Volume 130
Main Index

Issue 01

Does the “Superatom” Exist in Halogenated Aluminum Clusters? Young-Kyu Han and Jaehoon Jung pp 2–3 DOI: 10.1021/ja074225m Supporting Info

Rapid Bioenabled Formation of Ferroelectric BaTiO3 at Room Temperature from an Aqueous Salt Solution at Near Neutral pH Gul Ahmad, Matthew B. Dickerson, Ye Cai, Sharon E. Jones, Eric M. Ernst, Jonathan P. Vernon, Michael S. Haluska, Yunnan Fang, Jiadong Wang, Guru Subramanyam, Rajesh R. Naik, and Kenneth H. Sandhage pp 4–5 DOI: 10.1021/ja0744302 Supporting Info

Modulation of Water Exchange in Europium(III) DOTA−Tetraamide Complexes via Electronic Substituent Effects S. James Ratnakar, Mark Woods, Angelo J. M. Lubag, Zoltán Kovács, and A. Dean Sherry pp 6–7 DOI: 10.1021/ja076325y Supporting Info

Hydrogen−Deuterium Exchange and Selective Labeling of Deprotonated Amino Acids and Peptides in the Gas Phase Zhixin Tian, Lev Lis, and Steven R. Kass pp 8–9 DOI: 10.1021/ja076599l Supporting Info

Cholesterol Shows Preference for the Interior of Polyunsaturated Lipid Membranes Siewert J. Marrink, Alex H. de Vries, Thad. A. Harroun, John Katsaras, and Stephen R. Wassall pp 10–11 DOI: 10.1021/ja076641c Supporting Info

Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts Michael R. Salata and Tobin J. Marks pp 12–13 DOI: 10.1021/ja076857e Supporting Info

Semiconducting Lead−Sulfur−Organic Network Solids Dayna L. Turner, Thomas P. Vaid, Peter W. Stephens, Kevin H. Stone, Antonio G. DiPasquale, and Arnold L. Rheingold pp 14–15 DOI: 10.1021/ja0770983 Supporting Info

Organolanthanide-Based Synthesis of 1,2,3-Triazoles from Nitriles and Diazo Compounds William J. Evans, Elizabeth Montalvo, Timothy M. Champagne, Joseph W. Ziller, Antonio G. DiPasquale, and Arnold L. Rheingold pp 16–17 DOI: 10.1021/ja077298e Supporting Info

Highly Chemoselective Metal-Free Reduction of Tertiary Amides Guillaume Barbe and André B. Charette pp 18–19 DOI: 10.1021/ja077463q Supporting Info

Hydrogen-Bond Acceptance of Bifunctional Ligands in an Alkyne−Metal π Complex Douglas B. Grotjahn, Valentín Miranda-Soto, Elijah J. Kragulj, Daniel A. Lev, Gülin Erdogan, Xi Zeng, and Andrew L. Cooksy pp 20–21 DOI: 10.1021/ja0774616 Supporting Info

Fast Enzyme Dynamics at the Active Site of Formate Dehydrogenase Jigar N. Bandaria, Samrat Dutta, Sarah E. Hill, Amnon Kohen, and Christopher M. Cheatum pp 22–23 DOI: 10.1021/ja077599o

Giant Coercivity in a One-Dimensional Cobalt-Radical Coordination Magnet Norio Ishii, Yoshitomo Okamura, Susumu Chiba, Takashi Nogami, and Takayuki Ishida pp 24–25 DOI: 10.1021/ja077666e Supporting Info

The Role of Colloid Formation in the Photoinduced H2 Production with a RuII−PdII Supramolecular Complex:  A Study by GC, XPS, and TEM Pengxiang Lei, Maria Hedlund, Reiner Lomoth, Håkan Rensmo, Olof Johansson, and Leif Hammarström pp 26–27 DOI: 10.1021/ja0776780 Supporting Info

Superparamagnetic High-Magnetization Microspheres with an Fe3O4@SiO2 Core and Perpendicularly Aligned Mesoporous SiO2 Shell for Removal of Microcystins Yonghui Deng, Dawei Qi, Chunhui Deng, Xiangmin Zhang, and Dongyuan Zhao pp 28–29 DOI: 10.1021/ja0777584 Supporting Info

The Sugar Conformation Governs (6-4) Photoproduct Formation at the Dinucleotide Level Céline Desnous, B. Ravindra Babu, Céline Moriou, Javier Ulises Ortiz Mayo, Alain Favre, Jesper Wengel, and Pascale Clivio pp 30–31 DOI: 10.1021/ja077095q Supporting Info

Rapid Assembly of Complex 3D Siloxane Architectures David B. Thompson and Michael A. Brook pp 32–33 DOI: 10.1021/ja0778491 Supporting Info

Tunable Aptamer Capillary Electrophoresis and Its Application to Protein Analysis Hongquan Zhang, Xing-Fang Li, and X. Chris Le pp 34–35 DOI: 10.1021/ja0778747 Supporting Info

Multiple Logic Gates Based on Electrically Wired Surface-Reconstituted Enzymes Marcos Pita and Evgeny Katz pp 36–37 DOI: 10.1021/ja077908a Supporting Info

Redirecting the Cyclization Steps of Fungal Polyketide Synthase Suzanne M. Ma, Jixun Zhan, Xinkai Xie, Kenji Watanabe, Yi Tang, and Wenjun Zhang pp 38–39 DOI: 10.1021/ja078091o Supporting Info

Stepwise Self-Assembly of DNA Tile Lattices Using dsDNA Bridges Sung Ha Park, Gleb Finkelstein, and Thomas H. LaBean pp 40–41 DOI: 10.1021/ja078122f Supporting Info

Aligned Carbon Nanotube/Polymer Composite Films with Robust Flexibility, High Transparency, and Excellent Conductivity Huisheng Peng pp 42–43 DOI: 10.1021/ja078267m Supporting Info

Lateral Diffusion in Lipid Membranes through Collective Flows Emma Falck, Tomasz Róg, Mikko Karttunen, and Ilpo Vattulainen pp 44–45 DOI: 10.1021/ja7103558 Supporting Info

Enantioselective, Organocatalytic Oxy-Michael Addition to γ/δ-Hydroxy-α,β-enones:  Boronate-Amine Complexes as Chiral Hydroxide Synthons De Run Li, Andiappan Murugan, and J. R. Falck pp 46–48 DOI: 10.1021/ja076802c Supporting Info

Design of a Selective Metal Ion Switch for Self-Assembly of Peptide-Based Fibrils Steven N. Dublin and Vincent P. Conticello pp 49–51 DOI: 10.1021/ja0775016 Supporting Info

Palladium-Catalyzed Direct C−H Arylation of N-Iminopyridinium Ylides:  Application to the Synthesis of (±)-Anabasine Alexandre Larivée, James J. Mousseau, and André B. Charette pp 52–54 DOI: 10.1021/ja710073n Supporting Info

Electronic Structure Description of the cis-MoOS Unit in Models for Molybdenum Hydroxylases Christian J. Doonan, Nick D. Rubie, Katrina Peariso, Hugh H. Harris, Sushilla Z. Knottenbelt, Graham N. George, Charles G. Young, and Martin L. Kirk pp 55–65 DOI: 10.1021/ja068512m Supporting Info

Spectroscopic Characterization of Photolytically Generated Radical Ion Pairs in Single-Wall Carbon Nanotubes Bearing Surface-Immobilized Tetrathiafulvalenes M. Ángeles Herranz, Christian Ehli, Stéphane Campidelli, Miriam Gutiérrez, Gordon L. Hug, Kei Ohkubo, Shunichi Fukuzumi, Maurizio Prato, Nazario Martín, and Dirk M. Guldi pp 66–73 DOI: 10.1021/ja073975t Supporting Info

Size-Dependent Charge Collection in Junctions Containing Single-Size and Multi-Size Arrays of Colloidal CdSe Quantum Dots Emily A. Weiss, Ryan C. Chiechi, Scott M. Geyer, Venda J. Porter, David C. Bell, Moungi G. Bawendi, and George M. Whitesides pp 74–82 DOI: 10.1021/ja076438h Supporting Info

The Use of Size-Selective Excitation To Study Photocurrent through Junctions Containing Single-Size and Multi-Size Arrays of Colloidal CdSe Quantum Dots Emily A. Weiss, Venda J. Porter, Ryan C. Chiechi, Scott M. Geyer, David C. Bell, Moungi G. Bawendi, and George M. Whitesides pp 83–92 DOI: 10.1021/ja076439+ Supporting Info

Specific RNA Self-Assembly with Minimal Paranemic Motifs Kirill A. Afonin, Dennis J. Cieply, and Neocles B. Leontis pp 93–102 DOI: 10.1021/ja071516m Supporting Info

Charge-Transfer-to-Solvent-Driven Dissolution Dynamics of I-(H2O)2-5 upon Excitation:  Excited-State ab Initio Molecular Dynamics Simulations Maciej Kołaski, Han Myoung Lee, Chaeho Pak, and Kwang S. Kim pp 103–112 DOI: 10.1021/ja072427c

Rationally Designed Ligands that Inhibit the Aggregation of Large Gold Nanoparticles in Solution Shishan Zhang, Gyu Leem, La-ongnuan Srisombat, and T. Randall Lee pp 113–120 DOI: 10.1021/ja0724588 Supporting Info

Ion Dynamics and Water Percolation Effects in DNA Polymorphism Ivan Brovchenko, Aliaksei Krukau, Alla Oleinikova, and Alexey K. Mazur pp 121–131 DOI: 10.1021/ja0732882

Regulation Mechanism of Spin−Orbit Coupling in Charge-Transfer-Induced Luminescence of Imidazopyrazinone Derivatives Hiroshi Isobe, Syusuke Yamanaka, Seiki Kuramitsu, and Kizashi Yamaguchi pp 132–149 DOI: 10.1021/ja073834r Supporting Info

Interconvertable Modular Framework and Layered Lanthanide(III)-Etidronic Acid Coordination Polymers F. N. Shi, L. Cunha-Silva, R. A. S Ferreira, L. Mafra, T. Trindade, L. D. Carlos, F. A. Almeida Paz, and J. Rocha pp 150–167 DOI: 10.1021/ja074119k Supporting Info

Quantum Dot Fluorescence Quenching Pathways with Cr(III) Complexes. Photosensitized NO Production from trans-Cr(cyclam)(ONO)2+ Daniel Neuman, Alexis D. Ostrowski, Alexander A. Mikhailovsky, Ryan O. Absalonson, Geoffrey F. Strouse, and Peter C. Ford pp 168–175 DOI: 10.1021/ja074164s Supporting Info

Selecting Folded Proteins from a Library of Secondary Structural Elements James J. Graziano, Wenshe Liu, Roshan Perera, Bernhard H. Geierstanger, Scott A. Lesley, and Peter G. Schultz pp 176–185 DOI: 10.1021/ja074405w Supporting Info

2-(4,5,6,7-Tetrafluorobenzimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1- H-imidazole-3-oxide-1-oxyl, A Hydrogen-Bonded Organic Quasi-1D Ferromagnet Hidenori Murata, Yuji Miyazaki, Akira Inaba, Armando Paduan-Filho, Valdir Bindilatti, Nei Fernandes OliveiraJr., Zeynep Delen, and Paul M. Lahti pp 186–194 DOI: 10.1021/ja074211g Supporting Info

Enantioselective α-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel Xuebin Liao, Zhiqiang Weng, and John F. Hartwig pp 195–200 DOI: 10.1021/ja074453g Supporting Info

Design of Molecularly Ordered Framework of Mesoporous Silica with Squared One-Dimensional Channels Tatsuo Kimura, Hiroaki Tamura, Masato Tezuka, Dai Mochizuki, Tetsuro Shigeno, Tetsu Ohsuna, and Kazuyuki Kuroda pp 201–209 DOI: 10.1021/ja0744145 Supporting Info

Cyclometalated Iridium(III) Aquo Complexes:  Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water Neal D. McDaniel, Frederick J. Coughlin, Leonard L. Tinker, and Stefan Bernhard pp 210–217 DOI: 10.1021/ja074478f Supporting Info

Toward Efficient Nanoporous Catalysts:  Controlling Site-Isolation and Concentration of Grafted Catalytic Sites on Nanoporous Materials with Solvents and Colorimetric Elucidation of Their Site-Isolation Krishna K. Sharma, Abhishek Anan, Robert P. Buckley, Wayne Ouellette, and Tewodros Asefa pp 218–228 DOI: 10.1021/ja074128t Supporting Info

Two- and Three-Dimensional Smectic Ordering of Single-Handed Helical Polymers Hisanari Onouchi, Kento Okoshi, Takashi Kajitani, Shin-ichiro Sakurai, Kanji Nagai, Jiro Kumaki, Kiyotaka Onitsuka, and Eiji Yashima pp 229–236 DOI: 10.1021/ja074627u Supporting Info

Effect of ortho-SR Groups on O−H Bond Strength and H-Atom Donating Ability of Phenols:  A Possible Role for the Tyr-Cys Link in Galactose Oxidase Active Site? Riccardo Amorati, Francesca Catarzi, Stefano Menichetti, Gian Franco Pedulli, and Caterina Viglianisi pp 237–244 DOI: 10.1021/ja075554h Supporting Info

Target-Specific Chemical Acylation of Lectins by Ligand-Tethered DMAP Catalysts Yoichiro Koshi, Eiji Nakata, Masayoshi Miyagawa, Shinya Tsukiji, Tomohisa Ogawa, and Itaru Hamachi pp 245–251 DOI: 10.1021/ja075684q Supporting Info

Magnetic and Optical Bistability Driven by Thermally and Photoinduced Intramolecular Electron Transfer in a Molecular Cobalt−Iron Prussian Blue Analogue Dongfeng Li, Rodolphe Clérac, Olivier Roubeau, Etienne Harté, Corine Mathonière, Rémy Le Bris, and Stephen M. Holmes pp 252–258 DOI: 10.1021/ja0757632 Supporting Info

Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands:  A Case of Non-innocence in Organometallic Chemistry Jörg Maurer, Michael Linseis, Biprajit Sarkar, Brigitte Schwederski, Mark Niemeyer, Wolfgang Kaim, Stanislav Záliš, Chris Anson, Manfred Zabel, and Rainer F. Winter pp 259–268 DOI: 10.1021/ja075547t Supporting Info

Gold(I)-Catalyzed Intramolecular [4+2] Cycloadditions of Arylalkynes or 1,3-Enynes with Alkenes:  Scope and Mechanism Cristina Nieto-Oberhuber, Patricia Pérez-Galán, Elena Herrero-Gómez, Thorsten Lauterbach, Cristina Rodríguez, Salomé López, Christophe Bour, Antonio Rosellón, Diego J. Cárdenas, and Antonio M. Echavarren pp 269–279 DOI: 10.1021/ja075794x Supporting Info

Synthesis and Magnetic Investigation of Ordered Mesoporous Two-Line Ferrihydrite Harun Tüysüz, Elena Lorena Salabaş, Claudia Weidenthaler, and Ferdi Schüth pp 280–287 DOI: 10.1021/ja075528j Supporting Info

Tuning the Structural and Physical Properties of Cr2Ti3Se8 by Lithium Intercalation:  A Study of the Magnetic Properties, Investigation of Ion Mobility with NMR Spectroscopy and Electronic Band Structure Calculations Joseph Wontcheu, Wolfgang Bensch, Martin Wilkening, Paul Heitjans, Sylvio Indris, Paul Sideris, Clare P. Grey, Sergiy Mankovsky, and Hubert Ebert pp 288–299 DOI: 10.1021/ja076082+

Total Synthesis of (±)-Merrilactone A Wei He, Jie Huang, Xiufeng Sun, and Alison J. Frontier pp 300–308 DOI: 10.1021/ja0761986 Supporting Info

2D Correlation Deep UV Resonance Raman Spectroscopy of Early Events of Lysozyme Fibrillation:  Kinetic Mechanism and Potential Interpretation Pitfalls Victor A. Shashilov and Igor K. Lednev pp 309–317 DOI: 10.1021/ja076225s Supporting Info

Charge Transport in Single Au | Alkanedithiol | Au Junctions:  Coordination Geometries and Conformational Degrees of Freedom Chen Li, Ilya Pobelov, Thomas Wandlowski, Alexei Bagrets, Andreas Arnold, and Ferdinand Evers pp 318–326 DOI: 10.1021/ja0762386 Supporting Info

Synthesis and Use of Mechanism-Based Protein-Profiling Probes for Retaining β-d-Glucosaminidases Facilitate Identification of Pseudomonas aeruginosa NagZ Keith A. Stubbs, Adrian Scaffidi, Aleksandra W. Debowski, Brian L. Mark, Robert V. Stick, and David J. Vocadlo pp 327–335 DOI: 10.1021/ja0763605 Supporting Info

Pyrene Excimer Signaling Molecular Beacons for Probing Nucleic Acids Patrick Conlon, Chaoyong James Yang, Yanrong Wu, Yan Chen, Karen Martinez, Youngmi Kim, Nathan Stevens, Angel A. Marti, Steffen Jockusch, Nicholas J. Turro, and Weihong Tan pp 336–342 DOI: 10.1021/ja076411y

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons Chungen Liang, Florence Collet, Fabien Robert-Peillard, Paul Müller, Robert H. Dodd, and Philippe Dauban pp 343–350 DOI: 10.1021/ja076519d Supporting Info

Residue-Specific Radical-Directed Dissociation of Whole Proteins in the Gas Phase Tony Ly and Ryan R. Julian pp 351–358 DOI: 10.1021/ja076535a Supporting Info

Dipolar Chemical Shift Correlation Spectroscopy for Homonuclear Carbon Distance Measurements in Proteins in the Solid State:  Application to Structure Determination and Refinement Xiaohu Peng, David Libich, Rafal Janik, George Harauz, and Vladimir Ladizhansky pp 359–369 DOI: 10.1021/ja076658v Supporting Info

Small Au and Pt Clusters at the Anatase TiO2(101) Surface:  Behavior at Terraces, Steps, and Surface Oxygen Vacancies Xue-Qing Gong, Annabella Selloni, Olga Dulub, Peter Jacobson, and Ulrike Diebold pp 370–381 DOI: 10.1021/ja0773148

Hydroboration and Organic Synthesis:  9-Borabicyclo[3.3.1]nonane (9-BBN) By Ranjit S. Dhillon (Punjab Agricultural University, Ludhiana, India). Springer:  Berlin, Heidelberg, New York. 2007. xiv + 586 pp. $269.00. ISBN 978-3-540-49075-3. p 382 DOI: 10.1021/ja077003x

CRC Handbook of Chemistry and Physics, 88th ed Editor-in-Chief:  David R. Lide (National Institute of Standards and Technology) CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2007. 2640 pp. $139.95. ISBN 0-8493-0488-1. p 382 DOI: 10.1021/ja077011d

Explosives:  Completely Revised 6th ed By Rudolf Meyer (formerly of WASAG Chemie, Essen, Germany), Josef Köhler (Schardenberg, Austria), and Axel Homburg (Dynamit Nobel GmbH, Troisdorf, Germany). Wiley-VCH Verlag GmbH:  Weinheim. 2007.viii + 422 pp. $240. ISBN 978-3-527- 31656-4. p 382 DOI: 10.1021/ja0770126

Analytical Methods in Supramolecular Chemistry Edited by Christoph A. Schalley (Universität Berlin). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2007. xvi + 484 pp. $190.00. ISBN 978-3-527-31505-5. Christian Detellier pp 382–383 DOI: 10.1021/ja0769649

Spectroscopy in Catalysis:  An Introduction, Third, Completely Revised and Enlarged Edition By J. W. Niemantsverdriet (Eindhoven University of Technology, The Netherlands). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xviii + 326 pp. $135. ISBN 978-3-527-31651-9. Susannah L. Scott p 383 DOI: 10.1021/ja0770072

Fullerenes:  Principles and Applications Edited by Fernando Langa (University of Castilla La Mancha, Toledo, Spain) and Jean-François Nierengarten (CNRS, Toulouse, France). Royal Society of Chemistry:  Cambridge. 2007. xii + 398 pp. $169. ISBN 978-0-85404-551-8. W. E. Billups pp 383–384 DOI: 10.1021/ja076974+

Methods and Reagents for Green Chemistry:  An Introduction Edited by Pietro Tundo, Alvise Perosa, and Fulvio Zecchini (The Ca' Foscari University of Venise and National Interuniversity Consortium, “Chemistry for the Environment”, Venice, Italy). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xviii + 314 pp. $100. ISBN 978-0-471-75400-8. James Mack p 384 DOI: 10.1021/ja076991z

Issue 02

Locking of Helicity and Shape Complementarity in Diarylethene Dimers on Graphite Nathalie Katsonis, Andrea Minoia, Tibor Kudernac, Toshiki Mutai, Hong Xu, Hiroshi Uji-i, Roberto Lazzaroni, Steven De Feyter, and Ben L. Feringa pp 386–387 DOI: 10.1021/ja075917d Supporting Info

Microwave-Assisted Palladium(0)-Catalyzed Alkylative Cyclization of Allenyl Aldehydes Leading to 3-Substituted 3-Cycloalken-1-ols Hirokazu Tsukamoto, Tomotaka Matsumoto, and Yoshinori Kondo pp 388–389 DOI: 10.1021/ja076080p Supporting Info

Dithiabenzisapphyrin:  A Core-Modified Sapphyrin Bearing Exocyclic Double Bonds at the meso-Positions Seung-Doo Jeong, Jonathan L. Sessler, Vincent Lynch, and Chang-Hee Lee pp 390–391 DOI: 10.1021/ja075800p Supporting Info

Cation−Cation π−π Stacking in Small Ionic Clusters of 1,2,4-Triazolium Hui Li, Jerry A. Boatz, and Mark S. Gordon pp 392–393 DOI: 10.1021/ja076406u

1-Hexene Isomerization over Sulfated Mesoporous Ta Oxide:  The Effects of Active Site and Confinement Yuxiang Rao, Junjie Kang, and David Antonelli pp 394–395 DOI: 10.1021/ja076584n Supporting Info

Isomagnetophoresis to Discriminate Subtle Difference in Magnetic Susceptibility Joo H. Kang, Sungyoung Choi, Wonhye Lee, and Je-Kyun Park pp 396–397 DOI: 10.1021/ja0770678 Supporting Info

Enantioselective Organo-SOMO Catalysis:  The α-Vinylation of Aldehydes Hahn Kim and David W. C. MacMillan pp 398–399 DOI: 10.1021/ja077212h Supporting Info

High Gas Storage Capacities for Ionic Liquids through Chemical Complexation Daniel J. Tempel, Philip B. Henderson, Jeffrey R. Brzozowski, Ronald M. Pearlstein, and Hansong Cheng pp 400–401 DOI: 10.1021/ja077233b Supporting Info

Programming Multiple Protein Patterns on a Single DNA Nanostructure Justin D. Cohen, John P. Sadowski, and Peter B. Dervan pp 402–403 DOI: 10.1021/ja0772400 Supporting Info

An Enantioselective Organocatalytic Oxidative Dearomatization Strategy Ngoc T. Vo, Robert D. M. Pace, Fionn O'Hara, and Matthew J. Gaunt pp 404–405 DOI: 10.1021/ja077457u Supporting Info

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks Krista S. Walton, Andrew R. Millward, David Dubbeldam, Houston Frost, John J. Low, Omar M. Yaghi, and Randall Q. Snurr pp 406–407 DOI: 10.1021/ja076595g Supporting Info

[2,3-13C]-labeling of Aromatic ResiduesGetting a Head Start in the Magic-Angle-Spinning NMR Assignment of Membrane Proteins Matthias Hiller, Victoria A. Higman, Stefan Jehle, Barth-Jan van Rossum, Werner Kühlbrandt, and Hartmut Oschkinat pp 408–409 DOI: 10.1021/ja077589n Supporting Info

Potentiometric Detection of DNA Hybridization Apon Numnuam, Karin Y. Chumbimuni-Torres, Yun Xiang, Ralph Bash, Panote Thavarungkul, Proespichaya Kanatharana, Ernö Pretsch, Joseph Wang, and Eric Bakker pp 410–411 DOI: 10.1021/ja0775467 Supporting Info

A Pre-RNA Candidate Revisited:  Both Enantiomers of Flexible Nucleoside Triphosphates are DNA Polymerase Substrates Benjamin D. Heuberger and Christopher Switzer pp 412–413 DOI: 10.1021/ja0770680 Supporting Info

Unexpected Fractionation in Site-Specific 13C Isotopic Distribution Detected by Quantitative 13C NMR at Natural Abundance Eliot P. Botosoa, Elsa Caytan, Virginie Silvestre, Richard J. Robins, Serge Akoka, and Gérald S. Remaud pp 414–415 DOI: 10.1021/ja0771181

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals Chen Zhang, Chandra Kanta De, Rudrajit Mal, and Daniel Seidel pp 416–417 DOI: 10.1021/ja077473r Supporting Info

Enantioselective, NHC-Catalyzed Bicyclo-β-Lactam Formation via Direct Annulations of Enals and Unsaturated N-Sulfonyl Ketimines Ming He and Jeffrey W. Bode pp 418–419 DOI: 10.1021/ja0778592 Supporting Info

Direct Coupling of Catharanthine and Vindoline to Provide Vinblastine:  Total Synthesis of (+)- and ent-(−)-Vinblastine Hayato Ishikawa, David A. Colby, and Dale L. Boger pp 420–421 DOI: 10.1021/ja078192m Supporting Info

Total Syntheses of the Assigned Structures of Lituarines B and C Amos B. Smith, III, Matthew O. Duffey, Kallol Basu, Shawn P. Walsh, Hans W. Suennemann, and Michael Frohn pp 422–423 DOI: 10.1021/ja078293k Supporting Info

Enzymatic Oxidation of H2 in Atmospheric O2:  The Electrochemistry of Energy Generation from Trace H2 by Aerobic Microorganisms James A. Cracknell, Kylie A. Vincent, Marcus Ludwig, Oliver Lenz, Bärbel Friedrich, and Fraser A. Armstrong pp 424–425 DOI: 10.1021/ja078299+

Tri-tert-butylsilylsilylenes with Alkali Metal Substituents (tBu3Si)SiM (M = Li, K):  Electronically and Sterically Accessible Triplet Ground States Akira Sekiguchi, Takashi Tanaka, Masaaki Ichinohe, Kimio Akiyama, and Peter P. Gaspar pp 426–427 DOI: 10.1021/ja077628v Supporting Info

Geosmin Biosynthesis. Mechanism of the Fragmentation−Rearrangement in the Conversion of Germacradienol to Geosmin Jiaoyang Jiang and David E. Cane pp 428–429 DOI: 10.1021/ja077792i Supporting Info

Identification of (8S,9S,10S)-8,10-Dimethyl-1-octalin, a Key Intermediate in the Biosynthesis of Geosmin in Bacteria Thorben Nawrath, Jeroen S. Dickschat, Rolf Müller, Jiaoyang Jiang, David E. Cane, and Stefan Schulz pp 430–431 DOI: 10.1021/ja077790y Supporting Info

Evaluation of the Functional Role of the Heme-6-propionate Side Chain in Cytochrome P450cam Katsuyoshi Harada, Keisuke Sakurai, Kenichiro Ikemura, Takashi Ogura, Shun Hirota, Hideo Shimada, and Takashi Hayashi pp 432–433 DOI: 10.1021/ja077902l Supporting Info

Fundamental Electron-Transfer Properties of Non-heme Oxoiron(IV) Complexes Yong-Min Lee, Hiroaki Kotani, Tomoyoshi Suenobu, Wonwoo Nam, and Shunichi Fukuzumi pp 434–435 DOI: 10.1021/ja077994e Supporting Info

A Single-Molecule Assay to Directly Identify Solvent-Accessible Disulfide Bonds and Probe Their Effect on Protein Folding Sri Rama Koti Ainavarapu, Arun P. Wiita, Hector H. Huang, and Julio M. Fernandez pp 436–437 DOI: 10.1021/ja077851s Supporting Info

Synthesis and Characterization of meso-Aryl-Substituted Subchlorins Eiji Tsurumaki, Shohei Saito, Kil Suk Kim, Jong Min Lim, Yasuhide Inokuma, Dongho Kim, and Atsuhiro Osuka pp 438–439 DOI: 10.1021/ja078042b Supporting Info

A Strategy to Discover Inhibitors of O-Linked Glycosylation Benjamin J. Gross, Jonathan G. Swoboda, and Suzanne Walker pp 440–441 DOI: 10.1021/ja078125s Supporting Info

Highly Efficient, Living Coordinative Chain-Transfer Polymerization of Propene with ZnEt2:  Practical Production of Ultrahigh to Very Low Molecular Weight Amorphous Atactic Polypropenes of Extremely Narrow Polydispersity Wei Zhang and Lawrence R. Sita pp 442–443 DOI: 10.1021/ja078120v Supporting Info

Biodegradable pH-Sensing Dendritic Nanoprobes for Near-Infrared Fluorescence Lifetime and Intensity Imaging Adah Almutairi, Steven J. Guillaudeu, Mikhail Y. Berezin, Samuel Achilefu, and Jean M. J. Fréchet pp 444–445 DOI: 10.1021/ja078147e Supporting Info

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents Yunmi Lee, Katsuhiro Akiyama, Dennis G. Gillingham, M. Kevin Brown, and Amir H. Hoveyda pp 446–447 DOI: 10.1021/ja0782192 Supporting Info

Iron(II)-Templated Synthesis of [3]Rotaxanes by Passing Two Threads through the Same Ring Alexander I. Prikhod'ko, Fabien Durola, and Jean-Pierre Sauvage pp 448–449 DOI: 10.1021/ja078216p Supporting Info

Nanorods of Endohedral Metallofullerene Derivative Takahiro Tsuchiya, Ryotaro Kumashiro, Katsumi Tanigaki, Yoichiro Matsunaga, Midori O. Ishitsuka, Takatsugu Wakahara, Yutaka Maeda, Yuta Takano, Motoki Aoyagi, Takeshi Akasaka, Michael T. H. Liu, Tatsuhisa Kato, Kazutomo Suenaga, Jong S. Jeong, Sumio Iijima, Fumiko Kimura, Tsunehisa Kimura, and Shigeru Nagase pp 450–451 DOI: 10.1021/ja710396n Supporting Info

Transition-Metal-Free Synthesis of Poly(phenylene Ethynylene)s with Alternating Aryl-Perfluoroaryl Units Tanmoy Dutta, Kathy B. Woody, and Mark D. Watson pp 452–453 DOI: 10.1021/ja710564b Supporting Info

Detection of an η1-Alkene Intermediate of the Type [Cp2Zr(Me)(η1-alkene)]+:  The Role of Such Species in Metallocene Catalyst Deactivation to Allylic Species Mihaela Vatamanu, Goran Stojcevic, and Michael C. Baird pp 454–456 DOI: 10.1021/ja0742683 Supporting Info

Liposome Encapsulation of Conjugated Polyelectrolytes:  Toward a Liposome Beacon An Thien Ngo, Pierre Karam, Elisa Fuller, Melanie Burger, and Gonzalo Cosa pp 457–459 DOI: 10.1021/ja076217b Supporting Info

Chloride Anion Controlled Molecular “Switching”. Binding of 2,5,7-Trinitro-9-dicyanomethylenefluorene-C60 by Tetrathiafulvalene Calix[4]pyrrole and Photophysical Generation of Two Different Charge-Separated States Kent A. Nielsen, Ginka H. Sarova, Luis Martín-Gomis, Fernando Fernndez-Lzaro, Paul C. Stein, Lionel Sanguinet, Eric Levillain, Jonathan L. Sessler, Dirk M. Guldi, Ángela Sastre-Santos, and Jan O. Jeppesen pp 460–462 DOI: 10.1021/ja0772243 Supporting Info

Intramolecular Crosslinking of an Optically Inactive 310-Helical Peptide:  Stabilization of Structure and Helix Sense Naoki Ousaka, Tomohiro Sato, and Reiko Kuroda pp 463–465 DOI: 10.1021/ja077857h Supporting Info

Simple, Efficient, and Modular Syntheses of Polyene Natural Products via Iterative Cross-Coupling Suk Joong Lee, Kaitlyn C. Gray, James S. Paek, and Martin D. Burke pp 466–468 DOI: 10.1021/ja078129x Supporting Info

Fully Intermolecular Nickel-Catalyzed Three-Component Couplings via Internal Redox Ananda Herath, Wei Li, and John Montgomery pp 469–471 DOI: 10.1021/ja0781846 Supporting Info

Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP−Zn−ate):  New Approaches to Multisubstituted Benzenes Masanobu Uchiyama, Yuri Kobayashi, Taniyuki Furuyama, Shinji Nakamura, Yumiko Kajihara, Tomoko Miyoshi, Takao Sakamoto, Yoshinori Kondo, and Keiji Morokuma pp 472–480 DOI: 10.1021/ja071268u Supporting Info

31P Magic Angle Spinning NMR Spectroscopy of Paramagnetic Rare-Earth-Substituted Keggin and Wells−Dawson Solids Wenlin Huang, Mark Schopfer, Cheng Zhang, Robertha C. Howell, Louis Todaro, Becky A. Gee, Lynn C. Francesconi, and Tatyana Polenova pp 481–490 DOI: 10.1021/ja0714585 Supporting Info

Sequence-Specific, Dynamic Covalent Crosslinking in Aqueous Media Minfeng Li, Kazuhiro Yamato, Joseph S. Ferguson, Kiran Kumar Singarapu, Thomas Szyperski, and Bing Gong pp 491–500 DOI: 10.1021/ja072567m Supporting Info

Chemical Synthesis of a Glycoprotein Having an Intact Human Complex-Type Sialyloligosaccharide under the Boc and Fmoc Synthetic Strategies Naoki Yamamoto, Yasutaka Tanabe, Ryo Okamoto, Philip E. Dawson, and Yasuhiro Kajihara pp 501–510 DOI: 10.1021/ja072543f Supporting Info

Addition of Alkyl Radicals to Transition-Metal-Coordinated CO:  Calculation of the Reaction of [Ru(CO)5] and Related Complexes and Relevance to Alkane Carbonylation Faraj Hasanayn, Nadeen H. Nsouli, Adnan Al-Ayoubi, and Alan S. Goldman pp 511–521 DOI: 10.1021/ja072704f Supporting Info

Induced-Fit in the Gas Phase:  Conformational Effects on the Enantioselectivity of Chiral Tetra-Amide Macrocycles Francesco Gasparrini, Marco Pierini, Claudio Villani, Antonello Filippi, and Maurizio Speranza pp 522–534 DOI: 10.1021/ja073287+ Supporting Info

Rapid Protein−Ligand Costructures Using Chemical Shift Perturbations Jaime Stark and Robert Powers pp 535–545 DOI: 10.1021/ja0737974

ENDOR Characterization of a Synthetic Diiron Hydrazido Complex as a Model for Nitrogenase Intermediates Nicholas S. Lees, Rebecca L. McNaughton, Wilda Vargas Gregory, Patrick L. Holland, and Brian M. Hoffman pp 546–555 DOI: 10.1021/ja073934x Supporting Info

A Combinatorial Method for Solution-Phase Synthesis of Labeled Bivalent β-Turn Mimics Yu Angell, Dianjun Chen, Fouad Brahimi, H. Uri Saragovi, and Kevin Burgess pp 556–565 DOI: 10.1021/ja074717z Supporting Info

OFF−OFF−ON Switching of Fluorescence and Electron Transfer Depending on Stepwise Complex Formation of a Host Ligand with Guest Metal Ions Junpei Yuasa and Shunichi Fukuzumi pp 566–575 DOI: 10.1021/ja0748480 Supporting Info

Structure and Magnetism of Dinuclear Copper(II) Metallacyclophanes with Oligoacenebis(oxamate) Bridging Ligands:  Theoretical Predictions on Wirelike Magnetic Coupling Emilio Pardo, Rosa Carrasco, Rafael Ruiz-García, Miguel Julve, Francesc Lloret, M. Carmen Muñoz, Yves Journaux, Eliseo Ruiz, and Joan Cano pp 576–585 DOI: 10.1021/ja0747066 Supporting Info

Hierarchical Self-Assembly of Aminopyrazole Peptides into Nanorosettes in Water Petra Rzepecki, Katrin Hochdörffer, Torsten Schaller, Jan Zienau, Klaus Harms, Christian Ochsenfeld, Xiulan Xie, and Thomas Schrader pp 586–591 DOI: 10.1021/ja0744807 Supporting Info

Reversibility Effects on the Stereoselectivity of Pt(II)-Mediated Cascade Poly-ene Cyclizations Jeremiah A. Feducia and Michel R. Gagné pp 592–599 DOI: 10.1021/ja075518i Supporting Info

Complexation-Induced Transition of Nanorod to Network Aggregates:  Alternate Porphyrin and Cyclodextrin Arrays Yu Liu, Chen-Feng Ke, Heng-Yi Zhang, Jie Cui, and Fei Ding pp 600–605 DOI: 10.1021/ja075981v Supporting Info

Insight into the Mechanisms of Cooperative Self-Assembly:  The “Sergeants-and-Soldiers” Principle of Chiral and Achiral C3-Symmetrical Discotic Triamides Maarten M. J. Smulders, Albertus P. H. J. Schenning, and E. W. Meijer pp 606–611 DOI: 10.1021/ja075987k Supporting Info

Origins of Selectivity for the [2+2] Cycloaddition of α,β-unsaturated Ketones within a Porous Self-assembled Organic Framework Jun Yang, Mahender B. Dewal, Salvatore Profeta, Jr., Mark D. Smith, Youyong Li, and Linda S. Shimizu pp 612–621 DOI: 10.1021/ja076001+ Supporting Info

Reactivity of Hydrogen with Solid-State Films of Alkylamine- and Tetraoctylammonium Bromide-Stabilized Pd, PdAg, and PdAu Nanoparticles for Sensing and Catalysis Applications Francisco J. Ibañez and Francis P. Zamborini pp 622–633 DOI: 10.1021/ja076000h Supporting Info

Electrochemistry and Electrogenerated Chemiluminescence of 3,6-Di(spirobifluorene)-N-phenylcarbazole Sahar Rashidnadimi, Tsung Hsi Hung, Ken-Tsung Wong, and Allen J. Bard pp 634–639 DOI: 10.1021/ja076033x Supporting Info

Verification of Biochemical Activity for Proteins Nanografted on Gold Surfaces Cristian Staii, David W. Wood, and Giacinto Scoles pp 640–646 DOI: 10.1021/ja076157+

Discovery and Mechanistic Study of AlIII-Catalyzed Transamidation of Tertiary Amides Justin M. Hoerter, Karin M. Otte, Samuel H. Gellman, Qiang Cui, and Shannon S. Stahl pp 647–654 DOI: 10.1021/ja0762994 Supporting Info

Synthesis and Redox Behavior of Flavin Mononucleotide-Functionalized Single-Walled Carbon Nanotubes Sang-Yong Ju and Fotios Papadimitrakopoulos pp 655–664 DOI: 10.1021/ja076598t Supporting Info

Mechanism and Control of Rare Tautomer Trapping at a Metal−Metal Bond:  Adenine Binding to Dirhodium Antitumor Agents1 Dirk V. Deubel pp 665–675 DOI: 10.1021/ja076603t Supporting Info

X-Ray Absorption Spectroscopic and Theoretical Studies on (L)2[Cu2(S2)n]2+ Complexes:  Disulfide versus Disulfide(•1−) Bonding Ritimukta Sarangi, John T. York, Matthew E. Helton, Kiyoshi Fujisawa, Kenneth D. Karlin, William B. Tolman, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 676–686 DOI: 10.1021/ja0762745 Supporting Info

Temperature Triggered Self-Assembly of Polypeptides into Multivalent Spherical Micelles Matthew R. Dreher, Andrew J. Simnick, Karl Fischer, Richard J. Smith, Anand Patel, Manfred Schmidt, and Ashutosh Chilkoti pp 687–694 DOI: 10.1021/ja0764862 Supporting Info

Two-Dimensional Supramolecular Nanopatterns Formed by the Coadsorption of Guanine and Uracil at the Liquid/Solid Interface Wael Mamdouh, Ross E. A. Kelly, Mingdong Dong, Lev N. Kantorovich, and Flemming Besenbacher pp 695–702 DOI: 10.1021/ja076832f Supporting Info

DNA−Protein Cross-links between Guanine and Lysine Depend on the Mechanism of Oxidation for Formation of C5 Vs C8 Guanosine Adducts Xiaoyun Xu, James G. Muller, Yu Ye, and Cynthia J. Burrows pp 703–709 DOI: 10.1021/ja077102a Supporting Info

Strictosidine Synthase:  Mechanism of a Pictet−Spengler Catalyzing Enzyme Justin J. Maresh, Lesley-Ann Giddings, Anne Friedrich, Elke A. Loris, Santosh Panjikar, Bernhardt L. Trout, Joachim Stöckigt, Baron Peters, and Sarah E. O'Connor pp 710–723 DOI: 10.1021/ja077190z Supporting Info

Competitive Aryl−Iodide vs Aryl−Aryl Reductive Elimination Reactions in Pt(IV) Complexes:  Experimental and Theoretical Studies Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok, and Andrei N. Vedernikov pp 724–731 DOI: 10.1021/ja077258a Supporting Info

Toward a Rational Design of Poly(2,7-Carbazole) Derivatives for Solar Cells Nicolas Blouin, Alexandre Michaud, David Gendron, Salem Wakim, Emily Blair, Rodica Neagu-Plesu, Michel Belletête, Gilles Durocher, Ye Tao, and Mario Leclerc pp 732–742 DOI: 10.1021/ja0771989 Supporting Info

Synthesis and Conformational Studies of γ−Aminoxy Peptides Fei Chen, Ke-Sheng Song, Yun-Dong Wu, and Dan Yang pp 743–755 DOI: 10.1021/ja0772750 Supporting Info

Budding and Asymmetric Protein Microcompartmentation in Giant Vesicles Containing Two Aqueous Phases M. Scott Long, Ann-Sofie Cans, and Christine D. Keating pp 756–762 DOI: 10.1021/ja077439c Supporting Info

Oxidative Diamination of Alkenes with Ureas as Nitrogen Sources:  Mechanistic Pathways in the Presence of a High Oxidation State Palladium Catalyst Kilian Muñiz, Claas H. Hövelmann, and Jan Streuff pp 763–773 DOI: 10.1021/ja075041a Supporting Info

Simple and Effective 3D Recognition of Domoic Acid Using a Molecularly Imprinted Polymer [J. Am. Chem. Soc. 2007, 129, 13626−13632]. Koji Nemoto, Takuya Kubo, Makoto Nomachi, Tomoharu Sano, Takatoshi Matsumoto, Ken Hosoya, Tetsutaro Hattori, and Kunimitsu Kaya p 774 DOI: 10.1021/ja7106788

Mathematica 6.0 Wolfram Research, Inc., 100 Trade Center Drive, Champaign, IL 61820-7237. www.wolfram.com. See Web site for pricing information. Graeme Henkelman p 775 DOI: 10.1021/ja0769898

Bioactive Conformation I Edited by T. Peters (University of Lübeck, Germany). From the series:  Topics in Current Chemistry, 272. Springer:  Berlin, Heidelberg, New York. 2007. xii + 310 pp. $299.00. ISBN 978-3-540-49077-7. T. B. Grindley p 776 DOI: 10.1021/ja076948b

Modern Aspects of Electrochemistry, No. 41 Edited by Constantinos Vayenas (University of Patras, Greece), Ralph E. White (University of South Carolina), and Maria E. Gamboa-Adelco (Superior, CO). Springer Science + Business Media, LLC:  New York. 2007. xii + 308 pp. $139.00. ISBN 978-0-387-46107-6. Andrew C. Hillier pp 776–777 DOI: 10.1021/ja0769752

Nanobiotechnology II:  More Concepts and Applications Edited by Chad A. Mirkin (Northwestern University) and Christof M. Niemeyer (University of Dortmund). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xxvi + 432 pp. $190. ISBN 978-3-527-31673-1. Nicholas A. Peppas pp 777–778 DOI: 10.1021/ja076961w

Issue 03

Photovoltaic Charge Generation Visualized at the Nanoscale:  A Proof of Principle Andrea Liscio, Giovanna De Luca, Fabian Nolde, Vincenzo Palermo, Klaus Müllen, and Paolo Samorì pp 780–781 DOI: 10.1021/ja075291r Supporting Info

[Te2As2]2-:  A Planar Motif with “Conflicting” Aromaticity Angel Ugrinov, Ayusman Sen, Arthur C. Reber, Meichun Qian, and Shiv N. Khanna pp 782–783 DOI: 10.1021/ja075513l Supporting Info

Selective Fluorescent Chemosensor for the Bacterial Alarmone (p)ppGpp Hyun-Woo Rhee, Chang-Ro Lee, Seung-Hyon Cho, Mi-Ryung Song, Michael Cashel, Hyon E. Choy, Young-Jae Seok, and Jong-In Hong pp 784–785 DOI: 10.1021/ja0759139 Supporting Info

Probing Mode and Site of Substrate Water Binding to the Oxygen-Evolving Complex in the S2 State of Photosystem II by 17O-HYSCORE Spectroscopy Ji-Hu Su, Wolfgang Lubitz, and Johannes Messinger pp 786–787 DOI: 10.1021/ja076620i Supporting Info

Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand Mark R. Ringenberg, Swarna Latha Kokatam, Zachariah M. Heiden, and Thomas B. Rauchfuss pp 788–789 DOI: 10.1021/ja076801k Supporting Info

Trading Templates:  Supramolecular Transformations between {CoII13} and {CoII12} Nanoclusters Graham N. Newton, Geoffrey J. T. Cooper, Paul Kögerler, De-Liang Long, and Leroy Cronin pp 790–791 DOI: 10.1021/ja0768183 Supporting Info

Time-Programmed Peptide Helix Inversion of a Synthetic Metal Complex Triggered by an Achiral NO3- Anion Hiroyuki Miyake, Hiroshi Kamon, Ikuko Miyahara, Hideki Sugimoto, and Hiroshi Tsukube pp 792–793 DOI: 10.1021/ja0768385 Supporting Info

Paramagnetic Relaxation-Based 19F MRI Probe To Detect Protease Activity Shin Mizukami, Rika Takikawa, Fuminori Sugihara, Yuichiro Hori, Hidehito Tochio, Markus Wälchli, Masahiro Shirakawa, and Kazuya Kikuchi pp 794–795 DOI: 10.1021/ja077058z Supporting Info

Balancing Conformational and Oxidative Kinetic Traps during the Folding of Bovine Pancreatic Trypsin Inhibitor (BPTI) with Glutathione and Glutathione Disulfide Farhana M. Kibria and Watson J. Lees pp 796–797 DOI: 10.1021/ja077468n Supporting Info

Size Limitations for the Formation of Ordered Striped Nanoparticles Randy P. Carney, Gretchen A. DeVries, Cedric Dubois, Hyewon Kim, Jin Young Kim, Chetana Singh, Pradip K. Ghorai, Joseph B. Tracy, Rebecca L. Stiles, Royce W. Murray, Sharon C. Glotzer, and Francesco Stellacci pp 798–799 DOI: 10.1021/ja077383m Supporting Info

Low-Level Self-Assembly of Open Framework Based on Three Different Polyhedra:  Metal-Organic Analogue of Face-Centered Cubic Dodecaboride Hyungphil Chun pp 800–801 DOI: 10.1021/ja0776778 Supporting Info

Efficient Control of π-Alkyne and Vinylidene Complex Pathways for the W(CO)5(L)-Catalyzed Synthesis of Two Types of Nitrogen-Containing Bicyclic Compounds Yuji Onizawa, Hiroyuki Kusama, and Nobuharu Iwasawa pp 802–803 DOI: 10.1021/ja0782605 Supporting Info

Total Synthesis and Structural Revision of the Marine Macrolide Neopeltolide Daniel W. Custar, Thomas P. Zabawa, and Karl A. Scheidt pp 804–805 DOI: 10.1021/ja710080q Supporting Info

Matrix Isolation Chemistry in a Porous Metal−Organic Framework:  Photochemical Substitutions of N2 and H2 in Zn4O[(η6-1,4-Benzenedicarboxylate)Cr(CO)3]3 Steven S. Kaye and Jeffrey R. Long pp 806–807 DOI: 10.1021/ja7102108 Supporting Info

Catalytic Asymmetric Hydrogenation of 2,3,5-Trisubstituted Pyrroles Ryoichi Kuwano, Manabu Kashiwabara, Masato Ohsumi, and Hiroki Kusano pp 808–809 DOI: 10.1021/ja7102422 Supporting Info

The Catalytic Asymmetric Total Synthesis of Elatol David E. White, Ian C. Stewart, Robert H. Grubbs, and Brian M. Stoltz pp 810–811 DOI: 10.1021/ja710294k Supporting Info

An Efficient Protocol of Iridium-Catalyzed Allylic Substitution Reaction and Its Application to Polymer Synthesis:  Complementary Regio- and Stereoselective Allylation Polycondensation via Ir and Pd Catalyses Nobuyoshi Nomura, Susumu Komiyama, Hiroyuki Kasugai, and Marie Saba pp 812–814 DOI: 10.1021/ja076019k Supporting Info

Simulation of the Pressure and Temperature Folding/Unfolding Equilibrium of a Small RNA Hairpin Angel E. Garcia and Dietmar Paschek pp 815–817 DOI: 10.1021/ja074191i Supporting Info

A Single-Molecule Nanopore Device Detects DNA Polymerase Activity with Single-Nucleotide Resolution Scott L. Cockroft, John Chu, Manuel Amorin, and M. Reza Ghadiri pp 818–820 DOI: 10.1021/ja077082c Supporting Info

Toward β-Amino Acid Proteins:  Design, Synthesis, and Characterization of a Fifteen Kilodalton β-Peptide Tetramer E. James Petersson and Alanna Schepartz pp 821–823 DOI: 10.1021/ja077245x Supporting Info

Tunable Plasmonic Response from Alkanethiolate-Stabilized Gold Nanoparticle Superlattices:  Evidence of Near-Field Coupling Chi-Fan Chen, Shien-Der Tzeng, Hung-Ying Chen, Kuan-Jiuh Lin, and Shangjr Gwo pp 824–826 DOI: 10.1021/ja0773610 Supporting Info

Detection and Mechanistic Relevance of Transient Ligand Radicals Formed during [Ru(bpy)2(OH2)]2O4+-Catalyzed Water Oxidation Jonathan L. Cape and James K. Hurst pp 827–829 DOI: 10.1021/ja077276s Supporting Info

Direct Observation of the Preference of Hole Transfer over Electron Transfer for Radical Ion Pair Recombination in Donor−Bridge−Acceptor Molecules Zachary E. X. Dance, Michael J. Ahrens, Amy M. Vega, Annie Butler Ricks, David W. McCamant, Mark A. Ratner, and Michael R. Wasielewski pp 830–832 DOI: 10.1021/ja077386z Supporting Info

Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes:  Efficient Synthesis of Ynamides Tetsuya Hamada, Xuan Ye, and Shannon S. Stahl pp 833–835 DOI: 10.1021/ja077406x Supporting Info

Coordinative Self-Assembly and Solution-Phase X-ray Structural Characterization of Cavity-Tailored Porphyrin Boxes Suk Joong Lee, Karen L. Mulfort, Xiaobing Zuo, Andrew J. Goshe, Paul J. Wesson, SonBinh T. Nguyen, Joseph T. Hupp, and David M. Tiede pp 836–838 DOI: 10.1021/ja077661h Supporting Info

A New Family of Multiferrocene Complexes with Enhanced Control of Structure and Stoichiometry via Coordination-Driven Self-Assembly and Their Electrochemistry Hai-Bo Yang, Koushik Ghosh, Yue Zhao, Brian H. Northrop, Matthew M. Lyndon, David C. Muddiman, Henry S. White, and Peter J. Stang pp 839–841 DOI: 10.1021/ja710349j Supporting Info

l-Enantiomers of Transition State Analogue Inhibitors Bound to Human Purine Nucleoside Phosphorylase Agnes Rinaldo-Matthis, Andrew S. Murkin, Udupi A. Ramagopal, Keith Clinch, Simon P. H. Mee, Gary B. Evans, Peter C. Tyler, Richard H. Furneaux, Steven C. Almo, and Vern L. Schramm pp 842–844 DOI: 10.1021/ja710733g Supporting Info

Intermolecular Interaction-Induced Hierarchical Transformation in 1D Nanohybrids:  Analysis of Conformational Changes by 2D Correlation Spectroscopy Ho Seok Park, Yeong Suk Choi, Young Mee Jung, and Won Hi Hong pp 845–852 DOI: 10.1021/ja073074k Supporting Info

The Reaction Mechanism of the Hydroamination of Alkenes Catalyzed by Gold(I)−Phosphine:  The Role of the Counterion and the N-Nucleophile Substituents in the Proton-Transfer Step Gábor Kovács, Gregori Ujaque, and Agustí Lledós pp 853–864 DOI: 10.1021/ja073578i Supporting Info

Harnessing the Mechanism of Glutathione Reductase for Synthesis of Active Site Bound Metallic Nanoparticles and Electrical Connection to Electrodes Daniel Scott, Michael Toney, and Martin Muzikár pp 865–874 DOI: 10.1021/ja074660g Supporting Info

Catalysis of 3-Pyrrolidinecarboxylic Acid and Related Pyrrolidine Derivatives in Enantioselective anti-Mannich-Type Reactions:  Importance of the 3-Acid Group on Pyrrolidine for Stereocontrol Haile Zhang, Susumu Mitsumori, Naoto Utsumi, Masanori Imai, Noemi Garcia-Delgado, Maria Mifsud, Klaus Albertshofer, Paul Ha-Yeon Cheong, K. N. Houk, Fujie Tanaka, and Carlos F. Barbas, III pp 875–886 DOI: 10.1021/ja074907+ Supporting Info

Comparison of Electrical Properties of Viruses Studied by AC Capacitance Scanning Probe Microscopy Robert I. MacCuspie, Nurxat Nuraje, Sang-Yup Lee, Anne Runge, and Hiroshi Matsui pp 887–891 DOI: 10.1021/ja075244z

Metal-Coupled Folding of Cys2His2 Zinc-Finger Wenfei Li, Jian Zhang, Jun Wang, and Wei Wang pp 892–900 DOI: 10.1021/ja075302g Supporting Info

Interplay among Tetrahedrane, Butterfly Diradical, and Planar Rhombus Structures in the Chemistry of the Binuclear Iron Carbonyl Phosphinidene Complexes Fe2(CO)6(PX)2 Ioan Silaghi-Dumitrescu, Thomas E. Bitterwolf, and R. Bruce King pp 901–906 DOI: 10.1021/ja0748229

Supramolecular Isomerism, Framework Flexibility, Unsaturated Metal Center, and Porous Property of Ag(I)/Cu(I) 3,3‘,5,5‘-Tetrametyl-4,4‘-Bipyrazolate Jie-Peng Zhang and Susumu Kitagawa pp 907–917 DOI: 10.1021/ja075408b Supporting Info

Solid-State 19F NMR Spectroscopy Reveals That Trp41 Participates in the Gating Mechanism of the M2 Proton Channel of Influenza A Virus Raiker Witter, Farhod Nozirov, Ulrich Sternberg, Timothy A. Cross, Anne S. Ulrich, and Riqiang Fu pp 918–924 DOI: 10.1021/ja0754305 Supporting Info

Local Electronic Structure of Dicarba-closo-dodecarboranes C2B10H12 Timothy T. Fister, Fernando D. Vila, Gerald T. Seidler, Lukas Svec, John C. Linehan, and Julie O. Cross pp 925–932 DOI: 10.1021/ja074794u Supporting Info

Oxidations of N-(3-Indoleethyl) Cyclic Aliphatic Amines by Horseradish Peroxidase:  The Indole Ring Binds to the Enzyme and Mediates Electron-Transfer Amine Oxidation Ke-Qing Ling, Wen-Shan Li, and Lawrence M. Sayre pp 933–944 DOI: 10.1021/ja075905s Supporting Info

Quantifying Weak Hydrogen Bonding in Uracil and 4-Cyano-4‘-ethynylbiphenyl:  A Combined Computational and Experimental Investigation of NMR Chemical Shifts in the Solid State Anne-Christine Uldry, John M. Griffin, Jonathan R. Yates, Marta Pérez-Torralba, M. Dolores Santa María, Amy L. Webber, Maximus L. L. Beaumont, Ago Samoson, Rosa María Claramunt, Chris J. Pickard, and Steven P. Brown pp 945–954 DOI: 10.1021/ja075892i Supporting Info

Passivation of GaAs Nanocrystals by Chemical Functionalization Matthew C. Traub, Julie S. Biteen, Bruce S. Brunschwig, and Nathan S. Lewis pp 955–964 DOI: 10.1021/ja076034p

Formation and Characterization of Self-Organized TiO2 Nanotube Arrays by Pulse Anodization Wilaiwan Chanmanee, Apichon Watcharenwong, C. Ramannair Chenthamarakshan, Puangrat Kajitvichyanukul, Norma R. de Tacconi, and Krishnan Rajeshwar pp 965–974 DOI: 10.1021/ja076092a

Gold Nanoparticle Size Controlled by Polymeric Au(I) Thiolate Precursor Size Raymond P. Briñas, Minghui Hu, Luping Qian, Elena S. Lymar, and James F. Hainfeld pp 975–982 DOI: 10.1021/ja076333e Supporting Info

Addition of Adamantylidene to La2@C78:  Isolation and Single-Crystal X-ray Structural Determination of the Monoadducts Baopeng Cao, Hidefumi Nikawa, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Hiroshi Sawa, Zdenek Slanina, Naomi Mizorogi, and Shigeru Nagase pp 983–989 DOI: 10.1021/ja076462v Supporting Info

Syntheses, Structures, and Coordination Chemistry of Phosphole-Containing Hybrid Calixphyrins:  Promising Macrocyclic P,N2,X-Mixed Donor Ligands for Designing Reactive Transition-Metal Complexes Yoshihiro Matano, Tooru Miyajima, Noriaki Ochi, Takashi Nakabuchi, Motoo Shiro, Yoshihide Nakao, Shigeyoshi Sakaki, and Hiroshi Imahori pp 990–1002 DOI: 10.1021/ja076709o Supporting Info

Polarizing the Nazarov Cyclization:  The Impact of Dienone Substitution Pattern on Reactivity and Selectivity Wei He, Ildiko R. Herrick, Tulay A. Atesin, Patrick A. Caruana, Colleen A. Kellenberger, and Alison J. Frontier pp 1003–1011 DOI: 10.1021/ja077162g Supporting Info

Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake Shengqian Ma, Daofeng Sun, Jason M. Simmons, Christopher D. Collier, Daqiang Yuan, and Hong-Cai Zhou pp 1012–1016 DOI: 10.1021/ja0771639 Supporting Info

Length Dependence of the Coil β-Sheet Transition in a Membrane Environment Matthias Meier and Joachim Seelig pp 1017–1024 DOI: 10.1021/ja077231r

Effective Concentration as a Tool for Quantitatively Addressing Preorganization in Multicomponent Assemblies:  Application to the Selective Complexation of Lanthanide Cations Gabriel Canard, Sylvain Koeller, Gérald Bernardinelli, and Claude Piguet pp 1025–1040 DOI: 10.1021/ja0772290 Supporting Info

Designed Amino Acid ATRP Initiators for the Synthesis of Biohybrid Materials Rebecca M. Broyer, Grace M. Quaker, and Heather D. Maynard pp 1041–1047 DOI: 10.1021/ja0772546 Supporting Info

The Chemical Bond between Au(I) and the Noble Gases. Comparative Study of NgAuF and NgAu+ (Ng = Ar, Kr, Xe) by Density Functional and Coupled Cluster Methods Leonardo Belpassi, Ivan Infante, Francesco Tarantelli, and Lucas Visscher pp 1048–1060 DOI: 10.1021/ja0772647 Supporting Info

The Role of the Second Coordination Sphere of [Ni(PCy2NBz2)2](BF4)2 in Reversible Carbon Monoxide Binding Aaron D. Wilson, Kendra Fraze, Brendan Twamley, Susie M. Miller, Daniel L. DuBois, and M. Rakowski DuBois pp 1061–1068 DOI: 10.1021/ja077328d Supporting Info

Gas-Phase Synthesis of the Homo and Hetero Organocuprate Anions [MeCuMe]-, [EtCuEt]-, and [MeCuR]- Nicole Rijs, George N. Khairallah, Tom Waters, and Richard A. J. O'Hair pp 1069–1079 DOI: 10.1021/ja0773397 Supporting Info

Electrical Conductance of Conjugated Oligomers at the Single Molecule Level Roman Huber, Maria Teresa González, Songmei Wu, Michael Langer, Sergio Grunder, Viviana Horhoiu, Marcel Mayor, Martin R. Bryce, Changsheng Wang, Rukkiat Jitchati, Christian Schönenberger, and Michel Calame pp 1080–1084 DOI: 10.1021/ja0767940 Supporting Info

Supramolecular Pattern of Fullerene on 2D Bimolecular “Chessboard” Consisting of Bottom-up Assembly of Porphyrin and Phthalocyanine Molecules Soichiro Yoshimoto, Yosuke Honda, Osamu Ito, and Kingo Itaya pp 1085–1092 DOI: 10.1021/ja077407p Supporting Info

Formation of Pd/Au Nanostructures from Pd Nanowires via Galvanic Replacement Reaction Xiaowei Teng, Qi Wang, Ping Liu, Weiqiang Han, Anatoly I. Frenkel, Wen Wen, Nebojsa Marinkovic, Jonathan C. Hanson, and Jose A. Rodriguez pp 1093–1101 DOI: 10.1021/ja077303e Supporting Info

Toward a General Synthesis of Chlorins William G. O'Neal and Peter A. Jacobi pp 1102–1108 DOI: 10.1021/ja0780075 Supporting Info

Vapor−Solid−Solid Synthesis of Ge Nanowires from Vapor-Phase-Deposited Manganese Germanide Seeds [J. Am. Chem. Soc. 2007, 129, 10670−10671]. p 1109 DOI: 10.1021/ja076900y

Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride:  Study of Hydrogen Activation in a Ligand−Metal Bifunctional Hydrogenation Catalyst [J. Am. Chem. Soc. 2005, 127, 3100−3109]. Charles P. Casey, Jeffrey B. Johnson, Steven W. Singer, Qiang Cui p 1110 DOI: 10.1021/ja710851z

Physical Properties of Polymers Handbook, 2nd ed Edited by James E. Mark (University of Cincinnati, OH). Springer Science + Business Media, LLC:  New York. 2007. xx + 1076 pp. $349.00. ISBN 978-0-387-31235-4. George Christopher Martin p 1111 DOI: 10.1021/ja0769503

Hybrid Materials:  Synthesis, Characterization, and Applications. Edited by Guido Kickelbick (Technische Universität Wien, Austria). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xviii + 498 pp. $200.00. ISBN 978-3-527-31299-3. Alexander B. Morgan pp 1111–1112 DOI: 10.1021/ja710637a

The Way of Synthesis:  Evolution of Design and Methods for Natural Products By Tomáš Hudlicky and Josephine W. Reed (Brock University, St. Catharines, Canada). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xii + 1004 pp. $95.00. ISBN 978-3-527-31444-7. p 1112 DOI: 10.1021/ja077013y

New Avenues to Efficient Chemical Synthesis:  Emerging Technologies. Ernst Schering Foundation Symposium Proceedings 2006.3 Edited by P. H. Seeberger (ETH, Zürich) and T. Blume (Bayer Schering Pharma AG, Berlin). Springer-Verlag:  Berlin, Heidelberg. 2007. xiv + 242 pp. ISBN 978-3-540-70848-3. p 1112 DOI: 10.1021/ja077014q

Vitamin D Handbook:  Structures, Synonyms, and Properties Edited by G. W. A. Milne (Williamsburg, VA) and Michael Delander (MDs Research Library, Mountain View, CA). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 274 pp. $115. ISBN 978-0-470-13983-7. p 1112 DOI: 10.1021/ja7108932

Issue 04

Molecular Dynamics Simulations of the 30S Ribosomal Subunit Reveal a Preferred Tetracycline Binding Site Alexey Aleksandrov and Thomas Simonson pp 1114–1115 DOI: 10.1021/ja0741933 Supporting Info

Synthesis, Characterization, and Reactivity of a d2, Mo(IV) Complex Supported by a New OCO−Trianionic Pincer Ligand Soumya Sarkar, Adam R. Carlson, Melanie K. Veige, Joseph M. Falkowski, Khalil A. Abboud, and Adam S. Veige pp 1116–1117 DOI: 10.1021/ja074901k Supporting Info

High Mobility Single-Crystal Field-Effect Transistors from Bisindoloquinoline Semiconductors Eilaf Ahmed, Alejandro L. Briseno, Younan Xia, and Samson A. Jenekhe pp 1118–1119 DOI: 10.1021/ja077444g Supporting Info

Supramolecular Materials from Benzene-1,3,5-tricarboxamide-Based Nanorods Jorg Roosma, Tristan Mes, Philippe Leclère, Anja R. A. Palmans, and E. W. Meijer pp 1120–1121 DOI: 10.1021/ja0774764 Supporting Info

Layer-by-Layer Arrangement by Protein−Protein Interaction of Sulfite Oxidase and Cytochrome c Catalyzing Oxidation of Sulfite Roman Dronov, Dirk G. Kurth, Helmuth Möhwald, Roberto Spricigo, Silke Leimkühler, Ulla Wollenberger, K. V. Rajagopalan, Frieder W. Scheller, and Fred Lisdat pp 1122–1123 DOI: 10.1021/ja0768690 Supporting Info

CdS Quantum Dots Sensitized TiO2 Nanotube-Array Photoelectrodes Wen-Tao Sun, Yuan Yu, Hua-Yong Pan, Xian-Feng Gao, Qing Chen, and Lian-Mao Peng pp 1124–1125 DOI: 10.1021/ja0777741 Supporting Info

Rhodostreptomycins, Antibiotics Biosynthesized Following Horizontal Gene Transfer from Streptomyces padanus to Rhodococcus fascians Kazuhiko Kurosawa, Ion Ghiviriga, T. G. Sambandan, Philip A. Lessard, Joanna E. Barbara, ChoKyun Rha, and Anthony J. Sinskey pp 1126–1127 DOI: 10.1021/ja077821p Supporting Info

Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds Hien-Quang Do and Olafs Daugulis pp 1128–1129 DOI: 10.1021/ja077862l Supporting Info

Vertically Aligned Pearl-like Carbon Nanotube Arrays for Fiber Spinning Huisheng Peng, Menka Jain, Qingwen Li, Dean E. Peterson, Yuntian Zhu, and Quanxi Jia pp 1130–1131 DOI: 10.1021/ja077767c Supporting Info

Photosensitized 2 + 2 Cycloaddition Reaction Using Homochirality Generated by Spontaneous Crystallization Masami Sakamoto, Mamoru Kato, Yoko Aida, Kazuyuki Fujita, Takashi Mino, and Tsutomu Fujita pp 1132–1133 DOI: 10.1021/ja077912m Supporting Info

A Four-Coordinate Fe(III) Porphyrin Cation Ming Fang, Scott R. Wilson, and Kenneth S. Suslick pp 1134–1135 DOI: 10.1021/ja078061l Supporting Info

A Ring Size-Selective Reduction of Lactones Using SmI2 and H2O Lorna A. Duffy, Hiroshi Matsubara, and David J. Procter pp 1136–1137 DOI: 10.1021/ja078137d Supporting Info

Kinetically Controlled, High-Yield Synthesis of Au25 Clusters Manzhou Zhu, Eric Lanni, Niti Garg, Mark E. Bier, and Rongchao Jin pp 1138–1139 DOI: 10.1021/ja0782448 Supporting Info

Solid-State Photodecarbonylation of Diphenylcyclopropenone:  A Quantum Chain Process Made Possible by Ultrafast Energy Transfer Gregory Kuzmanich, Arunkumar Natarajan, Khin K. Chin, Marcel Veerman, Christopher J. Mortko, and Miguel A. Garcia-Garibay pp 1140–1141 DOI: 10.1021/ja078301x Supporting Info

Increased Electric Conductance through Physisorbed Oxygen on Copper Nanocables Sheathed in Carbon Ken Judai, Shigenori Numao, Ari Furuya, Junichi Nishijo, and Nobuyuki Nishi pp 1142–1143 DOI: 10.1021/ja078287o Supporting Info

Zero Thermal Expansion in PbTiO3-Based Perovskites Jun Chen, Xianran Xing, Ce Sun, Penghao Hu, Ranbo Yu, Xiaowei Wang, and Lihong Li pp 1144–1145 DOI: 10.1021/ja7100278 Supporting Info

Intrinsic Yellow Light Phosphor:  An Organic−Inorganic Hybrid Gallium Oxalatophosphate with Hexameric Octahedral Ga6(OH)4O26 Cluster Ya-Ching Yang and Sue-Lein Wang pp 1146–1147 DOI: 10.1021/ja7101423 Supporting Info

Tandem Carbon−Carbon and Carbon−Chlorine Bond Formation by Cu(II) Chloride-Promoted [3,3] Sigmatropic Rearrangement of N-Allylhydrazones Devon A. Mundal, Jennifer J. Lee, and Regan J. Thomson pp 1148–1149 DOI: 10.1021/ja7101967 Supporting Info

Biomimetic Total Synthesis of (−)-Erinacine E Hideaki Watanabe and Masahisa Nakada pp 1150–1151 DOI: 10.1021/ja7102795 Supporting Info

Charge Migration along the DNA Duplex:  Hole versus Electron Transport Benjamin Elias, Fangwei Shao, and Jacqueline K. Barton pp 1152–1153 DOI: 10.1021/ja710358p

Stereospecificity of Retinol Saturase:  Absolute Configuration, Synthesis, and Biological Evaluation of Dihydroretinoids Alexander R. Moise, Marta Domínguez, Susana Alvarez, Rosana Alvarez, Michael Schupp, Ana G. Cristancho, Philip D. Kiser, Angel R. de Lera, Mitchell A. Lazar, and Krzysztof Palczewski pp 1154–1155 DOI: 10.1021/ja710487q Supporting Info

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism Ismail Özdemir, Serpil Demir, Bekir Çetinkaya, Christophe Gourlaouen, Feliu Maseras, Christian Bruneau, and Pierre H. Dixneuf pp 1156–1157 DOI: 10.1021/ja710276x Supporting Info

Emergence of a Single Solid Chiral State from a Nearly Racemic Amino Acid Derivative Wim L. Noorduin, Toshiko Izumi, Alessia Millemaggi, Michel Leeman, Hugo Meekes, Willem J. P. Van Enckevort, Richard M. Kellogg, Bernard Kaptein, Elias Vlieg, and Donna G. Blackmond pp 1158–1159 DOI: 10.1021/ja7106349 Supporting Info

Expanding the Substrate Tolerance of Biotin Ligase through Exploration of Enzymes from Diverse Species Sarah A. Slavoff, Irwin Chen, Yoon-Aa Choi,and Alice Y. Ting pp 1160–1162 DOI: 10.1021/ja076655i Supporting Info

Intercalation Is Not Required for DNA Light-Switch Behavior Daniel A. Lutterman, Abdellatif Chouai, Yao Liu, Yujie Sun, Cristina D. Stewart, Kim R. Dunbar, and Claudia Turro pp 1163–1170 DOI: 10.1021/ja071001v Supporting Info

Metal Atoms Collinear with the Spiro Carbon of 6,6-Open Adducts, M2@C80(Ad) (M = La and Ce, Ad = Adamantylidene) Michio Yamada, Chika Someya, Takatsugu Wakahara, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Michael T. H. Liu, Naomi Mizorogi, and Shigeru Nagase pp 1171–1176 DOI: 10.1021/ja073924w Supporting Info

Conductive Sub-micrometric Wires of Platinum-Carbonyl Clusters Fabricated by Soft-Lithography Pierpaolo Greco, Massimiliano Cavallini, Pablo Stoliar, Santiago David Quiroga, Soumya Dutta, Stefano Zacchini, Maria Carmela Iapalucci, Vittorio Morandi, Silvia Milita, Pier Giorgio Merli, and Fabio Biscarini pp 1177–1182 DOI: 10.1021/ja074104m Supporting Info

Olefin Substitution in (silox)3M(olefin) (silox = tBu3SiO; M = Nb, Ta):  The Role of Density of States in Second vs Third Row Transition Metal Reactivity Kurt F. Hirsekorn, Elliott B. Hulley, Peter T. Wolczanski, and Thomas R. Cundari pp 1183–1196 DOI: 10.1021/ja074972j Supporting Info

Concerning the Reactivity of Dioxiranes. Observations from Experiments and Theory Cosimo Annese, Lucia D'Accolti, Anna Dinoi, Caterina Fusco, Remo Gandolfi, and Ruggero Curci pp 1197–1204 DOI: 10.1021/ja075068u Supporting Info

Structural and Spectroscopic Characterization of Mononuclear Copper(I) Nitrosyl Complexes:  End-on versus Side-on Coordination of NO to Copper(I) Kiyoshi Fujisawa, Akira Tateda, Yoshitaro Miyashita, Ken-ichi Okamoto, Florian Paulat, V. K. K. Praneeth, Anna Merkle, and Nicolai Lehnert pp 1205–1213 DOI: 10.1021/ja075071d Supporting Info

Elucidating the Intermolecular Interactions within a Desolvated Protein−Ligand Complex. An Experimental and Computational Study Elena N. Kitova, Mikyung Seo, Pierre-Nicholas Roy, and John S. Klassen pp 1214–1226 DOI: 10.1021/ja075333b Supporting Info

An Alternate Proton Acceptor for Excited-State Proton Transfer in Green Fluorescent Protein:  Rewiring GFP Deborah Stoner-Ma, Andrew A. Jaye, Kate L. Ronayne, Jérôme Nappa, Stephen R. Meech, and Peter J. Tonge pp 1227–1235 DOI: 10.1021/ja0754507

Solid-State NMR Spectroscopy Detects Interactions between Tryptophan Residues of the E. coli Sugar Transporter GalP and the α-Anomer of the d-Glucose Substrate Simon G. Patching, Peter J. F. Henderson, Richard B. Herbert, and David A. Middleton pp 1236–1244 DOI: 10.1021/ja075584k Supporting Info

Identifying the Presence of a Disulfide Linkage in Peptides by the Selective Elimination of Hydrogen Disulfide from Collisionally Activated Alkali and Alkaline Earth Metal Complexes Hugh I. Kim and J. L. Beauchamp pp 1245–1257 DOI: 10.1021/ja075698w

Influence of Doped Anions on Poly(3,4-ethylenedioxythiophene) as Hole Conductors for Iodine-Free Solid-State Dye-Sensitized Solar Cells Jiangbin Xia, Naruhiko Masaki, Monica Lira-Cantu, Yukyeong Kim, Kejian Jiang, and Shozo Yanagida pp 1258–1263 DOI: 10.1021/ja075704o Supporting Info

NMR Investigations of the Static and Dynamic Structures of Bisphosphonates on Human Bone:  a Molecular Model Sujoy Mukherjee, Yongcheng Song, and Eric Oldfield pp 1264–1273 DOI: 10.1021/ja0759949

Compact Biocompatible Quantum Dots Functionalized for Cellular Imaging Wenhao Liu, Mark Howarth, Andrew B. Greytak, Yi Zheng, Daniel G. Nocera, Alice Y. Ting, and Moungi G. Bawendi pp 1274–1284 DOI: 10.1021/ja076069p Supporting Info

Local Environments and Lithium Adsorption on the Iron Oxyhydroxides Lepidocrocite (γ-FeOOH) and Goethite (α-FeOOH):  A 2H and 7Li Solid-State MAS NMR Study Jongsik Kim, Ulla Gro Nielsen, and Clare P. Grey pp 1285–1295 DOI: 10.1021/ja0761028 Supporting Info

Tertiary Interactions Determine the Accuracy of RNA Folding Seema Chauhan and Sarah A. Woodson pp 1296–1303 DOI: 10.1021/ja076166i Supporting Info

Stacking Interactions and the Twist of DNA Valentino R. Cooper, Timo Thonhauser, Aaron Puzder, Elsebeth Schröder, Bengt I. Lundqvist, and David C. Langreth pp 1304–1308 DOI: 10.1021/ja0761941 Supporting Info

A Facile Synthesis of Uniform NH4TiOF3 Mesocrystals and Their Conversion to TiO2 Mesocrystals Lei Zhou, David Smyth-Boyle, and Paul O'Brien pp 1309–1320 DOI: 10.1021/ja076187c Supporting Info

Orthogonal Recognition in Dimeric Coiled Coils via Buried Polar-Group Modulation Maria L. Diss and Alan J. Kennan pp 1321–1327 DOI: 10.1021/ja076265w Supporting Info

Plasma Clearance of Bacteriophage Qβ Particles as a Function of Surface Charge Duane E. Prasuhn, Jr., Pratik Singh, Erica Strable, Steven Brown, Marianne Manchester, and M. G. Finn pp 1328–1334 DOI: 10.1021/ja075937f

Programmable Fluidic Production of Microparticles with Configurable Anisotropy Kyung Eun Sung, Siva A. Vanapalli, Deshpremy Mukhija, Hugh A. McKay, Joanna Mirecki Millunchick, Mark A. Burns, and Michael J. Solomon pp 1335–1340 DOI: 10.1021/ja0762700

Electron Capture Dissociation Proceeds with a Low Degree of Intramolecular Migration of Peptide Amide Hydrogens Kasper D. Rand, Christopher M. Adams, Roman A. Zubarev, and Thomas J. D. Jørgensen pp 1341–1349 DOI: 10.1021/ja076448i

Combination of an Anionic Terminator Multifunctional Initiator and Divergent Carbanionic Polymerization:  Application to the Synthesis of Dendrimer-Like Polymers and of Asymmetric and Miktoarm Stars Rachid Matmour and Yves Gnanou pp 1350–1361 DOI: 10.1021/ja076442t Supporting Info

Evidence of Graphitic AB Stacking Order of Graphite Oxides Hae-Kyung Jeong, Yun Pyo Lee, Rob J. W. E. Lahaye, Min-Ho Park, Kay Hyeok An, Ick Jun Kim, Cheol-Woong Yang, Chong Yun Park, Rodney S. Ruoff, and Young Hee Lee pp 1362–1366 DOI: 10.1021/ja076473o Supporting Info

Characterization of Solid-State Dye-Sensitized Solar Cells Utilizing High Absorption Coefficient Metal-Free Organic Dyes Wendy H. Howie, Frederik Claeyssens, Hidetoshi Miura, and Laurence M. Peter pp 1367–1375 DOI: 10.1021/ja076525+ Supporting Info

Zinc-Amyloid β Interactions on a Millisecond Time-Scale Stabilize Non-fibrillar Alzheimer-Related Species Dror Noy, Inna Solomonov, Ory Sinkevich, Talmon Arad, Kristian Kjaer, and Irit Sagi pp 1376–1383 DOI: 10.1021/ja076282l Supporting Info

Two-Dimensional Superdegeneracy and Structure−Magnetism Correlations in Strong Ferromagnet, Mn2Ga5 Sang-Hwan Kim, Magnus Boström, and Dong-Kyun Seo pp 1384–1391 DOI: 10.1021/ja0765924 Supporting Info

Effects of Template Sequence and Secondary Structure on DNA-Templated Reactivity Thomas M. Snyder, Brian N. Tse, and David R. Liu pp 1392–1401 DOI: 10.1021/ja076780u Supporting Info

On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper Amit A. Gokhale, James A. Dumesic, and Manos Mavrikakis pp 1402–1414 DOI: 10.1021/ja0768237

Metallic Single-Walled Carbon Nanotubes for Conductive Nanocomposites Wei Wang, K. A. Shiral Fernando, Yi Lin, Mohammed J. Meziani, L. Monica Veca, Li Cao, Puyu Zhang, Martin M. Kimani, and Ya-Ping Sun pp 1415–1419 DOI: 10.1021/ja0768035

Enhanced Metal Ion Selectivity of 2,9-Di-(pyrid-2-yl)-1,10-phenanthroline and Its Use as a Fluorescent Sensor for Cadmium(II) Gregory M. Cockrell, Gang Zhang, Donald G. VanDerveer, Randolph P. Thummel, and Robert D. Hancock pp 1420–1430 DOI: 10.1021/ja077141m Supporting Info

Does the Solid−Liquid Crystal Phase Transition Provoke the Spin-State Change in Spin-Crossover Metallomesogens? M. Seredyuk, A. B. Gaspar, V. Ksenofontov, Y. Galyametdinov, J. Kusz, and P. Gütlich pp 1431–1439 DOI: 10.1021/ja077265z Supporting Info

Metal-Catalyzed 1,2-Shift of Diverse Migrating Groups in Allenyl Systems as a New Paradigm toward Densely Functionalized Heterocycles Alexander S. Dudnik, Anna W. Sromek, Marina Rubina, Joseph T. Kim, Alexander V. Kel'in, and Vladimir Gevorgyan pp 1440–1452 DOI: 10.1021/ja0773507 Supporting Info

Using Ion Channel-Forming Peptides to Quantify Protein−Ligand Interactions Michael Mayer, Vincent Semetey, Irina Gitlin, Jerry Yang, and George M. Whitesides pp 1453–1465 DOI: 10.1021/ja077555f Supporting Info

Molecular Engineering of Supramolecular Scaffold Coatings that Can Reduce Static Platelet Adhesion Aryavarta M. S. Kumar, Sona Sivakova, Justin D. Fox, Jennifer E. Green, Roger E. Marchant, and Stuart J. Rowan pp 1466–1476 DOI: 10.1021/ja0775927 Supporting Info

One-Pot Synthesis and Characterization of Size-Controlled Bimagnetic FePt−Iron Oxide Heterodimer Nanocrystals Albert Figuerola, Angela Fiore, Riccardo Di Corato, Andrea Falqui, Cinzia Giannini, Edoardo Micotti, Alessandro Lascialfari, Maurizio Corti, Roberto Cingolani, Teresa Pellegrino, Pantaleo Davide Cozzoli, and Liberato Manna pp 1477–1487 DOI: 10.1021/ja078034v Supporting Info

Mg2+-Free Bacillus stearothermophilus Tryptophanyl-tRNA Synthetase Retains a Major Fraction of the Overall Rate Enhancement for Tryptophan Activation Violetta Weinreb and Charles W. Carter, Jr. pp 1488–1494 DOI: 10.1021/ja076557x

Cross Olefin Metathesis for the Selective Functionalization, Ferrocenylation, and Solubilization in Water of Olefin-Terminated Dendrimers, Polymers, and Gold Nanoparticles and for a Divergent Dendrimer Construction Cátia Ornelas, Denise Méry, Eric Cloutet, Jaime Ruiz Aranzaes, and Didier Astruc pp 1495–1506 DOI: 10.1021/ja077392v Supporting Info

Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor Sudeep Maheshwari, Edgar Jordan, Sandeep Kumar, Frank S. Bates, R. Lee Penn, Daniel F. Shantz, and Michael Tsapatsis pp 1507–1516 DOI: 10.1021/ja077711i

Amyloid-like Behavior in Abiotic, Amphiphilic Foldamers Valerie J. Bradford and Brent L. Iverson pp 1517–1524 DOI: 10.1021/ja0780840 Supporting Info

Issue 05

Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents:  Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome pp 1526–1527 DOI: 10.1021/ja073896h Supporting Info

Thermally Induced Transition between Open and Closed Spherical Pores in Ordered Mesoporous Silicas Michal Kruk and Chin Ming Hui pp 1528–1529 DOI: 10.1021/ja0749035 Supporting Info

Radially Diblock Nanotube:  Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene Justin L. Mynar, Takuya Yamamoto, Atsuko Kosaka, Takanori Fukushima, Noriyuki Ishii, and Takuzo Aida pp 1530–1531 DOI: 10.1021/ja075822b Supporting Info

Long-Lived Two-Photon Excited Luminescence of Water-Soluble Europium Complex:  Applications in Biological Imaging Using Two-Photon Scanning Microscopy Alexandre Picot, Anthony D'Aléo, Patrice L. Baldeck, Alexei Grichine, Alain Duperray, Chantal Andraud, and Olivier Maury pp 1532–1533 DOI: 10.1021/ja076837c Supporting Info

Efficient Modulation of the Third Order Nonlinear Optical Properties of Fullerene Derivatives Aurelio Mateo-Alonso, Kostas Iliopoulos, Stelios Couris, and Maurizio Prato pp 1534–1535 DOI: 10.1021/ja0771235

Inclusion of C60 into MCM-41 by Solvophobic Nature Satoshi Minakata, Ryoji Tsuruoka, and Mitsuo Komatsu pp 1536–1537 DOI: 10.1021/ja077114w Supporting Info

Multiple Probes are Required to Explore and Control the Rugged Energy Landscape of RNA Hairpins Changbong Hyeon and D. Thirumalai pp 1538–1539 DOI: 10.1021/ja0771641 Supporting Info

On the Proton Exclusion of Aquaporins:  A Statistical Mechanics Study Saree Phongphanphanee, Norio Yoshida, and Fumio Hirata pp 1540–1541 DOI: 10.1021/ja077087+ Supporting Info

Electrophoresis of Membrane-Associated Molecules in Packed Beds of Bilayer-Coated Particles Kenji Suzuki, Kazuo Hosokawa, and Mizuo Maeda pp 1542–1543 DOI: 10.1021/ja077418i Supporting Info

Heteroleptic Tm(II) Complexes:  One More Success for Trofimenko's Scorpionates Jianhua Cheng, Josef Takats, Michael J. Ferguson, and Robert McDonald pp 1544–1545 DOI: 10.1021/ja0776273 Supporting Info

Photoluminescent Europium-Containing Inner Sphere Conducting Metallopolymer Xiao-Yan Chen, Xiaoping Yang, and Bradley J. Holliday pp 1546–1547 DOI: 10.1021/ja077626a Supporting Info

Membranes Based on “Keplerate”-Type Polyoxometalates:  Slow, Passive Cation Transportation and Creation of Water Microenvironment Padmaja P. Mishra, Joe Pigga, and Tianbo Liu pp 1548–1549 DOI: 10.1021/ja077715n Supporting Info

Bright, Color-Tunable Fluorescent Dyes in the Visible−Near-Infrared Region Keitaro Umezawa, Yuki Nakamura, Hiroshi Makino, Daniel Citterio, and Koji Suzuki pp 1550–1551 DOI: 10.1021/ja077756j Supporting Info

Solvent-Mediated Photoinduced Electron Transfer in a Pyridinium Ionic Liquid Rebecca C. Vieira and Daniel E. Falvey pp 1552–1553 DOI: 10.1021/ja077797f Supporting Info

Metal-Mediated Retro Diels−Alder of Dicyclopentadiene Derivatives:  A Convenient Synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) Complexes Yu Liu, Bernhard Spingler, Paul Schmutz, and Roger Alberto pp 1554–1555 DOI: 10.1021/ja077741l Supporting Info

Photochemical and Thermal Isomerization of a Ruthenium(II)−Alloxazine Complex Involving an Unusual Coordination Mode Soushi Miyazaki, Takahiko Kojima, and Shunichi Fukuzumi pp 1556–1557 DOI: 10.1021/ja077954a Supporting Info

Orthogonal Synthesis of Indolines and Isoquinolines via Aryne Annulation Christopher D. Gilmore, Kevin M. Allan, and Brian M. Stoltz pp 1558–1559 DOI: 10.1021/ja0780582 Supporting Info

Supermolecular Building Blocks (SBBs) and Crystal Design:  12-Connected Open Frameworks Based on a Molecular Cubohemioctahedron Amy J. Cairns, Jason A. Perman, Lukasz Wojtas, Victor Ch. Kravtsov, Mohamed H. Alkordi, Mohamed Eddaoudi, and Michael J. Zaworotko pp 1560–1561 DOI: 10.1021/ja078060t Supporting Info

1,5-Enyne Metathesis Olivier Debleds and Jean-Marc Campagne pp 1562–1563 DOI: 10.1021/ja0780986 Supporting Info

New Modes for Coordination of Aromatic Heterocyclic Nitrogen Compounds to Molybdenum:  Catalytic Hydrogenation of Quinoline, Isoquinoline, and Quinoxaline by Mo(PMe3)4H4 Guang Zhu, Keliang Pang, and Gerard Parkin pp 1564–1565 DOI: 10.1021/ja078102d Supporting Info

Palladium-Catalyzed Cross-Coupling of α-Diazocarbonyl Compounds with Arylboronic Acids Cheng Peng, Yan Wang, and Jianbo Wang pp 1566–1567 DOI: 10.1021/ja0782293 Supporting Info

Nanostructured Rutile TiO2 for Selective Photocatalytic Oxidation of Aromatic Alcohols to Aldehydes in Water Sedat Yurdakal, Giovanni Palmisano, Vittorio Loddo, Vincenzo Augugliaro, and Leonardo Palmisano pp 1568–1569 DOI: 10.1021/ja709989e Supporting Info

Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Alkenes with Primary and Secondary Amines Zhijian Liu and John F. Hartwig pp 1570–1571 DOI: 10.1021/ja710126x Supporting Info

Correlating Molecular Orientation Distributions and Electrochemical Kinetics in Subpopulations of an Immobilized Protein Film Zeynep Ozkan Araci, Anne F. Runge, Walter J. Doherty III, and S. Scott Saavedra pp 1572–1573 DOI: 10.1021/ja710156d Supporting Info

Formation and Stability of a Vinyl Carbanion at the Active Site of Orotidine 5‘-Monophosphate Decarboxylase:  pKa of the C-6 Proton of Enzyme-Bound UMP Tina L. Amyes, Bryant M. Wood, Kui Chan, John A. Gerlt, and John P. Richard pp 1574–1575 DOI: 10.1021/ja710384t Supporting Info

Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones Takahiro Nishimura, Xun-Xiang Guo, Nanase Uchiyama, Taisuke Katoh, and Tamio Hayashi pp 1576–1577 DOI: 10.1021/ja710540s Supporting Info

Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network Tsuyoshi Haneda, Masaki Kawano, Takehide Kawamichi, and Makoto Fujita pp 1578–1579 DOI: 10.1021/ja7111564 Supporting Info

Ketone Super Silyl Enol Ethers in Sequential Reactions:  Diastereoselective Generation of Tertiary Carbinols in One Pot Matthew B. Boxer, Matsujiro Akakura, and Hisashi Yamamoto pp 1580–1582 DOI: 10.1021/ja7102586 Supporting Info

Steric Isotope Effects Gauged by the Bowl-Inversion Barrier in Selectively Deuterated Pentaarylcorannulenes Tomoharu Hayama, Kim K. Baldridge, Yao-Ting Wu, Anthony Linden, and Jay S. Siegel pp 1583–1591 DOI: 10.1021/ja073052y Supporting Info

Rearrangement, Nucleophilic Substitution, and Halogen Switch Reactions of Alkyl Halides over NaY Zeolite:  Formation of the Bicyclobutonium Cation Inside the Zeolite Cavity Marcelo Franco, Nilton Rosenbach, Jr., Glaucio B. Ferreira, Antônio C. O. Guerra, W. Bruce Kover, Cássia C. Turci, and Claudio J. A. Mota pp 1592–1600 DOI: 10.1021/ja0742939 Supporting Info

Near-IR MCD of the Nonheme Ferrous Active Site in Naphthalene 1,2-Dioxygenase:  Correlation to Crystallography and Structural Insight into the Mechanism of Rieske Dioxygenases Takehiro Ohta, Sarmistha Chakrabarty, John D. Lipscomb, and Edward I. Solomon pp 1601–1610 DOI: 10.1021/ja074769o Supporting Info

Bond or Cage Effect:  How Nitrophorins Transport and Release Nitric Oxide Marcelo A. Martí, Mariano C. González Lebrero, Adrián E. Roitberg, and Dario A. Estrin pp 1611–1618 DOI: 10.1021/ja075565a Supporting Info

The Canted Antiferromagnetic Approach to Single-Chain Magnets Kevin Bernot, Javier Luzon, Roberta Sessoli, Alessandro Vindigni, Julien Thion, Sébastien Richeter, Dominique Leclercq, Joulia Larionova, and Arie van der Lee pp 1619–1627 DOI: 10.1021/ja0751734 Supporting Info

High Turnover Remote Catalytic Oxygenation of Alkyl Groups:  How Steric Exclusion of Unbound Substrate Contributes to High Molecular Recognition Selectivity Siddhartha Das, Gary W. Brudvig, and Robert H. Crabtree pp 1628–1637 DOI: 10.1021/ja076039m Supporting Info

Diffusion of Oriented Single Molecules with Switchable Mobility in Networks of Long Unidimensional Nanochannels Christophe Jung, Johanna Kirstein, Barbara Platschek, Thomas Bein, Michael Budde, Irmgard Frank, Klaus Müllen, Jens Michaelis, and Christoph Bräuchle pp 1638–1648 DOI: 10.1021/ja075927e Supporting Info

Monolayer-Protected Nanoparticle Film Assemblies as Platforms for Controlling Interfacial and Adsorption Properties in Protein Monolayer Electrochemistry Andrew F. Loftus, Katelyn P. Reighard, Susanna A. Kapourales, and Michael C. Leopold pp 1649–1661 DOI: 10.1021/ja076312k Supporting Info

Off-Pathway, Oxygen-Dependent Thiamine Radical in the Krebs Cycle René A. W. Frank, Christopher W. M. Kay, Judy Hirst, and Ben F. Luisi pp 1662–1668 DOI: 10.1021/ja076468k Supporting Info

Rational Design of Macrometallocyclic Trinuclear Complexes with Superior π-Acidity and π-Basicity Sammer M. Tekarli, Thomas R. Cundari, and Mohammad A. Omary pp 1669–1675 DOI: 10.1021/ja076527u

A Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide Koichi Awazu, Makoto Fujimaki, Carsten Rockstuhl, Junji Tominaga, Hirotaka Murakami, Yoshimichi Ohki, Naoya Yoshida, and Toshiya Watanabe pp 1676–1680 DOI: 10.1021/ja076503n Supporting Info

Lanthanide-Binding Peptides for NMR Measurements of Residual Dipolar Couplings and Paramagnetic Effects from Multiple Angles Xun-Cheng Su, Kerry McAndrew, Thomas Huber, and Gottfried Otting pp 1681–1687 DOI: 10.1021/ja076564l Supporting Info

Mechanism of Product Release in NO Detoxification from Mycobacterium tuberculosis Truncated Hemoglobin N Marcelo A. Martí, Axel Bidon-Chanal, Alejandro Crespo, Syun-Ru Yeh, Victor Guallar, F. Javier Luque, and Darío A. Estrin pp 1688–1693 DOI: 10.1021/ja076853+ Supporting Info

Influence of Charge State on the Mechanism of CO Oxidation on Gold Clusters Christian Bürgel, Nelly M. Reilly, Grant E. Johnson, Roland Mitrić, Michele L. Kimble, A. W. Castleman, Jr., and Vlasta Bonaić-Koutecký pp 1694–1698 DOI: 10.1021/ja0768542

Silicon/Molecule Interfacial Electronic Modifications Tao He, Huanjun Ding, Naama Peor, Meng Lu, David A. Corley, Bo Chen, Yuval Ofir, Yongli Gao, Shlomo Yitzchaik, and James M. Tour pp 1699–1710 DOI: 10.1021/ja0768789

Picosecond Kinetic Study of the Photoinduced Homolysis of Benzhydryl Acetates:  The Nature of the Conversion of Radical Pairs into Ion Pairs Libby R. Heeb and Kevin S. Peters pp 1711–1717 DOI: 10.1021/ja077105n Supporting Info

Molecularly Defined Caprolactone Oligomers and Polymers:  Synthesis and Characterization Kenichi Takizawa, Chuanbing Tang, and Craig J. Hawker pp 1718–1726 DOI: 10.1021/ja077149w Supporting Info

Measured Rates of Fluoride/Metal Association Correlate with Rates of Superoxide/Metal Reactions for FeIIIEDTA(H2O)- and Related Complexes Jack S. Summers, Joseph B. Baker, Dan Meyerstein, Amir Mizrahi, Israel Zilbermann, Haim Cohen, Christopher M. Wilson, and Jamie R. Jones pp 1727–1734 DOI: 10.1021/ja077193b

Well-Defined Liquid Crystal Gels from Telechelic Polymers Yan Xia, Rafael Verduzco, Robert H. Grubbs, and Julia A. Kornfield pp 1735–1740 DOI: 10.1021/ja077192j Supporting Info

Transient States in [2 + 2] Photodimerization of Cinnamic Acid:  Correlation of Solid-State NMR and X-ray Analysis Mujeeb Khan, Gunther Brunklaus, Volker Enkelmann, and Hans-Wolfgang Spiess pp 1741–1748 DOI: 10.1021/ja0773711 Supporting Info

Influence of the Environment on the [4Fe−4S]2+ to [2Fe−2S]2+ Cluster Switch in the Transcriptional Regulator FNR Jason C. Crack, Alisa A. Gaskell, Jeffrey Green, Myles R. Cheesman, Nick E. Le Brun, and Andrew J. Thomson pp 1749–1758 DOI: 10.1021/ja077455+ Supporting Info

Noncovalent Approach to One-Dimensional Ion Conductors:  Enhancement of Ionic Conductivities in Nanostructured Columnar Liquid Crystals Harutoki Shimura, Masafumi Yoshio, Koji Hoshino, Tomohiro Mukai, Hiroyuki Ohno, and Takashi Kato pp 1759–1765 DOI: 10.1021/ja0775220 Supporting Info

Amine Basicity (pKb) Controls the Analyte Binding Energy on Single Walled Carbon Nanotube Electronic Sensor Arrays Chang Young Lee and Michael S. Strano pp 1766–1773 DOI: 10.1021/ja0776069 Supporting Info

Nanosecond to Microsecond Protein Dynamics Probed by Magnetic Relaxation Dispersion of Buried Water Molecules Erik Persson and Bertil Halle pp 1774–1787 DOI: 10.1021/ja0775873 Supporting Info

Titanocene Catalyzed 4-exo Cyclizations:  Mechanism, Experiment, Catalyst Design Joachim Friedrich, Katarzyna Walczak, Michael Dolg, Frederik Piestert, Thorsten Lauterbach, Dennis Worgull, and Andreas Gansäuer pp 1788–1796 DOI: 10.1021/ja077596b Supporting Info

Issue 06

The Catalytic Dehydrogenation of Ammonia-Borane Involving an Unexpected Hydrogen Transfer to Ligated Carbene and Subsequent Carbon−Hydrogen Activation Xinzheng Yang and Michael B. Hall pp 1798–1799 DOI: 10.1021/ja0751328 Supporting Info

Water at Hydrophobic Surfaces:  When Weaker Is Better Dennis K. Hore, Dave S. Walker, and Geraldine L. Richmond pp 1800–1801 DOI: 10.1021/ja0755616 Supporting Info

Stacking Energies for Average B-DNA Structures from the Combined Density Functional Theory and Symmetry-Adapted Perturbation Theory Approach Annamaria Fiethen, Georg Jansen, Andreas Hesselmann, and Martin Schütz pp 1802–1803 DOI: 10.1021/ja076781m Supporting Info

Sulfonylimidates as Nucleophiles in Catalytic Addition Reactions Ryosuke Matsubara, Florian Berthiol, and Shū Kobayashi pp 1804–1805 DOI: 10.1021/ja077054u Supporting Info

Structure and Activity of Largazole, a Potent Antiproliferative Agent from the Floridian Marine Cyanobacterium Symploca sp. Kanchan Taori, Valerie J. Paul, and Hendrik Luesch pp 1806–1807 DOI: 10.1021/ja7110064 Supporting Info

Ion−Dipole Interactions Are Asymptotically Unscreened by Water in Dipolar Nanopores, Yielding Patterned Ion Distributions Kevin Leung pp 1808–1809 DOI: 10.1021/ja076229x Supporting Info

Infrared Signature of DNA G-Quadruplexes in the Gas Phase Valérie Gabelica, Frédéric Rosu, Edwin De Pauw, Joël Lemaire, Jean-Christophe Gillet, Jean-Christophe Poully, Frédéric Lecomte, Gilles Grégoire, Jean-Pierre Schermann, and Charles Desfrançois pp 1810–1811 DOI: 10.1021/ja077321w Supporting Info

Hydrogen Peroxide:  A Poor Ligand to Gallium Tetraphenylporphyrin Antonio G. DiPasquale and James M. Mayer pp 1812–1813 DOI: 10.1021/ja077598w Supporting Info

Au-Containing All-Carbon 1,4-Dipoles:  Generation and [4 + 2] Annulation in the Formation of Carbo-/Heterocycles Guozhu Zhang, Xiaogen Huang, Guotao Li, and Liming Zhang pp 1814–1815 DOI: 10.1021/ja077948e Supporting Info

Synchrotron-Derived Vibrational Data Confirm Unprotonated Oxo Ligand in Myoglobin Compound II Weiqiao Zeng, Alexander Barabanschikov, Yunbin Zhang, Jiyong Zhao, Wolfgang Sturhahn, E. Ercan Alp, and J. Timothy Sage pp 1816–1817 DOI: 10.1021/ja077823+ Supporting Info

Hydrogen Absorption in the Core/Shell Interface of Pd/Pt Nanoparticles Hirokazu Kobayashi, Miho Yamauchi, Hiroshi Kitagawa, Yoshiki Kubota, Kenichi Kato, and Masaki Takata pp 1818–1819 DOI: 10.1021/ja078126k Supporting Info

Copper-Catalyzed 1,2-Double Amination of 1-Halo-1-alkynes. Concise Synthesis of Protected Tetrahydropyrazines and Related Heterocyclic Compounds Yasuhiro Fukudome, Hiroyuki Naito, Takeshi Hata, and Hirokazu Urabe pp 1820–1821 DOI: 10.1021/ja078163b Supporting Info

Discovery of Incednine as a Potent Modulator of the Anti-apoptotic Function of Bcl-xL from Microbial Origin Yushi Futamura, Ryuichi Sawa, Yoji Umezawa, Masayuki Igarashi, Hikaru Nakamura, Kimiko Hasegawa, Mikio Yamasaki, Etsu Tashiro, Yoshikazu Takahashi, Yuzuru Akamatsu, and Masaya Imoto pp 1822–1823 DOI: 10.1021/ja710124p Supporting Info

Möbius Aromaticity in N-Fused [24]Pentaphyrin upon Rh(I) Metalation Jong Kang Park, Zin Seok Yoon, Min-Chul Yoon, Kil Suk Kim, Shigeki Mori, Ji-Young Shin, Atsuhiro Osuka, and Dongho Kim pp 1824–1825 DOI: 10.1021/ja7100483 Supporting Info

Self-Duplicating Amplification in a Dynamic Combinatorial Library Shengguang Xu and Nicolas Giuseppone pp 1826–1827 DOI: 10.1021/ja710248q Supporting Info

On the Nature of Strong Hydrogen Atom Trapping Inside Pd Nanoparticles Hirokazu Kobayashi, Miho Yamauchi, Hiroshi Kitagawa, Yoshiki Kubota, Kenichi Kato, and Masaki Takata pp 1828–1829 DOI: 10.1021/ja7102372 Supporting Info

Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry:  Protonation versus Heteroatom Inclusion De-Liang Long, Carsten Streb, Yu-Fei Song, Scott Mitchell, and Leroy Cronin pp 1830–1832 DOI: 10.1021/ja075940z Supporting Info

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks Farid Nouar, Jarrod F. Eubank, Till Bousquet, Lukasz Wojtas, Michael J. Zaworotko, and Mohamed Eddaoudi pp 1833–1835 DOI: 10.1021/ja710123s Supporting Info

A Chemically-Driven Molecular Information Ratchet Mónica Alvarez-Pérez, Stephen M. Goldup, David A. Leigh, and Alexandra M. Z. Slawin pp 1836–1838 DOI: 10.1021/ja7102394 Supporting Info

Platinum-Catalyzed Phenyl and Methyl Group Transfer from Tin to Iridium:  Evidence for an Autocatalytic Reaction Pathway with an Unusual Preference for Methyl Transfer Stuart E. Smith, Jennifer M. Sasaki, Robert G. Bergman, Joseph E. Mondloch, and Richard G. Finke pp 1839–1841 DOI: 10.1021/ja710365x Supporting Info

Total Synthesis and Stereochemistry of Mycolactone F Han-Je Kim and Yoshito Kishi pp 1842–1844 DOI: 10.1021/ja7111838 Supporting Info

Self-Adaptable Catalysts:  Substrate-Dependent Ligand Configuration Raivis Zalubovskis, Alexis Bouet, Ester Fjellander, Samuel Constant, David Linder, Andreas Fischer, Jérôme Lacour, Timofei Privalov, and Christina Moberg pp 1845–1855 DOI: 10.1021/ja074044k Supporting Info

Anion-Induced Adsorption of Ferrocenated Nanoparticles Rebecca L. Stiles, Ramjee Balasubramanian, Stephen W. Feldberg, and Royce W. Murray pp 1856–1865 DOI: 10.1021/ja074161f Supporting Info

Self-Assembled Reverse Micelles in Supercritical CO2 Entrap Protein in Native State V. Sai Vikrama Chaitanya and Sanjib Senapati pp 1866–1870 DOI: 10.1021/ja0739234 Supporting Info

Water Confined in Nanotubes and between Graphene Sheets:  A First Principle Study Giancarlo Cicero, Jeffrey C. Grossman, Eric Schwegler, Francois Gygi, and Giulia Galli pp 1871–1878 DOI: 10.1021/ja074418+

Excitation Energy Migration Processes in Cyclic Porphyrin Arrays Probed by Single Molecule Spectroscopy Jaesung Yang, Mira Park, Zin Seok Yoon, Takaaki Hori, Xiaobin Peng, Naoki Aratani, Peter Dedecker, Jun-ichi Hotta, Hiroshi Uji-i, Michel Sliwa, Johan Hofkens, Atsuhiro Osuka, and Dongho Kim pp 1879–1884 DOI: 10.1021/ja075701b Supporting Info

Fluorinated Porphyrin Tweezer:  A Powerful Reporter of Absolute Configuration for erythro and threo Diols, Amino Alcohols, and Diamines Xiaoyong Li, Marina Tanasova, Chrysoula Vasileiou, and Babak Borhan pp 1885–1893 DOI: 10.1021/ja0752639 Supporting Info

Assessment of Water-Soluble π-Extended Squaraines as One- and Two-Photon Singlet Oxygen Photosensitizers:  Design, Synthesis, and Characterization Luca Beverina, Maurizio Crippa, Mirko Landenna, Riccardo Ruffo, Patrizio Salice, Fabio Silvestri, Silvia Versari, Alessandro Villa, Luca Ciaffoni, Elisabetta Collini, Camilla Ferrante, Silvia Bradamante, Claudio M. Mari, Renato Bozio, and Giorgio A. Pagani pp 1894–1902 DOI: 10.1021/ja075933a Supporting Info

