chun Xue Yuan, Yun Xing Yan, Lei Wang, Zhi Liu, Yan Ren, and Min Hua Jiang pp 3278–3279 DOI: 10.1021/ja043510s Supporting Info

Label-Free Electronic Detection of DNA-Hybridization on Nanogapped Gold Particle Film Hiroshi Shiigi, Shiho Tokonami, Hidetaka Yakabe, and Tsutomu Nagaoka pp 3280–3281 DOI: 10.1021/ja0445793

[2]Borametallocenophanes of Zr and Hf:  Synthesis, Structure, and Polymerization Activity Holger Braunschweig, Manuela Gross, Mario Kraft, Marc O. Kristen, and Dirk Leusser pp 3282–3283 DOI: 10.1021/ja042408s Supporting Info

Molecular Salts with Diquat-Based Electron Acceptors for Nonlinear Optics Benjamin J. Coe, James A. Harris, Bruce S. Brunschwig, Javier Garín, and Jesús Orduna pp 3284–3285 DOI: 10.1021/ja0431758 Supporting Info

Spectroscopic Evidence for the Supply of Reactive Oxygen during CO Oxidation Catalyzed by Gold Supported on Nanocrystalline CeO2 Javier Guzman, Silvio Carrettin, and Avelino Corma pp 3286–3287 DOI: 10.1021/ja043752s Supporting Info

Squaraine-Derived Rotaxanes:  Sterically Protected Fluorescent Near-IR Dyes Easwaran Arunkumar, Christopher C. Forbes, Bruce C. Noll, and Bradley D. Smith pp 3288–3289 DOI: 10.1021/ja042404n Supporting Info

Imidazo[1,5-a]pyridine:  A Versatile Architecture for Stable N-Heterocyclic Carbenes Manuel Alcarazo, Stephen J. Roseblade, Andrew R. Cowley, Rosario Fernández, John M. Brown, and José M. Lassaletta pp 3290–3291 DOI: 10.1021/ja0423769 Supporting Info

Evidence for Radical Fragmentations from Persistent Singlet Carbenes Xavier Cattoën, Karinne Miqueu, Heinz Gornitzka, Didier Bourissou, and Guy Bertrand pp 3292–3293 DOI: 10.1021/ja050028g Supporting Info

The Normal Range for Secondary Swain−Schaad Exponents without Tunneling or Kinetic Complexity Jennifer Hirschi and Daniel A. Singleton pp 3294–3295 DOI: 10.1021/ja0430752 Supporting Info

A New Synthetic Method for α-Alkoxycarbonyl Iminium Salt and Its Reaction with Nucleophiles Makoto Shimizu, Hiroyuki Itou, and Megumi Miura pp 3296–3297 DOI: 10.1021/ja042330f Supporting Info

The Role of Pd Nanoparticles in Ionic Liquid in the Heck Reaction Claudia C. Cassol, Alexandre P. Umpierre, Giovanna Machado, Silvana I. Wolke, and Jairton Dupont pp 3298–3299 DOI: 10.1021/ja0430043 Supporting Info

Synthesis and Fate of o-Carboxybenzophenones in the Biosynthesis of Aflatoxin Kevin M. Henry and Craig A. Townsend pp 3300–3309 DOI: 10.1021/ja045520z Supporting Info

Heme/Non-Heme Diiron(II) Complexes and O2, CO, and NO Adducts as Reduced and Substrate-Bound Models for the Active Site of Bacterial Nitric Oxide Reductase Ian M. Wasser, Hong-wei Huang, Pierre Moënne-Loccoz, and Kenneth D. Karlin pp 3310–3320 DOI: 10.1021/ja0458773 Supporting Info

Analogues of Vaccinia Virus DNA Topoisomerase I Modified at the Active Site Tyrosine Rong Gao, Yi Zhang, Ambar K. Choudhury, Larisa M. Dedkova, and Sidney M. Hecht pp 3321–3331 DOI: 10.1021/ja044182z

A New Four-Base Genetic Helix, yDNA, Composed of Widened Benzopyrimidine−Purine Pairs Alex H. F. Lee and Eric T. Kool pp 3332–3338 DOI: 10.1021/ja0430604 Supporting Info

Effect of PNA Backbone Modifications on Cyanine Dye Binding to PNA−DNA Duplexes Investigated by Optical Spectroscopy and Molecular Dynamics Simulations Isil Dilek, Marcela Madrid, Rojendra Singh, Christian P. Urrea, and Bruce A. Armitage pp 3339–3345 DOI: 10.1021/ja045145a Supporting Info

Effect of Proline and Glycine Residues on Dynamics and Barriers of Loop Formation in Polypeptide Chains Florian Krieger, Andreas Möglich, and Thomas Kiefhaber pp 3346–3352 DOI: 10.1021/ja042798i

Electrochemical and Guest Binding Properties of Fréchet- and Newkome-Type Dendrimers with a Single Viologen Unit Located at Their Apical Positions Winston Ong, Jodi Grindstaff, David Sobransingh, Rosa Toba, José María Quintela, Carlos Peinador, and Angel E. Kaifer pp 3353–3361 DOI: 10.1021/ja049530b Supporting Info

A Luminescent Receptor with Affinity for N-Terminal Histidine in Peptides in Aqueous Solution Michael Kruppa, Christian Mandl, Stefan Miltschitzky, and Burkhard König pp 3362–3365 DOI: 10.1021/ja043930h Supporting Info

Mineralization of Synthetic Polymer Scaffolds:  A Bottom-Up Approach for the Development of Artificial Bone Jie Song, Viengkham Malathong, and Carolyn R. Bertozzi pp 3366–3372 DOI: 10.1021/ja043776z Supporting Info

A Molecular Flytrap for the Selective Binding of Citrate and Other Tricarboxylates in Water Carsten Schmuck and Michael Schwegmann pp 3373–3379 DOI: 10.1021/ja0433469

Total Synthesis and Properties of the Crambescidin Core Zwitterionic Acid and Crambescidin 359 Zachary D. Aron and Larry E. Overman pp 3380–3390 DOI: 10.1021/ja042875+ Supporting Info

Intramolecular Electron Transfer in Bis(methylene) Adamantyl Radical Cation:  A Case Study of Diabatic Trapping Lluís Blancafort, Patricia Hunt, and Michael A. Robb pp 3391–3399 DOI: 10.1021/ja043879h Supporting Info

Synthesis and Application of Poly(phenylene Ethynylene)s for Bioconjugation:  A Conjugated Polymer-Based Fluorogenic Probe for Proteases Jordan H. Wosnick, Charlene M. Mello, and Timothy M. Swager pp 3400–3405 DOI: 10.1021/ja043134b Supporting Info

Ruthenium-Catalyzed Aromatization of Enediynes via Highly Regioselective Nucleophilic Additions on a π-Alkyne Functionality. A Useful Method for the Synthesis of Functionalized Benzene Derivatives Arjan Odedra, Chang-Jung Wu, Taduri Bhanu Pratap, Chun-Wei Huang, Ying-Fen Ran, and Rai-Shung Liu pp 3406–3412 DOI: 10.1021/ja043047j Supporting Info

Catalytic Asymmetric Cyano-Ethoxycarbonylation Reaction of Aldehydes using a YLi3Tris(binaphthoxide) (YLB) Complex:  Mechanism and Roles of Achiral Additives Noriyuki Yamagiwa, Jun Tian, Shigeki Matsunaga, and Masakatsu Shibasaki pp 3413–3422 DOI: 10.1021/ja042887v Supporting Info

Ligand-Assisted Reduction of Osmium Tetroxide with Molecular Hydrogen via a [3+2] Mechanism Ahmad Dehestani, Wai Han Lam, David A. Hrovat, Ernest R. Davidson, Weston Thatcher Borden, and James M. Mayer pp 3423–3432 DOI: 10.1021/ja043777r Supporting Info

A Metastable Prerequisite for the Growth of Lumazine Synthase Crystals Olga Gliko, Nikolaus Neumaier, Weichun Pan, Ilka Haase, Markus Fischer, Adelbert Bacher, Sevil Weinkauf, and Peter G. Vekilov pp 3433–3438 DOI: 10.1021/ja043218k

Comparison of Analytical Techniques for Purity Evaluation of Single-Walled Carbon Nanotubes Mikhail E. Itkis, Daniel E. Perea, Richard Jung, Sandip Niyogi, and Robert C. Haddon pp 3439–3448 DOI: 10.1021/ja043061w

Mononuclear Aluminum Hydroxide for the Design of Well-Defined Homogeneous Catalysts Guangcai Bai, Sanjay Singh, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 3449–3455 DOI: 10.1021/ja043585w Supporting Info

Charge Separation versus Recombination in Dye-Sensitized Nanocrystalline Solar Cells:  the Minimization of Kinetic Redundancy Saif A. Haque, Emilio Palomares, Byung M. Cho, Alex N. M. Green, Narukuni Hirata, David R. Klug, and James R. Durrant pp 3456–3462 DOI: 10.1021/ja0460357

Aqueous Dispersions of Single-wall and Multiwall Carbon Nanotubes with Designed Amphiphilic Polycations Vladimir A. Sinani, Muhammed K. Gheith, Alexander A. Yaroslavov, Anna A. Rakhnyanskaya, Kai Sun, Arif A. Mamedov, James P. Wicksted, and Nicholas A. Kotov pp 3463–3472 DOI: 10.1021/ja045670+ Supporting Info

Synthesis of Macrocycles via Cobalt-Mediated [2 + 2 + 2] Cycloadditions Llorente V. R. Boñaga, Han-Cheng Zhang, Alessandro F. Moretto, Hong Ye, Diane A. Gauthier, Jian Li, Gregory C. Leo, and Bruce E. Maryanoff pp 3473–3485 DOI: 10.1021/ja045001w Supporting Info

Two-Dimensional Pressure-Driven Nanorod-to-Nanowire Reactions in Langmuir Monolayers at Room Temperature Somobrata Acharya and Shlomo Efrima pp 3486–3490 DOI: 10.1021/ja044934p Supporting Info

Crystal Structure and Diffusion Path in the Fast Lithium-Ion Conductor La0.62Li0.16TiO3 Masatomo Yashima, Mitsuru Itoh, Yoshiyuki Inaguma, and Yukio Morii pp 3491–3495 DOI: 10.1021/ja0449224

Stable Transition Metal Complexes of an All-Metal Antiaromatic Molecule (Al4Li4):  Role of Complexations Ayan Datta and Swapan K. Pati pp 3496–3500 DOI: 10.1021/ja044344r Supporting Info

Lanthanide Clusters with Internal Ln Ions:  Highly Emissive Molecules with Solid-State Cores Anna Kornienko, Thomas J. Emge, G. Ajith Kumar, Richard E. Riman, and John G. Brennan pp 3501–3505 DOI: 10.1021/ja043655z Supporting Info

Metallurgy in a Beaker:  Nanoparticle Toolkit for the Rapid Low-Temperature Solution Synthesis of Functional Multimetallic Solid-State Materials Raymond E. Schaak, Amandeep K. Sra, Brian M. Leonard, Robert E. Cable, John C. Bauer, Yi-Fan Han, Joel Means, Winfried Teizer, Yolanda Vasquez, and Edward S. Funck pp 3506–3515 DOI: 10.1021/ja043335f Supporting Info

Interaction of a Bulky N-Heterocyclic Carbene Ligand with Rh(I) and Ir(I). Double C−H Activation and Isolation of Bare 14-Electron Rh(III) and Ir(III) Complexes Natalie M. Scott, Reto Dorta, Edwin D. Stevens, Andrea Correa, Luigi Cavallo, and Steven P. Nolan pp 3516–3526 DOI: 10.1021/ja043249f Supporting Info

A Tryptophan-Containing Open-Chain Framework for Tuning a High Selectivity for Ca2+ and 13C NMR Observation of a Ca2+−Indole Interaction in Aqueous Solution Yitong Li and Chi Ming Yang pp 3527–3530 DOI: 10.1021/ja046517i Supporting Info

Spectroscopic and Density Functional Studies of the Red Copper Site in Nitrosocyanin:  Role of the Protein in Determining Active Site Geometric and Electronic Structure Lipika Basumallick, Ritimukta Sarangi, Serena DeBeer George, Brad Elmore, Alan B. Hooper, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 3531–3544 DOI: 10.1021/ja044412+ Supporting Info

O-Atom Transport Catalysis by Atomic Cations in the Gas Phase:  Reduction of N2O by CO Voislav Blagojevic, Galina Orlova, and Diethard K. Bohme pp 3545–3555 DOI: 10.1021/ja044950m Supporting Info

On the Mechanism of Hydrophobic Association of Nanoscopic Solutes Niharendu Choudhury and B. Montgomery Pettitt pp 3556–3567 DOI: 10.1021/ja0441817

Asymmetric Induction during Yang Cyclization of α-Oxoamides:  The Power of a Covalently Linked Chiral Auxiliary Is Enhanced in the Crystalline State Arunkumar Natarajan, Joel T. Mague, and V. Ramamurthy pp 3568–3576 DOI: 10.1021/ja043999p Supporting Info

Macrophomate Synthase:  QM/MM Simulations Address the Diels−Alder versus Michael−Aldol Reaction Mechanism Cristiano Ruch Werneck Guimarães, Marina Udier-Blagović, and William L. Jorgensen pp 3577–3588 DOI: 10.1021/ja043905b

Limited Flexibility of Lactose Detected from Residual Dipolar Couplings Using Molecular Dynamics Simulations and Steric Alignment Methods Manuel Martín-Pastor, Angeles Canales, Francisco Corzana, Juan L. Asensio, and Jesús Jiménez-Barbero pp 3589–3595 DOI: 10.1021/ja043445m Supporting Info

Electrochemical Deposition of Mesoporous Nickel Hydroxide Films from Dilute Surfactant Solutions Yiwei Tan, Shalini Srinivasan, and Kyoung-Shin Choi pp 3596–3604 DOI: 10.1021/ja0434329 Supporting Info

2,6-Diarylnaphtho[1,8-bc:5,4-b‘c‘]dithiophenes as New High-Performance Semiconductors for Organic Field-Effect Transistors Kazuo Takimiya, Yoshihito Kunugi, Yuta Toyoshima, and Tetsuo Otsubo pp 3605–3612 DOI: 10.1021/ja043429p Supporting Info

Local and Global Effects of Metal Binding within the Small Subunit of Ribonucleotide Reductase Brad S. Pierce and Michael P. Hendrich pp 3613–3623 DOI: 10.1021/ja0491937

Computational Rationalization of the Dependence of the Enantioselectivity on the Nature of the Catalyst in the Vanadium-Catalyzed Oxidation of Sulfides by Hydrogen Peroxide David Balcells, Feliu Maseras, and Gregori Ujaque pp 3624–3634 DOI: 10.1021/ja0435384 Supporting Info

Enhanced Fluorescence Cyanide Detection at Physiologically Lethal Levels:  Reduced ICT-Based Signal Transduction Ramachandram Badugu, Joseph R. Lakowicz, and Chris D. Geddes pp 3635–3641 DOI: 10.1021/ja044421i

Electronic and Molecular Structure of High-Spin d4 Complexes:  Experimental and Theoretical Study of the [Cr(D2O)6]2+ Cation in Tutton's Salts [J. Am. Chem. Soc. 2004, 126, 16639−16652]. Christopher Dobe, Christopher Noble, Graham Carver, Philip L. W. Tregenna-Piggott, Garry J. McIntyre, Anne-Laure Barra, Antonia Neels, Stefan Janssen, and Fanni Juranyi p 3642 DOI: 10.1021/ja0504688

Catalytic Cyclization of o-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction [J. Am. Chem. Soc. 2004, 126, 15423−15430]. Itaru Nakamura, Gan B. Bajracharya, Huanyou Wu, Kengo Oishi, Yuya Mizushima, Ilya D. Gridnev, and Yoshinori Yamamoto p 3642 DOI: 10.1021/ja050594b

Carbonic Anhydrase:  Its Inhibitors and Activators. CRC Enzyme Inhibitors Series, Volume 1 Edited by Claudiu T. Supuran, Andrea Scozzafava (Universita degli Studi, Firenze), and Janet Conway (Pfizer Inc., New York). CRC Press LLC:  Boca Raton, FL. 2004. xii + 364 pp. $139.95. ISBN 0-415-30673-6. Robert McKenna p 3643 DOI: 10.1021/ja040999g

Supramolecular Assembly via Hydrogen Bonds II. Structure and Bonding, 111 Edited by D. M. P. Mingos (St. Edmund Hall, Oxford, UK). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xii + 180 pp. $149. ISBN 3-540-20086-X. Bing Gong pp 3643–3644 DOI: 10.1021/ja040942u

Applications of Evolutionary Computation in Chemistry. Structure and Bonding, 110 Edited by Roy L. Johnston (University of Birmingham). Series edited by D. M. Mingos (St. Edmund Hall, Oxford, UK). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 184 pp. $169.00. ISBN 3-540-40258-6. John Spencer Evans p 3644 DOI: 10.1021/ja040950a

Issue 11

New Phosphite−Oxazoline Ligands for Efficient Pd-Catalyzed Substitution Reactions Oscar Pàmies, Montserrat Diéguez, and Carmen Claver pp 3646–3647 DOI: 10.1021/ja0425738 Supporting Info

Site-Specific Phenylation of Pyridine Catalyzed by Phosphido-Bridged Ruthenium Dimer Complexes:  A Prototype for C−H Arylation of Electron-Deficient Heteroarenes Kamil Godula, Bengü Sezen, and Dalibor Sames pp 3648–3649 DOI: 10.1021/ja042510p Supporting Info

Nuclear Spin Driven Quantum Tunneling of Magnetization in a New Lanthanide Single-Molecule Magnet:  Bis(Phthalocyaninato)holmium Anion Naoto Ishikawa, Miki Sugita, and Wolfgang Wernsdorfer pp 3650–3651 DOI: 10.1021/ja0428661

Solid-State NMR Fermi Contact and Dipolar Shifts in Organometallic Complexes and Metalloporphyrins Yong Zhang, Haihong Sun, and Eric Oldfield pp 3652–3653 DOI: 10.1021/ja043461j Supporting Info

A Water Sluice Is Generated in the Active Site of Bovine Lens Leucine Aminopeptidase Stefan Erhardt, Elke Jaime, and Jennie Weston pp 3654–3655 DOI: 10.1021/ja042797q

Ni-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagents Using Alkyl Fluorides Jun Terao, Hiroyasu Watabe, and Nobuaki Kambe pp 3656–3657 DOI: 10.1021/ja042565r Supporting Info

Generation of Onions and Nanotubes of GaS and GaSe through Laser and Thermally Induced Exfoliation Ujjal K. Gautam, S. R. C. Vivekchand, A. Govindaraj, G. U. Kulkarni, N. R. Selvi, and C. N. R. Rao pp 3658–3659 DOI: 10.1021/ja042294k Supporting Info

A Synthetic Divalent Cholera Toxin Glycocalix[4]arene Ligand Having Higher Affinity than Natural GM1 Oligosaccharide Daniela Arosio, Marco Fontanella, Laura Baldini, Laura Mauri, Anna Bernardi, Alessandro Casnati, Francesco Sansone, and Rocco Ungaro pp 3660–3661 DOI: 10.1021/ja0444029 Supporting Info

Highly Regio- and Stereoselective Synthesis of Tetrasubstituted Cyclobutenes via Cyclodimerization of Alkynes Mediated by Zirconium Yuanhong Liu, Meina Liu, and Zhiquan Song pp 3662–3663 DOI: 10.1021/ja042636m Supporting Info

Effect of Added Nucleophilic Species on the Rate of Primary Amino Acid Nitrosation Gabriel da Silva, Eric M. Kennedy, and Bogdan Z. Dlugogorski pp 3664–3665 DOI: 10.1021/ja042449o Supporting Info

Dinuclear Asymmetric Zn Aldol Additions:  Formal Asymmetric Synthesis of Fostriecin Barry M. Trost, Mathias U. Frederiksen, Julien P. N. Papillon, Paul E. Harrington, Seunghoon Shin, and Brock T. Shireman pp 3666–3667 DOI: 10.1021/ja042435i Supporting Info

A Practical Catalytic Method for Preparing Highly Substituted Cyclobutanes and Cyclobutenes Kazato Inanaga, Kiyosei Takasu, and Masataka Ihara pp 3668–3669 DOI: 10.1021/ja042661s Supporting Info

Organocatalytic Regio- and Asymmetric C-Selective SNAr ReactionsStereoselective Synthesis of Optically Active Spiro-pyrrolidone-3,3‘-oxoindoles Marco Bella, Sara Kobbelgaard, and Karl Anker Jørgensen pp 3670–3671 DOI: 10.1021/ja050200g Supporting Info

Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction:  Cross-Dehydrogenative-Coupling between sp3 C−H Bond and sp3 C−H Bond Zhiping Li and Chao-Jun Li pp 3672–3673 DOI: 10.1021/ja050058j Supporting Info

A Hydrophobic Nanocapsule Controls the Photophysics of Aromatic Molecules by Suppressing Their Favored Solution Pathways Lakshmi S. Kaanumalle, Corinne L. D. Gibb, Bruce C. Gibb, and V. Ramamurthy pp 3674–3675 DOI: 10.1021/ja0425381 Supporting Info

Efficient Synthesis of Optically Active Atropisomeric Anilides through Catalytic Asymmetric N-Arylation Reaction Osamu Kitagawa, Masashi Takahashi, Masatoshi Yoshikawa, and Takeo Taguchi pp 3676–3677 DOI: 10.1021/ja042216x Supporting Info

Dual Function Catalysts. Dehydrogenation and Asymmetric Intramolecular Diels−Alder Cycloaddition of N-Hydroxy Formate Esters and Hydroxamic Acids:  Evidence for a Ruthenium−Acylnitroso Intermediate Chun P. Chow and Kenneth J. Shea pp 3678–3679 DOI: 10.1021/ja050059b Supporting Info

Bifunctional Organocatalysts for Enantioselective aza-Morita−Baylis−Hillman Reaction Katsuya Matsui, Shinobu Takizawa, and Hiroaki Sasai pp 3680–3681 DOI: 10.1021/ja0500254 Supporting Info

Reconstitution and Biochemical Characterization of a New Pyridoxal-5‘-Phosphate Biosynthetic Pathway Kristin E. Burns, Yun Xiang, Cynthia L. Kinsland, Fred W. McLafferty, and Tadhg P. Begley pp 3682–3683 DOI: 10.1021/ja042792t Supporting Info

Highly Sensitive Near-Infrared Fluorescent Probes for Nitric Oxide and Their Application to Isolated Organs Eita Sasaki, Hirotatsu Kojima, Hiroaki Nishimatsu, Yasuteru Urano, Kazuya Kikuchi, Yasunobu Hirata, and Tetsuo Nagano pp 3684–3685 DOI: 10.1021/ja042967z Supporting Info

Effects of Conformational Stability and Geometry of Guanidinium Display on Cell Entry by β-Peptides Terra B. Potocky, Anant K. Menon, and Samuel H. Gellman pp 3686–3687 DOI: 10.1021/ja042566j Supporting Info

Dienophile Twisting and Substituent Effects Influence Reaction Rates of Intramolecular Diels−Alder Cycloadditions:  A DFT Study Kelli S. Khuong, Chris M. Beaudry, Dirk Trauner, and K. N. Houk pp 3688–3689 DOI: 10.1021/ja050135a Supporting Info

Electrochemical Studies of Guanosine in DMF and Detection of Its Radical Cation in a Scanning Electrochemical Microscopy Nanogap Experiment Shuping Bi, Biao Liu, Fu-Ren F. Fan, and Allen J. Bard pp 3690–3691 DOI: 10.1021/ja042433y Supporting Info

Efficient DNA Interstrand Cross-Link Formation from a Nucleotide Radical In Seok Hong and Marc M. Greenberg pp 3692–3693 DOI: 10.1021/ja042434q Supporting Info

A Pentenyl Dianion-Based Strategy for Convergent Synthesis of Ene-1,5-diols Adilah B. Bahadoor, Alec Flyer, and Glenn C. Micalizio pp 3694–3695 DOI: 10.1021/ja050039+ Supporting Info

Total Synthesis of Brasoside and Littoralisone Ian K. Mangion and David W. C. MacMillan pp 3696–3697 DOI: 10.1021/ja050064f Supporting Info

Au42:  An Alternative Icosahedral Golden Fullerene Cage Yi Gao and Xiao Cheng Zeng pp 3698–3699 DOI: 10.1021/ja050435s Supporting Info

A Chemosensor Array for the Colorimetric Identification of 20 Natural Amino Acids Andrey Buryak and Kay Severin pp 3700–3701 DOI: 10.1021/ja042363v Supporting Info

Anomalous Fluorescence from the Azaxanthone Ketyl Radical in the Excited State Masanori Sakamoto, Xichen Cai, Michihiro Hara, Sachiko Tojo, Mamoru Fujitsuka, and Tetsuro Majima pp 3702–3703 DOI: 10.1021/ja043212v Supporting Info

Preparation and Crystal Structure of Two Bicyclo[1.1.0]butan-2-ones:  A Hybrid Oxyallyl−Cyclopropanone Motif Surbhi Bhargava, Jianjun Hou, Masood Parvez, and Ted S. Sorensen pp 3704–3705 DOI: 10.1021/ja043646q Supporting Info

Systematic Synthesis of Heterometallic Ni/Fe/S and Cu/Fe/S Clusters with a Pentlandite-like M8S6 Core Markos Koutmos, Harris Kalyvas, Yiannis Sanakis, Athanasios Simopoulos, and Dimitri Coucouvanis pp 3706–3707 DOI: 10.1021/ja042938o Supporting Info

Octacyanometallate-Based Single-Molecule Magnets:  CoII9MV6 (M = W, Mo) You Song, Peng Zhang, Xiao-Ming Ren, Xiao-Fei Shen, Yi-Zhi Li, and Xiao-Zeng You pp 3708–3709 DOI: 10.1021/ja042334k Supporting Info

Wafer-Scale Periodic Nanohole Arrays Templated from Two-Dimensional Nonclose-Packed Colloidal Crystals Peng Jiang and Michael J. McFarland pp 3710–3711 DOI: 10.1021/ja042789+ Supporting Info

Fluorinated Nanodiamond as a Wet Chemistry Precursor for Diamond Coatings Covalently Bonded to Glass Surface Yu Liu, Valery N. Khabashesku, and Naomi J. Halas pp 3712–3713 DOI: 10.1021/ja042389m Supporting Info

Direct Palladium-Catalyzed Arylation of Cyclopropenes Stepan Chuprakov, Michael Rubin, and Vladimir Gevorgyan pp 3714–3715 DOI: 10.1021/ja042380k Supporting Info

Unusual Heme−Histidine Bond in the Active Site of a Chaperone Donghan Lee, Konstantin Pervushin, Daniela Bischof, Martin Braun, and Linda Thöny-Meyer pp 3716–3717 DOI: 10.1021/ja044658e Supporting Info

Dual-Surface Modification of the Tobacco Mosaic Virus Tara L. Schlick, Zhebo Ding, Ernest W. Kovacs, and Matthew B. Francis pp 3718–3723 DOI: 10.1021/ja046239n Supporting Info

Ordering the Reductive and Cytochrome P450 Oxidative Steps in Demethylsterigmatocystin Formation Yields General Insights into the Biosynthesis of Aflatoxin and Related Fungal Metabolites Kevin M. Henry and Craig A. Townsend pp 3724–3733 DOI: 10.1021/ja0455188 Supporting Info

Evolutionarily Conserved Functional Mechanics across Pepsin-like and Retroviral Aspartic Proteases Michele Cascella, Cristian Micheletti, Ursula Rothlisberger, and Paolo Carloni pp 3734–3742 DOI: 10.1021/ja044608+ Supporting Info

Probing Site-Specific Calmodulin Calcium and Lanthanide Affinity by Grafting Yiming Ye, Hsiau-Wei Lee, Wei Yang, Sarah Shealy, and Jenny J. Yang pp 3743–3750 DOI: 10.1021/ja042786x Supporting Info

Spectroscopic and Functional Determination of the Interaction of Pb2+ with GATA Proteins Amy B. Ghering, Lisa M. Miller Jenkins, Brandy L. Schenck, Sandhya Deo, R. Aeryn Mayer, Michael J. Pikaart, James G. Omichinski, and Hilary A. Godwin pp 3751–3759 DOI: 10.1021/ja0464544 Supporting Info

Full and Partial Deuterium Solvent Isotope Effect Studies of α-Thrombin-Catalyzed Reactions of Natural Substrates Daoning Zhang and Ildiko M. Kovach pp 3760–3766 DOI: 10.1021/ja043258o Supporting Info

A Modular Strategy Toward the Synthesis of Heparin-like Oligosaccharides Using Monomeric Building Blocks in a Sequential Glycosylation Strategy Jeroen D. C. Codée, Bas Stubba, Marialuisa Schiattarella, Herman S. Overkleeft, Constant A. A. van Boeckel, Jacques H. van Boom, and Gijsbert A. van der Marel pp 3767–3773 DOI: 10.1021/ja045613g Supporting Info

Lewis Base Activation of Lewis Acids:  Catalytic, Enantioselective Addition of Silyl Ketene Acetals to Aldehydes Scott E. Denmark, Gregory L. Beutner, Thomas Wynn, and Martin D. Eastgate pp 3774–3789 DOI: 10.1021/ja047339w Supporting Info

Chiral Phosphine Lewis Bases Catalyzed Asymmetric aza-Baylis−Hillman Reaction of N-Sulfonated Imines with Activated Olefins Min Shi, Lian-Hui Chen, and Chao-Qun Li pp 3790–3800 DOI: 10.1021/ja0447255 Supporting Info

Carbocyanine Dyes as Efficient Reversible Single-Molecule Optical Switch Mike Heilemann, Emmanuel Margeat, Robert Kasper, Markus Sauer, and Philip Tinnefeld pp 3801–3806 DOI: 10.1021/ja044686x Supporting Info

Homolysis of Weak Ti−O Bonds:  Experimental and Theoretical Studies of Titanium Oxygen Bonds Derived from Stable Nitroxyl Radicals Kuo-Wei Huang, Joseph H. Han, Adam P. Cole, Charles B. Musgrave, and Robert M. Waymouth pp 3807–3816 DOI: 10.1021/ja044512f Supporting Info

Time−Temperature Superposition for Viscoelastic Properties of Regioregular Poly(3-hexylthiophene) Films A. Robert Hillman, Igor Efimov, and Magdalena Skompska pp 3817–3824 DOI: 10.1021/ja0437508

Preparation of Homopolymers and Block Copolymers in Miniemulsion by ATRP Using Activators Generated by Electron Transfer (AGET) Ke Min, Haifeng Gao, and Krzysztof Matyjaszewski pp 3825–3830 DOI: 10.1021/ja0429364

Recognition of Alkali Metal Halide Contact Ion Pairs by Uranyl−Salophen Receptors Bearing Aromatic Sidearms. The Role of Cation−π Interactions Massimo Cametti, Maija Nissinen, Antonella Dalla Cort, Luigi Mandolini, and Kari Rissanen pp 3831–3837 DOI: 10.1021/ja042807n Supporting Info

Highly Ordered “Defect-Free” Self-Assembled Hybrid Films with a Tetragonal Mesostructure Paolo Falcaro, Stefano Costacurta, Giovanni Mattei, Heinz Amenitsch, Augusto Marcelli, Mariangela Cestelli Guidi, Massimo Piccinini, Alessandro Nucara, Luca Malfatti, Tongjit Kidchob, and Plinio Innocenzi pp 3838–3846 DOI: 10.1021/ja0427956 Supporting Info

Continuous Spinning of a Single-Walled Carbon Nanotube−Nylon Composite Fiber Junbo Gao, Mikhail E. Itkis, Aiping Yu, Elena Bekyarova, Bin Zhao, and Robert C. Haddon pp 3847–3854 DOI: 10.1021/ja0446193 Supporting Info

Switching the Redox Mechanism:  Models for Proton-Coupled Electron Transfer from Tyrosine and Tryptophan Martin Sjödin, Stenbjörn Styring, Henriette Wolpher, Yunhua Xu, Licheng Sun, and Leif Hammarström pp 3855–3863 DOI: 10.1021/ja044395o Supporting Info

Electrochemical Synthesis, Crystal Structure, and Photomagnetic Properties of a Three-Dimensional Cyano-Bridged Copper−Molybdenum Complex Toshiya Hozumi, Kazuhito Hashimoto, and Shin-ichi Ohkoshi pp 3864–3869 DOI: 10.1021/ja044107o Supporting Info

Synthesis of Compact Multidentate Ligands to Prepare Stable Hydrophilic Quantum Dot Fluorophores H. Tetsuo Uyeda, Igor L. Medintz, Jyoti K. Jaiswal, Sanford M. Simon, and Hedi Mattoussi pp 3870–3878 DOI: 10.1021/ja044031w Supporting Info

The Binding Energy of Two Nitrilotriacetate Groups Sharing a Nickel Ion David Tareste, Frédéric Pincet, Marie Brellier, Charles Mioskowski, and Éric Perez pp 3879–3884 DOI: 10.1021/ja043525q Supporting Info

Origin of the Unusual Kinetics of Iron Deposition in Human H-Chain Ferritin Fadi Bou-Abdallah, Guanghua Zhao, Howard R. Mayne, Paolo Arosio, and N. Dennis Chasteen pp 3885–3893 DOI: 10.1021/ja044355k

Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller pp 3894–3909 DOI: 10.1021/ja045064e Supporting Info

Periodic Hexagonal Mesostructured Chalcogenides Based on Platinum and [SnSe4]4- and [SnTe4]4- Precursors. Solvent Dependence of Nanopore and Wall Organization Pantelis N. Trikalitis, Thomas Bakas, and Mercouri G. Kanatzidis pp 3910–3920 DOI: 10.1021/ja0447614 Supporting Info

Hypervalent, Low-Coordinate Phosphorus(III) Centers in Complexes of the Phosphadiazonium Cation with Chelate Ligands Neil Burford, Andrew D. Phillips, Heather A. Spinney, Michael Lumsden, Ulrike Werner-Zwanziger, Michael J. Ferguson, and Robert McDonald pp 3921–3927 DOI: 10.1021/ja043691y Supporting Info

Charge Separation and Catalytic Activity of Ag@TiO2 Core−Shell Composite Clusters under UV−Irradiation Tsutomu Hirakawa and Prashant V. Kamat pp 3928–3934 DOI: 10.1021/ja042925a

Parallel Biomolecular Computation on Surfaces with Advanced Finite Automata Michal Soreni, Sivan Yogev, Elizaveta Kossoy, Yuval Shoham, and Ehud Keinan pp 3935–3943 DOI: 10.1021/ja047168v

Protons Colliding with Crystalline Ice:  Proton Reflection and Collision Induced Water Desorption at Low Incidence Energies Pepa Cabrera Sanfelix, Ayman Al-Halabi, George R. Darling, Stephen Holloway, and Geert-Jan Kroes pp 3944–3951 DOI: 10.1021/ja040171u

Solvent Effects on the Vibrational Activity and Photodynamics of the Green Fluorescent Protein Chromophore:  A Quantum-Chemical Study Piero Altoe', Fernando Bernardi, Marco Garavelli, Giorgio Orlandi, and Fabrizia Negri pp 3952–3963 DOI: 10.1021/ja0451517 Supporting Info

A Theoretical Study on the Origin of π-Facial Stereoselectivity in the Alkylation of Enolates Derived from 4-Substituted γ-Butyrolactones Kaori Ando pp 3964–3972 DOI: 10.1021/ja044995n Supporting Info

Reactions of Charged Phenyl Radicals with Aliphatic Amino Acids in the Gas Phase Yiqun Huang, Leo Guler, Jenny Heidbrink, and Hilkka Kenttämaa pp 3973–3978 DOI: 10.1021/ja044676w

Magnetic Field Effects on Bioelectrocatalytic Reactions of Surface-Confined Enzyme Systems:  Enhanced Performance of Biofuel Cells Eugenii Katz, Oleg Lioubashevski, and Itamar Willner pp 3979–3988 DOI: 10.1021/ja044157t Supporting Info

Mechanisms of Methane Activation and Transformation on Molybdenum Oxide Based Catalysts Gang Fu, Xin Xu, Xin Lu, and Huilin Wan pp 3989–3996 DOI: 10.1021/ja0441099 Supporting Info

p-Channel Organic Semiconductors Based on Hybrid Acene−Thiophene Molecules for Thin-Film Transistor Applications Jeffrey A. Merlo, Christopher R. Newman, Christopher P. Gerlach, Tommie W. Kelley, Dawn V. Muyres, Sandra E. Fritz, Michael F. Toney, and C. Daniel Frisbie pp 3997–4009 DOI: 10.1021/ja044078h Supporting Info

Dynamical Flexibility and Proton Transfer in the Arginase Active Site Probed by ab Initio Molecular Dynamics Ivaylo Ivanov and Michael L. Klein pp 4010–4020 DOI: 10.1021/ja043693i

Ruthenium(II)-Catalyzed Hydrogenation of Carbon Dioxide to Formic Acid. Theoretical Study of Real Catalyst, Ligand Effects, and Solvation Effects Yu-ya Ohnishi, Tadashi Matsunaga, Yoshihide Nakao, Hirofumi Sato, and Shigeyoshi Sakaki pp 4021–4032 DOI: 10.1021/ja043697n Supporting Info

Conformational Analysis of Self-Organized Monolayers with Scanning Tunneling Microscopy at Near-Atomic Resolution Lukas J. Scherer, Leo Merz, Edwin C. Constable, Catherine E. Housecroft, Markus Neuburger, and B. A. Hermann pp 4033–4041 DOI: 10.1021/ja043638+ Supporting Info

Toward Understanding Mobile Proton Behavior from First Principles Calculation:  The Short Hydrogen Bond in Crystalline Urea−Phosphoric Acid Carole A. Morrison, Muhammad M. Siddick, Philip J. Camp, and Chick C. Wilson pp 4042–4048 DOI: 10.1021/ja043327z Supporting Info

Electron Transfer Pathways and Protein Response to Charge Separation in Photosynthetic Reaction Centers:  Time-Resolved High-Field ENDOR of the Spin-Correlated Radical Pair P865+QA- Oleg G. Poluektov, Lisa M. Utschig, Alexander A. Dubinskij, and Marion C. Thurnauer pp 4049–4059 DOI: 10.1021/ja043063g

Magnetoswitchable Electrochemistry Gated by Alkyl-Chain-Functionalized Magnetic Nanoparticles:  Control of Diffusional and Surface-Confined Electrochemical Processes Eugenii Katz, Ronan Baron, and Itamar Willner pp 4060–4070 DOI: 10.1021/ja042910c

Sensitivity of Polar Solvation Dynamics to the Secondary Structures of Aqueous Proteins and the Role of Surface Exposure of the Probe Sanjoy Bandyopadhyay, Sudip Chakraborty, Sundaram Balasubramanian, and Biman Bagchi pp 4071–4075 DOI: 10.1021/ja042847r

Infrared Photodissociation Spectroscopy of Electrosprayed Ions in a Fourier Transform Mass Spectrometer Han-Bin Oh, Cheng Lin, Harold Y. Hwang, Huili Zhai, Kathrin Breuker, Vladimir Zabrouskov, Barry K. Carpenter, and Fred W. McLafferty pp 4076–4083 DOI: 10.1021/ja040136n

Cluster-Phase Reactions:  Gas-Phase Phosphorylation of Peptides and Model Compounds with Triphosphate Anions Heather A. Cox, Robert Hodyss, and J. L. Beauchamp pp 4084–4090 DOI: 10.1021/ja0452673

Factors Governing the Substitution of La3+ for Ca2+ and Mg2+ in Metalloproteins:  A DFT/CDM Study Todor Dudev, Li-Ying Chang, and Carmay Lim pp 4091–4103 DOI: 10.1021/ja044404t

Ionization Potentials of Fluoroindoles and the Origin of Nonexponential Tryptophan Fluorescence Decay in Proteins Tiqing Liu, Patrik R. Callis, Ben H. Hesp, Mattijs de Groot, Wybren Jan Buma, and Jaap Broos pp 4104–4113 DOI: 10.1021/ja043154d Supporting Info

Microarray Platform for Profiling Enzyme Activities in Complex Proteomes [J. Am. Chem. Soc. 2004, 126, 15640−15641]. Stephan A. Sieber, Tony S. Mondala, Steven R. Head, and Benjamin F. Cravatt p 4114 DOI: 10.1021/ja0506915

Stepwise Hydration, and Multi-Body Deprotonation with Steep Negative Temperature Dependence, in the Benzene•+−Water System [J. Am. Chem. Soc. 2004, 126, 12766−12767]. Yehia Ibrahim, Edreese Alsharaeh, Keith Dias, Michael Meot-Ner (Mautner), and M. Samy El-Shall p 4114 DOI: 10.1021/ja059903o

ChemDraw Ultra 9.0. CambridgeSoft, 100 CambridgePark Drive, Cambridge, MA 02140. www. cambridgesoft.com. See Web site for pricing options. Kimberley R. Cousins pp 4115–4116 DOI: 10.1021/ja0410237

Issue 12

Solution Structure of a β-Peptide Ligand for hDM2 Joshua A. Kritzer, Michael E. Hodsdon, and Alanna Schepartz pp 4118–4119 DOI: 10.1021/ja042933r Supporting Info

The Role of Chelating Diamine Ligands in the Goldberg Reaction:  A Kinetic Study on the Copper-Catalyzed Amidation of Aryl Iodides Eric R. Strieter, Donna G. Blackmond, and Stephen L. Buchwald pp 4120–4121 DOI: 10.1021/ja050120c Supporting Info

Asymmetric End-Functionalization of Multi-Walled Carbon Nanotubes Kyung Min Lee, Lingchuan Li, and Liming Dai pp 4122–4123 DOI: 10.1021/ja0423670 Supporting Info

Switching of Intramolecular Charge Transfer in Cruciforms:  Metal Ion Sensing James N. Wilson and Uwe H. F. Bunz pp 4124–4125 DOI: 10.1021/ja050017n Supporting Info

Ligand Effect on the Growth and the Digestion of Co Nanocrystals Anna C. S. Samia, Kylee Hyzer, John A. Schlueter, Chang-Jin Qin, J. Samuel Jiang, Samuel D. Bader, and Xiao-Min Lin pp 4126–4127 DOI: 10.1021/ja044419r Supporting Info

Amphiphilic Polymethacrylate Derivatives as Antimicrobial Agents Kenichi Kuroda and William F. DeGrado pp 4128–4129 DOI: 10.1021/ja044205+ Supporting Info

Facile Modification of Collagen Directed by Collagen Mimetic Peptides Allen Y. Wang, Xiao Mo, Christopher S. Chen, and Seungju M. Yu pp 4130–4131 DOI: 10.1021/ja0431915 Supporting Info

Unprecedented Control over Polymerization of n-Hexyl Isocyanate using an Anionic Initiator Having Synchronized Function of Chain-End Protection Jun-Hwan Ahn, Yeong-Deuk Shin, G. Yogendra Nath, Sang-Yoon Park, M. Shahinur Rahman, Shashadhar Samal, and Jae-Suk Lee pp 4132–4133 DOI: 10.1021/ja0427000 Supporting Info

Insight into Binding of Alkanes to Transition Metals from NMR Spectroscopy of Isomeric Pentane and Isotopically Labeled Alkane Complexes Douglas J. Lawes, Spili Geftakis, and Graham E. Ball pp 4134–4135 DOI: 10.1021/ja044208m Supporting Info

Quantifying Adhesion Bond Parameters to Distinguish Interactions of Hydrophilic and Hydrophobic Blocks of Polystyrene−Poly-2-vinylpyridine with a Silicon Nitride Surface Pamela Y. Meadows, Jason E. Bemis, and Gilbert C. Walker pp 4136–4137 DOI: 10.1021/ja0427395 Supporting Info

Enantioselective Alkenylation and Phenylation Catalyzed by a Chiral CuF Complex Daisuke Tomita, Reiko Wada, Motomu Kanai, and Masakatsu Shibasaki pp 4138–4139 DOI: 10.1021/ja0507362 Supporting Info

(+)-Myristinin A, a Naturally Occurring DNA Polymerase β Inhibitor and Potent DNA-Damaging Agent David J. Maloney, Jing-Zhen Deng, Shelley R. Starck, Zhijie Gao, and Sidney M. Hecht pp 4140–4141 DOI: 10.1021/ja042727j Supporting Info

A Stable N-Heterocyclic Carbene with a Diboron Backbone Kelly E. Krahulic, Gary D. Enright, Masood Parvez, and Roland Roesler pp 4142–4143 DOI: 10.1021/ja050129e Supporting Info

(SR/RS)-Cyclohexanyl PNAs:  Conformationally Preorganized PNA Analogues with Unprecedented Preference for Duplex Formation with RNA T. Govindaraju, Vaijayanti A. Kumar, and Krishna N. Ganesh pp 4144–4145 DOI: 10.1021/ja044142v Supporting Info

19F NMR Characterization of the Thermodynamics and Dynamics of the Acid−Alkaline Transition in a Reconstituted Sperm Whale Metmyoglobin Satoshi Nagao, Yueki Hirai, Akihiro Suzuki, and Yasuhiko Yamamoto pp 4146–4147 DOI: 10.1021/ja043975i Supporting Info

Fourier Transform Infrared Characterization of the Azido Complex of Methane Monooxygenase Hydroxylase from Methylococcus capsulatus (Bath) Shen Lu, Matthew H. Sazinsky, James W. Whittaker, Stephen J. Lippard, and Pierre Moënne-Loccoz pp 4148–4149 DOI: 10.1021/ja044414u Supporting Info

RuO2-Loaded β-Ge3N4 as a Non-Oxide Photocatalyst for Overall Water Splitting Junya Sato, Nobuo Saito, Yoko Yamada, Kazuhiko Maeda, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen, and Yasunobu Inoue pp 4150–4151 DOI: 10.1021/ja042973v

A Ruthenium−Dihydrogen Putative Intermediate in Ketone Hydrogenation Robin J. Hamilton, Carolyn G. Leong, Glen Bigam, Mark Miskolzie, and Steven H. Bergens pp 4152–4153 DOI: 10.1021/ja043339k Supporting Info

Highly Enantioselective Friedel−Crafts Alkylations of Pyrroles and Indoles with α‘-Hydroxy Enones under Cu(II)-Simple Bis(oxazoline) Catalysis Claudio Palomo, Mikel Oiarbide, Bharat G. Kardak, Jesús M. García, and Anthony Linden pp 4154–4155 DOI: 10.1021/ja0423217 Supporting Info

Catalytic Coupling of Haloolefins with Anilides Vladimir G. Zaitsev and Olafs Daugulis pp 4156–4157 DOI: 10.1021/ja050366h Supporting Info

Cell-Permeable Near-Infrared Fluorogenic Substrates for Imaging β-Lactamase Activity Bengang Xing, Ashot Khanamiryan, and Jianghong Rao pp 4158–4159 DOI: 10.1021/ja042829+ Supporting Info

Liquid-Core Capsules via Interfacial Polymerization:  A Free-Radical Analogy of the Nylon Rope Trick Charles Scott, Dan Wu, Chia-Chi Ho, and Carlos C. Co pp 4160–4161 DOI: 10.1021/ja044532h Supporting Info

Electronic Structures and Properties of Twisted Polyacenes Joseph E. Norton and K. N. Houk pp 4162–4163 DOI: 10.1021/ja042379l Supporting Info

A Stable Single Piece of Unimolecularly π-Stacked Porphyrin Aggregate in a Thixotropic Low Molecular Weight Gel:  A One-Dimensional Molecular Template for Polydiacetylene Wiring up to Several Tens of Micrometers in Length Michihiro Shirakawa, Norifumi Fujita, and Seiji Shinkai pp 4164–4165 DOI: 10.1021/ja042869d Supporting Info

Monitoring the Growth of Polyoxomolybdate Nanoparticles in Suspension by Flow Field-Flow Fractionation Bailin Chen, Huijian Jiang, Yan Zhu, Arthur Cammers, and John P. Selegue pp 4166–4167 DOI: 10.1021/ja045067r

Bulky Diarylammonium Arenesulfonates as Selective Esterification Catalysts Kazuaki Ishihara, Shoko Nakagawa, and Akira Sakakura pp 4168–4169 DOI: 10.1021/ja050223v Supporting Info

Heptamethine Cyanine Dyes with a Large Stokes Shift and Strong Fluorescence:  A Paradigm for Excited-State Intramolecular Charge Transfer Xiaojun Peng, Fengling Song, Erhu Lu, Yanan Wang, Wei Zhou, Jiangli Fan, and Yunling Gao pp 4170–4171 DOI: 10.1021/ja043413z Supporting Info

Synthesis and Circular Dichroism of Tetraarylporphyrin−Oligonucleotide Conjugates Milan Balaz, Andrea E. Holmes, Michele Benedetti, Pamela C. Rodriguez, Nina Berova, Koji Nakanishi, and Gloria Proni pp 4172–4173 DOI: 10.1021/ja043373z Supporting Info

A Simple Glycol Nucleic Acid Lilu Zhang, Adam Peritz, and Eric Meggers pp 4174–4175 DOI: 10.1021/ja042564z Supporting Info

Design of an Intein that Can Be Inhibited with a Small Molecule Ligand Steffen Brenzel and Henning D. Mootz pp 4176–4177 DOI: 10.1021/ja043501j Supporting Info

Dioxygen Activation and Catalytic Aerobic Oxidation by a Mononuclear Nonheme Iron(II) Complex Sun Ok Kim, Chivukula V. Sastri, Mi Sook Seo, Jinheung Kim, and Wonwoo Nam pp 4178–4179 DOI: 10.1021/ja043083i Supporting Info

Sulfoxide Carbon−Sulfur Bond Activation Joseph M. O'Connor, Kevin D. Bunker, Arnold L. Rheingold, and Lev Zakharov pp 4180–4181 DOI: 10.1021/ja050160g Supporting Info

From CO Oxidation to CO2 Activation:  An Unexpected Catalytic Activity of Polymer-Supported Nanogold Feng Shi, Qinghua Zhang, Yubo Ma, Yude He, and Youquan Deng pp 4182–4183 DOI: 10.1021/ja042207o Supporting Info

Rapid Fixation of Methylene Chloride by a Macrocyclic Amine Jung-Jae Lee, Keith J. Stanger, Bruce C. Noll, Carlos Gonzalez, Manuel Marquez, and Bradley D. Smith pp 4184–4185 DOI: 10.1021/ja042208g Supporting Info

Ruthenium-Catalyzed Regioselective 1,3-Methylene Transfer by Cleavage of Two Adjacent σ-Carbon−Carbon Bonds:  An Easy and Selective Synthesis of Highly Subsituted Benzenes Jian-Jou Lian, Arjan Odedra, Chang-Jung Wu, and Rai-Shung Liu pp 4186–4187 DOI: 10.1021/ja0504901 Supporting Info

Graphitized Pitch-Based Carbons with Ordered Nanopores Synthesized by Using Colloidal Crystals as Templates Suk Bon Yoon, Geun Seok Chai, Soon Ki Kang, Jong-Sung Yu, Kamil P. Gierszal, and Mietek Jaroniec pp 4188–4189 DOI: 10.1021/ja0423466 Supporting Info

Dual Emission from a Family of Conjugated Dinuclear RuII Complexes Edith C. Glazer, Douglas Magde, and Yitzhak Tor pp 4190–4192 DOI: 10.1021/ja0440304 Supporting Info

@-Tides as Reporters for Molecular Associations Scott T. Phillips, Landy K. Blasdel, and Paul A. Bartlett pp 4193–4198 DOI: 10.1021/ja045122w Supporting Info

Quadruplex Formation by a Guanine-Rich PNA Oligomer Bhaskar Datta, Mark E. Bier, Subhadeep Roy, and Bruce A. Armitage pp 4199–4207 DOI: 10.1021/ja0446202 Supporting Info

Reaction Intermediates of Quinol Oxidation in a Photoactivatable System that Mimics Electron Transfer in the Cytochrome bc1 Complex Jonathan L. Cape, Michael K. Bowman, and David M. Kramer pp 4208–4215 DOI: 10.1021/ja043955g Supporting Info

Solution Structure of Vanabin2, a Vanadium(IV)-Binding Protein from the Vanadium-Rich Ascidian Ascidia sydneiensis samea Toshiyuki Hamada, Miwako Asanuma, Tatsuya Ueki, Fumiaki Hayashi, Naohiro Kobayashi, Shigeyuki Yokoyama, Hitoshi Michibata, and Hiroshi Hirota pp 4216–4222 DOI: 10.1021/ja042687j Supporting Info

RNA Structure Analysis at Single Nucleotide Resolution by Selective 2‘-Hydroxyl Acylation and Primer Extension (SHAPE) Edward J. Merino, Kevin A. Wilkinson, Jennifer L. Coughlan, and Kevin M. Weeks pp 4223–4231 DOI: 10.1021/ja043822v

Hybrid QM/MM and DFT Investigations of the Catalytic Mechanism and Inhibition of the Dinuclear Zinc Metallo-β-Lactamase CcrA from Bacteroides fragilis Hwangseo Park, Edward N. Brothers, and Kenneth M. Merz, Jr. pp 4232–4241 DOI: 10.1021/ja042607b

A Comparative Study of the Catalytic Mechanisms of the Zinc and Cadmium Containing Carbonic Anhydrase Tiziana Marino, Nino Russo, and Marirosa Toscano pp 4242–4253 DOI: 10.1021/ja045546q Supporting Info

Phospholipid Tubelets Bijaya K. Mishra, Colleen C. Garrett, and Britt N. Thomas pp 4254–4259 DOI: 10.1021/ja040191w

Guidelines in Implementing Enantioselective Indicator-Displacement Assays for α-Hydroxycarboxylates and Diols Lei Zhu, Zhenlin Zhong, and Eric V. Anslyn pp 4260–4269 DOI: 10.1021/ja0435945 Supporting Info

Triplet Acetylenes as Synthetic Equivalents of 1,2-Bicarbenes:  Phantom n,π* State Controls Reactivity in Triplet Photocycloaddition Tarek A. Zeidan, Serguei V. Kovalenko, Mariappan Manoharan, Ronald J. Clark, Ion Ghiviriga, and Igor V. Alabugin pp 4270–4285 DOI: 10.1021/ja043803l Supporting Info

Influence of Alkyl Substituents on the Solution- and Surface-Organization of Hexa-peri-hexabenzocoronenes Marcel Kastler, Wojciech Pisula, Daniel Wasserfallen, Tadeusz Pakula, and Klaus Müllen pp 4286–4296 DOI: 10.1021/ja0430696 Supporting Info

Total Syntheses of Amphidinolides T1 and T4 via Catalytic, Stereoselective, Reductive Macrocyclizations Elizabeth A. Colby, Karen C. O'Brien, and Timothy F. Jamison pp 4297–4307 DOI: 10.1021/ja042733f Supporting Info

Absolute Configuration, Conformation, and Circular Dichroism of Monocyclic Arene Dihydrodiol Metabolites:  It is All Due to the Heteroatom Substituents Jacek K. Gawronski, Marcin Kwit, Derek R. Boyd, Narain D. Sharma, John F. Malone, and Alex F. Drake pp 4308–4319 DOI: 10.1021/ja042895b Supporting Info

Tuning the Orientation of an Antigen by Adsorption onto Nanostriped Templates Antoine Pallandre, Benoit De Meersman, Françoise Blondeau, Bernard Nysten, and Alain M. Jonas pp 4320–4325 DOI: 10.1021/ja043656r

Convergent Total Synthesis of Gymnocin-A and Evaluation of Synthetic Analogues Chihiro Tsukano, Makoto Ebine, and Makoto Sasaki pp 4326–4335 DOI: 10.1021/ja042686r Supporting Info

Kinetics of 5α-Cholestan-3β-yl N-(2-Naphthyl)carbamate/n-Alkane Organogel Formation and Its Influence on the Fibrillar Networks Xiao Huang, Pierre Terech, Srinivasa R. Raghavan, and Richard G. Weiss pp 4336–4344 DOI: 10.1021/ja0426544 Supporting Info

Interstellar Chemistry:  A Strategy for Detecting Polycyclic Aromatic Hydrocarbons in Space F. J. Lovas, Robert J. McMahon, Jens-Uwe Grabow, Melanie Schnell, James Mack, Lawrence T. Scott, and Robert L. Kuczkowski pp 4345–4349 DOI: 10.1021/ja0426239 Supporting Info

Stereocontrolled Synthesis and Optical Properties of All-cis Poly(phenylene vinylenes) (PPVs):  A Method for Direct Patterning of PPVs Hiroyuki Katayama, Masato Nagao, Tatsuro Nishimura, Yukio Matsui, Kazutoshi Umeda, Kensuke Akamatsu, Takaaki Tsuruoka, Hidemi Nawafune, and Fumiyuki Ozawa pp 4350–4353 DOI: 10.1021/ja042853n Supporting Info

Syntheses and Structures of Hypervalent Pentacoordinate Carbon and Boron Compounds Bearing an Anthracene Skeleton − Elucidation of Hypervalent Interaction Based on X-ray Analysis and DFT Calculation Makoto Yamashita, Yohsuke Yamamoto, Kin-ya Akiba, Daisuke Hashizume, Fujiko Iwasaki, Nozomi Takagi, and Shigeru Nagase pp 4354–4371 DOI: 10.1021/ja0438011 Supporting Info

Investigation of the Crystallization Process in 2 nm CdSe Quantum Dots Xiaobo Chen, Anna C. S. Samia, Yongbing Lou, and Clemens Burda pp 4372–4375 DOI: 10.1021/ja0458219 Supporting Info

Trimethylsilylated Allyl Complexes of Nickel. The Stabilized Bis(π-allyl)nickel Complex [η3-1,3-(SiMe3)2C3H3]2Ni and Its Mono(π-allyl)NiX (X = Br, I) Derivatives Keith T. Quisenberry, J. Dominic Smith, Markus Voehler, Donald F. Stec, Timothy P. Hanusa, and William W. Brennessel pp 4376–4387 DOI: 10.1021/ja044308s Supporting Info

Binding and Condensation of Plasmid DNA onto Functionalized Carbon Nanotubes:  Toward the Construction of Nanotube-Based Gene Delivery Vectors Ravi Singh, Davide Pantarotto, David McCarthy, Olivier Chaloin, Johan Hoebeke, Charalambos D. Partidos, Jean-Paul Briand, Maurizio Prato, Alberto Bianco, and Kostas Kostarelos pp 4388–4396 DOI: 10.1021/ja0441561 Supporting Info

Molecular Rotor of Cs2([18]crown-6)3 in the Solid State Coupled with the Magnetism of [Ni(dmit)2] Tomoyuki Akutagawa, Kozo Shitagami, Sadafumi Nishihara, Sadamu Takeda, Tatsuo Hasegawa, Takayoshi Nakamura, Yuko Hosokoshi, Katsuya Inoue, Satoshi Ikeuchi, Yuji Miyazaki, and Kazuya Saito pp 4397–4402 DOI: 10.1021/ja043527a Supporting Info

The Electronic Structure of the Isoelectronic, Square-Planar Complexes [FeII(L)2]2- and [CoIII(LBu)2]- (L2- and (LBu)2- = Benzene-1,2-dithiolates):  An Experimental and Density Functional Theoretical Study Kallol Ray, Ameerunisha Begum, Thomas Weyhermüller, Stergios Piligkos, Joris van Slageren, Frank Neese, and Karl Wieghardt pp 4403–4415 DOI: 10.1021/ja042803i Supporting Info

Quantitative Determination of the Chemical Composition of Silica−Poly(norbornene) Nanocomposites Mark Anderson Jordi and Thomas A. P. Seery* pp 4416–4422 DOI: 10.1021/ja044456i Supporting Info

Is It Homogeneous or Heterogeneous Catalysis? Compelling Evidence for Both Types of Catalysts Derived from [Rh(η5-C5Me5)Cl2]2 as a Function of Temperature and Hydrogen Pressure Collin M. Hagen, Jason A. Widegren, Peter M. Maitlis, and Richard G. Finke pp 4423–4432 DOI: 10.1021/ja044154g Supporting Info

Theoretical Study of the Truncated Hemoglobin HbN:  Exploring the Molecular Basis of the NO Detoxification Mechanism Alejandro Crespo, Marcelo A. Martí, Susana G. Kalko, Antonio Morreale, Modesto Orozco, Jose L. Gelpi, F. Javier Luque, and Darío A. Estrin pp 4433–4444 DOI: 10.1021/ja0450004 Supporting Info

Water-Promoted Hydrolysis of a Highly Twisted Amide:  Rate Acceleration Caused by the Twist of the Amide Bond Jon Iñaki Mujika, Jose Maria Mercero, and Xabier Lopez pp 4445–4453 DOI: 10.1021/ja044873v Supporting Info

Mechanisms of Antibiotic Resistance:  QM/MM Modeling of the Acylation Reaction of a Class A β-Lactamase with Benzylpenicillin Johannes C. Hermann, Christian Hensen, Lars Ridder, Adrian J. Mulholland, and Hans-Dieter Höltje pp 4454–4465 DOI: 10.1021/ja044210d Supporting Info

Chemical Shift Correlations in Disordered Solids Sylvian Cadars, Anne Lesage, and Lyndon Emsley pp 4466–4476 DOI: 10.1021/ja043698f

Determination of Peptide Oligomerization in Lipid Bilayers Using 19F Spin Diffusion NMR Jarrod J. Buffy, Alan J. Waring, and Mei Hong pp 4477–4483 DOI: 10.1021/ja043621r Supporting Info

Rapid Detection of an Anthrax Biomarker by Surface-Enhanced Raman Spectroscopy Xiaoyu Zhang, Matthew A. Young, Olga Lyandres, and Richard P. Van Duyne pp 4484–4489 DOI: 10.1021/ja043623b

Viscosity of the Aqueous Liquid/Vapor Interfacial Region:  2D Electrochemical Measurements with a Piperidine Nitroxy Radical Probe Deng Guo Wu, Andrew D. Malec, Martin Head-Gordon, and Marcin Majda pp 4490–4496 DOI: 10.1021/ja042969j

Separation of Single-Walled Carbon Nanotubes on Silica Gel. Materials Morphology and Raman Excitation Wavelength Affect Data Interpretation Christopher A. Dyke, Michael P. Stewart, and James M. Tour pp 4497–4509 DOI: 10.1021/ja042828h

Regarding the Mechanism of Olefin Metathesis with Sol−Gel-Supported Ru-Based Complexes Bearing a Bidentate Carbene Ligand. Spectroscopic Evidence for Return of the Propagating Ru Carbene Jason S. Kingsbury and Amir H. Hoveyda pp 4510–4517 DOI: 10.1021/ja042668+ Supporting Info

Nature of the Catalytically Labile Oxygen at the Active Site of Xanthine Oxidase Christian J. Doonan, Amy Stockert, Russ Hille, and Graham N. George pp 4518–4522 DOI: 10.1021/ja042500o

Size-Dependent Phase Transformation Kinetics in Nanocrystalline ZnS Feng Huang and Jillian F. Banfield pp 4523–4529 DOI: 10.1021/ja048121c

Substituent Effects on the Edge-to-Face Aromatic Interactions Eun Cheol Lee, Byung Hee Hong, Ju Young Lee, Jong Chan Kim, Dongwook Kim, Yukyung Kim, P. Tarakeshwar, and Kwang S. Kim pp 4530–4537 DOI: 10.1021/ja037454r

Encyclopedia of Electrochemistry, Volume 8:  Organic Electrochemistry Edited by Hans J. Schäfer (Universität Münster). Series edited by Allen J. Bard and Martin Stratmann. Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. x + 654 pp. $455.00. ISBN 3-527-30400-2. J. M. Tanko p 4538 DOI: 10.1021/ja040998o

Macromolecules Containing Metal and Metal-Like Elements, Volume 3:  Biomedical Applications Edited by Alaa S. Abd-El-Aziz (The University of Winnipeg), Charles E. Carraher, Jr. (Florida State University), Charles U. Pittman, Jr. (Mississippi State University), John E. Sheats (Rider University), and Martel Zelden (Hobart and William Smith Colleges). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xiv + 218 pp. $125.00. ISBN 0-471-66737-4. Thomas S. Hughes pp 4538–4539 DOI: 10.1021/ja040973p

Ion Exchange and Solvent Extraction, Volume 17 Edited by Yizhak Marcus (The Hebrew University of Jerusalem) and Arup K. SenGupta (Lehigh University). Marcel Dekker, Inc.:  New York, Basel. 2004. xx + 390 pp. $185.00. ISBN 0-8247-5492-1. Spiro D. Alexandratos pp 4539–4540 DOI: 10.1021/ja0409762

Spin Crossover in Transition Metal Compounds III. Topics in Current Chemistry, 235 Edited by Philipp Gütlich (Johannes Gutenberg-Universität, Mainz) and Harold A. Goodwin (University of New South Wales). Springer-Verlag:  Berlin, Heidelberg. 2004. xiv + 268 pp. $259.00. ISBN 3-540-40395-7. Gary J. Long p 4540 DOI: 10.1021/ja041006h

Chromatography:  Fundamentals and Applications of Chromatography and Related Differential Migration Methods, Part A:  Fundamentals and Techniques, 6th ed. Journal of Chromatography Library, Volume 69A Edited by Erich Heftmann (Orinda, CA). Elsevier B. V.: Amsterdam. 2004. xl + 544 pp. $245.00. ISBN 0-444-51107-5. James W. Jorgenson pp 4540–4541 DOI: 10.1021/ja040972x

Orotidine Monophosphate Decarboxylase:  A Mechanistic Dialogue. Topics in Current Chemistry, 238 Edited by Jeehiun K. Lee (Rutgers University) and Dean J. Tantillo (University of California, Davis). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 152 pp. $139.00. ISBN 3-540-20566-7. Brian P. Callahan and Richard Wolfenden p 4541 DOI: 10.1021/ja040982y

Electronic Noses and Sensors for the Detection of Explosives Edited by Julian W. Gardner (University of Warwick) and Jehuda Yinon (University of Central Florida). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xviii + 308 pp. $132.00. ISBN 1-4020-2317-0. p 4541 DOI: 10.1021/ja041014y

Environmental Instrumentation and Analysis Handbook Edited by Randy D. Down (Forensic Analysis & Engineering Corp., Raleigh, NC) and Jay H. Lehr (The Heartland Institute, Chicago, IL and Bennett and Williams, Inc., Columbus, OH). John Wiley and Sons, Inc.:  Hoboken, NJ. 2005. x + 1068 pp. $150.00. ISBN 0-471-46354-X. pp 4541–4542 DOI: 10.1021/ja041011l

Carbocation Chemistry Edited by George A. Olah and G. K. Surya Prakash (Loker Hydrocarbon Research Institute, University of Southern California). John Wiley and Sons, Inc.:  Hoboken, NJ. 2004. x + 394 pp. $99.95. ISBN 0-471-28490-4. p 4542 DOI: 10.1021/ja041009u

Spectroscopy of Emerging Materials Edited by Eric C. Faulques (Institut des Matériaux Jean Rouxel, Nantes), Dale L. Perry (University of California, Berkeley), and Andrei V. Yeremenko (Verkin Institute of Low Temperature Physics and Engineering, Kharkov, Ukraine). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xii + 414 pp. $165.00. ISBN 1-4020-2394-4. p 4542 DOI: 10.1021/ja0410136

CRC Handbook of Chemistry and Physics:  A Ready-Reference of Chemical and Physical Data, 85th ed Edited by David R. Lide (National Institute of Standards and Technology). CRC Press LLC:  Boca Raton, FL. 2004. 2712 pp. $139.99. ISBN 0-8493-0485-7. p 4542 DOI: 10.1021/ja041017a

Issue 13

Design of Optical Switches as Metabolic Indicators:  New Fluorogenic Probes for Monoamine Oxidases (MAO A and B) Gong Chen, Dominic J. Yee, Niko G. Gubernator, and Dalibor Sames pp 4544–4545 DOI: 10.1021/ja0428457 Supporting Info

Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage Shohei Tashiro, Masahide Tominaga, Masaki Kawano, Bruno Therrien, Tomoji Ozeki, and Makoto Fujita pp 4546–4547 DOI: 10.1021/ja044782y Supporting Info

Self-Assembly of Supramolecular Chiral Insulated Molecular Wire Chun Li, Munenori Numata, Ah-Hyun Bae, Kazuo Sakurai, and Seiji Shinkai pp 4548–4549 DOI: 10.1021/ja050168q Supporting Info

Reversible O−O Bond Cleavage and Formation of a Peroxo Moiety of a Peroxocarbonate Ligand Mediated by an Iron(III) Complex Hideki Furutachi, Koji Hashimoto, Shigenori Nagatomo, Taichi Endo, Shuhei Fujinami, Yoshihito Watanabe, Teizo Kitagawa, and Masatatsu Suzuki pp 4550–4551 DOI: 10.1021/ja0427202 Supporting Info

Facile C−N Cleavage in a Series of Bridged Lactams Yao Lei, Aaron D. Wrobleski, Jennifer E. Golden, Douglas R. Powell, and Jeffrey Aubé pp 4552–4553 DOI: 10.1021/ja050214m Supporting Info

Resonance Assignment of Proteins with High Shift Degeneracy Based on 5D Spectral Information Encoded in G2FT NMR Experiments Hanudatta S. Atreya, Alexander Eletsky, and Thomas Szyperski pp 4554–4555 DOI: 10.1021/ja042562e Supporting Info

Phosphine Oxide Polymer for Water-Soluble Nanoparticles Sang-Wook Kim, Sungjee Kim, Joseph B. Tracy, Alan Jasanoff, and Moungi G. Bawendi pp 4556–4557 DOI: 10.1021/ja043577f Supporting Info

Structures of E. coli Peptide Deformylase Bound to Formate:  Insight into the Preference for Fe2+ over Zn2+ as the Active Site Metal Rinku Jain, Bing Hao, Ren-peng Liu, and Michael K. Chan pp 4558–4559 DOI: 10.1021/ja0503074 Supporting Info

Competitive Decay at Two- and Three-State Conical Intersections in Excited-State Intramolecular Proton Transfer Joshua D. Coe and Todd J. Martínez pp 4560–4561 DOI: 10.1021/ja043093j Supporting Info

Unexpected Reactivities of Cu2(diphosphine)2 Complexes in Alcohol:  Isolation, X-ray Crystal Structure, and Photoluminescent Properties of a Remarkably Stable [Cu3(diphosphine)3(μ3-H)]2+ Hydride Complex Zhong Mao, Jie-Sheng Huang, Chi-Ming Che, Nianyong Zhu, Sarana Ka-Yan Leung, and Zhong-Yuan Zhou pp 4562–4563 DOI: 10.1021/ja042335c Supporting Info

Patterning Phase Separation in Polymer Films with Dip-Pen Nanolithography David C. Coffey and David S. Ginger pp 4564–4565 DOI: 10.1021/ja0428917 Supporting Info

Synthesis and Characterization of a Coordinated Oxoborane:  Lewis Acid Stabilization of a Boron−Oxygen Double Bond Dragoslav Vidovic, Jennifer A. Moore, Jamie N. Jones, and Alan H. Cowley pp 4566–4567 DOI: 10.1021/ja0507564 Supporting Info

A Heterometal Single-Molecule Magnet of [MnIII2NiII2Cl2(salpa)2] Hiroki Oshio, Masayuki Nihei, Satoshi Koizumi, Takuya Shiga, Hiroyuki Nojiri, Motohiro Nakano, Naoki Shirakawa, and Mitsuhiro Akatsu pp 4568–4569 DOI: 10.1021/ja042217p Supporting Info

Highly Extended Conformation of Polyelectrolytes Incorporated into Hybrid Threadlike Micelles Studied by Small Angle Neutron Scattering Kenji Nakamura, Toshiyuki Shikata, Nobuaki Takahashi, and Toshiji Kanaya pp 4570–4571 DOI: 10.1021/ja050642s

Visible Light Sensitive Cyclomer and Its Tautomeric Dispiro Compound Formed from Bispyridinyl Diradical Takashi Muramatsu, Azumao Toyota, and Miho Suzuki pp 4572–4573 DOI: 10.1021/ja040262r Supporting Info

Selective Growth of Si Nanowire Arrays via Galvanic Displacement Processes in Water-in-Oil Microemulsions Di Gao, Rongrui He, Carlo Carraro, Roger T. Howe, Peidong Yang, and Roya Maboudian pp 4574–4575 DOI: 10.1021/ja043645y Supporting Info

Role of Cholesterol and Polyunsaturated Chains in Lipid−Protein Interactions:  Molecular Dynamics Simulation of Rhodopsin in a Realistic Membrane Environment Michael C. Pitman, Alan Grossfield, Frank Suits, and Scott E. Feller pp 4576–4577 DOI: 10.1021/ja042715y Supporting Info

[5 + 1] Annulation:  A Synthetic Strategy for Highly Substituted Phenols and Cyclohexenones Xihe Bi, Dewen Dong, Qun Liu, Wei Pan, Lei Zhao, and Bing Li pp 4578–4579 DOI: 10.1021/ja043023c Supporting Info

Pressure-Tuning of Magnetism and Linkage Isomerism in Iron(II) Hexacyanochromate Eugenio Coronado, Mari Carmen Giménez-López, Georgiy Levchenko, Francisco M. Romero, Valentín García-Baonza, Alla Milner, and Moshe Paz-Pasternak pp 4580–4581 DOI: 10.1021/ja043166z Supporting Info

Copolymerization of Ethylene with Cyclohexene (CHE) Catalyzed by Nonbridged Half-Titanocenes Containing Aryloxo Ligand:  Notable Effect of Both Cyclopentadienyl and Anionic Donor Ligand for Efficient CHE Incorporation Wei Wang, Michiya Fujiki, and Kotohiro Nomura pp 4582–4583 DOI: 10.1021/ja050274s Supporting Info

Enantioselective Synthesis of Nitroalkanes Bearing All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions Jing Wu, Dawn M. Mampreian, and Amir H. Hoveyda pp 4584–4585 DOI: 10.1021/ja050800f Supporting Info

Biomimetic Synthesis of trans,syn,trans-Fused Polyoxepanes:  Remarkable Substituent Effects on the endo-Regioselective Oxacyclization of Polyepoxides Jason C. Valentine, Frank E. McDonald, Wade A. Neiwert, and Kenneth I. Hardcastle pp 4586–4587 DOI: 10.1021/ja050013i Supporting Info

Laser-Induced Fragmentation of Transition Metal Nanoparticles in Ionic Liquids Marcos A. Gelesky, Alexandre P. Umpierre, Giovanna Machado, Ricardo R. B. Correia, Wictor C. Magno, Jonder Morais, Gunter Ebeling, and Jairton Dupont pp 4588–4589 DOI: 10.1021/ja042711t Supporting Info

Allenyl Azide Cycloaddition Chemistry. Synthesis of Pyrrolidine-Containing Bicycles and Tricycles via the Possible Intermediacy of Azatrimethylenemethane Species Ken S. Feldman and Malliga R. Iyer pp 4590–4591 DOI: 10.1021/ja050757w Supporting Info

Pd-Catalyzed C3-Selective Allylation of Indoles with Allyl Alcohols Promoted by Triethylborane Masanari Kimura, Makoto Futamata, Ryutaro Mukai, and Yoshinao Tamaru pp 4592–4593 DOI: 10.1021/ja0501161 Supporting Info

Asymmetric Nickel-Catalyzed Negishi Cross-Couplings of Secondary α-Bromo Amides with Organozinc Reagents Christian Fischer and Gregory C. Fu pp 4594–4595 DOI: 10.1021/ja0506509 Supporting Info

Total Synthesis of Cribrostatin IV:  Fine-Tuning the Character of an Amide Bond by Remote Control Collin Chan, Richard Heid, Shengping Zheng, Jinsong Guo, Bishan Zhou, Takeshi Furuuchi, and Samuel J. Danishefsky pp 4596–4598 DOI: 10.1021/ja050203t Supporting Info

Hammett Analysis of Selective Thyroid Hormone Receptor Modulators Reveals Structural and Electronic Requirements for Hormone Antagonists Ngoc-Ha Nguyen, James W. Apriletti, John D. Baxter, and Thomas S. Scanlan pp 4599–4608 DOI: 10.1021/ja0440093 Supporting Info

Methyl Scanning:  Total Synthesis of Demethylasterriquinone B1 and Derivatives for Identification of Sites of Interaction with and Isolation of Its Receptor(s) Michael C. Pirrung, Yufa Liu, Liu Deng, Diana K. Halstead, Zhitao Li, John F. May, Michael Wedel, Darrell A. Austin, and Nicholas J. G. Webster pp 4609–4624 DOI: 10.1021/ja044325h Supporting Info

Resonance Raman and Infrared Spectroscopic Studies of High-Output Forms of Human Soluble Guanylyl Cyclase Emil Martin, Kazimierz Czarnecki, Vasanthi Jayaraman, Ferid Murad, and James Kincaid pp 4625–4631 DOI: 10.1021/ja0440912

Structure-Based Optimization of a Non-β-lactam Lead Results in Inhibitors That Do Not Up-Regulate β-Lactamase Expression in Cell Culture Donatella Tondi, Federica Morandi, Richard Bonnet, M. Paola Costi, and Brian K. Shoichet pp 4632–4639 DOI: 10.1021/ja042984o Supporting Info

Unexpected Relative Aqueous Solubilities of a Phosphotyrosine Analogue and Two Phosphonate Derivatives Stefan Boresch, Martin Leitgeb, Aleksandra Beselman, and Alexander D. MacKerell, Jr. pp 4640–4648 DOI: 10.1021/ja044935h Supporting Info

Binding Mode and Transcriptional Activation Potential of High Affinity Ligands for the CBP KIX Domain Heather M. Volkman, Stacey E. Rutledge, and Alanna Schepartz pp 4649–4658 DOI: 10.1021/ja042761y Supporting Info

RNA SHAPE Chemistry Reveals Nonhierarchical Interactions Dominate Equilibrium Structural Transitions in tRNAAsp Transcripts Kevin A. Wilkinson, Edward J. Merino, and Kevin M. Weeks pp 4659–4667 DOI: 10.1021/ja0436749

Tryptophan Side Chain Electrostatic Interactions Determine Edge-to-Face vs Parallel-Displaced Tryptophan Side Chain Geometries in the Designed β-Hairpin “trpzip2” Olgun Guvench and Charles L. Brooks III pp 4668–4674 DOI: 10.1021/ja043492e

Entropic Stabilization of Isolated β-Sheets Philippe Dugourd, Rodolphe Antoine, Gary Breaux, Michel Broyer, and Martin F. Jarrold pp 4675–4679 DOI: 10.1021/ja0437499

Discrimination of Nitroxyl and Nitric Oxide by Water-Soluble Mn(III) Porphyrins Marcelo A. Martí, Sara E. Bari, Darío A. Estrin, and Fabio Doctorovich pp 4680–4684 DOI: 10.1021/ja044632n Supporting Info

Catalysts for Suzuki−Miyaura Coupling Processes:  Scope and Studies of the Effect of Ligand Structure Timothy E. Barder, Shawn D. Walker, Joseph R. Martinelli, and Stephen L. Buchwald pp 4685–4696 DOI: 10.1021/ja042491j Supporting Info

Thermodynamic and Kinetic Control in Selective Ligand Transfer in Conjugate Addition of Mixed Organocuprate Me(X)CuLi Masahiro Yamanaka and Eiichi Nakamura pp 4697–4706 DOI: 10.1021/ja049401v Supporting Info

Eliminating Positively Charged Lysine ε-NH3+ Groups on the Surface of Carbonic Anhydrase Has No Significant Influence on Its Folding from Sodium Dodecyl Sulfate Katherine L. Gudiksen, Irina Gitlin, Jerry Yang, Adam R. Urbach, Demetri T. Moustakas, and George M. Whitesides pp 4707–4714 DOI: 10.1021/ja043804d Supporting Info

Characterization of the FKBP·Rapamycin·FRB Ternary Complex Laura A. Banaszynski, Corey W. Liu, and Thomas J. Wandless pp 4715–4721 DOI: 10.1021/ja043277y Supporting Info

Elucidating the Vibrational Spectra of Hydrogen-Bonded Aggregates in Solution:  Electronic Structure Calculations with Implicit Solvent and First-Principles Molecular Dynamics Simulations with Explicit Solvent for 1-Hexanol in n-Hexane John M. Stubbs and J. Ilja Siepmann pp 4722–4729 DOI: 10.1021/ja044380q

Multielectron Redox Chemistry of Iron Porphyrinogens Julien Bachmann and Daniel G. Nocera pp 4730–4743 DOI: 10.1021/ja043132r Supporting Info

Exciton Migration in Rigid-Rod Conjugated Polymers:  An Improved Förster Model Emmanuelle Hennebicq, Geoffrey Pourtois, Gregory D. Scholes, Laura M. Herz, David M. Russell, Carlos Silva, Sepas Setayesh, Andrew C. Grimsdale, Klaus Müllen, Jean-Luc Brédas, and David Beljonne pp 4744–4762 DOI: 10.1021/ja0488784 Supporting Info

Ruthenium-Catalyzed Cycloisomerizations of Diynols Barry M. Trost and Michael T. Rudd pp 4763–4776 DOI: 10.1021/ja043097o Supporting Info

A Dopaquinone Model That Mimics the Water Addition Step of Cofactor Biogenesis in Copper Amine Oxidases Ke-Qing Ling and Lawrence M. Sayre pp 4777–4784 DOI: 10.1021/ja0455603 Supporting Info

Highly Efficient Photoinitiation in the Cerium(III)-Catalyzed Aqueous Autoxidation of Sulfur(IV). An Example of Comprehensive Evaluation of Photoinduced Chain Reacions Ildikó Kerezsi, Gábor Lente, and István Fábián pp 4785–4793 DOI: 10.1021/ja0439120 Supporting Info

Synthesis and Reactivity of Dimeric Ar‘TlTlAr‘ and Trimeric (Ar‘ ‘Tl)3 (Ar‘, Ar‘ ‘ = Bulky Terphenyl Group) Thallium(I) Derivatives:  Tl(I)−Tl(I) Bonding in Species Ligated by Monodentate Ligands Robert J. Wright, Andrew D. Phillips, Shirley Hino, and Philip P. Power pp 4794–4799 DOI: 10.1021/ja0432259 Supporting Info

Iridium(0) Nanocluster, Acid-Assisted Catalysis of Neat Acetone Hydrogenation at Room Temperature:  Exceptional Activity, Catalyst Lifetime, and Selectivity at Complete Conversion Saim Özkar and Richard G. Finke pp 4800–4808 DOI: 10.1021/ja0437813 Supporting Info

Thermodynamics, Kinetics, and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta) Kurt F. Hirsekorn, Adam S. Veige, Michael P. Marshak, Yelena Koldobskaya, Peter T. Wolczanski, Thomas R. Cundari, and Emil B. Lobkovsky pp 4809–4830 DOI: 10.1021/ja046180k Supporting Info

Cooperative Metal−Boron Interactions in the Reaction of nido-1,2-(Cp*RuH)2B3H7, Cp* = η5-C5Me5, with HCCPh Hong Yan, Bruce C. Noll, and Thomas P. Fehlner pp 4831–4844 DOI: 10.1021/ja042439n Supporting Info

Syntheses and Properties of Two-Dimensional Charged Nonlinear Optical Chromophores Incorporating Redox-Switchable cis-Tetraammineruthenium(II) Centers Benjamin J. Coe, James A. Harris, Lathe A. Jones, Bruce S. Brunschwig, Kai Song, Koen Clays, Javier Garín, Jesús Orduna, Simon J. Coles, and Michael B. Hursthouse pp 4845–4859 DOI: 10.1021/ja0424124 Supporting Info

Superexchange and Sequential Mechanisms in Charge Transfer with a Mediating State between the Donor and Acceptor Basil Pavlatos Paulson, John R. Miller, Wei-Xing Gan, and Gerhard Closs pp 4860–4868 DOI: 10.1021/ja044946a

Reactivity of Titanium Oxo Ethoxo Cluster [Ti16O16(OEt)32]. Versatile Precursor of Nanobuilding Block-Based Hybrid Materials Giulia Fornasieri, Laurence Rozes, Stéphanie Le Calvé, Bruno Alonso, Dominique Massiot, Marie Noëlle Rager, Michel Evain, Kamal Boubekeur, and Clément Sanchez pp 4869–4878 DOI: 10.1021/ja043330i Supporting Info

Structure of and Competitive Adsorption in Alkyl Dicarbamate Two-Dimensional Crystals Kibum Kim, Katherine E. Plass, and Adam J. Matzger pp 4879–4887 DOI: 10.1021/ja043028+ Supporting Info

Evolution of Fluorescein as a Platform for Finely Tunable Fluorescence Probes Yasuteru Urano, Mako Kamiya, Kojiro Kanda, Tasuku Ueno, Kenzo Hirose, and Tetsuo Nagano pp 4888–4894 DOI: 10.1021/ja043919h

Modeling Spin Interactions in a Cyclic Trimer and a Cuboidal Co4O4 Core with Co(II) in Tetrahedral and Octahedral Environments John F. Berry, F. Albert Cotton, Chun Y. Liu, Tongbu Lu, Carlos A. Murillo, Boris S. Tsukerblat, Dino Villagrán, and Xiaoping Wang pp 4895–4902 DOI: 10.1021/ja044185b Supporting Info

Controlled Electrophoretic Patterning of Polyaniline from a Colloidal Suspension Guofeng Li, Carlos Martinez, and Steve Semancik pp 4903–4909 DOI: 10.1021/ja0441763 Supporting Info

Structure, Recognition Properties, and Flexibility of the DNA·RNA Hybrid Agnes Noy, Alberto Pérez, Manuel Márquez, F. Javier Luque, and Modesto Orozco pp 4910–4920 DOI: 10.1021/ja043293v

Zn Protein Simulations Including Charge Transfer and Local Polarization Effects Dmitri V. Sakharov and Carmay Lim pp 4921–4929 DOI: 10.1021/ja0429115

Electrocatalytic O2 Reduction at Glassy Carbon Electrodes Modified with Dendrimer-Encapsulated Pt Nanoparticles Heechang Ye and Richard M. Crooks pp 4930–4934 DOI: 10.1021/ja0435900 Supporting Info

Use of Molecular Dynamics in the Design and Structure Determination of a Photoinducible β-Hairpin Vincent Kräutler, Andreas Aemissegger, Philippe H. Hünenberger, Donald Hilvert, Tomas Hansson, and Wilfred F. van Gunsteren pp 4935–4942 DOI: 10.1021/ja044253u Supporting Info

Variable-Temperature X-ray Crystallographic and DFT Computational Study of the NH···O/N···HO Tautomeric Competition in 1-(Arylazo)-2-naphthols. Outline of a Transiton-State Hydrogen-Bond Theory Paola Gilli, Valerio Bertolasi, Loretta Pretto, Liudmil Antonov, and Gastone Gilli pp 4943–4953 DOI: 10.1021/ja0453984 Supporting Info

CH5+:  Chemistry's Chameleon Unmasked Keiran C. Thompson, Deborah L. Crittenden, and Meredith J. T. Jordan pp 4954–4958 DOI: 10.1021/ja0482280 Supporting Info

Molecular Dynamics Simulation Study on a Monolayer of Half [2]Rotaxane Self-Assembled on Au(111) Yun Hee Jang, Seung Soon Jang, and William A. Goddard, III pp 4959–4964 DOI: 10.1021/ja044762w Supporting Info

On the Mechanism of THF Catalyzed Vinylic Lithiation of Allylamine Derivatives:  Structural Studies Using 2-D and Diffusion-Ordered NMR Spectroscopy Madeleine A. Jacobson, Ivan Keresztes, and Paul G. Williard pp 4965–4975 DOI: 10.1021/ja0479540

Ion Gels Prepared by in Situ Radical Polymerization of Vinyl Monomers in an Ionic Liquid and Their Characterization as Polymer Electrolytes Md. Abu Bin Hasan Susan, Taketo Kaneko, Akihiro Noda, and Masayoshi Watanabe pp 4976–4983 DOI: 10.1021/ja045155b Supporting Info

Handbook of Detergents, Part B:  Environmental Impact. Surfactant Science Series, Volume 121 Edited by Uri Zoller (Haifa University-Oranim, Israel). Marcel Dekker:  New York. 2004. xvi + 816 pp. $175.00. ISBN 0-8247-0353-7. p 4984 DOI: 10.1021/ja0410183

Ewing's Analytical Instrumentation Handbook, 3rd Ed Edited by Jack Cazes (Florida Atlantic University). Marcel Dekker, Inc.:  New York. 2005. xxiv + 1038 pp. $249.95. ISBN 0-8247-5348-8. p 4984 DOI: 10.1021/ja041032f

Handbook of Detergents, Part C:  Analysis. Surfactant Science Series, Volume 123 Edited by Heinrich Waldhoff (Henkek KGaA, Düsseldorf, Germany) and Rüdiger Spilker (Sasol Germany GmbH, Marl, Germany). Editor-in-Chief:  Uri Zoller (Haifa University-Oranim, Israel). Marcel Dekker:  New York. 2005. xii + 654 pp. $229.95. ISBN 0-8247-0351-0. p 4984 DOI: 10.1021/ja0410340

Issue 14

Organic Field-Effect Transistors from Solution-Deposited Functionalized Acenes with Mobilities as High as 1 cm2/V·s Marcia M. Payne, Sean R. Parkin, John E. Anthony, Chung-Chen Kuo, and Thomas N. Jackson pp 4986–4987 DOI: 10.1021/ja042353u Supporting Info

Demonstration of the Elusive Concentration-Gradient Paramagnetic Force Nicholas Leventis and Amala Dass pp 4988–4989 DOI: 10.1021/ja043169b Supporting Info

Silica-Coated Nanocomposites of Magnetic Nanoparticles and Quantum Dots Dong Kee Yi, S. Tamil Selvan, Su Seong Lee, Georgia C. Papaefthymiou, Darshan Kundaliya, and Jackie Y. Ying pp 4990–4991 DOI: 10.1021/ja0428863 Supporting Info

IR Study of Cross-Strand Coupling in a β-Hairpin Peptide Using Isotopic Labels Vladimír Setnika, Rong Huang, Catherine L. Thomas, Marcus A. Etienne, Jan Kubelka, Robert P. Hammer, and Timothy A. Keiderling pp 4992–4993 DOI: 10.1021/ja043007f Supporting Info

Detection of Intermediates in Cobalt-Catalyzed Hydroformylation Using para-Hydrogen-Induced Polarization Cyril Godard, Simon B. Duckett, Stacey Polas, Robert Tooze, and Adrian C. Whitwood pp 4994–4995 DOI: 10.1021/ja0434533 Supporting Info

Direct C-Arylation of Free (NH)-Indoles and Pyrroles Catalyzed by Ar−Rh(III) Complexes Assembled In Situ Xiang Wang, Benjamin S. Lane, and Dalibor Sames pp 4996–4997 DOI: 10.1021/ja050279p Supporting Info

Selective Formation of MSi16 (M = Sc, Ti, and V) Kiichirou Koyasu, Minoru Akutsu, Masaaki Mitsui, and Atsushi Nakajima pp 4998–4999 DOI: 10.1021/ja045380t Supporting Info

Protein Biosensors Based on Biofunctionalized Conical Gold Nanotubes Zuzanna Siwy, Lacramioara Trofin, Punit Kohli, Lane A. Baker, Christina Trautmann, and Charles R. Martin pp 5000–5001 DOI: 10.1021/ja043910f Supporting Info

Pairwise Coupling in an Arg-Phe-Met Triplet Stabilizes α-Helical Peptide via Shared Rotamer Preferences Teuku M. Iqbalsyah and Andrew J. Doig pp 5002–5003 DOI: 10.1021/ja043446e

Convergent Synthesis of a Fully Lipidated Glycosylphosphatidylinositol Anchor of Plasmodium falciparum Xinyu Liu, Yong-Uk Kwon, and Peter H. Seeberger pp 5004–5005 DOI: 10.1021/ja042374o Supporting Info

Vesicle Formed by Amphiphilc Cucurbit[6]uril:  Versatile, Noncovalent Modification of the Vesicle Surface, and Multivalent Binding of Sugar-Decorated Vesicles to Lectin Hyung-Kun Lee, Kyeng Min Park, Young Jin Jeon, Dongwoo Kim, Dong Hyun Oh, Hyung Seok Kim, Chan Kyung Park, and Kimoon Kim pp 5006–5007 DOI: 10.1021/ja042172s Supporting Info

Structural and Magnetic Evidence Concerning Spin Crossover in Formamidinate Compounds with Ru25+ Cores Panagiotis Angaridis, F. Albert Cotton, Carlos A. Murillo, Dino Villagrán, and Xiaoping Wang pp 5008–5009 DOI: 10.1021/ja050828r Supporting Info

Room-Temperature Ferroelectricity and Gigantic Dielectric Susceptibility on a Supramolecular Architecture of Phenazine and Deuterated Chloranilic Acid Sachio Horiuchi, Reiji Kumai, and Yoshinori Tokura pp 5010–5011 DOI: 10.1021/ja042212s Supporting Info

Mixed-Metal Triangular Trinuclear Complexes:  Dimers of Gold−Silver Mixed-Metal Complexes from Gold(I) Carbeniates and Silver(I) 3,5-Diphenylpyrazolates Ahmed A. Mohamed, Alfredo Burini, and John P. Fackler, Jr. pp 5012–5013 DOI: 10.1021/ja0429869 Supporting Info

Decomposition of Ammonia and Hydrogen on Ir Surfaces:  Structure Sensitivity and Nanometer-Scale Size Effects Wenhua Chen, Ivan Ermanoski, and Theodore E. Madey pp 5014–5015 DOI: 10.1021/ja042617c

Chiral Attachment of Styrene Mediated by Surface Dimers on Ge(100) Yun Jeong Hwang, Ansoon Kim, Eunkyung Hwang, and Sehun Kim pp 5016–5017 DOI: 10.1021/ja050234o Supporting Info

Dual Memory of Enantiomeric Helices in a Polyacetylene Induced by a Single Enantiomer Toyoharu Miyagawa, Akira Furuko, Katsuhiro Maeda, Hiroshi Katagiri, Yoshio Furusho, and Eiji Yashima pp 5018–5019 DOI: 10.1021/ja0509634 Supporting Info

Enhanced para-Xylene Selectivity in the Toluene Alkylation Reaction at Ultralow Contact Time John Breen, Robbie Burch, Manisha Kulkarni, Paul Collier, and Stan Golunski pp 5020–5021 DOI: 10.1021/ja046421o Supporting Info

Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C−H Bonds Naofumi Tsukada and John F. Hartwig pp 5022–5023 DOI: 10.1021/ja050612p Supporting Info

UV−Vis Microspectroscopy:  Probing the Initial Stages of Supported Metal Oxide Catalyst Preparation Leon G. A. van de Water, Jaap A. Bergwerff, T. Alexander Nijhuis, Krijn P. de Jong, and Bert M. Weckhuysen pp 5024–5025 DOI: 10.1021/ja044460u Supporting Info

Nucleobase Participation in Ribozyme Catalysis Zheng-yun Zhao, Aileen McLeod, Shinya Harusawa, Lisa Araki, Maho Yamaguchi, Takushi Kurihara, and David M. J. Lilley pp 5026–5027 DOI: 10.1021/ja0502775 Supporting Info

A Tandem Carbanion Addition/Carbon−Carbon Bond Cleavage Yields Alkynyl Ketones Shin Kamijo and Gregory B. Dudley pp 5028–5029 DOI: 10.1021/ja050663m Supporting Info

A Nickel-Catalyzed Route to Pyridines Michael M. McCormick, Hung A. Duong, Gang Zuo, and Janis Louie pp 5030–5031 DOI: 10.1021/ja0508931 Supporting Info

Direct Observation of a 14-Electron Ruthenacyclobutane Relevant to Olefin Metathesis Patricio E. Romero and Warren E. Piers pp 5032–5033 DOI: 10.1021/ja042259d Supporting Info

Fast, Comprehensive Two-Dimensional HPLC Separation of Tryptic Peptides Based on High-Temperature HPLC Dwight R. Stoll and Peter W. Carr pp 5034–5035 DOI: 10.1021/ja050145b Supporting Info

Control of Nanoparticle Location in Block Copolymers Julia J. Chiu, Bumjoon J. Kim, Edward J. Kramer, and David J. Pine pp 5036–5037 DOI: 10.1021/ja050376i

Metal-Templated Diyne Cyclodimerization and Cyclotrimerization Maria Paz Martin-Redondo, Ludmila Scoles, Brian T. Sterenberg, Konstantin A. Udachin, and Arthur J. Carty pp 5038–5039 DOI: 10.1021/ja050155c Supporting Info

Highly Active, Regioselective, and Enantioselective Hydroformylation with Rh Catalysts Ligated by Bis-3,4-diazaphospholanes Thomas P. Clark, Clark R. Landis, Susan L. Freed, Jerzy Klosin, and Khalil A. Abboud pp 5040–5042 DOI: 10.1021/ja050148o Supporting Info

Localized Surface Plasmon Resonance Sensing of Lipid-Membrane-Mediated Biorecognition Events Andreas Dahlin, Michael Zäch, Tomas Rindzevicius, Mikael Käll, Duncan S. Sutherland, and Fredrik Höök pp 5043–5048 DOI: 10.1021/ja043672o

Role of Protonation and of Axial Ligands in the Reductive Dechlorination of Alkyl Chlorides by Vitamin B12 Complexes. Reductive Cleavage of Chloroacetonitrile by Co(I) Cobalamins and Cobinamides Juan E. Argüello, Cyrille Costentin, Sophie Griveau, and Jean-Michel Savéant pp 5049–5055 DOI: 10.1021/ja042940f

Deoxythreosyl Phosphonate Nucleosides as Selective Anti-HIV Agents Tongfei Wu, Matheus Froeyen, Veerle Kempeneers, Christophe Pannecouque, Jing Wang, Roger Busson, Erik De Clercq, and Piet Herdewijn pp 5056–5065 DOI: 10.1021/ja043045z

An 15N NMR Spin Relaxation Dispersion Study of the Folding of a Pair of Engineered Mutants of Apocytochrome b562 Wing-Yiu Choy, Zheng Zhou, Yawen Bai, and Lewis E. Kay pp 5066–5072 DOI: 10.1021/ja042560u

Highly Enantioselective Phase-Transfer-Catalyzed Alkylation of Protected α-Amino Acid Amides toward Practical Asymmetric Synthesis of Vicinal Diamines, α-Amino Ketones, and α-Amino Alcohols Takashi Ooi, Mifune Takeuchi, Daisuke Kato, Yukitaka Uematsu, Eiji Tayama, Daiki Sakai, and Keiji Maruoka pp 5073–5083 DOI: 10.1021/ja0459328 Supporting Info

Di- and Trivalent Organogermanium Reactive Intermediates. Kinetics and Mechanisms of Some Reactions of Diphenylgermylene and Tetraphenyldigermene in Solution William J. Leigh and Cameron R. Harrington pp 5084–5096 DOI: 10.1021/ja043072p Supporting Info

Dendrimer-Encapsulated Pd Nanoparticles as Aqueous, Room-Temperature Catalysts for the Stille Reaction Joaquin C. Garcia-Martinez, Raphael Lezutekong, and Richard M. Crooks pp 5097–5103 DOI: 10.1021/ja042479r Supporting Info

New Insights into the Interactions of Serum Proteins with Bis(maltolato)oxovanadium(IV):  Transport and Biotransformation of Insulin-Enhancing Vanadium Pharmaceuticals Barry D. Liboiron, Katherine H. Thompson, Graeme R. Hanson, Edmond Lam, Nicolas Aebischer, and Chris Orvig pp 5104–5115 DOI: 10.1021/ja043944n Supporting Info

Poisoning of Heterogeneous, Late Transition Metal Dehydrocoupling Catalysts by Boranes and Other Group 13 Hydrides Cory A. Jaska, Timothy J. Clark, Scott B. Clendenning, Dan Grozea, Ayse Turak, Zheng-Hong Lu, and Ian Manners pp 5116–5124 DOI: 10.1021/ja0447412 Supporting Info

Effect of SOCl2 Treatment on Electrical and Mechanical Properties of Single-Wall Carbon Nanotube Networks Urszula Dettlaff-Weglikowska, Viera Skákalová, Ralf Graupner, Sung Ho Jhang, Byung Hoon Kim, Hyun Jung Lee, Lothar Ley, Yung Woo Park, Savas Berber, David Tománek, and Siegmar Roth pp 5125–5131 DOI: 10.1021/ja046685a

Reactions of Vinyl Acetate and Vinyl Trifluoroacetate with Cationic Diimine Pd(II) and Ni(II) Alkyl Complexes:  Identification of Problems Connected with Copolymerizations of These Monomers with Ethylene B. Scott Williams, Mark D. Leatherman, Peter S. White, and Maurice Brookhart pp 5132–5146 DOI: 10.1021/ja045969s Supporting Info

Rigid MIIL2Gd2III (M = Fe, Ru) Complexes of a Terpyridine-Based Heteroditopic Chelate:  A Class of Candidates for MRI Contrast Agents Jérôme Costa, Robert Ruloff, László Burai, Lothar Helm, and André E. Merbach pp 5147–5157 DOI: 10.1021/ja0424169 Supporting Info

Dye Sensitization of the Anatase (101) Crystal Surface by a Series of Dicarboxylated Thiacyanine Dyes S. Ushiroda, N. Ruzycki, Y. Lu, M. T. Spitler, and B. A. Parkinson pp 5158–5168 DOI: 10.1021/ja044001t

Luminescent Ruthenium(II)− and Rhenium(I)−Diimine Wires Bind Nitric Oxide Synthase Alexander R. Dunn, Wendy Belliston-Bittner, Jay R. Winkler, Elizabeth D. Getzoff, Dennis J. Stuehr, and Harry B. Gray pp 5169–5173 DOI: 10.1021/ja046971m Supporting Info

Theoretical Study on the Inhibition of Ribonucleotide Reductase by 2‘-Mercapto-2‘-deoxyribonucleoside-5‘-diphosphates Susana Pereira, Pedro Alexandrino Fernandes, and Maria João Ramos pp 5174–5179 DOI: 10.1021/ja046662w Supporting Info

Anisotropic Local Motions and Location of Amide Protons in Proteins Dimitri Bytchenkoff, Philippe Pelupessy, and Geoffrey Bodenhausen pp 5180–5185 DOI: 10.1021/ja043575v Supporting Info

Potentiometric, Electronic Structural, and Ground- and Excited-State Optical Properties of Conjugated Bis[(Porphinato)zinc(II)] Compounds Featuring Proquinoidal Spacer Units Kimihiro Susumu, Timothy V. Duncan, and Michael J. Therien pp 5186–5195 DOI: 10.1021/ja040243h Supporting Info

A Diameter-Selective Attack of Metallic Carbon Nanotubes by Nitronium Ions Kay Hyeok An, Jin Sung Park, Cheol-Min Yang, Seung Yol Jeong, Seong Chu Lim, Chul Kang, Joo-Hiuk Son, Mun Seok Jeong, and Young Hee Lee pp 5196–5203 DOI: 10.1021/ja0428199

Reactions of d0 Group 4 Amides with Dioxygen. Preparation of Unusual Oxo Aminoxy Complexes and Theoretical Studies of Their Formation Ruitao Wang, Xin-Hao Zhang, Shu-Jian Chen, Xianghua Yu, Chang-Sheng Wang, David B. Beach, Yun-Dong Wu, and Zi-Ling Xue pp 5204–5211 DOI: 10.1021/ja042307u Supporting Info

Synthesis and Reactivity of a (μ-1,1-Hydroperoxo)(μ-hydroxo)dicopper(II) Complex:  Ligand Hydroxylation by a Bridging Hydroperoxo Ligand Kyosuke Itoh, Hideki Hayashi, Hideki Furutachi, Takahiro Matsumoto, Shigenori Nagatomo, Takehiko Tosha, Shoichi Terada, Shuhei Fujinami, Masatatsu Suzuki, and Teizo Kitagawa pp 5212–5223 DOI: 10.1021/ja047437h Supporting Info

The Final Catalytic Step of Cytochrome P450 Aromatase:  A Density Functional Theory Study John C Hackett, Robert W. Brueggemeier, and Christopher M. Hadad pp 5224–5237 DOI: 10.1021/ja044716w Supporting Info

Anhydrous and Water-Assisted Proton Mobility in Phosphotungstic Acid Michael J. Janik, Robert J. Davis, and Matthew Neurock pp 5238–5245 DOI: 10.1021/ja042742o Supporting Info

Temperature Dependence of Quantum Effects in Liquid Water Lisandro Hernández de la Peña and Peter G. Kusalik pp 5246–5251 DOI: 10.1021/ja0424676

Oxygen Electroreduction through a Superoxide Intermediate on Bi-Modified Au Surfaces Xiao Li and Andrew A. Gewirth pp 5252–5260 DOI: 10.1021/ja043170a Supporting Info

Glutathione-Protected Gold Clusters Revisited:  Bridging the Gap between Gold(I)−Thiolate Complexes and Thiolate-Protected Gold Nanocrystals Yuichi Negishi, Katsuyuki Nobusada, and Tatsuya Tsukuda pp 5261–5270 DOI: 10.1021/ja042218h Supporting Info

Cinchona Alkaloid/Sulfinyl Chloride Combinations:  Enantioselective Sulfinylating Agents of Alcohols [J. Am. Chem. Soc. 2005, 127, 1374−1375]. Norio Shibata, Mitsuharu Matsunaga, Masaya Nakagawa, Takeo Fukuzumi, Shuichi Nakamura, and Takeshi Toru p 5271 DOI: 10.1021/ja051008h

Chiral Photochemistry. Molecular and Supramolecular Photochemistry, Volume 11 Edited by Yoshihisa Inoue (Osaka University) and Vaidhyanathan Ramamurthy (Tulane University). Marcel Dekker:  New York. 2004. xii + 686 pp. $185.00. ISBN 0-8247-5710-6. Nicholas J. Turro p 5272 DOI: 10.1021/ja0409917

Handbook of Biotransformations of Aromatic Compounds By Brian L. Goodwin (retired). CRC Press LLC:  Boca Raton, FL. 2005. 2128 pp. $450.00. ISBN 0-415-27176-2. p 5272 DOI: 10.1021/ja041055u

Issue 15

Virus Crystals as Nanocomposite Scaffolds Joshua C. Falkner, Mary E. Turner, Joan K. Bosworth, Timothy J. Trentler, John E. Johnson, Tianwei Lin, and Vicki L. Colvin pp 5274–5275 DOI: 10.1021/ja044496m Supporting Info

Study of Quasi-Monodisperse In2O3 Nanocrystals:  Synthesis and Optical Determination Qingsheng Liu, Weigang Lu, Aihui Ma, Jinke Tang, Jun Lin, and Jiye Fang pp 5276–5277 DOI: 10.1021/ja042550t Supporting Info

Hangman Salophens Shih-Yuan Liu and Daniel G. Nocera pp 5278–5279 DOI: 10.1021/ja042849b Supporting Info

Electrochemical Behavior of the Tris(pyridine)−Cu Funnel Complexes: An Overall Induced-Fit Process Involving an Entatic State through a Supramolecular Stress Nicolas Le Poul, Morgan Campion, Guillaume Izzet, Bénédicte Douziech, Olivia Reinaud, and Yves Le Mest pp 5280–5281 DOI: 10.1021/ja043073h Supporting Info

Intramolecular C−H/C−D Exchange in Cofacially Stacked Polyfluorenes via Electron-Induced Bond Activation Cheryl D. Stevenson, Matthew K. Kiesewetter, Richard C. Reiter, Sameh H. Abdelwahed, and Rajendra Rathore pp 5282–5283 DOI: 10.1021/ja0432261

Selective and Catalytic Arylation of N-Phenylpyrrolidine:  sp3 C−H Bond Functionalization in the Absence of a Directing Group Bengü Sezen and Dalibor Sames pp 5284–5285 DOI: 10.1021/ja050269o Supporting Info

Na5(In4S)(InS4)3·6H2O, a Zeolite-like Structure with Unusual SIn4 Tetrahedra Nanfeng Zheng, Xianhui Bu, and Pingyun Feng pp 5286–5287 DOI: 10.1021/ja050281g Supporting Info

Bio-orthogonal Affinity Purification of Direct Kinase Substrates Jasmina J. Allen, Scott E. Lazerwith, and Kevan M. Shokat pp 5288–5289 DOI: 10.1021/ja050727t Supporting Info

Unusually Short RNA Sequences:  Design of a 13-mer RNA that Selectively Binds and Recognizes Theophylline Peter C. Anderson and Sandro Mecozzi pp 5290–5291 DOI: 10.1021/ja0432463 Supporting Info

Activation of High-TC Ferromagnetism in Mn2+-Doped ZnO using Amines Kevin R. Kittilstved and Daniel R. Gamelin pp 5292–5293 DOI: 10.1021/ja050723o Supporting Info

Template-Free Directional Growth of Single-Walled Carbon Nanotubes on a- and r-Plane Sapphire Song Han, Xiaolei Liu, and Chongwu Zhou pp 5294–5295 DOI: 10.1021/ja042544x Supporting Info

Photoswitchable Orientational Patterns of Confined Domains in Monolayers Francesc Sagués, Rosa Albalat, Ramon Reigada, Joaquim Crusats, Jordi Ignés-Mullol, and Josep Claret pp 5296–5297 DOI: 10.1021/ja0502066 Supporting Info

Chemical Confirmation of a Pentavalent Phosphorane in Complex with β-Phosphoglucomutase Lee W. Tremblay, Guofeng Zhang, Jianying Dai, Debra Dunaway-Mariano, and Karen N. Allen pp 5298–5299 DOI: 10.1021/ja0509073 Supporting Info

Doubly Catalytic Sensing of HIV-1-Related CCR5 Sequence in Prokaryotic Cell-Free Translation System using Riboregulator-Controlled Luciferase Activity Shinsuke Sando, Atsushi Narita, Kenji Abe, and Yasuhiro Aoyama pp 5300–5301 DOI: 10.1021/ja0507057 Supporting Info

Imaging of Tautomerism in a Single Molecule Hubert Piwoński, Clemens Stupperich, Achim Hartschuh, Jerzy Sepioł, Alfred Meixner, and Jacek Waluk pp 5302–5303 DOI: 10.1021/ja043265c Supporting Info

Size-Selected (2−10 nm) Gold Nanoparticles for Matrix Assisted Laser Desorption Ionization of Peptides John A. McLean, Katherine A. Stumpo, and David H. Russell pp 5304–5305 DOI: 10.1021/ja043907w

Recognition of Single Nucleotide Polymorphisms using Scanning Potential Hairpin Denaturation Fang Wei, Chunlai Chen, Lin Zhai, Ning Zhang, and Xin Sheng Zhao pp 5306–5307 DOI: 10.1021/ja043661v Supporting Info

Biomimetic Hydrogen Evolution:  MoS2 Nanoparticles as Catalyst for Hydrogen Evolution Berit Hinnemann, Poul Georg Moses, Jacob Bonde, Kristina P. Jørgensen, Jane H. Nielsen, Sebastian Horch, Ib Chorkendorff, and Jens K. Nørskov pp 5308–5309 DOI: 10.1021/ja0504690 Supporting Info

Validation of the Binding Site Structure of the Cellular Retinol-Binding Protein (CRBP) by Ligand NMR Chemical Shift Perturbations Bing Wang and Kenneth M. Merz Jr. pp 5310–5311 DOI: 10.1021/ja042616k

Observation of a Quadrupole Plasmon Mode for a Colloidal Solution of Gold Nanoprisms Jill E. Millstone, Sungho Park, Kevin L. Shuford, Lidong Qin, George C. Schatz, and Chad A. Mirkin pp 5312–5313 DOI: 10.1021/ja043245a Supporting Info

Chelate and Pincer Carbene Complexes of Rhodium and Platinum Derived from Hexaphenylcarbodiphosphorane, Ph3PCPPh3 Kazuyuki Kubo, Nathan D. Jones, Michael J. Ferguson, Robert McDonald, and Ronald G. Cavell pp 5314–5315 DOI: 10.1021/ja0502831 Supporting Info

Synthesis of CoPt Nanorods in Ionic Liquids Yong Wang and Hong Yang pp 5316–5317 DOI: 10.1021/ja043625w Supporting Info

Highly Selective Optical Fluoride Ion Sensor with Submicromolar Detection Limit Based on Aluminum(III) Octaethylporphyrin in Thin Polymeric Film Ibrahim H. A. Badr and Mark E. Meyerhoff pp 5318–5319 DOI: 10.1021/ja0500153 Supporting Info

Rhodopsin Reconstituted into a Planar-Supported Lipid Bilayer Retains Photoactivity after Cross-Linking Polymerization of Lipid Monomers Varuni Subramaniam, Isabel D. Alves, Gilmar F. J. Salgado, Pick-Wei Lau, Ronald J. Wysocki, Jr., Zdzislaw Salamon, Gordon Tollin, Victor J. Hruby, Michael F. Brown, and S. Scott Saavedra pp 5320–5321 DOI: 10.1021/ja0423973 Supporting Info

Structural Evidence that Alkoxy Substituents Adopt Electronically Preferred Pseudoaxial Orientations in Six-Membered Ring Dioxocarbenium Ions Stephen Chamberland, Joseph W. Ziller, and K. A. Woerpel pp 5322–5323 DOI: 10.1021/ja050830i Supporting Info

Photochemical Myers−Saito and C2−C6 Cyclizations of Enyne−Allenes:  Direct Detection of Intermediates in Solution Michael Schmittel, Atul A. Mahajan, and Götz Bucher pp 5324–5325 DOI: 10.1021/ja044890k Supporting Info

A Comparison between Multibubble Sonoluminescence Intensity and the Temperature within Cavitation Bubbles Muthupandian Ashokkumar and Franz Grieser pp 5326–5327 DOI: 10.1021/ja050804k

Supramolecular Control of Valence-Tautomeric Equilibrium on Nanometer-Scale Gold Clusters Sofi Bin-Salamon, Scott Brewer, Stefan Franzen, Daniel L. Feldheim, Simon Lappi, and David A. Shultz pp 5328–5329 DOI: 10.1021/ja042520q Supporting Info

A Facile Approach to a d4 RuN:  Moiety Amy Walstrom, Maren Pink, Xiaofan Yang, John Tomaszewski, Mu-Hyun Baik, and Kenneth G. Caulton pp 5330–5331 DOI: 10.1021/ja050361k Supporting Info

Biosynthesis of Phloroglucinol Jihane Achkar, Mo Xian, Huimin Zhao, and J. W. Frost pp 5332–5333 DOI: 10.1021/ja042340g Supporting Info

Total Synthesis of (+)-Cyanthiwigin U Matthew W. B. Pfeiffer and Andrew J. Phillips pp 5334–5335 DOI: 10.1021/ja0509836 Supporting Info

High Performance n-Type Organic Field-Effect Transistors Based on π-Electronic Systems with Trifluoromethylphenyl Groups Shinji Ando, Jun-ichi Nishida, Hirokazu Tada, Youji Inoue, Shizuo Tokito, and Yoshiro Yamashita pp 5336–5337 DOI: 10.1021/ja042219+ Supporting Info

Electrostatic Manipulation of Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate within γ-Cyclodextrin Cavity through Chemical Modification. Inverted Product Distribution and Enhanced Enantioselectivity Asao Nakamura and Yoshihisa Inoue pp 5338–5339 DOI: 10.1021/ja050704e Supporting Info

The Direct Acyl-Alkylation of Arynes Uttam K. Tambar and Brian M. Stoltz pp 5340–5341 DOI: 10.1021/ja050859m Supporting Info

Enantioselective Synthesis of Stephacidin B Seth B. Herzon and Andrew G. Myers pp 5342–5344 DOI: 10.1021/ja0510616 Supporting Info

Prosthetic Heme Modification during Halide Ion Oxidation. Demonstration of Chloride Oxidation by Horseradish Peroxidase Liusheng Huang, Grzegorz Wojciechowski, and Paul R. Ortiz de Montellano pp 5345–5353 DOI: 10.1021/ja050278x

Single-Molecule Tracing on a Fluidic Microchip for Quantitative Detection of Low-Abundance Nucleic Acids Tza-Huei Wang, Yahui Peng, Chunyang Zhang, Pak Kin Wong, and Chih-Ming Ho pp 5354–5359 DOI: 10.1021/ja042642i Supporting Info

Mechanistic Studies on the Binding of Nitric Oxide to a Synthetic Heme−Thiolate Complex Relevant to Cytochrome P450 Alicja Franke, Grażyna Stochel, Noriyuki Suzuki, Tsunehiko Higuchi, Kimiko Okuzono, and Rudi van Eldik pp 5360–5375 DOI: 10.1021/ja047572u Supporting Info

Succinct Synthesis of β-Amino Acids via Chiral Isoxazolines Amelia A. Fuller, Bin Chen, Aaron R. Minter, and Anna K. Mapp pp 5376–5383 DOI: 10.1021/ja0431713 Supporting Info

Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion Do Hyun Ryu and E. J. Corey pp 5384–5387 DOI: 10.1021/ja050543e Supporting Info

Chemistry of the Diazeniumdiolates:  Z E Isomerism Yan-Ni Wang, D. Scott Bohle, Challice L. Bonifant, Gwendolyn N. Chmurny, Jack R. Collins, Keith M. Davies, Jeffrey Deschamps, Judith L. Flippen-Anderson, Larry K. Keefer, John R. Klose, Joseph E. Saavedra, David J. Waterhouse, and Joseph Ivanic pp 5388–5395 DOI: 10.1021/ja042258l Supporting Info

Ruthenium(salen)-Catalyzed Aerobic Oxidative Desymmetrization of meso-Diols and Its Kinetics Hideki Shimizu, Satoaki Onitsuka, Hiromichi Egami, and Tsutomu Katsuki pp 5396–5413 DOI: 10.1021/ja047608i

Dependence of Transition State Structure on Substrate:  The Intrinsic C-13 Kinetic Isotope Effect Is Different for Physiological and Slow Substrates of the Ornithine Decarboxylase Reaction Because of Different Hydrogen Bonding Structures Daria Sicinska, Donald G. Truhlar, and Piotr Paneth pp 5414–5422 DOI: 10.1021/ja042298p Supporting Info

Structure, Function, and Inhibition along the Reaction Coordinate of CTX-M β-Lactamases Yu Chen, Brian Shoichet, and Richard Bonnet pp 5423–5434 DOI: 10.1021/ja042850a

Glycopeptides Related to β-Endorphin Adopt Helical Amphipathic Conformations in the Presence of Lipid Bilayers Muthu Dhanasekaran, Michael M. Palian, Isabel Alves, Larisa Yeomans, Charles M. Keyari, Peg Davis, Edward J. Bilsky, Richard D. Egleton, Henry I. Yamamura, Neil E. Jacobsen, Gordon Tollin, Victor J. Hruby, Frank Porreca, and Robin Polt pp 5435–5448 DOI: 10.1021/ja0432158 Supporting Info

Spectroscopic and Computational Studies of Ni Superoxide Dismutase:  Electronic Structure Contributions to Enzymatic Function Adam T. Fiedler, Peter A. Bryngelson, Michael J. Maroney, and Thomas C. Brunold pp 5449–5462 DOI: 10.1021/ja042521i Supporting Info

Terephthalamide Derivatives as Mimetics of Helical Peptides:  Disruption of the Bcl-xL/Bak Interaction Hang Yin, Gui-in Lee, Kristine A. Sedey, Johanna M. Rodriguez, Hong-Gang Wang, Said M. Sebti, and Andrew D. Hamilton pp 5463–5468 DOI: 10.1021/ja0446404 Supporting Info

Substrate Oxidation by Copper−Dioxygen Adducts:  Mechanistic Considerations Jason Shearer, Christiana Xin Zhang, Lev N. Zakharov, Arnold L. Rheingold, and Kenneth D. Karlin pp 5469–5483 DOI: 10.1021/ja045191a Supporting Info

Spin-Crossover Dendrimers:  Generation Number-Dependent Cooperativity for Thermal Spin Transition Tsuyohiko Fujigaya, Dong-Lin Jiang, and Takuzo Aida pp 5484–5489 DOI: 10.1021/ja050275k

“Majority-Rules” Operative in Chiral Columnar Stacks of C3-Symmetrical Molecules Jeroen van Gestel, Anja R. A. Palmans, Bram Titulaer, Jef A. J. M. Vekemans, and E. W. Meijer pp 5490–5494 DOI: 10.1021/ja0501666

Copper(I) 1,2,4-Triazolates and Related Complexes:  Studies of the Solvothermal Ligand Reactions, Network Topologies, and Photoluminescence Properties Jie-Peng Zhang, Yan-Yong Lin, Xiao-Chun Huang, and Xiao-Ming Chen pp 5495–5506 DOI: 10.1021/ja042222t Supporting Info

Stepwise and Dramatic Enhancement of Anion Recognition with a Triple-Site Receptor Based on the Calix[4]arene Framework Using Two Different Cationic Effectors Tatsuya Nabeshima, Toshiyuki Saiki, Jun Iwabuchi, and Shigehisa Akine pp 5507–5511 DOI: 10.1021/ja042882y Supporting Info

Crystalline Polymorph Selection and Discovery with Polymer Heteronuclei Christopher P. Price, Adam L. Grzesiak, and Adam J. Matzger pp 5512–5517 DOI: 10.1021/ja042561m Supporting Info

Stereochemistry of Hexenyl Radical Cyclizations with tert-Butyl and Related Large Groups:  Substituent and Temperature Effects Jonathan C. Tripp, Carl H. Schiesser, and Dennis P. Curran pp 5518–5527 DOI: 10.1021/ja042595u Supporting Info

Scandium(III) Catalysis of Transimination Reactions. Independent and Constitutionally Coupled Reversible Processes Nicolas Giuseppone, Jean-Louis Schmitt, Evan Schwartz, and Jean-Marie Lehn pp 5528–5539 DOI: 10.1021/ja042469q

Kinetic Stabilization of an Oligomeric Protein by a Single Ligand Binding Event R. Luke Wiseman, Steven M. Johnson, Matthew S. Kelker, Ted Foss, Ian A. Wilson, and Jeffery W. Kelly pp 5540–5551 DOI: 10.1021/ja042929f Supporting Info

Role of Conformation and Electronic Structure in the Chemistry of Ground and Excited State o-Pyrazolylphenylnitrenes Claudio Carra, Thomas Bally, and Angelo Albini pp 5552–5562 DOI: 10.1021/ja043988w Supporting Info

Superacidifiers: Assessing the Activation and the Mode of Charge Transmission of the Extraordinary Electron-Withdrawing SO2CF3 and S(O)(NSO2CF3)CF3 Substituents in Carbanion Stabilization François Terrier, Emmanuel Magnier, Elyane Kizilian, Claude Wakselman, and Erwin Buncel pp 5563–5571 DOI: 10.1021/ja0436291 Supporting Info

Studies of an Enneanuclear Manganese Single-Molecule Magnet Stergios Piligkos, Gopalan Rajaraman, Monica Soler, Nadeschda Kirchner, Joris van Slageren, Roland Bircher, Simon Parsons, Hans-Ulrich Güdel, Jens Kortus, Wolfgang Wernsdorfer, George Christou, and Euan K. Brechin pp 5572–5580 DOI: 10.1021/ja042302x Supporting Info

The Influence of Sequence Context and Length on the Kinetics of DNA Duplex Formation from Complementary Hairpins Possessing (CNG) Repeats Anthony M. Paiva and Richard D. Sheardy pp 5581–5585 DOI: 10.1021/ja043783n Supporting Info

Poly-p-phenylene Phosphine/Polyaniline Alternating Copolymers:  Electronic Delocalization through Phosphorus Zhou Jin and Brett L. Lucht pp 5586–5595 DOI: 10.1021/ja043358u Supporting Info

Crotylsilane Reagents in the Synthesis of Complex Polyketide Natural Products:  Total Synthesis of (+)-Discodermolide Alexander Arefolov and James S. Panek pp 5596–5603 DOI: 10.1021/ja043168j Supporting Info

Catalytic Enantioselective Construction of All-Carbon Quaternary Stereocenters:  Synthetic and Mechanistic Studies of the C-Acylation of Silyl Ketene Acetals Ara H. Mermerian and Gregory C. Fu pp 5604–5607 DOI: 10.1021/ja043832w Supporting Info

A General Nonaqueous Route to Binary Metal Oxide Nanocrystals Involving a C−C Bond Cleavage Nicola Pinna, Georg Garnweitner, Markus Antonietti, and Markus Niederberger pp 5608–5612 DOI: 10.1021/ja042323r

MOCVD-Derived Highly Transparent, Conductive Zinc- and Tin-Doped Indium Oxide Thin Films:  Precursor Synthesis, Metastable Phase Film Growth and Characterization, and Application as Anodes in Polymer Light-Emitting Diodes Jun Ni, He Yan, Anchuang Wang, Yu Yang, Charlotte L. Stern, Andrew W. Metz, Shu Jin, Lian Wang, Tobin J. Marks, John R. Ireland, and Carl R. Kannewurf pp 5613–5624 DOI: 10.1021/ja044643g Supporting Info

Cobalt(III) Corroles as Electrocatalysts for the Reduction of Dioxygen:  Reactivity of a Monocorrole, Biscorroles, and Porphyrin−Corrole Dyads Karl M. Kadish, Laurent Frémond, Zhongping Ou, Jianguo Shao, Chunnian Shi, Fred C. Anson, Fabien Burdet, Claude P. Gros, Jean-Michel Barbe, and Roger Guilard pp 5625–5631 DOI: 10.1021/ja0501060

Determination of the Temperature Dependence of the H−D Spin−Spin Coupling Constant and the Isotope Effect on the Proton Chemical Shift for the Compressed Dihydride Complex [Cp*Ir(P−P)H2]2+ Ricard Gelabert, Miquel Moreno, José M. Lluch, Agustí Lledós, and D. Michael Heinekey pp 5632–5640 DOI: 10.1021/ja043011r

Redox-Noninnocence of the S,S‘-Coordinated Ligands in Bis(benzene-1,2-dithiolato)iron Complexes Kallol Ray, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 5641–5654 DOI: 10.1021/ja040237l Supporting Info

Reversible Enolization of β-Amino Carboxamides by Lithium Hexamethyldisilazide Anne J. McNeil and David B. Collum pp 5655–5661 DOI: 10.1021/ja043470s Supporting Info

Synthesis of Quantum-Sized Cubic ZnS Nanorods by the Oriented Attachment Mechanism Jung Ho Yu, Jin Joo, Hyun Min Park, Sung-Il Baik, Young Woon Kim, Sung Chul Kim, and Taeghwan Hyeon pp 5662–5670 DOI: 10.1021/ja044593f Supporting Info

Unexpected Behavior of the Surface Composition of PtRh Alloys during Chemical Reaction Alessandro Baraldi, Dario Giacomello, Luca Rumiz, Mauro Moretuzzo, Silvano Lizzit, Francesco Buatier de Mongeot, Giorgio Paolucci, Giovanni Comelli, Renzo Rosei, Bernard E. Nieuwenhuys, Ugo Valbusa, and Maya P. Kiskinova pp 5671–5674 DOI: 10.1021/ja044372+

Electronic Configuration Assignment and the Importance of Low-Lying Excited States in High-Spin Imidazole-Ligated Iron(II) Porphyrinates Chuanjiang Hu, Arne Roth, Mary K. Ellison, Jin An, Christina M. Ellis, Charles E. Schulz, and W. Robert Scheidt pp 5675–5688 DOI: 10.1021/ja044077p Supporting Info

Functionalization of Thioctic Acid-Capped Gold Nanoparticles for Specific Immobilization of Histidine-Tagged Proteins José M. Abad, Stijn F. L. Mertens, Marcos Pita, Victor M. Fernández, and David J. Schiffrin pp 5689–5694 DOI: 10.1021/ja042717i Supporting Info

Colorimetric Molecularly Imprinted Polymer Sensor Array using Dye Displacement Nathaniel T. Greene and Ken D. Shimizu pp 5695–5700 DOI: 10.1021/ja0468022

Evidence for d Orbital Aromaticity in Square Planar Coinage Metal Clusters Chaitanya S. Wannere, Clémence Corminboeuf, Zhi-Xiang Wang, Matthew D. Wodrich, R. Bruce King, and Paul v. R. Schleyer pp 5701–5705 DOI: 10.1021/ja042716q Supporting Info

Cross Surface Ambipolar Charge Percolation in Molecular Triads on Mesoscopic Oxide Films Qing Wang, Shaik M. Zakeeruddin, Jens Cremer, Peter Bäuerle, Robin Humphry-Baker, and Michael Grätzel pp 5706–5713 DOI: 10.1021/ja0426701 Supporting Info

Diffusion Measurements for Molecular Capsules:  Pulse Sequences Effect on Water Signal Decay Liat Avram and Yoram Cohen pp 5714–5719 DOI: 10.1021/ja043985j

Systematic Control of Photochemistry:  The Dynamics of Photoisomerization of a Model Cyanine Dye Patricia A. Hunt and Michael A. Robb pp 5720–5726 DOI: 10.1021/ja045652s Supporting Info

Recognition of Duplex RNA by Helix-Threading Peptides [J. Am. Chem. Soc. 2004, 126, 10603−10610]. Barry D. Gooch and Peter A. Beal p 5727 DOI: 10.1021/ja0515304

A Stereodivergent Approach to Chiral Non-Racemic N−Protected α,α-Dialkylated Amino Acids [J. Am. Chem. Soc. 2003, 125, 12106−12107]. Claude Spino,* and Cédrickx Godbout p 5727 DOI: 10.1021/ja0515654

Oxygen Isotope Effects on Electron Transfer to O2 Probed Using Chemically Modified Flavins Bound to Glucose Oxidase [J. Am. Chem. Soc. 2004, 126, 15120−15131]. Justine P. Roth, Roseanne Wincek, Gabrielle Nodet, Dale E. Edmondson, William S. McIntire, and Judith P. Klinman p 5727 DOI: 10.1021/ja059904g

Metal-Polymer Nanocomposites Edited by Luigi Nicolais and Gianfranco Carotenuto (National Research Council, Naples, Italy). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xiv + 300 pp. $99.95. ISBN 0-471-47131-3. P. Gregory Van Patten p 5728 DOI: 10.1021/ja041000s

Issue 16

One-Step Synthesis of Core(Cr)/Shell(γ-Fe2O3) Nanoparticles Jriuan Lai, Kurikka V. P. M. Shafi, Abraham Ulman, Katja Loos, Ronit Popovitz-Biro, Yongjae Lee, Thomas Vogt, and Claude Estournès pp 5730–5731 DOI: 10.1021/ja0443225 Supporting Info

Nanoscale Size Effect of Magnetic Nanocrystals and Their Utilization for Cancer Diagnosis via Magnetic Resonance Imaging Young-wook Jun, Yong-Min Huh, Jin-sil Choi, Jae-Hyun Lee, Ho-Taek Song, Sungjun Kim, Sungjun Kim, Sarah Yoon, Kyung-Sup Kim, Jeon-Soo Shin, Jin-Suck Suh, and Jinwoo Cheon pp 5732–5733 DOI: 10.1021/ja0422155 Supporting Info

Selective Interface Detection:  Mapping Binding Site Contacts in Membrane Proteins by NMR Spectroscopy Suzanne R. Kiihne, Alain F. L. Creemers, Willem J. de Grip, Petra H. M. Bovee-Geurts, Johan Lugtenburg, and Huub J. M. de Groot pp 5734–5735 DOI: 10.1021/ja045677r Supporting Info

Optically Addressed Droplet-Based Protein Assay Kenneth T. Kotz, Yu Gu, and Gregory W. Faris pp 5736–5737 DOI: 10.1021/ja050249m Supporting Info

Anion Directed Synthesis of Paddlane and Trisilver Tweezer Complexes Based upon Silver Coordination Chemistry Paul D. Custer, Jered C. Garrison, Claire A. Tessier, and Wiley J. Youngs pp 5738–5739 DOI: 10.1021/ja050154k Supporting Info

Stereochemically Stable Double-Helicate Dinuclear Complexes of Bis(dipyrromethene)s:  A Chiroptical Study Tabitha E. Wood, Nathan D. Dalgleish, Erin D. Power, Alison Thompson, Xiaoming Chen, and Yoshio Okamoto pp 5740–5741 DOI: 10.1021/ja0500613 Supporting Info

Electrostatic versus Steric Effects in Peptidomimicry:  Synthesis and Secondary Structure Analysis of Gramicidin S Analogues with (E)-Alkene Peptide Isosteres Jingbo Xiao, Bernard Weisblum, and Peter Wipf pp 5742–5743 DOI: 10.1021/ja051002s Supporting Info

Chelating Ligand Alters the Microscopic Mechanism of Mineral Dissolution Thomas D. Perry, IV, Owen W. Duckworth, Treavor A. Kendall, Scot T. Martin, and Ralph Mitchell pp 5744–5745 DOI: 10.1021/ja042737k Supporting Info

Indolactam-V Is Involved in the CH/π Interaction with Pro-11 of the PKCδ C1B Domain:  Application for the Structural Optimization of the PKCδ Ligand Yu Nakagawa, Kazuhiro Irie, Ryo C. Yanagita, Hajime Ohigashi, and Ken-ichiro Tsuda pp 5746–5747 DOI: 10.1021/ja050447d Supporting Info

Chiral Molecular Metals:  Syntheses, Structures, and Properties of the AsF6- Salts of Racemic (±)-, (R)-, and (S)-Tetrathiafulvalene−Oxazoline Derivatives Céline Réthoré, Narcis Avarvari, Enric Canadell, Pascale Auban-Senzier, and Marc Fourmigué pp 5748–5749 DOI: 10.1021/ja0503884 Supporting Info

Hopping in the Electron-Transfer Photocycle of the 1:1 Complex of Zn−Cytochrome c Peroxidase with Cytochrome c Jennifer L. Seifert, Thomas D. Pfister, Judith M. Nocek, Yi Lu, and Brian M. Hoffman pp 5750–5751 DOI: 10.1021/ja042459p

Electrogeneration of a Poly(pyrrole)-NTA Chelator Film for a Reversible Oriented Immobilization of Histidine-Tagged Proteins Naoufel Haddour, Serge Cosnier, and Chantal Gondran pp 5752–5753 DOI: 10.1021/ja050390v Supporting Info

β Sheet Structure in Amyloid β Fibrils and Vibrational Dipolar Coupling Cynthia Paul and Paul H. Axelsen pp 5754–5755 DOI: 10.1021/ja042569w Supporting Info

Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes:  Intermediates and Evidence for Catalysis through π-Arene Complexes Jun Takaya and John F. Hartwig pp 5756–5757 DOI: 10.1021/ja0506410 Supporting Info

Nanoclusters in Ionic Liquids:  Evidence for N-Heterocyclic Carbene Formation from Imidazolium-Based Ionic Liquids Detected by 2H NMR Lisa Starkey Ott, Morgan L. Cline, Maggel Deetlefs, Kenneth R. Seddon, and Richard G. Finke pp 5758–5759 DOI: 10.1021/ja0423320 Supporting Info

Demonstration of Tunable Reactivity for meta-Benzynes John J. Nash, Katrina E. Nizzi, Anthony Adeuya, Michael J. Yurkovich, Christopher J. Cramer, and Hilkka I. Kenttämaa pp 5760–5761 DOI: 10.1021/ja0449473

Studies on the Mechanism of Intermolecular Enyne Metathesis:  Kinetic Method and Alkyne Substituent Effects Brandon R. Galan, Anthony J. Giessert, Jerome B. Keister, and Steven T. Diver pp 5762–5763 DOI: 10.1021/ja050174m Supporting Info

Enantioselective Addition of Nitrones to Activated Cyclopropanes Mukund P. Sibi, Zhihua Ma, and Craig P. Jasperse pp 5764–5765 DOI: 10.1021/ja0421497 Supporting Info

Hydroboration with Pyridine Borane at Room Temperature Julia M. Clay and Edwin Vedejs pp 5766–5767 DOI: 10.1021/ja043743j Supporting Info

Tetrasilacyclobutadiene (tBu2MeSi)4Si4:  A New Ligand for Transition-Metal Complexes Kazunori Takanashi, Vladimir Ya. Lee, Tadahiro Matsuno, Masaaki Ichinohe, and Akira Sekiguchi pp 5768–5769 DOI: 10.1021/ja050938y Supporting Info

Experimental Evidence for Chair-Like Transition States in Aldol Reactions of Methyl Ketone Lithium Enolates:  Stereoselective Synthesis and Utilization of a Deuterium-Labeled Enolate as a Probe of Reaction Stereochemistry Christopher M. Liu, William J. Smith, III, Darin J. Gustin, and William R. Roush pp 5770–5771 DOI: 10.1021/ja050730c Supporting Info

An Easy Approach to Optically Active α-Amino Phosphonic Acid Derivatives by Chiral Zn(II)-Catalyzed Enantioselective Amination of Phosphonates Luca Bernardi, Wei Zhuang, and Karl Anker Jørgensen pp 5772–5773 DOI: 10.1021/ja050989v Supporting Info

Hydrogenated 1,4-Insertion of Butadiene in the Copolymerization with Propylene Using an Isospecific Zirconocene Catalyst Takeshi Ishihara and Takeshi Shiono pp 5774–5775 DOI: 10.1021/ja050987a Supporting Info

Synthesis of Highly Substituted Indolines and Indoles via Intramolecular [4 + 2] Cycloaddition of Ynamides and Conjugated Enynes Joshua R. Dunetz and Rick L. Danheiser pp 5776–5777 DOI: 10.1021/ja051180l Supporting Info

Conformational Flexibility of a Synthetic Glycosylaminoglycan Bound to a Fibroblast Growth Factor. FGF-1 Recognizes Both the 1C4 and 2SO Conformations of a Bioactive Heparin-like Hexasaccharide Angeles Canales, Jesús Angulo, Rafael Ojeda, Marta Bruix, Rosa Fayos, Rosa Lozano, Guillermo Giménez-Gallego, Manuel Martín-Lomas, Pedro M. Nieto, and Jesús Jiménez-Barbero pp 5778–5779 DOI: 10.1021/ja043363y Supporting Info

Time-Resolved Study of Thymine Dimer Formation Sylvie Marguet and Dimitra Markovitsi pp 5780–5781 DOI: 10.1021/ja050648h Supporting Info

Catalytic Synthesis of Tricyclic Quinoline Derivatives from the Regioselective Hydroamination and C−H Bond Activation Reaction of Benzocyclic Amines and Alkynes Chae S. Yi, Sang Young Yun, and Ilia A. Guzei pp 5782–5783 DOI: 10.1021/ja042318n Supporting Info

Dynamic Kinetic Resolution Catalyzed by Ir Axially Chiral Phosphine Catalyst:  Asymmetric Synthesis of anti Aromatic β-Hydroxy-α-amino Acid Esters Kazuishi Makino, Yasuhiro Hiroki, and Yasumasa Hamada pp 5784–5785 DOI: 10.1021/ja0432113 Supporting Info

Picosecond Dynamics of Ligand Interconversion in the Primary Docking Site of Heme Proteins Seongheun Kim and Manho Lim pp 5786–5787 DOI: 10.1021/ja050734h Supporting Info

Two-Dimensional Folded Chain Crystals of a Synthetic Polymer in a Langmuir−Blodgett Film Jiro Kumaki, Takehiro Kawauchi, and Eiji Yashima pp 5788–5789 DOI: 10.1021/ja050457e Supporting Info

Regioselective Synthesis of Multifunctional Hybrid Polysiloxanes Achieved by Pt−Nanocluster Catalysis Bhanu P. S. Chauhan and Jitendra S. Rathore pp 5790–5791 DOI: 10.1021/ja042824c Supporting Info

Electron Flow Generated by Gas Phase Exothermic Catalytic Reactions Using a Platinum−Gallium Nitride Nanodiode Xiaozhong Ji, Anthony Zuppero, Jawahar M. Gidwani, and Gabor A. Somorjai pp 5792–5793 DOI: 10.1021/ja050945m

Factors Controlling the Barriers to Degenerate Hydrogen Atom Transfers Christine Isborn, David A. Hrovat, Weston Thatcher Borden, James M. Mayer, and Barry K. Carpenter pp 5794–5795 DOI: 10.1021/ja050024b Supporting Info

Enhanced Sensitivity and Resolution in 1H Solid-State NMR Spectroscopy of Paramagnetic Complexes under Very Fast Magic Angle Spinning Nalinda P. Wickramasinghe, Medhat Shaibat, and Yoshitaka Ishii pp 5796–5797 DOI: 10.1021/ja042188i Supporting Info

Selectivity in Nickel-Catalyzed Rearrangements of Cyclopropylen-ynes Gang Zuo and Janis Louie pp 5798–5799 DOI: 10.1021/ja043253r Supporting Info

Phosphepines:  Convenient Access to Phosphinidene Complexes Mark L. G. Borst, Rosa E. Bulo, Christiaan W. Winkel, Danièle J. Gibney, Andreas W. Ehlers, Marius Schakel, Martin Lutz, Anthony L. Spek, and Koop Lammertsma pp 5800–5801 DOI: 10.1021/ja050817y Supporting Info

Synthesis of 2-Cyclopentenones by Gold(I)-Catalyzed Rautenstrauch Rearrangement Xiaodong Shi, David J. Gorin, and F. Dean Toste pp 5802–5803 DOI: 10.1021/ja051689g Supporting Info

De Novo Design of a Redox-Active Minimal Rubredoxin Mimic Vikas Nanda, Michael M. Rosenblatt, Artur Osyczka, Hidetoshi Kono, Zelleka Getahun, P. Leslie Dutton, Jeffery G. Saven, and William F. DeGrado pp 5804–5805 DOI: 10.1021/ja050553f Supporting Info

Total Synthesis and Complete Assignment of the Stereostructure of a Cytotoxic Bromotriterpene Polyether (+)-Aurilol Yoshiki Morimoto, Yoshihiro Nishikawa, and Mamoru Takaishi pp 5806–5807 DOI: 10.1021/ja050123p Supporting Info

Template-Directed Dynamic Synthesis of Mechanically Interlocked Dendrimers Ken C.-F. Leung, Fabio Aricó, Stuart J. Cantrill, and J. Fraser Stoddart pp 5808–5810 DOI: 10.1021/ja0501363 Supporting Info

Nanoscale Organization of a Phthalocyanine−Fullerene System:  Remarkable Stabilization of Charges in Photoactive 1-D Nanotubules Dirk M. Guldi, Andreas Gouloumis, Purificación Vázquez, Tomás Torres, Vasilios Georgakilas, and Maurizio Prato pp 5811–5813 DOI: 10.1021/ja043283u Supporting Info

Product Bound Structures of the Soluble Methane Monooxygenase Hydroxylase from Methylococcus capsulatus (Bath):  Protein Motion in the α-Subunit Matthew H. Sazinsky and Stephen J. Lippard pp 5814–5825 DOI: 10.1021/ja044099b Supporting Info

An NMR Method for the Determination of Protein-Binding Interfaces Using Dioxygen-Induced Spin−Lattice Relaxation Enhancement M. Sakakura, S. Noba, P. A. Luchette, I. Shimada, and R. S. Prosser pp 5826–5832 DOI: 10.1021/ja047825j

The Tunnel of Acetyl-Coenzyme A Synthase/Carbon Monoxide Dehydrogenase Regulates Delivery of CO to the Active Site Xiangshi Tan, Huay-Keng Loke, Shawn Fitch, and Paul A. Lindahl pp 5833–5839 DOI: 10.1021/ja043701v

Toward Identification of the Compound I Reactive Intermediate in Cytochrome P450 Chemistry:  A QM/MM Study of Its EPR and Mössbauer Parameters Jan C. Schöneboom, Frank Neese, and Walter Thiel pp 5840–5853 DOI: 10.1021/ja0424732 Supporting Info

CO Rebinding to Protoheme:  Investigations of the Proximal and Distal Contributions to the Geminate Rebinding Barrier Xiong Ye, Anchi Yu, Georgi Y. Georgiev, Florin Gruia, Dan Ionascu, Wenxiang Cao, J. Timothy Sage, and Paul M. Champion pp 5854–5861 DOI: 10.1021/ja042365f

A Designed Synthetic Analogue of 4-OT Is Specific for a Non-Natural Substrate Norman Metanis, Ehud Keinan, and Philip E. Dawson pp 5862–5868 DOI: 10.1021/ja050110b

Stereochemical Recognition of Doubly Functional Aminotransferase in 2-Deoxystreptamine Biosynthesis Kenichi Yokoyama, Fumitaka Kudo, Mieko Kuwahara, Kousuke Inomata, Hideyuki Tamegai, Tadashi Eguchi, and Katsumi Kakinuma pp 5869–5874 DOI: 10.1021/ja0445948 Supporting Info

Inclusion of Cut and As-Grown Single-Walled Carbon Nanotubes in the Helical Superstructure of Schizophyllan and Curdlan (β-1,3-Glucans) Munenori Numata, Masayoshi Asai, Kenji Kaneko, Ah-Hyun Bae, Teruaki Hasegawa, Kazuo Sakurai, and Seiji Shinkai pp 5875–5884 DOI: 10.1021/ja044168m Supporting Info

Counterion Dependent Dye Aggregates:  Nanorods and Nanorings of Tetra(p-carboxyphenyl)porphyrin Stephanie C. Doan, Saravanarajan Shanmugham, D. Eric Aston, and Jeanne L. McHale pp 5885–5892 DOI: 10.1021/ja0430651

Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5) Bearing a 2,6-Bis(p-substituted phenyloxymethyl)benzene Ligand Kin-ya Akiba, Yuji Moriyama, Mitsuhiro Mizozoe, Hideki Inohara, Takako Nishii, Yohsuke Yamamoto, Mao Minoura, Daisuke Hashizume, Fujiko Iwasaki, Nozomi Takagi, Kazuya Ishimura, and Shigeru Nagase pp 5893–5901 DOI: 10.1021/ja043802t Supporting Info

Intramolecular Photoinduced Charge Transfer in Rotaxanes Phoebe H. Kwan and Timothy M. Swager pp 5902–5909 DOI: 10.1021/ja042535o

Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate Nadia Malek, Thierry Maris, Michel Simard, and James D. Wuest pp 5910–5916 DOI: 10.1021/ja042233m Supporting Info

On the Chemical Nature of Graphene Edges:  Origin of Stability and Potential for Magnetism in Carbon Materials Ljubisa R. Radovic and Bradley Bockrath pp 5917–5927 DOI: 10.1021/ja050124h Supporting Info

Supramolecular Chelation Based on Folding Matthew T. Stone and Jeffrey S. Moore pp 5928–5935 DOI: 10.1021/ja050713n Supporting Info

A RuH2(CO)(PPh3)3-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon−Hydrogen Bond Cleavage Fumitoshi Kakiuchi, Yusuke Matsuura, Shintaro Kan, and Naoto Chatani pp 5936–5945 DOI: 10.1021/ja043334n Supporting Info

The Radical Trap in Atom Transfer Radical Polymerization Need Not Be Thermodynamically Stable. A Study of the MoX3(PMe3)3 Catalysts Sébastien Maria, François Stoffelbach, José Mata, Jean-Claude Daran, Philippe Richard, and Rinaldo Poli pp 5946–5956 DOI: 10.1021/ja043078e Supporting Info

The Mechanism of Selective Purine C-Nitration Revealed:  NMR Studies Demonstrate Formation and Radical Rearrangement of an N7-Nitramine Intermediate Boris Rodenko, Melle Koch, Alida M. van der Burg, Martin J. Wanner, and Gerrit-Jan Koomen pp 5957–5963 DOI: 10.1021/ja042590x Supporting Info

Ionic Liquid and Solid HF Equivalent Amine-Poly(Hydrogen Fluoride) Complexes Effecting Efficient Environmentally Friendly Isobutane−Isobutylene Alkylation George A. Olah, Thomas Mathew, Alain Goeppert, Béla Török, Imre Bucsi, Xing-Ya Li, Qi Wang, Eric R. Marinez, Patrice Batamack, Robert Aniszfeld, and G. K. Surya Prakash pp 5964–5969 DOI: 10.1021/ja0424878

Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (−)-Dragmacidin F from a Single Enantiomer of Quinic Acid Neil K. Garg, Daniel D. Caspi, and Brian M. Stoltz pp 5970–5978 DOI: 10.1021/ja050586v Supporting Info

Supramolecular Chemistry of Halogens:  Complementary Features of Inorganic (M−X) and Organic (C−X‘) Halogens Applied to M−X···X‘−C Halogen Bond Formation Fiorenzo Zordan, Lee Brammer, and Paul Sherwood pp 5979–5989 DOI: 10.1021/ja0435182 Supporting Info

Electronic Properties of Single-Walled Carbon Nanotube Networks Elena Bekyarova, Mikhail E. Itkis, Nelson Cabrera, Bin Zhao, Aiping Yu, Junbo Gao, and Robert C. Haddon pp 5990–5995 DOI: 10.1021/ja043153l Supporting Info

Electronic Structure, Magnetic Ordering, and Formation Pathway of the Transition Metal Oxide Hydride LaSrCoO3H0.7 Craig A. Bridges, George R. Darling, Michael A. Hayward, and Matthew J. Rosseinsky pp 5996–6011 DOI: 10.1021/ja042683e Supporting Info

Pyridine N-Alkylation by Lithium, Magnesium, and Zinc Alkyl Reagents:  Synthetic, Structural, and Mechanistic Studies on the Bis(imino)pyridine System Ian J. Blackmore, Vernon C. Gibson, Peter B. Hitchcock, Charles W. Rees, David J. Williams, and Andrew J. P. White pp 6012–6020 DOI: 10.1021/ja042657g Supporting Info

Carbon Nanotubes as Intracellular Protein Transporters:  Generality and Biological Functionality Nadine Wong Shi Kam and Hongjie Dai pp 6021–6026 DOI: 10.1021/ja050062v

Recognition of RNA by Amide Modified Backbone Nucleic Acids:  Molecular Dynamics Simulations of DNA−RNA Hybrids in Aqueous Solution Mafalda Nina, Raymonde Fonné-Pfister, Renaud Beaudegnies, Habiba Chekatt, Pierre M. J. Jung, Fiona Murphy-Kessabi, Alain De Mesmaeker, and Sebastian Wendeborn pp 6027–6038 DOI: 10.1021/ja0486566 Supporting Info

Temperature-Dependent Coordination in E. coli Manganese Superoxide Dismutase Leandro C. Tabares, Néstor Cortez, Ileana Agalidis, and Sun Un pp 6039–6047 DOI: 10.1021/ja047007r Supporting Info

A Computational Analysis of the Ring-Opening Polymerization of rac-Lactide Initiated by Single-Site β-Diketiminate Metal Complexes:  Defining the Mechanistic Pathway and the Origin of Stereocontrol Edward L. Marshall, Vernon C. Gibson, and Henry S. Rzepa pp 6048–6051 DOI: 10.1021/ja043819b Supporting Info

Electron Spin Dynamics as a Probe of Molecular Dynamics:  Temperature-Dependent Magnetic Field Effects on Charge Recombination within a Covalent Radical Ion Pair Emily A. Weiss, Michael J. Tauber, Mark A. Ratner, and Michael R. Wasielewski pp 6052–6061 DOI: 10.1021/ja043398y Supporting Info

Chemical Shift Anisotropy Tensors of Carbonyl, Nitrogen, and Amide Proton Nuclei in Proteins through Cross-Correlated Relaxation in NMR Spectroscopy Karine Loth, Philippe Pelupessy, and Geoffrey Bodenhausen pp 6062–6068 DOI: 10.1021/ja042863o Supporting Info

Efficient Epoxidation of a Terminal Alkene Containing Allylic Hydrogen Atoms:  trans-Methylstyrene on Cu{111} Rachael L. Cropley, Federico J. Williams, Andrew J. Urquhart, Owain P. H. Vaughan, Mintcho S. Tikhov, and Richard M. Lambert pp 6069–6076 DOI: 10.1021/ja042758e

Photoinduced Charge Generation and Recombination Dynamics in Model Donor/Acceptor Pairs for Organic Solar Cell Applications:  A Full Quantum-Chemical Treatment Vincent Lemaur, Michelle Steel, David Beljonne, Jean-Luc Brédas, and Jérôme Cornil pp 6077–6086 DOI: 10.1021/ja042390l

Enhancement of Platinum Octaethyl Porphyrin Phosphorescence near Nanotextured Silver Surfaces Shanlin Pan and Lewis J. Rothberg pp 6087–6094 DOI: 10.1021/ja043259g Supporting Info

Magnetic Interactions in Dinuclear MnIIIMnIV Complexes Covalently Tethered to Organic Radicals:  Spectroscopic Models for the S2Yz• State of Photosystem II Dana S. Marlin, Eckhard Bill, Thomas Weyhermüller, Eberhard Bothe, and Karl Wieghardt pp 6095–6108 DOI: 10.1021/ja042655w Supporting Info

Formation of Cationic Peptide Radicals by Gas-Phase Redox Reactions with Trivalent Chromium, Manganese, Iron, and Cobalt Complexes Christopher K. Barlow, W. David McFadyen, and Richard A. J. O'Hair pp 6109–6115 DOI: 10.1021/ja043088f

The Enthalpies of Formation of o-, m-, and p-Benzoquinone:  Gas-Phase Ion Energetics, Combustion Calorimetry, and Quantum Chemical Computations Combined Alireza Fattahi, Steven R. Kass, Joel F. Liebman, M. Agostinha R. Matos, Margarida S. Miranda, and Victor M. F. Morais pp 6116–6122 DOI: 10.1021/ja042612f

Layer-by-Layer Growth on Ge(100) via Spontaneous Urea Coupling Reactions Ansoon Kim, Michael A. Filler, Sehun Kim, and Stacey F. Bent pp 6123–6132 DOI: 10.1021/ja042751x

Specific Band Observed in VCD Predicts the Anomeric Configuration of Carbohydrates  [J. Am. Chem. Soc. 2004, 126, 9496−9497].  Kenji Monde, Tohru Taniguchi, Nobuaki Miura, and Shin-Ichiro Nishimura p 6133 DOI: 10.1021/ja0599059

Mathematica 5.1 Wolfram Research Inc., 100 Trade Center Drive, Champaign, IL 61820-7237. www.wolfram. com. Suggested retail price:  $1880 (U.S. and Canada) includes one year of premier service. Academic price:  $895. Student version:  $139.95. Dmitrii E. Makarov p 6134 DOI: 10.1021/ja041025r

Ion Exchange and Solvent Extraction, Volume 16 Edited by Arup K. SenGupta (Lehigh University) and Yizhak Marcus (The Hebrew University of Jerusalem). Marcel Dekker, Inc.:  New York, Basel. 2004. xviii + 378 pp. $225.00. ISBN 0-8247-5489-1. James S. Fritz p 6135 DOI: 10.1021/ja041021m

Handbook of Sol-Gel Science and Technology:  Processing, Characterization and Applications, Volumes I−III Set edited by Sumio Sakka (Professor Emeritus of Kyoto University). Kluwer Academic Publishers:  Boston, Dordrecht, London. 2005. lx + 1980 pp. $1500.00. ISBN 1-4020-7969-9. p 6135 DOI: 10.1021/ja041056m

Separations and Reactions in Organic Supramolecular Chemistry. Perspectives in Supramolecular Chemistry, Volume 8 Edited by Fumio Toda (Okayama University of Science) and Roger Bishop (University of New South Wales). John Wiley & Sons, Ltd.:  Chichester. 2004. xiv + 240 pp. $210.00. ISBN 0-470-85448-0. Willem Verboom pp 6135–6136 DOI: 10.1021/ja0409614

Issue 17

Tuning the Enantioselective N-Acetylation of Racemic Amines:  A Spectacular Salt Effect Stellios Arseniyadis, Pithani V. Subhash, Alain Valleix, Suju P. Mathew, Donna G. Blackmond, Alain Wagner, and Charles Mioskowski pp 6138–6139 DOI: 10.1021/ja051302+ Supporting Info

Site-Specific Binding of Quinones to Proteins through Thiol Addition and Addition−Elimination Reactions Wen-Wu Li, Jürgen Heinze, and Wolfgang Haehnel pp 6140–6141 DOI: 10.1021/ja050974x Supporting Info

Polypeptide and Carbohydrate Structure of an Intact Glycoprotein from Raman Optical Activity Fujiang Zhu, Neil W. Isaacs, Lutz Hecht, and Laurence D. Barron pp 6142–6143 DOI: 10.1021/ja051048l

Sorption−Desorption Behavior of Bispyrazolato−Copper(II) 1D Coordination Polymers Augusto Cingolani, Simona Galli, Norberto Masciocchi, Luciano Pandolfo, Claudio Pettinari, and Angelo Sironi pp 6144–6145 DOI: 10.1021/ja050856+ Supporting Info

Electrodeposition of Noble Metal Nanoparticles on Carbon Nanotubes Bernadette M. Quinn, Cees Dekker, and Serge G. Lemay pp 6146–6147 DOI: 10.1021/ja0508828 Supporting Info

Enzymatic Approach to Unnatural Glycosides with Diverse Aglycon Scaffolds Using Glycosyltransferase VinC Atsushi Minami, Rei Uchida, Tadashi Eguchi, and Katsumi Kakinuma pp 6148–6149 DOI: 10.1021/ja042848j Supporting Info

Protonation of the Acidic Residues in the Transmembrane Cation-Binding Sites of the Ca2+ Pump Yuji Sugita, Naoyuki Miyashita, Mitsunori Ikeguchi, Akinori Kidera, and Chikashi Toyoshima pp 6150–6151 DOI: 10.1021/ja0427505 Supporting Info

A New Family of Small Molecules To Probe the Reactivation of Mutant p53 Michael C. Myers, JinLing Wang, Jaclyn A. Iera, Jeong-kyu Bang, Toshiaki Hara, Shin'ichi Saito, Gerard P. Zambetti, and Daniel H. Appella pp 6152–6153 DOI: 10.1021/ja045752y Supporting Info

Heteronuclear Two-Bond Correlation:  Suppressing Heteronuclear Three-Bond or Higher NMR Correlations while Enhancing Two-Bond Correlations Even for Vanishing 2JCH Nils T. Nyberg, Jens Ø. Duus, and Ole W. Sørensen pp 6154–6155 DOI: 10.1021/ja050878w

Heterometallic Bismuth-Transition Metal Homoleptic β-Diketonates Evgeny V. Dikarev, Haitao Zhang, and Bo Li pp 6156–6157 DOI: 10.1021/ja051265m Supporting Info

Reversible Insulin Self-Assembly under Carbohydrate Control Thomas Hoeg-Jensen, Svend Havelund, Peter K. Nielsen, and Jan Markussen pp 6158–6159 DOI: 10.1021/ja051038k Supporting Info

Promiscuous Catalysis by the Tetrahymena Group I Ribozyme Marcello Forconi and Daniel Herschlag pp 6160–6161 DOI: 10.1021/ja050180i Supporting Info

Cooperative Friedel−Crafts Catalysis in Heterobimetallic Regime:  Alkylation of Aromatics by π-Activated Alcohols Joyanta Choudhury, Susmita Podder, and Sujit Roy pp 6162–6163 DOI: 10.1021/ja0506004 Supporting Info

Direct Evidence for the Gas Phase Thermal Polymerization of Styrene. Determination of the Initiation Mechanism and Structures of the Early Oligomers by Ion Mobility Edreese H. Alsharaeh, Yehia M. Ibrahim, and M. Samy El-Shall pp 6164–6165 DOI: 10.1021/ja042283r Supporting Info

A Magnetic Route to Measure the Average Oxidation State of Mixed-Valent Manganese in Manganese Oxide Octahedral Molecular Sieves (OMS) Xiong-Fei Shen, Yun-Shuang Ding, Jia Liu, Zhao-Hui Han, Joseph I. Budnick, William A. Hines, and Steven L. Suib pp 6166–6167 DOI: 10.1021/ja043406a Supporting Info

One-Bond C−C Coupling Constants in Ethers Are Not Primarily Determined by n−σ* Delocalization Charles L. Perrin and Máté Erdélyi pp 6168–6169 DOI: 10.1021/ja0504284

Three-Component Coupling Reactions of Silylglyoxylates, Alkynes, and Aldehydes:  A Chemoselective One-Step Glycolate Aldol Construction David A. Nicewicz and Jeffrey S. Johnson pp 6170–6171 DOI: 10.1021/ja043884l Supporting Info

Cp*Ru(PN) Complex-Catalyzed Isomerization of Allylic Alcohols and Its Application to the Asymmetric Synthesis of Muscone Masato Ito, Sachiko Kitahara, and Takao Ikariya pp 6172–6173 DOI: 10.1021/ja050770g Supporting Info

Enantioselective Reductive Cyclization of 1,6-Enynes via Rhodium-Catalyzed Asymmetric Hydrogenation:  C−C Bond Formation Precedes Hydrogen Activation Hye-Young Jang, Freddie W. Hughes, Hegui Gong, Junmei Zhang, Jennifer S. Brodbelt, and Michael J. Krische pp 6174–6175 DOI: 10.1021/ja042645v Supporting Info

Catalytic Asymmetric Synthesis of Esters from Ketenes Sheryl L. Wiskur and Gregory C. Fu pp 6176–6177 DOI: 10.1021/ja0506152 Supporting Info

Intramolecular [4 + 2] Cycloadditions of 1,3-Enynes or Arylalkynes with Alkenes with Highly Reactive Cationic Phosphine Au(I) Complexes Cristina Nieto-Oberhuber, Salomé López, and Antonio M. Echavarren pp 6178–6179 DOI: 10.1021/ja042257t Supporting Info

Single Crystal SnO2 Zigzag Nanobelts Junhong Duan, Shaoguang Yang, Hongwei Liu, Jiangfeng Gong, Hongbo Huang, Xiaoning Zhao, Rong Zhang, and Youwei Du pp 6180–6181 DOI: 10.1021/ja042748d Supporting Info

PdCl2-Catalyzed Two-Component Cross-Coupling Cyclization of 2,3-Allenoic Acids with 2,3-Allenols. An Efficient Synthesis of 4-(1‘,3‘-Dien-2‘-yl)-2(5H)-furanone Derivatives Shengming Ma and Zhenhua Gu pp 6182–6183 DOI: 10.1021/ja0500815 Supporting Info

Sodium Dialkyl-amidozincates:  Alkyl or Amido Bases? An Experimental and Theoretical Case Study Prokopis C. Andrikopoulos, David R. Armstrong, Helen R. L. Barley, William Clegg, Sophie H. Dale, Eva Hevia, Gordon W. Honeyman, Alan R. Kennedy, and Robert E. Mulvey pp 6184–6185 DOI: 10.1021/ja050860l Supporting Info

Total Synthesis of (+)-13-Deoxytedanolide Lisa D. Julian, Jason S. Newcom, and William R. Roush pp 6186–6187 DOI: 10.1021/ja050729d Supporting Info

Phase- and Size-Controlled Synthesis of Hexagonal and Cubic CoO Nanocrystals Won Seok Seo, Jae Ha Shim, Sang Jun Oh, Eun Kwang Lee, Nam Hwi Hur, and Joon T. Park pp 6188–6189 DOI: 10.1021/ja050359t Supporting Info

Mechanism and Origin of Enantioselectivity in the Rh2(OAc)(DPTI)3-Catalyzed Cyclopropenation of Alkynes Daniel T. Nowlan III and Daniel A. Singleton pp 6190–6191 DOI: 10.1021/ja0504441 Supporting Info

Thermodynamic Evidence for Ca2+-Mediated Self-Aggregation of Lewis X Gold Glyconanoparticles. A Model for Cell Adhesion via Carbohydrate−Carbohydrate Interaction Jesús M. de la Fuente, Peter Eaton, Africa G. Barrientos, Margarita Menéndez, and Soledad Penadés pp 6192–6197 DOI: 10.1021/ja0431354

Development of a Tandem Protein Trans-Splicing System Based on Native and Engineered Split Inteins Jianxin Shi and Tom W. Muir pp 6198–6206 DOI: 10.1021/ja042287w Supporting Info

Polypeptide Chains Containing d-γ-Hydroxyvaline Katarzyna Pisarewicz, David Mora, Fred C. Pflueger, Gregg B. Fields, and Frank Marí pp 6207–6215 DOI: 10.1021/ja050088m Supporting Info

Reactions of Nitrogen Oxides with Heme Models. Spectral and Kinetic Study of Nitric Oxide Reactions with Solid and Solute FeIII(TPP)(NO3) Tigran S. Kurtikyan, Gurgen M. Gulyan, Garik G. Martirosyan, Mark D. Lim, and Peter C. Ford pp 6216–6224 DOI: 10.1021/ja042237r Supporting Info

Photoinduced Carbon Monoxide Migration in a Synthetic Heme−Copper Complex H. Christopher Fry, Andrew D. Cohen, John P. Toscano, Gerald J. Meyer, and Kenneth D. Karlin pp 6225–6230 DOI: 10.1021/ja043199e Supporting Info

Trapping H- Bound to the Nitrogenase FeMo-Cofactor Active Site during H2 Evolution:  Characterization by ENDOR Spectroscopy Robert Y. Igarashi, Mikhail Laryukhin, Patricia C. Dos Santos, Hong-In Lee, Dennis R. Dean, Lance C. Seefeldt, and Brian M. Hoffman pp 6231–6241 DOI: 10.1021/ja043596p Supporting Info

Hybrid Nanocapsules:  Interactions of ABA Block Copolymers with Liposomes Tristan Ruysschaert, Andreas F. P. Sonnen, Thomas Haefele, Wolfgang Meier, Mathias Winterhalter, and Didier Fournier pp 6242–6247 DOI: 10.1021/ja043600x

Environmentally Responsive “Hairy” Nanoparticles:  Mixed Homopolymer Brushes on Silica Nanoparticles Synthesized by Living Radical Polymerization Techniques Dejin Li, Xia Sheng, and Bin Zhao pp 6248–6256 DOI: 10.1021/ja0422561 Supporting Info

Ab Initio Studies on the Radiationless Decay Mechanisms of the Lowest Excited Singlet States of 9H-Adenine Serhiy Perun, Andrzej L. Sobolewski, and Wolfgang Domcke pp 6257–6265 DOI: 10.1021/ja044321c Supporting Info

Construction of Polymeric δ-Graph:  A Doubly Fused Tricyclic Topology Yasuyuki Tezuka and Kohsuke Fujiyama pp 6266–6270 DOI: 10.1021/ja042198j Supporting Info

Asymmetrically Modified Silica Particles:  A Simple Particulate Surfactant for Stabilization of Oil Droplets in Water Yoshiko K. Takahara, Shigeru Ikeda, Satoru Ishino, Koji Tachi, Keita Ikeue, Takao Sakata, Toshiaki Hasegawa, Hirotaro Mori, Michio Matsumura, and Bunsho Ohtani pp 6271–6275 DOI: 10.1021/ja043581r Supporting Info

Biomimetic Synthesis of Antimalarial Naphthoquinones Jeremiah P. Malerich, Thomas J. Maimone, Gregory I. Elliott, and Dirk Trauner pp 6276–6283 DOI: 10.1021/ja050092y Supporting Info

A Highly Enantio- and Diastereoselective Catalytic Intramolecular Stetter Reaction Javier Read de Alaniz and Tomislav Rovis pp 6284–6289 DOI: 10.1021/ja0425132 Supporting Info

Why Do the Heavy-Atom Analogues of Acetylene E2H2 (E = Si−Pb) Exhibit Unusual Structures? Matthias Lein, Andreas Krapp, and Gernot Frenking pp 6290–6299 DOI: 10.1021/ja042295c Supporting Info

The Reaction of Tetrakis(dimethylamido)titanium with Self-Assembled Alkyltrichlorosilane Monolayers Possessing −OH, −NH2, and −CH3 Terminal Groups Aravind S. Killampalli, Paul F. Ma, and James R. Engstrom pp 6300–6310 DOI: 10.1021/ja047922c Supporting Info

Organolanthanide-Catalyzed Synthesis of Phosphine-Terminated Polyethylenes. Scope and Mechanism Amber M. Kawaoka and Tobin J. Marks pp 6311–6324 DOI: 10.1021/ja044174i Supporting Info

Carbon−Fluorine Bond Activation Coupled with Carbon−Carbon Bond Formation at Iridium. Confirmation of Complete Kinetic Diastereoselectivity at the New Carbon Stereocenter by Intramolecular Trapping Using Vinyl as the Migrating Group Russell P. Hughes, Roman B. Laritchev, Lev N. Zakharov, and Arnold L. Rheingold pp 6325–6334 DOI: 10.1021/ja042345d Supporting Info

Structures, Electronic States, Photoluminescence, and Carrier Transport Properties of 1,1-Disubstituted 2,3,4,5-Tetraphenylsiloles Gui Yu, Shiwei Yin, Yunqi Liu, Jiangshan Chen, Xinjun Xu, Xiaobo Sun, Dongge Ma, Xiaowei Zhan, Qian Peng, Zhigang Shuai, Benzhong Tang, Daoben Zhu, Weihai Fang, and Yi Luo pp 6335–6346 DOI: 10.1021/ja044628b Supporting Info

Ag4V2O6F2:  An Electrochemically Active and High Silver Density Phase Erin M. Sorensen, Heather K. Izumi, John T. Vaughey, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 6347–6352 DOI: 10.1021/ja050150f Supporting Info

Pyrolysis of Mesoporous Silica-Immobilized 1,3-Diphenylpropane. Impact of Pore Confinement and Size Michelle K. Kidder, Phillip F. Britt, Zongtao Zhang, Sheng Dai, Edward W. Hagaman, Alan L. Chaffee, and A. C. Buchanan, III pp 6353–6360 DOI: 10.1021/ja050389w

Liquid Hydrogen in Protonic Chabazite Adriano Zecchina, Silvia Bordiga, Jenny G. Vitillo, Gabriele Ricchiardi, Carlo Lamberti, Giuseppe Spoto, Morten Bjørgen, and Karl Petter Lillerud pp 6361–6366 DOI: 10.1021/ja050276c

The Formation Mechanism of a Textured Ceramic of Thermoelectric [Ca2CoO3]0.62[CoO2] on β-Co(OH)2 Templates through in Situ Topotactic Conversion Hiroshi Itahara, Won-Seon Seo, Sujeong Lee, Hiroshi Nozaki, Toshihiko Tani, and Kunihito Koumoto pp 6367–6373 DOI: 10.1021/ja0434883 Supporting Info

Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn4O(NTB)2] Eun Young Lee, Seung Yeon Jang, and Myunghyun Paik Suh pp 6374–6381 DOI: 10.1021/ja043756x Supporting Info

Reversible Molecular Switching of Ruthenium Bis(bipyridyl) Groups Bonded to Oligothiophenes:  Effect on Electrochemical and Spectroscopic Properties Carolyn Moorlag, Michael O. Wolf, Cornelia Bohne, and Brian O. Patrick pp 6382–6393 DOI: 10.1021/ja043573a Supporting Info

Solid-State Composite Electrolyte LiI/3-Hydroxypropionitrile/SiO2 for Dye-Sensitized Solar Cells Hongxia Wang, Hong Li, Bofei Xue, Zhaoxiang Wang, Qingbo Meng, and Liquan Chen pp 6394–6401 DOI: 10.1021/ja043268p Supporting Info

Large Structure Rearrangement of Colicin Ia Channel Domain after Membrane Binding from 2D 13C Spin Diffusion NMR Wenbin Luo, Xiaolan Yao, and Mei Hong pp 6402–6408 DOI: 10.1021/ja0433121 Supporting Info

Solution 1H NMR Characterization of the Distal H-Bond Network and the Effective Axial Field in the Resting-State, High-Spin Ferric, Substrate-Bound Complex of Heme Oxygenase from N. meningitidis Yangzhong Liu, Xuhong Zhang, Tadashi Yoshida, and Gerd N. La Mar pp 6409–6422 DOI: 10.1021/ja042339h Supporting Info

Electrochemically Controlled Hydrogen Bonding. Nitrobenzenes as Simple Redox-Dependent Receptors for Arylureas Jingjing Bu, Ninette D. Lilienthal, Jessica E. Woods, Cora E. Nohrden, KimPhuong T. Hoang, Daniel Truong, and Diane K. Smith pp 6423–6429 DOI: 10.1021/ja0462272

A Ruler for Determining the Position of Proteins in Membranes Robert D. Nielsen, Kepeng Che, Michael H. Gelb, and Bruce H. Robinson pp 6430–6442 DOI: 10.1021/ja042782s Supporting Info

AT Base Pair Anions versus (9-Methyl-A)(1-Methyl-T) Base Pair Anions Dunja Radisic, Kit H. Bowen, Jr., Iwona Dbkowska, Piotr Storoniak, Janusz Rak, and Maciej Gutowski pp 6443–6450 DOI: 10.1021/ja050724g Supporting Info

Solid-State NMR and Quantum Chemical Investigations of 13Cα Shielding Tensor Magnitudes and Orientations in Peptides:  Determining and ψ Torsion Angles Sungsool Wi, Haihong Sun, Eric Oldfield, and Mei Hong pp 6451–6458 DOI: 10.1021/ja042935b Supporting Info

Orientational Properties of Stretched Polystyrene Gels in Organic Solvents and the Suppression of Their Residual 1H NMR Signals Burkhard Luy, Kyryl Kobzar, Sebastian Knör, Julien Furrer, Dominik Heckmann, and Horst Kessler pp 6459–6465 DOI: 10.1021/ja043344o

Competing Simple Cleavage Reactions:  The Elimination of Alkyl Radicals from Amine Radical Cations Steen Hammerum, Kion Norrman, Theis I. Sølling, Peter E. Andersen, Lars Bo Jensen, and Tore Vulpius pp 6466–6475 DOI: 10.1021/ja043481l

Experimental Study of the Interplay between Long-Range Electron Transfer and Redox Probe Permeation at Self-Assembled Monolayers:  Evidence for Potential-Induced Ion Gating Juan José Calvente, German López-Pérez, Pablo Ramírez, Héctor Fernández, María Alicia Zón, Willem H. Mulder, and Rafael Andreu pp 6476–6486 DOI: 10.1021/ja050265j

The Microenvironment Effect on the Generation of Reactive Oxygen Species by Pd−Bacteriopheophorbide Yahel Vakrat-Haglili, Lev Weiner, Vlad Brumfeld, Alexander Brandis, Yoram Salomon, Brian Mcllroy, Brian C. Wilson, Anna Pawlak, Malgorzata Rozanowska, Tadeusz Sarna, and Avigdor Scherz pp 6487–6497 DOI: 10.1021/ja046210j Supporting Info

Surface and Interfacial Tension:  Measurement, Theory, and Applications. Surfactant Science Series, Volume 119 Edited by Stanley Hartland (ETH Swiss Federal Institute of Technology, Zürich). Marcel Dekker, Inc.:  New York, Basel. 2004. x + 620 pp. $175.00. ISBN 0-8247-5034-9. Qiong Zhou and P. Somasundaran p 6498 DOI: 10.1021/ja041019v

Polymer Synthesis. Advances in Polymer Science, 171 With contributions by Toshikazu Takata (Tokyo Institute of Technology), Nobuhiro Kihara, Yoshio Furusho (Osaka Prefecture University), Michinori Suginome (Kyoto University), Yoshihiko Ito (Doshisha University), Kohtaro Osakada, and Daisuke Takeuchi (Tokyo Institute of Technology). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 214 pp. $199.00. ISBN 3-540-21711-8. David E. Bergbreiter pp 6498–6499 DOI: 10.1021/ja041035s

Vapour and Trace Detection of Explosives for Anti-Terrorism Purposes Edited by Michael Krausa (Fraunhofer Institut für Chemische Technologie, Pfinztal, Germany) and Aleksey Alekseyvitch Reznev (SMC Technological Center MIET, Moscow, Russia). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. x + 152 pp. $94.00. ISBN 1-4020-2714-1. p 6499 DOI: 10.1021/ja041051p

Encyclopedia of Analytical Science, 2nd ed., Volumes 1−10 Edited by Paul J. Worsfold (University of Plymouth), Alan Townshend (University of Hull), and Colin E. Poole (Wayne State University). Elsevier:  Amsterdam. 2004. 5000 pp. $4570.00. ISBN 0-12-764100-9. p 6499 DOI: 10.1021/ja041052h

Charged Particle and Photon Interactions with Matter. Chemical, Physiochemical, and Biological Consequences with Applications Edited by A. Mozumder (University of Notre Dame, Notre Dame, Indiana) and Y. Hatano (Tokyo Institute of Technology, Tokyo, Japan). Marcel Dekker, Inc.:  New York, Basel. 2004. xii + 870 pp. $235.00. ISBN 0-8247-4623-6. Diane E. Cabelli pp 6499–6500 DOI: 10.1021/ja040913j

Comprehensive Organic Functional Group Transformations II, Volumes 1−7 Edited by Alan R. Katritzky (University of Florida) and Richard J. K. Taylor (University of York). Elsevier:  Amsterdam. 2004. 6400 pp. $4,950.00. ISBN 0-08-044256-0. p 6500 DOI: 10.1021/ja041053+

Issue 18

Direct Introduction of Single Protein Channels and Pores into Lipid Bilayers Matthew A. Holden and Hagan Bayley pp 6502–6503 DOI: 10.1021/ja042470p Supporting Info

Remote Asymmetric Induction in an Intramolecular Ionic Diels−Alder Reaction:  Application to the Total Synthesis of (+)-Dihydrocompactin Tarek Sammakia, Deidre M. Johns, Ganghyeok Kim, and Martin A. Berliner pp 6504–6505 DOI: 10.1021/ja043506g Supporting Info

Hydrogen Storage in the Dehydrated Prussian Blue Analogues M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long pp 6506–6507 DOI: 10.1021/ja051168t Supporting Info

Streptavidin as a Macroinitiator for Polymerization:  In Situ Protein−Polymer Conjugate Formation Debora Bontempo and Heather D. Maynard pp 6508–6509 DOI: 10.1021/ja042230+ Supporting Info

Square Nets of Tellurium:  Rare-Earth Dependent Variation in the Charge-Density Wave of RETe3 (RE = Rare-Earth Element) Christos Malliakas, Simon J. L. Billinge, Hyun Jeong Kim, and Mercouri G. Kanatzidis pp 6510–6511 DOI: 10.1021/ja0505292 Supporting Info

Polymorphs with Varying Platinum(II)−Thallium(I) Interactions Jay R. Stork, Marilyn M. Olmstead, and Alan L. Balch pp 6512–6513 DOI: 10.1021/ja050014a Supporting Info

Fluorescent Sensing and Selective Pb(II) Extraction by a Dansylamide Ion-Exchanger Konstantinos Kavallieratos, Jay M. Rosenberg, Wei-Zhong Chen, and Tong Ren pp 6514–6515 DOI: 10.1021/ja050296e Supporting Info

Selective Detection of Cysteine and Glutathione Using Gold Nanorods P. K. Sudeep, S. T. Shibu Joseph, and K. George Thomas pp 6516–6517 DOI: 10.1021/ja051145e Supporting Info

Influence of N-Methylation on a Cation−π Interaction Produces a Remarkably Stable β-Hairpin Peptide Robert M. Hughes and Marcey L. Waters pp 6518–6519 DOI: 10.1021/ja0507259 Supporting Info

A Highly Stable Quadruply Hydrogen-Bonded Heterocomplex Useful for Supramolecular Polymer Blends Taiho Park, Steven C. Zimmerman, and Shoji Nakashima pp 6520–6521 DOI: 10.1021/ja050996j

Fluorescence Detection of DNA by the Catalytic Activation of an Aptamer/Thrombin Complex Valeri Pavlov, Bella Shlyahovsky, and Itamar Willner pp 6522–6523 DOI: 10.1021/ja050678k

Effect of Microstructure on Molecular Oxygen Permeation through Condensed Phospholipid Monolayers Gang Pu, Marjorie L. Longo, and Mark A. Borden pp 6524–6525 DOI: 10.1021/ja051103q Supporting Info

Dilution-Induced Spheres-to-Vesicles Morphological Transition in Micelles from Block Copolymer/Surfactant Complexes Zhijun Hu, Alain M. Jonas, Sunil K. Varshney, and Jean-François Gohy pp 6526–6527 DOI: 10.1021/ja050053m Supporting Info

Synthetic Ion Channels with Rigid-Rod π-Stack Architecture that Open in Response to Charge-Transfer Complex Formation Pinaki Talukdar, Guillaume Bollot, Jiri Mareda, Naomi Sakai, and Stefan Matile pp 6528–6529 DOI: 10.1021/ja051260p Supporting Info

Transition Metal-Catalyzed Intermolecular [5+2] and [5+2+1] Cycloadditions of Allenes and Vinylcyclopropanes Hermann A. Wegner, Armin de Meijere, and Paul A. Wender pp 6530–6531 DOI: 10.1021/ja043671w Supporting Info

Toward Understanding How the Lactone Moiety of Discodermolide Affects Activity Simon J. Shaw, Kurt F. Sundermann, Mark A. Burlingame, David C. Myles, B. Scott Freeze, Ming Xian, Ignacio Brouard, and Amos B. Smith, III pp 6532–6533 DOI: 10.1021/ja051185i Supporting Info

Controllable Fabrication of Carbon Nanotube and Nanobelt with a Polyoxometalate-Assisted Mild Hydrothermal Process Zhenhui Kang, Enbo Wang, Baodong Mao, Zhongmin Su, Lei Gao, Suoyuan Lian, and Lin Xu pp 6534–6535 DOI: 10.1021/ja051228v Supporting Info

Unexpected Subtilisin-Catalyzed Hydrolysis of a Sulfinamide Bond in Preference to a Carboxamide Bond in N-Acyl Sulfinamides Paul F. Mugford, Vladimir P. Magloire, and Romas J. Kazlauskas pp 6536–6537 DOI: 10.1021/ja0506105 Supporting Info

Thermally Gated Liposomes Wen-Hua Chen and Steven L. Regen pp 6538–6539 DOI: 10.1021/ja0513584 Supporting Info

Direct Electrochemical Regeneration of Monooxygenase Subunits for Biocatalytic Asymmetric Epoxidation Frank Hollmann, Karin Hofstetter, Tilo Habicher, Bernhard Hauer, and Andreas Schmid pp 6540–6541 DOI: 10.1021/ja050997b Supporting Info

Evidence for Lower Critical Solution Behavior in Ionic Liquid Solutions Joanna Lachwa, Jerzy Szydlowski, Vesna Najdanovic-Visak, Luís P. N. Rebelo, Kenneth R. Seddon, Manuel Nunes da Ponte, José M. S. S. Esperança, and Henrique J. R. Guedes pp 6542–6543 DOI: 10.1021/ja0510257 Supporting Info

Can Decarbonylation of Acyl Radicals Be Overcome in Radical Addition Reactions? En Route to a Solution Employing N-Acyl Oxazolidinones and SmI2/H2O Christina M. Jensen, Karl B. Lindsay, Rolf H. Taaning, Jakob Karaffa, Anna Mette Hansen, and Troels Skrydstrup pp 6544–6545 DOI: 10.1021/ja050420u Supporting Info

Enzymatic Lithography of Phospholipid Bilayer Films by Stereoselective Hydrolysis Patricia Moraille and Antonella Badia pp 6546–6547 DOI: 10.1021/ja0511669 Supporting Info

Metal−Peroxo versus Metal−Oxo Oxidants in Non-Heme Iron-Catalyzed Olefin Oxidations:  Computational and Experimental Studies on the Effect of Water David Quiñonero, Keiji Morokuma, and Djamaladdin G. MusaevRubén Mas-Ballesté and Lawrence Que Jr. pp 6548–6549 DOI: 10.1021/ja051062y Supporting Info

Thiolate Ligands for Synthesis of Water-Soluble Gold Clusters Christopher J. Ackerson, Pablo D. Jadzinsky, and Roger D. Kornberg pp 6550–6551 DOI: 10.1021/ja046114i Supporting Info

Fluorination and Electrical Conductivity of BN Nanotubes Chengchun Tang, Yoshio Bando, Yang Huang, Shuanglin Yue, Changzhi Gu, FangFang Xu, and Dmitri Golberg pp 6552–6553 DOI: 10.1021/ja042388u Supporting Info

Effects of Rotational Symmetry Order on the Solid State Dynamics of Phenylene and Diamantane Rotators Steven D. Karlen, Rafael Ortiz, Orville L. Chapman, and Miguel A. Garcia-Garibay pp 6554–6555 DOI: 10.1021/ja042512+ Supporting Info

Coordinated Design of Cofactor and Active Site Structures in Development of New Protein Catalysts Takafumi Ueno, Tomomi Koshiyama, Masataka Ohashi, Kazuyoshi Kondo, Masaharu Kono, Atsuo Suzuki, Takashi Yamane, and Yoshihito Watanabe pp 6556–6562 DOI: 10.1021/ja045995q

Structural Mimicry of Two Cytochrome b562 Interhelical Loops Using Macrocycles Constrained by Oxazoles and Thiazoles Yogendra Singh, Martin J. Stoermer, Andrew J. Lucke, Tom Guthrie, and David P. Fairlie pp 6563–6572 DOI: 10.1021/ja0455300 Supporting Info

Laser Flash Photolysis Generation and Kinetic Studies of Porphyrin−Manganese−Oxo Intermediates. Rate Constants for Oxidations Effected by Porphyrin−MnV−Oxo Species and Apparent Disproportionation Equilibrium Constants for Porphyrin−MnIV−Oxo Species Rui Zhang, John H. Horner, and Martin Newcomb pp 6573–6582 DOI: 10.1021/ja045042s Supporting Info

Pairwise Decomposition of Residue Interaction Energies Using Semiempirical Quantum Mechanical Methods in Studies of Protein−Ligand Interaction Kaushik Raha, Arjan J. van der Vaart, Kevin E. Riley, Martin B. Peters, Lance M. Westerhoff, Hwanho Kim, and Kenneth M. Merz, Jr. pp 6583–6594 DOI: 10.1021/ja042666p Supporting Info

The Mechanism of Activation of a [NiFe]-Hydrogenase by Electrons, Hydrogen, and Carbon Monoxide Sophie E. Lamle, Simon P. J. Albracht, and Fraser A. Armstrong pp 6595–6604 DOI: 10.1021/ja0424934

Direct ESR Detection of Pentadienyl Radicals and Peroxyl Radicals in Lipid Peroxidation:  Mechanistic Insight into Regioselective Oxygenation in Lipoxygenases Hironori Kitaguchi, Kei Ohkubo, Seiji Ogo, and Shunichi Fukuzumi pp 6605–6609 DOI: 10.1021/ja044345j Supporting Info

Molecular Insight into the Electrostatic Membrane Surface Potential by 14N/31P MAS NMR Spectroscopy:  Nociceptin−Lipid Association Fredrick Lindström, Philip T. F. Williamson, and Gerhard Gröbner pp 6610–6616 DOI: 10.1021/ja042325b

Dynamic Behavior of Chiral Sulfonimidoyl-Substituted Allyl and Alkyl (Dimethylamino)titanium(IV) Complexes:  Metallotropic Shift, Reversible β-Hydride Elimination/Reinsertion, and ab Initio Calculations of Allyl and Alkyl Aminosulfoxonium Ylides Hans-Joachim Gais, Peter R. Bruns, Gerhard Raabe, Rüdiger Hainz, Marcel Schleusner, Jan Runsink, and Gadamsetti S. Babu pp 6617–6631 DOI: 10.1021/ja0433828 Supporting Info

Heterogeneously Catalyzed Aerobic Oxidative Biaryl Coupling of 2-Naphthols and Substituted Phenols in Water Mitsunori Matsushita, Keigo Kamata, Kazuya Yamaguchi, and Noritaka Mizuno pp 6632–6640 DOI: 10.1021/ja050436k Supporting Info

Mechanochromism of Piroxicam Accompanied by Intermolecular Proton Transfer Probed by Spectroscopic Methods and Solid-Phase Changes Agam R. Sheth, Joseph W. Lubach, Eric J. Munson, Francis X. Muller, and David J. W. Grant pp 6641–6651 DOI: 10.1021/ja045823t

Mechanistic Studies on the Cyclization of (Z)-1,2,4-Heptatrien-6-yne in Methanol:  A Possible Nonadiabatic Thermal Reaction Matthew E. Cremeens, Thomas S. Hughes, and Barry K. Carpenter pp 6652–6661 DOI: 10.1021/ja0445443 Supporting Info

Potent and Selective Structure-Based Dibenzofuran Inhibitors of Transthyretin Amyloidogenesis:  Kinetic Stabilization of the Native State H. Michael Petrassi, Steven M. Johnson, Hans E. Purkey, Kyle P. Chiang, Traci Walkup, Xin Jiang, Evan T. Powers, and Jeffery W. Kelly pp 6662–6671 DOI: 10.1021/ja044351f Supporting Info

Neutron Vibrational Spectroscopy Gives New Insights into the Structure of Poly(p-phenylene terephthalamide) M. Plazanet, F. Fontaine-Vive, K. H. Gardner, V. T. Forsyth, A. Ivanov, A. J. Ramirez-Cuesta, and M. R. Johnson pp 6672–6678 DOI: 10.1021/ja0437205 Supporting Info

Isotope Effects and the Nature of Enantioselectivity in the Shi Epoxidation. The Importance of Asynchronicity Daniel A. Singleton and Zhihong Wang pp 6679–6685 DOI: 10.1021/ja0435788 Supporting Info

In Situ Selection of Lead Compounds by Click Chemistry:  Target-Guided Optimization of Acetylcholinesterase Inhibitors Antoni Krasiński, Zoran Radić, Roman Manetsch, Jessica Raushel, Palmer Taylor, K. Barry Sharpless, and Hartmuth C. Kolb pp 6686–6692 DOI: 10.1021/ja043031t Supporting Info

A Theoretical Study of the Iminoxyl/Oxime Self-Exchange Reaction. A Five-Center, Cyclic Proton-Coupled Electron Transfer Gino A. DiLabio and K. U. Ingold pp 6693–6699 DOI: 10.1021/ja0500409 Supporting Info

Determination of Molecular Structure in Solution Using Vibrational Circular Dichroism Spectroscopy:  the Supramolecular Tetramer of S -2,2‘-Dimethyl-Biphenyl-6,6‘-Dicarboxylic Acid M. Urbanová, V. Setnika, F. J. Devlin, and P. J. Stephens pp 6700–6711 DOI: 10.1021/ja050483c Supporting Info

Thermal and Catalyzed [3,3]-Phosphorimidate Rearrangements Bin Chen and Anna K. Mapp pp 6712–6718 DOI: 10.1021/ja050759g Supporting Info

Ultrafast Energy-Electron Transfer Cascade in a Multichromophoric Light-Harvesting Molecular Square Armin Sautter, Başak Kükrer Kaletaş, Dietmar G. Schmid, Rainer Dobrawa, Mikhail Zimine, Günther Jung, Ivo H. M. van Stokkum, Luisa De Cola, René M. Williams, and Frank Würthner pp 6719–6729 DOI: 10.1021/ja0448216 Supporting Info

Phase Transition between Nanostructures of Titanate and Titanium Dioxides via Simple Wet-Chemical Reactions H. Y. Zhu, Y. Lan, X. P. Gao, S. P. Ringer, Z. F. Zheng, D. Y. Song, and J. C. Zhao pp 6730–6736 DOI: 10.1021/ja044689+

The Remarkable Axial Lability of Iron(III) Corrole Complexes Crisjoe A. Joseph and Peter C. Ford pp 6737–6743 DOI: 10.1021/ja044090+ Supporting Info

A Hybrid Quantum Dot−Antibody Fragment Fluorescence Resonance Energy Transfer-Based TNT Sensor Ellen R. Goldman, Igor L. Medintz, Jessica L. Whitley, Andrew Hayhurst, Aaron R. Clapp, H. Tetsuo Uyeda, Jeffrey R. Deschamps, Michael E. Lassman, and Hedi Mattoussi pp 6744–6751 DOI: 10.1021/ja043677l Supporting Info

Phospholipid Morphologies on Photochemically Patterned Silane Monolayers Michael C. Howland, Annapoorna R. Sapuri-Butti, Sanhita S. Dixit, Andrew M. Dattelbaum, Andrew P. Shreve, and Atul N. Parikh pp 6752–6765 DOI: 10.1021/ja043439q Supporting Info

A Charge-Transfer-Induced Spin Transition in a Discrete Complex:  The Role of Extrinsic Factors in Stabilizing Three Electronic Isomeric Forms of a Cyanide-Bridged Co/Fe Cluster Curtis P. Berlinguette, Alina Dragulescu-Andrasi, Andreas Sieber, Hans-Ulrich Güdel, Catalina Achim, and Kim R. Dunbar pp 6766–6779 DOI: 10.1021/ja043162u Supporting Info

Three-Dimensional Low Symmetry Mesoporous Silica Structures Templated from Tetra-Headgroup Rigid Bolaform Quaternary Ammonium Surfactant Shaodian Shen, Alfonso E. Garcia-Bennett, Zheng Liu, Qingyi Lu, Yifeng Shi, Yan Yan, Chengzhong Yu, Weichang Liu, Ya Cai, Osamu Terasaki, and Dongyuan Zhao pp 6780–6787 DOI: 10.1021/ja0502324 Supporting Info

Efficient Preparation of Functionalized Hybrid Organic/Inorganic Wells−Dawson-type Polyoxotungstates Sébastian Bareyt, Stergios Piligkos, Bernold Hasenknopf, Pierre Gouzerh, Emmanuel Lacôte, Serge Thorimbert, and Max Malacria pp 6788–6794 DOI: 10.1021/ja050397c Supporting Info

57Fe-Labeled Octamethylferrocenium Tetrafluoroborate. X-ray Crystal Structures of Conformational Isomers, Hyperfine Interactions, and Spin−Lattice Relaxation by Moessbauer Spectroscopy Herwig Schottenberger, Klaus Wurst, Ulrich J. Griesser, Ram K. R. Jetti, Gerhard Laus, Rolfe H. Herber, and Israel Nowik pp 6795–6801 DOI: 10.1021/ja050452h Supporting Info

Electric Field Induced Switching Behaviors of Monolayer-Modified Silicon Surfaces:  Surface Designs and Molecular Dynamics Simulations Yong Pei and Jing Ma pp 6802–6813 DOI: 10.1021/ja045506m Supporting Info

Ultra-Sensitive Imaging and Interfacial Analysis of Patterned Hydrophilic SAM Surfaces Using Energy Dissipation Chemical Force Microscopy Paul D. Ashby and Charles M. Lieber pp 6814–6818 DOI: 10.1021/ja0453127 Supporting Info

The Effect of the Particle Size on the Kinetics of CO Electrooxidation on High Surface Area Pt Catalysts Matthias Arenz, Karl J. J. Mayrhofer, Vojislav Stamenkovic, Berislav B. Blizanac, Tada Tomoyuki, Phil N. Ross, and Nenad M. Markovic pp 6819–6829 DOI: 10.1021/ja043602h Supporting Info

Water at a Hydrophilic Solid Surface Probed by Ab initio Molecular Dynamics:  Inhomogeneous Thin Layers of Dense Fluid Giancarlo Cicero, Jeffrey C. Grossman, Alessandra Catellani, and Giulia Galli pp 6830–6835 DOI: 10.1021/ja042963u

Electrostatic Recognition and Induced Fit in the κ-PVIIA Toxin Binding to Shaker Potassium Channel Xiaoqin Huang, Feng Dong, and Huan-Xiang Zhou pp 6836–6849 DOI: 10.1021/ja042641q Supporting Info

Charge Separation and Efficient Light Energy Conversion in Sensitized Mesoscopic Solar Cells Based on Binary Ionic Liquids Peng Wang, Bernard Wenger, Robin Humphry-Baker, Jacques-E. Moser, Joël Teuscher, Willi Kantlehner, Jochen Mezger, Edmont V. Stoyanov, Shaik M. Zakeeruddin, and Michael Grätzel pp 6850–6856 DOI: 10.1021/ja042232u Supporting Info

Ultrafast Dynamics of 2E State Formation in Cr(acac)3 Eric A. Juban and James K. McCusker pp 6857–6865 DOI: 10.1021/ja042153i

Free Energy Landscape of A-DNA to B-DNA Conversion in Aqueous Solution Nilesh K. Banavali and Benoît Roux pp 6866–6876 DOI: 10.1021/ja050482k Supporting Info

A Readily Available Chiral Ag-Based N-Heterocyclic Carbene Complex for Use in Efficient and Highly Enantioselective Ru-Catalyzed Olefin Metathesis and Cu-Catalyzed Allylic Alkylation Reactions Joshua J. Van Veldhuizen, John E. Campbell, Russell E. Giudici, and Amir H. Hoveyda pp 6877–6882 DOI: 10.1021/ja050179j Supporting Info

Photochemistry of an Azido-Functionalized Cryptand:  Controlling the Reactivity of an Extremely Long-Lived Singlet Aryl Nitrene by Complexation to Alkali Cations Götz Bucher, Christina Tönshoff, and Athanassios Nicolaides pp 6883–6892 DOI: 10.1021/ja0447208 Supporting Info

A Suite of 2H NMR Spin Relaxation Experiments for the Measurement of RNA Dynamics Pramodh Vallurupalli and Lewis E. Kay pp 6893–6901 DOI: 10.1021/ja0427799 Supporting Info

Theoretical Study of the Suicide Inhibition Mechanism of the Enzyme Pyruvate Formate Lyase by Methacrylate Maria de Fátima Lucas and Maria João Ramos pp 6902–6909 DOI: 10.1021/ja047699j Supporting Info

Efficient Synthesis of Optically Active Atropisomeric Anilides through Catalytic Asymmetric N-Arylation Reaction [J. Am. Chem. Soc. 2005, 127, 3676−3677]. Osamu Kitagawa, Masashi Takahashi, Masatoshi Yoshikawa, and Takeo Taguchi p 6910 DOI: 10.1021/ja051606w

Long-Range Charge Transfer in DNA I and Long-Range Charge Transfer in DNA II. Topics in Current Chemistry, 236 and 237, respectively Edited by Gary B. Schuster (Georgia Institute of Technology). Springer-Verlag:  Berlin, Heidelberg, New York. x + 200 pp. $189.00. ISBN 3-540-20127-0 (for DNA I) and x + 244 pp. $199.00. ISBN 3-540-20131-9 (for DNA II). Bruce E. Eaton and Jonathan Vaught pp 6911–6912 DOI: 10.1021/ja040960b

Issue 19

Deoxyribozyme-Based Ligase Logic Gates and Their Initial Circuits Milan N. Stojanovic, Stanka Semova, Dmitry Kolpashchikov, Joanne Macdonald, Clint Morgan, and Darko Stefanovic pp 6914–6915 DOI: 10.1021/ja043003a Supporting Info

Carbon Nanotubes with Covalently Linked Porphyrin Antennae:  Photoinduced Electron Transfer Durairaj Baskaran, Jimmy W. Mays, X. Peter Zhang, and Matthew S. Bratcher pp 6916–6917 DOI: 10.1021/ja0508222 Supporting Info

Long-Range Ordered Thin Films of Block Copolymers Prepared by Zone-Casting and Their Thermal Conversion into Ordered Nanostructured Carbon Chuanbing Tang, Adam Tracz, Michal Kruk, Rui Zhang, Detlef-M. Smilgies, Krzysztof Matyjaszewski, and Tomasz Kowalewski pp 6918–6919 DOI: 10.1021/ja0508929 Supporting Info

Stereoselective Enolizations Mediated by Magnesium and Calcium Bisamides: Contrasting Aggregation Behavior in Solution and in the Solid State Xuyang He, John F. Allan, Bruce C. Noll, Alan R. Kennedy, and Kenneth W. Henderson pp 6920–6921 DOI: 10.1021/ja051050c Supporting Info

Selective Functionalization of In2O3 Nanowire Mat Devices for Biosensing Applications Marco Curreli, Chao Li, Yinghua Sun, Bo Lei, Martin A. Gundersen, Mark E. Thompson, and Chongwu Zhou pp 6922–6923 DOI: 10.1021/ja0503478 Supporting Info

Diastereoselective [4+2] Annulation of Vinyl Carbodiimides with N-Alkyl Imines. Asymmetric Synthetic Access to the Batzelladine Alkaloids Michael A. Arnold, Sergio G. Durón, and David Y. Gin pp 6924–6925 DOI: 10.1021/ja0519029 Supporting Info

Mild Oxidative One-Carbon Homologation of Aldehyde to Amide Damien Bonne, Mouloud Dekhane, and Jieping Zhu pp 6926–6927 DOI: 10.1021/ja0511220 Supporting Info

Parallel Transformations of Cyclohexene Mediated by the Cp*W(NO) Fragment Xing Jin, Peter Legzdins, and Miriam S. A. Buschhaus pp 6928–6929 DOI: 10.1021/ja0426692 Supporting Info

“Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications Masayuki Okajima, Seiji Suga, Kenichiro Itami, and Jun-ichi Yoshida pp 6930–6931 DOI: 10.1021/ja050414y Supporting Info

Nickel-Catalyzed Intermolecular Alkyne Insertion into Cyclobutanones Masahiro Murakami, Shinji Ashida, and Takanori Matsuda pp 6932–6933 DOI: 10.1021/ja050674f Supporting Info

Mesoporous Silica Composites Containing Multiple Regions with Distinct Pore Size and Complex Pore Organization Anthony Y. Ku, Seth T. Taylor, and Sergio M. Loureiro pp 6934–6935 DOI: 10.1021/ja042202r Supporting Info

Amplification of Changes of a Thin Film's Macromolecular Structure into Macroscopic Reaction−Diffusion Patterns Agnieszka Bitner, Marcin Fiałkowski, Stoyan K. Smoukov, Christopher J. Campbell, and Bartosz A. Grzybowski pp 6936–6937 DOI: 10.1021/ja051128p Supporting Info

Photoisomerization of cis-1-(2-Naphthyl)-2-phenylethene in Methylcyclohexane at 77 K:  No Hula-Twist Jack Saltiel, Tallapragada S. R. Krishna, and Andrzej M. Turek pp 6938–6939 DOI: 10.1021/ja051196b

Multiple-Steering QM−MM Calculation of the Free Energy Profile in Chorismate Mutase Alejandro Crespo, Marcelo A. Martí, Darío A. Estrin, and Adrian E. Roitberg pp 6940–6941 DOI: 10.1021/ja0452830 Supporting Info

Strong Attraction among the Fully Hydrophilic {Mo72Fe30} Macroanions Guang Liu and Tianbo Liu pp 6942–6943 DOI: 10.1021/ja0510966

Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands Fabiola Barrios-Landeros and John F. Hartwig pp 6944–6945 DOI: 10.1021/ja042959i Supporting Info

One-Pot Regio- and Stereoselective Cyclization of 1,2,n-Triols Tao Zheng, Radha S. Narayan, Jennifer M. Schomaker, and Babak Borhan pp 6946–6947 DOI: 10.1021/ja043002i Supporting Info

Total Synthesis of (−)-Kendomycin Exploiting a Petasis−Ferrier Rearrangement/Ring-Closing Olefin Metathesis Synthetic Strategy Amos B. Smith, III, Eugen F. Mesaros, and Emmanuel A. Meyer pp 6948–6949 DOI: 10.1021/ja051420x Supporting Info

Alkyne Haloallylation [with Pd(II)] as a Core Strategy for Macrocycle Synthesis:  A Total Synthesis of (−)-Haterumalide NA/(−)-Oocydin A Thomas R. Hoye and Jizhou Wang pp 6950–6951 DOI: 10.1021/ja051749i Supporting Info

Alkenyl- and Aryl[2-(hydroxymethyl)phenyl]dimethylsilanes:  An Entry to Tetraorganosilicon Reagents for the Silicon-Based Cross-Coupling Reaction Yoshiaki Nakao, Hidekazu Imanaka, Akhila K. Sahoo, Akira Yada, and Tamejiro Hiyama pp 6952–6953 DOI: 10.1021/ja051281j Supporting Info

Stable Mononuclear Radical Anions of Heavier Group 13 Elements:  [(tBu2MeSi)3E•-]·[K+(2.2.2-Cryptand)] (E = Al, Ga) Masaaki Nakamoto, Tomoki Yamasaki, and Akira Sekiguchi pp 6954–6955 DOI: 10.1021/ja051814o Supporting Info

Highly Sodium-Selective Fluoroionophore Based on Conformational Restriction of Oligoethyleneglycol-Bridged Biaryl Boron−Dipyrromethene Koji Yamada, Yuki Nomura, Daniel Citterio, Naoko Iwasawa, and Koji Suzuki pp 6956–6957 DOI: 10.1021/ja042414o Supporting Info

A 2D Solid-State NMR Experiment To Resolve Overlapping Aromatic Resonances of Thiophene-Based Nematogens Tanneru Narasimhaswamy, Dong-Kuk Lee, Kazutoshi Yamamoto, Narayanasastri Somanathan, and Ayyalusamy Ramamoorthy pp 6958–6959 DOI: 10.1021/ja051160j Supporting Info

Polymer Electrolyte Gate Dielectric Reveals Finite Windows of High Conductivity in Organic Thin Film Transistors at High Charge Carrier Densities Matthew J. Panzer and C. Daniel Frisbie pp 6960–6961 DOI: 10.1021/ja051579+

Gold-Catalyzed Assembly of Heterobicyclic Systems Liming Zhang and Sergey A. Kozmin pp 6962–6963 DOI: 10.1021/ja051110e Supporting Info

Asymmetric Organocatalytic Epoxidation of α,β-Unsaturated Aldehydes with Hydrogen Peroxide Mauro Marigo, Johan Franzén, Thomas B. Poulsen, Wei Zhuang, and Karl Anker Jørgensen pp 6964–6965 DOI: 10.1021/ja051808s Supporting Info

Gold(I)-Catalyzed Intermolecular Addition of Phenols and Carboxylic Acids to Olefins Cai-Guang Yang and Chuan He pp 6966–6967 DOI: 10.1021/ja050392f Supporting Info

CuBr-Catalyzed Direct Indolation of Tetrahydroisoquinolines via Cross-Dehydrogenative Coupling between sp3 C−H and sp2 C−H Bonds Zhiping Li and Chao-Jun Li pp 6968–6969 DOI: 10.1021/ja0516054 Supporting Info

Serial Ligand Catalysis:  A Highly Selective Allylic C−H Oxidation Mark S. Chen, Narayanasamy Prabagaran, Nathan A. Labenz, and M. Christina White pp 6970–6971 DOI: 10.1021/ja0500198 Supporting Info

High Performance of Rh(Phebox) Catalysts in Asymmetric Reductive Aldol Reaction:  High Anti-Selectivity Hisao Nishiyama, Takushi Shiomi, Yasunori Tsuchiya, and Isamu Matsuda pp 6972–6973 DOI: 10.1021/ja050698m Supporting Info

Detection of a High-Barrier Conformational Change in the Active Site of Cytochrome P450cam upon Binding of Putidaredoxin Julie Y. Wei, Thomas C. Pochapsky, and Susan Sondej Pochapsky pp 6974–6976 DOI: 10.1021/ja051195j Supporting Info

Electron Transfer and Catalytic Control by the Iron−Sulfur Clusters in a Respiratory Enzyme, E. coli Fumarate Reductase Janette M. Hudson, Kerensa Heffron, Violetta Kotlyar, Yelizaveta Sher, Elena Maklashina, Gary Cecchini, and Fraser A. Armstrong pp 6977–6989 DOI: 10.1021/ja043404q Supporting Info

Disodium Guanosine 5‘-Monophosphate Self-Associates into Nanoscale Cylinders at pH 8:  A Combined Diffusion NMR Spectroscopy and Dynamic Light Scattering Study Alan Wong, Ramsey Ida, Lea Spindler, and Gang Wu pp 6990–6998 DOI: 10.1021/ja042794d

Design, Synthesis, and Biological Evaluation of HSP90 Inhibitors Based on Conformational Analysis of Radicicol and Its Analogues Emilie Moulin, Vincent Zoete, Sofia Barluenga, Martin Karplus, and Nicolas Winssinger pp 6999–7004 DOI: 10.1021/ja043101w Supporting Info

ENDOR Studies of the Ligation and Structure of the Non-Heme Iron Site in ACC Oxidase David L. Tierney, Amy M. Rocklin, John D. Lipscomb, Lawrence Que, Jr., and Brian M. Hoffman pp 7005–7013 DOI: 10.1021/ja0500862 Supporting Info

Development of Aliphatic Alcohols as Nucleophiles for Palladium-Catalyzed DYKAT Reactions:  Total Synthesis of (+)-Hippospongic Acid A Barry M. Trost, Michelle R. Machacek, and Hong C. Tsui pp 7014–7024 DOI: 10.1021/ja050340q Supporting Info

Dynamic and Structural NMR Studies of Cavitand-Based Coordination Cages Daniele Zuccaccia, Laura Pirondini, Roberta Pinalli, Enrico Dalcanale, and Alceo Macchioni pp 7025–7032 DOI: 10.1021/ja042265+

Intramolecular General Acid Catalysis of Phosphate Transfer. Nucleophilic Attack by Oxyanions on the PO32- Group Anthony J. Kirby, Neil Dutta-Roy, Davi da Silva, Jonathan M. Goodman, Marcelo F. Lima, Christo D. Roussev, and Faruk Nome pp 7033–7040 DOI: 10.1021/ja0502876 Supporting Info

External Electric Field Effects on State Energy and Photoexcitation Dynamics of Diphenylpolyenes Takakazu Nakabayashi, Md. Wahadoszamen, and Nobuhiro Ohta pp 7041–7052 DOI: 10.1021/ja0401444

Stepwise Hydration of Ionized Aromatics. Energies, Structures of the Hydrated Benzene Cation, and the Mechanism of Deprotonation Reactions Yehia M. Ibrahim, Michael Meot-Ner (Mautner), Edreese H. Alshraeh, M. Samy El-Shall, and Steve Scheiner pp 7053–7064 DOI: 10.1021/ja050477g Supporting Info

Picosecond Dynamics of Nonthermalized Excited States in Tris(2,2-bipyridine)ruthenium(II) Derivatives Elucidated by High Energy Excitation Sherri A. McFarland, Felix S. Lee, Karen A. W. Y. Cheng, Frances L. Cozens, and Norman P. Schepp pp 7065–7070 DOI: 10.1021/ja0461872 Supporting Info

A Combined Theoretical and Experimental Study of Efficient and Fast Titanocene-Catalyzed 3-exo Cyclizations Joachim Friedrich, Michael Dolg, Andreas Gansäuer, Daniel Geich-Gimbel, and Thorsten Lauterbach pp 7071–7077 DOI: 10.1021/ja050268w Supporting Info

Preparation of Copper Ion Complexes of Sterically Congested Diaryldiazomethanes Having a Pyridine Ligand and Characterization of Their Photoproducts Tetsuji Itoh, Masayoshi Matsuno, Eiko Kamiya, Katsuyuki Hirai, and Hideo Tomioka pp 7078–7093 DOI: 10.1021/ja0424225 Supporting Info

On the Electrophilicity of Hydroxyl Radical:  A Laser Flash Photolysis and Computational Study Matthew P. DeMatteo, James S. Poole, Xiaofeng Shi, Rakesh Sachdeva, Patrick G. Hatcher, Christopher M. Hadad, and Matthew S. Platz pp 7094–7109 DOI: 10.1021/ja043692q Supporting Info

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra Andrea C. Sudik, Andrew R. Millward, Nathan W. Ockwig, Adrien P. Côté, Jaheon Kim, and Omar M. Yaghi pp 7110–7118 DOI: 10.1021/ja042802q Supporting Info

Intramolecular Charge Transfer in 4-Aminobenzonitriles Does Not Necessarily Need the Twist Isabel Gómez, Mar Reguero, Martial Boggio-Pasqua, and Michael A. Robb pp 7119–7129 DOI: 10.1021/ja042413w Supporting Info

A Direct Comparison of One- and Two-Component Dendritic Self-Assembled Materials:  Elucidating Molecular Recognition Pathways Buqing Huang, Andrew R. Hirst, David K. Smith, Valeria Castelletto, and Ian W. Hamley pp 7130–7139 DOI: 10.1021/ja050412d Supporting Info

Designing PbSe Nanowires and Nanorings through Oriented Attachment of Nanoparticles Kyung-Sang Cho, Dmitri V. Talapin, Wolfgang Gaschler, and Christopher B. Murray pp 7140–7147 DOI: 10.1021/ja050107s Supporting Info

Spin-State Tuning at Pseudotetrahedral d7 Ions:  Examining the Structural and Magnetic Phenomena of Four-Coordinate [BP3]CoII−X Systems David M. Jenkins and Jonas C. Peters pp 7148–7165 DOI: 10.1021/ja045310m Supporting Info

Controllable Water Channel Gating of Nanometer Dimensions Rongzheng Wan, Jingyuan Li, Hangjun Lu, and Haiping Fang pp 7166–7170 DOI: 10.1021/ja050044d Supporting Info

Cyclocarbopalladation Involving an Unusual 1,5-Palladium Vinyl to Aryl Shift as Termination Step:  Theoretical Study of the Mechanism Antonio J. Mota, Alain Dedieu, Christophe Bour, and Jean Suffert pp 7171–7182 DOI: 10.1021/ja050453+ Supporting Info

Molecular Manipulation of Two- and Three-Dimensional Silica Nanostructures by Alkoxysilylation of a Layered Silicate Octosilicate and Subsequent Hydrolysis of Alkoxy Groups Dai Mochizuki, Atsushi Shimojima, Takeshi Imagawa, and Kazuyuki Kuroda pp 7183–7191 DOI: 10.1021/ja042194e Supporting Info

Simulations on the Thermal Decomposition of a Poly(dimethylsiloxane) Polymer Using the ReaxFF Reactive Force Field Kimberly Chenoweth, Sam Cheung, Adri C. T. van Duin, William A. Goddard III, and Edward M. Kober pp 7192–7202 DOI: 10.1021/ja050980t Supporting Info

Electron Binding Energies of Aqueous Alkali and Halide Ions:  EUV Photoelectron Spectroscopy of Liquid Solutions and Combined Ab Initio and Molecular Dynamics Calculations Bernd Winter, Ramona Weber, Ingolf V. Hertel, Manfred Faubel, Pavel Jungwirth, Eric C. Brown, and Stephen E. Bradforth pp 7203–7214 DOI: 10.1021/ja042908l

An Efficient Fragment-Based Approach for Predicting the Ground-State Energies and Structures of Large Molecules Shuhua Li, Wei Li, and Tao Fang pp 7215–7226 DOI: 10.1021/ja0427247 Supporting Info

Quantum-Chemical Predictions of Absolute Standard Redox Potentials of Diverse Organic Molecules and Free Radicals in Acetonitrile Yao Fu, Lei Liu, Hai-Zhu Yu, Yi-Min Wang, and Qing-Xiang Guo pp 7227–7234 DOI: 10.1021/ja0421856 Supporting Info

Probing Charge-Transfer Processes in Helium Nanodroplets by Optically Selected Mass Spectrometry (OSMS):  Charge Steering by Long-Range Interactions William K. Lewis, C. Michael Lindsay, Raymond J. Bemish, and Roger E. Miller pp 7235–7242 DOI: 10.1021/ja042489s

Infrared Spectroscopy of Gas-Phase Cr+ Coordination Complexes:  Determination of Binding Sites and Electronic States David T. Moore, Jos Oomens, John R. Eyler, Gert von Helden, Gerard Meijer, and Robert C. Dunbar pp 7243–7254 DOI: 10.1021/ja042431d Supporting Info

Substrate-Mediated Intermolecular Interactions:  A Quantitative Single Molecule Analysis E. Charles H. Sykes, Brent A. Mantooth, Patrick Han, Zachary J. Donhauser, and Paul S. Weiss pp 7255–7260 DOI: 10.1021/ja0472331 Supporting Info

Refinement of the Conformation of UDP−Galactose Bound to Galactosyltransferase Using the STD NMR Intensity-Restrained CORCEMA Optimization [J. Am. Chem. Soc. 2004, 126, 8610−8611]. V. Jayalakshmi, Thorsten Biet, Thomas Peters, and N. Rama Krishna p 7261 DOI: 10.1021/ja059907t

Fabrication of Colloidal Crystals with Tubular-like Packings  [J. Am. Chem. Soc. 2005, 127, 3268−3269]. Feng Li, Xavier Badel, Jan Linnros, and John B. Wiley p 7262 DOI: 10.1021/ja052158v

Total Synthesis of Cribrostatin IV:  Fine-Tuning the Character of an Amide Bond by Remote Control   [J. Am. Chem. Soc. 2005, 127, 4596−4598].  Collin Chan, Richard Heid, Shengping Zheng, Jinsong Guo, Bishan Zhou, Takeshi Furuuchi, and Samuel J. Danishefsky p 7262 DOI: 10.1021/ja059909d

Issue 20

Osmium Diboride, An Ultra-Incompressible, Hard Material Robert W. Cumberland, Michelle B. Weinberger, John J. Gilman, Simon M. Clark, Sarah H. Tolbert, and Richard B. Kaner pp 7264–7265 DOI: 10.1021/ja043806y

4-Connected Metal−Organic Assemblies Mediated via Heterochelation and Bridging of Single Metal Ions:  Kagomé Lattice and the M6L12 Octahedron Yunling Liu, Victor Ch. Kravtsov, Derek A. Beauchamp, Jarrod F. Eubank, and Mohamed Eddaoudi pp 7266–7267 DOI: 10.1021/ja051259q Supporting Info

Chemically Modified Opals as Thin Permselective Nanoporous Membranes Michael R. Newton, Andrew K. Bohaty, Henry S. White, and Ilya Zharov pp 7268–7269 DOI: 10.1021/ja043275d Supporting Info

Power-Law Solvation Dynamics in DNA over Six Decades in Time Daniele Andreatta, J. Louis Pérez Lustres, Sergey A. Kovalenko, Nikolaus P. Ernsting, Catherine J. Murphy, Robert S. Coleman, and Mark A. Berg pp 7270–7271 DOI: 10.1021/ja044177v Supporting Info

Chiral Discrimination in Photochromic Helicenes Tony J. Wigglesworth, David Sud, Tyler B. Norsten, Vikram S. Lekhi, and Neil R. Branda pp 7272–7273 DOI: 10.1021/ja050190j Supporting Info

Axial Methionine Has Much Less Influence on Reduction Potentials in a CuA Center than in a Blue Copper Center Hee Jung Hwang, Steven M. Berry, Mark J. Nilges, and Yi Lu pp 7274–7275 DOI: 10.1021/ja0501114 Supporting Info

η1:η2-Alkynyl-Bridged W−Si Complexes:  Formation, Structure, and Reaction with Acetone Hiroyuki Sakaba, Mako Yoshida, Chizuko Kabuto, and Kuninobu Kabuto pp 7276–7277 DOI: 10.1021/ja050441o Supporting Info

Nitrosoarene−Cu(I) Complexes Are Intermediates in Copper-Catalyzed Allylic Amination Radhey S. Srivastava, Masood A. Khan, and Kenneth M. Nicholas pp 7278–7279 DOI: 10.1021/ja044093m Supporting Info

Combining Microfluidic Networks and Peptide Arrays for Multi-Enzyme Assays Jing Su, Michelle R. Bringer, Rustem F. Ismagilov, and Milan Mrksich pp 7280–7281 DOI: 10.1021/ja051371o Supporting Info

Two-Photon Absorption at Telecommunications Wavelengths in a Dipolar Chromophore with a Pyrrole Auxiliary Donor and Thiazole Auxiliary Acceptor Luca Beverina, Jie Fu, Amalia Leclercq, Egbert Zojer, Peter Pacher, Stephen Barlow, Eric W. Van Stryland, David J. Hagan, Jean-Luc Brédas, and Seth R. Marder pp 7282–7283 DOI: 10.1021/ja050688l Supporting Info

Catalytic Enantioselective Thioester Aldol Reactions That Are Compatible with Protic Functional Groups Derek Magdziak, Gojko Lalic, Hong Myung Lee, Kevin C. Fortner, Allen D. Aloise, and Matthew D. Shair pp 7284–7285 DOI: 10.1021/ja051759j Supporting Info

14-Hydroxylation of Opiates:  Catalytic Direct Autoxidation of Codeinone to 14-Hydroxycodeinone Qibo Zhang, Joseph O. Rich, Ian C. Cotterill, David P. Pantaleone, and Peter C. Michels pp 7286–7287 DOI: 10.1021/ja051682z Supporting Info

Catalytic and Asymmetric Vinylogous Mukaiyama Reactions on Aliphatic Ketones:  Formal Asymmetric Synthesis of Taurospongin A Xavier Moreau, Belen Bazán-Tejeda, and Jean-Marc Campagne pp 7288–7289 DOI: 10.1021/ja051573k Supporting Info

Total Synthesis of Mycalamide A Jeong-Hun Sohn, Nobuaki Waizumi, H. Marlon Zhong, and Viresh H. Rawal pp 7290–7291 DOI: 10.1021/ja050728l Supporting Info

2D Correlation Analysis of the Continuum in Single Molecule Surface Enhanced Raman Spectroscopy Amy A. Moore, Michele L. Jacobson, Nadia Belabas, Kathy L. Rowlen, and David M. Jonas pp 7292–7293 DOI: 10.1021/ja043651u

Fixation of Both O2 and CO2 from Air by a Crystalline Palladium Complex Bearing N-Heterocyclic Carbene Ligands Makoto Yamashita, Kei Goto, and Takayuki Kawashima pp 7294–7295 DOI: 10.1021/ja051054h Supporting Info

Hydrophobically Assisted Switching Phase Synthesis:  The Flexible Combination of Solid-Phase and Solution-Phase Reactions Employed for Oligosaccharide Preparation Jörg Bauer and Jörg Rademann pp 7296–7297 DOI: 10.1021/ja051737x Supporting Info

Sol−Gel Reaction of Porphyrin-Based Superstructures in the Organogel Phase:  Creation of Mechanically Reinforced Porphyrin Hybrids Takanori Kishida, Norifumi Fujita, Kazuki Sada, and Seiji Shinkai pp 7298–7299 DOI: 10.1021/ja050563g Supporting Info

Quantum Control of a Chiral Molecular Motor Driven by Laser Pulses Masahiro Yamaki, Kunihito Hoki, Yukiyoshi Ohtsuki, Hirohiko Kono, and Yuichi Fujimura pp 7300–7301 DOI: 10.1021/ja0437757

Ionic Liquid-in-Oil Microemulsions Julian Eastoe, Sarah Gold, Sarah E. Rogers, Alison Paul, Tom Welton, Richard K. Heenan, and Isabelle Grillo pp 7302–7303 DOI: 10.1021/ja051155f Supporting Info

Syntheses of Shell Cross-Linked Micelles Using Acidic ABC Triblock Copolymers and Their Application as pH-Responsive Particulate Emulsifiers Syuji Fujii, Yuanli Cai, Jonathan V. M. Weaver, and Steven P. Armes pp 7304–7305 DOI: 10.1021/ja050049a Supporting Info

Dual Species Emission from Single Polyfluorene Molecules:  Signatures of Stress-Induced Planarization of Single Polymer Chains Klaus Becker and John M. Lupton pp 7306–7307 DOI: 10.1021/ja051583l

Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes Grégory L. J. Bar, Guy C. Lloyd-Jones, and Kevin I. Booker-Milburn pp 7308–7309 DOI: 10.1021/ja051181d Supporting Info

Escherichia coli Quinolinate Synthetase Does Indeed Harbor a [4Fe-4S] Cluster Robert M. Cicchillo, Loretta Tu, Jeffrey A. Stromberg, Lee M. Hoffart, Carsten Krebs, and Squire J. Booker pp 7310–7311 DOI: 10.1021/ja051369x Supporting Info