Dual Aperture Control on pH- and Anion-Driven Supramolecular Nanoscopic Hybrid Gate-like Ensembles Rosa Casasús, Estela Climent, Ma. Dolores Marcos, Ramón Martínez-Máñez, Félix Sancenón, Juan Soto, Pedro Amorós, Joan Cano, and Eliseo Ruiz pp 1903–1917 DOI: 10.1021/ja0756772

Inactivation of Microbial Arginine Deiminases by l-Canavanine Ling Li, Zhimin Li, Danqi Chen, Xuefeng Lu, Xiaohua Feng, Elizabeth C. Wright, Nathan O. Solberg, Debra Dunaway-Mariano, Patrick S. Mariano, Andrey Galkin, Liudmila Kulakova, Osnat Herzberg, Kari B. Green-Church, and Liwen Zhang pp 1918–1931 DOI: 10.1021/ja0760877 Supporting Info

Experimental and Theoretical Study of the Reactions between Neutral Vanadium Oxide Clusters and Ethane, Ethylene, and Acetylene Feng Dong, Scott Heinbuch, Yan Xie, Jorge J. Rocca, Elliot R. Bernstein, Zhe-Chen Wang, Ke Deng, and Sheng-Gui He pp 1932–1943 DOI: 10.1021/ja076007z Supporting Info

The Spectral Elucidation versus the X-ray Structure of the Critical Precursor Complex in Bimolecular Electron Transfers:  Application of Experimental/Theoretical Solvent Probes to Ion-Radical (Redox) Dyads Sergiy V. Rosokha, Marshall D. Newton, Almaz S. Jalilov, and Jay K. Kochi pp 1944–1952 DOI: 10.1021/ja076591b Supporting Info

Quantum Mechanical/Molecular Mechanical Study of Mechanisms of Heme Degradation by the Enzyme Heme Oxygenase:  The Strategic Function of the Water Cluster Hui Chen, Yohann Moreau, Etienne Derat, and Sason Shaik pp 1953–1965 DOI: 10.1021/ja076679p Supporting Info

A Common Mechanism for Branching, Cyclopropanation, and Cyclobutanation Reactions in the Isoprenoid Biosynthetic Pathway Hirekodathakallu V. Thulasiram, Hans K. Erickson, and C. Dale Poulter pp 1966–1971 DOI: 10.1021/ja0771282 Supporting Info

Infrared Spectra of the WH4(H2)4 Complex in Solid Hydrogen Xuefeng Wang, Lester Andrews, Ivan Infante, and Laura Gagliardi pp 1972–1978 DOI: 10.1021/ja077322o Supporting Info

Structure of the Fully Modified Left-Handed Cyclohexene Nucleic Acid Sequence GTGTACAC Koen Robeyns, Piet Herdewijn, and Luc Van Meervelt pp 1979–1984 DOI: 10.1021/ja077313f Supporting Info

Dynamics in the Transient Complex of Plastocyanin−Cytochrome f from Prochlorothrix hollandica Rinske Hulsker, Maria V. Baranova, George S. Bullerjahn, and Marcellus Ubbink pp 1985–1991 DOI: 10.1021/ja077453p Supporting Info

A Cheap Metal for a “Noble” Task:  Preparative and Mechanistic Aspects of Cycloisomerization and Cycloaddition Reactions Catalyzed by Low-Valent Iron Complexes Alois Fürstner, Keisuke Majima, Rubén Martín, Helga Krause, Egmont Kattnig, Richard Goddard, and Christian W. Lehmann pp 1992–2004 DOI: 10.1021/ja0777180 Supporting Info

Synthesis, Characterization, and Reactivity of a Uranyl β-Diketiminate Complex Trevor W. Hayton and Guang Wu pp 2005–2014 DOI: 10.1021/ja077538q Supporting Info

[FeFe]-Hydrogenase-Catalyzed H2 Production in a Photoelectrochemical Biofuel Cell Michael Hambourger, Miguel Gervaldo, Drazenka Svedruzic, Paul W. King, Devens Gust, Maria Ghirardi, Ana L. Moore, and Thomas A. Moore pp 2015–2022 DOI: 10.1021/ja077691k Supporting Info

Development of an Efficient Photocatalytic System for CO2 Reduction Using Rhenium(I) Complexes Based on Mechanistic Studies Hiroyuki Takeda, Kazuhide Koike, Haruo Inoue, and Osamu Ishitani pp 2023–2031 DOI: 10.1021/ja077752e Supporting Info

Controlled Synthesis and Upconverted Avalanche Luminescence of Cerium(III) and Neodymium(III) Orthovanadate Nanocrystals with High Uniformity of Size and Shape Hong Deng, Shihe Yang, Si Xiao, Hong-Mei Gong, and Qu-Quan Wang pp 2032–2040 DOI: 10.1021/ja0778141 Supporting Info

Glycine Enolates:  The Effect of Formation of Iminium Ions to Simple Ketones on α-Amino Carbon Acidity and a Comparison with Pyridoxal Iminium Ions Juan Crugeiras, Ana Rios, Enrique Riveiros, Tina L. Amyes, and John P. Richard pp 2041–2050 DOI: 10.1021/ja078006c Supporting Info

Carbon−Carbon Bond Activation of 2,2,6,6-Tetramethyl-piperidine-1-oxyl by a RhII Metalloradical:  A Combined Experimental and Theoretical Study Kin Shing Chan, Xin Zhu Li, Wojciech I. Dzik, and Bas de Bruin pp 2051–2061 DOI: 10.1021/ja078157f Supporting Info

Tailoring Electronic Structures of Carbon Nanotubes by Solvent with Electron-Donating and -Withdrawing Groups Hyeon-Jin Shin, Soo Min Kim, Seon-Mi Yoon, Anass Benayad, Ki Kang Kim, Sung Jin Kim, Hyun Ki Park, Jae-Young Choi, and Young Hee Lee pp 2062–2066 DOI: 10.1021/ja710036e Supporting Info

Lipid Bilayer Discs and Banded Tubules:  Photoinduced Lipid Sorting in Ternary Mixtures Jing Yuan, Steven M. Hira, Geoffrey F. Strouse, and Linda S. Hirst pp 2067–2072 DOI: 10.1021/ja710305c

Metallosupramolecular Polyelectrolytes Self-Assembled from Various Pyridine Ring-Substituted Bisterpyridines and Metal Ions:  Photophysical, Electrochemical, and Electrochromic Properties Fu She Han, Masayoshi Higuchi, and Dirk G. Kurth pp 2073–2081 DOI: 10.1021/ja710380a Supporting Info

C-Glycosylation Reactions of Sulfur-Substituted Glycosyl Donors:  Evidence against the Role of Neighboring-Group Participation Matthew G. Beaver, Susan B. Billings, and K. A. Woerpel pp 2082–2086 DOI: 10.1021/ja0767783 Supporting Info

Evolution of a Synthetic Strategy:  Total Synthesis of (±)-Welwitindolinone A Isonitrile Sarah E. Reisman, Joseph M. Ready, Matthew M. Weiss, Atsushi Hasuoka, Makoto Hirata, Kazuhiko Tamaki, Timo V. Ovaska, Catherine J. Smith, and John L. Wood pp 2087–2100 DOI: 10.1021/ja076663z Supporting Info

Effects of Macromolecular Crowding on Glycoprotein Processing Enzymes Kiichiro Totani, Yoshito Ihara, Ichiro Matsuo, and Yukishige Ito pp 2101–2107 DOI: 10.1021/ja077570k

Metal−Organic Coordination Interactions in Fe−Terephthalic Acid Networks on Cu(100) Steven L. Tait, Yeliang Wang, Giovanni Costantini, Nian Lin, Alessandro Baraldi, Friedrich Esch, Luca Petaccia, Silvano Lizzit, and Klaus Kern pp 2108–2113 DOI: 10.1021/ja0778186 Supporting Info

Concise, Asymmetric, Stereocontrolled Total Synthesis of Stephacidins A, B, and Notoamide B [J. Am. Chem. Soc. 2007, 129, 6336−6342]. p 2114 DOI: 10.1021/ja710740t Supporting Info

Organic Reactions, Volume 69 Editor-in-Chief:  Larry E. Overman (University of California, Irvine) John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. viii + 704 pp. $135.00. ISBN 978-0-470-22397-0. p 2115 DOI: 10.1021/ja711337y

Corrosion Handbook:  Corrosive Agents and Their Interaction with Materials. Volume 9:  Potassium Hydroxide, Ammonium and Ammonium Hydroxide. Completely Revised and Extended 2nd ed Edited by Gerhard Kreysa and Michael Schütze (DECHEMA e.V., Frankfurt, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim and DECHEMA e.V:  Frankfurt. 2007. xiv + 554 pp. $510. ISBN 978-3-527-31125-5. p 2115 DOI: 10.1021/ja800017r

Japanese-English Chemical Dictionary:  Including a Guide to Japanese Patents and Scientific Literature Edited by Markus Gewehr (BASF AG, Limburgerhof, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xviii + 662 pp. $215.00. ISBN 978-3-527-31293-1. p 2115 DOI: 10.1021/ja8000419

Photochemistry and Photophysics of Coordination Compounds I. Topics in Current Chemistry, 280 Edited by Vincenzo Balzani (Università di Bologna, Italy) and Sebastiano Campagna (Università di Messina, Italy) Springer:  Berlin, Heidelberg, New York. 2007. xiv + 274 pp. $269.00. ISBN 978-3-540-73346-1. Patrick E. Hoggard pp 2115–2116 DOI: 10.1021/ja0770227

Issue 07

Thermal and Catalytic Transylidations between Halonium Ylides and Synthesis and Reaction of Stable Aliphatic Chloronium Ylides Masahito Ochiai, Norihiro Tada, Takuya Okada, Atushi Sota, and Kazunori Miyamoto pp 2118–2119 DOI: 10.1021/ja074624h Supporting Info

An Effective Friedel−Crafts Postfunctionalization of Poly(N-vinylcarbazole) to Tune Carrier Transportation of Supramolecular Organic Semiconductors Based on π-Stacked Polymers for Nonvolatile Flash Memory Cell Ling-Hai Xie, Qi-Dan Ling, Xiao-Ya Hou, and Wei Huang pp 2120–2121 DOI: 10.1021/ja076720o Supporting Info

Synthesis, Characterization, and Application of Iodoacetamide Derivatives Utilized for the ALiPHAT Strategy D. Keith Williams, Jr., Corey W. Meadows, Ibrahim D. Bori, Adam M. Hawkridge, Daniel L. Comins, and David C. Muddiman pp 2122–2123 DOI: 10.1021/ja076849y Supporting Info

Petrobactin-Mediated Iron Transport in Pathogenic Bacteria:  Coordination Chemistry of an Unusual 3,4-Catecholate/Citrate Siderophore1 Rebecca J. Abergel, Anna M. Zawadzka, and Kenneth N. Raymond pp 2124–2125 DOI: 10.1021/ja077202g Supporting Info

The Effect of Charge on CO Binding in Rhodium Carbonyls:  From Bridging to Terminal CO Ingmar Swart, Frank M. F. de Groot, Bert M. Weckhuysen, David M. Rayner, Gerard Meijer, and André Fielicke pp 2126–2127 DOI: 10.1021/ja0772795 Supporting Info

Substrate Binding Triggers a Switch in the Iron Coordination in Dehaloperoxidase from Amphitrite ornata:  HYSCORE Experiments Tatyana I. Smirnova, Ralph T. Weber, Mike F. Davis, and Stefan Franzen pp 2128–2129 DOI: 10.1021/ja0772952 Supporting Info

The Role of πσ* Excited States in Electron-Induced DNA Strand Break Formation:  A Time-Dependent Density Functional Theory Study Anil Kumar and Michael D. Sevilla pp 2130–2131 DOI: 10.1021/ja077331x Supporting Info

Peptide−Sugar Ligation Catalyzed by Transpeptidase Sortase:  A Facile Approach to Neoglycoconjugate Synthesis Sharmishtha Samantaray, Uttara Marathe, Sayani Dasgupta, Vinay K. Nandicoori, and Rajendra P. Roy pp 2132–2133 DOI: 10.1021/ja077358g Supporting Info

Aligned Inclusion of Dipolar Dyes into Zeolite Channels by Inclusion in the Excited State Hyun Sung Kim, Tung Thanh Pham, and Kyung Byung Yoon pp 2134–2135 DOI: 10.1021/ja0774820 Supporting Info

Selective Formation of a Symmetric Sc3N@C78 Bisadduct:  Adduct Docking Controlled by an Internal Trimetallic Nitride Cluster Ting Cai, Liaosa Xu, Chunying Shu, Hunter A. Champion, Jonathan E. Reid, Clemens Anklin, Mark R. Anderson, Harry W. Gibson, and Harry C. Dorn pp 2136–2137 DOI: 10.1021/ja077630m Supporting Info

Selective Detection of Protein Secondary Structural Changes in Solution Protein−Polysaccharide Complexes Using Vibrational Circular Dichroism (VCD) Timothy R. Rudd, Richard J. Nichols, and Edwin A. Yates pp 2138–2139 DOI: 10.1021/ja077675n Supporting Info

Lipid−Protein Nanoscale Bilayers:  A Versatile Medium for NMR Investigations of Membrane Proteins and Membrane-Active Peptides Ekaterina N. Lyukmanova, Zakhar O. Shenkarev, Alexander S. Paramonov, Alexander G. Sobol, Tatiana V. Ovchinnikova, Vladimir V. Chupin, Mikhail P. Kirpichnikov, Marcel J. J. Blommers, and Alexander S. Arseniev pp 2140–2141 DOI: 10.1021/ja0777988 Supporting Info

Shape-Control of Protein Crystals in Patterned Microwells Liying Wang, Min Hyung Lee, Jeremy Barton, Laura Hughes, and Teri W. Odom pp 2142–2143 DOI: 10.1021/ja077956v Supporting Info

Titanium and Zirconium Complexes of Robust Salophan Ligands. Coordination Chemistry and Olefin Polymerization Catalysis Shimrit Gendler, Ayellet L. Zelikoff, Jacob Kopilov, Israel Goldberg, and Moshe Kol pp 2144–2145 DOI: 10.1021/ja077998j Supporting Info

Wet-Stamped Precipitant Gradients Control the Growth of Protein Microcrystals in an Array of Nanoliter Wells Goher Mahmud, Kyle J. M. Bishop, Yuriy Chegel, Stoyan K. Smoukov, and Bartosz A. Grzybowski pp 2146–2147 DOI: 10.1021/ja078051k Supporting Info

Reversible Ethylene Dihydrogen Mediated 11-Vertex nido → closo → nido Conversion in a Metallathiaborane Cluster Álvaro Álvarez, Ramón Macías, María José Fabra, Fernando J. Lahoz, and Luis A. Oro pp 2148–2149 DOI: 10.1021/ja078197j Supporting Info

Oxidatively Intercepting Heck Intermediates:  Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes Dipannita Kalyani and Melanie S. Sanford pp 2150–2151 DOI: 10.1021/ja0782798 Supporting Info

Ultrafast Two Dimensional-Infrared Spectroscopy of a Molecular Monolayer Jens Bredenbeck, Avishek Ghosh, Marc Smits, and Mischa Bonn pp 2152–2153 DOI: 10.1021/ja710099c Supporting Info

Mesoporous Silica Nanospheres as Highly Efficient MRI Contrast Agents Kathryn M. L. Taylor, Jason S. Kim, William J. Rieter, Hongyu An, Weili Lin, and Wenbin Lin pp 2154–2155 DOI: 10.1021/ja710193c Supporting Info

Completing the Circuit:  Direct-Observe 13C,15N Double-Quantum Spectroscopy Permits Sequential Resonance Assignments near a Paramagnetic Center in Acireductone Dioxygenase Susan Sondej Pochapsky, Joel C. Sunshine, and Thomas C. Pochapsky pp 2156–2157 DOI: 10.1021/ja710187x Supporting Info

Enantioselective Direct Amination of α-Cyanoacetates Catalyzed by Bifunctional Chiral Ru and Ir Amido Complexes Yasuharu Hasegawa, Masahito Watanabe, Ilya D. Gridnev, and Takao Ikariya pp 2158–2159 DOI: 10.1021/ja710273s Supporting Info

Lithium Ions Intercalated into Pyrene-Functionalized Carbon Nanotubes and Their Mass Transport:  A Chemical Route to Carbon Nanotube Schottky Diode Hyunseob Lim, Hyeon Suk Shin, Hyun-Joon Shin, and Hee Cheul Choi pp 2160–2161 DOI: 10.1021/ja710314a Supporting Info

Metallic Wires of Lanthanum Atoms Inside Carbon Nanotubes Lunhui Guan, Kazu Suenaga, Shingo Okubo, Toshiya Okazaki, and Sumio Iijima pp 2162–2163 DOI: 10.1021/ja7103069 Supporting Info

Mechanistic Studies of IspH in the Deoxyxylulose Phosphate Pathway:  Heterolytic C−O Bond Cleavage at C4 Position Youli Xiao, Zongbao K. Zhao, and Pinghua Liu pp 2164–2165 DOI: 10.1021/ja710245d Supporting Info

Transition-State Interactions Revealed in Purine Nucleoside Phosphorylase by Binding Isotope Effects Andrew S. Murkin, Peter C. Tyler, and Vern L. Schramm pp 2166–2167 DOI: 10.1021/ja7104398 Supporting Info

Alkynes as Stille Reaction Pseudohalides:  Gold- and Palladium-Cocatalyzed Synthesis of Tri- and Tetra-Substituted Olefins Yili Shi, Sonja M. Peterson, Walter W. Haberaecker III, and Suzanne A. Blum pp 2168–2169 DOI: 10.1021/ja710648b Supporting Info

A Bench-Stable Homodinuclear Ni2−Schiff Base Complex for Catalytic Asymmetric Synthesis of α-Tetrasubstituted anti-α,β-Diamino Acid Surrogates Zhihua Chen, Hiroyuki Morimoto, Shigeki Matsunaga, and Masakatsu Shibasaki pp 2170–2171 DOI: 10.1021/ja710398q Supporting Info

A Chiral Bis-Sulfoxide Ligand in Late-Transition Metal Catalysis; Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins Ronaldo Mariz, Xinjun Luan, Michele Gatti, Anthony Linden, and Reto Dorta pp 2172–2173 DOI: 10.1021/ja710665q Supporting Info

Direct C(sp3)−O Reductive Elimination of Olefin Oxides from PtIV-Oxetanes Prepared by Aerobic Oxidation of PtII Olefin Derivatives (Olefin = cis-Cyclooctene, Norbornene) Julia R. Khusnutdinova, Laura L. Newman, Peter Y. Zavalij, Yiu-Fai Lam, and Andrei N. Vedernikov pp 2174–2175 DOI: 10.1021/ja7107323 Supporting Info

Cobalt-Mediated η5-Pentadienyl/Alkyne [5 + 2] Cycloaddition. Synthesis and Characterization of Unbridged η2,η3-Coordinated Cycloheptadienyl Complexes Ross D. Witherell, Kai E. O. Ylijoki, and Jeffrey M. Stryker pp 2176–2177 DOI: 10.1021/ja710568d Supporting Info

Synthesis and Spectroscopic Properties of a Prototype Single Molecule Dual Imaging Agent Comprising a Heterobimetallic Rhenium−Gadolinium Complex Thelma Koullourou, Louise S. Natrajan, Hiren Bhavsar, Simon J.A. Pope, Jianghua Feng, Johanna Narvainen, Rachel Shaw, Emma Scales, Risto Kauppinen, Alan M. Kenwright, and Stephen Faulkner pp 2178–2179 DOI: 10.1021/ja710859p Supporting Info

On the Sensitivity of f Electrons to Their Chemical Environment Eric Furet, Karine Costuas, Philippe Rabiller, and Olivier Maury pp 2180–2183 DOI: 10.1021/ja073224r Supporting Info

Optimization of Activity-Based Probes for Proteomic Profiling of Histone Deacetylase Complexes Cleo M. Salisbury and Benjamin F. Cravatt pp 2184–2194 DOI: 10.1021/ja074138u

Chemical Properties of Oxopropenyl Adducts of Purine and Pyrimidine Nucleosides and Their Reactivity toward Amino Acid Cross-Link Formation Joseph Szekely, Carmelo J. Rizzo, and Lawrence J. Marnett pp 2195–2201 DOI: 10.1021/ja074506u Supporting Info

Determination of Peptide Backbone Torsion Angles Using Double-Quantum Dipolar Recoupling Solid-State NMR Spectroscopy Manish A. Mehta, Matthew T. Eddy, Seth A. McNeill, Frank D. Mills, and Joanna R. Long pp 2202–2212 DOI: 10.1021/ja074244w Supporting Info

Dynamic Interplay between Diffusion and Reaction:  Nitrogen Recombination on Rh{211} in Car Exhaust Catalysis Oliver R. Inderwildi, Stephen J. Jenkins, and David A. King pp 2213–2220 DOI: 10.1021/ja0754913

Paramagnet Enhanced Nuclear Relaxation of H2 in Organic Solvents and in H2@C60 Elena Sartori, Marco Ruzzi, Nicholas J. Turro, Koichi Komatsu, Yasujiro Murata, Ronald G. Lawler, and Anatoly L. Buchachenko pp 2221–2225 DOI: 10.1021/ja076071g

Electrical Detection of Amine Ligation to a Metalloporphyrin via a Hybrid SOI-MOSFET Bharath R. Takulapalli, Gez M. Laws, Paul A. Liddell, Joakim Andréasson, Zach Erno, Devens Gust, and Trevor J. Thornton pp 2226–2233 DOI: 10.1021/ja076328a

Synthesis and Activity of Ruthenium Olefin Metathesis Catalysts Coordinated with Thiazol-2-ylidene Ligands Georgios C. Vougioukalakis and Robert H. Grubbs pp 2234–2245 DOI: 10.1021/ja075849v Supporting Info

Bimetallic Effects in Homopolymerization of Styrene and Copolymerization of Ethylene and Styrenic Comonomers:  Scope, Kinetics, and Mechanism Neng Guo, Charlotte L. Stern, and Tobin J. Marks pp 2246–2261 DOI: 10.1021/ja076407m Supporting Info

Reconsideration of Serum Ti(IV) Transport:  Albumin and Transferrin Trafficking of Ti(IV) and Its Complexes Arthur D. Tinoco, Emily V. Eames, and Ann M. Valentine pp 2262–2270 DOI: 10.1021/ja076364+ Supporting Info

Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy Igor V. Stiopkin, Himali D. Jayathilake, Andrey N. Bordenyuk, and Alexander V. Benderskii pp 2271–2275 DOI: 10.1021/ja076708w

Single Electron Transfer-Promoted Photocyclization Reactions of Linked Acceptor−Polydonor Systems:  Effects of Chain Length and Type on the Efficiencies of Macrocyclic Ring-Forming Photoreactions of Tethered α-Silyl Ether Phthalimide Substrates Dae Won Cho, Jung Hei Choi, Sun Wha Oh, Chunsheng Quan, Ung Chan Yoon, Runtang Wang, Shaorong Yang, and Patrick S. Mariano pp 2276–2284 DOI: 10.1021/ja076846l Supporting Info

Spectroscopic Determination of Hydrogenation Rates and Intermediates during Carbonyl Hydrogenation Catalyzed by Shvo's Hydroxycyclopentadienyl Diruthenium Hydride Agrees with Kinetic Modeling Based on Independently Measured Rates of Elementary Reactions Charles P. Casey, Sharon E. Beetner, and Jeffrey B. Johnson pp 2285–2295 DOI: 10.1021/ja077525c Supporting Info

Hydrogenation of Single-Wall Carbon Nanotubes Using Polyamine Reagents:  Combined Experimental and Theoretical Study Glen P. Miller, Jeremy Kintigh, Eunja Kim, Philippe F. Weck, Savas Berber, and David Tománek pp 2296–2303 DOI: 10.1021/ja0775366

The Dynamics of Carbene Solvation:  An Ultrafast Study of p-Biphenylyltrifluoromethylcarbene Jin Wang, Jacek Kubicki, Terry L. Gustafson, and Matthew S. Platz pp 2304–2313 DOI: 10.1021/ja077705m Supporting Info

Calcium Adsorption on MgO(100):  Energetics, Structure, and Role of Defects Junfa Zhu, Jason A. Farmer, Nancy Ruzycki, Lijun Xu, Charles T. Campbell, and Graeme Henkelman pp 2314–2322 DOI: 10.1021/ja077865y

On the Nature of Rate Acceleration in the Synthesis and Fragmentation of Triazolines by Brønsted Acid:  Secondary Catalysis by Water (Hydronium Triflate) Ki Bum Hong, Matthew G. Donahue, and Jeffrey N. Johnston pp 2323–2328 DOI: 10.1021/ja0779452 Supporting Info

Preparation and Configurational Stability of Chiral Chloro-[D1]methyllithiums of 98% Enantiomeric Excess Dagmar C. Kapeller and Friedrich Hammerschmidt pp 2329–2335 DOI: 10.1021/ja0779708 Supporting Info

Discovery, Characterization, and Optimization of an Unnatural Base Pair for Expansion of the Genetic Alphabet Aaron M. Leconte, Gil Tae Hwang, Shigeo Matsuda, Petr Capek, Yoshiyuki Hari, and Floyd E. Romesberg pp 2336–2343 DOI: 10.1021/ja078223d Supporting Info

Stability, Dynamics, and Selectivity in the Assembly of Hydrogen-Bonded Hexameric Capsules Elizabeth S. Barrett, Trevor J. Dale, and Julius Rebek, Jr. pp 2344–2350 DOI: 10.1021/ja078009p Supporting Info

Evolution of the Total Syntheses of Ustiloxin Natural Products and Their Analogues Pixu Li, Cory D. Evans, Yongzhong Wu, Bin Cao, Ernest Hamel, and Madeleine M. Joullié pp 2351–2364 DOI: 10.1021/ja710363p Supporting Info

A Mixed-Valence Polyoxovanadate(III,IV) Cluster with a Calixarene Cap Exhibiting Ferromagnetic V(III)−V(IV) Interactions Christophe Aronica, Guillaume Chastanet, Ekaterina Zueva, Serguei A. Borshch, Juan M. Clemente-Juan, and Dominique Luneau pp 2365–2371 DOI: 10.1021/ja078030q Supporting Info

Amphiphilic Poly(phenyleneethynylene)s Can Mimic Antimicrobial Peptide Membrane Disordering Effect by Membrane Insertion [J. Am. Chem. Soc. 2006, 128, 13123−13129]. Yuji Ishitsuka, Lachelle Arnt, Jaroslaw Majewski, Shelli L. Frey, Maria Ratajczak, Kristian Kjaer, Gregory N. Tew, and Ka Yee C. Lee p 2372 DOI: 10.1021/ja079952w

Stereospecific Cross-Coupling of α-(Thiocarbamoyl)organostannanes with Alkenyl, Aryl, and Heteroaryl Iodides [J. Am. Chem. Soc. 2007, 129, 790−793]. J. R. Falck, Paresh K. Patel, and Anish Bandyopadhyay p 2372 DOI: 10.1021/ja800047k

DNA-Induced Programmable Fusion of Phospholipid Vesicles [J. Am. Chem. Soc. 2007, 129, 9584−9585]. Gudrun Stengel, Raphael Zahn, and Fredrik Höök p 2372 DOI: 10.1021/ja800081w

Issue 08

Protein Sequence- and pH-Dependent Hydration Probed by Terahertz Spectroscopy Simon Ebbinghaus, Seung Joong Kim, Matthias Heyden, Xin Yu, Martin Gruebele, David M. Leitner, and Martina Havenith pp 2374–2375 DOI: 10.1021/ja0746520 Supporting Info

Stimuli-Free Auto-Modulated Material Release from Mesoporous Nanocompartment Films Qingmin Ji, Masahiko Miyahara, Jonathan P. Hill, Somobrata Acharya, Ajayan Vinu, Suk Bon Yoon, Jong-Sung Yu, Kazutami Sakamoto, and Katsuhiko Ariga pp 2376–2377 DOI: 10.1021/ja076139s Supporting Info

Origins of Differences in Reactivities of Alkenes, Alkynes, and Allenes in [Rh(CO)2Cl]2-Catalyzed (5 + 2) Cycloaddition Reactions with Vinylcyclopropanes Zhi-Xiang Yu, Paul Ha-Yeon Cheong, Peng Liu, Claude Y. Legault, Paul A. Wender, and K. N. Houk pp 2378–2379 DOI: 10.1021/ja076444d Supporting Info

Aptamer-Based Optical Probes with Separated Molecular Recognition and Signal Transduction Modules Na Li and Chih-Ming Ho pp 2380–2381 DOI: 10.1021/ja076787b Supporting Info

Enzyme-Responsive Snap-Top Covered Silica Nanocontainers Kaushik Patel, Sarah Angelos, William R. Dichtel, Ali Coskun, Ying-Wei Yang, Jeffrey I. Zink, and J. Fraser Stoddart pp 2382–2383 DOI: 10.1021/ja0772086 Supporting Info

Monodisperse Oligo(phenylene vinylene) Ligands on CdSe Quantum Dots:  Synthesis and Polarization Anisotropy Measurements P. K. Sudeep, Kevin T. Early, Kevin D. McCarthy, Michael Y. Odoi, Michael D. Barnes, and Todd Emrick pp 2384–2385 DOI: 10.1021/ja077409+ Supporting Info

Spiro-Aziridine and Bislactam Formation from Bisketene−Imine Cycloadditions Annette D. Allen, Jazmin Godoy, Nanyan Fu, Michelle Nagy, Sandra Spadaro, Thomas T. Tidwell, and Sinisa Vukovic pp 2386–2387 DOI: 10.1021/ja077623y Supporting Info

Catalytic Inactivation of Human Carbonic Anhydrase I by a Metallopeptide−Sulfonamide Conjugate is Mediated by Oxidation of Active Site Residues Nikhil H. Gokhale, Seth Bradford, and J. A. Cowan pp 2388–2389 DOI: 10.1021/ja0778038 Supporting Info

Dramatic Enhancement of Hyperpolarized Xenon-129 2D-NMR Exchange Cross-Peak Signals in Nanotubes by Interruption of the Gas Flow Chi-Yuan Cheng, Jessica Pfeilsticker, and Clifford R. Bowers pp 2390–2391 DOI: 10.1021/ja078031i

Surface Patterning with Fluorescent Molecules Using Click Chemistry Directed by Scanning Electrochemical Microscopy Sung-Yu Ku, Ken-Tsung Wong, and Allen J. Bard pp 2392–2393 DOI: 10.1021/ja078183d Supporting Info

A Rational Approach to Fluorescence “Turn-On” Sensing of α-Amino-carboxylates Dowook Ryu, Eunju Park, Dae-Sik Kim, Shihai Yan, Jin Yong Lee, Byoung-Yong Chang, and Kyo Han Ahn pp 2394–2395 DOI: 10.1021/ja078308e Supporting Info

How Does an SN2 Reaction Take Place in Solution? Full Ab Initio MD Simulations for the Hydrolysis of the Methyl Diazonium Ion Makoto Sato, Hiroshi Yamataka, Yuto Komeiji, Yuji Mochizuki, Takeshi Ishikawa, and Tatsuya Nakano pp 2396–2397 DOI: 10.1021/ja710038c Supporting Info

Real-Time Fluorescence Detection of Protein Transduction into Live Cells Ya-Jung Lee, Silpi Datta, and Jean-Philippe Pellois pp 2398–2399 DOI: 10.1021/ja7102026 Supporting Info

Asymmetric Methyl Group Labeling as a Probe of Membrane Protein Homo-oligomers by NMR Spectroscopy Nathaniel J. Traaseth, Raffaello Verardi, and Gianluigi Veglia pp 2400–2401 DOI: 10.1021/ja711499r Supporting Info

Electron−Electron Double Resonance-Detected NMR to Measure Metal Hyperfine Interactions:  61Ni in the Ni−B State of the [NiFe] Hydrogenase of Desulfovibrio vulgaris Miyazaki F Marco Flores, Aruna Goenka Agrawal, Maurice van Gastel, Wolfgang Gärtner, and Wolfgang Lubitz pp 2402–2403 DOI: 10.1021/ja077976x Supporting Info

Cryptand-like Porphyrinoid Assembled with Three Dipyrrylpyridine Chains:  Synthesis, Structure, and Homotropic Positive Allosteric Binding of Carboxylic Acids Jun-ichiro Setsune and Keigo Watanabe pp 2404–2405 DOI: 10.1021/ja710424n Supporting Info

Unraveling the Biosynthesis of the Sporolide Cyclohexenone Building Block Ryan P. McGlinchey, Markus Nett, and Bradley S. Moore pp 2406–2407 DOI: 10.1021/ja710488m Supporting Info

A Lanthanide Phosphinidene Complex:  Synthesis, Structure, and Phospha-Wittig Reactivity Jason D. Masuda, Kimberly C. Jantunen, Oleg V. Ozerov, Kevin J. T. Noonan, Derek P. Gates, Brian L. Scott, and Jaqueline L. Kiplinger pp 2408–2409 DOI: 10.1021/ja7105306 Supporting Info

An Electroactive Dynamically Polydisperse Supramolecular Dendrimer Gustavo Fernández, Emilio M. Pérez, Luis Sánchez, and Nazario Martín pp 2410–2411 DOI: 10.1021/ja710505h Supporting Info

A High-Resolution 43Ca Solid-State NMR Study of the Calcium Sites of Hydroxyapatite Danielle Laurencin, Alan Wong, John V. Hanna, Ray Dupree, and Mark E. Smith pp 2412–2413 DOI: 10.1021/ja710557t Supporting Info

A Ferrous Center as Reaction Site for Hydration of a Nitrile Group into a Carboxamide in Mild Conditions Nasser K. Thallaj, Juliette Przybilla, Richard Welter, and Dominique Mandon pp 2414–2415 DOI: 10.1021/ja710560g Supporting Info

Highly Diastereo- and Enantioselective Additions of Homoenolates to Nitrones Catalyzed by N-Heterocyclic Carbenes Eric M. Phillips, Troy E. Reynolds, and Karl A. Scheidt pp 2416–2417 DOI: 10.1021/ja710521m Supporting Info

C−H Bond Activation by Air-Stable [(Diimine)MII(μ2-OH)]22+ Dimers (M = Pd, Pt) Travis J. Williams, Andrew J. M. Caffyn, Nilay Hazari, Paul F. Oblad, Jay A. Labinger, and John E. Bercaw pp 2418–2419 DOI: 10.1021/ja076740q Supporting Info

The Chemical Vapor Deposition of Nickel Phosphide or Selenide Thin Films from a Single Precursor Arunkumar Panneerselvam, Mohammad. A. Malik, Mohammad Afzaal, Paul O'Brien, and Madeleine Helliwell pp 2420–2421 DOI: 10.1021/ja078202j Supporting Info

Enantioselective Diels−Alder Reaction of Simple α,β-Unsaturated Ketones with a Cinchona Alkaloid Catalyst Ravi P. Singh, Keith Bartelson, Yi Wang, Heng Su, Xiaojie Lu, and Li Deng pp 2422–2423 DOI: 10.1021/ja078251w Supporting Info

Oxygen and Base-Free Oxidative Heck Reactions of Arylboronic Acids with Olefins Jiwu Ruan, Xinming Li, Ourida Saidi, and Jianliang Xiao pp 2424–2425 DOI: 10.1021/ja0782955 Supporting Info

Separation of Racemate from Excess Enantiomer of Chiral Nonracemic Compounds via Density Gradient Ultracentrifugation Yitzhak Mastai, Antje Völkel, and Helmut Cölfen pp 2426–2427 DOI: 10.1021/ja067905i Supporting Info

NMR Detection of Bifurcated Hydrogen Bonds in Large Proteins Aizhuo Liu, Zhenwei Lu, Jifeng Wang, Lishan Yao, Yue Li, and Honggao Yan pp 2428–2429 DOI: 10.1021/ja710114r Supporting Info

Strontium-Catalyzed Highly Enantioselective Michael Additions of Malonates to Enones Magno Agostinho and Shū Kobayashi pp 2430–2431 DOI: 10.1021/ja710332h Supporting Info

Accurately Probing Slow Motions on Millisecond Timescales with a Robust NMR Relaxation Experiment Dong Long, Maili Liu, and Daiwen Yang pp 2432–2433 DOI: 10.1021/ja710477h Supporting Info

Brønsted Acid-Catalyzed Insertion of Aryldiazoacetates to sp2 Carbon−CHO Bond:  Facile Construction of Chiral All-Carbon Quaternary Center Takuya Hashimoto, Yuki Naganawa, and Keiji Maruoka pp 2434–2435 DOI: 10.1021/ja710532j Supporting Info

Intramolecular Acid−Base Catalysis of a Phosphate Diester:  Modeling the Ribonuclease Mechanism Elisa S. Orth, Tiago A. S. Brandão, Humberto M.S. Milagre, Marcos N. Eberlin, and Faruk Nome pp 2436–2437 DOI: 10.1021/ja710693x Supporting Info

Asymmetric Friedel−Crafts Alkylation of Pyrroles with Nitroalkenes Using a Dinuclear Zinc Catalyst Barry M. Trost and Christoph Müller pp 2438–2439 DOI: 10.1021/ja711080y Supporting Info

Polyfunctional Binding of Thymidine 5‘-Triphosphate with a Synthetic Polyammonium Receptor Containing Aromatic Groups. Crystal Structure of the Nucleotide−Receptor Adduct Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Enrico Faggi, Claudia Giorgi, Samuele Santarelli, and Barbara Valtancoli pp 2440–2441 DOI: 10.1021/ja7106977 Supporting Info

DNA Linker-Mediated Crystallization of Nanocolloids Huiming Xiong, Daniel van der Lelie, and Oleg Gang pp 2442–2443 DOI: 10.1021/ja710710j Supporting Info

High-Field EPR Reveals the Strongly Temperature-Dependent Exchange Interaction in “Breathing” Crystals Cu(hfac)2LR Sergey L. Veber, Matvey V. Fedin, Alexey I. Potapov, Ksenia Yu. Maryunina, Galina V. Romanenko, Renad Z. Sagdeev, Victor I. Ovcharenko, Daniella Goldfarb, and Elena G. Bagryanskaya pp 2444–2445 DOI: 10.1021/ja710773u Supporting Info

Probing Transient Copper Chaperone−Wilson Disease Protein Interactions at the Single-Molecule Level with Nanovesicle Trapping Jaime J. Benítez, Aaron M. Keller, Patrick Ochieng, Liliya A. Yatsunyk, David L. Huffman, Amy C. Rosenzweig, and Peng Chen pp 2446–2447 DOI: 10.1021/ja7107867 Supporting Info

A Strategy for C−H Activation of Pyridines:  Direct C-2 Selective Alkenylation of Pyridines by Nickel/Lewis Acid Catalysis Yoshiaki Nakao, Kyalo Stephen Kanyiva, and Tamejiro Hiyama pp 2448–2449 DOI: 10.1021/ja710766j Supporting Info

Influence of Remote Asymmetric Centers in Reversible Encapsulation Complexes Michael P. Schramm, Per Restorp, Felix Zelder, and Julius Rebek, Jr. pp 2450–2451 DOI: 10.1021/ja076162d Supporting Info

The Stereoselective Formation of Bicyclic Enamines with Bridgehead Unsaturation via Tandem C−H Bond Activation/Alkenylation/Electrocyclization Sirilata Yotphan, Robert G. Bergman, and Jonathan A. Ellman pp 2452–2453 DOI: 10.1021/ja710981b Supporting Info

Organoactinides Promote the Tishchenko Reaction:  The Myth of Inactive Actinide−Alkoxo Complexes Tamer Andrea, Eyal Barnea, and Moris S. Eisen pp 2454–2455 DOI: 10.1021/ja710843q Supporting Info

Organocatalytic Enantioselective Mannich-Type Reaction of Phosphorus Ylides:  Synthesis of Chiral N-Boc-β-Amino-α-methylene Carboxylic Esters Yan Zhang, Yan-Kai Liu, Tai-Ran Kang, Ze-Kai Hu, and Ying-Chun Chen pp 2456–2457 DOI: 10.1021/ja7114844 Supporting Info

A Functional Hydrogenase Model:  Reversible Interconversion of H2 and H2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium−Germanium Complex Tsuyoshi Matsumoto, Yukiko Nakaya, Naohisa Itakura, and Kazuyuki Tatsumi pp 2458–2459 DOI: 10.1021/ja711325f Supporting Info

High-Temperature Dehydrogenation of Brønsted Acid Sites in Zeolites Michael J. Nash, Anne Marie Shough, Dustin W. Fickel, Douglas J. Doren, and Raul F. Lobo pp 2460–2462 DOI: 10.1021/ja709978r Supporting Info

Metallocene-Catalyzed Polymerization of Methacrylates to Highly Syndiotactic Polymers at High Temperatures Yalan Ning and Eugene Y.-X. Chen pp 2463–2465 DOI: 10.1021/ja710822g Supporting Info

The Facile Generation of a Tetramethyleneethane Type Radical Cation and Biradical Utilizing a 3,4-Di(α-styryl)furan and a Photoinduced ET and Back ET Sequence Teruyo Ikeda, Hiroshi Ikeda, Yasutake Takahashi, Masafumi Yamada, Kazuhiko Mizuno, Shozo Tero-Kubota, and Seigo Yamauchi pp 2466–2472 DOI: 10.1021/ja074000b Supporting Info

A Three-State Model for the Photophysics of Guanine Luis Serrano-Andrés, Manuela Merchán, and Antonio Carlos Borin pp 2473–2484 DOI: 10.1021/ja0744450 Supporting Info

Efficient Exciton Transport in Layers of Self-Assembled Porphyrin Derivatives Annemarie Huijser, Bart M. J. M. Suijkerbuijk, Robertus J. M. Klein Gebbink, Tom J. Savenije, and Laurens D.A. Siebbeles pp 2485–2492 DOI: 10.1021/ja075162a Supporting Info

Rh(I)-Catalyzed Arylation of Heterocycles via C−H Bond Activation:  Expanded Scope through Mechanistic Insight Jared C. Lewis, Ashley M. Berman, Robert G. Bergman, and Jonathan A. Ellman pp 2493–2500 DOI: 10.1021/ja0748985 Supporting Info

Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile Xiao-Qing Zhu, Ming-Tian Zhang, Ao Yu, Chun-Hua Wang, and Jin-Pei Cheng pp 2501–2516 DOI: 10.1021/ja075523m Supporting Info

Metal−Peptide Frameworks (MPFs):  “Bioinspired” Metal Organic Frameworks Alexandre Mantion, Lars Massüger, Pierre Rabu, Cornelia Palivan, Lynne B. McCusker, and Andreas Taubert pp 2517–2526 DOI: 10.1021/ja0762588 Supporting Info

Crystal Structure and Growth Mechanism of Unusually Long Fullerene (C60) Nanowires Junfeng Geng, Wuzong Zhou, Paul Skelton, Wenbo Yue, Ian A. Kinloch, Alan H. Windle, and Brian F. G. Johnson pp 2527–2534 DOI: 10.1021/ja076392s

Phosphorescent Platinum Acetylide Organogelators Thomas Cardolaccia, Yongjun Li, and Kirk S. Schanze pp 2535–2545 DOI: 10.1021/ja0765316 Supporting Info

High Relaxivity Gadolinium Hydroxypyridonate−Viral Capsid Conjugates:  Nanosized MRI Contrast Agents1 Ankona Datta, Jacob M. Hooker, Mauro Botta, Matthew B. Francis, Silvio Aime, and Kenneth N. Raymond pp 2546–2552 DOI: 10.1021/ja0765363 Supporting Info

Molecular Conductance Switch-On of Single Ruthenium Complex Molecules Kyoungja Seo, Alexander V. Konchenko, Junghyun Lee, Gyeong Sook Bang, and Hyoyoung Lee pp 2553–2559 DOI: 10.1021/ja077089u Supporting Info

Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert-Butylmethylphosphino)(di-tert-butylphosphino)methane:  Scope of Enantioselectivity and Mechanistic Study Ilya D. Gridnev, Tsuneo Imamoto, Garrett Hoge, Mitsuhiro Kouchi, and Hidetoshi Takahashi pp 2560–2572 DOI: 10.1021/ja076542z Supporting Info

B2(BO)22- Diboronyl Diborene:  A Linear Molecule with a Triple Boron−Boron Bond Si-Dian Li, Hua-Jin Zhai, and Lai-Sheng Wang pp 2573–2579 DOI: 10.1021/ja0771080 Supporting Info

Probing the Planar Tetra-, Penta-, and Hexacoordinate Carbon in Carbon−Boron Mixed Clusters Yong Pei and Xiao Cheng Zeng pp 2580–2592 DOI: 10.1021/ja077139v Supporting Info

Three State Redox-Active Molecular Shuttle That Switches in Solution and on a Surface Giulia Fioravanti, Natalia Haraszkiewicz, Euan R. Kay, Sandra M. Mendoza, Carlo Bruno, Massimo Marcaccio, Piet G. Wiering, Francesco Paolucci, Petra Rudolf, Albert M. Brouwer, and David A. Leigh pp 2593–2601 DOI: 10.1021/ja077223a Supporting Info

NMR Studies of the Dynamics of a Bifunctional Rhodamine Probe Attached to Troponin C Olivier Julien, Pascal Mercier, Leo Spyracopoulos, John E. T. Corrie, and Brian D. Sykes pp 2602–2609 DOI: 10.1021/ja0772694

Selective Oxidation on Metallic Carbon Nanotubes by Halogen Oxoanions Seon-Mi Yoon, Sung Jin Kim, Hyeon-Jin Shin, Anass Benayad, Seong Jae Choi, Ki Kang Kim, Soo Min Kim, Yong Jin Park, Gunn Kim, Jae-Young Choi, and Young Hee Lee pp 2610–2616 DOI: 10.1021/ja077449d Supporting Info

Structural Analysis of Bikunin Glycosaminoglycan Lianli Chi, Jeremy J. Wolff, Tatiana N. Laremore, Odile F. Restaino, Jin Xie, Chiara Schiraldi, Toshihiko Toida, I. Jonathan Amster, and Robert J. Linhardt pp 2617–2625 DOI: 10.1021/ja0778500 Supporting Info

Stable Luminescence from Individual Carbon Nanotubes in Acidic, Basic, and Biological Environments Juan G. Duque, Laurent Cognet, A. Nicholas G. Parra-Vasquez, Nolan Nicholas, Howard K. Schmidt, and Matteo Pasquali pp 2626–2633 DOI: 10.1021/ja0777234 Supporting Info

Phenylalanine near Inorganic Surfaces:  Conformational Statistics vs Specific Chemistry Luca M. Ghiringhelli and Luigi Delle Site pp 2634–2638 DOI: 10.1021/ja077817d

Rapid and Accurate Prediction of Binding Free Energies for Saquinavir-Bound HIV-1 Proteases Ileana Stoica, S. Kashif Sadiq, and Peter V. Coveney pp 2639–2648 DOI: 10.1021/ja0779250 Supporting Info

Transition State Structure of E. coli tRNA-Specific Adenosine Deaminase Minkui Luo and Vern L. Schramm pp 2649–2655 DOI: 10.1021/ja078008x Supporting Info

Harnessing the Chemical Activation Inherent to Carrier Protein-Bound Thioesters for the Characterization of Lipopeptide Fatty Acid Tailoring Enzymes Florian Kopp, Uwe Linne, Markus Oberthür, and Mohamed A. Marahiel pp 2656–2666 DOI: 10.1021/ja078081n Supporting Info

Probing Chemical Shifts of Invisible States of Proteins with Relaxation Dispersion NMR Spectroscopy: How Well Can We Do? D. Flemming Hansen, Pramodh Vallurupalli, Patrik Lundström, Philipp Neudecker, and Lewis E. Kay pp 2667–2675 DOI: 10.1021/ja078337p Supporting Info

One-Step Controllable Synthesis for High-Quality Ultrafine Metal Oxide Semiconductor Nanocrystals via a Separated Two-Phase Hydrolysis Reaction Kangjian Tang, Jianan Zhang, Wenfu Yan, Zhonghua Li, Yangdong Wang, Weimin Yang, Zaiku Xie, Taolei Sun, and Harald Fuchs pp 2676–2680 DOI: 10.1021/ja0778702 Supporting Info

Temperature-Induced Self-Pinning and Nanolayering of AuSi Eutectic Droplets Nicola Ferralis, Roya Maboudian, and Carlo Carraro pp 2681–2685 DOI: 10.1021/ja7101983 Supporting Info

Assessment of Chemically Separated Carbon Nanotubes for Nanoelectronics Li Zhang, Sasa Zaric, Xiaomin Tu, Xinran Wang, Wei Zhao, and Hongjie Dai pp 2686–2691 DOI: 10.1021/ja7106492

[Re(η5-C5H5)(CO)3]+ Family of 17-Electron Compounds:  Monomer/Dimer Equilibria and Other Reactions Daesung Chong, Derek R. Laws, Ayman Nafady, Paulo Jorge Costa, Arnold L. Rheingold, Maria José Calhorda, and William E. Geiger pp 2692–2703 DOI: 10.1021/ja710513n Supporting Info

Green Chemistry and Catalysis By Roger A. Sheldon, Isabel W. C. E. Arends, and Ulf Hanefeld (Delft University of Technology, The Netherlands). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xiv + 434 pp. $190. ISBN 978-3-527-30715-9. Patricia Ann Mabrouk p 2704 DOI: 10.1021/ja0769705

Issue 09

Chromophore Fluorination Enhances Crystallization and Stability of Soluble Anthradithiophene Semiconductors Sankar Subramanian, Sung Kyu Park, Sean R. Parkin, Vitaly Podzorov, Thomas N. Jackson, and John E. Anthony pp 2706–2707 DOI: 10.1021/ja073235k Supporting Info

Diastereoselective Cyclopropanation of Ketone Enols with Fischer Carbene Complexes José Barluenga, Marcos G. Suero, Iván Pérez-Sánchez, and Josefa Flórez pp 2708–2709 DOI: 10.1021/ja074363b Supporting Info

Stoichiometric Functionalization of Gold Nanoparticles in Solution through a Free Radical Polymerization Approach Christian Krüger, Seema Agarwal, and Andreas Greiner pp 2710–2711 DOI: 10.1021/ja0763495 Supporting Info

Elucidating the Protonation Site of Vanadium Peroxide Complexes and the Implications for Biomimetic Catalysis Curtis J. Schneider, James E. Penner-Hahn, and Vincent L. Pecoraro pp 2712–2713 DOI: 10.1021/ja077404c Supporting Info

Azafullerene Encapsulated Single-Walled Carbon Nanotubes with n-Type Electrical Transport Property Toshiro Kaneko, Yongfeng Li, Shohei Nishigaki, and Rikizo Hatakeyama pp 2714–2715 DOI: 10.1021/ja0773960 Supporting Info

Thermodynamics of Hydrogen Atom Transfer to a High-Valent Iron Imido Complex Ismael Nieto, Feizhi Ding, Ranko P. Bontchev, Haobin Wang, and Jeremy M. Smith pp 2716–2717 DOI: 10.1021/ja0776834 Supporting Info

Sub-100 nm Patterning of Supported Bilayers by Nanoshaving Lithography Jinjun Shi, Jixin Chen, and Paul S. Cremer pp 2718–2719 DOI: 10.1021/ja077730s Supporting Info

Preferential Trapping of C60 in Nanomesh Voids Hong Liang Zhang, Wei Chen, Han Huang, Lan Chen, and Andrew Thye Shen Wee pp 2720–2721 DOI: 10.1021/ja710009q

Total Synthesis of (+)-Superstolide A Mariola Tortosa, Neal A. Yakelis, and William R. Roush pp 2722–2723 DOI: 10.1021/ja710238h Supporting Info

Efficient Photocatalytic Decomposition of Acetaldehyde over a Solid-Solution Perovskite (Ag0.75Sr0.25)(Nb0.75Ti0.25)O3 under Visible-Light Irradiation Defa Wang, Tetsuya Kako, and Jinhua Ye pp 2724–2725 DOI: 10.1021/ja710805x Supporting Info

Calculations Find That Tunneling Plays a Major Role in the Reductive Elimination of Methane from Hydridomethylbis(trimethylphosphine)platinum:  How to Confirm This Computational Prediction Experimentally Ayan Datta, David A. Hrovat, and Weston Thatcher Borden pp 2726–2727 DOI: 10.1021/ja710260v Supporting Info

Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine Karen J. Blackmore, Neetu Lal, Joseph W. Ziller, and Alan F. Heyduk pp 2728–2729 DOI: 10.1021/ja710611v Supporting Info

Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor Celine Largeot, Cristelle Portet, John Chmiola, Pierre-Louis Taberna, Yury Gogotsi, and Patrice Simon pp 2730–2731 DOI: 10.1021/ja7106178 Supporting Info

Concentration as the Switch for Chiral Recognition in Biomembrane Models Cecilia Bombelli, Carlotta Bernardini, Gioia Elemento, Giovanna Mancini, Alessandro Sorrenti, and Claudio Villani pp 2732–2733 DOI: 10.1021/ja710687e

Probing Structure in Invisible Protein States with Anisotropic NMR Chemical Shifts Pramodh Vallurupalli, D. Flemming Hansen, and Lewis E. Kay pp 2734–2735 DOI: 10.1021/ja710817g Supporting Info

Formation of CeO2−ZrO2 Solid Solution Nanocages with Controllable Structures via Kirkendall Effect Xin Liang, Xun Wang, Yuan Zhuang, Biao Xu, Simin Kuang, and Yadong Li pp 2736–2737 DOI: 10.1021/ja7109629 Supporting Info

Enantioselective Synthesis of Bicyclo[2.2.2]octenones Using a Copper-Mediated Oxidative Dearomatization/[4 + 2] Dimerization Cascade1 Suwei Dong, Jianglong Zhu, and John A. Porco, Jr. pp 2738–2739 DOI: 10.1021/ja711018z Supporting Info

Direct Amination of Homoenolates Catalyzed by N-Heterocyclic Carbenes Audrey Chan and Karl A. Scheidt pp 2740–2741 DOI: 10.1021/ja711130p Supporting Info

A Templating Approach for Monodisperse Self-Assembled Organic Nanostructures Steve R. Bull, Liam C. Palmer, Nathaniel J. Fry, Megan A. Greenfield, Benjamin W. Messmore, Thomas J. Meade, and Samuel I. Stupp pp 2742–2743 DOI: 10.1021/ja710749q Supporting Info

Selective Optical Recognition and Quantification of Parts Per Million Levels of Cr6+ in Aqueous and Organic Media by Immobilized Polypyridyl Complexes on Glass Graham de Ruiter, Tarkeshwar Gupta, and Milko E. van der Boom pp 2744–2745 DOI: 10.1021/ja7110527 Supporting Info

Diastereo- and Enantioselective Hydrogenative Aldol Coupling of Vinyl Ketones:  Design of Effective Monodentate TADDOL-Like Phosphonite Ligands Cisco Bee, Soo Bong Han, Abbas Hassan, Hiroki Iida, and Michael J. Krische pp 2746–2747 DOI: 10.1021/ja710862u Supporting Info

Conducting Ferrocene Monolayers on Nonconducting Surfaces Fanny Hauquier, Jalal Ghilane, Bruno Fabre, and Philippe Hapiot pp 2748–2749 DOI: 10.1021/ja711147f Supporting Info

Plasmon-Based Nanolenses Assembled on a Well-Defined DNA Template Sébastien Bidault, F. Javier García de Abajo, and Albert Polman pp 2750–2751 DOI: 10.1021/ja711074n Supporting Info

Palladium-Catalyzed Dehydrogenative Cis Double Phosphorylation of Alkynes with H-Phosphonate Leading to (Z)-Bisphosphoryl-1-alkenes Li-Biao Han, Yutaka Ono, and Shigeru Shimada pp 2752–2753 DOI: 10.1021/ja7108272 Supporting Info

Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates Rachel H. Munday, Joseph R. Martinelli, and Stephen L. Buchwald pp 2754–2755 DOI: 10.1021/ja711449e Supporting Info

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary Allylic Chlorides with Alkylzincs Sunghee Son and Gregory C. Fu pp 2756–2757 DOI: 10.1021/ja800103z Supporting Info

Isomeric Metamorphosis:  Si3E (E = S, Se, and Te) Bicyclo[1.1.0]butane and Cyclobutene Vladimir Ya. Lee, Shogo Miyazaki, Hiroyuki Yasuda, and Akira Sekiguchi pp 2758–2759 DOI: 10.1021/ja800111r Supporting Info

Chemical State and Environment of Boron Dopant in B,N-Codoped Anatase TiO2 Nanoparticles:  An Avenue for Probing Diamagnetic Dopants in TiO2 by Electron Paramagnetic Resonance Spectroscopy Neeruganti O. Gopal, Hsin-Hsi Lo, and Shyue-Chu Ke pp 2760–2761 DOI: 10.1021/ja711424d Supporting Info

Structural Disorder and Diffusional Pathway of Oxide Ions in a Doped Pr2NiO4-Based Mixed Conductor Masatomo Yashima, Makiko Enoki, Takahiro Wakita, Roushown Ali, Yoshitaka Matsushita, Fujio Izumi, and Tatsumi Ishihara pp 2762–2763 DOI: 10.1021/ja711478h Supporting Info

Gold-Catalyzed Intermolecular Hetero-Dehydro-Diels−Alder Cycloaddition of Captodative Dienynes with Nitriles:  A New Reaction and Regioselective Direct Access to Pyridines José Barluenga, Manuel Ángel Fernández-Rodríguez, Patricia García-García, and Enrique Aguilar pp 2764–2765 DOI: 10.1021/ja7112917 Supporting Info

Accessing the Triplet Excited State in Perylenediimides Aaron A. Rachford, Sébastien Goeb, and Felix N. Castellano pp 2766–2767 DOI: 10.1021/ja800333y Supporting Info

Influence of Extreme Thermodynamic Conditions and Pyrite Surfaces on Peptide Synthesis in Aqueous Media Eduard Schreiner, Nisanth N. Nair, and Dominik Marx pp 2768–2770 DOI: 10.1021/ja7108085 Supporting Info

General Method for the Expedient Synthesis of Salt-Free Diorganozinc Reagents Using Zinc Methoxide Alexandre Côté and André B. Charette pp 2771–2773 DOI: 10.1021/ja710864p Supporting Info

Hydrogen Atom Transfer Reactions of Iron−Porphyrin−Imidazole Complexes as Models for Histidine-Ligated Heme Reactivity Jeffrey J. Warren and James M. Mayer pp 2774–2776 DOI: 10.1021/ja711057t Supporting Info

The “Staple” Motif:  A Key to Stability of Thiolate-Protected Gold Nanoclusters De-en Jiang, Murilo L. Tiago, Weidong Luo, and Sheng Dai pp 2777–2779 DOI: 10.1021/ja710991n Supporting Info

A One-Step Homogeneous Immunoassay for Cancer Biomarker Detection Using Gold Nanoparticle Probes Coupled with Dynamic Light Scattering Xiong Liu, Qiu Dai, Lauren Austin, Janelle Coutts, Genevieve Knowles, Jianhua Zou, Hui Chen, and Qun Huo pp 2780–2782 DOI: 10.1021/ja711298b Supporting Info

A Direct Route to Fluostatin C by a Fascinating Diels−Alder Reaction Maolin Yu and Samuel J. Danishefsky pp 2783–2785 DOI: 10.1021/ja7113757 Supporting Info

Mechanistic Studies of a Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes:  Protonolysis of a Stable Palladium Alkyl Complex Is the Turnover-Limiting Step Brian M. Cochran and Forrest E. Michael pp 2786–2792 DOI: 10.1021/ja0734997 Supporting Info

Autocatalytic Water Dissociation on Cu(110) at Near Ambient Conditions Klas Andersson, Guido Ketteler, Hendrik Bluhm, Susumu Yamamoto, Hirohito Ogasawara, Lars G. M. Pettersson, Miquel Salmeron, and Anders Nilsson pp 2793–2797 DOI: 10.1021/ja073727x Supporting Info

Enthalpy−Entropy Compensation Reveals Solvent Reorganization as a Driving Force for Supramolecular Encapsulation in Water Dennis H. Leung, Robert G. Bergman, and Kenneth N. Raymond pp 2798–2805 DOI: 10.1021/ja075975z Supporting Info

Charge-Separation in Uranium Diazomethane Complexes Leading to C−H Activation and Chemical Transformation Oanh P. Lam, Patrick L. Feng, Frank W. Heinemann, Joseph M. O'Connor, and Karsten Meyer pp 2806–2816 DOI: 10.1021/ja0766472

Role of the Active-Site Solvent in the Thermodynamics of Factor Xa Ligand Binding Robert Abel, Tom Young, Ramy Farid, Bruce J. Berne, and Richard A. Friesner pp 2817–2831 DOI: 10.1021/ja0771033 Supporting Info

Self-delivering Nanoemulsions for Dual Fluorine-19 MRI and Fluorescence Detection Jelena M. Janjic, Mangala Srinivas, Deepak K. K. Kadayakkara, and Eric T. Ahrens pp 2832–2841 DOI: 10.1021/ja077388j Supporting Info

Pressure-Induced Hydration and Order−Disorder Transition in a Synthetic Potassium Gallosilicate Zeolite with Gismondine Topology Yongjae Lee, Sun Jin Kim, Chi-Chang Kao, and Thomas Vogt pp 2842–2850 DOI: 10.1021/ja077443o Supporting Info

A 1,2-d(GpG) Cisplatin Intrastrand Cross-Link Influences the Rotational and Translational Setting of DNA in Nucleosomes Matthias Ober and Stephen J. Lippard pp 2851–2861 DOI: 10.1021/ja710220x Supporting Info

Adsorption of a Statherin Peptide Fragment on the Surface of Nanocrystallites of Hydroxyapatite Peng-Huan Chen, Yao-Hung Tseng, Yun Mou, Yi-Ling Tsai, Syuan-Ming Guo, Shing-Jong Huang, Steve S.-F. Yu, and Jerry C. C. Chan pp 2862–2868 DOI: 10.1021/ja076607y Supporting Info

Single-Crystal to Single-Crystal Structural Transformation and Photomagnetic Properties of a Porous Iron(II) Spin-Crossover Framework Suzanne M. Neville, Gregory J. Halder, Karena W. Chapman, Martin B. Duriska, Peter D. Southon, John D. Cashion, Jean-François Létard, Boujemaa Moubaraki, Keith S. Murray, and Cameron J. Kepert pp 2869–2876 DOI: 10.1021/ja077958f Supporting Info

A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand [J. Am. Chem. Soc. 2005, 127, 11948−11949]. Travis M. Anderson, Rui Cao, Elena Slonkina, Britt Hedman, Keith O. Hodgson, Kenneth I. Hardcastle, Wade A. Neiwert, Shaoxiong Wu, Martin L. Kirk, Sushilla Knottenbelt, Ezra C. Depperman, Bineta Keita, Louis Nadjo, Djamaladdin G. Musaev, Keiji Morokuma, and Craig L. Hill p 2877 DOI: 10.1021/ja711078v Supporting Info

Making Crystals By Design:  Methods, Techniques and Applications Edited by Dario Braga and Fabrizia Grepioni (University Bologna). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xiv + 348 pp. $190. ISBN 978-3-527-31506-2. K. Travis Holman p 2878 DOI: 10.1021/ja0769090

Endoglycosidases:  Biochemistry, Biotechnology, Application Edited by Masahiko Endo (Hirosaki University, Aomori, Japan), Sumihiro Hase (Osaka University, Osaka, Japan), Kenji Yamamoto (Kyoto University, Kyoto, Japan), and Keiichi Takagaki (Hirosaki University School of Medicine, Aomori, Japan). Kodansha Ltd:  Tokyo and Springer:  Berlin, Heidelberg, New York. 2006. xvi + 255 pp. $169.00. ISBN 4-06-212192-2 (Kodansha) and 3-540-34494-2 (Springer). Robin Polt, Ph.D. pp 2878–2879 DOI: 10.1021/ja076925x

Heterocycles from Carbohydrate Precursors. Topics in Heterocyclic Chemistry, 07 Edited by El Sayed H. El Ashry (Alexandria University, Egypt). Series Edited by R. R. Gupta. Springer:  Berlin, Heidelberg, New York. 2007. xii + 354 pp. $349.00. ISBN 3-540-72956-3. Cecilia H. Marzabadi p 2879 DOI: 10.1021/ja077015i

Advances in Chemical Physics, Volume 136 Edited by Stuart A. Rice (The University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 318 pp. $175. ISBN 978-0-471-68232-5. James M. Lisy pp 2879–2880 DOI: 10.1021/ja077010l

Analytical Instrumentation:  A Guide to Laboratory, Portable and Miniaturized Instruments By Gillian McMahon (Dublin City University, Ireland). John Wiley & Sons, Ltd:  Chichester. 2007. xxii + 296 pp. $100. ISBN 978-0-470-02795-0. p 2880 DOI: 10.1021/ja800425v

Progress in Inorganic Chemistry, Volume 55 Edited by Kenneth D. Karlin (Johns Hopkins University, Baltimore, MD). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. vi + 760 pp. $175.00. ISBN 978-0-471-68242-4. Pradip Mascharak pp 2880–2882 DOI: 10.1021/ja077001c

Issue 10

A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN)7]3- Danna E. Freedman, David M. Jenkins, Anthony T. Iavarone, and Jeffrey R. Long pp 2884–2885 DOI: 10.1021/ja077527x Supporting Info

Superconductivity in the AlB2-Type Ternary Rare-Earth Silicide YbGa1.1Si0.9 Motoharu Imai, Akira Sato, Takeshi Aoyagi, Takashi Kimura, Yoshitaka Matsushita, and Naohito Tsujii pp 2886–2887 DOI: 10.1021/ja077669r Supporting Info

Corrole as a Binucleating Ligand:  Preparation, Molecular Structure and Density Functional Theory Study of Diboron Corroles Amelia M. Albrett, Jeanet Conradie, Peter D. W. Boyd, George R. Clark, Abhik Ghosh, and Penelope J. Brothers pp 2888–2889 DOI: 10.1021/ja077785u Supporting Info

Semiconductor Quantum Dots as Two-Photon Sensitizers Smita Dayal and Clemens Burda pp 2890–2891 DOI: 10.1021/ja0781285

Cellular Uptake of a Fluorescent Calix[4]arene Derivative Ruth Lalor, Hugo Baillie-Johnson, Carl Redshaw, Susan E. Matthews, and Anja Mueller pp 2892–2893 DOI: 10.1021/ja0782596 Supporting Info

Predicting an Improvement of Secondary Catalytic Activity of Promiscuos Isochorismate Pyruvate Lyase by Computational Design Sergio Martí, Juan Andrés, Vicent Moliner, Estanislao Silla, Iñaki Tuñón, and Juan Bertrán pp 2894–2895 DOI: 10.1021/ja078334c Supporting Info

Solid-State Deuterium NMR Studies Reveal μs-ns Motions in the HIV-1 Transactivation Response RNA Recognition Site Greg L. Olsen, Dorothy C. Echodu, Zahra Shajani, Michael F. Bardaro, Jr., Gabriele Varani, and Gary P. Drobny pp 2896–2897 DOI: 10.1021/ja0778803 Supporting Info

Traceless Stereoinduction in the One-Pot Assembly of All Three Rings of Hexahydrodibenzopyrans Keith A. Korthals and William D. Wulff pp 2898–2899 DOI: 10.1021/ja077579m Supporting Info

Palladium-Catalyzed Methylation of Aryl C−H Bond by Using Peroxides Yuhua Zhang, Jianqing Feng, and Chao-Jun Li pp 2900–2901 DOI: 10.1021/ja0775063 Supporting Info

Designing Adsorbents for CO2 Capture from Flue Gas-Hyperbranched Aminosilicas Capable of Capturing CO2 Reversibly Jason C. Hicks, Jeffrey H. Drese, Daniel J. Fauth, McMahan L. Gray, Genggeng Qi, and Christopher W. Jones pp 2902–2903 DOI: 10.1021/ja077795v Supporting Info

Yttrium-Mediated Conversion of Vinyl Grignard Reagent to a 1,2-Dimetalated Ethane and Its Synthetic Application Ryoichi Tanaka, Hiroaki Sanjiki, and Hirokazu Urabe pp 2904–2905 DOI: 10.1021/ja077992u Supporting Info

Catalysis of Recombination and Its Limitation on Open Circuit Voltage for Dye Sensitized Photovoltaic Cells Using Phthalocyanine Dyes Brian C. O'Regan, Ismael López-Duarte, M. Victoria Martínez-Díaz, Amparo Forneli, Josep Albero, Ana Morandeira, Emilio Palomares, Tomás Torres, and James R. Durrant pp 2906–2907 DOI: 10.1021/ja078045o Supporting Info

Ruthenium-Catalyzed Vinylic Substitution Reactions with Nucleophiles via Butatrienylidene Intermediates Yoshihiro Yamauchi, Masahiro Yuki, Yoshiaki Tanabe, Yoshihiro Miyake, Youichi Inada, Sakae Uemura, and Yoshiaki Nishibayashi pp 2908–2909 DOI: 10.1021/ja710013y Supporting Info

Activity Increase of Horseradish Peroxidase in the Presence of Magnetic Particles Nikolaos G. Chalkias, Patarawan Kahawong, and Emmanuel P. Giannelis pp 2910–2911 DOI: 10.1021/ja7102263 Supporting Info

Bu2SnIH-Promoted Proximal Bond Cleavage of Methylenecyclopropanes and Successive Radical Cyclization and/or Pd-Catalyzed Coupling Reaction Naoki Hayashi, Yusuke Hirokawa, Ikuya Shibata, Makoto Yasuda, and Akio Baba pp 2912–2913 DOI: 10.1021/ja7103729 Supporting Info

Zn-Catalyzed Asymmetric Allylation for the Synthesis of Optically Active Allylglycine Derivatives. Regio- and Stereoselective Formal α-Addition of Allylboronates to Hydrazono Esters Mari Fujita, Takashi Nagano, Uwe Schneider, Tomoaki Hamada, Chikako Ogawa, and Shū Kobayashi pp 2914–2915 DOI: 10.1021/ja710627x Supporting Info

Rh-Catalyzed Carbonyl Hydroacylation:  An Enantioselective Approach to Lactones Zengming Shen, Hasan A. Khan, and Vy M. Dong pp 2916–2917 DOI: 10.1021/ja7109025 Supporting Info

Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity Masaki Daini, Akihiko Yamamoto, and Michinori Suginome pp 2918–2919 DOI: 10.1021/ja711160h Supporting Info

Cycloadditions of N-Sulfonyl Nitrones Generated by Lewis Acid Catalyzed Rearrangement of Oxaziridines Katherine M. Partridge, Mary E. Anzovino, and Tehshik P. Yoon pp 2920–2921 DOI: 10.1021/ja711335d Supporting Info

A Structurally Perfect S = 1/2 Metal−Organic Hybrid Kagomé Antiferromagnet Emily A. Nytko, Joel S. Helton, Peter Müller, and Daniel G. Nocera pp 2922–2923 DOI: 10.1021/ja709991u Supporting Info

Electrical Detection of TATA Binding Protein at DNA-Modified Microelectrodes Alon A. Gorodetsky, Ali Ebrahim, and Jacqueline K. Barton pp 2924–2925 DOI: 10.1021/ja7106756 Supporting Info

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles Nathalie Lebrasseur and Igor Larrosa pp 2926–2927 DOI: 10.1021/ja710731a Supporting Info

The Importance of Hydration for Inhibiting Ice Recrystallization with C-Linked Antifreeze Glycoproteins Pawel Czechura, Roger Y. Tam, Elena Dimitrijevic, Anastasia V. Murphy, and Robert N. Ben pp 2928–2929 DOI: 10.1021/ja7103262 Supporting Info

Imido Exchange in Bis(imido) Uranium(VI) Complexes with Aryl Isocyanates Liam P. Spencer, Ping Yang, Brian L. Scott, Enrique R. Batista, and James M. Boncella pp 2930–2931 DOI: 10.1021/ja7107454 Supporting Info

Reversible Single-Crystal-to-Single-Crystal Cross-Linking of a Ribbon of Cobalt Citrate Cubanes To Form a 2D Net Javier Campo, Larry R. Falvello, Isabel Mayoral, Fernando Palacio, Tatiana Soler, and Milagros Tomás pp 2932–2933 DOI: 10.1021/ja711040s Supporting Info

Split DNA Enzyme for Visual Single Nucleotide Polymorphism Typing Dmitry M. Kolpashchikov pp 2934–2935 DOI: 10.1021/ja711192e Supporting Info

DNA and RNA Can Be Equally Efficient Catalysts for Carbon−Carbon Bond Formation Madhavaiah Chandra and Scott K. Silverman pp 2936–2937 DOI: 10.1021/ja7111965 Supporting Info

Large and Stable Transmembrane Pores from Guanosine−Bile Acid Conjugates Ling Ma, Monica Melegari, Marco Colombini, and Jeffery T. Davis pp 2938–2939 DOI: 10.1021/ja7110702 Supporting Info

Ag−Au−Ag Heterometallic Nanorods Formed through Directed Anisotropic Growth Daeha Seo, Choong Il Yoo, Jongwook Jung, and Hyunjoon Song pp 2940–2941 DOI: 10.1021/ja711093j Supporting Info

MnO2/Poly(3,4-ethylenedioxythiophene) Coaxial Nanowires by One-Step Coelectrodeposition for Electrochemical Energy Storage Ran Liu and Sang Bok Lee pp 2942–2943 DOI: 10.1021/ja7112382 Supporting Info

Enzyme-Like Chemoselective Acylation of Alcohols in the Presence of Amines Catalyzed by a Tetranuclear Zinc Cluster Takashi Ohshima, Takanori Iwasaki, Yusuke Maegawa, Asako Yoshiyama, and Kazushi Mashima pp 2944–2945 DOI: 10.1021/ja711349r Supporting Info

Quadruple Helix Formation of a Photoresponsive Peptide Amphiphile and Its Light-Triggered Dissociation into Single Fibers Takahiro Muraoka, Honggang Cui, and Samuel I. Stupp pp 2946–2947 DOI: 10.1021/ja711213s Supporting Info

Minimally Cationic Cell-Permeable Miniature Proteins via α-Helical Arginine Display Betsy A. Smith, Douglas S. Daniels, Abigail E. Coplin, Gregory E. Jordan, Lynn M. McGregor, and Alanna Schepartz pp 2948–2949 DOI: 10.1021/ja800074v Supporting Info

Self-Assembly of a 3-D Triply Interlocked Chiral [2]Catenane Aleema Westcott, Julie Fisher, Lindsay P. Harding, Pierre Rizkallah, and Michaele J. Hardie pp 2950–2951 DOI: 10.1021/ja8002149 Supporting Info

Stabilization of the Collagen Triple Helix by O-Methylation of Hydroxyproline Residues Frank W. Kotch, Ilia A. Guzei, and Ronald T. Raines pp 2952–2953 DOI: 10.1021/ja800225k Supporting Info

An Unconventional Approach to the Enantioselective Synthesis of Caryophylloids Oleg V. Larionov and E. J. Corey pp 2954–2955 DOI: 10.1021/ja8003705 Supporting Info

Mechanistic Insights in the Reversal of Enantioselectivity of Chiral Catalysts by Achiral Catalysts in Asymmetric Autocatalysis François Lutz, Takashi Igarashi, Tomoyuki Kinoshita, Mai Asahina, Koichi Tsukiyama, Tsuneomi Kawasaki, and Kenso Soai pp 2956–2958 DOI: 10.1021/ja077156k Supporting Info

Neuroactive Chondroitin Sulfate Glycomimetics Manish Rawat, Cristal I. Gama, John B. Matson, and Linda C. Hsieh-Wilson pp 2959–2961 DOI: 10.1021/ja709993p Supporting Info

Palladium-Catalyzed Olefin Dioxygenation Yang Li, Datong Song, and Vy M. Dong pp 2962–2964 DOI: 10.1021/ja711029u Supporting Info

DNA-Directed Synthesis of Aniline and 4-Aminobiphenyl Oligomers:  Programmed Transfer of Sequence Information to a Conjoined Polymer Nanowire Bhaskar Datta and Gary B. Schuster pp 2965–2973 DOI: 10.1021/ja0726106 Supporting Info

Ultrafast Dynamics of Acetylacetone (2,4-Pentanedione) in the S2 State Lionel Poisson, Pascale Roubin, Stéphane Coussan, Benoît Soep, and Jean-Michel Mestdagh pp 2974–2983 DOI: 10.1021/ja0730819

Site-Specific Relaxation Kinetics of a Tryptophan Zipper Hairpin Peptide Using Temperature-Jump IR Spectroscopy and Isotopic Labeling Karin Hauser, Carsten Krejtschi, Rong Huang, Ling Wu, and Timothy A. Keiderling pp 2984–2992 DOI: 10.1021/ja074215l

Matrix Isolation, Spectroscopic Characterization, and Photoisomerization of m-Xylylene Patrik Neuhaus, Dirk Grote, and Wolfram Sander pp 2993–3000 DOI: 10.1021/ja073453d Supporting Info

Oxidation of 2‘-Deoxyguanosine 5‘-Monophosphate Photoinduced by Pterin:  Type I versus Type II Mechanism Gabriela Petroselli, M. Laura Dántola, Franco M. Cabrerizo, Alberto L. Capparelli, Carolina Lorente, Esther Oliveros, and Andrés H. Thomas pp 3001–3011 DOI: 10.1021/ja075367j Supporting Info

Direct Observation of the Ionization Step in Solvolysis Reactions:  Electrophilicity versus Electrofugality of Carbocations Heike F. Schaller, Alexander A. Tishkov, Xinliang Feng, and Herbert Mayr pp 3012–3022 DOI: 10.1021/ja0765464 Supporting Info

Versatile Synthesis Strategy for Carboxylic Acid−functionalized Upconverting Nanophosphors as Biological Labels Zhigang Chen, Huili Chen, He Hu, Mengxiao Yu, Fuyou Li, Qiang Zhang, Zhiguo Zhou, Tao Yi, and Chunhui Huang pp 3023–3029 DOI: 10.1021/ja076151k Supporting Info

Charge Carrier Formation in Polythiophene/Fullerene Blend Films Studied by Transient Absorption Spectroscopy Hideo Ohkita, Steffan Cook, Yeni Astuti, Warren Duffy, Steve Tierney, Weimin Zhang, Martin Heeney, Iain McCulloch, Jenny Nelson, Donal D. C. Bradley, and James R. Durrant pp 3030–3042 DOI: 10.1021/ja076568q Supporting Info

Mechanistic Studies on Pyridoxal Phosphate Synthase:  The Reaction Pathway Leading to a Chromophoric Intermediate Jeremiah W. Hanes, Kristin E. Burns, David G. Hilmey, Abhishek Chatterjee, Pieter C. Dorrestein, and Tadhg P. Begley pp 3043–3052 DOI: 10.1021/ja076604l

Role of Mg2+ in Hammerhead Ribozyme Catalysis from Molecular Simulation Tai-Sung Lee, Carlos Silva López, George M. Giambaşu, Monika Martick, William G. Scott, and Darrin M. York pp 3053–3064 DOI: 10.1021/ja076529e Supporting Info

Stabilization of Zwitterionic Structures of Amino Acids (Gly, Ala, Val, Leu, Ile, Ser and Pro) by Ammonium Ions in the Gas Phase Ronghu Wu and Terry B. McMahon pp 3065–3078 DOI: 10.1021/ja076685l Supporting Info

Crystal Design of Monometallic Single-Molecule Magnets Consisting of Cobalt-Aminoxyl Heterospins Shinji Kanegawa, Satoru Karasawa, Masataka Maeyama, Motohiro Nakano, and Noboru Koga pp 3079–3094 DOI: 10.1021/ja0767579 Supporting Info

Probing Local Structure in Zeolite Frameworks:  Ultrahigh-Field NMR Measurements and Accurate First-Principles Calculations of Zeolite 29Si Magnetic Shielding Tensors Darren H. Brouwer and Gary D. Enright pp 3095–3105 DOI: 10.1021/ja077430a Supporting Info

Self-Interaction Nanoparticle Spectroscopy:  A Nanoparticle-Based Protein Interaction Assay Peter M. Tessier, Jun Jinkoji, Yu-Chia Cheng, Jessica L. Prentice, and Abraham M. Lenhoff pp 3106–3112 DOI: 10.1021/ja077624q

Polymerized PolyHEMA Photonic Crystals:  pH and Ethanol Sensor Materials Xiangling Xu, Alexander V. Goponenko, and Sanford A. Asher pp 3113–3119 DOI: 10.1021/ja077979+

Unusual “Amphiphilic” Association of Hydrated Protons in Strong Acid Solution Feng Wang, Sergei Izvekov, and Gregory A. Voth pp 3120–3126 DOI: 10.1021/ja078106i

Hydrogen Bonding Effects on the Electronic Configuration of Five-Coordinate High-Spin Iron(II) Porphyrinates Chuanjiang Hu, Bruce C. Noll, Paula M. B. Piccoli, Arthur J. Schultz, Charles E. Schulz, and W. Robert Scheidt pp 3127–3136 DOI: 10.1021/ja078222l Supporting Info

Spectroscopic Observation of the Resonance-Stabilized 1-Phenylpropargyl Radical Neil J. Reilly, Damian L. Kokkin, Masakazu Nakajima, Klaas Nauta, Scott H. Kable, and Timothy W. Schmidt pp 3137–3142 DOI: 10.1021/ja078342t Supporting Info

Modular Fluorescent Benzobis(imidazolium) Salts:  Syntheses, Photophysical Analyses, and Applications Andrew J. Boydston, Peter D. Vu, Olga L. Dykhno, Vicki Chang, Alvin R. Wyatt, II, Adam S. Stockett, Eric T. Ritschdorff, Jason B. Shear, and Christopher W. Bielawski pp 3143–3156 DOI: 10.1021/ja7102247 Supporting Info

Investigation of Binding of UDP-Galf and UDP-[3-F]Galf to UDP-galactopyranose Mutase by STD-NMR Spectroscopy, Molecular Dynamics, and CORCEMA-ST Calculations Yue Yuan, Dustin W. Bleile, Xin Wen, David A. R. Sanders, Kenji Itoh, Hung-wen Liu, and B. Mario Pinto pp 3157–3168 DOI: 10.1021/ja7104152 Supporting Info

A Computational Study of Remote C−H Activation by Amine Radical Cations:  Implications for the Photochemical Reduction of Carbon Dioxide Robert D. Richardson and Barry K. Carpenter pp 3169–3180 DOI: 10.1021/ja710595u Supporting Info

Neutral Bis(α-iminopyridine)metal Complexes of the First-Row Transition Ions (Cr, Mn, Fe, Co, Ni, Zn) and Their Monocationic Analogues:  Mixed Valency Involving a Redox Noninnocent Ligand System Connie C. Lu, Eckhard Bill, Thomas Weyhermüller, Eberhard Bothe, and Karl Wieghardt pp 3181–3197 DOI: 10.1021/ja710663n Supporting Info

Adsorptive and Acidic Properties, Reversible Lattice Oxygen Evolution, and Catalytic Mechanism of Cryptomelane-Type Manganese Oxides as Oxidation Catalysts Jian Luo, Qiuhua Zhang, Javier Garcia-Martinez, and Steven L. Suib pp 3198–3207 DOI: 10.1021/ja077706e

Probing the Compound I-like Reactivity of a Bare High-Valent Oxo Iron Porphyrin Complex:  The Oxidation of Tertiary Amines Barbara Chiavarino, Romano Cipollini, Maria Elisa Crestoni, Simonetta Fornarini, Francesco Lanucara, and Andrea Lapi pp 3208–3217 DOI: 10.1021/ja077286t

Energetics and Dynamics of Electron Transfer and Proton Transfer in Dissociation of MetalIII(salen)−Peptide Complexes in the Gas Phase Julia Laskin, Zhibo Yang, and Ivan K. Chu pp 3218–3230 DOI: 10.1021/ja077690s Supporting Info

Metal Catalyzed Reductive C−C Bond Formation:  A Departure from Preformed Organometallic Reagents. Topics in Current Chemistry, 279 Edited by Michael J. Krische (University of Texas at Austin). Springer:  Berlin, Heidelberg, New York. 2007. xii + 264 pp. $269.00. ISBN 978-3-540-72878-8. Jeffrey M. Stryker p 3231 DOI: 10.1021/ja077019n

The Organic Chemistry of Drug Synthesis, Volume 7 By Daniel Lednicer (North Bethesda, MD). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xiv + 272 pp. $115.00. ISBN 978-0-470-10750-8. Katherine L. Seley-Radtke pp 3231–3232 DOI: 10.1021/ja800461a

Issue 11

Combinatorial Ligand Development Based on Mass Spectrometric Screening and a Double Mass-Labeling Strategy Christian Markert, Pirmin Rösel, and Andreas Pfaltz pp 3234–3235 DOI: 10.1021/ja0740317 Supporting Info

Hierarchical Interfacial Assembly of ABC Triblock Copolymer Jiwen Hu, Guojun Liu, and Gabriel Nijkang pp 3236–3237 DOI: 10.1021/ja075201i Supporting Info

Diamine Catalyzed Hemicyanine Dye Formation from Nonfluorescent Precursors through DNA Programmed Chemistry Yumei Huang and James M. Coull pp 3238–3239 DOI: 10.1021/ja0753602 Supporting Info

Nanotube Composites Consisting of Metal Nanoparticles and Polythiophene from Electropolymerization of Terthiophene-Functionalized Metal (Au, Pd) Nanoparticles Ryuhei Umeda, Hiroshi Awaji, Tsukasa Nakahodo, and Hisashi Fujihara pp 3240–3241 DOI: 10.1021/ja7114212 Supporting Info

Unconventional Biradical Character of Titanium Enolates I. de P. R. Moreira, J. M. Bofill, J. M. Anglada, J. G. Solsona, J. Nebot, P. Romea, and F. Urpí pp 3242–3243 DOI: 10.1021/ja076625f Supporting Info

One-Step, Room Temperature, Colorimetric Detection of Mercury (Hg2+) Using DNA/Nanoparticle Conjugates Xuejia Xue, Feng Wang, and Xiaogang Liu pp 3244–3245 DOI: 10.1021/ja076716c Supporting Info

Amphidynamic Character of Crystalline MOF-5:  Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment Stephanie L. Gould, David Tranchemontagne, Omar M. Yaghi, and Miguel A. Garcia-Garibay pp 3246–3247 DOI: 10.1021/ja077122c Supporting Info

A Chemical Sensor That Can Detect the Frequency of Ultrasound Joe Z. Sostaric pp 3248–3249 DOI: 10.1021/ja077311v Supporting Info

Arginine52 Controls the Photoisomerization Process in Photoactive Yellow Protein Gerrit Groenhof, Lars V. Schäfer, Martial Boggio-Pasqua, Helmut Grubmüller, and Michael A. Robb pp 3250–3251 DOI: 10.1021/ja078024u Supporting Info

Giant Thienylene-Acetylene-Ethylene Macrocycles with Large Two-Photon Absorption Cross Section and Semishape-Persistence Michele Williams-Harry, Ajit Bhaskar, Guda Ramakrishna, Theodore Goodson, III, Mika Imamura, Akane Mawatari, Kazumi Nakao, Hideo Enozawa, Tohru Nishinaga, and Masahiko Iyoda pp 3252–3253 DOI: 10.1021/ja078246s Supporting Info

Field Dependent Dynamic Nuclear Polarization with Radicals in Aqueous Solution Peter Höfer, Giacomo Parigi, Claudio Luchinat, Patrick Carl, Gisela Guthausen, Marcel Reese, Teresa Carlomagno, Christian Griesinger, and Marina Bennati pp 3254–3255 DOI: 10.1021/ja0783207

Controlled Viscoelastic Carbon Nanotube Fluids Youan Lei, Chuanxi Xiong, Hong Guo, Junlong Yao, Lijie Dong, and Xiaohong Su pp 3256–3257 DOI: 10.1021/ja710014q Supporting Info

Gold Nanoparticle Plasmonic Field Effect on the Primary Step of the Other Photosynthetic System in Nature, Bacteriorhodopsin Arianna Biesso, Wei Qian, and Mostafa A. El-Sayed pp 3258–3259 DOI: 10.1021/ja7099858

Divided Evolution:  A Scheme for Suppression of Line Broadening Induced by Conformational Exchange Anastasia Zhuravleva and Vladislav Yu. Orekhov pp 3260–3261 DOI: 10.1021/ja710056t Supporting Info

Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2+2+2] Cycloaddition of Carbodiimides Robert T. Yu and Tomislav Rovis pp 3262–3263 DOI: 10.1021/ja710065h Supporting Info

Inhibition of Helicobacter pylori Aminoacyl-tRNA Amidotransferase by Puromycin Analogues Christian Balg, Jonathan L. Huot, Jacques Lapointe, and Robert Chênevert pp 3264–3265 DOI: 10.1021/ja7100714 Supporting Info

Site-Selective sp2 and Benzylic sp3 Palladium-Catalyzed Direct Arylation Louis-Charles Campeau, Derek J. Schipper, and Keith Fagnou pp 3266–3267 DOI: 10.1021/ja710451s Supporting Info

Direct Benzylic Alkylation via Ni-Catalyzed Selective Benzylic sp3 C−O Activation Bing-Tao Guan, Shi-Kai Xiang, Bi-Qin Wang, Zuo-Peng Sun, Yang Wang, Ke-Qing Zhao, and Zhang-Jie Shi pp 3268–3269 DOI: 10.1021/ja710944j Supporting Info

Fluorometric Detection of Inositol Phosphates and the Activity of Their Enzymes with Synthetic Pores:  Discrimination of IP7 and IP6 and Phytate Sensing in Complex Matrices Sara M. Butterfield, Duy-Hien Tran, Honglu Zhang, Glenn D. Prestwich, and Stefan Matile pp 3270–3271 DOI: 10.1021/ja710186e Supporting Info

Breathing Life into Polycations:  Functionalization with pH-Responsive Endosomolytic Peptides and Polyethylene Glycol Enables siRNA Delivery Martin Meyer, Alexander Philipp, Reza Oskuee, Claudia Schmidt, and Ernst Wagner pp 3272–3273 DOI: 10.1021/ja710344v Supporting Info

Self-Assembled Binary Superlattices of CdSe and Au Nanocrystals and Their Fluorescence Properties Elena V. Shevchenko, Moritz Ringler, Alexander Schwemer, Dmitri V. Talapin, Thomas A. Klar, Andrey L. Rogach, Jochen Feldmann, and A. Paul Alivisatos pp 3274–3275 DOI: 10.1021/ja710619s Supporting Info

C2, C5, and C4 Azole N-Oxide Direct Arylation Including Room-Temperature Reactions Louis-Charles Campeau, Mégan Bertrand-Laperle, Jean-Philippe Leclerc, Elisia Villemure, Serge Gorelsky, and Keith Fagnou pp 3276–3277 DOI: 10.1021/ja7107068 Supporting Info

Photoactivatable Crosslinking Sugars for Capturing Glycoprotein Interactions Yoshihito Tanaka and Jennifer J. Kohler pp 3278–3279 DOI: 10.1021/ja7109772 Supporting Info

Asymmetric Peptide Nanoarray Surfaces for Studies of Single Cell Polarization Diana K. Hoover, Eugene W. L. Chan, and Muhammad N. Yousaf pp 3280–3281 DOI: 10.1021/ja711016m Supporting Info

Conjugated Oligoelectrolyte Electron Transport/Injection Layers for Organic Optoelectronic Devices Renqiang Yang, Yunhua Xu, Xuan-Dung Dang, Thuc-Quyen Nguyen, Yong Cao, and Guillermo C. Bazan pp 3282–3283 DOI: 10.1021/ja711068d Supporting Info

Free-Standing, Patternable Nanoparticle/Polymer Monolayer Arrays Formed by Evaporation Induced Self-Assembly at a Fluid Interface Jiebin Pang, Shisheng Xiong, Felix Jaeckel, Zaicheng Sun, Darren Dunphy, and C. Jeffrey Brinker pp 3284–3285 DOI: 10.1021/ja710994m Supporting Info

Redox-Switching of Nonlinear Optical Behavior in Langmuir−Blodgett Thin Films Containing a Ruthenium(II) Ammine Complex Leïla Boubekeur-Lecaque, Benjamin J. Coe, Koen Clays, Stijn Foerier, Thierry Verbiest, and Inge Asselberghs pp 3286–3287 DOI: 10.1021/ja711170q Supporting Info

Cycloaddition on Ge(100) of the Lewis Acid AlCl3 Soon Jung Jung, Young-Sang Youn, Hangil Lee, Ki-Jeong Kim, Bong Soo Kim, and Sehun Kim pp 3288–3289 DOI: 10.1021/ja7112307 Supporting Info

Synthesis of Programmable Tetra-ortho-Substituted Biaryl Compounds Using Diels−Alder Cycloadditions/Cycloreversions of Disubstituted Alkynyl Stannanes Johanna R. Perkins and Rich G. Carter pp 3290–3291 DOI: 10.1021/ja7113486 Supporting Info

Global Molecular Structure and Interfaces:  Refining an RNA:RNA Complex Structure Using Solution X-ray Scattering Data Xiaobing Zuo, Jingbu Wang, Trenton R. Foster, Charles D. Schwieters, David M. Tiede, Samuel E. Butcher, and Yun-Xing Wang pp 3292–3293 DOI: 10.1021/ja7114508 Supporting Info

Selective Growth of Metal and Binary Metal Tips on CdS Nanorods Susan E. Habas, Peidong Yang, and Taleb Mokari pp 3294–3295 DOI: 10.1021/ja800104w Supporting Info

Iron-Based Layered Superconductor La[O1-xFx]FeAs (x = 0.05−0.12) with Tc = 26 K Yoichi Kamihara, Takumi Watanabe, Masahiro Hirano, and Hideo Hosono pp 3296–3297 DOI: 10.1021/ja800073m Supporting Info

Planar, Twisted, and Trans-Bent:  Conformational Flexibility of Neutral Diborenes Yuzhong Wang, Brandon Quillian, Pingrong Wei, Yaoming Xie, Chaitanya S. Wannere, R. Bruce King, Henry F. Schaefer, III, Paul v. R. Schleyer, and Gregory H. Robinson pp 3298–3299 DOI: 10.1021/ja800257j Supporting Info

Near-Ideal Photodiodes from Sintered Gold Nanoparticle Films on Methyl-Terminated Si(111) Surfaces Stephen Maldonado, David Knapp, and Nathan S. Lewis pp 3300–3301 DOI: 10.1021/ja800603v Supporting Info

Catalytic Asymmetric Hiyama Cross-Couplings of Racemic α-Bromo Esters Xing Dai, Neil A. Strotman, and Gregory C. Fu pp 3302–3303 DOI: 10.1021/ja8009428 Supporting Info

Palladium-Catalyzed Oxidative Ethoxycarbonylation of Aromatic C−H Bond with Diethyl Azodicarboxylate Wing-Yiu Yu, Wing Nga Sit, Kin-Man Lai, Zhongyuan Zhou, and Albert S. C. Chan pp 3304–3306 DOI: 10.1021/ja710555g Supporting Info

The Photo-Favorskii Reaction of p-Hydroxyphenacyl Compounds Is Initiated by Water-Assisted, Adiabatic Extrusion of a Triplet Biradical Richard S. Givens, Dominik Heger, Bruno Hellrung, Yavor Kamdzhilov, Marek Mac, Peter G. Conrad, II, Elizabeth Cope, Jong I. Lee, Julio F. Mata-Segreda, Richard L. Schowen, and Jakob Wirz pp 3307–3309 DOI: 10.1021/ja7109579 Supporting Info

Coexistence and Coupling of Two Distinct Charge Density Waves in Sm2Te5 Christos D. Malliakas, Maria Iavarone, Jan Fedor, and Mercouri G. Kanatzidis pp 3310–3312 DOI: 10.1021/ja7111405 Supporting Info

Unusual Sculpting of Dipeptide Particles by Ultrasound Induces Gelation David Bardelang, Franck Camerel, James C. Margeson, Donald M. Leek, Marc Schmutz, Md. Badruz Zaman, Kui Yu, Dmitriy V. Soldatov, Raymond Ziessel, Christopher I. Ratcliffe, and John A. Ripmeester pp 3313–3315 DOI: 10.1021/ja711342y Supporting Info

Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis Sean A. Reed and M. Christina White pp 3316–3318 DOI: 10.1021/ja710206u Supporting Info

Effect of External Electric Fields on the C−H Bond Activation Reactivity of Nonheme Iron−Oxo Reagents Hajime Hirao, Hui Chen, Maria Angels Carvajal, Yong Wang, and Sason Shaik pp 3319–3327 DOI: 10.1021/ja070903t Supporting Info

A Density Functional Theory Investigation on the Mechanism of the Second Half-Reaction of Nitric Oxide Synthase Jesse J. Robinet, Kyung-Bin Cho, and James W. Gauld pp 3328–3334 DOI: 10.1021/ja072650+ Supporting Info

Modulating the Framework Negative Charge Density in the System [BDT−TTP•+]/[Re6S5Cl91-]/[Re6(S/Se)6Cl82-]/[Re6S7Cl73-]:  Templating by Isosteric Cluster Anions of Identical Symmetry and Shape, Variations of Incommensurate Band Filling, and Electronic Structure in 2D Metals Sandrine Perruchas, Kamal Boubekeur, Enric Canadell, Yohji Misaki, Pascale Auban-Senzier, Claude Pasquier, and Patrick Batail pp 3335–3348 DOI: 10.1021/ja074774s Supporting Info

Anomeric Effect in “High Energy” Phosphate Bonds. Selective Destabilization of the Scissile Bond and Modulation of the Exothermicity of Hydrolysis Eliza A. Ruben, Joshua A. Plumley, Michael S. Chapman, and Jeffrey D. Evanseck pp 3349–3358 DOI: 10.1021/ja073652x Supporting Info

Vibrational Signatures of Protonated, Phosphorylated Amino Acids in the Gas Phase Catarina F. Correia, Petru O. Balaj, Debora Scuderi, Philippe Maitre, and Gilles Ohanessian pp 3359–3370 DOI: 10.1021/ja073868z Supporting Info

Absolute Standard Hydrogen Electrode Potential Measured by Reduction of Aqueous Nanodrops in the Gas Phase William A. Donald, Ryan D. Leib, Jeremy T. O'Brien, Matthew F. Bush, and Evan R. Williams pp 3371–3381 DOI: 10.1021/ja073946i Supporting Info

Relationship between the Excited State Relaxation Paths of Rhodopsin and Isorhodopsin Angela Strambi, Pedro B. Coto, Luis Manuel Frutos, Nicolas Ferré, and Massimo Olivucci pp 3382–3388 DOI: 10.1021/ja0749082 Supporting Info

The Role of Conformation in Ion Permeation in a K+ Channel Carmen Domene, Satyavani Vemparala, Simone Furini, Kim Sharp, and Michael L. Klein pp 3389–3398 DOI: 10.1021/ja075164v Supporting Info

Self-Assembly of Patterned Monolayers with Nanometer Features:  Molecular Selection Based on Dipole Interactions and Chain Length Yanhu Wei, Wenjun Tong, and Matthew B. Zimmt pp 3399–3405 DOI: 10.1021/ja075170r Supporting Info

Structural and Rate Studies of the Formation of Substituted Benzynes Jason C. Riggs, Antonio Ramirez, Matthew E. Cremeens, Crystal G. Bashore, John Candler, Michael C. Wirtz, Jotham W. Coe, and David B. Collum pp 3406–3412 DOI: 10.1021/ja0754655 Supporting Info

Solid-State White Light-Emitting Electrochemical Cells Using Iridium-Based Cationic Transition Metal Complexes Hai-Ching Su, Hsiao-Fan Chen, Fu-Chuan Fang, Chih-Che Liu, Chung-Chih Wu, Ken-Tsung Wong, Yi-Hung Liu, and Shie-Ming Peng pp 3413–3419 DOI: 10.1021/ja076051e Supporting Info

On the Singlet−Triplet Splitting of Geminate Electron−Hole Pairs in Organic Semiconductors Seth Difley, David Beljonne, and Troy Van Voorhis pp 3420–3427 DOI: 10.1021/ja076125m Supporting Info

Quantum Mechanics/Molecular Mechanics Study of the Catalytic Cycle of Water Splitting in Photosystem II Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig, and Victor S. Batista pp 3428–3442 DOI: 10.1021/ja076130q Supporting Info

Computational Study of Thymine Dimer Radical Anion Splitting in the Self-Repair Process of Duplex DNA Fanny Masson, Teodoro Laino, Ivano Tavernelli, Ursula Rothlisberger, and Jürg Hutter pp 3443–3450 DOI: 10.1021/ja076081h Supporting Info

Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition Takanori Shibata, Yu-ki Tahara, Kohei Tamura, and Kohei Endo pp 3451–3457 DOI: 10.1021/ja0762083 Supporting Info

Effects of Shear Rate on Propagation of Blood Clotting Determined Using Microfluidics and Numerical Simulations Matthew K. Runyon, Christian J. Kastrup, Bethany L. Johnson-Kerner, Thuong G. Van Ha, and Rustem F. Ismagilov pp 3458–3464 DOI: 10.1021/ja076301r Supporting Info

Facile Synthesis for Ordered Mesoporous γ-Aluminas with High Thermal Stability Quan Yuan, An-Xiang Yin, Chen Luo, Ling-Dong Sun, Ya-Wen Zhang, Wen-Tao Duan, Hai-Chao Liu, and Chun-Hua Yan pp 3465–3472 DOI: 10.1021/ja0764308 Supporting Info

Methyl Cation Affinities of Commonly Used Organocatalysts Yin Wei, G. Narahari Sastry, and Hendrik Zipse pp 3473–3477 DOI: 10.1021/ja0764409 Supporting Info

Probing the Electronic Structures of [Cu2(μ-XR2)]n+ Diamond Cores as a Function of the Bridging X Atom (X = N or P) and Charge (n = 0, 1, 2) Seth B. Harkins, Neal P. Mankad, Alexander J. M. Miller, Robert K. Szilagyi, and Jonas C. Peters pp 3478–3485 DOI: 10.1021/ja076537v Supporting Info

Theoretical Analysis of Antisense Duplexes:  Determinants of the RNase H Susceptibility Agnes Noy, F. Javier Luque, and Modesto Orozco pp 3486–3496 DOI: 10.1021/ja076734u Supporting Info

Monolayers of Twisted Binaphthyls for Aromatic Crystallization at Low Nucleation Densities and High Growth Rates Sang-Mi Jeong and Ji-Woong Park pp 3497–3501 DOI: 10.1021/ja077291x Supporting Info

Thin Film Structure of Tetraceno[2,3-b]thiophene Characterized by Grazing Incidence X-ray Scattering and Near-Edge X-ray Absorption Fine Structure Analysis Quan Yuan, Stefan C. B. Mannsfeld, Ming L. Tang, Michael F. Toney, Jan Lüning, and Zhenan Bao pp 3502–3508 DOI: 10.1021/ja0773002 Supporting Info

Probing Electron Correlations in Molecules by Two-Dimensional Coherent Optical Spectroscopy Zhenyu Li, Darius Abramavicius, and Shaul Mukamel pp 3509–3515 DOI: 10.1021/ja0774414 Supporting Info

Functional Oligomers for the Control and Fixation of Spatial Organization in Nanoparticle Assemblies Chun-Kwei Wu, Kristi L. Hultman, Stephen O'Brien, and Jeffrey T. Koberstein pp 3516–3520 DOI: 10.1021/ja077625i Supporting Info

Generation and Tandem Reactions of 1-Alkenyl-1,1-Heterobimetallics:  Practical and Versatile Reagents for Organic Synthesis Hongmei Li, Patrick J. Carroll, and Patrick J. Walsh pp 3521–3531 DOI: 10.1021/ja077664u Supporting Info

Mixed-Valent Metals Bridged by a Radical Ligand:  Fact or Fiction Based on Structure-Oxidation State Correlations Biprajit Sarkar, Srikanta Patra, Jan Fiedler, Raghavan B. Sunoj, Deepa Janardanan, Goutam Kumar Lahiri, and Wolfgang Kaim pp 3532–3542 DOI: 10.1021/ja077676f Supporting Info

Polymer Structure and Solvent Effects on the Selective Dispersion of Single-Walled Carbon Nanotubes Jeong-Yuan Hwang, Adrian Nish, James Doig, Sigrid Douven, Chun-Wei Chen, Li-Chyong Chen, and Robin J. Nicholas pp 3543–3553 DOI: 10.1021/ja0777640 Supporting Info

Synthesis of Tetrahedral LiFeO2 and Its Behavior as a Cathode in Rechargeable Lithium Batteries A. Robert Armstrong, Daniel W. Tee, Fabio La Mantia, Petr Novák, and Peter G. Bruce pp 3554–3559 DOI: 10.1021/ja077651g Supporting Info

Chlorine Adsorption on Au(111):  Chlorine Overlayer or Surface Chloride? Weiwei Gao, Thomas A. Baker, Ling Zhou, Dilini S. Pinnaduwage, Efthimios Kaxiras, and Cynthia M. Friend pp 3560–3565 DOI: 10.1021/ja077989a Supporting Info

Ruthenium Complexes of C,C‘-Bis(ethynyl)carboranes:  An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers Mark A. Fox, Rachel L. Roberts, Thomas E. Baines, Boris Le Guennic, Jean-François Halet, František Hartl, Dmitri S. Yufit, David Albesa-Jové, Judith A. K. Howard, and Paul J. Low pp 3566–3578 DOI: 10.1021/ja0779755 Supporting Info

3D Structure Determination of the Crh Protein from Highly Ambiguous Solid-State NMR Restraints Antoine Loquet, Benjamin Bardiaux, Carole Gardiennet, Christophe Blanchet, Marc Baldus, Michael Nilges, Thérèse Malliavin, and Anja Böckmann pp 3579–3589 DOI: 10.1021/ja078014t Supporting Info

Direct NMR Detection of Alkali Metal Ions Bound to G-Quadruplex DNA Ramsey Ida and Gang Wu pp 3590–3602 DOI: 10.1021/ja709975z Supporting Info

Maturation of an Escherichia coli Ribosomal Peptide Antibiotic by ATP-Consuming N−P Bond Formation in Microcin C7 Rebecca F. Roush, Elizabeth M. Nolan, Frank Löhr, and Christopher T. Walsh pp 3603–3609 DOI: 10.1021/ja7101949 Supporting Info