Persistent (Amino)(Silyl)Carbenes Yves Canac, Salvador Conejero, Bruno Donnadieu, Wolfgand W. Schoeller, and Guy Bertrand pp 7312–7313 DOI: 10.1021/ja051109f Supporting Info

Structural Understanding of a Molecular Material that Is Accessed Only by a Solid-State Desolvation Process:  The Scope of Modern Powder X-ray Diffraction Techniques Fang Guo and Kenneth D. M. Harris pp 7314–7315 DOI: 10.1021/ja050733p Supporting Info

Magnetic Nanotubes for Magnetic-Field-Assisted Bioseparation, Biointeraction, and Drug Delivery Sang Jun Son, Jonathan Reichel, Bo He, Mattan Schuchman, and Sang Bok Lee pp 7316–7317 DOI: 10.1021/ja0517365 Supporting Info

A Class of Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenations of Ketones Aidan M. Hayes, David J. Morris, Guy J. Clarkson, and Martin Wills pp 7318–7319 DOI: 10.1021/ja051486s Supporting Info

Highly Enantioselective and Regioselective Nickel-Catalyzed Coupling of Allenes, Aldehydes, and Silanes Sze-Sze Ng and Timothy F. Jamison pp 7320–7321 DOI: 10.1021/ja0521831 Supporting Info

What Is the Effective Charge of TGA-Stabilized CdTe Nanocolloids? Alexander A. Yaroslavov, Vladimir A. Sinani, Anna A. Efimova, Ekaterina G. Yaroslavova, Anna A. Rakhnyanskaya, Yury A. Ermakov, and Nicholas A. Kotov pp 7322–7323 DOI: 10.1021/ja051095d

Radical Addition to “Cation Pool”. Reverse Process of Radical Cation Fragmentation Tomokazu Maruyama, Seiji Suga, and Jun-ichi Yoshida pp 7324–7325 DOI: 10.1021/ja0511218 Supporting Info

Low-Temperature Polyol Synthesis of AuCuSn2 and AuNiSn2:  Using Solution Chemistry to Access Ternary Intermetallic Compounds as Nanocrystals Brian M. Leonard, Nattamai S. P. Bhuvanesh, and Raymond E. Schaak pp 7326–7327 DOI: 10.1021/ja051481v Supporting Info

Dithiocarbamate Assembly on Gold Yan Zhao, Waleska Pérez-Segarra, Qicun Shi, and Alexander Wei pp 7328–7329 DOI: 10.1021/ja050432f Supporting Info

Oxidative C−H Activation/C−C Bond Forming Reactions:  Synthetic Scope and Mechanistic Insights Dipannita Kalyani, Nicholas R. Deprez, Lopa V. Desai, and Melanie S. Sanford pp 7330–7331 DOI: 10.1021/ja051402f Supporting Info

Understanding the Role of Oxidative Etching in the Polyol Synthesis of Pd Nanoparticles with Uniform Shape and Size Yujie Xiong, Jingyi Chen, Benjamin Wiley, and Younan XiaShaul Aloni and Yadong Yin pp 7332–7333 DOI: 10.1021/ja0513741 Supporting Info

Isocomplestatin:  Total Synthesis and Stereochemical Revision Toshio Shinohara, Hongbo Deng, Marc L. Snapper, and Amir H. Hoveyda pp 7334–7336 DOI: 10.1021/ja051790l Supporting Info

Probing the Interior of Peptide Amphiphile Supramolecular Aggregates John D. Tovar, Randal C. Claussen, and Samuel I. Stupp pp 7337–7345 DOI: 10.1021/ja043764d Supporting Info

Cytosine Catalysis of Nitrosative Guanine Deamination and Interstrand Cross-Link Formation Rainer Glaser, Hong Wu, and Michael Lewis pp 7346–7358 DOI: 10.1021/ja0501159 Supporting Info

Aziridine-2-carboxylic Acid-Containing Peptides:  Application to Solution- and Solid-Phase Convergent Site-Selective Peptide Modification Danica P. Galonić, Nathan D. Ide, Wilfred A. van der Donk, and David Y. Gin pp 7359–7369 DOI: 10.1021/ja050304r Supporting Info

Reactions of the Peroxo Intermediate of Soluble Methane Monooxygenase Hydroxylase with Ethers Laurance G. Beauvais and Stephen J. Lippard pp 7370–7378 DOI: 10.1021/ja050865i Supporting Info

Molecular Recognition of Saccharides by Proteins. Insights on the Origin of the Carbohydrate−Aromatic Interactions María del Carmen Fernández-Alonso, Francisco Javier Cañada, Jesús Jiménez-Barbero, and Gabriel Cuevas pp 7379–7386 DOI: 10.1021/ja051020+ Supporting Info

Measurement of Ribose Carbon Chemical Shift Tensors for A-form RNA by Liquid Crystal NMR Spectroscopy David L. Bryce, Alexander Grishaev, and Ad Bax pp 7387–7396 DOI: 10.1021/ja051039c Supporting Info

Ionic Thermotropic Liquid Crystal Dendrimers Rafael Martín-Rapún, Mercedes Marcos, Ana Omenat, Joaquín Barberá, Pilar Romero, and José L. Serrano pp 7397–7403 DOI: 10.1021/ja042264h Supporting Info

PEG- and Peptide-Grafted Aliphatic Polyesters by Click Chemistry Bryan Parrish, Rebecca B. Breitenkamp, and Todd Emrick pp 7404–7410 DOI: 10.1021/ja050310n Supporting Info

Intermolecular Electron-Transfer Mechanisms via Quantitative Structures and Ion-Pair Equilibria for Self-Exchange of Anionic (Dinitrobenzenide) Donors Sergiy V. Rosokha, Jian-Ming Lü, Marshall D. Newton, and Jay K. Kochi pp 7411–7420 DOI: 10.1021/ja051063q Supporting Info

Targeting the Tumor-Associated Folate Receptor with an 111In−DTPA Conjugate of Pteroic Acid Chun-Yen Ke, Carla J. Mathias, and Mark A. Green pp 7421–7426 DOI: 10.1021/ja043006n Supporting Info

Kinetic Analysis of an Efficient DNA-Dependent TNA Polymerase Allen Horhota, Keyong Zou, Justin K. Ichida, Biao Yu, Larry W. McLaughlin, Jack W. Szostak, and John C. Chaput pp 7427–7434 DOI: 10.1021/ja0428255 Supporting Info

Solvatochromism of Distyrylbenzene Pairs Bound Together by [2.2]Paracyclophane:  Evidence for a Polarizable “Through-Space” Delocalized State Janice W. Hong, Han Young Woo, Bin Liu, and Guillermo C. Bazan pp 7435–7443 DOI: 10.1021/ja044326+ Supporting Info

Mechanism of Enyne Metathesis Catalyzed by Grubbs Ruthenium−Carbene Complexes:  A DFT Study Jörg J. Lippstreu and Bernd F. Straub pp 7444–7457 DOI: 10.1021/ja042622g Supporting Info

Unexpected Stability of Aryl β-N-Acetylneuraminides in Neutral Solution:  Biological Implications for Sialyl Transfer Reactions Veedeeta Dookhun and Andrew J. Bennet pp 7458–7465 DOI: 10.1021/ja042280e Supporting Info

The Gas-Phase Acidity of 2(3H)-Oxepinone:  A Step toward an Experimental Heat of Formation for the 2-Oxepinoxy Radical Steven M. Kroner, Matthew P. DeMatteo, Christopher M. Hadad, and Barry K. Carpenter pp 7466–7473 DOI: 10.1021/ja050173u Supporting Info

Facile Preparation of Various Heteroaromatic Compounds via Azatitanacyclopentadiene Intermediates Daisuke Suzuki, Youhei Nobe, Yuko Watai, Ryoichi Tanaka, Yuuki Takayama, Fumie Sato, and Hirokazu Urabe pp 7474–7479 DOI: 10.1021/ja0502730 Supporting Info

Synthesis and Characterization of Highly Luminescent CdSe−Core CdS/Zn0.5Cd0.5S/ZnS Multishell Nanocrystals Renguo Xie, Ute Kolb, Jixue Li, Thomas Basché, and Alf Mews pp 7480–7488 DOI: 10.1021/ja042939g Supporting Info

Brightly Phosphorescent Trinuclear Copper(I) Complexes of Pyrazolates:  Substituent Effects on the Supramolecular Structure and Photophysics H. V. Rasika Dias, Himashinie V. K. Diyabalanage, Maha G. Eldabaja, Oussama Elbjeirami, Manal A. Rawashdeh-Omary, and Mohammad A. Omary pp 7489–7501 DOI: 10.1021/ja0427146 Supporting Info

Discovery and High-Throughput Screening of Heteroleptic Iridium Complexes for Photoinduced Hydrogen Production Jonas I. Goldsmith, William R. Hudson, Michael S. Lowry, Timothy H. Anderson, and Stefan Bernhard pp 7502–7510 DOI: 10.1021/ja0427101 Supporting Info

Quantum Effects on Hydrogen Isotope Adsorption on Single-Wall Carbon Nanohorns Hideki Tanaka, Hirofumi Kanoh, Masako Yudasaka, Sumio Iijima, and Katsumi Kaneko pp 7511–7516 DOI: 10.1021/ja0502573

NMR Detection of Single-Walled Carbon Nanotubes in Solution Alex Kitaygorodskiy, Wei Wang, Su-Yuan Xie, Yi Lin, K. A. Shiral Fernando, Xin Wang, Liangwei Qu, Bailin Chen, and Ya-Ping Sun pp 7517–7520 DOI: 10.1021/ja050342a Supporting Info

Synthesis of a New Class of Compounds Containing a Ln−O−Al Arrangement and Their Reactions and Catalytic Properties Jianfang Chai, Vojtech Jancik, Sanjay Singh, Hongping Zhu, Cheng He, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer, and Narayan S. Hosmane pp 7521–7528 DOI: 10.1021/ja050521s Supporting Info

Short- and Long-Range Order in the Positive Electrode Material, Li(NiMn)0.5O2:  A Joint X-ray and Neutron Diffraction, Pair Distribution Function Analysis and NMR Study Julien Bréger, Nicolas Dupré, Peter J. Chupas, Peter L. Lee, Thomas Proffen, John B. Parise, and Clare P. Grey pp 7529–7537 DOI: 10.1021/ja050697u

Functional One-Dimensional Lipid Bilayers on Carbon Nanotube Templates Alexander B. Artyukhin, Aleksei Shestakov, Jennifer Harper, Olgica Bakajin, Pieter Stroeve, and Aleksandr Noy pp 7538–7542 DOI: 10.1021/ja043431g

Solid State NMR Method for the Determination of 3D Zeolite Framework/Sorbate Structures:  1H/29Si CP MAS NMR Study of the High-Loaded Form of p-Xylene in ZSM-5 and Determination of the Unknown Structure of the Low-Loaded Form Colin A. Fyfe, Anix C. Diaz, Hiltrud Grondey, Andrew R. Lewis, and Hans Förster pp 7543–7558 DOI: 10.1021/ja0432822 Supporting Info

What Is Required to Stabilize Al3+? A Gas-Phase Perspective Ljiljana Puškar, Katharine Tomlins, Bridgette Duncombe, Hazel Cox, and Anthony J. Stace pp 7559–7569 DOI: 10.1021/ja042884i

The Molecular Basis of Resilience to the Effect of the Lys103Asn Mutation in Non-Nucleoside HIV-1 Reverse Transcriptase Inhibitors Studied by Targeted Molecular Dynamics Simulations Fátima Rodríguez-Barrios, Jan Balzarini, and Federico Gago pp 7570–7578 DOI: 10.1021/ja042289g Supporting Info

Electrochemical Reduction of NO by Hemin Adsorbed at Pyrolitic Graphite Matheus T. de Groot, Maarten Merkx, Ad H. Wonders, and Marc T. M. Koper pp 7579–7586 DOI: 10.1021/ja051151a Supporting Info

Studies of Organically Functionalized Mesoporous Silicas Using Heteronuclear Solid-State Correlation NMR Spectroscopy under Fast Magic Angle Spinning Julien Trebosc, Jerzy W. Wiench, Seong Huh, Victor S.-Y. Lin, and Marek Pruski pp 7587–7593 DOI: 10.1021/ja0509127

Supramolecular Layer-by-Layer Assembly:  Alternating Adsorptions of Guest- and Host-Functionalized Molecules and Particles Using Multivalent Supramolecular Interactions Olga Crespo-Biel, Barbara Dordi, David N. Reinhoudt, and Jurriaan Huskens pp 7594–7600 DOI: 10.1021/ja051093t

MCM-48-like Large Mesoporous Silicas with Tailored Pore Structure:  Facile Synthesis Domain in a Ternary Triblock Copolymer−Butanol−Water System Tae-Wan Kim, Freddy Kleitz, Blain Paul, and Ryong Ryoo pp 7601–7610 DOI: 10.1021/ja042601m Supporting Info

Synthesis, Optical Properties, and Growth Mechanism of Blue-Emitting CdSe Nanorods Steven G. Thoma, Arturo Sanchez, Paula P. Provencio, Billie L. Abrams, and Jess P. Wilcoxon pp 7611–7614 DOI: 10.1021/ja050501q

Modeling Rate-Controlling Solvent Effects. The Pericyclic Meisenheimer Rearrangement of N-Propargylmorpholine N-Oxide Zoltán Mucsi, Anna Szabó, István Hermecz, Árpád Kucsman, and Imre G. Csizmadia pp 7615–7631 DOI: 10.1021/ja042227q Supporting Info

Mechanisms and Applications of Plasmon-Induced Charge Separation at TiO2 Films Loaded with Gold Nanoparticles Yang Tian and Tetsu Tatsuma pp 7632–7637 DOI: 10.1021/ja042192u Supporting Info

Electrochemistry of Unfolded Cytochrome c in Neutral and Acidic Urea Solutions Milan Fedurco, Jan Augustynski, Chiara Indiani, Giulietta Smulevich, Marián Antalík, Mikuláš Bánó, Erik Sedlák, Mary C. Glascock, and John H. Dawson pp 7638–7646 DOI: 10.1021/ja050321g

Ferrocenylundecanethiol Self-Assembled Monolayer Charging Correlates with Negative Differential Resistance Measured by Conducting Probe Atomic Force Microscopy Alexei V. Tivanski and Gilbert C. Walker pp 7647–7653 DOI: 10.1021/ja0514491

Synthesis of Biaryls By Ivica Cepanec (BULUPO Pharmaceuticals, Zagreb, Croatia). Elsevier Ltd:  Oxford. 2004. xiv + 350 pp. $140.00. ISBN 0-08-044412-1. Victor Snieckus p 7654 DOI: 10.1021/ja040988n

Nitrosation Reactions and the Chemistry of Nitric Oxide By D. L. H. Williams (University of Durham, U.K.). Elsevier BV:  Amsterdam. 2004. xii + 268 pp. $209.00. ISBN 0-444-51721-9. Peter C. Ford pp 7654–7655 DOI: 10.1021/ja041042g

Inorganic Materials Chemistry Desk Reference, 2nd ed By D. Sangeeta (GE Aircraft Engines) and John R. LaGraff (Rensselaer Polytechnic Institute). CRC Press:  Boca Raton, FL. 2005. xii + 372 pp. $149.95. ISBN 0-8493-0910-7. p 7655 DOI: 10.1021/ja0410542

Insect Antifeedants By Opender Koul (Insect Biopesticide Research Centre, Jalandhar, India). CRC Press LLC:  Boca Raton, FL. 2005. xii + 1006 pp. $189.95. ISBN 0-415-33400-4. p 7655 DOI: 10.1021/ja059703c

Progress in Colloid and Polymer Science, Volume 126:  Trends in Colloid and Interface Science XVII Edited by Valérie Cabuil (Université Pierre et Marie Curie, Paris, France), Pierre Levitz (no affiliation given), and Clande Treiner (no affiliation given). Series edited by F. Kremer and W. Richtering. Springer:  Berlin, Heidelberg, New York. 2004. viii + 200 pp. $179.00. ISBN 3-540-20073-8. p 7655 DOI: 10.1021/ja059705x

Gas Adsorption Equilibria:  Experimental Methods and Adsorptive Isotherms By Jürgen U. Keller and Reiner Staudt (Universität Siegen). Springer:  New York. 2005. xiv + 442 pp. $139.00. ISBN 0-387-23597-3. Teresa J. Bandosz pp 7655–7656 DOI: 10.1021/ja041029w

Side Reactions in Organic Synthesis:  A Guide to Successful Synthesis Design By Florencio Zaragoza Dörwald (Novo Nordisk A/S, Malov, Denmark). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. xvi + 374 pp. $110.00. ISBN 3-527-31021-5. Kevin Burgess p 7656 DOI: 10.1021/ja059728b

Practical NMR Relaxation for Chemists By Vladimir I. Bakhmutov (Texas A&M University). John Wiley & Sons, Ltd:  Chichester, U.K. 2004. xii + 202 pp. $185.00. ISBN 0-470-09445-1. Cecil Dybowski pp 7656–7657 DOI: 10.1021/ja0597247

Molecular Light Scattering and Optical Activity, 2nd ed By Laurence Barron (University of Glasgow). Cambridge University Press:  Cambridge, U.K. 2004. xxii + 444 pp. $150.00. ISBN 0-521-81341-7. Bruce A. Garetz p 7657 DOI: 10.1021/ja041027b

Handbook of Ion Chromatography, 3rd, completely revised and enlarged edition, Volumes 1 and 2 By Joachim Weiss (Dionex GmbH). Wiley-VCH Verlag GmBH & Co. KGaA:  Weinheim, Germany. 2004. xiv + 894 pp. $395. ISBN 3-527-28701-9. Krishna L. Foster pp 7657–7658 DOI: 10.1021/ja041040w

Issue 21

Spectroscopic Evidence for the Formation of a Four-Coordinate Co2+Cobalamin Species upon Binding to the Human ATP:Cobalamin Adenosyltransferase Troy A. Stich, Mamoru Yamanishi, Ruma Banerjee, and Thomas C. Brunold pp 7660–7661 DOI: 10.1021/ja050546r Supporting Info

Poly(2,7-dibenzosilole):  A Blue Light Emitting Polymer Khai Leok Chan, Mary J. McKiernan, Carl R. Towns, and Andrew B. Holmes pp 7662–7663 DOI: 10.1021/ja0508065 Supporting Info

The Structure of the H3O+ Hydronium Ion in Benzene Evgenii S. Stoyanov, Stephan P. Hoffmann, Kee-Chan Kim, Fook S. Tham, and Christopher A. Reed pp 7664–7665 DOI: 10.1021/ja050401k Supporting Info

Chemical Sensing with LiMo3Se3 Nanowire Films Xiubin Qi and Frank E. Osterloh pp 7666–7667 DOI: 10.1021/ja050960r Supporting Info

Frustrated Molecular Packing in Highly Ordered Smectic Phase of Side-Chain Liquid Crystalline Polymer with Rigid Polyacetylene Backbone Chun Ye, Guoqiang Xu, Zhen-Qiang Yu, Jacky W. Y. Lam, Jee Hwan Jang, Hai-Lin Peng, Ying-Feng Tu, Zhong-Fan Liu, Kwang-Un Jeong, Stephen Z. D. Cheng, Er-Qiang Chen, and Ben Zhong Tang pp 7668–7669 DOI: 10.1021/ja050643k Supporting Info

A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer Xian-Ming Zhang, Rui-Qin Fang, and Hai-Shun Wu pp 7670–7671 DOI: 10.1021/ja050284t Supporting Info

A Metallocene-Complexed Dibismuthene: Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2) Yuzhong Wang, Brandon Quillian, Xiao-Juan Yang, Pingrong Wei, Zhongfang Chen, Chaitanya S. Wannere, Paul v. R. Schleyer, and Gregory H. Robinson pp 7672–7673 DOI: 10.1021/ja051704h Supporting Info

Multilevel Microfluidics via Single-Exposure Photolithography Michael W. Toepke and Paul J. A. Kenis pp 7674–7675 DOI: 10.1021/ja050660+ Supporting Info

[(Pd−Pd)@Ge18]4-:  A Palladium Dimer Inside the Largest Single-Cage Deltahedron Jose M. Goicoechea and Slavi C. Sevov pp 7676–7677 DOI: 10.1021/ja051224q Supporting Info

Cu(I) Luminescence from the Tetranuclear Cu4S4 Cofactor of a Synthetic 4-Helix Bundle Olesya A. Kharenko, David C. Kennedy, Borries Demeler, Michael J. Maroney, and Michael Y. Ogawa pp 7678–7679 DOI: 10.1021/ja042757m Supporting Info

Selective Inhibition of Factor Inhibiting Hypoxia-Inducible Factor Michael A. McDonough, Luke A. McNeill, Melanie Tilliet, Cyril A. Papamicaël, Qiu-Yun Chen, Biswadip Banerji, Kirsty S. Hewitson, and Christopher J. Schofield pp 7680–7681 DOI: 10.1021/ja050841b Supporting Info

Synthesis of Cyclic Endiamino Peptides Doron Pappo, Maida Vartanian, Steffen Lang, and Yoel Kashman pp 7682–7683 DOI: 10.1021/ja050299r Supporting Info

Phosphorylation-Driven Protein−Protein Interactions:  A Protein Kinase Sensing System Qunzhao Wang and David S. Lawrence pp 7684–7685 DOI: 10.1021/ja050789j Supporting Info

Anion Dependent Self-Assembly of “Tetra-Decker” and “Triple-Decker” Luminescent Tb(III) Salen Complexes Xiaoping Yang and Richard A. Jones pp 7686–7687 DOI: 10.1021/ja051292c Supporting Info

Fabrication of Non-Close-Packed Arrays of Colloidal Spheres by Soft Lithography Xin Yan, Jimin Yao, Guang Lu, Xiao Li, Junhu Zhang, Kun Han, and Bai Yang pp 7688–7689 DOI: 10.1021/ja0428208 Supporting Info

Palladium-Catalyzed Ring-Forming Aminoacetoxylation of Alkenes Erik J. Alexanian, Chulbom Lee, and Erik J. Sorensen pp 7690–7691 DOI: 10.1021/ja051406k Supporting Info

Characterization of Protein Encoded by spnR from the Spinosyn Gene Cluster of Saccharopolyspora spinosa:  Mechanistic Implications for Forosamine Biosynthesis Zongbao Zhao, Lin Hong, and Hung-wen Liu pp 7692–7693 DOI: 10.1021/ja042702k Supporting Info

Programmed Assembly of Two Different Ligands with Metallic Ions:  Generation of Self-Supported Noyori-type Catalysts for Heterogeneous Asymmetric Hydrogenation of Ketones Yuxue Liang, Qing Jing, Xin Li, Lei Shi, and Kuiling Ding pp 7694–7695 DOI: 10.1021/ja050737u Supporting Info

Dynamic Kinetic Resolution of Amino Acid Amide Catalyzed by d-Aminopeptidase and α-Amino-ε-caprolactam Racemase Yasuhisa Asano and Shigenori Yamaguchi pp 7696–7697 DOI: 10.1021/ja050300m Supporting Info

Carbanion-Mediated Photocages:  Rapid and Efficient Photorelease with Aqueous Compatibility Matthew Lukeman and Juan C. Scaiano pp 7698–7699 DOI: 10.1021/ja0517062 Supporting Info

Cooperativity in Chiroptical Sensing with Dendritic Zinc Porphyrins Wei-Shi Li, Dong-Lin Jiang, Yuki Suna, and Takuzo Aida pp 7700–7702 DOI: 10.1021/ja0513335 Supporting Info

A Concerted Mechanism for the Transfer of the Thiophosphinoyl Group from Aryl Dimethylphosphinothioate Esters to Oxyanionic Nucleophiles in Aqueous Solution Ikenna Onyido, Krzysztof Swierczek, Jamie Purcell, and Alvan C. Hengge pp 7703–7711 DOI: 10.1021/ja0501565 Supporting Info

UV Resonance Raman Determination of Polyproline II, Extended 2.51-Helix, and β-Sheet Ψ Angle Energy Landscape in Poly-l-Lysine and Poly-l-Glutamic Acid Aleksandr V. Mikhonin, Nataliya S. Myshakina, Sergei V. Bykov, and Sanford A. Asher pp 7712–7720 DOI: 10.1021/ja044636s

Nitric Oxide Interaction with Cytochrome c‘ and Its Relevance to Guanylate Cyclase. Why Does the Iron Histidine Bond Break? Marcelo A. Martí, Luciana Capece, Alejandro Crespo, Fabio Doctorovich, and Dario A. Estrin pp 7721–7728 DOI: 10.1021/ja042870c Supporting Info

Structure of the Nitrogen-Centered Radical Formed during Inactivation of E. coli Ribonucleotide Reductase by 2‘-Azido-2‘-deoxyuridine-5‘-diphosphate:  Trapping of the 3‘-Ketonucleotide Jörg Fritscher, Erin Artin, Stanislaw Wnuk, Galit Bar, John H. Robblee, Sylwia Kacprzak, Martin Kaupp, Robert G. Griffin, Marina Bennati, and JoAnne Stubbe pp 7729–7738 DOI: 10.1021/ja043111x Supporting Info

Base-Pairing, Tautomerism, and Mismatch Discrimination of 7-Halogenated 7-Deaza-2‘-deoxyisoguanosine:  Oligonucleotide Duplexes with Parallel and Antiparallel Chain Orientation Frank Seela, Xiaohua Peng, and Hong Li pp 7739–7751 DOI: 10.1021/ja0425785 Supporting Info

Hydrolysis of 2',3'-O-Methyleneadenosin-5'-yl Bis-5'-O-Methyluridin-3'-yl Phosphate:  The 2'-Hydroxy Group Stabilizes the Phosphorane Intermediate, Not the Departing 3'-Oxyanion, by Hydrogen Bonding Tuomas Lönnberg and Jonna Korhonen pp 7752–7758 DOI: 10.1021/ja050325l

Accelerated Arene Ligand Exchange in the (Arene)Cr(CO)2L Series M. F. Semmelhack, Anatoly Chlenov, and Douglas M. Ho pp 7759–7773 DOI: 10.1021/ja042705x Supporting Info

One-Pot Synthesis of Metalated Pyridines from Two Acetylenes, a Nitrile, and a Titanium(II) Alkoxide Ryoichi Tanaka, Akio Yuza, Yuko Watai, Daisuke Suzuki, Yuuki Takayama, Fumie Sato, and Hirokazu Urabe pp 7774–7780 DOI: 10.1021/ja050261e Supporting Info

Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH:  Experimental and Computational Studies Evan L. Werkema, Elsa Messines, Lionel Perrin, Laurent Maron, Odile Eisenstein, and Richard A. Andersen pp 7781–7795 DOI: 10.1021/ja0504800 Supporting Info

Surface Layering in Ionic Liquids:  An X-ray Reflectivity Study Eli Sloutskin, Benjamin M. Ocko, Lilach Tamam, Ivan Kuzmenko, Thomas Gog, and Moshe Deutsch pp 7796–7804 DOI: 10.1021/ja0509679 Supporting Info

Ruthenium-Catalyzed Ionic Hydrogenation of Iminium Cations. Scope and Mechanism Hairong Guan, Masanori Iimura, Matthew P. Magee, Jack R. Norton, and Guang Zhu pp 7805–7814 DOI: 10.1021/ja0506861 Supporting Info

Measurement of the Free-Energy Dependence of Interfacial Charge-Transfer Rate Constants using ZnO/H2O Semiconductor/Liquid Contacts Thomas W. Hamann, Florian Gstrein, Bruce S. Brunschwig, and Nathan S. Lewis pp 7815–7824 DOI: 10.1021/ja0436188 Supporting Info

Tungsten Allylimido Complexes Cl4(RCN)W(NC3H5) as Single-Source CVD Precursors for WNxCy Thin Films. Correlation of Precursor Fragmentation to Film Properties Omar J. Bchir, Kelly M. Green, Hiral M. Ajmera, Elizabeth A. Zapp, Timothy J. Anderson, Benjamin C. Brooks, Laurel L. Reitfort, David H. Powell, Khalil A. Abboud, and Lisa McElwee-White pp 7825–7833 DOI: 10.1021/ja043799d Supporting Info

Taxadiene Synthase-Catalyzed Cyclization of 6-Fluorogeranylgeranyl Diphosphate to 7-Fluoroverticillenes Yinghua Jin, David C. Williams, Rodney Croteau, and Robert M. Coates pp 7834–7842 DOI: 10.1021/ja050592r Supporting Info

The Synthesis of [(Bi2Te3)x{(TiTe2)y}1.36] Superlattices from Modulated Elemental Reactants Fred R. Harris, Stacey Standridge, and David C. Johnson pp 7843–7848 DOI: 10.1021/ja050799k

Templated Metal Catalysis for Single Nucleotide Specific DNA Sequence Detection Iris Boll, Roland Krämer, Jens Brunner, and Andriy Mokhir pp 7849–7856 DOI: 10.1021/ja0503332

Synthesis and Reactivity of Low-Coordinate Iron(II) Fluoride Complexes and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons Javier Vela, Jeremy M. Smith, Ying Yu, Nicole A. Ketterer, Christine J. Flaschenriem, Rene J. Lachicotte, and Patrick L. Holland pp 7857–7870 DOI: 10.1021/ja042672l Supporting Info

Truly Quantitative XPS Characterization of Organic Monolayers on Silicon: Study of Alkyl and Alkoxy Monolayers on H−Si(111) Xavier Wallart, Catherine Henry de Villeneuve, and Philippe Allongue pp 7871–7878 DOI: 10.1021/ja0430797 Supporting Info

Role for Bound Water and CH−π Aromatic Interactions in Photosynthetic Electron Transfer Colette A. Sacksteder, Shana L. Bender, and Bridgette A. Barry pp 7879–7890 DOI: 10.1021/ja050659a

In Situ Single-Crystal X-ray Diffraction Studies of Desorption and Sorption in a Flexible Nanoporous Molecular Framework Material Gregory J. Halder and Cameron J. Kepert pp 7891–7900 DOI: 10.1021/ja042420k Supporting Info

Dinitrogen Functionalization with Terminal Alkynes, Amines, and Hydrazines Promoted by [(η5-C5Me4H)2Zr]2(μ2,η2,η2-N2):  Observation of Side-On and End-On Diazenido Complexes in the Reduction of N2 to Hydrazine Wesley H. Bernskoetter, Jaime A. Pool, Emil Lobkovsky, and Paul J. Chirik pp 7901–7911 DOI: 10.1021/ja050387b Supporting Info

The Big Squeeze:  Guest Exchange in an M4L6 Supramolecular Host Anna V. Davis and Kenneth N. Raymond pp 7912–7919 DOI: 10.1021/ja051037s Supporting Info

Growth of Uniformly Aligned ZnO Nanowire Heterojunction Arrays on GaN, AlN, and Al0.5Ga0.5N Substrates Xudong Wang,Xudong Wang, Jinhui Song, Peng Li, Jae Hyun Ryou, Russell D. Dupuis, Christopher J. Summers, and Zhong L. Wang pp 7920–7923 DOI: 10.1021/ja050807x

Design of C2-Chiral Diamines That Are Computationally Predicted To Be a Million-fold More Basic than the Original Proton Sponges Roger W. Alder pp 7924–7931 DOI: 10.1021/ja051049d Supporting Info

Sensitivity and Specificity of Metal Surface-Immobilized “Molecular Beacon” Biosensors Hui Du, Christopher M. Strohsahl, James Camera, Benjamin L. Miller, and Todd D. Krauss pp 7932–7940 DOI: 10.1021/ja042482a Supporting Info

Ab Initio Nonadiabatic Molecular Dynamics of the Ultrafast Electron Injection across the Alizarin−TiO2 Interface Walter R. Duncan, William M. Stier, and Oleg V. Prezhdo pp 7941–7951 DOI: 10.1021/ja042156v

Theoretical and Experimental Investigations on the Reactions of Positively Charged Phenyl Radicals with Aromatic Amino Acids Yiqun Huang and Hilkka Kenttämaa pp 7952–7960 DOI: 10.1021/ja044314o

Spin Crossover in Transition Metal Compounds II. Topics in Current Chemistry, 234 Edited by Philipp Gütlich (Johannes Guternber-Universität, Mainz, Ger-many) and Harold A. Goodwin (University of New South Wales, Sydney, Australia). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xiv + 294 pp. $259.00. ISBN 3-540-40396-5. Martin L. Kirk p 7961 DOI: 10.1021/ja040990e

Progress in Colloid and Polymer Science, Volume 128. Surface and Colloid Science Edited by Fernando Galembeck (Universidade Estadual de Campinas, Brazil). Series edited by F. Kremer and W. Richtering. Springer:  Berlin, Heidelberg, New York. 2004. x + 314 pp. $225.00. ISBN 3-540-21247-7. p 7961 DOI: 10.1021/ja059718a

Binary Rare Earth Oxides Edited by G. Adachi (Juri Institute for Environmental Science and Chemistry, Osaka), N. Imanaka (Osaka University), and Z. C. Kang (International Center for Quantum Structures and State Key Laboratory for Surface Sciences, Beijing). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xiv + 258 pp. $125.00. ISBN 1-4020-2568-8. Jeffery L. Coffer pp 7961–7962 DOI: 10.1021/ja041010t

Issue 22

Theoretical Evidence for Enhanced NO Dimerization in Aromatic Hosts:  Implications for the Role of the Electrophile (NO)2 in Nitric Oxide Chemistry Yi-Lei Zhao, Michael D. Bartberger, Kei Goto, Keiichi Shimada, Takayuki Kawashima, and K. N. Houk pp 7964–7965 DOI: 10.1021/ja042247s Supporting Info

Detection of Fragmented Genomic DNA by PCR-Free Piezoelectric Sensing Using a Denaturation Approach Maria Minunni, Sara Tombelli, Jessica Fonti, Maria M. Spiriti, Marco Mascini, Patrizia Bogani, and Marcello Buiatti pp 7966–7967 DOI: 10.1021/ja051345q Supporting Info

Selective Si−C Bond Cleavage as Synthetic Entry to a Functionalized Lithiosilane Carsten Strohmann, Daniel Schildbach, and Dominik Auer pp 7968–7969 DOI: 10.1021/ja050360s Supporting Info

Probing Secondary Carbohydrate−Protein Interactions with Highly Dense Cyclodextrin-Centered Heteroglycoclusters:  The Heterocluster Effect Marta Gómez-García, Juan M. Benito, David Rodríguez-Lucena, Jian-Xin Yu, Kazimierz Chmurski, Carmen Ortiz Mellet, Ricardo Gutiérrez Gallego, Alfredo Maestre, Jacques Defaye, and José M. García Fernández pp 7970–7971 DOI: 10.1021/ja050934t Supporting Info

New Peptidomimetic Polymers for Antifouling Surfaces Andrea R. Statz, Robert J. Meagher, Annelise E. Barron, and Phillip B. Messersmith pp 7972–7973 DOI: 10.1021/ja0522534 Supporting Info

Substrate-Binding in Quinoprotein Ethanol Dehydrogenase from Pseudomonas aeruginosa Studied by Electron Paramagnetic Resonance at 94 GHz Christopher W. M. Kay, Bina Mennenga, Helmut Görisch, and Robert Bittl pp 7974–7975 DOI: 10.1021/ja050972c

Nonactin Biosynthesis:  The Product of the Resistance Gene Degrades Nonactin Stereospecifically to Form Homochiral Nonactate Dimers James E. Cox and Nigel D. Priestley pp 7976–7977 DOI: 10.1021/ja050068k

Screening of Protein Kinases by ATP-STD NMR Spectroscopy Mark A. McCoy, Mary M. Senior, and Daniel F. Wyss pp 7978–7979 DOI: 10.1021/ja0425942 Supporting Info

Controlling Interparticle Spacing among Metal Nanoparticles through Metal-Catalyzed Decomposition of Surrounding Polymer Matrix Kensuke Akamatsu, Hiroyuki Shinkai, Shingo Ikeda, Satoshi Adachi, Hidemi Nawafune, and Satoshi Tomita pp 7980–7981 DOI: 10.1021/ja050735+ Supporting Info

AlN Nanotube:  Round or Faceted? Xin Chen, Jing Ma, Zheng Hu, Qiang Wu, and Yi Chen pp 7982–7983 DOI: 10.1021/ja051505y Supporting Info

Ultrafast Dynamics of Resonance Energy Transfer in Cryptochrome Chaitanya Saxena, Haiyu Wang, I. Halil Kavakli, Aziz Sancar, and Dongping Zhong pp 7984–7985 DOI: 10.1021/ja0421607 Supporting Info

Colorimetric Enantiodiscrimination of α-Amino Acids in Protic Media J. Frantz Folmer-Andersen, Vincent M. Lynch, and Eric V. Anslyn pp 7986–7987 DOI: 10.1021/ja052029e Supporting Info

Structural Model of the Amyloid Fibril Formed by β2-Microglobulin #21−31 Fragment Based on Vibrational Spectroscopy Hirotsugu Hiramatsu, Yuji Goto, Hironobu Naiki, and Teizo Kitagawa pp 7988–7989 DOI: 10.1021/ja050844o

cis-Dihydroxylation and Epoxidation of Alkenes by [Mn2O(RCO2)2(tmtacn)2]:  Tailoring the Selectivity of a Highly H2O2-Efficient Catalyst Johannes W. de Boer, Jelle Brinksma, Wesley R. Browne, Auke Meetsma, Paul L. Alsters, Ronald Hage, and Ben L. Feringa pp 7990–7991 DOI: 10.1021/ja050990u Supporting Info

Mirror Image Nanostructures Benjamin W. Messmore, Preeti A. Sukerkar, and Samuel I. Stupp pp 7992–7993 DOI: 10.1021/ja051183y Supporting Info

Green Chemistry Strategies Using Crystal-to-Crystal Photoreactions:  Stereoselective Synthesis and Decarbonylation of trans-α,α‘-Dialkenoylcyclohexanones Christopher J. Mortko and Miguel A. Garcia-Garibay pp 7994–7995 DOI: 10.1021/ja0508166 Supporting Info

Enantioselective Recognition of Carboxylates:  A Receptor Derived from α-Aminoxy Acids Functions as a Chiral Shift Reagent for Carboxylic Acids Dan Yang, Xiang Li, Yun-Fei Fan, and Dan-Wei Zhang pp 7996–7997 DOI: 10.1021/ja051072z Supporting Info

A Small-Molecule-Based Approach to Sense Codon-Templated Natural-Unnatural Hybrid Peptides. Selective Silencing and Reassignment of the Sense Codon by Orthogonal Reacylation Stalling at the Single-Codon Level Shinsuke Sando, Keiichiro Kanatani, Nobuhiko Sato, Hironori Matsumoto, Takahiro Hohsaka, and Yasuhiro Aoyama pp 7998–7999 DOI: 10.1021/ja0502977 Supporting Info

Photorelease of Carboxylic Acids, Amino Acids, and Phosphates from N-Alkylpicolinium Esters Using Photosensitization by High Wavelength Laser Dyes Chitra Sundararajan and Daniel E. Falvey pp 8000–8001 DOI: 10.1021/ja050760f Supporting Info

Single-Crystalline CeB6 Nanowires Han Zhang, Qi Zhang, Jie Tang, and Lu-Chang Qin pp 8002–8003 DOI: 10.1021/ja051340t

Sequential Cross-Coupling of 1,4-Bissilylbutadienes:  Synthesis of Unsymmetrical 1,4-Disubstituted 1,3-Butadienes Scott E. Denmark and Steven A. Tymonko pp 8004–8005 DOI: 10.1021/ja0518373 Supporting Info

Enantioselective Syn-Selective Scandium-Catalyzed Ene Reactions David A. Evans and Jimmy Wu pp 8006–8007 DOI: 10.1021/ja0522130 Supporting Info

A “Nanonecklace” Synthesized from Monofunctionalized Gold Nanoparticles Qiu Dai, James G. Worden, Jonathan Trullinger, and Qun Huo pp 8008–8009 DOI: 10.1021/ja042610v Supporting Info

Solution NMR Spectroscopy of the Human Vasopressin V2 Receptor, A G Protein-Coupled Receptor Changlin Tian, Richard M. Breyer, Hak Jun Kim, Murthy D. Karra, David B. Friedman, Anne Karpay, and Charles R. Sanders pp 8010–8011 DOI: 10.1021/ja051161b Supporting Info

A Versatile and Conformationally Adaptable Fluorene-Based Receptor for Efficient Binding of Silver Cation Rajendra Rathore, Vincent J. Chebny, and Sameh H. Abdelwahed pp 8012–8013 DOI: 10.1021/ja051935o Supporting Info

Very Fast Two-Dimensional NMR Spectroscopy for Real-Time Investigation of Dynamic Events in Proteins on the Time Scale of Seconds Paul Schanda and Bernhard Brutscher pp 8014–8015 DOI: 10.1021/ja051306e Supporting Info

Polyoxometalate-Based Vesicle and Its Honeycomb Architectures on Solid Surfaces Weifeng Bu, Haolong Li, Hang Sun, Shengyan Yin, and Lixin Wu pp 8016–8017 DOI: 10.1021/ja042980j Supporting Info

Nanorubbing of Polythiophene Surfaces Gwennaelle Derue, Séverine Coppée, Sylvain Gabriele, Mathieu Surin, Victor Geskin, Fabien Monteverde, Philippe Leclère, Roberto Lazzaroni, and Pascal Damman pp 8018–8019 DOI: 10.1021/ja0505806

The Collapse of Nanobubbles in Water Francesca Lugli, Siegfried Höfinger, and Francesco Zerbetto pp 8020–8021 DOI: 10.1021/ja0505447 Supporting Info

Spiro-Cyclopropanation from Oxoallylsilanes Asunción Barbero, Pilar Castreño, and Francisco J. Pulido pp 8022–8023 DOI: 10.1021/ja051967b Supporting Info

1,1-Cycloaddition of Oxalyl Dichloride with Dialkenylmetal Compounds:  Formation of Cyclopentadienone Derivatives by the Reaction of 1,4,-Dilithio-1,3-dienes or Zirconacyclopentadienes with Oxalyl Chloride in the Presence of CuCl Chao Chen, Chanjuan Xi, Yanfeng Jiang, and Xiaoyin Hong pp 8024–8025 DOI: 10.1021/ja0506713 Supporting Info

Theoretical Investigation of C−H Hydroxylation by (N4Py)FeIVO2+:  An Oxidant More Powerful than P450? Devesh Kumar, Hajime Hirao, Lawrence Que, Jr., and Sason Shaik pp 8026–8027 DOI: 10.1021/ja0512428 Supporting Info

Functionalized Higher Acenes:  Hexacene and Heptacene Marcia M. Payne, Sean R. Parkin, and John E. Anthony pp 8028–8029 DOI: 10.1021/ja051798v Supporting Info

Aromatic and Antiaromatic Gold(III) Hexaphyrins with Multiple Gold−Carbon Bonds Shigeki Mori and Atsuhiro Osuka pp 8030–8031 DOI: 10.1021/ja051662x Supporting Info

RNA Guanine Quadruplex Invasion by Complementary and Homologous PNA Probes Violeta L. Marin and Bruce A. Armitage pp 8032–8033 DOI: 10.1021/ja051102y Supporting Info

The gem-Dialkyl Effect in Electron Transfer Reactions:  Rapid Synthesis of Seven-Membered Rings through an Electrochemical Annulation Jeffrey B. Sperry and Dennis L. Wright pp 8034–8035 DOI: 10.1021/ja051826+ Supporting Info

Hemoglobin−Superoxide DismutaseChemical Linkages That Create a Dual-Function Protein Amer Alagic, Agnieszka Koprianiuk, and Ronald Kluger pp 8036–8043 DOI: 10.1021/ja050339r Supporting Info

Asymmetric Allyl- and Crotylboration with the Robust, Versatile, and Recyclable 10-TMS-9-borabicyclo[3.3.2]decanes Carlos H. Burgos, Eda Canales, Karl Matos, and John A. Soderquist pp 8044–8049 DOI: 10.1021/ja043612i Supporting Info

Direct Palladium-Catalyzed C-2 and C-3 Arylation of Indoles:  A Mechanistic Rationale for Regioselectivity Benjamin S. Lane, Meghann A. Brown, and Dalibor Sames pp 8050–8057 DOI: 10.1021/ja043273t Supporting Info

Polymer Particles with Various Shapes and Morphologies Produced in Continuous Microfluidic Reactors Zhihong Nie, Shengqing Xu, Minseok Seo, Patrick C. Lewis, and Eugenia Kumacheva pp 8058–8063 DOI: 10.1021/ja042494w Supporting Info

Direct Observation of Delayed Fluorescence from a Remarkable Back-Isomerization in Cy5 Zhengxi Huang, Dongmei Ji, Andong Xia, Felix Koberling, Matthias Patting, and Rainer Erdmann pp 8064–8066 DOI: 10.1021/ja050050+ Supporting Info

The Oxidation-State Dependent Structural Conformation and Supramolecular Function of a Redox-Active [2]Rotaxane in Solution Kirill Nikitin and Donald Fitzmaurice pp 8067–8076 DOI: 10.1021/ja050694h

Sol−Gel Materials as Efficient Enzyme Protectors:  Preserving the Activity of Phosphatases under Extreme pH Conditions Hagit Frenkel-Mullerad and David Avnir pp 8077–8081 DOI: 10.1021/ja0507719 Supporting Info

Syntheses, Structures, Spectroscopic Properties, and π-Dimeric Interactions of [n.n]Quinquethiophenophanes Toyofumi Sakai, Teizi Satou, Takeshi Kaikawa, Kazuo Takimiya, Tetsuo Otsubo, and Yoshio Aso pp 8082–8089 DOI: 10.1021/ja050783u Supporting Info

The Hydrolysis of 4-Acyloxy-4-substituted-2,5-cyclohexadienones:  Limitations of Aryloxenium Ion Chemistry Michael Novak and Stephen A. Glover pp 8090–8097 DOI: 10.1021/ja050899q Supporting Info

Crystals in CrystalsNanocrystals within Mesoporous Zeolite Single Crystals Claus H. Christensen, Iver Schmidt, Anna Carlsson, Kim Johannsen, and Konrad Herbst pp 8098–8102 DOI: 10.1021/ja050380u

Glutamate Receptor Incorporated in a Mixed Hybrid Bilayer Lipid Membrane Array, as a Sensing Element of a Biosensor Working under Flowing Conditions Gabriele Favero, Luigi Campanella, Stefano Cavallo, Andrea D'Annibale, Maurizio Perrella, Elisabetta Mattei, and Tommaso Ferri pp 8103–8111 DOI: 10.1021/ja042904g

Autochelation in Dipeptide Boronic Acids:  pH-Dependent Structures and Equilibria of Asp-boroPro and His-boroPro by NMR Spectroscopy James L. Sudmeier, Yuhong Zhou, Jack H. Lai, Hlaing H. Maw, Wengen Wu, and William W. Bachovchin pp 8112–8119 DOI: 10.1021/ja050215e Supporting Info

Conductive Metal Nanowires Templated by the Nucleoprotein Filaments, Complex of DNA and RecA Protein Taro Nishinaka, Atsushi Takano, Yuko Doi, Makiko Hashimoto, Akira Nakamura, Yushu Matsushita, Jiro Kumaki, and Eiji Yashima pp 8120–8125 DOI: 10.1021/ja050487h Supporting Info

Reaction of Au55(PPh3)12Cl6 with Thiols Yields Thiolate Monolayer Protected Au75 Clusters Ramjee Balasubramanian, Rui Guo, Allan J. Mills, and Royce W. Murray pp 8126–8132 DOI: 10.1021/ja050793v Supporting Info

Structure and Bonding in Silver Halides. A Quantum Chemical Study of the Monomers:  Ag2X, AgX, AgX2, and AgX3 (X = F, Cl, Br, I) Hans-Christian Müller-Rösing, Axel Schulz, and Magdolna Hargittai pp 8133–8145 DOI: 10.1021/ja051442j Supporting Info

Use of Tunable Ligands Allows for Intermolecular Pd-Catalyzed C−O Bond Formation Andrei V. Vorogushin, Xiaohua Huang, and Stephen L. Buchwald pp 8146–8149 DOI: 10.1021/ja050471r Supporting Info

1,2-Didehydro[10]annulenes:  Structures, Aromaticity, and Cyclizations Armando Navarro-Vázquez and Peter R. Schreiner pp 8150–8159 DOI: 10.1021/ja0507968 Supporting Info

A Microreactor for Microwave-Assisted Capillary (Continuous Flow) Organic Synthesis Eamon Comer and Michael G. Organ pp 8160–8167 DOI: 10.1021/ja0512069

Interpretation of Protein Adsorption:  Surface-Induced Conformational Changes Paul Roach, David Farrar, and Carole C. Perry pp 8168–8173 DOI: 10.1021/ja042898o

An Alternate Route for the Synthesis of Hybrid Mesoporous Organosilica with Crystal-Like Pore Walls from Allylorganosilane Precursors Mahendra P. Kapoor, Shinji Inagaki, Shushiro Ikeda, Kiyomi Kakiuchi, Masahiko Suda, and Toyoshi Shimada pp 8174–8178 DOI: 10.1021/ja043062o

A Mechanism for Transition-Metal Nanoparticle Self-Assembly Claire Besson, Eric E. Finney, and Richard G. Finke pp 8179–8184 DOI: 10.1021/ja0504439 Supporting Info

New Family of Aminophenalenyl-Based Neutral Radical Molecular Conductors:  Synthesis, Structure, and Solid State Properties Swadhin K. Mandal, Mikhail E. Itkis, Xiaoliu Chi, Satyabrata Samanta, David Lidsky, Robert W. Reed, Richard T. Oakley, Fook S. Tham, and Robert C. Haddon pp 8185–8196 DOI: 10.1021/ja0502728 Supporting Info

Synthesis and Characterization of Water Soluble Single-Walled Carbon Nanotube Graft Copolymers Bin Zhao, Hui Hu, Aiping Yu, Daniel Perea, and Robert C. Haddon pp 8197–8203 DOI: 10.1021/ja042924i

Theory Favors a Stepwise Mechanism of Porphyrin Degradation by a Ferric Hydroperoxide Model of the Active Species of Heme Oxygenase Devesh Kumar, Samuël P. de Visser, and Sason Shaik pp 8204–8213 DOI: 10.1021/ja0446956 Supporting Info

Probing Side-Chain Dynamics in High Molecular Weight Proteins by Deuterium NMR Spin Relaxation:  An Application to an 82-kDa Enzyme Vitali Tugarinov, Jason E. Ollerenshaw, and Lewis E. Kay pp 8214–8225 DOI: 10.1021/ja0508830

Infrared Spectra of CH3−MoH, CH2MoH2, and CHMoH3 Formed by Activation of CH4 by Molybdenum Atoms Han-Gook Cho and Lester Andrews pp 8226–8231 DOI: 10.1021/ja0511568 Supporting Info

Unexpectedly Strong Energy Stabilization Inside the Hydrophobic Core of Small Protein Rubredoxin Mediated by Aromatic Residues:  Correlated Ab Initio Quantum Chemical Calculations [J. Amer. Chem. Soc. 2005, 127, 2615−2617]. Jiri Vondrasek, Lada Bendova, Vojtech Klusak, and Pavel Hobza p 8232 DOI: 10.1021/ja059908l

Issue 23

Fabrication of Flexible Carbon Nanotube Field Emitter Arrays by Direct Microwave Irradiation on Organic Polymer Substrate Beom-Jin Yoon, Eun Hwa Hong, Sang Eun Jee, Dong-Myung Yoon, Dae-Seob Shim, Gyu-Young Son, Yoo Jin Lee, Kun-Hong Lee, Hyung Seok Kim, and Chan Gyung Park pp 8234–8235 DOI: 10.1021/ja043823n

Polymer Micelle with Cross-Linked Ionic Core Tatiana K. Bronich, Paul A. Keifer, Luda S. Shlyakhtenko, and Alexander V. Kabanov pp 8236–8237 DOI: 10.1021/ja043042m Supporting Info

Cobalt-Filled Apoferritin for Suspended Single-Walled Carbon Nanotube Growth with Narrow Diameter Distribution Goo-Hwan Jeong, Akira Yamazaki, Satoru Suzuki, Hideyuki Yoshimura, Yoshihiro Kobayashi, and Yoshikazu Homma pp 8238–8239 DOI: 10.1021/ja0505144 Supporting Info

Electron Propagator Calculations Show that Alkyl Substituents Alter Porphyrin Ionization Energies O. Dolgounitcheva, V. G. Zakrzewski, and J. V. Ortiz pp 8240–8241 DOI: 10.1021/ja0507721 Supporting Info

Absolute Configuration of Chiral [2.2]Paracyclophanes with Intramolecular Charge-Transfer Interaction. Failure of the Exciton Chirality Method and Use of the Sector Rule Applied to the Cotton Effect of the CT Transition Takahiro Furo, Tadashi Mori, Takehiko Wada, and Yoshihisa Inoue pp 8242–8243 DOI: 10.1021/ja0508323 Supporting Info

Cyclobutenes by Platinum-Catalyzed Cycloisomerization Reactions of Enynes Alois Fürstner, Paul W. Davies, and Tobias Gress pp 8244–8245 DOI: 10.1021/ja050845g Supporting Info

Time-Resolved Resonance Raman Observation of the 2-Fluorenylnitrenium Ion Reaction with Guanosine to Form a C8 Intermediate Pik Ying Chan, Wai Ming Kwok, Sze Kui Lam, Pauline Chiu, and David Lee Phillips pp 8246–8247 DOI: 10.1021/ja0505651 Supporting Info

Radical Reactions of a Stable N-Heterocyclic Germylene:  EPR Study and DFT Calculation Boris Tumanskii, Pauline Pine, Yitzhak Apeloig, Nicholas J. Hill, and Robert West pp 8248–8249 DOI: 10.1021/ja051169l Supporting Info

Selective Cleavage of the C−C Bonds of Aminoethyl Groups, via a Multistep Pathway, by a Pincer Iridium Complex Xiawei Zhang, Thomas J. Emge, Rajshekhar Ghosh, and Alan S. Goldman pp 8250–8251 DOI: 10.1021/ja051300p Supporting Info

One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaCl3-Promoted Diethynylation of 1,4-Enynes and 1,4-Diynes Ryo Amemiya, Katsunori Suwa, Junji Toriyama, Yoshio Nishimura, and Masahiko Yamaguchi pp 8252–8253 DOI: 10.1021/ja051416l Supporting Info

A Potent Transactivation Domain Mimic with Activity in Living Cells Bo Liu, Prasanna G. Alluri, Peng Yu, and Thomas Kodadek pp 8254–8255 DOI: 10.1021/ja0515295 Supporting Info

Divergent Kinetic Control of Classical versus Ozonolytic Lactonization:  Mechanism-Based Diastereoselection Thomas R. Hoye and Troy D. Ryba pp 8256–8257 DOI: 10.1021/ja051604b Supporting Info

MauG-Dependent in Vitro Biosynthesis of Tryptophan Tryptophylquinone in Methylamine Dehydrogenase Yongting Wang, Xianghui Li, Limei H. Jones, Arwen R. Pearson, Carrie M. Wilmot, and Victor L. Davidson pp 8258–8259 DOI: 10.1021/ja051734k

An Anomeric Control on Remote Stereochemistry in the Synthesis of Spiroketals Sunil K. Ghosh, Richard P. Hsung, and Jia Liu pp 8260–8261 DOI: 10.1021/ja051745d Supporting Info

3-Center-4-Electron Bonding in [(silox)2MoNtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate Devon C. Rosenfeld, Peter T. Wolczanski, Khaldoon A. Barakat, Corneliu Buda, and Thomas R. Cundari pp 8262–8263 DOI: 10.1021/ja051070e Supporting Info

Highly Regioselective Ir-Catalyzed β-Borylation of Porphyrins via C−H Bond Activation and Construction of β−β-Linked Diporphyrin Hiroshi Hata, Hiroshi Shinokubo, and Atsuhiro Osuka pp 8264–8265 DOI: 10.1021/ja051073r Supporting Info

Photocontrolled Microphase Separation of Block Copolymers in Two Dimensions Sohei Kadota, Kenji Aoki, Shusaku Nagano, and Takahiro Seki pp 8266–8267 DOI: 10.1021/ja051200j Supporting Info

Nano-Welding by Scanning Probe Microscope Xiaojie Duan, Jin Zhang, Xing Ling, and Zhongfan Liu pp 8268–8269 DOI: 10.1021/ja051280r Supporting Info

Sensing of Antipyretic Carboxylates by Simple Chromogenic Calix[4]pyrroles Ryuhei Nishiyabu and Pavel Anzenbacher, Jr. pp 8270–8271 DOI: 10.1021/ja051421p Supporting Info

Determining the Mg2+ Stoichiometry for Folding an RNA Metal Ion Core Rhiju Das, Kevin J. Travers, Yu Bai, and Daniel Herschlag pp 8272–8273 DOI: 10.1021/ja051422h Supporting Info

In Situ Synthesis of Temperature-Sensitive Hollow Microspheres via Interfacial Polymerization Qunhui Sun and Yulin Deng pp 8274–8275 DOI: 10.1021/ja051487k Supporting Info

An Entry to a Chiral Dihydropyrazole Scaffold:  Enantioselective [3 + 2] Cycloaddition of Nitrile Imines Mukund P. Sibi, Levi M. Stanley, and Craig P. Jasperse pp 8276–8277 DOI: 10.1021/ja051650b Supporting Info

A Simple Structural-Based Approach to Prevent Aminoglycoside Inactivation by Bacterial Defense Proteins. Conformational Restriction Provides Effective Protection against Neomycin-B Nucleotidylation by ANT4 Juan Luis Asensio, Ana Hidalgo, Agatha Bastida, Mario Torrado, Francisco Corzana, Jose Luis Chiara, Eduardo García-Junceda, Javier Cañada, and Jesús Jiménez-Barbero pp 8278–8279 DOI: 10.1021/ja051722z Supporting Info

Polarized Emission of Individual Self-Assembled Oligo(p-phenylenevinylene)-Based Nanofibers on a Solid Support Cécile R. L. P. N. Jeukens, Pascal Jonkheijm, Frans J. P. Wijnen, Jeroen C. Gielen, Peter C. M. Christianen, Albertus P. H. J. Schenning, E. W. Meijer, and Jan C. Maan pp 8280–8281 DOI: 10.1021/ja051781c Supporting Info

Are C−H Groups Significant Hydrogen Bonding Sites in Anion Receptors? Benzene Complexes with Cl-, NO3-, and ClO4- Vyacheslav S. Bryantsev and Benjamin P. Hay pp 8282–8283 DOI: 10.1021/ja0518272 Supporting Info

Controlled Self-Assembly Triggered by Olefin Metathesis:  Cross-Linked Graphitic Nanotubes from an Amphiphilic Hexa-peri-hexabenzocoronene Wusong Jin, Takanori Fukushima, Atsuko Kosaka, Makiko Niki, Noriyuki Ishii, and Takuzo Aida pp 8284–8285 DOI: 10.1021/ja051859p Supporting Info

GaN:ZnO Solid Solution as a Photocatalyst for Visible-Light-Driven Overall Water Splitting Kazuhiko Maeda, Tsuyoshi Takata, Michikazu Hara, Nobuo Saito, Yasunobu Inoue, Hisayoshi Kobayashi, and Kazunari Domen pp 8286–8287 DOI: 10.1021/ja0518777 Supporting Info

Asymmetric Hydrogenation of tert-Alkyl Ketones Takeshi Ohkuma, Christian A. Sandoval, Rajagopal Srinivasan, Quinghong Lin, Yinmao Wei, Kilian Muñiz, and Ryoji Noyori pp 8288–8289 DOI: 10.1021/ja052071+ Supporting Info

A New Design for Light-Breakable Polymer Micelles Jinqiang Jiang, Xia Tong, and Yue Zhao pp 8290–8291 DOI: 10.1021/ja0521019 Supporting Info

Synthesis of (−)-Tetracycline Mark G. Charest, Dionicio R. Siegel, and Andrew G. Myers pp 8292–8293 DOI: 10.1021/ja052151d Supporting Info

Cobalt-Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides Jérôme Waser, Hisanori Nambu, and Erick M. Carreira pp 8294–8295 DOI: 10.1021/ja052164r Supporting Info

Bundle-like Assemblies of Cadmium Hydroxide Nanostrands and Anionic Dyes Yan-Hong Luo, Jianguo Huang, and Izumi Ichinose pp 8296–8297 DOI: 10.1021/ja052189q Supporting Info

Total Synthesis of Salinosporamide A Atsushi Endo and Samuel J. Danishefsky pp 8298–8299 DOI: 10.1021/ja0522783 Supporting Info

Sulfidative Purification of Carbon Nanotubes Integrated in Transistors Yo-Sep Min, Eun Ju Bae, and Wanjun Park pp 8300–8301 DOI: 10.1021/ja052320u Supporting Info

Selective Surface Activation of a Functional Monolayer for the Fabrication of Nanometer Scale Thiol Patterns and Directed Self-Assembly of Gold Nanoparticles Zachary M. Fresco and Jean M. J. Fréchet pp 8302–8303 DOI: 10.1021/ja052738s Supporting Info

Titanosilicate Molecular Sieve for Size-Screening Photocatalytic Conversion Yasuhiro Shiraishi, Naoya Saito, and Takayuki Hirai pp 8304–8306 DOI: 10.1021/ja042707h Supporting Info

Helical Rosette Nanotubes with Tunable Stability and Hierarchy Jesus G. Moralez, Jose Raez, Takeshi Yamazaki, R. Kishan Motkuri, Andriy Kovalenko, and Hicham Fenniri pp 8307–8309 DOI: 10.1021/ja051496t Supporting Info

Enzyme Control of Small-Molecule Coordination in FosA as Revealed by 31P Pulsed ENDOR and ESE-EPR Charles J. Walsby, Joshua Telser, Rachel E. Rigsby, Richard N. Armstrong, and Brian M. Hoffman pp 8310–8319 DOI: 10.1021/ja044094e Supporting Info

157 nm Pellicles (Thin Films) for Photolithography:  Mechanistic Investigation of the VUV and UV-C Photolysis of Fluorocarbons Kwangjoo Lee, Steffen Jockusch, Nicholas J. Turro, Roger H. French, Robert C. Wheland, M. F. Lemon, Andre M. Braun, Tatjana Widerschpan, David A. Dixon, Jun Li, Marius Ivan, and Paul Zimmerman pp 8320–8327 DOI: 10.1021/ja0440654 Supporting Info

Scan-Rate-Dependent Melting Transitions of Interleukin-1 Receptor (Type II):  Elucidation of Meaningful Thermodynamic and Kinetic Parameters of Aggregation Acquired from DSC Simulations Richard L. Remmele, Jr., Jian Zhang-van Enk, Vasu Dharmavaram, David Balaban, Mark Durst, Alex Shoshitaishvili, and Hugh Rand pp 8328–8339 DOI: 10.1021/ja043466g

Mechanistic Study of the SmI2/H2O/Amine-Mediated Reduction of Alkyl Halides:  Amine Base Strength (pKBH+) Dependent Rate Anders Dahlén and Göran Hilmersson pp 8340–8347 DOI: 10.1021/ja043323u Supporting Info

Adsorption of Acrylonitrile on Diamond and Silicon (001)−(2 × 1) Surfaces:  Effects of Dimer Structure on Reaction Pathways and Product Distributions Michael P. Schwartz, Daniel E. Barlow, John N. Russell, Jr., James E. Butler, Mark P. D'Evelyn, and Robert J. Hamers pp 8348–8354 DOI: 10.1021/ja042701s

Catalytic Asymmetric Vinylation and Dienylation of Ketones Hongmei Li and Patrick J. Walsh pp 8355–8361 DOI: 10.1021/ja0425740 Supporting Info

Synthesis, Structure, and 19F NMR Spectra of 1,3,7,10,14,17,23,28,31,40-C60(CF3)10 Ivan E. Kareev, Igor V. Kuvychko, Sergey F. Lebedkin, Susie M. Miller, Oren P. Anderson, Konrad Seppelt, Steven H. Strauss, and Olga V. Boltalina pp 8362–8375 DOI: 10.1021/ja050305j Supporting Info

Dissipation of Electronic Excitation Energy within a C60 [6:0]-Hexaadduct Carrying 12 Pyropheophorbide a Moieties Matthias Helmreich, Eugeny A. Ermilov, Matthias Meyer, Norbert Jux, Andreas Hirsch, and Beate Röder pp 8376–8385 DOI: 10.1021/ja0503581

Water Affects the Stereochemistry and Dioxygen Reactivity of Carboxylate-Rich Diiron(II) Models for the Diiron Centers in Dioxygen-Dependent Non-Heme Enzymes Sungho Yoon and Stephen J. Lippard pp 8386–8397 DOI: 10.1021/ja0512531 Supporting Info

Asymmetric Synthesis of α-Substituted β-Amino Ketones from Sulfinimines (N-Sulfinyl Imines). Synthesis of the Indolizidine Alkaloid (−)-223A Franklin A. Davis and Bin Yang pp 8398–8407 DOI: 10.1021/ja051452k Supporting Info

DNA Cleavage by Copper−ATCUN Complexes. Factors Influencing Cleavage Mechanism and Linearization of dsDNA Yan Jin and J. A. Cowan pp 8408–8415 DOI: 10.1021/ja0503985 Supporting Info

Gold Cluster Carbonyls:  Saturated Adsorption of CO on Gold Cluster Cations, Vibrational Spectroscopy, and Implications for Their Structures André Fielicke, Gert von Helden, Gerard Meijer, David B. Pedersen, Benoit Simard, and David M. Rayner pp 8416–8423 DOI: 10.1021/ja0509230

Ring Current Effects in the Active Site of Medium-Chain Acyl-CoA Dehydrogenase Revealed by NMR Spectroscopy Jiaquan Wu, Alasdair F. Bell, Andrew A. Jaye, and Peter J. Tonge pp 8424–8432 DOI: 10.1021/ja050083p

Generalized Synthesis of Metal Phosphide Nanorods via Thermal Decomposition of Continuously Delivered Metal−Phosphine Complexes Using a Syringe Pump Jongnam Park, Bonil Koo, Ki Youl Yoon, Yosun Hwang, Misun Kang, Je-Geun Park, and Taeghwan Hyeon pp 8433–8440 DOI: 10.1021/ja0427496 Supporting Info

Biochemical Investigation of Pikromycin Biosynthesis Employing Native Penta- and Hexaketide Chain Elongation Intermediates Courtney C. Aldrich, Brian J. Beck, Robert A. Fecik, and David H. Sherman pp 8441–8452 DOI: 10.1021/ja042592h Supporting Info

On the Parity in Helical Twisting Power of Ru(III) 1,3-Diketonates of C2 Symmetry in Nematic Liquid Crystals Jun Yoshida, Hisako Sato, Akihiko Yamagishi, and Naomi Hoshino pp 8453–8456 DOI: 10.1021/ja042549u Supporting Info

Syntheses, Structure, and Derivatization of Potassium Complexes of Penta(organo)[60]fullerene-Monoanion, -Dianion, and -Trianion into Hepta- and Octa(organo)fullerenes Yutaka Matsuo and Eiichi Nakamura pp 8457–8466 DOI: 10.1021/ja050318x Supporting Info

Competition at Chiral Metal Surfaces:  Fundamental Aspects of the Inversion of Enantioselectivity in Hydrogenations on Platinum Norberto Bonalumi, Angelo Vargas, Davide Ferri, Thomas Bürgi, Tamas Mallat, and Alfons Baiker pp 8467–8477 DOI: 10.1021/ja050424z Supporting Info

Insights into the Recognition and Association of Transmembrane α-Helices. The Free Energy of α-Helix Dimerization in Glycophorin A Jérôme Hénin, Andrew Pohorille, and Christophe Chipot pp 8478–8484 DOI: 10.1021/ja050581y Supporting Info

Cycloaddition Isomerizations of Adsorbed 1,3-Cyclohexadiene on Si(100)-2×1 Surface: First Neighbor Interactions Hee Soon Lee, Cheol Ho Choi, and Mark S. Gordon pp 8485–8491 DOI: 10.1021/ja050568d

Mercury Binding Sites in Thiol-Functionalized Mesostructured Silica Simon J. L. Billinge, Emily J. McKimmy, Mouath Shatnawi, HyunJeong Kim, Valeri Petkov, Didier Wermeille, and Thomas J. Pinnavaia pp 8492–8498 DOI: 10.1021/ja0506859

Using Mechanistic and Computational Studies To Explain Ligand Effects in the Palladium-Catalyzed Aerobic Oxidation of Alcohols Mitchell J. Schultz, Ryan S. Adler, Wiktor Zierkiewicz, Timofei Privalov, and Matthew S. Sigman pp 8499–8507 DOI: 10.1021/ja050949r Supporting Info

Electronic Coupling in Tetraanisylarylenediamine Mixed-Valence Systems:  The Interplay between Bridge Energy and Geometric Factors Christoph Lambert, Chad Risko, Veaceslav Coropceanu, Jürgen Schelter, Stephan Amthor, Nadine E. Gruhn, Jason C. Durivage, and Jean-Luc Brédas pp 8508–8516 DOI: 10.1021/ja0512172 Supporting Info

Polarizing a Hydrophobic Cavity for the Efficient Binding of Organic Guests:  The Case of Calix[6]tren, a Highly Efficient and Versatile Receptor for Neutral or Cationic Species Ulrich Darbost, Marie-Noëlle Rager, Samuel Petit, Ivan Jabin, and Olivia Reinaud pp 8517–8525 DOI: 10.1021/ja051299u Supporting Info

Enantioselective Synthesis of Cyclic Amides and Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis Elizabeth S. Sattely, G. Alexander Cortez, David C. Moebius, Richard R. Schrock, and Amir H. Hoveyda pp 8526–8533 DOI: 10.1021/ja051330s Supporting Info

6-Hydroxyquinoline-N-oxides:  A New Class of “Super” Photoacids1 Kyril M. Solntsev, Caroline E. Clower, Laren M. Tolbert, and Dan Huppert pp 8534–8544 DOI: 10.1021/ja0514545 Supporting Info

Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr*)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar* = C6H3-2,6(C6H2-2,4,6-Pri3)2 Tailuan Nguyen, Arunashree Panda, Marilyn M. Olmstead, Anne F. Richards, Mathias Stender, Marcin Brynda, and Philip P. Power pp 8545–8552 DOI: 10.1021/ja042958q Supporting Info

Helical Structures of N-Alkylated Poly(p-benzamide)s Aya Tanatani, Akihiro Yokoyama, Isao Azumaya, Yoshinori Takakura, Chikashi Mitsui, Motoo Shiro, Masanobu Uchiyama, Atsuya Muranaka, Nagao Kobayashi, and Tsutomu Yokozawa pp 8553–8561 DOI: 10.1021/ja0455291 Supporting Info

Controlling the Morphology of Cross β-Sheet Assemblies by Rational Design Songpon Deechongkit, Evan T. Powers, Shu-Li You, and Jeffery W. Kelly pp 8562–8570 DOI: 10.1021/ja050558c Supporting Info

Infrared Fingerprint Spectroscopy and Theoretical Studies of Potassium Ion Tagged Amino Acids and Peptides in the Gas Phase Nick C. Polfer, Béla Paizs, Lavina C. Snoek, Isabelle Compagnon, Sándor Suhai, Gerard Meijer, Gert von Helden, and Jos Oomens pp 8571–8579 DOI: 10.1021/ja050858u Supporting Info

Micropatterns of Spores Displaying Heterologous Proteins [J. Am. Chem. Soc. 2004, 126, 10512−10513]. Tae Jung Park, Kyung-Bok Lee, Seok Jae Lee, Jong Pil Park, Zee-Won Lee, Sang Yup Lee, Insung S. Choi, Soo-Keun Choi, Heung-Chae Jung, Jae-Gu Pan p 8580 DOI: 10.1021/ja059910c

Issue 24

“Volatilizable” Supports for High-Throughput Organic Synthesis Richard A. Houghten and Yongping Yu pp 8582–8583 DOI: 10.1021/ja0402396 Supporting Info

Generation of N-Heterocyclic Carbenes by Metal-Mediated Coupling of Propargylamine and Isocyanides Javier Ruiz, Gabriel García, Marta E. G. Mosquera, Bernabé F. Perandones, Marta P. Gonzalo, and Marilín Vivanco pp 8584–8585 DOI: 10.1021/ja042879e Supporting Info

Template-Synthesized DNA Nanotubes Shifeng Hou, Jiahai Wang, and Charles R. Martin pp 8586–8587 DOI: 10.1021/ja042343t Supporting Info

A Basket Tetradecavanadate Cluster with Blue Luminescence Lian Chen, Feilong Jiang, Zhengzhong Lin, Youfu Zhou, Chengyang Yue, and Maochun Hong pp 8588–8589 DOI: 10.1021/ja0422209 Supporting Info

Observation of an Fe(II) Spin-Crossover in a Cesium Iron Hexacyanochromate Wataru Kosaka, Kiyoshi Nomura, Kazuhito Hashimoto, and Shin-ichi Ohkoshi pp 8590–8591 DOI: 10.1021/ja050118l Supporting Info

Unique Toroidal Morphology from Composition and Sequence Control of Triblock Copolymers Zhiyun Chen, Honggang Cui, Kelly Hales, Zhibin Li, Kai Qi, Darrin J. Pochan, and Karen L. Wooley pp 8592–8593 DOI: 10.1021/ja050290p Supporting Info

Electrostatic Control of Aromatic Stacking Interactions Scott L. Cockroft, Christopher A. Hunter, Kevin R. Lawson, Julie Perkins, and Christopher J. Urch pp 8594–8595 DOI: 10.1021/ja050880n Supporting Info

Ion Transfer at Nanointerfaces between Water and Neat Organic Solvents Peng Sun, François O. Laforge, and Michael V. Mirkin pp 8596–8597 DOI: 10.1021/ja050999w

Single Molecule Visualization of Coordination-Assembled Porphyrin Macrocycles Reinforced with Covalent Linkings Osami Shoji, Hiroyuki Tanaka, Tomoji Kawai, and Yoshiaki Kobuke pp 8598–8599 DOI: 10.1021/ja051344y Supporting Info

Chemoselective Covalent Coupling of Oligonucleotide Probes to Self-Assembled Monolayers Neal K. Devaraj, Gregory P. Miller, Wataru Ebina, Boyko Kakaradov, James P. Collman, Eric T. Kool, and Christopher E. D. Chidsey pp 8600–8601 DOI: 10.1021/ja051462l Supporting Info

Direct Asymmetric Zn−Aldol Reaction of Methyl Vinyl Ketone and Its Synthetic Applications Barry M. Trost, Seunghoon Shin, and Joseph A. Sclafani pp 8602–8603 DOI: 10.1021/ja051526s Supporting Info

Primary Products and Mechanistic Considerations in Alkane Metathesis Jean Marie Basset, Christophe Copéret, Laurent Lefort, Barry M. Maunders, Olivier Maury, Erwan Le Roux, Guillaume Saggio, Sophie Soignier, Daravong Soulivong, Glenn J. Sunley, Mostafa Taoufik, and Jean Thivolle-Cazat pp 8604–8605 DOI: 10.1021/ja051679f Supporting Info

Conformational Change in Unsolvated Trp-cage Protein Probed by Fluorescence Anthony T. Iavarone and Joel H. Parks pp 8606–8607 DOI: 10.1021/ja051788u Supporting Info

Mechanism of Benzylsuccinate Synthase:  Stereochemistry of Toluene Addition to Fumarate and Maleate Chunhua Qiao and E. Neil G. Marsh pp 8608–8609 DOI: 10.1021/ja051972f Supporting Info

Double-Cuvette ISES:  In Situ Estimation of Enantioselectivity and Relative Rate for Catalyst Screening Sangeeta Dey, Kannan R. Karukurichi, Weijun Shen, and David B. Berkowitz pp 8610–8611 DOI: 10.1021/ja052010b Supporting Info

Design, Synthesis, and Reactivity of 1-Hydrazinodienes for Use in Organic Synthesis Glenn M. Sammis, Eric M. Flamme, Hao Xie, Douglas M. Ho, and Erik J. Sorensen pp 8612–8613 DOI: 10.1021/ja052383c Supporting Info

n-Type Field-Effect Transistors Made of an Individual Nitrogen-Doped Multiwalled Carbon Nanotube Kai Xiao, Yunqi Liu, Ping'an Hu, Gui Yu, Yanming Sun, and Daoben Zhu pp 8614–8617 DOI: 10.1021/ja042554y

Protein Structure Determination by High-Resolution Solid-State NMR Spectroscopy:  Application to Microcrystalline Ubiquitin Stephan G. Zech, A. Joshua Wand, and Ann E. McDermott pp 8618–8626 DOI: 10.1021/ja0503128 Supporting Info

Heats of Formation of Xenon Fluorides and the Fluxionality of XeF6 from High Level Electronic Structure Calculations David A. Dixon, Wibe A. de Jong, Kirk A. Peterson, Karl O. Christe, and Gary J. Schrobilgen pp 8627–8634 DOI: 10.1021/ja0423116 Supporting Info

A Study of the Mechanism and Kinetics of Cyclooctene Epoxidation Catalyzed by Iron(III) Tetrakispentafluorophenyl Porphyrin Ned A. Stephenson and Alexis T. Bell pp 8635–8643 DOI: 10.1021/ja043380n

Selective Synthesis of 5- or 6-Aryl Octahydrocyclopenta[b]pyrroles from a Common Precursor through Control of Competing Pathways in a Pd-Catalyzed Reaction Joshua E. Ney and John P. Wolfe pp 8644–8651 DOI: 10.1021/ja0430346 Supporting Info

An Efficient Unnatural Base Pair for a Base-Pair-Expanded Transcription System Tsuneo Mitsui, Michiko Kimoto, Yoko Harada, Shigeyuki Yokoyama, and Ichiro Hirao pp 8652–8658 DOI: 10.1021/ja0425280 Supporting Info

High Purity Anatase TiO2 Nanocrystals:  Near Room-Temperature Synthesis, Grain Growth Kinetics, and Surface Hydration Chemistry Guangshe Li, Liping Li, Juliana Boerio-Goates, and Brian F. Woodfield pp 8659–8666 DOI: 10.1021/ja050517g

Mechanistic Insights in Charge-Transfer-Induced Luminescence of 1,2-Dioxetanones with a Substituent of Low Oxidation Potential Hiroshi Isobe, Yu Takano, Mitsutaka Okumura, Seiki Kuramitsu, and Kizashi Yamaguchi pp 8667–8679 DOI: 10.1021/ja043295f Supporting Info

Neutral Structures with a Planar Tetracoordinated Carbon Based on Spiropentadiene Analogues Pierre M. Esteves, Narciso B. P. Ferreira, and Rodrigo J. Corrêa pp 8680–8685 DOI: 10.1021/ja042971a Supporting Info

Synthesis and Identification of Small Molecules that Potently Induce Apoptosis in Melanoma Cells through G1 Cell Cycle Arrest Robin S. Dothager, Karson S. Putt, Brittany J. Allen, Benjamin J. Leslie, Vitaliy Nesterenko, and Paul J. Hergenrother pp 8686–8696 DOI: 10.1021/ja042913p Supporting Info

Structures and Displacement of 1-Adamantanethiol Self-Assembled Monolayers on Au{111} Arrelaine A. Dameron, Lyndon F. Charles, and Paul S. Weiss pp 8697–8704 DOI: 10.1021/ja042621o

Protein Boson Peak Originated from Hydration-Related Multiple Minima Energy Landscape Yasumasa Joti, Akio Kitao, and Nobuhiro Go pp 8705–8709 DOI: 10.1021/ja0425886

Spectroscopic and Computational Studies of the ATP:Corrinoid Adenosyltransferase (CobA) from Salmonella enterica:  Insights into the Mechanism of Adenosylcobalamin Biosynthesis Troy A. Stich, Nicole R. Buan, Jorge C. Escalante-Semerena, and Thomas C. Brunold pp 8710–8719 DOI: 10.1021/ja042142p Supporting Info

Immobilization of Rhodium Complexes at Thiolate Monolayers on Gold Surfaces:  Catalytic and Structural Studies Thomas Belser, Meike Stöhr, and Andreas Pfaltz pp 8720–8731 DOI: 10.1021/ja0500714 Supporting Info

Crystal Structures, Electronic Properties, and Pressure-Induced Superconductivity of the Tetrahedral Cluster Compounds GaNb4S8, GaNb4Se8, and GaTa4Se8 Regina Pocha, Dirk Johrendt, Bingfang Ni, and Mohsen M. Abd-Elmeguid pp 8732–8740 DOI: 10.1021/ja050243x Supporting Info

Polymorphism in AB13 Nanoparticle Superlattices:  An Example of Semiconductor−Metal Metamaterials Elena V. Shevchenko, Dmitri V. Talapin, Stephen O'Brien, and Christopher B. Murray pp 8741–8747 DOI: 10.1021/ja050510z

Understanding the Template Preorganization Step of an Artificial Arginine Receptor Barbara Kirchner and Markus Reiher pp 8748–8756 DOI: 10.1021/ja050614+ Supporting Info

Bilayers and Interdigitation in Block Copolymer Vesicles Giuseppe Battaglia and Anthony J. Ryan pp 8757–8764 DOI: 10.1021/ja050742y

Theoretical Analysis of Factors Controlling the Nonalternating CO/C2H4 Copolymerization Alicja Haras, Artur Michalak, Bernhard Rieger, and Tom Ziegler pp 8765–8774 DOI: 10.1021/ja050861d

Fluorescence Correlation Spectroscopy, a Tool to Investigate Supramolecular Dynamics:  Inclusion Complexes of Pyronines with Cyclodextrin Wajih Al-Soufi, Belén Reija, Mercedes Novo, Suren Felekyan, Ralf Kühnemuth, and Claus A. M. Seidel pp 8775–8784 DOI: 10.1021/ja0508976 Supporting Info

(4,2)D Projection−Reconstruction Experiments for Protein Backbone Assignment:  Application to Human Carbonic Anhydrase II and Calbindin D28K Ronald A. Venters, Brian E. Coggins, Doug Kojetin, John Cavanagh, and Pei Zhou pp 8785–8795 DOI: 10.1021/ja0509580 Supporting Info

CdO as the Archetypical Transparent Conducting Oxide. Systematics of Dopant Ionic Radius and Electronic Structure Effects on Charge Transport and Band Structure Yu Yang, Shu Jin, Julia E. Medvedeva, John R. Ireland, Andrew W. Metz, Jun Ni, Mark C. Hersam, Arthur J. Freeman, and Tobin J. Marks pp 8796–8804 DOI: 10.1021/ja051272a

Three-Dimensional Structure of Nanocomposites from Atomic Pair Distribution Function Analysis:  Study of Polyaniline and (Polyaniline)0.5V2O5·1.0H2O Valeri Petkov, Vencislav Parvanov, Pantelis Trikalitis, Christos Malliakas, Tom Vogt, and Mercouri G. Kanatzidis pp 8805–8812 DOI: 10.1021/ja051315n Supporting Info

A Chemical Sensor for the Liquid-Ordered Phase Honghua Cao, Jianbing Zhang, Bingwen Jing, and Steven L. Regen pp 8813–8816 DOI: 10.1021/ja0513988 Supporting Info

Combined Ruthenium(II) and Lipase Catalysis for Efficient Dynamic Kinetic Resolution of Secondary Alcohols. Insight into the Racemization Mechanism Belén Martín-Matute, Michaela Edin, Krisztián Bogár, F. Betül Kaynak, and Jan-E. Bäckvall pp 8817–8825 DOI: 10.1021/ja051576x Supporting Info

Enantioselective Organocatalytic α-Fluorination of Aldehydes Teresa D. Beeson and David W. C. MacMillan pp 8826–8828 DOI: 10.1021/ja051805f Supporting Info

Influence of Inter- and Intramolecular Hydrogen Bonding on Kemp Decarboxylations from QM/MM Simulations Orlando Acevedo and William L. Jorgensen pp 8829–8834 DOI: 10.1021/ja051793y Supporting Info

Tuning First Molecular Hyperpolarizabilities through the Use of Proaromatic Spacers Raquel Andreu, Maria Jesús Blesa, Laura Carrasquer, Javier Garín, Jesús Orduna, Belén Villacampa, Rafael Alcalá, Juan Casado, Mari Carmen Ruiz Delgado, Juan T. López Navarrete, and Magali Allain pp 8835–8845 DOI: 10.1021/ja051819l Supporting Info

Synthesis of Stable and Cell-type Selective Analogues of Cyclic ADP−Ribose, a Ca2+-Mobilizing Second Messenger. Structure−Activity Relationship of the N1-Ribose Moiety1 Takashi Kudoh, Masayoshi Fukuoka, Satoshi Ichikawa, Takashi Murayama, Yasuo Ogawa, Minako Hashii, Haruhiro Higashida, Svenja Kunerth, Karin Weber, Andreas H. Guse, Barry V. L. Potter, Akira Matsuda, and Satoshi Shuto pp 8846–8855 DOI: 10.1021/ja050732x Supporting Info

Divergent Mechanisms of Suicide Inactivation for Ethanolamine Ammonia-Lyase Gregory M. Sandala, David M. Smith, and Leo Radom pp 8856–8864 DOI: 10.1021/ja051527k Supporting Info

Single-Step Covalent Functionalization of Polylactide Surfaces Ulrica Edlund, Martina Källrot, and Ann-Christine Albertsson pp 8865–8871 DOI: 10.1021/ja052073u

The Total Synthesis of Coleophomones B, C, and D K. C. Nicolaou, Tamsyn Montagnon, Georgios Vassilikogiannakis, and Casey J. N. Mathison pp 8872–8888 DOI: 10.1021/ja0509984 Supporting Info

Designed Ferromagnetic, Ferroelectric Bi2NiMnO6 Masaki Azuma, Kazuhide Takata, Takashi Saito, Shintaro Ishiwata, Yuichi Shimakawa, and Mikio Takano pp 8889–8892 DOI: 10.1021/ja0512576

Thickness Transition of a Rigid Supramolecular Polymer Laurent Bouteiller, Olivier Colombani, Frédéric Lortie, and Pierre Terech pp 8893–8898 DOI: 10.1021/ja0511016 Supporting Info

eHiTS 5.1.6 SimBioSys Inc., 135 Queen's Plate Drive, Unit 420, Toronto, Ontario M9W 6V1, Canada. http://simbiosys.ca/index.html. For pricing information, contact company. Sean Michael Kerwin pp 8899–8900 DOI: 10.1021/ja041024z

Issue 25

Diastereoselective Amplification of an Induced-Fit Receptor from a Dynamic Combinatorial Library Peter T. Corbett, Lok H. Tong, Jeremy K. M. Sanders, and Sijbren Otto pp 8902–8903 DOI: 10.1021/ja050790i Supporting Info

Measuring pKa Values in Protein Folding Transition State Ensembles by NMR Spectroscopy Martin Tollinger, Lewis E. Kay, and Julie D. Forman-Kay pp 8904–8905 DOI: 10.1021/ja051942c Supporting Info

Experimental and Theoretical Evidence for the Formation of Zinc Tricarbonyl in Solid Argon Ling Jiang and Qiang Xu pp 8906–8907 DOI: 10.1021/ja052329w Supporting Info

Protein Conformation-Induced Modulation of Ligand Binding Kinetics:  A Femtosecond Mid-IR Study of Nitric Oxide Binding Trajectories in Myoglobin Seongheun Kim and Manho Lim pp 8908–8909 DOI: 10.1021/ja0502270 Supporting Info

Chemoenzymatic Synthesis of the Polyketide Macrolactone 10-Deoxymethynolide Courtney C. Aldrich, Lakshmanan Venkatraman, David H. Sherman, and Robert A. Fecik pp 8910–8911 DOI: 10.1021/ja0504340 Supporting Info

Using Liquid Crystals to Report Membrane Proteins Captured by Affinity Microcontact Printing from Cell Lysates and Membrane Extracts Chang-Hyun Jang, Matthew L. Tingey, Nichole L. Korpi, Gregory J. Wiepz, Joan H. Schiller, Paul J. Bertics, and Nicholas L. Abbott pp 8912–8913 DOI: 10.1021/ja051079g

Monitoring Dopamine Release from Single Living Vesicles with Nanoelectrodes Wen-Zhan Wu, Wei-Hua Huang, Wei Wang, Zong-Li Wang, Jie-Ke Cheng, Tao Xu, Rong-Ying Zhang, Yu Chen, and Jie Liu pp 8914–8915 DOI: 10.1021/ja050385r Supporting Info

Fabrication of Uniform Magnetic Nanocomposite Spheres with a Magnetic Core/Mesoporous Silica Shell Structure Wenru Zhao, Jinlou Gu, Lingxia Zhang, Hangrong Chen, and Jianlin Shi pp 8916–8917 DOI: 10.1021/ja051113r Supporting Info

Fabrication of Carbon Nanotube−Molecule−Silicon Junctions Austen K. Flatt, Bo Chen, and James M. Tour pp 8918–8919 DOI: 10.1021/ja051269r Supporting Info

Membrane Media Create Small Nanospaces for Molecular Computation Seiichi Uchiyama, Gareth D. McClean, Kaoru Iwai, and A. Prasanna de Silva pp 8920–8921 DOI: 10.1021/ja0513638

Full-Color Photochromism of a Fused Dithienylethene Trimer Kenji Higashiguchi, Kenji Matsuda, Naoki Tanifuji, and Masahiro Irie pp 8922–8923 DOI: 10.1021/ja051467i Supporting Info

Redox-Induced Synthesis and Encapsulation of Metal Nanoparticles in Shell-Cross-Linked Organometallic Nanotubes Xiao-Song Wang, Hai Wang, Neil Coombs, Mitchell A. Winnik, and Ian Manners pp 8924–8925 DOI: 10.1021/ja051365s Supporting Info

Phosphaquinomethane and Phosphathienoquinomethanes, and Their Anion Radicals Fumiki Murakami, Shigeru Sasaki, and Masaaki Yoshifuji pp 8926–8927 DOI: 10.1021/ja052271l Supporting Info

Extensive Quinoidal Oligothiophenes with Dicyanomethylene Groups at Terminal Positions as Highly Amphoteric Redox Molecules Toshiaki Takahashi, Ken-ichi Matsuoka, Kazuo Takimiya, Tetsuo Otsubo, and Yoshio Aso pp 8928–8929 DOI: 10.1021/ja051840m Supporting Info

Simultaneous Targeted Immobilization of Anti-Human IgG-Coated Nanotubes and Anti-Mouse IgG-Coated Nanotubes on the Complementary Antigen-Patterned Surfaces via Biological Molecular Recognition Zheyuan Zhao, Ipsita A. Banerjee, and Hiroshi Matsui pp 8930–8931 DOI: 10.1021/ja051053p

Block Copolymer-Templated Chemistry on Si, Ge, InP, and GaAs Surfaces Masato Aizawa and Jillian M. Buriak pp 8932–8933 DOI: 10.1021/ja052281m Supporting Info

Photorelease of Alcohols from 2-Nitrobenzyl Ethers Proceeds via Hemiacetals and May Be Further Retarded by Buffers Intercepting the Primary aci-Nitro Intermediates Bruno Hellrung, Yavor Kamdzhilov, Markus Schwörer, and Jakob Wirz pp 8934–8935 DOI: 10.1021/ja052300s Supporting Info

Supramolecular Nano Networks Formed by Molecular-Recognition-Directed Self-Assembly of Ditopic Calix[5]arene and Dumbbell [60]Fullerene Takeharu Haino, Youko Matsumoto, and Yoshimasa Fukazawa pp 8936–8937 DOI: 10.1021/ja0524088 Supporting Info

Functional Oligo(vinyl acetate) CO2-philes for Solubilization and Emulsification Bien Tan and Andrew I. Cooper pp 8938–8939 DOI: 10.1021/ja052508d Supporting Info

A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis Chuan-De Wu, Aiguo Hu, Lin Zhang, and Wenbin Lin pp 8940–8941 DOI: 10.1021/ja052431t Supporting Info

Enantioselective Friedel−Crafts Alkylations of α,β-Unsaturated 2-Acyl Imidazoles Catalyzed by Bis(oxazolinyl)pyridine−Scandium(III) Triflate Complexes David A. Evans, Keith R. Fandrick, and Hyun-Ji Song pp 8942–8943 DOI: 10.1021/ja052433d Supporting Info

Exceptionally Facile CO Addition to a Saturated Ruthenium Complex Christine Bibal, Yegor D. Smurnyy, Maren Pink, and Kenneth G. Caulton pp 8944–8945 DOI: 10.1021/ja051296h Supporting Info

Acylation versus Sulfonylation in the Inhibition of Elastase by 3-Oxo-β-Sultams Wing Y. Tsang, Naveed Ahmed, Lindsay P. Harding, Karl Hemming, Andrew P. Laws, and Michael I. Page pp 8946–8947 DOI: 10.1021/ja050787z Supporting Info

Catalytic Enantioselective C−C Bond Forming Conjugate Additions with Vinyl Sulfones Hongming Li, Jun Song, Xiaofeng Liu, and Li Deng pp 8948–8949 DOI: 10.1021/ja0511063 Supporting Info

Dithiolato-Bridged Dinuclear Iron−Nickel Complexes [Fe(CO)2(CN)2(μ-SCH2CH2CH2S)Ni(S2CNR2)]- Modeling the Active Site of [NiFe] Hydrogenase Zilong Li, Yasuhiro Ohki, and Kazuyuki Tatsumi pp 8950–8951 DOI: 10.1021/ja051590+ Supporting Info

A Low-Threshold, High-Efficiency Microfluidic Waveguide Laser Dmitri V. Vezenov, Brian T. Mayers, Richard S. Conroy, George M. Whitesides, Preston T. Snee, Yinthai Chan, Daniel G. Nocera, and Moungi G. Bawendi pp 8952–8953 DOI: 10.1021/ja0517421 Supporting Info

Quantification of Singlet Oxygen Production in the Reaction of Superoxide with Hydrogen Peroxide Using a Selective Chemiluminescent Probe Laura A. MacManus-Spencer and Kristopher McNeill pp 8954–8955 DOI: 10.1021/ja052045b Supporting Info

The Template Synthesis of Double Coaxial Carbon Nanotubes with Nitrogen-Doped and Boron-Doped Multiwalls Quanhong Yang, Weihua Xu, Akira Tomita, and Takashi Kyotani pp 8956–8957 DOI: 10.1021/ja052357e Supporting Info

Fluorous Bulk Membranes for Potentiometric Sensors with Wide Selectivity Ranges:  Observation of Exceptionally Strong Ion Pair Formation Paul G. Boswell and Philippe Bühlmann pp 8958–8959 DOI: 10.1021/ja052403a Supporting Info

Concurrent Cyclopropanation by Carbenes and Carbanions Robert A. Moss and Jingzhi Tian pp 8960–8961 DOI: 10.1021/ja052426p Supporting Info

Catalytic Asymmetric Epoxidation of α,β-Unsaturated Esters Using an Yttrium-Biphenyldiol Complex Hiroyuki Kakei, Riichiro Tsuji, Takashi Ohshima, and Masakatsu Shibasaki pp 8962–8963 DOI: 10.1021/ja052466t Supporting Info

Thiourea-Catalyzed Enantioselective Cyanosilylation of Ketones Douglas E. Fuerst and Eric N. Jacobsen pp 8964–8965 DOI: 10.1021/ja052511x Supporting Info

Catalytic Asymmetric Hydrogenation of N-Iminopyridinium Ylides:  Expedient Approach to Enantioenriched Substituted Piperidine Derivatives Claude Y. Legault and André B. Charette pp 8966–8967 DOI: 10.1021/ja0525298 Supporting Info

Light-Controlled Molecular Switches Modulate Nanocrystal Fluorescence Linyong Zhu, Ming-Qiang Zhu, James K. Hurst, and Alexander D. Q. Li pp 8968–8970 DOI: 10.1021/ja0423421 Supporting Info

Total Synthesis of RK-397 Scott E. Denmark and Shinji Fujimori pp 8971–8973 DOI: 10.1021/ja052226d Supporting Info

An Efficient, Stereocontrolled Synthesis of a Potent Omuralide−Salinosporin Hybrid for Selective Proteasome Inhibition Leleti Rajender Reddy, Jean-François Fournier, B. V. Subba Reddy, and E. J. Corey pp 8974–8976 DOI: 10.1021/ja052376o Supporting Info

Evidence for the Isomerization and Decarboxylation in the Photoconversion of the Red Fluorescent Protein DsRed Satoshi Habuchi, Mircea Cotlet, Thomas Gensch, Teresa Bednarz, Sabina Haber-Pohlmeier, Jef Rozenski, Gunter Dirix, Jan Michiels, Jos Vanderleyden, Joachim Heberle, Frans C. De Schryver, and Johan Hofkens pp 8977–8984 DOI: 10.1021/ja047023o Supporting Info

Long-Range Magnetic Ordering in Iron Jarosites Prepared by Redox-Based Hydrothermal Methods Bart M. Bartlett and Daniel G. Nocera pp 8985–8993 DOI: 10.1021/ja050205d Supporting Info

Columnar Mesomorphic Organizations in Cyclotriphosphazenes Joaquín Barberá, Manuel Bardají, Josefina Jiménez, Antonio Laguna, M. Pilar Martínez, Luis Oriol, José Luis Serrano, and Irene Zaragozano pp 8994–9002 DOI: 10.1021/ja051042w Supporting Info

Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases:  Evidence for a Common Catalyst Cindy-Xing Yin and Richard G. Finke pp 9003–9013 DOI: 10.1021/ja051594e Supporting Info

Stable Hydrocarbon Diradical, An Analogue of Trimethylenemethane Andrzej Rajca, Kouichi Shiraishi, Matthew Vale, Hongxian Han, and Suchada Rajca pp 9014–9020 DOI: 10.1021/ja052002v Supporting Info

Electron Affinities of 1,1-Diaryl-2,3,4,5-tetraphenylsiloles:  Direct Measurements and Comparison with Experimental and Theoretical Estimates Xiaowei Zhan, Chad Risko, Fabrice Amy, Calvin Chan, Wei Zhao, Stephen Barlow, Antoine Kahn, Jean-Luc Brédas, and Seth R. Marder pp 9021–9029 DOI: 10.1021/ja051139i Supporting Info

Single-Crystal Studies of Peptide Prolyl and Glycyl 15N Shielding Tensors Kevin W. Waddell, Eduard Y. Chekmenev, and Richard J. Wittebort pp 9030–9035 DOI: 10.1021/ja044204h Supporting Info

Modulation of Calcium Oxalate Monohydrate Crystallization by Citrate through Selective Binding to Atomic Steps S. Roger Qiu, Andrzej Wierzbicki, E. Alan Salter, Salvador Zepeda, Chris A. Orme, John R. Hoyer, George H. Nancollas, Anita M. Cody, and James J. De Yoreo pp 9036–9044 DOI: 10.1021/ja043591s

Molecular Recognition of Carbohydrates with Artificial Receptors:  Mimicking the Binding Motifs Found in the Crystal Structures of Protein−Carbohydrate Complexes Monika Mazik, Hüseyin Cavga, and Peter G. Jones pp 9045–9052 DOI: 10.1021/ja043037i Supporting Info

Smectic Liquid Crystals from Supramolecular Guanidinium Alkanesulfonates Fabrice Mathevet, Patrick Masson, Jean-François Nicoud, and Antoine Skoulios pp 9053–9061 DOI: 10.1021/ja051312a Supporting Info

Effect of Tip Functionalization on Transport through Vertically Oriented Carbon Nanotube Membranes Mainak Majumder, Nitin Chopra, and Bruce J. Hinds pp 9062–9070 DOI: 10.1021/ja043013b

Highly Fluorescent Solid-State Asymmetric Spirosilabifluorene Derivatives Sang Ho Lee, Bo-Bin Jang, and Zakya H. Kafafi pp 9071–9078 DOI: 10.1021/ja042762q

Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide Szilárd Csihony, Darcy A. Culkin, Alan C. Sentman, Andrew P. Dove, Robert M. Waymouth, and James L. Hedrick pp 9079–9084 DOI: 10.1021/ja050909n Supporting Info

G-Matrix Fourier Transform NOESY-Based Protocol for High-Quality Protein Structure Determination Yang Shen, Hanudatta S. Atreya, Gaohua Liu, and Thomas Szyperski pp 9085–9099 DOI: 10.1021/ja0501870 Supporting Info

Photo-cross-linked Immobilization of Polyelectrolytes for Enzymatic Construction of Conductive Nanocomposites Sofia Trakhtenberg, Yelda Hangun-Balkir, John C. Warner, Ferdinando F. Bruno, Jayant Kumar, Ramaswamy Nagarajan, and Lynne A. Samuelson pp 9100–9104 DOI: 10.1021/ja042438v Supporting Info

Polaron Delocalization in Ladder Macromolecular Systems X. Z. Yan, J. Pawlas, T. Goodson, III, and J. F. Hartwig pp 9105–9116 DOI: 10.1021/ja050184n Supporting Info

How the Co−C Bond Is Cleaved in Coenzyme B12 Enzymes:  A Theoretical Study Kasper P. Jensen and Ulf Ryde pp 9117–9128 DOI: 10.1021/ja050744i Supporting Info

A Luminescence Sensor of Inositol 1,4,5-Triphosphate and Its Model Compound by Ruthenium-Templated Assembly of a Bis(Zn2+-Cyclen) Complex Having a 2,2‘-Bipyridyl Linker (Cyclen = 1,4,7,10-Tetraazacyclododecane) Shin Aoki, Mohd Zulkefeli, Motoo Shiro, Masanori Kohsako, Kei Takeda, and Eiichi Kimura pp 9129–9139 DOI: 10.1021/ja050876b Supporting Info

Powder Crystallography by Proton Solid-State NMR Spectroscopy Bénédicte Elena and Lyndon Emsley pp 9140–9146 DOI: 10.1021/ja051208t

The Role of the Peripheral Anionic Site and Cation−π Interactions in the Ligand Penetration of the Human AChE Gorge Davide Branduardi, Francesco Luigi Gervasio, Andrea Cavalli, Maurizio Recanatini, and Michele Parrinello pp 9147–9155 DOI: 10.1021/ja0512780 Supporting Info

Synthesis, Physical Properties, Multitemperature Crystal Structure, and 20 K Synchrotron X-ray Charge Density of a Magnetic Metal Organic Framework Structure, Mn3(C8O4H4)3(C5H11ON)2 Rasmus D. Poulsen, Anders Bentien, Marie Chevalier, and Bo B. Iversen pp 9156–9166 DOI: 10.1021/ja051233z Supporting Info

Conservation of μs−ms Enzyme Motions in the Apo- and Substrate-Mimicked State Heather Beach, Roger Cole, Michelle L. Gill, and J. Patrick Loria pp 9167–9176 DOI: 10.1021/ja0514949 Supporting Info

Nanostructuring, Compositional Fluctuations, and Atomic Ordering in the Thermoelectric Materials AgPbmSbTe2+m. The Myth of Solid Solutions Eric Quarez, Kuei-Fang Hsu, Robert Pcionek, N. Frangis, E. K. Polychroniadis, and Mercouri G. Kanatzidis pp 9177–9190 DOI: 10.1021/ja051653o Supporting Info

Magnetoswitchable Reactions of DNA Monolayers on Electrodes:  Gating the Processes by Hydrophobic Magnetic Nanoparticles Eugenii Katz, Yossi Weizmann, and Itamar Willner pp 9191–9200 DOI: 10.1021/ja0517771

Synthesis and Reaction of [{HC(CMeNAr)2}Mn]2 (Ar = 2,6-iPr2C6H3):  The Complex Containing Three-Coordinate Manganese(I) with a Mn−Mn Bond Exhibiting Unusual Magnetic Properties and Electronic Structure Jianfang Chai, Hongping Zhu, A. Claudia Stückl, Herbert W. Roesky, Jörg Magull, Alessandro Bencini, Andrea Caneschi, and Dante Gatteschi pp 9201–9206 DOI: 10.1021/ja042269e Supporting Info

Coordination-Based Gold Nanoparticle Layers Meni Wanunu, Ronit Popovitz-Biro, Hagai Cohen, Alexander Vaskevich, and Israel Rubinstein pp 9207–9215 DOI: 10.1021/ja050016v Supporting Info

“Concerted” Transition State, Stepwise Mechanism. Dynamics Effects in C2-C6 Enyne Allene Cyclizations Tefsit Bekele, Chad F. Christian, Mark A. Lipton, and Daniel A. Singleton pp 9216–9223 DOI: 10.1021/ja0508673 Supporting Info

Effect of Molecular Weight on the Exponential Growth and Morphology of Hyaluronan/Chitosan Multilayers:  A Surface Plasmon Resonance Spectroscopy and Atomic Force Microscopy Investigation Piotr Kujawa, Patricia Moraille, Jacqueline Sanchez, Antonella Badia, and Françoise M. Winnik pp 9224–9234 DOI: 10.1021/ja044385n Supporting Info

Electrochemical Gate-Controlled Conductance of Single Oligo(phenylene ethynylene)s Xiaoyin Xiao, Larry A. Nagahara, Adam M. Rawlett, and Nongjian Tao pp 9235–9240 DOI: 10.1021/ja050381m Supporting Info

Theoretical Prediction of Noble Gas Containing Anions FNgO- (Ng = He, Ar, and Kr) Tsung-Hui Li, Chun-Hao Mou, Hui-Ru Chen, and Wei-Ping Hu pp 9241–9245 DOI: 10.1021/ja051276f Supporting Info

Total Synthesis of Brevetoxin B Isao Kadota, Hiroyoshi Takamura, Hiroki Nishii, and Yoshinori Yamamoto pp 9246–9250 DOI: 10.1021/ja051171c Supporting Info

Highly Active, Immobilized Ruthenium Catalysts for Oxidation of Alcohols to Aldehydes and Ketones. Preparation and Use in Both Batch and Flow Systems Shū Kobayashi, Hiroyuki Miyamura, Ryo Akiyama, and Tasuku Ishida pp 9251–9254 DOI: 10.1021/ja051246c Supporting Info

A 13C NMR Study of the Molecular Dynamics and Phase Transition of Confined Benzene inside Titanate Nanotubes Xiao-Ping Tang, Jing-Chen Wang, Lewis W. Cary, Alfred Kleinhammes, and Yue Wu pp 9255–9259 DOI: 10.1021/ja051628i

Copper- or Phosphine-Catalyzed Reaction of Alkynes with Isocyanides. Regioselective Synthesis of Substituted Pyrroles Controlled by the Catalyst Shin Kamijo, Chikashi Kanazawa, and Yoshinori Yamamoto pp 9260–9266 DOI: 10.1021/ja051875m Supporting Info

Enhancement of O2 Dissociation on Au(111) by Adsorbed Oxygen:  Implications for Oxidation Catalysis Xingyi Deng, Byoung Koun Min, Amado Guloy, and Cynthia M. Friend pp 9267–9270 DOI: 10.1021/ja050144j

Efficient Preparation of Organic Substrate−RNA Conjugates via in Vitro Transcription Roberto Fiammengo, Kamil Musílek, and Andres Jäschke pp 9271–9276 DOI: 10.1021/ja051179m Supporting Info

Selective Solvent Interactions in a Fluorous Reaction System John T. Gerig pp 9277–9284 DOI: 10.1021/ja042314i Supporting Info

A Highly Efficient Organocatalyst for Direct Aldol Reactions of Ketones with Aldedydes Zhuo Tang, Zhi-Hua Yang, Xiao-Hua Chen, Lin-Feng Cun, Ai-Qiao Mi, Yao-Zhong Jiang, and Liu-Zhu Gong pp 9285–9289 DOI: 10.1021/ja0510156 Supporting Info

Kinetic Acidity of Aliphatic Hydrocarbons. Hydrogen Isotope Exchange with Cesium Cyclohexylamide in Cyclohexylamine1 Andrew Streitwieser, Thomas A. Keevil, David R. Taylor, and Edward C. Dart pp 9290–9297 DOI: 10.1021/ja051366k Supporting Info

Computational Characterization of the Role of the Base in the Suzuki−Miyaura Cross-Coupling Reaction Ataualpa A. C. Braga, Nelson H. Morgon, Gregori Ujaque, and Feliu Maseras pp 9298–9307 DOI: 10.1021/ja050583i Supporting Info

Structural and Electron-Transfer Characteristics of O-, S-, and Se-Tethered Porphyrin Monolayers on Si(100) [J. Am. Chem. Soc. 2004, 126, 15603−15612]. Amir A. Yasseri, Dennis Syomin, Robert S. Loewe, Jonathan S. Lindsey, Francisco Zaera, and David F. Bocian p 9308 DOI: 10.1021/ja053081d

TTF Chemistry:  Fundamentals and Applications of Tetrathiafulvalene Edited by Jun-ichi Yamada (Himeji Institute of Technology, Hyogo, Japan) and Toyonari Sugimoto (Osaka Prefecture University). Kodansha Ltd:  Tokyo and Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xviii + 446 pp. $229.00. ISBN 4-06-211164-0 (Kodansha) and 3-540-21004-0 (Springer). Françisco M. Raymo p 9309 DOI: 10.1021/ja041039x

Homogeneous Catalysis:  Understanding the Art By Piet W. N. M. van Leeuwen (University of Amsterdam). Kluwer Academic Publishers:  Dordrecht, Boston, London. 2004. xiv + 408 pp. $150.00. ISBN 1-4020-1999-8. Ross A. Widenhoefer pp 9309–9310 DOI: 10.1021/ja040992z

Chromatography:  Concepts and Contrasts, 2nd ed By James M. Miller (Drew University, Madison). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xxvi + 490 pp. $94.50. ISBN 0-471-47207-7. James D. Stuart p 9310 DOI: 10.1021/ja0410284

Issue 26

π-Conjugated Conjoined Double Helicene via a Sequence of Three Oxidative CC- and NN-Homocouplings Kouichi Shiraishi, Andrzej Rajca, Maren Pink, and Suchada Rajca pp 9312–9313 DOI: 10.1021/ja051521v Supporting Info

Alkaline Phosphatase Catalysis Is Ultrasensitive to Charge Sequestered between the Active Site Zinc Ions Ivana Nikolic-Hughes, Patrick J. O'Brien, and Daniel Herschlag pp 9314–9315 DOI: 10.1021/ja051603j Supporting Info

Sugar Sensing with Synthetic Multifunctional Pores Svetlana Litvinchuk, Nathalie Sordé, and Stefan Matile pp 9316–9317 DOI: 10.1021/ja052134o Supporting Info

Photochemically and Thermally Tunable Planar Defects in Colloidal Photonic Crystals Friederike Fleischhaker, André C. Arsenault, Vladimir Kitaev, Frank C. Peiris, Georg von Freymann, Ian Manners, Rudolf Zentel, and Geoffrey A. Ozin pp 9318–9319 DOI: 10.1021/ja0521573

Fluorescent Profiling of Natural Product Producers Joel S. Sandler, William Fenical, Brian M. Gulledge, A. Richard Chamberlin, and James J. La Clair pp 9320–9321 DOI: 10.1021/ja042756u Supporting Info

Platinum Stilbazoles:  Ring-Walking Coupled with Aryl−Halide Bond Activation David Strawser, Amir Karton, Olena V. Zenkina, Mark A. Iron, Linda J. W. Shimon, Jan M. L. Martin, and Milko E. van der Boom pp 9322–9323 DOI: 10.1021/ja050613h Supporting Info

Molecules That Assemble by Sound:  An Application to the Instant Gelation of Stable Organic Fluids Takeshi Naota and Hiroshi Koori pp 9324–9325 DOI: 10.1021/ja050809h Supporting Info

Bacterial Aerobic Synthesis of Nanocrystalline Magnetite Atul Bharde, Aijaz Wani, Yogesh Shouche, Pattayil A. Joy, Bhagavatula L. V. Prasad, and Murali Sastry pp 9326–9327 DOI: 10.1021/ja0508469 Supporting Info

Quantum Dot-Based Western Blot Technology for Ultrasensitive Detection of Tracer Proteins Rumiana Bakalova, Zhivko Zhelev, Hideki Ohba, and Yoshinobu Baba pp 9328–9329 DOI: 10.1021/ja0510055 Supporting Info

Remarkably Volatile Copper(II) Complexes of N,N‘-Unsymmetrically Substituted 1,3-Diketimines as Precursors for Cu Metal Deposition via CVD or ALD Kyung-Ho Park and Will J. Marshall pp 9330–9331 DOI: 10.1021/ja051158s Supporting Info

Light-Emitting Efficiency Tuning of Rod-Shaped π Conjugated Systems by Donor and Acceptor Groups Yoshihiro Yamaguchi, Takahiro Tanaka, Shigeya Kobayashi, Tateaki Wakamiya, Yoshio Matsubara, and Zen-ichi Yoshida pp 9332–9333 DOI: 10.1021/ja051588i Supporting Info

Explicit Treatment of Spin Labels in Modeling of Distance Constraints from Dipolar EPR and DEER Ken Sale, Likai Song, Yi-Shiuan Liu, Eduardo Perozo, and Piotr Fajer pp 9334–9335 DOI: 10.1021/ja051652w

Probing the Breadth of Macrolide Glycosyltransferases:  In Vitro Remodeling of a Polyketide Antibiotic Creates Active Bacterial Uptake and Enhances Potency Min Yang, Mark R. Proctor, David N. Bolam, James C. Errey, Robert A. Field, Harry J. Gilbert, and Benjamin G. Davis pp 9336–9337 DOI: 10.1021/ja051482n Supporting Info

Alkali Metals Plus Silica Gel:  Powerful Reducing Agents and Convenient Hydrogen Sources James L. Dye, Kevin D. Cram, Stephanie A. Urbin, Mikhail Y. Redko, James E. Jackson, and Michael Lefenfeld pp 9338–9339 DOI: 10.1021/ja051786+ Supporting Info

Biosynthesis of TDP-l-Mycarose:  The Specificity of a Single Enzyme Governs the Outcome of the Pathway Haruko Takahashi, Yung-nan Liu, Huawei Chen, and Hung-wen Liu pp 9340–9341 DOI: 10.1021/ja051409x Supporting Info

Synthesis of the Azaphilones Using Copper-Mediated Enantioselective Oxidative Dearomatization Jianglong Zhu, Nicholas P. Grigoriadis, Jonathan P. Lee, and John A. Porco, Jr. pp 9342–9343 DOI: 10.1021/ja052049g Supporting Info

Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex Nathan A. Eckert, Sebastian Stoian, Jeremy M. Smith, Emile L. Bominaar, Eckard Münck, and Patrick L. Holland pp 9344–9345 DOI: 10.1021/ja0436704 Supporting Info

An η6-Dienyne Transition-Metal Complex Joseph M. O'Connor, Seth J. Friese, Betsy L. Rodgers, Arnold L. Rheingold, and Lev Zakharov pp 9346–9347 DOI: 10.1021/ja042272y Supporting Info

High Facial Diastereoselectivity in Intra- and Intermolecular Reactions of Chiral Benzylic Cations Friedrich Mühlthau, Oliver Schuster, and Thorsten Bach pp 9348–9349 DOI: 10.1021/ja050626v Supporting Info

A REDOR NMR Study of a Phosphorylated Statherin Fragment Bound to Hydroxyapatite Crystals James M. Gibson, Vinodhkumar Raghunathan, Jennifer M. Popham, Patrick S. Stayton, and Gary P. Drobny pp 9350–9351 DOI: 10.1021/ja050910m Supporting Info

Asymmetric [2,3]-Sigmatropic Rearrangement of Allylic Ammonium Ylides Jan Blid, Olaf Panknin, and Peter Somfai pp 9352–9353 DOI: 10.1021/ja0510562 Supporting Info

Spinel Ferrite/MnO Core/Shell Nanoparticles:  Chemical Synthesis of All-Oxide Exchange Biased Architectures Ombretta Masala and Ram Seshadri pp 9354–9355 DOI: 10.1021/ja051244s Supporting Info

Surfactant Headgroup Orientation at the Air/Water Interface Dennis K. Hore, Daniel K. Beaman, and Geraldine L. Richmond pp 9356–9357 DOI: 10.1021/ja051492o

Mapping Polypeptide Self-Recognition through 1H Off-Resonance Relaxation Veronica Esposito, Rahul Das, and Giuseppe Melacini pp 9358–9359 DOI: 10.1021/ja051714i Supporting Info

Organocatalytic Asymmetric Direct Alkylation of α-Diazoester via C−H Bond Cleavage Daisuke Uraguchi, Keiichi Sorimachi, and Masahiro Terada pp 9360–9361 DOI: 10.1021/ja051922a Supporting Info

Synthesis of Nitric Oxide-Releasing Gold Nanoparticles Aaron R. Rothrock, Robert L. Donkers, and Mark H. Schoenfisch pp 9362–9363 DOI: 10.1021/ja052027u Supporting Info

Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide)titanium(IV) Complex−MAO Catalyst System Hao Zhang and Kotohiro Nomura pp 9364–9365 DOI: 10.1021/ja052198z Supporting Info

Highly Diastereoselective Hydrostannylation of Allyl and Homoallyl Alcohols with Dibutyl(trifluoromethanesulfoxy)stannane Katsukiyo Miura, Di Wang, and Akira Hosomi pp 9366–9367 DOI: 10.1021/ja052245n Supporting Info

Destroying Gadofullerene Aggregates by Salt Addition in Aqueous Solution of Gd@C60(OH)x and Gd@C60[C(COOH2)]10 Sabrina Laus, Balaji Sitharaman, Éva Tóth, Robert D. Bolskar, Lothar Helm, Subashini Asokan, Michael S. Wong, Lon J. Wilson, and André E. Merbach pp 9368–9369 DOI: 10.1021/ja052388+ Supporting Info

Thermal Isomerizations of 1-13C-2,2,3,3-d4-Cyclopropane to Isotopically Labeled Trimethylene Diradicals, 1-Propylidenes, and Propenes John E. Baldwin, Linda S. Day, and Stephanie R. Singer pp 9370–9371 DOI: 10.1021/ja052678q

Structure of Multiresponsive “Intelligent” Core−Shell Microgels Ingo Berndt, Jan Skov Pedersen, and Walter Richtering pp 9372–9373 DOI: 10.1021/ja051825h

Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters for Aerobic Alcohol Oxidation in Water Hironori Tsunoyama, Hidehiro Sakurai, Yuichi Negishi, and Tatsuya Tsukuda pp 9374–9375 DOI: 10.1021/ja052161e Supporting Info

Strong H2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg3(O2C-C10H6-CO2)3 Mircea Dinc and Jeffrey R. Long pp 9376–9377 DOI: 10.1021/ja0523082 Supporting Info

Steric Effects in Hula-Twist Photoisomerization. 1,4-Dimethyl- and 2,3-Dimethyl-1,4-diphenylbutadienes Lan-ying Yang, Robert S. H. Liu, Natalie L. Wendt, and Jin Liu pp 9378–9379 DOI: 10.1021/ja052312d Supporting Info

In situ Negative Patterning of p-Silicon via Scanning Probe Lithography in HF/EtOH Liquid Bridges Younghun Kim, Sung Koo Kang, Inhee Choi, Jeongjin Lee, and Jongheop Yi pp 9380–9381 DOI: 10.1021/ja052319v Supporting Info

In Vitro Selection of Aptamers with Affinity for Neuropeptide Y Using Capillary Electrophoresis Shaun D. Mendonsa and Michael T. Bowser pp 9382–9383 DOI: 10.1021/ja052406n Supporting Info

Unusual Reactivity of Tris(pyrazolyl)borate Zirconium Benzyl Complexes Han Lee and Richard F. Jordan pp 9384–9385 DOI: 10.1021/ja0527673 Supporting Info

Reversible Light and Air-Driven Lithography by Singlet Oxygen Werner Fudickar, Andreas Fery, and Torsten Linker pp 9386–9387 DOI: 10.1021/ja0517015 Supporting Info

Promiscuous Fatty Acyl CoA Ligases Produce Acyl-CoA and Acyl-SNAC Precursors for Polyketide Biosynthesis Pooja Arora, Archana Vats, Priti Saxena, Debasisa Mohanty, and Rajesh S. Gokhale pp 9388–9389 DOI: 10.1021/ja052991s Supporting Info

Competition between Receptors in Dynamic Combinatorial Libraries:  Amplification of the Fittest? Peter T. Corbett, Jeremy K. M. Sanders, and Sijbren Otto pp 9390–9392 DOI: 10.1021/ja0509026 Supporting Info

Heats of Formation of Co(CO)2NOPR3, R = CH3 and C2H5, and Its Ionic Fragments Zsolt Gengeliczki, Bálint Sztáray, Tomas Baer, Christopher Iceman, and Peter B. Armentrout pp 9393–9402 DOI: 10.1021/ja0504744 Supporting Info

Molecular AND and INHIBIT Gates Based on Control of Porphyrin Fluorescence by Photochromes Stephen D. Straight, Joakim Andréasson, Gerdenis Kodis, Subhajit Bandyopadhyay, Reginald H. Mitchell, Thomas A. Moore, Ana L. Moore, and Devens Gust pp 9403–9409 DOI: 10.1021/ja051218u

Tandem Sequence of Cross Metathesis−Ring-Closing Metathesis Reaction of Alkynyl Silyloxy-Tethered Enynes Sangho Park, Mansuk Kim, and Daesung Lee pp 9410–9415 DOI: 10.1021/ja0520159 Supporting Info

Synthesis and Characterization of Salts Containing the BrO3F2- Anion; A Rare Example of a Bromine(VII) Species John F. Lehmann and Gary J. Schrobilgen pp 9416–9427 DOI: 10.1021/ja0402607 Supporting Info

Synergistic Dimetallic Effects in Propargylic Substitution Reaction Catalyzed by Thiolate-Bridged Diruthenium Complex Salai Cheettu Ammal, Naohiko Yoshikai, Youichi Inada, Yoshiaki Nishibayashi, and Eiichi Nakamura pp 9428–9438 DOI: 10.1021/ja050298z Supporting Info

Telomestatin and Diseleno Sapphyrin Bind Selectively to Two Different Forms of the Human Telomeric G-Quadruplex Structure Evonne M. Rezler, Jeyaprakashnarayanan Seenisamy, Sridevi Bashyam, Mu-Yong Kim, Elizabeth White, W. David Wilson, and Laurence H. Hurley pp 9439–9447 DOI: 10.1021/ja0505088 Supporting Info

Direct Tyrosine Oxidation Using the MLCT Excited States of Rhenium Polypyridyl Complexes Steven Y. Reece and Daniel G. Nocera pp 9448–9458 DOI: 10.1021/ja0510360 Supporting Info

Cell-Penetrating cis-γ-Amino-l-Proline-Derived Peptides Josep Farrera-Sinfreu, Ernest Giralt, Susanna Castel, Fernando Albericio, and Miriam Royo pp 9459–9468 DOI: 10.1021/ja051648k Supporting Info

Docking, Triggering, and Biological Activity of Dynemicin A in DNA:  A Computational Study Tell Tuttle, Elfi Kraka, and Dieter Cremer pp 9469–9484 DOI: 10.1021/ja046251f Supporting Info

ENDOR Investigation of the Liganding Environment of Mixed-Spin Ferric Cytochrome c‘ Oleg M. Usov, Peter S−T. Choi, James P. Shapleigh, and Charles P. Scholes pp 9485–9494 DOI: 10.1021/ja043994s Supporting Info

Reexamination of Lead(II) Coordination Preferences in Sulfur-Rich Sites:  Implications for a Critical Mechanism of Lead Poisoning John S. Magyar, Tsu-Chien Weng, Charlotte M. Stern, David F. Dye, Brian W. Rous, John C. Payne, Brian M. Bridgewater, Ana Mijovilovich, Gerard Parkin, Jeffrey M. Zaleski, James E. Penner-Hahn, and Hilary Arnold Godwin pp 9495–9505 DOI: 10.1021/ja0424530 Supporting Info

Copper Oxide Nanocrystals Ming Yin, Chun-Kwei Wu, Yongbing Lou, Clemens Burda, Jeffrey T. Koberstein, Yimei Zhu, and Stephen O'Brien pp 9506–9511 DOI: 10.1021/ja050006u Supporting Info

Diameter-Selective Solubilization of Single-Walled Carbon Nanotubes by Reversible Cyclic Peptides Alfonso Ortiz-Acevedo, Hui Xie, Vasiliki Zorbas, William M. Sampson, Alan B. Dalton, Ray H. Baughman, Rockford K. Draper, Inga H. Musselman, and Gregg R. Dieckmann pp 9512–9517 DOI: 10.1021/ja050507f

Carbohydrate-Based DNA Ligands:  Sugar−Oligoamides as a Tool to Study Carbohydrate−Nucleic Acid Interactions Jason N. Martin, Eva M. Muñoz, Caroline Schwergold, Florence Souard, Juan Luis Asensio, Jesús Jiménez-Barbero, Javier Cañada, and Cristina Vicent pp 9518–9533 DOI: 10.1021/ja050794n Supporting Info

5-Endo-Dig Radical Cyclizations:  “The Poor Cousins” of the Radical Cyclizations Family Igor V. Alabugin and Mariappan Manoharan pp 9534–9545 DOI: 10.1021/ja050976h Supporting Info

Artificial Oligopeptide Scaffolds for Stoichiometric Metal Binding Brian P. Gilmartin, Kristi Ohr, Rebekah L. McLaughlin, Richard Koerner, and Mary Elizabeth Williams pp 9546–9555 DOI: 10.1021/ja0510818 Supporting Info

Hole-Induced Quenching of Triplet and Singlet Excitons in Conjugated Polymers Andre J. Gesquiere, So-Jung Park, and Paul F. Barbara pp 9556–9560 DOI: 10.1021/ja051271i

Three Challenges toward the Assignment of Absolute Configuration of Gymnocin-B Katsunori Tanaka, Yasuhiro Itagaki, Masayuki Satake, Hideo Naoki, Takeshi Yasumoto, Koji Nakanishi, and Nina Berova pp 9561–9570 DOI: 10.1021/ja0512677 Supporting Info

Chemoenzymatic Approach to Enantiopure Streptogramin B Variants:  Characterization of Stereoselective Pristinamycin I Cyclase from Streptomyces pristinaespiralis Christoph Mahlert, Stephan A. Sieber, Jan Grünewald, and Mohamed A. Marahiel pp 9571–9580 DOI: 10.1021/ja051254t

Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes:  Bonding by Interstitial Lithium Ions Ivan Aprahamian, David Eisenberg, Roy E. Hoffman, Tamar Sternfeld, Yutaka Matsuo, Edward A. Jackson, Eiichi Nakamura, Lawrence T. Scott, Tuvia Sheradsky, and Mordecai Rabinovitz pp 9581–9587 DOI: 10.1021/ja0515102 Supporting Info

Bioresponsive Hydrogel Microlenses Jongseong Kim, Satish Nayak, and L. Andrew Lyon pp 9588–9592 DOI: 10.1021/ja0519076 Supporting Info

Artificial Metalloprotease with Active Site Comprising Aldehyde Group and Cu(II)Cyclen Complex Sang Ho Yoo, Byoung June Lee, Hyunsook Kim, and Junghun Suh pp 9593–9602 DOI: 10.1021/ja052191h Supporting Info

Chiral Rodlike Platinum Complexes, Double Helical Chains, and Potential Asymmetric Hydrogenation Ligand Based on “Linear” Building Blocks:  1,8,9,16-Tetrahydroxytetraphenylene and 1,8,9,16-Tetrakis(diphenylphosphino)tetraphenylene Hai-Yan Peng, Chi-Keung Lam, Thomas C. W. Mak, Zongwei Cai, Wai-Tang Ma, Yu-Xue Li, and Henry N. C. Wong pp 9603–9611 DOI: 10.1021/ja051013l Supporting Info

Spectroscopic Characterization of Site-Specific [Fe4S4] Cluster Chemistry in Ferredoxin:Thioredoxin Reductase:  Implications for the Catalytic Mechanism Elizabeth M. Walters, Ricardo Garcia-Serres, Guy N. L. Jameson, Dominique A. Glauser, Florence Bourquin, Wanda Manieri, Peter Schürmann, Michael K. Johnson, and Boi Hanh Huynh pp 9612–9624 DOI: 10.1021/ja051909q

Cp*RuCl-Catalyzed Formal Intermolecular Cyclotrimerization of Three Unsymmetrical Alkynes through a Boron Temporary Tether:  Regioselective Four-Component Coupling Synthesis of Phthalides Yoshihiko Yamamoto, Jun-ichi Ishii, Hisao Nishiyama, and Kenji Itoh pp 9625–9631 DOI: 10.1021/ja051377d Supporting Info

Representing Receptor Flexibility in Ligand Docking through Relevant Normal Modes Claudio N. Cavasotto, Julio A. Kovacs, and Ruben A. Abagyan pp 9632–9640 DOI: 10.1021/ja042260c Supporting Info

Stereochemistry of β-Deuterium Isotope Effects on Amine Basicity Charles L. Perrin, Brian K. Ohta, Joshua Kuperman, Jordan Liberman, and Máté Erdélyi pp 9641–9647 DOI: 10.1021/ja0511927 Supporting Info

Blue Copper Model Complexes with Distorted Tetragonal Geometry Acting as Effective Electron-Transfer Mediators in Dye-Sensitized Solar Cells Shigeki Hattori, Yuji Wada, Shozo Yanagida, and Shunichi Fukuzumi pp 9648–9654 DOI: 10.1021/ja0506814 Supporting Info

Amines:  Synthesis, Properties and Applications By Stephen A. Lawrence (Mimas Ltd.). Cambridge University Press:  Cambridge, U.K. x + 372 pp. $180.00. ISBN 0-521-78284-8. Dennis G. Hall p 9655 DOI: 10.1021/ja041026j

Optical Spectra and Chemical Bonding in Transition Metal Complexes. Special Volume II Dedicated to Professor Jørgensen. Structure and Bonding, 107 Edited by Thomas Schönherr (Heinrich-Heine-Universität, Dusseldorf, Germany). Series Edited by D. M. Mingos. Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xvi + 310 pp. $239.00. ISBN 3-540-00854-3. Marc W. Perkovic pp 9655–9656 DOI: 10.1021/ja041041o

Handbook of Food Analytical Chemistry. Volumes 1 and 2 Edited by Ronald E. Wrolstad (Oregon State University), Terry E. Acree (Cornell University), Eric A. Decker (affiliation not given), Michael H. Penner (Oregon State University), David S. Reid (University of California, Davis), Steven J. Schwartz (Ohio State University), Charles F. Shoemaker (affiliation not given), Denise Smith (University of Idaho), and Peter Sporns (University of Alberta). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xvi + xvi + 1374 pp. $260.00 (set). ISBN 0-471-72187-5 (set). p 9656 DOI: 10.1021/ja059701s

Chemical Reagents for Protein Modification, 3rd ed By Roger L. Lundblad (Consultant in biotechnology, Chapel Hill, NC). CRC Press:  Boca Raton, FL. 2005. xii + 340 pp. $129.95. ISBN 0-8493-1983-8. Lawrence M. Sayre pp 9656–9657 DOI: 10.1021/ja0410439

Progress in Colloid and Polymer Science, Volume 127. Analytical Ultracentrifugation VII Edited by M. D. Lechner (Universität Osnabrück, Germany) and L. Börger (BASF Aktiengesellschaft, Ludwigshafen, Germany). Series edited by F. Kremer and W. Richtering. Springer:  Berlin, Heidelberg, New York. 2004. viii + 162 pp. $149.00. ISBN 3-540-20203-X. p 9657 DOI: 10.1021/ja0597045

Validation in Chemical Measurement Edited by Paul De Bièvre (Kasterlee, Belgium) and Helmut Günzler (Weinheim, Germany). Springer:  Berlin, Heidelberg, New York. 2005. x + 168 pp. $159.00. ISBN 3-540-20788-0. p 9657 DOI: 10.1021/ja059715y

Mixed Surfactant Systems, 2nd ed., Revised and Expanded. Volume 124 of the Surfactant Science Series Edited by Masahiko Abe (Tokyo University of Science) and John F. Scamehorn (University of Oklahoma). Marcel Dekker:  New York. 2005. xiv + 832 pp. $179.95. ISBN 0-8247-2150-0. Ray von Wandruszka pp 9657–9658 DOI: 10.1021/ja059708+

Traceability in Chemical Measurement Edited by Paul De Bièvre (Kasterlee, Belgium) and Helmut Günzler (Weinheim, Germany). Springer:  Berlin, Heidelberg, New York. 2005. xii + 298 pp. $229.00. ISBN 3-540-43989-7. p 9658 DOI: 10.1021/ja0597146

Issue 27

Bis(imino)pyridine Iron(II) Alkyl Cations for Olefin Polymerization Marco W. Bouwkamp, Emil Lobkovsky, and Paul J. Chirik pp 9660–9661 DOI: 10.1021/ja0524447 Supporting Info

Phosphorylation of an α-Synuclein Peptide Fragment Enhances Metal Binding Lucy L. Liu and Katherine J. Franz pp 9662–9663 DOI: 10.1021/ja043247v Supporting Info

Expanding the Conformational Pool of cis-β-Sugar Amino Acid:  Accommodation of β-hGly Motif in Robust 14-Helix Srivari Chandrasekhar, Marepally Srinivasa Reddy, Bathini Nagendra Babu, Bharatam Jagadeesh, Anabathula Prabhakar, and Bulusu Jagannadh pp 9664–9665 DOI: 10.1021/ja051014d Supporting Info

Sensitive, Label-Free DNA Diagnostics Based on Near-Field Microwave Imaging Barry Friedman, Mariafrancis A. Gaspar, Sergey Kalachikov, Kiejin Lee, Rastislav Levicky, Gang Shen, and Hyunjun Yoo pp 9666–9667 DOI: 10.1021/ja051760i Supporting Info

Helical Nanofibers from Aqueous Self-Assembly of an Oligo(p-phenylene)-Based Molecular Dumbbell Jinyoung Bae, Jin-Ho Choi, Yong-Sik Yoo, Nam-Keun Oh, Byung-Sun Kim, and Myongsoo Lee pp 9668–9669 DOI: 10.1021/ja051961m Supporting Info

Mechanism of DNA Threading Intercalation of Binuclear Ru Complexes:  Uni- or Bimolecular Pathways Depending on Ligand Structure and Binding Density Pär Nordell and Per Lincoln pp 9670–9671 DOI: 10.1021/ja0521674 Supporting Info

Using Microfluidics to Observe the Effect of Mixing on Nucleation of Protein Crystals Delai L. Chen, Cory J. Gerdts, and Rustem F. Ismagilov pp 9672–9673 DOI: 10.1021/ja052279v Supporting Info

An Acidic Layered Clay Is Combined with A Basic Layered Clay for One-Pot Sequential Reactions Ken Motokura, Noriaki Fujita, Kohsuke Mori, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 9674–9675 DOI: 10.1021/ja052386p Supporting Info

The Contact Interface of a 120 kD CheA−CheW Complex by Methyl TROSY Interaction Spectroscopy Damon J. Hamel and Frederick W. Dahlquist pp 9676–9677 DOI: 10.1021/ja052517m Supporting Info

Reversible Holographic Grating Formation in Polymer Solutions Benoit Loppinet, Elvira Somma, Nikos Vainos, and George Fytas pp 9678–9679 DOI: 10.1021/ja0529790

A Heteronuclear Bidentate Lewis Acid as a Phosphorescent Fluoride Sensor Mohand Melaimi and François P. Gabbaï pp 9680–9681 DOI: 10.1021/ja053058s Supporting Info

Catalytic, Enantioselective, Conjugate Alkyne Addition Thomas F. Knöpfel, Pablo Zarotti, Takashi Ichikawa, and Erick M. Carreira pp 9682–9683 DOI: 10.1021/ja052411r Supporting Info

Missing Metallofullerene La@C74 Hidefumi Nikawa, Takashi Kikuchi, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, G. M. Aminur Rahman, Takeshi Akasaka, Yutaka Maeda, Kenji Yoza, Ernst Horn, Kazunori Yamamoto, Naomi Mizorogi, and Shigeru Nagase pp 9684–9685 DOI: 10.1021/ja0524806 Supporting Info

As a Whole:  Crystalline Zinc Aluminate Nanotube Array−Nanonet Yu Wang and Kai Wu pp 9686–9687 DOI: 10.1021/ja0505402 Supporting Info

High Elongation of Polyelectrolyte Chains in the Osmotic Limit of Spherical Polyelectrolyte Brushes:  A Study by Cryogenic Transmission Electron Microscopy Alexander Wittemann, Markus Drechsler, Yeshayahu Talmon, and Matthias Ballauff pp 9688–9689 DOI: 10.1021/ja0513234

On the Origin of the Thermostabilization of Proteins Induced by Sodium Phosphate Rosa Fayos, Miquel Pons, and Oscar Millet pp 9690–9691 DOI: 10.1021/ja051352e Supporting Info

Highly Efficient Endoglycosidase-Catalyzed Synthesis of Glycopeptides Using Oligosaccharide Oxazolines as Donor Substrates Bing Li, Ying Zeng, Steven Hauser, Haijing Song, and Lai-Xi Wang pp 9692–9693 DOI: 10.1021/ja051715a Supporting Info

Rhodium Nanoparticles Stabilized by Ionic Copolymers in Ionic Liquids:  Long Lifetime Nanocluster Catalysts for Benzene Hydrogenation Xin-dong Mu, Jian-qiang Meng, Zi-Chen Li, and Yuan Kou pp 9694–9695 DOI: 10.1021/ja051803v Supporting Info

Bis(triarylmethylium)-Mediated Diaryl Ether Synthesis:  Oxidative Arylation of Phenols with N,N-Dialkyl-4-phenylthioanilines Terunobu Saitoh and Junji Ichikawa pp 9696–9697 DOI: 10.1021/ja051839n Supporting Info

Nanoparticulate Metal Complexes Prepared with Compressed Carbon Dioxide:  Correlation of Particle Morphology with Precursor Structure Chad A. Johnson, Sarika Sharma, Bala Subramaniam, and A. S. Borovik pp 9698–9699 DOI: 10.1021/ja052040e Supporting Info

Single Peptide Bonds Exhibit Poly(Pro)II (“Random Coil”) Circular Dichroism Spectra Isa Gokce, Robert W. Woody, Gregor Anderluh, and Jeremy H. Lakey pp 9700–9701 DOI: 10.1021/ja052632x Supporting Info

Conformationally Gated Electron Transfer in Iso-1-cytochrome c:  Engineering the Rate of a Conformational Switch Saritha Baddam and Bruce E. Bowler pp 9702–9703 DOI: 10.1021/ja0527368 Supporting Info

Möbius Aromaticity in [12]Annulene:  Cis−Trans Isomerization via Twist-Coupled Bond Shifting Claire Castro, William L. Karney, Miguel A. Valencia, Catherine M. H. Vu, and Ryan P. Pemberton pp 9704–9705 DOI: 10.1021/ja052447j Supporting Info

Palladium-Catalyzed Intramolecular Selenocarbamoylation of Alkynes with Carbamoselenoates:  Formation of α-Alkylidene-β-lactam Framework Masashi Toyofuku, Shin-ich Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu, and Nobuaki Kambe pp 9706–9707 DOI: 10.1021/ja052175k Supporting Info

Gold(I)-Catalyzed Ring Expansion of Cyclopropanols and Cyclobutanols Jordan P. Markham, Steven T. Staben, and F. Dean Toste pp 9708–9709 DOI: 10.1021/ja052831g Supporting Info

Design, Synthesis, Linear, and Nonlinear Optical Properties of Conjugated (Porphinato)zinc(II)-Based Donor−Acceptor Chromophores Featuring Nitrothiophenyl and Nitrooligothiophenyl Electron-Accepting Moieties Tian-Gao Zhang, Yuxia Zhao, Inge Asselberghs, André Persoons, Koen Clays, and Michael J. Therien pp 9710–9720 DOI: 10.1021/ja0402553 Supporting Info

Structural Analysis of Hybrid Titania-Based Mesostructured Composites Shannon W. Boettcher, Michael H. Bartl, Jerry G. Hu, and Galen D. Stucky pp 9721–9730 DOI: 10.1021/ja050753r Supporting Info

Direct Control of the Magnetic Interaction between Iron Oxide Nanoparticles through Dendrimer-Mediated Self-Assembly Benjamin L. Frankamp, Andrew K. Boal, Mark T. Tuominen, and Vincent M. Rotello pp 9731–9735 DOI: 10.1021/ja051351m Supporting Info

Comparative Study of Acetic Acid, Methanol, and Water Adsorbed on Anatase TiO2 Probed by Sum Frequency Generation Spectroscopy Chuan-yi Wang, Henning Groenzin, and Mary Jane Shultz pp 9736–9744 DOI: 10.1021/ja051996m Supporting Info

Linear Artificial Molecular Muscles Yi Liu, Amar H. Flood, Paul A. Bonvallet, Scott A. Vignon, Brian H. Northrop, Hsian-Rong Tseng, Jan O. Jeppesen, Tony J. Huang, Branden Brough, Marko Baller, Sergei Magonov, Santiago D. Solares, William A. Goddard, Chih-Ming Ho, and J. Fraser Stoddart pp 9745–9759 DOI: 10.1021/ja051088p Supporting Info

Probing Intramolecular Förster Resonance Energy Transfer in a Naphthaleneimide−Peryleneimide−Terrylenediimide-Based Dendrimer by Ensemble and Single-Molecule Fluorescence Spectroscopy Mircea Cotlet, Tom Vosch, Satoshi Habuchi, Tanja Weil, Klaus Müllen, Johan Hofkens, and Frans De Schryver pp 9760–9768 DOI: 10.1021/ja042656o

Synthesis and Magnetic Properties Comparison of M−Cu(II) and M−VO(II) Schiff Base−Porphyrazine Complexes:  What Is the Mechanism for Spin-Coupling? Min Zhao, Chang Zhong, Charlotte Stern, Anthony G. M. Barrett, and Brian M. Hoffman pp 9769–9775 DOI: 10.1021/ja0438112 Supporting Info

Self-Assembled Monolayers and Preorganization of Organosilanes Prior to Surface Grafting onto Silica:  A Quantum Mechanical Study A. Dkhissi, A. Estève, L. Jeloaica, D. Estève, and M. Djafari Rouhani pp 9776–9780 DOI: 10.1021/ja040246u

Geminal 2JCCH Spin−Spin Coupling Constants as Probes of the Glycosidic Torsion Angle in Oligosaccharides Thomas E. Klepach, Ian Carmichael, and Anthony S. Serianni pp 9781–9793 DOI: 10.1021/ja040251y Supporting Info

Azide-Inhibited Bacterial Heme Oxygenases Exhibit an S = 3/2 (dxz,dyz)3(dxy)1(dz2)1 Spin State:  Mechanistic Implications for Heme Oxidation Yuhong Zeng, Gregori A. Caignan, Richard A. Bunce, Juan Carlos Rodríguez, Angela Wilks, and Mario Rivera pp 9794–9807 DOI: 10.1021/ja0425987 Supporting Info

First-Principles Study of Superabundant Vacancy Formation in Metal Hydrides Changjun Zhang and Ali Alavi pp 9808–9817 DOI: 10.1021/ja050475w

Conformational Constraint as a Means for Understanding RNA-Aminoglycoside Specificity Kenneth F. Blount, Fang Zhao, Thomas Hermann, and Yitzhak Tor pp 9818–9829 DOI: 10.1021/ja050918w Supporting Info

Functional Single-Wall Carbon Nanotube NanohybridsAssociating SWNTs with Water-Soluble Enzyme Model Systems Dirk M. Guldi, G. M. Aminur Rahman, Norbert Jux, Domenico Balbinot, Uwe Hartnagel, Nikos Tagmatarchis, and Maurizio Prato pp 9830–9838 DOI: 10.1021/ja050930o Supporting Info

Theoretical Study of Binding of Metal-Doped Graphene Sheet and Carbon Nanotubes with Dioxin Hong Seok Kang pp 9839–9843 DOI: 10.1021/ja0509681

Stepwise Delivery of Two Methoxy Groups of Arylaldehyde Acetals across the Phenyl Ring. Vacant Site-Controlled Palladium Catalysis Itaru Nakamura, Yuya Mizushima, Ilya D. Gridnev, and Yoshinori Yamamoto pp 9844–9847 DOI: 10.1021/ja051114j Supporting Info

Reversible and Persistent Electrical Bistability in Single Crystals of a Self-Assembled π-Conjugated Tetraaryl System:  A Submicrometer Scale Electrical Characterization Shay Tal, Batya Blumer-Ganon, Moshe Kapon, and Yoav Eichen pp 9848–9854 DOI: 10.1021/ja051154n Supporting Info

Synthesis and Fundamental Studies of (H3Ge)xSiH4-x Molecules:  Precursors to Semiconductor Hetero- and Nanostructures on Si Cole J. Ritter, Changwu Hu, Andrew V. G. Chizmeshya, John Tolle, Douglas Klewer, Ignatius S. T. Tsong, and John Kouvetakis pp 9855–9864 DOI: 10.1021/ja051411o

Kinetics of Proton Release after Flash Photolysis of 1-(2-Nitrophenyl)ethyl Sulfate (Caged Sulfate) in Aqueous Solution Stefania Abbruzzetti, Silvia Sottini, Cristiano Viappiani, and John E. T. Corrie pp 9865–9874 DOI: 10.1021/ja051702x Supporting Info

Substituted Carborane-Appended Water-Soluble Single-Wall Carbon Nanotubes:  New Approach to Boron Neutron Capture Therapy Drug Delivery Zhu Yinghuai, Ang Thiam Peng, Keith Carpenter, John A. Maguire, Narayan S. Hosmane, and Masao Takagaki pp 9875–9880 DOI: 10.1021/ja0517116 Supporting Info

New Polymorphs of ROY and New Record for Coexisting Polymorphs of Solved Structures Shuang Chen, Ilia A. Guzei, and Lian Yu pp 9881–9885 DOI: 10.1021/ja052098t Supporting Info

Computational Studies of the Thermal Fragmentation of P-Arylphosphiranes:  Have Arylphosphinidenes Been Generated by This Method? Wai Han Lam, Peter P. Gaspar, David A. Hrovat, Dwight A. Trieber II, Ernest R. Davidson, and Weston Thatcher Borden pp 9886–9894 DOI: 10.1021/ja050891g Supporting Info

Adsorption of Water on Reconstructed Rutile TiO2(011)-(2×1):  TiO Double Bonds and Surface Reactivity Cristiana Di Valentin, Antonio Tilocca, Annabella Selloni, T. J. Beck, Andreas Klust, Matthias Batzill, Yaroslav Losovyj, and Ulrike Diebold pp 9895–9903 DOI: 10.1021/ja0511624 Supporting Info

C−H Activation by a Mononuclear Manganese(III) Hydroxide Complex:  Synthesis and Characterization of a Manganese-Lipoxygenase Mimic? Christian R. Goldsmith, Adam P. Cole, and T. Daniel P. Stack pp 9904–9912 DOI: 10.1021/ja039283w Supporting Info

Polyethylene Chain Growth on Zinc Catalyzed by Olefin Polymerization Catalysts:  A Comparative Investigation of Highly Active Catalyst Systems across the Transition Series Martin van Meurs, George J. P. Britovsek, Vernon C. Gibson, and Steven A. Cohen pp 9913–9923 DOI: 10.1021/ja050100a Supporting Info

Stereochemical Memory Effects in Alkene Radical Cation/Anion Contact Ion Pairs:  Effect of Substituents, and Models for Diastereoselectivity David Crich and Krishnakumar Ranganathan pp 9924–9929 DOI: 10.1021/ja051657t Supporting Info

Theoretical Considerations and Computational Analysis of the Complexity in Polyketide Synthesis Pathways Joanna González-Lergier, Linda J. Broadbelt, and Vassily Hatzimanikatis pp 9930–9938 DOI: 10.1021/ja051586y Supporting Info

Utilization of an Oxonia-Cope Rearrangement as a Mechanistic Probe for Prins Cyclizations Ramesh Jasti, Christopher D. Anderson, and Scott D. Rychnovsky pp 9939–9945 DOI: 10.1021/ja0518326 Supporting Info

Dimethylzinc-Mediated Additions of Alkenylzirconocenes to Aldimines. New Methodologies for Allylic Amine and C-Cyclopropylalkylamine Syntheses [J. Am. Chem. Soc. 2003, 125, 761−768]. Peter Wipf, Christopher Kendall, and Corey R. J. Stephenson p 9946 DOI: 10.1021/ja053169r

Issue 28

Design and Evolution of Copper Apatite Catalysts for N-Arylation of Heterocycles with Chloro- and Fluoroarenes Boyapati M. Choudary, Chidara Sridhar, Mannepalli L. Kantam, Gopaldasu T. Venkanna, and Bojja Sreedhar pp 9948–9949 DOI: 10.1021/ja0436594 Supporting Info

Synthesis, Isolation via Self-Assembly, and Single-Molecule Observation of a [60]Fullerene-End-Capped Isotactic Poly(methyl methacrylate) Takehiro Kawauchi, Jiro Kumaki, and Eiji Yashima pp 9950–9951 DOI: 10.1021/ja052166b Supporting Info

Synthetic Micelle Sensitive to IR Light via a Two-Photon Process Andrew P. Goodwin, Justin L. Mynar, Yingzhong Ma, Graham R. Fleming, and Jean M. J. Fréchet pp 9952–9953 DOI: 10.1021/ja0523035 Supporting Info

Block Copolymers under Periodic, Strong Three-Dimensional Confinement André C. Arsenault, David A. Rider, Nicolas Tétreault, Jennifer I.-L. Chen, Neil Coombs, Geoffrey A. Ozin, and Ian Manners pp 9954–9955 DOI: 10.1021/ja052483i

Chemical Reactivity of Sc3N@C80 and La2@C80 Yuko Iiduka, Ozora Ikenaga, Akihiro Sakuraba, Takatsugu Wakahara, Takahiro Tsuchiya, Yutaka Maeda, Tsukasa Nakahodo, Takeshi Akasaka, Masahiro Kako, Naomi Mizorogi, and Shigeru Nagase pp 9956–9957 DOI: 10.1021/ja052534b Supporting Info

Ni(II)−Bis[(R,R)-N,N‘-dibenzylcyclohexane-1,2-diamine]Br2 Catalyzed Enantioselective Michael Additions of 1,3-Dicarbonyl Compounds to Conjugated Nitroalkenes David A. Evans and Daniel Seidel pp 9958–9959 DOI: 10.1021/ja052935r Supporting Info

An Ab Initio Quantum Mechanics Calculation that Correlates with Ligand Orientation and DNA Cleavage Site Selectivity in Camptothecin−DNA−Topoisomerase I Ternary Cleavage Complexes Xiangshu Xiao and Mark Cushman pp 9960–9961 DOI: 10.1021/ja042485n Supporting Info

Synthesis of Gold Nanoparticles from Gold(I)−Alkanethiolate Complexes with Supramolecular Structures through Electron Beam Irradiation in TEM Jong-Uk Kim, Sang-Ho Cha, Kyusoon Shin, Jae Young Jho, and Jong-Chan Lee pp 9962–9963 DOI: 10.1021/ja042423x Supporting Info

Chiral Oligomers by Iterative Tandem Catalysis Bart A. C. van As, Jeroen van Buijtenen, Andreas Heise, Quirinus B. Broxterman, Gerard K. M. Verzijl, Anja R. A. Palmans, and E. W. Meijer pp 9964–9965 DOI: 10.1021/ja052347d Supporting Info

An Iterative Catalytic Route to Enantiopure Deoxypropionate Subunits:  Asymmetric Conjugate Addition of Grignard Reagents to α,β-Unsaturated Thioesters Renaud Des Mazery, Maddalena Pullez, Fernando López, Syuzanna R. Harutyunyan, Adriaan J. Minnaard, and Ben L. Feringa pp 9966–9967 DOI: 10.1021/ja053020f Supporting Info

Bergman Cyclization of Sterically Hindered Substrates and Observation of Phenyl-Shifted Products Kevin D. Lewis and Adam J. Matzger pp 9968–9969 DOI: 10.1021/ja042703c Supporting Info

Probing the Oxygen Activation Reaction in Intact Whole Mitochondria through Analysis of Molecular Vibrations Toshinari Takahashi, Shigeki Kuroiwa, Takashi Ogura, and Shinya Yoshikawa pp 9970–9971 DOI: 10.1021/ja051761a Supporting Info

Unprecedented Syndioselectivity and Syndiotactic Polyolefin Melting Temperature:  Polypropylene and Poly(4-methyl-1-pentene) from a Highly Active, Sterically Expanded η1-Fluorenyl−η1-Amido Zirconium Complex Levi J. Irwin and Stephen A. Miller pp 9972–9973 DOI: 10.1021/ja052256g Supporting Info

A Simple and General Chiral Silicon Lewis Acid for Asymmetric Synthesis:  Highly Enantioselective [3 + 2] Acylhydrazone−Enol Ether Cycloadditions Seiji Shirakawa, Pamela J. Lombardi, and James L. Leighton pp 9974–9975 DOI: 10.1021/ja052307+ Supporting Info

Highly Efficient Access to Strained Bicyclic Ketals via Gold-Catalyzed Cycloisomerization of Bis-homopropargylic Diols Sylvain Antoniotti, Emilie Genin, Véronique Michelet, and Jean-Pierre Genêt pp 9976–9977 DOI: 10.1021/ja0530671 Supporting Info

Cyclotrisilenylium Ion:  The Persilaaromatic Compound Masaaki Ichinohe, Masayasu Igarashi, Kaori Sanuki, and Akira Sekiguchi pp 9978–9979 DOI: 10.1021/ja053202+ Supporting Info

Dynamics and Thermodynamics of Dimerization of Parallel G-Quadruplexed DNA Formed from d(TTAGn) (n = 3−5) Yoshitake Kato, Takako Ohyama, Hajime Mita, and Yasuhiko Yamamoto pp 9980–9981 DOI: 10.1021/ja050191b Supporting Info

Lectin Arrays for Profiling Cell Surface Carbohydrate Expression Ting Zheng, Dora Peelen, and Lloyd M. Smith pp 9982–9983 DOI: 10.1021/ja0505550 Supporting Info

Multiwalled Carbon Nanotubes with Chemically Grafted Polyetherimides Jason J. Ge, Dong Zhang, Qing Li, Haoqing Hou, Matthew J. Graham, Liming Dai, Frank W. Harris, and Stephen Z. D. Cheng pp 9984–9985 DOI: 10.1021/ja050924s Supporting Info

Direct White Light Phosphor:  A Porous Zinc Gallophosphate with Tunable Yellow-to-White Luminescence Yueh-Chun Liao, Chia-Her Lin, and Sue-Lein Wang pp 9986–9987 DOI: 10.1021/ja0512879 Supporting Info

Selective Ortho Hydroxylation of Nitrobenzene with Molecular Oxygen Catalyzed by the H5PV2Mo10O40 Polyoxometalate Alexander M. Khenkin, Lev Weiner, and Ronny Neumann pp 9988–9989 DOI: 10.1021/ja051286g Supporting Info

Porous MoS2 Synthesized by Ultrasonic Spray Pyrolysis Sara E. Skrabalak and Kenneth S. Suslick pp 9990–9991 DOI: 10.1021/ja051654g Supporting Info

Surface Modulation of Magnetic Nanocrystals in the Development of Highly Efficient Magnetic Resonance Probes for Intracellular Labeling Ho-Taek Song, Jin-sil Choi, Yong-Min Huh, Sungjun Kim, Young-wook Jun, Jin-Suck Suh, and Jinwoo Cheon pp 9992–9993 DOI: 10.1021/ja051833y Supporting Info

Probing the Structure of Gas-Phase Metallic Clusters via Ligation Energetics:  Sequential Addition of C2H4 to Agm+ (m = 3−7) Manuel J. Manard, Paul R. Kemper, and Michael T. Bowers pp 9994–9995 DOI: 10.1021/ja052251j Supporting Info

Spectroscopic Identification of the Mixed Hydrogen and Carbon Dioxide Clathrate Hydrate Do-Youn Kim and Huen Lee pp 9996–9997 DOI: 10.1021/ja0523183 Supporting Info

The Absence of Favorable Aromatic Interactions between β-Sheet Peptides De Michael Chung, Yimeng Dou, Pierre Baldi, and James S. Nowick pp 9998–9999 DOI: 10.1021/ja052351p

Selective Detection of Catecholamines by Synthetic Receptors Embedded in Chromatic Polydiacetylene Vesicles Sofiya Kolusheva, Oliver Molt, Michael Herm, Thomas Schrader, and Raz Jelinek pp 10000–10001 DOI: 10.1021/ja052436q Supporting Info

Orientation Control of Fluorescence Resonance Energy Transfer Using DNA as a Helical Scaffold Frederick D. Lewis, Ligang Zhang, and Xiaobing Zuo pp 10002–10003 DOI: 10.1021/ja0524402 Supporting Info

Slow-onset Feedback Inhibition:  Inhibition of Mycobacterium tuberculosis α-Isopropylmalate Synthase by l-Leucine Luiz P. S. de Carvalho, Argyrides Argyrou, and John S. Blanchard pp 10004–10005 DOI: 10.1021/ja052513h Supporting Info

Preferential Oxidative Addition in Palladium(0)-Catalyzed Suzuki Cross-Coupling Reactions of Dihaloarenes with Arylboronic Acids Cheng-Guo Dong and Qiao-Sheng Hu pp 10006–10007 DOI: 10.1021/ja052547p Supporting Info

Submaximal Interpenetration and Bicontinuous Three-Dimensional Channels in Porous Molecular Networks Okba Saied, Thierry Maris, Xin Wang, Michel Simard, and James D. Wuest pp 10008–10009 DOI: 10.1021/ja052587t Supporting Info

Ru2(ap)4(σ-oligo(phenyleneethynyl)) Molecular Wires:  Synthesis and Electronic Characterization Amy Szuchmacher Blum, Tong Ren, Damon A. Parish, Scott A. Trammell, M. H. Moore, James G. Kushmerick, Guo-Lin Xu, Jeffrey R. Deschamps, Steven K. Pollack, and Ranganathan Shashidhar pp 10010–10011 DOI: 10.1021/ja052604e Supporting Info

Metal−Organic Thin-Film Transistor (MOTFT) Based on a Bis(o-diiminobenzosemiquinonate) Nickel(II) Complex Shin-ichiro Noro, Ho-Chol Chang, Taishi Takenobu, Yuji Murayama, Takayoshi Kanbara, Tetsuya Aoyama, Takafumi Sassa, Tatsuo Wada, Daisuke Tanaka, Susumu Kitagawa, Yoshihiro Iwasa, Tomoyuki Akutagawa, and Takayoshi Nakamura pp 10012–10013 DOI: 10.1021/ja052663s Supporting Info

A Molecular Beacon Approach to Measuring the DNA Permeability of Thin Films Angus P. R. Johnston and Frank Caruso pp 10014–10015 DOI: 10.1021/ja0527166 Supporting Info

Toward Cocaine Esterase Therapeutics Claude J. Rogers, Jenny M. Mee, Gunnar F. Kaufmann, Tobin J. Dickerson, and Kim D. Janda pp 10016–10017 DOI: 10.1021/ja053086a Supporting Info

A Tandem Orthogonal Proteolysis Strategy for High-Content Chemical Proteomics Anna E. Speers and Benjamin F. Cravatt pp 10018–10019 DOI: 10.1021/ja0532842 Supporting Info

Energy Funneling of IR Photons Captured by Dendritic Antennae and Acceptor Mode Specificity:  Anti-Stokes Resonance Raman Studies on Iron(III) Porphyrin Complexes with a Poly(aryl ether) Dendrimer Framework Yu-Jun Mo, Dong-Lin Jiang, Makoto Uyemura, Takuzo Aida, and Teizo Kitagawa pp 10020–10027 DOI: 10.1021/ja042196z Supporting Info

An Alkyne Hydrosilylation-Oxidation Strategy for the Selective Installation of Oxygen Functionality Barry M. Trost, Zachary T. Ball, and Kai M. Laemmerhold pp 10028–10038 DOI: 10.1021/ja051578h Supporting Info

Catalytic Ester−Amide Exchange Using Group (IV) Metal Alkoxide−Activator Complexes Chong Han, Jonathan P. Lee, Emil Lobkovsky, and John A. Porco, Jr. pp 10039–10044 DOI: 10.1021/ja0527976 Supporting Info

Mercaptopropyl-Modified Mesoporous Silica:  A Remarkable Support for the Preparation of a Reusable, Heterogeneous Palladium Catalyst for Coupling Reactions Cathleen M. Crudden, Mutyala Sateesh, and Roxanne Lewis pp 10045–10050 DOI: 10.1021/ja0430954 Supporting Info

Combining Single Wall Carbon Nanotubes and Photoactive Polymers for Photoconversion G. M. Aminur Rahman, Dirk M. Guldi, Rita Cagnoli, Adele Mucci, Luisa Schenetti, Lisa Vaccari, and Maurizio Prato pp 10051–10057 DOI: 10.1021/ja050396k Supporting Info

Advanced Surface Modification of Indium Tin Oxide for Improved Charge Injection in Organic Devices Eric L. Hanson, Jing Guo, Norbert Koch, Jeffrey Schwartz, and Steven L. Bernasek pp 10058–10062 DOI: 10.1021/ja050481s Supporting Info

Cadmium Sulphide Quantum Dots in Morphologically Tunable Triblock Copolymer Aggregates Nicolas Duxin, Futian Liu, Hojatollah Vali, and Adi Eisenberg pp 10063–10069 DOI: 10.1021/ja0505043 Supporting Info

Imidazole-Based Excited-State Intramolecular Proton-Transfer Materials:  Synthesis and Amplified Spontaneous Emission from a Large Single Crystal Sanghyuk Park, Oh-Hoon Kwon, Sehoon Kim, Sangwoo Park, Moon-Gun Choi, Myoungsik Cha, Soo Young Park, and Du-Jeon Jang pp 10070–10074 DOI: 10.1021/ja0508727 Supporting Info

Crystallographic and Spectroscopic Evidence for High Affinity Binding of FeEDTA(H2O)- to the Periplasmic Nickel Transporter NikA Mickaël V. Cherrier, Lydie Martin, Christine Cavazza, Lilian Jacquamet, David Lemaire, Jacques Gaillard, and Juan C. Fontecilla-Camps pp 10075–10082 DOI: 10.1021/ja0518530 Supporting Info

Conjugation Enhancement of Intramolecular Exciton Migration in Poly(p-phenylene ethynylene)s Evgueni E. Nesterov, Zhengguo Zhu, and Timothy M. Swager pp 10083–10088 DOI: 10.1021/ja051936g Supporting Info

Strongly Birefringent Pb3O2Cl2 Nanobelts Michael B. Sigman, Jr. and Brian A. Korgel pp 10089–10095 DOI: 10.1021/ja051956i Supporting Info

Direct Fabrication and Harvesting of Monodisperse, Shape-Specific Nanobiomaterials Jason P. Rolland, Benjamin W. Maynor, Larken E. Euliss, Ansley E. Exner, Ginger M. Denison, and Joseph M. DeSimone pp 10096–10100 DOI: 10.1021/ja051977c Supporting Info

Chiral Phase Transition in Two-Dimensional Supramolecular Assemblies of Prochiral Molecules Franck Vidal, Erik Delvigne, Sebastian Stepanow, Nian Lin, Johannes V. Barth, and Klaus Kern pp 10101–10106 DOI: 10.1021/ja0525049

A Highly Selective Fluorescent Chemosensor for Pb2+ Ji Young Kwon, Yun Jung Jang, Yoon Ju Lee, Kwan Mook Kim, Mi Sook Seo, Wonwoo Nam, and Juyoung Yoon pp 10107–10111 DOI: 10.1021/ja051075b Supporting Info

Bismuth Telluride Hexagonal Nanoplatelets and Their Two-Step Epitaxial Growth Weigang Lu, Yong Ding, Yuxi Chen, Zhong Lin Wang, and Jiye Fang pp 10112–10116 DOI: 10.1021/ja052286j

Biomimetic Studies on Anti-Thyroid Drugs and Thyroid Hormone Synthesis  [J. Am. Chem. Soc. 2004, 126, 2712−2713].  Gouriprasanna Roy, Munirathinam Nethaji, and G. Mugesh p 10117 DOI: 10.1021/ja053245q

Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated Dienes Promoted by Diethylzinc  [J. Am. Chem. Soc. 2004, 126, 14360−14361].  Masanari Kimura, Atsuko Miyachi, Keisuke Kojima, Shuji Tanaka, and Yoshinao Tamaru p 10117 DOI: 10.1021/ja0599115

The Chemistry of Pheromones and Other Semiochemicals I. Topics in Current Chemistry, 239 Edited by Stefan Schulz (Technische Universität Braunschweig). Springer:  Berlin, Heidelberg, New York. 2004. xii + 240 pp. $199.00. ISBN 3-540-20828-3. Jocelyn G. Millar pp 10118–10119 DOI: 10.1021/ja041036k

Polysaccharides:  Structural Diversity and Functional Versatility, 2nd ed Edited by Severian Dumitriu (University of Sherbrooke, Quebec). Marcel Dekker:  New York. 2005. xviii + 1204 pp. $269.95. ISBN 0-8247-5480-8. R. Erik Edens p 10119 DOI: 10.1021/ja0410486

Modern Aldol Reactions, Volumes 1 and 2 Edited by Rainer Mahrwald (Humboldt University, Berlin). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. 699 pp. $405.00. ISBN 3-527-30714-1. Barry B. Snider pp 10119–10120 DOI: 10.1021/ja0597101

Interfacial Nanochemistry:  Molecular Science and Engineering at Liquid-Liquid Interfaces Edited by Hitoshi Watarai (Osaka University), Norio Teramae (Tohoku University), and Tsuguo Sawada (Tokyo University). From the series:  Nanostructure Science and Technology. Edited by David J. Lockwood. Kluwer Academic/Plenum Publishers:  New York. 2005. xiv + 322 pp. $129.00. ISBN 0-306-48527-3. Thomas Fischer p 10120 DOI: 10.1021/ja059712l

Organic Reactions, Volume 65 Edited by Larry E. Overman (University of California, Irvine). John Wiley & Sons:  Hoboken, NJ. 2005. viii + 628 pp. $125.00. ISBN 0-471-68260-8. p 10120 DOI: 10.1021/ja059723e

Theilheimer's Synthetic Methods of Organic Chemistry, Volume 66, 2004 Edited by Alan F. Finch (Cambridge). S. Karger AG and the Thomson Corporation:  Basel. 2004. xxvi + 374 pp. $632.00. ISBN 3-8055-7854-7. p 10120 DOI: 10.1021/ja0597294

High-Resolution Continuum Source AAS:  The Better Way to Do Atomic Absorption Spectrometry By Bernard Welz (Universdade Federal de Santa Caterina, Florianoplis, Brazil), Helmut Becker-Ross, Stefan Florek, and Uwe Heitmann (ISAS, Institute for Analytical Sciences, Berlin). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim, Germany. 2005. xii + 295 pp. $130.00. ISBN 3-527-30736-2. David J. Butcher pp 10120–10121 DOI: 10.1021/ja0597395

New Techniques in Solid-State NMR. Topics in Current Chemistry, 246 Edited by Jacek Klinowski (University of Cambridge, UK). Springer:  Berlin, Heidelberg, New York. 2005. x + 358 pp. $299.00. ISBN 3-540-22168-9. Cecil Dybowski p 10121 DOI: 10.1021/ja059751x

Metal-Catalyzed Cross-Coupling Reactions, Second, Completely Revised and Enlarged Edition:  Volumes 1 and 2 Edited by Armin de Meijere (George-August-Universität, Göttingen) and Francois Diederich (ETH, Zürich). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xxii + xxii + 916 pp. $450.00. ISBN 3-527-30518-1. Jon C. Antilla pp 10121–10122 DOI: 10.1021/ja059731v

Issue 29

Reversing the Discovery Paradigm:  A New Approach to the Combinatorial Discovery of Fluorescent Chemosensors Jesse V. Mello and Nathaniel S. Finney pp 10124–10125 DOI: 10.1021/ja043682p Supporting Info

Effect of the Thiol−Thiolate Equilibrium on the Photophysical Properties of Aqueous CdSe/ZnS Nanocrystal Quantum Dots Sohee Jeong, Marc Achermann, Jagjit Nanda, Sergei Ivanov, Victor I. Klimov, and Jennifer A. Hollingsworth pp 10126–10127 DOI: 10.1021/ja042591p Supporting Info

Ultrafast Dynamics in Multibranched Structures with Enhanced Two-Photon Absorption Ying Wang, Guang S. He, Paras N. Prasad, and Theodore Goodson III pp 10128–10129 DOI: 10.1021/ja051099i Supporting Info

Structure-Based Design of Potent Non-Peptide MDM2 Inhibitors Ke Ding, Yipin Lu, Zaneta Nikolovska-Coleska, Su Qiu, Yousong Ding, Wei Gao, Jeanne Stuckey, Krzysztof Krajewski, Peter P. Roller, York Tomita, Damon A. Parrish, Jeffrey R. Deschamps, and Shaomeng Wang pp 10130–10131 DOI: 10.1021/ja051147z Supporting Info

Dendrimer-like PEO Glycopolymers Exhibit Anti-Inflammatory Properties Shyam M. Rele, Wanxing Cui, Lianchun Wang, Sijian Hou, Ginger Barr-Zarse, Daniel Tatton, Yves Gnanou, Jeffrey D. Esko, and Elliot L. Chaikof pp 10132–10133 DOI: 10.1021/ja0511974 Supporting Info

Triplet Excited States as Chiral Reporters for the Binding of Drugs to Transport Proteins M. Consuelo Jiménez, Miguel A. Miranda, and Ignacio Vayá pp 10134–10135 DOI: 10.1021/ja0514489

Artificial Polypeptide Scaffold for Protein Immobilization Kechun Zhang, Michael R. Diehl, and David A. Tirrell pp 10136–10137 DOI: 10.1021/ja051457h Supporting Info

High-Resolution Magic Angle Spinning NMR of the Neuronal Tau Protein Integrated in Alzheimer's-Like Paired Helical Fragments Alain Sillen, Jean-Michel Wieruszeski, Arnaud Leroy, Amena Ben Younes, Isabelle Landrieu, and Guy Lippens pp 10138–10139 DOI: 10.1021/ja0516211 Supporting Info

A Synthetic Route to Size-Controlled fcc and fct FePt Nanoparticles Luciano E. M. Howard, H. Loc Nguyen, Sean R. Giblin, Brian K. Tanner, Ian Terry, Andrew K. Hughes, and John S. O. Evans pp 10140–10141 DOI: 10.1021/ja051669e Supporting Info

High-Performance Organic Field-Effect Transistors Based on π-Extended Tetrathiafulvalene Derivatives Naraso, Jun-ichi Nishida, Shinji Ando, Jun Yamaguchi, Kenji Itaka, Hideomi Koinuma, Hirokazu Tada, Shizuo Tokito, and Yoshiro Yamashita pp 10142–10143 DOI: 10.1021/ja051755e Supporting Info

DNA Constraints Allow Rational Control of Macromolecular Conformation Chandrasekhar V. Miduturu and Scott K. Silverman pp 10144–10145 DOI: 10.1021/ja051950t Supporting Info

Neighbor Effect on PPII Conformation in Alanine Peptides Kang Chen, Zhigang Liu, Chunhui Zhou, Zhengshuang Shi, and Neville R. Kallenbach pp 10146–10147 DOI: 10.1021/ja052094o

Artificial Peptide-Nanospheres Self-Assembled from Three-Way Junctions of β-Sheet-Forming Peptides Kazunori Matsuura, Kazuya Murasato, and Nobuo Kimizuka pp 10148–10149 DOI: 10.1021/ja052644i Supporting Info

A Single-Chain Magnet Formed by a Twisted Arrangement of Ions with Easy-Plane Magnetic Anisotropy Takashi Kajiwara, Motohiro Nakano, Yukihiro Kaneko, Shinya Takaishi, Tasuku Ito, Masahiro Yamashita, Asako Igashira-Kamiyama, Hiroyuki Nojiri, Yuuki Ono, and Norimichi Kojima pp 10150–10151 DOI: 10.1021/ja052653r Supporting Info

ZnO−CdSe Nanoparticle Clusters as Directional Photoemitters with Tunable Wavelength Jin Young Kim and Frank E. Osterloh pp 10152–10153 DOI: 10.1021/ja052735f Supporting Info

Vesicle Array-Templated Large-Area Silica Surface Patterns Qihui Shi, Jianfang Wang, Michael D. Wyrsta, and Galen D. Stucky pp 10154–10155 DOI: 10.1021/ja052815j Supporting Info

Size of Supramolecular SNARE Complex:  Membrane-Directed Self-Assembly Won Jin Cho, Aleksandar Jeremic, and Bhanu P. Jena pp 10156–10157 DOI: 10.1021/ja052442m Supporting Info

Are Methyl Groups Electron-Donating or Electron-Withdrawing in Boron Clusters? Permethylation of o-Carborane Francesc Teixidor, Gemma Barberà, Albert Vaca, Raikko Kivekäs, Reijo Sillanpää, Josep Oliva, and Clara Viñas pp 10158–10159 DOI: 10.1021/ja052981r Supporting Info

DNA Electrochemistry through the Base Pairs Not the Sugar−Phosphate Backbone Tao Liu and Jacqueline K. Barton pp 10160–10161 DOI: 10.1021/ja053025c

A Naphthalene with Unusual Bond Alternation Made by Annelation with Bicyclo[2.1.1]hexene Units:  Aromaticity and Reactivity Takayuki Uto, Tohru Nishinaga, Akira Matsuura, Ryota Inoue, and Koichi Komatsu pp 10162–10163 DOI: 10.1021/ja053769q Supporting Info

Catalytic Enantioselective Fluorination of Oxindoles Yoshitaka Hamashima, Toshiaki Suzuki, Hisashi Takano, Yuta Shimura, and Mikiko Sodeoka pp 10164–10165 DOI: 10.1021/ja0513077 Supporting Info

Experimental Evidence for Large Ring Metallacycle Intermediates in Polyethylene Chain Growth Using Homogeneous Chromium Catalysts Atanas K. Tomov, Juan J. Chirinos, David J. Jones, Richard J. Long, and Vernon C. Gibson pp 10166–10167 DOI: 10.1021/ja051523f Supporting Info

Organomediated Morita−Baylis−Hillman Cyclization Reactions Marie E. Krafft and Thomas F. N. Haxell pp 10168–10169 DOI: 10.1021/ja052146+ Supporting Info

The Selective Preparation of an Aluminum Oxide and Its Isomeric C−H-Activated Hydroxide Hongping Zhu, Jianfang Chai, Vojtech Jancik, Herbert W. Roesky, William A. Merrill, and Philip P. Power pp 10170–10171 DOI: 10.1021/ja052400y Supporting Info

Inductive Effect-Assisted Chain-Growth Polycondensation. Synthetic Development from para- to meta-Substituted Aromatic Polyamides with Low Polydispersities Ryuji Sugi, Akihiro Yokoyama, Taniyuki Furuyama, Masanobu Uchiyama, and Tsutomu Yokozawa pp 10172–10173 DOI: 10.1021/ja052566z Supporting Info

Activation of a SiSi Bond by η1-Coordination to a Transition Metal Thi-loan Nguyen and David Scheschkewitz pp 10174–10175 DOI: 10.1021/ja052593p Supporting Info

High-Resolution NMR Studies of Encapsulated Proteins in Liquid Ethane Ronald W. Peterson, Brian G. Lefebvre, and A. Joshua Wand pp 10176–10177 DOI: 10.1021/ja0526517

Secondary Alpha Isotope Effects on Deuterium Tunneling in Triplet o-Methylanthrones:  Extraordinary Sensitivity to Barrier Width Luis M. Campos, Manoj V. Warrier, Krisztina Peterfy, K. N. Houk, and Miguel A. Garcia-Garibay pp 10178–10179 DOI: 10.1021/ja052487n Supporting Info

Cycloisomerization of Enynes via Rhodium Vinylidene-Mediated Catalysis Hahn Kim and Chulbom Lee pp 10180–10181 DOI: 10.1021/ja052775j Supporting Info

Stable Planar Six-π-Electron Six-Membered N-Heterocyclic Carbenes with Tunable Electronic Properties Carsten Präsang, Bruno Donnadieu, and Guy Bertrand pp 10182–10183 DOI: 10.1021/ja052987g Supporting Info

Reduction of N2 to Ammonia and Hydrazine Utilizing H2 as the Reductant John D. Gilbertson, Nathaniel K. Szymczak, and David R. Tyler pp 10184–10185 DOI: 10.1021/ja053030g Supporting Info

Sequential Catalytic Asymmetric Heck−Iminium Ion Cyclization:  Enantioselective Total Synthesis of the Strychnos Alkaloid Minfiensine Amy B. Dounay, Larry E. Overman, and Aaron D. Wrobleski pp 10186–10187 DOI: 10.1021/ja0533895 Supporting Info

A New Folding Paradigm for Repeat Proteins Tommi Kajander, Aitziber L. Cortajarena, Ewan R. G. Main, Simon G. J. Mochrie, and Lynne Regan pp 10188–10190 DOI: 10.1021/ja0524494 Supporting Info

Terphenyl-Based Bak BH3 α-Helical Proteomimetics as Low-Molecular-Weight Antagonists of Bcl-xL Hang Yin, Gui-in Lee, Kristine A. Sedey, Olaf Kutzki, Hyung Soon Park, Brendan P. Orner, Justin T. Ernst, Hong-Gang Wang, Said M. Sebti, and Andrew D. Hamilton pp 10191–10196 DOI: 10.1021/ja050122x Supporting Info

Selective Zinc Sensor Molecules with Various Affinities for Zn2+, Revealing Dynamics and Regional Distribution of Synaptically Released Zn2+ in Hippocampal Slices Kensuke Komatsu, Kazuya Kikuchi, Hirotatsu Kojima, Yasuteru Urano, and Tetsuo Nagano pp 10197–10204 DOI: 10.1021/ja050301e Supporting Info

High-Affinity Adaptors for Switchable Recognition of Histidine-Tagged Proteins Suman Lata, Annett Reichel, Roland Brock, Robert Tampé, and Jacob Piehler pp 10205–10215 DOI: 10.1021/ja050690c Supporting Info

An Investigation of Weak CH···O Hydrogen Bonds in Maltose Anomers by a Combination of Calculation and Experimental Solid-State NMR Spectroscopy Jonathan R. Yates, Tran N. Pham, Chris J. Pickard, Francesco Mauri, Ana M. Amado, Ana M. Gil, and Steven P. Brown pp 10216–10220 DOI: 10.1021/ja051019a Supporting Info

Optical Properties of CdSe Superlattices Natalia Zaitseva, Zu Rong Dai, Francisco R. Leon, and Denise Krol pp 10221–10226 DOI: 10.1021/ja051069f Supporting Info

Covalently Bound Hole-Injecting Nanostructures. Systematics of Molecular Architecture, Thickness, Saturation, and Electron-Blocking Characteristics on Organic Light-Emitting Diode Luminance, Turn-on Voltage, and Quantum Efficiency Qinglan Huang, Guennadi A. Evmenenko, Pulak Dutta, Paul Lee, Neal R. Armstrong, and Tobin J. Marks pp 10227–10242 DOI: 10.1021/ja051077w Supporting Info

Can Polarization of Triple Bond in Tolanes Be Deduced from 13C NMR Shifts? Re-evaluation of Factors Affecting Regiochemistry of the Palladium-Catalyzed Hydrostannation of Alkynes Michael Rubin, Alexander Trofimov, and Vladimir Gevorgyan pp 10243–10249 DOI: 10.1021/ja051274v Supporting Info

Metal “Capture” by a Heterotrimetalloligand, Heterometallic d10−d10 Interactions, and Unexpected Iron-to-Platinum Silyl Ligand Migration:  a Combined Experimental and Theoretical Study Walter Schuh, Pierre Braunstein, Marc Bénard, Marie-Madeleine Rohmer, and Richard Welter pp 10250–10258 DOI: 10.1021/ja051389z Supporting Info

Exploiting the Pd- and Ru-Catalyzed Cycloisomerizations:  Enantioselective Total Synthesis of (+)-Allocyathin B2 Barry M. Trost, Li Dong, and Gretchen M. Schroeder pp 10259–10268 DOI: 10.1021/ja051547m Supporting Info

γ-Fe2O3/II−VI Sulfide Nanocrystal Heterojunctions Kwan-Wook Kwon and Moonsub Shim pp 10269–10275 DOI: 10.1021/ja051713q Supporting Info

Structures and Hydration Enthalpies of Cationized Glutamine and Structural Analogues in the Gas Phase Andrew S. Lemoff, Matthew F. Bush, Chih-Che Wu, and Evan R. Williams pp 10276–10286 DOI: 10.1021/ja051743t

Large-Scale Separation of Metallic and Semiconducting Single-Walled Carbon Nanotubes Yutaka Maeda, Shin-ichi Kimura, Makoto Kanda, Yuya Hirashima, Tadashi Hasegawa, Takatsugu Wakahara, Yongfu Lian, Tsukasa Nakahodo, Takahiro Tsuchiya, Takeshi Akasaka, Jing Lu, Xinwei Zhang, Zhengxiang Gao, Yapeng Yu, Shigeru Nagase, Said Kazaoui, Nobutsugu Minami, Tetsuo Shimizu, Hiroshi Tokumoto, and Riichiro Saito pp 10287–10290 DOI: 10.1021/ja051774o Supporting Info

Ligand-Induced Haptotropic Rearrangements in Bis(indenyl)zirconium Sandwich Complexes Christopher A. Bradley, Emil Lobkovsky, Ivan Keresztes, and Paul J. Chirik pp 10291–10304 DOI: 10.1021/ja052033q Supporting Info

Why Are BINOL-Based Monophosphites Such Efficient Ligands in Rh-Catalyzed Asymmetric Olefin Hydrogenation? Manfred T. Reetz, Andreas Meiswinkel, Gerlinde Mehler, Klaus Angermund, Martin Graf, Walter Thiel, Richard Mynott, and Donna G. Blackmond pp 10305–10313 DOI: 10.1021/ja052025+

Chiroptical Effects in the Second Harmonic Signal of Collagens I and IV Ana-Maria Pena, Thierry Boulesteix, Thibault Dartigalongue, and Marie-Claire Schanne-Klein pp 10314–10322 DOI: 10.1021/ja0520969 Supporting Info

On the Mechanism of the Palladium(II)-Catalyzed Decarboxylative Olefination of Arene Carboxylic Acids. Crystallographic Characterization of Non-Phosphine Palladium(II) Intermediates and Observation of Their Stepwise Transformation in Heck-like Processes Daisuke Tanaka, Stuart P. Romeril, and Andrew G. Myers pp 10323–10333 DOI: 10.1021/ja052099l Supporting Info

Multicomponent Host−Guest Chemistry of Carboxylic Acid and Phosphonic Acid Based Guests with Dendritic Hosts:  An NMR Study Maarten A. C. Broeren, Bas F. M. de Waal, Marcel H. P. van Genderen, H. M. H. F. Sanders, George Fytas, and E. W. Meijer pp 10334–10343 DOI: 10.1021/ja052074m Supporting Info

Chemically Patterned Flat Stamps for Microcontact Printing Ruben B. A. Sharpe, Dirk Burdinski, Jurriaan Huskens, Harold J. W. Zandvliet, David N. Reinhoudt, and Bene Poelsema pp 10344–10349 DOI: 10.1021/ja052139l Supporting Info

Aggregation-Driven Growth of Size-Tunable Organic Nanoparticles Using Electronically Altered Conjugated Polymers Fuke Wang, Ming-Yong Han, Khine Yi Mya, Yubo Wang, and Yee-Hing Lai pp 10350–10355 DOI: 10.1021/ja0521730 Supporting Info

Structural Selection by Microsolvation:  Conformational Locking of Tryptamine Michael Schmitt, Marcel Böhm, Christian Ratzer, Chau Vu, Ivo Kalkman, and W. Leo Meerts pp 10356–10364 DOI: 10.1021/ja0522377 Supporting Info

A Solid-State NMR Method for Solution of Zeolite Crystal Structures Darren H. Brouwer, Richard J. Darton, Russell E. Morris, and Malcolm H. Levitt pp 10365–10370 DOI: 10.1021/ja052306h Supporting Info

Hierarchical Assembly of Helicate-Type Dinuclear Titanium(IV) Complexes Markus Albrecht, Sebastian Mirtschin, Marita de Groot, Ingo Janser, Jan Runsink, Gerhard Raabe, Michael Kogej, Christoph A. Schalley, and Roland Fröhlich pp 10371–10387 DOI: 10.1021/ja052326j Supporting Info

Low-Voltage Organic Field-Effect Transistors and Inverters Enabled by Ultrathin Cross-Linked Polymers as Gate Dielectrics Myung-Han Yoon, He Yan, Antonio Facchetti, and Tobin J. Marks pp 10388–10395 DOI: 10.1021/ja052488f

Stereoselective Syntheses of Rolliniastatin 1, Rollimembrin, and Membranacin Gyochang Keum, Cheol Hee Hwang, Soon Bang Kang, Youseung Kim, and Eun Lee pp 10396–10399 DOI: 10.1021/ja0526867 Supporting Info

Surface Patterning with Two-Dimensional Porphyrin Supramolecular Arrays Joe Otsuki, Emi Nagamine, Tomohide Kondo, Kosyo Iwasaki, Masumi Asakawa, and Koji Miyake pp 10400–10405 DOI: 10.1021/ja0531778

Zooxanthellamide Cs:  Vasoconstrictive Polyhydroxylated Macrolides with the Largest Lactone Ring Size from a Marine Dinoflagellate of Symbiodinium sp. Ken-ichi Onodera, Hideshi Nakamura, Yuichi Oba, Yasushi Ohizumi, and Makoto Ojika pp 10406–10411 DOI: 10.1021/ja050810g Supporting Info

Occurrence, Shape, and Dimensions of Large Surface Hemimicelles Made of Semifluorinated Alkanes. Elongated versus Circular Hemimicelles. Pit- and Tip-Centered Hemimicelles Guifang Zhang, Pascal Marie, Mounir Maaloum, Pierre Muller, Nicole Benoit, and Marie Pierre Krafft pp 10412–10419 DOI: 10.1021/ja0510515

Sunfish Cationic Amphiphiles:  Toward an Adaptative Lipoplex Morphology Marco Scarzello, Jarmila misterov, Anno Wagenaar, Marc C. A. Stuart, Dick Hoekstra, Jan B. F. N. Engberts, and Ron Hulst pp 10420–10429 DOI: 10.1021/ja0515147

Mössbauer Studies of the Iron−Sulfur Cluster-Free Hydrogenase:  The Electronic State of the Mononuclear Fe Active Site Seigo Shima, Erica J. Lyon, Rudolf K. Thauer, Bernd Mienert, and Eckhard Bill pp 10430–10435 DOI: 10.1021/ja051895o Supporting Info

Studies of C−S Bond Cleavage Reactions of Re(V) Dithiolates:  Synthesis, Reactivity, and Mechanism Ming Li, Arkady Ellern, and James H. Espenson pp 10436–10447 DOI: 10.1021/ja0519334 Supporting Info

Trimetallic Nitride Endohedral Metallofullerenes:  Reactivity Dictated by the Encapsulated Metal Cluster Claudia M. Cardona, Alex Kitaygorodskiy, and Luis Echegoyen pp 10448–10453 DOI: 10.1021/ja052153y Supporting Info

A Likely Biogenetic Gateway Linking 2-Aminoimidazolinone Metabolites of Sponges to Proline:  Spontaneous Oxidative Conversion of the Pyrrole-Proline-Guanidine Pseudo-peptide to Dispacamide A  [J. Am. Chem. Soc. 2004, 126, 10252−10253].  Nathalie Travert and Ali Al-Mourabit p 10454 DOI: 10.1021/ja053215n

Issue 30

Inversion of the Rectifying Effect in Diblock Molecular Diodes by Protonation Gustavo M. Morales, Ping Jiang, Shenwen Yuan, Youngu Lee, Arturo Sanchez, Wei You, and Luping Yu pp 10456–10457 DOI: 10.1021/ja051332c Supporting Info

Reaction of Hydroxyfullerene with Metal Salts:  A Route to Remediation and Immobilization Robin Anderson and Andrew R. Barron pp 10458–10459 DOI: 10.1021/ja051659d Supporting Info

Synthesis and Characterization of β-Haloalkenyl-λ3-bromanes:  Stereoselective Markovnikov Addition of Difluoro(aryl)-λ3-bromane to Terminal Acetylenes Masahito Ochiai, Yoshio Nishi, Takeshi Mori, Norihiro Tada, Takashi Suefuji, and Hermann J. Frohn pp 10460–10461 DOI: 10.1021/ja051690f Supporting Info

Stepwise Growth of a Single Polymer Chain Seong-Ho Shin and Hagan Bayley pp 10462–10463 DOI: 10.1021/ja052194u

Ion Sensing Coupled to Resonance Energy Transfer:  A Highly Selective and Sensitive Ratiometric Fluorescent Chemosensor for Ag(I) by a Modular Approach Ali Coskun and Engin U. Akkaya pp 10464–10465 DOI: 10.1021/ja052574f Supporting Info

Laminar Flow-Based Electrochemical Microreactor for Efficient Regeneration of Nicotinamide Cofactors for Biocatalysis Seong Kee Yoon, Eric R. Choban, Cheikhou Kane, Theodore Tzedakis, and Paul J. A. Kenis pp 10466–10467 DOI: 10.1021/ja052613n Supporting Info

Real-Time Membrane Fusion of Giant Polymer Vesicles Yongfeng Zhou and Deyue Yan pp 10468–10469 DOI: 10.1021/ja0505696 Supporting Info

A New Synthetic Approach to Phenol Derivatives:  Use of Ring-Closing Olefin Metathesis Kazuhiro Yoshida and Tsuneo Imamoto pp 10470–10471 DOI: 10.1021/ja050853x Supporting Info

Substrate Binding Modulates the Reduction Potential of DNA Photolyase Yvonne M. Gindt, Johannes P. M. Schelvis, Katie L. Thoren, and Tina H. Huang pp 10472–10473 DOI: 10.1021/ja051441r Supporting Info

Kinetic Resolution of Axially Chiral 2,2‘-Dihydroxy-1,1‘-biaryls by Palladium-Catalyzed Alcoholysis Hiroshi Aoyama, Makoto Tokunaga, Junya Kiyosu, Tetsuo Iwasawa, Yasushi Obora, and Yasushi Tsuji pp 10474–10475 DOI: 10.1021/ja051750h Supporting Info

The Ni-Mediated Cyclocarbonylation of Allyl Halides and Alkynes Made Catalytic. Evidence Supporting the Involvement of Pseudoradical NiI Species in the Mechanism M. Lluïsa Nadal, Julia Bosch, Josep M. Vila, Günter Klein, Susagna Ricart, and Josep M. Moretó pp 10476–10477 DOI: 10.1021/ja0525713 Supporting Info

Palladium Pincer Complex Catalyzed Substitution of Vinyl Cyclopropanes, Vinyl Aziridines, and Allyl Acetates with Tetrahydroxydiboron. An Efficient Route to Functionalized Allylboronic Acids and Potassium Trifluoro(allyl)borates Sara Sebelius, Vilhelm J. Olsson, and Kálmán J. Szabó pp 10478–10479 DOI: 10.1021/ja052885q Supporting Info

Ultrastable Au Nanocatalyst Supported on Surface-Modified TiO2 Nanocrystals Wenfu Yan, Shannon M. Mahurin, Zhengwei Pan, Steven H. Overbury, and Sheng Dai pp 10480–10481 DOI: 10.1021/ja053191k Supporting Info

Catalytic Enantioselective Negishi Reactions of Racemic Secondary Benzylic Halides Forrest O. Arp and Gregory C. Fu pp 10482–10483 DOI: 10.1021/ja053751f Supporting Info

Nanoparticles on the Basis of Highly Functionalized Dextrans Tim Liebert, Stephanie Hornig, Stephanie Hesse, and Thomas Heinze pp 10484–10485 DOI: 10.1021/ja052594h

Efficient Complexation of N-Acetyl Amino Acid Carboxylates in Water by an Artificial Receptor:  Unexpected Cooperativity in the Binding of Glutamate but Not Aspartate Carsten Schmuck and Lars Geiger pp 10486–10487 DOI: 10.1021/ja052699k Supporting Info

Modular Monodentate Phosphoramidite Ligands for Rhodium-Catalyzed Enantioselective Hydrogenation Yan Liu and Kuiling Ding pp 10488–10489 DOI: 10.1021/ja052749l Supporting Info

Identification of Partially Disordered Peptide Intermediates through Residue-Specific NMR Diffusion Measurements Yingjie Li, Seho Kim, Barbara Brodsky, and Jean Baum pp 10490–10491 DOI: 10.1021/ja052801d Supporting Info

Allosterically Activated Diels−Alder Catalysis by a Ribozyme Mark Helm, Markus Petermeier, Bixia Ge, Roberto Fiammengo, and Andres Jäschke pp 10492–10493 DOI: 10.1021/ja052886i Supporting Info

Proximity-Induced Catalysis by the Protein Kinase ERK2 Mark A. Rainey, Kari Callaway, Richard Barnes, Brian Wilson, and Kevin N. Dalby pp 10494–10495 DOI: 10.1021/ja052915p Supporting Info

Nanobelt Self-Assembly from an Organic n-Type Semiconductor:  Propoxyethyl-PTCDI Kaushik Balakrishnan, Aniket Datar, Randy Oitker, Hao Chen, Jianmin Zuo, and Ling Zang pp 10496–10497 DOI: 10.1021/ja052940v Supporting Info

Interfacial Polymerization within a Simplified Microfluidic Device:  Capturing Capsules Elizabeth Quevedo, Jeremy Steinbacher, and D. Tyler McQuade pp 10498–10499 DOI: 10.1021/ja0529945 Supporting Info

1,2-Halogen Migration in Haloallenyl Ketones:  Regiodivergent Synthesis of Halofurans Anna W. Sromek, Marina Rubina, and Vladimir Gevorgyan pp 10500–10501 DOI: 10.1021/ja053290y Supporting Info

Synthesis and Structure of Fused α-Oligothiophenes with up to Seven Rings Xinnan Zhang, Adrien P. Côté, and Adam J. Matzger pp 10502–10503 DOI: 10.1021/ja053326m Supporting Info

Design of an Organocatalyst for the Enantioselective Diels−Alder Reaction with α-Acyloxyacroleins Kazuaki Ishihara and Kazuhiko Nakano pp 10504–10505 DOI: 10.1021/ja053368a Supporting Info

Ni(II) Tol-BINAP-Catalyzed Enantioselective Orthoester Alkylations of N-Acylthiazolidinethiones David A. Evans and Regan J. Thomson pp 10506–10507 DOI: 10.1021/ja053386s Supporting Info

A Synthetic Breakthrough into an Unanticipated Stability Regime:  Readily Isolable Complexes in which C16−C28 Polyynediyl Chains Span Two Platinum Atoms Qinglin Zheng and J. A. Gladysz pp 10508–10509 DOI: 10.1021/ja0534598 Supporting Info

DNA Interstrand Cross-Link Formation Initiated by Reaction between Singlet Oxygen and a Modified Nucleotide In Seok Hong and Marc M. Greenberg pp 10510–10511 DOI: 10.1021/ja053493m Supporting Info

High-Valent Nonheme Iron. Two Distinct Iron(IV) Species Derived from a Common Iron(II) Precursor Michael P. Jensen, Miquel Costas, Raymond Y. N. Ho, József Kaizer, Antoni Mairata i Payeras, Eckard Münck, Lawrence Que, Jr., Jan-Uwe Rohde, and Audria Stubna pp 10512–10525 DOI: 10.1021/ja0438765 Supporting Info

Engineering InAsxP1-x/InP/ZnSe III−V Alloyed Core/Shell Quantum Dots for the Near-Infrared Sang-Wook Kim, John P. Zimmer, Shunsuke Ohnishi, Joseph B. Tracy, John V. Frangioni, and Moungi G. Bawendi pp 10526–10532 DOI: 10.1021/ja0434331

Sensitivity of Ammonia Interaction with Single-Walled Carbon Nanotube Bundles to the Presence of Defect Sites and Functionalities Xue Feng, Stephan Irle, Henryk Witek, Keiji Morokuma, Radisav Vidic, and Eric Borguet pp 10533–10538 DOI: 10.1021/ja042998u Supporting Info

Sterically Directed Functionalization of Aromatic C−H Bonds:  Selective Borylation Ortho to Cyano Groups in Arenes and Heterocycles Ghayoor A. Chotana, Michael A. Rak, and Milton R. Smith, III pp 10539–10544 DOI: 10.1021/ja0428309 Supporting Info

Crystal Structure Prediction of Aminols:  Advantages of a Supramolecular Synthon Approach with Experimental Structures Archan Dey, Michael T. Kirchner, Venu R. Vangala, Gautam R. Desiraju, Raju Mondal, and Judith A. K. Howard pp 10545–10559 DOI: 10.1021/ja042738c Supporting Info

Amphiphilic Guest Sorption of K2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] Ionic Crystal Ryosuke Kawamoto, Sayaka Uchida, and Noritaka Mizuno pp 10560–10567 DOI: 10.1021/ja042333s Supporting Info

Facile Diels−Alder Reactions with Pyridines Promoted by Tungsten Peter M. Graham, David A. Delafuente, Weijun Liu, William H. Myers, Michal Sabat, and W. D. Harman pp 10568–10572 DOI: 10.1021/ja050143r Supporting Info

Computational and ESR Studies of Electron Attachment to Decafluorocyclopentane, Octafluorocyclobutane, and Hexafluorocyclopropane:  Electron Affinities of the Molecules and the Structures of Their Stable Negative Ions as Determined from 13C and 19F Hyperfine Coupling Constants Adel M. ElSohly, Gregory S. Tschumper, Richard A. Crocombe, Jih Tzong Wang, and Ffrancon Williams pp 10573–10583 DOI: 10.1021/ja0505898 Supporting Info

Putative DNA Quadruplex Formation within the Human c-kit Oncogene Sarah Rankin, Anthony P. Reszka, Julian Huppert, Mire Zloh, Gary N. Parkinson, Alan K. Todd, Sylvain Ladame, Shankar Balasubramanian, and Stephen Neidle pp 10584–10589 DOI: 10.1021/ja050823u

Abiotic Metallofoldamers as Electrochemically Responsive Molecules Fan Zhang, Shi Bai, Glenn P. A. Yap, Vinod Tarwade, and Joseph M. Fox pp 10590–10599 DOI: 10.1021/ja050886c Supporting Info

Photoinduced Charge Transfer Processes along Triarylamine Redox Cascades Christoph Lambert, Jürgen Schelter, Torsten Fiebig, Daniela Mank, and Anton Trifonov pp 10600–10610 DOI: 10.1021/ja0511570 Supporting Info

Optical Spectra of Delocalized Dinitroaromatic Radical Anions Revisited Stephen F. Nelsen, Michael N. Weaver, Jeffrey I. Zink, and João P. Telo pp 10611–10622 DOI: 10.1021/ja051178u Supporting Info

Ligand-Stabilized Aromatic Three-Membered Gold Rings and Their Sandwichlike Complexes Athanassios C. Tsipis and Constantinos A. Tsipis pp 10623–10638 DOI: 10.1021/ja051415t Supporting Info

Electrochemical Templating of Metal Nanoparticles and Nanowires on Single-Walled Carbon Nanotube Networks Thomas M. Day, Patrick R. Unwin, Neil R. Wilson, and Julie V. Macpherson pp 10639–10647 DOI: 10.1021/ja051320r Supporting Info

On the Nature of the Transition State in Catechol O-Methyltransferase. A Complementary Study Based on Molecular Dynamics and Potential Energy Surface Explorations Maite Roca, Juan Andrés, Vicent Moliner, Iñaki Tuñón, and Juan Bertrán pp 10648–10655 DOI: 10.1021/ja051503d Supporting Info

A Joint Experimental and Theoretical Study of Cation−π Interactions:  Multiple-Decker Sandwich Complexes of Ferrocene with Alkali Metal Ions (Li+, Na+, K+, Rb+, Cs+) Alireza Haghiri Ilkhechi, Jose M. Mercero, Iñaki Silanes, Michael Bolte, Matthias Scheibitz, Hans-Wolfram Lerner, Jesus M. Ugalde, and Matthias Wagner pp 10656–10666 DOI: 10.1021/ja051544+ Supporting Info

Mycosamine Orientation of Amphotericin B Controlling Interaction with Ergosterol:  Sterol-Dependent Activity of Conformation-Restricted Derivatives with an Amino-Carbonyl Bridge Nobuaki Matsumori, Yuri Sawada, and Michio Murata pp 10667–10675 DOI: 10.1021/ja051597r Supporting Info

Generation of Superparamagnetic Liposomes Revealed as Highly Efficient MRI Contrast Agents for in Vivo Imaging Marie-Sophie Martina, Jean-Paul Fortin, Christine Ménager, Olivier Clément, Gillian Barratt, Cécile Grabielle-Madelmont, Florence Gazeau, Valérie Cabuil, and Sylviane Lesieur pp 10676–10685 DOI: 10.1021/ja0516460

Water-Assisted Oxo Mechanism for Heme Metabolism Takashi Kamachi and Kazunari Yoshizawa pp 10686–10692 DOI: 10.1021/ja051912+ Supporting Info

Noncovalent Modification of Chymotrypsin Surface Using an Amphiphilic Polymer Scaffold:  Implications in Modulating Protein Function Britto S. Sandanaraj, Dharma Rao Vutukuri, Joseph M. Simard, Akamol Klaikherd, Rui Hong, Vincent M. Rotello, and S. Thayumanavan pp 10693–10698 DOI: 10.1021/ja051947+ Supporting Info

Can the π-Facial Selectivity of Solvation Be Predicted by Atomistic Simulation? Roberto Berardi, Gianfranco Cainelli, Paola Galletti, Daria Giacomini, Andrea Gualandi, Luca Muccioli, and Claudio Zannoni pp 10699–10706 DOI: 10.1021/ja052199r Supporting Info

Microfabrication of Three-Dimensional Bioelectronic Architectures Ryan T. Hill, Jennifer L. Lyon, Richard Allen, Keith J. Stevenson, and Jason B. Shear pp 10707–10711 DOI: 10.1021/ja052211f

Cyano- and Isocyanotris(trifluoromethyl)borates:  Syntheses, Spectroscopic Properties, and Solid State Structures of K[(CF3)3BCN] and K[(CF3)3BNC] Maik Finze, Eduard Bernhardt, Helge Willner, and Christian W. Lehmann pp 10712–10722 DOI: 10.1021/ja0516357 Supporting Info

Mechanistic Investigations of the Ethylene Tetramerisation Reaction Matthew J. Overett, Kevin Blann, Annette Bollmann, John T. Dixon, Daleen Haasbroek, Esna Killian, Hulisani Maumela, David S. McGuinness, and David H. Morgan pp 10723–10730 DOI: 10.1021/ja052327b Supporting Info

X-ray Diffraction and DOSY NMR Characterization of Self-Assembled Supramolecular Metallocyclic Species in Solution Tünde Megyes, Hershel Jude, Tamás Grósz, Imre Bakó, Tamás Radnai, Gábor Tárkányi, Gábor Pálinkás, and Peter J. Stang pp 10731–10738 DOI: 10.1021/ja0523690 Supporting Info

Substrate Discrimination by Cholapod Anion Receptors:  Geometric Effects and the “Affinity−Selectivity Principle” John P. Clare, Alan J. Ayling, Jean-Baptiste Joos, Adam L. Sisson, Germinal Magro, M. Nieves Pérez-Payán, Timothy N. Lambert, Rameshwer Shukla, Bradley D. Smith, and Anthony P. Davis pp 10739–10746 DOI: 10.1021/ja0524144 Supporting Info

A Systematic Investigation of the Synthetic Utility of Glycopeptide Glycosyltransferases Markus Oberthür, Catherine Leimkuhler, Ryan G. Kruger, Wei Lu, Christopher T. Walsh, and Daniel Kahne pp 10747–10752 DOI: 10.1021/ja052945s Supporting Info

Modeling of Stimulated Hydrogel Volume Changes in Photonic Crystal Pb2+ Sensing Materials Alexander V. Goponenko and Sanford A. Asher pp 10753–10759 DOI: 10.1021/ja051456p Supporting Info

Reactivity of Monolayer-Protected Gold Nanoclusters at Dye-Sensitized Liquid/Liquid Interfaces Bin Su, Nicolas Eugster, and Hubert H. Girault pp 10760–10766 DOI: 10.1021/ja052415w Supporting Info

Total Synthesis of Ningalin D Akiyuki Hamasaki, Jeffrey M. Zimpleman, Inkyu Hwang, and Dale L. Boger pp 10767–10770 DOI: 10.1021/ja0526416 Supporting Info

Metallocenes in Regio- and Stereoselective Synthesis. Topics in Organometallic Chemistry, 8 Edited by Tamotsu Takahashi (Hokkaido University). Springer-Verlag:  Berlin, Heidelberg. 2005. x + 244 pp. $229.00. ISBN 3-540-01606-6. Michael C. Baird p 10771 DOI: 10.1021/ja059713d

Catalytic Antibodies Edited by Ehud Keinan (Technion-Israel Institute of Technology). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. xxx + 586 pp. $215.00. ISBN 3-527-30688-9. David B. Smithrud pp 10771–10772 DOI: 10.1021/ja059716q

Issue 31

Why Copper Is Intrinsically More Selective than Silver in Alkene Epoxidation:  Ethylene Oxidation on Cu(111) versus Ag(111) Daniel Torres, Nuria Lopez, Francesc Illas, and Richard M. Lambert pp 10774–10775 DOI: 10.1021/ja043227t Supporting Info

Chiral Lithium Binaphtholate Aqua Complex as a Highly Effective Asymmetric Catalyst for Cyanohydrin Synthesis Manabu Hatano, Takumi Ikeno, Takashi Miyamoto, and Kazuaki Ishihara pp 10776–10777 DOI: 10.1021/ja051125c Supporting Info

Intermolecular Proton Transfer in Solid Phase:  A Rare Example of Crystal-to-Crystal Transformation from Hydroxo- to Oxo-Bridged Iron(III) Molecule-Based Magnet Donatella Armentano, Giovanni De Munno, Teresa F. Mastropietro, Miguel Julve, and Francesc Lloret pp 10778–10779 DOI: 10.1021/ja051203w Supporting Info

Unambiguous Determination of the g-Matrix Orientation in a Neutral Flavin Radical by Pulsed Electron−Nuclear Double Resonance at 94 GHz Christopher W. M. Kay, Robert Bittl, Adelbert Bacher, Gerald Richter, and Stefan Weber pp 10780–10781 DOI: 10.1021/ja051572s

DNA Sequence-Enabled Reassembly of the Green Fluorescent Protein Cliff I. Stains, Jason R. Porter, Aik T. Ooi, David J. Segal, and Indraneel Ghosh pp 10782–10783 DOI: 10.1021/ja051969w Supporting Info

Simple Fluorescent Pyrimidine Analogues Detect the Presence of DNA Abasic Sites Nicholas J. Greco and Yitzhak Tor pp 10784–10785 DOI: 10.1021/ja052000a Supporting Info

Single Etch Patterning of Stacked Silver and Molybdenum Alloy Layers on Glass Using Microcontact Wave Printing Dirk Burdinski, Harold J. A. Brans, and Michel M. J. Decré pp 10786–10787 DOI: 10.1021/ja0523791 Supporting Info

A Single Molecule View of Bistilbene Photoisomerization on a Surface Using Scanning Tunneling Microscopy Chih-Song Tsai, Juen-Kai Wang, Rex T. Skodje, and Jiing-Chyuan Lin pp 10788–10789 DOI: 10.1021/ja052448b Supporting Info

Hydrogenation of Benzene Using Aqueous Solution of Polyoxometalates Reduced by CO over Gold Catalysts Gabriel J. Rodriguez-Rivera, Won Bae Kim, Steven T. Evans, Tobias Voitl, and James A. Dumesic pp 10790–10791 DOI: 10.1021/ja052453f Supporting Info

Creation of Hollow Zeolite Architectures by Controlled Desilication of Al-Zoned ZSM-5 Crystals Johan C. Groen, Torkel Bach, Ulrike Ziese, Anne M. Paulaime-van Donk, Krijn P. de Jong, Jacob A. Moulijn, and Javier Pérez-Ramírez pp 10792–10793 DOI: 10.1021/ja052592x Supporting Info

Low-Temperature Strategy to Synthesize Highly Ordered Mesoporous Silicas with Very Large Pores Jie Fan, Chengzhong Yu, Jie Lei, Qiang Zhang, Tingcheng Li, Bo Tu, Wuzong Zhou, and Dongyuan Zhao pp 10794–10795 DOI: 10.1021/ja052619c Supporting Info

Chemical Control of the DNA Light Switch:  Cycling the Switch ON and OFF Yao Liu, Abdellatif Chouai, Natalya N. Degtyareva, Daniel A. Lutterman, Kim R. Dunbar, and Claudia Turro pp 10796–10797 DOI: 10.1021/ja052648n Supporting Info

Single Molecular Multianalyte (Ca2+, Mg2+) Fluorescent Probe and Applications to Bioimaging Hirokazu Komatsu, Takahiro Miki, Daniel Citterio, Takeshi Kubota, Yutaka Shindo, Yoshiichiro Kitamura, Kotaro Oka, and Koji Suzuki pp 10798–10799 DOI: 10.1021/ja0528228 Supporting Info

Metal−Metal d−d Interaction through the Discrete Stacking of Mononuclear M(II) Complexes (M = Pt, Pd, and Cu) within an Organic-Pillared Coordination Cage Michito Yoshizawa, Kosuke Ono, Kazuhisa Kumazawa, Tatsuhisa Kato, and Makoto Fujita pp 10800–10801 DOI: 10.1021/ja053009f Supporting Info

Helical Structure of Single-Crystalline ZnGa2O4 Nanowires Seung Yong Bae, Jinyoung Lee, Hyunsung Jung, Jeunghee Park, and Jae-Pyoung Ahn pp 10802–10803 DOI: 10.1021/ja0534102 Supporting Info

Domino Coupling Relay Approach to Polycyclic Pyrrole-2-carboxylates Yoshihiko Yamamoto, Hiroki Hayashi, Tomoaki Saigoku, and Hisao Nishiyama pp 10804–10805 DOI: 10.1021/ja053408a Supporting Info

Substrate-Enhanced Electroless Deposition of Metal Nanoparticles on Carbon Nanotubes Liangti Qu and Liming Dai pp 10806–10807 DOI: 10.1021/ja053479+ Supporting Info

Expeditious Access to the Most Easily Ionized Closed-Shell Molecule, W2(hpp)4 F. Albert Cotton, James P. Donahue, Dennis L. Lichtenberger, Carlos A. Murillo, and Dino Villagrán pp 10808–10809 DOI: 10.1021/ja0535458

Exploring Uncharted Terrain in Nature's Structure Space Using Capillary NMR Spectroscopy:  13 Steroids from 50 Fireflies Matthew Gronquist, Jerrold Meinwald, Thomas Eisner, and Frank C. Schroeder pp 10810–10811 DOI: 10.1021/ja053617v Supporting Info

Oxaziridinium Salts as Hydrophobic Epoxidation Reagents:  Remarkable Hydrophobically-Directed Selectivity in Olefin Epoxidation Mark R. Biscoe and Ronald Breslow pp 10812–10813 DOI: 10.1021/ja053660i Supporting Info

A Family of New Boron-Containing Free Radicals Sheng-Gui He, Fumie X. Sunahori, and Dennis J. Clouthier pp 10814–10815 DOI: 10.1021/ja053736a Supporting Info

Ni(II) Tol-BINAP-Catalyzed Enantioselective Michael Reactions of β-Ketoesters and Unsaturated N-Acylthiazolidinethiones David A. Evans, Regan J. Thomson, and Francisco Franco pp 10816–10817 DOI: 10.1021/ja053820q Supporting Info

Total Synthesis of Asimicin via Highly Stereoselective [3 + 2] Annulation Reactions of Substituted Allylsilanes Jennifer M. Tinsley and William R. Roush pp 10818–10819 DOI: 10.1021/ja051986l Supporting Info

Addition of n-Butyllithium to an Aldimine:  Role of Chelation, Aggregation, and Cooperative Solvation Bo Qu and David B. Collum pp 10820–10821 DOI: 10.1021/ja0519987 Supporting Info

Synthesis of Gold Nanorod/Single-Wall Carbon Nanotube Heterojunctions Directly on Surfaces Aneta J. Mieszawska, Romaneh Jalilian, Gamini U. Sumanasekera, and Francis P. Zamborini pp 10822–10823 DOI: 10.1021/ja0521122 Supporting Info

Promotion of Proton Conduction in Polymer Electrolyte Membranes by 1H-1,2,3-Triazole Zhen Zhou, Siwen Li, Yuelan Zhang, Meilin Liu, and Wen Li pp 10824–10825 DOI: 10.1021/ja052280u Supporting Info

A Family of Microporous Materials Formed by Sn(IV) Phosphonate Nanoparticles Ayyappan Subbiah, David Pyle, Adam Rowland, Jin Huang, R. Aravinda Narayanan, P. Thiyagarajan, Jerzy Zoń, and Abraham Clearfield pp 10826–10827 DOI: 10.1021/ja052472p Supporting Info

The Burden Borne by Urease Brian P. Callahan, Yang Yuan, and Richard Wolfenden pp 10828–10829 DOI: 10.1021/ja0525399

A Chemical Model for Redox Regulation of Protein Tyrosine Phosphatase 1B (PTP1B) Activity Santhosh Sivaramakrishnan, Kripa Keerthi, and Kent S. Gates pp 10830–10831 DOI: 10.1021/ja052599e Supporting Info

Altering the Polymorphic Product Distribution in a Solid-State Dehydration Process by Rapid Sample Rotation in a Solid-State NMR Probe Mingcan Xu and Kenneth D. M. Harris pp 10832–10833 DOI: 10.1021/ja052668p

Intramolecular Diels−Alder Reactions of Optically Active Allenic Ketones:  Chirality Transfer in the Preparation of Substituted Oxa-Bridged Octalones Michael E. Jung and Sun-Joon Min pp 10834–10835 DOI: 10.1021/ja052771e Supporting Info

A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation Lei Shi, Yong-Qiang Tu, Min Wang, Fu-Min Zhang, Chun-An Fan, Yu-Ming Zhao, and Wu-Jiong Xia pp 10836–10837 DOI: 10.1021/ja0528331 Supporting Info

A Reversible Polymorphic Phase Change Which Affects the Luminescence and Aurophilic Interactions in the Gold(I) Cluster Complex, [μ3-S(AuCNC7H13)3](SbF6) Emily M. Gussenhoven, James C. Fettinger, David M. Pham, Mark M. Malwitz, and Alan L. Balch pp 10838–10839 DOI: 10.1021/ja052799q Supporting Info

Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, and David Milstein pp 10840–10841 DOI: 10.1021/ja052862b Supporting Info

Direct Monitoring of Metal Ion Transfer between Two Trafficking Proteins Richard Ledwidge, Rebecca Soinski, and Susan M. Miller pp 10842–10843 DOI: 10.1021/ja052872c Supporting Info

Strong, Low-Energy Two-Photon Absorption in Extended Amine-Terminated Cyano-Substituted Phenylenevinylene Oligomers Sung-Jae Chung, Mariacristina Rumi, Valérie Alain, Stephen Barlow, Joseph W. Perry, and Seth R. Marder pp 10844–10845 DOI: 10.1021/ja052926i Supporting Info

[(tBu2PCH2SiMe2)2N]RuCH3:  The Origin of Extremely Facile, Double H−C(sp3) Activation Generating a “Hydrido-Carbene” Complex Michael J. Ingleson, Xiaofan Yang, Maren Pink, and Kenneth G. Caulton pp 10846–10847 DOI: 10.1021/ja052973a Supporting Info

Multidimensional NMR Spectroscopy for Protein Characterization and Assignment inside Cells Patrick N. Reardon and Leonard D. Spicer pp 10848–10849 DOI: 10.1021/ja053145k

Asymmetric Synthesis of 3,3-Diarylpropanals with Chiral Diene−Rhodium Catalysts Jean-François Paquin, Christian Defieber, Corey R. J. Stephenson, and Erick M. Carreira pp 10850–10851 DOI: 10.1021/ja053270w Supporting Info

σ-Delocalization versus π-Resonance in α-Aryl-Substituted Vinyl Cations Thomas Müller, Dominik Margraf, and Yvonne Syha pp 10852–10860 DOI: 10.1021/ja0516864 Supporting Info

Oxidation of Methanol to Formaldehyde on Supported Vanadium Oxide Catalysts Compared to Gas Phase Molecules Jens Döbler, Marc Pritzsche, and Joachim Sauer pp 10861–10868 DOI: 10.1021/ja051720e Supporting Info

Cobalt Catalysts for the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide:  Combining High Activity and Selectivity Claire T. Cohen, Tony Chu, and Geoffrey W. Coates pp 10869–10878 DOI: 10.1021/ja051744l

Stereoselective C-Glycosylation Reactions of Ribose Derivatives:  Electronic Effects of Five-Membered Ring Oxocarbenium Ions Catharine H. Larsen, Brian H. Ridgway, Jared T. Shaw, Deborah M. Smith, and K. A. Woerpel pp 10879–10884 DOI: 10.1021/ja0524043 Supporting Info

A Simple Isomeric Separation of D5h and Ih Sc3N@C80 by Selective Chemical Oxidation Bevan Elliott, Lei Yu, and Luis Echegoyen pp 10885–10888 DOI: 10.1021/ja052446r Supporting Info

Coupled and Decoupled Dual Quantum Systems in One Semiconductor Nanocrystal David Battaglia, Bridgette Blackman, and Xiaogang Peng pp 10889–10897 DOI: 10.1021/ja0437297

B(C6F5)3- vs Al(C6F5)3-Derived Metallocenium Ion Pairs. Structural, Thermochemical, and Structural Dynamic Divergences Nicholas G. Stahl, Michael R. Salata, and Tobin J. Marks pp 10898–10909 DOI: 10.1021/ja0429622 Supporting Info

Specific Formation of Beads-on-a-Chain Structures on Giant DNA Using a Designed Polyamine Derivative Ning Chen, Anatoly A. Zinchenko, Shizuaki Murata, and Kenichi Yoshikawa pp 10910–10916 DOI: 10.1021/ja042509q Supporting Info

Nitrosonium-Catalyzed Decomposition of S-Nitrosothiols in Solution:  A Theoretical and Experimental Study Yi-Lei Zhao, Patrick R. McCarren, K. N. Houk, Bo Yoon Choi, and Eric J. Toone pp 10917–10924 DOI: 10.1021/ja050018f Supporting Info

The Hydrogen Chemistry of the FeMo-co Active Site of Nitrogenase Ian Dance pp 10925–10942 DOI: 10.1021/ja0504946 Supporting Info

UV−Resonance Raman Thermal Unfolding Study of Trp-Cage Shows That It Is Not a Simple Two-State Miniprotein Zeeshan Ahmed, Ilir A. Beta, Aleksandr V. Mikhonin, and Sanford A. Asher pp 10943–10950 DOI: 10.1021/ja050664e

Intense Fluorescence from Light-Driven Self-Assembled Aggregates of Nonionic Azobenzene Derivative Mina Han and Masahiko Hara pp 10951–10955 DOI: 10.1021/ja0509275

Toward an Easy Access to Dendrimer-like Poly(ethylene oxide)s Xiao-Shuang Feng, Daniel Taton, Elliot L. Chaikof, and Yves Gnanou pp 10956–10966 DOI: 10.1021/ja0509432

Development of a Quasi-Dynamic Pharmacophore Model for Anti-Complement Peptide Analogues Buddhadeb Mallik and Dimitrios Morikis pp 10967–10976 DOI: 10.1021/ja051004c Supporting Info

The Structure and the Large Nonlinear Optical Properties of Li@Calix[4]pyrrole Wei Chen, Zhi-Ru Li, Di Wu, Ying Li, Chia-Chung Sun, and Feng Long Gu pp 10977–10981 DOI: 10.1021/ja050601w Supporting Info

Pyrogenic Iron(III)-Doped TiO2 Nanopowders Synthesized in RF Thermal Plasma:  Phase Formation, Defect Structure, Band Gap, and Magnetic Properties X. H. Wang, J.-G. Li, H. Kamiyama, M. Katada, N. Ohashi, Y. Moriyoshi, and T. Ishigaki pp 10982–10990 DOI: 10.1021/ja051240n Supporting Info

Neutron Diffraction and Computer Simulation Studies of d-Xylose Philip E. Mason, George W. Neilson, John E. Enderby, Marie-Louise Saboungi, and John W. Brady pp 10991–10998 DOI: 10.1021/ja051376l

Folding a Nonbiological Polymer into a Compact Multihelical Structure Byoung-Chul Lee, Ronald N. Zuckermann, and Ken A. Dill pp 10999–11009 DOI: 10.1021/ja0514904 Supporting Info

Diferrous Cyanides as Models for the Fe-only Hydrogenases Christine A. Boyke, Jarl Ivar van der Vlugt, Thomas B. Rauchfuss, Scott R. Wilson, Giuseppe Zampella, and Luca De Gioia pp 11010–11018 DOI: 10.1021/ja051584d Supporting Info

QM/MM Study of the Role of the Solvent in the Formation of the Charge Separated Excited State in 9,9‘-Bianthryl Ferdinand C. Grozema, Marcel Swart, Robert W. J. Zijlstra, Jacob J. Piet, Laurens D. A. Siebbeles, and Piet Th. van Duijnen pp 11019–11028 DOI: 10.1021/ja051729g Supporting Info

Crystal Packing Mediates Enantioselective Ligand Recognition at the Peripheral Site of Acetylcholinesterase Haim Haviv, Dawn M. Wong, Harry M. Greenblatt, Paul R. Carlier, Yuan-Ping Pang, Israel Silman, and Joel L. Sussman pp 11029–11036 DOI: 10.1021/ja051765f Supporting Info

Discovery and Optimization of New Chromium Catalysts for Ethylene Oligomerization and Polymerization Aided by High-Throughput Screening David J. Jones, Vernon C. Gibson, Simon M. Green, Peter J. Maddox, Andrew J. P. White, and David J. Williams pp 11037–11046 DOI: 10.1021/ja0518171 Supporting Info

Tunable Command Layers for Liquid Crystal Alignment Johan Hoogboom, Paula M. L. Garcia, Matthijs B. J. Otten, Johannes A. A. W. Elemans, Joseph Sly, Sergiy V. Lazarenko, Theo Rasing, Alan E. Rowan, and Roeland J. M. Nolte pp 11047–11052 DOI: 10.1021/ja051865l Supporting Info

Atomistic-Scale Simulations of the Initial Chemical Events in the Thermal Initiation of Triacetonetriperoxide Adri C. T. van Duin, Yehuda Zeiri, Faina Dubnikova, Ronnie Kosloff, and William A. Goddard, III pp 11053–11062 DOI: 10.1021/ja052067y

Cooperative Hydrogen-Bonding Effects in a Water Square:  A Single-Crystal Neutron and Partial Atomic Charges and Hardness Analysis Study David R. Turner, Marc Henry, Clive Wilkinson, Garry J. McIntyre, Sax A. Mason, Andres E. Goeta, and Jonathan W. Steed pp 11063–11074 DOI: 10.1021/ja052081a Supporting Info