DNA Aptamer Folding on Gold Nanoparticles:  From Colloid Chemistry to Biosensors Weian Zhao, William Chiuman, Jeffrey C. F. Lam, Simon A. McManus, Wei Chen, Yuguo Cui, Robert Pelton, Michael A. Brook, and Yingfu Li pp 3610–3618 DOI: 10.1021/ja710241b Supporting Info

Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells Jae Kwan Lee, Wan Li Ma, Christoph J. Brabec, Jonathan Yuen, Ji Sun Moon, Jin Young Kim, Kwanghee Lee, Guillermo C. Bazan, and Alan J. Heeger pp 3619–3623 DOI: 10.1021/ja710079w Supporting Info

Synthesis and Photoluminescent Properties of Size-Controlled Germanium Nanocrystals from Phenyl Trichlorogermane-Derived Polymers Eric J. Henderson, Colin M. Hessel, and Jonathan G. C. Veinot pp 3624–3632 DOI: 10.1021/ja710286a Supporting Info

Total Synthesis of the Originally Proposed and Revised Structures of Palmerolide A and Isomers Thereof K. C. Nicolaou, Ya-Ping Sun, Ramakrishna Guduru, Biswadip Banerji, and David Y.-K. Chen pp 3633–3644 DOI: 10.1021/ja710485n Supporting Info

Synthesis of Dihydropyridines and Pyridines from Imines and Alkynes via C−H Activation Denise A. Colby, Robert G. Bergman, and Jonathan A. Ellman pp 3645–3651 DOI: 10.1021/ja7104784 Supporting Info

Facile and Selective Aliphatic C−H Bond Activation at Ambient Temperatures Initiated by Cp*W(NO)(CH2CMe3)(η3-CH2CHCHMe) Jenkins Y. K. Tsang, Miriam S. A. Buschhaus, Peter M. Graham, Christopher J. Semiao, Scott P. Semproni, Simon J. Kim, and Peter Legzdins pp 3652–3663 DOI: 10.1021/ja710606v Supporting Info

Dynamic Strength of the Silicon−Carbon Bond Observed over Three Decades of Force-Loading Rates Sebastian W. Schmidt, Martin K. Beyer, and Hauke Clausen-Schaumann pp 3664–3668 DOI: 10.1021/ja710642a Supporting Info

NMR Experiments Reveal the Molecular Basis of Receptor Recognition by a Calicivirus Christoph Rademacher, N. Rama Krishna, Monica Palcic, Francisco Parra, and Thomas Peters pp 3669–3675 DOI: 10.1021/ja710854r Supporting Info

Structural, Spectroscopic, and Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis Debashis Adhikari, Susanne Mossin, Falguni Basuli, John C. Huffman, Robert K. Szilagyi, Karsten Meyer, and Daniel J. Mindiola pp 3676–3682 DOI: 10.1021/ja7108486 Supporting Info

“Supramolecular” Assembly of Gold Nanorods End-Terminated with Polymer “Pom-Poms”:  Effect of Pom-Pom Structure on the Association Modes Zhihong Nie, Daniele Fava, Michael Rubinstein, and Eugenia Kumacheva pp 3683–3689 DOI: 10.1021/ja711150k Supporting Info

Vinylation of Aromatic Halides Using Inexpensive Organosilicon Reagents. Illustration of Design of Experiment Protocols Scott E. Denmark and Christopher R. Butler pp 3690–3704 DOI: 10.1021/ja7100888 Supporting Info

Issue 12

Protein Folding Kinetics Under Force from Molecular Simulation Robert B. Best and Gerhard Hummer pp 3706–3707 DOI: 10.1021/ja0762691 Supporting Info

Palladium(II)-Catalyzed Direct Arylation of Enaminones Using Organotrifluoroborates Haibo Ge, Micah J. Niphakis, and Gunda I. Georg pp 3708–3709 DOI: 10.1021/ja710221c Supporting Info

Intracellular Spatial Control of Fluorescent Magnetic Nanoparticles Jinhao Gao, Wei Zhang, Pingbo Huang, Bei Zhang, Xixiang Zhang, and Bing Xu pp 3710–3711 DOI: 10.1021/ja7103125 Supporting Info

Selective Detection of Vapor Phase Hydrogen Peroxide with Phthalocyanine Chemiresistors Forest I. Bohrer, Corneliu N. Colesniuc, Jeongwon Park, Ivan K. Schuller, Andrew C. Kummel, and William C. Trogler pp 3712–3713 DOI: 10.1021/ja710324f Supporting Info

Emissive Terbium Probe for Multiphoton in Vitro Cell Imaging Ga-Lai Law, Ka-Leung Wong, Cornelia Wing-Yin Man, Wing-Tak Wong, Sai-Wah Tsao, Michael Hon-Wah Lam, and Paul Kwan-Sing Lam pp 3714–3715 DOI: 10.1021/ja710418d Supporting Info

A Nanocarbon Film Electrode as a Platform for Exploring DNA Methylation Dai Kato, Naoyuki Sekioka, Akio Ueda, Ryoji Kurita, Shigeru Hirono, Koji Suzuki, and Osamu Niwa pp 3716–3717 DOI: 10.1021/ja710536p Supporting Info

Planar Meso Pentafluorophenyl Core Modified Isophlorins J. Sreedhar Reddy and Venkataramanarao G. Anand pp 3718–3719 DOI: 10.1021/ja710664y Supporting Info

Nature of Cl Bonding on the Au(111) Surface:  Evidence of a Mainly Covalent Interaction Thomas A. Baker, Cynthia M. Friend, and Efthimios Kaxiras pp 3720–3721 DOI: 10.1021/ja7109234 Supporting Info

Direct Observation of the Active Center for Methane Dehydroaromatization Using an Ultrahigh Field 95Mo NMR Spectroscopy Heng Zheng, Ding Ma, Xinhe Bao, Jian Zhi Hu, Ja Hun Kwak, Yong Wang, and Charles H. F. Peden pp 3722–3723 DOI: 10.1021/ja7110916 Supporting Info

N-Heterocyclic Carbene Complexes of Rh:  Reaction with Dioxygen without Oxidation Jeremy M. Praetorius, Daryl P. Allen, Ruiyao Wang, Jonathan D. Webb, Friedrich Grein, Pierre Kennepohl, and Cathleen M. Crudden pp 3724–3725 DOI: 10.1021/ja7108213 Supporting Info

Signal Amplification via Intramolecular Energy Transfer Using Tripodal Neutral Iridium(III) Complexes upon Binding to Avidin Tae-Hyuk Kwon, Jongchul Kwon, and Jong-In Hong pp 3726–3727 DOI: 10.1021/ja710803p Supporting Info

Direct Asymmetric Iodination of Aldehydes Using an Axially Chiral Bifunctional Amino Alcohol Catalyst Taichi Kano, Mitsuhiro Ueda, and Keiji Maruoka pp 3728–3729 DOI: 10.1021/ja074003o Supporting Info

Probing the Structure of CH5+ by Dissociative Charge Exchange Jennifer E. Mann, Zhen Xie, John D. Savee, Bastiaan J. Braams, Joel M. Bowman, and Robert E. Continetti pp 3730–3731 DOI: 10.1021/ja0782504 Supporting Info

Cp(Pri2MeP)FeH2SiR3:  Nonclassical Iron Silyl Dihydride Dmitry V. Gutsulyak, Lyudmila G. Kuzmina, Judith A. K. Howard, Sergei F. Vyboishchikov, and Georgii I. Nikonov pp 3732–3733 DOI: 10.1021/ja800983n Supporting Info

Efficient Amide-Directed Catalytic Asymmetric Hydroboration Sean M. Smith, Nathan C. Thacker, and James M. Takacs pp 3734–3735 DOI: 10.1021/ja710492q Supporting Info

Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of Enynes and Alkynes David J. Gorin, Iain D. G. Watson, and F. Dean Toste pp 3736–3737 DOI: 10.1021/ja710990d Supporting Info

Electrical Resistivity of Tetramethyltetratelluronaphtalene Crystal at Very High Pressures Examination of the Condition of Metallization of π Molecular Crystal HengBo Cui, Yoshinori Okano, Biao Zhou, Akiko Kobayashi, and Hayao Kobayashi pp 3738–3739 DOI: 10.1021/ja7114025 Supporting Info

Au-Catalyzed Synthesis of (1Z,3E)-2-Pivaloxy-1,3-Dienes from Propargylic Pivalates Guotao Li, Guozhu Zhang, and Liming Zhang pp 3740–3741 DOI: 10.1021/ja800001h Supporting Info

Difluoro-λ3-Bromane-Induced Oxidative Carbon−Carbon Bond-Forming Reactions:  Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles Masahito Ochiai, Akira Yoshimura, Takeshi Mori, Yoshio Nishi, and Masaya Hirobe pp 3742–3743 DOI: 10.1021/ja801097c Supporting Info

Imparting Nanoparticle Function with Size-Controlled Amphiphilic Polymers Yingchuan Chen, Rahul Thakar, and Preston T. Snee pp 3744–3745 DOI: 10.1021/ja711252n Supporting Info

Study of Concerted and Sequential Photochemical Wolff Rearrangement by Femtosecond UV−vis and IR Spectroscopy Gotard T. Burdzinski, Jin Wang, Terry L. Gustafson, and Matthew S. Platz pp 3746–3747 DOI: 10.1021/ja711346z Supporting Info

Reversible Loading and Unloading of Nanoparticles in “Exponentially” Growing Polyelectrolyte LBL Films Sudhanshu Srivastava, Vincent Ball, Paul Podsiadlo, Jungwoo Lee, Peter Ho, and Nicholas A. Kotov pp 3748–3749 DOI: 10.1021/ja7110288 Supporting Info

Simple and Accurate Quantification of Quantum Dots via Single-Particle Counting Chun-yang Zhang and Lawrence W. Johnson pp 3750–3751 DOI: 10.1021/ja711493q Supporting Info

Mechanically Manipulating the DNA Threading Intercalation Rate Thayaparan Paramanathan, Fredrik Westerlund, Micah J. McCauley, Ioulia Rouzina, Per Lincoln, and Mark C. Williams pp 3752–3753 DOI: 10.1021/ja711303p Supporting Info

Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18] Michael W. Heaven, Amala Dass, Peter S. White, Kennedy M. Holt, and Royce W. Murray pp 3754–3755 DOI: 10.1021/ja800561b Supporting Info

On the Structure of Thiolate-Protected Au25 Jaakko Akola, Michael Walter, Robert L. Whetten, Hannu Häkkinen, and Henrik Grönbeck pp 3756–3757 DOI: 10.1021/ja800594p Supporting Info

An Open-Framework Silicogermanate with 26-Ring Channels Built from Seven-Coordinated (Ge,Si)10(O,OH)28 Clusters Kirsten E. Christensen, Charlotte Bonneau, Mikaela Gustafsson, Lei Shi, Junliang Sun, Jekabs Grins, Kjell Jansson, Isabelle Sbille, Bao-Lian Su, and Xiaodong Zou pp 3758–3759 DOI: 10.1021/ja8002556 Supporting Info

A Photochemical Synthesis of Functionalized trans-Cyclooctenes Driven by Metal Complexation Maksim Royzen, Glenn P. A. Yap, and Joseph M. Fox pp 3760–3761 DOI: 10.1021/ja8001919 Supporting Info

TOF-2:  A Large 1D Channel Thorium Organic Framework Kang Min Ok, Jaeyoung Sung, Gang Hu, Robert M. J. Jacobs, and Dermot O'Hare pp 3762–3763 DOI: 10.1021/ja800395q Supporting Info

Stability of the Infinite Layer Structure with Iron Square Planar Coordination Cédric Tassel, Takashi Watanabe, Yoshihiro Tsujimoto, Naoaki Hayashi, Atsushi Kitada, Yuji Sumida, Takafumi Yamamoto, Hiroshi Kageyama, Mikio Takano, and Kazuyoshi Yoshimura pp 3764–3765 DOI: 10.1021/ja800415d Supporting Info

Lewis Acid Promoted Carbon−Carbon Bond Cleavage of γ-Silyloxy-β-hydroxy-α-diazoesters Cristian Draghici and Matthias Brewer pp 3766–3767 DOI: 10.1021/ja801004d Supporting Info

Quest for Zeolite-like Metal−Organic Frameworks:  On Pyrimidinecarboxylate Bis-Chelating Bridging Ligands Dorina F. Sava, Victor Ch. Kravtsov, Farid Nouar, Lukasz Wojtas, Jarrod F. Eubank, and Mohamed Eddaoudi pp 3768–3770 DOI: 10.1021/ja710616j Supporting Info

Easily Immobilized Di- and Tetraphosphine Linkers:  Rigid Scaffolds that Prevent Interactions of Metal Complexes with Oxide Supports Yuan Yang, Björn Beele, and Janet Blümel pp 3771–3773 DOI: 10.1021/ja800541c

Total Synthesis of (+)-Pinnatoxin A Craig E. Stivala and Armen Zakarian pp 3774–3776 DOI: 10.1021/ja800435j Supporting Info

Cobalt Dinitrosoalkane Complexes in the C−H Functionalization of Olefins Jennifer M. Schomaker, W. Christopher Boyd, Ian C. Stewart, F. Dean Toste, and Robert G. Bergman pp 3777–3779 DOI: 10.1021/ja800738d Supporting Info

Influence of Redox Molecules on the Electronic Conductance of Single-Walled Carbon Nanotube Field-Effect Transistors:  Application to Chemical and Biological Sensing Salah Boussaad, Bruce A. Diner, and Janine Fan pp 3780–3787 DOI: 10.1021/ja075131f

Growth of p- and n-Dopable Films from Electrochemically Generated C60 Cations Carlo Bruno, Massimo Marcaccio, Demis Paolucci, Carla Castellarin-Cudia, Andrea Goldoni, Alexey V. Streletskii, Thomas Drewello, Simona Barison, Alessandro Venturini, Francesco Zerbetto, and Francesco Paolucci pp 3788–3796 DOI: 10.1021/ja0733179 Supporting Info

Deuterated Protein Folds Obtained Directly from Unassigned Nuclear Overhauser Effect Data Guillermo A. Bermejo and Miguel Llinás pp 3797–3805 DOI: 10.1021/ja074836e Supporting Info

How Do SET-Domain Protein Lysine Methyltransferases Achieve the Methylation State Specificity? Revisited by Ab Initio QM/MM Molecular Dynamics Simulations Po Hu, Shenglong Wang, and Yingkai Zhang pp 3806–3813 DOI: 10.1021/ja075896n Supporting Info

NMR Hyperfine Shifts in Blue Copper Proteins:  A Quantum Chemical Investigation Yong Zhang and Eric Oldfield pp 3814–3823 DOI: 10.1021/ja075978b Supporting Info

Evidence of Water Reorientation on Model Electrocatalytic Surfaces from Nanosecond-Laser-Pulsed Experiments Nuria García-Aráez, Víctor Climent, and Juan M. Feliu pp 3824–3833 DOI: 10.1021/ja0761481

Experimental and Theoretical Charge Density Study of Chemical Bonding in a Co Dimer Complex Jacob Overgaard, Henrik F. Clausen, Jamie A. Platts, and Bo B. Iversen pp 3834–3843 DOI: 10.1021/ja076152c Supporting Info

Mononuclear versus Binuclear Metal-Binding Sites:  Metal-Binding Affinity and Selectivity from PDB Survey and DFT/CDM Calculations Tsung-Ying Yang, Todor Dudev, and Carmay Lim pp 3844–3852 DOI: 10.1021/ja076277h Supporting Info

Binding of Serotonin to the Human Serotonin Transporter. Molecular Modeling and Experimental Validation Leyla Celik, Steffen Sinning, Kasper Severinsen, Carsten G. Hansen, Maria S. Møller, Mikael Bols, Ove Wiborg, and Birgit Schiøtt pp 3853–3865 DOI: 10.1021/ja076403h Supporting Info

Spectroscopic and Density Functional Theory Studies of the Blue−Copper Site in M121SeM and C112SeC Azurin:  Cu−Se Versus Cu−S Bonding Ritimukta Sarangi, Serge I. Gorelsky, Lipika Basumallick, Hee Jung Hwang, Russell C. Pratt, T. Daniel P. Stack, Yi Lu, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 3866–3877 DOI: 10.1021/ja076495a Supporting Info

A Delicate Electronic Balance between Metal and Ligand in [Cu−P−Cu−P] Diamondoids:  Oxidation State Dependent Plasticity and the Formation of a Singlet Diradicaloid Young Min Rhee and Martin Head-Gordon pp 3878–3887 DOI: 10.1021/ja0764916 Supporting Info

Neutron Diffraction Studies on a 4-Coordinate Hydrogen Atom in an Yttrium Cluster Muhammed Yousufuddin, Matthias J. Gutmann, Jens Baldamus, Olivier Tardif, Zhaomin Hou, Sax A. Mason, Garry J. McIntyre, and Robert Bau pp 3888–3891 DOI: 10.1021/ja076520c Supporting Info

Peptide Amphiphile Nanofibers with Conjugated Polydiacetylene Backbones in Their Core Lorraine Hsu, Gregory L. Cvetanovich, and Samuel I. Stupp pp 3892–3899 DOI: 10.1021/ja076553s Supporting Info

Minimal Pharmacophoric Elements and Fragment Hopping, an Approach Directed at Molecular Diversity and Isozyme Selectivity. Design of Selective Neuronal Nitric Oxide Synthase Inhibitors Haitao Ji, Benjamin Z. Stanton, Jotaro Igarashi, Huiying Li, Pavel Martásek, Linda J. Roman, Thomas L. Poulos, and Richard B. Silverman pp 3900–3914 DOI: 10.1021/ja0772041 Supporting Info

Why Are Water−Hydrophobic Interfaces Charged? Konstantin N. Kudin and Roberto Car pp 3915–3919 DOI: 10.1021/ja077205t

Syndiotactic Polystyrene Nanofibrils in Silica Nanotube Reactors:  Understanding of Synthesis with Ultrahigh Molecular Weight Kyu Yong Choi, Joong Jin Han, Bo He, and Sang Bok Lee pp 3920–3926 DOI: 10.1021/ja077272n

Hyperdimensional NMR Spectroscopy with Nonlinear Sampling Victor A. Jaravine, Anastasia V. Zhuravleva, Perttu Permi, Ilgis Ibraghimov, and Vladislav Yu. Orekhov pp 3927–3936 DOI: 10.1021/ja077282o Supporting Info

Single-Crystalline, Size, and Orientation Controllable Nanowires and Ultralong Microwires of Organic Semiconductor with Strong Photoswitching Property Lang Jiang, Yanyan Fu, Hongxiang Li, and Wenping Hu pp 3937–3941 DOI: 10.1021/ja077600j Supporting Info

Trisphenalenyl-Based Neutral Radical Molecular Conductor Sushanta K. Pal, Mikhail E. Itkis, Fook S. Tham, Robert W. Reed, Richard T. Oakley, and Robert C. Haddon pp 3942–3951 DOI: 10.1021/ja077771o Supporting Info

Anionic Charge Is Prioritized over Geometry in Aluminum and Magnesium Fluoride Transition State Analogs of Phosphoryl Transfer Enzymes Nicola J. Baxter, G. Michael Blackburn, James P. Marston, Andrea M. Hounslow, Matthew J. Cliff, Wolfgang Bermel, Nicholas H. Williams, Florian Hollfelder, David E. Wemmer, and Jonathan P. Waltho pp 3952–3958 DOI: 10.1021/ja078000n

Protein Structure Determination from 13C Spin-Diffusion Solid-State NMR Spectroscopy Theofanis Manolikas, Torsten Herrmann, and Beat H. Meier pp 3959–3966 DOI: 10.1021/ja078039s Supporting Info

Simulations of DNA Pol λ R517 Mutants Indicate 517's Crucial Role in Ternary Complex Stability and Suggest DNA Slippage Origin Meredith C. Foley and Tamar Schlick pp 3967–3977 DOI: 10.1021/ja077982t Supporting Info

Guest-Induced Modification of a Magnetically Active Ultramicroporous, Gismondine-like, Copper(II) Coordination Network Jorge A. R. Navarro, Elisa Barea, Antonio Rodríguez-Diéguez, Juan M. Salas, Conchi O. Ania, José B. Parra, Norberto Masciocchi, Simona Galli, and Angelo Sironi pp 3978–3984 DOI: 10.1021/ja078074z

Fused Five-Membered Rings Determine the Stability of C60F60 Jianfeng Jia, Hai-Shun Wu, Xiao-Hong Xu, Xian-Ming Zhang, and Haijun Jiao pp 3985–3988 DOI: 10.1021/ja0781590 Supporting Info

Fluorescence of Size-Expanded DNA Bases:  Reporting on DNA Sequence and Structure with an Unnatural Genetic Set Andrew T. Krueger and Eric T. Kool pp 3989–3999 DOI: 10.1021/ja0782347 Supporting Info

A Microfluidic Fuel Cell with Flow-Through Porous Electrodes Erik Kjeang, Raphaelle Michel, David A. Harrington, Ned Djilali, and David Sinton pp 4000–4006 DOI: 10.1021/ja078248c

Quantum Dot Solar Cells. Tuning Photoresponse through Size and Shape Control of CdSe−TiO2 Architecture Anusorn Kongkanand, Kevin Tvrdy, Kensuke Takechi, Masaru Kuno, and Prashant V. Kamat pp 4007–4015 DOI: 10.1021/ja0782706 Supporting Info

Ag, Ag2S, and Ag2Se Nanocrystals:  Synthesis, Assembly, and Construction of Mesoporous Structures Dingsheng Wang, Ting Xie, Qing Peng, and Yadong Li pp 4016–4022 DOI: 10.1021/ja710004h Supporting Info

One-Dimensional Iron−Cyclopentadienyl Sandwich Molecular Wire with Half Metallic, Negative Differential Resistance and High-Spin Filter Efficiency Properties Liping Zhou, Shuo-Wang Yang, Man-Fai Ng, Michael B. Sullivan, Vincent B.C. Tan, and Lei Shen pp 4023–4027 DOI: 10.1021/ja7100246

Genetically Encoding Protein Oxidative Damage Heinz Neumann, Jennifer L. Hazen, John Weinstein, Ryan A. Mehl, and Jason W. Chin pp 4028–4033 DOI: 10.1021/ja710100d

A Quasi-Time-Resolved CryoTEM Study of the Nucleation of CaCO3 under Langmuir Monolayers Benoît P. Pichon, Paul H. H. Bomans, Peter M. Frederik, and Nico A. J. M. Sommerdijk pp 4034–4040 DOI: 10.1021/ja710416h Supporting Info

Oxide and Carbide Formation at Titanium/Organic Monolayer Interfaces Jason J. Blackstock, Carrie L. Donley, William F. Stickle, Douglas A. A. Ohlberg, J. Joshua Yang, Duncan R. Stewart, and R. Stanley Williams pp 4041–4047 DOI: 10.1021/ja710448e Supporting Info

Visualization of Transient Ultra-Weak Protein Self-Association in Solution Using Paramagnetic Relaxation Enhancement Chun Tang, Rodolfo Ghirlando, and G. Marius Clore pp 4048–4056 DOI: 10.1021/ja710493m

Role of Sulfide Radical Cations in Electron Transfer Promoted Molecular Oxygenations at Sulfur Edward L. Clennan and Chen Liao pp 4057–4068 DOI: 10.1021/ja710301s Supporting Info

Templation of the Excited-State Chemistry of α-(n-Alkyl) Dibenzyl Ketones:  How Guest Packing within a Nanoscale Supramolecular Capsule Influences Photochemistry Corinne L. D. Gibb, Arun Kumar Sundaresan, V. Ramamurthy, and Bruce C. Gibb pp 4069–4080 DOI: 10.1021/ja7107917 Supporting Info

Controlling a Single Protein in a Nanopore through Electrostatic Traps Mohammad M. Mohammad, Sumit Prakash, Andreas Matouschek, and Liviu Movileanu pp 4081–4088 DOI: 10.1021/ja710787a Supporting Info

Syntheses of Highly Fluorescent GFP-Chromophore Analogues Liangxing Wu and Kevin Burgess pp 4089–4096 DOI: 10.1021/ja710388h Supporting Info

Addition/Oxidative Rearrangement of 3-Furfurals and 3-Furyl Imines:  New Approaches to Substituted Furans and Pyrroles Ann Rowley Kelly, Michael H. Kerrigan, and Patrick J. Walsh pp 4097–4104 DOI: 10.1021/ja710988q Supporting Info

Induced Fit Interanion Discrimination by Binding-Induced Excimer Formation Maria H. Filby, Sara Jane Dickson, Nelsi Zaccheroni, Luca Prodi, Sara Bonacchi, Marco Montalti, Martin J. Paterson, Terry D. Humphries, Claudio Chiorboli,and Jonathan W. Steed pp 4105–4113 DOI: 10.1021/ja711012d Supporting Info

Syntheses of Trisila Analogues of Allyl Chlorides and Their Transformations to Chlorocyclotrisilanes, Cyclotrisilanides, and a Trisilaindane Kai Abersfelder and David Scheschkewitz pp 4114–4121 DOI: 10.1021/ja711169w Supporting Info

Optical Band Gap Modification of Single-Walled Carbon Nanotubes by Encapsulated Fullerenes Toshiya Okazaki, Shingo Okubo, Takeshi Nakanishi, Soon-Kil Joung, Takeshi Saito, Minoru Otani, Susumu Okada, Shunji Bandow, and Sumio Iijima pp 4122–4128 DOI: 10.1021/ja711103y

Calix[4]pyrrole:  A New Ion-Pair Receptor As Demonstrated by Liquid−Liquid Extraction Matthieu P. Wintergerst, Tatiana G. Levitskaia, Bruce A. Moyer, Jonathan L. Sessler, and Lætitia H. Delmau pp 4129–4139 DOI: 10.1021/ja7102179 Supporting Info

Arylallylic Lithium Compounds, Internally versus Externally Coordinated:  Comparison of Their Structures and Dynamic Behavior via X-ray Crystallography and NMR Gideon Fraenkel, Xiao Chen, Judith Gallucci, and Yulin Ren pp 4140–4145 DOI: 10.1021/ja0765215 Supporting Info

TMG-chitotriomycin, an Enzyme Inhibitor Specific for Insect and Fungal β-N-Acetylglucosaminidases, Produced by Actinomycete Streptomyces anulatus NBRC 13369 Hirokazu Usuki, Teruhiko Nitoda, Misato Ichikawa, Nahoko Yamaji, Takashi Iwashita, Hajime Komura, and Hiroshi Kanzaki pp 4146–4152 DOI: 10.1021/ja077641f Supporting Info

Powdered KOH in DMSO:  An Efficient Base for Asymmetric Cyclization via Memory of Chirality at Ambient Temperature Takeo Kawabata, Katsuhiko Moriyama, Shimpei Kawakami, and Kazunori Tsubaki pp 4153–4157 DOI: 10.1021/ja077684w Supporting Info

Variable Density Effect of Self-Assembled Polarizable Monolayers on the Electronic Properties of Silicon Naama Peor, Ruthy Sfez, and Shlomo Yitzchaik pp 4158–4165 DOI: 10.1021/ja077933g Supporting Info

Strain-Controlled, Photochemically, or Thermally Promoted Haptotropic Shifts of Cyclopentadienyl Ligands in Group 8 Metallocenophanes David E. Herbert, Makoto Tanabe, Sara C. Bourke, Alan J. Lough, and Ian Manners pp 4166–4176 DOI: 10.1021/ja077334+ Supporting Info

The Surface Conductivity at the Diamond/Aqueous Electrolyte Interface Jose A. Garrido, Andreas Härtl, Markus Dankerl, Andreas Reitinger, Martin Eickhoff, Andreas Helwig, Gerhard Müller, and Martin Stutzmann pp 4177–4181 DOI: 10.1021/ja078207g

Investigation of Structural Transition of Regenerated Silk Fibroin Aqueous Solution by Rheo-NMR Spectroscopy Kosuke Ohgo, Frank Bagusat, Tetsuo Asakura, and Ulrich Scheler pp 4182–4186 DOI: 10.1021/ja710011d

Experimental Observation of the Transition between Gas-Phase and Aqueous Solution Structures for Acetylcholine, Nicotine, and Muscarine Ions Mahamadou Seydou, Gilles Grégoire, Jean Liquier, J. Lemaire, Jean Pierre Schermann, and Charles Desfrançois pp 4187–4195 DOI: 10.1021/ja710040p Supporting Info

Stereodivergent Methodology for the Synthesis of Complex Pyrrolidines Stephen K. Jackson, Avedis Karadeolian, Alex B. Driega, and Michael A. Kerr pp 4196–4201 DOI: 10.1021/ja710289k Supporting Info

Alkyl-Functionalized Organic Dyes for Efficient Molecular Photovoltaics [J. Am. Chem. Soc. 2006, 128, 14256−14257]. Nagatoshi Koumura, Zhong-Sheng Wang, Shogo Mori, Masanori Miyashita, Eiji Suzuki, and Kohjiro Hara pp 4202–4203 DOI: 10.1021/ja7112596 Supporting Info

Microwave Synthesis of Highly Aligned Ultra Narrow Semiconductor Rods and Wires [J. Am. Chem. Soc. 2006, 128, 2790−2791]. Asit Baran Panda, Garry Glaspell, and M. Samy El-Shall p 4203 DOI: 10.1021/ja8003717

Stable Analogues of Aminoacyl-tRNA for Inhibition of an Essential Step of Bacterial Cell-Wall Synthesis [J. Am. Chem. Soc. 2007, 129, 12642−12643]. Maryline Chemama, Matthieu Fonvielle, Régis Villet, Michel Arthur, Jean-Marc Valéry, and Mélanie Etheve-Quelquejeu pp 4203–4204 DOI: 10.1021/ja710232g

Insight into the Mechanisms of Cooperative Self-Assembly:  The “Sergeants-and-Soldiers” Principle of Chiral and Achiral C3-Symmetrical Discotic Triamides [J. Am. Chem. Soc. 2008, 130, 606−611]. Maarten M. J. Smulders, Albertus P. H. J. Schenning, and E. W. Meijer p 4204 DOI: 10.1021/ja800820k

Photofunctional Transition Metal Complexes. Structure and Bonding, 123 Edited by Vivian W. W. Yam (The University of Hong Kong). Series edited by D. Michael P. Mingos. Springer:  Berlin, Heidelberg, New York. 2007 xii + 260 pp. $249.00. ISBN 978-3-540-36809-0. William B. Connick p 4205 DOI: 10.1021/ja077016a

Chemical Biology:  From Small Molecules to Systems Biology and Drug Design, Volumes 1−3 Edited by Stuart L. Schreiber (Harvard University, Cambridge, MA), Tarun M. Kapoor (Rockefeller University, New York, NY), and Günther Wess (GSF-Forschungszentrum für Umwelt und Gesundheit, Neuherberg, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. 1280 pp. $625. ISBN 978-3-527-31150-7. Megan E. Pomianek and Martin F. Semmelhack pp 4205–4206 DOI: 10.1021/ja076981y

Vanadium:  The Versatile Metal. ACS Symposium Series 974. Edited by Kenneth Kustin (Brandeis University), João Costa Pessoa (IST-Technical University of Lisboa), and Debbie C. Crans (Colorado State University) American Chemical Society:  Washington, D.C. (distributed by Oxford University Press). 2007. xliv + 448 pp. $175. ISBN 978-0-8412-7446-4. p 4206 DOI: 10.1021/ja800427w

Issue 13

Small-Molecule Fluorophores To Detect Cell-State Switching in the Context of High-Throughput Screening Bridget K. Wagner, Hyman A. Carrinski, Young-Hoon Ahn, Yun Kyung Kim, Tamara J. Gilbert, Dina A. Fomina, Stuart L. Schreiber, Young-Tae Chang, and Paul A. Clemons pp 4208–4209 DOI: 10.1021/ja077656d Supporting Info

Conversion of Anisotropically Phase-Segregated Pd/γ-Fe2O3 Nanoparticles into Exchange-Coupled fct-FePd/α-Fe Nanocomposite Magnets Toshiharu Teranishi, Ayako Wachi, Masayuki Kanehara, Tetsuya Shoji, Noritsugu Sakuma, and Masafumi Nakaya pp 4210–4211 DOI: 10.1021/ja077921v Supporting Info

PASADENA Hyperpolarization of Succinic Acid for MRI and NMR Spectroscopy Eduard Y. Chekmenev, Jan Hövener, Valerie A. Norton, Kent Harris, Lynne S. Batchelder, Pratip Bhattacharya, Brian D. Ross, and Daniel P. Weitekamp pp 4212–4213 DOI: 10.1021/ja7101218

Linear Assemblies of Magnetic Nanoparticles as MRI Contrast Agents Serena A. Corr, Stephen J. Byrne, Renata Tekoriute, Carla J. Meledandri, Dermot F. Brougham, Marina Lynch, Christian Kerskens, Laurence O'Dwyer, and Yurii K. Gun'ko pp 4214–4215 DOI: 10.1021/ja710172z Supporting Info

Two-Dimensional Graphene Nanoribbons Xiaoyin Yang, Xi Dou, Ali Rouhanipour, Linjie Zhi, Hans Joachim Räder, and Klaus Müllen pp 4216–4217 DOI: 10.1021/ja710234t Supporting Info

Azo Supramolecules on Au(111) with Controlled Size and Shape Yongfeng Wang, Xin Ge, Guillaume Schull, Richard Berndt, Claudia Bornholdt, Felix Koehler, and Rainer Herges pp 4218–4219 DOI: 10.1021/ja710414b Supporting Info

Alkyl Peroxides Reveal the Ring Opening Mechanism of Verdoheme Catalyzed by Heme Oxygenase Toshitaka Matsui, Kohei Omori, Hiromichi Jin, and Masao Ikeda-Saito pp 4220–4221 DOI: 10.1021/ja710495z Supporting Info

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity Atsushi Kawachi, Atsushi Tani, Junpei Shimada, and Yohsuke Yamamoto pp 4222–4223 DOI: 10.1021/ja710615r Supporting Info

Half-Metallicity in Edge-Modified Zigzag Graphene Nanoribbons Er-jun Kan, Zhenyu Li, Jinlong Yang, and J. G. Hou pp 4224–4225 DOI: 10.1021/ja710407t Supporting Info

Spontaneous Self-Assembly of Metal−Organic Cationic Nanocages to Form Monodisperse Hollow Vesicles in Dilute Solutions Dong Li, Jie Zhang, Kai Landskron, and Tianbo Liu pp 4226–4227 DOI: 10.1021/ja710820a

“Fatal Adsorption” of Brushlike Macromolecules:  High Sensitivity of C−C Bond Cleavage Rates to Substrate Surface Energy Natalia V. Lebedeva, Frank C. Sun, Hyung-il Lee, Krzysztof Matyjaszewski, and Sergei S. Sheiko pp 4228–4229 DOI: 10.1021/ja7111806 Supporting Info

A Structure−Permeability Relationship of Ultrathin Nanoporous Silicon Membrane:  A Comparison with the Nuclear Envelope Eunkyoung Kim, Hui Xiong, Christopher C. Striemer, David Z. Fang, Philippe M. Fauchet, James L. McGrath, and Shigeru Amemiya pp 4230–4231 DOI: 10.1021/ja711258w Supporting Info

Cleavage and Isomerization of UpU Promoted by Dinuclear Metal Ion Complexes Heidi Linjalahti, Guoqiang Feng, Juan C. Mareque-Rivas, Satu Mikkola, and Nicholas H. Williams pp 4232–4233 DOI: 10.1021/ja711347w Supporting Info

Biocomputing Security System:  Concatenated Enzyme-Based Logic Gates Operating as a Biomolecular Keypad Lock Guinevere Strack, Maryna Ornatska, Marcos Pita, and Evgeny Katz pp 4234–4235 DOI: 10.1021/ja7114713 Supporting Info

Site-Specific Prodrug Release Using Visible Light Michael Y. Jiang and David Dolphin pp 4236–4237 DOI: 10.1021/ja800140g Supporting Info

A Facile and Patternable Method for the Surface Modification of Carbon Nanotube Forests Using Perfluoroarylazides Stefan J. Pastine, David Okawa, Brian Kessler, Marco Rolandi, Mark Llorente, Alex Zettl, and Jean M. J. Fréchet pp 4238–4239 DOI: 10.1021/ja8003446 Supporting Info

Modular Synthesis of Functionalized Benzosiloles by Tin-Mediated Cyclization of (o-Alkynylphenyl)silane Laurean Ilies, Hayato Tsuji, Yoshiharu Sato, and Eiichi Nakamura pp 4240–4241 DOI: 10.1021/ja800636g Supporting Info

Stoichiometric and Homogeneous-Catalytic Diboration of the NN Double Bond of Azobenzene Holger Braunschweig and Thomas Kupfer pp 4242–4243 DOI: 10.1021/ja8006879 Supporting Info

Reactivity of Mononuclear Alkylperoxo Copper(II) Complex. O−O Bond Cleavage and C−H Bond Activation Atsushi Kunishita, Hirohito Ishimaru, Satoru Nakashima, Takashi Ogura, and Shinobu Itoh pp 4244–4245 DOI: 10.1021/ja800443s Supporting Info

Two-Photon Fluorescent Turn-On Probe for Lipid Rafts in Live Cell and Tissue Hwan Myung Kim, Byeong Ha Jeong, Ju-Yong Hyon, Myoung Jin An, Mun Sik Seo, Jin Hee Hong, Kyoung J. Lee, Chul Hoon Kim, Taiha Joo, Seok-Cheol Hong, and Bong Rae Cho pp 4246–4247 DOI: 10.1021/ja711391f Supporting Info

Carboxylation of an ansa-Zirconocene Dinitrogen Complex:  Regiospecific Hydrazine Synthesis from N2 and CO2 Donald J. Knobloch, Hannah E. Toomey, and Paul J. Chirik pp 4248–4249 DOI: 10.1021/ja8008506 Supporting Info

Unusually Weak Metal−Hydrogen Bonds in HV(CO)4(P−P) and Their Effectiveness as H• Donors Jongwook Choi, Mary E. Pulling, Deborah M. Smith, and Jack R. Norton pp 4250–4252 DOI: 10.1021/ja710455c Supporting Info

Stereoretentive Synthesis and Chemoselective Amide-Forming Ligations of C-Terminal Peptide α-Ketoacids Lei Ju, Alexander R. Lippert, and Jeffrey W. Bode pp 4253–4255 DOI: 10.1021/ja800053t Supporting Info

An RNA Aptamer-Based Electrochemical Biosensor for Detection of Theophylline in Serum Elena E. Ferapontova, Eva M. Olsen, and Kurt V. Gothelf pp 4256–4258 DOI: 10.1021/ja711326b Supporting Info

Demonstration of Molecular Assembly on Si (100) for CMOS-Compatible Molecule-Based Electronic Devices Nadine Gergel-Hackett, Christopher D. Zangmeister, Christina A. Hacker, Lee. J. Richter, and Curt. A. Richter pp 4259–4261 DOI: 10.1021/ja800378b Supporting Info

Redox Chemistry of the Triplet Complex (PNP)CoI Michael J. Ingleson, Maren Pink, Hongjun Fan, and Kenneth G. Caulton pp 4262–4276 DOI: 10.1021/ja074378+ Supporting Info

Intramolecular Energy Transfer within Butadiyne-Linked Chlorophyll and Porphyrin Dimer-Faced, Self-Assembled Prisms Richard F. Kelley, Suk Joong Lee, Thea M. Wilson, Yasuyuki Nakamura, David M. Tiede, Atsuhiro Osuka, Joseph T. Hupp, and Michael R. Wasielewski pp 4277–4284 DOI: 10.1021/ja075494f Supporting Info

Gas-Phase C−H and N−H Bond Activation by a High Valent Nitrido-Iron Dication and NH-Transfer to Activated Olefins Maria Schlangen, Johannes Neugebauer, Markus Reiher, Detlef Schröder, Jesús Pitarch López, Marco Haryono, Frank W. Heinemann, Andreas Grohmann, and Helmut Schwarz pp 4285–4294 DOI: 10.1021/ja075617w Supporting Info

The Degree of Structural Protection at the Edge β-Strands Determines the Pathway of Amyloid Formation in Globular Proteins Gemma Soldi, Francesco Bemporad, and Fabrizio Chiti pp 4295–4302 DOI: 10.1021/ja076628s Supporting Info

Topochemical 3D Polymerization of C60 under High Pressure at Elevated Temperatures Shoji Yamanaka, Nagesh S. Kini, Akira Kubo, Saeko Jida, and Hideaki Kuramoto pp 4303–4309 DOI: 10.1021/ja076761k Supporting Info

Mechanisms of Inter- and Intramolecular Communication in GPCRs and G Proteins Francesco Raimondi, Michele Seeber, Pier G. De Benedetti, and Francesca Fanelli pp 4310–4325 DOI: 10.1021/ja077268b Supporting Info

Preparation of Microscopic and Planar Oil−Water Interfaces That Are Decorated with Prescribed Densities of Insoluble Amphiphiles Maria-Victoria Meli, I-Hsin Lin, and Nicholas L. Abbott pp 4326–4333 DOI: 10.1021/ja077379a Supporting Info

Atomic Structure of a Short α-Helix Stabilized by a Main Chain Hydrogen-Bond Surrogate Jie Liu, Deyun Wang, Qi Zheng, Min Lu, and Paramjit S. Arora pp 4334–4337 DOI: 10.1021/ja077704u Supporting Info

On the Nature of Antimicrobial Activity:  A Model for Protegrin-1 Pores Allison A. Langham, Abdallah Sayyed Ahmad, and Yiannis N. Kaznessis pp 4338–4346 DOI: 10.1021/ja0780380 Supporting Info

Screening of π-Basic Naphthalene and Anthracene Amplifiers for π-Acidic Synthetic Pore Sensors Shinya Hagihara, Ludovic Gremaud, Guillaume Bollot, Jiri Mareda, and Stefan Matile pp 4347–4351 DOI: 10.1021/ja078256t Supporting Info

Iron Complexes of Dendrimer-Appended Carboxylates for Activating Dioxygen and Oxidizing Hydrocarbons Min Zhao, Brett Helms, Elena Slonkina, Simone Friedle, Dongwhan Lee, Jennifer DuBois, Britt Hedman, Keith O. Hodgson, Jean M. J. Fréchet, and Stephen J. Lippard pp 4352–4363 DOI: 10.1021/ja076817a Supporting Info

π•−π• Bonding Interactions Generated by Halogen Oxidation of Zirconium(IV) Redox-Active Ligand Complexes Nicole A. Ketterer, Hongjun Fan, Karen J. Blackmore, Xiaofan Yang, Joseph W. Ziller, Mu-Hyun Baik, and Alan F. Heyduk pp 4364–4374 DOI: 10.1021/ja077337m Supporting Info

Stereochemical Nonrigidity of a Chiral Rhodium Boryl Hydride Complex:  A σ-Borane Complex as Transition State for Isomerization Marius V. Câmpian, Eric Clot, Odile Eisenstein, Ulrike Helmstedt, Naseralla Jasim, Robin N. Perutz, Adrian C. Whitwood, and David Williamson pp 4375–4385 DOI: 10.1021/ja077357o Supporting Info

Determination of the Origin of Stereoselectivity in Multiple-Transition-State Reactions Using DFT Calculations:  Enantioselective Synthesis of Homoallylic Alcohols from Aliphatic Methyl Ketones via an Auxiliary-Mediated Allylation Lutz F. Tietze, Tom Kinzel, and Stefan Schmatz pp 4386–4395 DOI: 10.1021/ja078032a Supporting Info

2,3,5,6-Tetrafluorophenylnitren-4-yl:  Electron Paramagnetic Resonance Spectroscopic Characterization of a Quartet-Ground-State Nitreno Radical Wolfram Sander, Dirk Grote, Simone Kossmann, and Frank Neese pp 4396–4403 DOI: 10.1021/ja078171s

Computational Modeling of the Optical Rotation of Amino Acids:  A New Look at an Old Rule for pH Dependence of Optical Rotation Matthew D. Kundrat and Jochen Autschbach pp 4404–4414 DOI: 10.1021/ja078257l Supporting Info

Pressure-Induced Polymerization of Diiodobutadiyne in Assembled Cocrystals Christopher Wilhelm, Stephen A. Boyd, Samrat Chawda, Frank W. Fowler, Nancy S. Goroff, Gary P. Halada, Clare P. Grey, Joseph W. Lauher, Liang Luo, C. David Martin, John B. Parise, Cathy Tarabrella, and Jeffrey A. Webb pp 4415–4420 DOI: 10.1021/ja0782910 Supporting Info

Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton:  Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin Lei Jiao, Changxia Yuan, and Zhi-Xiang Yu pp 4421–4430 DOI: 10.1021/ja7100449 Supporting Info

Light Harvesting in Photosystem II Core Complexes Is Limited by the Transfer to the Trap:  Can the Core Complex Turn into a Photoprotective Mode? Grzegorz Raszewski and Thomas Renger pp 4431–4446 DOI: 10.1021/ja7099826 Supporting Info

Near-Infrared Light Activated Release of Nitric Oxide from Designed Photoactive Manganese Nitrosyls:  Strategy, Design, and Potential as NO Donors Aura A. Eroy-Reveles, Yvonne Leung, Christine M. Beavers, Marilyn M. Olmstead, and Pradip K. Mascharak pp 4447–4458 DOI: 10.1021/ja710265j Supporting Info

Scope and Mechanism of Formal SN2‘ Substitution Reactions of a Monomeric Imidozirconium Complex with Allylic Electrophiles Gojko Lalic, Jamin L. Krinsky, and Robert G. Bergman pp 4459–4465 DOI: 10.1021/ja7106096 Supporting Info

De Novo Design of Strand-Swapped β-Hairpin Hydrogels Radhika P. Nagarkar, Rohan A. Hule, Darrin J. Pochan, and Joel P. Schneider pp 4466–4474 DOI: 10.1021/ja710295t Supporting Info

Pressure Response of Three-Dimensional Cyanide-Bridged Bimetallic Magnets Masaaki Ohba, Wakako Kaneko, Susumu Kitagawa, Takuho Maeda, and Masaki Mito pp 4475–4484 DOI: 10.1021/ja7110509 Supporting Info

Generation and Spectroscopic Characterization of Ruthenacyclobutane and Ruthenium Olefin Carbene Intermediates Relevant to Ring Closing Metathesis Catalysis Edwin F. van der Eide, Patricio E. Romero, and Warren E. Piers pp 4485–4491 DOI: 10.1021/ja710364e Supporting Info

Construction of a Chiral Quaternary Carbon Center by Indium-Catalyzed Asymmetric α-Alkenylation of β-Ketoesters Taisuke Fujimoto, Kohei Endo, Hayato Tsuji, Masaharu Nakamura, and Eiichi Nakamura pp 4492–4496 DOI: 10.1021/ja710408f Supporting Info

Attaining Control by Design over the Hydrolytic Stability of Fe-TAML Oxidation Catalysts Victor Polshin, Delia-Laura Popescu, Andreas Fischer, Arani Chanda, David C. Horner, Evan S. Beach, Jennifer Henry, Yong-Li Qian, Colin P. Horwitz, Gabor Lente, Istvan Fabian, Eckard Münck, Emile L. Bominaar, Alexander D. Ryabov, and Terrence J. Collins pp 4497–4506 DOI: 10.1021/ja7106383 Supporting Info

Biosynthesis and Structures of Cyclomarins and Cyclomarazines, Prenylated Cyclic Peptides of Marine Actinobacterial Origin Andrew W. Schultz, Dong-Chan Oh, John R. Carney, R. Thomas Williamson, Daniel W. Udwary, Paul R. Jensen, Steven J. Gould, William Fenical, and Bradley S. Moore pp 4507–4516 DOI: 10.1021/ja711188x Supporting Info

Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction Paul Ha-Yeon Cheong, Philip Morganelli, Michael R. Luzung, K. N. Houk, and F. Dean Toste pp 4517–4526 DOI: 10.1021/ja711058f Supporting Info

Nanostructured AgPbmSbTem+2 System Bulk Materials with Enhanced Thermoelectric Performance Min Zhou, Jing-Feng Li, and Takuji Kita pp 4527–4532 DOI: 10.1021/ja7110652

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster Arti S. Pandey, Travis V. Harris, Logan J. Giles, John W. Peters, and Robert K. Szilagyi pp 4533–4540 DOI: 10.1021/ja711187e Supporting Info

Light-Controlled Supramolecular Helicity of a Liquid Crystalline Phase Using a Helical Polymer Functionalized with a Single Chiroptical Molecular Switch Dirk Pijper, Mahthild G. M. Jongejan, Auke Meetsma, and Ben L. Feringa pp 4541–4552 DOI: 10.1021/ja711283c Supporting Info

Regioselective Activation of Oxo Ligands in Functionalized Dawson Polyoxotungstates Cécile Boglio, Kévin Micoine, Étienne Derat, René Thouvenot, Bernold Hasenknopf, Serge Thorimbert, Emmanuel Lacôte, and Max Malacria pp 4553–4561 DOI: 10.1021/ja800072q Supporting Info

Identifying and Alleviating Electrochemical Side-Reactions in Light-Emitting Electrochemical Cells Junfeng Fang, Piotr Matyba, Nathaniel D. Robinson, and Ludvig Edman pp 4562–4568 DOI: 10.1021/ja7113294

Combinatorial Chemistry on Solid Supports. Topics in Current Chemistry, 278 Edited by Stefan Bräse (Universität Karlsruhe, Germany). Springer:  Berlin, Heidelberg, New York. 2007. xii + 360. $339.00. ISBN 978-3-540-72509-1. Rolando Perez-Pineiro and Hicham Fenniri pp 4569–4570 DOI: 10.1021/ja077018v

Computational and Structural Approaches to Drug Discovery:  Ligand-Protein Interactions Edited by Robert M. Stroud and Janet Finer-Moore (University of California, San Francisco). Royal Society of Chemistry:  Cambridge. 2008. $189.00. ISBN 978-0-85404-365-1. p 4570 DOI: 10.1021/ja800727t

Catalysts for Fine Chemical Synthesis:  Regio- and Stereo-Controlled Oxidations and Reductions, Volume 5 John Wiley & Sons, Ltd.:  Chichester. 2007. xvi + 312 pp. $200. ISBN 978-0-470-09022-0. p 4570 DOI: 10.1021/ja800768e

Targets in Heterocyclic Systems:  Chemistry and Properties, Volume 10 (2006) Edited by Orazio A. Attanasi (University of Urbino, Italy) and Domenico Spinelli (University of Bologna, Italy). Italian Society of Chemistry:  Rome. 2007. viii + 360 pp. $129.00. ISBN 978-88-86208-51-2. p 4570 DOI: 10.1021/ja801048k

Creative Chemical Sensor Systems. Topics in Current Chemistry, 277 Edited by Thomas Schrader (University of Duisburg-Essen, Germany). Springer:  Berlin, Heidelberg, New York. 2007. xiv + 304 pp. $269.00. ISBN 978-3-540-71546-7. Indraneel Ghosh pp 4570–4571 DOI: 10.1021/ja0770173

Fluorescence of Supermolecules, Polymers, and Nanosystems. Springer Series on Fluorescence, 04 Edited by M. N. Berberan-Santos (Instituto Superior Técnico, Lisboa, Portugal). Series edited by O. S. Wolfbeis. Springer:  Berlin, Heidelberg, New York. 2008. xviii + 468 pp. $269.00. ISBN 978-3-540-73927-2. p 4571 DOI: 10.1021/ja801006y

Superelectrophiles and Their Chemistry By George A. Olah (University of Southern California, Los Angeles) and Douglas A. Klumpp (Northern Illinois University, DeKalb). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. viii +302 pp. $125.00. ISBN 978-0-470-04961-7. Donald D. Aue pp 4571–4572 DOI: 10.1021/ja8008902

Issue 14

In Situ Generation of a Bisubstrate Analogue for Protein Arginine Methyltransferase 1 Tanesha Osborne, Rachel L. Weller Roska, Scott R. Rajski, and Paul R. Thompson pp 4574–4575 DOI: 10.1021/ja077104v Supporting Info

Solute-Induced Perturbations of Solvent-Shell Molecules Observed Using Multivariate Raman Curve Resolution Pradeep Perera, Melanie Wyche, Yvette Loethen, and Dor Ben-Amotz pp 4576–4577 DOI: 10.1021/ja077333h Supporting Info

On-Virus Construction of Polyvalent Glycan Ligands for Cell-Surface Receptors Eiton Kaltgrad, Mary K. O'Reilly, Liang Liao, Shoufa Han, James C. Paulson, and M. G. Finn pp 4578–4579 DOI: 10.1021/ja077801n Supporting Info

How Deep Is the Potential Well Confining a Protein in a Specific Conformation? A Single-Molecule Study on Temperature Dependence of Conformational Change between 5 and 18 K Hiroyuki Oikawa, Satoru Fujiyoshi, Takehisa Dewa, Mamoru Nango, and Michio Matsushita pp 4580–4581 DOI: 10.1021/ja078020p Supporting Info

A Homochiral Nanotubular Crystalline Framework of Metallomacrocycles for Enantioselective Recognition and Separation Gao Li, Weibin Yu, and Yong Cui pp 4582–4583 DOI: 10.1021/ja078317n Supporting Info

Bolalipid Membrane Structure Revealed by Solid-State 2H NMR Spectroscopy David P. Holland, Andrey V. Struts, Michael F. Brown, and David H. Thompson pp 4584–4585 DOI: 10.1021/ja710190p Supporting Info

Coincidence of Dynamical Transitions in a Soluble Protein and Its Hydration Water:  Direct Measurements by Neutron Scattering and MD Simulations Kathleen Wood, Andreas Frölich, Alessandro Paciaroni, Martine Moulin, Michael Härtlein, Giuseppe Zaccai, Douglas J. Tobias, and Martin Weik pp 4586–4587 DOI: 10.1021/ja710526r Supporting Info

Regioselective β-Metalation of meso-Phosphanylporphyrins. Structure and Optical Properties of Porphyrin Dimers Linked by Peripherally Fused Phosphametallacycles Yoshihiro Matano, Kazuaki Matsumoto, Yoshihide Nakao, Hidemitsu Uno, Shigeyoshi Sakaki, and Hiroshi Imahori pp 4588–4589 DOI: 10.1021/ja710542e Supporting Info

A New Catalytically Active Colloidal Platinum Nanocatalyst:  The Multiarmed Nanostar Single Crystal Mahmoud A. Mahmoud, Christopher E. Tabor, Mostafa A. El-Sayed, Yong Ding, and Zhong Lin Wang pp 4590–4591 DOI: 10.1021/ja710646t Supporting Info

A [3]Rotaxane with Two Porphyrinic Plates Acting as an Adaptable Receptor Julien Frey, Christian Tock, Jean-Paul Collin, Valérie Heitz, and Jean-Pierre Sauvage pp 4592–4593 DOI: 10.1021/ja7110493 Supporting Info

Ultra Narrow PbS Nanorods with Intense Fluorescence Somobrata Acharya, Ujjal K. Gautam, Toshio Sasaki, Yoshio Bando, Yuval Golan, and Katsuhiko Ariga pp 4594–4595 DOI: 10.1021/ja711064b Supporting Info

An ICT-Based Approach to Ratiometric Fluorescence Imaging of Hydrogen Peroxide Produced in Living Cells Duangkhae Srikun, Evan W. Miller, Dylan W. Domaille, and Christopher J. Chang pp 4596–4597 DOI: 10.1021/ja711480f Supporting Info

Therapeutic Target Metabolism Observed Using Hyperpolarized 15N Choline Cristina Gabellieri, Steven Reynolds, Arnon Lavie, Geoffrey S. Payne, Martin O. Leach, and Thomas R. Eykyn pp 4598–4599 DOI: 10.1021/ja8001293 Supporting Info

Structural Versatility of Anion−π Interactions in Halide Salts with Pentafluorophenyl Substituted Cations Markus Albrecht, Claudia Wessel, Marita de Groot, Kari Rissanen, and Arne Lüchow pp 4600–4601 DOI: 10.1021/ja800219g Supporting Info

Chirality of Amyloid Suprastructures Noa Rubin, Emanuel Perugia, Michal Goldschmidt, Mati Fridkin, and Lia Addadi pp 4602–4603 DOI: 10.1021/ja800328y Supporting Info

Manganous Phosphate Acts as a Superoxide Dismutase Kevin Barnese, Edith B. Gralla, Diane E. Cabelli, and Joan Selverstone Valentine pp 4604–4606 DOI: 10.1021/ja710162n Supporting Info

Molecular Modeling Based Approach to Potent P2−P4 Macrocyclic Inhibitors of Hepatitis C NS3/4A Protease Nigel J. Liverton, M. Katharine Holloway, John A. McCauley, Michael T. Rudd, John W. Butcher, Steven S. Carroll, Jillian DiMuzio, Christine Fandozzi, Kevin F. Gilbert, Shi-Shan Mao, Charles J. McIntyre, Kevin T. Nguyen, Joseph J. Romano, Mark Stahlhut, Bang-Lin Wan, David B. Olsen, and Joseph P. Vacca pp 4607–4609 DOI: 10.1021/ja711120r Supporting Info

Nucleophilic β-Oniovinylation:  Concept, Mechanism, Scope, and Applications Robert Weiss, Matthias Bess, Stefan M. Huber, and Frank W. Heinemann pp 4610–4617 DOI: 10.1021/ja071316a Supporting Info

Polycationic β-Cyclodextrin “Click Clusters”:  Monodisperse and Versatile Scaffolds for Nucleic Acid Delivery Sathya Srinivasachari, Katye M. Fichter, and Theresa M. Reineke pp 4618–4627 DOI: 10.1021/ja074597v Supporting Info

Spectroscopic and Electronic Structure Studies of Symmetrized Models for Reduced Members of the Dimethylsulfoxide Reductase Enzyme Family Rebecca L. McNaughton, Booyong S. Lim, Sushilla Z. Knottenbelt, Richard. H. Holm, and Martin L. Kirk pp 4628–4636 DOI: 10.1021/ja074691b Supporting Info

Organic n-Channel Transistors Based on Core-Cyanated Perylene Carboxylic Diimide Derivatives R. Thomas Weitz, Konstantin Amsharov, Ute Zschieschang, Esther Barrena Villas, Dipak K. Goswami, Marko Burghard, Helmut Dosch, Martin Jansen, Klaus Kern, and Hagen Klauk pp 4637–4645 DOI: 10.1021/ja074675e Supporting Info

DNA-Templated Polymerization of Side-Chain-Functionalized Peptide Nucleic Acid Aldehydes Ralph E. Kleiner, Yevgeny Brudno, Michael E. Birnbaum, and David R. Liu pp 4646–4659 DOI: 10.1021/ja0753997 Supporting Info

Structure, Self-Assembly, and Dual Role of a β-Defensin-like Peptide from the Chinese Soft-Shelled Turtle Eggshell Matrix Rajamani Lakshminarayanan, Subramanian Vivekanandan, Ramar Perumal Samy, Yajnavalka Banerjee, Emma Ooi Chi-Jin, Kay Wah Teo, Seetharama D. S. Jois, R. Manjunatha Kini, and Suresh Valiyaveettil pp 4660–4668 DOI: 10.1021/ja075659k Supporting Info

Direct Measurement of the Rate of Interconversion of Zirconaaziridine Enantiomers Sarah A. Cummings, Jon A. Tunge, and Jack R. Norton pp 4669–4679 DOI: 10.1021/ja0757935 Supporting Info

Quantum Mechanical/Molecular Mechanical Simulation Study of the Mechanism of Hairpin Ribozyme Catalysis Kwangho Nam, Jiali Gao, and Darrin M. York pp 4680–4691 DOI: 10.1021/ja0759141 Supporting Info

Investigation of Secondary Structure Elements by IR/UV Double Resonance Spectroscopy:  Analysis of an Isolated β-Sheet Model System Holger Fricke, Andreas Funk, Thomas Schrader, and Markus Gerhards pp 4692–4698 DOI: 10.1021/ja076031c Supporting Info

Effective Shielding of Triplet Energy Transfer to Conjugated Polymer by Its Dense Side Chains from Phosphor Dopant for Highly Efficient Electrophosphorescence Szu-Po Huang, Tzu-Hao Jen, Yen-Chun Chen, An-En Hsiao, Shu-Hui Yin, Hsiang-Yun Chen, and Show-An Chen pp 4699–4707 DOI: 10.1021/ja076413i Supporting Info

Distinguishing between Dexter and Rapid Sequential Electron Transfer in Covalently Linked Donor−Acceptor Assemblies Monica Soler and James K. McCusker pp 4708–4724 DOI: 10.1021/ja077096i Supporting Info

(Terpyridine)copper(II)−Carbon Nanohorns:  Metallo-nanocomplexes for Photoinduced Charge Separation Georgios Rotas, Atula S. D. Sandanayaka, Nikos Tagmatarchis, Toshinari Ichihashi, Masako Yudasaka, Sumio Iijima, and Osamu Ito pp 4725–4731 DOI: 10.1021/ja077090t Supporting Info

Evidence for Concerted Pathways in Ion-Pairing Coupled Electron Transfers Jean-Michel Savéant pp 4732–4741 DOI: 10.1021/ja077480f

Computer Simulation Study of the Structural Stability and Materials Properties of DNA-Intercalated Layered Double Hydroxides Mary-Ann Thyveetil, Peter V. Coveney, H. Chris Greenwell, and James L. Suter pp 4742–4756 DOI: 10.1021/ja077679s Supporting Info

Orientation of Fluorinated Cholesterol in Lipid Bilayers Analyzed by 19F Tensor Calculation and Solid-State NMR Nobuaki Matsumori, Yusuke Kasai, Tohru Oishi, Michio Murata, and Kaoru Nomura pp 4757–4766 DOI: 10.1021/ja077580l Supporting Info

C60/Corannulene on Cu(110):  A Surface-Supported Bistable Buckybowl−Buckyball Host−Guest System Wende Xiao, Daniele Passerone, Pascal Ruffieux, Kamel Aït−Mansour, Oliver Gröning, Erio Tosatti, Jay S. Siegel, and Roman Fasel pp 4767–4771 DOI: 10.1021/ja077816l Supporting Info

Single Molecule Conformational Dynamics of Adenylate Kinase:  Energy Landscape, Structural Correlations, and Transition State Ensembles Qiang Lu and Jin Wang pp 4772–4783 DOI: 10.1021/ja0780481 Supporting Info

Single-Conformation Ultraviolet and Infrared Spectroscopy of Model Synthetic Foldamers:  β-Peptides Ac-β3-hPhe-NHMe and Ac-β3-hTyr-NHMe Esteban E. Baquero, William H. James, III, Soo Hyuk Choi, Samuel H. Gellman, and Timothy S. Zwier pp 4784–4794 DOI: 10.1021/ja078271y Supporting Info

Single-Conformation Ultraviolet and Infrared Spectroscopy of Model Synthetic Foldamers:  β-Peptides Ac-β3-hPhe-β3-hAla-NHMe and Ac-β3-hAla-β3-hPhe-NHMe Esteban E. Baquero, William H. James III, Soo Hyuk Choi, Samuel H. Gellman, and Timothy S. Zwier pp 4795–4807 DOI: 10.1021/ja078272q Supporting Info

Gas-Phase Thermochemistry of Ruthenium Carbene Metathesis Catalysts Sebastian Torker, Daniel Merki, and Peter Chen pp 4808–4814 DOI: 10.1021/ja078149z Supporting Info

Self-Assembled Donor Comprising Quantum Dots and Fluorescent Proteins for Long-Range Fluorescence Resonance Energy Transfer Huachang Lu, Oliver Schöps, Ulrike Woggon, and Christof M. Niemeyer pp 4815–4827 DOI: 10.1021/ja078243f Supporting Info

Mechanisms of Catalyst Poisoning in Palladium-Catalyzed Cyanation of Haloarenes. Remarkably Facile C−N Bond Activation in the [(Ph3P)4Pd]/[Bu4N]+ CN- System Stefan Erhardt, Vladimir V. Grushin, Alison H. Kilpatrick, Stuart A. Macgregor, William J. Marshall, and D. Christopher Roe pp 4828–4845 DOI: 10.1021/ja078298h Supporting Info

Kinetic and Thermodynamic Characterization of CoII−Substrate Radical Pair Formation in Coenzyme B12-Dependent Ethanolamine Ammonia-Lyase in a Cryosolvent System by Using Time-Resolved, Full-Spectrum Continuous-Wave Electron Paramagnetic Resonance Spectroscopy Miao Wang and Kurt Warncke pp 4846–4858 DOI: 10.1021/ja710069y Supporting Info

Lithium Enolates of Simple Ketones:  Structure Determination Using the Method of Continuous Variation Lara R. Liou, Anne J. McNeil, Antonio Ramirez, Gilman E. S. Toombes, Jocelyn M. Gruver, and David B. Collum pp 4859–4868 DOI: 10.1021/ja7100642 Supporting Info

Solution Structure of a DNA Duplex Containing a Guanine−Difluorotoluene Pair:  A Wobble Pair without Hydrogen Bonding? Danielle A. Pfaff, Kristine M. Clarke, Timothy A. Parr, Joanna M. Cole, Bernhard H. Geierstanger, Deborah C. Tahmassebi, and Tammy J. Dwyer pp 4869–4878 DOI: 10.1021/ja7103608 Supporting Info

Utilizing the Lability of Lead Selenide to Produce Heterostructured Nanocrystals with Bright, Stable Infrared Emission Jeffrey M. Pietryga, Donald J. Werder, Darrick J. Williams, Joanna L. Casson, Richard D. Schaller, Victor I. Klimov, and Jennifer A. Hollingsworth pp 4879–4885 DOI: 10.1021/ja710437r Supporting Info

Design, Synthesis, and Properties of 2‘,4‘-BNANC:  A Bridged Nucleic Acid Analogue S. M. Abdur Rahman, Sayori Seki, Satoshi Obika, Haruhisa Yoshikawa, Kazuyuki Miyashita, and Takeshi Imanishi pp 4886–4896 DOI: 10.1021/ja710342q Supporting Info

Organocatalytic Asymmetric Conjugate Addition to Allenic Esters and Ketones Petteri Elsner, Luca Bernardi, Giorgio Dela Salla, Jacob Overgaard, and Karl Anker Jørgensen pp 4897–4905 DOI: 10.1021/ja710689c Supporting Info

Type II Isopentenyl Diphosphate Isomerase:  Irreversible Inactivation by Covalent Modification of Flavin Steven C. Rothman, Jonathan B. Johnston, Sungwon Lee, Joel R. Walker, and C. Dale Poulter pp 4906–4913 DOI: 10.1021/ja7108954 Supporting Info

Cyclic Peptide Inhibitors of Staphylococcal Virulence Prepared by Fmoc-Based Thiolactone Peptide Synthesis Elizabeth A. George, Richard P. Novick, and Tom W. Muir pp 4914–4924 DOI: 10.1021/ja711126e Supporting Info

Simultaneously Cycled NMR Spectroscopy David M. Parish and Thomas Szyperski pp 4925–4933 DOI: 10.1021/ja711454e Supporting Info

Proton Transfers in Aromatic and Antiaromatic Systems. How Aromatic or Antiaromatic Is the Transition State? An Ab Initio Study Claude F. Bernasconi, Philip J. Wenzel, and Mark L. Ragains pp 4934–4944 DOI: 10.1021/ja078185y Supporting Info

Covalent Heterogenization of a Discrete Mn(II) Bis-Phen Complex by a Metal-Template/Metal-Exchange Method:  An Epoxidation Catalyst with Enhanced Reactivity Tracy J. Terry and T. Daniel P. Stack pp 4945–4953 DOI: 10.1021/ja0742030 Supporting Info

In Vitro Characterization of the Enzymes Involved in TDP-d-Forosamine Biosynthesis in the Spinosyn Pathway of Saccharopolyspora spinosa Lin Hong, Zongbao Zhao, Charles E. Melançon III, Hua Zhang, and Hung-wen Liu pp 4954–4967 DOI: 10.1021/ja0771383

Fluorinated Bis(phenoxyketimine)titanium Complexes for the Living, Isoselective Polymerization of Propylene:  Multiblock Isotactic Polypropylene Copolymers via Sequential Monomer Addition Joseph B. Edson, Zhigang Wang, Edward J. Kramer, and Geoffrey W. Coates pp 4968–4977 DOI: 10.1021/ja077772g Supporting Info

Asymmetric Ni-Catalyzed Conjugate Allylation of Activated Enones Joshua D. Sieber and James P. Morken pp 4978–4983 DOI: 10.1021/ja710922h Supporting Info

Highly cis-1,4 Selective Polymerization of Dienes with Homogeneous Ziegler−Natta Catalysts Based on NCN-Pincer Rare Earth Metal Dichloride Precursors Wei Gao and Dongmei Cui pp 4984–4991 DOI: 10.1021/ja711146t Supporting Info

Mechanism of Reversible Alkyne Coupling at Zirconocene:  Ancillary Ligand Effects Adam D. Miller, Jennifer L. McBee, and T. Don Tilley pp 4992–4999 DOI: 10.1021/ja800025u Supporting Info

Vibrational Spectroscopy of Polymers:  Principles and Practice Edited by Neil J. Everall (ICI Measurement Science Group, Wilton, U.K.), John M. Chalmers (VS Consulting, Stokesley, U.K.), and Peter R. Griffiths (University of Idaho, Moscow, ID). John Wiley & Sons, Ltd:  Chichester. 2007. xii + 574 pp. $260. ISBN 978-0-470-01662-6. Peter Pulay p 5000 DOI: 10.1021/ja076986v

Environmental Radiochemical Analysis III Edited by Peter Warwick (Loughborough University, U.K.). Royal Society of Chemistry:  Cambridge. 2007. x + 220 pp. $209.00. ISBN 978-0-85404-263-0. p 5000 DOI: 10.1021/ja8014742

Characterization and Analysis of Polymers Edited by the staff at Wiley. John Wiley & Sons, Inc.:  Hoboken, NJ. 2008. x + 978 pp. $295.00. ISBN 978-0-470-23300-9. p 5000 DOI: 10.1021/ja801591j

Issue 15

High-density DNA Alignment on an Au(111) Surface Starting from Folded DNA Hiroshi Matsuura, Ayako Hirai, Fumihiko Yamada, Takuya Matsumoto and Tomoji Kawai pp 5002–5003 DOI: 10.1021/ja0773554 Supporting Info

Probing the Mechanical Stability of DNA in the Presence of Monovalent Cations Julea Vlassakis, Jeremy Williams, Kristi Hatch, Claudia Danilowicz, Vincent W. Coljee and Mara Prentiss pp 5004–5005 DOI: 10.1021/ja0776576 Supporting Info

Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst Andrea Sartorel, Mauro Carraro, Gianfranco Scorrano, Rita De Zorzi, Silvano Geremia, Neal D. McDaniel, Stefan Bernhard and Marcella Bonchio pp 5006–5007 DOI: 10.1021/ja077837f Supporting Info

Reductively Labile PRINT Particles for the Delivery of Doxorubicin to HeLa Cells Robby A. Petros, Patricia A. Ropp and Joseph M. DeSimone pp 5008–5009 DOI: 10.1021/ja801436j Supporting Info

Polydiacetylene Liposome Arrays for Selective Potassium Detection Jiseok Lee, Hyong-Jun Kim and Jinsang Kim pp 5010–5011 DOI: 10.1021/ja709996c Supporting Info

Catalyst Self-Adaptation in Conjugate Addition to Nitroalkenes and Nitroacrylates: Instant Chirality Control in Diphenylmethane-Based Phosphoramidite Ligands Kazuki Wakabayashi, Kohsuke Aikawa, Susumu Kawauchi and Koichi Mikami pp 5012–5013 DOI: 10.1021/ja710340n Supporting Info

Hadamard Amino-Acid-Type Edited NMR Experiment for Fast Protein Resonance Assignment Ewen Lescop, Rodolfo Rasia and Bernhard Brutscher pp 5014–5015 DOI: 10.1021/ja800914h Supporting Info

Photocurrent-Generating Properties of Organometallic Fullerene Molecules on an Electrode Yutaka Matsuo, Katsuhiko Kanaizuka, Keiko Matsuo, Yu-Wu Zhong, Takahiro Nakae and Eiichi Nakamura pp 5016–5017 DOI: 10.1021/ja800481d Supporting Info

The Electronic Origin of the Visible-Light Absorption Properties of C-, N- and S-Doped TiO2 Nanomaterials Xiaobo Chen and Clemens Burda pp 5018–5019 DOI: 10.1021/ja711023z Supporting Info

Catalytic Metallonitrene/Alkyne Metathesis: A Powerful Cascade Process for the Synthesis of Nitrogen-Containing Molecules Aaron R. Thornton and Simon B. Blakey pp 5020–5021 DOI: 10.1021/ja7111788 Supporting Info

para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property Tomoki Ogoshi, Suguru Kanai, Shuhei Fujinami, Tada-aki Yamagishi and Yoshiaki Nakamoto pp 5022–5023 DOI: 10.1021/ja711260m Supporting Info

Switching between Supramolecular Dimer and Nonthreaded Supramolecular Self-Assembly of Stilbene Amide-α-Cyclodextrin by Photoirradiation Kazuhiro Yamauchi, Yoshinori Takashima, Akihito Hashidzume, Hiroyasu Yamaguchi and Akira Harada pp 5024–5025 DOI: 10.1021/ja7113135 Supporting Info

“Giant” Multishell CdSe Nanocrystal Quantum Dots with Suppressed Blinking Yongfen Chen, Javier Vela, Han Htoon, Joanna L. Casson, Donald J. Werder, David A. Bussian, Victor I. Klimov and Jennifer A. Hollingsworth pp 5026–5027 DOI: 10.1021/ja711379k Supporting Info

Resolution Enhancement in Solid-State NMR of Oriented Membrane Proteins by Anisotropic Differential Linebroadening Thomas Vosegaard, Kresten Bertelsen, Jan M. Pedersen, Lea Thøgersen, Birgit Schiøtt, Emad Tajkhorshid, Troels Skrydstrup and Niels Chr. Nielsen pp 5028–5029 DOI: 10.1021/ja8000612 Supporting Info

Palladium-Catalyzed Cleavage Reaction of Carbon−Carbon Triple Bond with Molecular Oxygen Promoted by Lewis Acid Azhong Wang and Huanfeng Jiang pp 5030–5031 DOI: 10.1021/ja8002217 Supporting Info

Quantum-Sized Gold Clusters as Efficient Two-Photon Absorbers Guda Ramakrishna, Oleg Varnavski, Junhyung Kim, Dongil Lee and Theodore Goodson pp 5032–5033 DOI: 10.1021/ja800341v Supporting Info

Porous Carbon and Carbon/Metal Oxide Microfibers with Well-Controlled Pore Structure and Interface Qihui Shi, Hongjun Liang, Dan Feng, Jianfang Wang and Galen D. Stucky pp 5034–5035 DOI: 10.1021/ja800376t Supporting Info

Highly Sensitive and Stable Humidity Nanosensors Based on LiCl Doped TiO2 Electrospun Nanofibers Zhenyu Li, Hongnan Zhang, Wei Zheng, Wei Wang, Huimin Huang, Ce Wang, Alan G. MacDiarmid and Yen Wei pp 5036–5037 DOI: 10.1021/ja800176s Supporting Info

Oligonucleotide-Stabilized Ag Nanocluster Fluorophores Chris I. Richards, Sungmoon Choi, Jung-Cheng Hsiang, Yasuko Antoku, Tom Vosch, Angelo Bongiorno, Yih-Ling Tzeng and Robert M. Dickson pp 5038–5039 DOI: 10.1021/ja8005644

Molecular Assembly of a 3D-Ordered Multilayer Marc Altman, Olena Zenkina, Guennadi Evmenenko, Pulak Dutta and Milko E. van der Boom pp 5040–5041 DOI: 10.1021/ja800563h

Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization Shifa Zhu, Joshua V. Ruppel, Hongjian Lu, Lukasz Wojtas and X. Peter Zhang pp 5042–5043 DOI: 10.1021/ja7106838 Supporting Info

Non-Oxidative Coupling Reaction of Methane to Ethane and Hydrogen Catalyzed by the Silica-Supported Tantalum Hydride: (SiO)2Ta−H Daravong Soulivong, Sbastien Norsic, Mostafa Taoufik, Christophe Copret, Jean Thivolle-Cazat, Sudhakar Chakka and Jean-Marie Basset pp 5044–5045 DOI: 10.1021/ja800863x Supporting Info

Synthesis of [4.6.4.6]Fenestradienes and [4.6.4.6]Fenestrenes Based on an 8π−6π-Cyclization-Oxidation Cascade Catherine Hulot, Gaëlle Blond and Jean Suffert pp 5046–5047 DOI: 10.1021/ja800691c Supporting Info

Synthesis of Arylallenes by Palladium-Catalyzed Retro-Propargylation of Homopropargyl Alcohols Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu and Koichiro Oshima pp 5048–5049 DOI: 10.1021/ja800986m Supporting Info

Ring Opening/Fragmentation of Dihydropyrones for the Synthesis of Homopropargyl Alcohols Jumreang Tummatorn and Gregory B. Dudley pp 5050–5051 DOI: 10.1021/ja801018r Supporting Info

Facile Conversion of Cysteine and Alkyl Cysteines to Dehydroalanine on Protein Surfaces: Versatile and Switchable Access to Functionalized Proteins Gonçalo J. L. Bernardes, Justin M. Chalker, James C. Errey and Benjamin G. Davis pp 5052–5053 DOI: 10.1021/ja800800p Supporting Info

Engineering Strength, Porosity, and Emission Intensity of Nanostructured CdSe Networks by Altering the Building-Block Shape Hongtao Yu, Robert Bellair, Rangaramanujam M. Kannan and Stephanie L. Brock pp 5054–5055 DOI: 10.1021/ja801212e Supporting Info

Bi- and Terpyridyl Platinum(II) Chloro Complexes: Molecular Catalysts for the Photogeneration of Hydrogen from Water or Simply Precursors for Colloidal Platinum? Pingwu Du, Jacob Schneider, Fan Li, Wei Zhao, Upali Patel, Felix N. Castellano and Richard Eisenberg pp 5056–5058 DOI: 10.1021/ja711090w Supporting Info

Catalytic Dehydration of 2-Propanol on (WO3)3 Clusters on TiO2(110) Yu Kwon Kim, Roger Rousseau, Bruce D. Kay, J. M. White and Zdenek Dohnálek pp 5059–5061 DOI: 10.1021/ja800730g

Robust, Efficient, and Orthogonal Synthesis of Dendrimers via Thiol-ene “Click” Chemistry Kato L. Killops, Luis M. Campos and Craig J. Hawker pp 5062–5064 DOI: 10.1021/ja8006325 Supporting Info

Inelastic Electron Interaction with Chloroform Clusters embedded in Helium Droplets Stephan Denifl, Fabio Zappa, Ingo Mähr, Andreas Mauracher, Michael Probst, Tilmann D. Märk and Paul Scheier pp 5065–5071 DOI: 10.1021/ja075972m

Equilibrium and Non-equilibrium Kinetics of Self-Assembled Surfactant Monolayers: A Vibrational Sum-Frequency Study of Dodecanoate at the Fluorite−Water Interface Simon Schrödle and Geraldine L. Richmond pp 5072–5085 DOI: 10.1021/ja076664r

NMR-Based Analysis of Aminoglycoside Recognition by the Resistance Enzyme ANT(4′): The Pattern of OH/NH3+ Substitution Determines the Preferred Antibiotic Binding Mode and Is Critical for Drug Inactivation Julia Revuelta, Tatiana Vacas, Mario Torrado, Francisco Corzana, Carlos Gonzalez, Jesús Jiménez-Barbero, Margarita Menendez, Agatha Bastida and Juan Luis Asensio pp 5086–5103 DOI: 10.1021/ja076835s Supporting Info

Large Differences in Secondary Metal−Arene Interactions in the Transition-Metal Dimers ArMMAr (Ar = Terphenyl; M = Cr, Fe, or Co): Implications for Cr−Cr Quintuple Bonding Giovanni La Macchia, Laura Gagliardi, Philip P. Power and Marcin Brynda pp 5104–5114 DOI: 10.1021/ja0771890 Supporting Info

A Virtual Screen for Diverse Ligands: Discovery of Selective G Protein-Coupled Receptor Antagonists Stanislav Engel, Amanda P. Skoumbourdis, John Childress, Susanne Neumann, Jeffrey R. Deschamps, Craig J. Thomas, Anny-Odile Colson, Stefano Costanzi and Marvin C. Gershengorn pp 5115–5123 DOI: 10.1021/ja077620l Supporting Info

Electrostatic Control of Thickness and Stiffness in a Designed Protein Fiber David Papapostolou, Elizabeth H. C. Bromley, Christopher Bano and Derek N. Woolfson pp 5124–5130 DOI: 10.1021/ja0778444 Supporting Info

A Doorway State Leads to Photostability or Triplet Photodamage in Thymine DNA Wai-Ming Kwok, Chensheng Ma and David Lee Phillips pp 5131–5139 DOI: 10.1021/ja077831q Supporting Info

Modeling the Catalysis of Anti-Cocaine Catalytic Antibody: Competing Reaction Pathways and Free Energy Barriers Yongmei Pan, Daquan Gao and Chang-Guo Zhan pp 5140–5149 DOI: 10.1021/ja077972s Supporting Info

Effect of Water on the Catalytic Oxidation of Catechols Moses G. Gichinga and Susanne Striegler pp 5150–5156 DOI: 10.1021/ja078057+ Supporting Info

Effect of Structural Dynamics on Charge Transfer in DNA Hairpins Ferdinand C. Grozema, Stefano Tonzani, Yuri A. Berlin, George C. Schatz, Laurens D. A. Siebbeles and Mark A. Ratner pp 5157–5166 DOI: 10.1021/ja078162j Supporting Info

Probing the Electronic and Structural Properties of Chromium Oxide Clusters (CrO3)n− and (CrO3)n (n = 1–5): Photoelectron Spectroscopy and Density Functional Calculations Hua-Jin Zhai, Shenggang Li, David A. Dixon and Lai-Sheng Wang pp 5167–5177 DOI: 10.1021/ja077984d Supporting Info

Size-Induced Enhancement of Chemical Exchange Saturation Transfer (CEST) Contrast in Liposomes Jason M. Zhao, Yah-el Har-el, Michael T. McMahon, Jinyuan Zhou, A. Dean Sherry, George Sgouros, Jeff W. M. Bulte and Peter C. M. van Zijl pp 5178–5184 DOI: 10.1021/ja710159q Supporting Info

Mild Synthesis of a Family of Planar Triazinium Cations via Proton-Assisted Cyclization of Pyridyl Containing Azo Compounds and Studies on DNA Intercalation M. Sinan, M. Panda, A. Ghosh, K. Dhara, P. E. Fanwick, D. J. Chattopadhyay and S. Goswami pp 5185–5193 DOI: 10.1021/ja710211u Supporting Info

Perturbations to the Geometric and Electronic Structure of the CuA Site: Factors that Influence Delocalization and Their Contributions to Electron Transfer Xiangjin Xie, Serge I. Gorelsky, Ritimukta Sarangi, Dewain K. Garner, Hee Jung Hwang, Keith O. Hodgson, Britt Hedman, Yi Lu and Edward I. Solomon pp 5194–5205 DOI: 10.1021/ja7102668 Supporting Info

The Mechanism for the Rhodium-Catalyzed Decarbonylation of Aldehydes: A Combined Experimental and Theoretical Study Peter Fristrup, Michael Kreis, Anders Palmelund, Per-Ola Norrby and Robert Madsen pp 5206–5215 DOI: 10.1021/ja710270j Supporting Info

The Different Photoisomerization Efficiency of Azobenzene in the Lowest nπ* and ππ* Singlets: The Role of a Phantom State Irene Conti, Marco Garavelli and Giorgio Orlandi pp 5216–5230 DOI: 10.1021/ja710275e Supporting Info

Coherence Spectroscopy Investigations of the Low-Frequency Vibrations of Heme: Effects of Protein-Specific Perturbations Flaviu Gruia, Minoru Kubo, Xiong Ye, Dan Ionascu, Changyuan Lu, Robert K. Poole, Syun-Ru Yeh and Paul M. Champion pp 5231–5244 DOI: 10.1021/ja7104027

An Exploration of Mechanisms for the Transformation of 8-Oxoguanine to Guanidinohydantoin and Spiroiminodihydantoin by Density Functional Theory Barbara H. Munk, Cynthia J. Burrows and H. Bernhard Schlegel pp 5245–5256 DOI: 10.1021/ja7104448 Supporting Info

Transverse Pressure Induced Phase Transitions in Boron Nitride Nanotube Bundles and the Lightest Boron Nitride Crystal Shaogang Hao, Gang Zhou, Wenhui Duan, Jian Wu and Bing-Lin Gu pp 5257–5261 DOI: 10.1021/ja7107678 Supporting Info

Synthesis of Ordered Mesoporous NiO with Crystalline Walls and a Bimodal Pore Size Distribution Feng Jiao, Adrian H. Hill, Andrew Harrison, Aaron Berko, Alan V. Chadwick and Peter G. Bruce pp 5262–5266 DOI: 10.1021/ja710849r Supporting Info

AraC Regulatory Protein Mutants with Altered Effector Specificity Shuang-Yan Tang, Hossein Fazelinia and Patrick C. Cirino pp 5267–5271 DOI: 10.1021/ja7109053 Supporting Info

Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding Christopher R. Graves, Ping Yang, Stosh A. Kozimor, Anthony E. Vaughn, David L. Clark, Steven D. Conradson, Eric J. Schelter, Brian L. Scott, J. D. Thompson, P. Jeffrey Hay, David E. Morris and Jaqueline L. Kiplinger pp 5272–5285 DOI: 10.1021/ja711010h Supporting Info

Quantum Dot Nanobarcodes: Epitaxial Assembly of Nanoparticle−Polymer Complexes in Homogeneous Solution Jian Yang, Shivang R. Dave and Xiaohu Gao pp 5286–5292 DOI: 10.1021/ja710934v Supporting Info

Diiron Dithiolato Carbonyls Related to the HoxCO State of [FeFe]-Hydrogenase Aaron K. Justice, Mark J. Nilges, Thomas B. Rauchfuss, Scott R. Wilson, Luca De Gioia and Giuseppe Zampella pp 5293–5301 DOI: 10.1021/ja7113008 Supporting Info

Mechanism of Intramolecular Electron Transfer in the Photoexcited Zn-Substituted Cytochrome c: Theoretical and Experimental Perspective Yuichi Tokita, Jusuke Shimura, Hiroshi Nakajima, Yoshio Goto and Yoshihito Watanabe pp 5302–5310 DOI: 10.1021/ja711324t Supporting Info

Self-Assembly, Molecular Dynamics, and Kinetics of Structure Formation in Dipole-Functionalized Discotic Liquid Crystals Mahdy M. Elmahdy, Xi Dou, Mihail Mondeshki, George Floudas, Hans-Jürgen Butt, Hans W. Spiess and Klaus Müllen pp 5311–5319 DOI: 10.1021/ja7113618 Supporting Info

Coordination-Driven Self-Assembly of Cavity-Cored Multiple Crown Ether Derivatives and Poly[2]pseudorotaxanes Koushik Ghosh, Hai-Bo Yang, Brian H. Northrop, Matthew M. Lyndon, Yao-Rong Zheng, David C. Muddiman and Peter J. Stang pp 5320–5334 DOI: 10.1021/ja711502t Supporting Info

Tuning of the Size of Dy2O3 Nanoparticles for Optimal Performance as an MRI Contrast Agent Małgorzata Norek, Erik Kampert, Uli Zeitler and Joop A. Peters pp 5335–5340 DOI: 10.1021/ja711492y Supporting Info

On the Mechanism of Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by QUINOX, a Chiral Isoquinoline N-Oxide Andrei V. Malkov, Pedro Ramírez-López, Lada Biedermannová (née Bendová), Lubomír Rulíšek, Lenka Dufková, Martin Kotora, Fujiang Zhu and Pavel Koovský pp 5341–5348 DOI: 10.1021/ja711338q Supporting Info

Distinct and Long-Lived Activity States of Single Enzyme Molecules David M. Rissin, Hans H. Gorris and David R. Walt pp 5349–5353 DOI: 10.1021/ja711414f Supporting Info

Electrogenerated Chemiluminescence of a Spirobifluorene-Linked Bisanthracene: A Possible Simultaneous, Two-Electron Transfer Matthew M. Sartin, Chingfong Shu and Allen J. Bard pp 5354–5360 DOI: 10.1021/ja8000858 Supporting Info

α-CuV2O6 Nanowires: Hydrothermal Synthesis and Primary Lithium Battery Application Hua Ma, Shaoyan Zhang, Weiqiang Ji, Zhanliang Tao and Jun Chen pp 5361–5367 DOI: 10.1021/ja800109u Supporting Info

Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck−Iminium Ion Cyclization Amy B. Dounay, Philip G. Humphreys, Larry E. Overman and Aaron D. Wrobleski pp 5368–5377 DOI: 10.1021/ja800163v Supporting Info

Effect of the Heterointerface on Transport Properties of in Situ Formed MgO/Titanate Heterostructured Nanowires Kazuki Nagashima, Takeshi Yanagida, Hidekazu Tanaka, Shu Seki, Akinori Saeki, Seiichi Tagawa and Tomoji Kawai pp 5378–5382 DOI: 10.1021/ja800367a Supporting Info

Issue 16

De Novo Prediction of the Structures of M. tuberculosis Membrane Proteins Lintao Bu and Charles L. Brooks, pp 5384–5385 DOI: 10.1021/ja710213p Supporting Info

Activation in Prochiral Reaction Assemblies on Pt(111) Marc-Andr Lalibert, Stphane Lavoie, Bjørk Hammer, Gautier Mahieu and Peter H. McBreen pp 5386–5387 DOI: 10.1021/ja710297b

Formation of Trioctylamine from Octylamine On Au(111) Sigrid Weigelt, Joachim Schnadt, Anders K. Tuxen, Federico Masini, Christian Bombis, Carsten Busse, Cristina Isvoranu, Evren Ataman, Erik Lægsgaard, Flemming Besenbacher and Trolle R. Linderoth pp 5388–5389 DOI: 10.1021/ja710227g Supporting Info

Metal-Organic Framework as a Template for Porous Carbon Synthesis Bo Liu, Hiroshi Shioyama, Tomoki Akita and Qiang Xu pp 5390–5391 DOI: 10.1021/ja7106146 Supporting Info

Carbon Nanotube/Polythiophene Chemiresistive Sensors for Chemical Warfare Agents Fei Wang, Hongwei Gu and Timothy M. Swager pp 5392–5393 DOI: 10.1021/ja710795k Supporting Info

M35 Oxidation Induces Aβ40-like Structural and Dynamical Changes in Aβ42 Yilin Yan, Scott A. McCallum and Chunyu Wang pp 5394–5395 DOI: 10.1021/ja711189c Supporting Info

The Effect of a Trans-Locked Gly−Pro Alkene Isostere on Collagen Triple Helix Stability Nan Dai, Xiaodong J. Wang and Felicia A. Etzkorn pp 5396–5397 DOI: 10.1021/ja711021m Supporting Info

Exploiting the Nitrilotriacetic Acid Moiety for Biolabeling with Ultrastable Perylene Dyes Kalina Peneva, Gueorgui Mihov, Andreas Herrmann, Nawid Zarrabi, Michael Börsch, Thomas M. Duncan and Klaus Müllen pp 5398–5399 DOI: 10.1021/ja711322g Supporting Info

Increasing Complexity of a Diterpene Synthase Reaction with a Single Residue Switch Dana Morrone, Meimei Xu, D. Bruce Fulton, Mara K. Determan and Reuben J. Peters pp 5400–5401 DOI: 10.1021/ja710524w Supporting Info

The Important Role of Tetrahedral Ti4+ Sites in the Phase Transformation and Photocatalytic Activity of TiO2 Nanocomposites Gonghu Li, Nada M. Dimitrijevic, Le Chen, Jamie M. Nichols, Tijana Rajh and Kimberly A. Gray pp 5402–5403 DOI: 10.1021/ja711118u Supporting Info

Determination of Spin−Spin Couplings from Ultrahigh Resolution 3D NMR Spectra Obtained by Optimized Random Sampling and Multidimensional Fourier Transformation Krzysztof Kazimierczuk, Anna Zawadzka, Wiktor Komiski and Igor Zhukov pp 5404–5405 DOI: 10.1021/ja800622p Supporting Info

Localized Pd Overgrowth on Cubic Pt Nanocrystals for Enhanced Electrocatalytic Oxidation of Formic Acid Hyunjoo Lee, Susan E. Habas, Gabor A. Somorjai and Peidong Yang pp 5406–5407 DOI: 10.1021/ja800656y Supporting Info

Tandem Michael Addition/Ylide Epoxidation for the Synthesis of Highly Functionalized Cyclohexadiene Epoxide Derivatives Qing-Gang Wang, Xian-Ming Deng, Ben-Hu Zhu, Long-Wu Ye, Xiu-Li Sun, Chuan-Ying Li, Chun-Yin Zhu, Qi Shen and Yong Tang pp 5408–5409 DOI: 10.1021/ja800747m Supporting Info

Nickel-Catalyzed Addition of C−H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes Masamichi Shirakura and Michinori Suginome pp 5410–5411 DOI: 10.1021/ja800997j Supporting Info

Alumina-Supported SAPO-34 Membranes for CO2/CH4 Separation Moises A. Carreon, Shiguang Li, John L. Falconer and Richard D. Noble pp 5412–5413 DOI: 10.1021/ja801294f Supporting Info

Graphite Epoxide Jayanta Chattopadhyay, Arnab Mukherjee, Christopher E. Hamilton, JungHo Kang, Soma Chakraborty, Wenhua Guo, Kevin F. Kelly, Andrew R. Barron and W. Edward Billups pp 5414–5415 DOI: 10.1021/ja711063f Supporting Info

Disassembly of Noncovalent Amphiphilic Polymers with Proteins and Utility in Pattern Sensing Elamprakash N. Savariar, Suhrit Ghosh, Daniella C. Gonzlez and S. Thayumanavan pp 5416–5417 DOI: 10.1021/ja800164z Supporting Info

Ultrafast Carbene−Carbene Isomerization Jin Wang, Gotard Burdzinski, Jacek Kubicki, Terry L. Gustafson and Matthew S. Platz pp 5418–5419 DOI: 10.1021/ja8002827 Supporting Info

Synergy of Slow Photon and Chemically Amplified Photochemistry in Platinum Nanocluster-Loaded Inverse Titania Opals Jennifer I. L. Chen, Edward Loso, Naazia Ebrahim and Geoffrey A. Ozin pp 5420–5421 DOI: 10.1021/ja800288f Supporting Info

Discrimination of Nitroaromatics and Explosives Mimics by a Fluorescent Zn(salicylaldimine) Sensor Array Meaghan E. Germain and Michael J. Knapp pp 5422–5423 DOI: 10.1021/ja800403k Supporting Info

Highly Efficient Solar Cells Based on Poly(3-butylthiophene) Nanowires Hao Xin, Felix Sunjoo Kim and Samson A. Jenekhe pp 5424–5425 DOI: 10.1021/ja800411b Supporting Info

Pt Fibers with Stacked Donut-Like Mesospace by Assembling Pt Nanoparticles: Guided Deposition in Physically Confined Self-Assembly of Surfactants Yusuke Yamauchi, Azusa Takai, Tomota Nagaura, Satoru Inoue and Kazuyuki Kuroda pp 5426–5427 DOI: 10.1021/ja800269c Supporting Info

Growth of High-Density Parallel Arrays of Long Single-Walled Carbon Nanotubes on Quartz Substrates Lei Ding, Dongning Yuan and Jie Liu pp 5428–5429 DOI: 10.1021/ja8006947 Supporting Info

Thermodynamically Controlled Separation of Polyvalent 2-nm Gold Nanoparticle-Oligonucleotide Conjugates Jae-Seung Lee, Dwight S. Seferos, David A. Giljohann and Chad A. Mirkin pp 5430–5431 DOI: 10.1021/ja800797h Supporting Info

Anisotropic Assembly of Ag Nanoprisms Yeonjoo Bae, Nam Hoon Kim, Minjung Kim, Kang Yeol Lee and Sang Woo Han pp 5432–5433 DOI: 10.1021/ja800898v Supporting Info

Self-Immolative Polymers Amit Sagi, Roy Weinstain, Naama Karton and Doron Shabat pp 5434–5435 DOI: 10.1021/ja801065d Supporting Info

Solution−Liquid−Solid (SLS) Growth of Silicon Nanowires Andrew T. Heitsch, Dayne D. Fanfair, Hsing-Yu Tuan and Brian A. Korgel pp 5436–5437 DOI: 10.1021/ja8011353 Supporting Info

Shape-Specific, Monodisperse Nano-Molding of Protein Particles Jennifer Y. Kelly and Joseph M. DeSimone pp 5438–5439 DOI: 10.1021/ja8014428 Supporting Info

Mechanism of Growth of the Ge Wetting Layer Upon Exposure of Si(100)-2 × 1 to GeH4 Chie-Sheng Liu, Li-Wei Chou, Lu-Sheng Hong and Jyh-Chiang Jiang pp 5440–5442 DOI: 10.1021/ja710802s Supporting Info

Fluorescent Profiling of Modular Biosynthetic Enzymes by Complementary Metabolic and Activity Based Probes Jordan L. Meier, Andrew C. Mercer and Michael D. Burkart pp 5443–5445 DOI: 10.1021/ja711263w Supporting Info

New Chemistry with Old Functional Groups: On the Reaction of Isonitriles with Carboxylic Acids—A Route to Various Amide Types Xuechen Li and Samuel J. Danishefsky pp 5446–5448 DOI: 10.1021/ja800612r Supporting Info

A Group 13/Group 17 Analogue of CO and N2: Coordinative Trapping of the GaI Molecule Natalie D. Coombs, William Clegg, Amber L. Thompson, David J. Willock and Simon Aldridge pp 5449–5451 DOI: 10.1021/ja800876k Supporting Info

Electrocatalytic Performance of Fuel Oxidation by Pt3Ti Nanoparticles Hideki Abe, Futoshi Matsumoto, Laif R. Alden, Scott C. Warren, Héctor D. Abruña and Francis J. DiSalvo pp 5452–5458 DOI: 10.1021/ja075061c

Solid-State NMR Spectroscopy of Human Immunodeficiency Virus Fusion Peptides Associated with Host-Cell-Like Membranes: 2D Correlation Spectra and Distance Measurements Support a Fully Extended Conformation and Models for Specific Antiparallel Strand Registries Wei Qiang, Michele L. Bodner and David P. Weliky pp 5459–5471 DOI: 10.1021/ja077302m Supporting Info

Synthesis and Catalysis of Di- and Tetranuclear Metal Sandwich-Type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10− and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8− (M = Zr or Hf) Yuji Kikukawa, Syuhei Yamaguchi, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi and Noritaka Mizuno pp 5472–5478 DOI: 10.1021/ja078313i Supporting Info

The Mechanism of Ureido-Pyrimidinone:2,7-Diamido-Naphthyridine Complexation and the Presence of Kinetically Controlled Pathways in Multicomponent Hydrogen-Bonded Systems Tom F. A. de Greef, G. B. W. L. Ligthart, Martin Lutz, Anthony L. Spek, E. W. Meijer and Rint P. Sijbesma pp 5479–5486 DOI: 10.1021/ja709971y Supporting Info

Modification of Fluorophore Photophysics through Peptide-Driven Self-Assembly Kevin J. Channon, Glyn L. Devlin, Steven W. Magennis, Chris E. Finlayson, Anna K. Tickler, Carlos Silva and Cait E. MacPhee pp 5487–5491 DOI: 10.1021/ja710310c Supporting Info

Analysis of the Cryptophycin P450 Epoxidase Reveals Substrate Tolerance and Cooperativity Yousong Ding, Wolfgang H. Seufert, Zachary Q. Beck and David H. Sherman pp 5492–5498 DOI: 10.1021/ja710520q Supporting Info

Self-Assembled Monolayers of Electroactive Polychlorotriphenylmethyl Radicals on Au(111) Núria Crivillers, Marta Mas-Torrent, José Vidal-Gancedo, Jaume Veciana and Concepció Rovira pp 5499–5506 DOI: 10.1021/ja710845v Supporting Info

Adsorption and Reaction of 1-Epoxy-3-butene on Pt(111): Implications for Heterogeneous Catalysis of Unsaturated Oxygenates Andrea S. Loh, Scott W. Davis and J. Will Medlin pp 5507–5514 DOI: 10.1021/ja711013n Supporting Info

Molecule-Based Valence Tautomeric Bistability Synchronized with a Macroscopic Crystal-Melt Phase Transition Daisuke Kiriya, Ho-Chol Chang and Susumu Kitagawa pp 5515–5522 DOI: 10.1021/ja711268u Supporting Info

Surface-Enhanced Raman Spectroscopy of DNA Aoune Barhoumi, Dongmao Zhang, Felicia Tam and Naomi J. Halas pp 5523–5529 DOI: 10.1021/ja800023j Supporting Info

Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis of N-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl-, and Trifluoroalkyl-Substituted Ketoimines Peng Fu, Marc L. Snapper and Amir H. Hoveyda pp 5530–5541 DOI: 10.1021/ja8001343 Supporting Info

In the Pursuit for Better Actinide Ligands: An Efficient Strategy for their Discovery Henk H. Dam, Hans Beijleveld, David N. Reinhoudt and Willem Verboom pp 5542–5551 DOI: 10.1021/ja800222a Supporting Info

Metallicity in Individual MMX Chains Arrigo Calzolari, Simone S. Alexandre, Felix Zamora and Rosa Di Felice pp 5552–5562 DOI: 10.1021/ja800358c

Autoreduction of Pd−Co and Pt−Co Cyanogels: Exploration of Cyanometalate Coordination Chemistry at Elevated Temperatures Martina Vondrova, Tyrel M. McQueen, Christine M. Burgess, Douglas M. Ho and Andrew B. Bocarsly pp 5563–5572 DOI: 10.1021/ja8009764 Supporting Info

Ultracold Water Cluster Anions Fabio Zappa, Stephan Denifl, Ingo Mähr, Arntraud Bacher, Olof Echt, Tilmann D. Märk and Paul Scheier pp 5573–5578 DOI: 10.1021/ja075421w

Surface Reactivity of the Quinone/Hydroquinone Redox Center Tethered to Gold: Comparison of Delocalized and Saturated Bridges Scott A Trammell, Martin Moore, Daniel Lowy and Nikolai Lebedev pp 5579–5585 DOI: 10.1021/ja710246n Supporting Info

DFT Studies on the Mechanism of the Diboration of Aldehydes Catalyzed by Copper(I) Boryl Complexes Haitao Zhao, Li Dang, Todd B. Marder and Zhenyang Lin pp 5586–5594 DOI: 10.1021/ja710659y Supporting Info

Asymmetric Hydrogenation of Di and Trisubstituted Enol Phosphinates with N,P-Ligated Iridium Complexes Pradeep Cheruku, Jarle Diesen and Pher G. Andersson pp 5595–5599 DOI: 10.1021/ja711372c Supporting Info

Photochemical Oxidation of Halide Ions by a Nitratochromium(III) Complex. Kinetics, Mechanism, and Intermediates Mingming Cheng and Andreja Bakac pp 5600–5605 DOI: 10.1021/ja8000453

Sulfonic Acid-Functionalized Gold Nanoparticles: A Colloid-Bound Catalyst for Soft Lithographic Application on Self-Assembled Monolayers Xue-Mei Li, Vasile Paraschiv, Jurriaan Huskens and David N. Reinhoudt p 5606 DOI: 10.1021/ja801758r

Issue 17

Enantioselective Organocatalytic Michael Addition of Aldehydes to Nitroethylene: Efficient Access to γ2-Amino Acids Yonggui Chi, Li Guo, Nathan A. Kopf and Samuel H. Gellman pp 5608–5609 DOI: 10.1021/ja800345r Supporting Info

Peptide Catalyzed Asymmetric Conjugate Addition Reactions of Aldehydes to Nitroethylene—A Convenient Entry into γ2-Amino Acids Markus Wiesner, Jefferson D. Revell, Sandro Tonazzi and Helma Wennemers pp 5610–5611 DOI: 10.1021/ja801027s Supporting Info

Low Energy Electron Induced DNA Damage: Effects of Terminal Phosphate and Base Moieties on the Distribution of Damage Zejun Li, Yi Zheng, Pierre Cloutier, Lon Sanche and J. Richard Wagner pp 5612–5613 DOI: 10.1021/ja077601b Supporting Info

Studies on A New Biosynthetic Pathway for Menaquinone Haruo Seto, Yuusuke Jinnai, Tomoshige Hiratsuka, Miwako Fukawa, Kazuo Furihata, Nobuya Itoh and Tohru Dairi pp 5614–5615 DOI: 10.1021/ja710207s Supporting Info

Fabrication of Heterogeneous Binary Arrays of Nanoparticles via Colloidal Lithography Gang Zhang and Dayang Wang pp 5616–5617 DOI: 10.1021/ja710771j Supporting Info

Toward the Characterization of Peptidoglycan Structure and Protein−Peptidoglycan Interactions by Solid-State NMR Spectroscopy Thomas Kern, Sabine Hediger, Patrick Mller, Ccile Giustini, Bernard Joris, Catherine Bougault, Waldemar Vollmer and Jean-Pierre Simorre pp 5618–5619 DOI: 10.1021/ja7108135 Supporting Info

Synthesis of Cu−In−S Ternary Nanocrystals with Tunable Structure and Composition Daocheng Pan, Lijia An, Zhongming Sun, William Hou, Yang Yang, Zhengzhong Yang and Yunfeng Lu pp 5620–5621 DOI: 10.1021/ja711027j Supporting Info

Lipid-Packaged Linear Iron(II) Triazole Complexes in Solution: Controlled Spin Conversion via Solvophobic Self-Assembly Hiroyuki Matsukizono, Keita Kuroiwa and Nobuo Kimizuka pp 5622–5623 DOI: 10.1021/ja711355j Supporting Info

Selective Linear Triene Formation from Different Alkynes using Zr/Cu system Ken-ichiro Kanno, Eri Igarashi, Lishan Zhou, Kiyohiko Nakajima and Tamotsu Takahashi pp 5624–5625 DOI: 10.1021/ja8000387 Supporting Info

A Polymeric Domain That Promotes Cellular Internalization Erin M. Kolonko and Laura L. Kiessling pp 5626–5627 DOI: 10.1021/ja8001716 Supporting Info

Omni-Composites: A New Strategy for Forming Bulk Nanostructured Materials Jeffrey R. DiMaio, Baris Kokuoz and John Ballato pp 5628–5629 DOI: 10.1021/ja800093p

Asymmetric Catalysis via Dynamic Substrate/Ligand/Rare Earth Metal Conglomerate Akihiro Nojiri, Naoya Kumagai and Masakatsu Shibasaki pp 5630–5631 DOI: 10.1021/ja800326d Supporting Info

Photoinduced Ultrafast Electron Transfer from CdSe Quantum Dots to Re-bipyridyl Complexes Jier Huang, Dave Stockwell, Zhuangqun Huang, Debra L. Mohler and Tianquan Lian pp 5632–5633 DOI: 10.1021/ja8003683 Supporting Info

Enthalpy versus Entropy in Chlorocarbene/Alkene Addition Reactions Robert A. Moss, Lei Wang, Min Zhang, Christopher Skalit and Karsten Krogh-Jespersen pp 5634–5635 DOI: 10.1021/ja8005226 Supporting Info

Exclusive 5-exo-dig Hydroarylation of o-Alkynyl Biaryls Proceeding via C−H Activation Pathway Natalia Chernyak and Vladimir Gevorgyan pp 5636–5637 DOI: 10.1021/ja8006534 Supporting Info

Zigzag Boron−Carbon Nanotubes with Quasi-planar Tetracoordinate Carbons Congjie Zhang, Wenxiu Sun and Zexing Cao pp 5638–5639 DOI: 10.1021/ja800540x Supporting Info

Rational Design and Gas-Phase Characterization of Molecular Capsules by Self-Assembly of a Symmetric Hexasubstituted Benzene with Seven-Membered Lactams Pierre Baillargeon and Yves L. Dory pp 5640–5641 DOI: 10.1021/ja800734b Supporting Info

Upconversion Multicolor Fine-Tuning: Visible to Near-Infrared Emission from Lanthanide-Doped NaYF4 Nanoparticles Feng Wang and Xiaogang Liu pp 5642–5643 DOI: 10.1021/ja800868a Supporting Info

Suggestion of an Organometallic Intermediate in an Intramolecular Dechlorination Reaction Involving Copper(I) and a ArCH2Cl Moiety Debabrata Maiti, Amy A. Narducci Sarjeant, Shinobu Itoh and Kenneth D. Karlin pp 5644–5645 DOI: 10.1021/ja800795b Supporting Info

Ni(II)-Mediated Self-Assembly of Artificial β-Dipeptides Forming a Macrocyclic Tetranuclear Complex with Interior Spaces for In-Line Molecular Arrangement Ryosuke Miyake, Shohei Tashiro, Motoo Shiro, Kentaro Tanaka and Mitsuhiko Shionoya pp 5646–5647 DOI: 10.1021/ja8009555 Supporting Info

Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene Alexander V. Zabula, Tania Pape, Alexander Hepp, Falko M. Schappacher, Ute Ch. Rodewald, Rainer Pttgen and F. Ekkehardt Hahn pp 5648–5649 DOI: 10.1021/ja801000b Supporting Info

Necklace-Like Cu@Cross-Linked Poly(vinyl alcohol) Core−Shell Microcables by Hydrothermal Process Yong-Jie Zhan and Shu-Hong Yu pp 5650–5651 DOI: 10.1021/ja8010397 Supporting Info

Asymmetric Organocatalytic Three-Component 1,3-Dipolar Cycloaddition: Control of Stereochemistry via a Chiral Brønsted Acid Activated Dipole Xiao-Hua Chen, Wen-Quan Zhang and Liu-Zhu Gong pp 5652–5653 DOI: 10.1021/ja801034e Supporting Info

Asymmetric Direct Aldol Reaction of Functionalized Ketones Catalyzed by Amine Organocatalysts Based on Bispidine Jie Liu, Zhigang Yang, Zhen Wang, Fei Wang, Xiaohong Chen, Xiaohua Liu, Xiaoming Feng, Zhishan Su and Changwei Hu pp 5654–5655 DOI: 10.1021/ja800839w Supporting Info

Boronic Acid Converters for Reactive Hydrazide Amplifiers: Polyphenol Sensing in Green Tea with Synthetic Pores Shinya Hagihara, Hiroyuki Tanaka and Stefan Matile pp 5656–5657 DOI: 10.1021/ja801094p Supporting Info

Organocatalysis In a Synthetic Receptor with an Inwardly Directed Carboxylic Acid Siddhartha R. Shenoy, Fernando R. Pinacho Crisstomo, Tetsuo Iwasawa and Julius Rebek, pp 5658–5659 DOI: 10.1021/ja801107r Supporting Info

Cooperative, Highly Enantioselective Phosphinothiourea Catalysis of Imine−Allene [3 + 2] Cycloadditions Yuan-Qing Fang and Eric N. Jacobsen pp 5660–5661 DOI: 10.1021/ja801344w Supporting Info

Pyridine Ring Opening at Room Temperature at a Rhenium Tricarbonyl Bipyridine Complex Miguel A. Huertos, Julio Prez and Luca Riera pp 5662–5663 DOI: 10.1021/ja801655d Supporting Info

Mapping the Binding Site of Thiopeptide Antibiotics by Proximity-Induced Covalent Capture Sascha Baumann, Sebastian Schoof, Surendra D. Harkal and Hans-Dieter Arndt pp 5664–5666 DOI: 10.1021/ja710608w Supporting Info

Analysis of Protein Kinase Autophosphorylation Using Expressed Protein Ligation and Computational Modeling Kerry A. Pickin, Sidhartha Chaudhury, Blair C. R. Dancy, Jeffrey J. Gray and Philip A. Cole pp 5667–5669 DOI: 10.1021/ja711244h Supporting Info

Synthesis and AFM Structural Imaging of Dendrimer-Like Star-Branched Polystyrenes Alain Deffieux, Michel Schappacher, Akira Hirao and Takumi Watanabe pp 5670–5672 DOI: 10.1021/ja800881k Supporting Info

Extended X-ray Absorption Fine Structure and Nuclear Resonance Vibrational Spectroscopy Reveal that NifB-co, a FeMo-co Precursor, Comprises a 6Fe Core with an Interstitial Light Atom Simon J. George, Robert Y. Igarashi, Yuming Xiao, Jose A. Hernandez, Marie Demuez, Dehua Zhao, Yoshitaka Yoda, Paul W. Ludden, Luis M. Rubio and Stephen P. Cramer pp 5673–5680 DOI: 10.1021/ja0755358 Supporting Info

Rerouting the Folding Pathway of the Notch Ankyrin Domain by Reshaping the Energy Landscape Katherine W. Tripp and Doug Barrick pp 5681–5688 DOI: 10.1021/ja0763201

Identification of Acidic Phosphorus-Containing Ligands Involved in the Surface Chemistry of CdSe Nanoparticles Prepared in Tri-N-octylphosphine Oxide Solvents Jordan T. Kopping and Timothy E. Patten pp 5689–5698 DOI: 10.1021/ja077414d Supporting Info

Origin of the Dendritic Effect in Multivalent Enzyme-Like Catalysts Giovanni Zaupa, Paolo Scrimin and Leonard J. Prins pp 5699–5709 DOI: 10.1021/ja7113213 Supporting Info

Remarkable Magneto-Optical Properties of Europium Selenide Nanoparticles with Wide Energy Gaps Yasuchika Hasegawa, Taka-aki Adachi, Atsushi Tanaka, Mohammad Afzaal, Paul O’Brien, Takahiro Doi, Yukio Hinatsu, Koji Fujita, Katsuhisa Tanaka and Tsuyoshi Kawai pp 5710–5715 DOI: 10.1021/ja710165m Supporting Info

Toward Three-Dimensional Nanoengineering of Heterogeneous Catalysts Ilke Arslan, John C. Walmsley, Erling Rytter, Edvard Bergene and Paul A. Midgley pp 5716–5719 DOI: 10.1021/ja710299h Supporting Info

Quantum Dot FRET Biosensors that Respond to pH, to Proteolytic or Nucleolytic Cleavage, to DNA Synthesis, or to a Multiplexing Combination Miho Suzuki, Yuzuru Husimi, Hirokazu Komatsu, Koji Suzuki and Kenneth T. Douglas pp 5720–5725 DOI: 10.1021/ja710870e

Ligand Bonding and Dynamics on Colloidal Nanocrystals at Room Temperature: The Case of Alkylamines on CdSe Nanocrystals Xiaohui Ji, Danis Copenhaver, Christopher Sichmeller and Xiaogang Peng pp 5726–5735 DOI: 10.1021/ja710909f Supporting Info

STM Studies of Fusion of Cholesterol Suspensions and Mixed 1,2-Dimyristoyl-sn-glycero-3-phosphocholine (DMPC)/Cholesterol Vesicles onto a Au(111) Electrode Surface Slawomir Sek, Shimin Xu, Maohui Chen, Grzegorz Szymanski and Jacek Lipkowski pp 5736–5743 DOI: 10.1021/ja711020q Supporting Info

A Peptoid “Antibody Surrogate” That Antagonizes VEGF Receptor 2 Activity D. Gomika Udugamasooriya, Sean P. Dineen, Rolf A. Brekken and Thomas Kodadek pp 5744–5752 DOI: 10.1021/ja711193x Supporting Info

Reaction of Molecular Oxygen with a PdII-Hydride To Produce a PdII-Hydroperoxide: Experimental Evidence for an HX-Reductive-Elimination Pathway Michael M. Konnick and Shannon S. Stahl pp 5753–5762 DOI: 10.1021/ja7112504 Supporting Info

Morphology of Large ZSM-5 Crystals Unraveled by Fluorescence Microscopy Maarten B. J. Roeffaers, Rob Ameloot, Mukulesh Baruah, Hiroshi Uji-i, Metin Bulut, Gert De Cremer, Ulrich Müller, Pierre A. Jacobs, Johan Hofkens, Bert F. Sels and Dirk E. De Vos pp 5763–5772 DOI: 10.1021/ja7113147

Long-Range Influence of Carbohydrates on the Solvation Dynamics of WaterAnswers from Terahertz Absorption Measurements and Molecular Modeling Simulations M. Heyden, E. Bründermann, U. Heugen, G. Niehues, D. M. Leitner and M. Havenith pp 5773–5779 DOI: 10.1021/ja0781083

Folding Induced Assembly of Polypeptide Decorated Gold Nanoparticles Daniel Aili, Karin Enander, Johan Rydberg, Irina Nesterenko, Fredrik Björefors, Lars Baltzer and Bo Liedberg pp 5780–5788 DOI: 10.1021/ja711330f Supporting Info

Transition-State Analysis of the DNA Repair Enzyme MutY Joe A. B. McCann and Paul J. Berti pp 5789–5797 DOI: 10.1021/ja711363s Supporting Info

Magic Angle Spinning NMR Experiments for Structural Studies of Differentially Enriched Protein Interfaces and Protein Assemblies Jun Yang, Maria Luisa Tasayco and Tatyana Polenova pp 5798–5807 DOI: 10.1021/ja711304e Supporting Info

One-Step versus Stepwise Mechanism in Protonated Amino Acid-Promoted Electron-Transfer Reduction of a Quinone by Electron Donors and Two-Electron Reduction by a Dihydronicotinamide Adenine Dinucleotide Analogue. Interplay between Electron Transfer and Hydrogen Bonding Junpei Yuasa, Shunsuke Yamada and Shunichi Fukuzumi pp 5808–5820 DOI: 10.1021/ja8001452 Supporting Info

The Mechanism of the Rhodium(I)-Catalyzed [2 + 2 + 1] Carbocyclization Reaction of Dienes and CO: A Computational Study William H. Pitcock Jr., Richard L. Lord and Mu-Hyun Baik pp 5821–5830 DOI: 10.1021/ja800856p Supporting Info

Issue 18

Engineering Stacks of Aromatic Rings by the Interpenetration of Self-Assembled Coordination Cages Yoshihiro Yamauchi, Michito Yoshizawa and Makoto Fujita pp 5832–5833 DOI: 10.1021/ja077783+ Supporting Info

Capturing Transient Structures in the Elimination Reaction of Haloalkane in Solution by Transient X-ray Diffraction Jae Hyuk Lee, Tae Kyu Kim, Joonghan Kim, Qingyu Kong, Marco Cammarata, Maciej Lorenc, Michael Wulff and Hyotcherl Ihee pp 5834–5835 DOI: 10.1021/ja710267u

A Calcium-Modulated Plasmonic Switch W. Paige Hall, Jeffrey N. Anker, Yao Lin, Justin Modica, Milan Mrksich and Richard P. Van Duyne pp 5836–5837 DOI: 10.1021/ja7109037 Supporting Info

Isolation and Characterization of a Neutral Imino-semiquinone Radical Shawn M. Carter, Allyson Sia, Michael J. Shaw and Alan F. Heyduk pp 5838–5839 DOI: 10.1021/ja711185s Supporting Info

A New Method for N−N Bond Cleavage of N,N-Disubstituted Hydrazines to Secondary Amines and Direct Ortho Amination of Naphthol and Its Analogues Qiang Tang, Chao Zhang and Meiming Luo pp 5840–5841 DOI: 10.1021/ja711153b Supporting Info

Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br) Fabiola Barrios-Landeros, Brad P. Carrow and John F. Hartwig pp 5842–5843 DOI: 10.1021/ja711159y Supporting Info

Deprotonation Induced Ligand-to-Metal Electron Transfer: Synthesis of a Mixed-Valence Rh(−I,I) Dinuclear Compound and Its Reaction with Dioxygen Cristina Tejel, Miguel A. Ciriano, M. Pilar del Ro, Fieke J. van den Bruele, Dennis G. H. Hetterscheid, Nearchos Tsichlis i Spithas and Bas de Bruin pp 5844–5845 DOI: 10.1021/ja711495v Supporting Info

Synthesis of Two Mirror Image 4-Helix Junctions Derived from Glycerol Nucleic Acid Richard S. Zhang, Elizabeth O. McCullum and John C. Chaput pp 5846–5847 DOI: 10.1021/ja800079j Supporting Info

Metal−Carbon Nanotube Contacts: The Link between Schottky Barrier and Chemical Bonding Vincenzo Vitale, Alessandro Curioni and Wanda Andreoni pp 5848–5849 DOI: 10.1021/ja8002843 Supporting Info

The Role of Surface Basal Planes of Layered Mixed Metal Oxides in Selective Transformation of Lower Alkanes: Propane Ammoxidation over Surface ab Planes of Mo−V−Te−Nb−O M1 Phase N. Raveendran Shiju, Xinhua Liang, Alan W. Weimer, Chengdu Liang, Sheng Dai and Vadim V. Guliants pp 5850–5851 DOI: 10.1021/ja800575v Supporting Info

Genetic Engineering Combined with Deep UV Resonance Raman Spectroscopy for Structural Characterization of Amyloid-like Fibrils Vitali Sikirzhytski, Natalya I. Topilina, Seiichiro Higashiya, John T. Welch and Igor K. Lednev pp 5852–5853 DOI: 10.1021/ja8006275 Supporting Info

Size-Selective Lewis Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites Satoshi Horike, Mircea Dinc, Kentaro Tamaki and Jeffrey R. Long pp 5854–5855 DOI: 10.1021/ja800669j Supporting Info

Flexible Graphene Films via the Filtration of Water-Soluble Noncovalent Functionalized Graphene Sheets Yuxi Xu, Hua Bai, Gewu Lu, Chun Li and Gaoquan Shi pp 5856–5857 DOI: 10.1021/ja800745y Supporting Info

Iron-Catalyzed Direct Arylation through Directed C−H Bond Activation Jakob Norinder, Arimasa Matsumoto, Naohiko Yoshikai and Eiichi Nakamura pp 5858–5859 DOI: 10.1021/ja800818b Supporting Info

Synthesis and Structure Verification of the Vaccine Adjuvant QS-7-Api. Synthetic Access to Homogeneous Quillaja saponaria Immunostimulants Kai Deng, Michelle M. Adams and David Y. Gin pp 5860–5861 DOI: 10.1021/ja801008m Supporting Info

Synthesis of Large Quantities of Single-Walled Aluminogermanate Nanotube Clment Levard, Jrme Rose, Armand Masion, Emmanuel Doelsch, Daniel Borschneck, Luca Olivi, Christian Dominici, Olivier Grauby, Joseph C. Woicik and Jean-Yves Bottero pp 5862–5863 DOI: 10.1021/ja801045a Supporting Info

Tertiary Aromatic Amide for Memory of Chirality: Access to Enantioenriched α-Substituted Valine Mathieu Branca, Didier Gori, Rgis Guillot, Valrie Alezra and Cyrille Kouklovsky pp 5864–5865 DOI: 10.1021/ja801165z Supporting Info

A Diastereo- and Enantioselective Synthesis of α-Substituted syn-α,β-Diamino Acids Anand Singh and Jeffrey N. Johnston pp 5866–5867 DOI: 10.1021/ja8011808 Supporting Info

Highly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes Yawen Zhang, Michael E. Grass, John N. Kuhn, Feng Tao, Susan E. Habas, Wenyu Huang, Peidong Yang and Gabor A. Somorjai pp 5868–5869 DOI: 10.1021/ja801210s Supporting Info

2-Fluoro-ATP as a Versatile Tool for 19F NMR-Based Activity Screening Brian J. Stockman pp 5870–5871 DOI: 10.1021/ja801588u Supporting Info

Total Synthesis of Lobatoside E, A Potent Antitumor Cyclic Triterpene Saponin Chunsheng Zhu, Pingping Tang and Biao Yu pp 5872–5873 DOI: 10.1021/ja801669r Supporting Info

Oxygen-Atom Transfer from Carbon Dioxide to a Fischer Carbene at (PNP)Ir Matthew T. Whited and Robert H. Grubbs pp 5874–5875 DOI: 10.1021/ja801865c Supporting Info

Janus Micelles Induced by Olefin Metathesis Frederik Wurm, Hannah M. Knig, Stefan Hilf and Andreas F. M. Kilbinger pp 5876–5877 DOI: 10.1021/ja801919y Supporting Info

Asymmetric Droplet Interface Bilayers William L. Hwang, Min Chen, Brd Cronin, Matthew A. Holden and Hagan Bayley pp 5878–5879 DOI: 10.1021/ja802089s Supporting Info

Mapping the Evolution of Adsorption of Water in Nanoporous Silica by in situ Solid-State 1H NMR Spectroscopy Mingcan Xu, Kenneth D. M. Harris and John Meurig Thomas pp 5880–5882 DOI: 10.1021/ja8007243

Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties Manzhou Zhu, Christine M. Aikens, Frederick J. Hollander, George C. Schatz and Rongchao Jin pp 5883–5885 DOI: 10.1021/ja801173r Supporting Info

Dynamics of Silica-Supported Catalysts Determined by Combining Solid-State NMR Spectroscopy and DFT Calculations Frédéric Blanc, Jean-Marie Basset, Christophe Copéret, Amritanshu Sinha, Zachary J. Tonzetich, Richard R. Schrock, Xavier Solans-Monfort, Eric Clot, Odile Eisenstein, Anne Lesage and Lyndon Emsley pp 5886–5900 DOI: 10.1021/ja077749v Supporting Info

Spectral Signatures and Molecular Origin of Acid Dissociation Intermediates Radu Iftimie, Vibin Thomas, Sylvain Plessis, Patrick Marchand and Patrick Ayotte pp 5901–5907 DOI: 10.1021/ja077846o

Gadolinium Chelate Coated Gold Nanoparticles As Contrast Agents for Both X-ray Computed Tomography and Magnetic Resonance Imaging Christophe Alric, Jacqueline Taleb, Géraldine Le Duc, Céline Mandon, Claire Billotey, Alice Le Meur-Herland, Thierry Brochard, Francis Vocanson, Marc Janier, Pascal Perriat, Stéphane Roux and Olivier Tillement pp 5908–5915 DOI: 10.1021/ja078176p Supporting Info

Tailoring the Key in a Molecular Lock-and-Key Model System: The Propylene Oxide···2-Fluoroethanol Complex Nicole Borho and Yunjie Xu pp 5916–5921 DOI: 10.1021/ja0783411 Supporting Info

Characterization of Alzheimer’s-like Paired Helical Filaments from the Core Domain of Tau Protein Using Solid-State NMR Spectroscopy Ovidiu C. Andronesi, Martin von Bergen, Jacek Biernat, Karsten Seidel, Christian Griesinger, Eckhard Mandelkow and Marc Baldus pp 5922–5928 DOI: 10.1021/ja7100517 Supporting Info

Self-Assembled Zinc Chlorin Rod Antennae Powered by Peripheral Light-Harvesting Chromophores Cornelia Röger, Yuliya Miloslavina, Doris Brunner, Alfred R. Holzwarth and Frank Würthner pp 5929–5939 DOI: 10.1021/ja710253q Supporting Info

Nanoparticle MALDI-TOF Mass Spectrometry without Fragmentation: Au25(SCH2CH2Ph)18 and Mixed Monolayer Au25(SCH2CH2Ph)18−x(L)x Amala Dass, Anthony Stevenson, George R. Dubay, Joseph B. Tracy and Royce W. Murray pp 5940–5946 DOI: 10.1021/ja710323t Supporting Info

Noncovalent Cell Surface Engineering: Incorporation of Bioactive Synthetic Glycopolymers into Cellular Membranes David Rabuka, Martin B. Forstner, Jay T. Groves and Carolyn R. Bertozzi pp 5947–5953 DOI: 10.1021/ja710644g Supporting Info

Colloidal GaAs Quantum Wires: Solution−Liquid−Solid Synthesis and Quantum-Confinement Studies Angang Dong, Heng Yu, Fudong Wang and William E. Buhro pp 5954–5961 DOI: 10.1021/ja711408t Supporting Info

Atom-Based Thermochemistry: Crystal Atomization and Sublimation Enthalpies in Linear Relationships to Molecular Atomization Enthalpy László von Szentpály pp 5962–5973 DOI: 10.1021/ja710852w

Structural, Optical, and Electrical Properties of PbSe Nanocrystal Solids Treated Thermally or with Simple Amines Matt Law, Joseph M. Luther, Qing Song, Barbara K. Hughes, Craig L. Perkins and Arthur J. Nozik pp 5974–5985 DOI: 10.1021/ja800040c Supporting Info

The Bip Method, Based on the Induced Circular Dichroism of a Flexible Biphenyl Probe in Terminally Protected -Bip-Xaa*- Dipeptides, for Assignment of the Absolute Configuration of β-Amino Acids Laurence Dutot, Karen Wright, Anne Gaucher, Michel Wakselman, Jean-Paul Mazaleyrat, Marta De Zotti, Cristina Peggion, Fernando Formaggio and Claudio Toniolo pp 5986–5992 DOI: 10.1021/ja800059d Supporting Info

Interactions of the Hormone Oxytocin with Divalent Metal Ions Thomas Wyttenbach, Dengfeng Liu and Michael T. Bowers pp 5993–6000 DOI: 10.1021/ja8002342 Supporting Info

PEG-Detachable Polyplex Micelles Based on Disulfide-Linked Block Catiomers as Bioresponsive Nonviral Gene Vectors Seiji Takae, Kanjiro Miyata, Makoto Oba, Takehiko Ishii, Nobuhiro Nishiyama, Keiji Itaka, Yuichi Yamasaki, Hiroyuki Koyama and Kazunori Kataoka pp 6001–6009 DOI: 10.1021/ja800336v Supporting Info

Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework Jie-Peng Zhang and Xiao-Ming Chen pp 6010–6017 DOI: 10.1021/ja800550a Supporting Info

Syntheses of the Stemona Alkaloids (±)-Stenine, (±)-Neostenine, and (±)-13-Epineostenine Using a Stereodivergent Diels–Alder/Azido-Schmidt Reaction Kevin J. Frankowski, Jennifer E. Golden, Yibin Zeng, Yao Lei and Jeffrey Aubé pp 6018–6024 DOI: 10.1021/ja800574m Supporting Info

EP-2104R: A Fibrin-Specific Gadolinium-Based MRI Contrast Agent for Detection of Thrombus Kirsten Overoye-Chan, Steffi Koerner, Richard J. Looby, Andrew F. Kolodziej, Stephan G. Zech, Qing Deng, Jaclyn M. Chasse, Thomas J. McMurry and Peter Caravan pp 6025–6039 DOI: 10.1021/ja800834y Supporting Info

Optofluidic Encapsulation of Crystalline Colloidal Arrays into Spherical Membrane Shin-Hyun Kim, Seog-Jin Jeon and Seung-Man Yang pp 6040–6046 DOI: 10.1021/ja800844w Supporting Info

Indenyl Zirconium Dinitrogen Chemistry: N2 Coordination to an Isolated Zirconium Sandwich and Synthesis of Side-on, End-on Dinitrogen Compounds Doris Pun, Emil Lobkovsky and Paul J. Chirik pp 6047–6054 DOI: 10.1021/ja801021w Supporting Info

Identification of a Rearranged-Substrate, Product Radical Intermediate and the Contribution of a Product Radical Trap in Vitamin B12 Coenzyme-Dependent Ethanolamine Deaminase Catalysis Kurt Warncke, Jennifer C. Schmidt and Shyue-Chu Ke p 6055 DOI: 10.1021/ja801780x Supporting Info

Maturation of an Escherichia coli Ribosomal Peptide Antibiotic by ATP-Consuming N−P Bond Formation in Microcin C7 Rebecca F. Roush, Elizabeth M. Nolan, Frank Lhr and Christopher T. Walsh p 6055 DOI: 10.1021/ja802086j

Software Review of Prism 5 Dean R. Appling p 6056 DOI: 10.1021/ja801998j

Issue 19

Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes Yuichi Kajita, Seijiro Matsubara, Takuya Kurahashi pp 6058–6059 DOI: 10.1021/ja7114426 Supporting Info

Reactivity of the Triple Ion and Separated Ion Pair of Tris(trimethylsilyl)methyllithium with Aldehydes: A RINMR Study Amanda C. Jones, Aaron W. Sanders, William H. Sikorski, Kristin L. Jansen, Hans J. Reich pp 6060–6061 DOI: 10.1021/ja8003528 Supporting Info

Azafullerenes Encapsulated within Single-Walled Carbon Nanotubes Georgia Pagona, Georgios Rotas, Andrei N. Khlobystov, Thomas W. Chamberlain, Kyriakos Porfyrakis, Nikos Tagmatarchis pp 6062–6063 DOI: 10.1021/ja800760w Supporting Info

Ambipolar, High Performance, Acene-Based Organic Thin Film Transistors Ming L. Tang, Anna D. Reichardt, Nobuyuki Miyaki, Randall M. Stoltenberg, Zhenan Bao pp 6064–6065 DOI: 10.1021/ja8005918 Supporting Info

New Methods Enabling Efficient Incorporation of Unnatural Amino Acids in Yeast Qian Wang, Lei Wang pp 6066–6067 DOI: 10.1021/ja800894n Supporting Info

Identifying the Minimal Enzymes Required for Anhydrotetracycline Biosynthesis Wenjun Zhang, Kenji Watanabe, Xiaolu Cai, Michael E. Jung, Yi Tang, Jixun Zhan pp 6068–6069 DOI: 10.1021/ja800951e Supporting Info

Catalytic Asymmetric Epoxidation of Cyclic Enones Xingwang Wang, Corinna M. Reisinger, Benjamin List pp 6070–6071 DOI: 10.1021/ja801181u Supporting Info

A Catalytic Enantioselective Conjugate Addition of Cyanide to Enones Yuta Tanaka, Motomu Kanai, Masakatsu Shibasaki pp 6072–6073 DOI: 10.1021/ja801201r Supporting Info

A Bridging Hexazene (RNNNNNNR) Ligand from Reductive Coupling of Azides Ryan E. Cowley, Jrme Elhak, Nathan A. Eckert, William W. Brennessel, Eckhard Bill, Patrick L. Holland pp 6074–6075 DOI: 10.1021/ja801375g Supporting Info

Marangoni Flow-Induced Self-Assembly of Hexagonal and Stripelike Nanoparticle Patterns Yangjun Cai, Bi-min Zhang Newby pp 6076–6077 DOI: 10.1021/ja801438u Supporting Info

The Isolable Cation Radical of Disilene: Synthesis, Characterization, and a Reversible One-Electron Redox System Shigeyoshi Inoue, Masaaki Ichinohe, Akira Sekiguchi pp 6078–6079 DOI: 10.1021/ja801761w Supporting Info

Hydrogen Bonding Contributes to the Selectivity of Nucleotide Incorporation Opposite an Oxidized Abasic Lesion Haidong Huang, Marc M. Greenberg pp 6080–6081 DOI: 10.1021/ja801715c Supporting Info

Metal-Mediated Self-Assembly of Protein Superstructures: Influence of Secondary Interactions on Protein Oligomerization and Aggregation Eric N. Salgado, Richard A. Lewis, Jasmin Faraone-Mennella, F. Akif Tezcan pp 6082–6084 DOI: 10.1021/ja8012177 Supporting Info

Direct Measurement of Tertiary Contact Cooperativity in RNA Folding Bernie D. Sattin, Wei Zhao, Kevin Travers, Steven Chu and Daniel Herschlag pp 6085–6087 DOI: 10.1021/ja800919q Supporting Info

Effect of a Tridentate Ligand on the Structure, Electronic Structure, and Reactivity of the Copper(I) Nitrite Complex: Role of the Conserved Three-Histidine Ligand Environment of the Type-2 Copper Site in Copper-Containing Nitrite Reductases Masato Kujime, Chiemi Izumi, Masaaki Tomura, Masahiko Hada, Hiroshi Fujii pp 6088–6098 DOI: 10.1021/ja075575b Supporting Info

HIV-1 Protease Inhibitors from Inverse Design in the Substrate Envelope Exhibit Subnanomolar Binding to Drug-Resistant Variants Michael D. Altman, Akbar Ali, G. S. Kiran Kumar Reddy, Madhavi N. L. Nalam, Saima Ghafoor Anjum, Hong Cao, Sripriya Chellappan, Visvaldas Kairys, Miguel X. Fernandes, Michael K. Gilson, Celia A. Schiffer, Tariq M. Rana, Bruce Tidor pp 6099–6113 DOI: 10.1021/ja076558p Supporting Info

A Small Neutral Molecule with Two Noble-Gas Atoms: HXeOXeH Leonid Khriachtchev, Karoliina Isokoski, Arik Cohen, Markku Räsänen, R. Benny Gerber pp 6114–6118 DOI: 10.1021/ja077835v Supporting Info

Ruthenium Nanoparticles inside Porous [Zn4O(bdc)3] by Hydrogenolysis of Adsorbed [Ru(cod)(cot)]: A Solid-State Reference System for Surfactant-Stabilized Ruthenium Colloids Felicitas Schröder, Daniel Esken, Mirza Cokoja, Maurits W. E. van den Berg, Oleg I. Lebedev, Gustaaf Van Tendeloo, Bernadeta Walaszek, Gerd Buntkowsky, Hans-Heinrich Limbach, Bruno Chaudret, Roland A. Fischer pp 6119–6130 DOI: 10.1021/ja078231u Supporting Info

Ribosomal Synthesis of N-Methyl Peptides Alexander O. Subtelny, Matthew C. T. Hartman, Jack W. Szostak pp 6131–6136 DOI: 10.1021/ja710016v Supporting Info

Supramolecular Control for the Modular Synthesis of Pseudopeptidic Macrocycles through an Anion-Templated Reaction Ignacio Alfonso, Michael Bolte, Miriam Bru, M. Isabel Burguete, Santiago V. Luis, Jenifer Rubio pp 6137–6144 DOI: 10.1021/ja710132c Supporting Info

Structure and Dynamics of the Aβ21–30 Peptide from the Interplay of NMR Experiments and Molecular Simulations Nicolas L. Fawzi, Aaron H. Phillips, Jory Z. Ruscio, Michaeleen Doucleff, David E. Wemmer, Teresa Head-Gordon pp 6145–6158 DOI: 10.1021/ja710366c

Access to Enantioenriched α-Amino Esters via Rhodium-Catalyzed 1,4-Addition/Enantioselective Protonation Laure Navarre, Rémi Martinez, Jean-Pierre Genet and Sylvain Darses pp 6159–6169 DOI: 10.1021/ja710691p Supporting Info

Inherent Chirality Dominates the Visible/Near-Ultraviolet CD Spectrum of Rhodopsin Gennaro Pescitelli, Narasimha Sreerama, Piero Salvadori, Koji Nakanishi, Nina Berova, Robert W. Woody pp 6170–6181 DOI: 10.1021/ja711009y Supporting Info

Palladium Vacataporphyrin Reveals Conformational Rearrangements Involving Hückel and Möbius Macrocyclic Topologies Ewa Pacholska-Dudziak, Janusz Skonieczny, Miłosz Pawlicki, Ludmiła Szterenberg, Zbigniew Ciunik, Lechosław Latos-Grayski pp 6182–6195 DOI: 10.1021/ja711039c Supporting Info

Functional Determinants of a Synthetic Vesicle Fusion System Yun Gong, Mingming Ma, Yumei Luo, Dennis Bong pp 6196–6205 DOI: 10.1021/ja711184u

Chemical Reactivity of D3h C78 (Metallo)Fullerene: Regioselectivity Changes Induced by Sc3N Encapsulation Sílvia Osuna, Marcel Swart, Josep M. Campanera, Josep M. Poblet, Miquel Solà pp 6206–6214 DOI: 10.1021/ja711167v Supporting Info

Sifuvirtide Screens Rigid Membrane Surfaces. Establishment of a Correlation between Efficacy and Membrane Domain Selectivity among HIV Fusion Inhibitor Peptides Henri G. Franquelim, Luís M. S. Loura, Nuno C. Santos and Miguel A. R. B. Castanho pp 6215–6223 DOI: 10.1021/ja711247n Supporting Info

A QM/MM Approach to Interpreting 67Zn Solid-State NMR Data in Zinc Proteins Andrew S. Lipton, Robert W. Heck, Greg R. Staeheli, Marat Valiev, Wibe A. De Jong, Paul D. Ellis pp 6224–6230 DOI: 10.1021/ja711240t Supporting Info

Palladium-Catalyzed Diastereo- and Enantioselective Wagner−Meerwein Shift: Control of Absolute Stereochemistry in the C−C Bond Migration Event Barry M. Trost, Jia Xie pp 6231–6242 DOI: 10.1021/ja7111299 Supporting Info

Towards Zirconium Phosphonate-Based Microarrays for Probing DNA−Protein Interactions: Critical Influence of the Location of the Probe Anchoring Groups Julien Monot, Marc Petit, Sarah M. Lane, Isabelle Guisle, Jean Léger, Charles Tellier, Daniel R. Talham, Bruno Bujoli pp 6243–6251 DOI: 10.1021/ja711427q Supporting Info

Vapor–Liquid–Solid and Vapor–Solid Growth of Phase-Change Sb2Te3 Nanowires and Sb2Te3/GeTe Nanowire Heterostructures Jin Seok Lee, Sarah Brittman, Dong Yu, Hongkun Park pp 6252–6258 DOI: 10.1021/ja711481b Supporting Info

Molecular Engineering of Organic Sensitizers for Dye-Sensitized Solar Cell Applications Daniel P. Hagberg, Jun-Ho Yum, HyoJoong Lee, Filippo De Angelis, Tannia Marinado, Karl Martin Karlsson, Robin Humphry-Baker, Licheng Sun, Anders Hagfeldt, Michael Grätzel, Md. K. Nazeeruddin pp 6259–6266 DOI: 10.1021/ja800066y Supporting Info

Fluidic and Air-Stable Supported Lipid Bilayer and Cell-Mimicking Microarrays Yang Deng, Yini Wang, Bryan Holtz, Jingyi Li, Nathan Traaseth, Gianluigi Veglia, Benjamin J. Stottrup, Robert Elde, Duanqing Pei, Athena Guo, X.-Y. Zhu pp 6267–6271 DOI: 10.1021/ja800049f Supporting Info

Thiolate Bridging and Metal Exchange in Adducts of a Zinc Finger Model and PtII Complexes: Biomimetic Studies of Protein/Pt/DNA Interactions Elky Almaraz, Queite A. de Paula, Qin Liu, Joseph H. Reibenspies, Marcetta Y. Darensbourg, Nicholas P. Farrell pp 6272–6280 DOI: 10.1021/ja711254q Supporting Info

The Total Synthesis of Roquefortine C and a Rationale for the Thermodynamic Stability of Isoroquefortine C over Roquefortine C Ning Shangguan, Warren J. Hehre, William S. Ohlinger, Mary Pat Beavers, Madeleine M. Joullié pp 6281–6287 DOI: 10.1021/ja800067q Supporting Info

β-H Transfer from the Metallacyclobutane: A Key Step in the Deactivation and Byproduct Formation for the Well-Defined Silica-Supported Rhenium Alkylidene Alkene Metathesis Catalyst Anne-Marie Leduc, Alain Salameh, Daravong Soulivong, Mathieu Chabanas, Jean-Marie Basset, Christophe Copéret, Xavier Solans-Monfort, Eric Clot, Odile Eisenstein, Volker P. W. Böhm, Michael Röper pp 6288–6297 DOI: 10.1021/ja800189a Supporting Info

Modified Active Site Coordination in a Clinical Mutant of Sulfite Oxidase Christian J. Doonan, Heather L. Wilson, K. V. Rajagopalan, Robert M. Garrett, Brian Bennett, Roger C. Prince, Graham N. George p 6298 DOI: 10.1021/ja802011n

Book Review of Modern Biooxidation: Enzymes, Reactions and Applications Patrick C. Cirino p 6299 DOI: 10.1021/ja077021e

Book Review of Kirk-Othmer Separation Technology p 6299 DOI: 10.1021/ja801651b

Book Review of Capillary Electrophoresis: Methods of Protocols. Methods in Molecular Biology, 384 p 6299 DOI: 10.1021/ja802601n

Book Review of Bioactive Heterocycles IV. Topics in Heterocyclic Chemistry, 10 GordonW. Gribble pp 6299–6300 DOI: 10.1021/ja802172w

Book Review of Foldamers: Structure, Properties, and Applications MichaelR. Carrasco p 6300 DOI: 10.1021/ja802171z

Issue 20

One-Electron Reductive Template-Directed Ligation of Oligodeoxynucleotides Possessing a Disulfide Bond Kazuhito Tanabe, Emi Kuraseko, Yoshimi Yamamoto and Sei-ichi Nishimoto pp 6302–6303 DOI: 10.1021/ja7111614 Supporting Info

Hydrogen Peroxide and Dioxygen Activation by Dinuclear Copper Complexes in Aqueous Solution: Hydroxyl Radical Production Initiated by Internal Electron Transfer Qing Zhu, Yuxiang Lian, Sunita Thyagarajan, Steven E. Rokita, Kenneth D. Karlin and Neil V. Blough pp 6304–6305 DOI: 10.1021/ja800080z Supporting Info

NMR Crystallography of Zeolites: Refinement of an NMR-Solved Crystal Structure Using ab Initio Calculations of 29Si Chemical Shift Tensors Darren H. Brouwer pp 6306–6307 DOI: 10.1021/ja800227f Supporting Info

Photosystem I/Molecular Wire/Metal Nanoparticle Bioconjugates for the Photocatalytic Production of H2 Rebecca A. Grimme, Carolyn E. Lubner, Donald A. Bryant and John H. Golbeck pp 6308–6309 DOI: 10.1021/ja800923y Supporting Info

Differential Dynamical Effects of Macromolecular Crowding on an Intrinsically Disordered Protein and a Globular Protein: Implications for In-Cell NMR Spectroscopy Conggang Li, Lisa M. Charlton, Asha Lakkavaram, Christopher Seagle, Guifang Wang, Gregory B. Young, Jeffrey M. Macdonald and Gary J. Pielak pp 6310–6311 DOI: 10.1021/ja801020z Supporting Info

Direct UV-Replica Molding of Biomimetic Hierarchical Structure for Selective Wetting Se-Jin Choi, Kahp Y. Suh and Hong H. Lee pp 6312–6313 DOI: 10.1021/ja801010n Supporting Info

Transmembrane Nanopores from Porphyrin Supramolecules Akiharu Satake, Mika Yamamura, Masafumi Oda and Yoshiaki Kobuke pp 6314–6315 DOI: 10.1021/ja801129a Supporting Info

Asymmetric Synthesis of (−)-Incarvillateine Employing an Intramolecular Alkylation via Rh-Catalyzed Olefinic C−H Bond Activation Andy S. Tsai, Robert G. Bergman and Jonathan A. Ellman pp 6316–6317 DOI: 10.1021/ja8012159 Supporting Info

Combustion Synthesis and Characterization of Nanocrystalline WO3 Walter Morales, Michael Cason, Olawunmi Aina, Norma R. de Tacconi and Krishnan Rajeshwar pp 6318–6319 DOI: 10.1021/ja8012402 Supporting Info

Engineering Target-Responsive Hydrogels Based on Aptamer−Target Interactions Huanghao Yang, Haipeng Liu, Huaizhi Kang and Weihong Tan pp 6320–6321 DOI: 10.1021/ja801339w Supporting Info

One-Pot Multi-Component Asymmetric Cascade Reactions Catalyzed by Soluble Star Polymers with Highly Branched Non-Interpenetrating Catalytic Cores Yonggui Chi, Steven T. Scroggins and Jean M. J. Frchet pp 6322–6323 DOI: 10.1021/ja8013456 Supporting Info

Coibamide A, a Potent Antiproliferative Cyclic Depsipeptide from the Panamanian Marine Cyanobacterium Leptolyngbya sp. Rebecca A. Medina, Douglas E. Goeger, Patrice Hills, Susan L. Mooberry, Nelson Huang, Luz I. Romero, Eduardo Ortega-Barra, William H. Gerwick and Kerry L. McPhail pp 6324–6325 DOI: 10.1021/ja801383f Supporting Info

Direct Observation of Polymer-Stabilized Blue Phase I Structure with Confocal Laser Scanning Microscope Kenji Higashiguchi, Kei Yasui and Hirotsugu Kikuchi pp 6326–6327 DOI: 10.1021/ja801553g Supporting Info

Synthesis, Structure, and Reactivity of Naphthalyne−Co2(CO)6 Complexes Nobuharu Iwasawa, Maiko Otsuka, Satomi Yamashita, Masao Aoki and Jun Takaya pp 6328–6329 DOI: 10.1021/ja801569q Supporting Info

Stereoselective Synthesis of β-l-Rhamnopyranosides Yong Joo Lee, Akihiro Ishiwata and Yukishige Ito pp 6330–6331 DOI: 10.1021/ja801574q Supporting Info

Hg(II)···Pd(II) Metallophilic Interactions Mieock Kim, Thomas J. Taylor and Franois P. Gabba pp 6332–6333 DOI: 10.1021/ja801626c Supporting Info

Toward Stable Interfaces in Conjugated Polymers: Microporous Poly(p-phenylene) and Poly(phenyleneethynylene) Based on a Spirobifluorene Building Block Jens Weber and Arne Thomas pp 6334–6335 DOI: 10.1021/ja801691x Supporting Info

The Role of Tandem Acyl Carrier Protein Domains in Polyunsaturated Fatty Acid Biosynthesis Hui Jiang, Ross Zirkle, James G. Metz, Lisa Braun, Leslie Richter, Steven G. Van Lanen and Ben Shen pp 6336–6337 DOI: 10.1021/ja801911t Supporting Info

Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents Fumitoshi Shibahara, John F. Bower and Michael J. Krische pp 6338–6339 DOI: 10.1021/ja801213x Supporting Info

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate In Su Kim, Ming-Yu Ngai and Michael J. Krische pp 6340–6341 DOI: 10.1021/ja802001b Supporting Info

Selective Solar-Driven Reduction of CO2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell Emily E. Barton, David M. Rampulla and Andrew B. Bocarsly pp 6342–6344 DOI: 10.1021/ja0776327 Supporting Info

Pathways and Populations: Stereoelectronic Insights into the Exocyclic Torsion of 5-(Hydroxymethyl)tetrahydropyran H. Lee Woodcock, Bernard R. Brooks and Richard W. Pastor pp 6345–6347 DOI: 10.1021/ja077633z Supporting Info

Organogel Formation by a Cholesterol-Stoppered Bistable [2]Rotaxane and Its Dumbbell Precursor Yan-Li Zhao, Ivan Aprahamian, Ali Trabolsi, Natalia Erina and J. Fraser Stoddart pp 6348–6350 DOI: 10.1021/ja800731k Supporting Info

Fluorophore-Labeled β-Lactamase as a Biosensor for β-Lactam Antibiotics: A Study of the Biosensing Process Pak-Ho Chan, Pui-Kin So, Dik-Lung Ma, Yanxiang Zhao, Tat-Shing Lai, Wai-Hong Chung, Kwok-Chu Chan, Ka-Fai Yiu, Hoi-Wan Chan, Fung-Ming Siu, Chun-Wai Tsang, Yun-Chung Leung and Kwok-Yin Wong pp 6351–6361 DOI: 10.1021/ja076111g Supporting Info

Encapsulation of Protonated Diamines in a Water-Soluble, Chiral, Supramolecular Assembly Allows for Measurement of Hydrogen-Bond Breaking Followed by Nitrogen Inversion/Rotation Michael D. Pluth, Robert G. Bergman and Kenneth N. Raymond pp 6362–6366 DOI: 10.1021/ja076691h Supporting Info

Quantum Sieving Effect of Three-Dimensional Cu-Based Organic Framework for H2 and D2 Daisuke Noguchi, Hideki Tanaka, Atsushi Kondo, Hiroshi Kajiro, Hiroshi Noguchi, Tomonori Ohba, Hirofumi Kanoh and Katsumi Kaneko pp 6367–6372 DOI: 10.1021/ja077469f Supporting Info

Molecular Weight Recognition in the Multiple-Stranded Helix of a Synthetic Polymer without Specific Monomer–Monomer Interaction Jiro Kumaki, Takehiro Kawauchi, Koichi Ute, Tatsuki Kitayama and Eiji Yashima pp 6373–6380 DOI: 10.1021/ja077861t Supporting Info

l-Tryptophan Radical Cation Electron Spin Resonance Studies: Connecting Solution-Derived Hyperfine Coupling Constants with Protein Spectral Interpretations Henry D. Connor, Bradley E. Sturgeon, Carolyn Mottley, Herbert J. Sipe, and Ronald P. Mason pp 6381–6387 DOI: 10.1021/ja0780277 Supporting Info

Valence Parity Renders z•-Type Ions Chemically Distinct Shane L. Hubler, April Jue, Jason Keith, Graeme C. McAlister, Gheorghe Craciun and Joshua J. Coon pp 6388–6394 DOI: 10.1021/ja7099985 Supporting Info

Dynamics in a Pure Encounter Complex of Two Proteins Studied by Solution Scattering and Paramagnetic NMR Spectroscopy Xingfu Xu, Wolfgang Reinle, Frank Hannemann, Peter V. Konarev, Dmitri I. Svergun, Rita Bernhardt and Marcellus Ubbink pp 6395–6403 DOI: 10.1021/ja7101357 Supporting Info

Identification of a New Class of Nonpeptidic Inhibitors of Cruzain Katrien Brak, Patricia S. Doyle, James H. McKerrow and Jonathan A. Ellman pp 6404–6410 DOI: 10.1021/ja710254m Supporting Info

Surface Interactions and Quantum Kinetic Molecular Sieving for H2 and D2 Adsorption on a Mixed Metal−Organic Framework Material Banglin Chen, Xuebo Zhao, Apipong Putkham, Kunlun Hong, Emil B. Lobkovsky, Eric J. Hurtado, Ashleigh J. Fletcher and K. Mark Thomas pp 6411–6423 DOI: 10.1021/ja710144k Supporting Info

Amyloid Fiber Formation and Membrane Disruption are Separate Processes Localized in Two Distinct Regions of IAPP, the Type-2-Diabetes-Related Peptide Jeffrey R. Brender, Edgar L. Lee, Marchello A. Cavitt, Ari Gafni, Duncan G. Steel and Ayyalusamy Ramamoorthy pp 6424–6429 DOI: 10.1021/ja710484d

Steric Control in the Thermal Rearrangement of a Bicyclo[3.1.0]hex-2-ene Substituted at a Radical-Nonstabilizing Position William von Eggers Doering and Xin Zhao pp 6430–6437 DOI: 10.1021/ja7104812 Supporting Info

Measurement of the Binding of Cholera Toxin to GM1 Gangliosides on Solid Supported Lipid Bilayer Vesicles and Inhibition by Europium (III) Chloride Thomas L. Williams and A. Toby A. Jenkins pp 6438–6443 DOI: 10.1021/ja710543x

Functionalized Methanofullerenes Used as n-Type Materials in Bulk-Heterojunction Polymer Solar Cells and in Field-Effect Transistors Changduk Yang, Jin Young Kim, Shinuk Cho, Jae Kwan Lee, Alan J. Heeger and Fred Wudl pp 6444–6450 DOI: 10.1021/ja710621j Supporting Info

Sequence of Intramolecular Carbonylation and Asymmetric Hydrogenation Reactions: Highly Regio- and Enantioselective Synthesis of Medium Ring Tricyclic Lactams Shui-Ming Lu and Howard Alper pp 6451–6455 DOI: 10.1021/ja7111417 Supporting Info

Role of Hydrogen Bonding and Helix−Lipid Interactions in Transmembrane Helix Association Jinhyuk Lee and Wonpil Im pp 6456–6462 DOI: 10.1021/ja711239h Supporting Info

Effects of Alkaline Earth Metal Ion Complexation on Amino Acid Zwitterion Stability: Results from Infrared Action Spectroscopy Matthew F. Bush, Jos Oomens, Richard J. Saykally and Evan R. Williams pp 6463–6471 DOI: 10.1021/ja711343q Supporting Info

Quantitative Lid Dynamics of MDM2 Reveals Differential Ligand Binding Modes of the p53-Binding Cleft Scott A. Showalter, Lei Bruschweiler-Li, Eric Johnson, Fengli Zhang and Rafael Brüschweiler pp 6472–6478 DOI: 10.1021/ja800201j Supporting Info

Single-Molecule Force Spectroscopy Measurements of Bond Elongation during a Bimolecular Reaction Sri Rama Koti Ainavarapu, Arun P . Wiita, Lorna Dougan, Einar Uggerud and Julio M . Fernandez pp 6479–6487 DOI: 10.1021/ja800180u Supporting Info

A General and Rapid Cell-Free Approach for the Interrogation of Protein−Protein, Protein−DNA, and Protein−RNA Interactions and their Antagonists Utilizing Split-Protein Reporters Jason R. Porter, Cliff I. Stains, Benjamin W. Jester and Indraneel Ghosh pp 6488–6497 DOI: 10.1021/ja7114579 Supporting Info

Water-Soluble Cruciforms: Response to Protons and Selected Metal Ions Juan Tolosa, Anthony J. Zucchero and Uwe H. F. Bunz pp 6498–6506 DOI: 10.1021/ja800232f Supporting Info

Synthesis, Resolution, and VCD Analysis of an Enantiopure Diazaoxatricornan Derivative Pierre Mobian, Cyril Nicolas, Eric Francotte, Thomas Brgi and Jrme Lacour pp 6507–6514 DOI: 10.1021/ja800262j Supporting Info

Structure of Ternary Imide Li2Ca(NH)2 and Hydrogen Storage Mechanisms in Amide−Hydride System Hui Wu pp 6515–6522 DOI: 10.1021/ja800300e Supporting Info

Mechanistic Studies of the Copolymerization Reaction of Oxetane and Carbon Dioxide to Provide Aliphatic Polycarbonates Catalyzed by (Salen)CrX Complexes Donald J. Darensbourg, Adriana I. Moncada, Wonsook Choi and Joseph H. Reibenspies pp 6523–6533 DOI: 10.1021/ja800302c Supporting Info

Synthesis of Diamond-Shape Titanate Molecular Sheets with Different Sizes and Realization of Quantum Confinement Effect during Dimensionality Reduction from Two to Zero Eunju Lee Tae, Kee Eun Lee, Jong Seok Jeong and Kyung Byung Yoon pp 6534–6543 DOI: 10.1021/ja711467g Supporting Info

Crystallographic Characterization of Helical Secondary Structures in α/β-Peptides with 1:1 Residue Alternation Soo Hyuk Choi, Ilia A. Guzei, Lara C. Spencer and Samuel H. Gellman pp 6544–6550 DOI: 10.1021/ja800355p Supporting Info

Optical Properties of Ultrashort Semiconducting Single-Walled Carbon Nanotube Capsules Down to Sub-10 nm Xiaoming Sun, Sasa Zaric, Dan Daranciang, Kevin Welsher, Yuerui Lu, Xiaolin Li and Hongjie Dai pp 6551–6555 DOI: 10.1021/ja8006929 Supporting Info

Onset of 310-Helical Secondary Structure in Aib Oligopeptides Probed by Coherent 2D IR Spectroscopy Hiroaki Maekawa, Fernando Formaggio, Claudio Toniolo and Nien-Hui Ge pp 6556–6566 DOI: 10.1021/ja8007165 Supporting Info

Structural and Spectroscopic Characterization of a Charge-Separated Uranium Benzophenone Ketyl Radical Complex Oanh P. Lam, Christian Anthon, Frank W. Heinemann, Joseph M. O’Connor and Karsten Meyer pp 6567–6576 DOI: 10.1021/ja801007q Supporting Info

Experimental Evidence for Enzyme-Enhanced Coupled Motion/Quantum Mechanical Hydrogen Tunneling by Ketosteroid Isomerase Thomas C. Wilde, Grzegorz Blotny and Ralph M. Pollack pp 6577–6585 DOI: 10.1021/ja0732330 Supporting Info

Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure–Activity Relationships Qilong Shen, Tokutaro Ogata and John F. Hartwig pp 6586–6596 DOI: 10.1021/ja077074w Supporting Info

Carbon−Deuterium Bonds as Probes of Dihydrofolate Reductase Megan C. Thielges, David A. Case and Floyd E. Romesberg pp 6597–6603 DOI: 10.1021/ja0779607 Supporting Info

Influence of Solvent on Carbene Intersystem Crossing Rates Jin Wang, Jacek Kubicki, Huolei Peng and Matthew S. Platz pp 6604–6609 DOI: 10.1021/ja711385t Supporting Info

Activation of N-Sulfonyl Oxaziridines Using Copper(II) Catalysts: Aminohydroxylations of Styrenes and 1,3-Dienes David J. Michaelis, Michael A. Ischay and Tehshik P. Yoon pp 6610–6615 DOI: 10.1021/ja800495r Supporting Info

Characterization of the Two-Component, FAD-Dependent Monooxygenase SgcC That Requires Carrier Protein-Tethered Substrates for the Biosynthesis of the Enediyne Antitumor Antibiotic C-1027 Shuangjun Lin, Steven G. Van Lanen and Ben Shen pp 6616–6623 DOI: 10.1021/ja710601d Supporting Info

The Reactivity Patterns of Low-Coordinate Iron−Hydride Complexes Ying Yu, Azwana R. Sadique, Jeremy M. Smith, Thomas R. Dugan, Ryan E. Cowley, William W. Brennessel, Christine J. Flaschenriem, Eckhard Bill, Thomas R. Cundari and Patrick L. Holland pp 6624–6638 DOI: 10.1021/ja710669w Supporting Info

A Simple DNase Model System Comprising a Dinuclear Zn(II) Complex in Methanol Accelerates the Cleavage of a Series of Methyl Aryl Phosphate Diesters by 1011−1013 Alexei A. Neverov, C. Tony Liu, Shannon E. Bunn, David Edwards, Christopher J. White, Stephanie A. Melnychuk and R. Stan Brown pp 6639–6649 DOI: 10.1021/ja8006963 Supporting Info

Near-Infrared Light Activated Release of Nitric Oxide from Designed Photoactive Manganese Nitrosyls: Strategy, Design, and Potential as NO Donors Aura A. Eroy-Reveles, Yvonne Leung, Christine M. Beavers, Marilyn M. Olmstead and Pradip K. Mascharak p 6650 DOI: 10.1021/ja802581m

Book Review of Iminosugars: From Synthesis to Therapeutic Applications George A. O’Doherty p 6651 DOI: 10.1021/ja802441r

Book Review of Chemistry and Physics of Carbon, Vol. 30 p 6651 DOI: 10.1021/ja802573n

Book Review of Intelligent Materials T. Ross Kelly pp 6651–6652 DOI: 10.1021/ja802339z

Issue 21

JACS Virtual Issues Peter J. Stang p 6653 DOI: 10.1021/ja803236b

Total Synthesis of Biologically Active Natural Products William R. Roush pp 6654–6656 DOI: 10.1021/ja8028813

Efficient Synthetic Access to a New Family of Highly Potent Bryostatin Analogues via a Prins-Driven Macrocyclization Strategy Paul A. Wender, Brian A. DeChristopher and Adam J. Schrier pp 6658–6659 DOI: 10.1021/ja8015632 Supporting Info

Convergent Assembly of Highly Potent Analogues of Bryostatin 1 via Pyran Annulation: Bryostatin Look-Alikes That Mimic Phorbol Ester Function Gary E. Keck, Matthew B. Kraft, Anh P. Truong, Wei Li, Carina C. Sanchez, Noemi Kedei, Nancy E. Lewin and Peter M. Blumberg pp 6660–6661 DOI: 10.1021/ja8022169 Supporting Info

Synthesis of Multimeric MR Contrast Agents for Cellular Imaging Ying Song, Ellen K. Kohlmeir and Thomas J. Meade pp 6662–6663 DOI: 10.1021/ja0777990 Supporting Info

Bonding of Macromolecular Hydrogels Using Perturbants Gavrielle M. Price, Kengyeh K. Chu, James G. Truslow, Min D. Tang-Schomer, Andrew P. Golden, Jerome Mertz and Joe Tien pp 6664–6665 DOI: 10.1021/ja711340d Supporting Info

Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzeno Square Macrocycles on a Surface Kazukuni Tahara, Shengbin Lei, Wael Mamdouh, Yui Yamaguchi, Tomoyuki Ichikawa, Hiroshi Uji-i, Motohiro Sonoda, Keiji Hirose, Frans C. De Schryver, Steven De Feyter and Yoshito Tobe pp 6666–6667 DOI: 10.1021/ja711422h Supporting Info

Synthesis of Microporous Boron-Substituted Carbon (B/C) Materials Using Polymeric Precursors for Hydrogen Physisorption T. C. Mike Chung, Youmi Jeong, Qiang Chen, Alfred Kleinhammes and Yue Wu pp 6668–6669 DOI: 10.1021/ja800071y Supporting Info

Complete Supramolecular Self-Assembled Adlayer on a Silicon Surface at Room Temperature Younes Makoudi, Frank Palmino, Madjid Arab, Eric Duverger and Frdric Chrioux pp 6670–6671 DOI: 10.1021/ja8001259 Supporting Info

Molecular Rotor Measures Viscosity of Live Cells via Fluorescence Lifetime Imaging Marina K. Kuimova, Gokhan Yahioglu, James A. Levitt and Klaus Suhling pp 6672–6673 DOI: 10.1021/ja800570d Supporting Info

Temperature-Dependent Statistical Behavior of Single Molecular Conductance in Aqueous Solution Hui Cao, Jun Jiang, Jing Ma and Yi Luo pp 6674–6675 DOI: 10.1021/ja8007648 Supporting Info

A New Silicon Lewis Acid for Highly Enantioselective Mannich Reactions of Aliphatic Ketone-Derived Hydrazones Gregory T. Notte and James L. Leighton pp 6676–6677 DOI: 10.1021/ja800830h Supporting Info

Organized Formation of 2D Extended Covalent Organic Frameworks at Surfaces Nikolas A. A. Zwaneveld, Rmy Pawlak, Mathieu Abel, Daniel Catalin, Didier Gigmes, Denis Bertin and Louis Porte pp 6678–6679 DOI: 10.1021/ja800906f Supporting Info

Sialoside Analogue Arrays for Rapid Identification of High Affinity Siglec Ligands Ola Blixt, Shoufa Han, Liang Liao, Ying Zeng, Julia Hoffmann, Satoshi Futakawa and James C. Paulson pp 6680–6681 DOI: 10.1021/ja801052g Supporting Info

Methionine Ligand Lability of Type I Cytochromes c: Detection of Ligand Loss Using Protein Film Voltammetry Tao Ye, Ravinder Kaur, F. Timur Senguen, Lea V. Michel, Kara L. Bren and Sean J. Elliott pp 6682–6683 DOI: 10.1021/ja801071n Supporting Info

Calculations Predict Rapid Tunneling by Carbon from the Vibrational Ground State in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures Ayan Datta, David A. Hrovat and Weston Thatcher Borden pp 6684–6685 DOI: 10.1021/ja801089p Supporting Info

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides Mark R. Biscoe, Brett P. Fors and Stephen L. Buchwald pp 6686–6687 DOI: 10.1021/ja801137k Supporting Info

Evidence of the Chemical Uniaxial Strain Effect on Electrical Conductivity in the Spin-Crossover Conducting Molecular System: [FeIII(qnal)2][Pd(dmit)2]5·Acetone Kazuyuki Takahashi, Heng-Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga and Osamu Sato pp 6688–6689 DOI: 10.1021/ja801585r Supporting Info

Broken Helix in Vesicle and Micelle-Bound α-Synuclein: Insights from Site-Directed Spin Labeling-EPR Experiments and MD Simulations Marco Bortolus, Fabio Tombolato, Isabella Tessari, Marco Bisaglia, Stefano Mammi, Luigi Bubacco, Alberta Ferrarini and Anna Lisa Maniero pp 6690–6691 DOI: 10.1021/ja8010429 Supporting Info

Coupling between Molecular and Plasmonic Resonances in Freestanding Dye−Gold Nanorod Hybrid Nanostructures Weihai Ni, Zhi Yang, Huanjun Chen, Li Li and Jianfang Wang pp 6692–6693 DOI: 10.1021/ja8012374 Supporting Info

Enantioselective Alkyl−Alkyl Suzuki Cross-Couplings of Unactivated Homobenzylic Halides Bunnai Saito and Gregory C. Fu pp 6694–6695 DOI: 10.1021/ja8013677 Supporting Info

6-Peroxo-6-Zirconium Crown and Its Hafnium Analogue Embedded in a Triangular Polyanion: [M6(O2)6(OH)6(γ-SiW10O36)3]18− (M = Zr, Hf) Bassem S. Bassil, Sib Sankar Mal, Michael H. Dickman, Ulrich Kortz, Holger Oelrich and Lorenz Walder pp 6696–6697 DOI: 10.1021/ja801424q Supporting Info

Tracking Fiber Formation in Human Islet Amyloid Polypeptide with Automated 2D-IR Spectroscopy David B. Strasfeld, Yun L. Ling, Sang-Hee Shim and Martin T. Zanni pp 6698–6699 DOI: 10.1021/ja801483n Supporting Info

Reaction of a Copper−Dioxygen Complex with Nitrogen Monoxide (•NO) Leads to a Copper(II)−Peroxynitrite Species Debabrata Maiti, Dong-Heon Lee, Amy A. Narducci Sarjeant, Monita Y. M. Pau, Edward I. Solomon, Katya Gaoutchenova, Jörg Sundermeyer and Kenneth D. Karlin pp 6700–6701 DOI: 10.1021/ja801540e Supporting Info

Encapsulation and Dynamic Behavior of Two H2 Molecules in an Open-Cage C70 Yasujiro Murata, Shuhei Maeda, Michihisa Murata and Koichi Komatsu pp 6702–6703 DOI: 10.1021/ja801753m Supporting Info

A Polar Oxide ZnSnO3 with a LiNbO3-Type Structure Yoshiyuki Inaguma, Masashi Yoshida and Tetsuhiro Katsumata pp 6704–6705 DOI: 10.1021/ja801843v Supporting Info

Inhibitors of UDP-Galactopyranose Mutase Thwart Mycobacterial Growth Emily C. Dykhuizen, John F. May, Aimon Tongpenyai and Laura L. Kiessling pp 6706–6707 DOI: 10.1021/ja8018687 Supporting Info

Direct Observation of the Primary Bond-Twisting Dynamics of Stilbene Anion Radical I-Ren Lee, Luis Baares and Ahmed H. Zewail pp 6708–6709 DOI: 10.1021/ja801926m Supporting Info

Effect of O6-Methylguanine on the Stability of G-Quadruplex DNA Chongkham S. Mekmaysy, Luigi Petraccone, Nichola C. Garbett, Patricia A. Ragazzon, Robert Gray, John O. Trent and Jonathan B. Chaires pp 6710–6711 DOI: 10.1021/ja801976h Supporting Info

Mssbauer Evidence for an Exchange-Coupled {[Fe4S4]1+ Nip1+} A-Cluster in Isolated α Subunits of Acetyl-Coenzyme A Synthase/Carbon Monoxide Dehydrogenase Xiangshi Tan, Marlne Martinho, Audria Stubna, Paul A. Lindahl and Eckard Mnck pp 6712–6713 DOI: 10.1021/ja801981h Supporting Info

Direct Evidence for Deprotonation of a Lysine Side Chain Buried in the Hydrophobic Core of a Protein Yuki Takayama, Carlos A. Castaeda, Michael Chimenti, Bertrand Garca-Moreno and Junji Iwahara pp 6714–6715 DOI: 10.1021/ja801731g Supporting Info

Synthesis of [6.8]3Cyclacene: Conjugated Belt and Model for an Unusual Type of Carbon Nanotube Birgit Esser, Frank Rominger and Rolf Gleiter pp 6716–6717 DOI: 10.1021/ja801918n Supporting Info

A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions Banglin Chen, Liangbo Wang, Fatima Zapata, Guodong Qian and Emil B. Lobkovsky pp 6718–6719 DOI: 10.1021/ja802035e Supporting Info

Simple Enantioselective Approach to Synthetic Limonoids Douglas C. Behenna and E. J. Corey pp 6720–6721 DOI: 10.1021/ja802376g Supporting Info

Structural Basis of DNA Quadruplex Recognition by an Acridine Drug Nancy H. Campbell, Gary N. Parkinson, Anthony P. Reszka and Stephen Neidle pp 6722–6724 DOI: 10.1021/ja8016973 Supporting Info

Toward Long-Distance Mechanical Communication: Studies on a Ternary Complex Interconnected by a Bridging Rotary Module Hiroyuki Kai, Shinji Nara, Kazushi Kinbara and Takuzo Aida pp 6725–6727 DOI: 10.1021/ja801646b Supporting Info

A Model of the Oxygen-Evolving Center of Photosystem II Predicted by Structural Refinement Based on EXAFS Simulations Eduardo M. Sproviero, Jos A. Gascn, James P. McEvoy, Gary W. Brudvig and Victor S. Batista pp 6728–6730 DOI: 10.1021/ja801979n Supporting Info

Synthesis of Fluorine-18 Functionalized Nanoparticles for use as in vivo Molecular Imaging Agents John B. Matson and Robert H. Grubbs pp 6731–6733 DOI: 10.1021/ja802010d Supporting Info

Poly(3,4-ethylenedioxyselenophene) Asit Patra, Yair H. Wijsboom, Sanjio S. Zade, Mao Li, Yana Sheynin, Gregory Leitus and Michael Bendikov pp 6734–6736 DOI: 10.1021/ja8018675 Supporting Info

Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene Carley L. Chandler and Benjamin List pp 6737–6739 DOI: 10.1021/ja8024164 Supporting Info

Secondary Orbital Effect in the Electrocyclic Ring Closure of 7-Azahepta-1,2,4,6-tetraeneA CASSCF Molecular Orbital Study James A. Duncan, David E. G. Calkins and Mariya Chavarha pp 6740–6748 DOI: 10.1021/ja074402j Supporting Info

The Reaction Mechanism for the Organocatalytic Ring-Opening Polymerization of l-Lactide Using a Guanidine-Based Catalyst: Hydrogen-Bonded or Covalently Bound? Anthony Chuma, Hans W. Horn, William C. Swope, Russell C. Pratt, Lei Zhang, Bas G. G. Lohmeijer, Charles G. Wade, Robert M. Waymouth, James L. Hedrick and Julia E. Rice pp 6749–6754 DOI: 10.1021/ja0764411 Supporting Info

Stabilization by Extra-Helical Thymines of a DNA Duplex with Hoogsteen Base Pairs Joan Pous, Lourdes Urp, Juan A. Subirana, Catherine Gouyette, Jorge Navaza and J. Lourdes Campos pp 6755–6760 DOI: 10.1021/ja078022+ Supporting Info

Sodium Alanate Nanoparticles − Linking Size to Hydrogen Storage Properties Cornelis P. Bald, Bart P.C. Hereijgers, Johannes H. Bitter and Krijn P. de Jong pp 6761–6765 DOI: 10.1021/ja710667v Supporting Info

Silylidyne, HSiMoH3 and HSiWH3, and Silyl Metal Hydride, SiH3CrH, Products in Silane Reactions Xuefeng Wang and Lester Andrews pp 6766–6773 DOI: 10.1021/ja710810x Supporting Info

Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery Patricia Horcajada, Christian Serre, Guillaume Maurin, Naseem A. Ramsahye, Francisco Balas, Mara Vallet-Regí, Muriel Sebban, Francis Taulelle and Grard Férey pp 6774–6780 DOI: 10.1021/ja710973k Supporting Info

Conformation and Molecular Dynamics of Single Polystyrene Chain Confined in Coordination Nanospace Takashi Uemura, Satoshi Horike, Kana Kitagawa, Motohiro Mizuno, Kazunaka Endo, Silvia Bracco, Angiolina Comotti, Piero Sozzani, Masataka Nagaoka and Susumu Kitagawa pp 6781–6788 DOI: 10.1021/ja800087s Supporting Info

Observation of Uncorrelated Microscopic Motion in a Strongly Interacting Adsorbate System Gil Alexandrowicz, Pepijn R. Kole, Everett Y. M. Lee, Holly Hedgeland, Riccardo Ferrando, Andrew P. Jardine, William Allison and John Ellis pp 6789–6794 DOI: 10.1021/ja800118x Supporting Info

Structure-Dependent Reactivity of Semiconducting Single-Walled Carbon Nanotubes with Benzenediazonium Salts Condell D. Doyle, John-David R. Rocha, R. Bruce Weisman and James M. Tour pp 6795–6800 DOI: 10.1021/ja800198t

Water-Enhanced Low-Temperature CO Oxidation and Isotope Effects on Atomic Oxygen-Covered Au(111) Rotimi A. Ojifinni, Nathan S. Froemming, Jinlong Gong, Ming Pan, Tae S. Kim, J. M. White, Graeme Henkelman and C. Buddie Mullins pp 6801–6812 DOI: 10.1021/ja800351j

Single-Molecule Detection of Nitrogen Mustards by Covalent Reaction within a Protein Nanopore Hai-Chen Wu and Hagan Bayley pp 6813–6819 DOI: 10.1021/ja8004607 Supporting Info

An Enzyme-Based E-DNA Sensor for Sequence-Specific Detection of Femtomolar DNA Targets Gang Liu, Ying Wan, Vincent Gau, Jiong Zhang, Lihua Wang, Shiping Song and Chunhai Fan pp 6820–6825 DOI: 10.1021/ja800554t Supporting Info

Residue-Level Interrogation of Macromolecular Crowding Effects on Protein Stability Lisa M. Charlton, Christopher O. Barnes, Conggang Li, Jillian Orans, Gregory B. Young and Gary J. Pielak pp 6826–6830 DOI: 10.1021/ja8005995 Supporting Info

Nonadiabatic Deactivation of 9H-Adenine: A Comprehensive Picture Based on Mixed Quantum−Classical Dynamics Mario Barbatti and Hans Lischka pp 6831–6839 DOI: 10.1021/ja800589p Supporting Info

Bidentates versus Monodentates in Asymmetric Hydrogenation Catalysis: Synergic Effects on Rate and Allosteric Effects on Enantioselectivity David W. Norman, Charles A. Carraz, David J. Hyett, Paul G. Pringle, Joseph B. Sweeney, A. Guy Orpen, Hirrahataya Phetmung and Richard L. Wingad pp 6840–6847 DOI: 10.1021/ja800858x Supporting Info

Identification and Characterization of a New Family of Catalytically Highly Active Imidazolin-2-ylidenes Xinjun Luan, Ronaldo Mariz, Michele Gatti, Chiara Costabile, Albert Poater, Luigi Cavallo, Anthony Linden and Reto Dorta pp 6848–6858 DOI: 10.1021/ja800861p Supporting Info

Next Generation Hairpin Polyamides with (R)-3,4-Diaminobutyric Acid Turn Unit Christian Dose, Michelle E. Farkas, David M. Chenoweth and Peter B. Dervan pp 6859–6866 DOI: 10.1021/ja800888d Supporting Info

Printable Cross-Linked Polymer Blend Dielectrics. Design Strategies, Synthesis, Microstructures, and Electrical Properties, with Organic Field-Effect Transistors as Testbeds Choongik Kim, Zhiming Wang, Hyuk-Jin Choi, Young-Geun Ha, Antonio Facchetti and Tobin J. Marks pp 6867–6878 DOI: 10.1021/ja801047g Supporting Info

Nucleation and Growth of CaCO3 Mediated by the Egg-White Protein Ovalbumin: A Time-Resolved in situ Study Using Small-Angle Neutron Scattering Vitaliy Pipich, Mathias Balz, Stephan E. Wolf, Wolfgang Tremel and Dietmar Schwahn pp 6879–6892 DOI: 10.1021/ja801798h Supporting Info

Issue 22

Synthesis and Structure of a Hexacoordinate Carbon Compound Torahiko Yamaguchi, Yohsuke Yamamoto, Daisuke Kinoshita, Kin-ya Akiba, Yun Zhang, Christopher A. Reed, Daisuke Hashizume and Fujiko Iwasaki pp 6894–6895 DOI: 10.1021/ja710423d Supporting Info

Inhibition of HIV Fusion with Multivalent Gold Nanoparticles Mary-Catherine Bowman, T. Eric Ballard, Christopher J. Ackerson, Daniel L. Feldheim, David M. Margolis and Christian Melander pp 6896–6897 DOI: 10.1021/ja710321g Supporting Info

Copper(II) Binding to α-Synuclein, the Parkinson’s Protein Jennifer C. Lee, Harry B. Gray and Jay R. Winkler pp 6898–6899 DOI: 10.1021/ja711415b Supporting Info

Lanthanide Luminescent Displacement Assays: The Sensing of Phosphate Anions Using Eu(III)−Cyclen-Conjugated Gold Nanoparticles in Aqueous Solution Julien Massue, Susan J. Quinn and Thorfinnur Gunnlaugsson pp 6900–6901 DOI: 10.1021/ja800361e Supporting Info

Temperature-Dependent 3-D CuI Coordination Polymers of Calix[4]-bis-dithiacrown: Crystal-to-Crystal Transformation and Photoluminescence Change on Coordinated Solvent Removal Jai Young Lee, So Young Lee, Wonbo Sim, Ki-Min Park, Jineun Kim and Shim Sung Lee pp 6902–6903 DOI: 10.1021/ja8008693 Supporting Info

Pyrene-Zipper Array Assembled via RNA Duplex Formation Mitsunobu Nakamura, Yohei Murakami, Kazuhiro Sasa, Haruhisa Hayashi and Kazushige Yamana pp 6904–6905 DOI: 10.1021/ja801054t Supporting Info

Stereoselective Umpolung Tandem Addition of Heteroatoms to Phenol Michael A. Todd, Michal Sabat, William H. Myers, Timothy M. Smith and W. Dean Harman pp 6906–6907 DOI: 10.1021/ja801076z Supporting Info

Alkanethiol/Au(111) Self-Assembled Monolayers Contain Gold Adatoms: Scanning Tunneling Microscopy before and after Reaction with Atomic Hydrogen Natalie A. Kautz and S. Alex Kandel pp 6908–6909 DOI: 10.1021/ja8011325 Supporting Info

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters from N-tert-Butanesulfinyl Aldimines Melissa A. Beenen, Chihui An and Jonathan A. Ellman pp 6910–6911 DOI: 10.1021/ja800829y Supporting Info

Quantitative Determination of Singlet Oxygen Generated by Excited State Aromatic Amino Acids, Proteins, and Immunoglobulins Khin K. Chin, Colleen C. Trevithick-Sutton, Jeremy McCallum, Steffen Jockusch, Nicholas J. Turro, J. C. Scaiano, Christopher S. Foote and Miguel A. Garcia-Garibay pp 6912–6913 DOI: 10.1021/ja800926v Supporting Info

Optimizing the Signal Enhancement In Cryogenic ex situ DNP−NMR Spectroscopy Martin G. Saunders, Christian Ludwig and Ulrich L. Günther pp 6914–6915 DOI: 10.1021/ja800971t Supporting Info

Sustainable Radical Reduction through Catalytic Hydrogen Atom Transfer Andreas Gansuer, Chun-An Fan and Frederik Piestert pp 6916–6917 DOI: 10.1021/ja801232t Supporting Info

A Simple, Modular Synthesis of Substituted Pyridines Songbai Liu and Lanny S. Liebeskind pp 6918–6919 DOI: 10.1021/ja8013743 Supporting Info

Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand Masato Ohashi, Marcin Konkol, Iker Del Rosal, Romuald Poteau, Laurent Maron and Jun Okuda pp 6920–6921 DOI: 10.1021/ja801771u Supporting Info

Asymmetric Petasis Reactions Catalyzed by Chiral Biphenols Sha Lou and Scott E. Schaus pp 6922–6923 DOI: 10.1021/ja8018934 Supporting Info

Rhodium(I)-Catalyzed Cycloisomerizations of Bicyclobutanes Maciej A. A. Walczak and Peter Wipf pp 6924–6925 DOI: 10.1021/ja802906k Supporting Info

Charge Carrier Field Emission Determines the Number of Charges on Native State Proteins in Electrospray Ionization Christopher J. Hogan, , James A. Carroll, Henry W. Rohrs, Pratim Biswas and Michael L. Gross pp 6926–6927 DOI: 10.1021/ja801280c Supporting Info

Nanoparticle Plasmon-Assisted Two-Photon Polymerization Induced by Incoherent Excitation Source Kosei Ueno, Saulius Juodkazis, Toshiyuki Shibuya, Yukie Yokota, Vygantas Mizeikis, Keiji Sasaki and Hiroaki Misawa pp 6928–6929 DOI: 10.1021/ja801262r

Nonlinear Optical Properties as a Guide to Aromaticity in Congeneric Pentapyrrolic Expanded Porphyrins: Pentaphyrin, Sapphyrin, Isosmaragdyrin, and Orangarin Zin Seok Yoon, Dong-Gyu Cho, Kil Suk Kim, Jonathan L. Sessler and Dongho Kim pp 6930–6931 DOI: 10.1021/ja801395y Supporting Info

An Extended Conical Intersection Seam Associated with a Manifold of Decay Paths: Excited-State Intramolecular Proton Transfer in O-Hydroxybenzaldehyde Annapaola Migani, Llus Blancafort, Michael A. Robb and Anthony D. DeBellis pp 6932–6933 DOI: 10.1021/ja8013924 Supporting Info

Hierarchical Structure of Carbon Nanotube Networks Tirtha Chatterjee, Andrew Jackson and Ramanan Krishnamoorti pp 6934–6935 DOI: 10.1021/ja801480h Supporting Info

Vesicles and Organogels from Foldamers: A Solvent-Modulated Self-Assembling Process Wei Cai, Gui-Tao Wang, Yun-Xiang Xu, Xi-Kui Jiang and Zhan-Ting Li pp 6936–6937 DOI: 10.1021/ja801618p Supporting Info

Liquid Phase Adsorption by Microporous Coordination Polymers: Removal of Organosulfur Compounds Katie A. Cychosz, Antek G. Wong-Foy and Adam J. Matzger pp 6938–6939 DOI: 10.1021/ja802121u Supporting Info

Mechanistic Insights into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity Yuanzhi Xia, Alexander S. Dudnik, Vladimir Gevorgyan and Yahong Li pp 6940–6941 DOI: 10.1021/ja802144t Supporting Info

Structure of a 129Xe-Cryptophane Biosensor Complexed with Human Carbonic Anhydrase II Julie A. Aaron, Jennifer M. Chambers, Kevin M. Jude, Luigi Di Costanzo, Ivan J. Dmochowski and David W. Christianson pp 6942–6943 DOI: 10.1021/ja802214x Supporting Info

Au(I)-Catalyzed Efficient Synthesis of Functionalized Bicyclo[3.2.0]heptanes Guotao Li, Xiaogen Huang and Liming Zhang pp 6944–6945 DOI: 10.1021/ja802294t Supporting Info

A New Entry to Cascade Organocatalysis: Reactions of Stable Sulfur Ylides and Nitroolefins Sequentially Catalyzed by Thiourea and DMAP Liang-Qiu Lu, Yi-Ju Cao, Xiao-Peng Liu, Jing An, Chang-Jiang Yao, Zhi-Hui Ming and Wen-Jing Xiao pp 6946–6948 DOI: 10.1021/ja800746q Supporting Info

Epitaxial Growth of Heterogeneous Metal Nanocrystals: From Gold Nano-octahedra to Palladium and Silver Nanocubes Feng-Ru Fan, De-Yu Liu, Yuan-Fei Wu, Sai Duan, Zhao-Xiong Xie, Zhi-Yuan Jiang and Zhong-Qun Tian pp 6949–6951 DOI: 10.1021/ja801566d Supporting Info

Fluorescence Self-Quenching of a Mannosylated Poly(p-phenyleneethynylene) Induced by Concanavalin A Ronnie L. Phillips, Ik-Bum Kim, Laren M. Tolbert and Uwe H. F. Bunz pp 6952–6954 DOI: 10.1021/ja802094s Supporting Info

Crystal Structure and the Paraelectric-to-Ferroelectric Phase Transition of Nanoscale BaTiO3 Millicent B. Smith, Katharine Page, Theo Siegrist, Peter L. Redmond, Erich C. Walter, Ram Seshadri, Louis E. Brus and Michael L. Steigerwald pp 6955–6963 DOI: 10.1021/ja0758436

Assembly of Bionanostructures onto β-Cyclodextrin Molecular Printboards for Antibody Recognition and Lymphocyte Cell Counting Manon J. W. Ludden, Xiao Li, Jan Greve, Aart van Amerongen, Maryana Escalante, Vinod Subramaniam, David N. Reinhoudt and Jurriaan Huskens pp 6964–6973 DOI: 10.1021/ja078109v Supporting Info

Architecturally Diverse Nanostructured Foldamers Reveal Insightful Photoinduced Single-Molecule Dynamics Jason J. Han, Andrew D. Shaller, Wei Wang and Alexander D. Q. Li pp 6974–6982 DOI: 10.1021/ja078302p Supporting Info

Super Crystal Structures of Octahedral c-In2O3 Nanocrystals Weigang Lu, Qingsheng Liu, Zhaoyong Sun, Jibao He, Chidi Ezeolu and Jiye Fang pp 6983–6991 DOI: 10.1021/ja078303h Supporting Info

H2 Storage Materials (22KJ/mol) Using Organometallic Ti Fragments as σ-H2 Binding Sites Ahmad Hamaed, Michel Trudeau and David M. Antonelli pp 6992–6999 DOI: 10.1021/ja710288g

A Unified Perspective on the Hydrogen Atom Transfer and Proton-Coupled Electron Transfer Mechanisms in Terms of Topographic Features of the Ground and Excited Potential Energy Surfaces As Exemplified by the Reaction between Phenol and Radicals Oksana Tishchenko, Donald G. Truhlar, Arnout Ceulemans and Minh Tho Nguyen pp 7000–7010 DOI: 10.1021/ja7102907 Supporting Info

Evidence of Reciprocal Reorientation of the Catalytic and Hemopexin-Like Domains of Full-Length MMP-12 Ivano Bertini, Vito Calderone, Marco Fragai, Rahul Jaiswal, Claudio Luchinat, Maxime Melikian, Efstratios Mylonas and Dmitri I. Svergun pp 7011–7021 DOI: 10.1021/ja710491y Supporting Info

Combined Quantum Mechanics/Molecular Mechanics Study on the Reversible Isomerization of Glucose and Fructose Catalyzed by Pyrococcus furiosus Phosphoglucose Isomerase Ruibo Wu, Hujun Xie, Zexing Cao and Yirong Mo pp 7022–7031 DOI: 10.1021/ja710633c Supporting Info

Ion Association in [bmim][PF6]/Naphthalene Mixtures: An Experimental and Computational Study M. G. Del Ppolo, C. L. Mullan, J. D. Holbrey, C. Hardacre and P. Ballone pp 7032–7041 DOI: 10.1021/ja710841n Supporting Info

Fluorescence Blinking, Exciton Dynamics, and Energy Transfer Domains in Single Conjugated Polymer Chains Hongzhen Lin, Seyed R. Tabaei, Daniel Thomsson, Oleg Mirzov, Per-Olof Larsson and Ivan G. Scheblykin pp 7042–7051 DOI: 10.1021/ja800153d

Photoluminescence of Perovskite Nanosheets Prepared by Exfoliation of Layered Oxides, K2Ln2Ti3O10, KLnNb2O7, and RbLnTa2O7 (Ln: Lanthanide Ion) Shintaro Ida, Chikako Ogata, Miharu Eguchi, W. Justin Youngblood, Thomas E. Mallouk and Yasumichi Matsumoto pp 7052–7059 DOI: 10.1021/ja7114772 Supporting Info

Isolation and Structure Elucidation of Parnafungins, Antifungal Natural Products that Inhibit mRNA Polyadenylation Craig A. Parish, Scott K. Smith, Kathleen Calati, Deborah Zink, Kenneth Wilson, Terry Roemer, Bo Jiang, Deming Xu, Gerald Bills, Gonzalo Platas, Fernando Pelez, Maria Teresa Dez, Nancy Tsou, Arlene E. McKeown, Richard G. Ball, Mary Ann Powles, Lai Yeung, Paul Liberator and Guy Harris pp 7060–7066 DOI: 10.1021/ja711209p Supporting Info

Probing Silver Nanoparticles During Catalytic H2 Evolution Getahun Merga, Laura C. Cass, Daniel M. Chipman and Dan Meisel pp 7067–7076 DOI: 10.1021/ja800306a Supporting Info

Chiral Inversion of Gold Nanoparticles Cyrille Gautier and Thomas Brgi pp 7077–7084 DOI: 10.1021/ja800256r Supporting Info

X-ray Diffraction Analysis of Photochromic Reaction of Fulgides: Crystalline State Reaction Induced by Two-Photon Excitation Jun Harada, Ryo Nakajima and Keiichiro Ogawa pp 7085–7091 DOI: 10.1021/ja800353u Supporting Info

Deep Tunneling Dominates the Biologically Important Hydride Transfer Reaction from NADH to FMN in Morphinone Reductase Jiayun Pang, Sam Hay, Nigel S. Scrutton and Michael J. Sutcliffe pp 7092–7097 DOI: 10.1021/ja800471f Supporting Info

Geometric and Electronic Structure Studies of the Binuclear Nonheme Ferrous Active Site of Toluene-4-monooxygenase: Parallels with Methane Monooxygenase and Insight into the Role of the Effector Proteins in O2 Activation Jennifer K. Schwartz, Pin-pin Wei, Kevin H. Mitchell, Brian G. Fox and Edward I. Solomon pp 7098–7109 DOI: 10.1021/ja800654d Supporting Info

Pore-Filling-Dependent Selectivity Effects in the Vapor-Phase Separation of Xylene Isomers on the Metal−Organic Framework MIL-47 Vincent Finsy, Harry Verelst, Luc Alaerts, Dirk De Vos, Pierre A. Jacobs, Gino V. Baron and Joeri F. M. Denayer pp 7110–7118 DOI: 10.1021/ja800686c Supporting Info

Molecular Clusters in Two-Dimensional Surface-Confined Nanoporous Molecular Networks: Structure, Rigidity, and Dynamics Shengbin Lei, Kazukuni Tahara, Xinliang Feng, Shuhei Furukawa, Frans C. De Schryver, Klaus Müllen, Yoshito Tobe and Steven De Feyter pp 7119–7129 DOI: 10.1021/ja800801e Supporting Info

Electron Dynamics in Charge-Transfer-to-Solvent States of Aqueous Chloride Revealed by Cl− 2p Resonant Auger-Electron Spectroscopy Bernd Winter, Emad F. Aziz, Niklas Ottosson, Manfred Faubel, Nobuhiro Kosugi and Ingolf V. Hertel pp 7130–7138 DOI: 10.1021/ja8009742 Supporting Info

Self-Assembling Behavior of Amphiphilic Dendron Coils in the Bulk Crystalline and Liquid Crystalline States Yeon-Wook Chung, Jeong-Kyu Lee, Wang-Cheol Zin and Byoung-Ki Cho pp 7139–7147 DOI: 10.1021/ja801163m Supporting Info

Asymmetric Total Synthesis of (−)-Quinocarcin Yan-Chao Wu, Mlanie Liron and Jieping Zhu pp 7148–7152 DOI: 10.1021/ja800662q Supporting Info

Fluorine for Hydrogen Exchange in the Hydrofluorobenzene Derivatives C6HxF(6-x), where x = 2, 3, 4 and 5 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: The Solid State Isomerization of [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,5-C6HF4) to [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,6-C6HF4) Evan L. Werkema and Richard A. Andersen pp 7153–7165 DOI: 10.1021/ja800639f Supporting Info

Photochemically Induced Dynamic Nuclear Polarization in a C450A Mutant of the LOV2 Domain of the Avena sativa Blue-Light Receptor Phototropin Gerald Richter, Stefan Weber, Werner Rmisch, Adelbert Bacher, Markus Fischer and Wolfgang Eisenreich p 7166 DOI: 10.1021/ja802468f Supporting Info

Issue 23

Origin of Mutational Effects at the C3 and G8 Positions on Hammerhead Ribozyme Catalysis from Molecular Dynamics Simulations Tai-Sung Lee and Darrin M. York pp 7168–7169 DOI: 10.1021/ja711242b Supporting Info

Electron Transfer Activation of Chromopyrrolic Acid by Cytochrome P450 En Route to the Formation of an Antitumor Indolocarbazole Derivative: Theory Supports Experiment Yong Wang, Hajime Hirao, Hui Chen, Hiroyasu Onaka, Shingo Nagano and Sason Shaik pp 7170–7171 DOI: 10.1021/ja711426y Supporting Info

Structural and Dynamical Characterization of Fibrils from a Disease-Associated Alanine Expansion Domain Using Proteolysis and Solid-State NMR Spectroscopy Mirko Sackewitz, Holger A. Scheidt, Grit Lodderstedt, Angelika Schierhorn, Elisabeth Schwarz and Daniel Huster pp 7172–7173 DOI: 10.1021/ja800120s Supporting Info

A Donor−Acceptor Molecular Dyad Showing Multiple Electronic Energy-Transfer Processes in Crystalline and Amorphous States Andrew C. Benniston, Graeme Copley, Anthony Harriman, Dorota B. Rewinska, Ross W. Harrington and William Clegg pp 7174–7175 DOI: 10.1021/ja800387d Supporting Info

Enhancement of Photocatalytic H2 Evolution on CdS by Loading MoS2 as Cocatalyst under Visible Light Irradiation Xu Zong, Hongjian Yan, Guopeng Wu, Guijun Ma, Fuyu Wen, Lu Wang and Can Li pp 7176–7177 DOI: 10.1021/ja8007825 Supporting Info

Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of trans-Vinylcyclopropane-enes Lei Jiao, Siyu Ye and Zhi-Xiang Yu pp 7178–7179 DOI: 10.1021/ja8008715 Supporting Info

Structural Transformation due to Co-Host Inclusion in Ionic Clathrate Hydrates Kyuchul Shin, Sukjeong Choi, Jong-Ho Cha and Huen Lee pp 7180–7181 DOI: 10.1021/ja800873a Supporting Info

Two Color RNA Intercalating Probe for Cell Imaging Applications Nathan Stevens, Naphtali O’Connor, Harshad Vishwasrao, Diana Samaroo, Eric R. Kandel, Daniel L. Akins, Charles M. Drain and Nicholas J. Turro pp 7182–7183 DOI: 10.1021/ja8008924 Supporting Info

Solution Structure of HIV-1 Protease Flaps Probed by Comparison of Molecular Dynamics Simulation Ensembles and EPR Experiments Fangyu Ding, Melinda Layten and Carlos Simmerling pp 7184–7185 DOI: 10.1021/ja800893d Supporting Info

The C−O Stretch as an Unprecedently Large Spectral Marker for the Electron Transfer between Copper(II) and a Phenolate Anion Petr Milko, Jana Roithov, Nikos Tsierkezos and Detlef Schrder pp 7186–7187 DOI: 10.1021/ja801079r Supporting Info

Combined Raman Spectroscopy and Transmission Electron Microscopy Studies of a NanoBud Structure Ying Tian, Delphine Chassaing, Albert G. Nasibulin, Paola Ayala, Hua Jiang, Anton S. Anisimov and Esko I. Kauppinen pp 7188–7189 DOI: 10.1021/ja801120u Supporting Info

Pd(II)-Catalyzed Cross-Coupling of sp3 C−H Bonds with sp2 and sp3 Boronic Acids Using Air as the Oxidant Dong-Hui Wang, Masayuki Wasa, Ramesh Giri and Jin-Quan Yu pp 7190–7191 DOI: 10.1021/ja801355s Supporting Info

Spiro-Bridged Ladder-Type Poly(p-phenylene)s: Towards Structurally Perfect Light-Emitting Materials Yonggang Wu, Jianyuan Zhang, Zhuping Fei and Zhishan Bo pp 7192–7193 DOI: 10.1021/ja801422n Supporting Info

Control of up to Five Stereocenters in a Cascade Reaction: Synthesis of Highly Functionalized Five-Membered Rings Hao Li and Teck-Peng Loh pp 7194–7195 DOI: 10.1021/ja801488z Supporting Info

Spontaneous Formation and Electrogenerated Chemiluminescence of Tris(bipyridine) Ru(II) Derivative Nanobelts Jiaguo Yu, Fu-Ren F. Fan, Shanlin Pan, Vincent M. Lynch, Khalid M. Omer and Allen J. Bard pp 7196–7197 DOI: 10.1021/ja801342v Supporting Info

Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions Sarah E. Reisman, Abigail G. Doyle and Eric N. Jacobsen pp 7198–7199 DOI: 10.1021/ja801514m Supporting Info

Is Osmium Diboride An Ultra-Hard Material? Jun Yang, Hong Sun and Changfeng Chen pp 7200–7201 DOI: 10.1021/ja801520v Supporting Info

Chiral Phosphine-Catalyzed Enantioselective Construction of γ-Butenolides Through Substitution of Morita−Baylis−Hillman Acetates with 2-Trimethylsilyloxy Furan Ying-Qing Jiang, Yong-Ling Shi and Min Shi pp 7202–7203 DOI: 10.1021/ja802422d Supporting Info

Redox-Assisted Ring Closing Reaction of the Photogenerated Cyclophanediene Form of Bis(ferrocenyl)dimethyldihydropyrene with Interferrocene Electronic Communication Switching Satoshi Muratsugu, Shoko Kume and Hiroshi Nishihara pp 7204–7205 DOI: 10.1021/ja8016494 Supporting Info

An EPR and NMR Study of Supramolecular Effects on Paramagnetic Interaction between a Nitroxide Incarcerated within a Nanocapsule with a Nitroxide in Bulk Aqueous Media Judy Y.-C. Chen, Nithyanandhan Jayaraj, Steffen Jockusch, M. Francesca Ottaviani, V. Ramamurthy and Nicholas J. Turro pp 7206–7207 DOI: 10.1021/ja801667w Supporting Info

Chiral Pyranoside Phosphite−Oxazolines: A New Class of Ligand for Asymmetric Catalytic Hydrogenation of Alkenes Montserrat Diguez, Javier Mazuela, Oscar Pmies, J. Johan Verendel and Pher G. Andersson pp 7208–7209 DOI: 10.1021/ja801706s Supporting Info

Facile Concerted Proton−Electron Transfers in a Ruthenium Terpyridine-4′-Carboxylate Complex with a Long Distance Between the Redox and Basic Sites Virginia W. Manner, Antonio G. DiPasquale and James M. Mayer pp 7210–7211 DOI: 10.1021/ja801672w Supporting Info

Direct NMR Detection of the Binding of Functional Ligands to the Human Sweet Receptor, a Heterodimeric Family 3 GPCR Fariba M. Assadi-Porter, Marco Tonelli, Emeline Maillet, Klaas Hallenga, Outhiriaradjou Benard, Marianna Max and John L. Markley pp 7212–7213 DOI: 10.1021/ja8016939 Supporting Info

Gas-Phase Carbene Radical Anions: New Mechanistic Insights Stephanie M. Villano, Nicole Eyet, W. Carl Lineberger and Veronica M. Bierbaum pp 7214–7215 DOI: 10.1021/ja801819b

Two-Step Laser Mass Spectrometry of Asphaltenes Andrew E. Pomerantz, Matthew R. Hammond, Amy L. Morrow, Oliver C. Mullins and Richard N. Zare pp 7216–7217 DOI: 10.1021/ja801927v Supporting Info

A Path Sampling Study of Ru-Hydride-Catalyzed H2 Hydrogenation of Ethylene Christopher N. Rowley and Tom K. Woo pp 7218–7219 DOI: 10.1021/ja802219a Supporting Info

A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins Baoguo Zhao, Haifeng Du and Yian Shi pp 7220–7221 DOI: 10.1021/ja802242h Supporting Info

Unified Strategy for the Synthesis of the “Miscellaneous” Lycopodium Alkaloids: Total Synthesis of (±)-Lyconadin A Alakesh Bisai, Scott P. West and Richmond Sarpong pp 7222–7223 DOI: 10.1021/ja8028069 Supporting Info

Carbohydrate Monolayer Strategy for Electrochemical Assay of Cell Surface Carbohydrate Lin Ding, Wei Cheng, Xiaojian Wang, Shijia Ding and Huangxian Ju pp 7224–7225 DOI: 10.1021/ja801468b Supporting Info

Directed Assembly of Single-Walled Carbon Nanotubes via Drop-Casting onto a UV-Patterned Photosensitive Monolayer Julie A. Bardecker, Ali Afzali, George S. Tulevski, Teresita Graham, James B. Hannon and Alex K.-Y. Jen pp 7226–7227 DOI: 10.1021/ja802407f Supporting Info

Mechanistic Study of Samarium Diiodide-HMPA Initiated 5-exo-trig Ketyl−Olefin Coupling: The Role of HMPA in Post-Electron Transfer Steps Dhandapani V. Sadasivam, P. K. Sudhadevi Antharjanam, Edamana Prasad and Robert A. Flowers,, pp 7228–7229 DOI: 10.1021/ja802448x Supporting Info

Efficient Utilization of Nanospace of Layered Transition Metal Oxide HNbMoO6 as a Strong, Water-Tolerant Solid Acid Catalyst Caio Tagusagawa, Atsushi Takagaki, Shigenobu Hayashi and Kazunari Domen pp 7230–7231 DOI: 10.1021/ja802478d Supporting Info

Ribosomal Synthesis of Bicyclic Peptides via Two Orthogonal Inter-Side-Chain Reactions Yusuke Sako, Jumpei Morimoto, Hiroshi Murakami and Hiroaki Suga pp 7232–7234 DOI: 10.1021/ja800953c Supporting Info

The Catalytic Mechanism of an Aspartic Proteinase Explored with Neutron and X-ray Diffraction Leighton Coates, Han-Fang Tuan, Stephen Tomanicek, Andrey Kovalevsky, Marat Mustyakimov, Peter Erskine and Jon Cooper pp 7235–7237 DOI: 10.1021/ja801269x Supporting Info

π-Donor BETS Based Bifunctional Superconductor with Polymeric Dicyanamidomanganate(II) Anion Layer: κ-(BETS)2Mn[N(CN)2]3 Nataliya D. Kushch, Eduard B. Yagubskii, Mark V. Kartsovnik, Lev I. Buravov, Alexander D. Dubrovskii, Anatolii N. Chekhlov and Werner Biberacher pp 7238–7240 DOI: 10.1021/ja801841q Supporting Info

Synthesis of (+)-Cortistatin A Ryan A. Shenvi, Carlos A. Guerrero, Jun Shi, Chuang-Chuang Li and Phil S. Baran pp 7241–7243 DOI: 10.1021/ja8023466 Supporting Info

A Photoelectron Spectroscopic and Theoretical Study of B16− and B162−: An All-Boron Naphthalene Alina P. Sergeeva, Dmitry Yu. Zubarev, Hua-Jin Zhai, Alexander I. Boldyrev and Lai-Sheng Wang pp 7244–7246 DOI: 10.1021/ja802494z Supporting Info

1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization Ke Chen, Jeremy M. Richter and Phil S. Baran pp 7247–7249 DOI: 10.1021/ja802491q Supporting Info

Crystal Clear Structural Evidence for Electron Delocalization in 1,2-Dihydro-1,2-azaborines Eric R. Abbey, Lev N. Zakharov and Shih-Yuan Liu pp 7250–7252 DOI: 10.1021/ja8024966 Supporting Info

Total Synthesis of Cytotoxic Macrolide Amphidinolide B1 and the Proposed Structure of Amphidinolide B2 Liang Lu, Wei Zhang and Rich G. Carter pp 7253–7255 DOI: 10.1021/ja803012n Supporting Info

Identification of the Binding of Sceptrin to MreB via a Bidirectional Affinity Protocol Abimael D. Rodrguez, Martin J. Lear and James J. La Clair pp 7256–7258 DOI: 10.1021/ja7114019 Supporting Info

Theory and Practice of Enzyme Bioaffinity Electrodes. Direct Electrochemical Product Detection Benot Limoges, Damien Marchal, François Mavré, Jean-Michel Savéant and Bernd Schöllhorn pp 7259–7275 DOI: 10.1021/ja7102845

Theory and Practice of Enzyme Bioaffinity Electrodes. Chemical, Enzymatic, and Electrochemical Amplification of in Situ Product Detection Benoît Limoges, Damien Marchal, François Mavré and Jean-Michel Savéant pp 7276–7285 DOI: 10.1021/ja7102873

Triplet Pathways in Diarylethene Photochromism: Photophysical and Computational Study of Dyads Containing Ruthenium(II) Polypyridine and 1,2-Bis(2-methylbenzothiophene-3-yl)maleimide Units Maria Teresa Indelli, Stefano Carli, Marco Ghirotti, Claudio Chiorboli, Marcella Ravaglia, Marco Garavelli and Franco Scandola pp 7286–7299 DOI: 10.1021/ja711173z Supporting Info

Adsorption-Induced Intramolecular Dipole: Correlating Molecular Conformation and Interface Electronic Structure Norbert Koch, Alexander Gerlach, Steffen Duhm, Hendrik Glowatzki, Georg Heimel, Antje Vollmer, Yoichi Sakamoto, Toshiyasu Suzuki, Jörg Zegenhagen, Jürgen P. Rabe and Frank Schreiber pp 7300–7304 DOI: 10.1021/ja800286k Supporting Info

Solid-State Nuclear Magnetic Resonance Spectroscopy Studies of Furanose Ring Dynamics in the DNA HhaI Binding Site Gary A. Meints, Paul A. Miller, Kari Pederson, Zahra Shajani and Gary Drobny pp 7305–7314 DOI: 10.1021/ja075775n

Nanoparticle-Loaded Magnetophoretic Vesicles Maren Krack, Heinrich Hohenberg, Andreas Kornowski, Peter Lindner, Horst Weller and Stephan Frster pp 7315–7320 DOI: 10.1021/ja077398k Supporting Info

Large Entropy Difference between Terrace and Step Sites on Surfaces David E. Starr and Charles T. Campbell pp 7321–7327 DOI: 10.1021/ja077540h

Diastereoselective Nickel-Catalyzed Reductive Aldol Cyclizations Using Diethylzinc as the Stoichiometric Reductant: Scope and Mechanistic Insight Pekka M. Joensuu, Gordon J. Murray, Euan. A. F. Fordyce, Thomas Luebbers and Hon Wai Lam pp 7328–7338 DOI: 10.1021/ja0775624 Supporting Info

Are N,N-Dihydrodiazatetracene Derivatives Antiaromatic? Shaobin Miao, Scott M. Brombosz, Paul v. R. Schleyer, Judy I. Wu, Stephen Barlow, Seth R. Marder, Kenneth I. Hardcastle and Uwe H. F. Bunz pp 7339–7344 DOI: 10.1021/ja077614p Supporting Info

On the Functional Role of a Water Molecule in Clade 3 Catalases: A Proposal for the Mechanism by Which NADPH Prevents the Formation of Compound II Willi Sicking, Hans-Gert Korth, Herbert de Groot and Reiner Sustmann pp 7345–7356 DOI: 10.1021/ja077787e Supporting Info

Microscale NMR Screening of New Detergents for Membrane Protein Structural Biology Qinghai Zhang, Reto Horst, Michael Geralt, Xingquan Ma, Wen-Xu Hong, M. G. Finn, Raymond C. Stevens and Kurt Wthrich pp 7357–7363 DOI: 10.1021/ja077863d Supporting Info

Effects of Trimethylamine N-Oxide (TMAO) and Crowding Agents on the Stability of RNA Hairpins David L. Pincus, Changbong Hyeon and D. Thirumalai pp 7364–7372 DOI: 10.1021/ja078326w Supporting Info

From Triazines to Heptazines: Deciphering the Local Structure of Amorphous Nitrogen-Rich Carbon Nitride Materials James R. Holst and Edward G. Gillan pp 7373–7379 DOI: 10.1021/ja709992s Supporting Info

Role of Backbone−Solvent Interactions in Determining Conformational Equilibria of Intrinsically Disordered Proteins Hoang T. Tran, Albert Mao and Rohit V. Pappu pp 7380–7392 DOI: 10.1021/ja710446s Supporting Info

Singling out the Electrochemistry of Individual Single-Walled Carbon Nanotubes in Solution Demis Paolucci, Manuel Melle Franco, Matteo Iurlo, Massimo Marcaccio, Maurizio Prato, Francesco Zerbetto, Alain Pnicaud and Francesco Paolucci pp 7393–7399 DOI: 10.1021/ja710625p Supporting Info

Positioning Lipid Membrane Domains in Giant Vesicles by Micro-organization of Aqueous Cytoplasm Mimic Ann-Sofie Cans, Meghan Andes-Koback and Christine D. Keating pp 7400–7406 DOI: 10.1021/ja710746d Supporting Info

Insight into Substrate Binding in Shibasaki’s Li3(THF)n(BINOLate)3Ln Complexes and Implications in Catalysis Alfred J. Wooten, Patrick J. Carroll and Patrick J. Walsh pp 7407–7419 DOI: 10.1021/ja7107933 Supporting Info