In Vitro Characterization of Salmochelin and Enterobactin Trilactone Hydrolases IroD, IroE, and Fes Hening Lin, Michael A. Fischbach, David R. Liu, and Christopher T. Walsh pp 11075–11084 DOI: 10.1021/ja0522027 Supporting Info

Odd−Even Behavior of Ferroelectricity and Antiferroelectricity in Two Homologous Series of Bent-Core Mesogens Seng Kue Lee, Sung Heo, Jong Gun Lee, Kyung-Tae Kang, Kazuya Kumazawa, Koushi Nishida, Yoshio Shimbo, Yoichi Takanishi, Junji Watanabe, Takayuki Doi, Takashi Takahashi, and Hideo Takezoe pp 11085–11091 DOI: 10.1021/ja052315q Supporting Info

Synthesis of MFe3S4 Clusters Containing a Planar MII Site (M = Ni, Pd, Pt), a Structural Element in the C-Cluster of Carbon Monoxide Dehydrogenase Rashmishree Panda, Curtis P. Berlinguette, Yugen Zhang, and Richard H. Holm pp 11092–11101 DOI: 10.1021/ja052381s Supporting Info

The Palladium-Catalyzed Cross-Coupling Reaction of Carboxylic Anhydrides with Arylboronic Acids:  A DFT Study Lukas J. Goossen, Debasis Koley, Holger L. Hermann, and Walter Thiel pp 11102–11114 DOI: 10.1021/ja052435y Supporting Info

“Knock-Out” Analogues as a Tool to Quantify Supramolecular Processes:  A Theoretical Study of Molecular Interactions in Guanidiniocarbonyl Pyrrole Carboxylate Dimers Sebastian Schlund, Carsten Schmuck, and Bernd Engels pp 11115–11124 DOI: 10.1021/ja052536w Supporting Info

Exploring Assembly Energetics of the 30S Ribosomal Subunit Using an Implicit Solvent Approach Joanna Trylska, J. Andrew McCammon, and Charles L. Brooks III pp 11125–11133 DOI: 10.1021/ja052639e

Hierarchical Organization of Photoresponsive Hydrogen-Bonded Rosettes Shiki Yagai, Toshiharu Nakajima, Keiki Kishikawa, Shigeo Kohmoto, Takashi Karatsu, and Akihide Kitamura pp 11134–11139 DOI: 10.1021/ja052645a Supporting Info

Structural Models and Atomic Distribution of Bimetallic Nanoparticles as Investigated by X-ray Absorption Spectroscopy Bing-Joe Hwang, Loka Subramanyam Sarma, Jiun-Ming Chen, Ching-Hsiang Chen, Shou-Chu Shih, Guo-Rung Wang, Din-Goa Liu, Jyh-Fu Lee, and Mau-Tsu Tang pp 11140–11145 DOI: 10.1021/ja0526618 Supporting Info

Chemical and Electrochemical Reduction of Polyarene Manganese Tricarbonyl Cations:  Hapticity Changes and Generation of Syn- and Anti-Facial Bimetallic η4,η6-Naphthalene Complexes Jeffrey A. Reingold, Kurtis L. Virkaitis, Gene B. Carpenter, Shouheng Sun, Dwight A. Sweigart, Paul T. Czech, and Kenneth R. Overly pp 11146–11158 DOI: 10.1021/ja0527370 Supporting Info

Total Synthesis of Thiostrepton. Retrosynthetic Analysis and Construction of Key Building Blocks K. C. Nicolaou, Brian S. Safina, Mark Zak, Sang Hyup Lee, Marta Nevalainen, Marco Bella, Anthony A. Estrada, Christian Funke, Frédéric J. Zécri, and Stephan Bulat pp 11159–11175 DOI: 10.1021/ja0529337 Supporting Info

Total Synthesis of Thiostrepton. Assembly of Key Building Blocks and Completion of the Synthesis K. C. Nicolaou, Mark Zak, Brian S. Safina, Anthony A. Estrada, Sang Hyup Lee, and Marta Nevalainen pp 11176–11183 DOI: 10.1021/ja052934z Supporting Info

Hydride-Alkenylcarbyne to Alkenylcarbene Transformation in Bisphosphine-Osmium Complexes Tamara Bolaño, Ricardo Castarlenas, Miguel A. Esteruelas, F. Javier Modrego, and Enrique Oñate pp 11184–11195 DOI: 10.1021/ja053186g Supporting Info

A Strain-Promoted [3 + 2] Azide−Alkyne Cycloaddition for Covalent Modification of Biomolecules in Living Systems [J. Am. Chem. Soc. 2004, 126, 15046−15047]. Nicholas J. Agard, Jennifer A. Prescher, and Carolyn R. Bertozzi p 11196 DOI: 10.1021/ja059912x

Natural Product Synthesis I:  Target, Methods, Concepts. Topics in Current Chemistry, 243 Edited by Johann Mulzer (Universität Wien). Springer-Verlag:  Berlin, Heidelberg. 2005. x + 240 pp. $209.00. ISBN 3-540-21125-X. Philip Magnus p 11197 DOI: 10.1021/ja059717i

Geometric Structures of Phase Space in Multi-Dimensional Chaos:  Applications to Chemical Reaction Dynamics in Complex Systems, Parts A and B. Advances in Chemical Physics, Volume 130 Edited by Mikito Toda (Nara Women's University, Nara, Japan), Tamiki Komatsuzaki (Kobe University, Kobe, Japan), Tetsuro Konishi (Nagoya University, Nagoya, Japan), R. Steven Berry, and Stuart A. Rice (University of Chicago). Series edited by Stuart A. Rice. John Wiley & Sons:  Hoboken, NJ. 2005. xxvi + 542 pp (Part A) and xxvi + 682 pp (Part B). $350.00 (set). ISBN 0-471-71158-6 (set). p 11197 DOI: 10.1021/ja059726r

Protein Folding Handbook, Volumes 1−5 Edited by Johannes Buchner (Technische Universität München) and Thomas Kiefhaber (Biozentrum der Universität Basel). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. 2560 pp. $1300. ISBN 3-527-30784-2. p 11197 DOI: 10.1021/ja059738c

Seminars in Organic Synthesis:  XXIX Summer School “A. Corbella”, June 14−18, 2004, Palazzo Feltrinelli, Università degli Studi di Milano, Gargnano (BS) Committee Chairman, Franco Sannicolo‘ (Università di Milano). Società Chimica Italiana:  Rome. 2004. ii + 422 pp. $199.00. ISBN 88-86208-25-1. p 11197 DOI: 10.1021/ja059754+

Studies in Natural Products Chemistry, Volume 30:  Bioactive Natural Products (Part K) Edited by Atta-ur-Rahman (University of Karachi, Pakistan). Elsevier B.V.:  Amsterdam. 2005. xiv + 964 pp. $506.00. ISBN 0-444-51854-1. pp 11197–11198 DOI: 10.1021/ja0597348

Van Nostrand's Encyclopedia of Chemistry Edited by Glenn D. Considine (Editor-in-Chief), Greg Gallagher (Associate Editor), and Peter H. Kulik (Associate Editor). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xviii + 1832 pp. $195.95. ISBN 0-471-61525-0. p 11198 DOI: 10.1021/ja059722m

Issue 32

Direct Probe of Iron Vibrations Elucidates NO Activation of Heme Proteins Weiqiao Zeng, Nathan J. Silvernail, David C. Wharton, Georgi Y. Georgiev, Bogdan M. Leu, W. Robert Scheidt, Jiyong Zhao, Wolfgang Sturhahn, E. Ercan Alp, and J. Timothy Sage pp 11200–11201 DOI: 10.1021/ja051052x Supporting Info

Stereochemical Assignment of Intermediates in the Rifamycin Biosynthetic Pathway by Precursor-Directed Biosynthesis Ingo V. Hartung, Mathew A. Rude, Nathan A. Schnarr, Daniel Hunziker, and Chaitan Khosla pp 11202–11203 DOI: 10.1021/ja051430y Supporting Info

CO2 as a Supramolecular Assembly Agent: A Route for Lamellar Materials with a High Content of Amine Groups Johan Alauzun, Ahmad Mehdi, Catherine Reyé, and Robert J. P. Corriu pp 11204–11205 DOI: 10.1021/ja051518b Supporting Info

Versatile Diastereoselectivity in Formal [3,3]-Sigmatropic Shifts of Substituted 1-Alkenyl-3-alkylidenecyclobutanols and Their Silyl Ethers Michael E. Jung, Nobuko Nishimura, and Aaron R. Novack pp 11206–11207 DOI: 10.1021/ja051663p Supporting Info

Characterization of Dynamics of Perdeuterated Proteins by MAS Solid-State NMR Maggy Hologne, Katja Faelber, Anne Diehl, and Bernd Reif pp 11208–11209 DOI: 10.1021/ja051830l

Replication of a DNA Microarray Haohao Lin, Li Sun, and Richard M. Crooks pp 11210–11211 DOI: 10.1021/ja051914u Supporting Info

Redox Couples of Inducible Nitric Oxide Synthase Andrew K. Udit, Wendy Belliston-Bittner, Edith C. Glazer, Yen Hoang Le Nguyen, James M. Gillan, Michael G. Hill, Michael A. Marletta, David B. Goodin, and Harry B. Gray pp 11212–11213 DOI: 10.1021/ja0520114 Supporting Info

Excited-State Structure Determination of the Green Fluorescent Protein Chromophore Anwar Usman, Omar F. Mohammed, Erik T. J. Nibbering, Jian Dong, Kyril M. Solntsev, and Laren M. Tolbert pp 11214–11215 DOI: 10.1021/ja0520520 Supporting Info

DNA-Templated Photoinduced Silver Deposition Lorenzo Berti, Andrea Alessandrini, and Paolo Facci pp 11216–11217 DOI: 10.1021/ja052461w Supporting Info

Ti(IV) Binds to Human Serum Transferrin More Tightly Than Does Fe(III) Arthur D. Tinoco and Ann M. Valentine pp 11218–11219 DOI: 10.1021/ja052768v Supporting Info

Time-Resolved Detection of Melanin Free Radicals Quenching Reactive Oxygen Species Brandon-Luke L. Seagle, Kourous A. Rezai, Elzbieta M. Gasyna, Yasuhiro Kobori, Kasra A. Rezaei, and James R. Norris, Jr. pp 11220–11221 DOI: 10.1021/ja052773z Supporting Info

A Deep Cavitand Provides a Structured Environment for the Menschutkin Reaction Byron W. Purse, Arnaud Gissot, and Julius Rebek, Jr. pp 11222–11223 DOI: 10.1021/ja052877+ Supporting Info

Selection of Smart Aptamers by Equilibrium Capillary Electrophoresis of Equilibrium Mixtures (ECEEM) Andrei Drabovich, Maxim Berezovski, and Sergey N. Krylov pp 11224–11225 DOI: 10.1021/ja0530016 Supporting Info

Computational Study of Phosphatase Activity in Soluble Epoxide Hydrolase:  High Efficiency through a Water Bridge Mediated Proton Shuttle Marco De Vivo, Bernd Ensing, and Michael L. Klein pp 11226–11227 DOI: 10.1021/ja053049j Supporting Info

Self-Cleavable Stimulus Responsive Tags for Protein Purification without Chromatography Xin Ge, Daniel S. C. Yang, Kimberly Trabbic-Carlson, Bumjoon Kim, Ashutosh Chilkoti, and Carlos D. M. Filipe pp 11228–11229 DOI: 10.1021/ja0531125 Supporting Info

Force Spectroscopy of Quadruple H-Bonded Dimers by AFM:  Dynamic Bond Rupture and Molecular Time−Temperature Superposition Shan Zou, Holger Schönherr, and G. Julius Vancso pp 11230–11231 DOI: 10.1021/ja0531475 Supporting Info

Selective Recovery of Dynamic Guest Structure in a Nanoporous Prussian Blue through in Situ X-ray Diffraction:  A Differential Pair Distribution Function Analysis Karena W. Chapman, Peter J. Chupas, and Cameron J. Kepert pp 11232–11233 DOI: 10.1021/ja053266k Supporting Info

In Vivo Reporter Labeling of Proteins via Metabolic Delivery of Coenzyme A Analogues Kristine M. Clarke, Andrew C. Mercer, James J. La Clair, and Michael D. Burkart pp 11234–11235 DOI: 10.1021/ja052911k Supporting Info

Insulator−Metal Transition of Intrinsic Diamond Dongchan Shin, Hideyuki Watanabe, and Christoph E. Nebel pp 11236–11237 DOI: 10.1021/ja052834t

Unusual, Promoted Release of Guests from Amphiphilic Cross-Linked Polymer Networks Gerald O. Brown, Catherine Bergquist, Paul Ferm, and Karen L. Wooley pp 11238–11239 DOI: 10.1021/ja0534405 Supporting Info

Cyanuric Chloride as a Mild and Active Beckmann Rearrangement Catalyst Yoshiro Furuya, Kazuaki Ishihara, and Hisashi Yamamoto pp 11240–11241 DOI: 10.1021/ja053441x Supporting Info

Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex Ingrid Castro-Rodriguez and Karsten Meyer pp 11242–11243 DOI: 10.1021/ja053497r Supporting Info

Kinetic Resolutions of Azomethine Imines via Copper-Catalyzed [3 + 2] Cycloadditions Andrés Suárez, C. Wade Downey, and Gregory C. Fu pp 11244–11245 DOI: 10.1021/ja052876h Supporting Info

Sterically Congested in-Methylcyclophanes Qiuling Song, Douglas M. Ho, and Robert A. Pascal, Jr. pp 11246–11247 DOI: 10.1021/ja0529384 Supporting Info

A Terminal Ni(III)−Imide with Diverse Reactivity Pathways Elzbieta Kogut, Heather L. Wiencko, Libei Zhang, Douglas E. Cordeau, and Timothy H. Warren pp 11248–11249 DOI: 10.1021/ja0533186 Supporting Info

Copper(II) Acetate Promoted Intramolecular Diamination of Unactivated Olefins Thomas P. Zabawa, Dhanalakshmi Kasi, and Sherry R. Chemler pp 11250–11251 DOI: 10.1021/ja053335v Supporting Info

Catalytic Enantioselective Desymmetrization of meso-N-Acylaziridines with TMSCN Tsuyoshi Mita, Ikuo Fujimori, Reiko Wada, Jianfeng Wen, Motomu Kanai, and Masakatsu Shibasaki pp 11252–11253 DOI: 10.1021/ja053486y Supporting Info

Synthesis and Complete Stereochemical Assignment of Psymberin/Irciniastatin A Xin Jiang, Jorge García-Fortanet, and Jef K. De Brabander pp 11254–11255 DOI: 10.1021/ja0537068 Supporting Info

Asymmetric Mannich Reactions of β-Keto Esters with Acyl Imines Catalyzed by Cinchona Alkaloids Sha Lou, Brandon M. Taoka, Amal Ting, and Scott E. Schaus pp 11256–11257 DOI: 10.1021/ja0537373 Supporting Info

Synthesis of Substituted Oxa- and Aza[3.2.1] and [4.3.1]Bicyclics via an Unprecedented Molybdenum-Mediated 1,5-“Michael-Type” Reaction Yongqiang Zhang and Lanny S. Liebeskind pp 11258–11259 DOI: 10.1021/ja0538132 Supporting Info

Gold(I)-Catalyzed Intramolecular Acetylenic Schmidt Reaction David J. Gorin, Nicole R. Davis, and F. Dean Toste pp 11260–11261 DOI: 10.1021/ja053804t Supporting Info

Surface-Enhanced Raman Scattering and Polarized Photoluminescence from Catalytically Grown CdSe Nanobelts and Sheets Rayapati Venugopal, Ping-I Lin, Chung-Chan Liu, and Yit-Tsong Chen pp 11262–11268 DOI: 10.1021/ja044270j Supporting Info

Hydrogen-Mediated Reductive Coupling of Conjugated Alkynes with Ethyl (N-Sulfinyl)iminoacetates:  Synthesis of Unnatural α-Amino Acids via Rhodium-Catalyzed C−C Bond Forming Hydrogenation Jong-Rock Kong, Chang-Woo Cho, and Michael J. Krische pp 11269–11276 DOI: 10.1021/ja051104i Supporting Info

Endohedral Chemistry of C60-Based Fullerene Cages Yun Hang Hu and Eli Ruckenstein pp 11277–11282 DOI: 10.1021/ja043403y

Spontaneous “Phase Separation” of Patterned Binary Alkanethiol Mixtures Khalid Salaita, Anand Amarnath, Daniel Maspoch, Thomas B. Higgins, and Chad A. Mirkin pp 11283–11287 DOI: 10.1021/ja042393y Supporting Info

Structure of Zone-Cast HBC−C12H25 Films Dag W. Breiby, Oliver Bunk, Wojciech Pisula, Theis I. Sølling, Adam Tracz, Tadeusz Pakula, Klaus Müllen, and Martin M. Nielsen pp 11288–11293 DOI: 10.1021/ja042355e Supporting Info

Theoretical Studies of Stereoselectivities of Intramolecular Aldol Cyclizations Catalyzed by Amino Acids Fernando R. Clemente and K. N. Houk pp 11294–11302 DOI: 10.1021/ja0507620 Supporting Info

Generalized Mulliken−Hush Analysis of Electronic Coupling Interactions in Compressed π-Stacked Porphyrin−Bridge−Quinone Systems Jieru Zheng, Youn K. Kang, Michael J. Therien, and David N. Beratan pp 11303–11310 DOI: 10.1021/ja050984y Supporting Info

Quantum Tunneling and Quantum Phase Interference in a [MnII2MnIII2] Single-Molecule Magnet Lollita Lecren, Wolfgang Wernsdorfer, Yang-Guang Li, Olivier Roubeau, Hitoshi Miyasaka, and Rodolphe Clérac pp 11311–11317 DOI: 10.1021/ja050994z Supporting Info

Doping of Polyaniline by Acid−Base Chemistry:  Density Functional Calculations with Periodic Boundary Conditions Adrián Varela-Álvarez, José A. Sordo, and Gustavo E. Scuseria pp 11318–11327 DOI: 10.1021/ja051012t Supporting Info

Quantum Dot-Conjugated Hybridization Probes for Preliminary Screening of siRNA Sequences Rumiana Bakalova, Zhivko Zhelev, Hideki Ohba, and Yoshinobu Baba pp 11328–11335 DOI: 10.1021/ja051089h

Differential Effects of the Zn−His−Bkb vs Zn−His−[Asp/Glu] Triad on Zn-Core Stability and Reactivity Yen-lin Lin, Yu-ming Lee, and Carmay Lim pp 11336–11347 DOI: 10.1021/ja051304u Supporting Info

Boolean Control of Aptamer Binding States Dmitry M. Kolpashchikov and Milan N. Stojanovic pp 11348–11351 DOI: 10.1021/ja051362f Supporting Info

Dendrimers Made of Porphyrin Cores and Carbazole Chromophores as Peripheral Units. Absorption Spectra, Luminescence Properties, and Oxidation Behavior Frédérique Loiseau, Sebastiano Campagna, Ahmed Hameurlaine, and Wim Dehaen pp 11352–11363 DOI: 10.1021/ja0514444 Supporting Info

Folate-Receptor-Mediated Delivery of InP Quantum Dots for Bioimaging Using Confocal and Two-Photon Microscopy Dhruba J. Bharali, Derrick W. Lucey, Harishankar Jayakumar, Haridas E. Pudavar, and Paras N. Prasad pp 11364–11371 DOI: 10.1021/ja051455x Supporting Info

Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes:  C−H Activation Studies with Benzene Gaurav Bhalla, Xiang Yang Liu, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana pp 11372–11389 DOI: 10.1021/ja051532o Supporting Info

Single Polymer Chains as Specific Transducers of Molecular Recognition in Scanning Probe Microscopy Rachel Gabai, Lior Segev, and Ernesto Joselevich pp 11390–11398 DOI: 10.1021/ja051642v Supporting Info

Where Is the Spin? Understanding Electronic Structure and g-Tensors for Ruthenium Complexes with Redox-Active Quinonoid Ligands Christian Remenyi and Martin Kaupp pp 11399–11413 DOI: 10.1021/ja051811b Supporting Info

Hydrogen Bonding and Cooperativity in Isolated and Hydrated Sugars:  Mannose, Galactose, Glucose, and Lactose Pierre Çarçabal, Rebecca A. Jockusch, Isabel Hünig, Lavina C. Snoek, Romano T. Kroemer, Benjamin G. Davis, David P. Gamblin, Isabelle Compagnon, Jos Oomens, and John P. Simons pp 11414–11425 DOI: 10.1021/ja0518575 Supporting Info

Chromium(III) Octaethylporphyrinato Tetracarbonylcobaltate:  A Highly Active, Selective, and Versatile Catalyst for Epoxide Carbonylation Joseph A. R. Schmidt, Emil B. Lobkovsky, and Geoffrey W. Coates pp 11426–11435 DOI: 10.1021/ja051874u Supporting Info

Monomolecular DNA Nanoparticles for Intravenous Delivery of Genes Chandrashekhar Chittimalla, Liliane Zammut-Italiano, Guy Zuber, and Jean-Paul Behr pp 11436–11441 DOI: 10.1021/ja0522332

Fine Tuning the Anion Binding Properties of 2,6-Diamidopyridine Dipyrromethane Hybrid Macrocycles Jonathan L. Sessler, Evgeny Katayev, G. Dan Pantos, Pavel Scherbakov, Marina D. Reshetova, Victor N. Khrustalev, Vincent M. Lynch, and Yuri A. Ustynyuk pp 11442–11446 DOI: 10.1021/ja0522938 Supporting Info

Kinetics of the Interconversion of Parahydrogen and Orthohydrogen Catalyzed by Paramagnetic Complex Ions Mitsuru Matsumoto and James H. Espenson pp 11447–11453 DOI: 10.1021/ja0524292 Supporting Info

Water Production Reaction on Rh(110) Cristina Africh, Haiping Lin, Martina Corso, Friedrich Esch, Renzo Rosei, Werner A. Hofer, and Giovanni Comelli pp 11454–11459 DOI: 10.1021/ja0524301

Electronically Selective Chemical Functionalization of Carbon Nanotubes:  Correlation between Raman Spectral and Electrical Responses Congjun Wang, Qing Cao, Taner Ozel, Anshu Gaur, John A. Rogers, and Moonsub Shim pp 11460–11468 DOI: 10.1021/ja0526564

A Quantitative Model Describing the Selective Solubilization of Membrane Domains Sandro Keller, Alekos Tsamaloukas, and Heiko Heerklotz pp 11469–11476 DOI: 10.1021/ja052764q Supporting Info

Glutathione Peroxidase (GPx)-like Antioxidant Activity of the Organoselenium Drug Ebselen:  Unexpected Complications with Thiol Exchange Reactions Bani Kanta Sarma and G. Mugesh pp 11477–11485 DOI: 10.1021/ja052794t Supporting Info

Charge Propagation in “Ion Channel Sensors” Based on Protein-Modified Electrodes and Redox Marker Ions Peter Schön, Tesfaye Hailu Degefa, Simona Asaftei, Wolfdietrich Meyer, and Lorenz Walder pp 11486–11496 DOI: 10.1021/ja051574c Supporting Info

Variable-Temperature 19F NMR and Theoretical Study of 1,9- and 1,7-C60F(CF3) and Cs- and C1-C60F17(CF3):  Hindered CF3 Rotation and Through-Space JFF Coupling Ivan E. Kareev, Gustavo Santiso Quiñones, Igor V. Kuvychko, Pavel A. Khavrel, Ilya N. Ioffe, Ilya V. Goldt, Sergey F. Lebedkin, Konrad Seppelt, Steven H. Strauss, and Olga V. Boltalina pp 11497–11504 DOI: 10.1021/ja051954y Supporting Info

Total Synthesis of (−)-Spirotryprostatin B:  Synthesis and Related Studies Christiane Marti and Erick M. Carreira pp 11505–11515 DOI: 10.1021/ja0518880 Supporting Info

Use of Parallel Synthesis To Probe Structure−Activity Relationships among 12-Helical β-Peptides:  Evidence of a Limit on Antimicrobial Activity Emilie A. Porter, Bernard Weisblum, and Samuel H. Gellman pp 11516–11529 DOI: 10.1021/ja0519785 Supporting Info

NMR, 3D Analysis, Photopolymerization. Advances in Polymer Science, 170 With contributions by Rainer Kimmich (Universität Ulm), Nail Fatkullin (Kazan State University), Hiroshi Jinnai, Yukihiro Nishikawa (Kyoto Institute of Technology), Takayuki Ikehara (Kanagawa University), Toshio Nishi (Tokyo Institute of Technology), Hong-Bo Sun, and Satoshi Kawata (Osaka University). Springer-Verlag:  Berlin, Heidelberg. 2004. x + 294 pp. $199.00. ISBN 3-540-20510-1. Michael D. Meadows p 11530 DOI: 10.1021/ja041007+

Handbook of Layered Materials Edited by Scott M. Auerbach (University of Massachusetts, Amherst), Kathleen A. Carrado (Argonne National Laboratory), and Prabir K. Dutta (The Ohio State University). Marcel Dekker, Inc.:  New York, Basel. 2004. xii + 646 pp. $195.00. ISBN 0-8247-5349-6. Jack W. Johnson pp 11530–11531 DOI: 10.1021/ja041020u

Synthetic Organic Photochemistry. Molecular and Supramolecular Photochemistry, Volume 12 Edited by Axel G. Griesbeck (Universität zu Köln, Germany) and Jochen Mattay (Universität Bielefeld, Germany). Series edited by V. Ramamurthy and K. S. Schanze. Marcel Dekker:  New York. 2005. x + 630 pp. $199.95. ISBN 0-8247-5736-X. Frank B. Mallory p 11531 DOI: 10.1021/ja0410441

Transition Metal and Rare Earth Compounds III:  Excited States, Transitions, Interactions. Topics in Current Chemistry 241 Edited by Hartmut Yersin (Universität Regensberg). Springer-Verlag:  Berlin, Heidelberg. 2004. xii + 294 pp. $299.00. ISBN 3-540-20948-4. Alistair J. Lees pp 11531–11532 DOI: 10.1021/ja059707h

Issue 33

Properties of the Emitting State of the Green Fluorescent Protein Resolved at the CASPT2//CASSCF/CHARMM Level Adalgisa Sinicropi, Tadeusz Andruniow, Nicolas Ferré, Riccardo Basosi, and Massimo Olivucci pp 11534–11535 DOI: 10.1021/ja045269n Supporting Info

Hydrogen-Bonded Anionic Rosette Networks Assembled with Guanidinium and C3-Symmetric Oxoanion Building Blocks Chi-Keung Lam, Feng Xue, Jie-Peng Zhang, Xiao-Ming Chen, and Thomas C. W. Mak pp 11536–11537 DOI: 10.1021/ja050221a Supporting Info

Designing Interfaces That Function to Facilitate Charge Injection in Organic Light-Emitting Diodes Shinji Kato pp 11538–11539 DOI: 10.1021/ja052170n Supporting Info

NMR Heteronuclear Correlation between Quadrupolar Nuclei in Solids Dinu Iuga, Claudia Morais, Zhehong Gan, Daniel R. Neuville, Laurent Cormier, and Dominique Massiot pp 11540–11541 DOI: 10.1021/ja052452n Supporting Info

Conducting AFM and 2D GIXD Studies on Pentacene Thin Films Hoichang Yang, Tae Joo Shin, Mang-Mang Ling, Kilwon Cho, Chang Y. Ryu, and Zhenan Bao pp 11542–11543 DOI: 10.1021/ja052478e Supporting Info

Dynamic and Fluorescent Nanoscale Phenanthroline/Terpyridine Zinc(II) Ladders. Self-Recognition in Unlike Ligand/Like Metal Coordination Scenarios Michael Schmittel, Venkateshwarlu Kalsani, Ravuri S. K. Kishore, Helmut Cölfen, and Jan W. Bats pp 11544–11545 DOI: 10.1021/ja0525096 Supporting Info

Measured Depletion of Ions at the Biomembrane Interface Horia I. Petrache, Itamar Kimchi, Daniel Harries, and V. Adrian Parsegian pp 11546–11547 DOI: 10.1021/ja052549+

A Colorimetric Sensor Array for Organics in Water Chen Zhang and Kenneth S. Suslick pp 11548–11549 DOI: 10.1021/ja052606z Supporting Info

Octahedral Non-Heme Non-Oxo Fe(IV) Species Stabilized by a Redox-Innocent N-Methylated Cyclam−Acetate Ligand John F. Berry, Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, and Karl Wieghardt pp 11550–11551 DOI: 10.1021/ja052673t Supporting Info

Dual Modulation of a Molecular Switch with Exceptional Chiroptical Properties Zhi Yuan Wang, Erin K. Todd, Xian Sheng Meng, and Jian Ping Gao pp 11552–11553 DOI: 10.1021/ja0526721 Supporting Info

Carbon Nanotube Graphoepitaxy:  Highly Oriented Growth by Faceted Nanosteps Ariel Ismach, David Kantorovich, and Ernesto Joselevich pp 11554–11555 DOI: 10.1021/ja052759m Supporting Info

Alternating Hydrophilic and Hydrophobic Pockets in the Channel Structures of Organostannoxane Prismanes:  Preferential Confinement of Guest Molecules Vadapalli Chandrasekhar, Pakkirisamy Thilagar, James F. Bickley, and Alexander Steiner pp 11556–11557 DOI: 10.1021/ja052776b Supporting Info

Ribose 2‘-F Labeling:  A Simple Tool for the Characterization of RNA Secondary Structure Equilibria by 19F NMR Spectroscopy Christoph Kreutz, Hanspeter Kählig, Robert Konrat, and Ronald Micura pp 11558–11559 DOI: 10.1021/ja052844u Supporting Info

Synthesis and Structure of the Bidimensional Zeolite ITQ-32 with Small and Large Pores Angel Cantín, Avelino Corma, Sandra Leiva, Fernando Rey, Jordi Rius, and Susana Valencia pp 11560–11561 DOI: 10.1021/ja053040h Supporting Info

Filtered Backprojection for the Reconstruction of a High-Resolution (4,2)D CH3−NH NOESY Spectrum on a 29 kDa Protein Brian E. Coggins, Ronald A. Venters, and Pei Zhou pp 11562–11563 DOI: 10.1021/ja053110k Supporting Info

Phosphorescent Excited State of [Au2{(Ph2Sb)2O}3]2+:  Jahn−Teller Distortion at Only One Gold(I) Center Vilma R. Bojan, Eduardo J. Fernández, Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, M. Elena Olmos, and Cristian Silvestru pp 11564–11565 DOI: 10.1021/ja053237+ Supporting Info

A Highly Active, Isospecific Cobalt Catalyst for Propylene Oxide Polymerization Kathryn L. Peretti, Hiroharu Ajiro, Claire T. Cohen, Emil B. Lobkovsky, and Geoffrey W. Coates pp 11566–11567 DOI: 10.1021/ja053451y Supporting Info

G-Quartet-Induced Nanoparticle Assembly Zhi Li and Chad A. Mirkin pp 11568–11569 DOI: 10.1021/ja053547s

Side-Chain Chiral Centers of Amino Acid and Helical-Screw Handedness of Its Peptides Masakazu Tanaka, Kosuke Anan, Yosuke Demizu, Masaaki Kurihara, Mitsunobu Doi, and Hiroshi Suemune pp 11570–11571 DOI: 10.1021/ja053842c Supporting Info

B-Allyl-10-Ph-9-borabicyclo[3.3.2]decanes:  Strategically Designed for the Asymmetric Allylboration of Ketones Eda Canales, K. Ganeshwar Prasad, and John A. Soderquist pp 11572–11573 DOI: 10.1021/ja053865r Supporting Info

Bioelectrochemical Propulsion Nicolas Mano and Adam Heller pp 11574–11575 DOI: 10.1021/ja053937e Supporting Info

Ferrocene-Containing Cationic Lipids: Influence of Redox State on Cell Transfection Nicholas L. Abbott, Christopher M. Jewell, Melissa E. Hays, Yukishige Kondo, and David M. Lynn pp 11576–11577 DOI: 10.1021/ja054038t Supporting Info

Organic−Inorganic Hybrid Liquid Crystals:  Thermotropic Mesophases Formed by Hybridization of Liquid-Crystalline Phosphates and Monodispersed α-Fe2O3 Particles Kiyoshi Kanie and Atsushi Muramatsu pp 11578–11579 DOI: 10.1021/ja054232f Supporting Info

Structural Elucidation of Sumanene and Generation of Its Benzylic Anions Hidehiro Sakurai, Taro Daiko, Hiroyuki Sakane, Toru Amaya, and Toshikazu Hirao pp 11580–11581 DOI: 10.1021/ja0518169 Supporting Info

An Opened Route to 1,3-Dimethylenecyclobutanes via Sequential Ruthenium-Catalyzed [2 + 2] Cycloaddition of Allenyl Boronate and Palladium Suzuki Coupling Emilio Bustelo, Carine Guérot, Alain Hercouet, Bertrand Carboni, Loïc Toupet, and Pierre H. Dixneuf pp 11582–11583 DOI: 10.1021/ja051930r Supporting Info

Synthesis and Characterization of Single-Crystalline Alkali Titanate Nanowires Cheng-Yan Xu, Qi Zhang, Han Zhang, Liang Zhen, Jie Tang, and Lu-Chang Qin pp 11584–11585 DOI: 10.1021/ja0519841

Catalytic Asymmetric Staudinger Reactions to Form β-Lactams:  An Unanticipated Dependence of Diastereoselectivity on the Choice of the Nitrogen Substituent Elaine C. Lee, Brian L. Hodous, Enda Bergin, Crystal Shih, and Gregory C. Fu pp 11586–11587 DOI: 10.1021/ja052058p Supporting Info

Semisynthetic Tellurosubtilisin with Glutathione Peroxidase Activity Shizhong Mao, Zeyuan Dong, Junqiu Liu, Xiangqiu Li, Xiaoman Liu, Guimin Luo, and Jiacong Shen pp 11588–11589 DOI: 10.1021/ja052451v Supporting Info

Characterization of Reactive Sites in Supported Catalysts by 51V/15N Rotational Echo Double Resonance NMR Spectroscopy:  Formation of Phenylimido Groups at Surface-Bound Oxovanadium Sites Carole Brown, Randall Achey, Riqiang Fu, Thomas Gedris, and A. E. Stiegman pp 11590–11591 DOI: 10.1021/ja052579c Supporting Info

Dual Lewis Acid−Lewis Base Activation in Enantioselective Cyanation of Aldehydes Using Acetyl Cyanide and Cyanoformate as Cyanide Sources Stina Lundgren, Erica Wingstrand, Maël Penhoat, and Christina Moberg pp 11592–11593 DOI: 10.1021/ja052804q Supporting Info

Biosynthesis of the β-Amino Acid Moiety of the Enediyne Antitumor Antibiotic C-1027 Featuring β-Amino Acyl-S-carrier Protein Intermediates Steven G. Van Lanen, Pieter C. Dorrestein, Steve D. Christenson, Wen Liu, Jianhua Ju, Neil L. Kelleher, and Ben Shen pp 11594–11595 DOI: 10.1021/ja052871k Supporting Info

Preparation of Iron Amido Complexes via Putative Fe(IV) Imido Intermediates Robie L. Lucas, Douglas R. Powell, and A. S. Borovik pp 11596–11597 DOI: 10.1021/ja052952g Supporting Info

Enantioselective Organocatalytic Michael Additions of Aldehydes to Enones with Imidazolidinones:  Cocatalyst Effects and Evidence for an Enamine Intermediate Timothy J. Peelen, Yonggui Chi, and Samuel H. Gellman pp 11598–11599 DOI: 10.1021/ja0532584 Supporting Info

Unexpected Si:Al Effect on the Binary Mixtures Liquid Phase Adsorption Selectivities in Faujasite Zeolites Inge Daems, Alain Méthivier, Philibert Leflaive, Alain H. Fuchs, Gino V. Baron, and Joeri F. M. Denayer pp 11600–11601 DOI: 10.1021/ja053375z

Reconstitution of a New Cysteine Biosynthetic Pathway in Mycobacterium tuberculosis Kristin E. Burns, Sabine Baumgart, Pieter C. Dorrestein, Huili Zhai, Fred W. McLafferty, and Tadhg P. Begley pp 11602–11603 DOI: 10.1021/ja053476x Supporting Info

Nonlinear Magnetooptical Effects Caused by Piezoelectric Ferromagnetism in F3m-type Prussian Blue Analogues Tomohiro Nuida, Tomoyuki Matsuda, Hiroko Tokoro, Shunsuke Sakurai, Kazuhito Hashimoto, and Shin-ichi Ohkoshi pp 11604–11605 DOI: 10.1021/ja0535662 Supporting Info

Ruthenium-Catalyzed Cycloisomerization of cis-3-En-1-ynes to Cyclopentadiene and Related Derivatives through a 1,5-Sigmatropic Hydrogen Shift of Ruthenium−Vinylidene Intermediates Swarup Datta, Arjan Odedra, and Rai-Shung Liu pp 11606–11607 DOI: 10.1021/ja053674o Supporting Info

Core-Modified Expanded Porphyrins with Large Third-Order Nonlinear Optical Response Harapriya Rath, Jeyaraman Sankar, Viswanathan PrabhuRaja, Tavarekere K. Chandrashekar, Amit Nag, and Debabrata Goswami pp 11608–11609 DOI: 10.1021/ja0537575 Supporting Info

Radical Hydroxyalkylation of C−H Bond Adjacent to Nitrogen of Tertiary Amides, Ureas, and Amines Takehiko Yoshimitsu, Yoshimasa Arano, and Hiroto Nagaoka pp 11610–11611 DOI: 10.1021/ja053855q Supporting Info

The Activity of Escherichia coli Cyclopropane Fatty Acid Synthase Depends on the Presence of Bicarbonate David F. Iwig, Akira Uchida, Jeffrey A. Stromberg, and Squire J. Booker pp 11612–11613 DOI: 10.1021/ja053899z Supporting Info

Enantioselective Organocatalytic Allylic Amination Thomas B. Poulsen, Carlos Alemparte, and Karl Anker Jørgensen pp 11614–11615 DOI: 10.1021/ja0539847 Supporting Info

Enantioselective Organocatalytic Intramolecular Diels−Alder Reactions. The Asymmetric Synthesis of Solanapyrone D Rebecca M. Wilson, Wendy S. Jen, and David W. C. MacMillan pp 11616–11617 DOI: 10.1021/ja054008q Supporting Info

β-Aryl Eliminations from Rh(I) Iminyl Complexes Pinjing Zhao and John F. Hartwig pp 11618–11619 DOI: 10.1021/ja054132+ Supporting Info

Total Synthesis of Dictyodendrin B Alois Fürstner, Mathias M. Domostoj, and Bodo Scheiper pp 11620–11621 DOI: 10.1021/ja0541175 Supporting Info

A Modular and Efficient Synthesis of Functional Titanocenes Andreas Gansäuer, Dieter Franke, Thorsten Lauterbach, and Martin Nieger pp 11622–11623 DOI: 10.1021/ja054185r Supporting Info

Rapid 1H{13C}-Resolved Diffusion and Spin-Relaxation Measurements by NMR Spectroscopy Christian A. Steinbeck and Bradley F. Chmelka pp 11624–11635 DOI: 10.1021/ja0439064

Biosensing Using Porous Silicon Double-Layer Interferometers:  Reflective Interferometric Fourier Transform Spectroscopy Claudia Pacholski, Marta Sartor, Michael J. Sailor, Frédérique Cunin, and Gordon M. Miskelly pp 11636–11645 DOI: 10.1021/ja0511671

Binuclear Cyclopentadienylcobalt Carbonyls:  Comparison with Binuclear Iron Carbonyls Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer, III pp 11646–11651 DOI: 10.1021/ja051554a Supporting Info

Single d-Metal Atoms on Fs and Fs+ Defects of MgO(001):  A Theoretical Study across the Periodic Table Konstantin M. Neyman, Chan Inntam, Alexei V. Matveev, Vladimir A. Nasluzov, and Notker Rösch pp 11652–11660 DOI: 10.1021/ja052437i Supporting Info

Luminescent Silole Nanoparticles as Chemoselective Sensors for Cr(VI) Sarah J. Toal, Kelsey A. Jones, Douglas Magde, and William C. Trogler pp 11661–11665 DOI: 10.1021/ja052582w

Control of Extremely Fast Competitive Consecutive Reactions using Micromixing. Selective Friedel−Crafts Aminoalkylation Aiichiro Nagaki, Manabu Togai, Seiji Suga, Nobuaki Aoki, Kazuhiro Mae, and Jun-ichi Yoshida pp 11666–11675 DOI: 10.1021/ja0527424 Supporting Info

Dynamics of Xenon Binding Inside the Hydrophobic Cavity of Pseudo-Wild-type Bacteriophage T4 Lysozyme Explored through Xenon-Based NMR Spectroscopy Hervé Desvaux, Lionel Dubois, Gaspard Huber, Michael L. Quillin, Patrick Berthault, and Brian W. Matthews pp 11676–11683 DOI: 10.1021/ja053074p Supporting Info

The Binding Energy and Bonding in Dialane Daniel J. Goebbert, Heriberto Hernandez, Joseph S. Francisco, and Paul G. Wenthold pp 11684–11689 DOI: 10.1021/ja0424070 Supporting Info

Nature of Minor-Groove Binders−DNA Complexes in the Gas Phase Manuel Rueda, F.Javier Luque, and Modesto Orozco pp 11690–11698 DOI: 10.1021/ja0422110 Supporting Info

Comparison of the ATP Binding Sites of Protein Kinases Using Conformationally Diverse Bisindolylmaleimides Stephen Bartlett, Godfrey S. Beddard, Richard M. Jackson, Veysel Kayser, Colin Kilner, Andrew Leach, Adam Nelson, Peter R. Oledzki, Peter Parker, Gavin D. Reid, and Stuart L. Warriner pp 11699–11708 DOI: 10.1021/ja050576u Supporting Info

Dynamic Mechanism for the Autophosphorylation of CheA Histidine Kinase:  Molecular Dynamics Simulations Jian Zhang, Yechun Xu, Jianhua Shen, Xiaomin Luo, Jiagao Chen, Kaixian Chen, Weiliang Zhu, and Hualiang Jiang pp 11709–11719 DOI: 10.1021/ja051199o Supporting Info

Photoinduced Nitric Oxide Release from Nitrobenzene Derivatives Takayoshi Suzuki, Osamu Nagae, Yuka Kato, Hidehiko Nakagawa, Kiyoshi Fukuhara, and Naoki Miyata pp 11720–11726 DOI: 10.1021/ja0512024 Supporting Info

Ribosomal Synthesis of Unnatural Peptides Kristopher Josephson, Matthew C. T. Hartman, and Jack W. Szostak pp 11727–11735 DOI: 10.1021/ja0515809 Supporting Info

Solute−Solvent Interactions and Chiral Induction in Liquid Crystals Giorgio Celebre, Giuseppina De Luca, Michela Maiorino, Francesca Iemma, Alberta Ferrarini, Silvia Pieraccini, and Gian Piero Spada pp 11736–11744 DOI: 10.1021/ja051589a Supporting Info

Peroxidase-Catalyzed in Situ Polymerization of Surface Orientated Caffeic Acid Peng Xu, Hiroshi Uyama, James E. Whitten, Shiro Kobayashi, and David L. Kaplan pp 11745–11753 DOI: 10.1021/ja051637r

Oxygenated Hydrocarbon Ionic Surfactants Exhibit CO2 Solubility Xin Fan, Vijay K. Potluri, M. Chandler McLeod, Yang Wang, Juncheng Liu, Robert M. Enick, Andrew D. Hamilton, Christopher B. Roberts, J. Karl Johnson, and Eric J. Beckman pp 11754–11762 DOI: 10.1021/ja052037v Supporting Info

Synthesis and Energy-Transfer Properties of Hydrogen-Bonded Oligofluorenes Stephen P. Dudek, Maarten Pouderoijen, Robert Abbel, Albertus P. H. J. Schenning, and E. W. Meijer pp 11763–11768 DOI: 10.1021/ja052054k Supporting Info

End-Cap Effects on Vibrational Structures of Finite-Length Carbon Nanotubes Takashi Yumura, Daijirou Nozaki, Shunji Bandow, Kazunari Yoshizawa, and Sumio Iijima pp 11769–11776 DOI: 10.1021/ja0522579 Supporting Info

Tailoring the Optical Property by a Three-Dimensional Epitaxial Heterostructure:  A Case of ZnO/SnO2 Qin Kuang, Zhi-Yuan Jiang, Zhao-Xiong Xie, Shui-Chao Lin, Zhi-Wei Lin, Su-Yuan Xie, Rong-Bin Huang, and Lan-Sun Zheng pp 11777–11784 DOI: 10.1021/ja052259t

(EDT-TTF-CONH2)6[Re6Se8(CN)6], a Metallic Kagome-Type Organic−Inorganic Hybrid Compound:  Electronic Instability, Molecular Motion, and Charge Localization Stéphane A. Baudron, Patrick Batail, Claude Coulon, Rodolphe Clérac, Enric Canadell, Vladimir Laukhin, Roberto Melzi, Pawel Wzietek, Denis Jérome, Pascale Auban-Senzier, and Sylvain Ravy pp 11785–11797 DOI: 10.1021/ja0523385 Supporting Info

Cell Penetrating Agents Based on a Polyproline Helix Scaffold Yannick A. Fillon, Jason P. Anderson, and Jean Chmielewski pp 11798–11803 DOI: 10.1021/ja052377g Supporting Info

Combinatorial Synthesis of MUC1 Glycopeptides:  Polymer Blotting Facilitates Chemical and Enzymatic Synthesis of Highly Complicated Mucin Glycopeptides Masataka Fumoto, Hiroshi Hinou, Takashi Ohta, Takaomi Ito, Kuriko Yamada, Akio Takimoto, Hirosato Kondo, Hiroki Shimizu, Toshiyuki Inazu, Yoshiaki Nakahara, and Shin-Ichiro Nishimura pp 11804–11818 DOI: 10.1021/ja052521y Supporting Info

Conformationally Induced Electrostatic Stabilization of Persulfoxides:  A New Suggestion for Inhibition of Physical Quenching of Singlet Oxygen by Remote Functional Groups Edward L. Clennan, Sean E. Hightower, and Alexander Greer pp 11819–11826 DOI: 10.1021/ja0525509 Supporting Info

Van der Waals Interactions Dominate Ligand−Protein Association in a Protein Binding Site Occluded from Solvent Water Elizabeth Barratt, Richard J. Bingham, Daniel J. Warner, Charles A. Laughton, Simon E. V. Phillips, and Steve W. Homans pp 11827–11834 DOI: 10.1021/ja0527525 Supporting Info

Cooperation between Artificial Receptors and Supramolecular Hydrogels for Sensing and Discriminating Phosphate Derivatives Satoshi Yamaguchi, Ibuki Yoshimura, Takahiro Kohira, Shun-ichi Tamaru, and Itaru Hamachi pp 11835–11841 DOI: 10.1021/ja052838y Supporting Info

Conformationally Gated Switching between Superexchange and Hopping within Oligo-p-phenylene-Based Molecular Wires Emily A. Weiss, Michael J. Tauber, Richard F. Kelley, Michael J. Ahrens, Mark A. Ratner, and Michael R. Wasielewski pp 11842–11850 DOI: 10.1021/ja052901j Supporting Info

Phosphorescent Oxygen Sensor with Dendritic Protection and Two-Photon Absorbing Antenna Raymond P. Briñas, Thomas Troxler, Robin M. Hochstrasser, and Sergei A. Vinogradov pp 11851–11862 DOI: 10.1021/ja052947c Supporting Info

Reaction Pathways Leading to Arylene Ethynylene Macrocycles via Alkyne Metathesis Wei Zhang and Jeffrey S. Moore pp 11863–11870 DOI: 10.1021/ja053466w Supporting Info

Oxidation Resistant Germanium Nanowires:  Bulk Synthesis, Long Chain Alkanethiol Functionalization, and Langmuir−Blodgett Assembly Dunwei Wang, Ying-Lan Chang, Zhuang Liu, and Hongjie Dai pp 11871–11875 DOI: 10.1021/ja053836g Supporting Info

Fullerenes:  Chemistry and Reactions By Andreas Hirsch and Michael Brettreich (Friedrich Alexander University of Erlangen-Nuremberg). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. xviii + 423 pp. $180.00. ISBN 3-527-30820-2. W. E. Billups p 11876 DOI: 10.1021/ja059725z

Modern Raman SpectroscopyA Practical Approach By Ewen Smith (Strathclyde University, Glasgow, U.K.) and Geoffrey Dent (Intertek ASG and UMIST, Manchester, U.K.). John Wiley & Sons, Ltd:  Chichester. 2005. xii + 210 pp. $45.00. ISBN 0-471-49794-0. Patricia Ann Mabrouk pp 11876–11877 DOI: 10.1021/ja0597303

Electronic and Photoelectron Spectroscopy:  Fundamentals and Case Studies By Andrew M. Ellis (University of Leicester, U.K.), Miklos Feher (Neurocrine Biosciences, San Diego, CA), and Timothy G. Wright (University of Nottingham, U.K.). Cambridge University Press:  Cambridge. 2005. xiv + 286 pp. $55.00. ISBN 0-521-81737-4. Caroline Chick Jarrold p 11877 DOI: 10.1021/ja059737k

Name Reactions and Reagents in Organic Synthesis, 2nd ed By Bradford P. Mundy (Colby College, Waterville, ME), Michael G. Ellerd (Maxim Technologies, Bozeman, MT), and Frank G. Favaloro, Jr. (Helicon Therapeutics, Farmingdale, NY). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xvi + 882 pp. $89.95. ISBN 0-471-22854-0. pp 11877–11878 DOI: 10.1021/ja059767n

Electrochemical Aspects of Ionic Liquids Edited by Hiroyuki Ohno (Tokyo University of Agriculture and Technology). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xiii + 392 pp. $150.00. ISBN 0-471-64851-5. Keith J. Stevenson p 11878 DOI: 10.1021/ja059768f

Named Organic Reactions, 2nd ed By Thomas Laue and Andreas Plagens (Volkswagen AG, Wolfsburg, Germany). John Wiley & Sons, Ltd:  Chichester, U.K. 2005. x + 310 pp. $55.00. ISBN 0-470-01041-X. p 11878 DOI: 10.1021/ja0597810

Issue 34

Synthesis and Electrochemical Characterization of a Transition-Metal-Modified Ligand−Receptor Pair Amanda L. Eckermann, Kylie D. Barker, Matthew R. Hartings, Mark A. Ratner, and Thomas J. Meade pp 11880–11881 DOI: 10.1021/ja042922y Supporting Info

Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis Jay C. Conrad, Henrietta H. Parnas, Jennifer L. Snelgrove, and Deryn E. Fogg pp 11882–11883 DOI: 10.1021/ja042736s Supporting Info

Ordered Assembly of Protonated Porphyrin Driven by Single-Wall Carbon Nanotubes. J- and H-Aggregates to Nanorods Taku Hasobe, Shunichi Fukuzumi, and Prashant V. Kamat pp 11884–11885 DOI: 10.1021/ja050687t Supporting Info

Controlled Spacing of Cationic Gold Nanoparticles by Nanocrown RNA Alexey Y. Koyfman, Gary Braun, Sergei Magonov, Arkadiusz Chworos, Norbert O. Reich, and Luc Jaeger pp 11886–11887 DOI: 10.1021/ja051144m Supporting Info

Switch-Peptides:  Controlling Self-Assembly of Amyloid β-Derived Peptides in vitro by Consecutive Triggering of Acyl Migrations Sonia Dos Santos, Arunan Chandravarkar, Bhubaneswar Mandal, Richard Mimna, Karine Murat, Lydiane Saucède, Patricia Tella, Gabriele Tuchscherer, and Manfred Mutter pp 11888–11889 DOI: 10.1021/ja052083v Supporting Info

Excited-State Proton Transfer in Gas-Expanded Liquids:  The Roles of Pressure and Composition in Supercritical CO2/Methanol Mixtures Rui M. D. Nunes, Luis G. Arnaut, Kyril M. Solntsev, Laren M. Tolbert, and Sebastião J. Formosinho pp 11890–11891 DOI: 10.1021/ja052416o Supporting Info

A Rapid Label-Free Electrochemical Detection and Kinetic Study of Alzheimer's Amyloid Beta Aggregation Mun'delanji Vestergaard, Kagan Kerman, Masato Saito, Naoki Nagatani, Yuzuru Takamura, and Eiichi Tamiya pp 11892–11893 DOI: 10.1021/ja052522q Supporting Info

The Use of Phase-Inverting Emulsions to Show the Phenomenon of Interfacial Crystallization on Both Heating and Cooling Catherine E. Nicholson, Sharon J. Cooper, Claire Marcellin, and Matthew J. Jamieson pp 11894–11895 DOI: 10.1021/ja0526012 Supporting Info

Chelation-Controlled Diastereoselective Reduction of α-Fluoroketones Pramod K. Mohanta, Todd A. Davis, Jeremy R. Gooch, and Robert A. Flowers, II pp 11896–11897 DOI: 10.1021/ja052546x Supporting Info

A Reinterpretation of the Mechanism of the Simplest Reaction at an sp3-Hybridized Carbon Atom:  H + CD4 → CD3 + HD Jon P. Camden, Hans A. Bechtel, Davida J. Ankeny Brown, Marion R. Martin, Richard N. Zare, Wenfang Hu, György Lendvay, Diego Troya, and George C. Schatz pp 11898–11899 DOI: 10.1021/ja052684m

Gas Phase Formation of a 310-Helix in a Three-Residue Peptide Chain:  Role of Side Chain-Backbone Interactions as Evidenced by IR−UV Double Resonance Experiments Wutharath Chin, François Piuzzi, Jean-Pierre Dognon, Iliana Dimicoli, Benjamin Tardivel, and Michel Mons pp 11900–11901 DOI: 10.1021/ja052894z Supporting Info

Surface Plasmon Resonance-Mediated Colloid Gold Monolayer Junctions Yongdong Jin and Noga Friedman pp 11902–11903 DOI: 10.1021/ja052896j Supporting Info

Deep Cavitands Provide Organized Solvation of Reactions Richard J. Hooley and Julius Rebek, Jr. pp 11904–11905 DOI: 10.1021/ja052910s Supporting Info

Single-Walled Carbon Nanotube Biosensors Using Aptamers as Molecular Recognition Elements Hye-Mi So, Keehoon Won, Yong Hwan Kim, Byoung-Kye Kim, Beyong Hwan Ryu, Pil Sun Na, Hyojin Kim, and Jeong-O Lee pp 11906–11907 DOI: 10.1021/ja053094r Supporting Info

Geometrical H/D Isotope Effect on Hydrogen Bonds in Charged Water Clusters Masanori Tachikawa and Motoyuki Shiga pp 11908–11909 DOI: 10.1021/ja053135j Supporting Info

Bidirectional Electron Transfer in Photosystem I:  Direct Evidence from High-Frequency Time-Resolved EPR Spectroscopy Oleg G. Poluektov, Sergei V. Paschenko, Lisa M. Utschig, K. V. Lakshmi, and Marion C. Thurnauer pp 11910–11911 DOI: 10.1021/ja053315t Supporting Info

Exceptional Gas-Phase Enantioselectivity of Chiral Tetramide Macrocycles Antonello Filippi, Francesco Gasparrini, Marco Pierini, Maurizio Speranza, and Claudio Villani pp 11912–11913 DOI: 10.1021/ja0533038 Supporting Info

Characterizing the “Shell Phase” Formed from Amphiphilic Picolinates Fredric M. Menger, Ashley L. Galloway, and Dan Lundberg pp 11914–11915 DOI: 10.1021/ja053432o

Noninvasive In Situ Visualization of Supported Catalyst Preparations Using Multinuclear Magnetic Resonance Imaging Anna A. Lysova, Igor V. Koptyug, Renad Z. Sagdeev, Valentin N. Parmon, Jaap A. Bergwerff, and Bert M. Weckhuysen pp 11916–11917 DOI: 10.1021/ja053456v

Determination of the Packing Mode of the Coiled-Coil Domain of cGMP-Dependent Protein Kinase Iα in Solution Using Charge-Predicted Dipolar Couplings Markus Zweckstetter, Jason R. Schnell, and James J. Chou pp 11918–11919 DOI: 10.1021/ja0534654 Supporting Info

A General Strategy for the Assignment of Aliphatic Side-Chain Resonances of Uniformly 13C,15N-Labeled Large Proteins Yingqi Xu, Zhi Lin, Chien Ho, and Daiwen Yang pp 11920–11921 DOI: 10.1021/ja053539b Supporting Info

Ion Solvation by Channel Carbonyls Characterized by 17O Solid-State NMR at 21 T Jun Hu, Eduard Y. Chekmenev, Zhehong Gan, Peter L. Gor'kov, Saikat Saha, William W. Brey, and Timothy A. Cross pp 11922–11923 DOI: 10.1021/ja0535413

Reactions of SF6 with Organotitanium and Organozirconium Complexes:  The “Inert” SF6 as a Reactive Fluorinating Agent Rehan Basta, Benjamin G. Harvey, Atta M. Arif, and Richard D. Ernst pp 11924–11925 DOI: 10.1021/ja052214s Supporting Info

Asymmetric 1,3-Dipolar Cycloaddition Reaction of Nitrones and Acrolein with a Bis-Titanium Catalyst as Chiral Lewis Acid Taichi Kano, Takuya Hashimoto, and Keiji Maruoka pp 11926–11927 DOI: 10.1021/ja0523284 Supporting Info

Formation of Linear Tetramers of Diarylalkynes by the Zr/Cr System Tamotsu Takahashi, Yuanhong Liu, Atsushi Iesato, Shinji Chaki, Kiyohiko Nakajima, and Ken-ichiro Kanno pp 11928–11929 DOI: 10.1021/ja052864w Supporting Info

Iso-Migrastatin Congeners from Streptomyces platensis and Generation of a Glutarimide Polyketide Library Featuring the Dorrigocin, Lactimidomycin, Migrastatin, and NK30424 Scaffolds Jianhua Ju, Si-Kyu Lim, Hui Jiang, Jeong-Woo Seo, and Ben Shen pp 11930–11931 DOI: 10.1021/ja053118u Supporting Info

On the Mechanism of Negative Differential Resistance in Ferrocenylundecanethiol Self-Assembled Monolayers Jin He and Stuart M. Lindsay pp 11932–11933 DOI: 10.1021/ja0532279 Supporting Info

An Air-Stable P-Chiral Phosphine Ligand for Highly Enantioselective Transition-Metal-Catalyzed Reactions Tsuneo Imamoto, Keitaro Sugita, and Kazuhiro Yoshida pp 11934–11935 DOI: 10.1021/ja053458f Supporting Info

Titanium and Zirconium Complexes of Preorganized Tripodal Triaryloxide Ligands Fumio Akagi, Tsukasa Matsuo, and Hiroyuki Kawaguchi pp 11936–11937 DOI: 10.1021/ja053740m Supporting Info

Hydrogen Production from Hydrolytic Oxidation of Organosilanes Using a Cationic Oxorhenium Catalyst Elon A. Ison, Rex A. Corbin, and Mahdi M. Abu-Omar pp 11938–11939 DOI: 10.1021/ja053860u Supporting Info

Self-Assembly of a Nonionic Surfactant at the Graphite/Ionic Liquid Interface Rob Atkin and Gregory G. Warr pp 11940–11941 DOI: 10.1021/ja053904z

Regular Arrays of 2 nm Metal Nanoparticles for Deterministic Synthesis of Nanomaterials Ali Javey and Hongjie Dai pp 11942–11943 DOI: 10.1021/ja0536668

On the Chemistry of Zn−Zn Bonds, RZn−ZnR (R = [{(2,6-Pri2C6H3)N(Me)C}2CH]): Synthesis, Structure, and Computations Yuzhong Wang, Brandon Quillian, Pingrong Wei, Hongyan Wang, Xiao-Juan Yang, Yaoming Xie, R. Bruce King, Paul v. R. Schleyer, H. Fritz Schaefer, III, and Gregory H. Robinson pp 11944–11945 DOI: 10.1021/ja053819r Supporting Info

Site-Specific 13C Chemical Shift Anisotropy Measurements in a Uniformly 15N,13C-Labeled Microcrystalline Protein by 3D Magic-Angle Spinning NMR Spectroscopy Benjamin J. Wylie, W. Trent Franks, Daniel T. Graesser, and Chad M. Rienstra pp 11946–11947 DOI: 10.1021/ja053862e Supporting Info

A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand Travis M. Anderson, Rui Cao, Elena Slonkina, Britt Hedman, Keith O. Hodgson, Kenneth I. Hardcastle, Wade A. Neiwert, Shaoxiong Wu, Martin L. Kirk, Sushilla Knottenbelt, Ezra C. Depperman, Bineta Keita, Louis Nadjo, Djamaladdin G. Musaev, Keiji Morokuma, and Craig L. Hill pp 11948–11949 DOI: 10.1021/ja054131h Supporting Info

24-Fold Endohedral Functionalization of a Self-Assembled M12L24 Coordination Nanoball Masahide Tominaga, Kosuke Suzuki, Takashi Murase, and Makoto Fujita pp 11950–11951 DOI: 10.1021/ja054069o Supporting Info

Electrocatalytic Oxidation of DNA-Wrapped Carbon Nanotubes Mary E. Napier, Dominic O. Hull, and H. Holden Thorp pp 11952–11953 DOI: 10.1021/ja054162c Supporting Info

Thermal and Photocontrol of the Equilibrium between a 2-Phosphinoazobenzene and an Inner Phosphonium Salt Masaki Yamamura, Naokazu Kano, and Takayuki Kawashima pp 11954–11955 DOI: 10.1021/ja054293d Supporting Info

A Highly Efficient and Direct Approach for Synthesis of Enantiopure β-Amino Alcohols by Reductive Cross-Coupling of Chiral N-tert-Butanesulfinyl Imines with Aldehydes Yu-Wu Zhong, Yi-Zhou Dong, Kai Fang, Kenji Izumi, Ming-Hua Xu, and Guo-Qiang Lin pp 11956–11957 DOI: 10.1021/ja054401w Supporting Info

Short, Enantioselective Total Synthesis of Aflatoxin B2 Using an Asymmetric [3+2]-Cycloaddition Step Gang Zhou and E. J. Corey pp 11958–11959 DOI: 10.1021/ja054503m Supporting Info

Site-Selective Patterning Using Surfactant-Based Resists Noshir S. Pesika, Fengqiu Fan, Peter C. Searson, and Kathleen J. Stebe pp 11960–11962 DOI: 10.1021/ja050955n Supporting Info

Crystalline Superlattices from Single-Sized Quantum Dots Nanfeng Zheng, Xianhui Bu, Haiwei Lu, Qichun Zhang, and Pingyun Feng pp 11963–11965 DOI: 10.1021/ja053588o Supporting Info

Chimeric (α/β + α)-Peptide Ligands for the BH3-Recognition Cleft of Bcl-xL:  Critical Role of the Molecular Scaffold in Protein Surface Recognition Jack D. Sadowsky, Margaret A. Schmitt, Hee-Seung Lee, Naoki Umezawa, Shaomeng Wang, York Tomita, and Samuel H. Gellman pp 11966–11968 DOI: 10.1021/ja053678t Supporting Info

Geometric and Electronic Structure of the Heme−Peroxo−Copper Complex [(F8TPP)FeIII−(O22-)−CuII(TMPA)](ClO4) Diego del Río, Ritimukta Sarangi, Eduardo E. Chufán, Kenneth D. Karlin, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 11969–11978 DOI: 10.1021/ja043374r Supporting Info

Organolanthanide-Mediated Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes:  A Computational Exploration of Diverse Mechanistic Pathways for the Regioselective Generation of Functionalized Azacycles Supported by a Lanthanocene-Based Catalyst Complex Sven Tobisch pp 11979–11988 DOI: 10.1021/ja042546h Supporting Info

Separation of CO2 and N2 by Adsorption in C168 Schwarzite:  A Combination of Quantum Mechanics and Molecular Simulation Study Jianwen Jiang and Stanley I. Sandler pp 11989–11997 DOI: 10.1021/ja0424575 Supporting Info

Magnetically Responsive Carboxylated Magnetite-Polydipyrrole/Polydicarbazole Nanocomposites of Core−Shell Morphology. Preparation, Characterization, and Use in DNA Hybridization Jean-Paul Lellouche, Govindaraji Senthil, Augustine Joseph, Ludmila Buzhansky, Ian Bruce, Erika R. Bauminger, and Jacob Schlesinger pp 11998–12006 DOI: 10.1021/ja050285l Supporting Info

Magnetic and Porous Nanospheres from Ultrasonic Spray Pyrolysis Won Hyuk Suh and Kenneth S. Suslick pp 12007–12010 DOI: 10.1021/ja050693p Supporting Info

Single Molecule Spectroscopy as a Probe for Dye−Polymer Interactions Renaud A. L. Vallée, Philippe Marsal, Els Braeken, Satoshi Habuchi, Frans C. De Schryver, Mark Van der Auweraer, David Beljonne, and Johan Hofkens pp 12011–12020 DOI: 10.1021/ja051016y

Bead-linked Proteoliposomes:  A Reconstitution Method for NMR Analyses of Membrane Protein−Ligand Interactions Mariko Yokogawa, Koh Takeuchi, and Ichio Shimada pp 12021–12027 DOI: 10.1021/ja0511772

Mesosynthesis of ZnO−Silica Composites for Methanol Nanocatalysis S. Polarz, F. Neues, M. W. E. van den Berg, W. Grünert, and L. Khodeir pp 12028–12034 DOI: 10.1021/ja0516514 Supporting Info

Syntheses of RNAs with up to 100 Nucleotides Containing Site-Specific 2‘-Methylseleno Labels for Use in X-ray Crystallography Claudia Höbartner, Renate Rieder, Christoph Kreutz, Barbara Puffer, Kathrin Lang, Anna Polonskaia, Alexander Serganov, and Ronald Micura pp 12035–12045 DOI: 10.1021/ja051694k Supporting Info

Sulfur K-Edge XAS and DFT Calculations on P450 Model Complexes:  Effects of Hydrogen Bonding on Electronic Structure and Redox Potentials Abhishek Dey, Taka-aki Okamura, Norikazu Ueyama, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 12046–12053 DOI: 10.1021/ja0519031 Supporting Info

Kinetics and Mechanistic Aspects of the Heck Reaction Promoted by a CN−Palladacycle Crestina S. Consorti, Fabrício R. Flores, and Jairton Dupont pp 12054–12065 DOI: 10.1021/ja051834q Supporting Info

Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes Pinjing Zhao, Christopher Krug, and John F. Hartwig pp 12066–12073 DOI: 10.1021/ja052473h Supporting Info

Tunable pK of Amino Acid Residues at the Air−Water Interface Gives an L-zyme (Langmuir Enzyme) Katsuhiko Ariga, Takashi Nakanishi, Jonathan P. Hill, Makoto Shirai, Minoru Okuno, Takao Abe, and Jun-ichi Kikuchi pp 12074–12080 DOI: 10.1021/ja053226g Supporting Info

Synthesis and Properties of Carborane-Functionalized Aliphatic Polyester Dendrimers Matthew C. Parrott, Erin B. Marchington, John F. Valliant, and Alex Adronov pp 12081–12089 DOI: 10.1021/ja053730l Supporting Info

A General Strategy for Stereoselective Glycosylations Jin-Hwan Kim, Hai Yang, Jin Park, and Geert-Jan Boons pp 12090–12097 DOI: 10.1021/ja052548h Supporting Info

Unique CO Chemisorption Properties of Gold Hexamer:  Au6(CO)n- (n = 0−3) Hua-Jin Zhai, Boggavarapu Kiran, Bing Dai, Jun Li, and Lai-Sheng Wang pp 12098–12106 DOI: 10.1021/ja052618k Supporting Info

Sampling Unfolding Intermediates in Calmodulin by Single-Molecule Spectroscopy Brian D. Slaughter, Jay R. Unruh, E. Shane Price, Jason L. Huynh, Ramona J. Bieber Urbauer, and Carey K. Johnson pp 12107–12114 DOI: 10.1021/ja0526315 Supporting Info

Angular-Ratiometric Plasmon-Resonance Based Light Scattering for Bioaffinity Sensing Kadir Aslan, Patrick Holley, Lydia Davies, Joseph R. Lakowicz, and Chris D. Geddes pp 12115–12121 DOI: 10.1021/ja052739k

High Ionization Potential Conjugated Polymers Youngmi Kim, James E. Whitten, and Timothy M. Swager pp 12122–12130 DOI: 10.1021/ja052828x Supporting Info

Coordination-Driven Self-Assemblies with a Carborane Backbone Hershel Jude, Hendrik Disteldorf, Sonja Fischer, Tim Wedge, Adam M. Hawkridge, Atta M. Arif, M. Frederick Hawthorne, David C. Muddiman, and Peter J. Stang pp 12131–12139 DOI: 10.1021/ja053050i Supporting Info

Substituent Effects on Redox Potentials and Optical Gap Energies of Molecule-like Au38(SPhX)24 Nanoparticles Rui Guo and Royce W. Murray pp 12140–12143 DOI: 10.1021/ja053119m Supporting Info

An ab Initio Molecular Orbital Study of the Mechanism for the Gas-Phase Water-Mediated Decomposition and the Formation of Hydrates of Peroxyacetyl Nitrate (PAN) Yumin Li and Joseph S. Francisco pp 12144–12146 DOI: 10.1021/ja053916k Supporting Info

Cytochrome P450:  Structure, Mechanism, and Biochemistry, 3rd ed Edited by Paul R. Ortiz de Montellano (University of California, San Francisco). Kluwer Academic/Plenum Publishers:  New York. 2005. xx + 690 pp. $149.00. ISBN 0-306-48324-6. David R. Nelson pp 12147–12148 DOI: 10.1021/ja041050x

Bioelectronics:  From Theory to Applications Edited by Itamar Willner and Eugenii Katz (The Hebrew University of Jerusalem). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. xviii + 476 pp. $255.00. ISBN 3-527-30690-0. David E. Benson p 12148 DOI: 10.1021/ja059743g

Issue 35

Rationale for Kinetic Heterogeneity of Ultrafast Light-Induced Electron Transfer from Ru(II) Complex Sensitizers to Nanocrystalline TiO2 Bernard Wenger, Michael Grätzel, and Jacques-E. Moser pp 12150–12151 DOI: 10.1021/ja042141x

Vitamin E Imaging and Localization in the Neuronal Membrane Eric B. Monroe, John C. Jurchen, Jinju Lee, Stanislav S. Rubakhin, and Jonathan V. Sweedler pp 12152–12153 DOI: 10.1021/ja051223y Supporting Info

Does Catalysis of Reductive Dechlorination of Tetra- and Trichloroethylenes by Vitamin B12 and Corrinoid-Based Dehalogenases Follow an Electron Transfer Mechanism? Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 12154–12155 DOI: 10.1021/ja0520464 Supporting Info

H−C−SiH3:  Direct Generation and Spectroscopic Identification of Ethylidene's Cousin Peter R. Schreiner, Hans Peter Reisenauer, Kurt W. Sattelmeyer, and Wesley D. Allen pp 12156–12157 DOI: 10.1021/ja052043r Supporting Info

Aligned Arrays of Nanotubes and Segmented Nanotubes on Substrates Fabricated by Electrodeposition onto Nanorods Melissa S. Sander and Han Gao pp 12158–12159 DOI: 10.1021/ja0522231 Supporting Info

Toward Molecular Electronic Circuitry:  Selective Deposition of Metals on Patterned Self-Assembled Monolayer Surfaces Chuanzhen Zhou, Gabriella Nagy, and Amy V. Walker pp 12160–12161 DOI: 10.1021/ja052614f Supporting Info

Highly Efficient and Photostable Photosensitizer Based on BODIPY Chromophore Takatoshi Yogo, Yasuteru Urano, Yukiko Ishitsuka, Fumio Maniwa, and Tetsuo Nagano pp 12162–12163 DOI: 10.1021/ja0528533 Supporting Info

Patterned Growth of Large Oriented Organic Semiconductor Single Crystals on Self-Assembled Monolayer Templates Alejandro L. Briseno, Joanna Aizenberg, Yong-Jin. Han, Rebecca A. Penkala, Hyunsik Moon, Andrew J. Lovinger, Christian Kloc, and Zhenan Bao pp 12164–12165 DOI: 10.1021/ja052919u Supporting Info

Five-Order-of-Magnitude Reduction of the Triplet Lifetimes of N-Heterocycles by Complexation to a Trinuclear Mercury Complex Charlotte Burress, Oussama Elbjeirami, Mohammad A. Omary, and François P. Gabbaï pp 12166–12167 DOI: 10.1021/ja053004i Supporting Info

Mannose/Glucose-Functionalized Dendrimers To Investigate the Predictable Tunability of Multivalent Interactions Mark L. Wolfenden and Mary J. Cloninger pp 12168–12169 DOI: 10.1021/ja053008n Supporting Info

Copper Complexes for Fluorescence-Based NO Detection in Aqueous Solution Mi Hee Lim and Stephen J. Lippard pp 12170–12171 DOI: 10.1021/ja053150o Supporting Info

Isolation and Low-Temperature X-ray Analysis of Intramolecular Triarylmethane−Triarylmethylium Complex:  Preference for a C−H-Bridged Unsymmetric Structure Exhibiting a Facile 1,5-Hydride Shift and Charge-Transfer Interaction Hidetoshi Kawai, Takashi Takeda, Kenshu Fujiwara, and Takanori Suzuki pp 12172–12173 DOI: 10.1021/ja053161h Supporting Info

Selectivity in Platinum-Catalyzed cis−trans Carbon−Carbon Double-Bond Isomerization Ilkeun Lee and Francisco Zaera pp 12174–12175 DOI: 10.1021/ja0532281

Structure and Conductivity of the Crystalline Polymer Electrolyte β-PEO6:LiAsF6 Edward Staunton, Yuri G. Andreev, and Peter G. Bruce pp 12176–12177 DOI: 10.1021/ja053249v Supporting Info

Library versus Library Recognition and Inhibition of the HIV-1 Nef Allelome Allison Olszewski and Gregory A. Weiss pp 12178–12179 DOI: 10.1021/ja053316l Supporting Info

Room Temperature Hydroalkylation of Electron-Deficient Olefins:  sp3 C−H Functionalization via a Lewis Acid-Catalyzed Intramolecular Redox Event Stefan J. Pastine, Kevin M. McQuaid, and Dalibor Sames pp 12180–12181 DOI: 10.1021/ja053337f Supporting Info

Planar Chiral Cyclic Ether:  Asymmetric Resolution and Chirality Transformation Katsuhiko Tomooka, Nobuyuki Komine, Daisuke Fujiki, Takeshi Nakai, and Syun-ichi Yanagitsuru pp 12182–12183 DOI: 10.1021/ja053347g Supporting Info

Ruthenium-Catalyzed Hydrative Cyclization of 1,5-Enynes Yiyun Chen, Douglas M. Ho, and Chulbom Lee pp 12184–12185 DOI: 10.1021/ja053462r Supporting Info

Kinetic Control of Threading of Cyclodextrins onto Axle Molecules Tomoya Oshikiri, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 12186–12187 DOI: 10.1021/ja053532u Supporting Info

Practical Synthesis and Diels−Alder Chemistry of [4]Dendralene Alan D. Payne, Anthony C. Willis, and Michael S. Sherburn pp 12188–12189 DOI: 10.1021/ja053772+ Supporting Info

Reversible and Regioselective Reaction of La@C82 with Cyclopentadiene Yutaka Maeda, Jun Miyashita, Tadashi Hasegawa, Takatsugu Wakahara, Takahiro Tsuchiya, Tsukasa Nakahodo, Takeshi Akasaka, Naomi Mizorogi, Kaoru Kobayashi, Shigeru Nagase, Tatsuhisa Kato, Noritaka Ban, Hiroshi Nakajima, and Yoshihito Watanabe pp 12190–12191 DOI: 10.1021/ja053983e Supporting Info

Unique Spatial Heterogeneity in Ionic Liquids Yanting Wang and Gregory A. Voth pp 12192–12193 DOI: 10.1021/ja053796g Supporting Info

Molecularly Ordered Nanoporous Organosilicates Prepared with and without Surfactants Abdelhamid Sayari and Wenhui Wang pp 12194–12195 DOI: 10.1021/ja054103z Supporting Info

Chemical Aerosol Flow Synthesis of Semiconductor Nanoparticles Yuri T. Didenko and Kenneth S. Suslick pp 12196–12197 DOI: 10.1021/ja054124t Supporting Info

A Modular Nanoparticle-Based System for Reagentless Small Molecule Biosensing Marinella G. Sandros, De Gao, and David E. Benson pp 12198–12199 DOI: 10.1021/ja054166h Supporting Info

Highly Active and Stable DNAzyme−Carbon Nanotube Hybrids Tae-Jin Yim, Juewen Liu, Yi Lu, Ravi S. Kane, and Jonathan S. Dordick pp 12200–12201 DOI: 10.1021/ja0541581

Self-Assembly of Hexagonal DNA Two-Dimensional (2D) Arrays Yu He, Yi Chen, Haipeng Liu, Alexander E. Ribbe, and Chengde Mao pp 12202–12203 DOI: 10.1021/ja0541938 Supporting Info

DNA Charge Transport Leading to Disulfide Bond Formation Tadao Takada and Jacqueline K. Barton pp 12204–12205 DOI: 10.1021/ja054306n Supporting Info

Small Amounts of Achiral β-Amino Alcohols Reverse the Enantioselectivity of Chiral Catalysts in Cooperative Asymmetric Autocatalysis François Lutz, Takashi Igarashi, Tsuneomi Kawasaki, and Kenso Soai pp 12206–12207 DOI: 10.1021/ja054323c Supporting Info

K(UO)Si2O6:  A Pentavalent−Uranium Silicate Chih-Shan Chen, Shang-Fan Lee, and Kwang-Hwa Lii pp 12208–12209 DOI: 10.1021/ja0543853 Supporting Info

Correlation between Molecular Orbitals and Doping Dependence of the Electrical Conductivity in Electron-Doped Metal−Phthalocyanine Compounds Monica F. Craciun, Sven Rogge, and Alberto F. Morpurgo pp 12210–12211 DOI: 10.1021/ja054468j

An Antiaromatic Porphyrin Complex:  Tetraphenylporphyrinato(silicon)(L)2 (L = THF or Pyridine) Julie A. Cissell, Thomas P. Vaid, and Arnold L. Rheingold pp 12212–12213 DOI: 10.1021/ja0544713 Supporting Info

Oligoindole-Based Foldamers with a Helical Conformation Induced by Chloride Kyoung-Jin Chang, Byung-Nam Kang, Min-Hee Lee, and Kyu-Sung Jeong pp 12214–12215 DOI: 10.1021/ja0547984 Supporting Info

Asymmetry in 13C−13C COSY Spectra Provides Information on Ligand Geometry in Paramagnetic Proteins Ivano Bertini, Beatriz Jiménez, Mario Piccioli, and Luisa Poggi pp 12216–12217 DOI: 10.1021/ja051058m Supporting Info

The Isomerization Equilibrium between Cis and Trans Chloride Ruthenium Olefin Metathesis Catalysts from Quantum Mechanics Calculations Diego Benitez and William A. Goddard, III pp 12218–12219 DOI: 10.1021/ja051796a Supporting Info

Base Pair Stability of 8-Chloro- and 8-Iodo-2‘-deoxyguanosine Opposite 2‘-Deoxycytidine:  Implications Regarding the Bioactivity of 8-Oxo-2‘-deoxyguanosine Michelle L. Hamm, Sumika Rajguru, Anthony M. Downs, and Rushina Cholera pp 12220–12221 DOI: 10.1021/ja052578k Supporting Info

The Michael Addition−Elimination of Ylides to α,β-Unsaturated Imines. Highly Stereoselective Synthesis of Vinylcyclopropanecarbaldehydes and Vinylcyclopropylaziridines Jun-Cheng Zheng, Wei-Wei Liao, Yong Tang, Xiu-Li Sun, and Li-Xin Dai pp 12222–12223 DOI: 10.1021/ja052228y Supporting Info

Catalytic Asymmetric Cyanosilylation of Ketones by a Chiral Amino Acid Salt Xiaohua Liu, Bo Qin, Xin Zhou, Bin He, and Xiaoming Feng pp 12224–12225 DOI: 10.1021/ja052629d Supporting Info

Equilibrating C−S Bond Formation by C−H and S−S Bond Metathesis. Rhodium-Catalyzed Alkylthiolation Reaction of 1-Alkynes with Disulfides Mieko Arisawa, Kenji Fujimoto, Satoshi Morinaka, and Masahiko Yamaguchi pp 12226–12227 DOI: 10.1021/ja0527121 Supporting Info

How Substrate Solvation Contributes to the Enantioselectivity of Subtilisin toward Secondary Alcohols Christopher K. Savile and Romas J. Kazlauskas pp 12228–12229 DOI: 10.1021/ja0528937 Supporting Info

Synthesis of Spiro[4.5]trienones by Intramolecular ipso-Halocyclization of 4-(p-Methoxyaryl)-1-alkynes Xiaoxia Zhang and Richard C. Larock pp 12230–12231 DOI: 10.1021/ja053079m Supporting Info

Facile Activation of Dihydrogen by an Unsaturated Heavier Main Group Compound Geoffrey H. Spikes, James C. Fettinger, and Philip P. Power pp 12232–12233 DOI: 10.1021/ja053247a Supporting Info

Catalytic Asymmetric Synthesis of Piperidine Derivatives through the [4 + 2] Annulation of Imines with Allenes Ryan P. Wurz and Gregory C. Fu pp 12234–12235 DOI: 10.1021/ja053277d Supporting Info

Cycloisomerization of Enynes Catalyzed by Iron(0)−Ate Complexes Alois Fürstner, Rubén Martin, and Keisuke Majima pp 12236–12237 DOI: 10.1021/ja0532739 Supporting Info

An Anionic Rhodium η4-Quinonoid Complex as a Multifunctional Catalyst for the Arylation of Aldehydes with Arylboronic Acids Seung Uk Son, Sang Bok Kim, Jeffrey A. Reingold, Gene B. Carpenter, and Dwight A. Sweigart pp 12238–12239 DOI: 10.1021/ja0537981 Supporting Info

TDP-Mycaminose Biosynthetic Pathway Revised and Conversion of Desosamine Pathway to Mycaminose Pathway with One Gene Charles E. Melançon III, Wei-luen Yu, and Hung-wen Liu pp 12240–12241 DOI: 10.1021/ja053835o Supporting Info

Making Thiamin Work Faster:  Acid-Promoted Separation of Carbon Dioxide Qingyan Hu and Ronald Kluger pp 12242–12243 DOI: 10.1021/ja054165p

Iodobenzene-Catalyzed α-Acetoxylation of Ketones. In Situ Generation of Hypervalent (Diacyloxyiodo)benzenes Using m-Chloroperbenzoic Acid Masahito Ochiai, Yasunori Takeuchi, Tomoko Katayama, Takuya Sueda, and Kazunori Miyamoto pp 12244–12245 DOI: 10.1021/ja0542800 Supporting Info

In Situ Generation of Carboxylate:  An Efficient Strategy for a One-Pot Synthesis of Homo- and Heterometallic Polynuclear Complexes Konstantin S. Gavrilenko, Sergey V. Punin, Olivier Cador, Stéphane Golhen, Lahcène Ouahab, and Vitaly V. Pavlishchuk pp 12246–12253 DOI: 10.1021/ja050451p Supporting Info

Engineered Biosynthesis of Aklanonic Acid Analogues Taek Soon Lee, Chaitan Khosla, and Yi Tang pp 12254–12262 DOI: 10.1021/ja051429z Supporting Info

Lipid Modifications of a Ras Peptide Exhibit Altered Packing and Mobility versus Host Membrane as Detected by 2H Solid-State NMR Alexander Vogel, Catherine P. Katzka, Herbert Waldmann, Klaus Arnold, Michael F. Brown, and Daniel Huster pp 12263–12272 DOI: 10.1021/ja051856c Supporting Info

NCN Pincer Palladium Complexes:  Their Preparation via a Ligand Introduction Route and Their Catalytic Properties Kazuhiro Takenaka, Maki Minakawa, and Yasuhiro Uozumi pp 12273–12281 DOI: 10.1021/ja052780n Supporting Info

Kinetic and Spectroscopic Characterization of ACMSD from Pseudomonas fluorescens Reveals a Pentacoordinate Mononuclear Metallocofactor Tingfeng Li, Antoinette L. Walker, Hiroaki Iwaki, Yoshie Hasegawa, and Aimin Liu pp 12282–12290 DOI: 10.1021/ja0532234 Supporting Info

Magic-Angle Spinning Solid-State NMR Spectroscopy of the β1 Immunoglobulin Binding Domain of Protein G (GB1):  15N and 13C Chemical Shift Assignments and Conformational Analysis W. Trent Franks, Donghua H. Zhou, Benjamin J. Wylie, Brian G. Money, Daniel T. Graesser, Heather L. Frericks, Gurmukh Sahota, and Chad M. Rienstra pp 12291–12305 DOI: 10.1021/ja044497e Supporting Info

Reaction Coordinate Analysis for β-Diketone Cleavage by the Non-Heme Fe2+-Dependent Dioxygenase Dke1 Grit D. Straganz and Bernd Nidetzky pp 12306–12314 DOI: 10.1021/ja042313q Supporting Info

Alkane Coordination Selectivity in Hydrocarbon Activation by [Tp‘Rh(CNneopentyl)]:  The Role of Alkane Complexes Andrew J. Vetter, Christine Flaschenriem, and William D. Jones pp 12315–12322 DOI: 10.1021/ja042152q Supporting Info

Importance of Aromatic Content for Peptide/Single-Walled Carbon Nanotube Interactions Vasiliki Zorbas, Amy L. Smith, Hui Xie, Alfonso Ortiz-Acevedo, Alan B. Dalton, Gregg R. Dieckmann, Rockford K. Draper, Ray H. Baughman, and Inga H. Musselman pp 12323–12328 DOI: 10.1021/ja050747v Supporting Info

Optical Absorption of the Blue Fluorescent Protein: A First-Principles Study Xabier Lopez, Miguel A. L. Marques, Alberto Castro, and Angel Rubio pp 12329–12337 DOI: 10.1021/ja050935l Supporting Info

Microscopic Origins for the Favorable Solvation of Carbonate Ether Copolymers in CO2 Collin D. Wick, J. Ilja Siepmann, and Doros N. Theodorou pp 12338–12342 DOI: 10.1021/ja0510008

Fluorescent Amplifying Recognition for DNA G-Quadruplex Folding with a Cationic Conjugated Polymer:  A Platform for Homogeneous Potassium Detection Fang He, Yanli Tang, Shu Wang, Yuliang Li, and Daoben Zhu pp 12343–12346 DOI: 10.1021/ja051507i

Absorption of Schiff-Base Retinal Chromophores in Vacuo Lars H. Andersen, Iben B. Nielsen, Michael B. Kristensen, Mohamed O. A. El Ghazaly, Stefan Haacke, Mogens Brøndsted Nielsen, and Michael Åxman Petersen pp 12347–12350 DOI: 10.1021/ja051638j Supporting Info

Reversible Colorimetric Probes for Mercury Sensing Eugenio Coronado, José R. Galán-Mascarós, Carlos Martí-Gastaldo, Emilio Palomares, James R. Durrant, Ramón Vilar, M. Gratzel, and Md. K. Nazeeruddin pp 12351–12356 DOI: 10.1021/ja0517724 Supporting Info

Increase of the Photoluminescence Intensity of InP Nanowires by Photoassisted Surface Passivation Lambert K. van Vugt, Sandra J. Veen, Erik P. A. M. Bakkers, Aarnoud L. Roest, and Daniël Vanmaekelbergh pp 12357–12362 DOI: 10.1021/ja051860o

A Six-Bowl Carceplex That Entraps Seven Guest Molecules Darren A. Makeiff and John C. Sherman pp 12363–12367 DOI: 10.1021/ja0520621 Supporting Info

Model Electrochemical-Mass Spectrometric Studies of the Cytochrome P450-Catalyzed Oxidations of Cyclic Tertiary Allylamines Ulrik Jurva, Philippe Bissel, Emre M. Isin, Kazuo Igarashi, Simon Kuttab, and Neal Castagnoli, Jr. pp 12368–12377 DOI: 10.1021/ja052048o

Initial Members of the Family of Molecular Mid-Valent High-Nuclearity Iron Nitrides:  [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-) Miriam V. Bennett, Sebastian Stoian, Emile L. Bominaar, Eckard Münck, and Richard H. Holm pp 12378–12386 DOI: 10.1021/ja052150l Supporting Info

In Vivo Magnetic Resonance Detection of Cancer by Using Multifunctional Magnetic Nanocrystals Yong-Min Huh, Young-wook Jun, Ho-Taek Song, Sungjun Kim, Jin-sil Choi, Jae-Hyun Lee, Sarah Yoon, Kyung-Sup Kim, Jeon-Soo Shin, Jin-Suck Suh, and Jinwoo Cheon pp 12387–12391 DOI: 10.1021/ja052337c Supporting Info

Multiple Functionalization of Benzophenones Inside Polyphenylene Dendrimers − Toward Entrapped Ions and Radicals Stefan Bernhardt, Martin Baumgarten, Manfred Wagner, and Klaus Müllen pp 12392–12399 DOI: 10.1021/ja052856f Supporting Info

Reconstitution of Apo-Glucose Dehydrogenase on Pyrroloquinoline Quinone-Functionalized Au Nanoparticles Yields an Electrically Contacted Biocatalyst Maya Zayats, Eugenii Katz, Ronan Baron, and Itamar Willner pp 12400–12406 DOI: 10.1021/ja052841h

MaP Peptides:  Programming the Self-Assembly of Peptide-Based Mesoscopic Matrices Maxim G. Ryadnov and Derek N. Woolfson pp 12407–12415 DOI: 10.1021/ja052972i

Design and Synthesis of a Thermally Stable Organic Electride Mikhail Y. Redko, James E. Jackson, Rui H. Huang, and James L. Dye pp 12416–12422 DOI: 10.1021/ja053216f Supporting Info

Charged Polypeptide Vesicles with Controllable Diameter Eric P. Holowka, Darrin J. Pochan, and Timothy J. Deming pp 12423–12428 DOI: 10.1021/ja053557t Supporting Info

Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes [J. Am. Chem. Soc. 2005, 127, 10840−10841]. Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, and David Milstein p 12429 DOI: 10.1021/ja059914h Supporting Info

Reviews in Fluorescence 2004, Volume 1 Edited by Chris Geddes (University of Maryland Biotechnology Institute, Baltimore, MD) and Joseph R. Lakowicz (University of Maryland Biotechnology Institute). Kluwer Academic/Plenum Publishers:  New York. 2004. x + 410 pp. $149.00. ISBN 0-306-48460-9. Gary A. Baker p 12430 DOI: 10.1021/ja041012d

Modern Aspects of Electrochemistry, No. 38 Edited by B. E. Conway (University of Ottawa), C. G. Vayenas (University of Patras), Ralph E. White (University of South Carolina), Maria E. Gamboa-Adelco (Managing Editor, Superior, CO). Kluwer Academic/Plenum Publishers:  New York. 2005. xx + 544 pp. $155.00. ISBN 0-306-48703-9. Johna Leddy pp 12430–12431 DOI: 10.1021/ja041005p

Impedance Spectroscopy:  Theory, Experiment, and Applications, 2nd ed Edited by Evgenij Barsoukov (Texas Instruments Inc.) and J. Ross Macdonald (University of North Carolina, Chapel Hill). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xvii + 596 pp. $125.00. ISBN 0471-64749-7. Tal M. Nahir p 12431 DOI: 10.1021/ja059742o

Chemistry at Extreme Conditions Edited by M. Riad Manaa (Lawrence Livermore National Laboratory). Elsevier B.V.:  Amsterdam. 2005. xiv + 522 pp. $193.00. ISBN 0-444-51766-9. Thomas B. Brill p 12431 DOI: 10.1021/ja059761y

Progress in Heterocyclic Chemistry, Volume 16 Edited by G. W. Gribble (Dartmouth College) and John A. Joule (The University of Manchester). Elsevier B. V.:  Amsterdam. 2004. viii + 476 pp. $268.00. ISBN 0-08-044482-2. p 12431 DOI: 10.1021/ja059766v

Organic Reaction Mechanisms, 2000 Edited by A. C. Knipe (University of Ulster). Founding Editors:  A. C. Knipe and W. E. Watts. John Wiley & Sons, Ltd.:  Chichester, U.K. 2004. x + 668 pp. $565.00. ISBN 0-470-85439-1. pp 12431–12432 DOI: 10.1021/ja059784c

The Chemistry of Pheromones and Other Semiochemicals II. Topics in Current Chemistry, 240 Edited by Stefan Schulz (TU Braunschweig). Springer:  Berlin, Heidelberg, New York. 2005. xii + 334 pp. $249.00. ISBN 3-540-21308-2. L. E. L. (Bets) Rasmussen p 12432 DOI: 10.1021/ja0597350

Issue 36

Size-Specific Ligands for RNA Hairpin Loops Jason R. Thomas, Xianjun Liu, and Paul J. Hergenrother pp 12434–12435 DOI: 10.1021/ja051685b Supporting Info

Bioconjugates for Tunable Peptide Fragmentation:  Free Radical Initiated Peptide Sequencing (FRIPS) Robert Hodyss, Heather A. Cox, and J. L. Beauchamp pp 12436–12437 DOI: 10.1021/ja052042z Supporting Info

Inter-Ligand Energy Transfer and Related Emission Change in the Cyclometalated Heteroleptic Iridium Complex:  Facile and Efficient Color Tuning over the Whole Visible Range by the Ancillary Ligand Structure Youngmin You and Soo Young Park pp 12438–12439 DOI: 10.1021/ja052880t Supporting Info

Iodomethylzinc Phosphates:  Powerful Reagents for the Cyclopropanation of Alkenes Marie-Christine Lacasse, Cyril Poulard, and André B. Charette pp 12440–12441 DOI: 10.1021/ja0529687 Supporting Info

Binary Malachite Green Aptamer for Fluorescent Detection of Nucleic Acids Dmitry M. Kolpashchikov pp 12442–12443 DOI: 10.1021/ja0529788 Supporting Info

Multipole Plasmon Resonances of Submicron Silver Particles Amar S. Kumbhar, Mark K. Kinnan, and George Chumanov pp 12444–12445 DOI: 10.1021/ja053242d Supporting Info

Wetting in Hydrophobic Nanochannels:  A Challenge of Classical Capillarity Roy Helmy, Yuri Kazakevich, Chaoying Ni, and Alexander Y. Fadeev pp 12446–12447 DOI: 10.1021/ja053267c Supporting Info

Ionic Rotors. Preparation, Structure, and Dynamic Solid-State 2D NMR Study of the 1,4-Diethynylbenzenebis(triphenylborate) Dianion James R. Gardinier, Perry J. Pellechia, and Mark D. Smith pp 12448–12449 DOI: 10.1021/ja053256j Supporting Info

Current-Induced Low-Resistance State and Its Crystal Structure of a TTF-Based Dimeric Donor Salt Michio M. Matsushita and Tadashi Sugawara pp 12450–12451 DOI: 10.1021/ja053488i Supporting Info

Fabrication of Polydiacetylene Nanowires by Associated Self-Polymerization and Self-Assembly Processes for Efficient Field Emission Properties Haiyang Gan, Huibiao Liu, Yongjun Li, Qing Zhao, Yuliang Li, Shu Wang, Tonggang Jiu, Ning Wang, Xiaorong He, Dapeng Yu, and Daoben Zhu pp 12452–12453 DOI: 10.1021/ja053352k Supporting Info

Hydride Ion as Photoelectron Donor in Microporous Crystal Satoru Matsuishi, Katsuro Hayashi, Masahiro Hirano, and Hideo Hosono pp 12454–12455 DOI: 10.1021/ja053568m

Stereochemical Promiscuity in Artificial Transcriptional Activators Sara J. Buhrlage, Brian B. Brennan, Aaron R. Minter, and Anna K. Mapp pp 12456–12457 DOI: 10.1021/ja0536567 Supporting Info

Release and Report:  A New Photolabile Caging System with a Two-Photon Fluorescence Reporting Function Janaki R. R. Majjigapu, Alexei N. Kurchan, Rudresha Kottani, Tiffany P. Gustafson, and Andrei G. Kutateladze pp 12458–12459 DOI: 10.1021/ja053654m Supporting Info

Mitochondrial Targeting of Selective Electron Scavengers:  Synthesis and Biological Analysis of Hemigramicidin−TEMPO Conjugates Peter Wipf, Jingbo Xiao, Jianfei Jiang, Natalia A. Belikova, Vladimir A. Tyurin, Mitchell P. Fink, and Valerian E. Kagan pp 12460–12461 DOI: 10.1021/ja053679l Supporting Info

Enantioselective Reduction of Imines Catalyzed by a Rhenium(V)−Oxo Complex Kristine A. Nolin, Richard W. Ahn, and F. Dean Toste pp 12462–12463 DOI: 10.1021/ja050831a Supporting Info

Bright White Light through Up-Conversion of a Single NIR Source from Sol−Gel-Derived Thin Film Made with Ln3+-Doped LaF3 Nanoparticles Sri Sivakumar, Frank C. J. M van Veggel, and Mati Raudsepp pp 12464–12465 DOI: 10.1021/ja052583o Supporting Info

Regio- and Enantioselective Intermolecular Rhodium-Catalyzed [2+2+2] Carbocyclization Reactions of 1,6-Enynes with Methyl Arylpropiolates P. Andrew Evans, Kwong Wah Lai, and James R. Sawyer pp 12466–12467 DOI: 10.1021/ja053123y Supporting Info

Pt-Catalyzed Pentannulations from In Situ Generated Metallo−Carbenoids Utilizing Propargylic Esters B. A. Bhanu Prasad, Francis K. Yoshimoto, and Richmond Sarpong pp 12468–12469 DOI: 10.1021/ja053192c Supporting Info

Polymerase Evolution:  Efforts toward Expansion of the Genetic Code Aaron M. Leconte, Liangjing Chen, and Floyd E. Romesberg pp 12470–12471 DOI: 10.1021/ja053322h Supporting Info

Interrupted Nazarov Cyclization on Silica Gel Francis Dhoro and Marcus A. Tius pp 12472–12473 DOI: 10.1021/ja053393g Supporting Info

Biologically Relevant Phosphoranes:  Structural Characterization of a Nucleotidyl Phosphorane1 Natalya V. Timosheva, A. Chandrasekaran, and Robert R. Holmes pp 12474–12475 DOI: 10.1021/ja053422n Supporting Info

Synthesis of the Tetrahydroisoquinoline Alkaloid (±)-Renieramycin G and a (±)-Lemonomycinone Analogue from a Common Intermediate Philip Magnus and Kenneth S. Matthews pp 12476–12477 DOI: 10.1021/ja0535817 Supporting Info

Covalent Intermediates and Enzyme Proficiency Thomas C. Bruice and Paula Yurkanis Bruice pp 12478–12479 DOI: 10.1021/ja053714o

Mixed-Metal Pt Monolayer Electrocatalysts for Enhanced Oxygen Reduction Kinetics Junliang Zhang, Miomir B. Vukmirovic, Kotaro Sasaki, Anand Udaykumar Nilekar, Manos Mavrikakis, and Radoslav R. Adzic pp 12480–12481 DOI: 10.1021/ja053695i Supporting Info

Correlating Second Harmonic Optical Responses of Single Ag Nanoparticles with Morphology Rongchao Jin, Justin E. Jureller, Hee Y. Kim, and Norbert F. Scherer pp 12482–12483 DOI: 10.1021/ja0537169 Supporting Info

Complementary Detection of Prostate-Specific Antigen Using In2O3 Nanowires and Carbon Nanotubes Chao Li, Marco Curreli, Henry Lin, Bo Lei, F. N. Ishikawa, Ram Datar, Richard J. Cote, Mark E. Thompson, and Chongwu Zhou pp 12484–12485 DOI: 10.1021/ja053761g Supporting Info

Magnetically Recoverable Chiral Catalysts Immobilized on Magnetite Nanoparticles for Asymmetric Hydrogenation of Aromatic Ketones Aiguo Hu, Gordon T. Yee, and Wenbin Lin pp 12486–12487 DOI: 10.1021/ja053881o Supporting Info

Beyond a T-Shape Pankaj Sinha, Angela K. Wilson, and Mohammad A. Omary pp 12488–12489 DOI: 10.1021/ja053895u Supporting Info

Electrochemical Approach to Concerted Proton and Electron Transfers. Reduction of the Water−Superoxide Ion Complex Cyrille Costentin, Dennis H. Evans, Marc Robert, Jean-Michel Savéant, and Pradyumna S. Singh pp 12490–12491 DOI: 10.1021/ja053911n Supporting Info

Functionalization of Carbon Nanotubes via Cleavable Disulfide Bonds for Efficient Intracellular Delivery of siRNA and Potent Gene Silencing Nadine Wong Shi Kam, Zhuang Liu, and Hongjie Dai pp 12492–12493 DOI: 10.1021/ja053962k Supporting Info

Axial Ligand Substituted Nonheme FeIVO Complexes:  Observation of Near-UV LMCT Bands and FeO Raman Vibrations Chivukula V. Sastri, Mi Joo Park, Takehiro Ohta, Timothy A. Jackson, Audria Stubna, Mi Sook Seo, Jimin Lee, Jinheung Kim, Teizo Kitagawa, Eckard Münck, Lawrence Que, Jr., and Wonwoo Nam pp 12494–12495 DOI: 10.1021/ja0540573 Supporting Info

A Modular Approach to Main-Chain Organometallic Polymers Andrew J. Boydston, Kyle A. Williams, and Christopher W. Bielawski pp 12496–12497 DOI: 10.1021/ja054029k Supporting Info

Low-Temperature Growth of Single-Walled Carbon Nanotubes by Water Plasma Chemical Vapor Deposition Yo-Sep Min, Eun Ju Bae, Byung Seok Oh, Donghun Kang, and Wanjun Park pp 12498–12499 DOI: 10.1021/ja054108w Supporting Info

Structural Determination of Metallofullerene Sc3C82 Revisited:  A Surprising Finding Yuko Iiduka, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, Akihiro Sakuraba, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Tatsuhisa Kato, Michael T. H. Liu, Naomi Mizorogi, Kaoru Kobayashi, and Shigeru Nagase pp 12500–12501 DOI: 10.1021/ja054209u Supporting Info

Crystalline−Crystalline Block Copolymers of Regioregular Poly(3-hexylthiophene) and Polyethylene by Ring-Opening Metathesis Polymerization Christopher P. Radano, Oren A. Scherman, Natalie Stingelin-Stutzmann, Christian Müller, Dag W. Breiby, Paul Smith, René A. J. Janssen, and E. W. Meijer pp 12502–12503 DOI: 10.1021/ja054698y Supporting Info

One-Pot Synthesis of Hollow Superparamagnetic CoPt Nanospheres Yolanda Vasquez, Amandeep K. Sra, and Raymond E. Schaak pp 12504–12505 DOI: 10.1021/ja054442s Supporting Info

Stereoselective Cross-Coupling Reaction of 1,1-Diboryl-1-alkenes with Electrophiles:  A Highly Stereocontrolled Approach to 1,1,2-Triaryl-1-alkenes Masaki Shimizu, Chihiro Nakamaki, Katsuhiro Shimono, Michael Schelper, Takuya Kurahashi, and Tamejiro Hiyama pp 12506–12507 DOI: 10.1021/ja054484g Supporting Info

A Fullerene−Paclitaxel Chemotherapeutic:  Synthesis, Characterization, and Study of Biological Activity in Tissue Culture Tatiana Y. Zakharian, Alexander Seryshev, Balaji Sitharaman, Brian E. Gilbert, Vernon Knight, and Lon J. Wilson pp 12508–12509 DOI: 10.1021/ja0546525 Supporting Info

Coumarin-Strapped Calix[4]pyrrole:  A Fluorogenic Anion Receptor Modulated by Cation and Anion Binding Hidekazu Miyaji, Hae-Kyung Kim, Eun-Kyung Sim, Chang-Kiu Lee, Won-Seob Cho, Jonathan L. Sessler, and Chang-Hee Lee pp 12510–12512 DOI: 10.1021/ja053612y Supporting Info

Deoxygenation of Alcohols Employing Water as the Hydrogen Atom Source David A. Spiegel, Kenneth B. Wiberg, Laura N. Schacherer, Matthew R. Medeiros, and John L. Wood pp 12513–12515 DOI: 10.1021/ja052185l Supporting Info

Chemical Tuning of the Electronic Properties in a Periodic Surfactant-Templated Nanostructured Semiconductor Scott D. Korlann, Andrew E. Riley, Bradley L. Kirsch, B. Simon Mun, and Sarah H. Tolbert pp 12516–12527 DOI: 10.1021/ja045446k Supporting Info

High-Resolution Iterative Frequency Identification for NMR as a General Strategy for Multidimensional Data Collection Hamid R. Eghbalnia, Arash Bahrami, Marco Tonelli, Klaas Hallenga, and John L. Markley pp 12528–12536 DOI: 10.1021/ja052120i Supporting Info

Synthesis, Characterization, and Energetic Properties of Diazido Heteroaromatic High-Nitrogen C−N Compound My Hang V. Huynh, Michael A. Hiskey, David E. Chavez, Darren L. Naud, and Richard D. Gilardi pp 12537–12543 DOI: 10.1021/ja0509735

A Solid State 13C NMR, Crystallographic, and Quantum Chemical Investigation of Chemical Shifts and Hydrogen Bonding in Histidine Dipeptides Feng Cheng, Haihong Sun, Yong Zhang, Dushyant Mukkamala, and Eric Oldfield pp 12544–12554 DOI: 10.1021/ja051528c Supporting Info

19-Electron Intermediates and Cage-Effects in the Photochemical Disproportionation of [CpW(CO)3]2 with Lewis Bases James F. Cahoon, Matthias F. Kling, Stefan Schmatz, and Charles B. Harris pp 12555–12565 DOI: 10.1021/ja052221g Supporting Info

Density Functional Investigation of the Mitsunobu Reaction Stephan Schenk, Jennie Weston, and Ernst Anders pp 12566–12576 DOI: 10.1021/ja052362i Supporting Info

Polypeptide-Templated Synthesis of Hexagonal Silica Platelets Melanie M. Tomczak, Diana D. Glawe, Lawrence F. Drummy, Charles G. Lawrence, Morley O. Stone, Carole C. Perry, Darrin J. Pochan, Timothy J. Deming, and Rajesh R. Naik pp 12577–12582 DOI: 10.1021/ja0524503 Supporting Info

Thermodynamic and Strain Effects in the Competition between 5-Exo-dig and 6-Endo-dig Cyclizations of Vinyl and Aryl Radicals Igor V. Alabugin and Mariappan Manoharan pp 12583–12594 DOI: 10.1021/ja052677y Supporting Info

Hierarchically Structured Monolithic Silicalite-1 Consisting of Crystallized Nanoparticles and Its Performance in the Beckmann Rearrangement of Cyclohexanone Oxime Wen-Cui Li, An-Hui Lu, Regina Palkovits, Wolfgang Schmidt, Bernd Spliethoff, and Ferdi Schüth pp 12595–12600 DOI: 10.1021/ja052693v

A Spectroscopic and Electrochemical Approach to the Study of the Interactions and Photoinduced Electron Transfer between Catechol and Anatase Nanoparticles in Aqueous Solution Teresa Lana-Villarreal, Antonio Rodes, Juan M. Pérez, and Roberto Gómez pp 12601–12611 DOI: 10.1021/ja052798y Supporting Info

Selecting Topology and Connectivity through Metal-Directed Macrocyclization Reactions:  A Square Planar Palladium [2]Catenate and Two Noninterlocked Isomers Anne-Marie L. Fuller, David A. Leigh, Paul J. Lusby, Alexandra M. Z. Slawin, and D. Barney Walker pp 12612–12619 DOI: 10.1021/ja053005a Supporting Info

NMR Assignment Methods for the Aromatic Ring Resonances of Phenylalanine and Tyrosine Residues in Proteins Takuya Torizawa, Akira Mei Ono, Tsutomu Terauchi, and Masatsune Kainosho pp 12620–12626 DOI: 10.1021/ja051386m

Electron Transfer versus Proton Transfer in Gas-Phase Ion/Ion Reactions of Polyprotonated Peptides Harsha P. Gunawardena, Min He, Paul A. Chrisman, Sharon J. Pitteri, Jason M. Hogan, Brittany D. M. Hodges, and Scott A. McLuckey pp 12627–12639 DOI: 10.1021/ja0526057 Supporting Info

Platinum-Based Catalysts for the Hydroamination of Olefins with Sulfonamides and Weakly Basic Anilines Dmitry Karshtedt, Alexis T. Bell, and T. Don Tilley pp 12640–12646 DOI: 10.1021/ja052836d Supporting Info

The Octarepeat Domain of the Prion Protein Binds Cu(II) with Three Distinct Coordination Modes at pH 7.4 Madhuri Chattopadhyay, Eric D. Walter, Dustin J. Newell, Pilgrim J. Jackson, Eliah Aronoff-Spencer, Jack Peisach, Gary J. Gerfen, Brian Bennett, William E. Antholine, and Glenn L. Millhauser pp 12647–12656 DOI: 10.1021/ja053254z Supporting Info

Molecular Recognition via Triplex Formation of Mixed Purine/Pyrimidine DNA Sequences Using OligoTRIPs Jian-Sen Li, Fa-Xian Chen, Ronald Shikiya, Luis A. Marky, and Barry Gold pp 12657–12665 DOI: 10.1021/ja0530218

Endonuclease-Based Logic Gates and Sensors Using Magnetic Force-Amplified Readout of DNA Scission on Cantilevers Yossi Weizmann, Roey Elnathan, Oleg Lioubashevski, and Itamar Willner pp 12666–12672 DOI: 10.1021/ja0533287

Direct Molecular Detection of Nucleic Acids by Fluorescence Signal Amplification Hoang A. Ho, Kim Doré, Maurice Boissinot, Michel G. Bergeron, Robert M. Tanguay, Denis Boudreau, and Mario Leclerc pp 12673–12676 DOI: 10.1021/ja053417j Supporting Info

Stimuli-Responsive Disassembly of Nanoparticle Aggregates for Light-Up Colorimetric Sensing Juewen Liu and Yi Lu pp 12677–12683 DOI: 10.1021/ja053567u

Asymmetric Total Syntheses of (−)-Jorumycin, (−)-Renieramycin G, 3-epi-Jorumycin, and 3-epi-Renieramycin G Jonathan W. Lane, Yuyin Chen, and Robert M. Williams pp 12684–12690 DOI: 10.1021/ja0535918 Supporting Info

Proof of Large Positive Zero-Field Splitting in a Ru25+ Paddlewheel Wei-Zhong Chen, F. Albert Cotton, Naresh S. Dalal, Carlos A. Murillo, Chris M. Ramsey, Tong Ren, and Xiaoping Wang pp 12691–12696 DOI: 10.1021/ja053615a Supporting Info

Selective Self-Organization of Guest Molecules in Self-Assembled Molecular Boxes Jessica M. C. A. Kerckhoffs, Mattijs G. J. ten Cate, Miguel A. Mateos-Timoneda, Fijs W. B. van Leeuwen, Bianca Snellink-Ruël, Anthony L. Spek, Huub Kooijman, Mercedes Crego-Calama, and David N. Reinhoudt pp 12697–12708 DOI: 10.1021/ja0536973 Supporting Info

Engineered Biosynthesis of Plant Polyketides:  Chain Length Control in an Octaketide-Producing Plant Type III Polyketide Synthase Ikuro Abe, Satoshi Oguro, Yoriko Utsumi, Yukie Sano, and Hiroshi Noguchi pp 12709–12716 DOI: 10.1021/ja053945v

Molybdenum−Sulfur Dimers as Electrocatalysts for the Production of Hydrogen at Low Overpotentials Aaron M. Appel, Daniel L. DuBois, and M. Rakowski DuBois pp 12717–12726 DOI: 10.1021/ja054034o Supporting Info

Poly(choloyl)-Based Amphiphiles as Pore-Forming Agents:  Transport-Active Monomers by Design Wen-Hua Chen, Xue-Bin Shao, and Steven L. Regen pp 12727–12735 DOI: 10.1021/ja053527q Supporting Info

Single-Step Preparation of Mesoporous, Anatase-Based Titanium−Vanadium Oxide and Its Application Jing-Jong Shyue and Mark R. De Guire pp 12736–12742 DOI: 10.1021/ja0536365

Optical Recognition of Surface Chirality at Au(hkl) Single Crystalline Surfaces by Second Harmonic Generation Rotational Anisotropy Ichizo Yagi, Masaki Chiba, and Kohei Uosaki pp 12743–12746 DOI: 10.1021/ja053724p Supporting Info

Functional Molecular Nanostructures. Topics in Current Chemistry, 245 Edited by A. Dieter Schlüter (ETH-Honggerberg, Zürich). Springer:  Berlin, Heidelberg, New York. 2005. x + 328 pp. $265.00. ISBN 3-540-21926-9. Eugene R. Zubarev pp 12747–12748 DOI: 10.1021/ja0597606

Molecules in Interaction with Surfaces and Interfaces. Lecture Notes in Physics, 634 Edited by Reinhold Haberlandt, Dieter Michel, Andreas Pöppl, and Rolf Stannarius (Universität Leipzig). Springer-Verlag:  Berlin, Heidelberg. 2004. xviii + 512 pp. $129.95. ISBN 3-540-20539-X. Sarah C. Larsen p 12748 DOI: 10.1021/ja041031n

Issue 37

Two-Dimensional Self-Assembly of a Two-Component Molecular System:  Formation of an Ordered and Homogeneous Molecular Mesh Feng Tao and Steven L. Bernasek pp 12750–12751 DOI: 10.1021/ja050365p Supporting Info

Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links Zheng Ni, Abderrahim Yassar, Tarek Antoun, and Omar M. Yaghi pp 12752–12753 DOI: 10.1021/ja052055c Supporting Info

A Thermodynamic Investigation into the Binding Properties of DNA Functionalized Gold Nanoparticle Probes and Molecular Fluorophore Probes Abigail K. R. Lytton-Jean and Chad A. Mirkin pp 12754–12755 DOI: 10.1021/ja052255o Supporting Info

Liposomes as Protective Capsules for Active Silica Sol−Gel Biocomposite Synthesis Ye Li and Wai Tak Yip pp 12756–12757 DOI: 10.1021/ja0525354 Supporting Info

Phenyl Radicals React with Dinucleoside Phosphates by Addition to Purine Bases and H-Atom Abstraction from a Sugar Moiety Ji-ang Liu, Christopher J. Petzold, Luis E. Ramirez-Arizmendi, James Perez, and Hilkka Kenttämaa pp 12758–12759 DOI: 10.1021/ja052766a Supporting Info

Chemistry of Tetrathiomolybdate:  Aziridine Ring Opening Reactions and Facile Synthesis of Interesting Sulfur Heterocycles Devarajulu Sureshkumar, Srinivasa Murthy Koutha, and Srinivasan Chandrasekaran pp 12760–12761 DOI: 10.1021/ja052969z Supporting Info

Small Molecule Inhibitors of Bacterial Quorum Sensing and Biofilm Formation Grant D. Geske, Rachel J. Wezeman, Adam P. Siegel, and Helen E. Blackwell pp 12762–12763 DOI: 10.1021/ja0530321 Supporting Info

Efficient, Accurate Calculation of Rotational Diffusion and NMR Relaxation of Globular Proteins from Atomic-Level Structures and Approximate Hydrodynamic Calculations Alvaro Ortega and Jose García de la Torre pp 12764–12765 DOI: 10.1021/ja053080l Supporting Info

Facile Conversion of Aptamers into Sensors Using a 2‘-Ribose-Linked Fluorophore Edward J. Merino and Kevin M. Weeks pp 12766–12767 DOI: 10.1021/ja053189t Supporting Info

Cisplatin Carbonato Complexes. Implications for Uptake, Antitumor Properties, and Toxicity Corey R. Centerwall, Jerry Goodisman, Deborah J. Kerwood, and James C. Dabrowiak pp 12768–12769 DOI: 10.1021/ja053353c Supporting Info

Multicolor Imaging of Cell Surface Proteins Laura Vivero-Pol, Nathalie George, Holger Krumm, Kai Johnsson, and Nils Johnsson pp 12770–12771 DOI: 10.1021/ja0533850 Supporting Info

Molecular Assembly of Superquenchers in Signaling Molecular Interactions Chaoyong James Yang, Hui Lin, and Weihong Tan pp 12772–12773 DOI: 10.1021/ja053482t Supporting Info

Excited State Enantiodifferentiating Interactions between a Chiral Benzophenone Derivative and Nucleosides Virginie Lhiaubet-Vallet, Susana Encinas, and Miguel A. Miranda pp 12774–12775 DOI: 10.1021/ja053518h Supporting Info

Synthesis and Purification of a Metallic Nitride Fullerene BisAdduct:  Exploring the Reactivity of Gd3N@C80 Steven Stevenson, Ryan R. Stephen, Thomas M. Amos, Veronica R. Cadorette, Jonathan E. Reid, and J. Paige Phillips pp 12776–12777 DOI: 10.1021/ja0535312 Supporting Info

Hsp90 Inhibitors Identified from a Library of Novobiocin Analogues Xiao Ming Yu, Gang Shen, Len Neckers, Helen Blake, Jeff Holzbeierlein, Benjamin Cronk, and Brian S. J. Blagg pp 12778–12779 DOI: 10.1021/ja0535864 Supporting Info

Hydrolytic Degradation of Poly(ethylene oxide)-block-Polycaprolactone Worm Micelles Yan Geng and Dennis E. Discher pp 12780–12781 DOI: 10.1021/ja053902e Supporting Info

Polydiacetylene/Silica Nanocomposites with Tunable Mesostructure and Thermochromatism from Diacetylenic Assembling Molecules Huisheng Peng, Jing Tang, Jiebin Pang, Daoyong Chen, Lu Yang, Henry S. Ashbaugh, C. Jeffrey Brinker, Zhenzhong Yang, and Yunfeng Lu pp 12782–12783 DOI: 10.1021/ja053966p Supporting Info

Hydrophobic Brønsted Acid−Base Ionic Liquids Based on PAMAM Dendrimers with High Proton Conductivity and Blue Photoluminescence Jing-Fang Huang, Huimin Luo, Chengdu Liang, I−Wen Sun, Gary A. Baker, and Sheng Dai pp 12784–12785 DOI: 10.1021/ja053965x Supporting Info

Electronic Tuning of Mg2Cu6Ga5. A Route to Crystalline Approximant and Quasicrystalline Phases Qisheng Lin and John D. Corbett pp 12786–12787 DOI: 10.1021/ja0539645 Supporting Info

MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area Thomas Devic, Christian Serre, Nathalie Audebrand, Jérôme Marrot, and Gérard Férey pp 12788–12789 DOI: 10.1021/ja053992n Supporting Info

Unusually Stable Palladium(IV) Complexes:  Detailed Mechanistic Investigation of C−O Bond-Forming Reductive Elimination Allison R. Dick, Jeff W. Kampf, and Melanie S. Sanford pp 12790–12791 DOI: 10.1021/ja0541940 Supporting Info

Nanotubes Fabricated from Ni−Naphthalocyanine by a Template Method Linjie Zhi, Tatiana Gorelik, Jishan Wu, Ute Kolb, and Klaus Müllen pp 12792–12793 DOI: 10.1021/ja054263a Supporting Info

Discrete Water Hexamers and Template-Assisted Molecular Recognition in an Elastic Zincophosphate Lattice Yueh-Chun Liao, Yao-Chen Jiang, and Sue-Lein Wang pp 12794–12795 DOI: 10.1021/ja054357k Supporting Info

Formation of Phosphorus−Nitrogen Bonds by Reduction of a Titanium Phosphine Complex under Molecular Nitrogen Lara Morello, Peihua Yu, Christopher D. Carmichael, Brian O. Patrick, and Michael D. Fryzuk pp 12796–12797 DOI: 10.1021/ja054467r Supporting Info

Controlled Silicon Surface Functionalization by Alkene Hydrosilylation Alexander Langner, Anthony Panarello, Sandrine Rivillon, Oleksiy Vassylyev, Johannes G. Khinast, and Yves J. Chabal pp 12798–12799 DOI: 10.1021/ja054634n Supporting Info

pH-Responsive Vesicles Based on a Hydrolytically Self-Cross-Linkable Copolymer Jianzhong Du and Steven P. Armes pp 12800–12801 DOI: 10.1021/ja054755n Supporting Info

A New Family of Ru Complexes for Water Oxidation Ruifa Zong and Randolph P. Thummel pp 12802–12803 DOI: 10.1021/ja054791m Supporting Info

The Interstitial Atom of the Nitrogenase FeMo-Cofactor:  ENDOR and ESEEM Evidence That it is Not a Nitrogen Tran-Chin Yang, Nathan K. Maeser, Mikhail Laryukhin, Hong-In Lee, Dennis R. Dean, Lance C. Seefeldt, and Brian M. Hoffman pp 12804–12805 DOI: 10.1021/ja0552489

Tandem Aldol−Allylation and Aldol−Aldol Reactions with Ketone-Derived Enolsilanes:  Highly Diastereoselective Single-Step Synthesis of Complex Tertiary Carbinols Xiaolun Wang, Qinglin Meng, Nicholas R. Perl, Yue Xu, and James L. Leighton pp 12806–12807 DOI: 10.1021/ja053593s Supporting Info

Brønsted Acid-Catalyzed Allylboration:  Short and Stereodivergent Synthesis of All Four Eupomatilone Diastereomers with Crystallographic Assignments Siu Hong Yu, Michael J. Ferguson, Robert McDonald, and Dennis G. Hall pp 12808–12809 DOI: 10.1021/ja054171l Supporting Info

AlMe3-Promoted Oxidative Cyclization of η2-Alkene and η2-Ketone on Nickel(0). Observation of Intermediate in Methyl Transfer Process Sensuke Ogoshi, Mizu Ueta, Tomoya Arai, and Hideo Kurosawa pp 12810–12811 DOI: 10.1021/ja0542486 Supporting Info

The Synthesis of Silica Nanospheres Doped with Polyoxometalates Mark Green, Joanna Harries, Gareth Wakefield, and Robin Taylor pp 12812–12813 DOI: 10.1021/ja0543200 Supporting Info

Formation and Oxidation State of CeO2-x Nanotubes Wei-Qiang Han, Lijun Wu, and Yimei Zhu pp 12814–12815 DOI: 10.1021/ja054533p Supporting Info

Surfactant-Free Synthesis and Functionalization of Gold Nanoparticles Martin Schulz-Dobrick, K. Vijaya Sarathy, and Martin Jansen pp 12816–12817 DOI: 10.1021/ja054734t Supporting Info

Cross and Ring-Closing Metathesis of 1,3-Diynes:  Metallotropic [1,3]-Shift of Ruthenium Carbenes Mansuk Kim, Reagan L. Miller, and Daesung Lee pp 12818–12819 DOI: 10.1021/ja054875v Supporting Info

Adsorption-Driven Photocatalytic Activity of Mesoporous Titanium Dioxide Yasuhiro Shiraishi, Naoya Saito, and Takayuki Hirai pp 12820–12822 DOI: 10.1021/ja053265s Supporting Info

Effect of Subsurface Oxygen on the Reactivity of the Ag(111) Surface Ye Xu, Jeff Greeley, and Manos Mavrikakis pp 12823–12827 DOI: 10.1021/ja043727m

Generating MnO2 Nanoparticles Using Simulated Amorphization and Recrystallization Thi X. T. Sayle, C. Richard A. Catlow, R. Regina Maphanga, Phuti E. Ngoepe, and Dean C. Sayle pp 12828–12837 DOI: 10.1021/ja0434073 Supporting Info

Conformations of Laulimalide in DMSO-d6 Pahk Thepchatri, Daniel O. Cicero, Edith Monteagudo, Arun K. Ghosh, Ben Cornett, Eric R. Weeks, and James P. Snyder pp 12838–12846 DOI: 10.1021/ja042890e Supporting Info

A Gadolinium Chelate for Detection of β-Glucuronidase:  A Self-Immolative Approach Joseph A. Duimstra, Frank J. Femia, and Thomas J. Meade pp 12847–12855 DOI: 10.1021/ja042162r Supporting Info

Comparative Photophysics of [26]- and [28]Hexaphyrins(1.1.1.1.1.1):  Large Two-Photon Absorption Cross Section of Aromatic [26]Hexaphyrins(1.1.1.1.1.1) Tae Kyu Ahn, Jung Ho Kwon, Deok Yun Kim, Dae Won Cho, Dae Hong Jeong, Seong Keun Kim, Masaaki Suzuki, Soji Shimizu, Atsuhiro Osuka, and Dongho Kim pp 12856–12861 DOI: 10.1021/ja050895l Supporting Info

Metallacryptate Single-Molecule Magnets:  Effect of Lower Molecular Symmetry on Blocking Temperature Curtis M. Zaleski, Ezra C. Depperman, Catherine Dendrinou-Samara, Maria Alexiou, Jeff W. Kampf, Dimitris P. Kessissoglou, Martin L. Kirk, and Vincent L. Pecoraro pp 12862–12872 DOI: 10.1021/ja050951i Supporting Info

Tunable Inhibition and Denaturation of α-Chymotrypsin with Amino Acid-Functionalized Gold Nanoparticles Chang-Cheng You, Mrinmoy De, Gang Han, and Vincent M. Rotello pp 12873–12881 DOI: 10.1021/ja0512881 Supporting Info

Semisynthesis of a Glycosylated Im7 Analogue for Protein Folding Studies Christian P. R. Hackenberger, Claire T. Friel, Sheena E. Radford, and Barbara Imperiali pp 12882–12889 DOI: 10.1021/ja051855k

Effects of Packing Structure on the Optoelectronic and Charge Transport Properties in Poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) Carrie L. Donley, Jana Zaumseil, Jens W. Andreasen, Martin M. Nielsen, Henning Sirringhaus, Richard H. Friend, and Ji-Seon Kim pp 12890–12899 DOI: 10.1021/ja051891j

Electronic Structure of Compound I in Human Isoforms of Cytochrome P450 from QM/MM Modeling Christine M. Bathelt, Jolanta Zurek, Adrian J. Mulholland, and Jeremy N. Harvey pp 12900–12908 DOI: 10.1021/ja0520924 Supporting Info

Anion Template Effect on the Self-Assembly and Interconversion of Metallacyclophanes Cristian Saul Campos-Fernández, Brandi L. Schottel, Helen T. Chifotides, Jitendra K. Bera, John Bacsa, John M. Koomen, David H. Russell, and Kim R. Dunbar pp 12909–12923 DOI: 10.1021/ja052108q Supporting Info

Uniform Catalytic Site in Sn-β-Zeolite Determined Using X-ray Absorption Fine Structure Simon R. Bare, Shelly D. Kelly, Wharton Sinkler, John J. Low, Frank S. Modica, Susana Valencia, Avelino Corma, and Laszlo T. Nemeth pp 12924–12932 DOI: 10.1021/ja052543k Supporting Info

A Dynamic Coupling Model for Sum Frequency Chiral Response from Liquids Composed of Molecules with a Chiral Side Chain and an Achiral Chromophore Na Ji and Yuen-Ron Shen pp 12933–12942 DOI: 10.1021/ja052715d Supporting Info

Chiral Induction in Quinoline-Derived Oligoamide Foldamers:  Assignment of Helical Handedness and Role of Steric Effects Christel Dolain, Hua Jiang, Jean-Michel Léger, Philippe Guionneau, and Ivan Huc pp 12943–12951 DOI: 10.1021/ja0527828 Supporting Info

Coded Amino Acids in Gas Phase:  The Shape of Isoleucine Alberto Lesarri, Raquel Sánchez, Emilio J. Cocinero, Juan C. López, and José L. Alonso pp 12952–12956 DOI: 10.1021/ja0528073 Supporting Info

Isotope Effects on the Enzymatic and Nonenzymatic Reactions of Chorismate S. Kirk Wright, Michael S. DeClue, Ajay Mandal, Lac Lee, Olaf Wiest, W. Wallace Cleland, and Donald Hilvert pp 12957–12964 DOI: 10.1021/ja052929v Supporting Info

Determination of Membrane Protein Structure and Dynamics by Magic-Angle-Spinning Solid-State NMR Spectroscopy Ovidiu C. Andronesi, Stefan Becker, Karsten Seidel, Henrike Heise, Howard S. Young, and Marc Baldus pp 12965–12974 DOI: 10.1021/ja0530164 Supporting Info

Molecular Mechanisms of Photoinduced Oxygen Evolution, PL Emission, and Surface Roughening at Atomically Smooth (110) and (100) n-TiO2 (Rutile) Surfaces in Aqueous Acidic Solutions Ryuhei Nakamura, Tomoaki Okamura, Naomichi Ohashi, Akihito Imanishi, and Yoshihiro Nakato pp 12975–12983 DOI: 10.1021/ja053252e

Complexation of Ferrocene Derivatives by the Cucurbit[7]uril Host:  A Comparative Study of the Cucurbituril and Cyclodextrin Host Families Woo Sung Jeon, Kwangyul Moon, Sang Hyun Park, Hyungpil Chun, Young Ho Ko, Jin Yong Lee, Eun Sung Lee, S. Samal, N. Selvapalam, Mikhail V. Rekharsky, Vladimir Sindelar, David Sobransingh, Yoshihisa Inoue, Angel E. Kaifer, and Kimoon Kim pp 12984–12989 DOI: 10.1021/ja052912c Supporting Info

Synthesis and Characterization of [PtIn6](GeO4)2O and Its Solid Solution [PtIn6](GaO4)2-x(GeO4)xOx/2 (0 ≤ x ≤ 2):  Gradual Color Change of the Solid Solution from Black (x = 0) to Yellow (x = 2) as a Consequence of Quantum Dot Effect Jürgen Köhler, Holger Friedrich, Myung-Hwan Whangbo, and Antoine Villesuzanne pp 12990–12996 DOI: 10.1021/ja053280x Supporting Info

Conformational Substates Modulate Hydride Transfer in Dihydrofolate Reductase Ian F. Thorpe and Charles L. Brooks III pp 12997–13006 DOI: 10.1021/ja053558l Supporting Info

Two States and Two More in the Mechanisms of Hydroxylation and Epoxidation by Cytochrome P450 Hajime Hirao, Devesh Kumar, Walter Thiel, and Sason Shaik pp 13007–13018 DOI: 10.1021/ja053847+ Supporting Info

Metal versus Ligand Alkylation in the Reactivity of the (Bis-iminopyridinato)Fe Catalyst Jennifer Scott, Sandro Gambarotta, Ilia Korobkov, and Peter H. M. Budzelaar pp 13019–13029 DOI: 10.1021/ja054152b Supporting Info

Metal-Assembling Dendrimers with a Triarylamine Core and Their Application to a Dye-Sensitized Solar Cell Norifusa Satoh, Toshio Nakashima, and Kimihisa Yamamoto pp 13030–13038 DOI: 10.1021/ja050765c Supporting Info

Dynamic Nature of the Transition State for the SN1 Reaction Mechanism of Diphenylmethyl Acetates Kevin S. Peters, Sarah Gasparrini, and Libby R. Heeb pp 13039–13047 DOI: 10.1021/ja051219m

Highly Stereoselective Benzylation of N-Sulfinylketimines José Luis García Ruano, José Alemán, and Alejandro Parra pp 13048–13054 DOI: 10.1021/ja0515203 Supporting Info

The Role of Mesopores in Intracrystalline Transport in USY Zeolite:  PFG NMR Diffusion Study on Various Length Scales P. Kortunov, S. Vasenkov, J. Kärger, R. Valiullin, P. Gottschalk, M. Fé Elía, M. Perez, M. Stöcker, B. Drescher, G. McElhiney, C. Berger, R. Gläser, and J. Weitkamp pp 13055–13059 DOI: 10.1021/ja053134r

ESI-MS Studies on the Mechanism of Pd(0)-Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction Hao Guo, Rong Qian, Yuanxi Liao, Shengming Ma, and Yinlong Guo pp 13060–13064 DOI: 10.1021/ja052588l Supporting Info

Experimental Determination of the Heat of Hydrogenation of Phenylcyclobutadiene Alireza Fattahi, Lev Lis, and Steven R. Kass pp 13065–13069 DOI: 10.1021/ja0525511 Supporting Info

Extraordinary Cluster Formation and Intramolecular Ligand−Ligand Interactions in Cyanoactylene Mediated by Mg+•:  Implications for the Atmospheric Chemistry of Titan and for Circumstellar Chemistry Rebecca K. Milburn, Alan C. Hopkinson, and Diethard K. Bohme pp 13070–13078 DOI: 10.1021/ja053302f Supporting Info

Design of an Organocatalyst for the Enantioselective Diels−Alder Reaction with α-Acyloxyacroleins [J. Am. Chem. Soc. 2005, 127, 10504−10505]. Kazuaki Ishihara and Kazuhiko Nakano p 13079 DOI: 10.1021/ja0549603 Supporting Info

Natural Product Synthesis II:  Targets, Methods, Concepts. Topics in Current Chemistry, 244 Edited by Johann Mulzer (Universität Wien). Springer:  Berlin, Heidelberg, New York. 2005. x + 270 pp. $219.00. ISBN 3-540-21124-1. Timothy A. Blizzard p 13080 DOI: 10.1021/ja059756u

Catalysts for Fine Chemical Synthesis, Volume 3:  Metal Catalysed Carbon-Carbon Bond-Forming Reactions Edited by Stanley M. Roberts, Jianliang Xiao (University of Liverpool), John Whittall, and Tom E. Pickett (The Heath, Runcorn Stylacats Ltd, U.K.). John Wiley and Sons, Ltd.:  Chichester. 2004. xxiv + 256 pp. $180.00. ISBN 0-470-86199-1. p 13080 DOI: 10.1021/ja059777o

Issue 38

Spatially Resolved Suzuki Coupling Reaction Initiated and Controlled Using a Catalytic AFM Probe Jason J. Davis, Karl S. Coleman, Katerina L. Busuttil, and Claire B. Bagshaw pp 13082–13083 DOI: 10.1021/ja043235+ Supporting Info

Combined Affinity and Catalytic Biosensor:  In Situ Enzymatic Activity Monitoring of Surface-Bound Enzymes Fei Xu, Guoliang Zhen, Fang Yu, Eva Kuennemann, Marcus Textor, and Wolfgang Knoll pp 13084–13085 DOI: 10.1021/ja050818q Supporting Info

Positive Heterotropic Cooperativity for Selective Guest Binding via Electronic Communications through a Fused Zinc Porphyrin Array Hiroshi Sato, Kentaro Tashiro, Hideyuki Shinmori, Atsuhiro Osuka, Yasujiro Murata, Koichi Komatsu, and Takuzo Aida pp 13086–13087 DOI: 10.1021/ja052993c Supporting Info

Light Activated Recombination Kristian H. Link, Youheng Shi, and John T. Koh pp 13088–13089 DOI: 10.1021/ja0531226 Supporting Info

Linear HThThH:  A Candidate for a Th−Th Triple Bond Michal Straka and Pekka Pyykkö pp 13090–13091 DOI: 10.1021/ja052723u Supporting Info

A Self-Ordered, Crystalline Glass, Mesoporous Nanocomposite with High Proton Conductivity of 2 × 10-2 S cm-1 at Intermediate Temperature Masanori Yamada, Donglin Li, Itaru Honma, and Haoshen Zhou pp 13092–13093 DOI: 10.1021/ja052914x Supporting Info

Arylfluoroborates and Alkylfluorosilicates as Potential PET Imaging Agents:  High-Yielding Aqueous Biomolecular 18F-Labeling Richard Ting, Michael J. Adam, Thomas J. Ruth, and David M. Perrin pp 13094–13095 DOI: 10.1021/ja053293a Supporting Info

Polymer−Micelle Incarcerated Scandium as a Polymer-Supported Catalyst for High-Throughput Organic Synthesis Masahiro Takeuchi, Ryo Akiyama, and Shū Kobayashi pp 13096–13097 DOI: 10.1021/ja053176f Supporting Info

Zwitterion−Dianion Complexes and Anion−Anion Clusters with Negative Dissociation Energies Steven R. Kass pp 13098–13099 DOI: 10.1021/ja053391w Supporting Info

Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells José L. Fernández, Vadari Raghuveer, Arumugam Manthiram, and Allen J. Bard pp 13100–13101 DOI: 10.1021/ja0534710 Supporting Info

Coordination-Induced Formation of Submicrometer-Scale, Monodisperse, Spherical Colloids of Organic−Inorganic Hybrid Materials at Room Temperature Xuping Sun, Shaojun Dong, and Erkang Wang pp 13102–13103 DOI: 10.1021/ja0534809 Supporting Info

Antibody-Catalyzed Asymmetric Intramolecular Michael Addition of Aldehydes and Ketones to Yield the Disfavored Cis-Product Roy Weinstain, Richard A. Lerner, Carlos F. Barbas, III, and Doron Shabat pp 13104–13105 DOI: 10.1021/ja0536825 Supporting Info

Trapping, Stabilization, and Characterization of an Enolate Anion of a 1,6-Adduct of Benzophenone Chelated by a Sodium Alkylamidozincate Cation Eva Hevia, Gordon W. Honeyman, Alan R. Kennedy, and Robert E. Mulvey pp 13106–13107 DOI: 10.1021/ja053756c Supporting Info

Dithiadiazuliporphyrin:  Facile Generation of Carbaporphyrinoid Cation Radical and Dication Natasza Sprutta, Marta Świderska, and Lechosław Latos-Grażyński pp 13108–13109 DOI: 10.1021/ja053723x Supporting Info

Probing Specific Lipid−Protein Interaction by Saturation Transfer Difference NMR Spectroscopy Olivier Soubias and Klaus Gawrisch pp 13110–13111 DOI: 10.1021/ja0538942

Intermolecular C−N Addition of Amides and S−N Addition of Sulfinamides to Arynes Zhijian Liu and Richard C. Larock pp 13112–13113 DOI: 10.1021/ja054079p Supporting Info

A Clear-Cut Experimental Method to Discriminate between In-Plane and Out-of-Plane Molecular Transition Moments Alexandra R. Albunia, Giuseppe Milano, Vincenzo Venditto, and Gaetano Guerra pp 13114–13115 DOI: 10.1021/ja054092+

Cp2TiCl2-Catalyzed Regio- and Chemoselective One-Step Synthesis of γ-Substituted Allylsilanes from Terminal Alkenes Using Dianion-Type Zincate (SiSiNOL-Zn-ate) Shinji Nakamura, Masanobu Uchiyama, and Tomohiko Ohwada pp 13116–13117 DOI: 10.1021/ja0541074 Supporting Info

Recyclable Catalyst for Conversion of Carbon Dioxide into Formate Attributable to an Oxyanion on the Catalyst Ligand Yuichiro Himeda, Nobuko Onozawa-Komatsuzaki, Hideki Sugihara, and Kazuyuki Kasuga pp 13118–13119 DOI: 10.1021/ja054236k Supporting Info

Single-Crystalline GdB6 Nanowire Field Emitters Han Zhang, Qi Zhang, Gongpu Zhao, Jie Tang, Otto Zhou, and Lu−Chang Qin pp 13120–13121 DOI: 10.1021/ja054251p Supporting Info

A Biomimetically Inspired, Efficient Synthesis of the South 7 Hemisphere of Cephalostatin 7 Jong Seok Lee and Philip L. Fuchs pp 13122–13123 DOI: 10.1021/ja0531935 Supporting Info

General Deoxyribozyme-Catalyzed Synthesis of Native 3‘−5‘ RNA Linkages Whitney E. Purtha, Rebecca L. Coppins, Mary K. Smalley, and Scott K. Silverman pp 13124–13125 DOI: 10.1021/ja0533702 Supporting Info

Inhibiting HIV Fusion with a β-Peptide Foldamer Olen M. Stephens, Sunghwan Kim, Brett D. Welch, Michael E. Hodsdon, Michael S. Kay, and Alanna Schepartz pp 13126–13127 DOI: 10.1021/ja053444+ Supporting Info

Monitoring DNA Structures by Dual Fluorescence of Pyrene Derivatives Akimitsu Okamoto, Kazuki Tainaka, Ken-ichiro Nishiza, and Isao Saito pp 13128–13129 DOI: 10.1021/ja053609e Supporting Info

Residue Requirements for Helical Folding in Short α/β-Peptides:  Crystallographic Characterization of the 11-Helix in an Optimized Sequence Margaret A. Schmitt, Soo Hyuk Choi, Ilia A. Guzei, and Samuel H. Gellman pp 13130–13131 DOI: 10.1021/ja0536163 Supporting Info

Formation of an Infinite 2D-Layered Water of (H2O)45 Cluster in a Cryptand−Water Supramolecular Complex:  A Template Effect P. S. Lakshminarayanan, Eringathodi Suresh, and Pradyut Ghosh pp 13132–13133 DOI: 10.1021/ja054068w Supporting Info

A Discrete Metallocyclic Complex that Retains Its Solvent-Templated Channel Structure on Guest Removal to Yield a Porous, Gas Sorbing Material Liliana Dobrzańska, Gareth O. Lloyd, Helgard G. Raubenheimer, and Leonard J. Barbour pp 13134–13135 DOI: 10.1021/ja054119p Supporting Info

Fourfold [2]Rotaxanes Based on Calix[4]arenes Carmine Gaeta, Myroslav O. Vysotsky, Anca Bogdan, and Volker Böhmer pp 13136–13137 DOI: 10.1021/ja054184z Supporting Info

Highly Enantio- and Diastereoselective Tandem Generation of Cyclopropyl Alcohols with up to Four Contiguous Stereocenters Hun Young Kim, Alice E. Lurain, Patricia García-García, Patrick J. Carroll, and Patrick J. Walsh pp 13138–13139 DOI: 10.1021/ja0539239 Supporting Info

Diastereoselective Zinco-Cyclopropanation of Chiral Allylic Alcohols with gem-Dizinc Carbenoids Jean-François Fournier, Simon Mathieu, and André B. Charette pp 13140–13141 DOI: 10.1021/ja054328+ Supporting Info

The Heavy Analogue of CpLi:  Lithium 1,2-Disila-3-germacyclopentadienide, a 6π-Electron Aromatic System Vladimir Ya. Lee, Risa Kato, Masaaki Ichinohe, and Akira Sekiguchi pp 13142–13143 DOI: 10.1021/ja054398g Supporting Info

Total Synthesis of (±)-Taiwaniaquinol B via a Domino Intramolecular Friedel−Crafts Acylation/Carbonyl α-tert-Alkylation Reaction Eric Fillion and Dan Fishlock pp 13144–13145 DOI: 10.1021/ja054447p Supporting Info

Heterolytic H2 Activation Mediated by Low-Coordinate L3Fe-(μ-N)-FeL3 Complexes to Generate Fe(μ-NH)(μ-H)Fe Species Steven D. Brown, Mark P. Mehn, and Jonas C. Peters pp 13146–13147 DOI: 10.1021/ja0544509 Supporting Info

A Route to Annulated Indoles via a Palladium-Catalyzed Tandem Alkylation/Direct Arylation Reaction Cyril Bressy, Dino Alberico, and Mark Lautens pp 13148–13149 DOI: 10.1021/ja054472v Supporting Info

Self-Encapsulation of Homogeneous Catalyst Species into Polymer Gel Leading to a Facile and Efficient Separation System of Amine Products in the Ru-Catalyzed Reduction of Carboxamides with Polymethylhydrosiloxane (PMHS) Yukihiro Motoyama, Kaoru Mitsui, Toshiki Ishida, and Hideo Nagashima pp 13150–13151 DOI: 10.1021/ja054453l Supporting Info

Reactivity of the N-Methylene-5,8-didehydroisoquinolinium Triradical Ion Katrina E. Nizzi, F. Sedinam Amegayibor, John J. Nash, and Hilkka I. Kenttämaa pp 13152–13153 DOI: 10.1021/ja054514f

Highly Regioselective Arylation of sp3 C−H Bonds Catalyzed by Palladium Acetate Vladimir G. Zaitsev, Dmitry Shabashov, and Olafs Daugulis pp 13154–13155 DOI: 10.1021/ja054549f Supporting Info

Access to Macrocyclic Endocyclic and Exocyclic Allylic Alcohols by Nickel-Catalyzed Reductive Cyclization of Ynals Beth Knapp-Reed, Gireesh M. Mahandru, and John Montgomery pp 13156–13157 DOI: 10.1021/ja054590i Supporting Info

A Highly Efficient Approach to [4]Pseudocatenanes by Threefold Metathesis Reactions of a Triptycene-Based Tris[2]pseudorotaxane Xiao-Zhang Zhu and Chuan-Feng Chen pp 13158–13159 DOI: 10.1021/ja0546020 Supporting Info

Electropolymerization of an Immiscible Monomer in Aqueous Electrolytes Using Acoustic Emulsification Ryosuke Asami, Mahito Atobe, and Toshio Fuchigami pp 13160–13161 DOI: 10.1021/ja0546931 Supporting Info

Fluorous-Based Carbohydrate Microarrays Kwang-Seuk Ko, Firoz A. Jaipuri, and Nicola L. Pohl pp 13162–13163 DOI: 10.1021/ja054811k Supporting Info

A Steroid-Conjugated Contrast Agent for Magnetic Resonance Imaging of Cell Signaling Jiyoun Lee, Mark J. Zylka, David J. Anderson, Joanna E. Burdette, Teresa K. Woodruff, and Thomas J. Meade pp 13164–13166 DOI: 10.1021/ja051294x Supporting Info

Nanocrystalline MgO for Asymmetric Henry and Michael Reactions Boyapati M. Choudary, Kalluri V. S. Ranganath, Ujjwal Pal, Mannepalli L. Kantam, and Bojja Sreedhar pp 13167–13171 DOI: 10.1021/ja0440248 Supporting Info

Pd-Mediated Activation of Molecular Oxygen in a Nonpolar Medium Jason M. Keith, Robert J. Nielsen, Jonas Oxgaard, and William A. Goddard III pp 13172–13179 DOI: 10.1021/ja043094b Supporting Info

DFT Investigation of H2 Activation by [M(NHPnPr3)(‘S3‘)] (M = Ni, Pd). Insight into Key Factors Relevant to the Design of Hydrogenase Functional Models Giuseppe Zampella, Maurizio Bruschi, Piercarlo Fantucci, and Luca De Gioia pp 13180–13189 DOI: 10.1021/ja0508424 Supporting Info

Theoretical Study on the Photolysis Mechanism of 2,3-Diazabicyclo[2.2.2]oct-2-ene Hui Chen and Shuhua Li pp 13190–13199 DOI: 10.1021/ja050002p Supporting Info

Amphiphilic Homopolymer as a Reaction Medium in Water:  Product Selectivity within Polymeric Nanopockets Selvanathan Arumugam, Dharma Rao Vutukuri, S. Thayumanavan, and V. Ramamurthy pp 13200–13206 DOI: 10.1021/ja051107v Supporting Info

NMR Spectroscopic Characterization of Millisecond Protein Folding by Transverse Relaxation Dispersion Measurements Markus Zeeb and Jochen Balbach pp 13207–13212 DOI: 10.1021/ja051141+

RNA Catalysis in Model Protocell Vesicles Irene A. Chen, Kourosh Salehi-Ashtiani, and Jack W. Szostak pp 13213–13219 DOI: 10.1021/ja051784p Supporting Info

Monitoring the Effects of Antagonists on Protein−Protein Interactions with NMR Spectroscopy Loyola D'Silva, Przemyslaw Ozdowy, Marcin Krajewski, Ulli Rothweiler, Mahavir Singh, and Tad A. Holak pp 13220–13226 DOI: 10.1021/ja052143x Supporting Info

Thermodynamics of DNA Hybridization on Gold Nanoparticles Jun Xu and Stephen L. Craig pp 13227–13231 DOI: 10.1021/ja052352h Supporting Info

Kinetics of Transient End-to-End Contact of Single-Stranded DNAs Kiyohiko Kawai, Hiroko Yoshida, Akira Sugimoto, Mamoru Fujitsuka, and Tetsuro Majima pp 13232–13237 DOI: 10.1021/ja0524999 Supporting Info

Conformational Dynamics of Phototropin 2 LOV2 Domain with the Linker upon Photoexcitation Takeshi Eitoku, Yusuke Nakasone, Daisuke Matsuoka, Satoru Tokutomi, and Masahide Terazima pp 13238–13244 DOI: 10.1021/ja052523i

Fidelity Discrimination in DNA Polymerase β:  Differing Closing Profiles for a Mismatched (G:A) versus Matched (G:C) Base Pair Ravi Radhakrishnan and Tamar Schlick pp 13245–13252 DOI: 10.1021/ja052623o Supporting Info

Double-Modification of Lectin Using Two Distinct Chemistries for Fluorescent Ratiometric Sensing and Imaging Saccharides in Test Tube or in Cell Eiji Nakata, Yoichiro Koshi, Erina Koga, Yoshiki Katayama, and Itaru Hamachi pp 13253–13261 DOI: 10.1021/ja052731a Supporting Info

Axinelloside A, an Unprecedented Highly Sulfated Lipopolysaccharide Inhibiting Telomerase, from the Marine Sponge, Axinella infundibula1 Kaoru Warabi, Toshiyuki Hamada, Yoichi Nakao, Shigeki Matsunaga, Hiroshi Hirota, Rob W. M. van Soest, and Nobuhiro Fusetani pp 13262–13270 DOI: 10.1021/ja052688r Supporting Info

Efficient Synthesis of a β-Peptide Combinatorial Library with Microwave Irradiation Justin K. Murray, Bilal Farooqi, Jack D. Sadowsky, Mark Scalf, Wesley A. Freund, Lloyd M. Smith, Jiandong Chen, and Samuel H. Gellman pp 13271–13280 DOI: 10.1021/ja052733v Supporting Info

A Highly π-Stacked Organic Semiconductor for Field-Effect Transistors Based on Linearly Condensed Pentathienoacene Kai Xiao, Yunqi Liu, Ting Qi, Wei Zhang, Fang Wang, Jianhua Gao, Wenfeng Qiu, Yongqiang Ma, Guanglei Cui, Shiyan Chen, Xiaowei Zhan, Gui Yu, Jingui Qin, Wenping Hu, and Daoben Zhu pp 13281–13286 DOI: 10.1021/ja052816b Supporting Info

From an Inactive Prokaryotic SOD Homologue to an Active Protein through Site-Directed Mutagenesis Lucia Banci, Manuela Benvenuti, Ivano Bertini, Diane E. Cabelli, Vito Calderone, Adele Fantoni, Stefano Mangani, Manuele Migliardi, and Maria Silvia Viezzoli pp 13287–13292 DOI: 10.1021/ja052790o Supporting Info

Multilabeled Pyrene-Functionalized 2‘-Amino-LNA Probes for Nucleic Acid Detection in Homogeneous Fluorescence Assays Patrick J. Hrdlicka, B. Ravindra Babu, Mads D. Sørensen, Niels Harrit, and Jesper Wengel pp 13293–13299 DOI: 10.1021/ja052887a Supporting Info

Supercapacitive Admittance Tomoscopy Jean Gamby, Jean-Pierre Abid, and Hubert H. Girault pp 13300–13304 DOI: 10.1021/ja050602o

Dialkylaminopyridine-Functionalized Mesoporous Silica Nanosphere as an Efficient and Highly Stable Heterogeneous Nucleophilic Catalyst Hung-Ting Chen, Seong Huh, Jerzy W. Wiench, Marek Pruski, and Victor S.-Y. Lin pp 13305–13311 DOI: 10.1021/ja0524898

pH Controls the Rate and Mechanism of Nitrosylation of Water-Soluble FeIII Porphyrin Complexes Maria Wolak and Rudi van Eldik pp 13312–13315 DOI: 10.1021/ja052855n Supporting Info

Potassium Ion Transport by Valinomycin across a Hg-Supported Lipid Bilayer Lucia Becucci, Maria Rosa Moncelli, Renate Naumann, and Rolando Guidelli pp 13316–13323 DOI: 10.1021/ja052920t Supporting Info

Aromaticity of Planar Boron Clusters Confirmed Jun-ichi Aihara, Hideaki Kanno, and Toshimasa Ishida pp 13324–13330 DOI: 10.1021/ja053171i

Side Reactions in Controlling the Quality, Yield, and Stability of High Quality Colloidal Nanocrystals Yongfen Chen, Myeongseob Kim, Guoda Lian, Mathew B. Johnson, and Xiaogang Peng pp 13331–13337 DOI: 10.1021/ja053151g Supporting Info

Structural Basis for the Enantioselectivity of an Epoxide Ring Opening Reaction Catalyzed by Halo Alcohol Dehalogenase HheC René M. de Jong, Jan J. W. Tiesinga, Alessandra Villa, Lixia Tang, Dick B. Janssen, and Bauke W. Dijkstra pp 13338–13343 DOI: 10.1021/ja0531733

New Photoswitching Unit for Magnetic Interaction:  Diarylethene with 2,5-Bis(arylethynyl)-3-thienyl Group Naoki Tanifuji, Masahiro Irie, and Kenji Matsuda pp 13344–13353 DOI: 10.1021/ja053200p Supporting Info

Strong Electronic Couplings between Ferrocenyl Centers Mediated by Bis-Ethynyl/Butadiynyl Diruthenium Bridges Guo-Lin Xu, Robert J. Crutchley, Maria C. DeRosa, Qing-Jiang Pan, Hong-Xing Zhang, Xiaoping Wang, and Tong Ren pp 13354–13363 DOI: 10.1021/ja0534452 Supporting Info

Incisive Structure−Spectroscopic Correlation in Oligothiophenes Functionalized with (±) Inductive/Mesomeric Fluorine Groups:  Joint Raman and DFT Study Juan Casado, Víctor Hernández, María C. Ruiz Delgado, Rocío P. Ortiz, Juan T. López Navarrete, Antonio Facchetti, and Tobin J. Marks pp 13364–13372 DOI: 10.1021/ja053296n Supporting Info

Nanochannel Array Plastics with Tailored Surface Chemistry Javid Rzayev and Marc A. Hillmyer pp 13373–13379 DOI: 10.1021/ja053731d Supporting Info

Sensitivity Improvement in 19F NMR-Based Screening Experiments:  Theoretical Considerations and Experimental Applications Claudio Dalvit, Nicola Mongelli, Gianluca Papeo, Patrizia Giordano, Marina Veronesi, Detlef Moskau, and Rainer Kümmerle pp 13380–13385 DOI: 10.1021/ja0542385

Enantioselective 1,3-Dipolar Cycloaddition of Nitrones to Methacrolein Catalyzed by (η5-C5Me5)M{(R)-Prophos} Containing Complexes (M = Rh, Ir; (R)-Prophos = 1,2-bis(Diphenylphosphino)propane):  On the Origin of the Enantioselectivity Daniel Carmona, M. Pilar Lamata, Fernando Viguri, Ricardo Rodríguez, Luis A. Oro, Fernando J. Lahoz, Ana I. Balana, Tomás Tejero, and Pedro Merino pp 13386–13398 DOI: 10.1021/ja0539443 Supporting Info

Three-Dimensional Nonlinear Optical Chromophores Based on Metal-to-Ligand Charge-Transfer from Ruthenium(II) or Iron(II) Centers Benjamin J. Coe, James A. Harris, Bruce S. Brunschwig, Inge Asselberghs, Koen Clays, Javier Garín, and Jesús Orduna pp 13399–13410 DOI: 10.1021/ja053879x Supporting Info

Synthesis and Characterization of Li[(Ni0.8Co0.1Mn0.1)0.8(Ni0.5Mn0.5)0.2]O2 with the Microscale Core−Shell Structure as the Positive Electrode Material for Lithium Batteries Yang-Kook Sun, Seung-Taek Myung, Myung-Hoon Kim, Jai Prakash, and Khalil Amine pp 13411–13418 DOI: 10.1021/ja053675g Supporting Info

Lewis Acid−Lewis Acid Heterobimetallic Cooperative Catalysis:  Mechanistic Studies and Application in Enantioselective Aza-Michael Reaction Noriyuki Yamagiwa, Hongbo Qin, Shigeki Matsunaga, and Masakatsu Shibasaki pp 13419–13427 DOI: 10.1021/ja054066b Supporting Info

Correlation between Isoniazid Resistance and Superoxide Reactivity in Mycobacterium tuberculosis KatG Reza A. Ghiladi, Katalin F. Medzihradszky, Frank M. Rusnak, and Paul R. Ortiz de Montellano pp 13428–13442 DOI: 10.1021/ja054366t Supporting Info

Issue 39

The Allylic Azide Rearrangement:  Achieving Selectivity Alina K. Feldman, Benoît Colasson, K. Barry Sharpless, and Valery V. Fokin pp 13444–13445 DOI: 10.1021/ja050622q Supporting Info

Molecular Models of Lipopeptide Detergents:  Large Coiled-Coils with Hydrocarbon Interiors Evan Kelly, Gilbert G. Privé, and D. Peter Tieleman pp 13446–13447 DOI: 10.1021/ja051275n Supporting Info

Loading of Hydrophobic Materials into Polymer Particles:  Implications for Fluorescent Nanosensors and Drug Delivery Huiguang Zhu and Michael J. McShane pp 13448–13449 DOI: 10.1021/ja052188y Supporting Info

Catalytic Enantioselective Synthesis of Glutamic Acid Derivatives via Tandem Conjugate Addition−Elimination of Activated Allylic Acetates under Chiral PTC Conditions P. Veeraraghavan Ramachandran, Sateesh Madhi, Layla Bland-Berry, M. Venkat Ram Reddy, and Martin J. O'Donnell pp 13450–13451 DOI: 10.1021/ja052638m Supporting Info

Delocalization of Free Electron Density through Phenylene−Ethynylene:  Structural Changes Studied by Time-Resolved Infrared Spectroscopy1 Dmitry E. Polyansky, Evgeny O. Danilov, Sergey V. Voskresensky, Michael A. J. Rodgers, and Douglas C. Neckers pp 13452–13453 DOI: 10.1021/ja053120l Supporting Info

Photoinduced Reversible Change of Fluid Viscosity Hideki Sakai, Yoichi Orihara, Hideki Kodashima, Atsutoshi Matsumura, Takahiro Ohkubo, Koji Tsuchiya, and Masahiko Abe pp 13454–13455 DOI: 10.1021/ja053323+ Supporting Info

Room-Temperature and Solution-State Observation of the Mixed-Valence Cation Radical Dimer of Tetrathiafulvalene, [(TTF)2]+•, within a Self-Assembled Cage Michito Yoshizawa, Kazuhisa Kumazawa, and Makoto Fujita pp 13456–13457 DOI: 10.1021/ja053508g Supporting Info

Superhydrophobic Perpendicular Nanopin Film by the Bottom-Up Process Eiji Hosono, Shinobu Fujihara, Itaru Honma, and Haoshen Zhou pp 13458–13459 DOI: 10.1021/ja053745j Supporting Info

Protein Film Electrochemistry of Microsomes Genetically Enriched in Human Cytochrome P450 Monooxygenases Nasreen Sultana, John B. Schenkman, and James F. Rusling pp 13460–13461 DOI: 10.1021/ja0538334 Supporting Info

A Structurally Perfect S = 1/2 Kagomé Antiferromagnet Matthew P. Shores, Emily A. Nytko, Bart M. Bartlett, and Daniel G. Nocera pp 13462–13463 DOI: 10.1021/ja053891p Supporting Info

Large-Scale Synthesis of Thiolated Au25 Clusters via Ligand Exchange Reactions of Phosphine-Stabilized Au11 Clusters Yukatsu Shichibu, Yuichi Negishi, Tatsuya Tsukuda, and Toshiharu Teranishi pp 13464–13465 DOI: 10.1021/ja053915s Supporting Info

Improving the Catalytic Activity of Candida antarctica Lipase B by Circular Permutation Zhen Qian and Stefan Lutz pp 13466–13467 DOI: 10.1021/ja053932h Supporting Info

On the Origin of High E Selectivity in the Wittig Reaction of Stabilized Ylides:  Importance of Dipole−Dipole Interactions Raphaël Robiette, Jeffery Richardson, Varinder K. Aggarwal, and Jeremy N. Harvey pp 13468–13469 DOI: 10.1021/ja0539589 Supporting Info

A Highly Reactive Mononuclear Zn(II) Complex for Phosphodiester Cleavage Guoqiang Feng, Juan C. Mareque-Rivas, R. Torres Martín de Rosales, and Nicholas H. Williams pp 13470–13471 DOI: 10.1021/ja054003t Supporting Info

Capturing Intermediate Structures of Alzheimer's β-Amyloid, Aβ(1−40), by Solid-State NMR Spectroscopy Sandra Chimon and Yoshitaka Ishii pp 13472–13473 DOI: 10.1021/ja054039l Supporting Info

Lanthanide Complexes for Second Order Nonlinear Optics:  Evidence for the Direct Contribution of f Electrons to the Quadratic Hyperpolarizability1 Nicolas Tancrez, Christophe Feuvrie, Isabelle Ledoux, Joseph Zyss, Loïc Toupet, Hubert Le Bozec, and Olivier Maury pp 13474–13475 DOI: 10.1021/ja054065j Supporting Info

High Electron Mobility in Solution-Cast and Vapor-Deposited Phenacyl−Quaterthiophene-Based Field-Effect Transistors:  Toward N-Type Polythiophenes Joseph A. Letizia, Antonio Facchetti, Charlotte L. Stern, Mark A. Ratner, and Tobin J. Marks pp 13476–13477 DOI: 10.1021/ja054276o Supporting Info

Anion Binding Motifs:  Topicity and Charge in Amidocryptands Sung Ok Kang, Douglas Powell, and Kristin Bowman-James pp 13478–13479 DOI: 10.1021/ja054332l Supporting Info

Macroscopic Expression of the Chirality of Amino Alcohols by a Double Amplification Mechanism in Liquid Crystalline Media Rienk Eelkema and Ben L. Feringa pp 13480–13481 DOI: 10.1021/ja054352n Supporting Info

Aligned Porous Materials by Directional Freezing of Solutions in Liquid CO2 Haifei Zhang, James Long, and Andrew I. Cooper pp 13482–13483 DOI: 10.1021/ja054353f Supporting Info

Sequential Energy and Electron Transfer in Aggregates of Tetrakis[oligo(p-phenylene vinylene)] Porphyrins and C60 in Water Martin Wolffs, Freek J. M. Hoeben, Edwin H. A. Beckers, Albertus P. H. J. Schenning, and E. W. Meijer pp 13484–13485 DOI: 10.1021/ja054406t Supporting Info

Multiway Decomposition of NMR Spectra with Coupled Evolution Periods Daniel Malmodin and Martin Billeter pp 13486–13487 DOI: 10.1021/ja0545822 Supporting Info

Experimental Evidence for the Reorganization of β-Strands within Aggregates of the Aβ(16−22) Peptide Sarah A. Petty and Sean M. Decatur pp 13488–13489 DOI: 10.1021/ja054663y Supporting Info

Reductive Alkylation of Proteins Using Iridium Catalyzed Transfer Hydrogenation Jesse M. McFarland and Matthew B. Francis pp 13490–13491 DOI: 10.1021/ja054686c Supporting Info

Hierarchical Assembly of SnO2 Nanorod Arrays on α-Fe2O3 Nanotubes:  A Case of Interfacial Lattice Compatibility Dong-Feng Zhang, Ling-Dong Sun, Chun-Jiang Jia, Zheng-Guang Yan, Li-Ping You, and Chun-Hua Yan pp 13492–13493 DOI: 10.1021/ja054771k Supporting Info

Autocatalytic Alkyne Cycloadditions:  Evidence for Colloidal Pt Catalysis Rowshan Ara Begum, Nripen Chanda, T. V. V. Ramakrishna, and Paul R. Sharp pp 13494–13495 DOI: 10.1021/ja054863+ Supporting Info

Total Synthesis of (+)-Lithospermic Acid by Asymmetric Intramolecular Alkylation via Catalytic C−H Bond Activation Steven J. O'Malley, Kian L. Tan, Anja Watzke, Robert G. Bergman, and Jonathan A. Ellman pp 13496–13497 DOI: 10.1021/ja052680h Supporting Info

Rhenium-Catalyzed Formation of Indene Frameworks via C−H Bond Activation:  [3+2] Annulation of Aromatic Aldimines and Acetylenes Yoichiro Kuninobu, Atsushi Kawata, and Kazuhiko Takai pp 13498–13499 DOI: 10.1021/ja0528174 Supporting Info

EPR and Infrared Spectroscopic Evidence That a Kinetically Competent Paramagnetic Intermediate is Formed When Acetyl-Coenzyme A Synthase Reacts with CO Simon J. George, Javier Seravalli, and Stephen W. Ragsdale pp 13500–13501 DOI: 10.1021/ja0528329 Supporting Info

Kinetic Resolution of α-Acetoxy N-Acyl Oxazolidinethiones by a Chiral O-Nucleophilic Acyl Transfer Catalyst Gregory T. Notte, Tarek Sammakia, and Peter J. Steel pp 13502–13503 DOI: 10.1021/ja053743z Supporting Info

Efficient Strategy for the Rapid Backbone Assignment of Membrane Proteins Nikola Trbovic, Christian Klammt, Alexander Koglin, Frank Löhr, Frank Bernhard, and Volker Dötsch pp 13504–13505 DOI: 10.1021/ja0540270

Coordination Environment of Aqueous Uranyl(VI) Ion Michael Bühl, Romain Diss, and Georges Wipff pp 13506–13507 DOI: 10.1021/ja054186j Supporting Info

A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Iad Bicontinuous Cubic Structure Fuqiang Zhang, Yan Meng, Dong Gu, Yan Yan, Chengzhong Yu, Bo Tu, and Dongyuan Zhao pp 13508–13509 DOI: 10.1021/ja0545721 Supporting Info

Catalytic Decarboxylative sp−sp3 Coupling Dinesh Kumar Rayabarapu and Jon A. Tunge pp 13510–13511 DOI: 10.1021/ja0542688 Supporting Info

Brønsted Acid-Promoted Cyclizations of 1-Siloxy-1,5-diynes Jianwei Sun and Sergey A. Kozmin pp 13512–13513 DOI: 10.1021/ja055054t Supporting Info

Total Synthesis of (−)-Scabronine G, an Inducer of Neurotrophic Factor Production Stephen P. Waters, Yuan Tian, Yue-Ming Li, and Samuel J. Danishefsky pp 13514–13515 DOI: 10.1021/ja055220x Supporting Info

Intact Size-Selected Aun Clusters on a TiO2(110)-(1 × 1) Surface at Room Temperature Xiao Tong, Lauren Benz, Paul Kemper, Horia Metiu, Michael T. Bowers, and Steven K. Buratto pp 13516–13518 DOI: 10.1021/ja052778w

Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47 Sandrine Bourrelly, Philip L. Llewellyn, Christian Serre, Franck Millange, Thierry Loiseau, and Gérard Férey pp 13519–13521 DOI: 10.1021/ja054668v

On the Development of Sensor Molecules that Display FeIII-amplified Fluorescence Julia L. Bricks, Anton Kovalchuk, Christian Trieflinger, Marianne Nofz, Michael Büschel, Alexei I. Tolmachev, Jörg Daub, and Knut Rurack pp 13522–13529 DOI: 10.1021/ja050652t

Elongation of Ordered Peptide Aggregate of an Amyloidogenic Hexapeptide NFGAIL Observed in Molecular Dynamics Simulations with Explicit Solvent Chun Wu, Hongxing Lei, and Yong Duan pp 13530–13537 DOI: 10.1021/ja050767x Supporting Info

Strikingly Long C···C Distances in 1,2-Disubstituted ortho-Carboranes and Their Dianions Josep M. Oliva, Neil L. Allan, Paul v. R. Schleyer, Clara Viñas, and Francesc Teixidor pp 13538–13547 DOI: 10.1021/ja052091b Supporting Info

Thermal Equilibrium of High- and Low-Spin Forms of Cytochrome P450 BM-3:  Repositioning of the Substrate? Tijana Jovanovic, Ramy Farid, Richard A. Friesner, and Ann E. McDermott pp 13548–13552 DOI: 10.1021/ja0524604

Low-Temperature Studies of Encapsulated Proteins Wade D. Van Horn, Alana K. Simorellis, and Peter F. Flynn pp 13553–13560 DOI: 10.1021/ja052805i

Midpoint Potentials of Hemes a and a3 in the Quinol Oxidase from Acidianus ambivalens are Inverted Smilja Todorovic, Manuela M. Pereira, Tiago M. Bandeiras, Miguel Teixeira, Peter Hildebrandt, and Daniel H. Murgida pp 13561–13566 DOI: 10.1021/ja052921l

Unique Emission from Polymer Based Lanthanide Alloys Raja Shunmugam and Gregory N. Tew pp 13567–13572 DOI: 10.1021/ja053048r Supporting Info

Deposition Precipitation for the Preparation of Carbon Nanofiber Supported Nickel Catalysts Martijn K. van der Lee, A. Jos van Dillen, Johannes H. Bitter, and Krijn P. de Jong pp 13573–13582 DOI: 10.1021/ja053038q

Electroenzymatic Reactions. Investigation of a Reductive Dehalogenase by Means of Electrogenerated Redox Cosubstrates Gabriele Diekert, Denitsa Gugova, Benoît Limoges, Marc Robert, and Jean-Michel Savéant pp 13583–13588 DOI: 10.1021/ja053403d

Total Synthesis of (+)-Amphidinolide A. Assembly of the Fragments Barry M. Trost, Stephen T. Wrobleski, John D. Chisholm, Paul E. Harrington, and Michael Jung pp 13589–13597 DOI: 10.1021/ja0533646 Supporting Info

Total Synthesis of (+)-Amphidinolide A. Structure Elucidation and Completion of the Synthesis Barry M. Trost, Paul E. Harrington, John D. Chisholm, and Stephen T. Wrobleski pp 13598–13610 DOI: 10.1021/ja053365y Supporting Info

Principal Active Species of Horseradish Peroxidase, Compound I:  A Hybrid Quantum Mechanical/Molecular Mechanical Study Etienne Derat, Shimrit Cohen, Sason Shaik, Ahmet Altun, and Walter Thiel pp 13611–13621 DOI: 10.1021/ja0534046 Supporting Info

Crystal Structures, Reactivity and Inferred Acylation Transition States for 2‘-Amine Substituted RNA Costin M. Gherghe, Joseph M. Krahn, and Kevin M. Weeks pp 13622–13628 DOI: 10.1021/ja053647y Supporting Info

Phosphine−Substrate Recognition through the C−H···O Hydrogen Bond:  Application to the Asymmetric Pauson−Khand Reaction Jordi Solà, Antoni Riera, Xavier Verdaguer, and Miguel A. Maestro pp 13629–13633 DOI: 10.1021/ja053653u Supporting Info

Structural and Dynamical Basis of Broad Substrate Specificity, Catalytic Mechanism, and Inhibition of Cytochrome P450 3A4 Hwangseo Park, Sangyoub Lee, and Junghun Suh pp 13634–13642 DOI: 10.1021/ja053809q Supporting Info

Insight into Enzymatic C−F Bond Formation from QM and QM/MM Calculations Hans Martin Senn, David O'Hagan, and Walter Thiel pp 13643–13655 DOI: 10.1021/ja053875s Supporting Info

Ferroelectric Liquid Crystals Induced by Dopants with Axially Chiral 2,2‘-Spirobiindan-1,1‘-dione Cores Christopher J. Boulton, Jeremy G. Finden, Eagranie Yuh, Jeffrey J. Sutherland, Michael D. Wand, Gang Wu, and Robert P. Lemieux pp 13656–13665 DOI: 10.1021/ja054322k Supporting Info

Metathesis Reaction of Formaldehyde Acetals:  An Easy Entry into the Dynamic Covalent Chemistry of Cyclophane Formation Roberta Cacciapaglia, Stefano Di Stefano, and Luigi Mandolini pp 13666–13671 DOI: 10.1021/ja054362o

Probing Competitive Enantioselective Approach Vectors Operating in the Jacobsen−Katsuki Epoxidation:  A Kinetic Study of Methyl-Substituted Styrenes Peter Fristrup, Brian B. Dideriksen, David Tanner, and Per-Ola Norrby pp 13672–13679 DOI: 10.1021/ja051851f Supporting Info

Variable-Temperature, Variable-Field Magnetic Circular Dichroism Studies of Tris-Hydroxy- and μ3-Oxo-Bridged Trinuclear Cu(II) Complexes:  Evaluation of Proposed Structures of the Native Intermediate of the Multicopper Oxidases Jungjoo Yoon, Liviu M. Mirica, T. Daniel P. Stack, and Edward I. Solomon pp 13680–13693 DOI: 10.1021/ja0525152 Supporting Info

Electrochemical and Chemical Formation of [Mn4IVO5(terpy)4(H2O)2]6+, in Relation with the Photosystem II Oxygen-Evolving Center Model [Mn2III,IVO2(terpy)2(H2O)2]3+ Carole Baffert, Sophie Romain, Aurélien Richardot, Jean-Claude Leprêtre, Bertrand Lefebvre, Alain Deronzier, and Marie-Noëlle Collomb pp 13694–13704 DOI: 10.1021/ja052595+ Supporting Info

Three-Membered Ring or Open Chain Molecule − (F3C)F2SiONMe2 a Model for the α-Effect in Silicon Chemistry Norbert W. Mitzel, Krunoslav Vojinović, Roland Fröhlich, Thomas Foerster, Heather E. Robertson, Konstantin B. Borisenko, and David W. H. Rankin pp 13705–13713 DOI: 10.1021/ja052865o Supporting Info

Organic Free Radicals in Superheated Water Studied by Muon Spin Spectroscopy Paul W. Percival, Jean-Claude Brodovitch, Khashayar Ghandi, Brett M. McCollum, and Iain McKenzie pp 13714–13719 DOI: 10.1021/ja0537070 Supporting Info

Chemical Synthesis of 23 kDa Glycoprotein by Repetitive Segment Condensation:  A Synthesis of MUC2 Basal Motif Carrying Multiple O-GalNAc Moieties Hironobu Hojo, Yoshiyuki Matsumoto, Yuko Nakahara, Emi Ito, Yusuke Suzuki, Minoru Suzuki, Akemi Suzuki, and Yoshiaki Nakahara pp 13720–13725 DOI: 10.1021/ja053711b Supporting Info

Highly Emissive Conjugated Polymer Excimers Youngmi Kim, Jean Bouffard, Steven E. Kooi, and Timothy M. Swager pp 13726–13731 DOI: 10.1021/ja053893+ Supporting Info

Polyphenyl Macrocyclic Oligophenylenes Qiuling Song, Christopher W. Lebeis, Xianfeng Shen, Douglas M. Ho, and Robert A. Pascal, Jr. pp 13732–13737 DOI: 10.1021/ja0541985 Supporting Info

Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes [J. Am. Chem. Soc. 2004, 126, 12325−12335]. Jye-Shane Yang, Kang-Ling Liau, Chin-Min Wang, and Chung-Yu Hwang p 13738 DOI: 10.1021/ja055119s

Regioselective Synthesis of Multifunctional Hybrid Polysiloxanes Achieved by Pt−Nanocluster Catalysis [J. Am. Chem. Soc. 2005, 127, 5790−5791]. Bhanu P. S. Chauhan and Jitendra S. Rathore p 13738 DOI: 10.1021/ja059915+

Magnetism:  Molecules to Materials V Edited by Joel S. Miller (University of Utah) and Marc Drillon (Institut de Physique et Chimie des Matériaux de Strasbourg). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2005. xiv + 381 pp. $190.00. ISBN 3-527-30665-X. Mark M. Turnbull p 13739 DOI: 10.1021/ja0597707

Chemistry and Physics of Carbon, Volume 29 Edited by Ljubisa R. Radovic (Pennsylvania State University). Marcel Dekker:  New York. 2004. xvi + 430 pp. $189.95. ISBN 0-8247-4088-2. Suresh C. Sharma pp 13739–13740 DOI: 10.1021/ja041047d

Templates in Chemistry I. Topics in Current Chemistry, 248 Edited by Christoph A. Schalley, Fritz Vögtle, and Karl H. Dötz (Kekule Institute für Organische Chemie and Biochemie, Bonn). Springer-Verlag:  Berlin, Heidelberg. 2004. x + 280 pp. $229.00. ISBN 3-540-22547-1. Photon Rao p 13740 DOI: 10.1021/ja059758e

Handbook of Prompt Gamma Activation Analysis with Neutron Beams Edited by Gábor L. Molnár (Chemical Research Centre, Budapest). Kluwer Academic Publishers:  Dordrecht, Boston, London. 2004. xvi + 424 pp. $180.00. ISBN 1-4020-1304-3. Sheldon Landsberger pp 13740–13741 DOI: 10.1021/ja059792t

Progress in Inorganic Chemistry, Volume 54 Edited by Kenneth Karlin (Johns Hopkins University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. viii + 536 pp. $150.00. ISBN 0-471-72348-7. Kenneth J. Klabunde p 13741 DOI: 10.1021/ja059796y

Principles and Applications of Density Functional Theory in Inorganic Chemistry, Vols. I and II. Structure and Bonding, Vols. 112 and 113 Edited by N. Kaltoyannis (University College London) and J. E. McGrady (University of York). Series edited by D. M. P. Mingos. Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 194 pp. $149.00. ISBN 3-540-21860-2 (Vol. 1) and x + 244 pp. $199.00. ISBN 3-540-21861-0 (Vol. 2). Michael B. Hall pp 13741–13742 DOI: 10.1021/ja0410385

Issue 40

Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111) Stephan Hermes, Felicitas Schröder, Rolf Chelmowski, Christof Wöll, and Roland A. Fischer pp 13744–13745 DOI: 10.1021/ja053523l Supporting Info

Synthesis of Organo-Silane Functionalized Nanocrystal Micelles and Their Self-Assembly Hongyou Fan, Zhu Chen, C. Jeffrey Brinker, Jacalyn Clawson, and Todd Alam pp 13746–13747 DOI: 10.1021/ja053795o Supporting Info

A Family of Main-Chain Polymeric Lewis Acids:  Synthesis and Fluorescent Sensing Properties of Boron-Modified Polythiophenes Anand Sundararaman, Maria Victor, Resmi Varughese, and Frieder Jäkle pp 13748–13749 DOI: 10.1021/ja0537880 Supporting Info

All-Aromatic, Nanometer-Scale, Gold-Cluster Thiolate Complexes Ryan C. Price and Robert L. Whetten pp 13750–13751 DOI: 10.1021/ja053968+ Supporting Info

[Cu3(μ-S)2]3+ Clusters Supported by N-Donor Ligands:  Progress Toward a Synthetic Model of the Catalytic Site of Nitrous Oxide Reductase Eric C. Brown, John T. York, William E. Antholine, Eliseo Ruiz, Santiago Alvarez, and William B. Tolman pp 13752–13753 DOI: 10.1021/ja053971t Supporting Info

Computational Study of the Mechanism of Cyclometalation by Palladium Acetate David L. Davies, Steven M. A. Donald, and Stuart A. Macgregor pp 13754–13755 DOI: 10.1021/ja052047w Supporting Info

Synthesis and Characterization of 3D CoPt Nanostructures Vassilios Tzitzios, Dimitrios Niarchos, Margariti Gjoka, Nikos Boukos, and Dimitrios Petridis pp 13756–13757 DOI: 10.1021/ja053044m

Visible Light Induced Reversible Extrusion of Nitric Oxide from a Ruthenium(II) Nitrosyl Complex:  A Facile Delivery of Nitric Oxide Raju Prakash, Alexander U. Czaja, Frank W. Heinemann, and Dieter Sellmann pp 13758–13759 DOI: 10.1021/ja053758x Supporting Info

Asymmetric Alkynylation of Aldehydes Catalyzed by an In(III)/BINOL Complex Ryo Takita, Kenichiro Yakura, Takashi Ohshima, and Masakatsu Shibasaki pp 13760–13761 DOI: 10.1021/ja053946n Supporting Info

pH Variation as the Switch for Chiral Recognition in a Biomembrane Model Francesca Ceccacci, Giovanna Mancini, Alessio Sferrazza, and Claudio Villani pp 13762–13763 DOI: 10.1021/ja053961s Supporting Info

The Direct Detection of an Aryl Azide Excited State:  An Ultrafast Study of the Photochemistry of para- and ortho-Biphenyl Azide Gotard T. Burdzinski, Terry L. Gustafson, John C Hackett, Christopher M. Hadad, and Matthew S. Platz pp 13764–13765 DOI: 10.1021/ja054135m

Investigating Bacterial N-Linked Glycosylation:  Synthesis and Glycosyl Acceptor Activity of the Undecaprenyl Pyrophosphate-Linked Bacillosamine Eranthie Weerapana, Kerney Jebrell Glover, Mark M. Chen, and Barbara Imperiali pp 13766–13767 DOI: 10.1021/ja054265v Supporting Info

Improved Excitation Schemes for Multiple-Quantum Magic-Angle Spinning for Quadrupolar Nuclei Designed Using Optimal Control Theory Thomas Vosegaard, Cindie Kehlet, Navin Khaneja, Steffen J. Glaser, and Niels Chr. Nielsen pp 13768–13769 DOI: 10.1021/ja054035g Supporting Info

A C2-Symmetric, Living α-Diimine Ni(II) Catalyst:  Regioblock Copolymers from Propylene Anna E. Cherian, Jeffrey M. Rose, Emil B. Lobkovsky, and Geoffrey W. Coates pp 13770–13771 DOI: 10.1021/ja0540021 Supporting Info

Recent Advances in Characterization of CaCu3Ti4O12 Thin Films by Spectroscopic Ellipsometric Metrology Raffaella Lo Nigro, Graziella Malandrino, Roberta G. Toro, Maria Losurdo, Giovanni Bruno, and Ignazio L. Fragalà pp 13772–13773 DOI: 10.1021/ja0541229 Supporting Info

Synthesis, Structure, and Reactivity of a Zirconocene−Carboryne Precursor Liang Deng, Hoi-Shan Chan, and Zuowei Xie pp 13774–13775 DOI: 10.1021/ja054207+ Supporting Info

Photochemical Generation of a Highly Reactive Iron−Oxo Intermediate. A True Iron(V)−Oxo Species? Dilusha N. Harischandra, Rui Zhang, and Martin Newcomb pp 13776–13777 DOI: 10.1021/ja0542439 Supporting Info

Fast Peptidyl cis−trans Isomerization within the Flexible Gly-Rich Flaps of HIV-1 Protease Donald Hamelberg and J. Andrew McCammon pp 13778–13779 DOI: 10.1021/ja054338a Supporting Info

A Peptide Motif Recognizing a Polymer Stereoregularity Takeshi Serizawa, Toshiki Sawada, Hisao Matsuno, Teruhiko Matsubara, and Toshinori Sato pp 13780–13781 DOI: 10.1021/ja054402o Supporting Info

Diamond-Hexagonal Semiconductor Nanocones with Controllable Apex Angle Linyou Cao, Lee Laim, Chaoying Ni, Bahram Nabet, and Jonathan E. Spanier pp 13782–13783 DOI: 10.1021/ja0544814 Supporting Info

The α-Helix Folds More Rapidly at the C-Terminus Than at the N-Terminus Angela Pozo Ramajo, Sarah A. Petty, Agnieszka Starzyk, Sean M. Decatur, and Martin Volk pp 13784–13785 DOI: 10.1021/ja054500+

Flash Ignition and Initiation of Explosives−Nanotubes Mixture M. Riad Manaa, Alexander R. Mitchell, Raul G. Garza, Philip F. Pagoria, and Bruce E. Watkins pp 13786–13787 DOI: 10.1021/ja0547127

A Microfluidic Biomaterial Mario Cabodi, Nak Won Choi, Jason P. Gleghorn, Christopher S. D. Lee, Lawrence J. Bonassar, and Abraham D. Stroock pp 13788–13789 DOI: 10.1021/ja054820t Supporting Info

A Polar Oxide with a Large Magnetization Synthesized at Ambient Pressure Helen Hughes, Mathieu M. B. Allix, Craig A. Bridges, John B. Claridge, Xiaojun Kuang, Hongjun Niu, Stephen Taylor, Wenhai Song, and Matthew J. Rosseinsky pp 13790–13791 DOI: 10.1021/ja054839w Supporting Info

High-Yield Synthesis of Single-Crystalline Antimony Telluride Hexagonal Nanoplates Using a Solvothermal Approach Wenzhong Wang,Wenzhong Wang, Bed Poudel, Jian Yang, D. Z. Wang, and Z. F. Ren pp 13792–13793 DOI: 10.1021/ja054861p

Two-Photon Absorption in Aqueous Micellar Solutions Han Young Woo, Dmitry Korystov, Alexander Mikhailovsky, Thuc-Quyen Nguyen, and Guillermo C. Bazan pp 13794–13795 DOI: 10.1021/ja054911q Supporting Info

Stereocontrolled Synthesis of Spiroketals via a Remarkable Methanol-Induced Kinetic Spirocyclization Reaction Justin S. Potuzak, Sirkka B. Moilanen, and Derek S. Tan pp 13796–13797 DOI: 10.1021/ja055033z Supporting Info

Thiourea-Based Bifunctional Organocatalysis:  Supramolecular Recognition for Living Polymerization Andrew P. Dove, Russell C. Pratt, Bas G. G. Lohmeijer, Robert M. Waymouth, and James L. Hedrick pp 13798–13799 DOI: 10.1021/ja0543346 Supporting Info

Plasmonic Nanoparticle Chains via a Morphological, Sphere-to-String Transition Youngjong Kang, Kris J. Erickson, and T. Andrew Taton pp 13800–13801 DOI: 10.1021/ja055090s Supporting Info

Selective Precipitation of Prions by Polyoxometalate Complexes In Su Lee, Jeffrey R. Long, Stanley B. Prusiner, and Jiri G. Safar pp 13802–13803 DOI: 10.1021/ja055219y Supporting Info

Dynamic Chiral Selection and Amplification Using Photoresponsive Organogelators Jaap J. D. de Jong, Theodora D. Tiemersma-Wegman, Jan H. van Esch, and Ben L. Feringa pp 13804–13805 DOI: 10.1021/ja055268a Supporting Info

Cross-Conjugated Oligothiophenes Derived from the (C2S)n Helix:  Asymmetric Synthesis and Structure of Carbon−Sulfur [11]Helicene Makoto Miyasaka, Andrzej Rajca, Maren Pink, and Suchada Rajca pp 13806–13807 DOI: 10.1021/ja055414c Supporting Info

Organic Nanodielectrics for Low Voltage Carbon Nanotube Thin Film Transistors and Complementary Logic Gates Seung-Hyun Hur, Myung-Han Yoon, Anshu Gaur, Moonsub Shim, Antonio Facchetti, Tobin J. Marks, and John A. Rogers pp 13808–13809 DOI: 10.1021/ja0553203 Supporting Info

Enantioselective Synthesis of Apoptolidinone:  Exploiting the Versatility of Thiazolidinethione Chiral Auxiliaries Michael T. Crimmins, Hamish S. Christie, Kleem Chaudhary, and Alan Long pp 13810–13812 DOI: 10.1021/ja0549289 Supporting Info

Enantioselective Total Synthesis of Isoedunol and β-Araneosene Featuring Unconventional Strategy and Methodology Jason S. Kingsbury and E. J. Corey pp 13813–13815 DOI: 10.1021/ja055137+ Supporting Info

Observation of Ligand Binding to Cytochrome P450 BM-3 by Means of Solid-State NMR Spectroscopy Tijana Jovanovic and Ann E. McDermott pp 13816–13821 DOI: 10.1021/ja0438314

How Enzyme Dynamics Helps Catalyze a Reaction in Atomic Detail:  A Transition Path Sampling Study Jodi E. Basner and Steven D. Schwartz pp 13822–13831 DOI: 10.1021/ja043320h

Spectroscopic and Electronic Structure Studies of the Trinuclear Cu Cluster Active Site of the Multicopper Oxidase Laccase:  Nature of Its Coordination Unsaturation Liliana Quintanar, Jungjoo Yoon, Constantino P. Aznar, Amy E. Palmer, K. Kristoffer Andersson, R. David Britt, and Edward I. Solomon pp 13832–13845 DOI: 10.1021/ja0421405 Supporting Info

Control of Localized Nanorod Formation and Patterns of Semiconducting CuTCNQ Phase I Crystals by Scanning Electrochemical Microscopy Aaron K. Neufeld, Anthony P. O'Mullane, and Alan M. Bond pp 13846–13853 DOI: 10.1021/ja050561w Supporting Info

High-Temperature Microfluidic Synthesis of CdSe Nanocrystals in Nanoliter Droplets Emory M. Chan, A. Paul Alivisatos, and Richard A. Mathies pp 13854–13861 DOI: 10.1021/ja051381p

Dendrimer-Based Transient Supramolecular Networks Ron M. Versteegen, D. J. M. van Beek, Rint P. Sijbesma, Dimitris Vlassopoulos, George Fytas, and E. W. Meijer pp 13862–13868 DOI: 10.1021/ja051775g Supporting Info

Selective and Controlled Synthesis of α- and β-Cobalt Hydroxides in Highly Developed Hexagonal Platelets Zhaoping Liu, Renzhi Ma, Minoru Osada, Kazunori Takada, and Takayoshi Sasaki pp 13869–13874 DOI: 10.1021/ja0523338 Supporting Info

All-cis Cyclic Peptides Romuald Poteau and Georges Trinquier pp 13875–13889 DOI: 10.1021/ja052342g Supporting Info

Specific Adenine Alkylation by Pyrrole−Imidazole CBI Conjugates Toshikazu Bando, Akihiko Narita, Shunta Sasaki, and Hiroshi Sugiyama pp 13890–13895 DOI: 10.1021/ja052412j

Probing Stepwise Complexation in Phenylazomethine Dendrimers by a Metallo-Porphyrin Core Takane Imaoka, Reiko Tanaka, Sachiko Arimoto, Makoto Sakai, Masaaki Fujii, and Kimihisa Yamamoto pp 13896–13905 DOI: 10.1021/ja0524797 Supporting Info

Dynamic Behavior of DNA Base Pairs Containing 8-Oxoguanine Xiaolin Cheng, Catherine Kelso, Viktor Hornak, Carlos de los Santos, Arthur P. Grollman, and Carlos Simmerling pp 13906–13918 DOI: 10.1021/ja052542s Supporting Info

Intermolecular Packing and Alignment in an Ordered β-Hairpin Antimicrobial Peptide Aggregate from 2D Solid-State NMR Ming Tang, Alan J. Waring, and Mei Hong pp 13919–13927 DOI: 10.1021/ja0526665 Supporting Info

Profiling pH Gradients Across Nanocapillary Array Membranes Connecting Microfluidic Channels Keqing Fa, Joseph J. Tulock, Jonathan V. Sweedler, and Paul W. Bohn pp 13928–13933 DOI: 10.1021/ja052708p Supporting Info

Direct Chemical Synthesis of Chiral Methanol of 98% ee and Its Conversion to [2H1,3H]Methyl Tosylate and [2H1,3H-Methyl]Methionine Biljana Peric Simov, Frank Wuggenig, Kurt Mereiter, Hendrik Andres, Julien France, Peter Schnelli, and Friedrich Hammerschmidt pp 13934–13940 DOI: 10.1021/ja051568g Supporting Info

Structure Analyses of Dodecylated Single-Walled Carbon Nanotubes Feng Liang, Lawrence B. Alemany, Jonathan M. Beach, and W. Edward Billups pp 13941–13948 DOI: 10.1021/ja052870s Supporting Info

Measurement of the Dependence of Interfacial Charge-Transfer Rate Constants on the Reorganization Energy of Redox Species at n-ZnO/H2O Interfaces Thomas W. Hamann, Florian Gstrein, Bruce S. Brunschwig, and Nathan S. Lewis pp 13949–13954 DOI: 10.1021/ja0515452

Chelate Bis(imino)pyridine Cobalt Complexes:  Synthesis, Reduction, and Evidence for the Generation of Ethene Polymerization Catalysts by Li+ Cation Activation Nina Kleigrewe, Winfried Steffen, Tobias Blömker, Gerald Kehr, Roland Fröhlich, Birgit Wibbeling, Gerhard Erker, Julia-Christina Wasilke, Guang Wu, and Guillermo C. Bazan pp 13955–13968 DOI: 10.1021/ja052129k Supporting Info

Formation of Intrastrand Cross-Link Products between Cytosine and Adenine from UV Irradiation of d(BrCA) and Duplex DNA Containing a 5-Bromocytosine Haizheng Hong and Yinsheng Wang pp 13969–13977 DOI: 10.1021/ja0531677 Supporting Info

Neutral and Cationic VIV/VV Mixed-Valence Alkoxo-polyoxovanadium Clusters [V6O7(OR)12]n+ (R = −CH3, −C2H5):  Structural, Cyclovoltammetric and IR-Spectroscopic Investigations on Mixed Valency in a Hexanuclear Core Charles Daniel and Hans Hartl pp 13978–13987 DOI: 10.1021/ja052902b Supporting Info

Kinetic and Mechanistic Studies of Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases Cindy-Xing Yin and Richard G. Finke pp 13988–13996 DOI: 10.1021/ja052998+ Supporting Info

Probing Ruthenium−Acetylide Bonding Interactions:  Synthesis, Electrochemistry, and Spectroscopic Studies of Acetylide−Ruthenium Complexes Supported by Tetradentate Macrocyclic Amine and Diphosphine Ligands Chun-Yuen Wong, Chi-Ming Che, Michael C. W. Chan, Jie Han, King-Hung Leung, David Lee Phillips, Kwok-Yin Wong, and Nianyong Zhu pp 13997–14007 DOI: 10.1021/ja053076+ Supporting Info

Heterometallic Chalcogenido Clusters Containing Lanthanides and Main Group Metals:  Emissive Precursors to Ternary Solid-State Compounds Anna Kornienko, Santanu Banerjee, G. Ajith Kumar, Richard E. Riman, Thomas J. Emge, and John G. Brennan pp 14008–14014 DOI: 10.1021/ja0534708 Supporting Info

d0 Re-Based Olefin Metathesis Catalysts, Re(CR)(CHR)(X)(Y):  The Key Role of X and Y Ligands for Efficient Active Sites Xavier Solans-Monfort, Eric Clot, Christophe Copéret, and Odile Eisenstein pp 14015–14025 DOI: 10.1021/ja053528i Supporting Info

Role of the Cocatalyst in the Copolymerization of CO2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes Donald J. Darensbourg and Ryan M. Mackiewicz pp 14026–14038 DOI: 10.1021/ja053544f Supporting Info

Intramolecular NH···S Hydrogen Bonding in the Zinc Thiolate Complex [TmPh]ZnSCH2C(O)NHPh:  A Mechanistic Investigation of Thiolate Alkylation as Probed by Kinetics Studies and by Kinetic Isotope Effects Melissa M. Morlok, Kevin E. Janak, Guang Zhu, Duncan A. Quarless, and Gerard Parkin pp 14039–14050 DOI: 10.1021/ja0536670 Supporting Info

Kinetics and Mechanism of N2 Hydrogenation in Bis(cyclopentadienyl) Zirconium Complexes and Dinitrogen Functionalization by 1,2-Addition of a Saturated C−H Bond Wesley H. Bernskoetter, Emil Lobkovsky, and Paul J. Chirik pp 14051–14061 DOI: 10.1021/ja0538841 Supporting Info

Reduction of Imines by Hydroxycyclopentadienyl Ruthenium Hydride:  Intramolecular Trapping Evidence for Hydride and Proton Transfer Outside the Coordination Sphere of the Metal Charles P. Casey, Galina A. Bikzhanova, Qiang Cui, and Ilia A. Guzei pp 14062–14071 DOI: 10.1021/ja053956o Supporting Info

A Flexible Docking Procedure for the Exploration of Peptide Binding Selectivity to Known Structures and Homology Models of PDZ Domains Masha Y. Niv and Harel Weinstein pp 14072–14079 DOI: 10.1021/ja054195s Supporting Info

Determination of the Conformation of Trimethoprim in the Binding Pocket of Bovine Dihydrofolate Reductase from a STD-NMR Intensity-Restrained CORCEMA-ST Optimization V. Jayalakshmi and N. Rama Krishna pp 14080–14084 DOI: 10.1021/ja054192f

The Structure of the Homogeneous Oxidation Catalyst, Mn(II)(Br-1)x, in Supercritical Water:  An X-ray Absorption Fine-Structure Study Yongsheng Chen, John L. Fulton, and Walter Partenheimer pp 14085–14093 DOI: 10.1021/ja053421v Supporting Info

La4Cu3-xZnxMoO12:  Zinc-Doped Cuprates with Kagomé Lattices Guobao Li, Liping You, Wutao Wei, Yue Lu, Jing Ju, Anders Wannberg, Håkan Rundlöf, Xiaodong Zou, Tao Yang, Shujian Tian, Fuhui Liao, Naoki Toyota, and Jianhua Lin pp 14094–14099 DOI: 10.1021/ja053489a Supporting Info

argE-Encoded N-Acetyl-l-Ornithine Deacetylase from Escherichia coli Contains a Dinuclear Metalloactive Site Wade C. McGregor, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz pp 14100–14107 DOI: 10.1021/ja054081g

Self-Assembly of Designed Oligomeric Siloxanes with Alkyl Chains into Silica-Based Hybrid Mesostructures Atsushi Shimojima, Zheng Liu, Tetsu Ohsuna, Osamu Terasaki, and Kazuyuki Kuroda pp 14108–14116 DOI: 10.1021/ja0541736 Supporting Info

Characterization of Porous Solids and Powders:  Surface Area, Pore Size and Density By S. Lowell (Quantachrome Instruments, Boynton Beach), J. E. Shields (C. W. Post Campus of Long Island University), M. A. Thomas, and M. Thommes (Quantachrome In-struments). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xiv + 348 pp. $159.00. ISBN 1-4020-2302-2. Mohamed Eddaoudi p 14117 DOI: 10.1021/ja041016i

Molecularly Imprinted Materials:  Science and Technology Edited by Mingdi Yan (Portland State University) and Olof Ramström (Royal Institute of Technology, Stockholm). Marcel Dekker:  New York. 2005. xiv + 734 pp. $179.95. ISBN 0-8247-5353-4. Bruce P. Branchaud pp 14117–14118 DOI: 10.1021/ja041037c

Nanophotonics By Paras N. Prasad (SUNY, Buffalo). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xvi + 416 pp. $84.95. ISBN 0-471-64988-0. Gary A. Baker pp 14118–14119 DOI: 10.1021/ja041022e

Ultrathin Electrochemical Chemo- and Biosensors:  Technology and Performance. Springer Series on Chemical Sensors and Biosensors, 02 Edited by Vladimir M. Mirsky (University of Regensburg). Series edited by Otto S. Wolfbeis. Springer-Verlag:  Berlin, Heidelberg. 2004. xx + 358 pp. $129.00. ISBN 3-540-21285-X. John T. McDevitt pp 14119–14120 DOI: 10.1021/ja041045t

Issue 41

Enzymatic Fabrication of DNA Nanostructures:  Extension of a Self-assembled Oligonucleotide Monolayer on Gold Arrays Dominic C. Chow, Woo-Kyung Lee, Stefan Zauscher, and Ashutosh Chilkoti pp 14122–14123 DOI: 10.1021/ja052491z Supporting Info

Dispersing Nanotubes with Surfactants:  A Microscopic Statistical Mechanical Analysis Nikhil Patel and Sergei A. Egorov pp 14124–14125 DOI: 10.1021/ja0530570 Supporting Info

Revisiting Noncovalent SO2−Amine Chemistry:  An Indicator−Displacement Assay for Colorimetric Detection of SO2 Alexander V. Leontiev and Dmitry M. Rudkevich pp 14126–14127 DOI: 10.1021/ja053260v Supporting Info

In Vitro Reconstitution of EryCIII Activity for the Preparation of Unnatural Macrolides Yanqiu Yuan, Hak Suk Chung, Catherine Leimkuhler, Christopher T. Walsh, Daniel Kahne, and Suzanne Walker pp 14128–14129 DOI: 10.1021/ja053704n Supporting Info

Completely Geometrically Optimized DFT/ONIOM Triple-Helical Collagen-like Structures Containing the ProProGly, ProProAla, ProProDAla, and ProProDSer Triads Midas (I-Hsien) Tsai, Yujia Xu, and J. J. Dannenberg pp 14130–14131 DOI: 10.1021/ja053768y Supporting Info

Enzyme Redesign:  Two Mutations Cooperate to Convert Cycloartenol Synthase into an Accurate Lanosterol Synthase Silvia Lodeiro, Tanja Schulz-Gasch, and Seiichi P. T. Matsuda pp 14132–14133 DOI: 10.1021/ja053791j Supporting Info

Separate Metal Requirements for Loop Interactions and Catalysis in the Extended Hammerhead Ribozyme Nak-Kyoon Kim, Ayaluru Murali, and Victoria J. DeRose pp 14134–14135 DOI: 10.1021/ja0541027 Supporting Info

Methyltransferase-Directed DNA Strand Scission Lindsay R. Comstock and Scott R. Rajski pp 14136–14137 DOI: 10.1021/ja054128y Supporting Info

A Supramolecular Fluorescence Sensor for Pyrovanadate as a Functional Model of Vanadium Haloperoxidase Xiao-an Zhang and Wolf-D. Woggon pp 14138–14139 DOI: 10.1021/ja053209r Supporting Info

Morphogenesis of Highly Ordered Mixed-Valent Mesoporous Molybdenum Oxides Jinglu Chen, Christian Burger, Chirakkal V. Krishnan, and Benjamin Chu pp 14140–14141 DOI: 10.1021/ja054023v Supporting Info

A General Route for Post-Translational Cyclization of mRNA Display Libraries Steven W. Millward, Terry T. Takahashi, and Richard W. Roberts pp 14142–14143 DOI: 10.1021/ja054373h Supporting Info

Photophysical Properties of [Ru(phen)2(dppz)]2+ Intercalated into DNA:  An Integrated Car−Parrinello and TDDFT Study Simona Fantacci, Filippo De Angelis, Antonio Sgamellotti, Alessandro Marrone, and Nazzareno Re pp 14144–14145 DOI: 10.1021/ja054368d Supporting Info

Enhancing 2-Iodoxybenzoic Acid Reactivity by Exploiting a Hypervalent Twist Julius T. Su and William A. Goddard III pp 14146–14147 DOI: 10.1021/ja054446x Supporting Info

Potent, Selective Pyrone-Based Inhibitors of Stromelysin-1 David T. Puerta, John Mongan, Ba L. Tran, J. Andrew McCammon, and Seth M. Cohen pp 14148–14149 DOI: 10.1021/ja054558o Supporting Info

Selective Dye-Labeling of Newly Synthesized Proteins in Bacterial Cells Kimberly E. Beatty, Fang Xie, Qian Wang, and David A. Tirrell pp 14150–14151 DOI: 10.1021/ja054643w Supporting Info

Cross Dipole Stacking in the Crystal of Distyrylbenzene Derivative:  The Approach toward High Solid-State Luminescence Efficiency Zengqi Xie, Bing Yang, Feng Li, Gang Cheng, Linlin Liu, Guangdi Yang, Hai Xu, Ling Ye, Muddasir Hanif, Shiyong Liu, Dongge Ma, and Yuguang Ma pp 14152–14153 DOI: 10.1021/ja054661d Supporting Info

Preparation of Fullerene−Polyyne Nanospheres via Thermally Induced Solid-State Polymerization Ningzhang Zhou, Erika F. Merschrod S., and Yuming Zhao pp 14154–14155 DOI: 10.1021/ja054669n Supporting Info

Narrow Pore-Diameter Polypyrrole Nanotubes Xinyu Zhang and Sanjeev K. Manohar pp 14156–14157 DOI: 10.1021/ja054789v Supporting Info

Synthesis of Functionalized Asymmetric Star Polymers Containing Conductive Polyacetylene Segments by Living Anionic Polymerization Youliang Zhao, Tomoya Higashihara, Kenji Sugiyama, and Akira Hirao pp 14158–14159 DOI: 10.1021/ja054821l Supporting Info

Design and Construction of a 2D Metal Organic Framework with Multiple Cavities:  A Nonregular Net with a Paracyclophane that Codes for Multiply Fused Nodes Giannis S. Papaefstathiou, Tomislav Frišić, and Leonard R. MacGillivray pp 14160–14161 DOI: 10.1021/ja054841n Supporting Info

Temperature- or Guest-Induced Drastic Single-Crystal-to-Single-Crystal Transformations of a Nanoporous Coordination Polymer Jie-Peng Zhang, Yan-Yong Lin, Wei-Xiong Zhang, and Xiao-Ming Chen pp 14162–14163 DOI: 10.1021/ja054913a Supporting Info

An NMR Determination of CO Diffusion on Platinum Electrocatalysts Takeshi Kobayashi, Panakkattu K. Babu, Lajos Gancs, Jong Ho Chung, Eric Oldfield, and Andrzej Wieckowski pp 14164–14165 DOI: 10.1021/ja0550475 Supporting Info

Stable Metallic Behavior and Antiferromagnetic Ordering of Fe(III) d Spins in (EDO-TTFVO)2·FeCl4 Hideki Fujiwara, Kenji Wada, Takashi Hiraoka, Toshiki Hayashi, Toyonari Sugimoto, Hiroyuki Nakazumi, Keiichi Yokogawa, Masayasu Teramura, Syuma Yasuzuka, Keizo Murata, and Takehiko Mori pp 14166–14167 DOI: 10.1021/ja055263d Supporting Info

Self-Assembly of Programmed Building Blocks into Structurally Uniform Dendrimers Yuliya Rudzevich, Valentyn Rudzevich, Chulsoon Moon, Ingo Schnell, Karl Fischer, and Volker Böhmer pp 14168–14169 DOI: 10.1021/ja055357n Supporting Info

Transformation of Isotropic Fluid to Nematic Gel Triggered by Dynamic Bridging of Supramolecular Nanocylinders Ja-Hyoung Ryu and Myongsoo Lee pp 14170–14171 DOI: 10.1021/ja055583x Supporting Info

CH Activation with an O-Donor Iridium−Methoxo Complex William J. Tenn, III, Kenneth J. H. Young, Gaurav Bhalla, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana pp 14172–14173 DOI: 10.1021/ja051497l Supporting Info

Evidence for the Net Addition of Arene C−H Bonds across a Ru(II)−Hydroxide Bond Yuee Feng, Marty Lail, Khaldoon A. Barakat, Thomas R. Cundari, T. Brent Gunnoe, and Jeffrey L. Petersen pp 14174–14175 DOI: 10.1021/ja054101e Supporting Info

Persistence Length Control of the Polyelectrolyte Layer-by-Layer Self-Assembly on Carbon Nanotubes Shih-Chieh J. Huang, Alexander B. Artyukhin, Yinmin Wang, Jiann-Wen Ju, Pieter Stroeve, and Aleksandr Noy pp 14176–14177 DOI: 10.1021/ja053060j Supporting Info

Atomic Layer Deposition in Nanometer-Level Replication of Cellulosic Substances and Preparation of Photocatalytic TiO2/Cellulose Composites Marianna Kemell, Viljami Pore, Mikko Ritala, Markku Leskelä, and Mika Lindén pp 14178–14179 DOI: 10.1021/ja0532887

Gold(III)-Catalyzed Nucleophilic Substitution of Propargylic Alcohols Marie Georgy, Valérie Boucard, and Jean-Marc Campagne pp 14180–14181 DOI: 10.1021/ja0534147 Supporting Info

Biradical Intermediate in the [2 + 2] Photocycloaddition of Dienes and Alkenes to [60]Fullerene Maria Hatzimarinaki, Manolis M. Roubelakis, and Michael Orfanopoulos pp 14182–14183 DOI: 10.1021/ja053431w Supporting Info

Shape-Controlled Synthesis of Manganese Oxide Octahedral Molecular Sieve Three-Dimensional Nanostructures Jikang Yuan, Wei-Na Li, Sinue Gomez, and Steven L. Suib pp 14184–14185 DOI: 10.1021/ja053463j

Dynamic Kinetic Asymmetric Allylic Alkylations of Allenes Barry M. Trost, Daniel R. Fandrick, and Diana C. Dinh pp 14186–14187 DOI: 10.1021/ja0543705 Supporting Info

Diazeniumdiolate Ions as Leaving Groups in Anomeric Displacement Reactions:  A Protection−Deprotection Strategy for Ionic Diazeniumdiolates Brett M. Showalter, Melissa M. Reynolds, Carlos A. Valdez, Joseph E. Saavedra, Keith M. Davies, John R. Klose, Gwendolyn N. Chmurny, Michael L. Citro, Joseph J. Barchi, Jr., Scott I. Merz, Mark E. Meyerhoff, and Larry K. Keefer pp 14188–14189 DOI: 10.1021/ja054510a Supporting Info

Dehydroaromatization of Quinoxalines:  One-Step Syntheses of Trinuclear 1,6,7,12,13,18-Hexaazatrinaphthylene Titanium Complexes Ingmar M. Piglosiewicz, Ruediger Beckhaus, Wolfgang Saak, and Detlev Haase pp 14190–14191 DOI: 10.1021/ja054740p Supporting Info

Alkylation of Magnesium Enamide with Alkyl Chlorides and Fluorides Takuji Hatakeyama, Shingo Ito, Masaharu Nakamura, and Eiichi Nakamura pp 14192–14193 DOI: 10.1021/ja055306q Supporting Info

Simple Alkenes as Substitutes for Organometallic Reagents:  Nickel-Catalyzed, Intermolecular Coupling of Aldehydes, Silyl Triflates, and Alpha Olefins Sze-Sze Ng and Timothy F. Jamison pp 14194–14195 DOI: 10.1021/ja055363j Supporting Info

Activation of C−H Bonds of Arenes:  Selectivity and Reactivity in Bis(pyridyl) Platinum(II) Complexes Fenbao Zhang, Christopher W. Kirby, Douglas W. Hairsine, Michael C. Jennings, and Richard J. Puddephatt pp 14196–14197 DOI: 10.1021/ja055436z Supporting Info

N-Tosyloxycarbamates as a Source of Metal Nitrenes:  Rhodium-Catalyzed C−H Insertion and Aziridination Reactions Hélène Lebel, Kim Huard, and Sylvain Lectard pp 14198–14199 DOI: 10.1021/ja0552850 Supporting Info

Total Synthesis of (±)-Garsubellin A Akiyoshi Kuramochi, Hiroyuki Usuda, Kenzo Yamatsugu, Motomu Kanai, and Masakatsu Shibasaki pp 14200–14201 DOI: 10.1021/ja055301t Supporting Info

Unprecedented Coordination Modes and Demetalation Pathways for Unbridged Polyenyl Ligands. Ruthenium η1,η4-Cycloheptadienyl Complexes from Allyl/Alkyne Cycloaddition Christina M. Older, Robert McDonald, and Jeffrey M. Stryker pp 14202–14203 DOI: 10.1021/ja0556023 Supporting Info

A Mild Radical Procedure for the Reduction of B-Alkylcatecholboranes to Alkanes Davide Pozzi, Eoin M. Scanlan, and Philippe Renaud pp 14204–14205 DOI: 10.1021/ja055691j Supporting Info

Dichlorodiazirine:  A Nitrogenous Precursor for Dichlorocarbene Gaosheng Chu, Robert A. Moss, and Ronald R. Sauers pp 14206–14207 DOI: 10.1021/ja055656c Supporting Info

Light-Driven Molecular Motors:  Stepwise Thermal Helix Inversion during Unidirectional Rotation of Sterically Overcrowded Biphenanthrylidenes Matthijs K. J. ter Wiel, Richard A. van Delden, Auke Meetsma, and Ben L. Feringa pp 14208–14222 DOI: 10.1021/ja052201e Supporting Info

Catalysis of Enantioselective [2+1]-Cycloaddition Reactions of Ethyl Diazoacetate and Terminal Acetylenes Using Mixed-Ligand Complexes of the Series Rh2(RCO2)n (L*4-n). Stereochemical Heuristics for Ligand Exchange and Catalyst Synthesis Yan Lou, Travis P. Remarchuk, and E. J. Corey pp 14223–14230 DOI: 10.1021/ja052254w Supporting Info

Structure and Dynamics of Solvated Sn(II) in Aqueous Solution:  An ab Initio QM/MM MD Approach Thomas S. Hofer, Andreas B. Pribil, Bernhard R. Randolf, and Bernd M. Rode pp 14231–14238 DOI: 10.1021/ja052700f Supporting Info

Alkene cis-Dihydroxylation by [(Me3tacn)(CF3CO2)RuVIO2]ClO4 (Me3tacn = 1,4,7-Trimethyl-1,4,7-triazacyclononane):  Structural Characterization of [3 + 2] Cycloadducts and Kinetic Studies Wing-Ping Yip, Wing-Yiu Yu, Nianyong Zhu, and Chi-Ming Che pp 14239–14249 DOI: 10.1021/ja0528230 Supporting Info

The Coordination of Uranyl in Water:  A Combined Quantum Chemical and Molecular Simulation Study Daniel Hagberg, Gunnar Karlström, Björn O. Roos, and Laura Gagliardi pp 14250–14256 DOI: 10.1021/ja0526719

Charge Recombination via Intercolumnar Electron Tunneling through the Lipid-like Mantle of Discotic Hexa-alkyl-hexa-peri-hexabenzocoronenes John M. Warman, Jorge Piris, Wojciech Pisula, Marcel Kastler, Daniel Wasserfallen, and Klaus Müllen pp 14257–14262 DOI: 10.1021/ja053225o

Mechanism of the Mild Functionalization of Arenes by Diboron Reagents Catalyzed by Iridium Complexes. Intermediacy and Chemistry of Bipyridine-Ligated Iridium Trisboryl Complexes Timothy M. Boller, Jaclyn M. Murphy, Marko Hapke, Tatsuo Ishiyama, Norio Miyaura, and John F. Hartwig pp 14263–14278 DOI: 10.1021/ja053433g

The Influence of Aqueous versus Glassy Solvents on Protein Dynamics:  Vibrational Echo Experiments and Molecular Dynamics Simulations Aaron M. Massari, Ilya J. Finkelstein, Brian L. McClain, Anne Goj, Xin Wen, Kara L. Bren, Roger F. Loring, and Michael D. Fayer pp 14279–14289 DOI: 10.1021/ja053627w Supporting Info

Magnetic Field Dependence of Photo-CIDNP MAS NMR on Photosynthetic Reaction Centers of Rhodobacter sphaeroides WT Shipra Prakash, Alia, Peter Gast, Huub J. M. de Groot, Gunnar Jeschke, and Jörg Matysik pp 14290–14298 DOI: 10.1021/ja054015e

Covalent Attachment of a Transition Metal Coordination Complex to Functionalized Oligo(phenylene-ethynylene) Self-Assembled Monolayers Abhishek Dube, Andrew R. Chadeayne, Manish Sharma, Peter T. Wolczanski, and James R. Engstrom pp 14299–14309 DOI: 10.1021/ja054378e Supporting Info

Naked (C5Me5)2M Cations (M = Sc, Ti, and V) and Their Fluoroarene Complexes Marco W. Bouwkamp, Peter H. M. Budzelaar, Jeroen Gercama, Isabel Del Hierro Morales, Jeanette de Wolf, Auke Meetsma, Sergei I. Troyanov, Jan H. Teuben, and Bart Hessen pp 14310–14319 DOI: 10.1021/ja054544i Supporting Info

Interpreting NMR Data for β-Peptides Using Molecular Dynamics Simulations Daniel Trzesniak, Alice Glättli, Bernhard Jaun, and Wilfred F. van Gunsteren pp 14320–14329 DOI: 10.1021/ja044285h Supporting Info

Theoretical Studies on the Magnetic Switching Controlled by Stacking Patterns of Bis(maleonitriledithiolato) Nickelate(III) Dimers Zhaoping Ni, Xiaoming Ren, Jing Ma, Jingli Xie, Chunlin Ni, Zhida Chen, and Qingjin Meng pp 14330–14338 DOI: 10.1021/ja050631z Supporting Info

Catalytic Mechanism of Limonene Epoxide Hydrolase, a Theoretical Study Kathrin H. Hopmann, B. Martin Hallberg, and Fahmi Himo pp 14339–14347 DOI: 10.1021/ja050940p Supporting Info

Hydrogen Cycling of Niobium and Vanadium Catalyzed Nanostructured Magnesium H. Gijs Schimmel, Jacques Huot, Laurent C. Chapon, Frans D. Tichelaar, and Fokko M. Mulder pp 14348–14354 DOI: 10.1021/ja051508a Supporting Info

Interstrand and Intrastrand DNA−DNA Cross-Linking by 1,2,3,4-Diepoxybutane:  Role of Stereochemistry Soobong Park, Christopher Anderson, Rachel Loeber, Mahadevan Seetharaman, Roger Jones, and Natalia Tretyakova pp 14355–14365 DOI: 10.1021/ja051979x Supporting Info

Synthesis and Crystal Structure of an Open Capsule-Type Octanuclear Heterometallic Sulfide Cluster with a Linked Incomplete Double Cubane Framework without an Intramolecular Inversion Center Bunsho Kure, Seiji Ogo, Daisuke Inoki, Hidetaka Nakai, Kiyoshi Isobe, and Shunichi Fukuzumi pp 14366–14374 DOI: 10.1021/ja051748q Supporting Info

Diastereomer-Differentiating Photochemistry of β-Arylbutyrophenones:  Yang Cyclization versus Type II Elimination Nidhi Singhal, Apurba L. Koner, Prasenjit Mal, Paloth Venugopalan, Werner M. Nau, and Jarugu Narasimha Moorthy pp 14375–14382 DOI: 10.1021/ja0523643 Supporting Info

Synthesis of Lipidated Green Fluorescent Protein and Its Incorporation in Supported Lipid Bilayers Michael J. Grogan, Yoshihisa Kaizuka, Rosemary M. Conrad, Jay T. Groves, and Carolyn R. Bertozzi pp 14383–14387 DOI: 10.1021/ja052407f

Modeling Spontaneous Formation of Precursor Nanoparticles in Clear-Solution Zeolite Synthesis M. Jorge, Scott M. Auerbach, and P. A. Monson pp 14388–14400 DOI: 10.1021/ja052402i

Modeling Multiple Species of Nicotine and Deschloroepibatidine Interacting with α4β2 Nicotinic Acetylcholine Receptor:  From Microscopic Binding to Phenomenological Binding Affinity Xiaoqin Huang, Fang Zheng, Peter A. Crooks, Linda P. Dwoskin, and Chang-Guo Zhan pp 14401–14414 DOI: 10.1021/ja052681+ Supporting Info

A Molecular Tweezer for Lysine and Arginine Michael Fokkens, Thomas Schrader, and Frank-Gerrit Klärner pp 14415–14421 DOI: 10.1021/ja052806a Supporting Info

Heme Carbonyls:  Environmental Effects on νC-O and Fe−C/C−O Bond Length Correlations Nathan J. Silvernail, Arne Roth, Charles E. Schulz, Bruce C. Noll, and W. Robert Scheidt pp 14422–14433 DOI: 10.1021/ja053148x Supporting Info

Detection and Automatic Repair of Nucleotide Base-Pair Mutations by Coherent Light Ioannis Thanopulos and Moshe Shapiro pp 14434–14438 DOI: 10.1021/ja053396t

Antibiotic Recognition by Binuclear Metallo-β-Lactamases Revealed by X-ray Crystallography James Spencer, Jonathan Read, Richard B. Sessions, Steven Howell, G. Michael Blackburn, and Steven J. Gamblin pp 14439–14444 DOI: 10.1021/ja0536062 Supporting Info

DNA as Helical Ruler:  Exciton-Coupled Circular Dichroism in DNA Conjugates Frederick D. Lewis, Ligang Zhang, Xiaoyang Liu, Xiaobing Zuo, David M. Tiede, Hai Long, and George C. Schatz pp 14445–14453 DOI: 10.1021/ja0539387 Supporting Info

Unraveling the Crystallization Mechanism of CoAPO-5 Molecular Sieves under Hydrothermal Conditions Didier Grandjean, Andrew M. Beale, Andrei V. Petukhov, and Bert M. Weckhuysen pp 14454–14465 DOI: 10.1021/ja054014m

Characterization of the Cation and Temperature Dependence of DNA Quadruplex Hydrogen Bond Properties Using High-Resolution NMR Andrew J. Dingley, Robert D. Peterson, Stephan Grzesiek, and Juli Feigon pp 14466–14472 DOI: 10.1021/ja0540369

Strong Resistance of Phosphorylcholine Self-Assembled Monolayers to Protein Adsorption:  Insights into Nonfouling Properties of Zwitterionic Materials Shengfu Chen, Jie Zheng, Lingyan Li, and Shaoyi Jiang pp 14473–14478 DOI: 10.1021/ja054169u

Low-Temperature Activation and Deactivation of High-Curie-Temperature Ferromagnetism in a New Diluted Magnetic Semiconductor:  Ni2+-Doped SnO2 Paul I. Archer, Pavle V. Radovanovic, Steve M. Heald, and Daniel R. Gamelin pp 14479–14487 DOI: 10.1021/ja054205p Supporting Info

Small-Molecule Dynamics and Mechanisms Underlying the Macroscopic Mechanical Properties of Coordinatively Cross-Linked Polymer Networks Wayne C. Yount, David M. Loveless, and Stephen L. Craig pp 14488–14496 DOI: 10.1021/ja054298a Supporting Info

Divergent Oxidative Rearrangements in Solution and in a Zeolite:  Distal vs Proximal Bond Cleavage of Methylenecyclopropanes Hiroshi Ikeda, Tsuyoshi Nomura, Kimio Akiyama, Mitsuhiro Oshima, Heinz D. Roth, Shozo Tero-Kubota, and Tsutomu Miyashi pp 14497–14504 DOI: 10.1021/ja045930n Supporting Info

Specific Ion Effects on the Water Solubility of Macromolecules:  PNIPAM and the Hofmeister Series Yanjie Zhang, Steven Furyk, David E. Bergbreiter, and Paul S. Cremer pp 14505–14510 DOI: 10.1021/ja0546424 Supporting Info

Charge-Mediated Recognition of N-Terminal Tryptophan in Aqueous Solution by a Synthetic Host Meghan E. Bush, Nicole D. Bouley, and Adam R. Urbach pp 14511–14517 DOI: 10.1021/ja0548440 Supporting Info

Functionalization of Single-Walled Carbon Nanotubes with Well-Defined Polystyrene by “Click” Coupling Huaming Li, Fuyong Cheng, Andy M. Duft, and Alex Adronov pp 14518–14524 DOI: 10.1021/ja054958b Supporting Info

What is What in the Nanoworld:  A Handbook on Nanoscience and Nanotechnology By Victor E. Borisenko (Belarusian State University, Minsk, Belarus) and Stefano Ossicini (University of Modena and Reggio Emilia, Emilia, Italy). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xii + 336 pp. $190.00. ISBN 3-527-40493-7. p 14525 DOI: 10.1021/ja059771z

Asymmetric Organocatalysis:  From Biomimetic Concepts to Applications in Asymmetric Synthesis By Albrecht Berkessel (Universität zu Köln, Germany) and Harald Gröger (Service Center Biocatalysis, Hanau-Wolfgang, Germany). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim, Germany. 2005. xiv + 440 pp. $195.00. ISBN 3-527-30517-3. Merritt B. Andrus pp 14525–14526 DOI: 10.1021/ja059773j