Magnetic Structure of the Large-Spin Mn10 and Mn19 Complexes: A Theoretical Complement to an Experimental Milestone Eliseo Ruiz, Thomas Cauchy, Joan Cano, Ruben Costa, Javier Tercero and Santiago Alvarez pp 7420–7426 DOI: 10.1021/ja800092s Supporting Info

Solid-State NMR Spectroscopy Applied to a Chimeric Potassium Channel in Lipid Bilayers Robert Schneider, Christian Ader, Adam Lange, Karin Giller, Sönke Hornig, Olaf Pongs, Stefan Becker and Marc Baldus pp 7427–7435 DOI: 10.1021/ja800190c Supporting Info

Electrochemical Recognition of Synthetic Heparin Mimetic at Liquid/Liquid Microinterfaces Patrick J. Rodgers, Ping Jing, Yushin Kim and Shigeru Amemiya pp 7436–7442 DOI: 10.1021/ja800568q Supporting Info

Surface-Enhanced Resonance Raman Spectroscopic Characterization of the Protein Native Structure Manliang Feng and Hiroyasu Tachikawa pp 7443–7448 DOI: 10.1021/ja8006337 Supporting Info

Organometallic Enantiomeric Scaffolding: General Access to 2-Substituted Oxa- and Azabicyclo[3.2.1]octenes via a Brønsted Acid Catalyzed [5 + 2] Cycloaddition Reaction Ethel C. Garnier and Lanny S. Liebeskind pp 7449–7458 DOI: 10.1021/ja800664v Supporting Info

Is Fullerene C60 Large Enough to Host a Multiply Bonded Dimetal? Ivan Infante, Laura Gagliardi and Gustavo E. Scuseria pp 7459–7465 DOI: 10.1021/ja800847j Supporting Info

Chemical Synthesis of the GHIJKLMNO Ring System of Maitotoxin K. C. Nicolaou, Michael O. Frederick, Antonio C. B. Burtoloso, Ross M. Denton, Fatima Rivas, Kevin P. Cole, Robert J. Aversa, Romelo Gibe, Taiki Umezawa and Takahiro Suzuki pp 7466–7476 DOI: 10.1021/ja801139f Supporting Info

Dynamic Effects on Reaction Rates in a Michael Addition Catalyzed by Chalcone Isomerase. Beyond the Frozen Environment Approach J. Javier Ruiz-Perna, Iaki Tun, Vicente Moliner, James T. Hynes and Maite Roca pp 7477–7488 DOI: 10.1021/ja801156y

Expanding the Realm of Ultrafast Protein Folding: gpW, a Midsize Natural Single-Domain with α+β Topology that Folds Downhill Adam Fung, Peng Li, Raquel Godoy-Ruiz, Jose M. Sanchez-Ruiz and Victor Muoz pp 7489–7495 DOI: 10.1021/ja801401a

Spontaneous Generation of Amphiphilic Block Copolymer Micelles with Multiple Morphologies through Interfacial Instabilities Jintao Zhu and Ryan C. Hayward pp 7496–7502 DOI: 10.1021/ja801268e Supporting Info

Nanomechanical Function from Self-Organizable Dendronized Helical Polyphenylacetylenes Virgil Percec, Jonathan G. Rudick, Mihai Peterca and Paul A. Heiney pp 7503–7508 DOI: 10.1021/ja801863e Supporting Info

Synthetic Collagen Heterotrimers: Structural Mimics of Wild-Type and Mutant Collagen Type I Varun Gauba and Jeffrey D. Hartgerink pp 7509–7515 DOI: 10.1021/ja801670v Supporting Info

Software Review of UN-SCAN-IT: Graph Digitizing Software R. Alan May and Keith J. Stevenson p 7516 DOI: 10.1021/ja803067d

Issue 24

AuAdatomsinSelf-AssemblyofBenzenethiolontheAu(111)Surface Peter Maksymovych and John T. Yates, pp 7518–7519 DOI: 10.1021/ja800577w Supporting Info

Edge-Directed Dynamic Covalent Synthesis of a Chiral Nanocube Di Xu and Ralf Warmuth pp 7520–7521 DOI: 10.1021/ja800803c Supporting Info

Stable Aqueous ZnO@Polymer Core−Shell Nanoparticles with Tunable Photoluminescence and Their Application in Cell Imaging Huan-Ming Xiong, Yang Xu, Qing-Guang Ren and Yong-Yao Xia pp 7522–7523 DOI: 10.1021/ja800999u Supporting Info

A Stepwise Mechanism for the Mechanochemical Synthesis of Halogen-Bonded Cocrystal Architectures Dominik Cini, Tomislav Frii and William Jones pp 7524–7525 DOI: 10.1021/ja801164v Supporting Info

Entrainer Effect on Photochirogenesis in Near- and Supercritical Carbon Dioxide: Dramatic Enhancement of Enantioselectivity Yasuhiro Nishiyama, Takehiko Wada, Sadayuki Asaoka, Tadashi Mori, Taylor A. McCarty, Nadine D. Kraut, Frank V. Bright and Yoshihisa Inoue pp 7526–7527 DOI: 10.1021/ja801254z Supporting Info

Vapor Phase Self-Assembly of Molecular Gate Dielectrics for Thin Film Transistors Sara A. DiBenedetto, David Frattarelli, Mark A. Ratner, Antonio Facchetti and Tobin J. Marks pp 7528–7529 DOI: 10.1021/ja801309g Supporting Info

Targeting Abasic Sites and Single Base Bulges in DNA with Metalloinsertors Brian M. Zeglis, Jennifer A. Boland and Jacqueline K. Barton pp 7530–7531 DOI: 10.1021/ja801479y Supporting Info

Catalytic Enantioselective [2 + 4] and [2 + 2] Cycloaddition Reactions with Propiolamides Kazuaki Ishihara and Makoto Fushimi pp 7532–7533 DOI: 10.1021/ja8015318 Supporting Info

Silyl-Directed, Iridium-Catalyzed ortho-Borylation of Arenes. A One-Pot ortho-Borylation of Phenols, Arylamines, and Alkylarenes Timothy A. Boebel and John. F. Hartwig pp 7534–7535 DOI: 10.1021/ja8015878 Supporting Info

Liquid Crystalline Phase of G-Tetrad DNA for NMR Study of Detergent-Solubilized Proteins Justin Lorieau, Lishan Yao and Ad Bax pp 7536–7537 DOI: 10.1021/ja801729f Supporting Info

Axial Donating Ligands: A New Strategy for Late Transition Metal Olefin Polymerization Catalysis Dennis H. Leung, Joseph W. Ziller and Zhibin Guan pp 7538–7539 DOI: 10.1021/ja8017847 Supporting Info

Probing the Bottom of a Folding Funnel Using Conformationally Gated Electron Transfer Reactions Swati Bandi and Bruce E. Bowler pp 7540–7541 DOI: 10.1021/ja801941r Supporting Info

Ultrasmall c(RGDyK)-Coated Fe3O4 Nanoparticles and Their Specific Targeting to Integrin αvβ3-Rich Tumor Cells Jin Xie, Kai Chen, Ha-Young Lee, Chenjie Xu, Andrew R. Hsu, Sheng Peng, Xiaoyuan Chen and Shouheng Sun pp 7542–7543 DOI: 10.1021/ja802003h Supporting Info

Wireless Electrochemical DNA Microarray Sensor Kwok-Fan Chow, Franois Mavr and Richard M. Crooks pp 7544–7545 DOI: 10.1021/ja802013q Supporting Info

Surprisingly Long-Lived Ascorbyl Radicals in Acetonitrile: Concerted Proton−Electron Transfer Reactions and Thermochemistry Jeffrey J. Warren and James M. Mayer pp 7546–7547 DOI: 10.1021/ja802055t Supporting Info

Rates of Spontaneous Cleavage of Glucose, Fructose, Sucrose, and Trehalose in Water, and the Catalytic Proficiencies of Invertase and Trehalas Richard Wolfenden and Yang Yuan pp 7548–7549 DOI: 10.1021/ja802206s Supporting Info

Molecular Complexation and Binding Studied by Electrophoretic NMR Spectroscopy Fredrik Hallberg, Christoph F. Weise, Pavel V. Yushmanov, Erik Thyboll Pettersson, Peter Stilbs and Istvn Fur pp 7550–7551 DOI: 10.1021/ja8023324 Supporting Info

Pyrylogens: Synthesis, Structural, Electrochemical, and Photophysical Characterization of a New Class of Electron Transfer Sensitizers Edward L. Clennan, Chen Liao and Erambo Ayokosok pp 7552–7553 DOI: 10.1021/ja802343v Supporting Info

Myxochelin Biosynthesis: Direct Evidence for Two- and Four-Electron Reduction of a Carrier Protein-Bound Thioester Yanyan Li, Kira J. Weissman and Rolf Mller pp 7554–7555 DOI: 10.1021/ja8025278 Supporting Info

Asymmetric Imino Aza-enamine Reaction Catalyzed by Axially Chiral Dicarboxylic Acid: Use of Arylaldehyde N,N-Dialkylhydrazones as Acyl Anion Equivalent Takuya Hashimoto, Maya Hirose and Keiji Maruoka pp 7556–7557 DOI: 10.1021/ja802704j Supporting Info

Ring-Opening Reactions of Aromatic N-Heterocycles by Scandium and Yttrium Alkyl Complexes Colin T. Carver and Paula L. Diaconescu pp 7558–7559 DOI: 10.1021/ja802728k Supporting Info

Stereocontrolled Synthesis of Z-Dienes via an Unexpected Pericyclic Cascade Rearrangement of 5-Amino-2,4-pentadienals Sarah E. Steinhardt, Joel S. Silverston and Christopher D. Vanderwal pp 7560–7561 DOI: 10.1021/ja8028125 Supporting Info

Total Synthesis of the Securinega Alkaloid (−)-Secu’amamine A Peng Liu, Sungwoo Hong and Steven M. Weinreb pp 7562–7563 DOI: 10.1021/ja802700z Supporting Info

The Mechanism of 1,4 Alkyl Group Migration in Hypervalent Halonium Ylides: The Stereochemical Course Robert M. Moriarty, Sachin Tyagi, Daniela Ivanov and Mircea Constantinescu pp 7564–7565 DOI: 10.1021/ja802735f Supporting Info

Total Synthesis of (−)-Corilagin Hidetoshi Yamada, Kohei Nagao, Kazutoyo Dokei, Yusuke Kasai and Naoki Michihata pp 7566–7567 DOI: 10.1021/ja803111z Supporting Info

Total Synthesis of (±)-Actinophyllic Acid Connor L. Martin, Larry E. Overman and Jason M. Rohde pp 7568–7569 DOI: 10.1021/ja803158y Supporting Info

Modular Construction of Oxide StructuresCompositional Control of Transition Metal Coordination Environments Christophe Tenailleau, Mathieu Allix, John B. Claridge, Maryvonne Hervieu, Michael F. Thomas, James P. Hirst and Matthew J. Rosseinsky pp 7570–7583 DOI: 10.1021/ja077762f Supporting Info

Conformation-Dependent Ligand Regulation of ATP Hydrolysis by Human KSP: Activation of Basal Hydrolysis and Inhibition of Microtubule-Stimulated Hydrolysis by a Single, Small Molecule Modulator Lusong Luo, Jeffrey D. Carson, Kathleen S. Molnar, Steven J. Tuske, Stephen J. Coales, Yoshitomo Hamuro, Chiu-mei Sung, Valery Sudakin, Kurt R. Auger, Dashyant Dhanak, Jeffrey R. Jackson, Pearl S. Huang, Peter J. Tummino and Robert A. Copeland pp 7584–7591 DOI: 10.1021/ja710889h Supporting Info

Ni(II) and Co(II) Sensing by Escherichia coli RcnR Jeffrey S. Iwig, Sharon Leitch, Robert W. Herbst, Michael J. Maroney and Peter T. Chivers pp 7592–7606 DOI: 10.1021/ja710067d Supporting Info

Electronic Excitations and Spectra in Single-Stranded DNA Stefano Tonzani and George C. Schatz pp 7607–7612 DOI: 10.1021/ja7103894 Supporting Info

Intrinsically Chiral Aromaticity. Rules Incorporating Linking Number, Twist, and Writhe for Higher-Twist Mbius Annulenes Shay M. Rappaport and Henry S. Rzepa pp 7613–7619 DOI: 10.1021/ja710438j Supporting Info

Coordination-Driven Face-Directed Self-Assembly of Trigonal Prisms. Face-Based Conformational Chirality Douglas C. Caskey, Takuya Yamamoto, Chris Addicott, Richard K. Shoemaker, Jaroslav Vacek, Adam M. Hawkridge, David C. Muddiman, Gregg S. Kottas, Josef Michl and Peter J. Stang pp 7620–7628 DOI: 10.1021/ja710715e Supporting Info

Pyridine Ligand Rotation in Self-Assembled Trigonal Prisms. Evidence for Intracage Solvent Vapor Bubbles Jaroslav Vacek, Douglas C. Caskey, Dominik Horinek, Richard K. Shoemaker, Peter J. Stang and Josef Michl pp 7629–7638 DOI: 10.1021/ja801341m Supporting Info

Characterization of a Three-Component Coupling Reaction on Proteins by Isotopic Labeling and Nuclear Magnetic Resonance Spectroscopy Jesse M. McFarland, Neel S. Joshi and Matthew B. Francis pp 7639–7644 DOI: 10.1021/ja710927q Supporting Info

Experimental Evidence for an Inverse Hydrogen Migration in Arginine Radicals Shigeo Hayakawa, Hiroshi Matsubara, Subhasis Panja, Preben Hvelplund, Steen Brøndsted Nielsen, Xiaohong Chen and Frantiek Tureek pp 7645–7654 DOI: 10.1021/ja800207x Supporting Info

Opposite Stereochemical Courses for Enzyme-Mediated Alkene Reductions of an Enantiomeric Substrate Pair Despina J. Bougioukou and Jon D. Stewart pp 7655–7658 DOI: 10.1021/ja800200r Supporting Info

Unexpectedly Similar Charge Transfer Rates through Benzo-Annulated Bicyclo[2.2.2]octanes Randall H. Goldsmith, Josh Vura-Weis, Amy M. Scott, Sachin Borkar, Ayusman Sen, Mark A. Ratner and Michael R. Wasielewski pp 7659–7669 DOI: 10.1021/ja8004623 Supporting Info

Synthesis, Characterization, and Transistor Response of Semiconducting Silole Polymers with Substantial Hole Mobility and Air Stability. Experiment and Theory Gang Lu, Hakan Usta, Chad Risko, Lian Wang, Antonio Facchetti, Mark A. Ratner and Tobin J. Marks pp 7670–7685 DOI: 10.1021/ja800424m Supporting Info

Structures and Charging of α-Alumina (0001)/Water Interfaces Studied by Sum-Frequency Vibrational Spectroscopy Luning Zhang, Chuanshan Tian, Glenn A. Waychunas and Y. Ron Shen pp 7686–7694 DOI: 10.1021/ja8011116

Ultrafast Dynamics and Anionic Active States of the Flavin Cofactor in Cryptochrome and Photolyase Ya-Ting Kao, Chuang Tan, Sang-Hun Song, Nuri ztürk, Jiang Li, Lijuan Wang, Aziz Sancar and Dongping Zhong pp 7695–7701 DOI: 10.1021/ja801152h

Poly(diiododiacetylene): Preparation, Isolation, and Full Characterization of a Very Simple Poly(diacetylene) Liang Luo, Christopher Wilhelm, Aiwu Sun, Clare P. Grey, Joseph W. Lauher and Nancy S. Goroff pp 7702–7709 DOI: 10.1021/ja8011403 Supporting Info

Synthetic Control of the Pore Dimension and Surface Area in Conjugated Microporous Polymer and Copolymer Networks Jia-Xing Jiang, Fabing Su, Abbie Trewin, Colin D. Wood, Hongjun Niu, James T. A. Jones, Yaroslav Z. Khimyak and Andrew I. Cooper pp 7710–7720 DOI: 10.1021/ja8010176 Supporting Info

Compositional and Electric Field Dependence of the Dissociation of Charge Transfer Excitons in Alternating Polyfluorene Copolymer/Fullerene Blends Dirk Veldman, zlem pek, Stefan C. J. Meskers, Jrgen Sweelssen, Marc M. Koetse, Sjoerd C. Veenstra, Jan M. Kroon, Svetlana S. van Bavel, Joachim Loos and Ren A. J. Janssen pp 7721–7735 DOI: 10.1021/ja8012598 Supporting Info

Bifunctional CD22 Ligands Use Multimeric Immunoglobulins as Protein Scaffolds in Assembly of Immune Complexes on B Cells Mary K. O’Reilly, Brian E. Collins, Shoufa Han, Liang Liao, Cory Rillahan, Pavel I. Kitov, David R. Bundle and James C. Paulson pp 7736–7745 DOI: 10.1021/ja802008q Supporting Info

Insights into the Structural Specificity of the Cytotoxicity of 3-Deoxyphosphatidylinositols Yanling K. Wang, Wei Chen, Derek Blair, Mingming Pu, Yingju Xu, Scott J. Miller, Alfred G. Redfield, Thomas C. Chiles and Mary F. Roberts pp 7746–7755 DOI: 10.1021/ja710348r

Bonding of Seven Carbonyl Groups to a Single Metal Atom: Theoretical Study of M(CO)n (M = Ti, Zr, Hf; n = 7, 6, 5, 4) Qiong Luo, Qian-Shu Li, Zhong Heng Yu, Yaoming Xie, R. Bruce King and Henry F. Schaefer, pp 7756–7765 DOI: 10.1021/ja8003655 Supporting Info

Cu2+ Binding Modes of Recombinant α-Synuclein − Insights from EPR Spectroscopy Simon C. Drew, Su Ling Leong, Chi L. L. Pham, Deborah J. Tew, Colin L. Masters, Luke A. Miles, Roberto Cappai and Kevin J. Barnham pp 7766–7773 DOI: 10.1021/ja800708x Supporting Info

Book Review of Tomorrows Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry p 7774 DOI: 10.1021/ja802762w

Book Review of Organic Reactions, Volume 70 p 7774 DOI: 10.1021/ja803031j

Issue 25

Tunneling in C−H Oxidation Reactions by an Oxoiron(IV) Porphyrin Radical Cation: Direct Measurements of Very Large H/D Kinetic Isotope Effects Zhengzheng Pan, John H. Horner and Martin Newcomb pp 7776–7777 DOI: 10.1021/ja802484n Supporting Info

Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies Bo Zheng, Hao Dong, Junfeng Bai, Yizhi Li, Shuhua Li and Manfred Scheer pp 7778–7779 DOI: 10.1021/ja800439p Supporting Info

Pristine Simple Oxides as Visible Light Driven Photocatalysts: Highly Efficient Decomposition of Organic Compounds over Platinum-Loaded Tungsten Oxide Ryu Abe, Hitoshi Takami, Naoya Murakami and Bunsho Ohtani pp 7780–7781 DOI: 10.1021/ja800835q Supporting Info

Cooperative Catalysis with Chiral Brønsted Acid-Rh2(OAc)4: Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines Wenhao Hu, Xinfang Xu, Jing Zhou, Wei-Jun Liu, Haoxi Huang, Juan Hu, Liping Yang and Liu-Zhu Gong pp 7782–7783 DOI: 10.1021/ja801755z Supporting Info

Trapping and Structural Elucidation of a Very Advanced Intermediate in the Lesion-Extrusion Pathway of hOGG1 Seongmin Lee, Christopher T. Radom and Gregory L. Verdine pp 7784–7785 DOI: 10.1021/ja800821t Supporting Info

Iridium Corroles Joshua H. Palmer, Michael W. Day, Aaron D. Wilson, Lawrence M. Henling, Zeev Gross and Harry B. Gray pp 7786–7787 DOI: 10.1021/ja801049t Supporting Info

When Things Are Not as They Seem: Quantum Interference Turns Molecular Electron Transfer “Rules” Upside Down Gemma C. Solomon, David Q. Andrews, Richard P. Van Duyne and Mark A. Ratner pp 7788–7789 DOI: 10.1021/ja801379b Supporting Info

Quantum Size Effect Directed Selective Self-Assembling of Cobalt Phthalocyanine on Pb(111) Thin Films Peng Jiang, Xucun Ma, Yanxiao Ning, Canli Song, Xi Chen, Jin-Feng Jia and Qi-Kun Xue pp 7790–7791 DOI: 10.1021/ja801255w

Manganese-Catalyzed Benzene Synthesis by [2+2+2] Coupling of 1,3-Dicarbonyl Compound and Terminal Acetylene Hayato Tsuji, Ken-ichi Yamagata, Taisuke Fujimoto and Eiichi Nakamura pp 7792–7793 DOI: 10.1021/ja8015186 Supporting Info

Cell-Based Fluorescence Screen for K+ Channels and Transporters Using an Extracellular Triazacryptand-Based K+ Sensor Wan Namkung, Prashant Padmawar, Aaron D. Mills and A. S. Verkman pp 7794–7795 DOI: 10.1021/ja8014499 Supporting Info

Antiparallel Arrangement of the Helices of Vesicle-Bound α-Synuclein Malte Drescher, Gertjan Veldhuis, Bart D. van Rooijen, Sergey Milikisyants, Vinod Subramaniam and Martina Huber pp 7796–7797 DOI: 10.1021/ja801594s Supporting Info

The Putative Diels−Alderase Macrophomate Synthase is an Efficient Aldolase Jrg M. Serafimov, Dennis Gillingham, Simon Kuster and Donald Hilvert pp 7798–7799 DOI: 10.1021/ja8017994 Supporting Info

One-Step Multicomponent Encapsulation by Compound-Fluidic Electrospray Hongyan Chen, Yong Zhao, Yanlin Song and Lei Jiang pp 7800–7801 DOI: 10.1021/ja801803x Supporting Info

Direct Examination of H2O2 Activation by a Heme Peroxidase Justine P. Roth and Christopher J. Cramer pp 7802–7803 DOI: 10.1021/ja802098c Supporting Info

Calculation of Residual Dipolar Couplings from Disordered State Ensembles Using Local Alignment Joseph A. Marsh, Jennifer M. R. Baker, Martin Tollinger and Julie D. Forman-Kay pp 7804–7805 DOI: 10.1021/ja802220c Supporting Info

A Fluorescent Core−Shell Dendritic Macromolecule Specifically Stains The Extracellular Matrix Meizhen Yin, Jie Shen, Gert O. Pflugfelder and Klaus Mllen pp 7806–7807 DOI: 10.1021/ja8022362 Supporting Info

Imaging of Conformational Changes of Biotinylated Triamide Molecules Covalently Bonded to a Carbon Nanotube Surface Eiichi Nakamura, Masanori Koshino, Takatsugu Tanaka, Yoshiko Niimi, Koji Harano, Yuki Nakamura and Hiroyuki Isobe pp 7808–7809 DOI: 10.1021/ja8022708 Supporting Info

Reaction of Carboxylic Acids and Isonitriles in Small Spaces Jun-Li Hou, Dariush Ajami and Julius Rebek, pp 7810–7811 DOI: 10.1021/ja802288k Supporting Info

Synthesis of All-Conjugated Diblock Copolymers by Quasi-Living Polymerization and Observation of Their Microphase Separation Yue Zhang, Keisuke Tajima, Kouske Hirota and Kazuhito Hashimoto pp 7812–7813 DOI: 10.1021/ja8023516 Supporting Info

Au Dimers on Thin MgO(001) Films: Flat and Charged or Upright and Neutral? V. Simic-Milosevic, M. Heyde, N. Nilius, T. Knig, H.-P. Rust, M. Sterrer, T. Risse, H.-J. Freund, L. Giordano and G. Pacchioni pp 7814–7815 DOI: 10.1021/ja8024388 Supporting Info

A Mechanistic Probe for Asymmetric Reactions: Deuterium Isotope Effects at Enantiotopic Groups Jason D. West, Sean E. Stafford and Matthew P. Meyer pp 7816–7817 DOI: 10.1021/ja8026899 Supporting Info

Simultaneous Detection and Deconvolution of Congested NMR Spectra Containing Three Isotopically Labeled Species Larry R. Masterson, Marco Tonelli, John L. Markley and Gianluigi Veglia pp 7818–7819 DOI: 10.1021/ja802701w Supporting Info

Toward Reliable Gold Nanoparticle Patterning On Self-Assembled DNA Nanoscaffold Jaswinder Sharma, Rahul Chhabra, Casper S. Andersen, Kurt V. Gothelf, Hao Yan and Yan Liu pp 7820–7821 DOI: 10.1021/ja802853r Supporting Info

Engineered Biosynthesis of Antiprotealide and Other Unnatural Salinosporamide Proteasome Inhibitors Ryan P. McGlinchey, Markus Nett, Alessandra S. Eustquio, Ratnakar N. Asolkar, William Fenical and Bradley S. Moore pp 7822–7823 DOI: 10.1021/ja8029398 Supporting Info

Cu-Facilitated C−O Bond Formation Using N-Hydroxyphthalimide: Efficient and Selective Functionalization of Benzyl and Allylic C−H Bonds Ji Min Lee, Eun Ju Park, Seung Hwan Cho and Sukbok Chang pp 7824–7825 DOI: 10.1021/ja8031218 Supporting Info

Beyond Aresta’s Complex: Ni- and Pd-Catalyzed Organozinc Coupling with CO2 Charles S. Yeung and Vy M. Dong pp 7826–7827 DOI: 10.1021/ja803435w Supporting Info

Preparation of Substituted Enol Derivatives From Terminal Alkynes and Their Synthetic Utility John R. DeBergh, Kathleen M. Spivey and Joseph M. Ready pp 7828–7829 DOI: 10.1021/ja803480b Supporting Info

Structural Prediction of Thiolate-Protected Au38: A Face-Fused Bi-icosahedral Au Core Yong Pei, Yi Gao and Xiao Cheng Zeng pp 7830–7832 DOI: 10.1021/ja802975b Supporting Info

Binary Superlattices of PbSe and CdSe Nanocrystals Karin Overgaag, Wiel Evers, Bart de Nijs, Rolf Koole, Johannes Meeldijk and Daniel Vanmaekelbergh pp 7833–7835 DOI: 10.1021/ja802932m Supporting Info

Chelation of a Proton by an Aliphatic Tertiary Diamine Sepideh Yaghmaei, Sevana Khodagholian, J. Michael Kaiser, Fook S. Tham, Leonard J. Mueller and Thomas Hellman Morton pp 7836–7838 DOI: 10.1021/ja8018725 Supporting Info

Diacid Linkers That Promote Parallel β-Sheet Secondary Structure in Water Felix Freire, John D. Fisk, Aaron J. Peoples, Monika Ivancic, Ilia A. Guzei and Samuel H. Gellman pp 7839–7841 DOI: 10.1021/ja802042c Supporting Info

Metal Fluorides Form Strong Hydrogen Bonds and Halogen Bonds: Measuring Interaction Enthalpies and Entropies in Solution Stefano Libri, Naseralla A. Jasim, Robin N. Perutz and Lee Brammer pp 7842–7844 DOI: 10.1021/ja8020318 Supporting Info

Conformationally Driven Asymmetric Induction of a Catalytic Dendrimer Jianfeng Yu, T. V. RajanBabu and Jon R. Parquette pp 7845–7847 DOI: 10.1021/ja802308a Supporting Info

Broadly Hysteretic H2 Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate) Hye Jin Choi, Mircea Dinc and Jeffrey R. Long pp 7848–7850 DOI: 10.1021/ja8024092 Supporting Info

Molecular Recognition Based on Low-Affinity Polyvalent Interactions: Selective Binding of a Carboxylated Polymer to Fibronectin Fibrils of Live Fibroblast Cells Reagan L. McRae, Ronnie L. Phillips, Ik-Bum Kim, Uwe H. F. Bunz and Christoph J. Fahrni pp 7851–7853 DOI: 10.1021/ja8007402 Supporting Info

Is the Isolated Pentagon Rule Merely a Suggestion for Endohedral Fullerenes? The Structure of a Second Egg-Shaped Endohedral FullereneGd3N@Cs(39663)-C82 Brandon Q. Mercado, Christine M. Beavers, Marilyn M. Olmstead, Manuel N. Chaur, Kenneth Walker, Brian C. Holloway, Luis Echegoyen and Alan L. Balch pp 7854–7855 DOI: 10.1021/ja8032263 Supporting Info

Crystal Structure of Thioflavin T Bound to the Peripheral Site of Torpedo californica Acetylcholinesterase Reveals How Thioflavin T Acts as a Sensitive Fluorescent Reporter of Ligand Binding to the Acylation Site Michal Harel, Leilani K. Sonoda, Israel Silman, Joel L. Sussman and Terrone L. Rosenberry pp 7856–7861 DOI: 10.1021/ja7109822

Are the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric α-Carbon-Centered Triglycine Radical Cations in the Gas Phase Ivan K. Chu, Junfang Zhao, Minjie Xu, Shiu On Siu, Alan C. Hopkinson and K. W. Michael Siu pp 7862–7872 DOI: 10.1021/ja801108j Supporting Info

Design of an N-Methylated Peptide Inhibitor of α-Synuclein Aggregation Guided by Solid-State NMR Jillian Madine, Andrew J. Doig and David A. Middleton pp 7873–7881 DOI: 10.1021/ja075356q

Pyrolysis, Crystallization, and Sintering of Mesostructured Titania Thin Films Assessed by in Situ Thermal Ellipsometry John D. Bass, David Grosso, Cdric Boissiere and Clment Sanchez pp 7882–7897 DOI: 10.1021/ja078140x Supporting Info

Evidence of an Intermediate and Parallel Pathways in Protein Unfolding from Single-Molecule Fluorescence Angel Orte, Timothy D. Craggs, Samuel S. White, Sophie E. Jackson and David Klenerman pp 7898–7907 DOI: 10.1021/ja709973m Supporting Info

Electronically Activated Actin Protein Polymerization and Alignment Ian Y. Wong, Matthew J. Footer and Nicholas A. Melosh pp 7908–7915 DOI: 10.1021/ja7103284

Self-Assembly of Surfactants and Polymorphic Transition in Nanotubes Noriyoshi Arai, Kenji Yasuoka and X. C. Zeng pp 7916–7920 DOI: 10.1021/ja7108739 Supporting Info

The Electronic Role of DNA-Functionalized Carbon Nanotubes: Efficacy for in Situ Polymerization of Conducting Polymer Nanocomposites Yufeng Ma, Pui Lam Chiu, Arnaldo Serrano, Shah R. Ali, Alex M. Chen and Huixin He pp 7921–7928 DOI: 10.1021/ja7112189 Supporting Info

Origin of Selectivity Switch in Fischer−Tropsch Synthesis over Ru and Rh from First-Principles Statistical Mechanics Studies Jia Chen and Zhi-Pan Liu pp 7929–7937 DOI: 10.1021/ja7112239 Supporting Info

Double-Stranded Helical Polymers Consisting of Complementary Homopolymers Takeshi Maeda, Yoshio Furusho, Shin-Ichiro Sakurai, Jiro Kumaki, Kento Okoshi and Eiji Yashima pp 7938–7945 DOI: 10.1021/ja711447s Supporting Info

Growth, New Growth, and Amplification of Carbon Nanotubes as a Function of Catalyst Composition Christopher A. Crouse, Benji Maruyama, Ramon Colorado Jr., Tyson Back and Andrew R. Barron pp 7946–7954 DOI: 10.1021/ja800233b Supporting Info

Asymmetric Aza-Henry Reaction Under Phase Transfer Catalysis: An Experimental and Theoretical Study Enrique Gomez-Bengoa, Anthony Linden, Rosa Lpez, Idoia Mgica-Mendiola, Mikel Oiarbide and Claudio Palomo pp 7955–7966 DOI: 10.1021/ja800253z Supporting Info

Instantaneous Low Temperature Gelation by a Multicomponent Organogelator Liquid System Based on Ammonium Salts Daniel Garca Velzquez, David Daz Daz, ngel Gutirrez Ravelo and Jos Juan Marrero Tellado pp 7967–7973 DOI: 10.1021/ja8002777 Supporting Info

Synthesis and Reactivity Studies of Iminoboryl Complexes Holger Braunschweig, Thomas Kupfer, Krzysztof Radacki, Achim Schneider, Fabian Seeler, Katharina Uttinger and Hongmei Wu pp 7974–7983 DOI: 10.1021/ja8016889 Supporting Info

Evaluation of the Carbene Hydride Mechanism in the Carbon−Carbon Bond Formation Process of Alkane Metathesis through a DFT Study Sandra Schinzel, Henry Chermette, Christophe Copret and Jean-Marie Basset pp 7984–7987 DOI: 10.1021/ja800474h Supporting Info

Synchrotron X-ray Charge Density Study of Coordination Polymer Co3(C8H4O4)4(C4H12N)2(C5H11NO)3 at 16 K H. F. Clausen, J. Overgaard, Y. S. Chen and B. B. Iversen pp 7988–7996 DOI: 10.1021/ja8007215 Supporting Info

Synthesis of Cadmium Telluride Quantum Wires and the Similarity of Their Effective Band Gaps to Those of Equidiameter Cadmium Telluride Quantum Dots Jianwei Sun, Lin-Wang Wang and William E. Buhro pp 7997–8005 DOI: 10.1021/ja800837v Supporting Info

A Supramolecular Receptor of Diatomic Molecules (O2, CO, NO) in Aqueous Solution Koji Kano, Yoshiki Itoh, Hiroaki Kitagishi, Takashi Hayashi and Shun Hirota pp 8006–8015 DOI: 10.1021/ja8009583 Supporting Info

Metal Cation-Induced Deformation of DNA Self-Assembled Monolayers on Silicon: Vibrational Sum Frequency Generation Spectroscopy Hidehiko Asanuma, Hidenori Noguchi, Kohei Uosaki and Hua-Zhong Yu pp 8016–8022 DOI: 10.1021/ja801023r

Immobilized DNA Switches as Electronic Sensors for Picomolar Detection of Plasma Proteins Yu Chuan Huang, Bixia Ge, Dipankar Sen and Hua-Zhong Yu pp 8023–8029 DOI: 10.1021/ja8011066 Supporting Info

Chemical Imaging of Corrosion: Sum Frequency Generation Imaging Microscopy of Cyanide on Gold at the Solid−Liquid Interface Katherine Cimatu and Steven Baldelli pp 8030–8037 DOI: 10.1021/ja8011676

Selective Detection of Mercury (II) Ion Using Nonlinear Optical Properties of Gold Nanoparticles Gopala Krishna Darbha, Anant Kumar Singh, Uma Shanker Rai, Eugene Yu, Hongtao Yu and Paresh Chandra Ray pp 8038–8043 DOI: 10.1021/ja801412b

Functional Mimicry of Carboxypeptidase A by a Combination of Transition State Stabilization and a Defined Orientation of Catalytic Moieties in Molecularly Imprinted Polymers Jun-qiu Liu and Gnter Wulff pp 8044–8054 DOI: 10.1021/ja8012648

Quantitative Conformational Analysis of Partially Folded Proteins from Residual Dipolar Couplings: Application to the Molecular Recognition Element of Sendai Virus Nucleoprotein Malene Ringkjøbing Jensen, Klaartje Houben, Ewen Lescop, Laurence Blanchard, Rob W. H. Ruigrok and Martin Blackledge pp 8055–8061 DOI: 10.1021/ja801332d Supporting Info

Comparative Structural and Chemical Studies of Ferritin Cores with Gradual Removal of their Iron Contents Natividad Glvez, Beln Fernndez, Purificacin Snchez, Rafael Cuesta, Marcelo Ceoln, Miguel Clemente-Len, Susana Trasobares, Miguel Lpez-Haro, Jose J. Calvino, Odile Stphan and Jos M. Domnguez-Vera pp 8062–8068 DOI: 10.1021/ja800492z Supporting Info

Enantiomer-Specific Binding of Ruthenium(II) Molecular Wires by the Amine Oxidase of Arthrobacter globiformis David B. Langley, Doreen E. Brown, Lionel E. Cheruzel, Stephen M. Contakes, Anthony P. Duff, Kimberly M. Hilmer, David M. Dooley, Harry B. Gray, J. Mitchell Guss and Hans C. Freeman pp 8069–8078 DOI: 10.1021/ja801289f Supporting Info

Effect of Thioxopeptide Bonds on α-Helix Structure and Stability Andreas Reiner, Dirk Wildemann, Gunter Fischer and Thomas Kiefhaber pp 8079–8084 DOI: 10.1021/ja8015044 Supporting Info

Artificial Metalloenzyme for Enantioselective Sulfoxidation Based on Vanadyl-Loaded Streptavidin Anca Pordea, Marc Creus, Jaroslaw Panek, Carole Duboc, Dborah Mathis, Marjana Novic and Thomas R. Ward pp 8085–8088 DOI: 10.1021/ja8017219 Supporting Info

A Strategy for Position-Selective Epoxidation of Polyprenols Vijay Gnanadesikan and E. J. Corey pp 8089–8093 DOI: 10.1021/ja801899v Supporting Info

Microwave-Induced Multiple Functionalization of Carbon Nanotubes Fulvio G. Brunetti, M. Antonia Herrero, Juan de M. Muoz, Angel Daz-Ortiz, Jessica Alfonsi, Moreno Meneghetti, Maurizio Prato and Ester Vzquez pp 8094–8100 DOI: 10.1021/ja801971k Supporting Info

Exciton Energy Transfer-Assisted Photoluminescence Brightening from Freestanding Single-Walled Carbon Nanotube Bundles Toshiaki Kato and Rikizo Hatakeyama pp 8101–8107 DOI: 10.1021/ja802427v Supporting Info

Proton-Coupled Electron Transfer in a Model for Tyrosine Oxidation in Photosystem II Claudio Carra, Nedialka Iordanova and Sharon Hammes-Schiffer p 8108 DOI: 10.1021/ja803574n

Issue 26

Supramolecular Self-Assembly of Amphiphiles on Carbon Nanotubes: A Versatile Strategy for the Construction of CNT/Metal Nanohybrids, Application to Electrocatalysis Nicolas Mackiewicz, Geetarani Surendran, Hynd Remita, Bineta Keita, Guangjin Zhang, Louis Nadjo, Agns Hagge, Eric Doris and Charles Mioskowski pp 8110–8111 DOI: 10.1021/ja8026373 Supporting Info

In Situ Small-Angle X-ray Scattering Observation of Pt Catalyst Particle Growth During Potential Cycling Matt C. Smith, James A. Gilbert, Jennifer R. Mawdsley, Snke Seifert and Deborah J. Myers pp 8112–8113 DOI: 10.1021/ja801138t Supporting Info

A Semiconductor Bulk Material That Emits Direct White Light Wooseok Ki and Jing Li pp 8114–8115 DOI: 10.1021/ja801601y Supporting Info

Structural Basis of Thiamine Pyrophosphate Analogues Binding to the Eukaryotic Riboswitch Stphane Thore, Christian Frick and Nenad Ban pp 8116–8117 DOI: 10.1021/ja801708e Supporting Info

Asymmetric Cycloadditions of Palladium-Polarized Aza-o-xylylenes Chao Wang and Jon A. Tunge pp 8118–8119 DOI: 10.1021/ja801742h Supporting Info

Effect of Water on the Ionothermal Synthesis of Molecular Sieves Huaijun Ma, Zhijian Tian, Renshun Xu, Bingchun Wang, Ying Wei, Lei Wang, Yunpeng Xu, Weiping Zhang and Liwu Lin pp 8120–8121 DOI: 10.1021/ja802207p Supporting Info

18O Kinetic Isotope Effects in Non-Heme Iron Enzymes: Probing the Nature of Fe/O2 Intermediates Liviu M. Mirica, Kevin P. McCusker, Jeffrey W. Munos, Hung-wen Liu and Judith P. Klinman pp 8122–8123 DOI: 10.1021/ja800265s Supporting Info

Polymerase Chain Reaction and Transcription Using Locked Nucleic Acid Nucleotide Triphosphates Rakesh N. Veedu, Birte Vester and Jesper Wengel pp 8124–8125 DOI: 10.1021/ja801389n Supporting Info

Single-Walled MoO3 Nanotubes Shi Hu and Xun Wang pp 8126–8127 DOI: 10.1021/ja801448c Supporting Info

Regiocontrolled Copolymerization of Methyl Acrylate with Carbon Monoxide Akifumi Nakamura, Kagehiro Munakata, Takuya Kochi and Kyoko Nozaki pp 8128–8129 DOI: 10.1021/ja802161n Supporting Info

Bicyclic Guanidinium Tetraphenylborate: A Photobase Generator and A Photocatalyst for Living Anionic Ring-Opening Polymerization and Cross-Linking of Polymeric Materials Containing Ester and Hydroxy Groups Xun Sun, Jian Ping Gao and Zhi Yuan Wang pp 8130–8131 DOI: 10.1021/ja802816g Supporting Info

Highly Chemoselective and Stereoselective Synthesis of Z-Enol Silanes Ananda Herath and John Montgomery pp 8132–8133 DOI: 10.1021/ja802844v Supporting Info

Catalytic Enantioselective Peroxidation of α,β-Unsaturated Ketones Xiaojie Lu, Yan Liu, Bingfeng Sun, Brittany Cindric and Li Deng pp 8134–8135 DOI: 10.1021/ja802982h Supporting Info

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions Xiaodan Zhao and Zhengkun Yu pp 8136–8137 DOI: 10.1021/ja803154h Supporting Info

A One-Step Highly Sensitive Method for DNA Detection Using Dynamic Light Scattering Qiu Dai, Xiong Liu, Janelle Coutts, Lauren Austin and Qun Huo pp 8138–8139 DOI: 10.1021/ja801947e Supporting Info

Room-Temperature Chemical Synthesis of Shape-Controlled Indium Nanoparticles Nam Hawn Chou, Xianglin Ke, Peter Schiffer and Raymond E. Schaak pp 8140–8141 DOI: 10.1021/ja801949c Supporting Info

Characterization of a Carbonyl-Conjugated Polyene Precursor in 10-Membered Enediyne Biosynthesis Rong Kong, Lan Pei Goh, Chong Wai Liew, Qin Shi Ho, Elavazhagan Murugan, Bin Li, Kai Tang and Zhao-Xun Liang pp 8142–8143 DOI: 10.1021/ja8019643 Supporting Info

Aqueous Noncovalent Functionalization and Controlled Near-Surface Carbon Doping of Multiwalled Boron Nitride Nanotubes Wenlong Wang, Yoshio Bando, Chunyi Zhi, Wangyang Fu, Enge Wang and Dmitri Golberg pp 8144–8145 DOI: 10.1021/ja8020878 Supporting Info

Site-Specific Unfolding Thermodynamics of a Helix-Turn-Helix Protein Krista E. Amunson, Loren Ackels and Jan Kubelka pp 8146–8147 DOI: 10.1021/ja802185e Supporting Info

Monomethylarsenite Competes with Zn2+ for Binding Sites in the Glucocorticoid Receptor Anne M. Spuches and Dean E. Wilcox pp 8148–8149 DOI: 10.1021/ja802179p Supporting Info

Pseudoequivalent Nitrogen Atoms in Aqueous Imidazole Distinguished by Chemical Shifts in Photoelectron Spectroscopy Dirk Nolting, Niklas Ottosson, Manfred Faubel, Ingolf V. Hertel and Bernd Winter pp 8150–8151 DOI: 10.1021/ja8022384 Supporting Info

Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene Xinran Wang, Scott M. Tabakman and Hongjie Dai pp 8152–8153 DOI: 10.1021/ja8023059 Supporting Info

Imaging Glycosylation Hongda Wang, Linda Obenauer-Kutner, Mei Lin, Yunping Huang, Michael J. Grace and Stuart M. Lindsay pp 8154–8155 DOI: 10.1021/ja802535p

Nickel Complexes of a Pincer NN2 Ligand: Multiple Carbon−Chloride Activation of CH2Cl2 and CHCl3 Leads to Selective Carbon−Carbon Bond Formation Zsolt Csok, Oleg Vechorkin, Seth B. Harkins, Rosario Scopelliti and Xile Hu pp 8156–8157 DOI: 10.1021/ja8025938 Supporting Info

Duplex Structure of a Minimal Nucleic Acid Mark K. Schlegel, Lars-Oliver Essen and Eric Meggers pp 8158–8159 DOI: 10.1021/ja802788g Supporting Info

Asymmetric [2 + 2] Olefin Cross Photoaddition in a Self-Assembled Host with Remote Chiral Auxiliaries Yuki Nishioka, Takumi Yamaguchi, Masaki Kawano and Makoto Fujita pp 8160–8161 DOI: 10.1021/ja802818t Supporting Info

Assembly of Crystalline Halogen-Bonded Materials by Physical Vapor Deposition Tanya Shirman, Dalia Freeman, Yael Diskin Posner, Isai Feldman, Antonio Facchetti and Milko E. van der Boom pp 8162–8163 DOI: 10.1021/ja8029784 Supporting Info

Synthetic Nanomotors in Microchannel Networks: Directional Microchip Motion and Controlled Manipulation of Cargo Jared Burdick, Rawiwan Laocharoensuk, Philip M. Wheat, Jonathan D. Posner and Joseph Wang pp 8164–8165 DOI: 10.1021/ja803529u Supporting Info

On-Wire Lithography-Generated Molecule-Based Transport Junctions: A New Testbed for Molecular Electronics Xiaodong Chen, You-Moon Jeon, Jae-Won Jang, Lidong Qin, Fengwei Huo, Wei Wei and Chad A. Mirkin pp 8166–8168 DOI: 10.1021/ja800338w Supporting Info

Detection of Intact Influenza Viruses using Biotinylated Biantennary S-Sialosides Ramesh R. Kale, Harshini Mukundan, Dominique N. Price, J. Foster Harris, Daniel M. Lewallen, Basil I. Swanson, Jurgen G. Schmidt and Suri S. Iyer pp 8169–8171 DOI: 10.1021/ja800842v Supporting Info

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions Robert J. Phipps, Neil P. Grimster and Matthew J. Gaunt pp 8172–8174 DOI: 10.1021/ja801767s Supporting Info

Remotely Triggered Liposome Release by Near-Infrared Light Absorption via Hollow Gold Nanoshells Guohui Wu, Alexander Mikhailovsky, Htet A. Khant, Caroline Fu, Wah Chiu and Joseph A. Zasadzinski pp 8175–8177 DOI: 10.1021/ja802656d Supporting Info

Methodology for Synthesizing Crystalline Metallosilicates with Expanded Pore Windows Through Molecular Alkoxysilylation of Zeolitic Lamellar Precursors Peng Wu, Juanfang Ruan, Lingling Wang, LeiLei Wu, Yong Wang, Yueming Liu, Weibin Fan, Mingyuan He, Osamu Terasaki and Takashi Tatsumi pp 8178–8187 DOI: 10.1021/ja0758739 Supporting Info

DNA Hybridization-Induced Reorientation of Liquid Crystal Anchoring at the Nematic Liquid Crystal/Aqueous Interface Andrew D. Price and Daniel K. Schwartz pp 8188–8194 DOI: 10.1021/ja0774055

Origins of Superstructure Ordering and Incommensurability in Stuffed CoSn-Type Phases Daniel C. Fredrickson, Sven Lidin, Gerard Venturini, Bernard Malaman and Jeppe Christensen pp 8195–8214 DOI: 10.1021/ja077380+ Supporting Info

Conformational Changes in the Metallo-β-lactamase ImiS During the Catalytic Reaction: An EPR Spectrokinetic Study of Co(II)-Spin Label Interactions Narayan Sharma, Zhenxin Hu, Michael W. Crowder and Brian Bennett pp 8215–8222 DOI: 10.1021/ja0774562

On the Origin of Alternating Bond Distortions and the Emergence of Chirality in Polyoxometalate Anions Likai Yan, Xavier Lpez, Jorge J. Carb, Richard Sniatynsky, Dean C. Duncan and Josep M. Poblet pp 8223–8233 DOI: 10.1021/ja711008n Supporting Info

DNA and DNAzyme-Mediated 2D Colloidal Assembly Margaret H. S. Shyr, Daryl P. Wernette, Pierre Wiltzius, Yi Lu and Paul V. Braun pp 8234–8240 DOI: 10.1021/ja711026r

Electrochemistry of Individual Molecules in Zeptoliter Volumes Peng Sun and Michael V. Mirkin pp 8241–8250 DOI: 10.1021/ja711088j Supporting Info

Aryl Vinyl Sulfonates and Sulfones as Active Site-Directed and Mechanism-Based Probes for Protein Tyrosine Phosphatases Sijiu Liu, Bo Zhou, Heyi Yang, Yantao He, Zhong-Xing Jiang, Sanjai Kumar, Li Wu and Zhong-Yin Zhang pp 8251–8260 DOI: 10.1021/ja711125p Supporting Info

Structure and Magnetic Properties of Oxychalcogenides A2F2Fe2OQ2 (A = Sr, Ba; Q = S, Se) with Fe2O Square Planar Layers Representing an Antiferromagnetic Checkerboard Spin Lattice Houria Kabbour, Etienne Janod, Benot Corraze, Michel Danot, Changhoon Lee, Myung-Hwan Whangbo and Laurent Cario pp 8261–8270 DOI: 10.1021/ja711139g Supporting Info

Twisted Perylene Stereodimers Reveal Chiral Molecular Assembly Codes Wei Wang, Andrew D. Shaller and Alexander D. Q. Li pp 8271–8279 DOI: 10.1021/ja7111959 Supporting Info

One- and Two-Photon Induced Polymerization of Methylmethacrylate Using Colloidal CdS Semiconductor Quantum Dots Nicholas C. Strandwitz, Anzar Khan, Shannon W. Boettcher, Alexander A. Mikhailovsky, Craig J. Hawker, Thuc-Quyen Nguyen and Galen D. Stucky pp 8280–8288 DOI: 10.1021/ja711295k Supporting Info

Interaction between Water-Soluble Peptidic CdSe/ZnS Nanocrystals and Membranes: Formation of Hybrid Vesicles and Condensed Lamellar Phases Aurlien Dif, Etienne Henry, Franck Artzner, Michle Baudy-Floc’h, Marc Schmutz, Maxime Dahan and Valrie Marchi-Artzner pp 8289–8296 DOI: 10.1021/ja711378g Supporting Info

Pyrazine-Containing Acene-Type Molecular Ribbons with up to 16 Rectilinearly Arranged Fused Aromatic Rings Baoxiang Gao, Ming Wang, Yanxiang Cheng, Lixiang Wang, Xiabin Jing and Fosong Wang pp 8297–8306 DOI: 10.1021/ja800311a Supporting Info

Orchestration of Discoid Polyketide Cyclization in the Resistomycin Pathway Kathrin Fritzsche, Keishi Ishida and Christian Hertweck pp 8307–8316 DOI: 10.1021/ja800251m Supporting Info

Conformational Preferences of the Aglycon Moiety in Models and Analogs of GlcNAc-Asn Linkage: Crystal Structures and ab Initio Quantum Chemical Calculations of N-(β-d-Glycopyranosyl)haloacetamides Mohamed Mohamed Naseer Ali, Udayanath Aich, Babu Varghese, Serge Prez, Anne Imberty and Duraikkannu Loganathan pp 8317–8325 DOI: 10.1021/ja800335m Supporting Info

Pyridone Dipeptide Backbone Scan To Elucidate Structural Properties of a Flexible Peptide Segment Michael Haack, Sebastian Enck, Harald Seger, Armin Geyer and Annette G. Beck-Sickinger pp 8326–8336 DOI: 10.1021/ja8004495 Supporting Info

Mechanistic Study of Photomediated Triangular Silver Nanoprism Growth Can Xue, Gabriella S. Mtraux, Jill E. Millstone and Chad A. Mirkin pp 8337–8344 DOI: 10.1021/ja8005258 Supporting Info

Gating of Single Synthetic Nanopores by Proton-Driven DNA Molecular Motors Fan Xia, Wei Guo, Youdong Mao, Xu Hou, Jianming Xue, Hongwei Xia, Lin Wang, Yanling Song, Hang Ji, Qi Ouyang, Yugang Wang and Lei Jiang pp 8345–8350 DOI: 10.1021/ja800266p Supporting Info

Carbon Nanotube-Quenched Fluorescent Oligonucleotides: Probes that Fluoresce upon Hybridization Ronghua Yang, Jianyu Jin, Yan Chen, Na Shao, Huaizhi Kang, Zeyu Xiao, Zhiwen Tang, Yanrong Wu, Zhi Zhu and Weihong Tan pp 8351–8358 DOI: 10.1021/ja800604z Supporting Info

π-Stacked Interactions in Explosive Crystals: Buffers against External Mechanical Stimuli Chaoyang Zhang, Xiaochuan Wang and Hui Huang pp 8359–8365 DOI: 10.1021/ja800712e Supporting Info

Importance of Solution Equilibria in the Directed Assembly of Metal Chalcogenide Mesostructures Santanu Bag and Mercouri G. Kanatzidis pp 8366–8376 DOI: 10.1021/ja800741h Supporting Info

The Fate of C5′ Radicals of Purine Nucleosides under Oxidative Conditions Fabien Boussicault, Panagiotis Kaloudis, Clara Caminal, Quinto G. Mulazzani and Chryssostomos Chatgilialoglu pp 8377–8385 DOI: 10.1021/ja800763j Supporting Info

Role of Exposed Metal Sites in Hydrogen Storage in MOFs Jenny G. Vitillo, Laura Regli, Sachin Chavan, Gabriele Ricchiardi, Giuseppe Spoto, Pascal D. C. Dietzel, Silvia Bordiga and Adriano Zecchina pp 8386–8396 DOI: 10.1021/ja8007159 Supporting Info

Quantifying Two-Bond 1HN−13CO and One-Bond 1Hα−13Cα Dipolar Couplings of Invisible Protein States by Spin-State Selective Relaxation Dispersion NMR Spectroscopy D. Flemming Hansen, Pramodh Vallurupalli and Lewis E. Kay pp 8397–8405 DOI: 10.1021/ja801005n

Diaminocarbene and Phosphonium Ylide Ligands: A Systematic Comparison of their Donor Character Yves Canac, Christine Lepetit, Mohammed Abdalilah, Carine Duhayon and Remi Chauvin pp 8406–8413 DOI: 10.1021/ja801159v Supporting Info

Enhanced Conductivity and Magnetic Ordering in Isostructural Heavy Atom Radicals Craig M. Robertson, Alicea A. Leitch, Kristina Cvrkalj, Robert W. Reed, Daniel J. T. Myles, Paul A. Dube and Richard T. Oakley pp 8414–8425 DOI: 10.1021/ja801070d Supporting Info

Supramolecular Self-Assembly of Cyclodextrin and Higher Water Soluble Guest: Thermodynamics and Topological Studies Frederico B. De Sousa, ngelo M. Leite Denadai, Ivana S. Lula, Clebio S. Nascimento Jr., Nathlia S. G. Fernandes Neto, Ana C. Lima, Wagner B. De Almeida and Rubn D. Sinisterra pp 8426–8436 DOI: 10.1021/ja801080v Supporting Info

How Do Analogous α-Chloroenamides and α-Iodoenamides Give Different Product Distributions in 5-Endo Radical Cyclizations? Dennis P. Curran, David B. Guthrie and Steven J. Geib pp 8437–8445 DOI: 10.1021/ja8012962 Supporting Info

Cucurbit[n]uril Formation Proceeds by Step-Growth Cyclo-oligomerization Wei-Hao Huang, Peter Y. Zavalij and Lyle Isaacs pp 8446–8454 DOI: 10.1021/ja8013693 Supporting Info

Total Synthesis and Molecular Target of Largazole, a Histone Deacetylase Inhibitor Yongcheng Ying, Kanchan Taori, Hyoungsu Kim, Jiyong Hong and Hendrik Luesch pp 8455–8459 DOI: 10.1021/ja8013727 Supporting Info

Characterization of Conformational Exchange of a Histidine Side Chain: Protonation, Rotamerization, and Tautomerization of His61 in Plastocyanin from Anabaena variabilis Mathias A. S. Hass, D. Flemming Hansen, Hans E. M. Christensen, Jens J. Led and Lewis E. Kay pp 8460–8470 DOI: 10.1021/ja801330h Supporting Info

Structural Studies of the Molybdenum Center of the Pathogenic R160Q Mutant of Human Sulfite Oxidase by Pulsed EPR Spectroscopy and 17O and 33S Labeling Andrei V. Astashkin, Kayunta Johnson-Winters, Eric L. Klein, Changjian Feng, Heather L. Wilson, K. V. Rajagopalan, Arnold M. Raitsimring and John H. Enemark pp 8471–8480 DOI: 10.1021/ja801406f Supporting Info

Catalytic Enantioselective Allyl- and Crotylboration of Aldehydes Using Chiral Diol•SnCl4 Complexes. Optimization, Substrate Scope and Mechanistic Investigations Vivek Rauniyar, Huimin Zhai and Dennis G. Hall pp 8481–8490 DOI: 10.1021/ja8016076 Supporting Info

Cooperativity and Tunable Excited State Deactivation: Modular Self-Assembly of Depsipeptide Dendrons on a Hamilton Receptor Modified Porphyrin Platform Jan-Frederik Gnichwitz, Mateusz Wielopolski, Kristine Hartnagel, Uwe Hartnagel, Dirk M. Guldi and Andreas Hirsch pp 8491–8501 DOI: 10.1021/ja8018065 Supporting Info

Thermodynamical Equilibrium of Binary Supramolecular Networks at the Liquid−Solid Interface Lorenz Kampschulte, Tova L. Werblowsky, Ravuri S. K. Kishore, Michael Schmittel, Wolfgang M. Heckl and Markus Lackinger pp 8502–8507 DOI: 10.1021/ja801883t Supporting Info

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach Kristine K. Tanabe, Zhenqiang Wang and Seth M. Cohen pp 8508–8517 DOI: 10.1021/ja801848j Supporting Info

Transition State for Alkyl Group Hydrogenation on Pt(111) Pingping Ye and Andrew J. Gellman pp 8518–8526 DOI: 10.1021/ja075292j Supporting Info

Kinetics of Redox Polymer-Mediated Enzyme Electrodes Joshua W. Gallaway and Scott A. Calabrese Barton pp 8527–8536 DOI: 10.1021/ja0781543 Supporting Info

Stereoselective Direct Glycosylation with Anomeric Hydroxy Sugars by Activation with Phthalic Anhydride and Trifluoromethanesulfonic Anhydride Involving Glycosyl Phthalate Intermediates Kwan Soo Kim, Dinanath Baburao Fulse, Ju Yuel Baek, Bo-Young Lee and Heung Bae Jeon pp 8537–8547 DOI: 10.1021/ja710935z Supporting Info

Solvent Effects and Activation Parameters in the Competitive Cleavage of C−CN and C−H Bonds in 2-Methyl-3-Butenenitrile Using [(dippe)NiH]2 Brett D. Swartz, Nicole M. Reinartz, William W. Brennessel, Juventino J. Garca and William D. Jones pp 8548–8554 DOI: 10.1021/ja8000216 Supporting Info

Reductive Reactivity of the Organolanthanide Hydrides, [(C5Me5)2LnH]x, Leads to ansa-Allyl Cyclopentadienyl (η5-C5Me4CH2−C5Me4CH2-η3)2- and Trianionic Cyclooctatetraenyl (C8H7)3- Ligands William J. Evans, Benjamin M. Schmiege, Sara E. Lorenz, Kevin A. Miller, Timothy M. Champagne, Joseph W. Ziller, Antonio G. DiPasquale and Arnold L. Rheingold pp 8555–8563 DOI: 10.1021/ja8011726 Supporting Info

Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure−Activity Relationships Qilong Shen, Tokutaro Ogata and John F. Hartwig p 8564 DOI: 10.1021/ja803423d

Book Review of “Modern Biooxidation: Enzymes, Reactions and Applications” Patrick C. Cirino p 8564 DOI: 10.1021/ja803448e

Book Review of Handbook of Molecular Force Spectroscopy Matthew F. Paige p 8565 DOI: 10.1021/ja8034784

Book Review of Applications of Physical Methods to Inorganic and Bioinorganic Chemistry John H. Dawson pp 8565–8566 DOI: 10.1021/ja803558f

Book Review of Reviews in Computational Chemistry, Volume 25 Aln Aspuru-Guzik p 8566 DOI: 10.1021/ja077020m

Book Review of Inorganic Mass Spectrometry: Principles and Applications J. Scott McIndoe pp 8566–8567 DOI: 10.1021/ja803138g

Book Review of Six-Membered Transition States in Organic Synthesis Tomislav Rovis p 8567 DOI: 10.1021/ja803438j

Book Review of Amino Group Chemistry: From Synthesis to the Life Sciences Michael C. Pirrung p 8567 DOI: 10.1021/ja803747n

Book Review of Light, Water, Hydrogen: The Solar Generation of Hydrogen by Water Photoelectrolysis Allen J. Bard pp 8567–8568 DOI: 10.1021/ja803884k

Issue 27

The Information Age and the JACS Beta Site Peter J. Stang and Sonja Krane p 8569 DOI: 10.1021/ja804408t

Design of an Organic Chromophore for P-Type Dye-Sensitized Solar Cells Peng Qin, Hongjun Zhu, Tomas Edvinsson, Gerrit Boschloo, Anders Hagfeldt and Licheng Sun pp 8570–8571 DOI: 10.1021/ja8001474 Supporting Info

Density Oscillations in a Nanoscale Water Film on Salt: Insight from Ab Initio Molecular Dynamics Limin Liu, Matthias Krack and Angelos Michaelides pp 8572–8573 DOI: 10.1021/ja8014296 Supporting Info

Highly Stereoselective Photocyclodimerization of α-Cyclodextrin-Appended Anthracene Mediated by γ-Cyclodextrin and Cucurbit[8]uril: A Dramatic Steric Effect Operating Outside the Binding Site Cheng Yang, Tadashi Mori, Yumi Origane, Young Ho Ko, Narayanan Selvapalam, Kimoon Kim and Yoshihisa Inoue pp 8574–8575 DOI: 10.1021/ja8032923 Supporting Info

Sterically Hindered Diazonium Salts for the Grafting of a Monolayer on Metals Catherine Combellas, Frederic Kanoufi, Jean Pinson and Fetah I. Podvorica pp 8576–8577 DOI: 10.1021/ja8018912 Supporting Info

Synthesis and Biophysical Characterization of Oligonucleotides Containing a 4′-Selenonucleotide Jonathan K. Watts, Blair D. Johnston, Kumarasamy Jayakanthan, Alexander S. Wahba, B. Mario Pinto and Masad J. Damha pp 8578–8579 DOI: 10.1021/ja802205u Supporting Info

Air-Stable, Solution-Processable n-Channel and Ambipolar Semiconductors for Thin-Film Transistors Based on the Indenofluorenebis(dicyanovinylene) Core Hakan Usta, Antonio Facchetti and Tobin J. Marks pp 8580–8581 DOI: 10.1021/ja802266u Supporting Info

Single Molecule Conductance of Porphyrin Wires with Ultralow Attenuation Gita Sedghi, Katsutoshi Sawada, Louisa J. Esdaile, Markus Hoffmann, Harry L. Anderson, Donald Bethell, Wolfgang Haiss, Simon J. Higgins and Richard J. Nichols pp 8582–8583 DOI: 10.1021/ja802281c Supporting Info

Iridium-Catalyzed Enantioselective Hydrogenation of α,β-Unsaturated Carboxylic Acids Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song and Qi-Lin Zhou pp 8584–8585 DOI: 10.1021/ja802399v Supporting Info

Reductive Coupling of Metal Triangles in Sandwich Complexes Tetsuro Murahashi, Yasuhiro Hashimoto, Koji Chiyoda, Mayu Fujimoto, Tomohito Uemura, Ryou Inoue, Sensuke Ogoshi and Hideo Kurosawa pp 8586–8587 DOI: 10.1021/ja802624p Supporting Info

Spectroelectrochemical Characterization of a Pentaheme Cytochrome in Solution and as Electrocatalytically Active Films on Nanocrystalline Metal-Oxide Electrodes Sophie J. Marritt, Gemma L. Kemp, Li Xiaoe, James R. Durrant, Myles R. Cheesman and Julea N. Butt pp 8588–8589 DOI: 10.1021/ja802641a Supporting Info

Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation Haifeng Du, Baoguo Zhao and Yian Shi pp 8590–8591 DOI: 10.1021/ja8027394 Supporting Info

Asymmetric Synthesis of a Chiral Buckybowl, Trimethylsumanene Shuhei Higashibayashi and Hidehiro Sakurai pp 8592–8593 DOI: 10.1021/ja802822k Supporting Info

Probing the Active Site of a Diels−Alderase Ribozyme by Photoaffinity Cross-Linking Richard Wombacher and Andres Jschke pp 8594–8595 DOI: 10.1021/ja802931q Supporting Info

CrAsH−Quantum Dot Nanohybrids for Smart Targeting of Proteins Emilie Genin, Olivier Carion, Benoit Mahler, Benoit Dubertret, Nathalie Arhel, Pierre Charneau, Eric Doris and Charles Mioskowski pp 8596–8597 DOI: 10.1021/ja802987q Supporting Info

Separating Solids: Purification of Metal-Organic Framework Materials Omar K. Farha, Karen L. Mulfort, Alison M. Thorsness and Joseph T. Hupp pp 8598–8599 DOI: 10.1021/ja803097e Supporting Info

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3 Complexes Galyna G. Dubinina, Hideki Furutachi and David A. Vicic pp 8600–8601 DOI: 10.1021/ja802946s Supporting Info

One-Pot Synthesis of Highly Functionalized Pyridines via a Rhodium Carbenoid Induced Ring Expansion of Isoxazoles James R. Manning and Huw M. L. Davies pp 8602–8603 DOI: 10.1021/ja803139k Supporting Info

Vinyl Quinones as Diels−Alder Dienes: Concise Synthesis of (−)-Halenaquinone Michael A. Kienzler, Sandy Suseno and Dirk Trauner pp 8604–8605 DOI: 10.1021/ja8035042 Supporting Info

Highly anti-Selective Asymmetric Nitro-Mannich Reactions Catalyzed by Bifunctional Amine-Thiourea-Bearing Multiple Hydrogen-Bonding Donors Chun-Jiang Wang, Xiu-Qin Dong, Zhi-Hai Zhang, Zhi-Yong Xue and Huai-Long Teng pp 8606–8607 DOI: 10.1021/ja803538x Supporting Info

Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications Nirmalya K. Chaki, Yuichi Negishi, Hironori Tsunoyama, Yukatsu Shichibu and Tatsuya Tsukuda pp 8608–8610 DOI: 10.1021/ja8005379 Supporting Info

Carbon-on-Metal Films for Surface Plasmon Resonance Detection of DNA Arrays Matthew R. Lockett, Stephen C. Weibel, Margaret F. Phillips, Michael R. Shortreed, Bin Sun, Robert M. Corn, Robert J. Hamers, Franco Cerrina and Lloyd M. Smith pp 8611–8613 DOI: 10.1021/ja802454c Supporting Info

Surface-Charge Induced Ion Depletion and Sample Stacking near Single Nanopores in Microfluidic Devices Kaimeng Zhou, Michelle L. Kovarik and Stephen C. Jacobson pp 8614–8616 DOI: 10.1021/ja802692x Supporting Info

Mononuclear and Dinuclear Molybdenum and Tungsten Complexes of p-tert-Butyltetrathiacalix[4]arene and p-tert-Butyltetrasulfonylcalix[4]arene: Facile Cleavage of the Calixarene Ligand Framework by Nickel Daniela Buccella and Gerard Parkin pp 8617–8619 DOI: 10.1021/ja803215x Supporting Info

NMR Studies of Ultrafast Intramolecular Proton Tautomerism in Crystalline and Amorphous N,N′-Diphenyl-6-aminofulvene-1-aldimine: Solid-State, Kinetic Isotope, and Tunneling Effects Juan Miguel Lopez del Amo, Uwe Langer, Vernica Torres, Gerd Buntkowsky, Hans-Martin Vieth, Marta Prez-Torralba, Dionsia Sanz, Rosa Mara Claramunt, Jos Elguero and Hans-Heinrich Limbach pp 8620–8632 DOI: 10.1021/ja801506n Supporting Info

Highly Efficient Circulating Tumor Cell Isolation from Whole Blood and Label-Free Enumeration Using Polymer-Based Microfluidics with an Integrated Conductivity Sensor Andr A. Adams, Paul I. Okagbare, Juan Feng, Matuesz L. Hupert, Don Patterson, Jost Gttert, Robin L. McCarley, Dimitris Nikitopoulos, Michael C. Murphy and Steven A. Soper pp 8633–8641 DOI: 10.1021/ja8015022 Supporting Info

Scope and Mechanism for Lewis Acid-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes: Evidence for a Stereospecific Intimate Ion Pair Pathway Patrick D. Pohlhaus, Shanina D. Sanders, Andrew T. Parsons, Wei Li and Jeffrey S. Johnson pp 8642–8650 DOI: 10.1021/ja8015928 Supporting Info

Oligopeptides and Copeptides of Homochiral Sequence, via β-Sheets, from Mixtures of Racemic α-Amino Acids, in a One-Pot Reaction in Water; Relevance to Biochirogenesis Roni A. Illos, Fabricio R. Bisogno, Gilles Clodic, Gerard Bolbach, Isabelle Weissbuch and Meir Lahav pp 8651–8659 DOI: 10.1021/ja709969v Supporting Info

Indirect, Reversible High-Density Hydrogen Storage in Compact Metal Ammine Salts Rasmus Z. Sørensen, Jens S. Hummelshøj, Asbjørn Klerke, Jacob Birke Reves, Tejs Vegge, Jens K. Nørskov and Claus H. Christensen pp 8660–8668 DOI: 10.1021/ja076762c Supporting Info

Amine-Directed Hydroboration: Scope and Limitations Matthew Scheideman, Guoqiang Wang and Edwin Vedejs pp 8669–8676 DOI: 10.1021/ja0774663 Supporting Info

Bond Selection in the Photoisomerization Reaction of Anionic Green Fluorescent Protein and Kindling Fluorescent Protein Chromophore Models Seth Olsen and Sean C. Smith pp 8677–8689 DOI: 10.1021/ja078193e Supporting Info

A Route toward the Generation of Thermally Stable Au Cluster Anions Supported on the MgO Surface Gianfranco Pacchioni, Sabrina Sicolo, Cristiana Di Valentin, Mario Chiesa and Elio Giamello pp 8690–8695 DOI: 10.1021/ja710969t Supporting Info

On the Origin of the Stabilization of the Zwitterionic Resting State of Cysteine Proteases: A Theoretical Study Milena Mladenovic, Reinhold F. Fink, Walter Thiel, Tanja Schirmeister and Bernd Engels pp 8696–8705 DOI: 10.1021/ja711043x Supporting Info

Approach to Formation of Multifunctional Polyester Particles in Controlled Nanoscopic Dimensions Alice E. van der Ende, Evan J. Kravitz and Eva Harth pp 8706–8713 DOI: 10.1021/ja711417h Supporting Info

Noncovalently Connected Micelles, Nanoparticles, and Metal-Functionalized Nanocages Using Supramolecular Self-Assembly Adam O. Moughton and Rachel K. O’Reilly pp 8714–8725 DOI: 10.1021/ja800230k

Lithium Hexamethyldisilazide-Mediated Enolizations: Influence of Triethylamine on E/Z Selectivities and Enolate Reactivities Peter F. Godenschwager and David B. Collum pp 8726–8732 DOI: 10.1021/ja800250q Supporting Info

Multipurpose Organically Modified Carbon Nanotubes: From Functionalization to Nanotube Composites Vasilios Georgakilas, Athanasios Bourlinos, Dimitrios Gournis, Theodoros Tsoufis, Christos Trapalis, Aurelio Mateo-Alonso and Maurizio Prato pp 8733–8740 DOI: 10.1021/ja8002952

Theoretical Study of the Mechanism of Hantzsch Ester Hydrogenation of Imines Catalyzed by Chiral BINOL-Phosphoric Acids Luis Simn and Jonathan M. Goodman pp 8741–8747 DOI: 10.1021/ja800793t Supporting Info

Transforming Nonselective into Chemoselective Metal Catalysts for the Hydrogenation of Substituted Nitroaromatics Avelino Corma, Pedro Serna, Patricia Concepcin and Jos Juan Calvino pp 8748–8753 DOI: 10.1021/ja800959g Supporting Info

Enantiodiscrimination in Deuterium NMR Spectra of Flexible Chiral Molecules with Average Axial Symmetry Dissolved in Chiral Liquid Crystals: The Case of Tridioxyethylenetriphenylene Philippe Lesot, Olivier Lafon, Herbert Zimmermann and Zeev Luz pp 8754–8761 DOI: 10.1021/ja800957a

Artificial DNA Made Exclusively of Nonnatural C-Nucleosides with Four Types of Nonnatural Bases Yasuhiro Doi, Junya Chiba, Tomoyuki Morikawa and Masahiko Inouye pp 8762–8768 DOI: 10.1021/ja801058h Supporting Info

Acyl Group Migration and Cleavage in Selectively Protected β-d-Galactopyranosides as Studied by NMR Spectroscopy and Kinetic Calculations Mattias U. Roslund, Olli Aitio, Johan Wrnå, Hannu Maaheimo, Dmitry Yu. Murzin and Reko Leino pp 8769–8772 DOI: 10.1021/ja801177s Supporting Info

Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions Alois Frstner, Rubn Martin, Helga Krause, Gnter Seidel, Richard Goddard and Christian W. Lehmann pp 8773–8787 DOI: 10.1021/ja801466t Supporting Info

Ruthenium Porphyrin Functionalized Single-Walled Carbon Nanotube ArraysA Step Toward Light Harvesting Antenna and Multibit Information Storage Jingxian Yu, Simon Mathew, Benjamin S. Flavel, Martin R. Johnston and Joe G. Shapter pp 8788–8796 DOI: 10.1021/ja801142k Supporting Info

Ultrafast Electron Transfer Dynamics at NH3/Cu(111) Interfaces: Determination of the Transient Tunneling Barrier Julia Sthler, Michael Meyer, Daniela O. Kusmierek, Uwe Bovensiepen and Martin Wolf pp 8797–8803 DOI: 10.1021/ja801682u Supporting Info

Context-Dependent Fluorescence Detection of a Phosphorylated Tyrosine Residue by a Ribonucleopeptide Tetsuya Hasegawa, Masaki Hagihara, Masatora Fukuda, Shun Nakano, Nobutaka Fujieda and Takashi Morii pp 8804–8812 DOI: 10.1021/ja801734f Supporting Info

A Facile Route for Creating “Reverse” Vesicles: Insights into “Reverse” Self-Assembly in Organic Liquids Shih-Huang Tung, Hee-Young Lee and Srinivasa R. Raghavan pp 8813–8817 DOI: 10.1021/ja801895n Supporting Info

Where Does the Electron Go? Electron Distribution and Reactivity of Peptide Cation Radicals Formed by Electron Transfer in the Gas phase Frantiek Tureek, Xiaohong Chen and Changtong Hao pp 8818–8833 DOI: 10.1021/ja8019005 Supporting Info

Sensitization of Ruthenium Nitrosyls to Visible Light via Direct Coordination of the Dye Resorufin: Trackable NO Donors for Light-Triggered NO Delivery to Cellular Targets Michael J. Rose, Nicole L. Fry, Rebecca Marlow, Lindsay Hinck and Pradip K. Mascharak pp 8834–8846 DOI: 10.1021/ja801823f Supporting Info

Biomimetic Nanostructures: Creating a High-Affinity Zinc-Binding Site in a Folded Nonbiological Polymer Byoung-Chul Lee, Tammy K. Chu, Ken A. Dill and Ronald N. Zuckermann pp 8847–8855 DOI: 10.1021/ja802125x Supporting Info

Asymmetric Insertion of Membrane Proteins in Lipid Bilayers by Solid-State NMR Paramagnetic Relaxation Enhancement: A Cell-Penetrating Peptide Example Yongchao Su, Rajeswari Mani and Mei Hong pp 8856–8864 DOI: 10.1021/ja802383t Supporting Info

Rapid and Enantioselective Synthetic Approaches to Germanicol and Other Pentacyclic Triterpenes Karavadhi Surendra and E. J. Corey pp 8865–8869 DOI: 10.1021/ja802730a Supporting Info

Isotopically Discriminated NMR Spectroscopy: A Tool for Investigating Complex Protein Interactions in Vitro Alexander P. Golovanov, Richard T. Blankley, Johanna M. Avis and Wolfgang Bermel p 8870 DOI: 10.1021/ja8036004 Supporting Info

Book Review of Bio-inorganic Hybrid Nanomaterials: Strategies, Synthesis, Characterization and Applications Tewodros (Teddy) Asefa p 8871 DOI: 10.1021/ja803891f

Book Review of Asymmetric Synthesis with Chemical and Biological Methods Michael Harmata pp 8871–8872 DOI: 10.1021/ja803319f

Book Review of Inorganic and Organometallic Macromolecules: Design and Application Robert H. Neilson p 8872 DOI: 10.1021/ja803965a

Book Review of Macromolecules, Volume 3: Physical Structures and Properties p 8872 DOI: 10.1021/ja803970a

Issue 28

Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates Murad A. AlDamen, Juan M. Clemente-Juan, Eugenio Coronado, Carlos Mart-Gastaldo and Alejandro Gaita-Ario pp 8874–8875 DOI: 10.1021/ja801659m Supporting Info

Photoacoustic Measurement of Electron Injection Efficiencies and Energies from Excited Sensitizer Dyes into Nanocrystalline TiO2 Films Carlos Serpa, Johann Schabauer, Ana P. Piedade, Carlos J. P. Monteiro, Mariette M. Pereira, Peter Douglas, Hugh D. Burrows and Luis G. Arnaut pp 8876–8877 DOI: 10.1021/ja801928z Supporting Info

Scanning Tunneling Microscopy Investigation of a Supramolecular Self-Assembled Three-Dimensional Chiral Prism on a Au(111) Surface Qun-Hui Yuan, Cun-Ji Yan, Hui-Juan Yan, Li-Jun Wan, Brian H. Northrop, Hershel Jude and Peter J. Stang pp 8878–8879 DOI: 10.1021/ja801934w Supporting Info

Gas-Phase Synthesis and Reactivity of a Gold Carbene Complex Alexey Fedorov, Marc-Etienne Moret and Peter Chen pp 8880–8881 DOI: 10.1021/ja802060t Supporting Info

Highly Crystalline Inverse Opal Transition Metal Oxides via a Combined Assembly of Soft and Hard Chemistries M. Christopher Orilall, Neal M. Abrams, Jinwoo Lee, Francis J. DiSalvo and Ulrich Wiesner pp 8882–8883 DOI: 10.1021/ja802093u Supporting Info

Slow Conformational Dynamics at C2′-endo Nucleotides in RNA Costin M. Gherghe, Stefanie A. Mortimer, Joseph M. Krahn, Nancy L. Thompson and Kevin M. Weeks pp 8884–8885 DOI: 10.1021/ja802691e Supporting Info

Amphiphilic Molecular Design as a Rational Strategy for Tailoring Bicontinuous Electron Donor and Acceptor Arrays: Photoconductive Liquid Crystalline Oligothiophene−C60 Dyads Wei-Shi Li, Yohei Yamamoto, Takanori Fukushima, Akinori Saeki, Shu Seki, Seiichi Tagawa, Hiroyasu Masunaga, Sono Sasaki, Masaki Takata and Takuzo Aida pp 8886–8887 DOI: 10.1021/ja802757w Supporting Info

A Monomeric MnIII−Peroxo Complex Derived Directly from Dioxygen Ryan L. Shook, William A. Gunderson, John Greaves, Joseph W. Ziller, Michael P. Hendrich and A. S. Borovik pp 8888–8889 DOI: 10.1021/ja802775e Supporting Info

Quantum Dot Solar Cells. Electrophoretic Deposition of CdSe−C60 Composite Films and Capture of Photogenerated Electrons with nC60 Cluster Shell Patrick Brown and Prashant V. Kamat pp 8890–8891 DOI: 10.1021/ja802810c Supporting Info

Nanometer Arrays of Functional Light Harvesting Antenna Complexes by Nanoimprint Lithography and Host−Guest Interactions Maryana Escalante, Yiping Zhao, Manon J. W. Ludden, Rolf Vermeij, John D. Olsen, Erwin Berenschot, C. Neil Hunter, Jurriaan Huskens, Vinod Subramaniam and Cees Otto pp 8892–8893 DOI: 10.1021/ja802843m Supporting Info

Asymmetric Hydrogenation Approaches to Valuable, Acyclic 1,3-Hydroxymethyl Chirons Ye Zhu and Kevin Burgess pp 8894–8895 DOI: 10.1021/ja802909b Supporting Info

Unusual Mechanisms Can Dominate Reactions at Hyperthermal Energies: An Example from O(3P) + HCl → ClO + H Jianming Zhang, Jon P. Camden, Amy L. Brunsvold, Hari P. Upadhyaya, Timothy K. Minton and George C. Schatz pp 8896–8897 DOI: 10.1021/ja803080q Supporting Info

Allylic Alcohols as Radical Allylating Agents. An Overall Olefination of Aldehydes and Ketones Nicolas Charrier, Batrice Quiclet-Sire and Samir Z. Zard pp 8898–8899 DOI: 10.1021/ja802899m Supporting Info

Ultrathin Gold Nanowires Can Be Obtained by Reducing Polymeric Strands of Oleylamine−AuCl Complexes Formed via Aurophilic Interaction Xianmao Lu, Mustafa S. Yavuz, Hsing-Yu Tuan, Brian A. Korgel and Younan Xia pp 8900–8901 DOI: 10.1021/ja803343m Supporting Info

Ultrathin Au Nanowires and Their Transport Properties Chao Wang, Yongjie Hu, Charles M. Lieber and Shouheng Sun pp 8902–8903 DOI: 10.1021/ja803408f Supporting Info

Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity Shin Takemoto, Shohei Otsuki, Yasuhiro Hashimoto, Ken Kamikawa and Hiroyuki Matsuzaka pp 8904–8905 DOI: 10.1021/ja8033922 Supporting Info

Electrogenerated Chemiluminescence of Single Conjugated Polymer Nanoparticles Ya-Lan Chang, Rodrigo E. Palacios, Fu-Ren F. Fan, Allen J. Bard and Paul F. Barbara pp 8906–8907 DOI: 10.1021/ja803454x Supporting Info

Biochemistry and Molecular Genetics of the Biosynthesis of the Earthy Odorant Methylisoborneol in Streptomyces coelicolor Chieh-Mei Wang and David E. Cane pp 8908–8909 DOI: 10.1021/ja803639g Supporting Info

Self-Assembly of Chiral Molecular Honeycomb Networks on Au(111) Wende Xiao, Xinliang Feng, Pascal Ruffieux, Oliver Grning, Klaus Mllen and Roman Fasel pp 8910–8912 DOI: 10.1021/ja7106542 Supporting Info

Self-Propagating Assembly of a Molecular-Based Multilayer Leila Motiei, Marc Altman, Tarkeshwar Gupta, Fabio Lupo, Antonino Gulino, Guennadi Evmenenko, Pulak Dutta and Milko E. van der Boom pp 8913–8915 DOI: 10.1021/ja802470g Supporting Info

Microwave Synthesis of CdSe and CdTe Nanocrystals in Nonabsorbing Alkanes Aaron L. Washington II and Geoffrey F. Strouse pp 8916–8922 DOI: 10.1021/ja711115r Supporting Info

Ruthenium-Catalyzed Azide−Alkyne Cycloaddition: Scope and Mechanism Brant C. Boren, Sridhar Narayan, Lars K. Rasmussen, Li Zhang, Haitao Zhao, Zhenyang Lin, Guochen Jia and Valery V. Fokin pp 8923–8930 DOI: 10.1021/ja0749993 Supporting Info

Mapping of Two Networks of Residues That Exhibit Structural and Dynamical Changes upon Binding in a PDZ Domain Protein Anne Dhulesia, Joerg Gsponer and Michele Vendruscolo pp 8931–8939 DOI: 10.1021/ja0752080 Supporting Info

Formation and Reactivity of a Persistent Radical in a Dinuclear Molybdenum Complex Aaron M. Appel, Suh-Jane Lee, James A. Franz, Daniel L. DuBois, M. Rakowski DuBois, Jerome C. Birnbaum and Brendan Twamley pp 8940–8951 DOI: 10.1021/ja078115r Supporting Info

Ligand-Tuned Regioselectivity of a Cobalt-Catalyzed Diels−Alder Reaction. A Theoretical Study Philipp Mrschel, Judith Janikowski, Gerhard Hilt and Gernot Frenking pp 8952–8966 DOI: 10.1021/ja078242n Supporting Info

Femtosecond Fluorescence and Intersystem Crossing in Rhenium(I) Carbonyl−Bipyridine Complexes Andrea Cannizzo, Ana Maria Blanco-Rodrguez, Amal El Nahhas, Jakub ebera, Stanislav Zli, Antonn Vlek, Jr. and Majed Chergui pp 8967–8974 DOI: 10.1021/ja710763w Supporting Info

Probing the Substrate Specificity of Golgi α-Mannosidase II by Use of Synthetic Oligosaccharides and a Catalytic Nucleophile Mutant Wei Zhong, Douglas A. Kuntz, Brian Ember, Harminder Singh, Kelley W. Moremen, David R. Rose and Geert-Jan Boons pp 8975–8983 DOI: 10.1021/ja711248y Supporting Info

Synthetic, Mechanistic, and Computational Investigations of Nitrile-Alkyne Cross-Metathesis Andrea M. Geyer, Eric S. Wiedner, J. Brannon Gary, Robyn L. Gdula, Nicola C. Kuhlmann, Marc J. A. Johnson, Barry D. Dunietz and Jeff W. Kampf pp 8984–8999 DOI: 10.1021/ja800020w Supporting Info

Ligand Tuning in Asymmetric Hydrovinylation of 1,3-Dienes: A Stereoselective Route to Either Steroid-C20 (S) or -C20 (R) Derivatives Biswajit Saha, Craig R. Smith and T. V. RajanBabu pp 9000–9005 DOI: 10.1021/ja711475f Supporting Info

Proton-Sponge Coated Quantum Dots for siRNA Delivery and Intracellular Imaging Maksym V. Yezhelyev, Lifeng Qi, Ruth M. O’Regan, Shuming Nie and Xiaohu Gao pp 9006–9012 DOI: 10.1021/ja800086u Supporting Info

Conduction Properties of Bipyridinium-Functionalized Molecular Wires Alexei Bagrets, Andreas Arnold and Ferdinand Evers pp 9013–9018 DOI: 10.1021/ja800459k Supporting Info

Single-Laser-Shot-Induced Complete Bidirectional Spin Transition at Room Temperature in Single Crystals of (FeII(pyrazine)(Pt(CN)4)) Saioa Cobo, Denis Ostrovskii, Sbastien Bonhommeau, Laure Vendier, Gbor Molnr, Lionel Salmon, Koichiro Tanaka and Azzedine Bousseksou pp 9019–9024 DOI: 10.1021/ja800878f Supporting Info

Combined Electrostatics and Hydrogen Bonding Determine Intermolecular Interactions Between Polyphosphoinositides Ilya Levental, Andrejs Cbers and Paul A. Janmey pp 9025–9030 DOI: 10.1021/ja800948c

Conformational Energetics of Cationic Backbone Rearrangements in Triterpenoid Biosynthesis Provide an Insight into Enzymatic Control of Product Lszl Krti, Rong-Jie Chein and E. J. Corey pp 9031–9036 DOI: 10.1021/ja800980h Supporting Info

DFT Study on Chemical N2 Fixation by Using a Cubane-Type RuIr3S4 Cluster: Energy Profile for Binding and Reduction of N2 to Ammonia via Ru−N−NHx (x = 1−3) Intermediates with Unique Structures Hiromasa Tanaka, Hiroyuki Mori, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe and Kazunari Yoshizawa pp 9037–9047 DOI: 10.1021/ja8009567 Supporting Info

Comprehensive Structural Studies of 2′,3′-Difluorinated Nucleosides: Comparison of Theory, Solution, and Solid State Joseph J. Barchi, , Rajeshri G. Karki, Marc C. Nicklaus, Maqbool A. Siddiqui, Clifford George, Igor A. Mikhailopulo and Victor E. Marquez pp 9048–9057 DOI: 10.1021/ja800964g Supporting Info

Noncovalent Interactions under Extreme Conditions: High-Pressure and Low-Temperature Diffraction Studies of the Isostructural Metal−Organic Networks (4-Chloropyridinium)2[CoX4] (X = Cl, Br) Guillermo Mínguez Espallargas, Lee Brammer, David R. Allan, Colin R. Pulham, Neil Robertson and John E. Warren pp 9058–9071 DOI: 10.1021/ja8010868 Supporting Info

Backbone Dynamics in the DNA HhaI Protein Binding Site Kari Pederson, Gary A. Meints, Zahra Shajani, Paul A. Miller and Gary P. Drobny pp 9072–9079 DOI: 10.1021/ja801243d

Intrinsic Diffusion of Hydrogen on Rutile TiO2(110) Shao-Chun Li, Zhenrong Zhang, Daniel Sheppard, Bruce D. Kay, J. M. White, Yingge Du, Igor Lyubinetsky, Graeme Henkelman and Zdenek Dohnlek pp 9080–9088 DOI: 10.1021/ja8012825 Supporting Info

Ranging Correlated Motion (1.5 nm) of Two Coaxially Arranged Rotors Mediated by Helix Inversion of a Supramolecular Transmitter Shuichi Hiraoka, Erika Okuno, Takaaki Tanaka, Motoo Shiro and Mitsuhiko Shionoya pp 9089–9098 DOI: 10.1021/ja8014583 Supporting Info

Diarylnitroxide Diradicals: Low-Temperature Oxidation of Diarylamines to Nitroxides Andrzej Rajca, Matthew Vale and Suchada Rajca pp 9099–9105 DOI: 10.1021/ja8016335 Supporting Info

Site-Specific 18F-Labeling of the Protein Hormone Leptin Using a General Two-Step Ligation Procedure Robert R. Flavell, Paresh Kothari, Maya Bar-Dagan, Michael Synan, Shankar Vallabhajosula, Jeffrey M. Friedman, Tom W. Muir and Giovanni Ceccarini pp 9106–9112 DOI: 10.1021/ja801666z Supporting Info

Low-Molecular-Weight Gelators: Elucidating the Principles of Gelation Based on Gelator Solubility and a Cooperative Self-Assembly Model Andrew R. Hirst, Ian A. Coates, Thomas R. Boucheteau, Juan F. Miravet, Beatriu Escuder, Valeria Castelletto, Ian W. Hamley and David K. Smith pp 9113–9121 DOI: 10.1021/ja801804c Supporting Info

Reactivity and Infrared Spectroscopy of Gaseous Hydrated Trivalent Metal Ions Matthew F. Bush, Richard J. Saykally and Evan R. Williams pp 9122–9128 DOI: 10.1021/ja801894d Supporting Info

Chemical Understanding of a Non-IPR Metallofullerene: Stabilization of Encaged Metals on Fused-Pentagon Bonds in La2@C72 Xing Lu, Hidefumi Nikawa, Tsukasa Nakahodo, Takahiro Tsuchiya, Midori O. Ishitsuka, Yutaka Maeda, Takeshi Akasaka, Makoto Toki, Hiroshi Sawa, Zdenek Slanina, Naomi Mizorogi and Shigeru Nagase pp 9129–9136 DOI: 10.1021/ja8019577 Supporting Info

Aptamer-Facilitated Biomarker Discovery (AptaBiD) Maxim V. Berezovski, Matthias Lechmann, Michael U. Musheev, Tak W. Mak and Sergey N. Krylov pp 9137–9143 DOI: 10.1021/ja801951p

The Role of the 5f Orbitals in Bonding, Aromaticity, and Reactivity of Planar Isocyclic and Heterocyclic Uranium Clusters Athanassios C. Tsipis, Christos E. Kefalidis and Constantinos A. Tsipis pp 9144–9155 DOI: 10.1021/ja802344z Supporting Info

Probing the Electronic Structure and Chemical Bonding of Gold Oxides and Sulfides in AuOn− and AuSn− (n = 1, 2) Hua-Jin Zhai, Christian Brgel, Vlasta Bonacic-Koutecky and Lai-Sheng Wang pp 9156–9167 DOI: 10.1021/ja802408b Supporting Info

Ab Initio/GIAO-CCSD(T) Study of Structures, Energies, and 13C NMR Chemical Shifts of C4H7+ and C5H9+ Ions: Relative Stability and Dynamic Aspects of the Cyclopropylcarbinyl vs Bicyclobutonium Ions George A. Olah, G. K. Surya Prakash and Golam Rasul pp 9168–9172 DOI: 10.1021/ja802445s Supporting Info

Synthesis and Self-Association Properties of Functionalized C3-Symmetric Hexakis(p-substituted-phenylethynyl)triindoles Eva M. Garca-Frutos and Berta Gmez-Lor pp 9173–9177 DOI: 10.1021/ja8025399 Supporting Info

Contact Model for the Prediction of NMR N−H Order Parameters in Globular Proteins Fengli Zhang and Rafael Brschweiler p 9178 DOI: 10.1021/ja8020445 Supporting Info

Issue 29

An “Anti-Baldwin” 3-Exo-Dig Cyclization: Preparation of Vinylidene Cyclopropanes from Electron-Poor Alkenes Matthew J. Campbell, Patrick D. Pohlhaus, Geanna Min, Kohsuke Ohmatsu and Jeffrey S. Johnson pp 9180–9181 DOI: 10.1021/ja803553a Supporting Info

Oxygen-Directed Intramolecular Hydroboration Robert-Andr F. Rarig, Matthew Scheideman and Edwin Vedejs pp 9182–9183 DOI: 10.1021/ja800402g Supporting Info

Highly Stable Organic Modification of Si(111) Surfaces: Towards Reacting Si with Further Functionalities while Preserving the Desirable Chemical Properties of Full Si−C Atop Site Terminations Sreenivasa Reddy Puniredd, Ossama Assad and Hossam Haick pp 9184–9185 DOI: 10.1021/ja800855s

Ligand-Directed Nanobialys as Theranostic Agent for Drug Delivery and Manganese-Based Magnetic Resonance Imaging of Vascular Targets Dipanjan Pan, Shelton D. Caruthers, Grace Hu, Angana Senpan, Mike J. Scott, Patrick J. Gaffney, Samuel A. Wickline and Gregory M. Lanza pp 9186–9187 DOI: 10.1021/ja801482d Supporting Info

Oxygen Reactivity of the Biferrous Site in the de novo Designed Four Helix Bundle Peptide DFsc: Nature of the “Intermediate” and Reaction Mechanism Jennifer R. Calhoun, Caleb B. Bell, , Thomas J. Smith, Thomas J. Thamann, William F. DeGrado and Edward I. Solomon pp 9188–9189 DOI: 10.1021/ja801657y Supporting Info

Detection of Trace Hg2+ via Induced Circular Dichroism of DNA Wrapped Around Single-Walled Carbon Nanotubes Xueyun Gao, Gengmei Xing, Yanlian Yang, Xiaoli Shi, Ru Liu, Weiguo Chu, Long Jing, Feng Zhao, Chang Ye, Hui Yuan, Xiaohong Fang, Chen Wang and Yuliang Zhao pp 9190–9191 DOI: 10.1021/ja801793k Supporting Info

Azobenzenes as Light-Controlled Molecular Electronic Switches in Nanoscale Metal−Molecule−Metal Junctions Jeffrey M. Mativetsky, Giuseppina Pace, Mark Elbing, Maria A. Rampi, Marcel Mayor and Paolo Samorì pp 9192–9193 DOI: 10.1021/ja8018093 Supporting Info

The Rate Ladder of Proton-Coupled Tyrosine Oxidation in Water: A Systematic Dependence on Hydrogen Bonds and Protonation State Tania Irebo, Olof Johansson and Leif Hammarstrm pp 9194–9195 DOI: 10.1021/ja802076v Supporting Info

Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes Lauren M. Huffman and Shannon S. Stahl pp 9196–9197 DOI: 10.1021/ja802123p Supporting Info

Light-Controlled Organic/Inorganic P−N Junction Nanowires Yanbing Guo, Qingxin Tang, Huibiao Liu, Yajie Zhang, Yuliang Li, Wenping Hu, Shu Wang and Daoben Zhu pp 9198–9199 DOI: 10.1021/ja8021494 Supporting Info

An Unexpected Switch in the Modulation of AI-2-Based Quorum Sensing Discovered through Synthetic 4,5-Dihydroxy-2,3-pentanedione Analogues Colin A. Lowery, Junguk Park, Gunnar F. Kaufmann and Kim D. Janda pp 9200–9201 DOI: 10.1021/ja802353j Supporting Info

An Organic Sensitizer with a Fused Dithienothiophene Unit for Efficient and Stable Dye-Sensitized Solar Cells Hao Qin, Sophie Wenger, Mingfei Xu, Feifei Gao, Xiaoyan Jing, Peng Wang, Shaik M. Zakeeruddin and Michael Grtzel pp 9202–9203 DOI: 10.1021/ja8024438 Supporting Info

A Photoactivatable Push−Pull Fluorophore for Single-Molecule Imaging in Live Cells Samuel J. Lord, Nicholas R. Conley, Hsiao-lu D. Lee, Reichel Samuel, Na Liu, Robert J. Twieg and W. E. Moerner pp 9204–9205 DOI: 10.1021/ja802883k Supporting Info

Complete Structural Characterization of Metallacyclic Complexes in Solution-Phase Using Simultaneously X-ray Diffraction and Molecular Dynamics Simulation Tnde Megyes, Szabolcs Blint, Imre Bak, Tams Grsz and Gbor Plinks pp 9206–9207 DOI: 10.1021/ja802793g Supporting Info

Spectroscopic Observation of Atomic Hydrogen Radicals Entrapped in Icy Hydrogen Hydrate Sun-Hwa Yeon, Jiwoong Seol, Youngjune Park, Dong-Yeun Koh, Young Soo Kang and Huen Lee pp 9208–9209 DOI: 10.1021/ja802952p

Catalytic Scaffolding Ligands: An Efficient Strategy for Directing Reactions Thomas E. Lightburn, Michael T. Dombrowski and Kian L. Tan pp 9210–9211 DOI: 10.1021/ja803011d Supporting Info

Co-opting the Cell Wall in Fighting Methicillin-Resistant Staphylococcus aureus: Potent Inhibition of PBP 2a by Two Anti-MRSA β-Lactam Antibiotics Adriel Villegas-Estrada, Mijoon Lee, Dusan Hesek, Sergei B. Vakulenko and Shahriar Mobashery pp 9212–9213 DOI: 10.1021/ja8029448 Supporting Info

Electron Transfer-Initiated Diels−Alder Cycloadditions of 2′-Hydroxychalcones Huan Cong, Dustin Ledbetter, Gerard T. Rowe, John P. Caradonna and John A. Porco, pp 9214–9215 DOI: 10.1021/ja803094u Supporting Info

Sol−Gel Synthesis of Low-Dimensional Silica within Coordination Nanochannels Takashi Uemura, Daisuke Hiramatsu, Kaname Yoshida, Seiji Isoda and Susumu Kitagawa pp 9216–9217 DOI: 10.1021/ja8030906 Supporting Info

9-Borabicyclo[3.3.2]decanes and the Asymmetric Hydroboration of 1,1-Disubstituted Alkenes Ana Z. Gonzalez, Jos G. Romn, Eduvigis Gonzalez, Judith Martinez, Jesus R. Medina, Karl Matos and John A. Soderquist pp 9218–9219 DOI: 10.1021/ja803119p Supporting Info

A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination David N. Zalatan and J. Du Bois pp 9220–9221 DOI: 10.1021/ja8031955 Supporting Info

[4 + 2] Cycloadditions of N-Alkenyl Iminium Ions: Structurally Complex Heterocycles from a Three-Component Diels−Alder Reaction Sequence Nihar Sarkar, Abhisek Banerjee and Scott G. Nelson pp 9222–9223 DOI: 10.1021/ja8028153 Supporting Info

Silicon Nanowire Radial p−n Junction Solar Cells Erik C. Garnett and Peidong Yang pp 9224–9225 DOI: 10.1021/ja8032907 Supporting Info

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex Elisa Calimano and T. Don Tilley pp 9226–9227 DOI: 10.1021/ja803332h Supporting Info

Enantioselective Claisen Rearrangements with a Hydrogen-Bond Donor Catalyst Christopher Uyeda and Eric N. Jacobsen pp 9228–9229 DOI: 10.1021/ja803370x Supporting Info

ortho-Quinone Methides from para-Quinones: Total Synthesis of Rubioncolin B Jean-Philip Lumb, Kevin C. Choong and Dirk Trauner pp 9230–9231 DOI: 10.1021/ja803498r Supporting Info

High-Throughput Screening of Identity, Enantiomeric Excess, and Concentration Using MLCT Transitions in CD Spectroscopy Sonia Nieto, Vincent M. Lynch, Eric V. Anslyn, Hyunwoo Kim and Jik Chin pp 9232–9233 DOI: 10.1021/ja803443j Supporting Info

Biomimetic Seleninates and Selenonates Mohannad Abdo and Spencer Knapp pp 9234–9235 DOI: 10.1021/ja8034448 Supporting Info

Electron Transport and Electrochemistry of Mesomorphic Fullerenes with Long-Range Ordered Lamellae Takashi Nakanishi, Yanfei Shen, Jiaobing Wang, Shiki Yagai, Masahiro Funahashi, Takashi Kato, Paulo Fernandes, Helmuth Mhwald and Dirk G. Kurth pp 9236–9237 DOI: 10.1021/ja803593j Supporting Info

Enantioselective Total Synthesis of Lycopodine Hua Yang, Rich G. Carter and Lev N. Zakharov pp 9238–9239 DOI: 10.1021/ja803613w Supporting Info

Ternary I−III−VI Quantum Dots Luminescent in the Red to Near-Infrared Peter M. Allen and Moungi G. Bawendi pp 9240–9241 DOI: 10.1021/ja8036349 Supporting Info

Doping Dependence of the Pressure Response of Tc in the SmO1-xFxFeAs Superconductors Yasuhiro Takabayashi, Martin T. McDonald, Dionisis Papanikolaou, Serena Margadonna, G. Wu, R. H. Liu, X. H. Chen and Kosmas Prassides pp 9242–9243 DOI: 10.1021/ja8036838 Supporting Info

Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation Nathan D. Shapiro and F. Dean Toste pp 9244–9245 DOI: 10.1021/ja803890t Supporting Info

A Brønsted Acid Catalyst for the Enantioselective Protonation Reaction Cheol Hong Cheon and Hisashi Yamamoto pp 9246–9247 DOI: 10.1021/ja8041542 Supporting Info

Carbon Avoids Hypercoordination in CB6−, CB62−, and C2B5− Planar Carbon−Boron Clusters Boris B. Averkiev, Dmitry Yu. Zubarev, Lei-Ming Wang, Wei Huang, Lai-Sheng Wang and Alexander I. Boldyrev pp 9248–9250 DOI: 10.1021/ja801211p Supporting Info

Protein−Protein Interaction Detection in Vitro and in Cells by Proximity Biotinylation Marta Fernndez-Surez, T. Scott Chen and Alice Y. Ting pp 9251–9253 DOI: 10.1021/ja801445p Supporting Info

Palladium-Catalyzed C−H Functionalization of Pyridine N-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes Seung Hwan Cho, Seung Jun Hwang and Sukbok Chang pp 9254–9256 DOI: 10.1021/ja8026295 Supporting Info

Efficient Cross-Coupling of Secondary Alkyltrifluoroborates with Aryl ChloridesReaction Discovery Using Parallel Microscale Experimentation Spencer D. Dreher, Peter G. Dormer, Deidre L. Sandrock and Gary A. Molander pp 9257–9259 DOI: 10.1021/ja8031423 Supporting Info

Rational Design of Protein-Based MRI Contrast Agents Jenny J. Yang, Jianhua Yang, Lixia Wei, Omar Zurkiya, Wei Yang, Shunyi Li, Jin Zou, Yubin Zhou, Anna L Wilkins Maniccia, Hui Mao, Fuqiang Zhao, Russell Malchow, Shumin Zhao, Julian Johnson, Xiaoping Hu, Eirik Krogstad and Zhi-Ren Liu pp 9260–9267 DOI: 10.1021/ja800736h Supporting Info

In vivo Incorporation of Unnatural Amino Acids to Probe Structure, Dynamics, and Ligand Binding in a Large Protein by Nuclear Magnetic Resonance Spectroscopy Susan E. Cellitti, David H. Jones, Leanna Lagpacan, Xueshi Hao, Qiong Zhang, Huiyong Hu, Scott M. Brittain, Achim Brinker, Jeremy Caldwell, Badry Bursulaya, Glen Spraggon, Ansgar Brock, Youngha Ryu, Tetsuo Uno, Peter G. Schultz and Bernhard H. Geierstanger pp 9268–9281 DOI: 10.1021/ja801602q Supporting Info

Calcium-43 Chemical Shift Tensors as Probes of Calcium Binding Environments. Insight into the Structure of the Vaterite CaCO3 Polymorph by 43Ca Solid-State NMR Spectroscopy David L. Bryce, Elijah B. Bultz and Dominic Aebi pp 9282–9292 DOI: 10.1021/ja8017253 Supporting Info

Investigation of the Mechanism of the Cell Wall dd-Carboxypeptidase Reaction of Penicillin-Binding Protein 5 of Escherichia coli by Quantum Mechanics/Molecular Mechanics Calculations Qicun Shi, Samy O. Meroueh, Jed F. Fisher and Shahriar Mobashery pp 9293–9303 DOI: 10.1021/ja801727k Supporting Info

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations Thomas Schaub, Peter Fischer, Andreas Steffen, Thomas Braun, Udo Radius and Andreas Mix pp 9304–9317 DOI: 10.1021/ja074640e Supporting Info

Conformational Control of the QA to QB Electron Transfer in Bacterial Reaction Centers: Evidence for a Frozen Conformational Landscape below −25 °C Nicolas Ginet* and Jrme Lavergne* pp 9318–9331 DOI: 10.1021/ja076504f

Characterization of Mg2+ Binding to the DNA Repair Protein Apurinic/Apyrimidic Endonuclease 1 via Solid-State 25Mg NMR Spectroscopy A. S. Lipton, R. W. Heck, S. Primak, D. R. McNeill, D. M. Wilson, and P. D. Ellis pp 9332–9341 DOI: 10.1021/ja0776881 Supporting Info

How the C−O Bond Breaks during Methanol Decomposition on Nanocrystallites of Palladium Catalysts Ilya V. Yudanov, Alexei V. Matveev, Konstantin M. Neyman and Notker Rsch pp 9342–9352 DOI: 10.1021/ja078322r Supporting Info

Water Activity Regulates the QA− to QB Electron Transfer in Photosynthetic Reaction Centers from Rhodobacter sphaeroides Gerardo Palazzo, Francesco Francia, Antonia Mallardi, Mauro Giustini, Francesco Lopez and Giovanni Venturoli pp 9353–9363 DOI: 10.1021/ja801963a Supporting Info

Single-Molecule Motions of Oligoarginine Transporter Conjugates on the Plasma Membrane of Chinese Hamster Ovary Cells H.-L. Lee, E. A. Dubikovskaya, H. Hwang, A. N. Semyonov, H. Wang, L. R. Jones, R. J. Twieg, W. E. Moerner and P. A. Wender pp 9364–9370 DOI: 10.1021/ja710798b Supporting Info

Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution−HOPG Interface Ryota Arai, Shinobu Uemura, Masahiro Irie and Kenji Matsuda pp 9371–9379 DOI: 10.1021/ja711041p Supporting Info

Potential Energy Surfaces for All-trans P5H6+ and P5Me6+ May Be Less Complicated than Anticipated Qian-Shu Li, Zhifeng Pu, Yaoming Xie, Paul von Rague Schleyer and Henry F. Schaefer pp 9380–9385 DOI: 10.1021/ja800177p Supporting Info

Noncovalent Triblock Copolymers Based on a Coiled-Coil Peptide Motif Hana Robson Marsden, Alexander V. Korobko, Ellen N. M. van Leeuwen, Emilie M. Pouget, Sandra J. Veen, Nico A. J. M. Sommerdijk and Alexander Kros pp 9386–9393 DOI: 10.1021/ja800254w Supporting Info

Shining Light on Dinitrogen Cleavage: Structural Features, Redox Chemistry, and Photochemistry of the Key Intermediate Bridging Dinitrogen Complex John J. Curley, Timothy R. Cook, Steven Y. Reece, Peter Mller and Christopher C. Cummins pp 9394–9405 DOI: 10.1021/ja8002638 Supporting Info

Orbital Views of the Electron Transport in Molecular Devices Kazunari Yoshizawa, Tomofumi Tada and Aleksandar Staykov pp 9406–9413 DOI: 10.1021/ja800638t Supporting Info

Effect of Confinement in Carbon Nanotubes on the Activity of Fischer−Tropsch Iron Catalyst Wei Chen, Zhongli Fan, Xiulian Pan and Xinhe Bao pp 9414–9419 DOI: 10.1021/ja8008192 Supporting Info

A Case for Using Randomly Labeled Polymers to Study Long-Range Polymer Chain Dynamics by Fluorescence Mark Ingratta, Jon Hollinger and Jean Duhamel pp 9420–9428 DOI: 10.1021/ja800897m Supporting Info

Palladium-Catalyzed Oxidative Carbonylation of Alkyl and Aryl Indium Reagents with CO under Mild Conditions Yingsheng Zhao, Liqun Jin, Peng Li and Aiwen Lei pp 9429–9433 DOI: 10.1021/ja801116s Supporting Info

Systematic Studies on Structural Parameters for Nanotubular Assembly of Hexa-peri-hexabenzocoronenes Wusong Jin, Yohei Yamamoto, Takanori Fukushima, Noriyuki Ishii, Jungeun Kim, Kenichi Kato, Masaki Takata and Takuzo Aida pp 9434–9440 DOI: 10.1021/ja801179e Supporting Info

Spectroscopic Definition of the Ferroxidase Site in M Ferritin: Comparison of Binuclear Substrate vs Cofactor Active Sites Jennifer K. Schwartz, Xiaofeng S. Liu, Takehiko Tosha, Elizabeth C. Theil and Edward I. Solomon pp 9441–9450 DOI: 10.1021/ja801251q Supporting Info

Androgynous Porphyrins. Silver(II) Quinoxalinoporphyrins Act as Both Good Electron Donors and Acceptors Shunichi Fukuzumi, Kei Ohkubo, Weihua Zhu, Maxine Sintic, Tony Khoury, Paul J. Sintic, Wenbo E, Zhongping Ou, Maxwell J. Crossley and Karl M. Kadish pp 9451–9458 DOI: 10.1021/ja801318b Supporting Info

Inner-Sphere Mechanism for Molecular Oxygen Reduction Catalyzed by Copper Amine Oxidases Arnab Mukherjee, Valeriy V. Smirnov, Michael P. Lanci, Doreen E. Brown, Eric M. Shepard, David M. Dooley and Justine P. Roth pp 9459–9473 DOI: 10.1021/ja801378f Supporting Info

Conformational Changes and Gating at the Selectivity Filter of Potassium Channels Carmen Domene, Michael L. Klein, Davide Branduardi, Francesco L. Gervasio and Michele Parrinello pp 9474–9480 DOI: 10.1021/ja801792g Supporting Info

Nanoscale Co-organization of Quantum Dots and Conjugated Polymers Using Polymeric Micelles As Templates Mingfeng Wang, Sandeep Kumar, Anna Lee, Neda Felorzabihi, Lei Shen, Fei Zhao, Pablo Froimowicz, Gregory D. Scholes and Mitchell A. Winnik pp 9481–9491 DOI: 10.1021/ja801931m Supporting Info

Optimization of Azoles as Anti-Human Immunodeficiency Virus Agents Guided by Free-Energy Calculations Jacob G. Zeevaart, Ligong Wang, Vinay V. Thakur, Cheryl S. Leung, Julian Tirado-Rives, Christopher M. Bailey, Robert A. Domaoal, Karen S. Anderson and William L. Jorgensen pp 9492–9499 DOI: 10.1021/ja8019214 Supporting Info

Photovoltage Mechanism for Room Light Conversion of Citrate Stabilized Silver Nanocrystal Seeds to Large Nanoprisms Xiaomu Wu, Peter L. Redmond, Haitao Liu, Yihui Chen, Michael Steigerwald and Louis Brus pp 9500–9506 DOI: 10.1021/ja8018669 Supporting Info

Changes in Conformational Dynamics of mRNA upon AtGRP7 Binding Studied by Fluorescence Correlation Spectroscopy Mark Schttpelz, Jan C. Schning, Sren Doose, Hannes Neuweiler, Elisabeth Peters, Dorothee Staiger and Markus Sauer pp 9507–9513 DOI: 10.1021/ja801994z Supporting Info

Dioxygen Activation at a Mononuclear Cu(I) Center Embedded in the Calix[6]arene-Tren Core Guillaume Izzet, Joceline Zeitouny, Huriye Akdas-Killig, Yves Frapart, Stphane Mnage, Bndicte Douziech, Ivan Jabin, Yves Le Mest and Olivia Reinaud pp 9514–9523 DOI: 10.1021/ja8019406 Supporting Info

P2 Addition to Terminal Phosphide MP Triple Bonds: A Rational Synthesis of cyclo-P3 Complexes Nicholas A. Piro and Christopher C. Cummins pp 9524–9535 DOI: 10.1021/ja802080m Supporting Info

Natively Unfolded Protein Stability as a Coil-to-Globule Transition in Charge/Hydropathy Space Henry S. Ashbaugh and Harold W. Hatch pp 9536–9542 DOI: 10.1021/ja802124e Supporting Info

Microfluidic Fabrication of Monodisperse Biocompatible and Biodegradable Polymersomes with Controlled Permeability Ho Cheung Shum, Jin-Woong Kim and David A. Weitz pp 9543–9549 DOI: 10.1021/ja802157y Supporting Info

Effects of Ion Solvation and Volume Change of Reaction on the Equilibrium and Morphology in Cation-Exchange Reaction of Nanocrystals Stacey E. Wark, Chih-Hao Hsia and Dong Hee Son pp 9550–9555 DOI: 10.1021/ja802187c Supporting Info

Synthesis of an Oligodeoxyribonucleotide Adduct of Mitomycin C by the Postoligomerization Method via a Triamino Mitosene Elise Champeil, Manuel M. Paz, Sweta Ladwa, Cristina C. Clement, Andrzej Zatorski and Maria Tomasz pp 9556–9565 DOI: 10.1021/ja802118p Supporting Info

Selective Recognition of Alkyl Pyranosides in Protic and Aprotic Solvents Prakash B. Palde, Peter C. Gareiss and Benjamin L. Miller pp 9566–9573 DOI: 10.1021/ja802229f Supporting Info

Supramolecular Control of Split-GFP Reassembly by Conjugation of β-Cyclodextrin and Coumarin Units Seiji Sakamoto and Kazuaki Kudo pp 9574–9582 DOI: 10.1021/ja802313a Supporting Info

Peptide−Nanowire Hybrid Materials for Selective Sensing of Small Molecules Michael C. McAlpine, Heather D. Agnew, Rosemary D. Rohde, Mario Blanco, Habib Ahmad, Andreea D. Stuparu, William A. Goddard, and James R. Heath pp 9583–9589 DOI: 10.1021/ja802506d Supporting Info

Mechanism of Ligand Photodissociation in Photoactivable [Ru(bpy)2L2]2+ Complexes: A Density Functional Theory Study Luca Salassa, Claudio Garino, Giovanni Salassa, Roberto Gobetto and Carlo Nervi pp 9590–9597 DOI: 10.1021/ja8025906 Supporting Info

Enzymatic Ligation Creates Discrete Multinanoparticle Building Blocks for Self-Assembly Shelley A. Claridge, Alexander J. Mastroianni, Yeung B. Au, Huiyang W. Liang, Christine M. Micheel, Jean M. J. Frchet and A. Paul Alivisatos pp 9598–9605 DOI: 10.1021/ja8026746 Supporting Info

Stoichiometry and Physical Chemistry of Promiscuous Aggregate-Based Inhibitors Kristin E. D. Coan and Brian K. Shoichet pp 9606–9612 DOI: 10.1021/ja802977h

Orthogonal Pd- and Cu-Based Catalyst Systems for C- and N-Arylation of Oxindoles Ryan A. Altman, Alan M. Hyde, Xiaohua Huang and Stephen L. Buchwald pp 9613–9620 DOI: 10.1021/ja803179s Supporting Info

Issue 30

New Nucleotide Pairs for Stable DNA Triplexes Stabilized by Stacking Interaction Masahiro Mizuta, Jun-ichi Banba, Takashi Kanamori, Ryuya Tawarada, Akihiro Ohkubo, Mitsuo Sekine and Kohji Seio pp 9622–9623 DOI: 10.1021/ja800991m Supporting Info

Detection and Relative Quantification of Proteins by Surface Enhanced Raman Using Isotopic Labels Shirshendu K. Deb, Brandon Davis, Giselle M. Knudsen, Ravindra Gudihal, Dor Ben-Amotz and V. Jo Davisson pp 9624–9625 DOI: 10.1021/ja800772p Supporting Info

Hydrogen Adsorption in a Highly Stable Porous Rare-Earth Metal-Organic Framework: Sorption Properties and Neutron Diffraction Studies Junhua Luo, Hongwu Xu, Yun Liu, Yusheng Zhao, Luke L. Daemen, Craig Brown, Tatiana V. Timofeeva, Shengqian Ma and Hong-Cai Zhou pp 9626–9627 DOI: 10.1021/ja801411f Supporting Info

Cooperative Melting in Caged Dimers of Rigid Small Molecule-DNA Hybrids Brian R. Stepp, Julianne M. Gibbs-Davis, Dorothea L. F. Koh and SonBinh T. Nguyen pp 9628–9629 DOI: 10.1021/ja801572n Supporting Info

Gallium−Sulfide Supertetrahedral Clusters as Building Blocks of Covalent Organic−Inorganic Networks Paz Vaqueiro and M. Lucia Romero pp 9630–9631 DOI: 10.1021/ja801619e Supporting Info

Growth of Narrowly Dispersed Porphyrin Nanowires and Their Hierarchical Assembly into Macroscopic Columns Suk Joong Lee, Joseph T. Hupp and SonBinh T. Nguyen pp 9632–9633 DOI: 10.1021/ja801733t Supporting Info

Evidence for Hydroxyl Radical Generation During Lipid (Linoleate) Peroxidation Mathieu Frenette and Juan C. Scaiano pp 9634–9635 DOI: 10.1021/ja801858e Supporting Info

Self-Assembled Monolayer-Assisted Chemical Transfer of In Situ Functionalized Carbon Nanotubes Wei Lin, Yonghao Xiu, Hongjin Jiang, Rongwei Zhang, Owen Hildreth, Kyoung-Sik Moon and C. P. Wong pp 9636–9637 DOI: 10.1021/ja802142g Supporting Info

A Targetable Fluorescent Probe for Imaging Hydrogen Peroxide in the Mitochondria of Living Cells Bryan C. Dickinson and Christopher J. Chang pp 9638–9639 DOI: 10.1021/ja802355u Supporting Info

A Cyclopentadienide Analogue Containing Divalent Germanium and a Heavy Cyclobutadiene-like Dianion with an Unusual Ge4 Core Wenyuan Wang, Shenglai Yao, Christoph van Wllen and Matthias Driess pp 9640–9641 DOI: 10.1021/ja802502b Supporting Info

Allyl Sulfides Are Privileged Substrates in Aqueous Cross-Metathesis: Application to Site-Selective Protein Modification Yuya A. Lin, Justin M. Chalker, Nicola Floyd, Gonalo J. L. Bernardes and Benjamin G. Davis pp 9642–9643 DOI: 10.1021/ja8026168 Supporting Info

A New Approach to Amplified Telomerase Detection with Polyvalent Oligonucleotide Nanoparticle Conjugates Gengfeng Zheng, Weston L. Daniel and Chad A. Mirkin pp 9644–9645 DOI: 10.1021/ja803035p Supporting Info

Self-Promoted DNA Interstrand Cross-Link Formation by an Abasic Site Jonathan T. Sczepanski, Aaron C. Jacobs and Marc M. Greenberg pp 9646–9647 DOI: 10.1021/ja8030642 Supporting Info

Synthesis and Properties of Supramolecular Ionic Networks Michel Wathier and Mark W. Grinstaff pp 9648–9649 DOI: 10.1021/ja803248q Supporting Info

Identification of Strong DNA Binding Motifs for Bleomycin Yoshitsugu Akiyama, Qian Ma, Erin Edgar, Andrei Laikhter and Sidney M. Hecht pp 9650–9651 DOI: 10.1021/ja802905g Supporting Info

Cyclin A Probes by Means of Intermolecular Sensitization of Terbium-Chelating Peptides Elena Pazos, Daniel Torrecilla, Miguel Vzquez Lpez, Luis Castedo, Jos L. Mascareas, Anxo Vidal and M. Eugenio Vzquez pp 9652–9653 DOI: 10.1021/ja803520q Supporting Info

Selective Functionalization of a Genetically Encoded Alkene-Containing Protein via “Photoclick Chemistry” in Bacterial Cells Wenjiao Song, Yizhong Wang, Jun Qu and Qing Lin pp 9654–9655 DOI: 10.1021/ja803598e Supporting Info

Comparing the Structural Topology of Integral and Peripheral Membrane Proteins Utilizing Electron Paramagnetic Resonance Spectroscopy Daniel J. Mayo, Johnson J. Inbaraj, Nidhi Subbaraman, Stuart M. Grosser, Christopher A. Chan and Gary A. Lorigan pp 9656–9657 DOI: 10.1021/ja803590w Supporting Info

Surface Phases and Photocatalytic Activity Correlation of Bi2O3/Bi2O4-x Nanocomposite Abdul Hameed, Tiziano Montini, Valentina Gombac and Paolo Fornasiero pp 9658–9659 DOI: 10.1021/ja803603y Supporting Info

Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues Andrew L. Goodwin, David A. Keen, Matthew G. Tucker, Martin T. Dove, Lars Peters and John S. O. Evans pp 9660–9661 DOI: 10.1021/ja803623u Supporting Info

Dehydrogenative Cyclocondensation of Aldehydes, Alkynes, and Dialkylsilanes Ryan D. Baxter and John Montgomery pp 9662–9663 DOI: 10.1021/ja803774s Supporting Info

Deconstructing Green Fluorescent Protein Kevin P. Kent, William Childs and Steven G. Boxer pp 9664–9665 DOI: 10.1021/ja803782x Supporting Info

The Trapezoidal Cylinder Phase: A New Mode of Self-Assembly in Liquid-Crystalline Soft Matter Feng Liu, Bin Chen, Benjamin Glettner, Marko Prehm, Malay Kumar Das, Ute Baumeister, Xiangbing Zeng, Goran Ungar and Carsten Tschierske pp 9666–9667 DOI: 10.1021/ja8038932 Supporting Info

Stabilization of Ketone and Aldehyde Enols by Formation of Hydrogen Bonds to Phosphazene Enolates and Their Aldol Products Kristopher J. Kolonko and Hans J. Reich pp 9668–9669 DOI: 10.1021/ja804221x Supporting Info

Detection of Innersphere Interactions between Magnesium Hydrate and the Phosphate Backbone of the HDV Ribozyme Using Raman Crystallography Bo Gong, Yuanyuan Chen, Eric L. Christian, Jui-Hui Chen, Elaine Chase, Durga M. Chadalavada, Rieko Yajima, Barbara L. Golden, Philip C. Bevilacqua and Paul R. Carey pp 9670–9672 DOI: 10.1021/ja801861s Supporting Info

Au−PbS Core−Shell Nanocrystals: Plasmonic Absorption Enhancement and Electrical Doping via Intra-particle Charge Transfer Jong-Soo Lee, Elena V. Shevchenko and Dmitri V. Talapin pp 9673–9675 DOI: 10.1021/ja802890f Supporting Info

Structural Insight into RNA Hairpin Folding Intermediates Gregory R. Bowman, Xuhui Huang, Yuan Yao, Jian Sun, Gunnar Carlsson, Leonidas J. Guibas and Vijay S. Pande pp 9676–9678 DOI: 10.1021/ja8032857 Supporting Info

n-Channel Polymers by Design: Optimizing the Interplay of Solubilizing Substituents, Crystal Packing, and Field-Effect Transistor Characteristics in Polymeric Bithiophene-Imide Semiconductors Joseph A. Letizia, Michael R. Salata, Caitlin M. Tribout, Antonio Facchetti, Mark A. Ratner and Tobin J. Marks pp 9679–9694 DOI: 10.1021/ja710815a Supporting Info

X-ray Structure of Snow Flea Antifreeze Protein Determined by Racemic Crystallization of Synthetic Protein Enantiomers Brad L. Pentelute, Zachary P. Gates, Valentina Tereshko, Jennifer L. Dashnau, Jane M. Vanderkooi, Anthony A. Kossiakoff and Stephen B. H. Kent pp 9695–9701 DOI: 10.1021/ja8013538

Mirror Image Forms of Snow Flea Antifreeze Protein Prepared by Total Chemical Synthesis Have Identical Antifreeze Activities Brad L. Pentelute, Zachary P. Gates, Jennifer L. Dashnau, Jane M. Vanderkooi and Stephen B. H. Kent pp 9702–9707 DOI: 10.1021/ja801352j Supporting Info

A DFT Study on the Formation of a Phosphohistidine Intermediate in Prostatic Acid Phosphatase Satyan Sharma, Arvi Rauk and Andr H. Juffer pp 9708–9716 DOI: 10.1021/ja710047a Supporting Info

A Dramatic Switch of Enantioselectivity in Asymmetric Heck Reaction by Benzylic Substituents of Ligands Wen-Qiong Wu, Qian Peng, Da-Xuan Dong, Xue-Long Hou and Yun-Dong Wu pp 9717–9725 DOI: 10.1021/ja7104174 Supporting Info

Imprinting of Molecular Recognition Sites through Electropolymerization of Functionalized Au Nanoparticles: Development of an Electrochemical TNT Sensor Based on π-Donor−Acceptor Interactions Michael Riskin, Ran Tel-Vered, Tatyana Bourenko, Eran Granot and Itamar Willner pp 9726–9733 DOI: 10.1021/ja711278c Supporting Info

Discrete Photopatternable π-Conjugated Oligomers for Electrochromic Devices Christian B. Nielsen, Alex Angerhofer, Khalil A. Abboud and John R. Reynolds pp 9734–9746 DOI: 10.1021/ja7112273 Supporting Info

On the Molecular Mechanism of Drug Intercalation into DNA: A Simulation Study of the Intercalation Pathway, Free Energy, and DNA Structural Changes Arnab Mukherjee, Richard Lavery, Biman Bagchi and James T. Hynes pp 9747–9755 DOI: 10.1021/ja8001666 Supporting Info

Temperature Independence of the Photoinduced Electron Injection in Dye-Sensitized TiO2 Rationalized by Ab Initio Time-Domain Density Functional Theory Walter R. Duncan and Oleg V. Prezhdo pp 9756–9762 DOI: 10.1021/ja800268x

Comprehensive Investigation of Self-Assembled Monolayer Formation on Ferromagnetic Thin Film Surfaces Paul G. Hoertz, Jeremy R. Niskala, Peng Dai, Hayden T. Black and Wei You pp 9763–9772 DOI: 10.1021/ja800278a Supporting Info

Ultrafast Excited-State Dynamics of Nanoscale Near-Infrared Emissive Polymersomes Timothy V. Duncan, P. Peter Ghoroghchian, Igor V. Rubtsov, Daniel A. Hammer and Michael J. Therien pp 9773–9784 DOI: 10.1021/ja711497w Supporting Info

Rapidly Infrared-Assisted Cooperatively Self-Assembled Highly Ordered Multiscale Porous Materials Zhongyu Zheng, Kuiyi Gao, Yanhong Luo, Dongmei Li, Qingbo Meng, Yuren Wang and Daozhong Zhang pp 9785–9789 DOI: 10.1021/ja800327n Supporting Info

Zeolite-Catalyzed Hydrogenation of Carbon Dioxide and Ethene Bun Chan and Leo Radom pp 9790–9799 DOI: 10.1021/ja800840q Supporting Info

Low-Frequency Mode Activity of Heme: Femtosecond Coherence Spectroscopy of Iron Porphine Halides and Nitrophorin Minoru Kubo, Flaviu Gruia, Abdelkrim Benabbas, Alexander Barabanschikov, William R. Montfort, Estelle M. Maes and Paul M. Champion pp 9800–9811 DOI: 10.1021/ja800916d Supporting Info

Electron Transport by Molecular Motion of redox-DNA Strands: Unexpectedly Slow Rotational Dynamics of 20-mer ds-DNA Chains End-Grafted onto Surfaces via C6 Linkers Agns Anne and Christophe Demaille pp 9812–9823 DOI: 10.1021/ja801074m

Molecular Clip and Tweezer Introduce New Mechanisms of Enzyme Inhibition Peter Talbiersky, Frank Bastkowski, Frank-Gerrit Klrner and Thomas Schrader pp 9824–9828 DOI: 10.1021/ja801441j Supporting Info

Facial Symmetry in Protein Self-Assembly Anil K. Mehta, Kun Lu, W. Seth Childers, Yan Liang, Steven N. Dublin, Jijun Dong, James P. Snyder, Sai Venkatesh Pingali, Pappannan Thiyagarajan and David G. Lynn pp 9829–9835 DOI: 10.1021/ja801511n Supporting Info

Antimicrobial Polymers Prepared by ROMP with Unprecedented Selectivity: A Molecular Construction Kit Approach Karen Lienkamp, Ahmad E. Madkour, Ashlan Musante, Christopher F. Nelson, Klaus Nsslein and Gregory N. Tew pp 9836–9843 DOI: 10.1021/ja801662y Supporting Info

Direct Observation of the Gating Step in Protein Electron Transfer: Electric-Field-Controlled Protein Dynamics Anja Kranich, Hoang Khoa Ly, Peter Hildebrandt and Daniel H. Murgida pp 9844–9848 DOI: 10.1021/ja8016895 Supporting Info

Biomolecular Engineering by Combinatorial Design and High-Throughput Screening: Small, Soluble Peptides That Permeabilize Membranes Ramesh Rathinakumar and William C. Wimley pp 9849–9858 DOI: 10.1021/ja8017863

Cymantrene Radical Cation Family: Spectral and Structural Characterization of the Half-Sandwich Analogues of Ferrocenium Ion Derek R. Laws, Daesung Chong, Karen Nash, Arnold L. Rheingold and William E. Geiger pp 9859–9870 DOI: 10.1021/ja801930q Supporting Info

Determining Secondary Structure in Spider Dragline Silk by Carbon−Carbon Correlation Solid-State NMR Spectroscopy Gregory P. Holland, Melinda S. Creager, Janelle E. Jenkins, Randolph V. Lewis and Jeffery L. Yarger pp 9871–9877 DOI: 10.1021/ja8021208 Supporting Info

Stabilization of Fully Reduced Iron−Sulfur Clusters by Carbene Ligation: The [FenSn]0 Oxidation Levels (n = 4, 8) Liang Deng and R. H. Holm pp 9878–9886 DOI: 10.1021/ja802111w Supporting Info

Origin of the SN2 Benzylic Effect Boris Galabov, Valia Nikolova, Jeremiah J. Wilke, Henry F. Schaefer, and Wesley D. Allen pp 9887–9896 DOI: 10.1021/ja802246y Supporting Info

Symmetry Controlled Spin Polarized Conductance in Au Nanowires Renato B. Pontes, E. Z. da Silva, A. Fazzio and Antnio J. R. da Silva pp 9897–9903 DOI: 10.1021/ja8020457

Dicarbollylamine Ligand as a Tunable Template for σ,σ- and π,σ-Bonding Modes: Syntheses, Structures, and Theoretical Studies of η5:η1-Coordinated Constrained-Geometry Group 13 Metal Complexes Jong-Dae Lee, Sung-Kwan Kim, Tae-Jin Kim, Won-Sik Han, Young-Joo Lee, Dae-Hwan Yoo, Minserk Cheong, Jaejung Ko and Sang Ook Kang pp 9904–9917 DOI: 10.1021/ja802163q Supporting Info

Crystal Plane Dependent Growth of Aligned Single-Walled Carbon Nanotubes on Sapphire Naoki Ishigami, Hiroki Ago, Kenta Imamoto, Masaharu Tsuji, Konstantin Iakoubovskii and Nobutsugu Minami pp 9918–9924 DOI: 10.1021/ja8024752 Supporting Info

An Eight Residue Fragment of an Acyl Carrier Protein Suffices for Post-Translational Introduction of Fluorescent Pantetheinyl Arms in Protein Modification in vitro and in vivo Zhe Zhou, Alexander Koglin, Yu Wang, Andrew P. McMahon and Christopher T. Walsh pp 9925–9930 DOI: 10.1021/ja802657n Supporting Info

Demonstrating Structural Deformation in an Inorganic Nanotube Yuri G. Andreev and Peter G. Bruce pp 9931–9934 DOI: 10.1021/ja8028334

Multi-Step Microfluidic Polymerization Reactions Conducted in Droplets: The Internal Trigger Approach Wei Li, Hung H. Pham, Zhihong Nie, Brendan MacDonald, Axel Genther and Eugenia Kumacheva pp 9935–9941 DOI: 10.1021/ja8029174 Supporting Info

Aluminum-Catalyzed Asymmetric Alkylations of Pyridyl-Substituted Alkynyl Ketones with Dialkylzinc Reagents Donna K. Friel, Marc L. Snapper and Amir H. Hoveyda pp 9942–9951 DOI: 10.1021/ja802935w Supporting Info

Gradient Shape-Persistent π-Conjugated Dendrimers for Light-Harvesting: Synthesis, Photophysical Properties, and Energy Funneling Jin-Liang Wang, Jing Yan, Zheng-Ming Tang, Qi Xiao, Yuguo Ma and Jian Pei pp 9952–9962 DOI: 10.1021/ja803109r Supporting Info

Cold Denaturation of Yeast Frataxin Offers the Clue to Understand the Effect of Alcohols on Protein Stability Stephen R. Martin, Veronica Esposito, Paolo De Los Rios, Annalisa Pastore and Piero Andrea Temussi pp 9963–9970 DOI: 10.1021/ja803280e Supporting Info

Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides Jesse W. Tye, Zhiqiang Weng, Adam M. Johns, Christopher D. Incarvito and John F. Hartwig pp 9971–9983 DOI: 10.1021/ja076668w Supporting Info

Reactivity of Titanium Dioxide with Oxygen at Room Temperature and the Related Charge Transfer J. Nowotny, T. Bak, L. R. Sheppard and M. K. Nowotny pp 9984–9993 DOI: 10.1021/ja7108695

Surface-Tuned Assembly of Porphyrin Coordination Oligomers Matthieu Koepf, Jennifer A. Wytko, Jean-Pierre Bucher and Jean Weiss pp 9994–10001 DOI: 10.1021/ja800039a Supporting Info

Mercury−Platinum Tunneling Junctions Incorporating Supramolecular Host−Guest Assemblies Colm T. Mallon, Andrea McNally, Tia E. Keyes and Robert J. Forster pp 10002–10007 DOI: 10.1021/ja8011319

Pairwise Interactions between Linear Alkanes in Water Measured by AFM Force Spectroscopy Chad Ray, Jason R. Brown, Andrea Kirkpatrick and Boris B. Akhremitchev pp 10008–10018 DOI: 10.1021/ja801568y Supporting Info

Chemical Synthesis and Biological Evaluation of Palmerolide A Analogues K.C. Nicolaou, Gulice Y. C. Leung, Dattatraya H. Dethe, Ramakrishna Guduru, Ya-Ping Sun, Chek Shik Lim and David Y.-K. Chen pp 10019–10023 DOI: 10.1021/ja802803e Supporting Info

Bioinspired Polyene Cyclization Promoted by Intermolecular Chiral Acetal-SnCl4 or Chiral N-Acetal-TiCl4: Investigation of the Mechanism and Identification of the Key Intermediates Yu-Jun Zhao and Teck-Peng Loh pp 10024–10029 DOI: 10.1021/ja802896n Supporting Info

Book Review of Iminosugars: From Synthesis to Therapeutic Applications. George A. O’Doherty p 10030 DOI: 10.1021/ja804234k

Book Review of Inorganic Reactions in Water p 10031 DOI: 10.1021/ja804032j

Book Review of Turning Points in Solid-State, Materials and Surface Science: A Book in Celebration of the Life and Work of Sir John Meurig Thomas p 10031 DOI: 10.1021/ja804151t

Book Review of Bioconjugate Techniques p 10031 DOI: 10.1021/ja8042917

Book Review of Carbohydrate Chemistry and Biochemistry: Structure and Mechanism Todd L. Lowary pp 10031–10032 DOI: 10.1021/ja804181r

Book Review of Calixarenes: An Introduction, 2nd ed. Donal H. Macartney p 10032 DOI: 10.1021/ja804385t

Book Review of Microporous Framework Solids Scott R. J. Oliver pp 10032–10033 DOI: 10.1021/ja804404a

Book Review of Recent Research Developments in Heterocyclic Chemistry, 2007 Eric Block p 10033 DOI: 10.1021/ja804441w

Book Review of Nanostructure Materials in Electrochemistry Diego J. Daz pp 10033–10034 DOI: 10.1021/ja804493q

Issue 31

Molecular Dynamics Simulation of the HOONO Decomposition and the HO•/NO2• Caged Radical Pair in Water Hakan Gunaydin and K. N. Houk pp 10036–10037 DOI: 10.1021/ja711365e Supporting Info

Reversible Emergence of a Self-Assembled Layered Structure From Three-Dimensional Isotropic Ionic Crystal of a Cluster Compound (4-HNC5H4OH)2Mo6Cl14 Driven By Absorption of Water and Alcohols Kei Inumaru, Takashi Kikudome, Hiroshi Fukuoka and Shoji Yamanaka pp 10038–10039 DOI: 10.1021/ja802752y Supporting Info

A Platinum Supramolecular Square as an Effective G-Quadruplex Binder and Telomerase Inhibitor Roxanne Kieltyka, Pablo Englebienne, Johans Fakhoury, Chantal Autexier, Nicolas Moitessier and Hanadi F. Sleiman pp 10040–10041 DOI: 10.1021/ja8014023 Supporting Info

Electronic Properties of Conjugated Polyelectrolyte Thin Films Jung Hwa Seo and Thuc-Quyen Nguyen pp 10042–10043 DOI: 10.1021/ja801451e Supporting Info

Reversible Mechanochromic Luminescence of [(C6F5Au)2(μ-1,4-Diisocyanobenzene)] Hajime Ito, Tomohisa Saito, Naoya Oshima, Noboru Kitamura, Shoji Ishizaka, Yukio Hinatsu, Makoto Wakeshima, Masako Kato, Kiyoshi Tsuge and Masaya Sawamura pp 10044–10045 DOI: 10.1021/ja8019356 Supporting Info

Self-Assembly and Cross-linking of FePt Nanoparticles at Planar and Colloidal Liquid−Liquid Interfaces Palaniappan Arumugam, Debabrata Patra, Bappaditya Samanta, Sarit S. Agasti, Chandramouleeswaran Subramani and Vincent M. Rotello pp 10046–10047 DOI: 10.1021/ja802178s Supporting Info

Microwave Activation of Enzymatic Catalysis Douglas D. Young, Jason Nichols, Robert M. Kelly and Alexander Deiters pp 10048–10049 DOI: 10.1021/ja802404g Supporting Info

Autonomous DNA Computing Machine Based on Photochemical Gate Transition Shinzi Ogasawara, Takehiro Ami and Kenzo Fujimoto pp 10050–10051 DOI: 10.1021/ja802583z Supporting Info

Cyclic 1,3-Dipoles or Acyclic Phosphonium Ylides? Electronic Characterization of “Montralones” Elizabeth H. Krenske, K. N. Houk, Bruce A. Arndtsen and Daniel J. St. Cyr pp 10052–10053 DOI: 10.1021/ja802646f Supporting Info

Controllable Redox Reaction of Chemically Purified DNA−Single Walled Carbon Nanotube Hybrids with Hydrogen Peroxide Yang Xu, Pehr E. Pehrsson, Liwei Chen and Wei Zhao pp 10054–10055 DOI: 10.1021/ja802743h Supporting Info

Self-Assembly of Perylenediimide and Naphthalenediimide Nanostructures on Glass Substrates through Deposition from the Gas Phase Hai-Feng Ji, Ravish Majithia, Xin Yang, Xiaohe Xu and Karren More pp 10056–10057 DOI: 10.1021/ja803079w Supporting Info

Ti(IV)-Centered Dynamic Interconversion between Pd(II), Ti(IV)-Containing Ring and Cage Molecules Shuichi Hiraoka, Yoko Sakata and Mitsuhiko Shionoya pp 10058–10059 DOI: 10.1021/ja803115j Supporting Info

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride Takeru Furuya and Tobias Ritter pp 10060–10061 DOI: 10.1021/ja803187x Supporting Info

Isothermal Assembly of DNA Origami Structures Using Denaturing Agents Ralf Jungmann, Tim Liedl, Thomas L. Sobey, William Shih and Friedrich C. Simmel pp 10062–10063 DOI: 10.1021/ja8030196 Supporting Info

Selective Disruption of Early/Recycling Endosomes: Release of Disulfide-Linked Cargo Mediated by a N-Alkyl-3β-Cholesterylamine-Capped Peptide Qi Sun, Sutang Cai and Blake R. Peterson pp 10064–10065 DOI: 10.1021/ja803380a Supporting Info

Distinct Reactivity of Pd(OTs)2: The Intermolecular Pd(II)-Catalyzed 1,2-Carboamination of Dienes Chris E. Houlden, Chris D. Bailey, J. Gair Ford, Michel R. Gagn, Guy C. Lloyd-Jones and Kevin I. Booker-Milburn pp 10066–10067 DOI: 10.1021/ja803397y Supporting Info

(CrCl3)3@2[C4mim][OMe]Molecular Cluster-Type Chromium(III) Chloride Stabilized in a Salt Matrix Bert Mallick, Harald Kierspel and Anja-Verena Mudring pp 10068–10069 DOI: 10.1021/ja803322k Supporting Info

Electrochemically Controlled Hydrogen Bonding. Electrolyte Effects in an Oxidation-Based Arylurea−Amide System Jessica E. Woods, Yu Ge and Diane K. Smith pp 10070–10071 DOI: 10.1021/ja803453e Supporting Info

Hydrogen-Bond-Induced Hysteresis in the Compression/Relaxation of Monolayer Films Jennifer L. Sorrells and Fredric M. Menger pp 10072–10073 DOI: 10.1021/ja803491y Supporting Info

Synthesis of Octacarboxy Spherosilicate Hongzhi Liu, Shin-ichi Kondo, Nobuhiro Takeda and Masafumi Unno pp 10074–10075 DOI: 10.1021/ja803513n Supporting Info

Enantio- and Diastereoselective Catalytic Alkylation Reactions with Aziridines Thomas A. Moss, David R. Fenwick and Darren J. Dixon pp 10076–10077 DOI: 10.1021/ja8036965 Supporting Info

Catalytic Asymmetric Synthesis of 2,2-Disubstituted Terminal Epoxides via Dimethyloxosulfonium Methylide Addition to Ketones Toshihiko Sone, Akitake Yamaguchi, Shigeki Matsunaga and Masakatsu Shibasaki pp 10078–10079 DOI: 10.1021/ja803864p Supporting Info

Formation of Tricyclic [4.3.3.0] Adducts between 8-Oxoguanosine and Tyrosine under Conditions of Oxidative DNA−Protein Cross-Linking Xiaoyun Xu, Aaron M. Fleming, James G. Muller and Cynthia J. Burrows pp 10080–10081 DOI: 10.1021/ja803896d Supporting Info

Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor Shau-Hua Ueng, Malika Makhlouf Brahmi, tienne Derat, Louis Fensterbank, Emmanuel Lacte, Max Malacria and Dennis P. Curran pp 10082–10083 DOI: 10.1021/ja804150k Supporting Info

Bis-Sulfonyl Ethylene as Masked Acetylene Equivalent in Catalytic Asymmetric [3 + 2] Cycloaddition of Azomethine Ylides Ana Lpez-Prez, Javier Adrio and Juan C. Carretero pp 10084–10085 DOI: 10.1021/ja804021m Supporting Info

A Heterobimetallic Complex With an Unsupported Uranium(III)−Aluminum(I) Bond: (CpSiMe3)3U−AlCp* (Cp* = C5Me5) Stefan G. Minasian, Jamin L. Krinsky, Valerie A. Williams and John Arnold pp 10086–10087 DOI: 10.1021/ja8042382 Supporting Info

Bidirectional Transfer of Phenyl and Methyl Groups between PtIV and Boron in Platinum Dipyridylborato Complexes Eugene Khaskin, Peter Y. Zavalij and Andrei N. Vedernikov pp 10088–10089 DOI: 10.1021/ja804222c Supporting Info

Extended Metal-Atom Chains with an Inert Second Row Transition Metal: [Ru5(μ5-tpda)4X2] (tpda2− = tripyridyldiamido dianion, X = Cl and NCS) Caixia Yin, Gin-Chen Huang, Ching-Kuo Kuo, Ming-Dung Fu, Hao-Cheng Lu, Jhih-Hong Ke, Kai-Neng Shih, Yi-Lin Huang, Gene-Hsiang Lee, Chen-Yu Yeh, Chun-hsien Chen and Shie-Ming Peng pp 10090–10092 DOI: 10.1021/ja8016818 Supporting Info

Reactions of a Metallacyclobutene Complex with Alkenes Ryan L. Holland, Kevin D. Bunker, Christopher H. Chen, Antonio G. DiPasquale, Arnold L. Rheingold, Kim K. Baldridge and Joseph M. O’Connor pp 10093–10095 DOI: 10.1021/ja803701z Supporting Info

Isopenicillin N Synthase Mediates Thiolate Oxidation to Sulfenate in a Depsipeptide Substrate Analogue: Implications for Oxygen Binding and a Link to Nitrile Hydratase? Wei Ge, Ian J. Clifton, Jeanette E. Stok, Robert M. Adlington, Jack E. Baldwin and Peter J. Rutledge pp 10096–10102 DOI: 10.1021/ja8005397 Supporting Info

Kinetic Evaluation of Highly Active Supported Gold Catalysts Prepared from Monolayer-Protected Clusters: An Experimental Michaelis−Menten Approach for Determining the Oxygen Binding Constant during CO Oxidation Catalysis Cormac G. Long, John D. Gilbertson, Ganesh Vijayaraghavan, Keith J. Stevenson, Christopher J. Pursell and Bert D. Chandler pp 10103–10115 DOI: 10.1021/ja801279a Supporting Info

Insight into the Mechanism of the Asymmetric Ring-Opening Aminolysis of 4,4-Dimethyl-3,5,8-trioxabicyclo[5.1.0]octane Catalyzed by Titanium/BINOLate/Water System: Evidence for the Ti(BINOLate)2-Bearing Active Catalyst Entities and the Role of Water Hongli Bao, Jing Zhou, Zheng Wang, Yinlong Guo, Tianpa You and Kuiling Ding pp 10116–10127 DOI: 10.1021/ja801847r Supporting Info

A Valence Bond Modeling of Trends in Hydrogen Abstraction Barriers and Transition States of Hydroxylation Reactions Catalyzed by Cytochrome P450 Enzymes Sason Shaik, Devesh Kumar and Sam P. de Visser pp 10128–10140 DOI: 10.1021/ja8019615 Supporting Info

Atomistic Insights into Rhodopsin Activation from a Dynamic Model Irina G. Tikhonova, Robert B. Best, Stanislav Engel, Marvin C. Gershengorn, Gerhard Hummer and Stefano Costanzi pp 10141–10149 DOI: 10.1021/ja0765520 Supporting Info

Synthesis, Crystallization Mechanism, and Catalytic Properties of Titanium-Rich TS-1 Free of Extraframework Titanium Species Weibin Fan, Ren-Guan Duan, Toshiyuki Yokoi, Peng Wu, Yoshihiro Kubota and Takashi Tatsumi pp 10150–10164 DOI: 10.1021/ja7100399 Supporting Info

Evolution of Standing Mesochannels on Porous Anodic Alumina Substrates with Designed Conical Holes Yusuke Yamauchi, Tomota Nagaura, Ayako Ishikawa, Toyohiro Chikyow and Satoru Inoue pp 10165–10170 DOI: 10.1021/ja7107036 Supporting Info

Dynamics of Excited-State Conformational Relaxation and Electronic Delocalization in Conjugated Porphyrin Oligomers Ming-Hua Chang, Markus Hoffmann, Harry L. Anderson and Laura M. Herz pp 10171–10178 DOI: 10.1021/ja711222c Supporting Info

Antiaromatic Spacer-Bridged Bisfluorenyl Dications Generated by Superacid Induced Ionization Bart J. Dahl and Nancy S. Mills pp 10179–10186 DOI: 10.1021/ja711501k Supporting Info

Theory of 1,3-Dipolar Cycloadditions: Distortion/Interaction and Frontier Molecular Orbital Models Daniel H. Ess and K. N. Houk pp 10187–10198 DOI: 10.1021/ja800009z Supporting Info

Zn Modification of the Reactivity of Pd(111) Toward Methanol and Formaldehyde Eseoghene Jeroro and John M. Vohs pp 10199–10207 DOI: 10.1021/ja8001265

G-Quadruplex DNA Assemblies: Loop Length, Cation Identity, and Multimer Formation Nicolas Smargiasso, Frdric Rosu, Wei Hsia, Pierre Colson, Erin Shammel Baker, Michael T. Bowers, Edwin De Pauw and Valrie Gabelica pp 10208–10216 DOI: 10.1021/ja801535e Supporting Info

Design and Synthesis of Ladder-Shaped Tetracyclic, Heptacyclic, and Decacyclic Ethers and Evaluation of the Interaction with Transmembrane Proteins Kohei Torikai, Tohru Oishi, Satoru Ujihara, Nobuaki Matsumori, Keiichi Konoki, Michio Murata and Saburo Aimoto pp 10217–10226 DOI: 10.1021/ja801576v Supporting Info

Thermodynamics and Mechanism of the Deamidation of Sodium-Bound Asparagine A. L. Heaton and P. B. Armentrout pp 10227–10232 DOI: 10.1021/ja801726g Supporting Info

NMR-Assisted Prediction of RNA Secondary Structure: Identification of a Probable Pseudoknot in the Coding Region of an R2 Retrotransposon James M. Hart, Scott D. Kennedy, David H. Mathews and Douglas H. Turner pp 10233–10239 DOI: 10.1021/ja8026696 Supporting Info

Protein−Matrix Coupling/Uncoupling in “Dry” Systems of Photosynthetic Reaction Center Embedded in Trehalose/Sucrose: The Origin of Trehalose Peculiarity Francesco Francia, Manuela Dezi, Antonia Mallardi, Gerardo Palazzo, Lorenzo Cordone and Giovanni Venturoli pp 10240–10246 DOI: 10.1021/ja801801p Supporting Info

Energetics of Cyclohexene Adsorption and Reaction on Pt(111) by Low-Temperature Microcalorimetry Ole Lytken, Wanda Lew, Jonathan J. W. Harris, Ebbe K. Vestergaard, J. Michael Gottfried and Charles T. Campbell pp 10247–10257 DOI: 10.1021/ja801856s

Magnetic Nanoparticle−Peptide Conjugates for in Vitro and in Vivo Targeting and Extraction of Cancer Cells Kenneth E. Scarberry, Erin B. Dickerson, John F. McDonald and Z. John Zhang pp 10258–10262 DOI: 10.1021/ja801969b Supporting Info

Tracking the Chemistry of Unsaturated C3H3 Groups Adsorbed on a Silver Surface: Propargyl−Allenyl−Acetylide Triple Bond Migration, Self-Hydrogenation, and Carbon−Carbon Bond Formation Hsuan Kung, Shin-Mou Wu, Yu-Jui Wu, Yaw-Wen Yang and Chao-Ming Chiang pp 10263–10273 DOI: 10.1021/ja803509y

The Complex Role of the Triphenylmethyl Motif in Anticancer Compounds Rahul Palchaudhuri, Vitaliy Nesterenko and Paul J. Hergenrother pp 10274–10281 DOI: 10.1021/ja8020999 Supporting Info

Effect of Base Stacking on the Acid−Base Properties of the Adenine Cation Radical [A•+] in Solution: ESR and DFT Studies Amitava Adhikary, Anil Kumar, Deepti Khanduri and Michael D. Sevilla pp 10282–10292 DOI: 10.1021/ja802122s Supporting Info

Biomimetic Synthesis of Resorcylate Natural Products Utilizing Late Stage Aromatization: Concise Total Syntheses of the Marine Antifungal Agents 15G256ι and 15G256β Ismael Navarro, Jean-Franois Basset, Sverine Hebbe, Sarah M. Major, Thomas Werner, Catherine Howsham, Jan Brckow and Anthony G. M. Barrett pp 10293–10298 DOI: 10.1021/ja803445u Supporting Info

Interstrand Cross-Link Formation in Duplex and Triplex DNA by Modified Pyrimidines Xiaohua Peng, In Seok Hong, Hong Li, Michael M. Seidman and Marc M. Greenberg pp 10299–10306 DOI: 10.1021/ja802177u Supporting Info

Rational Design of a Minimal Size Sensor Array for Metal Ion Detection Manuel A. Palacios, Zhuo Wang, Victor A. Montes, Grigory V. Zyryanov and Pavel Anzenbacher, pp 10307–10314 DOI: 10.1021/ja802377k Supporting Info

Designed Supramolecular Assembly of Hydrogen-Bonded Anionic Rosette Layers Jie Han, Chung-Wah Yau, Chi-Keung Lam and Thomas C. W. Mak pp 10315–10326 DOI: 10.1021/ja802425q Supporting Info

Construction of Aryliridium−Salen Complexes: Enantio- and Cis-Selective Cyclopropanation of Conjugated and Nonconjugated Olefins Hidehiro Suematsu, Shigefumi Kanchiku, Tatsuya Uchida and Tsutomu Katsuki pp 10327–10337 DOI: 10.1021/ja802561t Supporting Info

Stimuli-Responsive Polyguanidino-Oxanorbornene Membrane Transporters as Multicomponent Sensors in Complex Matrices Andreas Hennig, Gregory J. Gabriel, Gregory N. Tew and Stefan Matile pp 10338–10344 DOI: 10.1021/ja802587j Supporting Info

Thermal Signature of Hydrophobic Hydration Dynamics Johan Qvist and Bertil Halle pp 10345–10353 DOI: 10.1021/ja802668w Supporting Info

Intra- and Intermolecular NMR Studies on the Activation of Arylcyclometallated Hafnium Pyridyl-Amido Olefin Polymerization Precatalysts Cristiano Zuccaccia, Alceo Macchioni, Vincenzo Busico, Roberta Cipullo, Giovanni Talarico, Francesca Alfano, Harold W. Boone, Kevin A. Frazier, Phillip D. Hustad, James C. Stevens, Paul C. Vosejpka and Khalil A. Abboud pp 10354–10368 DOI: 10.1021/ja802072n Supporting Info

Mechanistic Consequences of Composition in Acid Catalysis by Polyoxometalate Keggin Clusters Josef Macht, Michael J. Janik, Matthew Neurock and Enrique Iglesia pp 10369–10379 DOI: 10.1021/ja803114r Supporting Info

Inspection of the Duality of a Verdazyl-Based Radical in Transition Metal Complexes: A π* Donor Ligand and a Magnetic Partner Jean-Baptiste Rota, Lucie Norel, Cyrille Train, Nadia Ben Amor, Daniel Maynau and Vincent Robert pp 10380–10385 DOI: 10.1021/ja802027u

Characterization and Application of Controllable Local Chemical Changes Produced by Reagent Delivery from a Nanopipet Joe D. Piper, Chao Li, Chien-Jung Lo, Richard Berry, Yuri Korchev, Liming Ying and David Klenerman pp 10386–10393 DOI: 10.1021/ja8022253 Supporting Info

Planar Pentacoordinate Carbon in CAl5+: A Global Minimum Yong Pei, Wei An, Keigo Ito, Paul von Ragu Schleyer and Xiao Cheng Zeng pp 10394–10400 DOI: 10.1021/ja803365x Supporting Info

A Rigorous Framework To Interpret Water Relaxivity. The Case Study of a Gd(III) Complex with an α-Cyclodextrin Derivative Clia S. Bonnet, Pascal H. Fries, Andre Gadelle, Serge Gambarelli and Pascale Delangle pp 10401–10413 DOI: 10.1021/ja802347r Supporting Info

Combined Experimental and Theoretical Study of the Mechanism and Enantioselectivity of Palladium- Catalyzed Intermolecular Heck Coupling Signe T. Henriksen, Per-Ola Norrby, Pivi Kaukoranta and Pher G. Andersson pp 10414–10421 DOI: 10.1021/ja802991y Supporting Info

Evidence from Mechanistic Probes for Distinct Hydroperoxide Rearrangement Mechanisms in the Intradiol and Extradiol Catechol Dioxygenases Meite Xin and Timothy D. H. Bugg pp 10422–10430 DOI: 10.1021/ja8029569 Supporting Info

Supramolecular Architectures of β-Cyclodextrin-Modified Chitosan and Pyrene Derivatives Mediated by Carbon Nanotubes and Their DNA Condensation Yu Liu, Zhi-Lin Yu, Ying-Ming Zhang, Dong-Sheng Guo and Yu-Ping Liu pp 10431–10439 DOI: 10.1021/ja802465g Supporting Info

Exceptional Behavior over the Whole Adsorption−Storage−Delivery Cycle for NO in Porous Metal Organic Frameworks Alistair C. McKinlay, Bo Xiao, David S. Wragg, Paul S. Wheatley, Ian L. Megson and Russell E. Morris pp 10440–10444 DOI: 10.1021/ja801997r Supporting Info

Experimental Evidence for a Highly Reversible Excited State Equilibrium between s-Cis and s-Trans Rotational Isomers of 2-Methoxynaphthalene in Solution Ioanna Balomenou and George Pistolis p 10445 DOI: 10.1021/ja804688e

Book Review of Halogen Bonding: Fundamentals and Applications. Structure and Bonding, 126 Peter Politzer pp 10446–10447 DOI: 10.1021/ja804186p

Book Review of X-ray Crystallography of Biomacromolecules: A Practical Guide Jon Robertus p 10447 DOI: 10.1021/ja8027586

Book Review of Computational Modeling for Homogeneous and Enzymatic Catalysis: A Knowledge-Base for Designing Efficient Catalysts Russell J. Boyd pp 10447–10448 DOI: 10.1021/ja8046975

Book Review of Handbook of RAFT Polymerization Devon A. Shipp p 10448 DOI: 10.1021/ja804579v

Book Review of Annual Review of Physical Chemistry, Volume 59, 2008 p 10448 DOI: 10.1021/ja804861j

Issue 32

Order−Disorder Antiferroelectric Phase Transition in a Hybrid Inorganic−Organic Framework with the Perovskite Architecture Prashant Jain, Naresh S. Dalal, Brian H. Toby, Harold W. Kroto and Anthony K. Cheetham pp 10450–10451 DOI: 10.1021/ja801952e

Spatially Resolved NMR Thermometry of an Operating Fixed-Bed Catalytic Reactor Igor V. Koptyug, Alexey V. Khomichev, Anna A. Lysova and Renad Z. Sagdeev pp 10452–10453 DOI: 10.1021/ja802075m Supporting Info

Shear-Induced Long-Range Uniaxial Assembly of Polyaromatic Monolayers at Molecular Resolution Shern-Long Lee, Cher-Yi Jason Chi, Min-Jie Huang, Chun-hsien Chen, Chia-Wen Li, Kamalkishore Pati and Rai-Shung Liu pp 10454–10455 DOI: 10.1021/ja8024017 Supporting Info

On-Chip Fuel Cell: Micro Direct Methanol Fuel Cell of an Air-Breathing, Membraneless, and Monolithic Design Satoshi Tominaka, Sousuke Ohta, Hiroyuki Obata, Toshiyuki Momma and Tetsuya Osaka pp 10456–10457 DOI: 10.1021/ja8024214 Supporting Info

Identification of a Gene Cluster That Directs Putrebactin Biosynthesis in Shewanella Species: PubC Catalyzes Cyclodimerization of N-Hydroxy-N-succinylputrescine Nadia Kadi, Simon Arbache, Lijiang Song, Daniel Oves-Costales and Gregory L. Challis pp 10458–10459 DOI: 10.1021/ja8027263 Supporting Info

Cyclic Single-Molecule Magnet in Heterospin System Daisuke Yoshihara, Satoru Karasawa and Noboru Koga pp 10460–10461 DOI: 10.1021/ja802895d Supporting Info

DNA-Controlled Assembly of Soft Nanoparticles Ulla Jakobsen, Adam C. Simonsen and Stefan Vogel pp 10462–10463 DOI: 10.1021/ja8030054 Supporting Info

New Polyethylene Macroinitiators and Their Subsequent Grafting by Atom Transfer Radical Polymerization Yanika Schneider, Jason D. Azoulay, Robert C. Coffin and Guillermo C. Bazan pp 10464–10465 DOI: 10.1021/ja803006d Supporting Info

A Bioinspired Construct That Mimics the Proton Coupled Electron Transfer between P680•+ and the TyrZ-His190 Pair of Photosystem II Gary F. Moore, Michael Hambourger, Miguel Gervaldo, Oleg G. Poluektov, Tijana Rajh, Devens Gust, Thomas A. Moore and Ana L. Moore pp 10466–10467 DOI: 10.1021/ja803015m Supporting Info

3D Framework Containing Cu4Br4 Cubane as Connecting Node with Strong Ferroelectricity Wen Zhang, Ren-Gen Xiong and Songping D. Huang pp 10468–10469 DOI: 10.1021/ja803021v Supporting Info

Air-assisted High-performance Field-effect Transistor with Thin Films of Picene Hideki Okamoto, Naoko Kawasaki, Yumiko Kaji, Yoshihiro Kubozono, Akihiko Fujiwara and Minoru Yamaji pp 10470–10471 DOI: 10.1021/ja803291a Supporting Info

Luminescent and Raman Active Silver Nanoparticles with Polycrystalline Structure Jie Zheng, Yong Ding, Bozhi Tian, Zhong Lin Wang and Xiaowei Zhuang pp 10472–10473 DOI: 10.1021/ja803302p Supporting Info

Light-Mediated Liberation of Enzymatic Activity: “Small Molecule” Caged Protein Equivalents Haishan Li, Jung-Mi Hah and David S. Lawrence pp 10474–10475 DOI: 10.1021/ja803395d Supporting Info

Kinetic Investigation of Porphyrin Interaction with Chiral Templates Reveals Unexpected Features of the Induction and Self-Propagation Mechanism of Chiral Memory Rosaria Lauceri, Giovanni Francesco Fasciglione, Alessandro D’Urso, Stefano Marini, Roberto Purrello and Massimiliano Coletta pp 10476–10477 DOI: 10.1021/ja803426q Supporting Info

Concise Synthesis of Spirocyclic, Bridged γ-Butyrolactones via Stereospecific, Dyotropic Rearrangements of β-Lactones Involving 1,2-Acyl and δ-Lactone Migrations Vikram C. Purohit, Andrea S. Matla and Daniel Romo pp 10478–10479 DOI: 10.1021/ja803579z Supporting Info

Electrokinetics in Microfluidic Channels Containing a Floating Electrode Rahul Dhopeshwarkar, Dzmitry Hlushkou, Mark Nguyen, Ulrich Tallarek and Richard M. Crooks pp 10480–10481 DOI: 10.1021/ja8036405 Supporting Info

Controllable Synthesis of Cu2S Nanocrystals and Their Assembly into a Superlattice Zhongbin Zhuang, Qing Peng, Boce Zhang and Yadong Li pp 10482–10483 DOI: 10.1021/ja803644g Supporting Info

MHz Unidirectional Rotation of Molecular Rotary Motors Martin Klok, Nicola Boyle, Mary T. Pryce, Auke Meetsma, Wesley R. Browne and Ben L. Feringa pp 10484–10485 DOI: 10.1021/ja8037245 Supporting Info

A Dipicolinic Acid Tag for Rigid Lanthanide Tagging of Proteins and Paramagnetic NMR Spectroscopy Xun-Cheng Su, Bradley Man, Sophie Beeren, Haobo Liang, Shane Simonsen, Christophe Schmitz, Thomas Huber, Barbara A. Messerle and Gottfried Otting pp 10486–10487 DOI: 10.1021/ja803741f Supporting Info

Vertical Growth of Ge Nanowires from Biotemplated Au Nanoparticle Catalysts Yajaira Sierra-Sastre, Sukgeun Choi, S. T. Picraux and Carl A. Batt pp 10488–10489 DOI: 10.1021/ja8037382 Supporting Info

Double-Quantum 13C Nuclear Magnetic Resonance of Bathorhodopsin, the First Photointermediate in Mammalian Vision Maria Concistr, Axel Gansmller, Neville McLean, Ole G. Johannessen, Ildefonso Marn Montesinos, Petra H. M. Bovee-Geurts, Peter Verdegem, Johan Lugtenburg, Richard C. D. Brown, Willem J. DeGrip and Malcolm H. Levitt pp 10490–10491 DOI: 10.1021/ja803801u Supporting Info

Isostructural Self-Assembly of 2′-Deoxyguanosine Derivatives in Aqueous and Organic Media Marilyn Garca-Arriaga, Gerard Hobley and Jos M. Rivera pp 10492–10493 DOI: 10.1021/ja8039019 Supporting Info

Acetal-Derivatized Dextran: An Acid-Responsive Biodegradable Material for Therapeutic Applications Eric M. Bachelder, Tristan T. Beaudette, Kyle E. Broaders, Jesse Dashe and Jean M. J. Frchet pp 10494–10495 DOI: 10.1021/ja803947s Supporting Info

Direct Oxidative Cyanation Based on the Concept of Site Isolation Toshiki Tajima and Atsushi Nakajima pp 10496–10497 DOI: 10.1021/ja804048a Supporting Info

Ruthenium-Catalyzed Enantioselective Carbon−Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles Such As Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives Koji Fukamizu, Yoshihiro Miyake and Yoshiaki Nishibayashi pp 10498–10499 DOI: 10.1021/ja8038745 Supporting Info

A 64-Nuclear Cubic Cage Incorporating Propeller-like FeIII8 Apices and HCOO− Edges Tao Liu, Yan-Juan Zhang, Zhe-Ming Wang and Song Gao pp 10500–10501 DOI: 10.1021/ja803846z Supporting Info

Dioxabenzosapphyrin: A New Benzodifuran-Derived Sapphyrin Analogue Dong-Gyu Cho, Patrick Plitt, Sung Kuk Kim, Vincent Lynch, Seong-Jin Hong, Chang-Hee Lee and Jonathan L. Sessler pp 10502–10503 DOI: 10.1021/ja804090w Supporting Info

Platinum-Catalyzed Intramolecular Vinylchalcogenation of Alkynes with β-Phenylchalcogeno Conjugated Amides Masashi Toyofuku, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe pp 10504–10505 DOI: 10.1021/ja804121j Supporting Info

Demonstration of a Chemical Transformation Inside a Fullerene. The Reversible Conversion of the Allotropes of H2@C60 Nicholas J. Turro, Angel A. Mart, Judy Y.-C. Chen, Steffen Jockusch, Ronald G. Lawler, Marco Ruzzi, Elena Sartori, Shih-Ching Chuang, Koichi Komatsu and Yasujiro Murata pp 10506–10507 DOI: 10.1021/ja804311c

N−C Bond Formation of NO Ligands on Ruthenium Complexes with Concurrent Vinylic C−H Activation and Subsequent Proton-Induced Reactivities of the Resulting Nitrosovinyl Species Yasuhiro Arikawa, Taiki Asayama, Kazuki Itatani and Masayoshi Onishi pp 10508–10509 DOI: 10.1021/ja804095u Supporting Info

Direct Acylation of Aryl Bromides with Aldehydes by Palladium Catalysis Jiwu Ruan, Ourida Saidi, Jonathan A. Iggo and Jianliang Xiao pp 10510–10511 DOI: 10.1021/ja804351z Supporting Info

Control of the Coordination Structure of Organometallic Palladium Complexes in an apo-Ferritin Cage Satoshi Abe, Jochen Niemeyer, Mizue Abe, Yusuke Takezawa, Takafumi Ueno, Tatsuo Hikage, Gerhard Erker and Yoshihito Watanabe pp 10512–10514 DOI: 10.1021/ja802463a Supporting Info

Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex Jeremiah J. Scepaniak, Meita D. Fulton, Ranko P. Bontchev, Eileen N. Duesler, Martin L. Kirk and Jeremy M. Smith pp 10515–10517 DOI: 10.1021/ja8027372 Supporting Info

Observation of a Hidden Intermediate in the Stille Reaction. Study of the Reversal of the Transmetalation Step Mnica H. Prez-Temprano, Ainara Nova, Juan A. Casares and Pablo Espinet pp 10518–10520 DOI: 10.1021/ja802994v Supporting Info

Catalytic Enantioselective Pudovik Reaction of Aldehydes and Aldimines with Tethered Bis(8-quinolinato) (TBOx) Aluminum Complex Joshua P. Abell and Hisashi Yamamoto pp 10521–10523 DOI: 10.1021/ja803859p Supporting Info

Guest-Dependent High Pressure Phenomena in a Nanoporous Metal−Organic Framework Material Karena W. Chapman, Gregory J. Halder and Peter J. Chupas pp 10524–10526 DOI: 10.1021/ja804079z Supporting Info

Spectroscopic and Crystallographic Characterization of a Tetrameric Hemoglobin Oxidation Reveals Structural Features of the Functional Intermediate Relaxed/Tense State Luigi Vitagliano, Alessandro Vergara, Giovanna Bonomi, Antonello Merlino, Cinzia Verde, Guido di Prisco, Barry D. Howes, Giulietta Smulevich and Lelio Mazzarella pp 10527–10535 DOI: 10.1021/ja803363p Supporting Info

Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold Trevor M. Willey, Jason D. Fabbri, Jonathan R. I. Lee, Peter R. Schreiner, Andrey A. Fokin, Boryslav A. Tkachenko, Nataliya A. Fokina, Jeremy E. P. Dahl, Robert M. K. Carlson, Andrew L. Vance, Wanli Yang, Louis J. Terminello, Tony van Buuren and Nicolas A. Melosh pp 10536–10544 DOI: 10.1021/ja711131e Supporting Info

Multifunctional Nanostructures Based on Inorganic Nanoparticles and Oligothiophenes and Their Exploitation for Cellular Studies Alessandra Quarta, Riccardo Di Corato, Liberato Manna, Simona Argentiere, Roberto Cingolani, Giovanna Barbarella and Teresa Pellegrino pp 10545–10555 DOI: 10.1021/ja800102v Supporting Info

Effect of the Phase States of Self-Assembled Monolayers on Pentacene Growth and Thin-Film Transistor Characteristics Hwa Sung Lee, Do Hwan Kim, Jeong Ho Cho, Minkyu Hwang, Yunseok Jang and Kilwon Cho pp 10556–10564 DOI: 10.1021/ja800142t Supporting Info

Rational Enhancement of Second-Order Nonlinearity: Bis-(4-methoxyphenyl)hetero-aryl-amino Donor-Based Chromophores: Design, Synthesis, and Electrooptic Activity Joshua A. Davies, Arumugasamy Elangovan, Philip A. Sullivan, Benjamin C. Olbricht, Denise H. Bale, Todd R. Ewy, Christine M. Isborn, Bruce E. Eichinger, Bruce H. Robinson, Philip J. Reid, Xiaosong Li and Larry R. Dalton pp 10565–10575 DOI: 10.1021/ja8007424 Supporting Info

Formation and Bonding of Alane Clusters on Al(111) Surfaces Studied by Infrared Absorption Spectroscopy and Theoretical Modeling Santanu Chaudhuri, Sylvie Rangan, Jean-Francois Veyan, James T. Muckerman and Yves J. Chabal pp 10576–10587 DOI: 10.1021/ja800136k

The pH Dependent Nuclearity Variation of {Mo154-x}-type Polyoxomolybdates and Tectonic Effect on Their Aggregations Sayaka Shishido and Tomoji Ozeki pp 10588–10595 DOI: 10.1021/ja800784a Supporting Info

NMR Structure of the Complex between the Tfb1 Subunit of TFIIH and the Activation Domain of VP16: Structural Similarities between VP16 and p53 Chantal Langlois, Caroline Mas, Paola Di Lello, Lisa M. Miller Jenkins, Pascale Legault and James G. Omichinski pp 10596–10604 DOI: 10.1021/ja800975h Supporting Info

To Dope Mn2+ in a Semiconducting Nanocrystal Angshuman Nag, S. Chakraborty and D. D. Sarma pp 10605–10611 DOI: 10.1021/ja801249z Supporting Info

Pd(I) Phosphine Carbonyl and Hydride Complexes Implicated in the Palladium-Catalyzed Oxo Process Miguel Baya, Jennifer Houghton, Denes Konya, Yohan Champouret, Jean-Claude Daran, Karina Q. Almeida Leñero, Lodewijk Schoon, Wilhelmus P. Mul, A. Bart van Oort, Nicolaas Meijboom, Eite Drent, A. Guy Orpen and Rinaldo Poli pp 10612–10624 DOI: 10.1021/ja8012903 Supporting Info

Methyl Proton Contacts Obtained Using Heteronuclear Through-Bond Transfers in Solid-State NMR Spectroscopy Antoine Loquet, Sgolne Laage, Carole Gardiennet, Bndicte Elena, Lyndon Emsley, Anja Bckmann and Anne Lesage pp 10625–10632 DOI: 10.1021/ja801464g Supporting Info

Mechanistic Studies of the Triggered Release of Liposomal Contents by Matrix Metalloproteinase-9 Adekunle I. Elegbede, Jayati Banerjee, Andrea J. Hanson, Shakila Tobwala, Bratati Ganguli, Rongying Wang, Xiaoning Lu, D. K. Srivastava and Sanku Mallik pp 10633–10642 DOI: 10.1021/ja801548g

Highly Efficient Drug Delivery with Gold Nanoparticle Vectors for in Vivo Photodynamic Therapy of Cancer Yu Cheng, Anna C. Samia, Joseph D. Meyers, Irene Panagopoulos, Baowei Fei and Clemens Burda pp 10643–10647 DOI: 10.1021/ja801631c

Atomic Force Microscopy Studies of DNA-Wrapped Carbon Nanotube Structure and Binding to Quantum Dots Jennifer F. Campbell, Ingrid Tessmer, H. Holden Thorp and Dorothy A. Erie pp 10648–10655 DOI: 10.1021/ja801720c Supporting Info

Direct Electrodeposition of Cu2Sb for Lithium-Ion Battery Anodes James M. Mosby and Amy L. Prieto pp 10656–10661 DOI: 10.1021/ja801745n Supporting Info

Polymorphism of Zn[Au(CN)2]2 and Its Luminescent Sensory Response to NH3 Vapor Michael J. Katz, Taramatee Ramnial, Hua-Zhong Yu and Daniel B. Leznoff pp 10662–10673 DOI: 10.1021/ja801773p Supporting Info

Large exTTF-Based Dendrimers. Self-Assembly and Peripheral Cooperative Multiencapsulation of C60 Gustavo Fernndez, Luis Snchez, Emilio M. Prez and Nazario Martn pp 10674–10683 DOI: 10.1021/ja8018498 Supporting Info

The Carbon-Skeleton Rearrangement in Tropane Alkaloid Biosynthesis Gregory M. Sandala, David M. Smith and Leo Radom pp 10684–10690 DOI: 10.1021/ja801869a Supporting Info

Solvent Interactions and Conformational Choice in a Core N-Glycan Segment: Gas Phase Conformation of the Central, Branching Trimannose Unit and its Singly Hydrated Complex E. Cristina Stanca-Kaposta, David P. Gamblin, Emilio J. Cocinero, Jann Frey, Romano T. Kroemer, Antony J. Fairbanks, Benjamin G. Davis and John P. Simons pp 10691–10696 DOI: 10.1021/ja801892h Supporting Info

Modeling of Graphite Oxide D. W. Boukhvalov and M. I. Katsnelson pp 10697–10701 DOI: 10.1021/ja8021686 Supporting Info

Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants Wei Tang, Yungwan Kwak, Wade Braunecker, Nicolay V. Tsarevsky, Michelle L. Coote and Krzysztof Matyjaszewski pp 10702–10713 DOI: 10.1021/ja802290a Supporting Info

Orientational Dependence of Linear Dichroism Exemplified by Dyed Spherulites Jason B. Benedict, John H. Freudenthal, Eva Hollis and Bart Kahr pp 10714–10719 DOI: 10.1021/ja802322t Supporting Info

Enhance the Optical Absorptivity of Nanocrystalline TiO2 Film with High Molar Extinction Coefficient Ruthenium Sensitizers for High Performance Dye-Sensitized Solar Cells Feifei Gao, Yuan Wang, Dong Shi, Jing Zhang, Mingkui Wang, Xiaoyan Jing, Robin Humphry-Baker, Peng Wang, Shaik M. Zakeeruddin and Michael Grtzel pp 10720–10728 DOI: 10.1021/ja801942j Supporting Info

Multiethynyl Corannulenes: Synthesis, Structure, and Properties Yao-Ting Wu, Davide Bandera, Roman Maag, Anthony Linden, Kim K. Baldridge and Jay S. Siegel pp 10729–10739 DOI: 10.1021/ja802334n Supporting Info

Selective Metal Deposition on Photoswitchable Molecular Surfaces Tsuyoshi Tsujioka, Yusuke Sesumi, Rie Takagi, Kyoko Masui, Satoshi Yokojima, Kingo Uchida and Shinichiro Nakamura pp 10740–10747 DOI: 10.1021/ja802430q Supporting Info

Opposed Steric Constraints in Human DNA Polymerase β and E. coli DNA Polymerase I Francesca Di Pasquale, Daniela Fischer, Dina Grohmann, Tobias Restle, Armin Geyer and Andreas Marx pp 10748–10757 DOI: 10.1021/ja8028284

Structure of an F430 Variant from Archaea Associated with Anaerobic Oxidation of Methane Stefan Mayr, Christopher Latkoczy, Martin Krger, Detlef Gnther, Seigo Shima, Rudolf K. Thauer, Friedrich Widdel and Bernhard Jaun pp 10758–10767 DOI: 10.1021/ja802929z Supporting Info

Molecular Basis of DNA Photodimerization: Intrinsic Production of Cyclobutane Cytosine Dimers Daniel Roca-Sanjun, Gloria Olaso-Gonzlez, Israel Gonzlez-Ramrez, Luis Serrano-Andrs and Manuela Merchn pp 10768–10779 DOI: 10.1021/ja803068n Supporting Info

Synthesis and Characterization of Amino Derivatives of Persistent Trityl Radicals as Dual Function pH and Oxygen Paramagnetic Probes Ilirian Dhimitruka, Andrey A. Bobko, Christopher M. Hadad, Jay L. Zweier and Valery V. Khramtsov pp 10780–10787 DOI: 10.1021/ja803083z Supporting Info

Molecular Structure from a Single NMR Experiment riks Kupe and Ray Freeman pp 10788–10792 DOI: 10.1021/ja8036492 Supporting Info

Characterization of Subdomain IIA Binding Site of Human Serum Albumin in its Native, Unfolded, and Refolded States Using Small Molecular Probes Osama K. Abou-Zied and Othman I. K. Al-Shihi pp 10793–10801 DOI: 10.1021/ja8031289 Supporting Info

Design and Use of Organic Nanoparticles Prepared from Star-Shaped Polymers with Reactive End Groups Lieven M. Van Renterghem, Mieke Lammens, Bart Dervaux, Pascal Viville, Roberto Lazzaroni and Filip E. Du Prez pp 10802–10811 DOI: 10.1021/ja801055f Supporting Info

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization Travis J. Hebden, Melanie C. Denney, Vincent Pons, Paula M. B. Piccoli, Thomas F. Koetzle, Arthur J. Schultz, Werner Kaminsky, Karen I. Goldberg and D. Michael Heinekey pp 10812–10820 DOI: 10.1021/ja801898m Supporting Info

Efficient Catalytic Oxidation of Alkanes by Lewis Acid/[OsVI(N)Cl4]− Using Peroxides as Terminal Oxidants. Evidence for a Metal-Based Active Intermediate Shek-Man Yiu, Wai-Lun Man and Tai-Chu Lau pp 10821–10827 DOI: 10.1021/ja802625e Supporting Info

Hydroboration with Pyridine Borane at Room Temperature Julia M. Clay, Andrew G. Karatjas and Edwin Vedejs p 10828 DOI: 10.1021/ja8046602

Book Review of Dihydrogen Bonds: Principles, Experiments, and Applications Ray L. Sweany p 10829 DOI: 10.1021/ja804798f

Book Review of Asymmetric Organic Synthesis with Enzymes Sylvie Garneau-Tsodikova pp 10829–10830 DOI: 10.1021/ja8049047

Book Review of Organic Reactions, Volume 71 p 10830 DOI: 10.1021/ja804868c

Issue 33

Controlled Cyclopolymerization through Quantitative 19-Membered Ring Formation Bungo Ochiai, Yuuko Ootani and Takeshi Endo pp 10832–10833 DOI: 10.1021/ja801491m Supporting Info

Dynamic Combinatorial Discovery of a [2]-Catenane and its Guest-Induced Conversion into a Molecular Square Host Kevin R. West, R. Fred Ludlow, Peter T. Corbett, Pol Besenius, Friederike M. Mansfeld, Peter A. G. Cormack, David C. Sherrington, Jonathan M. Goodman, Marc C. A. Stuart and Sijbren Otto pp 10834–10835 DOI: 10.1021/ja801508q Supporting Info

Oxidative Quenching and Degradation of Polymer-Encapsulated Quantum Dots: New Insights into the Long-Term Fate and Toxicity of Nanocrystals in Vivo Michael C. Mancini, Brad A. Kairdolf, Andrew M. Smith and Shuming Nie pp 10836–10837 DOI: 10.1021/ja8040477 Supporting Info

CO2 Coordination by Inorganic Polyoxoanion in Water Guanggang Gao, Fengyan Li, Lin Xu, Xizheng Liu and Yanyan Yang pp 10838–10839 DOI: 10.1021/ja801560t Supporting Info

Two Dimensional Chiral Networks Emerging from the Aryl−F···H Hydrogen-Bond-Driven Self-Assembly of Partially Fluorinated Rigid Molecular Structures Zhongcheng Mu, Lijin Shu, Harald Fuchs, Marcel Mayor and Lifeng Chi pp 10840–10841 DOI: 10.1021/ja801925q Supporting Info

Does Electrospray Ionization Produce Gas-Phase or Liquid-Phase Structures? Zhixin Tian and Steven R. Kass pp 10842–10843 DOI: 10.1021/ja802088u Supporting Info

Ground-State Recovery Following UV Excitation is Much Slower in G·C−DNA Duplexes and Hairpins Than in Mononucleotides Carlos E. Crespo-Hernndez, Kimberly de La Harpe and Bern Kohler pp 10844–10845 DOI: 10.1021/ja802183s Supporting Info

Determination of Physiological Thiols by Electrochemical Detection with Piazselenole and Its Application in Rat Breast Cancer Cells 4T-1 Wei Wang, Lin Li, Shufeng Liu, Cuiping Ma and Shusheng Zhang pp 10846–10847 DOI: 10.1021/ja802273p Supporting Info

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates Serge I. Gorelsky, David Lapointe and Keith Fagnou pp 10848–10849 DOI: 10.1021/ja802533u Supporting Info

Evidence for Dynamics on a 100 ns Time Scale from Single- and Double-Quantum Nitrogen-14 NMR in Solid Peptides Simone Cavadini, Anuji Abraham, Simone Ulzega and Geoffrey Bodenhausen pp 10850–10851 DOI: 10.1021/ja802603q

Ion-Sensitive “Isothermal” Responsive Polymers Prepared in Water Johannes Pall Magnusson, Adnan Khan, George Pasparakis, Aram Omer Saeed, Wenxin Wang and Cameron Alexander pp 10852–10853 DOI: 10.1021/ja802609r Supporting Info

Substituent Effects in the Benzene Dimer are Due to Direct Interactions of the Substituents with the Unsubstituted Benzene Steven E. Wheeler and K. N. Houk pp 10854–10855 DOI: 10.1021/ja802849j Supporting Info

Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Nanotubes Zhi Zhu, Zhiwen Tang, Joseph A. Phillips, Ronghua Yang, Hui Wang and Weihong Tan pp 10856–10857 DOI: 10.1021/ja802913f Supporting Info

Separating Chemical Shift and Quadrupolar Anisotropies via Multiple-Quantum NMR Spectroscopy Jason T. Ash, Nicole M. Trease and Philip J. Grandinetti pp 10858–10859 DOI: 10.1021/ja802865x Supporting Info

Finding the Proton in a Key Intermediate of anti-Markovnikov Alkyne Hydration by a Bifunctional Catalyst Douglas B. Grotjahn, Elijah J. Kragulj, Constantinos D. Zeinalipour-Yazdi, Valentn Miranda-Soto, Daniel A. Lev and Andrew L. Cooksy pp 10860–10861 DOI: 10.1021/ja803106z Supporting Info

Hydrogen Evolution Reaction Catalyzed by Proton-Coupled Redox Cycle of 4,4′-Bipyridine Monolayer Adsorbed on Silver Electrodes Taro Uchida, Hirokazu Mogami, Akira Yamakata, Yoichi Sasaki and Masatoshi Osawa pp 10862–10863 DOI: 10.1021/ja803446s Supporting Info

Iterative Molecular Assembly Based on the Cation-Pool Method. Convergent Synthesis of Dendritic Molecules Toshiki Nokami, Kousuke Ohata, Masafumi Inoue, Hiroaki Tsuyama, Akito Shibuya, Kazuya Soga, Masayuki Okajima, Seiji Suga and Jun-ichi Yoshida pp 10864–10865 DOI: 10.1021/ja803487q Supporting Info

Block Copolymer-like Self-Assembly of Fluorocarbon End-Functionalized Polystyrene and Polybutylmethacrylate Jingguo Shen and Thieo Hogen-Esch pp 10866–10867 DOI: 10.1021/ja803375a Supporting Info

Utilization of the Three-Dimensional Volcano Surface To Understand the Chemistry of Multiphase Systems in Heterogeneous Catalysis Jun Cheng and P. Hu pp 10868–10869 DOI: 10.1021/ja803555g Supporting Info

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores Stephen R. Caskey, Antek G. Wong-Foy and Adam J. Matzger pp 10870–10871 DOI: 10.1021/ja8036096 Supporting Info

An NMR Experiment for Simultaneous TROSY-Based Detection of Amide and Methyl Groups in Large Proteins Chenyun Guo, Daoning Zhang and Vitali Tugarinov pp 10872–10873 DOI: 10.1021/ja8036178

Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp2Zr(H)Cl Xiaotao Pu and Joseph M. Ready pp 10874–10875 DOI: 10.1021/ja8035527 Supporting Info

PEGylated Nanographene Oxide for Delivery of Water-Insoluble Cancer Drugs Zhuang Liu, Joshua T. Robinson, Xiaoming Sun and Hongjie Dai pp 10876–10877 DOI: 10.1021/ja803688x Supporting Info

Chiral Ammonium Betaines: A Bifunctional Organic Base Catalyst for Asymmetric Mannich-Type Reaction of α-Nitrocarboxylates Daisuke Uraguchi, Kyohei Koshimoto and Takashi Ooi pp 10878–10879 DOI: 10.1021/ja8041004 Supporting Info

Helical Carbon and Graphitic Films Prepared from Iodine-Doped Helical Polyacetylene Film Using Morphology-Retaining Carbonization Mutsumasa Kyotani, Satoshi Matsushita, Takuro Nagai, Yoshio Matsui, Masaki Shimomura, Akira Kaito and Kazuo Akagi pp 10880–10881 DOI: 10.1021/ja803865e Supporting Info

Coupling Across a DNA Helical Turn Yields a Hybrid DNA/Organic Catenane Doubly Tailed with Functional Termini Yu Liu, Akinori Kuzuya, Ruojie Sha, Johan Guillaume, Risheng Wang, James W. Canary and Nadrian C. Seeman pp 10882–10883 DOI: 10.1021/ja8041096 Supporting Info

Separation and Molecular-Level Segregation of Complex Alkane Mixtures in Metal−Organic Frameworks David Dubbeldam, Casey J. Galvin, Krista S. Walton, Donald E. Ellis and Randall Q. Snurr pp 10884–10885 DOI: 10.1021/ja804039c Supporting Info

Total Synthesis of (±)-Psychotrimine Timothy Newhouse and Phil S. Baran pp 10886–10887 DOI: 10.1021/ja8042307 Supporting Info

Biochemically Controlled Bioelectrocatalytic Interface Tsz Kin Tam, Jian Zhou, Marcos Pita, Maryna Ornatska, Sergiy Minko and Evgeny Katz pp 10888–10889 DOI: 10.1021/ja8043882 Supporting Info

Fluoride Ion Chelation By a Bidentate Phosphonium/Borane Lewis Acid Todd W. Hudnall, Young-Min Kim, Magnus W. P. Bebbington, Didier Bourissou and Franois P. Gabba pp 10890–10891 DOI: 10.1021/ja804492y Supporting Info

Pyramidal Lead Sulfide Crystallites With High Energy {113} Facets Dongbo Fan, P. John Thomas and Paul O’Brien pp 10892–10894 DOI: 10.1021/ja804516q Supporting Info

Solution Phase Measurement of Both Weak σ and C−H···X− Hydrogen Bonding Interactions in Synthetic Anion Receptors Orion B. Berryman, Aaron C. Sather, Benjamin P. Hay, Jeffrey S. Meisner and Darren W. Johnson pp 10895–10897 DOI: 10.1021/ja8035652 Supporting Info

Rearrangement of the (6S,8R,11S) and (6R,8S,11R) Exocyclic 1,N2-Deoxyguanosine Adducts of trans-4-Hydroxynonenal to N2-Deoxyguanosine Cyclic Hemiacetal Adducts When Placed Complementary to Cytosine in Duplex DNA Hai Huang, Hao Wang, Nan Qi, Albena Kozekova, Carmelo J. Rizzo and Michael P. Stone pp 10898–10906 DOI: 10.1021/ja801824b

A Nickel Hydride Complex in the Active Site of Methyl-Coenzyme M Reductase: Implications for the Catalytic Cycle Jeffrey Harmer, Cinzia Finazzo, Rafal Piskorski, Sieglinde Ebner, Evert C. Duin, Meike Goenrich, Rudolf K. Thauer, Markus Reiher, Arthur Schweiger, Dariush Hinderberger and Bernhard Jaun pp 10907–10920 DOI: 10.1021/ja710949e Supporting Info

DNA Structural Distortions Induced by Ruthenium−Arene Anticancer Compounds Christian Gossens, Ivano Tavernelli and Ursula Rothlisberger pp 10921–10928 DOI: 10.1021/ja800194a Supporting Info

Nitric Oxide Physiological Responses and Delivery Mechanisms Probed by Water-Soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC Yi-Ju Chen, Wei-Chi Ku, Li-Ting Feng, Ming-Li Tsai, Chung-Hung Hsieh, Wen-Hwei Hsu, Wen-Feng Liaw, Chen-Hsiung Hung and Yu-Ju Chen pp 10929–10938 DOI: 10.1021/ja711494m Supporting Info

Hydration and Conformational Mechanics of Single, End-Tethered Elastin-like Polypeptides Alexei Valiaev, Dong Woo Lim, Scott Schmidler, Robert L. Clark, Ashutosh Chilkoti and Stefan Zauscher pp 10939–10946 DOI: 10.1021/ja800502h Supporting Info

Effect of Spin−Orbit Coupling on Reduction Potentials of Octahedral Ruthenium(II/III) and Osmium(II/III) Complexes Martin Srnec, Jakub Chalupsk, Miroslav Fojta, Lucie Zendlov, Ludk Havran, Michal Hocek, Mojmr Kvala and Lubomr Rulek pp 10947–10954 DOI: 10.1021/ja800616s Supporting Info

Phosphodiester Cleavage in Ribonuclease H Occurs via an Associative Two-Metal-Aided Catalytic Mechanism Marco De Vivo, Matteo Dal Peraro and Michael L. Klein pp 10955–10962 DOI: 10.1021/ja8005786 Supporting Info

A New Model for Thermal Diffusion: Kinetic Approach Pierre-Arnaud Artola, Bernard Rousseau and Guillaume Galliro pp 10963–10969 DOI: 10.1021/ja800817f

Time, Space, and Spectrally Resolved Studies on J-Aggregate Interactions in Zeolite L Nanochannels Michael Busby, Christian Blum, Marc Tibben, Sandra Fibikar, Gion Calzaferri, Vinod Subramaniam and Luisa De Cola pp 10970–10976 DOI: 10.1021/ja801178p Supporting Info

Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled “Nanozyme” Courtney J. Hastings, Dorothea Fiedler, Robert G. Bergman and Kenneth N. Raymond pp 10977–10983 DOI: 10.1021/ja8013055 Supporting Info

In Search of Efficient 5-Endo-dig Cyclization of a Carbon-Centered Radical: 40 Years from a Prediction to Another Success for the Baldwin Rules Igor V. Alabugin, Vitaliy I. Timokhin, Jason N. Abrams, Mariappan Manoharan, Rachel Abrams and Ion Ghiviriga pp 10984–10995 DOI: 10.1021/ja801478n Supporting Info

Comprehensive Mechanism and Structure-Sensitivity of Ethanol Oxidation on Platinum: New Transition-State Searching Method for Resolving the Complex Reaction Network Hui-Fang Wang and Zhi-Pan Liu pp 10996–11004 DOI: 10.1021/ja801648h Supporting Info

Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C−H Bond Activation and Carbon−Carbon Bond Formation Shun-Ichi Murahashi, Takahiro Nakae, Hiroyuki Terai and Naruyoshi Komiya pp 11005–11012 DOI: 10.1021/ja8017362 Supporting Info

Cyclic [2]Pseudorotaxane Tetramers Consisting of Two Rigid Rods Threaded through Two Bis-Macrocycles: Copper(I)-Templated Synthesis and X-ray Structure Studies Julien Frey, Christian Tock, Jean-Paul Collin, Valrie Heitz, Jean-Pierre Sauvage and Kari Rissanen pp 11013–11022 DOI: 10.1021/ja801924y Supporting Info

Nitrogen-14 Solid-State NMR Spectroscopy of Aligned Phospholipid Bilayers to Probe Peptide−Lipid Interaction and Oligomerization of Membrane Associated Peptides Ayyalusamy Ramamoorthy, Dong-Kuk Lee, Jose S. Santos and Katherine A. Henzler-Wildman pp 11023–11029 DOI: 10.1021/ja802210u

Atomic Scale Insights on Chlorinated γ-Alumina Surfaces Mathieu Digne, Pascal Raybaud, Philippe Sautet, Denis Guillaume and Herv Toulhoat pp 11030–11039 DOI: 10.1021/ja8019593

End Capping Ring-Opening Olefin Metathesis Polymerization Polymers with Vinyl Lactones Stefan Hilf, Robert H. Grubbs and Andreas F. M. Kilbinger pp 11040–11048 DOI: 10.1021/ja8022863 Supporting Info

Synthesis and Stability of Monolayer-Protected Au38 Clusters Outi Toikkanen, Virginia Ruiz, Gunilla Rnnholm, Nisse Kalkkinen, Peter Liljeroth and Bernadette M. Quinn pp 11049–11055 DOI: 10.1021/ja802317t Supporting Info

Application of Solid-State 35Cl NMR to the Structural Characterization of Hydrochloride Pharmaceuticals and their Polymorphs Hiyam Hamaed, Jenna M. Pawlowski, Benjamin F.T. Cooper, Riqiang Fu, S. Holger Eichhorn and Robert W. Schurko pp 11056–11065 DOI: 10.1021/ja802486q Supporting Info

Role of Water in Mediating the Assembly of Alzheimer Amyloid-β Aβ16−22 Protofilaments Mary Griffin Krone, Lan Hua, Patricia Soto, Ruhong Zhou, B. J. Berne and Joan-Emma Shea pp 11066–11072 DOI: 10.1021/ja8017303 Supporting Info

Conducting Polymer Memory Devices Based on Dynamic Doping Sudip Barman, Fengjun Deng and Richard L. McCreery pp 11073–11081 DOI: 10.1021/ja802673w Supporting Info

Isomorphism of Anhydrous Tetrahedral Halides and Silicon Chalcogenides: Energy Landscape of Crystalline BeF2, BeCl2, SiO2, and SiS2 Martijn A. Zwijnenburg, Furio Cor and Robert G. Bell pp 11082–11087 DOI: 10.1021/ja8026967 Supporting Info

Kinetics and Mechanism of Olefin Epoxidation with Aqueous H2O2 and a Highly Selective Surface-Modified TaSBA15 Heterogeneous Catalyst Daniel A. Ruddy and T. Don Tilley pp 11088–11096 DOI: 10.1021/ja8027313 Supporting Info

Dependence of Amino Acid Side Chain 13C Shifts on Dihedral Angle: Application to Conformational Analysis Robert E. London, Brett D. Wingad and Geoffrey A. Mueller pp 11097–11105 DOI: 10.1021/ja802729t Supporting Info

Hydrogen Production under Aerobic Conditions by Membrane-Bound Hydrogenases from Ralstonia Species Gabrielle Goldet, Annemarie F. Wait, James A. Cracknell, Kylie A. Vincent, Marcus Ludwig, Oliver Lenz, Brbel Friedrich and Fraser A. Armstrong pp 11106–11113 DOI: 10.1021/ja8027668 Supporting Info

Total Synthesis, Revised Structure, and Biological Evaluation of Biyouyanagin A and Analogues Thereof K. C. Nicolaou, T. Robert Wu, David Sarlah, David M. Shaw, Eric Rowcliffe and Dennis R. Burton pp 11114–11121 DOI: 10.1021/ja802805c Supporting Info

Molecular All-Photonic Encoder−Decoder Joakim Andrasson, Stephen D. Straight, Thomas A. Moore, Ana L. Moore and Devens Gust pp 11122–11128 DOI: 10.1021/ja802845z

Mixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers Maria Manoli, Anna Collins, Simon Parsons, Andrea Candini, Marco Evangelisti and Euan K. Brechin pp 11129–11139 DOI: 10.1021/ja802829d Supporting Info

Molecular Mechanisms of a Single H2O Diffusion on Palladium Surfaces Jibiao Li, Shenglong Zhu, Ying Li and Fuhui Wang pp 11140–11142 DOI: 10.1021/ja802819f Supporting Info

Nonadditivity of Secondary Deuterium Isotope Effects on Basicity of Trimethylamine Charles L. Perrin and Yanmei Dong pp 11143–11148 DOI: 10.1021/ja803084w Supporting Info

Thioesterase-Like Role for Fungal PKS-NRPS Hybrid Reductive Domains James W. Sims and Eric W. Schmidt pp 11149–11155 DOI: 10.1021/ja803078z Supporting Info

Selective Peptide Binding Using Facially Amphiphilic Dendrimers Andrea Gomez-Escudero, Malar A. Azagarsamy, Naresh Theddu, Richard W. Vachet and S. Thayumanavan pp 11156–11163 DOI: 10.1021/ja803082v

Bridging Across Length Scales: Multi-Scale Ordering of Supported Lipid Bilayers via Lipoprotein Self-assembly and Surface Patterning Madhuri S. Vinchurkar, Daniel A. Bricarello, Jens O. Lagerstedt, James P. Buban, Henning Stahlberg, Michael N. Oda, John C. Voss and Atul N. Parikh pp 11164–11169 DOI: 10.1021/ja803110v Supporting Info

Heteronuclear NMR Investigation on the Structure and Dynamics of the Chromophore Binding Pocket of the Cyanobacterial Phytochrome Cph1 Janina Hahn, Holger M. Strauss and Peter Schmieder pp 11170–11178 DOI: 10.1021/ja8031086

G-Quadruplex Formation by Human Telomeric Repeats-Containing RNA in Na+ Solution Yan Xu, Kuniyuki Kaminaga and Makoto Komiyama pp 11179–11184 DOI: 10.1021/ja8031532 Supporting Info

Two-Dimensional Combinatorial Screening Identifies Specific Aminoglycoside−RNA Internal Loop Partners Matthew D. Disney, Lucas P. Labuda, Dustin J. Paul, Shane G. Poplawski, Alexei Pushechnikov, Tuan Tran, Sai P. Velagapudi, Meilan Wu and Jessica L. Childs-Disney pp 11185–11194 DOI: 10.1021/ja803234t Supporting Info

Ultrafast UV−Vis and IR Studies of p-Biphenylyl Acetyl and Carbomethoxy Carbenes Jin Wang, Gotard Burdzinski, Jacek Kubicki and Matthew S. Platz pp 11195–11209 DOI: 10.1021/ja803096p Supporting Info

Palladium(II)-Catalyzed Rearrangement of Glycal Trichloroacetimidates: Application to the Stereoselective Synthesis of Glycosyl Ureas Gregory J. Mercer, Jaemoon Yang, Matthew J. McKay and Hien M. Nguyen pp 11210–11218 DOI: 10.1021/ja803378k Supporting Info

Total Synthesis and Biological Mode of Action of Largazole: A Potent Class I Histone Deacetylase Inhibitor Albert Bowers, Nathan West, Jack Taunton, Stuart L. Schreiber, James E. Bradner and Robert M. Williams pp 11219–11222 DOI: 10.1021/ja8033763 Supporting Info

Nonhydrolytic Synthesis of High-Quality Anisotropically Shaped Brookite TiO2 Nanocrystals Raffaella Buonsanti, Vincenzo Grillo, Elvio Carlino, Cinzia Giannini, Tobias Kipp, Roberto Cingolani and Pantaleo Davide Cozzoli pp 11223–11233 DOI: 10.1021/ja803559b Supporting Info

Proton Affinity of Methyl Nitrite and Methyl Peroxynitrite: Implications for Measuring Branching Ratios of Alkyl Nitrates and Nitrites Rose M. Ravelo and Joseph S. Francisco pp 11234–11239 DOI: 10.1021/ja8045662 Supporting Info

Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of trans-Vinylcyclopropane-enes Lei Jiao, Siyu Ye and Zhi-Xiang Yu p 11240 DOI: 10.1021/ja805112v

Book Review of Handbook of Chemical Glycosylation: Advances in Stereoselectivity and Therapeutic Relevance Ryan Gilmour and Peter H. Seeberger p 11241 DOI: 10.1021/ja805038e

Book Review of Advances in Chemical Physics, Volume 138 Amy S. Mullin pp 11241–11242 DOI: 10.1021/ja805061g

Book Review of Materials Handbook: A Concise Desktop Reference, 2nd ed. p 11242 DOI: 10.1021/ja805138a

Book Review of Pharmaceutical Applications of Raman Spectroscopy p 11242 DOI: 10.1021/ja805341d

Issue 34

Preparation of σ- and π-Allylcopper(III) Intermediates in SN2 and SN2′ Reactions of Organocuprate(I) Reagents with Allylic Substrates Erika R. Bartholomew, Steven H. Bertz, Stephen Cope, Michael Murphy and Craig A. Ogle pp 11244–11245 DOI: 10.1021/ja801186c Supporting Info

How Fast Do Metal Organic Polyhedra Form in Solution? Kinetics of [Cu2(5-OH-bdc)2L2]12 Formation in Methanol Randy W. Larsen pp 11246–11247 DOI: 10.1021/ja802605v Supporting Info

Catalytic C−H Amination for the Preparation of Substituted 1,2-Diamines David E. Olson and J. Du Bois pp 11248–11249 DOI: 10.1021/ja803344v Supporting Info

Carbonate Formation and Decomposition on Atomic Oxygen Precovered Au(111) Rotimi A. Ojifinni, Jinlong Gong, Nathan S. Froemming, David W. Flaherty, Ming Pan, Graeme Henkelman and C. Buddie Mullins pp 11250–11251 DOI: 10.1021/ja803482h

Blocking the Lateral Film Growth at the Nanoscale in Area-Selective Atomic Layer Deposition Robin H. A. Ras, Elina Sahramo, Jari Malm, Janne Raula and Maarit Karppinen pp 11252–11253 DOI: 10.1021/ja803471g Supporting Info

Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers Feng Wang, Chenyou Han, Chunlin He, Qizhong Zhou, Jinqiang Zhang, Cong Wang, Ning Li and Feihe Huang pp 11254–11255 DOI: 10.1021/ja8035465 Supporting Info

Self-Etching Reconstruction of Hierarchically Mesoporous F-TiO2 Hollow Microspherical Photocatalyst for Concurrent Membrane Water Purifications Jia Hong Pan, Xiwang Zhang, Alan Jianhong Du, Darren D. Sun and James O. Leckie pp 11256–11257 DOI: 10.1021/ja803582m Supporting Info

Remarkable Rare-Earth Metal Silicide Oxides with Planar Si6 Rings Limin Wang, Zhongjia Tang, Bernd Lorenz and Arnold M. Guloy pp 11258–11259 DOI: 10.1021/ja803632x Supporting Info

Indicator Displacement Assays as Molecular Timers Andrey Buryak, Friederike Zaubitzer, Alexei Pozdnoukhov and Kay Severin pp 11260–11261 DOI: 10.1021/ja8037118 Supporting Info

An Unusally Diverse Array of Products Formed upon Carbonylation of a Dialkylniobium Complex Neil C. Tomson, Andrew Yan, John Arnold and Robert G. Bergman pp 11262–11263 DOI: 10.1021/ja803729k Supporting Info

Engineering Selectivity in Heterogeneous Catalysis: Ag Nanowires as Selective Ethylene Epoxidation Catalysts Phillip Christopher and Suljo Linic pp 11264–11265 DOI: 10.1021/ja803818k Supporting Info

On the Origin of NMR Dipolar Waves in Transient Helical Elements of Partially Folded Proteins Malene Ringkjøbing Jensen and Martin Blackledge pp 11266–11267 DOI: 10.1021/ja8039184 Supporting Info

Aptamer Switch Probe Based on Intramolecular Displacement Zhiwen Tang, Prabodhika Mallikaratchy, Ronghua Yang, Youngmi Kim, Zhi Zhu, Hui Wang and Weihong Tan pp 11268–11269 DOI: 10.1021/ja804119s Supporting Info

A General and Highly Selective Chelate-Controlled Intermolecular Oxidative Heck Reaction Jared H. Delcamp, Alexandria P. Brucks and M. Christina White pp 11270–11271 DOI: 10.1021/ja804120r Supporting Info

Unusual Oxidation of Organics at Interfaces from the Bottom Up and Atmospheric Implications Federico Karagulian, Christopher W. Dilbeck and Barbara J. Finlayson-Pitts pp 11272–11273 DOI: 10.1021/ja8041965

Evidence for Protein Radical-Mediated Nuclear Tunneling in Fatty Acid α-Oxygenase Ankur Gupta, Arnab Mukherjee, Kenji Matsui and Justine P. Roth pp 11274–11275 DOI: 10.1021/ja8042273 Supporting Info

Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride Tsuneyuki Kobayashi, Hirohisa Ohmiya, Hideki Yorimitsu and Koichiro Oshima pp 11276–11277 DOI: 10.1021/ja804277x Supporting Info

Minimizing the Hydrodynamic Size of Quantum Dots with Multifunctional Multidentate Polymer Ligands Andrew M. Smith and Shuming Nie pp 11278–11279 DOI: 10.1021/ja804306c Supporting Info

Intermittent Electron Transfer Activity From Single CdSe/ZnS Quantum Dots Abey Issac, Shengye Jin and Tianquan Lian pp 11280–11281 DOI: 10.1021/ja8043085 Supporting Info

Mismatched Hartmann−Hahn Conditions Cause Proton-Mediated Intermolecular Magnetization Transfer between Dilute Low-Spin Nuclei in NMR of Static Solids Alexander A. Nevzorov pp 11282–11283 DOI: 10.1021/ja804326b Supporting Info

Stereoselective Interaction between DNA and Chiral Surfaces Kangjian Tang, Hui Gan, Yong Li, Lifeng Chi, Taolei Sun and Harald Fuchs pp 11284–11285 DOI: 10.1021/ja8044184 Supporting Info

A Stable Anionic N-Heterocyclic Carbene and Its Zwitterionic Complexes Vincent Csar, Nol Lugan and Guy Lavigne pp 11286–11287 DOI: 10.1021/ja804296t Supporting Info

Temperature-Regulated Activity of Responsive Polymer−Protein Conjugates Prepared by Grafting-from via RAFT Polymerization Priyadarsi De, Ming Li, Sudershan R. Gondi and Brent S. Sumerlin pp 11288–11289 DOI: 10.1021/ja804495v Supporting Info

Microelectrode Arrays and Ceric Ammonium Nitrate: A Simple Strategy for Developing New Site-Selective Synthetic Methods David Kesselring, Karl Maurer and Kevin D. Moeller pp 11290–11291 DOI: 10.1021/ja804661h Supporting Info

An Expedient Asymmetric Synthesis of Platencin K. C. Nicolaou, Qiao-Yan Toh and David Y.-K. Chen pp 11292–11293 DOI: 10.1021/ja804588r Supporting Info

A Redox-Switchable α-Cyclodextrin-Based [2]Rotaxane Yan-Li Zhao, William R. Dichtel, Ali Trabolsi, Sourav Saha, Ivan Aprahamian and J. Fraser Stoddart pp 11294–11296 DOI: 10.1021/ja8036146 Supporting Info

Enantioselective Total Syntheses of Nankakurines A and B: Confirmation of Structure and Establishment of Absolute Configuration Bradley L. Nilsson, Larry E. Overman, Javier Read de Alaniz and Jason M. Rohde pp 11297–11299 DOI: 10.1021/ja804624u Supporting Info

Pd-Catalyzed Direct Arylation of Tautomerizable Heterocycles with Aryl Boronic Acids via C−OH Bond Activation Using Phosphonium Salts Fu-An Kang, Zhihua Sui and William V. Murray pp 11300–11302 DOI: 10.1021/ja804804p Supporting Info

New Open-Chain Tetrapyrroles as Chromophores in the Plant Photoreceptor Phytochrome Uwe Robben, Ingo Lindner and Wolfgang Grtner pp 11303–11311 DOI: 10.1021/ja076728y Supporting Info

High Carrier Density and Capacitance in TiO2 Nanotube Arrays Induced by Electrochemical Doping Francisco Fabregat-Santiago, Eva M. Barea, Juan Bisquert, Gopal K. Mor, Karthik Shankar and Craig A. Grimes pp 11312–11316 DOI: 10.1021/ja710899q

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir Rajshekhar Ghosh, Thomas J. Emge, Karsten Krogh-Jespersen and Alan S. Goldman pp 11317–11327 DOI: 10.1021/ja800434r Supporting Info

Structure Determination of an Interstrand-Type Cis-Anti Cyclobutane Thymine Dimer Produced in High Yield by UVB Light in an Oligodeoxynucleotide at Acidic pH Dian G. T. Su, Jeffrey L.-F. Kao, Michael L. Gross and John-Stephen A. Taylor pp 11328–11337 DOI: 10.1021/ja8010836 Supporting Info

Fluorescent Conjugated Polyelectrolyte as an Indicator for Convenient Detection of DNA Methylation Fude Feng, Hongzhong Wang, Lingli Han and Shu Wang pp 11338–11343 DOI: 10.1021/ja8011963 Supporting Info

Photolysis of Dibenzyl Ketones Sorbed on MFI Zeolites in the Presence of Spectator Molecules: Cage Effects, Kinetics, and External Surface Sites Characterization Alberto Moscatelli, Zhiqiang Liu, Xuegong Lei, Joanne Dyer, Lloyd Abrams, M. Francesca Ottaviani and Nicholas J. Turro pp 11344–11354 DOI: 10.1021/ja801487v

Visible Light-Induced Electron Transfer from Di-μ-oxo-Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores Walter W. Weare, Yulia Pushkar, Vittal K. Yachandra and Heinz Frei pp 11355–11363 DOI: 10.1021/ja801546a Supporting Info

Oxygen Self-Doping in Hollandite-Type Vanadium Oxyhydroxide Nanorods Igor Djerdj, Denis Sheptyakov, Fabia Gozzo, Denis Aron, Reinhard Nesper and Markus Niederberger pp 11364–11375 DOI: 10.1021/ja801813a Supporting Info

Synthesis, Reactivity, and Electronic Structure of [n]Vanadoarenophanes: An Experimental and Theoretical Study Holger Braunschweig, Martin Kaupp, Christopher J. Adams, Thomas Kupfer, Krzysztof Radacki, Sandra Schinzel and pp 11376–11393 DOI: 10.1021/ja802034p Supporting Info

Biosynthesis of the Thiamin-Thiazole in Eukaryotes: Identification of a Thiazole Tautomer Intermediate Abhishek Chatterjee, Frank C. Schroeder, Christopher T. Jurgenson, Steven E. Ealick and Tadhg P. Begley pp 11394–11398 DOI: 10.1021/ja802140a Supporting Info