Fundamental World of Quantum Chemistry:  A Tribute to the Memory of Per-Olov Löwdin, Volume III Edited by Erkki J. Brändas (Uppsala University, Sweden) and Eugene S. Kryachko (Bogoliubov Institute for Theoretical Physics, Kiev, Ukraine, and University of Leuven, Belgium). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xlvi + 677 pp. $225.00. ISBN 1-4020-2583-1. Russell J. Boyd p 14526 DOI: 10.1021/ja0598006

New Theories for Chemistry By Jan C. A. Boeyens (University of Pretoria, South Africa). Elsevier B. V.:  Amsterdam. 2005. xii + 280 pp. $170.00. ISBN 0-444-51867-3. Joel F. Liebman pp 14526–14527 DOI: 10.1021/ja0598053

Targets in Heterocyclic Systems:  Chemistry and Properties, Volume 7 (2003) Edited by Orazio A. Attanasi (University of Urbino) and Domenico Spinelli (University of Bologna). Italian Society of Chemistry:  Rome. 2004. vi + 294 pp. $79.95. ISBN 88-86208-28. Philip DeShong p 14527 DOI: 10.1021/ja059732n

The Maillard Reaction:  Chemistry, Biochemistry and Implications By Harry Nursten (The University of Reading, Reading, U.K.). Royal Society of Chemistry:  Cambridge. 2005. xii + 214 pp. $199.00. ISBN 0-85404-964-9. John W. Baynes pp 14527–14528 DOI: 10.1021/ja059794d

Chemical Thermodynamics for Industry Edited by T. M. Letcher (University of Natal, Durban, South Africa). Royal Society of Chemistry:  Cambridge. 2004. xviii + 276 pp. $249.00. ISBN 0-85404-591-0. p 14528 DOI: 10.1021/ja0597909

Issue 42

Tetrahedral n-Type Materials:  Efficient Quenching of the Excitation of p-Type Polymers in Amorphous Films Palaniswamy Ganesan, Xiaoniu Yang, Joachim Loos, Tom J. Savenije, Ruben D. Abellon, Han Zuilhof, and Ernst J. R. Sudhölter pp 14530–14531 DOI: 10.1021/ja053689m Supporting Info

Detection of Single Oxygen Molecules with Fluorescence-Labeled Hemocyanins Wolfgang Erker, Sven Sdorra, and Thomas Basché pp 14532–14533 DOI: 10.1021/ja053720k Supporting Info

Enthalpies of Hydrogen-Bonds in α-Helical Peptides. An ONIOM DFT/AM1 Study Robert Wieczorek and J. J. Dannenberg pp 14534–14535 DOI: 10.1021/ja053839t Supporting Info

Solid-Phase Synthesis of Polymers Using the Ring-Opening Metathesis Polymerization Jason K. Pontrello, Matthew J. Allen, Eric S. Underbakke, and Laura L. Kiessling pp 14536–14537 DOI: 10.1021/ja053931p Supporting Info

The Reactant State for Substrate-Activated Turnover of Acetylthiocholine by Butyrylcholinesterase is a Tetrahedral Intermediate Jose R. Tormos, Kenneth L. Wiley, Javier Seravalli, Florian Nachon, Patrick Masson, Yvain Nicolet, and Daniel M. Quinn pp 14538–14539 DOI: 10.1021/ja052401q Supporting Info

Synthesis and Structure of 16 π Octaalkyltetraphenylporphyrins Yohsuke Yamamoto, Akihiro Yamamoto, Shin-ya Furuta, Masanori Horie, Megumi Kodama, Wataru Sato, Kin-ya Akiba, Seiji Tsuzuki, Tadafumi Uchimaru, Daisuke Hashizume, and Fujiko Iwasaki pp 14540–14541 DOI: 10.1021/ja052842+ Supporting Info

Proton-Catalyzed Hydroamination and Hydroarylation Reactions of Anilines and Alkenes:  A Dramatic Effect of Counteranions on Reaction Efficiency Laura L. Anderson, John Arnold, and Robert G. Bergman pp 14542–14543 DOI: 10.1021/ja053700i Supporting Info

Flavin-Catalyzed Generation of Diimide:  An Environmentally Friendly Method for the Aerobic Hydrogenation of Olefins Yasushi Imada, Hiroki Iida, and Takeshi Naota pp 14544–14545 DOI: 10.1021/ja053976q Supporting Info

A Highly Efficient Carbon−Carbon Bond Formation Reaction via Nucleophilic Addition to N-Alkylaldimines without Acids or Metallic Species Hisao Nemoto, Tomoyuki Kawamura, and Norikazu Miyoshi pp 14546–14547 DOI: 10.1021/ja054010h Supporting Info

Reversible Protein Adsorption and Bioadhesion on Monolayers Terminated with Mixtures of Oligo(ethylene glycol) and Methyl Groups Subramanian Balamurugan, Linnea K. Ista, Juchao Yan, Gabriel P. López, Jörg Fick, Michael Himmelhaus, and Michael Grunze pp 14548–14549 DOI: 10.1021/ja054156g Supporting Info

1-Alkoxyallene as an Effective Precursor for Regio- and Stereocontrolled Allylation Reactions with Aliphatic Aldehydes via Bis-Stannylation David R. Williams and Micheal W. Fultz pp 14550–14551 DOI: 10.1021/ja054201k Supporting Info

Lewis Acid-Catalyzed Rearrangement of Multi-Substituted Arylvinylidenecyclopropanes Guang-Cai Xu, Le-Ping Liu, Jian-Mei Lu, and Min Shi pp 14552–14553 DOI: 10.1021/ja054988e Supporting Info

Instant “Base-Promoted” Generation of Roper's-type Ru(0) Complexes Ru(CO)2(PR3)3 from a Simple Carbonylchlororuthenium(II) Precursor Stephane Sentets, Maria del Carmen Rodriguez Martinez, Laure Vendier, Bruno Donnadieu, Vincent Huc, Noël Lugan, and Guy Lavigne pp 14554–14555 DOI: 10.1021/ja055066e Supporting Info

Silver-Catalyzed Asymmetric Sakurai−Hosomi Allylation of Ketones Manabu Wadamoto and Hisashi Yamamoto pp 14556–14557 DOI: 10.1021/ja0553351 Supporting Info

Subcellular, Time-Resolved Studies of Singlet Oxygen in Single Cells John W. Snyder, Esben Skovsen, John D. C. Lambert, and Peter R. Ogilby pp 14558–14559 DOI: 10.1021/ja055342p

Combined C−H Functionalization/C−N Bond Formation Route to Carbazoles W. C. Peter Tsang, Nan Zheng, and Stephen L. Buchwald pp 14560–14561 DOI: 10.1021/ja055353i Supporting Info

Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor Lixin Zhang, Yi Luo, and Zhaomin Hou pp 14562–14563 DOI: 10.1021/ja055397r Supporting Info

pH-Controlled Switching of Photocurrent Direction by Self-Assembled Monolayer of Helical Peptides Shiro Yasutomi, Tomoyuki Morita, and Shunsaku Kimura pp 14564–14565 DOI: 10.1021/ja055624p Supporting Info

Catalytic, Asymmetric, “Interrupted” Feist−Bénary Reactions Michael A. Calter, Ryan M. Phillips, and Christine Flaschenriem pp 14566–14567 DOI: 10.1021/ja055752d Supporting Info

A General Route to Very Small Polymer Particles with Controlled Microstructures Vincent Monteil, Peter Wehrmann, and Stefan Mecking pp 14568–14569 DOI: 10.1021/ja0558084 Supporting Info

Positional Control of Encapsulated Atoms Inside a Fullerene Cage by Exohedral Addition Michio Yamada, Tsukasa Nakahodo, Takatsugu Wakahara, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Masahiro Kako, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Kaoru Kobayashi, and Shigeru Nagase pp 14570–14571 DOI: 10.1021/ja054346r Supporting Info

FHA Domain−Ligand Interactions:  Importance of Integrating Chemical and Biological Approaches Anjali Mahajan, Chunhua Yuan, Brietta L. Pike, Jörg Heierhorst, Chi-Fon Chang, and Ming-Daw Tsai pp 14572–14573 DOI: 10.1021/ja054538m Supporting Info

Light-Regulated Electrostatic Interactions in Colloidal Suspensions Kyle N. Plunkett, Ali Mohraz, Richard T. Haasch, Jennifer A. Lewis, and Jeffrey S. Moore pp 14574–14575 DOI: 10.1021/ja054666a Supporting Info

Fine Tuning the Purity of Blue Emission from Polydioctylfluorene by End-Capping with Electron-Deficient Moieties Ming-Chin Hung, Jin-Long Liao, Show-An Chen, Su-Hua Chen, and An-Chung Su pp 14576–14577 DOI: 10.1021/ja054777+ Supporting Info

Probing Structure and Functional Dynamics of (Large) Proteins with Aromatic Rings:  L-GFT-TROSY (4,3)D HCCH NMR Spectroscopy Alexander Eletsky, Hanudatta S. Atreya, Gaohua Liu, and Thomas Szyperski pp 14578–14579 DOI: 10.1021/ja054895x Supporting Info

Solvent Molecules in an Epitaxially Grown Scaffold of Star-Shaped Nanographenes Frank Jäckel, Min Ai, Jishan Wu, Klaus Müllen, and Jürgen P. Rabe pp 14580–14581 DOI: 10.1021/ja054920z Supporting Info

Clustering of Ti on a C60 Surface and Its Effect on Hydrogen Storage Qiang Sun, Qian Wang, Puru Jena, and Yoshiyuki Kawazoe pp 14582–14583 DOI: 10.1021/ja0550125

A Rapid Library Screen for Tailoring β-Peptide Structure and Function Joshua A. Kritzer, Nathan W. Luedtke, Elizabeth A. Harker, and Alanna Schepartz pp 14584–14585 DOI: 10.1021/ja055050o Supporting Info

Palladium(II)-Catalyzed Intramolecular Diamination of Unfunctionalized Alkenes Jan Streuff, Claas H. Hövelmann, Martin Nieger, and Kilian Muñiz pp 14586–14587 DOI: 10.1021/ja055190y Supporting Info

Discovery of O-GlcNAc Transferase Inhibitors Benjamin J. Gross, Brian C. Kraybill, and Suzanne Walker pp 14588–14589 DOI: 10.1021/ja0555217 Supporting Info

Ionic Conduction in Zn3(PO4)2·4H2O Enables Efficient Discharge of the Zinc Anode in Serum Woonsup Shin, Junghyun Lee, Yousung Kim, Hugo Steinfink, and Adam Heller pp 14590–14591 DOI: 10.1021/ja0556068

Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition Jooho Kim, Zdenek Dohnálek, and Bruce D. Kay pp 14592–14593 DOI: 10.1021/ja055764z

Direct Repair of the Exocyclic DNA Adduct 1,N6-Ethenoadenine by the DNA Repair AlkB Proteins Yukiko Mishina, Cai-Guang Yang, and Chuan He pp 14594–14595 DOI: 10.1021/ja055957m Supporting Info

Normal Mode Analysis of Pyrococcus furiosus Rubredoxin via Nuclear Resonance Vibrational Spectroscopy (NRVS) and Resonance Raman Spectroscopy Yuming Xiao, Hongxin Wang, Simon J. George, Matt C. Smith, Michael W. W. Adams, Francis E. Jenney, Jr., Wolfgang Sturhahn, Ercan E. Alp, Jiyong Zhao, Y. Yoda, Abishek Dey, Edward I. Solomon, and Stephen P. Cramer pp 14596–14606 DOI: 10.1021/ja042960h Supporting Info

Determination of O[H] and CO Coverage and Adsorption Sites on PtRu Electrodes in an Operating PEM Fuel Cell Christina Roth, Nathalie Benker, Thorsten Buhrmester, Marian Mazurek, Matthias Loster, Hartmut Fuess, Diederik C. Koningsberger, and David E. Ramaker pp 14607–14615 DOI: 10.1021/ja050139f Supporting Info

The Maximin Principle of π-Radical Packings Thomas Devic, Min Yuan, Judy Adams, Daniel C. Fredrickson, Stephen Lee, and D. Venkataraman pp 14616–14627 DOI: 10.1021/ja050346f Supporting Info

Influence of Metal Coordination on the Mismatch Tolerance of Ligand-Modified PNA Duplexes Richard M. Watson, Yury A. Skorik, Goutam K. Patra, and Catalina Achim pp 14628–14639 DOI: 10.1021/ja051336h Supporting Info

Characterization and 2D Self-Assembly of CdSe Quantum Dots at the Air−Water Interface Kerim M. Gattás-Asfura, Celeste A. Constantine, Matthew J. Lynn, Daniel A. Thimann, Xiaojun Ji, and Roger M. Leblanc pp 14640–14646 DOI: 10.1021/ja0514848 Supporting Info

Synthesis of Helical Polyacetylene in Chiral Nematic Liquid Crystals Using Crown Ether Type Binaphthyl Derivatives as Chiral Dopants Kazuo Akagi, Shouxue Guo, Taizou Mori, Munju Goh, Guangzhe Piao, and Mutsumasa Kyotani pp 14647–14654 DOI: 10.1021/ja051548e

Inorganic Oxide Core, Polymer Shell Nanocomposite as a High K Gate Dielectric for Flexible Electronics Applications Ashok Maliakal, Howard Katz, Pat M. Cotts, Shekhar Subramoney, and Peter Mirau pp 14655–14662 DOI: 10.1021/ja052035a Supporting Info

Sugar Pucker Modulates the Cross-Correlated Relaxation Rates across the Glycosidic Bond in DNA Vladimír Sychrovský, Norbert Müller, Bohdan Schneider, Vilko Smreki, Vladimir Špirko, Jiří Šponer, and Lukáš Trantírek pp 14663–14667 DOI: 10.1021/ja050894t Supporting Info

Highly Enantio- and Diastereoselective One-Pot Synthesis of Acyclic Epoxy Alcohols and Allylic Epoxy Alcohols Ann Rowley Kelly, Alice E. Lurain, and Patrick J. Walsh pp 14668–14674 DOI: 10.1021/ja051291k Supporting Info

Catalytic Conjugate Additions of Carbonyl Anions under Neutral Aqueous Conditions Michael C. Myers, Ashwin R. Bharadwaj, Benjamin C. Milgram, and Karl A. Scheidt pp 14675–14680 DOI: 10.1021/ja0520161 Supporting Info

Stability of Luminescent Trivalent Cerium in Silica Host Glasses Modified by Boron and Phosphorus Carmen Canevali, Mariachiara Mattoni, Franca Morazzoni, Roberto Scotti, Mariano Casu, Anna Musinu, Radenka Krsmanovic, Stefano Polizzi, Adolfo Speghini, and Marco Bettinelli pp 14681–14691 DOI: 10.1021/ja052502o Supporting Info

Copolymerization of Ethylene with Polar Monomers:  Chain Propagation and Side Reactions. A DFT Theoretical Study Using Zwitterionic Ni(II) and Pd(II) Catalysts Miklos J. Szabo, Natasha M. Galea, Artur Michalak, Sheng-Yong Yang, Laurent F. Groux, Warren E. Piers, and Tom Ziegler pp 14692–14703 DOI: 10.1021/ja052350x Supporting Info

Receptor for Anionic Pyrene Derivatives Provides the Basis for New Biomembrane Assays Christine A. Winschel, Amar Kalidindi, Ibrahim Zgani, John L. Magruder, and Vladimir Sidorov pp 14704–14713 DOI: 10.1021/ja052397i Supporting Info

Control of Quinone Redox Potentials in Photosystem II:  Electron Transfer and Photoprotection Hiroshi Ishikita and Ernst-Walter Knapp pp 14714–14720 DOI: 10.1021/ja052567r Supporting Info

Solvent Effects on the Two-Photon Absorption of Distyrylbenzene Chromophores Han Young Woo, Bin Liu, Bernhard Kohler, Dmitry Korystov, Alexander Mikhailovsky, and Guillermo C. Bazan pp 14721–14729 DOI: 10.1021/ja052906g Supporting Info

Formation of Disilanes in the Reaction of Stable Silylenes with Halocarbons Daniel F. Moser, Akinobu Naka, Ilia A. Guzei, Thomas Müller, and Robert West pp 14730–14738 DOI: 10.1021/ja052584g Supporting Info

Conformational Heterogeneity of Surface-Grafted Amyloidogenic Fragments of Alpha-Synuclein Dimers Detected by Atomic Force Microscopy Chad Ray and Boris B. Akhremitchev pp 14739–14744 DOI: 10.1021/ja052932e

Synthesis, Structure, and α-Elimination Chemistry of Hafnocene Triarylstannyl Complexes Nathan R. Neale and T. Don Tilley pp 14745–14755 DOI: 10.1021/ja0529586 Supporting Info

Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene:  Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts Hongbo Li, Liting Li, David J. Schwartz, Matthew V. Metz, Tobin J. Marks, Louise Liable-Sands, and Arnold L. Rheingold pp 14756–14768 DOI: 10.1021/ja052995x Supporting Info

Electroactive Supramolecular Self-Assembled Fibers Comprised of Doped Tetrathiafulvalene-Based Gelators Tetsu Kitamura, Suguru Nakaso, Norihiro Mizoshita, Yusuke Tochigi, Takeshi Shimomura, Masaya Moriyama, Kohzo Ito, and Takashi Kato pp 14769–14775 DOI: 10.1021/ja053496z Supporting Info

Intramolecular Carbonylation Reactions with Recyclable Palladium-Complexed Dendrimers on Silica:  Synthesis of Oxygen, Nitrogen, or Sulfur-Containing Medium Ring Fused Heterocycles Shui-Ming Lu and Howard Alper pp 14776–14784 DOI: 10.1021/ja053650h Supporting Info

Divergent Enantioselective Synthesis of (−)-Galanthamine and (−)-Morphine Barry M. Trost, Weiping Tang, and F. Dean Toste pp 14785–14803 DOI: 10.1021/ja054449+ Supporting Info

Molecular Dynamics Simulation of Amphiphilic Bistable [2]Rotaxane Langmuir Monolayers at the Air/Water Interface Seung Soon Jang, Yun Hee Jang, Yong-Hoon Kim, William A. Goddard III, Jang Wook Choi, James R. Heath, Bo W. Laursen, Amar H. Flood, J. Fraser Stoddart, Kasper Nørgaard, and Thomas Bjørnholm pp 14804–14816 DOI: 10.1021/ja0531531

Origin of Enantioselection in Chiral Alcohol Oxidation Catalyzed by Pd[(−)-sparteine]Cl2 Jaime A. Mueller, Anne Cowell, Bert D. Chandler, and Matthew S. Sigman pp 14817–14824 DOI: 10.1021/ja053195p Supporting Info

Theoretical Characterization of α-Helix and β-Hairpin Folding Kinetics Isabella Daidone, Marco D'Abramo, Alfredo Di Nola, and Andrea Amadei pp 14825–14832 DOI: 10.1021/ja053383f

Biomimetic Zinc Funnel Complexes Based on Calix[6]N3ArO Ligands:  An Acid−Base Switch for Guest Binding Olivier Sénèque, Marie-Noëlle Rager, Michel Giorgi, Thierry Prangé, Alain Tomas, and Olivia Reinaud pp 14833–14840 DOI: 10.1021/ja053620e Supporting Info

Van der Waals Complexes of Polar Aromatic Molecules:  Unexpected Structures for Dimers of Azulene Manuel Piacenza and Stefan Grimme pp 14841–14848 DOI: 10.1021/ja053613q Supporting Info

Stable and Selective Formation of Hoogsteen-Type Triplexes and Duplexes Using Twisted Intercalating Nucleic Acids (TINA) Prepared via Postsynthetic Sonogashira Solid-Phase Coupling Reactions Vyacheslav V. Filichev and Erik B. Pedersen pp 14849–14858 DOI: 10.1021/ja053645d Supporting Info

Toward π-Conjugated Molecule Bundles:  Synthesis of a Series of B,B‘,B‘‘-Trianthryl-N,N‘,N‘‘-triarylborazines and the Bundle Effects on Their Properties Atsushi Wakamiya, Toshihisa Ide, and Shigehiro Yamaguchi pp 14859–14866 DOI: 10.1021/ja0537171 Supporting Info

Green Chemical Functionalization of Single-Walled Carbon Nanotubes in Ionic Liquids B. Katherine Price, Jared L. Hudson, and James M. Tour pp 14867–14870 DOI: 10.1021/ja053998c

Catalysts for Hydrogen Evolution from the [NiFe] Hydrogenase to the Ni2P(001) Surface:  The Importance of Ensemble Effect Ping Liu and José A. Rodriguez pp 14871–14878 DOI: 10.1021/ja0540019

Nonperfect Synchronization of Reaction Center Rehybridization in the Transition State of the Hydride Transfer Catalyzed by Dihydrofolate Reductase Jingzhi Pu, Shuhua Ma, Mireia Garcia-Viloca, Jiali Gao, Donald G. Truhlar, and Amnon Kohen pp 14879–14886 DOI: 10.1021/ja054170t

Palladium-Catalyzed Allylic Transposition of (Allyloxy) Iminodiazaphospholidines:  A Formal [3,3]-Aza-phospha-oxa-Cope Sigmatropic Rearrangement for the Stereoselective Synthesis of Allylic Amines Ernest E. Lee and Robert A. Batey pp 14887–14893 DOI: 10.1021/ja054161k Supporting Info

Absolute Rates of Hole Transfer in DNA Kittusamy Senthilkumar, Ferdinand C. Grozema, Célia Fonseca Guerra, F. Matthias Bickelhaupt, Frederick D. Lewis, Yuri A. Berlin, Mark A. Ratner, and Laurens D. A. Siebbeles pp 14894–14903 DOI: 10.1021/ja054257e Supporting Info

Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering Jesse L. C. Rowsell, Juergen Eckert, and Omar M. Yaghi pp 14904–14910 DOI: 10.1021/ja0542690 Supporting Info

7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles José Justicia, Juan L. Oller-López, Araceli G. Campaña, J. Enrique Oltra, Juan M. Cuerva, Elena Buñuel, and Diego J. Cárdenas pp 14911–14921 DOI: 10.1021/ja054316o Supporting Info

Temperature-Sensitive Dendritic Micelles Sivakumar V. Aathimanikandan, Elamprakash N. Savariar, and S. Thayumanavan pp 14922–14929 DOI: 10.1021/ja054542y Supporting Info

Temperature Dependence of Inhomogeneous Broadening:  On the Meaning of Isosbestic Points Phillip L. Geissler pp 14930–14935 DOI: 10.1021/ja0545214

Enhanced Fluorescence from Arrays of Nanoholes in a Gold Film Alexandre G. Brolo, Shing C. Kwok, Matthew G. Moffitt, Reuven Gordon, Jason Riordon, and Karen L. Kavanagh pp 14936–14941 DOI: 10.1021/ja0548687

Orthogonal Approaches to the Simultaneous and Cascade Functionalization of Macromolecules Using Click Chemistry Michael Malkoch, Raymond J. Thibault, Eric Drockenmuller, Martin Messerschmidt, Brigitte Voit, Thomas P. Russell, and Craig J. Hawker pp 14942–14949 DOI: 10.1021/ja0549751 Supporting Info

Silicon-Mediated Transformations of Functional Groups By Helmut Vorbrüggen (Free University, Berlin). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim, Germany. 2004. xii + 364 pp. $120.00. ISBN 3-527-30668-4. Marshall W. Logue p 14950 DOI: 10.1021/ja0597202

Chemoinformatics in Drug Discovery, Volume 23 Edited by Tudor I. Oprea (University of New Mexico). From the series Methods and Principles in Medicinal Chemistry. Edited by R. Mannhold, H. Kubinyi, and G. Folkers. Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim, Germany. xxii + 494 pp. $185. ISBN 3-527-30753-2. William J. Welsh p 14950 DOI: 10.1021/ja0597404

Metathesis Polymerization. Advances in Polymer Science, Volume 176 Edited by Michael R. Buchmeiser (University of Innsbruck). Springer:  Berlin, Heidelberg, New York. 2005. xii + 142 pp. $139.00. ISBN 3-540-23358-X. Anne M. LaPointe pp 14950–14951 DOI: 10.1021/ja0597597

Enantioselective Synthesis of β-Amino Acids, 2nd ed Edited by Eusebio Juaristi (Cinvestav-IPN, Mexico) and Vadim A. Soloshonok (University of Oklahoma, Norman). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xx + 634 pp. $175.00. ISBN 0-471-46738-3. Enugurthi Brahmachary p 14951 DOI: 10.1021/ja059764a

Modification and Blending of Synthetic and Natural Macromolecules Edited by Francesco Ciardelli (University of Pisa) and Stanislaw Penczek (Polish Academy of Science, Lodz). Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2004. xviii + 344 pp. $169.00. ISBN 1-4020-2733-8. pp 14951–14952 DOI: 10.1021/ja059788h

The Vocabulary and Concepts of Organic Chemistry, 2nd ed By Milton Orchin, Roger S. Macomber, Allan R. Pinhas, and R. Marshall Wilson (All at University of Cincinnati). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. viii + 894 pp. $125.00. ISBN 0-471-68028-1. p 14952 DOI: 10.1021/ja059793l

Thermal Analysis of Polymeric Materials By Bernhard Wunderlich (Knoxville, TN). Springer:  Berlin, Heidelberg, New York. 2005. xvi + 894 pp. $89.95. ISBN 3-540-23629-5. Julie P. Harmon p 14952 DOI: 10.1021/ja059803i

Issue 43

A Strategy for the Development of Small-Molecule-Based Sensors That Strongly Fluoresce When Bound to a Specific RNA Brian A. Sparano and Kazunori Koide pp 14954–14955 DOI: 10.1021/ja0530319 Supporting Info

Iron Tris(dibenzoylmethane)-Centered Polylactide Stars:  Multiple Roles for the Metal Complex in Lactide Ring-Opening Polymerization Jessica L. Gorczynski, Jianbin Chen, and Cassandra L. Fraser pp 14956–14957 DOI: 10.1021/ja0530927 Supporting Info

Direct Observation of the Disorder of the Methyl Group of (R)-1,2-Diaminopropane Ligand in the Quasi-1D Bromo-Bridged Ni(III) Complex by STM Mari Sasaki, Shinya Takaishi, Hitoshi Miyasaka, Ken-ichi Sugiura, and Masahiro Yamashita pp 14958–14959 DOI: 10.1021/ja053715g Supporting Info

Intermediates Trapped during Nitrogenase Reduction of NN, CH3−NNH, and H2N−NH2 Brett M. Barney, Tran-Chin Yang, Robert Y. Igarashi, Patricia C. Dos Santos, Mikhail Laryukhin, Hong-In Lee, Brian M. Hoffman, Dennis R. Dean, and Lance C. Seefeldt pp 14960–14961 DOI: 10.1021/ja0539342

A Ratiometric Fluorescence Probe for Selective Visual Sensing of Zn2+ Ayyappanpillai Ajayaghosh, Priya Carol, and Sivaramapanicker Sreejith pp 14962–14963 DOI: 10.1021/ja054149s Supporting Info

Diode or Tunnel-Diode Characteristics? Resolving the Catalytic Consequences of Proton Coupled Electron Transfer in a Multi-Centered Oxidoreductase James D. Gwyer, David J. Richardson, and Julea N. Butt pp 14964–14965 DOI: 10.1021/ja054160s Supporting Info

Assembly of Polymeric Silver(I) Complexes of Isomeric Phenylenediethynides with the Supramolecular Synthons Agn C2RC2 Agn (R = p-, m-, o-C6H4; n = 4, 5) Liang Zhao and Thomas C. W. Mak pp 14966–14967 DOI: 10.1021/ja054176i Supporting Info

Self-Assembly of Photoactive TiO2−Cyclodextrin Wires Jun Feng, Alex Miedaner, Phil Ahrenkiel, Michael E. Himmel, Calvin Curtis, and David Ginley pp 14968–14969 DOI: 10.1021/ja054448h Supporting Info

A Simple Method To Predict Protein Flexibility Using Secondary Chemical Shifts Mark V. Berjanskii and David S. Wishart pp 14970–14971 DOI: 10.1021/ja054842f Supporting Info

A Halogen-Bonding-Based Heteroditopic Receptor for Alkali Metal Halides Andrea Mele, Pierangelo Metrangolo, Hannes Neukirch, Tullio Pilati, and Giuseppe Resnati pp 14972–14973 DOI: 10.1021/ja054862h Supporting Info

High-Resolution Mn EXAFS of the Oxygen-Evolving Complex in Photosystem II:  Structural Implications for the Mn4Ca Cluster Junko Yano, Yulia Pushkar, Pieter Glatzel, Azul Lewis, Kenneth Sauer, Johannes Messinger, Uwe Bergmann, and Vittal Yachandra pp 14974–14975 DOI: 10.1021/ja054873a Supporting Info

Structural Characterization of a p-Acetylphenylalanyl Aminoacyl-tRNA Synthetase James M. Turner, James Graziano, Glen Spraggon, and Peter G. Schultz pp 14976–14977 DOI: 10.1021/ja0549042 Supporting Info

Luminescence from the trans-Dioxotechnetium(V) Chromophore Andrew S. Del Negro, Zheming Wang, Carl J. Seliskar, William R. Heineman, B. Patrick Sullivan, Sean E. Hightower, Timothy L. Hubler, and Samuel A. Bryan pp 14978–14979 DOI: 10.1021/ja054906m Supporting Info

Creation of a Mixed-Valence State from One-Dimensionally Aligned TTF Utilizing the Self-Assembling Nature of a Low Molecular-Weight Gel Tatsuya Kitahara, Michihiro Shirakawa, Shin-ichiro Kawano, Uwe Beginn, Norifumi Fujita, and Seiji Shinkai pp 14980–14981 DOI: 10.1021/ja0552038 Supporting Info

Crystallization on Confined Engineered Surfaces:  A Method to Control Crystal Size and Generate Different Polymorphs Alfred Y. Lee, In Sung Lee, Severine S. Dette, Jana Boerner, and Allan S. Myerson pp 14982–14983 DOI: 10.1021/ja055416x Supporting Info

Monitoring Multiple Active Sites on Thiotemplate Enzymes in Parallel:  A Molecular Movie of Yersiniabactin Bioassembly Shaun M. McLoughlin and Neil L. Kelleher pp 14984–14985 DOI: 10.1021/ja0555264 Supporting Info

Characterization of a New Tailoring Domain in Polyketide Biogenesis:  The Amine Transferase Domain of MycA in the Mycosubtilin Gene Cluster Zachary D. Aron, Pieter C. Dorrestein, Jonathan R. Blackhall, Neil L. Kelleher, and Christopher T. Walsh pp 14986–14987 DOI: 10.1021/ja055247g Supporting Info

Catalytic Enantioselective Alkylations of Tetrasubstituted Olefins. Synthesis of All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Enones Alexander W. Hird and Amir H. Hoveyda pp 14988–14989 DOI: 10.1021/ja0553811 Supporting Info

One-Dimensional Assembly of Chalcogenide Nanoclusters with Bifunctional Covalent Linkers Nanfeng Zheng, Xianhui Bu, Haiwei Lu, Lan Chen, and Pingyun Feng pp 14990–14991 DOI: 10.1021/ja055376x Supporting Info

Nanosphere Arrays with Controlled Sub-10-nm Gaps as Surface-Enhanced Raman Spectroscopy Substrates Hui Wang, Carly S. Levin, and Naomi J. Halas pp 14992–14993 DOI: 10.1021/ja055633y Supporting Info

Relaying Asymmetry of Transient Atropisomers of o-Iodoanilides by Radical Cyclizations Marc Petit, Andre J. B. Lapierre, and Dennis P. Curran pp 14994–14995 DOI: 10.1021/ja055666d Supporting Info

n-Type Organic Field-Effect Transistors with Very High Electron Mobility Based on Thiazole Oligomers with Trifluoromethylphenyl Groups Shinji Ando, Ryo Murakami, Jun-ichi Nishida, Hirokazu Tada, Youji Inoue, Shizuo Tokito, and Yoshiro Yamashita pp 14996–14997 DOI: 10.1021/ja055686f Supporting Info

The Rotational Spectrum and Structure of HOOOH Kohsuke Suma, Yoshihiro Sumiyoshi, and Yasuki Endo pp 14998–14999 DOI: 10.1021/ja0556530 Supporting Info

In(OH)BDC·0.75BDCH2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic−Organic Vernier Structure Ekaterina V. Anokhina, Marie Vougo-Zanda, Xiqu Wang, and Allan J. Jacobson pp 15000–15001 DOI: 10.1021/ja055757a Supporting Info

Isochorismate Pyruvate Lyase:  A Pericyclic Reaction Mechanism? Michael S. DeClue, Kim K. Baldridge, Dominik E. Künzler, Peter Kast, and Donald Hilvert pp 15002–15003 DOI: 10.1021/ja055871t Supporting Info

DNA Damage by Fasicularin Sanjay Dutta, Hideki Abe, Sakae Aoyagi, Chihiro Kibayashi, and Kent S. Gates pp 15004–15005 DOI: 10.1021/ja053735i Supporting Info

3/2-Order Chain Kinetics Involving a Postulated Dicationic Intermediate in the Isomerization of a P−Isocyano to a P−Cyano Azaphosphatrane Monocation Jesudoss V. Kingston, John G. Verkade, and James H. Espenson pp 15006–15007 DOI: 10.1021/ja054164x

ZiCo:  A Peptide Designed to Switch Folded State upon Binding Zinc Eleonora Cerasoli, Belinda K. Sharpe, and Derek N. Woolfson pp 15008–15009 DOI: 10.1021/ja0543604 Supporting Info

Synthesis, Characterization, and Structure of Cyclopenta[c]thiophenes and Their Manganese Complexes Chad A. Snyder, John P. Selegue, Nathan C. Tice, Chad E. Wallace, Mark T. Blankenbuehler, Sean Parkin, Keith D. E. Allen, and Ryan T. Beck pp 15010–15011 DOI: 10.1021/ja054513n Supporting Info

Oxidation Reactions of the Phosphinidene Oxide Ligand María Alonso, M. Angeles Alvarez, M. Esther García, Miguel A. Ruiz, Hayrullo Hamidov, and John C. Jeffery pp 15012–15013 DOI: 10.1021/ja054941t Supporting Info

EPR Distance Measurements Support a Model for Long-Range Radical Initiation in E. coli Ribonucleotide Reductase Marina Bennati, John H. Robblee, Veronica Mugnaini, Joanne Stubbe, Jack H. Freed, and Peter Borbat pp 15014–15015 DOI: 10.1021/ja054991y

Highly Stereoselective [2,3]-Sigmatropic Rearrangement of Sulfur Ylide Generated through Cu(I) Carbene and Sulfides Ming Ma, Lingling Peng, Changkun Li, Xiu Zhang, and Jianbo Wang pp 15016–15017 DOI: 10.1021/ja055021d Supporting Info

Proton-Mediated Electron Configuration Change in High-Spin Iron(II) Porphyrinates Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 15018–15019 DOI: 10.1021/ja055129t Supporting Info

A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium Russell P. Hughes, Roman B. Laritchev, Jian Yuan, James A. Golen, Adam N. Rucker, and Arnold L. Rheingold pp 15020–15021 DOI: 10.1021/ja055166k Supporting Info

Synthesis of 2,3-Disubstituted Benzofurans by Platinum−Olefin-Catalyzed Carboalkoxylation of o-Alkynylphenyl Acetals Itaru Nakamura, Yuya Mizushima, and Yoshinori Yamamoto pp 15022–15023 DOI: 10.1021/ja055202f Supporting Info

Heterocycles by PtCl2-Catalyzed Intramolecular Carboalkoxylation or Carboamination of Alkynes Alois Fürstner and Paul W. Davies pp 15024–15025 DOI: 10.1021/ja055659p Supporting Info

Total Synthesis of Reblastatin Iwona E. Wrona, Ana E. Gabarda, Gwilherm Evano, and James S. Panek pp 15026–15027 DOI: 10.1021/ja055384d Supporting Info

Synthesis of Dihydronaphthalenes via Aryne Diels−Alder Reactions:  Scope and Diastereoselectivity Chris Dockendorff, Stefan Sahli, Madeline Olsen, Ludovic Milhau, and Mark Lautens pp 15028–15029 DOI: 10.1021/ja055498p Supporting Info

Controlled Fabrication of 1D Molecular Lines Across the Dimer Rows on the Si(100)−(2 × 1)−H Surface through the Radical Chain Reaction Md. Zakir Hossain, Hiroyuki S. Kato, and Maki Kawai pp 15030–15031 DOI: 10.1021/ja055515a

Composite Alignment Media for the Measurement of Independent Sets of NMR Residual Dipolar Couplings Ke Ruan and Joel R. Tolman pp 15032–15033 DOI: 10.1021/ja055520e Supporting Info

Single Crystal Manganese Oxide Multipods by Oriented Attachment David Zitoun, Nicola Pinna, Nathalie Frolet, and Claude Belin pp 15034–15035 DOI: 10.1021/ja0555926 Supporting Info

Catalytic Asymmetric Reductive Michael Cyclization Jung Woon Yang, Maria T. Hechavarria Fonseca, and Benjamin List pp 15036–15037 DOI: 10.1021/ja055735o Supporting Info

Stereocontrolled Total Synthesis of (−)-Eudistomin C Tohru Yamashita, Nobutaka Kawai, Hidetoshi Tokuyama, and Tohru Fukuyama pp 15038–15039 DOI: 10.1021/ja055832h Supporting Info

Direct Experimental Observation of the Effect of the Base Pairing on the Oxidation Potential of Guanine Tonino Caruso, Maurizio Carotenuto, Ermanno Vasca, and Andrea Peluso pp 15040–15041 DOI: 10.1021/ja055130s Supporting Info

Discovery of a Biologically Active Thiostrepton Fragment K. C. Nicolaou, Mark Zak, Shai Rahimipour, Anthony A. Estrada, Sang Hyup Lee, Aurora O'Brate, Paraskevi Giannakakou, and M. Reza Ghadiri pp 15042–15044 DOI: 10.1021/ja0552803 Supporting Info

Directing and Sensing Changes in Molecular Conformation on Individual Carbon Nanotube Field Effect Transistors Xuefeng Guo, Limin Huang, Stephen O'Brien, Philip Kim, and Colin Nuckolls pp 15045–15047 DOI: 10.1021/ja054335y Supporting Info

An Unprecedented Twist to ODCase Catalytic Activity Masahiro Fujihashi, Angelica M. Bello, Ewa Poduch, Lianhu Wei, Subhash C. Annedi, Emil F. Pai, and Lakshmi P. Kotra pp 15048–15050 DOI: 10.1021/ja054865u Supporting Info

Enantioselective Organo-Cascade Catalysis Yong Huang, Abbas M. Walji, Catharine H. Larsen, and David W. C. MacMillan pp 15051–15053 DOI: 10.1021/ja055545d Supporting Info

Periodic ab Initio Approach for the Cooperative Effect of CH/π Interaction in Crystals:  Relative Energy of CH/π and Hydrogen-Bonding Interactions Yuka Kobayashi and Kazuhiko Saigo pp 15054–15060 DOI: 10.1021/ja0434580

Catalytic Transesterification of Dialkyl Phosphates by a Bioinspired Dicopper(II) Macrocyclic Complex Malgorzata Jagoda, Sabine Warzeska, Hans Pritzkow, Hubert Wadepohl, Petra Imhof, Jeremy C. Smith, and Roland Krämer pp 15061–15070 DOI: 10.1021/ja051357b Supporting Info

A Versatile Toolbox for Variable DNA Functionalization at High Density Stefan Jäger, Goran Rasched, Hagit Kornreich-Leshem, Marianne Engeser, Oliver Thum, and Michael Famulok pp 15071–15082 DOI: 10.1021/ja051725b Supporting Info

Mechanistic Insights into the Phosphine-Free RuCp*-Diamine-Catalyzed Hydrogenation of Aryl Ketones:  Experimental and Theoretical Evidence for an Alcohol-Mediated Dihydrogen Activation Christian Hedberg, Klas Källström, Per I. Arvidsson, Peter Brandt and Pher G. Andersson pp 15083–15090 DOI: 10.1021/ja051920q Supporting Info

Electronic and Steric Effects on Molecular Dihydrogen Activation in [Cp*OsH4(L)]+ (L = PPh3, AsPh3, and PCy3) Charles Edwin Webster, Christopher L. Gross, Dianna M. Young, Gregory S. Girolami, Arthur J. Schultz, Michael B. Hall, and Juergen Eckert pp 15091–15101 DOI: 10.1021/ja052336k Supporting Info

Knots in Globule and Coil Phases of a Model Polyethylene Peter Virnau, Yacov Kantor, and Mehran Kardar pp 15102–15106 DOI: 10.1021/ja052438a

Soft Vesicles Formed by Diblock Codendrimers of Poly(benzyl ether) and Poly(methallyl dichloride) Miao Yang, Wei Wang, Fei Yuan, Xiwen Zhang, Jinying Li, Fuxia Liang, Binglin He, Britt Minch, and Gerhard Wegner pp 15107–15111 DOI: 10.1021/ja052713t Supporting Info

Transport of Organic Solutes through Amorphous Teflon AF Films Hong Zhao, Jie Zhang, Nianqiang Wu, Xu Zhang, Katie Crowley, and Stephen G. Weber pp 15112–15119 DOI: 10.1021/ja052875p Supporting Info

Triplet State Photosensitization of Nanocrystalline Metal Oxide Electrodes by Zinc-Substituted Cytochrome c:  Application to Hydrogen Evolution Yeni Astuti, Emilio Palomares, Saif Ahmed Haque, and James Robert Durrant pp 15120–15126 DOI: 10.1021/ja0533444

Common Semiopen Conformations of Mg2+-Free Ras, Rho, Rab, Arf, and Ran Proteins Combined with GDP and Their Similarity with GEF-Bound Forms Kenichi Mori, Masayuki Hata, Saburo Neya, and Tyuji Hoshino pp 15127–15137 DOI: 10.1021/ja0467972 Supporting Info

Separating the Contribution of Translational and Rotational Diffusion to Protein Association Yosef Yehuda Kuttner, Noga Kozer, Eugenia Segal, Gideon Schreiber, and Gilad Haran pp 15138–15144 DOI: 10.1021/ja053681c Supporting Info

Understanding How the Herpes Thymidine Kinase Orchestrates Optimal Sugar and Nucleobase Conformations To Accommodate Its Substrate at the Active Site:  A Chemical Approach Victor E. Marquez, Yongseok Choi, Maria Julieta Comin, Pamela Russ, Clifford George, Mahmoud Huleihel, Tsipi Ben-Kasus, and Riad Agbaria pp 15145–15150 DOI: 10.1021/ja053789s Supporting Info

Evidence of a Borderline Region between E1cb and E2 Elimination Reaction Mechanisms:  A Combined Experimental and Theoretical Study of Systems Activated by the Pyridine Ring Sergio Alunni, Filippo De Angelis, Laura Ottavi, Magdalini Papavasileiou, and Francesco Tarantelli pp 15151–15160 DOI: 10.1021/ja0539138 Supporting Info

Detection of the His-Heme Fe2+−NO Species in the Reduction of NO to N2O by ba3-Oxidase from Thermus thermophilus Eftychia Pinakoulaki, Takehiro Ohta, Tewfik Soulimane, Teizo Kitagawa, and Constantinos Varotsis pp 15161–15167 DOI: 10.1021/ja0539490 Supporting Info

Formation and Stabilization Model of the 42-mer Aβ Radical:  Implications for the Long-Lasting Oxidative Stress in Alzheimer's Disease Kazuma Murakami, Kazuhiro Irie, Hajime Ohigashi, Hideyuki Hara, Masaya Nagao, Takahiko Shimizu, and Takuji Shirasawa pp 15168–15174 DOI: 10.1021/ja054041c Supporting Info

Characterization of Oxygen Dynamics in ZrW2O8 Matthew R. Hampson, John S. O. Evans, and Paul Hodgkinson pp 15175–15181 DOI: 10.1021/ja054063z Supporting Info

Long-Range Electronic Coupling of MM Quadruple Bonds (M = Mo or W) via a 2,6-Azulenedicarboxylate Bridge Mikhail V. Barybin, Malcolm H. Chisholm, Naresh S. Dalal, Thomas H. Holovics, Nathan J. Patmore, Randall E. Robinson, and David J. Zipse pp 15182–15190 DOI: 10.1021/ja0541884 Supporting Info

Mechanism of White Phosphorus Activation by Three-Coordinate Molybdenum(III) Complexes:  A Thermochemical, Kinetic, and Quantum Chemical Investigation Frances H. Stephens, Marc J. A. Johnson, Christopher C. Cummins, Olga P. Kryatova, Sergey V. Kryatov, Elena V. Rybak-Akimova, J. Eric McDonough, and Carl D. Hoff pp 15191–15200 DOI: 10.1021/ja054253+ Supporting Info

Single Molecule Spectroscopic Investigation on Conformational Heterogeneity of Directly Linked Zinc(II) Porphyrin Arrays Mira Park, Sung Cho, Zin Seok Yoon, Naoki Aratani, Atsuhiro Osuka, and Dongho Kim pp 15201–15206 DOI: 10.1021/ja0544861 Supporting Info

Anti-Thyroid Drugs and Thyroid Hormone Synthesis:  Effect of Methimazole Derivatives on Peroxidase-Catalyzed Reactions Gouriprasanna Roy and G. Mugesh pp 15207–15217 DOI: 10.1021/ja054497u Supporting Info

Dependence of Field Switched Ordered Arrays of Dinuclear Mixed-Valence Complexes on the Distance between the Redox Centers and the Size of the Counterions Hua Qi, Anuradha Gupta, Bruce C. Noll, Gregory L. Snider, Yuhui Lu, Craig Lent, and Thomas P. Fehlner pp 15218–15227 DOI: 10.1021/ja054508j Supporting Info

Magnetic Field and Temperature Dependencies Shed Light on the Recombination Kinetics of a Transition Metal Donor/Acceptor System T. von Feilitzsch, P. Härter, O. Schiemann, M. E. Michel-Beyerle, U. E. Steiner, and P. Gilch pp 15228–15235 DOI: 10.1021/ja0547174

Combinatorial Multinuclear NMR and X-ray Diffraction Studies of Uranium(VI)-Nucleotide Complexes Zoltán Szabó, István Furó, and Ingeborg Csöregh pp 15236–15247 DOI: 10.1021/ja0550273 Supporting Info

Role of Protein Dynamics in Reaction Rate Enhancement by Enzymes Pratul K. Agarwal pp 15248–15256 DOI: 10.1021/ja055251s Supporting Info

Thermoreversible Cis−Cisoidal to Cis−Transoidal Isomerization of Helical Dendronized Polyphenylacetylenes Virgil Percec, Jonathan G. Rudick, Mihai Peterca, Martin Wagner, Makoto Obata, Catherine M. Mitchell, Wook-Dong Cho, Venkatachalapathy S. K. Balagurusamy, and Paul A. Heiney pp 15257–15264 DOI: 10.1021/ja055406w Supporting Info

A General Method for Preparation of Metal Carbenes via Solution- and Polymer-Based Approaches Mark Gandelman, Kyaw M. Naing, Boris Rybtchinski, Elena Poverenov, Yehoshoa Ben-David, Nissan Ashkenazi, Regis M. Gauvin, and David Milstein pp 15265–15272 DOI: 10.1021/ja050781+

The Structure of a Mixed LNA/DNA:RNA Duplex Is Driven by Conformational Coupling between LNA and Deoxyribose Residues as Determined from 13C Relaxation Measurements Katrine E. Nielsen and H. Peter Spielmann pp 15273–15282 DOI: 10.1021/ja051026z Supporting Info

Electronic Relaxation Dynamics of Water Cluster Anions Arthur E. Bragg, Jan R. R. Verlet, Aster Kammrath, Ori Cheshnovsky, and Daniel M. Neumark pp 15283–15295 DOI: 10.1021/ja052811e

Michael Addition Reactions between Chiral Equivalents of a Nucleophilic Glycine and (S)- or (R)-3-[(E)-Enoyl]-4-phenyl-1,3-oxazolidin-2-ones as a General Method for Efficient Preparation of β-Substituted Pyroglutamic Acids. Case of Topographically Controlled Stereoselectivity Vadim A. Soloshonok, Chaozhong Cai, Takeshi Yamada, Hisanori Ueki, Yasufumi Ohfune, and Victor J. Hruby pp 15296–15303 DOI: 10.1021/ja0535561 Supporting Info

The F/Ph Rearrangement Reaction of [(Ph3P)3RhF], the Fluoride Congener of Wilkinson's Catalyst Stuart A. Macgregor, D. Christopher Roe, William J. Marshall, Karen M. Bloch, Vladimir I. Bakhmutov, and Vladimir V. Grushin pp 15304–15321 DOI: 10.1021/ja054506z Supporting Info

Bismuth Spheres Grown in Self-Nested Cavities in a Silicon Wafer Hong Liu and Zhong Lin Wang pp 15322–15326 DOI: 10.1021/ja0547634

Nucleic Acid Analysis Using an Expanded Genetic Alphabet to Quench Fluorescence [J. Am. Chem. Soc. 2004, 126, 4550−4556]. Christopher B. Sherrill, David J. Marshall, Michael J. Moser, Christine A. Larsen, Lygia Daudé-Snow, and James R. Prudent p 15327 DOI: 10.1021/ja059917u

Advances in Chemical Physics, Volume 129 Edited by Stuart A. Rice (University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. x + 644 pp. $175.00. ISBN 0-471-44527-4. p 15328 DOI: 10.1021/ja059727j

New Aspects in Phosphorus Chemistry V. Topics in Current Chemistry, 250 Edited by Jean-Pierre Majoral (CNRS Toulouse, France). Springer:  Berlin, Heidelberg, New York. 2005. xiv + 276 pp. $259.00. ISBN 3-540-22498-X. Neil Burford p 15328 DOI: 10.1021/ja0597754

Dead Ends and Detours:  Direct Ways to Successful Total Synthesis By Miguel A. Sierra (Universidad Complutense, Madrid) and María C. de la Torre (CSIC, Madrid). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. xiv + 276 pp. $79.95. ISBN 3-527-30644-7. p 15328 DOI: 10.1021/ja059778g

Issue 44

Complementary Matching in Domain Formation within Lipid Bilayers Mark J. Stevens pp 15330–15331 DOI: 10.1021/ja043611q Supporting Info

Lacticin 481 Synthetase Phosphorylates its Substrate during Lantibiotic Production Champak Chatterjee, Leah M. Miller, Yong L. Leung, Lili Xie, Myongsin Yi, Neil L. Kelleher, and Wilfred A. van der Donk pp 15332–15333 DOI: 10.1021/ja0543043 Supporting Info

Water Molecules in a Protein Cavity Detected by a Statistical−Mechanical Theory Takashi Imai, Ryusuke Hiraoka, Andriy Kovalenko, and Fumio Hirata pp 15334–15335 DOI: 10.1021/ja054434b Supporting Info

Quasi-Continuous Growth of Ultralong Carbon Nanotube Arrays Byung Hee Hong, Ju Young Lee, Tobias Beetz, Yimei Zhu, Philip Kim, and Kwang S. Kim pp 15336–15337 DOI: 10.1021/ja054454d

Stable, Reproducible Nanorecording on Rotaxane Thin Films Min Feng, Xuefeng Guo, Xiao Lin, Xiaobo He, Wei Ji, Shixuan Du, Deqing Zhang, Daoben Zhu, and Hongjun Gao pp 15338–15339 DOI: 10.1021/ja054836j Supporting Info

Bromine is an Endogenous Component of a Vanadium Bromoperoxidase Martin C. Feiters, Catherine Leblanc, Frithjof C. Küpper, Wolfram Meyer-Klaucke, Gurvan Michel, and Philippe Potin pp 15340–15341 DOI: 10.1021/ja053416r Supporting Info

Sensitization of Nanocrystalline TiO2 with Black Absorbers Based on Os and Ru Polypyridine Complexes Silvano Altobello, Roberto Argazzi, Stefano Caramori, Cristiano Contado, Simone Da Fré, Patrizia Rubino, Christophe Choné, Gerardo Larramona, and Carlo Alberto Bignozzi pp 15342–15343 DOI: 10.1021/ja053438d Supporting Info

A Proposal for the Mechanism-of-Action of Diazoparaquinone Natural Products Ken S. Feldman and Kyle J. Eastman pp 15344–15345 DOI: 10.1021/ja053880w Supporting Info

The Tolman Length:  Is It Positive or Negative? Yi An Lei, Tikhon Bykov, Soohaeng Yoo, and Xiao Cheng Zeng pp 15346–15347 DOI: 10.1021/ja054297i Supporting Info

Direct Electrodeposition of Highly Dense Bi/Sb Superlattice Nanowire Arrays F. H. Xue, G. T. Fei, B. Wu, P. Cui, and L. D. Zhang pp 15348–15349 DOI: 10.1021/ja0547073 Supporting Info

Functional GPCR Microarrays Yulong Hong, Brian L. Webb, Hui Su, Eric J. Mozdy, Ye Fang, Qi Wu, Li Liu, Jonathan Beck, Ann M. Ferrie, Srikanth Raghavan, John Mauro, Alain Carre, Dirk Müeller, Fang Lai, Brian Rasnow, Michael Johnson, Hosung Min, John Salon, and Joydeep Lahiri pp 15350–15351 DOI: 10.1021/ja055101h Supporting Info

Synthesis, Resolution, and Aldol Reactions of a Planar-Chiral Lewis Acid Complex Shih-Yuan Liu, Ivory D. Hills, and Gregory C. Fu pp 15352–15353 DOI: 10.1021/ja0552702 Supporting Info

Regio- and Stereoselective Homocoupling of γ-Arylated tert-Propargyl Alcohols with Liberation of a Ketone Molecule and Successive Cyclization To Produce Fluorescent Dihydrofuran Derivatives Atsushi Funayama, Tetsuya Satoh, and Masahiro Miura pp 15354–15355 DOI: 10.1021/ja055452w Supporting Info

Blue Ferrocenium Azurin:  An Organometalloprotein with Tunable Redox Properties Hee Jung Hwang, James R. Carey, Evan T. Brower, Alan J. Gengenbach, Joseph A. Abramite, and Yi Lu pp 15356–15357 DOI: 10.1021/ja054983h Supporting Info

Polymer Nano- and Microspheres with Bumpy and Chain-Segregated Surfaces Ronghua Zheng, Guojun Liu, and Xiaohu Yan pp 15358–15359 DOI: 10.1021/ja054937h Supporting Info

Exogenous Nitrile Substrate Hydroxylation by a New Dicopper-Hydroperoxide Complex Lei Li, Amy A. Narducci Sarjeant, Michael A. Vance, Lev. N. Zakharov, Arnold L. Rheingold, Edward I. Solomon, and Kenneth D. Karlin pp 15360–15361 DOI: 10.1021/ja054948a Supporting Info

Three-Layer Composite Magnetic Nanoparticle Probes for DNA Savka I. Stoeva, Fengwei Huo, Jae-Seung Lee, and Chad A. Mirkin pp 15362–15363 DOI: 10.1021/ja055056d Supporting Info

Facile Ru−H2 Heterolytic Activation and Intramolecular Proton Transfer Assisted by Basic N-Centers in the Ligands Félix A. Jalón, Blanca R. Manzano, Agustín Caballero, M. Carmen Carrión, Lucía Santos, Gustavo Espino, and Miquel Moreno pp 15364–15365 DOI: 10.1021/ja055116f Supporting Info

E-Olefin Dipeptide Isostere Incorporation into a Polypeptide Backbone Enables Hydrogen Bond Perturbation:  Probing the Requirements for Alzheimer's Amyloidogenesis Yanwen Fu, Jan Bieschke, and Jeffery W. Kelly pp 15366–15367 DOI: 10.1021/ja0551382 Supporting Info

DNA Single Strands Tethered to Fused Quartz/Water Interfaces Studied by Second Harmonic Generation Faith C. Boman, Michael J. Musorrafiti, Julianne M. Gibbs, Brian R. Stepp, Anne M. Salazar, SonBinh T. Nguyen, and Franz M. Geiger pp 15368–15369 DOI: 10.1021/ja055468m Supporting Info

Nature of the Cytochrome c Molten Globule Ekaterina V. Pletneva, Harry B. Gray, and Jay R. Winkler pp 15370–15371 DOI: 10.1021/ja0555318 Supporting Info

Polyether-Bridged Sexithiophene as a Complexation-Gated Molecular Wire for Intramolecular Photoinduced Electron Transfer Takuro Oike, Tomoyuki Kurata, Kazuo Takimiya, Tetsuo Otsubo, Yoshio Aso, Huimin Zhang, Yasuyuki Araki, and Osamu Ito pp 15372–15373 DOI: 10.1021/ja055648w Supporting Info

Mechanism for Reduction Catalysis by Metal Oxo:  Hydrosilation of Organic Carbonyl Groups Catalyzed by a Rhenium(V) Oxo Complex Elon A. Ison, Evan R. Trivedi, Rex A. Corbin, and Mahdi M. Abu-Omar pp 15374–15375 DOI: 10.1021/ja055704t Supporting Info

A Stable Fused Bicyclic Disilene as a Model for Silicon Surface Hideki Kobayashi, Takeaki Iwamoto, and Mitsuo Kira pp 15376–15377 DOI: 10.1021/ja055718z Supporting Info

White-Light Emission from Magic-Sized Cadmium Selenide Nanocrystals Michael J. Bowers II, James R. McBride, and Sandra J. Rosenthal pp 15378–15379 DOI: 10.1021/ja055470d Supporting Info

Initial Example of a Triangular Single-Molecule Magnet from Ligand-Induced Structural Distortion of a [MnIII3O]7+ Complex Theocharis C. Stamatatos, Dolos Foguet-Albiol, Constantinos C. Stoumpos, Catherine P. Raptopoulou, Aris Terzis, Wolfang Wernsdorfer, Spyros P. Perlepes, and George Christou pp 15380–15381 DOI: 10.1021/ja0558138 Supporting Info

Catalytic Ni/Cr-Mediated Macrocyclization without Use of High-Dilution Techniques Kosuke Namba and Yoshito Kishi pp 15382–15383 DOI: 10.1021/ja055966v Supporting Info

Modeling Side-On NO Coordination to Type 2 Copper in Nitrite Reductase:  Structures, Energetics, and Bonding Ingar H. Wasbotten and Abhik Ghosh pp 15384–15385 DOI: 10.1021/ja0559909 Supporting Info

Proteasome Inhibition by a Totally Synthetic β-Lactam Related to Salinosporamide A and Omuralide Philip C. Hogan and E. J. Corey pp 15386–15387 DOI: 10.1021/ja056284a Supporting Info

Broad Spectral Domain Fluorescence Wavelength Modulation of Visible and Near-Infrared Emissive Polymersomes P. Peter Ghoroghchian, Paul R. Frail, Kimihiro Susumu, Tae-Hong Park, Sophia P. Wu, H. Tetsuo Uyeda, Daniel A. Hammer, and Michael J. Therien pp 15388–15390 DOI: 10.1021/ja055571b Supporting Info

Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C−H Bonds Using Hydrogen Peroxide Benjamin H. Brodsky and J. Du Bois pp 15391–15393 DOI: 10.1021/ja055549i Supporting Info

Enantioselective Total Syntheses of Welwitindolinone A and Fischerindoles I and G Phil S. Baran and Jeremy M. Richter pp 15394–15396 DOI: 10.1021/ja056171r Supporting Info

Ab Initio QM/MM Study of Class A β-Lactamase Acylation:  Dual Participation of Glu166 and Lys73 in a Concerted Base Promotion of Ser70 Samy O. Meroueh, Jed F. Fisher, H. Bernhard Schlegel, and Shahriar Mobashery pp 15397–15407 DOI: 10.1021/ja051592u Supporting Info

A Strand-Loop-Strand Structure Is a Possible Intermediate in Fibril Elongation:  Long Time Simulations of Amyloid-β Peptide (10−35) Wei Han and Yun-Dong Wu pp 15408–15416 DOI: 10.1021/ja051699h Supporting Info

Long-Lived Spin-Correlated Pairs Generated by Photolysis of Naphthalene Occluded in Non-Brønsted Acidic ZSM-5 Zeolites Alain Moissette, Séverine Marquis, David Cornu, Hervé Vezin, and Claude Brémard pp 15417–15428 DOI: 10.1021/ja0518225

New Hints on the pH-Driven Tautomeric Equilibria of the Topotecan Anticancer Drug in Aqueous Solutions from an Integrated Spectroscopic and Quantum-Mechanical Approach Nico Sanna, Giovanni Chillemi, Andrea Grandi, Silvia Castelli, Alessandro Desideri, and Vincenzo Barone pp 15429–15436 DOI: 10.1021/ja052637u Supporting Info

Raman and IR Spectroscopy of Chemically Processed Single-Walled Carbon Nanotubes Un Jeong Kim, Clascidia A. Furtado, Xiaoming Liu, Gugang Chen, and Peter C. Eklund pp 15437–15445 DOI: 10.1021/ja052951o

Adsorption of Ions to the Surface of Dilute Electrolyte Solutions:  The Jones−Ray Effect Revisited Poul B. Petersen and Richard J. Saykally pp 15446–15452 DOI: 10.1021/ja053224w

Al-Catalyzed Enantioselective Alkylation of α-Ketoesters by Dialkylzinc Reagents. Enhancement of Enantioselectivity and Reactivity by an Achiral Lewis Base Additive Laura C. Wieland, Hongbo Deng, Marc L. Snapper, and Amir H. Hoveyda pp 15453–15456 DOI: 10.1021/ja053259w Supporting Info

The Peculiar Trend of Cyclic Perfluoroalkane Electron Affinities with Increasing Ring Size Ankan Paul, Chaitanya S. Wannere, Veronica Kasalova, Paul v. R. Schleyer, and Henry F. Schaefer III pp 15457–15469 DOI: 10.1021/ja053310w Supporting Info

Kinetic and Spectroscopic Studies of the [Palladium(Ar-bian)]-Catalyzed Semi-Hydrogenation of 4-Octyne Alexander M. Kluwer, Tehila S. Koblenz, Thorsten Jonischkeit, Klaus Woelk, and Cornelis J. Elsevier pp 15470–15480 DOI: 10.1021/ja052729j Supporting Info

Perforated Layer Structures in Liquid Crystalline Rod−Coil Block Copolymers Kishore K. Tenneti, Xiaofang Chen, Christopher Y. Li, Yingfeng Tu, Xinhua Wan, Qi-Feng Zhou, Igors Sics, and Benjamin S. Hsiao pp 15481–15490 DOI: 10.1021/ja053548k Supporting Info

Reactant Concentrations from Fluorescence Correlation Spectroscopy with Tailored Fluorescent Probes. An Example of Local Calibration-Free pH Measurement Sandrine Charier, Adrien Meglio, Damien Alcor, Emmanuelle Cogné-Laage, Jean-François Allemand, Ludovic Jullien, and Annie Lemarchand pp 15491–15505 DOI: 10.1021/ja053909w Supporting Info

A Simple Iridium Catalyst with a Single Resolved Stereocenter for Enantioselective Allylic Amination. Catalyst Selection from Mechanistic Analysis Andreas Leitner, Shashank Shekhar, Mark J. Pouy, and John F. Hartwig pp 15506–15514 DOI: 10.1021/ja054331t Supporting Info

On the Correlation between Bond-Length Change and Vibrational Frequency Shift in Hydrogen-Bonded Complexes:  A Computational Study of Y···HCl Dimers (Y = N2, CO, BF) Sean A. C. McDowell and A. David Buckingham pp 15515–15520 DOI: 10.1021/ja0543651 Supporting Info

Substrate Activity Screening:  A Fragment-Based Method for the Rapid Identification of Nonpeptidic Protease Inhibitors Warren J. L. Wood, Andrew W. Patterson, Hiroyuki Tsuruoka, Rishi K. Jain, and Jonathan A. Ellman pp 15521–15527 DOI: 10.1021/ja0547230 Supporting Info

Chiral Zirconium Catalysts Using Multidentate BINOL Derivatives for Catalytic Enantioselective Mannich-Type Reactions; Ligand Optimization and Approaches to Elucidation of the Catalyst Structure Yoichi Ihori, Yasuhiro Yamashita, Haruro Ishitani, and Shū Kobayashi pp 15528–15535 DOI: 10.1021/ja053524d Supporting Info

Large Optical Activity of Gold Nanocluster Enantiomers Induced by a Pair of Optically Active Penicillamines Hiroshi Yao, Kanae Miki, Naoki Nishida, Akito Sasaki, and Keisaku Kimura pp 15536–15543 DOI: 10.1021/ja053504b Supporting Info

Control of Photochemical, Photophysical, Electrochemical, and Photocatalytic Properties of Rhenium(I) Complexes Using Intramolecular Weak Interactions between Ligands Hideaki Tsubaki, Akiko Sekine, Yuji Ohashi, Kazuhide Koike, Hiroyuki Takeda, and Osamu Ishitani pp 15544–15555 DOI: 10.1021/ja053814u Supporting Info

Planar Polarized Light Emission from CdSe Nanoparticle Clusters Jin Young Kim, Hiroki Hiramatsu, and Frank E. Osterloh pp 15556–15561 DOI: 10.1021/ja0541377 Supporting Info

Electrical Discharge in a Nanometer-Sized Air/Water Gap Observed by Atomic Force Microscopy Xian Ning Xie, Hong Jing Chung, Chorng Haur Sow, Kazimierz Adamiak, and Andrew Thye Shen Wee pp 15562–15567 DOI: 10.1021/ja054225r Supporting Info

Activation of High-TC Ferromagnetism in Co2+:TiO2 and Cr3+:TiO2 Nanorods and Nanocrystals by Grain Boundary Defects J. Daniel Bryan, Steven A. Santangelo, Sean C. Keveren, and Daniel R. Gamelin pp 15568–15574 DOI: 10.1021/ja0543447 Supporting Info

Effect of Temperature, Cholesterol Content, and Antioxidant Structure on the Mobility of Vitamin E Constituents in Biomembrane Models Studied by Laterally Diffusion-Controlled Fluorescence Quenching Andreas F.-P. Sonnen, Huseyin Bakirci, Thomas Netscher, and Werner M. Nau pp 15575–15584 DOI: 10.1021/ja054367l Supporting Info

Carbon−Fluorine Bond Activation Coupled with Carbon−Hydrogen Bond Formation α to Iridium:  Kinetics, Mechanism, and Diastereoselectivity Shaun A. Garratt, Russell P. Hughes, Ivan Kovacik, Antony J. Ward, Stefan Willemsen, and Donghui Zhang pp 15585–15594 DOI: 10.1021/ja0545012

Growth and Assembly of Crystalline Tungsten Oxide Nanostructures Assisted by Bioligation Julien Polleux, Nicola Pinna, Markus Antonietti, and Markus Niederberger pp 15595–15601 DOI: 10.1021/ja0544915

Multiple-Site Exchange in Proteins Studied with a Suite of Six NMR Relaxation Dispersion Experiments:  An Application to the Folding of a Fyn SH3 Domain Mutant Dmitry M. Korzhnev, Philipp Neudecker, Anthony Mittermaier, Vladislav Yu. Orekhov, and Lewis E. Kay pp 15602–15611 DOI: 10.1021/ja054550e Supporting Info

Differential Solvation and Tautomer Stability of a Model Base Pair within the Minor and Major Grooves of DNA François-Yves Dupradeau, David A. Case, Chengzhi Yu, Ralph Jimenez, and Floyd E. Romesberg pp 15612–15617 DOI: 10.1021/ja054607x Supporting Info

Nano-Segregated Polymeric Film Exhibiting High Ionic Conductivities Kenji Kishimoto, Tomoyuki Suzawa, Tomoki Yokota, Tomohiro Mukai, Hiroyuki Ohno, and Takashi Kato pp 15618–15623 DOI: 10.1021/ja0549594 Supporting Info

Photocontrol of DNA Binding Specificity of a Miniature Engrailed Homeodomain Lucia Guerrero, Oliver S. Smart, G. Andrew Woolley, and Rudolf K. Allemann pp 15624–15629 DOI: 10.1021/ja0550428 Supporting Info

Direct Observation of a Transverse Vibrational Mechanism for Negative Thermal Expansion in Zn(CN)2:  An Atomic Pair Distribution Function Analysis Karena W. Chapman, Peter J. Chupas, and Cameron J. Kepert pp 15630–15636 DOI: 10.1021/ja055197f Supporting Info

Nonequilibrium Synthesis and Assembly of Hybrid Inorganic−Protein Nanostructures Using an Engineered DNA Binding Protein Haixia Dai, Woo-Seok Choe, Corrine K. Thai, Mehmet Sarikaya, Beth A. Traxler, François Baneyx, and Daniel T. Schwartz pp 15637–15643 DOI: 10.1021/ja055499h

Total Synthesis of the Thiopeptide Antibiotic Amythiamicin D Rachael A. Hughes, Stewart P. Thompson, Lilian Alcaraz, and Christopher J. Moody pp 15644–15651 DOI: 10.1021/ja0547937 Supporting Info

Total Synthesis of (−)-Crambidine and Definition of the Relative Configuration of Its Unique Tetracyclic Guanidinium Core Larry E. Overman and Young Ho Rhee pp 15652–15658 DOI: 10.1021/ja055464h Supporting Info

Immobilized Catalysts:  Solid Phases, Immobilization and Applications. Topics in Current Chemistry, 242 Edited by A. Kirschning (Universität Hannover). Springer:  Berlin, Heidelberg, New York. 2004. x + 336 pp. $299.00. ISBN 3-540-20915-8. Richard A. Jones p 15659 DOI: 10.1021/ja059706p

Macromolecules Containing Metal and Metal-like Elements, Volume 4:  Group IVA Polymers Edited by Alaa S. Abd-El-Aziz (University of Winnipeg), Charles E. Carraher, Jr. (Florida Atlantic University), Charles U. Pittman, Jr. (Mississippi State University) and Martel Zeldin (Hobart and William Smith Colleges). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xviii + 348 pp. $125.00. ISBN 0-471-68238-1. Michael A. Brook p 15659 DOI: 10.1021/ja059736s

Modern Rhodium-Catalyzed Organic Reactions Edited by P. Andrew Evans (Indiana University). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xxiv + 474 pp. $185.00. ISBN 3-527-30683-8. Joseph M. O'Connor pp 15659–15660 DOI: 10.1021/ja0597451

Issue 45

A General Acid−Base Mechanism for the Stabilization of a Tetrahedral Adduct in a Serine−Carboxyl Peptidase:  A Computational Study Haobo Guo, Alexander Wlodawer, and Hong Guo pp 15662–15663 DOI: 10.1021/ja0520565 Supporting Info

Locked Nucleic Acid Molecular Beacons Lin Wang, Chaoyong James Yang, Colin D. Medley, Steven A. Benner, and Weihong Tan pp 15664–15665 DOI: 10.1021/ja052498g Supporting Info

Highly Selective Chromogenic and Redox or Fluorescent Sensors of Hg2+ in Aqueous Environment Based on 1,4-Disubstituted Azines Antonio Caballero, Rosario Martínez, Vega Lloveras, Imma Ratera, José Vidal-Gancedo, Klaus Wurst, Alberto Tárraga, Pedro Molina, and Jaume Veciana pp 15666–15667 DOI: 10.1021/ja0545766 Supporting Info

Amine Capture Strategy for Peptide Bond Formation by Means of Quinolinium Thioester Salts Stéphane Leleu, Maël Penhoat, Alexis Bouet, Georges Dupas, Cyril Papamicaël, Francis Marsais, and Vincent Levacher pp 15668–15669 DOI: 10.1021/ja054775p Supporting Info

Stable Biomimetic Super-Hydrophobic Engineering Materials Zhiguang Guo, Feng Zhou, Jingcheng Hao, and Weimin Liu pp 15670–15671 DOI: 10.1021/ja0547836 Supporting Info

Iron-Catalyzed Olefin cis-Dihydroxylation Using a Bio-Inspired N,N,O-Ligand Paul D. Oldenburg, Albert A. Shteinman, and Lawrence Que, Jr. pp 15672–15673 DOI: 10.1021/ja054947i Supporting Info

Ionization Spectroscopy of a DNA Base:  Vacuum-Ultraviolet Mass-Analyzed Threshold Ionization Spectroscopy of Jet-Cooled Thymine Kyo-Won Choi, Joo-Hee Lee, and Sang Kyu Kim pp 15674–15675 DOI: 10.1021/ja055018u Supporting Info

Anodic Preparation of [Re2Cp2(CO)6]2+:  A Dimeric Dication that Provides the Powerful One-Electron Oxidant [ReCp(CO)3]+ Daesung Chong, Ayman Nafady, Paulo Jorge Costa, Maria José Calhorda, and William E. Geiger pp 15676–15677 DOI: 10.1021/ja055045k Supporting Info

How Bulky Is a Bulky Ligand:  Energetic Consequences of Steric Constraint in Ligand-Directed Cluster Assembly and Disassembly Xuan Jiang, John C. Bollinger, and Dongwhan Lee pp 15678–15679 DOI: 10.1021/ja055225u Supporting Info

Gold-Caged Metal Clusters with Large HOMO−LUMO Gap and High Electron Affinity Yi Gao, Satya Bulusu, and Xiao Cheng Zeng pp 15680–15681 DOI: 10.1021/ja055407o Supporting Info

Electron-Precise/Deficient La5-xCaxGe4 (3.4 ≤ x ≤ 3.8) and Ce5-xCaxGe4 (3.0 ≤ x ≤ 3.3):  Probing Low-Valence Electron Concentrations in Metal-Rich Gd5Si4-type Germanides Li-Ming Wu, Sang-Hwan Kim, and Dong-Kyun Seo pp 15682–15683 DOI: 10.1021/ja055568s Supporting Info

Carbon-to-Metal Hydrogen Atom Transfer:  Direct Observation Using Time-Resolved Infrared Spectroscopy Jie Zhang, David C. Grills, Kuo-Wei Huang, Etsuko Fujita, and R. Morris Bullock pp 15684–15685 DOI: 10.1021/ja0555724 Supporting Info

Millimeter Scale Alignment of Magnetic Nanoparticle Functionalized Microtubules in Magnetic Fields Mark Platt, Gayatri Muthukrishnan, William O. Hancock, and Mary Elizabeth Williams pp 15686–15687 DOI: 10.1021/ja055815s Supporting Info

AFM Single Molecule Experiments at the Solid−Liquid Interface:  In Situ Conformation of Adsorbed Flexible Polyelectrolyte Chains Yuri Roiter and Sergiy Minko pp 15688–15689 DOI: 10.1021/ja0558239 Supporting Info

The Burial of Solvent-Accessible Surface Area is a Predictor of Polypeptide Folding and Misfolding as a Function of Chain Elongation Neşe Kurt and Silvia Cavagnero pp 15690–15691 DOI: 10.1021/ja0560682 Supporting Info

Color-Tunable Photoluminescence of Alloyed CdSxSe1-x Nanobelts Anlian Pan, Hua Yang, Ruibin Liu, Richeng Yu, Bingsuo Zou, and Zhonglin Wang pp 15692–15693 DOI: 10.1021/ja056116i Supporting Info

Self-Assembly of Hollow Cones in a Bola-amphiphile/Hexadiamine Salt Solution Jean-Paul Douliez pp 15694–15695 DOI: 10.1021/ja0560478 Supporting Info

Brønsted Acid-Catalyzed Imine Amidation Gerald B. Rowland, Haile Zhang, Emily B. Rowland, Spandan Chennamadhavuni, Yong Wang, and Jon C. Antilla pp 15696–15697 DOI: 10.1021/ja0533085 Supporting Info

Self-Catalytic Behavior of Carbon Nanotubes Zhenping Zhu, Yi Lu, Dahong Qiao, Shuli Bai, Tuoping Hu, Li Li, and Jianfeng Zheng pp 15698–15699 DOI: 10.1021/ja053844x Supporting Info

High Performance Organic Field-Effect Transistors Based on Amphiphilic Tris(phthalocyaninato) Rare Earth Triple-Decker Complexes Yanli Chen, Wei Su, Ming Bai, Jianzhuang Jiang, Xiyou Li, Yunqi Liu, Lingxuan Wang, and Shuangqing Wang pp 15700–15701 DOI: 10.1021/ja054343e Supporting Info

Carbon Monoxide-Promoted Carbene Insertion into the Aryl Substituent of an N-Heterocyclic Carbene Ligand:  Buchner Reaction in a Ruthenium Carbene Complex Brandon R. Galan, Milan Gembicky, Paulina M. Dominiak, Jerome B. Keister, and Steven T. Diver pp 15702–15703 DOI: 10.1021/ja0545618 Supporting Info

Total Synthesis of Piericidin A1 and B1 Martin J. Schnermann and Dale L. Boger pp 15704–15705 DOI: 10.1021/ja055041f Supporting Info

Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron−Chlorine Bond Akihiko Yamamoto and Michinori Suginome pp 15706–15707 DOI: 10.1021/ja055396z Supporting Info

Activation of Orotidine 5‘-Monophosphate Decarboxylase by Phosphite Dianion:  The Whole Substrate is the Sum of Two Parts Tina L. Amyes, John P. Richard, and James J. Tait pp 15708–15709 DOI: 10.1021/ja055493s Supporting Info

Asymmetric Multicomponent Domino Reactions and Highly Enantioselective Conjugated Addition of Thiols to α,β-Unsaturated Aldehydes Mauro Marigo, Tobias Schulte, Johan Franzén, and Karl Anker Jørgensen pp 15710–15711 DOI: 10.1021/ja055291w Supporting Info

An Expeditious Total Synthesis of (±)-Stenine Yibin Zeng and Jeffrey Aubé pp 15712–15713 DOI: 10.1021/ja055629m Supporting Info

Stable Triplet of Uracil−Uracil Basepairs in a Small Antisense RNA Yiping Zhan and Gordon S. Rule pp 15714–15715 DOI: 10.1021/ja055675m Supporting Info

Synthesis of Fused Polycyclic Aromatics by Palladium-Catalyzed Annulation of Arynes Using 2-Halobiaryls Zhijian Liu, Xiaoxia Zhang, and Richard C. Larock pp 15716–15717 DOI: 10.1021/ja055781o Supporting Info

High Yield Solution−Liquid−Solid Synthesis of Germanium Nanowires Xianmao Lu, Dayne D. Fanfair, Keith P. Johnston, and Brian A. Korgel pp 15718–15719 DOI: 10.1021/ja055850z Supporting Info

Determination of a Large Reorganization Energy Barrier for Hydride Abstraction by Glucose Oxidase David W. Brinkley and Justine P. Roth pp 15720–15721 DOI: 10.1021/ja056025l Supporting Info

Route to GaN and VN Assisted by Carbothermal Reduction Process Huaizhou Zhao, Ming Lei, Xin'an Yang, Jikang Jian, and Xiaolong Chen pp 15722–15723 DOI: 10.1021/ja055877i Supporting Info

Chirality- and Diameter-Dependent Reactivity of NO2 on Carbon Nanotube Walls Kwanyong Seo, Kyung Ah Park, Changwook Kim, Seungwu Han, Bongsoo Kim, and Young Hee Lee pp 15724–15729 DOI: 10.1021/ja052556y Supporting Info

One-Electron Reduction Potential for Oxygen- and Sulfur-Centered Organic Radicals in Protic and Aprotic Solvents Marcel Schmidt am Busch and Ernst-Walter Knapp pp 15730–15737 DOI: 10.1021/ja0526923 Supporting Info

1,8-Bis(hexamethyltriaminophosphazenyl)naphthalene, HMPN:  A Superbasic Bisphosphazene “Proton Sponge” Volker Raab, Ekaterina Gauchenova, Alexei Merkoulov, Klaus Harms, Jörg Sundermeyer, Borislav Kovaević, and Zvonimir B. Maksić pp 15738–15743 DOI: 10.1021/ja052647v Supporting Info

Slow Diffusion by Singlet State NMR Spectroscopy Simone Cavadini, Jens Dittmer, Sasa Antonijevic, and Geoffrey Bodenhausen pp 15744–15748 DOI: 10.1021/ja052897b

Enzymatic Synthesis of Layered Titanium Phosphates at Low Temperature and Neutral pH by Cell-Surface Display of Silicatein-α Paul Curnow, Paul H. Bessette, David Kisailus, Meredith M. Murr, Patrick S. Daugherty, and Daniel E. Morse pp 15749–15755 DOI: 10.1021/ja054307f

Nonradical Zinc−Barbier Reaction for Diastereoselective Synthesis of Vicinal Amino Alcohols Lise Keinicke, Peter Fristrup, Per-Ola Norrby, and Robert Madsen pp 15756–15761 DOI: 10.1021/ja054706a Supporting Info

Octasubstituted Metal-Free Phthalocyanine as Core of Phosphorus Dendrimers:  A Probe for the Properties of the Internal Structure Julien Leclaire, Rodolphe Dagiral, Suzanne Fery-Forgues, Yannick Coppel, Bruno Donnadieu, Anne-Marie Caminade, and Jean-Pierre Majoral pp 15762–15770 DOI: 10.1021/ja054797b Supporting Info

Nonlinear Optical Studies of the Agricultural Antibiotic Morantel Interacting with Silica/Water Interfaces Christopher T. Konek, Kimberly D. Illg, Hind A. Al-Abadleh, Andrea B. Voges, Grace Yin, Michael J. Musorrafiti, Catherine M. Schmidt, and Franz M. Geiger pp 15771–15777 DOI: 10.1021/ja054837b

Active Site Structure of Class I Ribonucleotide Reductase Intermediate X:  A Density Functional Theory Analysis of Structure, Energetics, and Spectroscopy Wen-Ge Han, Tiqing Liu, Timothy Lovell, and Louis Noodleman pp 15778–15790 DOI: 10.1021/ja050904q Supporting Info

Microwave-Enhanced Reaction Rates for Nanoparticle Synthesis Jeffrey A. Gerbec, Donny Magana, Aaron Washington, and Geoffrey F. Strouse pp 15791–15800 DOI: 10.1021/ja052463g Supporting Info

Practical Route to Relative Diffusion Coefficients and Electronic Relaxation Rates of Paramagnetic Metal Complexes in Solution by Model-Independent Outer-Sphere NMRD. Potentiality for MRI Contrast Agents Pascal H. Fries, Christelle Gateau, and Marinella Mazzanti pp 15801–15814 DOI: 10.1021/ja052800l Supporting Info

Thioredoxin and Lipoic Acid Catalyze the Denitrosation of Low Molecular Weight and Protein S-Nitrosothiols Detcho A. Stoyanovsky, Yulia Y. Tyurina, Vladimir A. Tyurin, Deepthi Anand, Dhara N. Mandavia, David Gius, Juliana Ivanova, Bruce Pitt, Timothy R. Billiar, and Valerian E. Kagan pp 15815–15823 DOI: 10.1021/ja0529135 Supporting Info

Mild Palladium-Catalyzed Selective Monoarylation of Nitriles Lingyun Wu and John F. Hartwig pp 15824–15832 DOI: 10.1021/ja053027x Supporting Info

Marked Dependence on Carrier-Ligand Bulk but Not on Carrier-Ligand Chirality of the Duplex versus Single-Strand Forms of a DNA Oligonucleotide with a Series of G−Pt(II)−G Intrastrand Cross-Links Modeling Cisplatin−DNA Adducts Vladimir Beljanski, Julie M. Villanueva, Paul W. Doetsch, Giovanni Natile, and Luigi G. Marzilli pp 15833–15842 DOI: 10.1021/ja053089n Supporting Info

Biomimetic Anchor for Surface-Initiated Polymerization from Metal Substrates Xiaowu Fan, Lijun Lin, Jeffrey L. Dalsin, and Phillip B. Messersmith pp 15843–15847 DOI: 10.1021/ja0532638 Supporting Info

Synergy of Intramolecular Hydrogen-Bonding Network in myo-Inositol 2-Monophosphate:  Theoretical Investigations into the Electronic Structure, Proton Transfer, and pKa Ping Yang, Pushpalatha P. N. Murthy, and Richard E. Brown pp 15848–15861 DOI: 10.1021/ja053371u Supporting Info

Molecular Umbrella-Assisted Transport of an Oligonucleotide across Cholesterol-Rich Phospholipid Bilayers Vaclav Janout, Bingwen Jing, and Steven L. Regen pp 15862–15870 DOI: 10.1021/ja053930x

Autocatalytic Modification of the Prosthetic Heme of Horseradish but Not Lactoperoxidase by Thiocyanate Oxidation Products. A Role for Heme−Protein Covalent Cross-Linking Grzegorz Wojciechowski, Liusheng Huang, and Paul R. Ortiz de Montellano pp 15871–15879 DOI: 10.1021/ja054084t Supporting Info

Electron Inventory, Kinetic Assignment (En), Structure, and Bonding of Nitrogenase Turnover Intermediates with C2H2 and CO Hong-In Lee, Morten Sørlie, Jason Christiansen, Tran-Chin Yang, Junlong Shao, Dennis R. Dean, Brian J. Hales, and Brian M. Hoffman pp 15880–15890 DOI: 10.1021/ja054078x Supporting Info

A Multi-Mode-Driven Molecular Shuttle:  Photochemically and Thermally Reactive Azobenzene Rotaxanes Hiroto Murakami, Atsushi Kawabuchi, Rika Matsumoto, Takeshi Ido, and Naotoshi Nakashima pp 15891–15899 DOI: 10.1021/ja053690l Supporting Info

Oxoselenido Clusters of the Lanthanides:  Rational Introduction of Oxo Ligands and Near-IR Emission from Nd(III) Santanu Banerjee, Louise Huebner, Michael D. Romanelli, G. Ajith Kumar, Richard. E. Riman, Thomas J. Emge, and John G. Brennan pp 15900–15906 DOI: 10.1021/ja054261q Supporting Info

Picosecond Photoreduction of Inducible Nitric Oxide Synthase by Rhenium(I)−Diimine Wires Wendy Belliston-Bittner, Alexander R. Dunn, Yen Hoang Le Nguyen, Dennis J. Stuehr, Jay R. Winkler, and Harry B. Gray pp 15907–15915 DOI: 10.1021/ja0543088 Supporting Info

Potential Dependent Organization of Water at the Electrified Metal−Liquid Interface Zachary D. Schultz, Scott K. Shaw, and Andrew A. Gewirth pp 15916–15922 DOI: 10.1021/ja0543393 Supporting Info

Stereoelectronic and Steric Effects in the Collagen Triple Helix:  Toward a Code for Strand Association Jonathan A. Hodges and Ronald T. Raines pp 15923–15932 DOI: 10.1021/ja054674r Supporting Info

O2 and CO Binding Properties of Artificial Hemoproteins Formed by Complexing Iron Protoporphyrin IX with Human Serum Albumin Mutants Teruyuki Komatsu, Naomi Ohmichi, Akito Nakagawa, Patricia A. Zunszain, Stephen Curry, and Eishun Tsuchida pp 15933–15942 DOI: 10.1021/ja054819u Supporting Info

Micropatterning Chemical Oscillations:  Waves, Autofocusing, and Symmetry Breaking Kyle J. M. Bishop, Marcin Fiałkowski, and Bartosz A. Grzybowski pp 15943–15948 DOI: 10.1021/ja054851o Supporting Info

Detection of Homocysteine and Cysteine Weihua Wang, Oleksandr Rusin, Xiangyang Xu, Kyu Kwang Kim, Jorge O. Escobedo, Sayo O. Fakayode, Kristin A. Fletcher, Mark Lowry, Corin M. Schowalter, Candace M. Lawrence, Frank R. Fronczek, Isiah M. Warner, and Robert M. Strongin pp 15949–15958 DOI: 10.1021/ja054962n Supporting Info

The Cucurbit[n]uril Family:  Prime Components for Self-Sorting Systems Simin Liu, Christian Ruspic, Pritam Mukhopadhyay, Sriparna Chakrabarti, Peter Y. Zavalij, and Lyle Isaacs pp 15959–15967 DOI: 10.1021/ja055013x Supporting Info

Self-Organization of Bidisperse Colloids in Water Droplets Young-Sang Cho, Gi-Ra Yi, Jong-Min Lim, Shin-Hyun Kim, Vinothan N. Manoharan, David J. Pine, and Seung-Man Yang pp 15968–15975 DOI: 10.1021/ja0550632

Self-Assembly of Mercaptane−Metallacarborane Complexes by an Unconventional Cooperative Effect:  A C−H···S−H···H−B Hydrogen/Dihydrogen Bond Interaction José Giner Planas, Clara Viñas, Francesc Teixidor, Aleix Comas-Vives, Gregori Ujaque, Agustí Lledós, Mark E. Light, and Michael B. Hursthouse pp 15976–15982 DOI: 10.1021/ja055210w Supporting Info

How Stable Is trans-Cycloheptene? Michael E. Squillacote, James DeFellipis, and Qingning Shu pp 15983–15988 DOI: 10.1021/ja055388i Supporting Info

Encyclopedia of Chromatography, 2nd ed., Volumes 1 and 2 Edited by Jack Cazes (Florida Atlantic University). Taylor and Francis Group, LLC:  Boca Raton, FL. 2005. 1928 pp. $506.00. ISBN 0-8247-2786-X. p 15989 DOI: 10.1021/ja059802q

Progress in Inorganic Chemistry, Volume 35 Edited by Kenneth D. Karlin (Johns Hopkins University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. viii + 604 pp. $150.00. ISBN 0-471-46370-1. Andrew R. Barron p 15989 DOI: 10.1021/ja059804a

Humic Substances:  Molecular Details and Applications in Land and Water Conservation Edited by Elham A Ghabbour (Northeastern University, Boston and Soil, Water and Environmental Research Institute, Alexandria, Egypt) and Geoffrey Davies (Northeastern University). Taylor and Francis, Inc.:  New York. 2005. xviii + 268 pp. $119.95. ISBN 1-59169-031-5. pp 15989–15990 DOI: 10.1021/ja059787p

CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures By Christian Wohlfarth (Martin Luther University, Halle-Wittenberg, Germany). CRC Press LLC (imprint of Taylor & Francis Group):  Boca Raton, FL. 2005. x + 642 pp. $269.95. ISBN 0-8493-3246-X. p 15990 DOI: 10.1021/ja059789+

Acetylene Chemistry:  Chemistry, Biology, and Material Science Edited by François Diederich (ETH-Zuerich), Peter J. Stang, (University of Utah, Salt Lake City), and Rik R. Tykwinski, (University of Alberta, Edmonton). Wiley-VCH GmbH & Co. KGaA:  Weinheim. xx + 508 pp. $185.00. ISBN 3-527-30781-8. Alex G. Fallis pp 15990–15991 DOI: 10.1021/ja059782s

Metal Carbenes in Organic Synthesis. Topics in Organometallic Chemistry, 13 Edited by K. H. Dötz (Rheinische Friedrich-Wilhelms-Universität). Springer-Verlag:  Berlin, Heidelberg. 2004. x + 378 pp. $359.00. ISBN 3-540-21833-5. William D. Wulff pp 15991–15992 DOI: 10.1021/ja041046l

Contrast Agents III:  RadiopharmaceuticalsFrom Diagnostics to Therapeutics:  Topics in Current Chemistry, 252 Edited by Werner Krause (Berlex, Monteville, NJ). Springer:  Berlin, Heidelberg, New York. 2005. xii + 222 pp. $189.00. ISBN 3-540-22577-3. John A. Katzenellenbogen p 15992 DOI: 10.1021/ja0597496

Issue 46

An Electrochemical Color-Switchable RGB Dye:  Tristable [2]Catenane Wei-Qiao Deng, Amar H. Flood, J. Fraser Stoddart, and William A. Goddard III pp 15994–15995 DOI: 10.1021/ja0431298 Supporting Info

Perfectly Dissolved Boron Nitride Nanotubes Due to Polymer Wrapping Chunyi Zhi, Yoshio Bando, Chengchun Tang, Rongguo Xie, Takashi Sekiguchi, and Dmitri Golberg pp 15996–15997 DOI: 10.1021/ja053917c Supporting Info

Ruthenium-Catalyzed Cycloaddition of Alkynes and Organic Azides Li Zhang, Xinguo Chen, Peng Xue, Herman H. Y. Sun, Ian D. Williams, K. Barry Sharpless, Valery V. Fokin, and Guochen Jia pp 15998–15999 DOI: 10.1021/ja054114s Supporting Info

Efficient Primer Strand Extension beyond Oxadiazole Carboxamide Nucleobases Olga Adelfinskaya, Vishal C. Nashine, Donald E. Bergstrom, and V. Jo Davisson pp 16000–16001 DOI: 10.1021/ja054226j Supporting Info

Room-Temperature Wurtzite ZnS Nanocrystal Growth on Zn Finger-like Peptide Nanotubes by Controlling Their Unfolding Peptide Structures Ipsita A. Banerjee, Lingtao Yu, and Hiroshi Matsui pp 16002–16003 DOI: 10.1021/ja054907e Supporting Info

Iron Substitution for Sodium in a Carboxylate-Bridged, Heterodinuclear Sodium−Iron Complex Jeremy J. Kodanko, Dong Xu, Datong Song, and Stephen J. Lippard pp 16004–16005 DOI: 10.1021/ja054943d Supporting Info

Tailoring of Nanoscale Porosity in Carbide-Derived Carbons for Hydrogen Storage Yury Gogotsi, Ranjan K. Dash, Gleb Yushin, Taner Yildirim, Giovanna Laudisio, and John E. Fischer pp 16006–16007 DOI: 10.1021/ja0550529 Supporting Info

Oriented Immobilization of Desulfovibrio gigas Hydrogenase onto Carbon Electrodes by Covalent Bonds for Nonmediated Oxidation of H2 Olaf Rüdiger, Jose M. Abad, E. Claude Hatchikian, Victor M. Fernandez, and Antonio L. De Lacey pp 16008–16009 DOI: 10.1021/ja0554312 Supporting Info

Electronic Dissymmetry in Chiral Recognition Seth N. Brown, Everett T. Chu, Michael W. Hull, and Bruce C. Noll pp 16010–16011 DOI: 10.1021/ja055598v Supporting Info

Characterization of a Diferrous Terminal Hydride Mechanistically Relevant to the Fe-Only Hydrogenases Jarl Ivar van der Vlugt, Thomas B. Rauchfuss, C. Matthew Whaley, and Scott R. Wilson pp 16012–16013 DOI: 10.1021/ja055475a Supporting Info

Enantiospecific Sn(II)- and Sn(IV)-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes Patrick D. Pohlhaus and Jeffrey S. Johnson pp 16014–16015 DOI: 10.1021/ja055777c Supporting Info

Intermolecular C−H Bond Activation Promoted by a Titanium Alkylidyne Brad C. Bailey, Hongjun Fan, Erich W. Baum, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola pp 16016–16017 DOI: 10.1021/ja0556934 Supporting Info

Identification by 15N Refocused INADEQUATE MAS NMR of Intermolecular Hydrogen Bonding that Directs the Self-Assembly of Modified DNA Bases Tran N. Pham, Stefano Masiero, Giovanni Gottarelli, and Steven P. Brown pp 16018–16019 DOI: 10.1021/ja056188+ Supporting Info

Synthesis of Single-Crystalline CoP Nanowires by a One-Pot Metal−Organic Route Yang Li, M. Azad Malik, and Paul O'Brien pp 16020–16021 DOI: 10.1021/ja055963i

Conducting Polymer Electrochemical Switching as an Easy Means for Designing Active Plasmonic Devices Yann R. Leroux, Jean Christophe Lacroix, Kathleen I. Chane-Ching, Claire Fave, Nordin Félidj, Georges Lévi, Jean Aubard, Joachim R. Krenn, and Andreas Hohenau pp 16022–16023 DOI: 10.1021/ja054915v Supporting Info

High Symmetric 18-Facet Polyhedron Nanocrystals of Cu7S4 with a Hollow Nanocage Hongliang Cao, Xuefeng Qian, Cheng Wang, Xiaodong Ma, Jie Yin, and Zikang Zhu pp 16024–16025 DOI: 10.1021/ja055265y Supporting Info

Modeling Errors in NOE Data with a Log-normal Distribution Improves the Quality of NMR Structures Wolfgang Rieping, Michael Habeck, and Michael Nilges pp 16026–16027 DOI: 10.1021/ja055092c

Cysteine-Derived Organocatalyst in a Highly Enantioselective Intramolecular Michael Reaction Yujiro Hayashi, Hiroaki Gotoh, Tomohiro Tamura, Hirofumi Yamaguchi, Ryouhei Masui, and Mitsuru Shoji pp 16028–16029 DOI: 10.1021/ja055740s Supporting Info

Screening Mercury Levels in Fish with a Selective Fluorescent Chemosensor Sungho Yoon, Aaron E. Albers, Audrey P. Wong, and Christopher J. Chang pp 16030–16031 DOI: 10.1021/ja0557987 Supporting Info

Structural Snapshots of a Flexible Cu2P2 Core that Accommodates the Oxidation States CuICuI, Cu1.5Cu1.5, and CuIICuII Neal P. Mankad, Eric Rivard, Seth B. Harkins, and Jonas C. Peters pp 16032–16033 DOI: 10.1021/ja056071l Supporting Info

Copper-Catalyzed γ-Selective and Stereospecific Substitution Reaction of Allylic Carbonates with Diboron:  Efficient Route to Chiral Allylboron Compounds Hajime Ito, Chika Kawakami, and Masaya Sawamura pp 16034–16035 DOI: 10.1021/ja056099x Supporting Info

Steric Constraint in the Primary Photoproduct of an Archaeal Rhodopsin from Regiospecific Perturbation of C−D Stretching Vibration of the Retinyl Chromophore Yuki Sudo, Yuji Furutani, Akimori Wada, Masayoshi Ito, Naoki Kamo, and Hideki Kandori pp 16036–16037 DOI: 10.1021/ja056203a

Total Synthesis of Lucilactaene, A Cell Cycle Inhibitor Active in p53-Inactive Cells Robert S. Coleman, Matthew C. Walczak, and Erica L. Campbell pp 16038–16039 DOI: 10.1021/ja056217g Supporting Info

Synthesis of Bifunctional Polymer Nanotubes from Silicon Nanowire Templates via Atom Transfer Radical Polymerization Martin J. Mulvihill, Benjamin L. Rupert, Rongrui He, Allon Hochbaum, John Arnold, and Peidong Yang pp 16040–16041 DOI: 10.1021/ja056242m Supporting Info

Hydroacylation of 2-Vinyl Benzaldehyde Systems:  An Efficient Method for the Synthesis of Chiral 3-Substituted Indanones Kousik Kundu, James V. McCullagh, and Andrew T. Morehead, Jr. pp 16042–16043 DOI: 10.1021/ja0564416 Supporting Info

Tetrahydropyran Rings from a Mukaiyama−Michael Cascade Reaction Megan L. Bolla, Brian Patterson, and Scott D. Rychnovsky pp 16044–16045 DOI: 10.1021/ja056483u Supporting Info

Copper-Catalyzed Hydrative Amide Synthesis with Terminal Alkyne, Sulfonyl Azide, and Water Seung Hwan Cho, Eun Jeong Yoo, Imhyuck Bae, and Sukbok Chang pp 16046–16047 DOI: 10.1021/ja056399e Supporting Info

Reactions of AlnIx- with Methyl Iodide:  The Enhanced Stability of Al7I and the Chemical Significance of Active Centers Denis E. Bergeron, Patrick J. Roach, A.Welford Castleman, Jr., Naiche O. Jones, J. Ulises Reveles, and Shiv N. Khanna pp 16048–16053 DOI: 10.1021/ja050338z

Charge Shift and Triplet State Formation in the 9-Mesityl-10-methylacridinium Cation Andrew C. Benniston, Anthony Harriman, Peiyi Li, James P. Rostron, Hendrik J. van Ramesdonk, Michiel M. Groeneveld, Hong Zhang, and Jan W. Verhoeven pp 16054–16064 DOI: 10.1021/ja052967e Supporting Info

Observation of the Anisotropic Photoinduced Magnetization Effect in Co−Fe Prussian Blue Thin Films Fabricated by Using Clay Langmuir−Blodgett Films as a Template Takashi Yamamoto, Yasushi Umemura, Osamu Sato, and Yasuaki Einaga pp 16065–16073 DOI: 10.1021/ja053131e Supporting Info

Sequence-Dependent Conformational Energy of DNA Derived from Molecular Dynamics Simulations:  Toward Understanding the Indirect Readout Mechanism in Protein−DNA Recognition Marcos J. Araúzo-Bravo, Satoshi Fujii, Hidetoshi Kono, Shandar Ahmad, and Akinori Sarai pp 16074–16089 DOI: 10.1021/ja053241l Supporting Info

Redox−Transmetalation Process as a Generalized Synthetic Strategy for Core−Shell Magnetic Nanoparticles Woo-ram Lee, Min Gyu Kim, Joon-rak Choi, Jong-Il Park, Seung Jin Ko, Sang Jun Oh, and Jinwoo Cheon pp 16090–16097 DOI: 10.1021/ja053659j Supporting Info

Spectroscopic and Computational Studies of the de Novo Designed Protein DF2t:  Correlation to the Biferrous Active Site of Ribonucleotide Reductase and Factors That Affect O2 Reactivity Pin-pin Wei, Andrew J. Skulan, Herschel Wade, William F. DeGrado, and Edward I. Solomon pp 16098–16106 DOI: 10.1021/ja053661a Supporting Info

Photoswitched Cell Adhesion on Surfaces with RGD Peptides Jörg Auernheimer, Claudia Dahmen, Ulrich Hersel, Andreas Bausch, and Horst Kessler pp 16107–16110 DOI: 10.1021/ja053648q Supporting Info

Geometry, Phase Stability, and Electronic Properties of Isolated Selenium Chains Incorporated in a Nanoporous Matrix Irene Ling Li, Jian Pang Zhai, Pascale Launois, Shuang Chen Ruan, and Zi Kang Tang pp 16111–16119 DOI: 10.1021/ja053686+

The Dynamics of the B−A Transition of Natural DNA Double Helices Davis Jose and Dietmar Porschke pp 16120–16128 DOI: 10.1021/ja053691d Supporting Info

Evidence for a Two-Step Mechanism in Electronically Selective Single-Walled Carbon Nanotube Reactions Monica L. Usrey, Ethan S. Lippmann, and Michael S. Strano pp 16129–16135 DOI: 10.1021/ja0537530 Supporting Info

Synthesis of Two Types of Nanoparticles in Polyelectrolyte Capsule Nanoreactors and Their Dual Functionality Won San Choi, Hye Young Koo, Jeong-Ho Park, and Dong-Yu Kim pp 16136–16142 DOI: 10.1021/ja053981u Supporting Info

[12]Annulynes Matthew N. Gard, Matthew K. Kiesewetter, Richard C. Reiter, and Cheryl D. Stevenson pp 16143–16150 DOI: 10.1021/ja053886l Supporting Info

Geometry and Cooperativity Effects in Adenosine−Carboxylic Acid Complexes Sebastian Schlund, Milena Mladenovic, Eline M. Basílio Janke, Bernd Engels, and Klaus Weisz pp 16151–16158 DOI: 10.1021/ja0531430 Supporting Info

Oxidative Activation of n-Butane on Sulfated Zirconia Xuebing Li, Katsutoshi Nagaoka, Laurent J. Simon, Roberta Olindo, Johannes A. Lercher, Alexander Hofmann, and Joachim Sauer pp 16159–16166 DOI: 10.1021/ja054126d

Enthalpy−Entropy Compensation is Not a General Feature of Weak Association David M. Ford pp 16167–16170 DOI: 10.1021/ja054519c

Evidences for Zeolite Nucleation at the Solid−Liquid Interface of Gel Cavities Valentin P. Valtchev and Krassimir N. Bozhilov pp 16171–16177 DOI: 10.1021/ja0546267 Supporting Info

A New Class of Macrocyclic Lanthanide Complexes for Cell Labeling and Magnetic Resonance Imaging Applications Quan Zheng, Houquan Dai, Matthew E. Merritt, Craig Malloy, Cai Yuan Pan, and Wen-Hong Li pp 16178–16188 DOI: 10.1021/ja054593v Supporting Info

Regulation of Saccharide Binding with Basic Poly(ethynylpyridine)s by H+-Induced Helix Formation Hajime Abe, Nozomi Masuda, Minoru Waki, and Masahiko Inouye pp 16189–16196 DOI: 10.1021/ja054134u Supporting Info

Energetics of Binuclear Spin Transition Complexes Samir Zein and Serguei A. Borshch pp 16197–16201 DOI: 10.1021/ja054282k Supporting Info

Matrix-Induced Intensity Fluctuations in the Fluorescence from Single Oligo(phenylenevinylene) Molecules Melissa A. Summers, Guillermo C. Bazan, and Steven K. Buratto pp 16202–16206 DOI: 10.1021/ja054337i Supporting Info

A DFT Study of the Thermal, Orbital Symmetry Forbidden, Cyclophanediene to Dihydropyrene Electrocyclic Reaction. Predictions to Improve the Dimethyldihydropyrene Photoswitches Richard Vaughan Williams, W. Daniel Edwards, Reginald H. Mitchell, and Stephen G. Robinson pp 16207–16214 DOI: 10.1021/ja054553r Supporting Info

Thermodynamics and Kinetics of PNA−DNA Quadruplex-Forming Chimeras Luigi Petraccone, Bruno Pagano, Veronica Esposito, Antonio Randazzo, Gennaro Piccialli, Guido Barone, Carlo A. Mattia, and Concetta Giancola pp 16215–16223 DOI: 10.1021/ja0545923 Supporting Info

Heme Release in Myoglobin−DDAB Films and Its Role in Electrochemical NO Reduction Matheus T. de Groot, Maarten Merkx, and Marc T. M. Koper pp 16224–16232 DOI: 10.1021/ja0546572 Supporting Info

High Anisotropy of the Field-Effect Transistor Mobility in Magnetically Aligned Discotic Liquid-Crystalline Semiconductors Igor O. Shklyarevskiy, Pascal Jonkheijm, Natalie Stutzmann, Dorothee Wasserberg, Harry J. Wondergem, Peter C. M. Christianen, Albertus P. H. J. Schenning, Dago M. de Leeuw, Željko Tomović, Jishan Wu, Klaus Müllen, and Jan C. Maan pp 16233–16237 DOI: 10.1021/ja054694t

Improved Molecular Rectification from Self-Assembled Monolayers of a Sterically Hindered Dye Geoffrey J. Ashwell and Abdul Mohib pp 16238–16244 DOI: 10.1021/ja054699q

Structural Evolution of Hexa-peri-hexabenzocoronene Adlayers in Heteroepitaxy on n-Pentacontane Template Monolayers Luc Piot, Alexandr Marchenko, Jishan Wu, Klaus Müllen, and Denis Fichou pp 16245–16250 DOI: 10.1021/ja0548844

Measuring Antiaromaticity by an Analysis of Ring Current and Coupling Constant changes in a Cyclopentadienone-Fused Dihydropyrene Reginald H. Mitchell, Rui Zhang, Wei Fan, and David J. Berg pp 16251–16254 DOI: 10.1021/ja055356v

Regiospecific and Stereoselective Syntheses of (±)-Reserpine and (−)-Reserpine Gilbert Stork, Peng Cho Tang, Michael Casey, Burton Goodman, and Masahiro Toyota pp 16255–16262 DOI: 10.1021/ja055744x Supporting Info

Shock-Absorbing and Failure Mechanisms of WS2 and MoS2 Nanoparticles with Fullerene-like Structures under Shock Wave Pressure Yan Qiu Zhu, Toshimori Sekine, Yan Hui Li, Michael W. Fay, Yi Min Zhao, C. H. Patrick Poa, Wen Xin Wang, Martin J. Roe, Paul D. Brown, Niles Fleischer, and Reshef Tenne pp 16263–16272 DOI: 10.1021/ja054715j

Very Large Swelling in Hybrid Frameworks:  A Combined Computational and Powder Diffraction Study Caroline Mellot-Draznieks, Christian Serre, Suzy Surblé, Nathalie Audebrand, and Gérard Férey pp 16273–16278 DOI: 10.1021/ja054900x Supporting Info

Self-Organization of a Self-Assembled Supramolecular Rectangle, Square, and Three-Dimensional Cage on Au(111) Surfaces Qun-Hui Yuan, Li-Jun Wan, Hershel Jude, and Peter J. Stang pp 16279–16286 DOI: 10.1021/ja0549300

Electro Pen Nanolithography Yuguang Cai and Benjamin M. Ocko pp 16287–16291 DOI: 10.1021/ja054951u

Purification of Endohedral Trimetallic Nitride Fullerenes in a Single, Facile Step Zhongxin Ge, James C. Duchamp, Ting Cai, Harry W. Gibson, and Harry C. Dorn pp 16292–16298 DOI: 10.1021/ja055089t Supporting Info

An Anion-Dependent Switch in Selectivity Results from a Change of C−H Activation Mechanism in the Reaction of an Imidazolium Salt with IrH5(PPh3)2 Leah N. Appelhans, Daniele Zuccaccia, Anes Kovacevic, Anthony R. Chianese, John R. Miecznikowski, Alceo Macchioni, Eric Clot, Odile Eisenstein, and Robert H. Crabtree pp 16299–16311 DOI: 10.1021/ja055317j Supporting Info

Magnetic Properties and Crystal Structure of a One-Dimensional Phase of Tetrakis(μ2-benzoato-O,O‘)-bis(dimethyl sulfoxide)dicopper(II) Yasmi Reyes-Ortega, José L. Alcántara-Flores, María C. Hernández-Galindo, Daniel Ramírez-Rosales, Sylvain Bernès, Juán C. Ramírez-García, Rafael Zamorano-Ulloa, and Roberto Escudero pp 16312–16317 DOI: 10.1021/ja055316r Supporting Info

Molecular Recognition in Structured Matrixes:  Control of Guest Localization in Block Copolymer Films Roy Shenhar, Hao Xu, Benjamin L. Frankamp, Thomas E. Mates, Amitav Sanyal, Oktay Uzun, and Vincent M. Rotello pp 16318–16324 DOI: 10.1021/ja055490f Supporting Info

Anionogenic Ferromagnets Jisk J. Attema, Gilles A. de Wijs, Graeme R. Blake, and Robert A. de Groot pp 16325–16328 DOI: 10.1021/ja0550834

Tandem Catalysis:  Generating Multiple Contiguous Carbon−Carbon Bonds through a Ruthenium-Catalyzed Ring-Closing Metathesis/Kharasch Addition Benjamin A. Seigal, Cristina Fajardo, and Marc L. Snapper pp 16329–16332 DOI: 10.1021/ja055806j Supporting Info

Controlled Self-Assembly of Carbohydrate Conjugate Rod−Coil Amphiphiles for Supramolecular Multivalent Ligands Byung-Sun Kim, Dong-Je Hong, Jinyoung Bae, and Myongsoo Lee pp 16333–16337 DOI: 10.1021/ja055999a Supporting Info

A Reversible Polymorphic Phase Change Which Affects the Luminescence and Aurophilic Interactions in the Gold(I) Cluster Complex, [μ3-S(AuCNC7H13)3](SbF6) [J. Am. Chem. Soc. 2005, 127, 10838−10839]. Emily M. Gussenhoven, James C. Fettinger, David M. Pham, Mark M. Malwitz, and Alan L. Balch p 16338 DOI: 10.1021/ja056393p

Understanding the Formation of New Clusters of Alkali and Alkaline Earth Metals:  A New Synthetic Approach, Single-Crystal Structures, and Theoretical Calculations [J. Am. Chem. Soc. 2003, 125, 3593−3604]. Katharina M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, and H. Chermette p 16338 DOI: 10.1021/ja056591g