Origins of Enhanced Proton Transport in the Y7F Mutant of Human Carbonic Anhydrase II C. Mark Maupin, Marissa G. Saunders, Ian F. Thorpe, Robert McKenna, David N. Silverman and Gregory A. Voth pp 11399–11408 DOI: 10.1021/ja802264j Supporting Info

Planar Chiral Azobenzenophanes as Chiroptic Switches for Photon Mode Reversible Reflection Color Control in Induced Chiral Nematic Liquid Crystals Manoj Mathews and Nobuyuki Tamaoki pp 11409–11416 DOI: 10.1021/ja802472t Supporting Info

Carbon Dioxide Hydrogenation on Ni(110) Erik Vesselli, Loredana De Rogatis, Xunlei Ding, Alessandro Baraldi, Letizia Savio, Luca Vattuone, Mario Rocca, Paolo Fornasiero, Maria Peressi, Alfonso Baldereschi, Renzo Rosei and Giovanni Comelli pp 11417–11422 DOI: 10.1021/ja802554g

Supramolecular Catalysis of Orthoformate Hydrolysis in Basic Solution: An Enzyme-Like Mechanism Michael D. Pluth, Robert G. Bergman and Kenneth N. Raymond pp 11423–11429 DOI: 10.1021/ja802839v Supporting Info

Mesoporous Compound Semiconductors from the Reaction of Metal Ions with Deltahedral [Ge9]4− Clusters Gerasimos S. Armatas and Mercouri G. Kanatzidis pp 11430–11436 DOI: 10.1021/ja802940w Supporting Info

Soluble Poly(diacetylene)s Using the Perfluorophenyl−Phenyl Motif as a Supramolecular Synthon Rui Xu, W. Bernd Schweizer and Holger Frauenrath pp 11437–11445 DOI: 10.1021/ja802964a Supporting Info

Isolation and Structural Characterization of Capistruin, a Lasso Peptide Predicted from the Genome Sequence of Burkholderia thailandensis E264 Thomas A. Knappe, Uwe Linne, Sverine Zirah, Sylvie Rebuffat, Xiulan Xie and Mohamed A. Marahiel pp 11446–11454 DOI: 10.1021/ja802966g Supporting Info

Alkene Hydrogenation on an 11-Vertex Rhodathiaborane with Full Cluster Participation lvaro lvarez, Ramn Macas, Jonathan Bould, Mara Jos Fabra, Fernando J. Lahoz and Luis A. Oro pp 11455–11466 DOI: 10.1021/ja802993m Supporting Info

Targeted Single-Wall Carbon Nanotube-Mediated Pt(IV) Prodrug Delivery Using Folate as a Homing Device Shanta Dhar, Zhuang Liu, Jrgen Thomale, Hongjie Dai and Stephen J. Lippard pp 11467–11476 DOI: 10.1021/ja803036e Supporting Info

Kinetics of Folding and Binding of an Intrinsically Disordered Protein: The Inhibitor of Yeast Aspartic Proteinase YPrA Ranjani Narayanan, Omjoy K. Ganesh, Arthur S. Edison and Stephen J. Hagen pp 11477–11485 DOI: 10.1021/ja803221c Supporting Info

Second-Generation Difluorinated Cyclooctynes for Copper-Free Click Chemistry Julian A. Codelli, Jeremy M. Baskin, Nicholas J. Agard and Carolyn R. Bertozzi pp 11486–11493 DOI: 10.1021/ja803086r Supporting Info

Synthesis, Characterization, and Computational Studies of 6-(RR′N)-nido-5,7-C2B8H11: A Polyborane Cluster with a Cage-Boron Having an Exopolyhedral Dative Boron−Nitrogen Double Bond Yuqi Li and Larry G. Sneddon pp 11494–11502 DOI: 10.1021/ja803297b Supporting Info

Facile Decoration of Functionalized Single-Wall Carbon Nanotubes with Phthalocyanines via “Click Chemistry” Stphane Campidelli, Beatriz Ballesteros, Arianna Filoramo, David Daz Daz, Gema de la Torre, Toms Torres, G. M. Aminur Rahman, Christian Ehli, Daniel Kiessling, Fabian Werner, Vito Sgobba, Dirk M. Guldi, Carla Cioffi, Maurizio Prato and Jean-Philippe Bourgoin pp 11503–11509 DOI: 10.1021/ja8033262 Supporting Info

Direct Imaging of Surface Topology and Pore System of Ordered Mesoporous Silica (MCM-41, SBA-15, and KIT-6) and Nanocast Metal Oxides by High Resolution Scanning Electron Microscopy Harun Tysz, Christian W. Lehmann, Hans Bongard, Bernd Tesche, Roland Schmidt and Ferdi Schth pp 11510–11517 DOI: 10.1021/ja803362s Supporting Info

Self-Directed Chain Reaction by Small Ketones with the Dangling Bond Site on the Si(100)-(2 × 1)-H Surface: Acetophenone, A Unique Example Md. Zakir Hossain, Hiroyuki S. Kato and Maki Kawai pp 11518–11523 DOI: 10.1021/ja8033944

The Siderocalin/Enterobactin Interaction: A Link between Mammalian Immunity and Bacterial Iron Transport1 Rebecca J. Abergel, Matthew C. Clifton, Juan C. Pizarro, Jeffrey A. Warner, David K. Shuh, Roland K. Strong and Kenneth N. Raymond pp 11524–11534 DOI: 10.1021/ja803524w Supporting Info

Radical Cascade Transformations of Tris(o-aryleneethynylenes) into Substituted Benzo[a]indeno[2,1-c]fluorenes Igor V. Alabugin, Kerry Gilmore, Satish Patil, Mariappan Manoharan, Serguei V. Kovalenko, Ronald J. Clark and Ion Ghiviriga pp 11535–11545 DOI: 10.1021/ja8038213 Supporting Info

Intermolecular Enolate Heterocoupling: Scope, Mechanism, and Application Michael P. DeMartino, Ke Chen and Phil S. Baran pp 11546–11560 DOI: 10.1021/ja804159y Supporting Info

A Targetable Fluorescent Probe for Imaging Hydrogen Peroxide in the Mitochondria of Living Cells Bryan C. Dickinson and Christopher J. Chang p 11561 DOI: 10.1021/ja805448s

Book Review of Modern Alkaloids: Structure, Isolation, Synthesis and Biology Robert M. Williams, Ph.D. p 11562 DOI: 10.1021/ja8031345

Issue 35

Acid-Sensitive Semiperfluoroalkyl Resorcinarene: An Imaging Material for Organic Electronics Jin-Kyun Lee, Margarita Chatzichristidi, Alexander A. Zakhidov, Priscilla G. Taylor, John A. DeFranco, Ha Soo Hwang, Hon Hang Fong, Andrew B. Holmes, George G. Malliaras and Christopher K. Ober pp 11564–11565 DOI: 10.1021/ja803493m Supporting Info

Direct Evidence for Interactions between Acidic Functional Groups and Silanols in Cubic Mesoporous Organosilicas Hui-Hsu Gavin Tsai, Guang-Liang Jheng and Hsien-Ming Kao pp 11566–11567 DOI: 10.1021/ja802051a Supporting Info

An All-Solid-State Dye-Sensitized Solar Cell-Based Poly(N-alkyl-4-vinyl-pyridine iodide) Electrolyte with Efficiency of 5.64% Jihuai Wu, Sanchun Hao, Zhang Lan, Jianming Lin, Miaoliang Huang, Yunfang Huang, Pingjiang Li, Shu Yin and Tsugio Sato pp 11568–11569 DOI: 10.1021/ja802158q

Synthesis and Structure of Duplex DNA Containing the Genotoxic Nucleobase Lesion N7-Methylguanine Seongmin Lee, Brian R. Bowman, Yoshihito Ueno, Shuyu Wang and Gregory L. Verdine pp 11570–11571 DOI: 10.1021/ja8025328 Supporting Info

Reversibly Permeable Nanomembranes of Polymeric Microcapsules Andre G. Skirtach, Peter Karageorgiev, Matthieu F. Bdard, Gleb. B. Sukhorukov and Helmuth Mhwald pp 11572–11573 DOI: 10.1021/ja8027636 Supporting Info

Electron Capture Dissociation of Electrosprayed Protein Ions for Spatially Resolved Hydrogen Exchange Measurements Jingxi Pan, Jun Han, Christoph H. Borchers and Lars Konermann pp 11574–11575 DOI: 10.1021/ja802871c Supporting Info

Direct In-Gel Fluorescence Detection and Cellular Imaging of O-GlcNAc-Modified Proteins Peter M. Clark, Jessica F. Dweck, Daniel E. Mason, Courtenay R. Hart, Suzanne B. Buck, Eric C. Peters, Brian J. Agnew and Linda C. Hsieh-Wilson pp 11576–11577 DOI: 10.1021/ja8030467 Supporting Info

Dissecting Entropic Coiling and Poor Solvent Effects in Protein Collapse Frauke Grter, Pascal Heider, Ronen Zangi and B. J. Berne pp 11578–11579 DOI: 10.1021/ja802341q Supporting Info

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials Sang Soo Han, Hiroyasu Furukawa, Omar M. Yaghi and William A. Goddard, pp 11580–11581 DOI: 10.1021/ja803247y Supporting Info

Specific Ion Binding to Nonpolar Surface Patches of Proteins Mikael Lund, Lubo Vrbka and Pavel Jungwirth pp 11582–11583 DOI: 10.1021/ja803274p

Nanoscale Coordination Polymers for Platinum-Based Anticancer Drug Delivery William J. Rieter, Kimberly M. Pott, Kathryn M. L. Taylor and Wenbin Lin pp 11584–11585 DOI: 10.1021/ja803383k Supporting Info

Slow Cation Transfer Follows Sensitizer Regeneration at Anatase TiO2 Interfaces Aaron Staniszewski, Shane Ardo, Yali Sun, Felix N. Castellano and Gerald J. Meyer pp 11586–11587 DOI: 10.1021/ja803668z Supporting Info

One-pot Synthesis of Highly Luminescent InP/ZnS Nanocrystals without Precursor Injection Liang Li and Peter Reiss pp 11588–11589 DOI: 10.1021/ja803687e Supporting Info

PCR-like Cascade Reactions in the Context of an Allosteric Enzyme Mimic Hyo Jae Yoon and Chad A. Mirkin pp 11590–11591 DOI: 10.1021/ja804076q Supporting Info

In Situ Quantitative Measurement of Concentration Profiles in a Microreactor with Submicron Resolution Using Multiplex CARS Microscopy Dawn Schafer, Jeff A. Squier, Jan van Maarseveen, Daniel Bonn, Mischa Bonn and Michiel Mller pp 11592–11593 DOI: 10.1021/ja804158n Supporting Info

Amphiphilic Janus Gold Nanoparticles via Combining “Solid-State Grafting-to” and “Grafting-from” Methods Bingbing Wang, Bing Li, Bin Zhao and Christopher Y. Li pp 11594–11595 DOI: 10.1021/ja804192e Supporting Info

Arsenic(II) Sulfide Quantum Dots Prepared by a Wet Process from its Bulk Junzhong Wang, Ming Lin, Tianyu Zhang, Yongli Yan, Paul C. Ho, Qing-Hua Xu and Kian Ping Loh pp 11596–11597 DOI: 10.1021/ja804436w Supporting Info

Stereospecificity of Ketoreductase Domains 1 and 2 of the Tylactone Modular Polyketide Synthase Roselyne Castonguay, Chiara R. Valenzano, Alice Y. Chen, Adrian Keatinge-Clay, Chaitan Khosla and David E. Cane pp 11598–11599 DOI: 10.1021/ja804453p Supporting Info

Lewis Acid-Catalyzed Intermolecular [4 + 2] Cycloaddition of 3-Alkoxycyclobutanones to Aldehydes and Ketones Jun-ichi Matsuo, Shun Sasaki, Hiroyuki Tanaka and Hiroyuki Ishibashi pp 11600–11601 DOI: 10.1021/ja8045684 Supporting Info

Water-Soluble Ag Nanoclusters Exhibit Strong Two-Photon-Induced Fluorescence Sandeep A. Patel, Chris I. Richards, Jung-Cheng Hsiang and Robert M. Dickson pp 11602–11603 DOI: 10.1021/ja804710r Supporting Info

Fast and Highly Regioselective Allylation of Indole and Pyrrole Compounds by Allyl Alcohols Using Ru-Sulfonate Catalysts Alexey B. Zaitsev, Stefan Gruber, Pascal A. Plss, Paul. S. Pregosin, Luis F. Veiros and Michael Wrle pp 11604–11605 DOI: 10.1021/ja804379k Supporting Info

High Yield Synthesis of Bracelet-like Hydrophilic Ni−Co Magnetic Alloy Flux-Closure Nanorings Ming-Jun Hu, Yang Lu, Sen Zhang, Shi-Rui Guo, Bin Lin, Meng Zhang and Shu-Hong Yu pp 11606–11607 DOI: 10.1021/ja804467g Supporting Info

Methane Storage in Dry Water Gas Hydrates Weixing Wang, Christopher L. Bray, Dave J. Adams and Andrew I. Cooper pp 11608–11609 DOI: 10.1021/ja8048173 Supporting Info

Reversible Heterolysis of H2 Mediated by an M−S(Thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase Yasuhiro Ohki, Mayumi Sakamoto and Kazuyuki Tatsumi pp 11610–11611 DOI: 10.1021/ja804848w Supporting Info

Aromatic Diosmatricyclic Nitrogen-Containing Compounds Miguel A. Esteruelas, Ana B. Masamunt, Montserrat Olivn, Enrique Oate and Marta Valencia pp 11612–11613 DOI: 10.1021/ja8048892 Supporting Info

Polyunsaturated Fatty-Acid-Like Trans-Enoyl Reductases Utilized in Polyketide Biosynthesis Stefanie B. Bumpus, Nathan A. Magarvey, Neil L. Kelleher, Christopher T. Walsh and Christopher T. Calderone pp 11614–11616 DOI: 10.1021/ja8040042 Supporting Info

Ribosyl Geometry in the Transition State of Streptococcus pneumoniae Methylthioadenosine Nucleosidase from the 3′-2H Kinetic Isotope Effect Minkui Luo and Vern L. Schramm pp 11617–11619 DOI: 10.1021/ja804578m Supporting Info

Alkylated Trimethylene-Bridged Bis(p-Phenylenediamines) Stephen F. Nelsen, Gaoquan Li, Kevin P. Schultz, Hieu Q. Tran and Ilia A. Guzei, Dennis H. Evans pp 11620–11622 DOI: 10.1021/ja802292g Supporting Info

Morphology Controlled Self-Assembled Nanostructures of Sandwich Mixed (Phthalocyaninato)(Porphyrinato) Europium Triple-Deckers. Effect of Hydrogen Bonding on Tuning the Intermolecular Interaction Guifen Lu, Yanli Chen, Yuexing Zhang, Meng Bao, Yongzhong Bian, Xiyou Li and Jianzhuang Jiang pp 11623–11630 DOI: 10.1021/ja802493v Supporting Info

Bis(imino)pyridine Iron Alkyls Containing β-Hydrogens: Synthesis, Evaluation of Kinetic Stability, and Decomposition Pathways Involving Chelate Participation Ryan J. Trovitch, Emil Lobkovsky and Paul J. Chirik pp 11631–11640 DOI: 10.1021/ja803296f Supporting Info

Mixed-Ligand Molecular Paneling: Dodecanuclear Cuboctahedral Coordination Cages Based on a Combination of Edge-Bridging and Face-Capping Ligands Nawal K. Al-Rasbi, Ian S. Tidmarsh, Stephen P. Argent, Harry Adams, Lindsay P. Harding and Michael D. Ward pp 11641–11649 DOI: 10.1021/ja803847w Supporting Info

Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra Hiroyasu Furukawa, Jaheon Kim, Nathan W. Ockwig, Michael O’Keeffe and Omar M. Yaghi pp 11650–11661 DOI: 10.1021/ja803783c Supporting Info

Janus-Type Dendrimer-like Poly(ethylene oxide)s Xiaoshuang Feng, Daniel Taton, Emmanuel Ibarboure, Elliot L. Chaikof and Yves Gnanou pp 11662–11676 DOI: 10.1021/ja7103119

Ibuprofen Induces an Allosteric Conformational Transition in the Heme Complex of Human Serum Albumin with Significant Effects on Heme Ligation Francesco P. Nicoletti, Barry D. Howes, Maria Fittipaldi, Gabriella Fanali, Mauro Fasano, Paolo Ascenzi and Giulietta Smulevich pp 11677–11688 DOI: 10.1021/ja800966t Supporting Info

The Mechanism Responsible for Extraordinary Cs Ion Selectivity in Crystalline Silicotitanate Aaron J. Celestian, James D. Kubicki, Jonathon Hanson, Abraham Clearfield and John B. Parise pp 11689–11694 DOI: 10.1021/ja801134a Supporting Info

Time-Resolved Fluorescence Spectroscopy Reveals Functional Differences of Cationic Polymer−DNA Complexes Elina Vuorimaa, Arto Urtti, Raimo Seppnen, Helge Lemmetyinen and Marjo Yliperttula pp 11695–11700 DOI: 10.1021/ja801503h

Interconversion of the cis-5R,6S- and trans-5R,6R-Thymine Glycol Lesions in Duplex DNA Kyle L. Brown, Travis Adams, Vijay P. Jasti, Ashis K. Basu and Michael P. Stone pp 11701–11710 DOI: 10.1021/ja8016544 Supporting Info

Stabilizing Bicontinuous Nanophase Segregation in πCP−C60 Donor−Acceptor Blends Zhongyuan Zhou, Xiwen Chen and Steven Holdcroft pp 11711–11718 DOI: 10.1021/ja802021z Supporting Info

Crystal Structures of n-BuLi Adducts with (R,R)-TMCDA and the Consequences for the Deprotonation of Benzene Carsten Strohmann and Viktoria H. Gessner pp 11719–11725 DOI: 10.1021/ja8017187 Supporting Info

Characterization of a Chiral Enolate Aggregate and Observation of 6Li−1H Scalar Coupling Deyu Li, Chengzao Sun and Paul G. Williard pp 11726–11736 DOI: 10.1021/ja802114j Supporting Info

Antimony Oxide Hydroxide Ethanedisulfonate: a Cationic Layered Metal Oxide for Lewis Acid Applications Claudia H. Swanson, Harris A. Shaikh, David L. Rogow, Allen G. Oliver, Charles F. Campana and Scott R. J. Oliver pp 11737–11741 DOI: 10.1021/ja802420h Supporting Info

Ab Initio Study of the Mechanism for Photoinduced Yl-Oxygen Exchange in Uranyl(VI) in Acidic Aqueous Solution Florent Ral, Valrie Vallet, Ulf Wahlgren and Ingmar Grenthe pp 11742–11751 DOI: 10.1021/ja8026407 Supporting Info

PNA versus DNA: Effects of Structural Fluctuations on Electronic Structure and Hole-Transport Mechanisms Elizabeth Hatcher, Alexander Balaeff, Shahar Keinan, Ravindra Venkatramani and David N. Beratan pp 11752–11761 DOI: 10.1021/ja802541e Supporting Info

Optimization of a Biomimetic Transamination Reaction Rebecca A. Scheck, Michel T. Dedeo, Anthony T. Iavarone and Matthew B. Francis pp 11762–11770 DOI: 10.1021/ja802495w Supporting Info

Enhancement of the Reactivity of Photochemically Generated Enediynes via Keto−Enol Tautomerization Grigori Karpov, Alexander Kuzmin and Vladimir V. Popik pp 11771–11777 DOI: 10.1021/ja802688c Supporting Info

Chiral Kagom Lattice from Simple Ditopic Molecular Bricks U. Schlickum, R. Decker, F. Klappenberger, G. Zoppellaro, S. Klyatskaya, W. Auwrter, S. Neppl, K. Kern, H. Brune, M. Ruben and J. V. Barth pp 11778–11782 DOI: 10.1021/ja8028119 Supporting Info

DNA-Based Asymmetric Catalysis: Sequence-Dependent Rate Acceleration and Enantioselectivity Arnold J. Boersma, Jaap E. Klijn, Ben L. Feringa and Gerard Roelfes pp 11783–11790 DOI: 10.1021/ja803170m Supporting Info

Self-Assembly of Discotic Mesogens in Solution and in Liquid Crystalline Phases: Effects of Substituent Position and Hydrogen Bonding Christine Lavigueur, E. Johan Foster and Vance E. Williams pp 11791–11800 DOI: 10.1021/ja803406k Supporting Info

Site-Specific Interactions of Cu(II) with α and β-Synuclein: Bridging the Molecular Gap between Metal Binding and Aggregation Andrs Binolfi, Gonzalo R. Lamberto, Rosario Duran, Liliana Quintanar, Carlos W. Bertoncini, Jose M. Souza, Carlos Cerveansky, Markus Zweckstetter, Christian Griesinger and Claudio O. Fernndez pp 11801–11812 DOI: 10.1021/ja803494v Supporting Info

Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis Yun Liu, Jae-Hyuk Her, Anne Dailly, Anibal J. Ramirez-Cuesta, Dan A. Neumann and Craig M. Brown pp 11813–11818 DOI: 10.1021/ja803669w Supporting Info

Deracemization of a Dynamic Combinatorial Library Induced by (−)-Cytidine and (−)-2-Thiocytidine Mee-Kyung Chung, Christine M. Hebling, James W. Jorgenson, Kay Severin, Stephen J. Lee and Michel R. Gagn pp 11819–11827 DOI: 10.1021/ja803658n Supporting Info

Multifunctional Yolk−Shell Nanoparticles: A Potential MRI Contrast and Anticancer Agent Jinhao Gao, Gaolin Liang, Jerry S. Cheung, Yue Pan, Yi Kuang, Fan Zhao, Bei Zhang, Xixiang Zhang, Ed X. Wu and Bing Xu pp 11828–11833 DOI: 10.1021/ja803920b Supporting Info

Total Synthesis of Cytotoxic Macrolide Amphidinolide B1 and the Proposed Structure of Amphidinolide B2 Liang Lu, Wei Zhang and Rich G. Carter p 11834 DOI: 10.1021/ja8049518

Issue 36

Photoswitched DNA-Binding of a Photochromic Spiropyran Johanna Andersson, Shiming Li, Per Lincoln and Joakim Andrasson pp 11836–11837 DOI: 10.1021/ja801968f Supporting Info

A Role for Confined Water in Chaperonin Function Jeremy L. England, Del Lucent and Vijay S. Pande pp 11838–11839 DOI: 10.1021/ja802248m Supporting Info

Low-Temperature Single-Wall Carbon Nanotubes Synthesis: Feedstock Decomposition Limited Growth Elena Mora, John M. Pigos, Feng Ding, Boris I. Yakobson and Avetik R. Harutyunyan pp 11840–11841 DOI: 10.1021/ja8035724

Iridium Metal Complexes as an Unambiguous Probe of Intramolecular Vibrational Redistribution Gordon J. Hedley, Arvydas Ruseckas, Zehua Liu, Shih-Chun Lo, Paul L. Burn and Ifor D. W. Samuel pp 11842–11843 DOI: 10.1021/ja8036383

A Distorted Tetrahedral Metal Oxide Cluster inside an Icosahedral Carbon Cage. Synthesis, Isolation, and Structural Characterization of Sc4(μ3-O)2@Ih-C80 Steven Stevenson, Mary A. Mackey, Melissa A. Stuart, J. Paige Phillips, Michael L. Easterling, Christopher J. Chancellor, Marilyn M. Olmstead and Alan L. Balch pp 11844–11845 DOI: 10.1021/ja803679u Supporting Info

SERRS-Based Enzymatic Probes for the Detection of Protease Activity Andrew Ingram, Louise Byers, Karen Faulds, Barry D. Moore and Duncan Graham pp 11846–11847 DOI: 10.1021/ja803655h Supporting Info

Photoinduced High-Quality Ultrathin SiO2 Film from Hybrid Nanosheet at Room Temperature Yeji Kim, Feng Zhao, Masaya Mitsuishi, Akira Watanabe and Tokuji Miyashita pp 11848–11849 DOI: 10.1021/ja803852w Supporting Info

Reaction of Isonitriles with Carboxylic Acids in a Cavitand: Observation of Elusive Isoimide Intermediates Per Restorp and Julius Rebek, pp 11850–11851 DOI: 10.1021/ja803854r Supporting Info

Ligand Controlled Highly Regio- and Enantioselective Synthesis of α-Acyloxyketones by Palladium-Catalyzed Allylic Alkylation of 1,2-Enediol Carbonates Barry M. Trost, Jiayi Xu and Thomas Schmidt pp 11852–11853 DOI: 10.1021/ja8038954 Supporting Info

Chemical Denaturants Inhibit the Onset of Dewetting Jeremy L. England, Vijay S. Pande and Gilad Haran pp 11854–11855 DOI: 10.1021/ja803972g Supporting Info

A Soret Marker Band for Four-Coordinate Ferric Heme Proteins from Absorption Spectra of Isolated Fe(III)-Heme+ and Fe(III)-Heme+(His) Ions in Vacuo Morten Køcks Lykkegaard, Anneli Ehlerding, Preben Hvelplund, Umesh Kadhane, Maj-Britt Suhr Kirketerp, Steen Brøndsted Nielsen, Subhasis Panja, Jean Ann Wyer and Henning Zettergren pp 11856–11857 DOI: 10.1021/ja803460c

Controlled Assembly of Eccentrically Encapsulated Gold Nanoparticles Tao Chen, Miaoxin Yang, Xinjiao Wang, Li Huey Tan and Hongyu Chen pp 11858–11859 DOI: 10.1021/ja8040288 Supporting Info

Identification of the Structures of Superlong Oriented Single-Walled Carbon Nanotube Arrays by Electrodeposition of Metal and Raman Spectroscopy Shaoming Huang, Yong Qian, Jiangying Chen, Qiran Cai, Li Wan, Shun Wang and Wenbing Hu pp 11860–11861 DOI: 10.1021/ja803682j Supporting Info

“Inject-Mix-React-Separate-and-Quantitate” (IMReSQ) Method for Screening Enzyme Inhibitors Edmund Wong, Victor Okhonin, Maxim V. Berezovski, Tomoyoshi Nozaki, Herbert Waldmann, Kirill Alexandrov and Sergey N. Krylov pp 11862–11863 DOI: 10.1021/ja804544x Supporting Info

13C-Sialic Acid Labeling of Glycans on Glycoproteins Using ST6Gal-I Megan A. Macnaughtan, Fang Tian, Shan Liu, Lu Meng, Seongha Park, Parastoo Azadi, Kelley W. Moremen and James H. Prestegard pp 11864–11865 DOI: 10.1021/ja804614w Supporting Info

Low-Temperature Solution Synthesis of the Non-Equilibrium Ordered Intermetallic Compounds Au3Fe, Au3Co, and Au3Ni as Nanocrystals Yolanda Vasquez, Zhiping Luo and Raymond E. Schaak pp 11866–11867 DOI: 10.1021/ja804858u Supporting Info

Indolocarbazole-Based Foldamers Capable of Binding Halides in Water Jae-min Suk and Kyu-Sung Jeong pp 11868–11869 DOI: 10.1021/ja804845m Supporting Info

Context-Dependent Photodimerization in Isolated Thymine−Thymine Steps in DNA Mahesh Hariharan and Frederick D. Lewis pp 11870–11871 DOI: 10.1021/ja804950j Supporting Info

Reticular Synthesis of Covalent Organic Borosilicate Frameworks Joseph R. Hunt, Christian J. Doonan, James D. LeVangie, Adrien P. Ct and Omar M. Yaghi pp 11872–11873 DOI: 10.1021/ja805064f Supporting Info

Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids Alexander J. M. Miller, Jay A. Labinger and John E. Bercaw pp 11874–11875 DOI: 10.1021/ja805108z Supporting Info

Nitrosonium Salts, NO+X− (X = B(3,5-diCF3Ph)4− or PW12O403−), as Electrophilic Catalysts for Alkene Activation in Arene Alkylation and Dimerization Reactions Alexander M. Khenkin and Ronny Neumann pp 11876–11877 DOI: 10.1021/ja8051377 Supporting Info

Lytic Transglycosylase MltB of Escherichia coli and Its Role in Recycling of Peptidoglycan Strands of Bacterial Cell Wall Maxim Suvorov, Mijoon Lee, Dusan Hesek, Bill Boggess and Shahriar Mobashery pp 11878–11879 DOI: 10.1021/ja805482b Supporting Info

Entrapment of an Organometallic Complex within a Metal: A Concept for Heterogeneous Catalysis Itzik Yosef, Raed Abu-Reziq and David Avnir pp 11880–11882 DOI: 10.1021/ja804112z Supporting Info

Direct Observation of the Gas-Phase Criegee Intermediate (CH2OO) Craig A. Taatjes, Giovanni Meloni, Talitha M. Selby, Adam J. Trevitt, David L. Osborn, Carl J. Percival and Dudley E. Shallcross pp 11883–11885 DOI: 10.1021/ja804165q Supporting Info

Supramolecule-to-Supramolecule Transformations of Coordination-Driven Self-Assembled Polygons Liang Zhao, Brian H. Northrop and Peter J. Stang pp 11886–11888 DOI: 10.1021/ja805770w Supporting Info

Helix-Sense-Controlled Synthesis of Optically Active Poly(methyl methacrylate) Stereocomplexes Takehiro Kawauchi, Atsushi Kitaura, Jiro Kumaki, Hiroshi Kusanagi and Eiji Yashima pp 11889–11891 DOI: 10.1021/ja8048805 Supporting Info

13C-Labeled N-Acetyl-neuraminic Acid in Aqueous Solution: Detection and Quantification of Acyclic Keto, Keto Hydrate, and Enol Forms by 13C NMR Spectroscopy Thomas Klepach, Ian Carmichael and Anthony S. Serianni pp 11892–11900 DOI: 10.1021/ja077565g Supporting Info

Structure/Reactivity Studies on an α-Lithiated Benzylsilane: Chemical Interpretation of Experimental Charge Density Holger Ott, Christian Dschlein, Dirk Leusser, Daniel Schildbach, Timo Seibel, Dietmar Stalke and Carsten Strohmann pp 11901–11911 DOI: 10.1021/ja711104q Supporting Info

Electron and Hole Transport To Trap Groups at the Ends of Conjugated Polyfluorenes Sadayuki Asaoka, Norihiko Takeda, Tomokazu Iyoda, Andrew R. Cook and John R. Miller pp 11912–11920 DOI: 10.1021/ja800426z Supporting Info

Using α-Helical Coiled-Coils to Design Nanostructured Metalloporphyrin Arrays Karen A. McAllister, Hongling Zou, Frank V. Cochran, Gretchen M. Bender, Alessandro Senes, H. Christopher Fry, Vikas Nanda, Patricia A. Keenan, James D. Lear, Jeffery G. Saven, Michael J. Therien, J. Kent Blasie and William F. DeGrado pp 11921–11927 DOI: 10.1021/ja800697g Supporting Info

Activation of CS2 and CS by ML3 Complexes Alireza Ariafard, Nigel J. Brookes, Robert Stranger and Brian F. Yates pp 11928–11938 DOI: 10.1021/ja800946e Supporting Info

Hydroxylase Activity of Met471Cys Tyramine β-Monooxygenase Corinna R. Hess, Zinian Wu, Adora Ng, Erin E. Gray, Michele A. McGuirl and Judith P. Klinman pp 11939–11944 DOI: 10.1021/ja800408h

Sugar-Assisted Glycopeptide Ligation with Complex Oligosaccharides: Scope and Limitations Clay S. Bennett, Stephen M. Dean, Richard J. Payne, Simon Ficht, Ashraf Brik and Chi-Huey Wong pp 11945–11952 DOI: 10.1021/ja8010513 Supporting Info

Monolayer Control of Discotic Liquid Crystal by Electromigration of Dewetted Layers in Thin Film Devices Annalisa Cal, Pablo Stoliar, Massimiliano Cavallini, Sergey Sergeyev, Yves H. Geerts and Fabio Biscarini pp 11953–11958 DOI: 10.1021/ja801337v Supporting Info

Transition-Metal Nanocluster Size vs Formation Time and the Catalytically Effective Nucleus Number: A Mechanism-Based Treatment Murielle A. Watzky, Eric E. Finney and Richard G. Finke pp 11959–11969 DOI: 10.1021/ja8017412 Supporting Info

An Atom-Economic and Selective Ruthenium-Catalyzed Redox Isomerization of Propargylic Alcohols. An Efficient Strategy for the Synthesis of Leukotrienes Barry M. Trost and Robert C. Livingston pp 11970–11978 DOI: 10.1021/ja804105m Supporting Info

Direct Observations of the Metal−Ligand Bifunctional Addition Step in an Enantioselective Ketone Hydrogenation Robin J. Hamilton and Steven H. Bergens pp 11979–11987 DOI: 10.1021/ja8034812 Supporting Info

Selective Methylative Homologation: An Alternate Route to Alkane Upgrading John E. Bercaw, Nilay Hazari, Jay A. Labinger, Valerie J. Scott and Glenn J. Sunley pp 11988–11995 DOI: 10.1021/ja803029s Supporting Info

Atomic Layer Deposition of Hafnium Oxide from Hafnium Chloride and Water Atashi B. Mukhopadhyay, Charles B. Musgrave and Javier Fdez. Sanz pp 11996–12006 DOI: 10.1021/ja801616u

Changes in Dynamics of SRE-RNA on Binding to the VTS1p-SAM Domain Studied by 13C NMR Relaxation Florian C. Oberstrass, Frdric H.-T. Allain and Sapna Ravindranathan pp 12007–12020 DOI: 10.1021/ja8023115 Supporting Info

Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site Matthew T. Olsen, Maurizio Bruschi, Luca De Gioia, Thomas B. Rauchfuss and Scott R. Wilson pp 12021–12030 DOI: 10.1021/ja802268p Supporting Info

Organocatalytic Asymmetric Synthesis of α,α-Disubstituted α-Amino Acids and Derivatives Silvia Cabrera, Efraim Reyes, Jos Alemn, Andrea Milelli, Sara Kobbelgaard and Karl Anker Jørgensen pp 12031–12037 DOI: 10.1021/ja804567h Supporting Info

Targeting Metastable Coiled-Coil Domains by Computational Design Patrick Barth, Allyn Schoeffler and Tom Alber pp 12038–12044 DOI: 10.1021/ja802447e

Toward [18F]-Labeled Aryltrifluoroborate Radiotracers: In Vivo Positron Emission Tomography Imaging of Stable Aryltrifluoroborate Clearance in Mice Richard Ting, Curtis Harwig, Ulrich auf dem Keller, Siobhan McCormick, Pamela Austin, Christopher M. Overall, Michael J. Adam, Thomas J. Ruth and David M. Perrin pp 12045–12055 DOI: 10.1021/ja802734t Supporting Info

Au ↔ N Synergy and N-Doping of Metal Oxide-Based Photocatalysts Jess Graciani, Akira Nambu, Jaime Evans, Jos A. Rodriguez and Javier Fdez. Sanz pp 12056–12063 DOI: 10.1021/ja802861u

Bistability in Fc-PTM Crystals: The Role of Intermolecular Electrostatic Interactions Gabriele D’Avino, Luca Grisanti, Judith Guasch, Imma Ratera, Jaume Veciana and Anna Painelli pp 12064–12072 DOI: 10.1021/ja803049g Supporting Info

Automated NMR Assignment of Protein Side Chain Resonances Using Automated Projection Spectroscopy (APSY) Sebastian Hiller, Rosmarie Joss and Gerhard Wider pp 12073–12079 DOI: 10.1021/ja803161d Supporting Info

Charge-Density-Wave to Mott−Hubbard Phase Transition in Quasi-One-Dimensional Bromo-Bridged Pd Compounds Shinya Takaishi, Mitsuhito Takamura, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Muneaki Iwata, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Hiroyuki Nishikawa, Hiroki Oshio, Kenichi Kato and Masaki Takata pp 12080–12084 DOI: 10.1021/ja8032026 Supporting Info

Evidence for Nonstatistical Dynamics in the Wolff Rearrangement of a Carbene Aviva E. Litovitz, Ivan Keresztes and Barry K. Carpenter pp 12085–12094 DOI: 10.1021/ja803230a Supporting Info

Turn-On Fluorescence Sensing of Nucleoside Polyphosphates Using a Xanthene-Based Zn(II) Complex Chemosensor Akio Ojida, Ippei Takashima, Takahiro Kohira, Hiroshi Nonaka and Itaru Hamachi pp 12095–12101 DOI: 10.1021/ja803262w Supporting Info

Isolation, Structure, and Antibacterial Activity of Philipimycin, A Thiazolyl Peptide Discovered from Actinoplanes philippinensis MA7347 Chaowei Zhang, James Occi, Prakash Masurekar, John F. Barrett, Deborah L. Zink, Scott Smith, Russell Onishi, Sookhee Ha, Oscar Salazar, Olga Genilloud, Angela Basilio, Francisca Vicente, Charles Gill, Emily J. Hickey, Karen Dorso, Mary Motyl and Sheo B. Singh pp 12102–12110 DOI: 10.1021/ja803183u Supporting Info

Strong, Size-Selective, and Electronically Tunable C−H···Halide Binding with Steric Control over Aggregation from Synthetically Modular, Shape-Persistent [34]Triazolophanes Yongjun Li and Amar H. Flood pp 12111–12122 DOI: 10.1021/ja803341y Supporting Info

Oriented Organic Islands and One-Dimensional Chains on a Au(111) Surface Fabricated by Electrodeposition: An STM Study Rui Wen, Ge-Bo Pan and Li-Jun Wan pp 12123–12127 DOI: 10.1021/ja803588j Supporting Info

The Nature of the Hydrated Proton H(aq)+ in Organic Solvents Evgenii S. Stoyanov, Irina V. Stoyanova, Fook S. Tham and Christopher A. Reed pp 12128–12138 DOI: 10.1021/ja803535s Supporting Info

Polyanionic Gallium Hydrides from AlB2-Type Precursors AeGaE (Ae = Ca, Sr, Ba; E = Si, Ge, Sn) Michael J. Evans, Gregory P. Holland, Francisco J. Garcia-Garcia and Ulrich Hussermann pp 12139–12147 DOI: 10.1021/ja803664y Supporting Info

Most Efficient Cocaine Hydrolase Designed by Virtual Screening of Transition States Fang Zheng, Wenchao Yang, Mei-Chuan Ko, Junjun Liu, Hoon Cho, Daquan Gao, Min Tong, Hsin-Hsiung Tai, James H. Woods and Chang-Guo Zhan pp 12148–12155 DOI: 10.1021/ja803646t Supporting Info

Nanoparticle-Mediated Intervalence Transfer Wei Chen, Shaowei Chen, Feizhi Ding, Haobin Wang, Lauren E. Brown and Joseph P. Konopelski pp 12156–12162 DOI: 10.1021/ja803887b Supporting Info

The Benzil−Cyanide Reaction and Its Application to the Development of a Selective Cyanide Anion Indicator Dong-Gyu Cho, Jong Hoon Kim and Jonathan L. Sessler pp 12163–12167 DOI: 10.1021/ja8039025 Supporting Info

Amino Acid Selective Cross-Saturation Method for Identification of Proximal Residue Pairs in a Protein−Protein Complex Shunsuke Igarashi, Masanori Osawa, Koh Takeuchi, Shin-ichiro Ozawa and Ichio Shimada pp 12168–12176 DOI: 10.1021/ja804062t

Diastereoselective Ni-Catalyzed Negishi Cross-Coupling Approach to Saturated, Fully Oxygenated C-Alkyl and C-Aryl Glycosides Hegui Gong and Michel R. Gagn pp 12177–12183 DOI: 10.1021/ja8041564 Supporting Info

Stereospecific Synthesis of C2 Symmetric Diamines from the Mother Diamine by Resonance-Assisted Hydrogen-Bond Directed Diaza-Cope Rearrangement Hyunwoo Kim, Yen Nguyen, Cindy Pai-Hui Yen, Leonid Chagal, Alan J. Lough, B. Moon Kim and Jik Chin pp 12184–12191 DOI: 10.1021/ja803951u Supporting Info

“Three-Dimensional Hybridization” with Polyvalent DNA−Gold Nanoparticle Conjugates Sarah J. Hurst, Haley D. Hill and Chad A. Mirkin pp 12192–12200 DOI: 10.1021/ja804266j Supporting Info

Issue 37

Molecular Design of Thin Film Optoelectronic Materials for Solar Cells Jeffrey S. Moore pp 12201–12203 DOI: 10.1021/ja806392t

Structure−Property Relationships in Redox-Gated Single Molecule Junctions − A Comparison of Pyrrolo-Tetrathiafulvalene and Viologen Redox Groups Edmund Leary, Simon J. Higgins, Harm van Zalinge, Wolfgang Haiss, Richard J. Nichols, Sune Nygaard, Jan Oskar Jeppesen and Jens Ulstrup pp 12204–12205 DOI: 10.1021/ja8014605 Supporting Info

Combinatorial Discovery of Full-Color-Tunable Emissive Fluorescent Probes Using a Single Core Skeleton, 1,2-Dihydropyrrolo[3,4-β]indolizin-3-one Eunha Kim, Minseob Koh, Jihoon Ryu and Seung Bum Park pp 12206–12207 DOI: 10.1021/ja8020268 Supporting Info

Thermodynamic and Structural Basis of Phosphorylation-Induced Disorder-to-Order Transition in the Regulatory Light Chain of Smooth Muscle Myosin L. Michel Espinoza-Fonseca, David Kast and David D. Thomas pp 12208–12209 DOI: 10.1021/ja803143g Supporting Info

Photochemistry of Adsorbed Nitrate Jennifer Schuttlefield, Gayan Rubasinghege, Mohamed El-Maazawi, Jason Bone and Vicki H. Grassian pp 12210–12211 DOI: 10.1021/ja802342m Supporting Info

Site-Specific Radical Directed Dissociation of Peptides at Phosphorylated Residues Jolene K. Diedrich and Ryan R. Julian pp 12212–12213 DOI: 10.1021/ja8023719 Supporting Info

Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides: p-Orientation in the Polyarylthiolation of Polyfluorobenzenes Mieko Arisawa, Takaaki Suzuki, Tomofumi Ishikawa and Masahiko Yamaguchi pp 12214–12215 DOI: 10.1021/ja8049996 Supporting Info

Catalytic Asymmetric Addition of Alcohols to Imines: Enantioselective Preparation of Chiral N,O-Aminals Guilong Li, Frank R. Fronczek and Jon C. Antilla pp 12216–12217 DOI: 10.1021/ja8033334 Supporting Info

Two-Vial, LC−MS Identification of Ephedrine Receptors from a Solution-Phase Dynamic Combinatorial Library of over 9000 Components R. Frederick Ludlow and Sijbren Otto pp 12218–12219 DOI: 10.1021/ja803317k Supporting Info

Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity Jianrong (Steve) Zhou and John F. Hartwig pp 12220–12221 DOI: 10.1021/ja803523z Supporting Info

Color Kinetic Nanoparticles Baris Kokuoz, Jeffrey R. DiMaio, Courtney J. Kucera, David D. Evanoff, and John Ballato pp 12222–12223 DOI: 10.1021/ja803898y

Hock Cleavage of Cholesterol 5α-Hydroperoxide: An Ozone-Free Pathway to the Cholesterol Ozonolysis Products Identified in Arterial Plaque and Brain Tissue Johan Brinkhorst, Susheel J. Nara and Derek A. Pratt pp 12224–12225 DOI: 10.1021/ja804162d Supporting Info

Time-Resolved Dimerization of a PAS-LOV Protein Measured with Photocoupled Small Angle X-ray Scattering Jessica S. Lamb, Brian D. Zoltowski, Suzette A. Pabit, Brian R. Crane and Lois Pollack pp 12226–12227 DOI: 10.1021/ja804236f Supporting Info

Total Synthesis of Haterumalides NA and NC via a Chromium-Mediated Macrocyclization Jennifer M. Schomaker and Babak Borhan pp 12228–12229 DOI: 10.1021/ja8043695 Supporting Info

Epoxide Hydrolase Lsd19 for Polyether Formation in the Biosynthesis of Lasalocid A: Direct Experimental Evidence on Polyene-Polyepoxide Hypothesis in Polyether Biosynthesis Yoshihiro Shichijo, Akira Migita, Hiroki Oguri, Mami Watanabe, Tetsuo Tokiwano, Kenji Watanabe and Hideaki Oikawa pp 12230–12231 DOI: 10.1021/ja8040543 Supporting Info

Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity J. Brian Hewgley, Shannon S. Stahl and Marisa C. Kozlowski pp 12232–12233 DOI: 10.1021/ja804570b Supporting Info

meso-(4-(N,N-Dialkylamino)phenyl)-Substituted Subporphyrins: Remarkably Perturbed Absorption Spectra and Enhanced Fluorescence by Intramolecular Charge Transfer Interactions Yasuhide Inokuma, Shanmugam Easwaramoorthi, Zin Seok Yoon, Dongho Kim and Atsuhiro Osuka pp 12234–12235 DOI: 10.1021/ja804846v Supporting Info

cis-Δ2,3-Double Bond of Phoslactomycins Is Generated by a Post-PKS Tailoring Enzyme Nadaraj Palaniappan, Mamoun M. Alhamadsheh and Kevin A. Reynolds pp 12236–12237 DOI: 10.1021/ja8044162 Supporting Info

Formation of Secondary Triplet Species after Excitation of Fluoroquinolones in the Presence of Relatively Strong Bases Fernando Lorenzo, Suppiah Navaratnam and Norman S. Allen pp 12238–12239 DOI: 10.1021/ja8044713

New Aldehyde Tag Sequences Identified by Screening Formylglycine Generating Enzymes in Vitro and in Vivo Jason S. Rush and Carolyn R. Bertozzi pp 12240–12241 DOI: 10.1021/ja804530w Supporting Info

Successful Dispersion Polymerization in Supercritical CO2 Using Polyvinylalkylate Hydrocarbon Surfactants Synthesized and Anchored via RAFT Hyunsuk Lee, Elaine Terry, Mengmeng Zong, Nicholas Arrowsmith, Sbastien Perrier, Kristofer J. Thurecht and Steven M. Howdle pp 12242–12243 DOI: 10.1021/ja8046156 Supporting Info

Strong Correlation between SHAPE Chemistry and the Generalized NMR Order Parameter (S2) in RNA Costin M. Gherghe, Zahra Shajani, Kevin A. Wilkinson, Gabriele Varani and Kevin M. Weeks pp 12244–12245 DOI: 10.1021/ja804541s Supporting Info

A Photolabile Ligand for Light-Activated Release of Caged Copper Katie L. Ciesienski, Kathryn L. Haas, Marina G. Dickens, Yohannes T. Tesema and Katherine J. Franz pp 12246–12247 DOI: 10.1021/ja8047442 Supporting Info

Catalytic Enantioselective Aldol Additions of α-Isothiocyanato Imides to Aldehydes Le Li, Eric G. Klauber and Daniel Seidel pp 12248–12249 DOI: 10.1021/ja804838y Supporting Info

Palladium-Catalyzed Hiyama Cross-Couplings of Aryl Arenesulfonates with Arylsilanes Liang Zhang and Jie Wu pp 12250–12251 DOI: 10.1021/ja804672m Supporting Info

Transition from Complete to Partial Wetting within Membrane Compartments Yanhong Li, Reinhard Lipowsky and Rumiana Dimova pp 12252–12253 DOI: 10.1021/ja8048496 Supporting Info

On the Effect of Low-Energy Electron Induced DNA Strand Break in Aqueous Solution: A Theoretical Study Indicating Guanine as a Weak Link in DNA Patric Schyman and Aatto Laaksonen pp 12254–12255 DOI: 10.1021/ja805000g Supporting Info

Alkali Metal Reductions of Organic Molecules: Why Mediated Electron Transfer from Lithium Is Faster than Direct Reduction Neil V. Rees, Ronan Baron, Neil M. Kershaw, Timothy J. Donohoe and Richard G. Compton pp 12256–12257 DOI: 10.1021/ja805086w Supporting Info

Multi-Electron Reduction from Alkyl/Hydride Ligand Combinations in U4+ Complexes William J. Evans, Elizabeth Montalvo, Stosh A. Kozimor and Kevin A. Miller pp 12258–12259 DOI: 10.1021/ja805107v Supporting Info

Mechanistically Inspired Design of FeIII−TAML Peroxide-Activating Catalysts Delia-Laura Popescu, Arani Chanda, Matthew J. Stadler, Sujit Mondal, Jacqui Tehranchi, Alexander D. Ryabov and Terrence J. Collins pp 12260–12261 DOI: 10.1021/ja805099e Supporting Info

Chain-Length Dependent Nematic Ordering of Conjugated Polymers in a Liquid Crystal Solvent Alexei Tcherniak, David Solis, , Saumyakanti Khatua, Andrew A. Tangonan, T. Randall Lee and Stephan Link pp 12262–12263 DOI: 10.1021/ja805017m Supporting Info

Reversible Restructuring of Aqueous Block Copolymer Assemblies through Stimulus-Induced Changes in Amphiphilicity Anand Sundararaman, Tim Stephan and Robert B. Grubbs pp 12264–12265 DOI: 10.1021/ja8052688 Supporting Info

Chain-Terminus Triggered Chiral Memory in an Optically Inactive 310-Helical Peptide Naoki Ousaka, Yoshihito Inai and Reiko Kuroda pp 12266–12267 DOI: 10.1021/ja805647k Supporting Info

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination Yang Peng, Bobby D. Ellis, Xinping Wang and Philip P. Power pp 12268–12269 DOI: 10.1021/ja805358u Supporting Info

1/∞[ZrPSe6−]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts Santanu Banerjee, Christos D. Malliakas, Joon I. Jang, John B. Ketterson and Mercouri G. Kanatzidis pp 12270–12272 DOI: 10.1021/ja804166m Supporting Info

Structure and Properties of Small Molecule−Polymer Blend Semiconductors for Organic Thin Film Transistors Jihoon Kang, Nayool Shin, Do Young Jang, Vivek M. Prabhu and Do Y. Yoon pp 12273–12275 DOI: 10.1021/ja804013n Supporting Info

Nitrosobenzene-Mediated C−C Bond Cleavage Reactions and Spectral Observation of an Oxazetidin-4-one Ring System Joshua N. Payette and Hisashi Yamamoto pp 12276–12278 DOI: 10.1021/ja804325f Supporting Info

Reaction Chemistry and Ligand Exchange at Cadmium−Selenide Nanocrystal Surfaces Jonathan S. Owen, Jungwon Park, Paul-Emile Trudeau and A. Paul Alivisatos pp 12279–12281 DOI: 10.1021/ja804414f Supporting Info

A Latent Oxazoline Electrophile for N−O−C Bond Formation in Pseudomonine Biosynthesis Elizabeth S. Sattely and Christopher T. Walsh pp 12282–12284 DOI: 10.1021/ja804499r Supporting Info

Two-Dimensional Pentacene:3,4,9,10-Perylenetetracarboxylic Dianhydride Supramolecular Chiral Networks on Ag(111) Wei Chen, Hui Li, Han Huang, Yuanxi Fu, Hong Liang Zhang, Jing Ma and Andrew Thye Shen Wee pp 12285–12289 DOI: 10.1021/ja801577z

Large Two-Photon Absorption Cross Sections of Hemiporphyrazines in the Excited State: The Multiphoton Absorption Process of Hemiporphyrazines with Different Central Metals Danilo Dini, Mario J.F. Calvete, Michael Hanack, Vincenzo Amendola and Moreno Meneghetti pp 12290–12298 DOI: 10.1021/ja802678u Supporting Info

Density Functional Theory Study on a Missing Piece in Understanding of Heme Chemistry: The Reaction Mechanism for Indoleamine 2,3-Dioxygenase and Tryptophan 2,3-Dioxygenase Lung Wa Chung, Xin Li, Hiroshi Sugimoto, Yoshitsugu Shiro and Keiji Morokuma pp 12299–12309 DOI: 10.1021/ja803107w Supporting Info

Temperature-Dependent Interconversion of Phosphoramidite−Cu Complexes Detected by Combined Diffusion Studies, 31P NMR, and Low-Temperature NMR Spectroscopy Katrin Schober, Hongxia Zhang and Ruth M. Gschwind pp 12310–12317 DOI: 10.1021/ja8047317 Supporting Info

Using Enantioselective Indicator Displacement Assays To Determine the Enantiomeric Excess of α-Amino Acids Diana Leung, J. Frantz Folmer-Andersen, Vincent M. Lynch and Eric V. Anslyn pp 12318–12327 DOI: 10.1021/ja803806c Supporting Info

Transitioning Enantioselective Indicator Displacement Assays for α-Amino Acids to Protocols Amenable to High-Throughput Screening Diana Leung and Eric V. Anslyn pp 12328–12333 DOI: 10.1021/ja8038079 Supporting Info

Critical Assessment of Nucleic Acid Electrostatics via Experimental and Computational Investigation of an Unfolded State Ensemble Yu Bai, Vincent B. Chu, Jan Lipfert, Vijay S. Pande, Daniel Herschlag and Sebastian Doniach pp 12334–12341 DOI: 10.1021/ja800854u Supporting Info

Early Homogenous Amorphous Precursor Stages of Calcium Carbonate and Subsequent Crystal Growth in Levitated Droplets Stephan E. Wolf, Jork Leiterer, Michael Kappl, Franziska Emmerling and Wolfgang Tremel pp 12342–12347 DOI: 10.1021/ja800984y Supporting Info

Quantitative Microarray Analysis of Intact Glycolipid−CD1d Interaction and Correlation with Cell-Based Cytokine Production Pi-Hui Liang, Masakazu Imamura, Xiangming Li, Douglass Wu, Masakazu Fujio, Richard T. Guy, Bing-Ching Wu, Moriya Tsuji and Chi-Huey Wong pp 12348–12354 DOI: 10.1021/ja8012787 Supporting Info

Total Synthesis of Chlorofusin, Its Seven Chromophore Diastereomers, and Key Partial Structures Ryan C. Clark, Sang Yeul Lee and Dale L. Boger pp 12355–12369 DOI: 10.1021/ja8012819 Supporting Info

Highly Selective Sorption of Small Unsaturated Hydrocarbons by Nonporous Flexible Framework with Silver Ion Sayaka Uchida, Ryosuke Kawamoto, Hanae Tagami, Yoshinao Nakagawa and Noritaka Mizuno pp 12370–12376 DOI: 10.1021/ja801453c Supporting Info

Polarization Energies in Oligoacene Semiconductor Crystals Joseph E. Norton and Jean-Luc Brdas pp 12377–12384 DOI: 10.1021/ja8017797 Supporting Info

Assigning Vibrational Spectra of Ferryl-Oxo Intermediates of Cytochrome c Oxidase by Periodic Orbits and Molecular Dynamics Vangelis Daskalakis, Stavros C. Farantos and Constantinos Varotsis pp 12385–12393 DOI: 10.1021/ja801840y

Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes Timothy A. Jackson, Jan-Uwe Rohde, Mi Sook Seo, Chivukula V. Sastri, Raymond DeHont, Audria Stubna, Takehiro Ohta, Teizo Kitagawa, Eckard Mnck, Wonwoo Nam and Lawrence Que, pp 12394–12407 DOI: 10.1021/ja8022576 Supporting Info

Polypeptide Friction and Adhesion on Hydrophobic and Hydrophilic Surfaces: A Molecular Dynamics Case Study Andreas Serr, Dominik Horinek and Roland R. Netz pp 12408–12413 DOI: 10.1021/ja802234f

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2 (M = Rh, Ir) Ling Li, William W. Brennessel and William D. Jones pp 12414–12419 DOI: 10.1021/ja802415h Supporting Info

Residual Ligand Entropy in the Binding of p-Substituted Benzenesulfonamide Ligands to Bovine Carbonic Anhydrase II Henning Stckmann, Agnieszka Bronowska, Neil R. Syme, Gary S. Thompson, Arnout P. Kalverda, Stuart L. Warriner and Steve W. Homans pp 12420–12426 DOI: 10.1021/ja803755m Supporting Info

Hysteresis in the Physisorption of CO2 and N2 in a Flexible Pillared Layer Nickel Cyanide Jeffrey T. Culp, Milton R. Smith, Edward Bittner and Bradley Bockrath pp 12427–12434 DOI: 10.1021/ja802474b Supporting Info

Structural Studies of Heparan Sulfate Hexasaccharides: New Insights into Iduronate Conformational Behavior Kevin J. Murphy, Neil McLay and David A. Pye pp 12435–12444 DOI: 10.1021/ja802863p

Structure, Magnetism, and Theoretical Study of a Mixed-Valence CoII3CoIII4 Heptanuclear Wheel: Lack of SMM Behavior despite Negative Magnetic Anisotropy Liviu F. Chibotaru, Liviu Ungur, Christophe Aronica, Hani Elmoll, Guillaume Pilet and Dominique Luneau pp 12445–12455 DOI: 10.1021/ja8029416 Supporting Info

Direct Site-Selective Covalent Protein Immobilization Catalyzed by a Phosphopantetheinyl Transferase Lu Shin Wong, Jenny Thirlway and Jason Micklefield pp 12456–12464 DOI: 10.1021/ja8030278 Supporting Info

Lipid−Rhodopsin Hydrophobic Mismatch Alters Rhodopsin Helical Content Olivier Soubias, Shui-Lin Niu, Drake C. Mitchell and Klaus Gawrisch pp 12465–12471 DOI: 10.1021/ja803599x Supporting Info

Synthesis of 1-Oxadecalins from Anisole Promoted by Tungsten Edward C. Lis, , Rebecca J. Salomon, Michal Sabat, William H. Myers and W. Dean Harman pp 12472–12476 DOI: 10.1021/ja803605m Supporting Info

Mesitylboron-Substituted Ladder-Type Pentaphenylenes: Charge-Transfer, Electronic Communication, and Sensing Properties Gang Zhou, Martin Baumgarten and Klaus Mllen pp 12477–12484 DOI: 10.1021/ja803627x Supporting Info

Role of Host Layer Flexibility in DNA Guest Intercalation Revealed by Computer Simulation of Layered Nanomaterials Mary-Ann Thyveetil, Peter V. Coveney, H. Christopher Greenwell and James L. Suter pp 12485–12495 DOI: 10.1021/ja8037068 Supporting Info

The Mechanism of Long-Range Exciton Diffusion in a Nematically Organized Porphyrin Layer Annemarie Huijser, Tom J. Savenije, Stefan C. J. Meskers, Martien J. W. Vermeulen and Laurens D. A. Siebbeles pp 12496–12500 DOI: 10.1021/ja803753y Supporting Info

A Conclusive Mechanism of the Photoinduced Reaction Cascade in Blue Light Using Flavin Photoreceptors Keyarash Sadeghian, Marco Bocola and Martin Schtz pp 12501–12513 DOI: 10.1021/ja803726a Supporting Info

Stereoselective Dichlorination of Allylic Alcohol Derivatives to Access Key Stereochemical Arrays of the Chlorosulfolipids Grant M. Shibuya, Jacob S. Kanady and Christopher D. Vanderwal pp 12514–12518 DOI: 10.1021/ja804167v Supporting Info

Quantum Chemical Study of Lewis Acid Catalyzed Allylboration of Aldehydes Ken Sakata and Hiroshi Fujimoto pp 12519–12526 DOI: 10.1021/ja804168z Supporting Info

SnO2 Quantum Dots and Quantum Wires: Controllable Synthesis, Self-Assembled 2D Architectures, and Gas-Sensing Properties Xiangxing Xu, Jing Zhuang and Xun Wang pp 12527–12535 DOI: 10.1021/ja8040527 Supporting Info

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes Suzanne C. Bart, Christian Anthon, Frank W. Heinemann, Eckhard Bill, Norman M. Edelstein and Karsten Meyer pp 12536–12546 DOI: 10.1021/ja804263w Supporting Info

Book Review of Asymmetric Phase Transfer Catalysis Katharina M. Lippert and Peter R. Schreiner p 12547 DOI: 10.1021/ja805398n

Book Review of Origin of Life: Chemical Approach p 12547 DOI: 10.1021/ja805583q

Book Review of Atom Resolved Surface Reactions: Nanocatalysis Philippe Bhlmann pp 12547–12548 DOI: 10.1021/ja805420f

Book Review of Molecular Modeling of Proteins. Methods in Molecular Biology, 443 Andrzej Kloczkowski and Robert L. Jernigan p 12548 DOI: 10.1021/ja805842d

Book Review of Hazardous Chemicals Desk Reference, 6th ed. p 12549 DOI: 10.1021/ja805584m

Book Review of Electrodeposition from Ionic Liquids Professor Laurie Peter p 12549 DOI: 10.1021/ja8057937

Book Review of Tailor-Made Polymers: Via Immobilization of Alpha-Olefin Polymerization Catalysts Lothar Stahl pp 12549–12550 DOI: 10.1021/ja805981t

Issue 38

Ethylene Decomposition at Undercoordinated Sites on Cu(410) Tatyana Kravchuk, Luca Vattuone, Luke Burkholder, Wilfred T. Tysoe and Mario Rocca pp 12552–12553 DOI: 10.1021/ja802105z Supporting Info

Investigation of Cation-π Interactions in Biological Systems Ronghu Wu and Terry B. McMahon pp 12554–12555 DOI: 10.1021/ja802117s Supporting Info

Single Molecule Charging by Atomic Force Microscopy Chuleekorn Chotsuwan and Silas C. Blackstock pp 12556–12557 DOI: 10.1021/ja802419y Supporting Info

Click Chemistry for High-Density Biofunctionalization of Mesoporous Silica Axel Schlossbauer, David Schaffert, Johann Kecht, Ernst Wagner and Thomas Bein pp 12558–12559 DOI: 10.1021/ja803018w Supporting Info

Junction Probes − Sequence Specific Detection of Nucleic Acids via Template Enhanced Hybridization Processes Shizuka Nakayama, Lei Yan and Herman O. Sintim pp 12560–12561 DOI: 10.1021/ja803146f Supporting Info

N-Trimethylsilyl Amines for Controlled Ring-Opening Polymerization of Amino Acid N-Carboxyanhydrides and Facile End Group Functionalization of Polypeptides Hua Lu and Jianjun Cheng pp 12562–12563 DOI: 10.1021/ja803304x Supporting Info

Fluorescence Imaging of Intracellular Cadmium Using a Dual-Excitation Ratiometric Chemosensor Masayasu Taki, Mika Desaki, Akio Ojida, Shohei Iyoshi, Tasuku Hirayama, Itaru Hamachi and Yukio Yamamoto pp 12564–12565 DOI: 10.1021/ja803429z Supporting Info

Visible-Light Induced Water Detoxification Catalyzed by PtII Dye Sensitized Titania Wei Zhao, Yali Sun and Felix N. Castellano pp 12566–12567 DOI: 10.1021/ja803522v Supporting Info

Native Conformation at Specific Residues in Recombinant Inclusion Body Protein in Whole Cells Determined with Solid-State NMR Spectroscopy Jaime Curtis-Fisk, Ryan M. Spencer and David P. Weliky pp 12568–12569 DOI: 10.1021/ja8039426 Supporting Info

Mitochondria-Targeted Chemotherapeutics: The Rational Design of Gold(I) N-Heterocyclic Carbene Complexes That Are Selectively Toxic to Cancer Cells and Target Protein Selenols in Preference to Thiols James L. Hickey, Rasha A. Ruhayel, Peter J. Barnard, Murray V. Baker, Susan J. Berners-Price and Aleksandra Filipovska pp 12570–12571 DOI: 10.1021/ja804027j Supporting Info

Large Coupled Magnetoresponses in EuNbO2N A. Beln Jorge, Judith Or-Sol, Ana M. Bea, Nandang Mufti, Thomas T. M. Palstra, Jennifer A. Rodgers, J. Paul Attfield and Amparo Fuertes pp 12572–12573 DOI: 10.1021/ja804139g Supporting Info

Fluorescence and Hybridization Properties of Peptide Nucleic Acid Containing a Substituted Phenylpyrrolocytosine Designed to Engage Guanine with an Additional H-Bond Filip Wojciechowski and Robert H. E. Hudson pp 12574–12575 DOI: 10.1021/ja804233g Supporting Info

A Homogeneous System for the Photogeneration of Hydrogen from Water Based on a Platinum(II) Terpyridyl Acetylide Chromophore and a Molecular Cobalt Catalyst Pingwu Du, Kathryn Knowles and Richard Eisenberg pp 12576–12577 DOI: 10.1021/ja804650g Supporting Info

Trans−Cis Isomerization is Responsible for the Red-Shifted Fluorescence in Variants of the Red Fluorescent Protein eqFP611 Karin Nienhaus, Herbert Nar, Ralf Heilker, Jrg Wiedenmann and G. Ulrich Nienhaus pp 12578–12579 DOI: 10.1021/ja8046443 Supporting Info

High Performance Solution-Processed Indium Oxide Thin-Film Transistors Hyun Sung Kim, Paul D. Byrne, Antonio Facchetti and Tobin J. Marks pp 12580–12581 DOI: 10.1021/ja804262z Supporting Info

The Long-Lived Nuclear Singlet State of 15N-Nitrous Oxide in Solution Giuseppe Pileio, Marina Carravetta, Eric Hughes and Malcolm H. Levitt pp 12582–12583 DOI: 10.1021/ja803601d

Comparison of “Polarization Inversion with Spin Exchange at Magic Angle” and “Geometric Analysis of Labeled Alanines” Methods for Transmembrane Helix Alignment Vitaly V. Vostrikov, Christopher V. Grant, Anna E. Daily, Stanley J. Opella and Roger E. Koeppe, pp 12584–12585 DOI: 10.1021/ja803734k Supporting Info

Imidazolium Salts: A Mild Reducing and Antioxidative Reagent Lan Zhao, Chunyan Zhang, Lang Zhuo, Yugen Zhang and Jackie Y. Ying pp 12586–12587 DOI: 10.1021/ja8037883 Supporting Info

Highly Enantioselective Diels−Alder Reactions of Danishefsky Type Dienes with Electron-Deficient Alkenes Catalyzed by Yb(III)-BINAMIDE Complexes Yukinori Sudo, Daisuke Shirasaki, Shinji Harada and Atsushi Nishida pp 12588–12589 DOI: 10.1021/ja804430n Supporting Info

Artificial Enzymes with Thiazolium and Imidazolium Coenzyme Mimics Huanyu Zhao, Frank W. Foss, and Ronald Breslow pp 12590–12591 DOI: 10.1021/ja804577q Supporting Info

Branch-Selective Reductive Coupling of 2-Vinyl Pyridines and Imines via Rhodium Catalyzed C−C Bond Forming Hydrogenation Venukrishnan Komanduri, Christopher D. Grant and Michael J. Krische pp 12592–12593 DOI: 10.1021/ja805056g Supporting Info

Asymmetric Intramolecular Arylcyanation of Unactivated Olefins via C−CN Bond Activation Mary P. Watson and Eric N. Jacobsen pp 12594–12595 DOI: 10.1021/ja805094j Supporting Info

Highly Enantioselective Aza Morita−Baylis−Hillman Reaction Catalyzed by Bifunctional β-Isocupreidine Derivatives Nacim Abermil, Graldine Masson and Jieping Zhu pp 12596–12597 DOI: 10.1021/ja805122j Supporting Info

Au-Containing All-Carbon 1,3-Dipoles: Generation and [3+2] Cycloaddition Reactions Guozhu Zhang and Liming Zhang pp 12598–12599 DOI: 10.1021/ja804690u Supporting Info

An Accurate Force Field Model for the Strain Energy Analysis of the Covalent Organic Framework COF-102 Rochus Schmid and Maxim Tafipolsky pp 12600–12601 DOI: 10.1021/ja804734g Supporting Info

Synthesis of Platinum Nanowheels Using a Bicellar Template Yujiang Song, Rachel M. Dorin, Robert M. Garcia, Ying-Bing Jiang, Haorong Wang, Peng Li, Yan Qiu, Frank van Swol, James E. Miller and John A. Shelnutt pp 12602–12603 DOI: 10.1021/ja8047464 Supporting Info

NMR, Mass Spectrometry and Chemical Evidence Reveal a Different Chemical Structure for Methanobactin That Contains Oxazolone Rings Lee A. Behling, Scott C. Hartsel, David E. Lewis, Alan A. DiSpirito, Dong W. Choi, Larry R. Masterson, Gianluigi Veglia and Warren H. Gallagher pp 12604–12605 DOI: 10.1021/ja804747d Supporting Info

Tight Binding and Fluorescent Sensing of Oxalate in Water Lijun Tang, Jinhee Park, Hae-Jo Kim, Youngmee Kim, Sung Jin Kim, Jik Chin and Kwan Mook Kim pp 12606–12607 DOI: 10.1021/ja804753n Supporting Info

Electron Tomography Shows Molecular Anchoring Within a Layer-by-Layer Film Matthijn R. J. Vos, Monica Breurken, Philippe E. L. G. Leclre, Paul H. H. Bomans, Felix de Haas, Peter M. Frederik, John A. Jansen, Roeland J. M. Nolte and Nico A. J. M. Sommerdijk pp 12608–12609 DOI: 10.1021/ja804930d Supporting Info

Metal-Triggered Radial Self-Assembly of Collagen Peptide Fibers David E. Przybyla and Jean Chmielewski pp 12610–12611 DOI: 10.1021/ja804942w Supporting Info

Creation of Nanostructures with Poly(methyl methacrylate)-Mediated Nanotransfer Printing Liying Jiao, Ben Fan, Xiaojun Xian, Zhongyun Wu, Jin Zhang and Zhongfan Liu pp 12612–12613 DOI: 10.1021/ja805070b Supporting Info

Preparation of Azafullerene Derivatives from Fullerene-Mixed Peroxides and Single Crystal X-ray Structures of Azafulleroid and Azafullerene Gaihong Zhang, Shaohua Huang, Zuo Xiao, Quan Chen, Liangbing Gan and Zheming Wang pp 12614–12615 DOI: 10.1021/ja805072h Supporting Info

Probing the Structure of Single-Molecule Surface-Enhanced Raman Scattering Hot Spots Jon P. Camden, Jon A. Dieringer, Yingmin Wang, David J. Masiello, Lawrence D. Marks, George C. Schatz and Richard P. Van Duyne pp 12616–12617 DOI: 10.1021/ja8051427

Evidence That the (6−4) Photolyase Mechanism Can Proceed through an Oxetane Intermediate Sadia Asgatay, Christian Petermann, Dominique Harakat, Dominique Guillaume, John-Stephen Taylor and Pascale Clivio pp 12618–12619 DOI: 10.1021/ja805214s Supporting Info

A Rainbow of Fluoromodules: A Promiscuous scFv Protein Binds to and Activates a Diverse Set of Fluorogenic Cyanine Dyes Hayriye zhalici-nal, Crystal Lee Pow, Sarah A. Marks, Lawrence D. Jesper, Gloria L. Silva, Nathaniel I. Shank, Elizabeth W. Jones, James M. Burnette, , Peter B. Berget and Bruce A. Armitage pp 12620–12621 DOI: 10.1021/ja805042p Supporting Info

Detection of Single-Molecule DNA Hybridization Using Enzymatic Amplification in an Array of Femtoliter-Sized Reaction Vessels Zhaohui Li, Ryan B. Hayman and David R. Walt pp 12622–12623 DOI: 10.1021/ja8053018 Supporting Info

Similar Membrane Affinity of Mono- and Di-S-acylated Ras Membrane Anchors: A New Twist in the Role of Protein Lipidation Alemayehu A. Gorfe and J. Andrew McCammon pp 12624–12625 DOI: 10.1021/ja805110q

Crystals as Molecules: Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks William Morris, Christian J. Doonan, Hiroyasu Furukawa, Rahul Banerjee and Omar M. Yaghi pp 12626–12627 DOI: 10.1021/ja805222x Supporting Info

η2-Organoazide Complexes of Nickel and Their Conversion to Terminal Imido Complexes via Dinitrogen Extrusion Rory Waterman and Gregory L. Hillhouse pp 12628–12629 DOI: 10.1021/ja805530z Supporting Info

A Stereoselective Synthesis of (+)-Gonyautoxin 3 John V. Mulcahy and J. Du Bois pp 12630–12631 DOI: 10.1021/ja805651g Supporting Info

Activation of H2 by Phosphinoboranes R2PB(C6F5)2 Stephen J. Geier, Thomas M. Gilbert and Douglas W. Stephan pp 12632–12633 DOI: 10.1021/ja805493y Supporting Info

Purification of High Aspect Ratio Gold Nanorods: Complete Removal of Platelets Bishnu P. Khanal and Eugene R. Zubarev pp 12634–12635 DOI: 10.1021/ja806043p Supporting Info

Selecting Aptamers for a Glycoprotein through the Incorporation of the Boronic Acid Moiety Minyong Li, Na Lin, Zhen Huang, Lupei Du, Craig Altier, Hao Fang and Binghe Wang pp 12636–12638 DOI: 10.1021/ja801510d Supporting Info

Zeolite-like Metal−Organic Frameworks as Platforms for Applications: On Metalloporphyrin-Based Catalysts Mohamed H. Alkordi, Yunling Liu, Randy W. Larsen, Jarrod F. Eubank and Mohamed Eddaoudi pp 12639–12641 DOI: 10.1021/ja804703w Supporting Info

Insight into the Mechanisms of the Ethylbenzene Disproportionation: Transition State Shape Selectivity on Zeolites Jun Huang, Yijiao Jiang, V. R. Reddy Marthala and Michael Hunger pp 12642–12644 DOI: 10.1021/ja8042849 Supporting Info

Nickel-Catalyzed Asymmetric Cross-Couplings of Racemic Propargylic Halides with Arylzinc Reagents Sean W. Smith and Gregory C. Fu pp 12645–12647 DOI: 10.1021/ja805165y Supporting Info

Stereospecific Nucleophilic Substitution of Optically Pure H-Phosphinates: A General Way for the Preparation of Chiral P-Stereogenic Phosphine Oxides Qing Xu, Chang-Qiu Zhao and Li-Biao Han pp 12648–12655 DOI: 10.1021/ja804412k Supporting Info

Inhibition of Class A β-Lactamases by Carbapenems: Crystallographic Observation of Two Conformations of Meropenem in SHV-1 Michiyosi Nukaga, Christopher R. Bethel, Jodi M. Thomson, Andrea M. Hujer, Anne Distler, Vernon E. Anderson, James R. Knox and Robert A. Bonomo pp 12656–12662 DOI: 10.1021/ja7111146

Density Functional Theory Calculations of Hydrogen-Bond-Mediated NMR J Coupling in the Solid State Sin A. Joyce, Jonathan R. Yates, Chris J. Pickard and Steven P. Brown pp 12663–12670 DOI: 10.1021/ja800419m Supporting Info

Residue Ionization in LpxC Directly Observed by 67Zn NMR Spectroscopy Andrew S. Lipton, Robert W. Heck, Marcy Hernick, Carol A. Fierke and Paul D. Ellis pp 12671–12679 DOI: 10.1021/ja801776c Supporting Info

Electron Capture by a Hydrated Gaseous Peptide: Effects of Water on Fragmentation and Molecular Survival James S. Prell, Jeremy T. O’Brien, Anne I. S. Holm, Ryan D. Leib, William A. Donald and Evan R. Williams pp 12680–12689 DOI: 10.1021/ja8022434

Wired-Enzyme Core−Shell Au Nanoparticle Biosensor P. Scodeller, V. Flexer, R. Szamocki, E. J. Calvo, N. Tognalli, H. Troiani and A. Fainstein pp 12690–12697 DOI: 10.1021/ja802318f Supporting Info

Nanosolids, Slushes, and Nanoliquids: Characterization of Nanophases in Metal Clusters and Nanoparticles Zhen Hua Li and Donald G. Truhlar pp 12698–12711 DOI: 10.1021/ja802389d Supporting Info

Resolving the Structure of Ligands Bound to the Surface of Superparamagnetic Iron Oxide Nanoparticles by High-Resolution Magic-Angle Spinning NMR Spectroscopy Laura Polito, Miriam Colombo, Diego Monti, Sergio Melato, Enrico Caneva and Davide Prosperi pp 12712–12724 DOI: 10.1021/ja802479n Supporting Info

Binding of ADP in the Mitochondrial ADP/ATP Carrier Is Driven by an Electrostatic Funnel Franois Dehez, Eva Pebay-Peyroula and Christophe Chipot pp 12725–12733 DOI: 10.1021/ja8033087 Supporting Info

Ordered DNA Wrapping Switches on Luminescence in Single-Walled Nanotube Dispersions Helen Cathcart, Valeria Nicolosi, J. Marguerite Hughes, Werner J. Blau, John M. Kelly, Susan J. Quinn and Jonathan N. Coleman pp 12734–12744 DOI: 10.1021/ja803273s Supporting Info

Extended Model Free Approach To Analyze Correlation Functions of Multidomain Proteins in the Presence of Motional Coupling Kang Chen and Nico Tjandra pp 12745–12751 DOI: 10.1021/ja803557t Supporting Info

Nitroxide Paramagnet-Induced Para−Ortho Conversion and Nuclear Spin Relaxation of H2 in Organic Solvents Elena Sartori, Marco Ruzzi, Ronald G. Lawler and Nicholas J. Turro pp 12752–12756 DOI: 10.1021/ja8037195

Fermi Level Engineering of Single-Walled Carbon Nanotubes by AuCl3 Doping Ki Kang Kim, Jung Jun Bae, Hyeon Ki Park, Soo Min Kim, Hong-Zhang Geng, Kyung Ah Park, Hyeon-Jin Shin, Seon-Mi Yoon, Anass Benayad, Jae-Young Choi and Young Hee Lee pp 12757–12761 DOI: 10.1021/ja8038689 Supporting Info

Ab Initio Evaluation of the Thermodynamic and Electrochemical Properties of Alkyl Halides and Radicals and Their Mechanistic Implications for Atom Transfer Radical Polymerization Ching Yeh Lin, Michelle L. Coote, Armando Gennaro and Krzysztof Matyjaszewski pp 12762–12774 DOI: 10.1021/ja8038823 Supporting Info

Cyclic Ruthenium-Alkylidene Catalysts for Ring-Expansion Metathesis Polymerization Andrew J. Boydston, Yan Xia, Julia A. Kornfield, Irina A. Gorodetskaya and Robert H. Grubbs pp 12775–12782 DOI: 10.1021/ja8037849 Supporting Info

Conformational Changes in Photoexcited (R)-(+)-1,1′-Bi-2-naphthol Studied by Time-Resolved Circular Dichroism Claire Niezborala and Franois Hache pp 12783–12786 DOI: 10.1021/ja8039844 Supporting Info

Hydrolysis of Cellulose by Amorphous Carbon Bearing SO3H, COOH, and OH Groups Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi and Michikazu Hara pp 12787–12793 DOI: 10.1021/ja803983h Supporting Info

A Biomimetic Approach to Oxidized Sites in the Xanthine Oxidoreductase Family: Synthesis and Stereochemistry of Tungsten(VI) Analogue Complexes Stanislav Groysman, Jun-Jieh Wang, Ranitendranath Tagore, Sonny C. Lee and R. H. Holm pp 12794–12807 DOI: 10.1021/ja804000k Supporting Info

Prediction of the Conditions for Breathing of Metal Organic Framework Materials Using a Combination of X-ray Powder Diffraction, Microcalorimetry, and Molecular Simulation Philip L. Llewellyn, Guillaume Maurin, Thomas Devic, Sandra Loera-Serna, Nilton Rosenbach, Christian Serre, Sandrine Bourrelly, Patricia Horcajada, Yaroslav Filinchuk and Grard Frey pp 12808–12814 DOI: 10.1021/ja803899q Supporting Info

Fabrication of Truncated Rhombic Dodecahedral Cu2O Nanocages and Nanoframes by Particle Aggregation and Acidic Etching Chun-Hong Kuo and Michael H. Huang pp 12815–12820 DOI: 10.1021/ja804625s Supporting Info

Recognition-Domain Focused Chemosensors: Versatile and Efficient Reporters of Protein Kinase Activity Elvedin Lukovi, Juan A. Gonzlez-Vera and Barbara Imperiali pp 12821–12827 DOI: 10.1021/ja8046188 Supporting Info

Low-Bandgap Poly(Thiophene-Phenylene-Thiophene) Derivatives with Broaden Absorption Spectra for Use in High-Performance Bulk-Heterojunction Polymer Solar Cells Chih-Ping Chen, Shu-Hua Chan, Teng-Chih Chao, Ching Ting and Bao-Tsan Ko pp 12828–12833 DOI: 10.1021/ja801877k Supporting Info

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride Takeru Furuya and Tobias Ritter p 12834 DOI: 10.1021/ja8065013

Book Review of Advances in Chemical Physics, Volume 139 Edward W. Castner, p 12835 DOI: 10.1021/ja805896h

Book Review of Inorganic Materials Synthesis and Fabrication Raul F. Lobo pp 12835–12836 DOI: 10.1021/ja806170n

Issue 39

Intermolecular Rhodium-Catalyzed [3+2+2] Carbocyclization of Alkenylidenecyclopropanes with Activated Alkynes: Regio- and Diastereoselective Construction of cis-Fused Bicycloheptadienes P. Andrew Evans and Phillip A. Inglesby pp 12838–12839 DOI: 10.1021/ja803691p Supporting Info

Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct Takeshi Akasaka, Takayoshi Kono, Yuji Takematsu, Hidefumi Nikawa, Tsukasa Nakahodo, Takatsugu Wakahara, Midori O. Ishitsuka, Takahiro Tsuchiya, Yutaka Maeda, Michael T. H. Liu, Kenji Yoza, Tatsuhisa Kato, Kazunori Yamamoto, Naomi Mizorogi, Zdenek Slanina and Shigeru Nagase pp 12840–12841 DOI: 10.1021/ja802156n Supporting Info

Directed Assembly of Chiral Oxidovanadium(V) Methoxides into C4-Symmetric Metal(I) Vanadate-Centered Quadruplexes: Synergistic K+- and Ag+-specific Transport Chien-Tien Chen, Ya-Hui Lin and Ting-Shen Kuo pp 12842–12843 DOI: 10.1021/ja8051552 Supporting Info

Nepheline from K2CO3/Nanosized Sodalite as a Prospective Candidate for Diesel Soot Combustion Riichiro Kimura, Junji Wakabayashi, S. P. Elangovan, Masaru Ogura and Tatsuya Okubo pp 12844–12845 DOI: 10.1021/ja802102q Supporting Info

Fluorescent Signaling Based on Sulfoxide Profluorophores: Application to the Visual Detection of the Explosive TATP Sergey Malashikhin and Nathaniel S. Finney pp 12846–12847 DOI: 10.1021/ja802989v Supporting Info

Formation of Complex Organics from Acetylene Catalyzed by Ionized Benzene Paul O. Momoh, Abdel-Rahman Soliman, Michael Meot-Ner, Alessandra Ricca and M. Samy El-Shall pp 12848–12849 DOI: 10.1021/ja803282c Supporting Info

On/Off Photoswitching of the Electropolymerizability of Terthiophenes Jetsuda Areephong, Tibor Kudernac, Jaap J. D. de Jong, Gregory T. Carroll, Davide Pantorott, Johan Hjelm, Wesley R. Browne and Ben L. Feringa pp 12850–12851 DOI: 10.1021/ja803714p Supporting Info

One-Pot Synthesis of Robust Core/Shell Gold Nanoparticles Hongchen Dong, Manzhou Zhu, Jeong Ae Yoon, Haifeng Gao, Rongchao Jin and Krzysztof Matyjaszewski pp 12852–12853 DOI: 10.1021/ja8038097 Supporting Info

Synthesis of DNA−Organic Molecule−DNA Triblock Oligomers Using the Amide Coupling Reaction and Their Enzymatic Amplification Jungkyu K. Lee, Young Hwan Jung, Randall M. Stoltenberg, Jeffery B.-H. Tok and Zhenan Bao pp 12854–12855 DOI: 10.1021/ja8044458 Supporting Info

Membrane-Bound α-Synuclein Forms an Extended Helix: Long-Distance Pulsed ESR Measurements Using Vesicles, Bicelles, and Rodlike Micelles Elka R. Georgieva, Trudy F. Ramlall, Peter P. Borbat, Jack H. Freed and David Eliezer pp 12856–12857 DOI: 10.1021/ja804517m Supporting Info

Exciton Trapping in π-Conjugated Materials: A Quantum-Chemistry-Based Protocol Applied to Perylene Bisimide Dye Aggregates Reinhold F. Fink, Joachim Seibt, Volker Engel, Manuel Renz, Martin Kaupp, Stefan Lochbrunner, Hong-Mei Zhao, Johannes Pfister, Frank Wrthner and Bernd Engels pp 12858–12859 DOI: 10.1021/ja804331b Supporting Info

G^C Quartet A DNA-Inspired Janus-GC Heterocycle: Synthesis, Structural Analysis, and Self-Organization Ali Asadi, Brian O. Patrick and David M. Perrin pp 12860–12861 DOI: 10.1021/ja8047128 Supporting Info

Origin of the Regio- and Stereoselectivity of Allylic Substitution of Organocopper Reagents Naohiko Yoshikai, Song-Lin Zhang and Eiichi Nakamura pp 12862–12863 DOI: 10.1021/ja804682r Supporting Info

Physical Polymerization and Liquid Crystallization of RNA Oligomers Giuliano Zanchetta, Tommaso Bellini, Michi Nakata and Noel A. Clark pp 12864–12865 DOI: 10.1021/ja804718c Supporting Info

One-Pot Synthesis, Encapsulation, and Solubilization of Size-Tuned Quantum Dots with Amphiphilic Multidentate Ligands Brad A. Kairdolf, Andrew M. Smith and Shuming Nie pp 12866–12867 DOI: 10.1021/ja804755q Supporting Info

Magnetic Field Affects Enzymatic ATP Synthesis Anatoly L. Buchachenko and Dmitry A. Kuznetsov pp 12868–12869 DOI: 10.1021/ja804819k

Tuning the Ionization Energy of Organic Semiconductor Films: The Role of Intramolecular Polar Bonds Ingo Salzmann, Steffen Duhm, Georg Heimel, Martin Oehzelt, Rolf Kniprath, Robert L. Johnson, Jrgen P. Rabe and Norbert Koch pp 12870–12871 DOI: 10.1021/ja804793a Supporting Info

General Method for Synthesis of Functionalized Macrocycles and Catenanes Utilizing “Click” Chemistry Jackson D. Megiatto, and David I. Schuster pp 12872–12873 DOI: 10.1021/ja8050519 Supporting Info

Intramolecular Arylcyanation of Alkenes Catalyzed by Nickel/AlMe2Cl Yoshiaki Nakao, Shiro Ebata, Akira Yada, Tamejiro Hiyama, Masashi Ikawa and Sensuke Ogoshi pp 12874–12875 DOI: 10.1021/ja805088r Supporting Info

Phosphorus-Containing Block Copolymer Templates Can Control the Size and Shape of Gold Nanostructures Kevin J. T. Noonan, Bronwyn H. Gillon, Vittorio Cappello and Derek P. Gates pp 12876–12877 DOI: 10.1021/ja805076y Supporting Info

A Terminal Borylene Ruthenium Complex: From B−H Activation to Reversible Hydrogen Release Gilles Alcaraz, Ulrike Helmstedt, Eric Clot, Laure Vendier and Sylviane Sabo-Etienne pp 12878–12879 DOI: 10.1021/ja805164n Supporting Info

Mechanism of Efficient Firefly Bioluminescence via Adiabatic Transition State and Seam of Sloped Conical Intersection Lung Wa Chung, Shigehiko Hayashi, Marcus Lundberg, Toru Nakatsu, Hiroaki Kato and Keiji Morokuma pp 12880–12881 DOI: 10.1021/ja8052464 Supporting Info

Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis Jian Zhang, Shumei Chen, Tao Wu, Pingyun Feng and Xianhui Bu pp 12882–12883 DOI: 10.1021/ja805272j Supporting Info

LOV-Like Flavin-Cys Adduct Formation by Introducing a Cys Residue in the BLUF Domain of TePixD Hiroyuki Suzuki, Koji Okajima, Masahiko Ikeuchi and Takumi Noguchi pp 12884–12885 DOI: 10.1021/ja805363u Supporting Info

Efficient Visible Light Photocatalysis of [2+2] Enone Cycloadditions Michael A. Ischay, Mary E. Anzovino, Juana Du and Tehshik P. Yoon pp 12886–12887 DOI: 10.1021/ja805387f Supporting Info

The Topopyrones Poison Human DNA Topoisomerases I and II Qasim A. Khan, Mark A. Elban and Sidney M. Hecht pp 12888–12889 DOI: 10.1021/ja805421b Supporting Info

Protein Binding Has a Large Effect on Radical Mediated DNA Damage Xiaohua Peng, Ying Z. Pigli, Phoebe A. Rice and Marc M. Greenberg pp 12890–12891 DOI: 10.1021/ja805440v Supporting Info

Multiple Insertion of a Silyl Vinyl Ether by (α-Diimine)PdMe+ Species Changle Chen, Shuji Luo and Richard F. Jordan pp 12892–12893 DOI: 10.1021/ja8056858 Supporting Info

An Expeditious Synthesis of C(3)−N(1′) Heterodimeric Indolines Vinson R. Espejo and Jon D. Rainier pp 12894–12895 DOI: 10.1021/ja8061908 Supporting Info

Orthogonal Self-Assembly of Interconnected One-Dimensional Inorganic and Organic Nanostructures on the Si(100) Surface Qing Hua Wang and Mark C. Hersam pp 12896–12897 DOI: 10.1021/ja806123j Supporting Info

Reversible Intramolecular C−C Bond Formation/Breaking and Color Switching Mediated by a N,C-Chelate in (2-ph-py)BMes2 and (5-BMes2-2-ph-py)BMes2 Ying-Li Rao, Hazem Amarne, Shu-Bin Zhao, Theresa M. McCormick, Sanela Marti, Yi Sun, Rui-Yao Wang and Suning Wang pp 12898–12900 DOI: 10.1021/ja8052046 Supporting Info

Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation Song Lin, Chun-Xiao Song, Gui-Xin Cai, Wen-Hua Wang and Zhang-Jie Shi pp 12901–12903 DOI: 10.1021/ja803452p Supporting Info

Enantioselective Total Synthesis of Clavirolide C. Applications of Cu-Catalyzed Asymmetric Conjugate Additions and Ru-Catalyzed Ring-Closing Metathesis M. Kevin Brown and Amir H. Hoveyda pp 12904–12906 DOI: 10.1021/ja8058414 Supporting Info

Stereoselective Synthesis of cis- or trans-3,5-Disubstituted Pyrazolidines via Pd-Catalyzed Carboamination Reactions: Use of Allylic Strain to Control Product Stereochemistry Through N-Substituent Manipulation Natalie C. Giampietro and John P. Wolfe pp 12907–12911 DOI: 10.1021/ja8050487 Supporting Info

Electron Transport and Recombination in Dye-Sensitized Mesoporous TiO2 Probed by Photoinduced Charge-Conductivity Modulation Spectroscopy with Monte Carlo Modeling Annamaria Petrozza, Chris Groves and Henry J. Snaith pp 12912–12920 DOI: 10.1021/ja802108r

Redox-Mediated Synthesis and Encapsulation of Inorganic Nanoparticles in Shell-Cross-Linked Cylindrical Polyferrocenylsilane Block Copolymer Micelles Hai Wang, Xiaosong Wang, Mitchell A. Winnik and Ian Manners pp 12921–12930 DOI: 10.1021/ja8028558 Supporting Info

Low Coordinate, Monomeric Molybdenum and Tungsten(III) Complexes: Structure, Reactivity and Calculational Studies of (silox)3Mo and (silox)3ML (M = Mo, W; L = PMe3, CO; silox = tBu3SiO) David S. Kuiper, Peter T. Wolczanski, Emil B. Lobkovsky and Thomas R. Cundari pp 12931–12943 DOI: 10.1021/ja802706u Supporting Info

Electrochemical Pinning of the Fermi Level: Mediation of Photoluminescence from Gallium Nitride and Zinc Oxide Vidhya Chakrapani, Chandrashekhar Pendyala, Kathleen Kash, Alfred B. Anderson, Mahendra K. Sunkara and John C. Angus pp 12944–12952 DOI: 10.1021/ja710999r

High-Affinity Small Molecule−Phospholipid Complex Formation: Binding of Siramesine to Phosphatidic Acid Mikko J. Parry, Juha-Matti I. Alakoskela, Himanshu Khandelia, Subramanian Arun Kumar, Marja Jttel, Ajay K. Mahalka and Paavo K. J. Kinnunen pp 12953–12960 DOI: 10.1021/ja800516w Supporting Info

Is the Bound Substrate in Nitric Oxide Synthase Protonated or Neutral and What Is the Active Oxidant that Performs Substrate Hydroxylation? Sam P. de Visser and Lee Siew Tan pp 12961–12974 DOI: 10.1021/ja8010995 Supporting Info

Why Does Fluoride Anion Accelerate Transmetalation between Vinylsilane and Palladium(II)−Vinyl Complex? Theoretical Study Akihiro Sugiyama, Yu-ya Ohnishi, Mayu Nakaoka, Yoshihide Nakao, Hirofumi Sato, Shigeyoshi Sakaki, Yoshiaki Nakao and Tamejiro Hiyama pp 12975–12985 DOI: 10.1021/ja801362e Supporting Info

Attachment of Molecular Hydrogen to an Isolated Boron Cation: An Infrared and ab initio Study Viktoras Dryza, Berwyck L. J. Poad and Evan J. Bieske pp 12986–12991 DOI: 10.1021/ja8018302 Supporting Info

M2@C79N (M = Y, Tb): Isolation and Characterization of Stable Endohedral Metallofullerenes Exhibiting M−M Bonding Interactions inside Aza[80]fullerene Cages Tianming Zuo, Liaosa Xu, Christine M. Beavers, Marilyn M. Olmstead, Wujun Fu, T. Daniel Crawford, Alan L. Balch and Harry C. Dorn pp 12992–12997 DOI: 10.1021/ja802417d Supporting Info

Solution Structures of Chemoenzymatically Synthesized Heparin and Its Precursors Zhenqing Zhang, Scott A. McCallum, Jin Xie, Lidia Nieto, Francisco Corzana, Jess Jimnez-Barbero, Miao Chen, Jian Liu and Robert J. Linhardt pp 12998–13007 DOI: 10.1021/ja8026345 Supporting Info

Electronic and Optical Properties of Magnesium Phthalocyanine (MgPc) Solid Films Studied by Soft X-Ray Excited Optical Luminescence and X-Ray Absorption Spectroscopies N. Peltekis, B. N. Holland, S. Krishnamurthy, I. T. McGovern, N. R. J. Poolton, S. Patel and C. McGuinness pp 13008–13012 DOI: 10.1021/ja803063b

Experimental and Theoretical Studies of the Structures and Interactions of Vancomycin Antibiotics with Cell Wall Analogues Zhibo Yang, Erich R. Vorpagel and Julia Laskin pp 13013–13022 DOI: 10.1021/ja802643g Supporting Info

Differential Tuning of the Electron Transfer Parameters in 1,3,5-Triarylpyrazolines: A Rational Design Approach for Optimizing the Contrast Ratio of Fluorescent Probes John Cody, Subrata Mandal, Liuchun Yang and Christoph J. Fahrni pp 13023–13032 DOI: 10.1021/ja803074y Supporting Info

Interfacial Structures of Acidic and Basic Aqueous Solutions Chuanshan Tian, Na Ji, Glenn A. Waychunas and Y. Ron Shen pp 13033–13039 DOI: 10.1021/ja8021297

Structure and Dynamics of a Partially Folded Protein Are Decoupled from Its Mechanism of Aggregation Giulia Calloni, Christofer Lendel, Silvia Campioni, Silva Giannini, Alessandra Gliozzi, Annalisa Relini, Michele Vendruscolo, Christopher M. Dobson, Xavier Salvatella and Fabrizio Chiti pp 13040–13050 DOI: 10.1021/ja8029224 Supporting Info

Catalytic Tuning of a Phosphinoethane Ligand for Enhanced C−H Activation Thomas R. Cundari, J. Oscar C. Jimenez-Halla, Glenn R. Morello and Sridhar Vaddadi pp 13051–13058 DOI: 10.1021/ja803176j Supporting Info

Realization of a “Lockable” Molecular Switch via pH- and Redox-Modulated Cyclization Craig J. Richmond, Alexis D. C. Parenty, Yu-Fei Song, Graeme Cooke and Leroy Cronin pp 13059–13065 DOI: 10.1021/ja803338m Supporting Info

Dual Function of the Hydration Layer around an Antifreeze Protein Revealed by Atomistic Molecular Dynamics Simulations David R. Nutt and Jeremy C. Smith pp 13066–13073 DOI: 10.1021/ja8034027

Divalent Cation-Induced Variations in Polyelectrolyte Conformation and Controlling Calcite Morphologies: Direct Observation of the Phase Transition by Atomic Force Microscopy Ranjith Krishna Pai and Saju Pillai pp 13074–13078 DOI: 10.1021/ja803371c

Hollow Spherical Supramolecular Dendrimers Virgil Percec, Mihai Peterca, Andrs E. Dulcey, Mohammad R. Imam, Steven D. Hudson, Sami Nummelin, Peter Adelman and Paul A. Heiney pp 13079–13094 DOI: 10.1021/ja8034703 Supporting Info

Highly Effective Colorimetric and Visual Detection of Nucleic Acids Using an Asymmetrically Split Peroxidase DNAzyme Minggang Deng, Dan Zhang, Yangyang Zhou and Xiang Zhou pp 13095–13102 DOI: 10.1021/ja803507d

The Dynamics of Water at DNA Interfaces: Computational Studies of Hoechst 33258 Bound to DNA Kristina E. Furse and Steven A. Corcelli pp 13103–13109 DOI: 10.1021/ja803728g Supporting Info

Design, Synthesis, and Biological Evaluation of Platensimycin Analogues with Varying Degrees of Molecular Complexity K. C. Nicolaou, Antonia F. Stepan, Troy Lister, Ang Li, Ana Montero, G. Scott Tria, Craig I. Turner, Yefeng Tang, Jianhua Wang, Ross M. Denton and David J. Edmonds pp 13110–13119 DOI: 10.1021/ja8044376 Supporting Info

Optoelectronic and Charge Transport Properties at Organic−Organic Semiconductor Interfaces: Comparison between Polyfluorene-Based Polymer Blend and Copolymer Ji-Seon Kim, Linus Lu, Paiboon Sreearunothai, Alex Seeley, Keng-Hoong Yim, Annamaria Petrozza, Craig E. Murphy, David Beljonne, Jrme Cornil and Richard H. Friend pp 13120–13131 DOI: 10.1021/ja803766j

Ultrafast Dynamics of Flavins in Five Redox States Ya-Ting Kao, Chaitanya Saxena, Ting-Fang He, Lijun Guo, Lijuan Wang, Aziz Sancar and Dongping Zhong pp 13132–13139 DOI: 10.1021/ja8045469

Facile Large-Scale Fabrication of Proton Conducting Channels Basit Yameen, Anke Kaltbeitzel, Andreas Langner, Hatice Duran, Frank Mller, Ulrich Gsele, Omar Azzaroni and Wolfgang Knoll pp 13140–13144 DOI: 10.1021/ja804683j

Sequential C−Si Bond Formations from Diphenylsilane: Application to Silanediol Peptide Isostere Precursors Lone Nielsen and Troels Skrydstrup pp 13145–13151 DOI: 10.1021/ja804720p Supporting Info

Synthesis and Shape-Tailoring of Copper Sulfide/Indium Sulfide-Based Nanocrystals Wei Han, Luoxin Yi, Nan Zhao, Aiwei Tang, Mingyuan Gao and Zhiyong Tang pp 13152–13161 DOI: 10.1021/ja8046393 Supporting Info

Crown-6-calix[4]arene-Capped Calix[4]pyrrole: An Ion-Pair Receptor for Solvent-Separated CsF Ions Jonathan L. Sessler, Sung Kuk Kim, Dustin E. Gross, Chang-Hee Lee, Jong Seung Kim and Vincent M. Lynch pp 13162–13166 DOI: 10.1021/ja804976f Supporting Info

Highly Disordered Polymer Field Effect Transistors: N-Alkyl Dithieno[3,2-b:2′,3′-d]pyrrole-Based Copolymers with Surprisingly High Charge Carrier Mobilities Junying Liu, Rui Zhang, Genevive Sauv, Tomasz Kowalewski and Richard D. McCullough pp 13167–13176 DOI: 10.1021/ja803077v

Formal Synthesis of (−)-Kendomycin Featuring a Prins-Cyclization To Construct the Macrocycle Kevin B. Bahnck and Scott D. Rychnovsky pp 13177–13181 DOI: 10.1021/ja805187p Supporting Info

Hyperdimensional NMR Spectroscopy with Nonlinear Sampling Victor A. Jaravine, Anastasia V. Zhuravleva, Perttu Permi, Ilgis Ibraghimov and Vladislav Yu. Orekhov p 13182 DOI: 10.1021/ja8066463

Book Review of “Tomorrow’s Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry” p 13182 DOI: 10.1021/ja804483h

Book Review of Trace Quantitative Analysis by Mass Spectrometry John V. Goodpaster p 13183 DOI: 10.1021/ja806615z

Book Review of Ionic Liquids in Synthesis: Second, Completely Revised and Enlarged Edition, Volumes 1 and 2 James Mack pp 13183–13184 DOI: 10.1021/ja805338y

Book Review of Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure Moises A. Carreon p 13184 DOI: 10.1021/ja806745b

Issue 40

Conditional Glycosylation in Eukaryotic Cells Using a Biocompatible Chemical Inducer of Dimerization Jennifer L. Czlapinski, Michael W. Schelle, Lawrence W. Miller, Scott T. Laughlin, Jennifer J. Kohler, Virginia W. Cornish and Carolyn R. Bertozzi pp 13186–13187 DOI: 10.1021/ja8037728 Supporting Info

DNA Polymerase-Catalyzed DNA Network Growth Sascha Keller, Jie Wang, Madhaviah Chandra, Rdiger Berger and Andreas Marx pp 13188–13189 DOI: 10.1021/ja8045348 Supporting Info

A Janus-Wedge DNA Triplex with A-W1-T and G-W2-C Base Triplets Han Chen, Meena and Larry W. McLaughlin pp 13190–13191 DOI: 10.1021/ja804607v Supporting Info

Exploration of Single Molecule Events in a Haloperoxidase and Its Biomimic: Localization of Halogenation Activity Virginia Martnez Martnez, Gert De Cremer, Maarten B. J. Roeffaers, Michel Sliwa, Mukulesh Baruah, Dirk E. De Vos, Johan Hofkens and Bert F. Sels pp 13192–13193 DOI: 10.1021/ja804606m Supporting Info

Biosynthesis of a Site-Specific DNA Cleaving Protein Hyun Soo Lee and Peter G. Schultz pp 13194–13195 DOI: 10.1021/ja804653f Supporting Info

Seleninate in Place of Phosphate: Irreversible Inhibition of Protein Tyrosine Phosphatases Mohannad Abdo, Sijiu Liu, Bo Zhou, Chad D. Walls, Li Wu, Spencer Knapp and Zhong-Yin Zhang pp 13196–13197 DOI: 10.1021/ja804489m Supporting Info

Fullerene-Based Anchoring Groups for Molecular Electronics Christian A. Martin, Dapeng Ding, Jakob Kryger Sørensen, Thomas Bjørnholm, Jan M. van Ruitenbeek and Herre S. J. van der Zant pp 13198–13199 DOI: 10.1021/ja804699a Supporting Info

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants Valentn Miranda-Soto, Douglas B. Grotjahn, Antonio G. DiPasquale and Arnold L. Rheingold pp 13200–13201 DOI: 10.1021/ja804713u Supporting Info

Tetrathienoacene Copolymers As High Mobility, Soluble Organic Semiconductors Hon Hang Fong, Vladimir A. Pozdin, Aram Amassian, George G. Malliaras, Detlef-M. Smilgies, Mingqian He, Susan Gasper, Feixia Zhang and Michael Sorensen pp 13202–13203 DOI: 10.1021/ja804872x Supporting Info

Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines Sze-Man Yu and Stefan Mecking pp 13204–13205 DOI: 10.1021/ja805304p Supporting Info

An Electrochromic Nanostructured Liquid Crystal Consisting of π-Conjugated and Ionic Moieties Sanami Yazaki, Masahiro Funahashi and Takashi Kato pp 13206–13207 DOI: 10.1021/ja805339q Supporting Info

Asymmetric Hydrogenation of Cyclic Imines with an Ionic Cp*Rh(III) Catalyst Chaoqun Li and Jianliang Xiao pp 13208–13209 DOI: 10.1021/ja8050958 Supporting Info

Remote Substituent Effects and Regioselective Enhancement of Electrophilic Substitutions in Helical Aromatic Oligoamides Kolupula Srinivas, Brice Kauffmann, Christel Dolain, Jean-Michel Lger, Lon Ghosez and Ivan Huc pp 13210–13211 DOI: 10.1021/ja805178j Supporting Info

Structure of Li2FeSiO4 Shin-ichi Nishimura, Shogo Hayase, Ryoji Kanno, Masatomo Yashima, Noriaki Nakayama and Atsuo Yamada pp 13212–13213 DOI: 10.1021/ja805543p Supporting Info

Oxidation of a Mustard Gas Analogue Using an Aldehyde/O2 System Catalyzed by V-Doped Mesoporous Silica Stephanie R. Livingston and Christopher C. Landry pp 13214–13215 DOI: 10.1021/ja8056166 Supporting Info

A Stereochemical Test of a Proposed Structural Feature of the Nicotinic Acetylcholine Receptor Ariele P. Hanek, Henry A. Lester and Dennis A. Dougherty pp 13216–13218 DOI: 10.1021/ja8015457 Supporting Info

Regioselective De Novo Synthesis of Cyanohydroxypyridines with a Concerted Cycloaddition Mechanism Jin-Yong Lu, John A. Keith, Wei-Zheng Shen, Markus Schrmann, Hans Preut, Timo Jacob and Hans-Dieter Arndt pp 13219–13221 DOI: 10.1021/ja804078v Supporting Info

On the Two-Component Microwave-Mediated Reaction of Isonitriles with Carboxylic Acids: Regarding Alleged Formimidate Carboxylate Mixed Anhydrides Xuechen Li, Yu Yuan, William F. Berkowitz, Louis J. Todaro and Samuel J. Danishefsky pp 13222–13224 DOI: 10.1021/ja8047078 Supporting Info