Absolute Configuration of Chiral [2.2]Paracyclophanes with Intramolecular Charge-Transfer Interaction. Failure of the Exciton Chirality Method and Use of the Sector Rule Applied to the Cotton Effect of the C−T Transition  [J. Am. Chem. Soc. 2005, 127, 8242−8243]. Takahiro Furo, Tadashi Mori, Takehiko Wada, and Yoshihisa Inoue p 16338 DOI: 10.1021/ja056608v

Intramolecular Diels−Alder Reactions of Optically Active Allenic Ketones:  Chirality Transfer in the Preparation of Substituted Oxa-BridgedOctalones [J. Am. Chem. Soc. 2005, 127, 10834−10835]. Michael E. Jung and Sun-Joon Min p 16338 DOI: 10.1021/ja059918m

Hydrogen-Mediated Reductive Coupling of Conjugated Alkynes with Ethyl (N-Sulfinyl)iminoacetates:  Synthesis of Unnatural α-Amino Acids via Rhodium-Catalyzed C−C Bond Forming Hydrogenation  [J. Am. Chem. Soc. 2005, 127, 11269−11276].  Jong-Rock Kong, Chang-Woo Cho, and Michael J. Krische p 16338 DOI: 10.1021/ja059919e

Quantal Density Functional Theory By Viraht Sahni (City University of New York, Brooklyn). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xiv + 256 pp. $129.00. ISBN 3-540-40884-3. Steven M. Valone p 16339 DOI: 10.1021/ja059747l

Mass Spectrometry in Biophysics:  Conformation and Dynamics of Biomolecules By Igor A. Kaltashov and Stephen J. Eyles (University of Massachusetts at Amherst). From the Wiley-Interscience Series in Mass Spectrometry. Edited by Dominic M. Desiderio and Nico M. M. Nibbering. John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xvi + 458 pp. $89.95. ISBN 0-471-45602-0. Kym F. Faull pp 16339–16340 DOI: 10.1021/ja059763i

Issue 47

A Transition-Metal-Catalyzed Enediyne Cycloaromatization Joseph M. O'Connor, Seth J. Friese, and Betsy L. Rodgers pp 16342–16343 DOI: 10.1021/ja050060a Supporting Info

A Ribose Sugar Conformational Switch in the LTR-Retrotransposon Ty3 Polypurine Tract-Containing RNA/DNA Hybrid Hye Young Yi-Brunozzi, Danielle M. Brabazon, Daniela Lener, Stuart F. J. Le Grice, and John P. Marino pp 16344–16345 DOI: 10.1021/ja0534203 Supporting Info

α,ω-Distyryl Oligothiophenes:  High Mobility Semiconductors for Environmentally Stable Organic Thin Film Transistors Christine Videlot-Ackermann, Jörg Ackermann, Hugues Brisset, Koji Kawamura, Noriyuki Yoshimoto, Pascal Raynal, Ahmed El Kassmi, and Frédéric Fages pp 16346–16347 DOI: 10.1021/ja054358c Supporting Info

Using Meta Conjugation To Enhance Charge Separation versus Charge Recombination in Phenylacetylene Donor−Bridge−Acceptor Complexes Alexis L. Thompson, Tai-Sang Ahn, K. R. Justin Thomas, S. Thayumanavan, Todd J. Martínez, and Christopher J. Bardeen pp 16348–16349 DOI: 10.1021/ja054543q Supporting Info

Low-Barrier Hydrogen Bond between Phosphate and the Amide Group in Phosphopeptide Jin-Tang Du, Yan-Mei Li, Wei Wei, Guo-Shi Wu, Yu-Fen Zhao, Kenji Kanazawa, Tadashi Nemoto, and Hiroshi Nakanishi pp 16350–16351 DOI: 10.1021/ja054568p Supporting Info

A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate Shengchang Xiang, Xintao Wu, Jianjun Zhang,Jianjun Zhang, Ruibiao Fu, Shengmin Hu, and Xudong ZhangXudong Zhang pp 16352–16353 DOI: 10.1021/ja0546065 Supporting Info

Porous BCN Nanotubular Fibers:  Growth and Spatially Resolved Cathodoluminescence Long-Wei Yin, Yoshio Bando, Dmitri Golberg, Alexandre Gloter, Mu-Sen Li, Xiaoli Yuan, and Takashi Sekiguchi pp 16354–16355 DOI: 10.1021/ja054887g Supporting Info

Double Direct Templating of Periodically Nanostructured ZnS Hollow Microspheres Alejandro Wolosiuk, Onur Armagan, and Paul V. Braun pp 16356–16357 DOI: 10.1021/ja054927g Supporting Info

High Charge-Carrier Mobility in an Amorphous Hexaazatrinaphthylene Derivative Bilal R. Kaafarani, Takeshi Kondo, Junsheng Yu, Qing Zhang, Davide Dattilo, Chad Risko, Simon C. Jones, Stephen Barlow, Benoit Domercq, Fabrice Amy, Antoine Kahn, Jean-Luc Brédas, Bernard Kippelen, and Seth R. Marder pp 16358–16359 DOI: 10.1021/ja0553147 Supporting Info

Supramolecular Photonic Therapeutic Agents Shane O. McDonnell, Michael J. Hall, Lorcan T. Allen, Annette Byrne, William M. Gallagher, and Donal F. O'Shea pp 16360–16361 DOI: 10.1021/ja0553497 Supporting Info

A Metal−Organic Framework Functionalized with Free Carboxylic Acid Sites and Its Selective Binding of a Cl(H2O)4- Cluster Radu Custelcean and Maryna G. Gorbunova pp 16362–16363 DOI: 10.1021/ja055528o Supporting Info

Selective Anion Encapsulation by a Metalated Cryptophane with a π-Acidic Interior Robert M. Fairchild and K. Travis Holman pp 16364–16365 DOI: 10.1021/ja055560i Supporting Info

Silylmethyl-Substituted Aziridine and Azetidine as Masked 1,3- and 1,4-Dipoles for Formal [3 + 2] and [4 + 2] Cycloaddition Reactions Veejendra K. Yadav and Vardhineedi Sriramurthy pp 16366–16367 DOI: 10.1021/ja055664t Supporting Info

Reaction Products with Internal Energy beyond the Kinematic Limit Result from Trajectories Far from the Minimum Energy Path:  An Example from H + HBr → H2 + Br Andrew E. Pomerantz, Jon P. Camden, Albert S. Chiou, Florian Ausfelder, Navdeep Chawla, William L. Hase, and Richard N. Zare pp 16368–16369 DOI: 10.1021/ja055440a Supporting Info

Preorganization in Highly Enantioselective Diaza-Cope Rearrangement Reaction Hae-Jo Kim, Hyunwoo Kim, Gamil Alhakimi, Eui June Jeong, Nirusha Thavarajah, Lisa Studnicki, Alicja Koprianiuk, Alan J. Lough, Junghun Suh, and Jik Chin pp 16370–16371 DOI: 10.1021/ja055776k Supporting Info

A Low-Molecular-Mass Gelator with an Electroactive Tetrathiafulvalene Group:  Tuning the Gel Formation by Charge-Transfer Interaction and Oxidation Cheng Wang, Deqing Zhang, and Daoben Zhu pp 16372–16373 DOI: 10.1021/ja055800u Supporting Info

Solvent Polarization and Kinetic Isotope Effects in Nitroethane Deprotonation and Implications to the Nitroalkane Oxidase Reaction Dan T. Major, Darrin M. York, and Jiali Gao pp 16374–16375 DOI: 10.1021/ja055881u Supporting Info

Large-Scale Ni-Doped ZnO Nanowire Arrays and Electrical and Optical Properties Jr H. He, Chang S. Lao, Lih J. Chen, Dragomir Davidovic, and Zhong L. Wang pp 16376–16377 DOI: 10.1021/ja0559193

Catalytic Asymmetric Deprotonation Using a Ligand Exchange Approach Matthew J. McGrath and Peter O'Brien pp 16378–16379 DOI: 10.1021/ja056026d Supporting Info

Catechol Oxidase Activity of Di-Cu2+-Substituted Aminopeptidase from Streptomyces griseus Giordano F. Z. da Silva and Li-June Ming pp 16380–16381 DOI: 10.1021/ja056034u

A Capping Methodology for the Synthesis of Lower μ-Oxo-phthalocyaninato Silicon Oligomers Andrew N. Cammidge, Fabien Nekelson, Madeleine Helliwell, Martin J. Heeney, and Michael J. Cook pp 16382–16383 DOI: 10.1021/ja0558443 Supporting Info

Effect of Core Size on the Partition of Organic Solutes in the Monolayer of Water-Soluble Nanoparticles:  An ESR Investigation Marco Lucarini, Paola Franchi, Gian Franco Pedulli, Cristina Gentilini, Stefano Polizzi, Paolo Pengo, Paolo Scrimin, and Lucia Pasquato pp 16384–16385 DOI: 10.1021/ja0560534 Supporting Info

Highly Enantioseletive Biginelli Reaction Using a New Chiral Ytterbium Catalyst:  Asymmetric Synthesis of Dihydropyrimidines Yijun Huang, Fengyue Yang, and Chengjian Zhu pp 16386–16387 DOI: 10.1021/ja056092f Supporting Info

Tertiary Contact Formation in α-Synuclein Probed by Electron Transfer Jennifer C. Lee, Harry B. Gray, and Jay R. Winkler pp 16388–16389 DOI: 10.1021/ja0561901 Supporting Info

Dynamical Arrest of Electron Transfer Reorganization in Super-Cooled Water Pradip K. Ghorai and Dmitry V. Matyushov pp 16390–16391 DOI: 10.1021/ja0535920 Supporting Info

Monodisperse Protein-Based Glycopolymers via a Combined Biosynthetic and Chemical Approach Ying Wang and Kristi L. Kiick pp 16392–16393 DOI: 10.1021/ja055102+ Supporting Info

Highly Enantioselective Copper(I)−Fesulphos-Catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides Silvia Cabrera, Ramón Gómez Arrayás, and Juan C. Carretero pp 16394–16395 DOI: 10.1021/ja0552186 Supporting Info

Direct Synthesis of Mesoporous Titania Particles Having a Crystalline Wall Hirobumi Shibata, Taku Ogura, Tatsuya Mukai, Takahiro Ohkubo, Hideki Sakai, and Masahiko Abe pp 16396–16397 DOI: 10.1021/ja0552601

Size-Controlled Synthesis of Near-Monodisperse Gold Nanoparticles in the 1−4 nm Range Using Polymeric Stabilizers Irshad Hussain, Susan Graham, Zhenxin Wang, Bien Tan, David C. Sherrington, Steven P. Rannard, Andrew I. Cooper, and Mathias Brust pp 16398–16399 DOI: 10.1021/ja055321v Supporting Info

A Bimetallic Complex Containing a Cyclopentadienyl-Annulated Imidazol-2-ylidene Anthony J. Arduengo, III, Daniela Tapu, and William J. Marshall pp 16400–16401 DOI: 10.1021/ja055565f Supporting Info

Unfolding of Heptameric Co-chaperonin Protein Follows “Fly Casting” Mechanism:  Observation of Transient Nonnative Heptamer Michael Perham, Mingzhi Chen, Jianpeng Ma, and Pernilla Wittung-Stafshede pp 16402–16403 DOI: 10.1021/ja055574o Supporting Info

An Electric Cyclophane:  Cavity Control Based on the Rotation of a Paraphenylene by Redox Switching Hirohiko Kanazawa, Masayoshi Higuchi, and Kimihisa Yamamoto pp 16404–16405 DOI: 10.1021/ja055681i Supporting Info

Enantioselective Protonation of Catalytically Generated Chiral Enolates as an Approach to the Synthesis of α-Chloroesters Nathan T. Reynolds and Tomislav Rovis pp 16406–16407 DOI: 10.1021/ja055918a Supporting Info

anti-Selective Direct Asymmetric Mannich Reactions Catalyzed by Axially Chiral Amino Sulfonamide as an Organocatalyst Taichi Kano, Yukako Yamaguchi, Osamu Tokuda, and Keiji Maruoka pp 16408–16409 DOI: 10.1021/ja056008w Supporting Info

Cationic Palladium-Catalyzed Hydrosilylative Cross-Coupling of Alkynes with Alkenes Takamitsu Shimamoto, Motoharu Chimori, Hiroaki Sogawa, and Keiji Yamamoto pp 16410–16411 DOI: 10.1021/ja0558342 Supporting Info

l-Canavanine Is a Time-Controlled Mechanism-Based Inhibitor of Pseudomonas aeruginosa Arginine Deiminase Xuefeng Lu, Ling Li, Xiaohua Feng, Yan Wu, Debra Dunaway-Mariano, John R. Engen, and Patrick S. Mariano pp 16412–16413 DOI: 10.1021/ja056226p Supporting Info

Intrinsic Isotope Effects on Benzylic Hydroxylation by the Aromatic Amino Acid Hydroxylases:  Evidence for Hydrogen Tunneling, Coupled Motion, and Similar Reactivities Jorge Alex Pavon and Paul F. Fitzpatrick pp 16414–16415 DOI: 10.1021/ja0562651 Supporting Info

A Green Chemistry Approach to a More Efficient Asymmetric Catalyst:  Solvent-Free and Highly Concentrated Alkyl Additions to Ketones Sang-Jin Jeon, Hongmei Li, and Patrick J. Walsh pp 16416–16425 DOI: 10.1021/ja052200m Supporting Info

Structural and Spectroscopic Demonstration of Agostic C−C Interactions in Electron-Deficient Metallacyclobutanes and Related Cage Complexes:  Possible Implications for Olefin Polymerizations and Metatheses Benjamin G. Harvey, Charles L. Mayne, Atta M. Arif, and Richard D. Ernst pp 16426–16435 DOI: 10.1021/ja052287b Supporting Info

Fe3+-Hydroxide Ligation in the Superoxide Reductase from Desulfoarculus baarsii Is Associated with pH Dependent Spectral Changes Christelle Mathé, Vincent Nivière, and Tony A. Mattioli pp 16436–16441 DOI: 10.1021/ja053808y

Cloning, Sequencing, Analysis, and Heterologous Expression of the Fredericamycin Biosynthetic Gene Cluster from Streptomyces griseus Evelyn Wendt-Pienkowski, Yong Huang, Jian Zhang, Bensheng Li, Hao Jiang, Hyungjin Kwon, C. Richard Hutchinson, and Ben Shen pp 16442–16452 DOI: 10.1021/ja054376u Supporting Info

Reduction Potential Tuning at a Type 1 Copper Site Does Not Compromise Electron Transfer Reactivity Sachiko Yanagisawa and Christopher Dennison pp 16453–16459 DOI: 10.1021/ja054426v Supporting Info

Thermodynamics of Rhodium Hydride Reactions with CO, Aldehydes, and Olefins in Water:  Organo-Rhodium Porphyrin Bond Dissociation Free Energies Xuefeng Fu and Bradford B. Wayland pp 16460–16467 DOI: 10.1021/ja054548n

Palladium-Catalyzed Synthesis of 2,1‘-Disubstituted Tetrahydrofurans from γ-Hydroxy Internal Alkenes. Evidence for Alkene Insertion into a Pd−O Bond and Stereochemical Scrambling via β-Hydride Elimination Michael B. Hay and John P. Wolfe pp 16468–16476 DOI: 10.1021/ja054754v Supporting Info

A Bisphosphonate Monoamide Analogue of DOTA:  A Potential Agent for Bone Targeting Vojtěch Kubíek, Jakub Rudovský, Jan Kotek, Petr Hermann, Luce Vander Elst, Robert N. Muller, Zvonimir I. Kolar, Hubert Th. Wolterbeek, Joop A. Peters, and Ivan Lukeš pp 16477–16485 DOI: 10.1021/ja054905u Supporting Info

pH-Responsive Copolymer Films by Surface-Catalyzed Growth Dongshun Bai, Brian M. Habersberger, and G. Kane Jennings pp 16486–16493 DOI: 10.1021/ja055460c

The Electron Density of Bridging Hydrides Observed via Experimental and Theoretical Investigations on [Cr2(μ2-H)(Co)10]- Piero Macchi, Daniela Donghi, and Angelo Sironi pp 16494–16504 DOI: 10.1021/ja055308a Supporting Info

Comparisons of NMR Spectral Quality and Success in Crystallization Demonstrate that NMR and X-ray Crystallography Are Complementary Methods for Small Protein Structure Determination David A. Snyder, Yang Chen, Natalia G. Denissova, Thomas Acton, James M. Aramini, Melissa Ciano, Richard Karlin, Jinfeng Liu, Philip Manor, P. A. Rajan, Paolo Rossi, G. V. T. Swapna, Rong Xiao, Burkhard Rost, John Hunt, and Gaetano T. Montelione pp 16505–16511 DOI: 10.1021/ja053564h Supporting Info

NMR and X-ray Crystallography, Complementary Tools in Structural Proteomics of Small Proteins Adelinda A. Yee, Alexei Savchenko, Alexandr Ignachenko, Jonathan Lukin, Xiaohui Xu, Tatiana Skarina, Elena Evdokimova, Cheng Song Liu, Anthony Semesi, Valerie Guido, Aled M. Edwards, and Cheryl H. Arrowsmith pp 16512–16517 DOI: 10.1021/ja053565+ Supporting Info

Interconversions of Aryl Radicals by 1,4-Shifts of Hydrogen Atoms. A Synthesis of Benzo[a]corannulene Lingqing Peng and Lawrence T. Scott pp 16518–16521 DOI: 10.1021/ja054984+ Supporting Info

Co−C Bond Activation in Methylmalonyl-CoA Mutase by Stabilization of the Post-homolysis Product Co2+Cobalamin Amanda J. Brooks, Monica Vlasie, Ruma Banerjee, and Thomas C. Brunold pp 16522–16528 DOI: 10.1021/ja0503736 Supporting Info

Experimental Evidence for Ultrafast Electronic Relaxation in Molecules, Mediated by Diffuse States Eric Gloaguen, Jean-Michel Mestdagh, Lionel Poisson, Fabien Lepetit, Jean-Paul Visticot, Benoit Soep, Marcela Coroiu, André T. J. B. Eppink, and David H. Parker pp 16529–16534 DOI: 10.1021/ja052269u

Calcium Ion Responsive DNA Binding in a Zinc Finger Fusion Protein Akira Onoda, Nozomi Arai, Naoto Shimazu, Hitoshi Yamamoto, and Takeshi Yamamura pp 16535–16540 DOI: 10.1021/ja052477m Supporting Info

Role of Heme Types in Heme-Copper Oxidases:  Effects of Replacing a Heme b with a Heme o Mimic in an Engineered Heme-Copper Center in Myoglobin§ Ningyan Wang, Xuan Zhao, and Yi Lu pp 16541–16547 DOI: 10.1021/ja052659g Supporting Info

Spectroscopic Studies of Metal Binding and Metal Selectivity in Bacillus subtilis BSco, a Homologue of the Yeast Mitochondrial Protein Sco1p Luisa Andruzzi, Michiko Nakano, Mark J. Nilges, and Ninian J. Blackburn pp 16548–16558 DOI: 10.1021/ja0529539 Supporting Info

Synthesis and Characterization of a Highly Reducing Neutral “Extended Viologen” and the Isostructural Hydrocarbon 4,4‘ ‘‘ ‘-Di-n-octyl-p-quaterphenyl William W. Porter III, Thomas P. Vaid, and Arnold L. Rheingold pp 16559–16566 DOI: 10.1021/ja053084q Supporting Info

Spectroscopic and Kinetic Studies of Arabidopsis thaliana Sulfite Oxidase: Nature of the Redox-Active Orbital and Electronic Structure Contributions to Catalysis Craig Hemann, Brian L. Hood, Meita Fulton, Robert Hänsch, Günter Schwarz, Ralf R. Mendel, Martin L. Kirk, and Russ Hille pp 16567–16577 DOI: 10.1021/ja0530873 Supporting Info

Carbohydrate Rod Conjugates:  Ternary Rod−Coil Molecules Forming Complex Liquid Crystal Structures Bin Chen, Ute Baumeister, Gerhard Pelzl, Malay Kumar Das, Xiangbing Zeng, Goran Ungar, and Carsten Tschierske pp 16578–16591 DOI: 10.1021/ja0535357 Supporting Info

Chemical Basis of DNA Sugar−Phosphate Cleavage by Low-Energy Electrons Yi Zheng, Pierre Cloutier, Darel J. Hunting, Léon Sanche, and J. Richard Wagner pp 16592–16598 DOI: 10.1021/ja054129q

Solvation Dynamics in Ni+(H2O)n Clusters Probed with Infrared Spectroscopy Richard S. Walters, E. Dinesh Pillai, and Michael A. Duncan pp 16599–16610 DOI: 10.1021/ja0542587 Supporting Info

Time-Scale- and Temperature-Dependent Mechanical Properties of Viscoelastic Poly(3,4-ethylenedioxythiophene) Films A. Robert Hillman, Igor Efimov, and Karl S. Ryder pp 16611–16620 DOI: 10.1021/ja054259z

Refinement of Multidomain Protein Structures by Combination of Solution Small-Angle X-ray Scattering and NMR Data Alexander Grishaev, Justin Wu, Jill Trewhella, and Ad Bax pp 16621–16628 DOI: 10.1021/ja054342m Supporting Info

Imido Transfer from Bis(imido)ruthenium(VI) Porphyrins to Hydrocarbons:  Effect of Imido Substituents, C−H Bond Dissociation Energies, and RuVI/V Reduction Potentials Sarana Ka-Yan Leung, Wai-Man Tsui, Jie-Sheng Huang, Chi-Ming Che, Jiang-Lin Liang, and Nianyong Zhu pp 16629–16640 DOI: 10.1021/ja0542789 Supporting Info

A Photocycle for Hydrogen Production from Two-Electron Mixed-Valence Complexes Arthur J. Esswein, Adam S. Veige, and Daniel G. Nocera pp 16641–16651 DOI: 10.1021/ja054371x Supporting Info

Boronate-Based Fluorescent Probes for Imaging Cellular Hydrogen Peroxide Evan W. Miller, Aaron E. Albers, Arnd Pralle, Ehud Y. Isacoff, and Christopher J. Chang pp 16652–16659 DOI: 10.1021/ja054474f

Secondary Structure Sensitivity of Hydrogen Bond Lifetime Dynamics in the Protein Hydration Layer Sanjoy Bandyopadhyay, Sudip Chakraborty, and Biman Bagchi pp 16660–16667 DOI: 10.1021/ja054462u Supporting Info

Polypeptide Helices in Hybrid Peptide Sequences Kuppanna Ananda, Prema G. Vasudev, Anindita Sengupta, K. Muruga Poopathi Raja, Narayanaswamy Shamala, and Padmanabhan Balaram pp 16668–16674 DOI: 10.1021/ja055799z Supporting Info

Hydrogen Storage in Magnesium Clusters:  Quantum Chemical Study Rudy W. P. Wagemans, Joop H. van Lenthe, Petra E. de Jongh, A. Jos van Dillen, and Krijn P. de Jong pp 16675–16680 DOI: 10.1021/ja054569h Supporting Info

Stable, Specific, and Reversible Base Pairing via Schiff Base Chikara Dohno, Akimitsu Okamoto, and Isao Saito pp 16681–16684 DOI: 10.1021/ja054618q

Sequence-Specific Fluorescence Detection of DNA by Polyamide−Thiazole Orange Conjugates Eric J. Fechter, Bogdan Olenyuk, and Peter B. Dervan pp 16685–16691 DOI: 10.1021/ja054650k Supporting Info

Laminated Morphology of Nontwisting β-Sheet Fibrils Constructed via Peptide Self-Assembly Matthew S. Lamm, Karthikan Rajagopal, Joel P. Schneider, and Darrin J. Pochan pp 16692–16700 DOI: 10.1021/ja054721f Supporting Info

Dynamic Effects in MAS and MQMAS NMR Spectra of Half-Integer Quadrupolar Nuclei:  Calculations and an Application to the Double Perovskite Cryolite Mrignayani Kotecha, Santanu Chaudhuri, Clare P. Grey, and Lucio Frydman pp 16701–16712 DOI: 10.1021/ja0549749

Pulsed EPR Investigations of Systems Modeling Molybdenum Enzymes:  Hyperfine and Quadrupole Parameters of Oxo-17O in [Mo17O(SPh)4]- Andrei V. Astashkin, Frank Neese, Arnold M. Raitsimring, J. Jon A. Cooney, Eric Bultman, and John H. Enemark pp 16713–16722 DOI: 10.1021/ja055472y Supporting Info

205Tl NMR Methods for the Characterization of Monovalent Cation Binding to Nucleic Acids Michelle L. Gill, Scott A. Strobel, and J. Patrick Loria pp 16723–16732 DOI: 10.1021/ja055358f

Toward a Molecular Scale Interpretation of Excitation Energy Transfer in Solvated Bichromophoric Systems Carles Curutchet and Benedetta Mennucci pp 16733–16744 DOI: 10.1021/ja055489g Supporting Info

Stereoselective Construction of trans-Disubstituted Azabicycles Using Oxauracil as a Novel Free Radical Acceptor [J. Am. Chem. Soc. 2000, 122, 11009−11010]. P. Andrew Evans, Thara Manangan, and Arnold L. Rheingold p 16745 DOI: 10.1021/ja056443q

Modern Techniques for Characterizing Magnetic Materials Edited by Yimei Zhu (Brookhaven National Laboratory). Springer:  New York. 2005. xx + 600 pp. ISBN 1-4020-8007-7. Chris Leighton p 16746 DOI: 10.1021/ja059776w

Advanced Computer Simulation Approaches for Soft Matter Sciences I. Advances in Polymer Science, 173 Edited by Christian Holm and Kurt Kremer (MPI für Polymerforschung, Mainz). Springer:  Berlin, Heidelberg, New York. 2005. xii + 276 pp. $149.00. ISBN 3-540-22058-5. Vincent K. Shen pp 16746–16747 DOI: 10.1021/ja059762q

Dynamic Studies in Biology:  Phototriggers, Photoswitches, and Caged Biomolecules Edited by Maurice Goeldner (Université L. Pasteur Strasbourg, France) and Richard Givens (University of Kansas, USA). Wiley-VCH GmbH & Co. KGaA:  Weinheim. 2005. xxviii + 558 pp. $259.00. ISBN 3-527-30783-4. Daniel E. Falvey p 16747 DOI: 10.1021/ja059783k

Functional Synthetic Receptors Edited by Thomas Schrader (Philipps-Universität Marburg) and Andrew D. Hamilton (Yale University). Wiley-VCH Verlag GbH & Co. KgaA:  Weinheim. 2005. xii + 428 pp. $180.00. ISBN 3-527-30655-2. Simon H. Friedman pp 16747–16748 DOI: 10.1021/ja0597808

Modern Allene Chemistry, Volumes 1−2 Edited by Norbert Krause (University of Dortmund, Germany) and A. Stephen K. Hashmi (University of Stuttgart, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2004. xvi + xii + 1143 pp. $525. ISBN 3-527-30671-4. Richard P. Johnson p 16748 DOI: 10.1021/ja059772r

Issue 48

Two Generalizable Routes to Terminal Carbido Complexes Stephen R. Caskey, Michael H. Stewart, Jonathon E. Kivela, Joseph R. Sootsman, Marc J. A. Johnson, and Jeff W. Kampf pp 16750–16751 DOI: 10.1021/ja0453735 Supporting Info

Incorporating Lanthanide Cations with Cadmium Selenide Nanocrystals:  A Strategy to Sensitize and Protect Tb(III) Demetra A. Chengelis, Adrienne M. Yingling, Paul D. Badger, Chad M. Shade, and Stéphane Petoud pp 16752–16753 DOI: 10.1021/ja0511725 Supporting Info

Synthesis, Structure, and Reactivity of Unexpectedly Stable Spiroepoxy-β-Lactones Obtained by Epoxidation of 4-Alkylidene-2-Oxetanones Richard J. Duffy, Kay A. Morris, and Daniel Romo pp 16754–16755 DOI: 10.1021/ja053478h Supporting Info

In Situ Fabrication of Three-Dimensional Chemical Patterns in Fused Silica Separation Capillaries with Polymerized Phospholipids Eric E. Ross, Elisabeth Mansfield, Yiding Huang, and Craig A. Aspinwall pp 16756–16757 DOI: 10.1021/ja0539995 Supporting Info

Air-Breathing Laminar Flow-Based Microfluidic Fuel Cell Ranga S. Jayashree, Lajos Gancs, Eric R. Choban, Alex Primak, Dilip Natarajan, Larry J. Markoski, and Paul J. A. Kenis pp 16758–16759 DOI: 10.1021/ja054599k Supporting Info

A Rhodamine-Based Fluorescent and Colorimetric Chemodosimeter for the Rapid Detection of Hg2+ Ions in Aqueous Media Young-Keun Yang, Keun-Jeong Yook, and Jinsung Tae pp 16760–16761 DOI: 10.1021/ja054855t Supporting Info

Bifunctional Activation and Racemization in the Catalytic Asymmetric Aza-Baylis−Hillman Reaction Pascal Buskens, Jürgen Klankermayer, and Walter Leitner pp 16762–16763 DOI: 10.1021/ja0550024 Supporting Info

Tetraplatinated Artificial Oligopeptides Afford High Affinity Intercalation into dsDNA Lauren A. Levine, Christopher M. Morgan, Kristi Ohr, and Mary Elizabeth Williams pp 16764–16765 DOI: 10.1021/ja055162f Supporting Info

Equilibrium/Nonequilibrium Initial Configurations in Forward/Reverse Electron Transfer within Mixed-Metal Hemoglobin Hybrids Ami D. Patel, Judith M. Nocek, and Brian M. Hoffman pp 16766–16767 DOI: 10.1021/ja0552242

The Bis-urea Motif as a Tool To Functionalize Self-Assembled Nanoribbons Matthijn R. J. Vos, Gorka Etxebarria Jardĺ, Anna Llanes Pallas, Monica Breurken, Otto L. J. van Asselen, Paul H. H. Bomans, Phillip E. L. G. Leclère, Peter M. Frederik, Roeland J. M. Nolte, and Nico A. J. M. Sommerdijk pp 16768–16769 DOI: 10.1021/ja055075n Supporting Info

Absolute Molecular Weight of Polyaniline Harsha S. Kolla, Sumedh P. Surwade, Xinyu Zhang, Alan G. MacDiarmid, and Sanjeev K. Manohar pp 16770–16771 DOI: 10.1021/ja055327k Supporting Info

Halobenzenes and Ir(I):  Kinetic C−H Oxidative Addition and Thermodynamic C−Hal Oxidative Addition Lei Fan, Sean Parkin, and Oleg V. Ozerov pp 16772–16773 DOI: 10.1021/ja0557637 Supporting Info

High Resolution Printing of DNA Feature on Poly(methyl methacrylate) Substrates Using Supramolecular Nano-Stamping Arum Amy Yu, Tim Savas, Stefano Cabrini, Enzo diFabrizio, Henry I. Smith, and Francesco Stellacci pp 16774–16775 DOI: 10.1021/ja055762e Supporting Info

A Cobalt(III)−Salen Complex with an Axial Substituent in the Diamine Backbone:  Stereoselective Recognition of Amino Alcohols Hae-Jo Kim, Woosung Kim, Alan J. Lough, B. Moon Kim, and Jik Chin pp 16776–16777 DOI: 10.1021/ja0557785 Supporting Info

Remarkable Phosphine-Effect on the Intramolecular Aldol Reactions of Unsaturated 1,5-Diketones:  Highly Regioselective Synthesis of Cross-Conjugated Dienones Reema K. Thalji and William R. Roush pp 16778–16779 DOI: 10.1021/ja054085l Supporting Info

N2 Provides Insight into the Mechanism of H−C(sp3) Bond Cleavage Amy Walstrom, Maren Pink, Nikolai P. Tsvetkov, Hongjun Fan, Michael Ingleson, and Kenneth G. Caulton pp 16780–16781 DOI: 10.1021/ja0547580 Supporting Info

Synthesis of α-P-Modified Nucleoside Diphosphates with Ethylenediamine Ping Li, Zhihong Xu, Hongyan Liu, Charlotta K. Wennefors, Mikhail I. Dobrikov, János Ludwig, and Barbara Ramsay Shaw pp 16782–16783 DOI: 10.1021/ja055179y Supporting Info

Preparation and Characterization of Unique Inorganic−Organic Hybrid Mesoporous Materials Incorporating Arenetricarbonyl Complexes [−C6H4M(CO)3−] (M = Cr, Mo) Takashi Kamegawa, Takahiro Sakai, Masaya Matsuoka, and Masakazu Anpo pp 16784–16785 DOI: 10.1021/ja055851r

Controlling Molecular Diffusion in Self-Spreading Lipid Bilayer Using Periodic Array of Ultra-Small Metallic Architecture on Solid Surface Hideki Nabika, Atsushi Sasaki, Baku Takimoto, Yoshitaka Sawai, Shengtai He, and Kei Murakoshi pp 16786–16787 DOI: 10.1021/ja0559597 Supporting Info

Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou pp 16788–16789 DOI: 10.1021/ja0560027 Supporting Info

Zirconium-Mediated SN2‘ Substitution of Allylic Ethers:  Regio- and Stereospecific Formation of Protected Allylic Amines Gojko Lalic, Suzanne A. Blum, and Robert G. Bergman pp 16790–16791 DOI: 10.1021/ja056132f Supporting Info

In situ Crystallization of Low-Melting Ionic Liquids Angshuman R. Choudhury, Neil Winterton, Alexander Steiner, Andrew I. Cooper, and Kathleen A. Johnson pp 16792–16793 DOI: 10.1021/ja055956u Supporting Info

Homopolymer Micelles in Heterogeneous Solvent Mixtures Subhadeep Basu, Dharma Rao Vutukuri, and S. Thayumanavan pp 16794–16795 DOI: 10.1021/ja056042a Supporting Info

Synthesis of (−)-Quinocarcin by Directed Condensation of α-Amino Aldehydes Soojin Kwon and Andrew G. Myers pp 16796–16797 DOI: 10.1021/ja056206n Supporting Info

Cucurbit[10]uril Simin Liu, Peter Y. Zavalij, and Lyle Isaacs pp 16798–16799 DOI: 10.1021/ja056287n Supporting Info

A Selective, Noncovalent Assay for Base Flipping in DNA Lauren L. O'Neil and Olaf Wiest pp 16800–16801 DOI: 10.1021/ja056274+ Supporting Info

The Predictably Elusive Form II of Aspirin Peddy Vishweshwar, Jennifer A. McMahon, Mark Oliveira, Matthew L. Peterson, and Michael J. Zaworotko pp 16802–16803 DOI: 10.1021/ja056455b Supporting Info

Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters:  Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes Liming Zhang pp 16804–16805 DOI: 10.1021/ja056419c Supporting Info

SO2:H2O Surface Complex Found at the Vapor/Water Interface Teresa L. Tarbuck and Geraldine L. Richmond pp 16806–16807 DOI: 10.1021/ja056478q

Direct Imaging and Spectroscopic Characterization of Stimulus-Responsive Microgels Syuji Fujii, Steven P. Armes, Tohru Araki, and Harald Ade pp 16808–16809 DOI: 10.1021/ja056589p Supporting Info

Determination of the Size Distribution of Sonoluminescence Bubbles in a Pulsed Acoustic Field Judy Lee, Muthupandian Ashokkumar, Sandra Kentish, and Franz Grieser pp 16810–16811 DOI: 10.1021/ja0566432

QZ1 and QZ2:  Rapid, Reversible Quinoline-Derivatized Fluoresceins for Sensing Biological Zn(II) Elizabeth M. Nolan, Jacek Jaworski, Ken-Ichi Okamoto, Yasunori Hayashi, Morgan Sheng, and Stephen J. Lippard pp 16812–16823 DOI: 10.1021/ja052184t Supporting Info

The Fate of Dicationic States in Molecular Clusters of Benzene and Related Compounds Michael S. Deleuze, Jean-Pierre Francois, and Eugene S. Kryachko pp 16824–16834 DOI: 10.1021/ja042238j Supporting Info

Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers Mohammad K. Nazeeruddin, Filippo De Angelis, Simona Fantacci, Annabella Selloni, Guido Viscardi, Paul Liska, Seigo Ito, Bessho Takeru, and Michael Grätzel pp 16835–16847 DOI: 10.1021/ja052467l Supporting Info

Hydration State of Nonionic Surfactant Monolayers at the Liquid/Vapor Interface:  Structure Determination by Vibrational Sum Frequency Spectroscopy Eric Tyrode, C. Magnus Johnson, Atte Kumpulainen, Mark W. Rutland, and Per M. Claesson pp 16848–16859 DOI: 10.1021/ja053289z Supporting Info

Tubular Configurations and Structure-Dependent Anisotropic Strains in GaS Multi-Walled Sub-Microtubes Fang-Fang Xu, Junqing Hu, and Yoshio Bando pp 16860–16865 DOI: 10.1021/ja053340z

Intermolecular Charge Transfer between Heterocyclic Oligomers. Effects of Heteroatom and Molecular Packing on Hopping Transport in Organic Semiconductors Geoffrey R. Hutchison, Mark A. Ratner, and Tobin J. Marks pp 16866–16881 DOI: 10.1021/ja0533996 Supporting Info

Spectroscopic Studies of the Anaerobic Enzyme−Substrate Complex of Catechol 1,2-Dioxygenase Geoff P. Horsman, Andrew Jirasek, Frédéric H. Vaillancourt, Christopher J. Barbosa, Andrzej A. Jarzecki, Changliang Xu, Yasmina Mekmouche, Thomas G. Spiro, John D. Lipscomb, Michael W. Blades, Robin F. B. Turner, and Lindsay D. Eltis pp 16882–16891 DOI: 10.1021/ja053800o Supporting Info

Shell Click-Crosslinked (SCC) Nanoparticles:  A New Methodology for Synthesis and Orthogonal Functionalization Maisie J. Joralemon, Rachel K. O'Reilly, Craig J. Hawker, and Karen L. Wooley pp 16892–16899 DOI: 10.1021/ja053919x

Intervalence Transitions in the Mixed-Valence Monocations of Bis(triarylamines) Linked with Vinylene and Phenylene−Vinylene Bridges Stephen Barlow, Chad Risko, Sung-Jae Chung, Neil M. Tucker, Veaceslav Coropceanu, Simon C. Jones, Zerubba Levi, Jean-Luc Brédas, and Seth R. Marder pp 16900–16911 DOI: 10.1021/ja054136e Supporting Info

N-Triazinylammonium Tetrafluoroborates. A New Generation of Efficient Coupling Reagents Useful for Peptide Synthesis Zbigniew J. Kamiński, Beata Kolesińska, Justyna Kolesińska, Giuseppina Sabatino, Mario Chelli, Paolo Rovero, Michał Błaszczyk, Marek L. Główka, and Anna Maria Papini pp 16912–16920 DOI: 10.1021/ja054260y Supporting Info

Temperature-Dependent Studies of NO Recombination to Heme and Heme Proteins Dan Ionascu, Flaviu Gruia, Xiong Ye, Anchi Yu, Florin Rosca, Chris Beck, Andrey Demidov, John S. Olson, and Paul M. Champion pp 16921–16934 DOI: 10.1021/ja054249y

Nature of the Chemical Bond between Metal Atoms and Oxide Surfaces:  New Evidences from Spin Density Studies of K Atoms on Alkaline Earth Oxides Mario Chiesa, Elio Giamello, Cristiana Di Valentin, Gianfranco Pacchioni, Zbigniew Sojka, and Sabine Van Doorslaer pp 16935–16944 DOI: 10.1021/ja0542901 Supporting Info

Effects of Turn Stability on the Kinetics of Refolding of a Hairpin in a β-sheet Nicole N.-W. Kuo, Joseph J.-T. Huang, Jaroslava Miksovska, Rita P.-Y. Chen, Randy W. Larsen, and Sunney I. Chan pp 16945–16954 DOI: 10.1021/ja0543191 Supporting Info

In Situ Preparation of Protein−“Smart” Polymer Conjugates with Retention of Bioactivity Karina L. Heredia, Debora Bontempo, Tiffany Ly, Joshua T. Byers, Sven Halstenberg, and Heather D. Maynard pp 16955–16960 DOI: 10.1021/ja054482w Supporting Info

Energetic Characterization of Short Helical Polyalanine Peptides in Water:  Analysis of 13CO Chemical Shift Data Robert J. Kennedy, Sharon M. Walker, and Daniel S. Kemp pp 16961–16968 DOI: 10.1021/ja054645g Supporting Info

A Quantum Dynamical Treatment of Symmetry-Induced Kinetic Isotope Effects in the Formation of He2+ Junkai Xie, Bill Poirier, and Gregory I. Gellene pp 16969–16975 DOI: 10.1021/ja0517419

Coordinative Properties of Highly Fluorinated Solvents with Amino and Ether Groups Paul G. Boswell, Elizabeth C. Lugert, József Rábai, Elizabeth A. Amin, and Philippe Bühlmann pp 16976–16984 DOI: 10.1021/ja055816k Supporting Info

3H-Benzophosphepine Complexes:  Versatile Phosphinidene Precursors Mark L. G. Borst, Rosa E. Bulo, Danièle J. Gibney, Yonathan Alem, Frans J. J. de Kanter, Andreas W. Ehlers, Marius Schakel, Martin Lutz, Anthony L. Spek, and Koop Lammertsma pp 16985–16999 DOI: 10.1021/ja054885w Supporting Info

Scope and Mechanistic Study of the Ruthenium-Catalyzed ortho-C−H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes Chae S. Yi and Sang Young Yun pp 17000–17006 DOI: 10.1021/ja055608s Supporting Info

Critical Influence of Adsorption Geometry in the Heterogeneous Epoxidation of “Allylic” Alkenes:  Structure and Reactivity of Three Phenylpropene Isomers on Cu(111) Federico J. Williams, Rachael L. Cropley, Owain P. H. Vaughan, Andrew J. Urquhart, Mintcho S. Tikhov, Christine Kolczewski, Klaus Hermann, and Richard M. Lambert pp 17007–17011 DOI: 10.1021/ja055635i Supporting Info

Enantioselective Addition of Secondary Phosphines to Methacrylonitrile:  Catalysis and Mechanism Aaron D. Sadow and Antonio Togni pp 17012–17024 DOI: 10.1021/ja0555163 Supporting Info

Light-Activated Hydrogel Formation via the Triggered Folding and Self-Assembly of a Designed Peptide Lisa A. Haines, Karthikan Rajagopal, Bulent Ozbas, Daphne A. Salick, Darrin J. Pochan, and Joel P. Schneider pp 17025–17029 DOI: 10.1021/ja054719o Supporting Info

Vibrational Spectroscopy and Structures of Ni+(C2H2)n (n =1−4) Complexes Richard S. Walters, E. Dinesh Pillai, Paul v. R. Schleyer, and Michael A. Duncan pp 17030–17042 DOI: 10.1021/ja054800r Supporting Info

Search for Improved Host Architectures:  Application of de Novo Structure-Based Design and High-Throughput Screening Methods To Identify Optimal Building Blocks for Multidentate Ethers Benjamin P. Hay, Alexander A. Oliferenko, Jamal Uddin, Cungen Zhang, and Timothy K. Firman pp 17043–17053 DOI: 10.1021/ja055169x Supporting Info

DNA Molecular Motor Driven Micromechanical Cantilever Arrays Wenmiao Shu, Dongsheng Liu, Moyu Watari, Christian K. Riener, Torsten Strunz, Mark E. Welland, Shankar Balasubramanian, and Rachel A. McKendry pp 17054–17060 DOI: 10.1021/ja0554514 Supporting Info

Strong Solute−Solute Dispersive Interactions in a Protein−Ligand Complex Richard Malham, Sarah Johnstone, Richard J. Bingham, Elizabeth Barratt, Simon E. V. Phillips, Charles A. Laughton, and Steve W. Homans pp 17061–17067 DOI: 10.1021/ja055454g Supporting Info

Mechanistic Insights into an Unprecedented C−C Bond Activation on a Rh/Ga Bimetallic Complex:  A Combined Experimental/Computational Approach Thomas Cadenbach, Christian Gemel, Rochus Schmid, and Roland A. Fischer pp 17068–17078 DOI: 10.1021/ja055298d Supporting Info

A Complete Set of NMR Chemical Shifts and Spin−Spin Coupling Constants for l-Alanyl-l-alanine Zwitterion and Analysis of Its Conformational Behavior Petr Bouř, Miloš Buděšínský, Vladimír Špirko, Josef Kapitán, Jaroslav Šebestík, and Vladimír Sychrovský pp 17079–17089 DOI: 10.1021/ja0552343 Supporting Info

Three-Dimensional Self-Organization of Supramolecular Self-Assembled Porphyrin Hollow Hexagonal Nanoprisms Jin-Song Hu, Yu-Guo Guo, Han-Pu Liang, Li-Jun Wan, and Li Jiang pp 17090–17095 DOI: 10.1021/ja0553912 Supporting Info

Weak Intramolecular Interactions in Ethylene Glycol Identified by Vapor Phase OH−Stretching Overtone Spectroscopy Daryl L. Howard, Poul Jørgensen, and Henrik G. Kjaergaard pp 17096–17103 DOI: 10.1021/ja055827d Supporting Info

Kinetic Capillary Electrophoresis (KCE):  A Conceptual Platform for Kinetic Homogeneous Affinity Methods Alexander Petrov, Victor Okhonin, Maxim Berezovski, and Sergey N. Krylov pp 17104–17110 DOI: 10.1021/ja056232l

Catalyst-Controlled Asymmetric Synthesis of Fostriecin and 8-epi-Fostriecin Keisuke Maki, Rie Motoki, Kunihiko Fujii, Motomu Kanai, Takayasu Kobayashi, Shinri Tamura, and Masakatsu Shibasaki pp 17111–17117 DOI: 10.1021/ja0562043 Supporting Info

Kinetically Controlled Synthesis of Triangular and Hexagonal Nanoplates of Palladium and Their SPR/SERS Properties Yujie Xiong, Joseph M. McLellan, Jingyi Chen, Yadong Yin, Zhi-Yuan Li, and Younan Xia pp 17118–17127 DOI: 10.1021/ja056498s Supporting Info

Reviews in Computational Chemistry, Volume 21 Edited by Kenny B. Lipkowitz (North Dakota State University), Raima Larter (Indiana University-Purdue University), and Thomas R. Cundari (University of North Texas). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xxviii + 443 pp. $150.00. ISBN 0-471-68239-X. Peter T. Cummings p 17128 DOI: 10.1021/ja059753h

Issue 49

Collective Behavior of Franck−Condon Excited States and Energy Transfer in DNA Double Helices Dimitra Markovitsi, Delphine Onidas, Thomas Gustavsson, Francis Talbot, and Elodie Lazzarotto pp 17130–17131 DOI: 10.1021/ja054955z Supporting Info

Protease-Mediated Ligation of Abiotic Oligomers Barney Yoo and Kent Kirshenbaum pp 17132–17133 DOI: 10.1021/ja055105m Supporting Info

Nonpeptidic Foldamers from Amino Acids:  Synthesis and Characterization of 1,3-Substituted Triazole Oligomers Nicholas G. Angelo and Paramjit S. Arora pp 17134–17135 DOI: 10.1021/ja056406z Supporting Info

A Singly Bonded Derivative of Endohedral Metallofullerene:  La@C82CBr(COOC2H5)2 Lai Feng, Tsukasa Nakahodo, Takatsugu Wakahara, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Tatsuhisa Kato, Ernst Horn, Kenji Yoza, Naomi Mizorogi, and Shigeru Nagase pp 17136–17137 DOI: 10.1021/ja055484j Supporting Info

Where is the Sodium in Self-Assembled Monolayers of Single-Stranded DNA? Supratim Guha Ray, Hagai Cohen, Ron Naaman, and Yitzhak Rabin pp 17138–17139 DOI: 10.1021/ja055201n Supporting Info

Self-Assembly of Symmetric Finite-Size DNA Nanoarrays Yan Liu, Yonggang Ke, and Hao Yan pp 17140–17141 DOI: 10.1021/ja055614o Supporting Info

The Copper Chelator Methanobactin from Methylosinus trichosporium OB3b Binds Copper(I) Amanda S. Hakemian, Christine E. Tinberg, Kalyan C. Kondapalli, Joshua Telser, Brian M. Hoffman, Timothy L. Stemmler, and Amy C. Rosenzweig pp 17142–17143 DOI: 10.1021/ja0558140 Supporting Info

Immobilization of Proteins on Boron Nitride Nanotubes Chunyi Zhi, Yoshio Bando, Chengchun Tang, and Dmitri Golberg pp 17144–17145 DOI: 10.1021/ja055989+ Supporting Info

Polarized Raman Confocal Microscopy of Single Gallium Nitride Nanowires Peter J. Pauzauskie, David Talaga, Kwanyong Seo, Peidong Yang, and François Lagugné-Labarthet pp 17146–17147 DOI: 10.1021/ja056006b Supporting Info

Organic and Organometallic Derivatives of Dihydrogen-Encapsulated [60]Fullerene Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, and Eiichi Nakamura pp 17148–17149 DOI: 10.1021/ja056077a Supporting Info

Catalytic Micropumps:  Microscopic Convective Fluid Flow and Pattern Formation Timothy R. Kline, Walter F. Paxton, Yang Wang, Darrell Velegol, Thomas E. Mallouk, and Ayusman Sen pp 17150–17151 DOI: 10.1021/ja056069u Supporting Info

Guest-Induced Asymmetry in a Metal−Organic Porous Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation Tapas Kumar Maji, Golam Mostafa, Ryotaro Matsuda, and Susumu Kitagawa pp 17152–17153 DOI: 10.1021/ja0561439 Supporting Info

Spectroscopic and Theoretical Evidence for Oxazolone Ring Formation in Collision-Induced Dissociation of Peptides Nick C. Polfer, Jos Oomens, Sándor Suhai, and Béla Paizs pp 17154–17155 DOI: 10.1021/ja056553x Supporting Info

Substrate-Induced Raman Frequency Variation for Single-Walled Carbon Nanotubes Yingying Zhang, Jin Zhang, Hyungbin Son, Jing Kong, and Zhongfan Liu pp 17156–17157 DOI: 10.1021/ja056793c Supporting Info

N-Acylureido Functionality as Acceptor Substituent in Solvatochromic Fluorescence Probes:  Detection of Carboxylic Acids, Alcohols, and Fluoride Ions Cornelia Bohne, Heiko Ihmels, Michael Waidelich, and Chang Yihwa pp 17158–17159 DOI: 10.1021/ja052262c Supporting Info

Prevention of Undesirable Isomerization during Olefin Metathesis Soon Hyeok Hong, Daniel P. Sanders, Choon Woo Lee, and Robert H. Grubbs pp 17160–17161 DOI: 10.1021/ja052939w Supporting Info

Iron in the Service of Chromium:  The ortho-Benzannulation of trans,trans-Dienyl Fischer Carbene Complexes Yiqian Lian and William D. Wulff pp 17162–17163 DOI: 10.1021/ja0540268 Supporting Info

Arylmagnesiation of Alkynes Catalyzed Cooperatively by Iron and Copper Complexes Eiji Shirakawa, Takafumi Yamagami, Takahiro Kimura, Shigeru Yamaguchi, and Tamio Hayashi pp 17164–17165 DOI: 10.1021/ja0542136 Supporting Info

Synergism between Molybdenum and Lanthanum in the Disproportionation of Hydrogen Peroxide into Singlet Oxygen Joos Wahlen, Dirk E. De Vos, Marijke H. Groothaert, Véronique Nardello, Jean-Marie Aubry, Paul L. Alsters, and Pierre A. Jacobs pp 17166–17167 DOI: 10.1021/ja0547026 Supporting Info

Catalytic Enantioselective Conia-Ene Reaction Britton K. Corkey and F. Dean Toste pp 17168–17169 DOI: 10.1021/ja055059q Supporting Info

Olefin Oxygenation by the Hydroperoxide Adduct of a Nonheme Manganese(IV) Complex:  Epoxidations by a Metallo−Peracid Produces Gentle Selective Oxidations Guochuan Yin, Maria Buchalova, Andrew M. Danby, Chris M. Perkins, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch pp 17170–17171 DOI: 10.1021/ja055413k Supporting Info

Boroarsenates:  A Framework Motif and Family Templated on Cations and Anions Seth B. Wiggin and Mark T. Weller pp 17172–17173 DOI: 10.1021/ja055262l Supporting Info

Microemulsion-Templated Synthesis of Carbon Nanotube-Supported Pd and Rh Nanoparticles for Catalytic Applications Byunghoon Yoon and Chien M. Wai pp 17174–17175 DOI: 10.1021/ja055530f Supporting Info

Multicomponent Domino Reaction from β-Ketoamides:  Highly Efficient Access to Original Polyfunctionalized 2,6-Diazabicyclo[2.2.2]octane Cores Frédéric Liéby-Muller, Thierry Constantieux, and Jean Rodriguez pp 17176–17177 DOI: 10.1021/ja055885z Supporting Info

Selective Oxidation of Styrene on an Oxygen-Covered Au(111) Xingyi Deng and Cynthia M. Friend pp 17178–17179 DOI: 10.1021/ja0557031 Supporting Info

Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones Barry M. Trost and Jiayi Xu pp 17180–17181 DOI: 10.1021/ja055968f Supporting Info

Synthesis and Evaluation of a Potent and Selective Cell-Permeable p300 Histone Acetyltransferase Inhibitor Yujun Zheng, Karanam Balasubramanyam, Marek Cebrat, Donald Buck, Fabien Guidez, Arthur Zelent, Rhoda M. Alani, and Philip A. Cole pp 17182–17183 DOI: 10.1021/ja0558544 Supporting Info

An Annulation toward Fused Bicyclolactones Rene-Viet Nguyen and Chao-Jun Li pp 17184–17185 DOI: 10.1021/ja055883e Supporting Info

Aliphatic Carbon−Carbon Bond Cleavage Reactivity of a Mononuclear Ni(II) cis-β-Keto−Enolate Complex in the Presence of Base and O2:  A Model Reaction for Acireductone Dioxygenase (ARD) Ewa Szajna, Atta M. Arif, and Lisa M. Berreau pp 17186–17187 DOI: 10.1021/ja056346x Supporting Info

Formation of Indene Derivatives from Bis(cyclopentadienyl)titanacyclopentadienes with Alkyl Group Migration via Carbon−Carbon Bond Cleavage Tamotsu Takahashi, Yuichi Kuzuba, Fanzhi Kong, Kiyohiko Nakajima, and Zhenfeng Xi pp 17188–17189 DOI: 10.1021/ja0561789 Supporting Info

Weak Alignment of Paramagnetic Proteins Warrants Correction for Residual CSA Effects in Measurements of Pseudocontact Shifts Michael John, Ah Young Park, Guido Pintacuda, Nicholas E. Dixon, and Gottfried Otting pp 17190–17191 DOI: 10.1021/ja0564259 Supporting Info

Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates Timm Graening and John F. Hartwig pp 17192–17193 DOI: 10.1021/ja0566275 Supporting Info

Cobalt-Catalyzed Dimerization of α-Olefins to Give Linear α-Olefin Products Richard D. Broene, Maurice Brookhart, William M. Lamanna, and Anthony F. Volpe, Jr. pp 17194–17195 DOI: 10.1021/ja056655n Supporting Info

Efficient Homogeneous Catalysis in the Reduction of CO2 to CO David S. Laitar, Peter Müller, and Joseph P. Sadighi pp 17196–17197 DOI: 10.1021/ja0566679 Supporting Info

A Synthetic Cycle for H2/CO Activation and Allene Synthesis Using Recyclable Zirconium Complexes Tsukasa Matsuo and Hiroyuki Kawaguchi pp 17198–17199 DOI: 10.1021/ja0567079 Supporting Info

Establishing the Absolute Configuration of the Asbestinins:  Enantioselective Total Synthesis of 11-Acetoxy-4-deoxyasbestinin D Michael T. Crimmins and J. Michael Ellis pp 17200–17201 DOI: 10.1021/ja056921x Supporting Info

O-GlcNAcase Catalyzes Cleavage of Thioglycosides without General Acid Catalysis Matthew S. Macauley, Keith A. Stubbs, and David J. Vocadlo pp 17202–17203 DOI: 10.1021/ja0567687 Supporting Info

Formation of a Paramagnetic Al Complex and Extrusion of Fe during the Reaction of (Diiminepyridine)Fe with AlR3 (R = Me, Et) Jennifer Scott, Sandro Gambarotta, Ilia Korobkov, Quinten Knijnenburg, Bas de Bruin, and Peter H. M. Budzelaar pp 17204–17206 DOI: 10.1021/ja056135s Supporting Info

Ethene Epoxidation Selectivity Inhibited by Twisted Oxametallacycle:  A DFT Study on Ag Surface-Oxide Marie-Laure Bocquet and David Loffreda pp 17207–17215 DOI: 10.1021/ja051397f Supporting Info

The Energetic and Structural Effects of Single Amino Acid Substitutions upon Capped α-Helical Peptides Containing 17 Amino Acid Residues. An ONIOM DFT/AM1 Study Robert Wieczorek and J. J. Dannenberg pp 17216–17223 DOI: 10.1021/ja052689j Supporting Info

Thermotropic Uniaxial and Biaxial Nematic and Smectic Phases in Bent-Core Mesogens Veena Prasad, Shin-Woong Kang, K. A. Suresh, Leela Joshi, Qingbing Wang, and Satyendra Kumar pp 17224–17227 DOI: 10.1021/ja052769n Supporting Info

Elastomeric Flexible Free-Standing Hydrogen-Bonded Nanoscale Assemblies Jodie L. Lutkenhaus, Kristin D. Hrabak, Kathleen McEnnis, and Paula T. Hammond pp 17228–17234 DOI: 10.1021/ja053472s Supporting Info

Solution 1H NMR Confirmation of Folding in Short o-Phenylene Ethynylene Oligomers Ticora V. Jones, Morris M. Slutsky, Roberto Laos, Tom F. A. de Greef, and Gregory N. Tew pp 17235–17240 DOI: 10.1021/ja053530+ Supporting Info

Structural Transitions in the Polyalanine α-Helix under Uniaxial Strain Joel Ireta, Jörg Neugebauer, Matthias Scheffler, Arturo Rojo, and Marcelo Galván pp 17241–17244 DOI: 10.1021/ja053538j

Photochemically Induced Dynamic Nuclear Polarization in a C450A Mutant of the LOV2 Domain of the Avena sativa Blue-Light Receptor Phototropin Gerald Richter, Stefan Weber, Werner Römisch, Adelbert Bacher, Markus Fischer, and Wolfgang Eisenreich pp 17245–17252 DOI: 10.1021/ja053785n Supporting Info

Effect of a Bound Non-Nucleoside RT Inhibitor on the Dynamics of Wild-Type and Mutant HIV-1 Reverse Transcriptase Zhigang Zhou, Marcela Madrid, Jeffrey D. Evanseck, and Jeffry D. Madura pp 17253–17260 DOI: 10.1021/ja053973d Supporting Info

Crystalline Ice Grown on the Surface of the Ferroelectric Polymer Poly(vinylidene fluoride) (70%) and Trifluoroethylene (30%) Luis G. Rosa, Jie Xiao, Yaroslav B. Losovyj, Yi Gao, Ivan N. Yakovkin, Xiao C. Zeng, and Peter A. Dowben pp 17261–17265 DOI: 10.1021/ja054159t

Response of a Designed Metalloprotein to Changes in Metal Ion Coordination, Exogenous Ligands, and Active Site Volume Determined by X-ray Crystallography Silvano Geremia, Luigi Di Costanzo, Lucio Randaccio, Donald E. Engel, Angela Lombardi, Flavia Nastri, and William F. DeGrado pp 17266–17276 DOI: 10.1021/ja054199x Supporting Info

(3 + 1) Assembly of Three Human Telomeric Repeats into an Asymmetric Dimeric G-Quadruplex Na Zhang, Anh Tuân Phan, and Dinshaw J. Patel pp 17277–17285 DOI: 10.1021/ja0543090 Supporting Info

Site-Specific Fluorescent Labeling of RNA Molecules by Specific Transcription Using Unnatural Base Pairs Rie Kawai, Michiko Kimoto, Shuji Ikeda, Tsuneo Mitsui, Masayuki Endo, Shigeyuki Yokoyama, and Ichiro Hirao pp 17286–17295 DOI: 10.1021/ja0542946 Supporting Info

Proton to Carbon-13 INEPT in Solid-State NMR Spectroscopy Bénédicte Elena, Anne Lesage, Stefan Steuernagel, Anja Böckmann, and Lyndon Emsley pp 17296–17302 DOI: 10.1021/ja054411x

Catalytic Reaction Mechanism of Homogentisate Dioxygenase:  A Hybrid DFT Study Tomasz Borowski, Valentin Georgiev, and Per E. M. Siegbahn pp 17303–17314 DOI: 10.1021/ja054433j Supporting Info

Preparation of High Quality Electrical Insulator Self-Assembled Monolayers on Gold. Experimental Investigation of the Conduction Mechanism through Organic Thin Films Steffen Maisch, Frank Buckel, and Franz Effenberger pp 17315–17322 DOI: 10.1021/ja0548992 Supporting Info

Characterization of Steric and Electronic Properties of NiN2S2 Complexes as S-Donor Metallodithiolate Ligands Marilyn V. Rampersad, Stephen P. Jeffery, Melissa L. Golden, Jonghyuk Lee, Joseph H. Reibenspies, Donald J. Darensbourg, and Marcetta Y. Darensbourg pp 17323–17334 DOI: 10.1021/ja055051g Supporting Info

Influence of Tetrahydrofuran on Reactivity, Aggregation, and Aggregate Structure of Dimethylcuprates in Diethyl Ether Wolfram Henze, Armand Vyater, Norbert Krause, and Ruth M. Gschwind pp 17335–17342 DOI: 10.1021/ja055085o Supporting Info

Observation of 1MLCT and 3MLCT Excited States in Quadruply Bonded Mo2 and W2 Complexes Matthew J. Byrnes, Malcolm H. Chisholm, Judith A. Gallucci, Yao Liu, Ramkrishna Ramnauth, and Claudia Turro pp 17343–17352 DOI: 10.1021/ja055136h Supporting Info

Slow Relaxation in a One-Dimensional Rational Assembly of Antiferromagnetically Coupled [Mn4] Single-Molecule Magnets Lollita Lecren, Olivier Roubeau, Claude Coulon, Yang-Guang Li, Xavier F. Le Goff, Wolfgang Wernsdorfer, Hitoshi Miyasaka, and Rodolphe Clérac pp 17353–17363 DOI: 10.1021/ja0551685 Supporting Info

Intermolecular Electron-Transfer Reactions in Soluble Methane Monooxygenase:  A Role for Hysteresis in Protein Function Jessica L. Blazyk, George T. Gassner, and Stephen J. Lippard pp 17364–17376 DOI: 10.1021/ja0554054 Supporting Info

Elucidation of Fatty Acid Amide Hydrolase Inhibition by Potent α-Ketoheterocycle Derivatives from Monte Carlo Simulations Cristiano Ruch Werneck Guimarães, Dale L. Boger, and William L. Jorgensen pp 17377–17384 DOI: 10.1021/ja055438j Supporting Info

Observing Capillarity in Hydrophobic Silica Nanotubes Karthik Jayaraman, Kenji Okamoto, Sang Jun Son, Charles Luckett, Azeem H. Gopalani, Sang Bok Lee, and Douglas S. English pp 17385–17392 DOI: 10.1021/ja055535c Supporting Info

Polyketide Double Bond Biosynthesis. Mechanistic Analysis of the Dehydratase-Containing Module 2 of the Picromycin/Methymycin Polyketide Synthase Jiaquan Wu, Toby J. Zaleski, Chiara Valenzano, Chaitan Khosla, and David E. Cane pp 17393–17404 DOI: 10.1021/ja055672+ Supporting Info

A Differential Array of Metalated Synthetic Receptors for the Analysis of Tripeptide Mixtures Aaron T. Wright, Eric V. Anslyn, and John T. McDevitt pp 17405–17411 DOI: 10.1021/ja055696g Supporting Info

Uracil-Directed Ligand Tethering:  An Efficient Strategy for Uracil DNA Glycosylase (UNG) Inhibitor Development Yu Lin Jiang, Daniel J. Krosky, Lauren Seiple, and James T. Stivers pp 17412–17420 DOI: 10.1021/ja055846n Supporting Info

Molecular Engineering of the Polarity and Interactions of Molecular Electronic Switches Penelope A. Lewis, Christina E. Inman, Francisco Maya, James M. Tour, James E. Hutchison, and Paul S. Weiss pp 17421–17426 DOI: 10.1021/ja055787d

Geminate Rebinding in R-State Hemoglobin:  Kinetic and Computational Evidence for Multiple Hydrophobic Pockets Silvia Sottini, Stefania Abbruzzetti, Francesca Spyrakis, Stefano Bettati, Luca Ronda, Andrea Mozzarelli, and Cristiano Viappiani pp 17427–17432 DOI: 10.1021/ja056101k Supporting Info

Isopentenyl Diphosphate Isomerase. Mechanism-Based Inhibition by Diene Analogues of Isopentenyl Diphosphate and Dimethylallyl Diphosphate Zheng Wu, Johan Wouters, and C. Dale Poulter pp 17433–17438 DOI: 10.1021/ja056187h

Cross-Nucleation between ROY Polymorphs Shuang Chen, Hanmi Xi, and Lian Yu pp 17439–17444 DOI: 10.1021/ja056072d

Sequence Dependence of Charge Transport through DNA Domains Fangwei Shao, Katherine Augustyn, and Jacqueline K. Barton pp 17445–17452 DOI: 10.1021/ja0563399

Quantitative Angle-Resolved SPR Imaging of DNA−DNA and DNA−Drug Kinetics Lauren K. Wolf, Dominic E. Fullenkamp, and Rosina M. Georgiadis pp 17453–17459 DOI: 10.1021/ja056422w Supporting Info

Hydrogen-Bonding-Driven Preorganized Zinc Porphyrin Receptors for Efficient Complexation of C60, C70, and C60 Derivatives Zong-Quan Wu, Xue-Bin Shao, Chuang Li, Jun-Li Hou, Kui Wang, Xi-Kui Jiang, and Zhan-Ting Li pp 17460–17468 DOI: 10.1021/ja056509h Supporting Info

Direct Detection of Dimethylstannylene and Tetramethyldistannene in Solution and the Gas Phase by Laser Flash Photolysis of 1,1-Dimethylstannacyclopent-3-enes Rosa Becerra, Peter P. Gaspar, Cameron R. Harrington, William J. Leigh, Ignacio Vargas-Baca, Robin Walsh, and Dong Zhou pp 17469–17478 DOI: 10.1021/ja052675d Supporting Info

Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li1-xCo1/3Ni1/3Mn1/3O2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy Won-Sub Yoon, Mahalingam Balasubramanian, Kyung Yoon Chung, Xiao-Qing Yang, James McBreen, Clare P. Grey, and Daniel A. Fischer pp 17479–17487 DOI: 10.1021/ja0530568

Importance of Tensor Asymmetry for the Analysis of 2H NMR Spectra from Deuterated Aromatic Rings Peter Pulay, Erin M. Scherer, Patrick C. A. van der Wel, and Roger E. Koeppe II pp 17488–17493 DOI: 10.1021/ja054935x

Calcium, Strontium, Barium, and Ytterbium Complexes with Cyclooctatetraenyl or Cyclononatetraenyl Ligands1 Marc D. Walter, Gotthelf Wolmershäuser, and Helmut Sitzmann pp 17494–17503 DOI: 10.1021/ja0550071 Supporting Info

Light Induced Manganese Oxidation and Long-Lived Charge Separation in a Mn2II,II−RuII(bpy)3−Acceptor Triad Magnus Borgström, Nizamuddin Shaikh, Olof Johansson, Magnus F. Anderlund, Stenbjörn Styring, Björn Åkermark, Ann Magnuson, and Leif Hammarström pp 17504–17515 DOI: 10.1021/ja055243b Supporting Info

New Insights into the Mechanism of Palladium-Catalyzed Allylic Amination Iain D. G. Watson and Andrei K. Yudin pp 17516–17529 DOI: 10.1021/ja055288c Supporting Info

Reactions of the Heavier Group 14 Element Alkyne Analogues Ar‘EEAr‘ (Ar‘ = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with Unsaturated Molecules:  Probing the Character of the EE Multiple Bonds Chunming Cui, Marilyn M. Olmstead, James C. Fettinger, Geoffrey H. Spikes, and Philip P. Power pp 17530–17541 DOI: 10.1021/ja055372s Supporting Info

Catalyst-Transfer Polycondensation. Mechanism of Ni-Catalyzed Chain-Growth Polymerization Leading to Well-Defined Poly(3-hexylthiophene) Ryo Miyakoshi, Akihiro Yokoyama, and Tsutomu Yokozawa pp 17542–17547 DOI: 10.1021/ja0556880 Supporting Info

Protonation of Carbon Single-Walled Nanotubes Studied Using 13C and 1H−13C Cross Polarization Nuclear Magnetic Resonance and Raman Spectroscopies Chaiwat Engtrakul, Mark F. Davis, Thomas Gennett, Anne C. Dillon, Kim M. Jones, and Michael J. Heben pp 17548–17555 DOI: 10.1021/ja0557886

Different Transition-State Structures for the Reactions of β-Lactams and Analogous β-Sultams with Serine β-Lactamases Wing Y. Tsang, Naveed Ahmed, Paul S. Hinchliffe, J. Matthew Wood, Lindsay P. Harding, Andrew P. Laws, and Michael I. Page pp 17556–17564 DOI: 10.1021/ja056124z Supporting Info

Role of the Cocatalyst in the Copolymerization of CO2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes [J. Am. Chem. Soc. 2005, 127, 14026−14038]. Donald J. Darensbourg, Ryan Mackiewicz, and Jody L. Rodgers p 17565 DOI: 10.1021/ja059920d

Handbook of Reagents for Organic Synthesis:  Reagents for High-Throughput Solid-Phase and Solution-Phase Organic Synthesis Edited by Peter Wipf (University of Pittsburgh). John Wiley & Sons, Ltd.:  Chichester. 2005. xii + 380 pp. $140.00. ISBN 0-470-86298-X. p 17566 DOI: 10.1021/ja059798i

Chemistry of Natural Products By Sujata V. Bhat (Indian Institute of Technology Bombay, Mumbai, India), Bhimsen A. Nagasampagi (National Chemistry Laboratory, Pune, India), and Meenakshi Sivakumar (Quest Research Center, Mulund, Mumbai, India). Springer:  Berlin, Heidelberg. 2005. xxxii + 840 pp. $199.00. ISBN 3-540-40669-7. p 17566 DOI: 10.1021/ja059799a

Phosphorus World:  Chemistry, Biochemistry and Technology By D. E. C. Corbridge (Harrogate, UK). D. E. C. Corbridge:  P.O. Box 504, Harrogate HG3 1WN, UK. 2005. http://www.phosphorusworld.com. $85.00. CD-ROM. Richard A. Kemp pp 17566–17567 DOI: 10.1021/ja059786x

The Comprehensive e-Book of Named Organic Reactions and Their Mechanisms By Elbertus Kruiswijk. The Chemical Bookstore:  Aberaman, U.K. 2005. http://www.namedorganicreactions.co.uk. 1980 pp. Approximately $23.00. Tomislav Rovis pp 17567–17568 DOI: 10.1021/ja0597653

Issue 50

Pore Formation Coupled to Ion Transport through Lipid Membranes as Induced by Transmembrane Ionic Charge Imbalance:  Atomistic Molecular Dynamics Study Andrey A. Gurtovenko and Ilpo Vattulainen pp 17570–17571 DOI: 10.1021/ja053129n Supporting Info

MRI Thermometry Based on PARACEST Agents Shanrong Zhang, Craig R. Malloy, and A. Dean Sherry pp 17572–17573 DOI: 10.1021/ja053799t Supporting Info

Ultrafast Intermolecular Zero Quantum Spectroscopy Gigi Galiana, Rosa T. Branca, and Warren S. Warren pp 17574–17575 DOI: 10.1021/ja054463m

Combinatorial Biomimetics. Optimization of a Composition of Copper(II) Poly-l-Histidine Complex as an Electrocatalyst for O2 Reduction by Scanning Electrochemical Microscopy Yu Ching Weng, Fu-Ren F. Fan, and Allen J. Bard pp 17576–17577 DOI: 10.1021/ja054812c Supporting Info

Supramolecular Oxidation of Anilines Using Hydrogen Peroxide as Stoichiometric Oxidant Lavinia Marinescu, Merete Mølbach, Cyril Rousseau, and Mikael Bols pp 17578–17579 DOI: 10.1021/ja054457q Supporting Info

A Polydiacetylene-Based Fluorescent Sensor Chip Jong-Man Kim, Young Bok Lee, Doo Ho Yang, Ji-Seok Lee, Gil Sun Lee, and Dong June Ahn pp 17580–17581 DOI: 10.1021/ja0547275 Supporting Info

The Ferrous Verdoheme−Heme Oxygenase Complex is Six-Coordinate and Low-Spin Christopher O. Damaso, Richard A. Bunce, Mikhail V. Barybin, Angela Wilks, and Mario Rivera pp 17582–17583 DOI: 10.1021/ja055099u Supporting Info

Cellular Logic with Orthogonal Ribosomes Oliver Rackham and Jason W. Chin pp 17584–17585 DOI: 10.1021/ja055338d Supporting Info

An Alternative of CdSe Nanocrystal Emitters:  Pure and Tunable Impurity Emissions in ZnSe Nanocrystals Narayan Pradhan, David Goorskey, Jason Thessing, and Xiaogang Peng pp 17586–17587 DOI: 10.1021/ja055557z Supporting Info

RNA GG·UU Motif Binds K+ but Not Mg2+ Yupeng Fan, Barbara L. Gaffney, and Roger A. Jones pp 17588–17589 DOI: 10.1021/ja0555522 Supporting Info

Self-Assembly of DNA Double-Double Crossover Complexes into High-Density, Doubly Connected, Planar Structures Dustin Reishus, Bilal Shaw, Yuriy Brun, Nickolas Chelyapov, and Leonard Adleman pp 17590–17591 DOI: 10.1021/ja0557177 Supporting Info

Synthesis, Neutron Structure, and Reactivity of the Bis(dihydrogen) Complex RuH2(η2-H2)2(PCyp3)2 Stabilized by Two Tricyclopentylphosphines Mary Grellier, Laure Vendier, Bruno Chaudret, Alberto Albinati, Silvia Rizzato, Sax Mason, and Sylviane Sabo-Etienne pp 17592–17593 DOI: 10.1021/ja055126g Supporting Info

Characterization of Kinetics and Products of the Baeyer−Villiger Oxygenase MtmOIV, The Key Enzyme of the Biosynthetic Pathway toward the Natural Product Anticancer Drug Mithramycin from Streptomyces argillaceus Miranda Gibson, Mohammad Nur-e-alam, Fredilyn Lipata, Marcos A. Oliveira, and Jürgen Rohr pp 17594–17595 DOI: 10.1021/ja055750t Supporting Info

Structural Control of Self-Assembled Nanofibers by Artificial β-Sheet Peptides Composed of d- or l-Isomer Tomoyuki Koga, Miho Matsuoka, and Nobuyuki Higashi pp 17596–17597 DOI: 10.1021/ja0558387 Supporting Info

A Mixed-Valence Coordination Polymer Featuring Two-Dimensional Ferroelectric Order:  {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeCl4)}n (Et2dtc- = diethyldithiocarbamate) Takashi Okubo, Ryo Kawajiri, Tadaoki Mitani, and Tatsuya Shimoda pp 17598–17599 DOI: 10.1021/ja056030p Supporting Info

Deposition of CTAB-Terminated Nanorods on Bacteria to Form Highly Conducting Hybrid Systems Vikas Berry, Anand Gole, Subrata Kundu, Catherine J. Murphy, and Ravi F. Saraf pp 17600–17601 DOI: 10.1021/ja056428l Supporting Info

A Propeller-like Uranyl Metallomesogen Thomas Cardinaels, Jan Ramaekers, Daniel Guillon, Bertrand Donnio, and Koen Binnemans pp 17602–17603 DOI: 10.1021/ja056664w Supporting Info

Bright Fluorescent Nanodiamonds:  No Photobleaching and Low Cytotoxicity Shu-Jung Yu, Ming-Wei Kang, Huan-Cheng Chang, Kuan-Ming Chen, and Yueh-Chung Yu pp 17604–17605 DOI: 10.1021/ja0567081 Supporting Info

Self-Assembling a Molecular Pegboard Kyle Lund, Yan Liu, Stuart Lindsay, and Hao Yan pp 17606–17607 DOI: 10.1021/ja0568446 Supporting Info

Simultaneous, Segregated Storage of Two Agents in a Multicompartment Micelle Timothy P. Lodge, April Rasdal, Zhibo Li, and Marc A. Hillmyer pp 17608–17609 DOI: 10.1021/ja056841t Supporting Info

Creating Responsive Surfaces with Tailored Wettability Switching Kinetics and Reconstruction Reversibility Julie A. Crowe and Jan Genzer pp 17610–17611 DOI: 10.1021/ja056926u

Acceleration of a Nanomotor:  Electronic Control of the Rotary Speed of a Light-Driven Molecular Rotor Dirk Pijper, Richard A. van Delden, Auke Meetsma, and Ben L. Feringa pp 17612–17613 DOI: 10.1021/ja054499e Supporting Info

Rhodium-Catalyzed Alkyne Hydrothiolation with Aromatic and Aliphatic Thiols Changsheng Cao, Lauren R. Fraser, and Jennifer A. Love pp 17614–17615 DOI: 10.1021/ja055096h Supporting Info

Living Ring-Opening Polymerization of N-Sulfonylaziridines:  Synthesis of High Molecular Weight Linear Polyamines Ian C. Stewart, Cameron C. Lee, Robert G. Bergman, and F. Dean Toste pp 17616–17617 DOI: 10.1021/ja0554357 Supporting Info

A Multifunctional Pasteurella multocida Sialyltransferase:  A Powerful Tool for the Synthesis of Sialoside Libraries Hai Yu, Harshal Chokhawala, Rebekah Karpel, Hui Yu, Bingyuan Wu, Jianbo Zhang, Yingxin Zhang, Qiang Jia, and Xi Chen pp 17618–17619 DOI: 10.1021/ja0561690 Supporting Info

Chemoenzymatic Dynamic Kinetic Resolution of Primary Amines Jens Paetzold and Jan E. Bäckvall pp 17620–17621 DOI: 10.1021/ja056306t Supporting Info

Catalytic Enantioselective Aza-Henry Reaction with Broad Substrate Scope Claudio Palomo, Mikel Oiarbide, Antonio Laso, and Rosa López pp 17622–17623 DOI: 10.1021/ja056594t Supporting Info

Disubstituted Imidazolium-2-Carboxylates as Efficient Precursors to N-Heterocyclic Carbene Complexes of Rh, Ru, Ir, and Pd Adelina M. Voutchkova, Leah N. Appelhans, Anthony R. Chianese, and Robert H. Crabtree pp 17624–17625 DOI: 10.1021/ja056625k Supporting Info

Mass Spectrometry Assisted Assignment of NMR Resonances in Reductively 13C-Methylated Proteins Megan A. Macnaughtan, Austin M. Kane, and James H. Prestegard pp 17626–17627 DOI: 10.1021/ja056977r

Identification and Hydrogenation of C2 on Pt(111) Rongping Deng, Eldad Herceg, and Michael Trenary pp 17628–17633 DOI: 10.1021/ja052607r

Spectroscopic Characterization of Hydroxide and Aqua Complexes of Fe(II)-Protoheme, Structural Models for the Axial Coordination of the Atypical Heme of Membrane Cytochrome b6f Complexes Adrienne Gomez de Gracia, Luc Bordes, and Alain Desbois pp 17634–17643 DOI: 10.1021/ja052791g Supporting Info

Alkyne Hydrosilylation Catalyzed by a Cationic Ruthenium Complex:  Efficient and General Trans Addition Barry M. Trost and Zachary T. Ball pp 17644–17655 DOI: 10.1021/ja0528580 Supporting Info

Guanidinophosphazenes:  Design, Synthesis, and Basicity in THF and in the Gas Phase Alexander A. Kolomeitsev, Ilmar A. Koppel, Toomas Rodima, Jan Barten, Enno Lork, Gerd-Volker Röschenthaler, Ivari Kaljurand, Agnes Kütt, Ivar Koppel, Vahur Mäemets, and Ivo Leito pp 17656–17666 DOI: 10.1021/ja053543n Supporting Info

Hybrids of the Hemiasterlin Analogue Taltobulin and the Dolastatins Are Potent Antimicrotubule Agents Arie Zask, Joshua Kaplan, Sylvia Musto, and Frank Loganzo pp 17667–17671 DOI: 10.1021/ja053663v Supporting Info

Synthesis of Chiral Self-Assembling Rhombs and Their Characterization in Solution, in the Gas Phase, and at the Liquid−Solid Interface Kyung Seok Jeong, Sun Young Kim, Ueon-Sang Shin, Michael Kogej, Nguyen T. M. Hai, Peter Broekmann, Nakcheol Jeong, Barbara Kirchner, Markus Reiher, and Christoph A. Schalley pp 17672–17685 DOI: 10.1021/ja053781i Supporting Info

Spectroscopic Characterization of Interstrand Carbinolamine Cross-Links Formed in the 5‘-CpG-3‘ Sequence by the Acrolein-Derived γ-OH-1,N 2-Propano-2‘-deoxyguanosine DNA Adduct Young-Jin Cho, Hye-Young Kim, Hai Huang, Alvira Slutsky, Irina G. Minko, Hao Wang, Lubomir V. Nechev, Ivan D. Kozekov, Albena Kozekova, Pamela Tamura, Jaison Jacob, Markus Voehler, Thomas M. Harris, R. Stephen Lloyd, Carmelo J. Rizzo, and Michael P. Stone pp 17686–17696 DOI: 10.1021/ja053897e Supporting Info

Application of MCD Spectroscopy and TD−DFT to a Highly Non-Planar Porphyrinoid Ring System. New Insights on Red−Shifted Porphyrinoid Spectral Bands John Mack, Yoshiaki Asano, Nagao Kobayashi, and Martin J. Stillman pp 17697–17711 DOI: 10.1021/ja0540728 Supporting Info

The High-Valent Iron−Oxo Species of Polyoxometalate, if It Can Be Made, Will Be a Highly Potent Catalyst for C−H Hydroxylation and Double-Bond Epoxidation Devesh Kumar, Etienne Derat, Alexander M. Khenkin, Ronny Neumann, and Sason Shaik pp 17712–17718 DOI: 10.1021/ja0542340 Supporting Info

Coupe du Roi Bisection of Proteins. Spontaneous Tetramerization of Two Peptides That Span the Sequence of the Rabbit Uteroglobin Monomer Ernesto Nicolás, Cristina Ferrer, Lorena Taboada, and Ernest Giralt pp 17719–17733 DOI: 10.1021/ja0539793

Competition between Glutathione and Guanine for a Ruthenium(II) Arene Anticancer Complex: Detection of a Sulfenato Intermediate Fuyi Wang, Jingjing Xu, Abraha Habtemariam, Juraj Bella, and Peter J. Sadler pp 17734–17743 DOI: 10.1021/ja053387k Supporting Info

Spin Density and Coenzyme M Coordination Geometry of the ox1 Form of Methyl-Coenzyme M Reductase:  A Pulse EPR Study Jeffrey Harmer, Cinzia Finazzo, Rafal Piskorski, Carsten Bauer, Bernhard Jaun, Evert C. Duin, Meike Goenrich, Rudolf K. Thauer, Sabine Van Doorslaer, and Arthur Schweiger pp 17744–17755 DOI: 10.1021/ja053794w Supporting Info

Silicon-Initiated Carbonylative Carbotricyclization and [2+2+2+1] Cycloaddition of Enediynes Catalyzed by Rhodium Complexes Bibia Bennacer, Masaki Fujiwara, Seung-Yub Lee, and Iwao Ojima pp 17756–17767 DOI: 10.1021/ja054221m Supporting Info

Enthalpic Pair Interaction Coefficient between Zwitterions of l-α-Amino Acids and Urea Molecule as a Hydrophobicity Parameter of Amino Acid Side Chains Bartlomiej Palecz pp 17768–17771 DOI: 10.1021/ja054407l

Heat of Hydrogenation of 1,5-Dehydroquadricyclane. A Computational and Experimental Study of a Highly Pyramidalized Alkene Rebecca L. Hoenigman, Shuji Kato, Veronica M. Bierbaum, and Weston Thatcher Borden pp 17772–17777 DOI: 10.1021/ja054720n Supporting Info

Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation Raissa M. Trend, Yeeman K. Ramtohul, and Brian M. Stoltz pp 17778–17788 DOI: 10.1021/ja055534k Supporting Info

Generalized Anomeric Interpretation of the “High-Energy” N−P Bond in N-Methyl-N‘-phosphorylguanidine:  Importance of Reinforcing Stereoelectronic Effects in “High-Energy” Phosphoester Bonds Eliza A. Ruben, Michael S. Chapman, and Jeffrey D. Evanseck pp 17789–17798 DOI: 10.1021/ja054708v Supporting Info

Design and Synthesis of Intramolecular Charge Transfer-Based Fluorescent Reagents for the Highly-Sensitive Detection of Proteins Yoshio Suzuki and Kenji Yokoyama pp 17799–17802 DOI: 10.1021/ja054739q Supporting Info

Nano- and Microscopic Surface Wrinkles of Linearly Increasing Heights Prepared by Periodic Precipitation Stoyan K. Smoukov, Agnieszka Bitner, Christopher J. Campbell, Kristiana Kandere-Grzybowska, and Bartosz A. Grzybowski pp 17803–17807 DOI: 10.1021/ja054882j

Unique Layered Double Hydroxide Morphologies Using Reverse Microemulsion Synthesis Gang Hu and Dermot O'Hare pp 17808–17813 DOI: 10.1021/ja0549392 Supporting Info

RNA-Mediated Control of Metal Nanoparticle Shape Lina A. Gugliotti, Daniel L. Feldheim, and Bruce E. Eaton pp 17814–17818 DOI: 10.1021/ja055039o

Properties of a Mixed-Valence (FeII)2(FeIII)2 Square Cell for Utilization in the Quantum Cellular Automata Paradigm for Molecular Electronics Jieying Jiao, Gary J. Long, Leila Rebbouh, Fernande Grandjean, Alicia M. Beatty, and Thomas P. Fehlner pp 17819–17831 DOI: 10.1021/ja0550935 Supporting Info

Organic Syntheses on an Icosahedral Borane Surface:  Closomer Structures with Twelvefold Functionality Tiejun Li, Satish S. Jalisatgi, Michael J. Bayer, Andreas Maderna, Saeed I. Khan, and M. Frederick Hawthorne pp 17832–17841 DOI: 10.1021/ja055226m Supporting Info

Why Is the Partial Molar Volume of CO2 So Small When Dissolved in a Room Temperature Ionic Liquid? Structure and Dynamics of CO2 Dissolved in [Bmim+] [PF6-] Xuhui Huang, Claudio J. Margulis, Yuhui Li, and Bruce J. Berne pp 17842–17851 DOI: 10.1021/ja055315z

Properties of Inhibitors of Methane Hydrate Formation via Molecular Dynamics Simulations Brian J. Anderson, Jefferson W. Tester, Gian Paolo Borghi, and Bernhardt L. Trout pp 17852–17862 DOI: 10.1021/ja0554965

Measuring Site-Specific Cluster−Surface Bond Formation Regina Hoffmann, Clemens Barth, Adam S. Foster, Alexander L. Shluger, Hans J. Hug, Hans-Joachim Güntherodt, Risto M. Nieminen, and Michael Reichling pp 17863–17866 DOI: 10.1021/ja055267i Supporting Info

Solvent Friction Effect on Intramolecular Electron Transfer Min Liu, Naoki Ito, Mark Maroncelli, David H. Waldeck, Anna M. Oliver, and Michael N. Paddon-Row pp 17867–17876 DOI: 10.1021/ja055596a Supporting Info

Branched Coordination Multilayers on Gold Meni Wanunu, Alexander Vaskevich, Sidney R. Cohen, Hagai Cohen, Rina Arad-Yellin, Abraham Shanzer, and Israel Rubinstein pp 17877–17887 DOI: 10.1021/ja0556676 Supporting Info

Brønsted Base-Modulated Regioselectivity in the Aerobic Oxidative Amination of Styrene Catalyzed by Palladium Vitaliy I. Timokhin and Shannon S. Stahl pp 17888–17893 DOI: 10.1021/ja0562806 Supporting Info

Oligomeric Cholates:  Amphiphilic Foldamers with Nanometer-Sized Hydrophilic Cavities Yan Zhao and Zhenqi Zhong pp 17894–17901 DOI: 10.1021/ja056151p Supporting Info

Programming the Internal Structure and Stability of Helical Pores Self-Assembled from Dendritic Dipeptides via the Protective Groups of the Peptide Virgil Percec, Andrés E. Dulcey, Mihai Peterca, Monica Ilies, Monika J. Sienkowska, and Paul A. Heiney pp 17902–17909 DOI: 10.1021/ja056313h Supporting Info

Fully Stereocontrolled Total Syntheses of the Prostacyclin Analogues 16S-Iloprost and 16S-3-Oxa-Iloprost by a Common Route, Using Alkenylcopper-Azoalkene Conjugate Addition, Asymmetric Olefination, and Allylic Alkylation Guido J. Kramp, Mikhail Kim, Hans-Joachim Gais, and Cornelia Vermeeren pp 17910–17920 DOI: 10.1021/ja0558037 Supporting Info

Ru-Catalyzed Alkene−Alkyne Coupling. Total Synthesis of Amphidinolide P Barry M. Trost, Julien P. N. Papillon, and Thomas Nussbaumer pp 17921–17937 DOI: 10.1021/ja055967n Supporting Info

Fesulphos-Palladium(II) Complexes as Well-Defined Catalysts for Enantioselective Ring Opening of Meso Heterobicyclic Alkenes with Organozinc Reagents Silvia Cabrera, Ramón Gómez Arrayás, Inés Alonso, and Juan C. Carretero pp 17938–17947 DOI: 10.1021/ja055692b Supporting Info

Theoretical Study of the 13C NMR Spectroscopy of Single-Walled Carbon Nanotubes Nicholas A. Besley, Jeremy J. Titman, and Matthew D. Wright pp 17948–17953 DOI: 10.1021/ja055888b Supporting Info

Oxygen- and Temperature-Dependent Kinetic Isotope Effects in Choline Oxidase:  Correlating Reversible Hydride Transfer with Environmentally Enhanced Tunneling Fan Fan and Giovanni Gadda pp 17954–17961 DOI: 10.1021/ja0560377 Supporting Info

A Ferroelectrically Switchable Columnar Liquid Crystal Phase with Achiral Molecules:  Superstructures and Properties of Liquid Crystalline Ureas [J. Am. Chem. Soc. 2005, 127, 2565−2571]. Keiki Kishikawa, Shoichiro Nakahara, Yohei Nishikawa, Shigeo Kohmoto, and Makoto Yamamoto p 17962 DOI: 10.1021/ja0564867

Electrochemistry of Immobilized Particles and Droplets By Fritz Scholz, Uwe Schröder (Universität Greifswald, Germany), and Rubin Gulaboski (Universidade do Porto, Portugal). Springer:  Berlin, Heidelberg, New York. 2005. xiv + 290 pp. $129.00. ISBN 3-540-22005-4. Daniel A. Scherson p 17963 DOI: 10.1021/ja059746t

Mechanisms in Homogeneous Catalysis:  A Spectroscopic Approach Edited by Brian Heaton (University of Liverpool). Wiley-VCH GmbH & Co. KGaA:  Weiheim. 2005. xvi + 388 pp. $180.00. ISBN 3-527-31025-8 Robert H. Morris pp 17963–17964 DOI: 10.1021/ja0597956

Advanced Biomaterials for Medical Applications Edited by David W. Thomas (Cardiff University, UK). Kluwer Academic Publishers:  Dordrecht. 2004. xii + 200 pp. $88.00. ISBN 1-4020-2906-3. p 17964 DOI: 10.1021/ja059797q

Handbook of Hydroxyacetophenones:  Preparation and Physical Properties. Enlarged Second Edition, Volumes 1−2 By Robert Martin (Institut Curie, Paris, France). Springer:  Dordrecht. 2005. xiv + 554 pp (Volume 1) and xvi + 556 pp (Volume 2). $650.00 (Set). ISBN 1-4020-2290-5 (Set). p 17964 DOI: 10.1021/ja059801y

Issue 51

Oxygen Binding to Tyrosinase from Streptomyces antibioticus Studied by Laser Flash Photolysis Shun Hirota, Takumi Kawahara, Emanuela Lonardi, Ellen de Waal, Noriaki Funasaki, and Gerard W. Canters pp 17966–17967 DOI: 10.1021/ja0541128

Defining Long-Range Order and Local Disorder in Native α-Synuclein Using Residual Dipolar Couplings Pau Bernadó, Carlos W. Bertoncini, Christian Griesinger, Markus Zweckstetter, and Martin Blackledge pp 17968–17969 DOI: 10.1021/ja055538p Supporting Info

Direct Measurement of Barrier Heights in Protein Folding Athi N. Naganathan, Jose M. Sanchez-Ruiz, and Victor Muñoz pp 17970–17971 DOI: 10.1021/ja055996y Supporting Info

Entrapping of Exohedral Metallofullerenes in Carbon Nanotubes:  (CsC60)n@SWNT Nano-Peapods Bao-Yun Sun, Yuta Sato, Kazutomo Suenaga, Toshiya Okazaki, Naoki Kishi, Toshiki Sugai, Shunji Bandow, Sumio Iijima, and Hisanori Shinohara pp 17972–17973 DOI: 10.1021/ja056238a Supporting Info

1JNH Values Show that N1···N3 Hydrogen Bonds Are Stronger in dsRNA A:U than dsDNA A:T Base Pairs Marlon N. Manalo, Xiangming Kong, and Andy LiWang pp 17974–17975 DOI: 10.1021/ja055826l Supporting Info

Perpendicular Organization of Macromolecules:  Synthesis and Alignment Studies of a Soluble Poly(iptycene) Samuel W. Thomas, III, Timothy M. Long, Brian D. Pate, Steven R. Kline, Edwin L. Thomas, and Timothy M. Swager pp 17976–17977 DOI: 10.1021/ja056241u Supporting Info

Nickel-Catalyzed Cross-Coupling Reaction of Aryl Fluorides and Chlorides with Grignard Reagents under Nickel/Magnesium Bimetallic Cooperation Naohiko Yoshikai, Hiroko Mashima, and Eiichi Nakamura pp 17978–17979 DOI: 10.1021/ja056327n Supporting Info

Guest-Dependent Negative Thermal Expansion in Nanoporous Prussian Blue Analogues MIIPtIV(CN)6·x{H2O} (0 ≤ x ≤ 2; M = Zn, Cd) Andrew L. Goodwin, Karena W. Chapman, and Cameron J. Kepert pp 17980–17981 DOI: 10.1021/ja056460f Supporting Info

pH-Sensitive Vesicles Based on a Biocompatible Zwitterionic Diblock Copolymer Jianzhong Du, Yiqing Tang, Andrew L. Lewis, and Steven P. Armes pp 17982–17983 DOI: 10.1021/ja056514l Supporting Info

Energy Transfer in Self-Assembled [n]-Acene Fibers Involving ≥100 Donors Per Acceptor André Del Guerzo, Alexandre G. L. Olive, Jens Reichwagen, Henning Hopf, and Jean-Pierre Desvergne pp 17984–17985 DOI: 10.1021/ja0566228 Supporting Info

Spin-Frustrated Organic-Inorganic Hybrids of Lindgrenite Matthew P. Shores, Bart M. Bartlett, and Daniel G. Nocera pp 17986–17987 DOI: 10.1021/ja056666g Supporting Info

Fast Carbon−Carbon Bond Formation by a Promiscuous Lipase Maria Svedendahl, Karl Hult, and Per Berglund pp 17988–17989 DOI: 10.1021/ja056660r

A Reagentless Signal-On Architecture for Electronic, Aptamer-Based Sensors via Target-Induced Strand Displacement Yi Xiao, Brian D. Piorek, Kevin W. Plaxco, and Alan J. Heeger pp 17990–17991 DOI: 10.1021/ja056555h Supporting Info

A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unsaturated Imines and Triaryl-Substituted Quinolines Falguni Basuli, Halikhedkar Aneetha, John C. Huffman, and Daniel J. Mindiola pp 17992–17993 DOI: 10.1021/ja0566026 Supporting Info

A Chiral Luminescent Au16 Ring Self-Assembled from Achiral Components Shu-Yan Yu, Zhong-Xing Zhang, Eddie Chung-Chin Cheng, Yi-Zhi Li, Vivian Wing-Wah Yam, Hai-Ping Huang, and Rongben Zhang pp 17994–17995 DOI: 10.1021/ja0565727 Supporting Info

Budding Dynamics of Multicomponent Tubular Vesicles Li Li, Xinyu Liang, Meiyu Lin, Feng Qiu, and Yuliang Yang pp 17996–17997 DOI: 10.1021/ja0567438

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature Andrew R. Millward and Omar M. Yaghi pp 17998–17999 DOI: 10.1021/ja0570032 Supporting Info

The Inverted Cucurbit[n]uril Family Lyle Isaacs, Sang-Kyu Park, Simin Liu, Young Ho Ko, Narayanan Selvapalam, Youngkook Kim, Hyunuk Kim, Peter Y. Zavalij, Ghyung-Hwa Kim, Heung-Soo Lee, and Kimoon Kim pp 18000–18001 DOI: 10.1021/ja056988k Supporting Info

Gold(I)-Catalyzed Stereoselective Olefin Cyclopropanation Magnus J. Johansson, David J. Gorin, Steven T. Staben, and F. Dean Toste pp 18002–18003 DOI: 10.1021/ja0552500 Supporting Info

Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic Ligand Bingtao Guan, Dong Xing, Guixing Cai, Xiaobin Wan, Nan Yu, Zhao Fang, Liping Yang, and Zhangjie Shi pp 18004–18005 DOI: 10.1021/ja055398j Supporting Info

Air-Assisted Addition of Grignard Reagents to Olefins. A Simple Protocol for a Three-Component Coupling Process Yielding Alcohols Youhei Nobe, Kyohei Arayama, and Hirokazu Urabe pp 18006–18007 DOI: 10.1021/ja055732b Supporting Info

Enzymatic Cyclization of Dioxidosqualene to Heterocyclic Triterpenes Hui Shan, Michael J. R. Segura, William K. Wilson, Silvia Lodeiro, and Seiichi P. T. Matsuda pp 18008–18009 DOI: 10.1021/ja055822g Supporting Info

Engineering Pt in Ceria for a Maximum Metal−Support Interaction in Catalysis Connie M. Y. Yeung, Kai Man K. Yu, Qi Jia Fu, David Thompsett, Michael I. Petch, and Shik Chi Tsang pp 18010–18011 DOI: 10.1021/ja056102c Supporting Info

Rhodium-Catalyzed Reductive Aldol Reactions Using Aldehydes as the Stoichiometric Reductants Michael C. Willis and Robert L. Woodward pp 18012–18013 DOI: 10.1021/ja056130v Supporting Info

Expedient Synthesis of Cyclopropane α-Amino Acids by the Catalytic Asymmetric Cyclopropanation of Alkenes Using Iodonium Ylides Derived from Methyl Nitroacetate Benoît Moreau and André B. Charette pp 18014–18015 DOI: 10.1021/ja056192l Supporting Info

Allosteric Control of Oligonucleotide Hybridization by Metal-Induced Cyclization Mareike Göritz and Roland Krämer pp 18016–18017 DOI: 10.1021/ja056463s Supporting Info

Synthesis of Multiwalled Carbon Nanotubes through a Modified Wolff−Kishner Reduction Process Wenzhong Wang,Wenzhong Wang, Bed Poudel, D. Z. Wang, and Z. F. Ren pp 18018–18019 DOI: 10.1021/ja056654v

A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem:  Regioselective Catalytic Direct Arylation of Pyridine N-Oxides Louis-Charles Campeau, Sophie Rousseaux, and Keith Fagnou pp 18020–18021 DOI: 10.1021/ja056800x Supporting Info

The Chlorate−Iodine Clock Reaction André P. Oliveira and Roberto B. Faria pp 18022–18023 DOI: 10.1021/ja0570537

Metathesis and Metallotropy:  A Versatile Combination for the Synthesis of Oligoenynes Mansuk Kim and Daesung Lee pp 18024–18025 DOI: 10.1021/ja057153c Supporting Info

Synthesis and Characterization of Stabilized Subnanometric Cobalt Metal Particles Eva Barea, Xavier Batlle, Patrick Bourges, Avelino Corma, Vicente Fornés, Amílcar Labarta, and Víctor F. Puntes pp 18026–18030 DOI: 10.1021/ja053746b Supporting Info

Hydroxylation of Phenolic Compounds by a Peroxodicopper(II) Complex:  Further Insight into the Mechanism of Tyrosinase Sara Palavicini, Alessandro Granata, Enrico Monzani, and Luigi Casella pp 18031–18036 DOI: 10.1021/ja0544298 Supporting Info

Intramolecular Metathesis of a Vinyl Group with Vinylidene CC Double Bond in Ru Complexes Yung-Sheng Yen, Ying-Chih Lin, Shou-Ling Huang, Yi-Hung Liu, Hui-Ling Sung, and Yu Wang pp 18037–18045 DOI: 10.1021/ja054994a Supporting Info

Aza-Cope Rearrangement−Mannich Cyclizations for the Formation of Complex Tricyclic Amines:  Stereocontrolled Total Synthesis of (±)-Gelsemine William G. Earley, Jon E. Jacobsen, Andrew Madin, G. Patrick Meier, Christopher J. O'Donnell, Taeboem Oh, David W. Old, Larry E. Overman, and Matthew J. Sharp pp 18046–18053 DOI: 10.1021/ja055710p Supporting Info

Use of the Intramolecular Heck Reaction for Forming Congested Quaternary Carbon Stereocenters. Stereocontrolled Total Synthesis of (±)-Gelsemine Andrew Madin, Christopher J. O'Donnell, Taeboem Oh, David W. Old, Larry E. Overman, and Matthew J. Sharp pp 18054–18065 DOI: 10.1021/ja055711h Supporting Info

σ-Borane Coordinated to Nickel(0) and Some Related Nickel(II) Trihydride Complexes Marco G. Crestani, Miguel Muñoz-Hernández, Alma Arévalo, Alberto Acosta-Ramírez, and Juventino J. García pp 18066–18073 DOI: 10.1021/ja056000m Supporting Info

C−H Activations at Iridium(I) Square-Planar Complexes Promoted by a Fifth Ligand Marta Martín, Olga Torres, Enrique Oñate, Eduardo Sola, and Luis A. Oro pp 18074–18084 DOI: 10.1021/ja0557233 Supporting Info

Regioselectively Trisilylated Hexopyranosides through Homogeneously Catalyzed Silane Alcoholysis Mee-Kyung Chung and Marcel Schlaf pp 18085–18092 DOI: 10.1021/ja056283i Supporting Info

Mechanistic Impact of Water Addition to SmI2:  Consequences in the Ground and Transition State Edamana Prasad and Robert A. Flowers II pp 18093–18099 DOI: 10.1021/ja056352t Supporting Info

Structural Evolution of the Chromophore in the Primary Stages of Trans/Cis Isomerization in Photoactive Yellow Protein Karsten Heyne, Omar F. Mohammed, Anwar Usman, Jens Dreyer, Erik T. J. Nibbering, and Michael A. Cusanovich pp 18100–18106 DOI: 10.1021/ja051210k Supporting Info

Pressure Independence of Stereomutation and Fragmentation in the Bis-spirocyclobutanes, anti- and syn-2,9-Dicyanodispiro[5.0.5.2]tetradeca-1,8-dienes Frank-Gerrit Klärner, Frank Wurche, William von E. Doering, and Jiade Yang pp 18107–18113 DOI: 10.1021/ja053168z

Carbocation-Forming Reactions in Ionic Liquids Xavier Creary, Elizabeth D. Willis, and Madeleine Gagnon pp 18114–18120 DOI: 10.1021/ja0536623 Supporting Info

A Stereoelectronic Effect on Turn Formation Due to Proline Substitution in Elastin-Mimetic Polypeptides Wookhyun Kim, R. Andrew McMillan, James P. Snyder, and Vincent P. Conticello pp 18121–18132 DOI: 10.1021/ja054105j Supporting Info

A Quadruply Hydrogen Bonded Heterocomplex Displaying High-Fidelity Recognition Taiho Park, Eric M. Todd, Shoji Nakashima, and Steven C. Zimmerman pp 18133–18142 DOI: 10.1021/ja0545517 Supporting Info

Base Pairing and Replicative Processing of the Formamidopyrimidine-dG DNA Lesion Matthias Ober, Heiko Müller, Carsten Pieck, Johannes Gierlich, and Thomas Carell pp 18143–18149 DOI: 10.1021/ja0549188 Supporting Info

Electronically Coupled MM Quadruply-Bonded Complexes (M = Mo or W) Employing Functionalized Terephthalate Bridges:  Toward Molecular Rheostats and Switches Malcolm H. Chisholm, Florian Feil, Christopher M. Hadad, and Nathan J. Patmore pp 18150–18158 DOI: 10.1021/ja0550982 Supporting Info

Pressure Enhanced Conductivity in Bis-1,2,3-Thiaselenazolyl Dimers Leanne Beer, Jaclyn L. Brusso, Robert C. Haddon, Mikhail E. Itkis, Holger Kleinke, Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, John F. Richardson, Richard A. Secco, and Xueyang Yu pp 18159–18170 DOI: 10.1021/ja055122b Supporting Info

Conformational Dynamics of the Isoalloxazine in Substrate-Free p-Hydroxybenzoate Hydroxylase:  Single-Molecule Studies Jeffrey R. Brender, Joe Dertouzos, David P. Ballou, Vincent Massey, Bruce A. Palfey, Barrie Entsch, Duncan G. Steel, and Ari Gafni pp 18171–18178 DOI: 10.1021/ja055171o

Electrochemical Definitions of O2 Sensitivity and Oxidative Inactivation in Hydrogenases Kylie A. Vincent, Alison Parkin, Oliver Lenz, Simon P. J. Albracht, Juan C. Fontecilla-Camps, Richard Cammack, Bärbel Friedrich, and Fraser A. Armstrong pp 18179–18189 DOI: 10.1021/ja055160v

Quantitative Analysis of Backbone Dynamics in a Crystalline Protein from Nitrogen-15 Spin−Lattice Relaxation Nicolas Giraud, Martin Blackledge, Maurice Goldman, Anja Böckmann, Anne Lesage, François Penin, and Lyndon Emsley pp 18190–18201 DOI: 10.1021/ja055182h Supporting Info

Utilization of a Combination of Weak Hydrogen-Bonding Interactions and Phase Segregation to Yield Highly Thermosensitive Supramolecular Polymers Sona Sivakova, David A. Bohnsack, Michael E. Mackay, Phiriyatorn Suwanmala, and Stuart J. Rowan pp 18202–18211 DOI: 10.1021/ja055245w Supporting Info

Quantum Dot-Based Multiplexed Fluorescence Resonance Energy Transfer Aaron R. Clapp, Igor L. Medintz, H. Tetsuo Uyeda, Brent R. Fisher, Ellen R. Goldman, Moungi G. Bawendi, and Hedi Mattoussi pp 18212–18221 DOI: 10.1021/ja054630i Supporting Info

Probing Shapes of Bichromophoric Metal−Organic Complexes Using Ion Mobility Mass Spectrometry Erin Shammel Baker, John E. Bushnell, Stephen R. Wecksler, Mark D. Lim, Manuel J. Manard, Nicholas F. Dupuis, Peter C. Ford, and Michael T. Bowers pp 18222–18228 DOI: 10.1021/ja0553699 Supporting Info

Site-Selective Metal Binding by Designed α-Helical Peptides Manolis Matzapetakis and Vincent L. Pecoraro pp 18229–18233 DOI: 10.1021/ja055433m Supporting Info

Influence of Thermal Fluctuations on Interfacial Electron Transfer in Functionalized TiO2 Semiconductors Sabas G. Abuabara, Luis G. C. Rego, and Victor S. Batista pp 18234–18242 DOI: 10.1021/ja055185u

Synthesis of Stable Dodecaalkoxy Derivatives of hypercloso-B12H12 Omar K. Farha, Richard L. Julius, Mark W. Lee, Ramon E. Huertas, Carolyn B. Knobler, and M. Frederick Hawthorne pp 18243–18251 DOI: 10.1021/ja0556373 Supporting Info

Simulations of Stochastic Sensing of Proteins Chung Yin Kong and M. Muthukumar pp 18252–18261 DOI: 10.1021/ja055695o

Semiconductor Rings Fabricated by Self-Assembly of Nanocrystals Bin Liu and Hua Chun Zeng pp 18262–18268 DOI: 10.1021/ja055734w

In Situ Spectroscopic Study of the Oxidation and Reduction of Pd(111) Guido Ketteler, D. Frank Ogletree, Hendrik Bluhm, Hongjian Liu, Eleonore L. D. Hebenstreit, and Miquel Salmeron pp 18269–18273 DOI: 10.1021/ja055754y Supporting Info

Location, Acid Strength, and Mobility of the Acidic Protons in Keggin 12-H3PW12O40:  A Combined Solid-State NMR Spectroscopy and DFT Quantum Chemical Calculation Study Jun Yang, Michael J. Janik, Ding Ma, Anmin Zheng, Mingjin Zhang, Matthew Neurock, Robert J. Davis, Chaohui Ye, and Feng Deng pp 18274–18280 DOI: 10.1021/ja055925z Supporting Info

Cation Dependence of Chloride Ion Complexation by Open-Chained Receptor Molecules in Chloroform Solution Robert Pajewski, Riccardo Ferdani, Jolanta Pajewska, Ruiqiong Li, and George W. Gokel pp 18281–18295 DOI: 10.1021/ja0558894

A General Organocatalyst for Direct α-Functionalization of Aldehydes:  Stereoselective C−C, C−N, C−F, C−Br, and C−S Bond-Forming Reactions. Scope and Mechanistic Insights Johan Franzén, Mauro Marigo, Doris Fielenbach, Tobias C. Wabnitz, Anne Kjrsgaard, and Karl Anker Jørgensen pp 18296–18304 DOI: 10.1021/ja056120u Supporting Info

Raising the Conductivity of Crystalline Polymer Electrolytes by Aliovalent Doping Chuhong Zhang, Edward Staunton, Yuri G. Andreev, and Peter G. Bruce pp 18305–18308 DOI: 10.1021/ja056129w Supporting Info

Structure and Function of GDP-Mannose-3‘,5‘-Epimerase:  An Enzyme which Performs Three Chemical Reactions at the Same Active Site Louise L. Major, Beata A. Wolucka, and James H. Naismith pp 18309–18320 DOI: 10.1021/ja056490i Supporting Info

Controlling Molecular Crystal Polymorphism with Self-Assembled Monolayer Templates Rupa Hiremath, Joseph A. Basile, Stephen W. Varney, and Jennifer A. Swift pp 18321–18327 DOI: 10.1021/ja0565119 Supporting Info

Diazonium−Protein Adducts for Graphite Electrode Microarrays Modification:  Direct and Addressed Electrochemical Immobilization Benjamin P. Corgier, Christophe A. Marquette, and Loïc J. Blum pp 18328–18332 DOI: 10.1021/ja056946w Supporting Info

Surface Layering in Ionic Liquids:  An X-ray Reflectivity Study [J. Am. Chem. Soc. 2005, 127, 7796−7804]. Eli Sloutskin, Benjamin M. Ocko, Lilach Tamam, Ivan Kuzmenko, Thomas Gog, and Moshe Deutsch p 18333 DOI: 10.1021/ja059913p