Addressing Mechanistic Issues in the Coupling of Isonitriles and Carboxylic Acids: Potential Routes to Peptidic Constructs Xuechen Li, Yu Yuan, Cindy Kan and Samuel J. Danishefsky pp 13225–13227 DOI: 10.1021/ja804709s Supporting Info

Extending the Capability of STM Break Junction for Conductance Measurement of Atomic-Size Nanowires: An Electrochemical Strategy Xiao-Shun Zhou, Yi-Min Wei, Ling Liu, Zhao-Bin Chen, Jing Tang and Bing-Wei Mao pp 13228–13230 DOI: 10.1021/ja8055276 Supporting Info

Stereocontrolled Alkylative Construction of Quaternary Carbon Centers David A. Kummer, William J. Chain, Marvin R. Morales, Olga Quiroga and Andrew G. Myers pp 13231–13233 DOI: 10.1021/ja806021y Supporting Info

Cubic versus Spherical Magnetic Nanoparticles: The Role of Surface Anisotropy G. Salazar-Alvarez, J. Qin, V. epelk, I. Bergmann, M. Vasilakaki, K. N. Trohidou, J. D. Ardisson, W. A. A. Macedo, M. Mikhaylova, M. Muhammed, M. D. Bar and J. Nogus pp 13234–13239 DOI: 10.1021/ja0768744 Supporting Info

Quantum Mechanics/Molecular Mechanics Investigation of the Chemical Reaction in Dpo4 Reveals Water-Dependent Pathways and Requirements for Active Site Reorganization Yanli Wang and Tamar Schlick pp 13240–13250 DOI: 10.1021/ja802215c Supporting Info

Detection of Mismatched DNA on Partially Negatively Charged Diamond Surfaces by Optical and Potentiometric Methods Shoma Kuga, Jung-Hoon Yang, Hironori Takahashi, Kazuyuki Hirama, Takayuki Iwasaki and Hiroshi Kawarada pp 13251–13263 DOI: 10.1021/ja710167z Supporting Info

Solution Structure of a Peptide Nucleic Acid Duplex from NMR Data: Features and Limitations Wei He, Elizabeth Hatcher, Alexander Balaeff, David N. Beratan, Roberto R. Gil, Marcela Madrid and Catalina Achim pp 13264–13273 DOI: 10.1021/ja800652h Supporting Info

Supramolecular Chemistry in the Structure Direction of Microporous Materials from Aromatic Structure-Directing Agents Luis Gmez-Hortigela, Fernando Lpez-Arbeloa, Furio Cor and Joaquín Prez-Pariente pp 13274–13284 DOI: 10.1021/ja8023725 Supporting Info

Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization Lopa V. Desai, Kara J. Stowers and Melanie S. Sanford pp 13285–13293 DOI: 10.1021/ja8045519 Supporting Info

Residual Dipolar Coupling Measurements of Transmembrane Proteins Using Aligned Low-q Bicelles and High-Resolution Magic Angle Spinning NMR Spectroscopy Christian G. Canlas, Dejian Ma, Pei Tang and Yan Xu pp 13294–13300 DOI: 10.1021/ja802578z Supporting Info

Facilitated Permeation of Antibiotics across Membrane Channels − Interaction of the Quinolone Moxifloxacin with the OmpF Channel Tivadar Mach, Patricia Neves, Enrico Spiga, Helge Weingart, Mathias Winterhalter, Paolo Ruggerone, Matteo Ceccarelli and Paula Gameiro pp 13301–13309 DOI: 10.1021/ja803188c Supporting Info

Spectra and Kinetic Studies of the Compound I Derivative of Cytochrome P450 119 Xin Sheng, John H. Horner and Martin Newcomb pp 13310–13320 DOI: 10.1021/ja802652b Supporting Info

Development of Catalytic Asymmetric 1,4-Addition and [3 + 2] Cycloaddition Reactions Using Chiral Calcium Complexes Tetsu Tsubogo, Susumu Saito, Kazutaka Seki, Yasuhiro Yamashita and Sh Kobayashi pp 13321–13332 DOI: 10.1021/ja8032058 Supporting Info

From Microporous Regular Frameworks to Mesoporous Materials with Ultrahigh Surface Area: Dynamic Reorganization of Porous Polymer Networks Pierre Kuhn, Aurlien Forget, Dangsheng Su, Arne Thomas and Markus Antonietti pp 13333–13337 DOI: 10.1021/ja803708s Supporting Info

Molecular Chemistry in a Zeolite: Genesis of a Zeolite Y-Supported Ruthenium Complex Catalyst Isao Ogino and Bruce C. Gates pp 13338–13346 DOI: 10.1021/ja804265r Supporting Info

Solubility of Lysozyme in the Presence of Aqueous Chloride Salts: Common-Ion Effect and Its Role on Solubility and Crystal Thermodynamics Onofrio Annunziata, Andrew Payne and Ying Wang pp 13347–13352 DOI: 10.1021/ja804304e Supporting Info

Like Polarity Ion/Ion Reactions Enable the Investigation of Specific Metal Interactions in Nucleic Acids and Their Noncovalent Assemblies Kevin B. Turner, Sarah A. Monti and Daniele Fabris pp 13353–13363 DOI: 10.1021/ja8045734 Supporting Info

Dye-Sensitized Solar Cells Based on Oriented TiO2 Nanotube Arrays: Transport, Trapping, and Transfer of Electrons James R. Jennings, Andrei Ghicov, Laurence M. Peter, Patrik Schmuki and Alison B. Walker pp 13364–13372 DOI: 10.1021/ja804852z Supporting Info

Exchange of Organic Radicals with Organo-Cobalt Complexes Formed in the Living Radical Polymerization of Vinyl Acetate Shan Li, Bas de Bruin, Chi-How Peng, Michael Fryd and Bradford B. Wayland pp 13373–13381 DOI: 10.1021/ja804010h Supporting Info

Proton Dynamics and Room-Temperature Ferroelectricity in Anilate Salts with a Proton Sponge Sachio Horiuchi, Reiji Kumai, Yusuke Tokunaga and Yoshinori Tokura pp 13382–13391 DOI: 10.1021/ja8032235 Supporting Info

18,18′-Dihexyl[9,9′]biphenanthro[9,10-b]triphenylene: Construction and Consequences of a Profoundly Hindered Aryl−Aryl Single Bond Cameron L. Hilton, Jeremy M. Crowfoot, Pawel Rempala and Benjamin T. King pp 13392–13399 DOI: 10.1021/ja803396n Supporting Info

β-Lactams as Selective Chemical Probes for the in Vivo Labeling of Bacterial Enzymes Involved in Cell Wall Biosynthesis, Antibiotic Resistance, and Virulence Isabell Staub and Stephan A. Sieber pp 13400–13409 DOI: 10.1021/ja803349j Supporting Info

The Difference a Se Makes? Oxygen-Tolerant Hydrogen Production by the [NiFeSe]-Hydrogenase from Desulfomicrobium baculatum Alison Parkin, Gabrielle Goldet, Christine Cavazza, Juan C. Fontecilla-Camps and Fraser A. Armstrong pp 13410–13416 DOI: 10.1021/ja803657d Supporting Info

To Dope or Not To Dope: The Effect of Sonicating Single-Wall Carbon Nanotubes in Common Laboratory Solvents on Their Electronic Structure Kevin R. Moonoosawmy and Peter Kruse pp 13417–13424 DOI: 10.1021/ja8036788 Supporting Info

In Situ Observation of the Internal Structure and Composition of Biomineralized Emiliania huxleyi Calcite by Solid-State NMR Spectroscopy Ronen Gertman, Ira Ben Shir, Shifi Kababya and Asher Schmidt pp 13425–13432 DOI: 10.1021/ja803985d

Nanopatterning of Donor/Acceptor Hybrid Supramolecular Architectures on Highly Oriented Pyrolytic Graphite: A Scanning Tunneling Microscopy Study Ling Wang, Qing Chen, Ge-Bo Pan, Li-Jun Wan, Shiming Zhang, Xiaowei Zhan, Brian H. Northrop and Peter J. Stang pp 13433–13441 DOI: 10.1021/ja8040515 Supporting Info

Nanoscale Organization of Thiol and Arylsulfonic Acid on Silica Leads to a Highly Active and Selective Bifunctional, Heterogeneous Catalyst Eric L. Margelefsky, Anissa Bendjriou, Ryan K. Zeidan, Vronique Dufaud and Mark E. Davis pp 13442–13449 DOI: 10.1021/ja804082m Supporting Info

Foldamer Organogels: A Circular Dichroism Study of Glucose-Mediated Dynamic Helicity Induction and Amplification Wei Cai, Gui-Tao Wang, Ping Du, Ren-Xiao Wang, Xi-Kui Jiang and Zhan-Ting Li pp 13450–13459 DOI: 10.1021/ja8043322 Supporting Info

Competing Adsorption between Hydrated Peptides and Water onto Metal Surfaces: From Electronic to Conformational Properties Luca M. Ghiringhelli, Berk Hess, Nico F. A. van der Vegt and Luigi Delle Site pp 13460–13464 DOI: 10.1021/ja804350v

Atomic Contacts via Electrochemistry in Water/Cyclodextrin Media: A Step Toward Protected Atomic Contacts Yann R. Leroux, Claire Fave, Dodzi Zigah, Gaelle Trippe-Allard and Jean Christophe Lacroix pp 13465–13470 DOI: 10.1021/ja804680w Supporting Info

Synthesis and X-ray or NMR/DFT Structure Elucidation of Twenty-One New Trifluoromethyl Derivatives of Soluble Cage Isomers of C76, C78, C84, and C90 Ivan E. Kareev, Alexey A. Popov, Igor V. Kuvychko, Natalia B. Shustova, Sergey F. Lebedkin, Vyachevslav P. Bubnov, Oren P. Anderson, Konrad Seppelt, Steven H. Strauss and Olga V. Boltalina pp 13471–13489 DOI: 10.1021/ja8041614 Supporting Info

Magnetic Properties and Magnetic Structures of Synthetic Natrochalcites, NaMII2(D3O2)(MoO4)2, M = Co or Ni Serge Vilminot, Gilles Andr, Francoise Boure-Vigneron, Peter J. Baker, Stephen J. Blundell and Mohamedally Kurmoo pp 13490–13499 DOI: 10.1021/ja804685u Supporting Info

Oligonucleotide−Oligospermine Conjugates (Zip Nucleic Acids): A Convenient Means of Finely Tuning Hybridization Temperatures Rgis Noir, Mitsuharu Kotera, Bndicte Pons, Jean-Serge Remy and Jean-Paul Behr pp 13500–13505 DOI: 10.1021/ja804727a Supporting Info

Structure and Activity of Largazole, a Potent Antiproliferative Agent from the Floridian Marine Cyanobacterium Symploca sp. Kanchan Taori, Valerie J. Paul and Hendrik Luesch p 13506 DOI: 10.1021/ja806461e

Issue 41

Dynamic Kinetic Resolution of Racemic β-Haloalcohols: Direct Access to Enantioenriched Epoxides Robert M. Haak, Florian Berthiol, Thomas Jerphagnon, Arnaud J. A. Gayet, Chiara Tarabiono, Christiaan P. Postema, Vincent Ritleng, Michel Pfeffer, Dick B. Janssen, Adriaan J. Minnaard, Ben L. Feringa and Johannes G. de Vries pp 13508–13509 DOI: 10.1021/ja805128x Supporting Info

Binuclear Complexes Containing a Methylnickel Moiety: Relevance to Organonickel Intermediates in Acetyl Coenzyme A Synthase Catalysis William G. Dougherty, Krishnan Rangan, Molly J. O’Hagan, Glenn P. A. Yap and Charles G. Riordan pp 13510–13511 DOI: 10.1021/ja803795k Supporting Info

Binary and Gray-Scale Patterning of Chemical Functionality on Polymer Films Linjie Li, Meghan Driscoll, George Kumi, Ronald Hernandez, Karen J. Gaskell, Wolfgang Losert and John T. Fourkas pp 13512–13513 DOI: 10.1021/ja803999r Supporting Info

Multiple Peptide Conformations Give Rise to Similar Binding Affinities: Molecular Simulations of p53-MDM2 Shubhra Ghosh Dastidar, David P. Lane and Chandra S. Verma pp 13514–13515 DOI: 10.1021/ja804289g Supporting Info

Relating Pore Structure to Activity at the Subcrystal Level for ZSM-5: An Electron Backscattering Diffraction and Fluorescence Microscopy Study Maarten B. J. Roeffaers, Rob Ameloot, Anton-Jan Bons, Wilfried Mortier, Gert De Cremer, Ren de Kloe, Johan Hofkens, Dirk E. De Vos and Bert F. Sels pp 13516–13517 DOI: 10.1021/ja8048767 Supporting Info

Tetrazine Ligation: Fast Bioconjugation Based on Inverse-Electron-Demand Diels−Alder Reactivity Melissa L. Blackman, Maksim Royzen and Joseph M. Fox pp 13518–13519 DOI: 10.1021/ja8053805 Supporting Info

NMR Monitoring of Chain-Specific Stability in Heterotrimeric Collagen Peptides Balaraman Madhan, Jianxi Xiao, Geetha Thiagarajan, Jean Baum and Barbara Brodsky pp 13520–13521 DOI: 10.1021/ja805496v

Electronic Structure and Magnetism in Transition Metals Doped 8-Hydroxy-Quinoline Aluminum Jeong Min Baik, Yoon Shon, Seung Joo Lee, Yoon Hee Jeong, Tae Won Kang and Jong-Lam Lee pp 13522–13523 DOI: 10.1021/ja805276p Supporting Info

Enantioselective Organocatalytic Direct Michael Addition of Nitroalkanes to Nitroalkenes Promoted by a Unique Bifunctional DMAP-Thiourea Constantinos Rabalakos and William D. Wulff pp 13524–13525 DOI: 10.1021/ja805390k Supporting Info

Synthesis of Indoles via Domino Reaction of N-Aryl Amides and Ethyl Diazoacetate Sun-Liang Cui, Jing Wang and Yan-Guang Wang pp 13526–13527 DOI: 10.1021/ja805706r Supporting Info

Cu(I)-Catalyzed Regioselective Synthesis of Polysubstituted Furans from Propargylic Esters via Postulated (2-Furyl)carbene Complexes Jos Barluenga, Lorena Riesgo, Rubn Vicente, Luis A. Lpez and Miguel Toms pp 13528–13529 DOI: 10.1021/ja8058342 Supporting Info

From N-Alkylimidazole Ligands at a Rhenium Center: Ring Opening or Formation of NHC Complexes Miguel A. Huertos, Julio Prez, Luca Riera and Amador Menndez-Velzquez pp 13530–13531 DOI: 10.1021/ja805888f Supporting Info

Oxatriquinane and Oxatriquinacene: Extraordinary Oxonium Ions Mark Mascal, Nema Hafezi, Nabin K. Meher and James C. Fettinger pp 13532–13533 DOI: 10.1021/ja805686u Supporting Info

1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals Paulson Mathew, Antonia Neels and Martin Albrecht pp 13534–13535 DOI: 10.1021/ja805781s Supporting Info

From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond Shenglai Yao, Carsten Milsmann, Eckhard Bill, Karl Wieghardt and Matthias Driess pp 13536–13537 DOI: 10.1021/ja806101h Supporting Info

Dual Role of Alkynyl Halides in One-Step Synthesis of Alkynyl Epoxides Alexander Trofimov, Natalia Chernyak and Vladimir Gevorgyan pp 13538–13539 DOI: 10.1021/ja806178r Supporting Info

Multiplexed Multicolor Raman Imaging of Live Cells with Isotopically Modified Single Walled Carbon Nanotubes Zhuang Liu, Xiaolin Li, Scott M. Tabakman, Kaili Jiang, Shoushan Fan and Hongjie Dai pp 13540–13541 DOI: 10.1021/ja806242t Supporting Info

Intramolecular Anodic Olefin Coupling Reactions: The Use of a Nitrogen Trapping Group Hai-Chao Xu and Kevin D. Moeller pp 13542–13543 DOI: 10.1021/ja806259z Supporting Info

Natural Abundance Solution 13C NMR Studies of a Phototropin with Photoinduced Polarization Wolfgang Eisenreich, Monika Joshi, Stefan Weber, Adelbert Bacher and Markus Fischer pp 13544–13545 DOI: 10.1021/ja805856r Supporting Info

Turning a Scorpion Toxin into an Antitumor Miniprotein Chong Li, Min Liu, Juahdi Monbo, Guozhang Zou, Changqing Li, Weirong Yuan, Davide Zella, Wei-Yue Lu and Wuyuan Lu pp 13546–13548 DOI: 10.1021/ja8042036 Supporting Info

Thermal C1−C5 Diradical Cyclization of Enediynes Chandrasekhar Vavilala, Neal Byrne, Christina M. Kraml, Douglas M. Ho and Robert A. Pascal, pp 13549–13551 DOI: 10.1021/ja803413f Supporting Info

A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides Brett P. Fors, Donald A. Watson, Mark R. Biscoe and Stephen L. Buchwald pp 13552–13554 DOI: 10.1021/ja8055358 Supporting Info

A New Peptide-Based Method for the Design and Synthesis of Nanoparticle Superstructures: Construction of Highly Ordered Gold Nanoparticle Double Helices Chun-Long Chen, Peijun Zhang and Nathaniel L. Rosi pp 13555–13557 DOI: 10.1021/ja805683r Supporting Info

Interfacial Charge Recombination Between e−−TiO2 and the I−/I3− Electrolyte in Ruthenium Heteroleptic Complexes: Dye Molecular Structure−Open Circuit Voltage Relationship Anna Reynal, Amparo Forneli, Eugenia Martinez-Ferrero, Antonio Snchez-Daz, Antn Vidal-Ferran, Brian C. O’Regan and Emilio Palomares pp 13558–13567 DOI: 10.1021/ja800513m

Unambiguous Identification of Mbius Aromaticity for meso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1) Jeyaraman Sankar, Shigeki Mori, Shohei Saito, Harapriya Rath, Masaaki Suzuki, Yasuhide Inokuma, Hiroshi Shinokubo, Kil Suk Kim, Zin Seok Yoon, Jae-Yoon Shin, Jong Min Lim, Yoichi Matsuzaki, Osamu Matsushita, Atsuya Muranaka, Nagao Kobayashi, Dongho Kim and Atsuhiro Osuka pp 13568–13579 DOI: 10.1021/ja801983d Supporting Info

Pressure and Temperature Jump Relaxation Kinetics of the Conformational Change in Salmonella typhimurium Tryptophan Synthase l-Serine Complex: Large Activation Compressibility and Heat Capacity Changes Demonstrate the Contribution of Solvation Robert S. Phillips, Edith W. Miles, Peter McPhie, Stephane Marchal, Cdric Georges, Yves Dupont and Reinhard Lange pp 13580–13588 DOI: 10.1021/ja8018466

Hydration Contributions to Association in Polyelectrolyte Multilayers and Complexes: Visualizing Hydrophobicity Joseph B. Schlenoff, Amir H. Rmaile and Claudiu B. Bucur pp 13589–13597 DOI: 10.1021/ja802054k Supporting Info

Toward a Prostate Specific Antigen-Based Prostate Cancer Diagnostic Assay: Preparation of Keyhole Limpet Hemocyanin -Conjugated Normal and Transformed Prostate Specific Antigen Fragments Vadim Y. Dudkin, Justin S. Miller, Anna S. Dudkina, Christophe Antczak, David A. Scheinberg and Samuel J. Danishefsky pp 13598–13607 DOI: 10.1021/ja8028137 Supporting Info

Intramolecular O−H···O Hydrogen-Bond-Mediated Reversal in the Partitioning of Conformationally Restricted Triplet 1,4-Biradicals and Amplification of Diastereodifferentiation in Their Lifetimes Jarugu Narasimha Moorthy, Subhas Samanta, Apurba L. Koner, Satyajit Saha and Werner M. Nau pp 13608–13617 DOI: 10.1021/ja8032179 Supporting Info

Photoinduced Mechanism of Formation and Growth of Polycyclic Aromatic Hydrocarbons in Low-Temperature Environments via Successive Ethynyl Radical Additions Alexander M. Mebel, Vadim V. Kislov and Ralf I. Kaiser pp 13618–13629 DOI: 10.1021/ja804198a Supporting Info

A Versatile Amino Acid Analogue of the Solvatochromic Fluorophore 4-N,N-Dimethylamino-1,8-naphthalimide: A Powerful Tool for the Study of Dynamic Protein Interactions Galen Loving and Barbara Imperiali pp 13630–13638 DOI: 10.1021/ja804754y Supporting Info

Fluorine Substituted Adenosines As Probes of Nucleobase Protonation in Functional RNAs Ian T. Suydam and Scott A. Strobel pp 13639–13648 DOI: 10.1021/ja803336y Supporting Info

Water Phase Transition Induced by a Stone−Wales Defect in a Boron Nitride Nanotube Chang Y. Won and N. R. Aluru pp 13649–13652 DOI: 10.1021/ja803245d Supporting Info

Charge Recombination in Organic Photovoltaic Devices with High Open-Circuit Voltages Sebastian Westenhoff, Ian A. Howard, Justin M. Hodgkiss, Kiril R. Kirov, Hugo A. Bronstein, Charlotte K. Williams, Neil C. Greenham and Richard H. Friend pp 13653–13658 DOI: 10.1021/ja803054g Supporting Info

Vicinal Deuterium Perturbations on Hydrogen NMR Chemical Shifts in Cyclohexanes Daniel J. O’Leary, Damian G. Allis, Bruce S. Hudson, Shelly James, Katherine B. Morgera and John E. Baldwin pp 13659–13663 DOI: 10.1021/ja802903a Supporting Info

Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer Angiolina Comotti, Silvia Bracco, Piero Sozzani, Satoshi Horike, Ryotaro Matsuda, Jinxi Chen, Masaki Takata, Yoshiki Kubota and Susumu Kitagawa pp 13664–13672 DOI: 10.1021/ja802589u Supporting Info

Mechanistic Study of Protein Phosphatase-1 (PP1), A Catalytically Promiscuous Enzyme Claire McWhirter, Elizabeth A. Lund, Eric A. Tanifum, Guoqiang Feng, Qaiser I. Sheikh, Alvan C. Hengge and Nicholas H. Williams pp 13673–13682 DOI: 10.1021/ja803612z Supporting Info

Localization of Spin and Charge in Phenalenyl-Based Neutral Radical Conductors Robert C. Haddon, Arindam Sarkar, Sushanta K. Pal, Xiaoliu Chi, Mikhail E. Itkis and Fook S. Tham pp 13683–13690 DOI: 10.1021/ja8037307 Supporting Info

Self-Assembly of α-Helical Coiled Coil Nanofibers He Dong, Sergey E. Paramonov and Jeffrey D. Hartgerink pp 13691–13695 DOI: 10.1021/ja8037323 Supporting Info

Testing Geometrical Discrimination within an Enzyme Active Site: Constrained Hydrogen Bonding in the Ketosteroid Isomerase Oxyanion Hole Paul A. Sigala, Daniel A. Kraut, Jose M. M. Caaveiro, Brandon Pybus, Eliza A. Ruben, Dagmar Ringe, Gregory A. Petsko and Daniel Herschlag pp 13696–13708 DOI: 10.1021/ja803928m Supporting Info

Anionic Snieckus−Fries Rearrangement: Solvent Effects and Role of Mixed Aggregates Jason C. Riggs, Kanwal J. Singh, Ma Yun and David B. Collum pp 13709–13717 DOI: 10.1021/ja804087r Supporting Info

Organocuprate Conjugate Addition: Structural Features of Diastereomeric and Supramolecular π-Intermediates Wolfram Henze, Tobias Grtner and Ruth M. Gschwind pp 13718–13726 DOI: 10.1021/ja8041433 Supporting Info

Highly Stable Organic Monolayers for Reacting Silicon with Further Functionalities: The Effect of the C−C Bond nearest the Silicon Surface Sreenivasa Reddy Puniredd, Ossama Assad and Hossam Haick pp 13727–13734 DOI: 10.1021/ja804674z

Theoretical Study of the Oxygen Exchange in Uranyl Hydroxide. An Old Riddle Solved? Grigory A. Shamov and Georg Schreckenbach pp 13735–13744 DOI: 10.1021/ja804742f Supporting Info

Pd-Catalyzed Enantioselective Aerobic Oxidation of Secondary Alcohols: Applications to the Total Synthesis of Alkaloids Shyam Krishnan, Jeffrey T. Bagdanoff, David C. Ebner, Yeeman K. Ramtohul, Uttam K. Tambar and Brian M. Stoltz pp 13745–13754 DOI: 10.1021/ja804738b Supporting Info

Influence of Selectivity on the Supramolecular Polymerization of AB-Type Polymers Capable of Both A·A and A·B Interactions Tom F. A. de Greef, Gianfranco Ercolani, G. B. W. L. Ligthart, E. W. Meijer and Rint P. Sijbesma pp 13755–13764 DOI: 10.1021/ja8046409 Supporting Info

Total Syntheses of (+)- and (−)-Peribysin E Angie R. Angeles, Stephen P. Waters and Samuel J. Danishefsky pp 13765–13770 DOI: 10.1021/ja8048207 Supporting Info

Viewing Membrane-Bound Molecular Umbrellas by Parallax Analyses Masaharu Kondo, Mohamed Mehiri and Steven L. Regen pp 13771–13777 DOI: 10.1021/ja804929m Supporting Info

The Lyconadins: Enantioselective Total Syntheses of (+)-Lyconadin A and (−)-Lyconadin B Douglas C. Beshore and Amos B. Smith, pp 13778–13789 DOI: 10.1021/ja804939r Supporting Info

Expeditious Chemoenzymatic Synthesis of Homogeneous N-Glycoproteins Carrying Defined Oligosaccharide Ligands Hirofumi Ochiai, Wei Huang and Lai-Xi Wang pp 13790–13803 DOI: 10.1021/ja805044x Supporting Info

Rhodium-Catalyzed Hydroformylation of Cyclopropenes William M. Sherrill and Michael Rubin pp 13804–13809 DOI: 10.1021/ja805059f Supporting Info

Coherence Spectroscopy Investigations of the Low-Frequency Vibrations of Heme: Effects of Protein-Specific Perturbations Flaviu Gruia, Minoru Kubo, Xiong Ye, Dan Ionascu, Changyuan Lu, Robert K. Poole, Syun-Ru Yeh and Paul M. Champion p 13810 DOI: 10.1021/ja8067275

Detection of Trace Hg2+ via Induced Circular Dichroism of DNA Wrapped Around Single-Walled Carbon Nanotubes Xueyun Gao, Gengmei Xing, Yanlian Yang, Xiaoli Shi, Ru Liu, Weiguo Chu, Long Jing, Feng Zhao, Chang Ye, Hui Yuan, Xiaohong Fang, Chen Wang and Yuliang Zhao p 13810 DOI: 10.1021/ja8056453

Lewis Acid-Catalyzed Intermolecular [4 + 2] Cycloaddition of 3-Alkoxycyclobutanones to Aldehydes and Ketones Jun-ichi Matsuo, Shun Sasaki, Hiroyuki Tanaka and Hiroyuki Ishibashi p 13810 DOI: 10.1021/ja806907a

Issue 42

Prominent Electron Transport Property Observed for Triply Fused Metalloporphyrin Dimer: Directed Columnar Liquid Crystalline Assembly by Amphiphilic Molecular Design Tsuneaki Sakurai, Keyu Shi, Hiroshi Sato, Kentaro Tashiro, Atsuhiro Osuka, Akinori Saeki, Shu Seki, Seiichi Tagawa, Sono Sasaki, Hiroyasu Masunaga, Keiichi Osaka, Masaki Takata and Takuzo Aida pp 13812–13813 DOI: 10.1021/ja8030714 Supporting Info

Extraordinary Circularly Polarized Luminescence Activity Exhibited by Cesium Tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) Complexes in EtOH and CHCl3 Solutions Jamie L. Lunkley, Dai Shirotani, Kazuaki Yamanari, Sumio Kaizaki and Gilles Muller pp 13814–13815 DOI: 10.1021/ja805681w Supporting Info

Mechanistic Studies on the Reductive Cyclooligomerisation of CO by U(III) Mixed Sandwich Complexes; the Molecular Structure of [(U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)]2(μ-η1:η1-C2O2) Alistair S. Frey, F. Geoffrey N. Cloke, Peter B. Hitchcock, Iain J. Day, Jennifer C. Green and Georgina Aitken pp 13816–13817 DOI: 10.1021/ja8059792 Supporting Info

Enhanced Activity for Oxygen Reduction Reaction on “Pt3Co” Nanoparticles: Direct Evidence of Percolated and Sandwich-Segregation Structures Shuo Chen, Paulo J. Ferreira, Wenchao Sheng, Naoaki Yabuuchi, Lawrence F. Allard and Yang Shao-Horn pp 13818–13819 DOI: 10.1021/ja802513y Supporting Info

Bcl-XL-Templated Assembly of Its Own Protein−Protein Interaction Modulator from Fragments Decorated with Thio Acids and Sulfonyl Azides Xiangdong Hu, Jiazhi Sun, Hong-Gang Wang and Roman Manetsch pp 13820–13821 DOI: 10.1021/ja802683u Supporting Info

Bilayer in Small Bicelles Revealed by Lipid−Protein Interactions Using NMR Spectroscopy Donghan Lee, Korvin F. A. Walter, Ann-Kathrin Brckner, Christian Hilty, Stefan Becker and Christian Griesinger pp 13822–13823 DOI: 10.1021/ja803686p Supporting Info

Catalytic Use of Indium(0) for Carbon−Carbon Bond Transformations in Water: General Catalytic Allylations of Ketones with Allylboronates Uwe Schneider, Masaharu Ueno and Sh Kobayashi pp 13824–13825 DOI: 10.1021/ja804182j Supporting Info

A Bifunctional Monomer Derived from Lactide for Toughening Polylactide Feng Jing and Marc A. Hillmyer pp 13826–13827 DOI: 10.1021/ja804357u Supporting Info

Struture Stability and Compressibility of Iron-Based Superconductor Nd(O0.88F0.12)FeAs under High Pressure Jinggeng Zhao, Luhong Wang, Dawei Dong, Zhiguo Liu, Haozhe Liu, Genfu Chen, Dan Wu, Jianlin Luo, Nanlin Wang, Yong Yu, Changqing Jin and Quanzhong Guo pp 13828–13829 DOI: 10.1021/ja804229k

Oxygen Atom Transfer from Nitrite Mediated by Fe(III) Porphyrins in Aqueous Solution Chosu Khin, Julie Heinecke and Peter C. Ford pp 13830–13831 DOI: 10.1021/ja804520y Supporting Info

Formation and Spectroscopy of a Tryptophan Radical Containing Peptide in the Gas Phase Laure Joly, Rodolphe Antoine, Abdul-Rahman Allouche and Philippe Dugourd pp 13832–13833 DOI: 10.1021/ja804508d Supporting Info

Chirality-Controlled and Solvent-Templated Catenation Isomerism in Metal−Organic Frameworks Liqing Ma and Wenbin Lin pp 13834–13835 DOI: 10.1021/ja804944r Supporting Info

Origin of Enantioselectivity in CF3−PIP-Catalyzed Kinetic Resolution of Secondary Benzylic Alcohols Ximin Li, Peng Liu, K. N. Houk and Vladimir B. Birman pp 13836–13837 DOI: 10.1021/ja805275s Supporting Info

Networking of Calixcrowns: From Heteronuclear Endo/Exocyclic Coordination Polymers to A Photoluminescence Switch Jai Young Lee, Hyun Jee Kim, Jong Hwa Jung, Wonbo Sim and Shim Sung Lee pp 13838–13839 DOI: 10.1021/ja805337n Supporting Info

One-Dimensional Optoelectronic Nanostructures Derived from the Aqueous Self-Assembly of π-Conjugated Oligopeptides Stephen R. Diegelmann, Justin M. Gorham and John D. Tovar pp 13840–13841 DOI: 10.1021/ja805491d Supporting Info

Design of Liquid Crystals with “de Vries-Like” Properties: Organosiloxane Mesogen with a 5-Phenylpyrimidine Core Jeffrey C. Roberts, Nadia Kapernaum, Frank Giesselmann and Robert P. Lemieux pp 13842–13843 DOI: 10.1021/ja805672q Supporting Info

Realization of SOMO−HOMO Level Conversion for a TEMPO-Dithiolate Ligand by Coordination to Platinum(II) Tetsuro Kusamoto, Shoko Kume and Hiroshi Nishihara pp 13844–13845 DOI: 10.1021/ja805751h Supporting Info

Two-Coordinate d9 Complexes. Synthesis and Oxidation of NHC Nickel(I) Amides Carl A. Laskowski and Gregory L. Hillhouse pp 13846–13847 DOI: 10.1021/ja805804s Supporting Info

Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature Tokutaro Ogata and John F. Hartwig pp 13848–13849 DOI: 10.1021/ja805810p Supporting Info

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Jasmina Hafizovic Cavka, Søren Jakobsen, Unni Olsbye, Nathalie Guillou, Carlo Lamberti, Silvia Bordiga and Karl Petter Lillerud pp 13850–13851 DOI: 10.1021/ja8057953 Supporting Info

Integrative Self-Sorting: Construction of a Cascade-Stoppered Hetero[3]rotaxane Wei Jiang, Henrik D. F. Winkler and Christoph A. Schalley pp 13852–13853 DOI: 10.1021/ja806009d Supporting Info

Polymeric PARACEST Agents for Enhancing MRI Contrast Sensitivity Yunkou Wu, Youfu Zhou, Olivier Ouari, Mark Woods, Piyu Zhao, Todd C. Soesbe, Garry E. Kiefer and A. Dean Sherry pp 13854–13855 DOI: 10.1021/ja805775u Supporting Info

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne Takahiro Sasamori, Koji Hironaka, Yusuke Sugiyama, Nozomi Takagi, Shigeru Nagase, Yoshinobu Hosoi, Yukio Furukawa and Norihiro Tokitoh pp 13856–13857 DOI: 10.1021/ja8061002 Supporting Info

An Extraordinary Cylinder-to-Cylinder Transition in the Aqueous Assemblies of Fluorescently Labeled Rod−Coil Amphiphiles Kyung-Hee Han, Eunji Lee, Jong Seung Kim and Byoung-Ki Cho pp 13858–13859 DOI: 10.1021/ja806128e Supporting Info

Molecular Recognition of Chiral Conformers: A Rotational Study of the Dimers of Glycidol Assimo Maris, Barbara M. Giuliano, Daria Bonazzi and Walther Caminati pp 13860–13861 DOI: 10.1021/ja8057887 Supporting Info

Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β2-Amino Acids Nolwenn J. A. Martin, Xu Cheng and Benjamin List pp 13862–13863 DOI: 10.1021/ja8069852 Supporting Info

Acid Promoted Cinnamyl Ion Mobility within Peptide Derived Macrocycles Hongda Zhao, Lidet Negash, Qi Wei, Thomas G. LaCour, Sandi Jo Estill, Emanuela Capota, Andrew A. Pieper and Patrick G. Harran pp 13864–13866 DOI: 10.1021/ja803299h Supporting Info

How the π Conjugation Length Affects the Fluorescence Emission Efficiency Yoshihiro Yamaguchi, Yoshio Matsubara, Takanori Ochi, Tateaki Wakamiya and Zen-ichi Yoshida pp 13867–13869 DOI: 10.1021/ja8040493 Supporting Info

Enzyme-like Acceleration for the Hydrolysis of a DNA Model Promoted by a Dinuclear Zn(II) Catalyst in Dilute Aqueous Ethanol C. Tony Liu, Alexei A. Neverov and R. Stan Brown pp 13870–13872 DOI: 10.1021/ja805801j Supporting Info

Total Synthesis of (+)-Lepadin B: Stereoselective Synthesis of Nonracemic Polysubstituted Hydroquinolines Using an RC-ROM Process Guillaume Barbe and Andr B. Charette pp 13873–13875 DOI: 10.1021/ja8068215 Supporting Info

Probing the Self-Assembly of Inorganic Cluster Architectures in Solution with Cryospray Mass Spectrometry: Growth of Polyoxomolybdate Clusters and Polymers Mediated by Silver(I) Ions Elizabeth F. Wilson, Hamera Abbas, Bridgette J. Duncombe, Carsten Streb, De-Liang Long and Leroy Cronin pp 13876–13884 DOI: 10.1021/ja802514q Supporting Info

Mechanism of Photocatalytic Water Splitting in TiO2. Reaction of Water with Photoholes, Importance of Charge Carrier Dynamics, and Evidence for Four-Hole Chemistry Junwang Tang, James R. Durrant and David R. Klug pp 13885–13891 DOI: 10.1021/ja8034637 Supporting Info

Deeper Insight into the Mechanism of the Reaction of Photogenerated Metallaketenes and Imines Israel Fernndez, Miguel A. Sierra, Mara J. Mancheo, Mar Gmez-Gallego and Fernando P. Cosso pp 13892–13899 DOI: 10.1021/ja8024406 Supporting Info

Gd5−xYxTt4 (Tt = Si or Ge): Effect of Metal Substitution on Structure, Bonding, and Magnetism Sumohan Misra and Gordon J. Miller pp 13900–13911 DOI: 10.1021/ja802848r Supporting Info

Stoichiometric Zirconium Oxide Cations as Potential Building Blocks for Cluster Assembled Catalysts Grant E. Johnson, Roland Mitri, Eric C. Tyo, Vlasta Bonai-Kouteck and A. W. Castleman, pp 13912–13920 DOI: 10.1021/ja803246n

Dynamic Allosteric Control of Noncovalent DNA Catalysis Reactions David Yu Zhang and Erik Winfree pp 13921–13926 DOI: 10.1021/ja803318t

Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast Vibrational Spectroscopy Wei Zhao, David E. Moilanen, Emily E. Fenn and Michael D. Fayer pp 13927–13937 DOI: 10.1021/ja803252y

The Unfolded Ensemble and Folding Mechanism of the C-Terminal GB1 β-Hairpin Massimiliano Bonomi, Davide Branduardi, Francesco L. Gervasio and Michele Parrinello pp 13938–13944 DOI: 10.1021/ja803652f Supporting Info

Charge-Transfer and Spin Dynamics in DNA Hairpin Conjugates with Perylenediimide as a Base-Pair Surrogate Tarek A. Zeidan, Raanan Carmieli, Richard F. Kelley, Thea M. Wilson, Frederick D. Lewis and Michael R. Wasielewski pp 13945–13955 DOI: 10.1021/ja803765r Supporting Info

Charge-Transfer-Based Mechanism for Half-Metallicity and Ferromagnetism in One-Dimensional Organometallic Sandwich Molecular Wires Lei Shen, Shuo-Wang Yang, Man-Fai Ng, Valeri Ligatchev, Liping Zhou and Yuanping Feng pp 13956–13960 DOI: 10.1021/ja804053a

Light-Induced Excited-State Spin Trapping in Tetrazole-Based Spin Crossover Systems Beln Ordejn, Coen de Graaf and Carmen Sousa pp 13961–13968 DOI: 10.1021/ja804506h Supporting Info

Orchestration of Concurrent Oxidation and Reduction Cycles for Stereoinversion and Deracemisation of sec-Alcohols Constance V. Voss, Christian C. Gruber, Kurt Faber, Tanja Knaus, Peter Macheroux and Wolfgang Kroutil pp 13969–13972 DOI: 10.1021/ja804816a Supporting Info

Glycine Exists Mainly as Monomers, Not Dimers, in Supersaturated Aqueous Solutions: Implications for Understanding Its Crystallization and Polymorphism Jun Huang, Thomas C. Stringfellow and Lian Yu pp 13973–13980 DOI: 10.1021/ja804836d

Entropy- and Hydrolytic-Driven Positional Switching of Macrocycle between Imine- and Hydrogen-Bonding Stations in Rotaxane-Based Molecular Shuttles Takeshi Umehara, Hidetoshi Kawai, Kenshu Fujiwara and Takanori Suzuki pp 13981–13988 DOI: 10.1021/ja804888b Supporting Info

Total Synthesis of (+)-Cassaine via Transannular Diels−Alder Reaction Serge Phoenix, Maddi Sridhar Reddy and Pierre Deslongchamps pp 13989–13995 DOI: 10.1021/ja805097s Supporting Info

Putting Ammonia into a Chemically Opened Fullerene Keith E. Whitener, , Michael Frunzi, Sho-ichi Iwamatsu, Shizuaki Murata, R. James Cross and Martin Saunders pp 13996–13999 DOI: 10.1021/ja805579m Supporting Info

Salt-Specific Stability and Denaturation of a Short Salt-Bridge-Forming α-Helix Joachim Dzubiella pp 14000–14007 DOI: 10.1021/ja805562g

Sequence- and Chain-Length-Specific Complementary Double-Helix Formation Hiroshi Ito, Yoshio Furusho, Toshihide Hasegawa and Eiji Yashima pp 14008–14015 DOI: 10.1021/ja806194e Supporting Info

A Valence Bond Modeling of Trends in Hydrogen Abstraction Barriers and Transition States of Hydroxylation Reactions Catalyzed by Cytochrome P450 Enzymes Sason Shaik, Devesh Kumar and Sam P. de Visser p 14016 DOI: 10.1021/ja806917f

An Expedient Asymmetric Synthesis of Platencin K. C. Nicolaou, Qiao-Yan Toh and David Y.-K. Chen p 14016 DOI: 10.1021/ja806849z

Book Review of Ribozymes and RNA Catalysis Victoria J. DeRose p 14017 DOI: 10.1021/ja806587z

Book Review of Organic Synthesis: State of the Art 2005−2007 pp 14017–14018 DOI: 10.1021/ja806854z

Book Review of Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications, Volumes 1−3 David S. Glueck p 14018 DOI: 10.1021/ja8067758

Book Review of The Inorganic Radiochemistry of Heavy Elements: Methods for Studying Gaseous Compounds Gregory R. Choppin pp 14018–14019 DOI: 10.1021/ja807013h

Book Review of Nanomaterials Chemistry: Recent Developments and New Directions Richard D. Adams p 14019 DOI: 10.1021/ja806755n

Book Review of Annual Review of Materials Research. Volume 38, 2008 p 14019 DOI: 10.1021/ja807114v

Book Review of DNA Interactions with Polymers and Surfactants Tatiana Segura pp 14019–14020 DOI: 10.1021/ja807118r

Book Review of Carbons and Carbon Supported Catalysts in Hydroprocessing p 14020 DOI: 10.1021/ja807116w

Book Review of Organic Nanostructures Prashant V. Kamat p 14020 DOI: 10.1021/ja8072935

Issue 43

Biosynthesis of (−)-(1S,2R)-Allocoronamic Acyl Thioester by an FeII-Dependent Halogenase and a Cyclopropane-Forming Flavoprotein Christopher S. Neumann and Christopher T. Walsh pp 14022–14023 DOI: 10.1021/ja8064667 Supporting Info

Tandem Action of the O2- and FADH2-Dependent Halogenases KtzQ and KtzR Produce 6,7-Dichlorotryptophan for Kutzneride Assembly John R. Heemstra, and Christopher T. Walsh pp 14024–14025 DOI: 10.1021/ja806467a Supporting Info

Structure Sensitivity of Carbon−Nitrogen Ring Opening: Impact of Platinum Particle Size from below 1 to 5 nm upon Pyrrole Hydrogenation Product Selectivity over Monodisperse Platinum Nanoparticles Loaded onto Mesoporous Silica John N. Kuhn, Wenyu Huang, Chia-Kuang Tsung, Yawen Zhang and Gabor A. Somorjai pp 14026–14027 DOI: 10.1021/ja805050c Supporting Info

Raman Spectroscopy Shows Interchain through Space Charge Delocalization in a Mixed Valence Oligothiophene Cation and in Its π-Dimeric Biradicaloid Dication Juan Casado, Kazuo Takimiya, Tetsuo Otsubo, Francisco J. Ramírez, J. Joaquín Quirante, Rocío Ponce Ortiz, Sandra R. Gonzlez, María Moreno Oliva and Juan T. Lpez Navarrete pp 14028–14029 DOI: 10.1021/ja806207j Supporting Info

2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations Arnaud Voituriez, Armen Panossian, Nicolas Fleury-Brgeot, Pascal Retailleau and Angela Marinetti pp 14030–14031 DOI: 10.1021/ja806060a Supporting Info

Polymorphism of a Hexa-host: Isolation of Four Different Single-Crystal Phases by Melt Crystallization Dinabandhu Das and Leonard J. Barbour pp 14032–14033 DOI: 10.1021/ja804940v Supporting Info

Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes Nicole Blaquiere, Sarah Diallo-Garcia, Serge I. Gorelsky, Daniel A. Black and Keith Fagnou pp 14034–14035 DOI: 10.1021/ja804235t Supporting Info

Trigger Mechanism for the Catalytic Hydrogen Activation by Monoiron (Iron−Sulfur Cluster-Free) Hydrogenase Xinzheng Yang and Michael B. Hall pp 14036–14037 DOI: 10.1021/ja804364p Supporting Info

Synthesis of Hexagonal Nickel Hydroxide Nanosheets by Exfoliation of Layered Nickel Hydroxide Intercalated with Dodecyl Sulfate Ions Shintaro Ida, Daisuke Shiga, Michio Koinuma and Yasumichi Matsumoto pp 14038–14039 DOI: 10.1021/ja804397n Supporting Info

Correlation of Molecular Orientation and Packing Density in a dsDNA Self-Assembled Monolayer Observable with Surface-Enhanced Raman Spectroscopy Aoune Barhoumi, Dongmao Zhang and Naomi J. Halas pp 14040–14041 DOI: 10.1021/ja804367c Supporting Info

On-Wire Conversion Chemistry: Engineering Solid-State Complexity into Striped Metal Nanowires using Solution Chemistry Reactions Mary E. Anderson, Matthew R. Buck, Ian T. Sines, Karl D. Oyler and Raymond E. Schaak pp 14042–14043 DOI: 10.1021/ja804743b Supporting Info

Patterning Reactive Microdomains inside Polydimethylsiloxane Microchannels by Trapping and Melting Functional Polymer Particles Masashi Yamamoto, Masumi Yamada, Nobuhiro Nonaka, Shizuka Fukushima, Masahiro Yasuda and Minoru Seki pp 14044–14045 DOI: 10.1021/ja804803s Supporting Info

N2 Hydrogenation from Activated End-On Bis(indenyl) Zirconium Dinitrogen Complexes Doris Pun, Christopher A. Bradley, Emil Lobkovsky, Ivan Keresztes and Paul J. Chirik pp 14046–14047 DOI: 10.1021/ja8048332 Supporting Info

An Unexpected Diethyl Azodicarboxylate-Promoted Dehydrogenation of Tertiaryamine and Tandem Reaction with Sulfonyl Azide Xiaoliang Xu, Xiaonian Li, Lei Ma, Ning Ye and Bojie Weng pp 14048–14049 DOI: 10.1021/ja8047514 Supporting Info

Mechanism of Enzymatic Birch Reduction: Stereochemical Course and Exchange Reactions of Benzoyl-CoA Reductase Brbel Thiele, Oliver Rieder, Bernard T. Golding, Michael Mller and Matthias Boll pp 14050–14051 DOI: 10.1021/ja805091w Supporting Info

Nickel-Catalyzed Enantioselective Alkylative Coupling of Alkynes and Aldehydes: Synthesis of Chiral Allylic Alcohols with Tetrasubstituted Olefins Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou and Qi-Lin Zhou pp 14052–14053 DOI: 10.1021/ja805296k Supporting Info

Fabrication of Surface-Supported Low-Dimensional Polyimide Networks Matthias Treier, Neville V. Richardson and Roman Fasel pp 14054–14055 DOI: 10.1021/ja805342n Supporting Info

A High-Affinity Metal-Binding Peptide from Escherichia coli HypB Kim C. Chan Chung, Li Cao, Alistair V. Dias, Ingrid J. Pickering, Graham N. George and Deborah B. Zamble pp 14056–14057 DOI: 10.1021/ja8055003 Supporting Info

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions Masayuki Wasa and Jin-Quan Yu pp 14058–14059 DOI: 10.1021/ja807129e Supporting Info

Dynamics of Ligand Binding from 13C NMR Relaxation Dispersion at Natural Abundance John S. Zintsmaster, Brian D. Wilson and Jeffrey W. Peng pp 14060–14061 DOI: 10.1021/ja805839y Supporting Info

Synthesis of Cp−Re Complexes via Olefinic C−H Activation and Successive Formation of Cyclopentadienes Yoichiro Kuninobu, Yuta Nishina, Takashi Matsuki and Kazuhiko Takai pp 14062–14063 DOI: 10.1021/ja805921f Supporting Info

A Metal−Organic Nanotube Exhibiting Reversible Adsorption of (H2O)12 Cluster Fangna Dai, Haiyan He and Daofeng Sun pp 14064–14065 DOI: 10.1021/ja805920t Supporting Info

Catalytic Asymmetric Intermolecular Stetter Reaction of Glyoxamides with Alkylidenemalonates Qin Liu, Stphane Perreault and Tomislav Rovis pp 14066–14067 DOI: 10.1021/ja805680z Supporting Info

Isolated Peptidoglycan Glycosyltransferases from Different Organisms Produce Different Glycan Chain Lengths Tsung-Shing Andrew Wang, Sara Aviva Manning, Suzanne Walker and Daniel Kahne pp 14068–14069 DOI: 10.1021/ja806016y Supporting Info

From the X-ray Compact Structure to the Elongated Form of the Full-Length MMP-2 Enzyme in Solution: A Molecular Dynamics Study Natalia Daz, Dimas Surez and Haydee Valds pp 14070–14071 DOI: 10.1021/ja806090v Supporting Info

“Naked” Iron-5,10,15-triphenylcorrole on Cu(111): Observation of Chirality on a Surface and Manipulation of Multiple Conformational States by STM Stefan Kuck, Germar Hoffmann, Martin Brring, Martin Fechtel, Markus Funk and Roland Wiesendanger pp 14072–14073 DOI: 10.1021/ja8059478 Supporting Info

Click-Type Reaction of Aromatic Polyamines for Improvement of Thermal and Optoelectronic Properties Tsuyoshi Michinobu pp 14074–14075 DOI: 10.1021/ja8061612 Supporting Info

Selective Detection of Protein Crystals by Second Harmonic Microscopy Ronald D. Wampler, David J. Kissick, Christopher J. Dehen, Ellen J. Gualtieri, Jessica L. Grey, Hai-Feng Wang, David H. Thompson, Ji-Xin Cheng and Garth J. Simpson pp 14076–14077 DOI: 10.1021/ja805983b Supporting Info

Reactions of Strained Hydrocarbons with Alkene and Alkyne Metathesis Catalysts Matthew Carnes, Daniela Buccella, Theo Siegrist, Michael L. Steigerwald and Colin Nuckolls pp 14078–14079 DOI: 10.1021/ja806351m Supporting Info

Relative Stability of Helices Determines the Folding Landscape of Adenine Riboswitch Aptamers Jong-Chin Lin and D. Thirumalai pp 14080–14081 DOI: 10.1021/ja8063638 Supporting Info

Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds Ramesh Giri and Jin-Quan Yu pp 14082–14083 DOI: 10.1021/ja8063827 Supporting Info

Multistep Synthesis of Complex Boronic Acids from Simple MIDA Boronates Eric P. Gillis and Martin D. Burke pp 14084–14085 DOI: 10.1021/ja8063759 Supporting Info

An Efficient Methyltrioxorhenium(VII)-Catalyzed Transformation of Hydrotrioxides (ROOOH) into Dihydrogen Trioxide (HOOOH) Ana Bergant, Janez Cerkovnik, Boo Plesniar and Tell Tuttle pp 14086–14087 DOI: 10.1021/ja806411a Supporting Info

Chiral Tetraaminophosphonium Carboxylate-Catalyzed Direct Mannich-Type Reaction Daisuke Uraguchi, Yusuke Ueki and Takashi Ooi pp 14088–14089 DOI: 10.1021/ja806311e Supporting Info

Catalytic Intermolecular Allylic CH Alkylation Andrew J. Young and M. Christina White pp 14090–14091 DOI: 10.1021/ja806867p Supporting Info

Strategy for Employing Unstabilized Nucleophiles in Palladium-Catalyzed Asymmetric Allylic Alkylations Barry M. Trost and David A. Thaisrivongs pp 14092–14093 DOI: 10.1021/ja806781u Supporting Info

Ruthenium Hydride-Catalyzed Addition of Aldehydes to Dienes Leading to β,γ-Unsaturated Ketones Sohei Omura, Takahide Fukuyama, Jiro Horiguchi, Yuji Murakami and Ilhyong Ryu pp 14094–14095 DOI: 10.1021/ja806929y Supporting Info

Isomerization in Fluorescent Protein Chromophores Involves Addition/Elimination Jian Dong, Fardokht Abulwerdi, Anthony Baldridge, Janusz Kowalik, Kyril M. Solntsev and Laren M. Tolbert pp 14096–14098 DOI: 10.1021/ja803416h Supporting Info

Chiral Periodic Mesoporous Organosilicates Based on Axially Chiral Monomers: Transmission of Chirality in the Solid State Stephanie MacQuarrie, Matthew P. Thompson, Alexandre Blanc, Nicholas J. Mosey, Robert P. Lemieux and Cathleen M. Crudden pp 14099–14101 DOI: 10.1021/ja804866e Supporting Info

Constructing Highly Conducting Metal−Metal Bonded Solids by Electrocrystallization of [PtII2(RCS2)4] (RCS2− = Dithiocarboxylato, R = Methyl or Ethyl) Minoru Mitsumi, Hidekazu Ueda, Kazumi Furukawa, Yoshiki Ozawa, Koshiro Toriumi and Mohamedally Kurmoo pp 14102–14104 DOI: 10.1021/ja805794a Supporting Info

Femtosecond Time-Resolved Optical and Raman Spectroscopy of Photoinduced Spin Crossover: Temporal Resolution of Low-to-High Spin Optical Switching Amanda L. Smeigh, Mark Creelman, Richard A. Mathies and James K. McCusker pp 14105–14107 DOI: 10.1021/ja805949s Supporting Info

Pseudomorphic Transformation of Highly Ordered Mesoporous Co3O4 to CoO via Reduction with Glycerol Harun Tysz, Yong Liu, Claudia Weidenthaler and Ferdi Schth pp 14108–14110 DOI: 10.1021/ja806202v Supporting Info

A Global Metabolite Profiling Approach to Identify Protein−Metabolite Interactions Ranitendranath Tagore, Horatio R. Thomas, Edwin A. Homan, Ali Munawar and Alan Saghatelian pp 14111–14113 DOI: 10.1021/ja806463c Supporting Info

Semiconducting Tellurium−Iron−Copper Carbonyl Polymers Minghuey Shieh, Chia-Hua Ho, Wen-Shyan Sheu, Bo-Gaun Chen, Yen-Yi Chu, Chia-Yeh Miu, Hsiang-Lin Liu and Chih-Chiang Shen pp 14114–14116 DOI: 10.1021/ja8065623 Supporting Info

Molecular Tweezers for Hydrogen: Synthesis, Characterization, and Reactivity Victor Sumerin, Felix Schulz, Michiko Atsumi, Cong Wang, Martin Nieger, Markku Leskel, Timo Repo, Pekka Pyykk and Bernhard Rieger pp 14117–14119 DOI: 10.1021/ja806627s Supporting Info

Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C−C Bond-Forming Transfer Hydrogenation: Synthesis of β,γ-Unsaturated Ketones Fumitoshi Shibahara, John F. Bower and Michael J. Krische pp 14120–14122 DOI: 10.1021/ja805356j Supporting Info

Imaging Induction of Cytoprotective Enzymes in Intact Human Cells: Coumberone, a Metabolic Reporter for Human AKR1C Enzymes Reveals Activation by Panaxytriol, an Active Component of Red Ginseng Marlin Halim, Dominic J. Yee and Dalibor Sames pp 14123–14128 DOI: 10.1021/ja801245y Supporting Info

Substrate-Promoted Formation of a Catalytically Competent Binuclear Center and Regulation of Reactivity in a Glycerophosphodiesterase from Enterobacter aerogenes Kieran S. Hadler, Eric A. Tanifum, Sylvia Hsu-Chen Yip, Nataa Miti, Luke W. Guddat, Colin J. Jackson, Lawrence R. Gahan, Kelly Nguyen, Paul D. Carr, David L. Ollis, Alvan C. Hengge, James A. Larrabee and Gerhard Schenk pp 14129–14138 DOI: 10.1021/ja803346w Supporting Info

Multiplexed Screening of Cellular Uptake of Gold Nanoparticles Using Laser Desorption/Ionization Mass Spectrometry Zheng-Jiang Zhu, Partha S. Ghosh, Oscar R. Miranda, Richard W. Vachet and Vincent M. Rotello pp 14139–14143 DOI: 10.1021/ja805392f Supporting Info

Importance of the Number of Acid Molecules and the Strength of the Base for Double-Ion Formation in (H2SO4)m·Base·(H2O)6 Clusters Kelly E. Anderson, J. Ilja Siepmann, Peter H. McMurry and Joost VandeVondele pp 14144–14147 DOI: 10.1021/ja8019774

Peptide Synthesis in Aqueous Environments: The Role of Extreme Conditions on Amino Acid Activation Nisanth N. Nair, Eduard Schreiner and Dominik Marx pp 14148–14160 DOI: 10.1021/ja802370c

Diverse Polymorphism of G-Quadruplexes as a Kinetic Phenomenon Iztok Prislan, Jurij Lah and Gorazd Vesnaver pp 14161–14169 DOI: 10.1021/ja8026604 Supporting Info

Selective Adsorption and Separation of ortho-Substituted Alkylaromatics with the Microporous Aluminum Terephthalate MIL-53 Luc Alaerts, Michael Maes, Lars Giebeler, Pierre A. Jacobs, Johan A. Martens, Joeri F. M. Denayer, Christine E. A. Kirschhock and Dirk E. De Vos pp 14170–14178 DOI: 10.1021/ja802761z Supporting Info

Microsolvation and 13C−Li NMR Coupling Rudolf Knorr, Thomas Menke, Kathrin Ferchland, Johann Mehlstubl and David S. Stephenson pp 14179–14188 DOI: 10.1021/ja8026828 Supporting Info

Rational Tuning of the Thiolate Donor in Model Complexes of Superoxide Reductase: Direct Evidence for a trans Influence in FeIII−OOR Complexes Frances Namuswe, Gary D. Kasper, Amy A. Narducci Sarjeant, Takahiro Hayashi, Courtney M. Krest, Michael T. Green, Pierre Monne-Loccoz and David P. Goldberg pp 14189–14200 DOI: 10.1021/ja8031828 Supporting Info

Postsynthesis Racemization and Place Exchange Reactions. Another Step To Unravel the Origin of Chirality for Chiral Ligand-Capped Gold Nanoparticles Hao Qi and Torsten Hegmann pp 14201–14206 DOI: 10.1021/ja8032444 Supporting Info

Role of the Zn1 and Zn2 sites in Metallo-β-lactamase L1 Zhenxin Hu, Gopalraj Periyannan, Brian Bennett and Michael W. Crowder pp 14207–14216 DOI: 10.1021/ja8035916

Highly Sensitive and Selective Colorimetric Sensors for Uranyl (UO22+): Development and Comparison of Labeled and Label-Free DNAzyme-Gold Nanoparticle Systems Jung Heon Lee, Zidong Wang, Juewen Liu and Yi Lu pp 14217–14226 DOI: 10.1021/ja803607z Supporting Info

Selective Photochemical Functionalization of Surfactant-Dispersed Single Wall Carbon Nanotubes in Water Noe T. Alvarez, Carter Kittrell, Howard K. Schmidt, Robert H. Hauge, Paul S. Engel and James M. Tour pp 14227–14233 DOI: 10.1021/ja804164y

Stereochemical Determination and Complex Biosynthetic Assembly of Etnangien, a Highly Potent RNA Polymerase Inhibitor from the Myxobacterium Sorangium cellulosum Dirk Menche, Fatih Arikan, Olena Perlova, Nicole Horstmann, Wiebke Ahlbrecht, Silke C. Wenzel, Rolf Jansen, Herbert Irschik and Rolf Mller pp 14234–14243 DOI: 10.1021/ja804194c Supporting Info

Optically Transparent, Amphiphilic Networks Based on Blends of Perfluoropolyethers and Poly(ethylene glycol) Zhaokang Hu, Liang Chen, Douglas E. Betts, Ashish Pandya, Marc A. Hillmyer and Joseph M. DeSimone pp 14244–14252 DOI: 10.1021/ja803991n

Folding of Elongated Proteins: Conventional or Anomalous? Tzachi Hagai and Yaakov Levy pp 14253–14262 DOI: 10.1021/ja804280p Supporting Info

Corrole−Fullerene Dyads: Formation of Long-Lived Charge-Separated States in Nonpolar Solvents Francis DSouza, Raghu Chitta, Kei Ohkubo, Mariusz Tasior, Navaneetha K. Subbaiyan, Melvin E. Zandler, Maciek K. Rogacki, Daniel T. Gryko and Shunichi Fukuzumi pp 14263–14272 DOI: 10.1021/ja804665y Supporting Info

Silica−Void−Gold Nanoparticles: Temporally Stable Surface-Enhanced Raman Scattering Substrates Maryuri Roca and Amanda J. Haes pp 14273–14279 DOI: 10.1021/ja8059039

NMR-Based Mapping of Disulfide Bridges in Cysteine-Rich Peptides: Application to the μ-Conotoxin SxIIIA Aleksandra Walewska, Jack J. Skalicky, Darrell R. Davis, Min-Min Zhang, Estuardo Lopez-Vera, Maren Watkins, Tiffany S. Han, Doju Yoshikami, Baldomero M. Olivera and Grzegorz Bulaj pp 14280–14286 DOI: 10.1021/ja804303p Supporting Info

Stacking and Not Solely Topology of T3 Loops Controls Rigidity and Ammonium Ion Movement within d(G4T3G4)2 G-Quadruplex Peter Podbevek, Primo ket and Janez Plavec pp 14287–14293 DOI: 10.1021/ja8048282

Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks Franois-Xavier Coudert, Marie Jeffroy, Alain H. Fuchs, Anne Boutin and Caroline Mellot-Draznieks pp 14294–14302 DOI: 10.1021/ja805129c Supporting Info

Reversible Oxidative Addition and Reductive Elimination of Fluorinated Disulfides at Gold(I) Thiolate Complexes: A New Ligand Exchange Mechanism Robert E. Bachman, Sheri A. Bodolosky-Bettis, Chelsea J. Pyle and Margaret Anne Gray pp 14303–14310 DOI: 10.1021/ja805266r Supporting Info

Highly Selective Synthesis of the Ring-B Reduced Chlorins by Ferric Chloride-Mediated Oxidation of Bacteriochlorins: Effects of the Fused Imide vs Isocyclic Ring on Photophysical and Electrochemical Properties Chao Liu, Mahabeer P. Dobhal, Manivannan Ethirajan, Joseph R. Missert, Ravindra K. Pandey, Sathyamangalam Balasubramanian, Dinesh K. Sukumaran, Min Zhang, Karl M. Kadish, Kei Ohkubo and Shunichi Fukuzumi pp 14311–14323 DOI: 10.1021/ja8050298 Supporting Info

Simple Host−Guest Chemistry To Modulate the Process of Concentration and Crystallization of Membrane Proteins by Detergent Capture in a Microfluidic Device Liang Li, Sigrid Nachtergaele, Annela M. Seddon, Valentina Tereshko, Nina Ponomarenko and Rustem F. Ismagilov pp 14324–14328 DOI: 10.1021/ja805361j Supporting Info

Acetylacetonate Anchors for Robust Functionalization of TiO2 Nanoparticles with Mn(II)−Terpyridine Complexes William R. McNamara, Robert C. Snoeberger, , Gonghu Li, James M. Schleicher, Clyde W. Cady, Macarena Poyatos, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista pp 14329–14338 DOI: 10.1021/ja805498w Supporting Info

Donors and Acceptors Based on Triangular Dehydrobenzo[12]annulenes: Formation of a Triple-Layered Rosette Structure by a Charge-Transfer Complex Kazukuni Tahara, Takumi Fujita, Motohiro Sonoda, Motoo Shiro and Yoshito Tobe pp 14339–14345 DOI: 10.1021/ja804604y Supporting Info

Bacterial Membranes as Predictors of Antimicrobial Potency Richard M. Epand, Shahar Rotem, Amram Mor, Bob Berno and Raquel F. Epand pp 14346–14352 DOI: 10.1021/ja8062327 Supporting Info

Issue 44

“Clickable” Metal−Organic Framework Yuta Goto, Hiroki Sato, Seiji Shinkai and Kazuki Sada pp 14354–14355 DOI: 10.1021/ja7114053 Supporting Info

A Facile Method to Prepare Macroscopically Oriented Mesostructured Silica Film: Controlling the Orientation of Mesochannels in Multilayer Films by Air Flow Bin Su, Xuemin Lu and Qinghua Lu pp 14356–14357 DOI: 10.1021/ja8003254 Supporting Info

Manganese-Based Nanoscale Metal−Organic Frameworks for Magnetic Resonance Imaging Kathryn M. L. Taylor, William J. Rieter and Wenbin Lin pp 14358–14359 DOI: 10.1021/ja803777x Supporting Info

Controlled Loadings in a Mesoporous Material: Click-on Silica Jun Nakazawa and T. Daniel P. Stack pp 14360–14361 DOI: 10.1021/ja804237b Supporting Info

Highly Diastereoselective Switchable Enantioselective Mannich Reaction of Glycine Derivatives with Imines Xiao-Xia Yan, Qian Peng, Qing Li, Kai Zhang, Jun Yao, Xue-Long Hou and Yun-Dong Wu pp 14362–14363 DOI: 10.1021/ja804527r Supporting Info

Anion Transfer at a Micro-Water/1,2-Dichloroethane Interface Facilitated by β-Octafluoro-meso-octamethylcalix[4]pyrrole Renfa Cui, Qing Li, Dustin E. Gross, Xin Meng, Bo Li, Manuel Marquez, Ronghua Yang, Jonathan L. Sessler and Yuanhua Shao pp 14364–14365 DOI: 10.1021/ja804631p Supporting Info

Onion-Shell Metal−Organic Polyhedra (MOPs): A General Approach to Decorate the Exteriors of MOPs using Principles of Supramolecular Chemistry Tamara D. Hamilton, Giannis S. Papaefstathiou, Tomislav Frii, Dejan-Kreimir Buar and Leonard R. MacGillivray pp 14366–14367 DOI: 10.1021/ja804863u Supporting Info

A Self-Assembled Organic Capsule Formed from the Union of Six Hexagram-Shaped Amphiphile Molecules Shuichi Hiraoka, Koji Harano, Motoo Shiro and Mitsuhiko Shionoya pp 14368–14369 DOI: 10.1021/ja804885k Supporting Info

The Promiscuity of β-Strand Pairing Allows for Rational Design of β-Sheet Face Inversion Koki Makabe and Shohei Koide pp 14370–14371 DOI: 10.1021/ja805011h Supporting Info

Encapsulation Efficiency Measured on Single Small Unilamellar Vesicles Brian Lohse, Pierre-Yves Bolinger and Dimitrios Stamou pp 14372–14373 DOI: 10.1021/ja805030w Supporting Info

Competitive C−I versus C−CN Reductive Elimination from a RhIII Complex. Selectivity is Controlled by the Solvent Moran Feller, Mark A. Iron, Linda J. W. Shimon, Yael Diskin-Posner, Gregory Leitus and David Milstein pp 14374–14375 DOI: 10.1021/ja8046798 Supporting Info

Lanthanide-Based Protease Activity Sensors for Time-Resolved Fluorescence Measurements Shin Mizukami, Kazuhiro Tonai, Masahiro Kaneko and Kazuya Kikuchi pp 14376–14377 DOI: 10.1021/ja800322b Supporting Info

CuH-Catalyzed Enantioselective Intramolecular Reductive Aldol Reactions Generating Three New Contiguous Asymmetric Stereocenters Bruce H. Lipshutz, Benjamin Amorelli and John B. Unger pp 14378–14379 DOI: 10.1021/ja8045475 Supporting Info

Trans-Selective Asymmetric Aziridination of Diazoacetamides and N-Boc Imines Catalyzed by Axially Chiral Dicarboxylic Acid Takuya Hashimoto, Nanase Uchiyama and Keiji Maruoka pp 14380–14381 DOI: 10.1021/ja805635c Supporting Info

Exploiting an Inherent Neighboring Group Effect of α-Amino Acids To Synthesize Extremely Hindered Dipeptides Zachary Z. Brown and Christian E. Schafmeister pp 14382–14383 DOI: 10.1021/ja806063k Supporting Info

Red-Excitation Resonance Raman Analysis of the νFeO Mode of Ferryl-Oxo Hemoproteins Kenichiro Ikemura, Masahiro Mukai, Hideo Shimada, Tomitake Tsukihara, Satoru Yamaguchi, Kyoko Shinzawa-Itoh, Shinya Yoshikawa and Takashi Ogura pp 14384–14385 DOI: 10.1021/ja805735g Supporting Info

Enhanced Anion Exchange for Selective Sulfate Extraction: Overcoming the Hofmeister Bias Christopher J. Fowler, Tamara J. Haverlock, Bruce A. Moyer, James A. Shriver, Dustin E. Gross, Manuel Marquez, Jonathan L. Sessler, Md. Alamgir Hossain and Kristin Bowman-James pp 14386–14387 DOI: 10.1021/ja806511b Supporting Info

N-Heterocyclic Superelectrophiles and Evidence for Single Electron Transfer Chemistry Kiran Kumar Solingapuram Sai, Matthew J. Tokarz, Andrew P. Malunchuk, Chong Zheng, Thomas M. Gilbert and Douglas A. Klumpp pp 14388–14389 DOI: 10.1021/ja8062953 Supporting Info

A Designed Single-Step Method for Synthesis and Structural Study of Organic−Inorganic Hybrid Materials: Well-Ordered Layered Manganese Oxide Nanocomposites Chun-Hu Chen, Vincent Mark B. Crisostomo, Wei-Na Li, Linping Xu and Steven L. Suib pp 14390–14391 DOI: 10.1021/ja805585v Supporting Info

Solution-Gated Epitaxial Graphene as pH Sensor Priscilla Kailian Ang, Wei Chen, Andrew Thye Shen Wee and Kian Ping Loh pp 14392–14393 DOI: 10.1021/ja805090z Supporting Info

Electron Hopping through the 15 Å Triple Tryptophan Molecular Wire in DNA Photolyase Occurs within 30 ps Andras Lukacs, Andr P. M. Eker, Martin Byrdin, Klaus Brettel and Marten H. Vos pp 14394–14395 DOI: 10.1021/ja805261m

Generation and Assembly of Spheroid-like Particles Tao Deng, James R. Cournoyer, James H. Schermerhorn, Joleyn Balch, Yu Du and Margaret L. Blohm pp 14396–14397 DOI: 10.1021/ja805278x Supporting Info

A Diazirine-Based Nucleoside Analogue for Efficient DNA Interstrand Photocross-Linking Zhihai Qiu, Lianghua Lu, Xing Jian and Chuan He pp 14398–14399 DOI: 10.1021/ja805445j Supporting Info

β-Lactones as Specific Inhibitors of ClpP Attenuate the Production of Extracellular Virulence Factors of Staphylococcus aureus Thomas Bttcher and Stephan A. Sieber pp 14400–14401 DOI: 10.1021/ja8051365 Supporting Info

Theoretical Investigation of Water Exchange on the Nanometer-Sized Polyoxocation AlO4Al12(OH)24(H2O)127+ (Keggin-Al13) in Aqueous Solution Zhaosheng Qian, Hui Feng, Wenjing Yang and Shuping Bi pp 14402–14403 DOI: 10.1021/ja805503t Supporting Info

Stress-Induced Chemical Detection Using Flexible Metal−Organic Frameworks Mark D. Allendorf, Ronald J. T. Houk, Leanne Andruszkiewicz, A. Alec Talin, Joel Pikarsky, Arnab Choudhury, Kenneth A. Gall and Peter J. Hesketh pp 14404–14405 DOI: 10.1021/ja805235k Supporting Info

Template Effects in Vinyl Acetate Synthesis on PdAu Surface Alloys: A Density Functional Theory Study Mnica García-Mota and Nria Lpez pp 14406–14407 DOI: 10.1021/ja805519v Supporting Info

Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups Jie Zhang, Yu-Fei Song, Leroy Cronin and Tianbo Liu pp 14408–14409 DOI: 10.1021/ja805644a Supporting Info

Pyromellitic Diimides: Minimal Cores for High Mobility n-Channel Transistor Semiconductors Qingdong Zheng, Jia Huang, Amy Sarjeant and Howard E. Katz pp 14410–14411 DOI: 10.1021/ja805746h Supporting Info

Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation Viktoria H. Gessner and Carsten Strohmann pp 14412–14413 DOI: 10.1021/ja8058205 Supporting Info

Catch and Release: DNA Tweezers that Can Capture, Hold, and Release an Object under Control Xiaogang Han, Zihao Zhou, Fan Yang and Zhaoxiang Deng pp 14414–14415 DOI: 10.1021/ja805945r Supporting Info

Chiral Squaramide Derivatives are Excellent Hydrogen Bond Donor Catalysts Jeremiah P. Malerich, Koji Hagihara and Viresh H. Rawal pp 14416–14417 DOI: 10.1021/ja805693p Supporting Info

Tunable Redox-Responsive Hybrid Nanogated Ensembles Rui Liu, Xiang Zhao, Tao Wu and Pingyun Feng pp 14418–14419 DOI: 10.1021/ja8060886 Supporting Info

Bacterial Homologue of Human Blood Group A Transferase Wen Yi, Jie Shen, Guangyan Zhou, Jianjun Li and Peng George Wang pp 14420–14421 DOI: 10.1021/ja805844y Supporting Info

Cross-Coupling Reactions of Aryl Pivalates with Boronic Acids Kyle W. Quasdorf, Xia Tian and Neil K. Garg pp 14422–14423 DOI: 10.1021/ja806244b Supporting Info

Patterning Nanodomains with Orthogonal Functionalities: Solventless Synthesis of Self-Sorting Surfaces Sung Gap Im, Ki Wan Bong, Byeong-Su Kim, Salmaan H. Baxamusa, Paula T. Hammond, Patrick S. Doyle and Karen K. Gleason pp 14424–14425 DOI: 10.1021/ja806030z Supporting Info

Fragmentation of an Infinite ZnO2 Square Plane into Discrete [ZnO2]2− Linear Units in the Oxyselenide Ba2ZnO2Ag2Se2 Sebastian J. C. Herkelrath, Ian Saratovsky, Joke Hadermann and Simon J. Clarke pp 14426–14427 DOI: 10.1021/ja8063414 Supporting Info

Superconductivity Induced by Co-Doping in Quaternary Fluoroarsenide CaFeAsF Satoru Matsuishi, Yasunori Inoue, Takatoshi Nomura, Hiroshi Yanagi, Masahiro Hirano and Hideo Hosono pp 14428–14429 DOI: 10.1021/ja806357j Supporting Info

Dendronized Supramolecular Nanocapsules: pH Independent, Water-Soluble, Deep-Cavity Cavitands Assemble via the Hydrophobic Effect Marco D. Giles, Simin Liu, Roy L. Emanuel, Bruce C. Gibb and Scott M. Grayson pp 14430–14431 DOI: 10.1021/ja806457x Supporting Info

Amine-Borane σ-Complexes of Rhodium. Relevance to the Catalytic Dehydrogenation of Amine-Boranes Thomas M. Douglas, Adrian B. Chaplin and Andrew S. Weller pp 14432–14433 DOI: 10.1021/ja806582n Supporting Info

Improved Cooperativity of Spin-Labile Iron(III) Centers by Self-Assembly in Solution Claudio Gandolfi, Christian Moitzi, Peter Schurtenberger, Grace G. Morgan and Martin Albrecht pp 14434–14435 DOI: 10.1021/ja806611y Supporting Info

pH Controlled Release of Chromone from Chromone-Fe3O4 Nanoparticles Baodui Wang, Chenjie Xu, Jin Xie, Zhengyin Yang and Shouheng Sun pp 14436–14437 DOI: 10.1021/ja806519m Supporting Info

Lewis Acid Stabilized Methylidene and Oxoscandium Complexes Jennifer Scott, Hongjun Fan, Benjamin F. Wicker, Alison R. Fout, Mu-Hyun Baik and Daniel J. Mindiola pp 14438–14439 DOI: 10.1021/ja806635x Supporting Info

Pt(II)- and Pt(IV)-Bridged Cofacial Diporphyrins via Carbon−Transition Metal σ-Bonds Shigeru Yamaguchi, Taisuke Katoh, Hiroshi Shinokubo and Atsuhiro Osuka pp 14440–14441 DOI: 10.1021/ja8066385 Supporting Info

Chemical Synthesis of Gold Nanowires in Acidic Solutions Franklin Kim, Kwonnam Sohn, Jinsong Wu and Jiaxing Huang pp 14442–14443 DOI: 10.1021/ja806759v Supporting Info

Anionic Amphiphilic Dendrimers as Antibacterial Agents Steven R. Meyers, Frank S. Juhn, Aaron P. Griset, Nathanael R. Luman and Mark W. Grinstaff pp 14444–14445 DOI: 10.1021/ja806912a Supporting Info

Surface Structure of Metal−Organic Framework Grown on Self-Assembled Monolayers Revealed by High-Resolution Atomic Force Microscopy Katarzyna Szelagowska-Kunstman, Piotr Cyganik, Maria Goryl, Denise Zacher, Zita Puterova, Roland A. Fischer and Marek Szymonski pp 14446–14447 DOI: 10.1021/ja8069743

Stepped Strips from Self-Organization of Oligo(p-phenylene) Rods with Lateral Dendritic Chains Dong-Je Hong, Eunji Lee, Jeong-Kyu Lee, Wang-Cheol Zin, Minwoo Han, Eunji Sim and Myongsoo Lee pp 14448–14449 DOI: 10.1021/ja807035j Supporting Info

Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines Chaoqun Li, Chao Wang, Barbara Villa-Marcos and Jianliang Xiao pp 14450–14451 DOI: 10.1021/ja807188s Supporting Info

Relay Catalysis by a Metal-Complex/Brønsted Acid Binary System in a Tandem Isomerization/Carbon−Carbon Bond Forming Sequence Keiichi Sorimachi and Masahiro Terada pp 14452–14453 DOI: 10.1021/ja807591m Supporting Info

Real Time Imaging of Supramolecular Assembly Formation via Programmed Nucleolipid Recognition Louis Moreau, Michel Camplo, Michel Wathier, Nada Taib, Michel Laguerre, Isabelle Bestel, Mark W. Grinstaff and Philippe Barthlmy pp 14454–14455 DOI: 10.1021/ja805974g Supporting Info

Intra- and Intermembrane Pairwise Molecular Recognition between Synthetic Hydrogen-Bonding Phospholipids Mingming Ma, Angel Paredes and Dennis Bong pp 14456–14458 DOI: 10.1021/ja806954u Supporting Info

Nernstian Adsorbate-like Bulk Layer of Organic Radical Polymers for High-Density Charge Storage Purposes Kenichi Oyaizu, Yuko Ando, Hiroaki Konishi and Hiroyuki Nishide pp 14459–14461 DOI: 10.1021/ja803742b Supporting Info

Mechanistic Investigations of the Iridium(III)-Catalyzed Aerobic Oxidation of Primary and Secondary Alcohols Bi Jiang, Yuee Feng and Elon A. Ison pp 14462–14464 DOI: 10.1021/ja8049595 Supporting Info

Electron Paramagnetic Resonance Detection of Intermediates in the Enzymatic Cycle of an Extradiol Dioxygenase William A. Gunderson, Anna I. Zatsman, Joseph P. Emerson, Erik R. Farquhar, Lawrence Que, , John D. Lipscomb and Michael P. Hendrich pp 14465–14467 DOI: 10.1021/ja8052255 Supporting Info

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates Bing-Tao Guan, Yang Wang, Bi-Jie Li, Da-Gang Yu and Zhang-Jie Shi pp 14468–14470 DOI: 10.1021/ja8056503 Supporting Info

Counterintuitive Kinetics in Tsuji-Trost Allylation: Ion-Pair Partitioning and Implications for Asymmetric Catalysis Louise A. Evans, Natalie Fey, Jeremy N. Harvey, David Hose, Guy C. Lloyd-Jones, Paul Murray, A. Guy Orpen, Robert Osborne, Gareth J. J. Owen-Smith and Mark Purdie pp 14471–14473 DOI: 10.1021/ja806278e Supporting Info

Oxidative C−C Bond Cleavage of Primary Alcohols and Vicinal Diols Catalyzed by H5PV2Mo10O40 by an Electron Transfer and Oxygen Transfer Reaction Mechanism Alexander M. Khenkin and Ronny Neumann pp 14474–14476 DOI: 10.1021/ja8063233 Supporting Info

Direct Catalytic Asymmetric Addition of Allylic Cyanides to Ketoimines Ryo Yazaki, Tatsuya Nitabaru, Naoya Kumagai and Masakatsu Shibasaki pp 14477–14479 DOI: 10.1021/ja806572b Supporting Info

Microcapsules Ejecting Nanosized Species into the Environment Bruno G. De Geest, Michael J. McShane, Jo Demeester, Stefaan C. De Smedt and Wim E. Hennink pp 14480–14482 DOI: 10.1021/ja806574h Supporting Info

Insight into the Reduction of Pyruvic Acid to Lactic Acid over Cu{110}: The Crucial Role of Intramolecular Tunneling in Direct Hydrogenation Glenn Jones and Stephen J. Jenkins pp 14483–14492 DOI: 10.1021/ja077786m Supporting Info

Mechanism of OMP Decarboxylation in Orotidine 5′-Monophosphate Decarboxylase Hao Hu, Amy Boone and Weitao Yang pp 14493–14503 DOI: 10.1021/ja801202j Supporting Info

Mechanistic Characterization of the HDV Genomic Ribozyme: Solvent Isotope Effects and Proton Inventories in the Absence of Divalent Metal Ions Support C75 as the General Acid Andrea L. Cerrone-Szakal, Nathan A. Siegfried and Philip C. Bevilacqua pp 14504–14520 DOI: 10.1021/ja801816k Supporting Info

Raftlike Mixtures of Sphingomyelin and Cholesterol Investigated by Solid-State 2H NMR Spectroscopy Tim Bartels, Ravi S. Lankalapalli, Robert Bittman, Klaus Beyer and Michael F. Brown pp 14521–14532 DOI: 10.1021/ja801789t Supporting Info

Design and Synthesis of Highly Sensitive Fluorogenic Substrates for Glutathione S-Transferase and Application for Activity Imaging in Living Cells Yuuta Fujikawa, Yasuteru Urano, Toru Komatsu, Kenjiro Hanaoka, Hirotatsu Kojima, Takuya Terai, Hideshi Inoue and Tetsuo Nagano pp 14533–14543 DOI: 10.1021/ja802423n Supporting Info

Control Elements in Dynamically Determined Selectivity on a Bifurcating Surface Jacqueline B. Thomas, Jack R. Waas, Michael Harmata and Daniel A. Singleton pp 14544–14555 DOI: 10.1021/ja802577v Supporting Info

Triggering Water Exchange Mechanisms via Chelate Architecture. Shielding of Transition Metal Centers by Aminopolycarboxylate Spectator Ligands Joachim Maigut, Roland Meier, Achim Zahl and Rudi van Eldik pp 14556–14569 DOI: 10.1021/ja802842q Supporting Info

Photomodulation of Ionic Interaction and Reactivity: Reversible Photoconversion between Imidazolium and Imidazolinium Takuya Nakashima, Masako Goto, Shigekazu Kawai and Tsuyoshi Kawai pp 14570–14575 DOI: 10.1021/ja802986y Supporting Info

Oligo(p-phenylenevinylene)−Peptide Conjugates: Synthesis and Self-Assembly in Solution and at the Solid−Liquid Interface Rachid Matmour, Inge De Cat, Subi J. George, Wencke Adriaens, Philippe Leclre, Paul H. H. Bomans, Nico A. J. M. Sommerdijk, Jeroen C. Gielen, Peter C. M. Christianen, Jeroen T. Heldens, Jan C. M. van Hest, Dennis W. P. M. Lwik, Steven De Feyter, E. W. Meijer and Albertus P. H. J. Schenning pp 14576–14583 DOI: 10.1021/ja803026j Supporting Info

Hidden Histidine Radical Rearrangements upon Electron Transfer to Gas-Phase Peptide Ions. Experimental Evidence and Theoretical Analysis Frantiek Tureek, Jace W. Jones, Tyrell Towle, Subhasis Panja, Steen Brøndsted Nielsen, Preben Hvelplund and Bela Paizs pp 14584–14596 DOI: 10.1021/ja8036367 Supporting Info

1-(1-Naphthyl)Ethylamine Adsorption on Platinum Surfaces: On the Mechanism of Chiral Modification in Catalysis Ilkeun Lee, Zhen Ma, Shinji Kaneko and Francisco Zaera pp 14597–14604 DOI: 10.1021/ja803667v Supporting Info

The Relationship between Nanoscale Architecture and Function in Photovoltaic Multichromophoric Arrays as Visualized by Kelvin Probe Force Microscopy Vincenzo Palermo, Matthijs B. J. Otten, Andrea Liscio, Erik Schwartz, Pieter A. J. de Witte, Maria Angela Castriciano, Martijn M. Wienk, Fabian Nolde, Giovanna De Luca, Jeroen J. L. M. Cornelissen, Ren A. J. Janssen, Klaus Mllen, Alan E. Rowan, Roeland J. M. Nolte and Paolo Samor pp 14605–14614 DOI: 10.1021/ja804069n Supporting Info

Photoinduced Reorganization of Motor-Doped Chiral Liquid Crystals: Bridging Molecular Isomerization and Texture Rotation Alessandro Bosco, Mahthild G. M. Jongejan, Rienk Eelkema, Nathalie Katsonis, Emmanuelle Lacaze, Alberta Ferrarini and Ben L. Feringa pp 14615–14624 DOI: 10.1021/ja8039629 Supporting Info

Carbohydrate−π Interactions: What Are They Worth? Zachary R. Laughrey, Sarah E. Kiehna, Alex J. Riemen and Marcey L. Waters pp 14625–14633 DOI: 10.1021/ja803960x Supporting Info

Carbene−Alkene Complexes between a Nucleophilic Carbene and Electron-Poor Alkenes Jean-Luc Mieusset, Michael Abraham and Udo H. Brinker pp 14634–14639 DOI: 10.1021/ja8042118 Supporting Info

Conformational Preferences of an Amyloidogenic Peptide: IR Spectroscopy of Ac-VQIVYK-NHMe Timothy D. Vaden, Sally A. N. Gowers, Tjalling S. J. A. de Boer, Jeffrey D. Steill, Jos Oomens and Lavina C. Snoek pp 14640–14650 DOI: 10.1021/ja804213s Supporting Info

DNA Polymorphism as an Origin of Adenine-Thymine Tract Length-Dependent Threading Intercalation Rate Pr Nordell, Fredrik Westerlund, Anna Reymer, Afaf H. El-Sagheer, Tom Brown, Bengt Nordn and Per Lincoln pp 14651–14658 DOI: 10.1021/ja804427q Supporting Info

Systematic Synthesis, Isolation, and Photophysical Properties of Linear-Shaped Re(I) Oligomers and Polymers with 2−20 Units Youhei Yamamoto, Shuhei Sawa, Yusuke Funada, Tatsuki Morimoto, Magnus Falkenstrm, Hiroshi Miyasaka, Sayaka Shishido, Tomoji Ozeki, Kazuhide Koike and Osamu Ishitani pp 14659–14674 DOI: 10.1021/ja8044579 Supporting Info

Probing the Lower Size Limit for Protein-Like Fold Stability: Ten-Residue Microproteins With Specific, Rigid Structures in Water Brandon L. Kier and Niels H. Andersen pp 14675–14683 DOI: 10.1021/ja804656h Supporting Info

Atomic Force Microscopy Imaging and Dilute Solution Properties of Cyclic and Linear Polystyrene Combs Michel Schappacher and Alain Deffieux pp 14684–14689 DOI: 10.1021/ja804780s Supporting Info

Amine-Functionalized Task-Specific Ionic Liquids: A Mechanistic Explanation for the Dramatic Increase in Viscosity upon Complexation with CO2 from Molecular Simulation Keith E. Gutowski and Edward J. Maginn pp 14690–14704 DOI: 10.1021/ja804654b Supporting Info

Molecular Structure of Self-Assembled Chiral Nanoribbons and Nanotubules Revealed in the Hydrated State Reiko Oda, Franck Artzner, Michel Laguerre and Ivan Huc pp 14705–14712 DOI: 10.1021/ja8048964 Supporting Info

Investigation of an Efficient Palladium-Catalyzed C(sp)−C(sp) Cross-Coupling Reaction Using Phosphine−Olefin Ligand: Application and Mechanistic Aspects Wei Shi, Yingdong Luo, Xiancai Luo, Lei Chao, Heng Zhang, Jian Wang and Aiwen Lei pp 14713–14720 DOI: 10.1021/ja8049436 Supporting Info

Improving the Effectiveness of Interfacial Trapping in Removing Single-Walled Carbon Nanotube Bundles Randy K. Wang, Hyun-Ok Park, Wei-Chiang Chen, Carlos Silvera-Batista, Ryan D. Reeves, Jason E. Butler and Kirk J. Ziegler pp 14721–14728 DOI: 10.1021/ja804982b Supporting Info

A Highly Anisotropic Cobalt(II)-Based Single-Chain Magnet: Exploration of Spin Canting in an Antiferromagnetic Array Andrei V. Palii, Oleg S. Reu, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Zhong-Ming Sun, Jiang-Gao Mao, Andrey V. Prosvirin, Han-Hua Zhao and Kim R. Dunbar pp 14729–14738 DOI: 10.1021/ja8050052 Supporting Info

Redox-Triggered Contents Release from Liposomes Winston Ong, Yuming Yang, Angela C. Cruciano and Robin L. McCarley pp 14739–14744 DOI: 10.1021/ja8050469 Supporting Info

Hydrogen Atom Transfer Reactions of a Ruthenium Imidazole Complex: Hydrogen Tunneling and the Applicability of the Marcus Cross Relation Adam Wu and James M. Mayer pp 14745–14754 DOI: 10.1021/ja805067h

Hexagonal-Close-Packed, Hierarchical Amorphous TiO2 Nanocolumn Arrays: Transferability, Enhanced Photocatalytic Activity, and Superamphiphilicity without UV Irradiation Yue Li, Takeshi Sasaki, Yoshiki Shimizu and Naoto Koshizaki pp 14755–14762 DOI: 10.1021/ja805077q Supporting Info

Fragmentation of Fiberlike Structures: Sonication Studies of Cylindrical Block Copolymer Micelles and Behavioral Comparisons to Biological Fibrils Grald Gurin, Hai Wang, Ian Manners and Mitchell A. Winnik pp 14763–14771 DOI: 10.1021/ja805262v Supporting Info

Formation of Spectral Intermediate G−C and A−T Anion Complex in Duplex DNA Studied by Pulse Radiolysis Ryuhei Yamagami, Kazuo Kobayashi and Seiichi Tagawa pp 14772–14777 DOI: 10.1021/ja805127e

Nature of the Fe−O2 Bonding in Oxy-Myoglobin: Effect of the Protein Hui Chen, Masao Ikeda-Saito and Sason Shaik pp 14778–14790 DOI: 10.1021/ja805434m Supporting Info

Ferromagnetic Ordering in Bisthiaselenazolyl Radicals: Variations on a Tetragonal Theme Craig M. Robertson, Alicea A. Leitch, Kristina Cvrkalj, Daniel J. T. Myles, Robert W. Reed, Paul A. Dube and Richard T. Oakley pp 14791–14801 DOI: 10.1021/ja8054436 Supporting Info

Design, Synthesis, and Evaluation of a Lanthanide Chelating Protein Probe: CLaNP-5 Yields Predictable Paramagnetic Effects Independent of Environment Peter H. J. Keizers, Athanasios Saragliadis, Yoshitaka Hiruma, Mark Overhand and Marcellus Ubbink pp 14802–14812 DOI: 10.1021/ja8054832 Supporting Info

Nanosized Pd37(CO)28{P(p-Tolyl)3}12 Containing Geometrically Unprecedented Central 23-Atom Interpenetrating Tri-icosahedral Palladium Kernel of Double Icosahedral Units: Its Postulated Metal-Core Evolution and Resulting Stereochemical Implications Evgueni G. Mednikov and Lawrence F. Dahl pp 14813–14821 DOI: 10.1021/ja805679j Supporting Info

Solution-Based II−VI Core/Shell Nanowire Heterostructures Jim A. Goebl, Robert W. Black, James Puthussery, Jay Giblin, Thomas H. Kosel and Masaru Kuno pp 14822–14833 DOI: 10.1021/ja805538p Supporting Info

Alkali and Alkaline-Earth Metal Amidoboranes: Structure, Crystal Chemistry, and Hydrogen Storage Properties Hui Wu, Wei Zhou and Taner Yildirim pp 14834–14839 DOI: 10.1021/ja806243f Supporting Info

Molecular Structure of Helical Supramolecular Dendrimers Mihai Peterca, Virgil Percec, Mohammad R. Imam, Pawaret Leowanawat, Kentaro Morimitsu and Paul A. Heiney pp 14840–14852 DOI: 10.1021/ja806524m Supporting Info

Spiroacetal Biosynthesis in Insects from Diptera to Hymenoptera: The Giant Ichneumon Wasp Megarhyssa nortoni nortoni Cresson Brett D. Schwartz, Christopher J. Moore, Fredrik Rahm, Patricia Y. Hayes, William Kitching and James J. De Voss pp 14853–14860 DOI: 10.1021/ja8036433 Supporting Info

Tethered Dinuclear Europium(III) Macrocyclic Catalysts for the Cleavage of RNA Kido Nwe, Christopher M. Andolina and Janet R. Morrow pp 14861–14871 DOI: 10.1021/ja8037799 Supporting Info

Unnatural Substrate Repertoire of A, B, and X Family DNA Polymerases Gil Tae Hwang and Floyd E. Romesberg pp 14872–14882 DOI: 10.1021/ja803833h Supporting Info

Dianion and Dication of Tetrabenzo[5.7]fulvalene. Greater Antiaromaticity than Aromaticity in Comparable Systems Ashley M. Piekarski, Nancy S. Mills and Abraham Yousef pp 14883–14890 DOI: 10.1021/ja8042323 Supporting Info

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition In Su Kim, Ming-Yu Ngai and Michael J. Krische pp 14891–14899 DOI: 10.1021/ja805722e Supporting Info

Ruthenium-Catalyzed Azide−Alkyne Cycloaddition: Scope and Mechanism Brant C. Boren, Sridhar Narayan, Lars K. Rasmussen, Li Zhang, Haitao Zhao, Zhenyang Lin, Guochen Jia and Valery V. Fokin p 14900 DOI: 10.1021/ja805956e

Book Review of Metal Vinylidenes and Allenylidenes in Catalysis: From Reactivity to Applications in Synthesis Richmond Sarpong p 14901 DOI: 10.1021/ja807249d

Book Review of Nitroxides: Applications in Chemistry, Biomedicine, and Materials Science Suchada Rajca and Andrzej Rajca pp 14901–14902 DOI: 10.1021/ja807722s

Issue 45

Three-Dimensional Orientation of the Qy Electronic Transition Dipole Moment within the Chlorophyll a Molecule Determined by Femtosecond Polarization Resolved VIS Pump−IR Probe Spectroscopy Martin Linke, Alexandra Lauer, Theodore von Haimberger, Angelica Zacarias and Karsten Heyne pp 14904–14905 DOI: 10.1021/ja804096s Supporting Info

Design of Polymeric Carriers for Cancer-Specific Gene Targeting: Utilization of Abnormal Protein Kinase Cα Activation in Cancer Cells Jeong-Hun Kang, Daisuke Asai, Jong-Hwan Kim, Takeshi Mori, Riki Toita, Tetsuro Tomiyama, Yoji Asami, Jun Oishi, Yuko T. Sato, Takuro Niidome, Byungdug Jun, Hideki Nakashima and Yoshiki Katayama pp 14906–14907 DOI: 10.1021/ja805364s Supporting Info

Femtosecond Dynamics of Isolated Phenylcarbenes Bastian Noller, Lionel Poisson, Raman Maksimenka, Ingo Fischer and Jean-Michel Mestdagh pp 14908–14909 DOI: 10.1021/ja804133c Supporting Info

Azidation of Silicon(111) Surfaces Peigen Cao, Ke Xu and James R. Heath pp 14910–14911 DOI: 10.1021/ja804448p Supporting Info

Spectroscopic Signatures of Nitrogen-Substituted Zeolites Karl D. Hammond, Fulya Dogan, Geoffrey A. Tompsett, Vishal Agarwal, W. Curtis Conner, , Clare P. Grey and Scott M. Auerbach pp 14912–14913 DOI: 10.1021/ja8044844 Supporting Info

Oxidation in Three-Liquid-Phase Microemulsion Systems Using “Balanced Catalytic Surfactants” Vronique Nardello-Rataj, Laurent Caron, Cdric Borde and Jean-Marie Aubry pp 14914–14915 DOI: 10.1021/ja805220p Supporting Info

Structure of Electron-Capture Dissociation Fragments from Charge-Tagged Peptides Probed by Tunable Infrared Multiple Photon Dissociation Gilles Frison, Guillaume van der Rest, Frantiek Tureek, Thierry Besson, Jol Lemaire, Philippe Matre and Julia Chamot-Rooke pp 14916–14917 DOI: 10.1021/ja805257v Supporting Info

Characterization of a Conserved “Threonine Clasp” in CAP-Gly Domains: Role of a Functionally Critical OH/π Interaction in Protein Recognition Michael J. Plevin, Ikuko Hayashi and Mitsuhiko Ikura pp 14918–14919 DOI: 10.1021/ja805576n Supporting Info

Selective Stabilization of Natively Folded RNA Structure by DNA Constraints Joseph P. Gerdt, Chandrasekhar V. Miduturu and Scott K. Silverman pp 14920–14921 DOI: 10.1021/ja8057277 Supporting Info

2D and 3D Ordered Columnar Liquid Crystal Phases by Bundles of Bolaamphiphiles with Swallow-Tail Side Chains Marko Prehm, Feng Liu, Xiangbing Zeng, Goran Ungar and Carsten Tschierske pp 14922–14923 DOI: 10.1021/ja805742t Supporting Info

Origin of the Selectivity for Trans-to-Cis Isomerization in 2-Butene on Pt(111) Single Crystal Surfaces Franoise Delbecq and Francisco Zaera pp 14924–14925 DOI: 10.1021/ja805803u Supporting Info

Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines Ashley M. Berman, Jared C. Lewis, Robert G. Bergman and Jonathan A. Ellman pp 14926–14927 DOI: 10.1021/ja8059396 Supporting Info

Experimentally-Based Recommendations of Density Functionals for Predicting Properties in Mechanically Interlocked Molecules Diego Benitez, Ekaterina Tkatchouk, Il Yoon, J. Fraser Stoddart and William A. Goddard, pp 14928–14929 DOI: 10.1021/ja805953u Supporting Info

Nitridation-Driven Conductive Li4Ti5O12 for Lithium Ion Batteries Kyu-Sung Park, Anass Benayad, Dae-Joon Kang and Seok-Gwang Doo pp 14930–14931 DOI: 10.1021/ja806104n Supporting Info

The Better Tag Remains Unseen Florian G. Durst, Horng Der Ou, Frank Lhr, Volker Dtsch and Wesley E. Straub pp 14932–14933 DOI: 10.1021/ja806212j Supporting Info

Surface-Enhanced Raman Nanoparticle Beacons Based on Bioconjugated Gold Nanocrystals and Long Range Plasmonic Coupling Ximei Qian, Xi Zhou and Shuming Nie pp 14934–14935 DOI: 10.1021/ja8062502 Supporting Info

Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO2 Catherine M. Williams, Jeffrey B. Johnson and Tomislav Rovis pp 14936–14937 DOI: 10.1021/ja8062925 Supporting Info

Charge Transfer Reactions along a Supramolecular Redox Gradient Aurelio Mateo-Alonso, Christian Ehli, Dirk M. Guldi and Maurizio Prato pp 14938–14939 DOI: 10.1021/ja8063155 Supporting Info

Hydroaminoalkylation of Unactivated Olefins with Dialkylamines Seth B. Herzon and John F. Hartwig pp 14940–14941 DOI: 10.1021/ja806367e Supporting Info

A Concise Asymmetric Total Synthesis of Aspidophytine K. C. Nicolaou, Stephen M. Dalby and Utpal Majumder pp 14942–14943 DOI: 10.1021/ja806176w Supporting Info

A Supramolecularly-Caged Ionic Iridium(III) Complex Yielding Bright and Very Stable Solid-State Light-Emitting Electrochemical Cells Stefan Graber, Kevin Doyle, Markus Neuburger, Catherine E. Housecroft, Edwin C. Constable, Rubn D. Costa, Enrique Ort, Diego Repetto and Henk J. Bolink pp 14944–14945 DOI: 10.1021/ja805900e Supporting Info

“Bottom-Up” Meets “Top-Down” Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178]24− and Disassembly to [P3W39O134]19− Chullikkattil P. Pradeep, De-Liang Long, Carsten Streb and Leroy Cronin pp 14946–14947 DOI: 10.1021/ja806596j Supporting Info

Positive and Negative Magnetodielectric Effects in A-Site Ordered (BiMn3)Mn4O12 Perovskite Naoki Imamura, Maarit Karppinen, Teruki Motohashi, Desheng Fu, Mitsuru Itoh and Hisao Yamauchi pp 14948–14949 DOI: 10.1021/ja806487d Supporting Info

DNA-Small Molecule Chimera with Responsive Protein-Binding Ability D. Calvin Harris, Xiaozhu Chu and Janarthanan Jayawickramarajah pp 14950–14951 DOI: 10.1021/ja806552c Supporting Info

Peptide-Based SAMs that Resist the Adsorption of Proteins Rolf Chelmowski, Stephan David Kster, Andreas Kerstan, Andreas Prekelt, Christian Grunwald, Tobias Winkler, Nils Metzler-Nolte, Andreas Terfort and Christof Wll pp 14952–14953 DOI: 10.1021/ja8065754 Supporting Info

Curve-Structured Phenalenyl Chemistry: Synthesis, Electronic Structure, and Bowl-Inversion Barrier of a Phenalenyl-Fused Corannulene Anion Shinsuke Nishida, Yasushi Morita, Akira Ueda, Tadahiro Kobayashi, Kozo Fukui, Kanako Ogasawara, Kazunobu Sato, Takeji Takui and Kazuhiro Nakasuji pp 14954–14955 DOI: 10.1021/ja806708j Supporting Info

Molecular Structure of a Cyclopropyl Substituted Vinyl Cation Andrea Klaer, Wolfgang Saak, Detlev Haase and Thomas Mller pp 14956–14957 DOI: 10.1021/ja8069055 Supporting Info

Patterned Growth of Vertically Aligned ZnO Nanowire Arrays on Inorganic Substrates at Low Temperature without Catalyst Sheng Xu, Yaguang Wei, Melanie Kirkham, Jin Liu, Wenjie Mai, Dragomir Davidovic, Robert L. Snyder and Zhong Lin Wang pp 14958–14959 DOI: 10.1021/ja806952j Supporting Info

Asymmetric Synthesis of Bicyclo[4.3.1]decadienes and Bicyclo[3.3.2]decadienes via [6 + 3] Trimethylenemethane Cycloaddition with Tropones Barry M. Trost, Patrick J. McDougall, Olaf Hartmann and Peter T. Wathen pp 14960–14961 DOI: 10.1021/ja806979b Supporting Info

State-to-State Dynamics of H + O2 Reaction, Evidence for Nonstatistical Behavior Zhigang Sun, Dong H. Zhang, Chuanxiu Xu, Shulan Zhou, Daiqian Xie, Gyrgy Lendvay, Soo-Y. Lee, Shi Ying Lin and Hua Guo pp 14962–14963 DOI: 10.1021/ja8068616 Supporting Info

Extending Pummerer Reaction Chemistry. Application to the Total Synthesis of (±)-Dibromoagelaspongin Ken S. Feldman and Matthew D. Fodor pp 14964–14965 DOI: 10.1021/ja807020d Supporting Info

Control over Self-Assembly through Reversible Charging of the Aromatic Building Blocks in Photofunctional Supramolecular Fibers Jonathan Baram, Elijah Shirman, Netanel Ben-Shitrit, Alona Ustinov, Haim Weissman, Iddo Pinkas, Sharon G. Wolf and Boris Rybtchinski pp 14966–14967 DOI: 10.1021/ja807027w Supporting Info

Highly Efficient Mechanochemical Scission of Silver-Carbene Coordination Polymers S. Karthikeyan, Stephanie L. Potisek, Alessio Piermattei and Rint P. Sijbesma pp 14968–14969 DOI: 10.1021/ja806887k Supporting Info

Carbene-Stabilized Diphosphorus Yuzhong Wang, Yaoming Xie, Pingrong Wei, R. Bruce King, Henry F. Schaefer, III, Paul v. R. Schleyer and Gregory H. Robinson pp 14970–14971 DOI: 10.1021/ja807828t Supporting Info

Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles Tony Horneff, Stepan Chuprakov, Natalia Chernyak, Vladimir Gevorgyan and Valery V. Fokin pp 14972–14974 DOI: 10.1021/ja805079v Supporting Info

Chemical−Clathrate Hybrid Hydrogen Storage: Storage in Both Guest and Host Timothy A. Strobel, Yongkwan Kim, Gary S. Andrews, Jack R. Ferrell III, Carolyn A. Koh, Andrew M. Herring and E. Dendy Sloan pp 14975–14977 DOI: 10.1021/ja805492n

Size and Shape Control of Colloidally Synthesized IV−VI Nanoparticulate Tin(II) Sulfide Stephen G. Hickey, Christian Waurisch, Bernd Rellinghaus and Alexander Eychmller pp 14978–14980 DOI: 10.1021/ja8048755 Supporting Info

Structural Analysis of Spiro β-Lactone Proteasome Inhibitors Michael Groll, Emily P. Balskus and Eric N. Jacobsen pp 14981–14983 DOI: 10.1021/ja806059t Supporting Info

Chiral Anion-Mediated Asymmetric Ring Opening of meso-Aziridinium and Episulfonium Ions Gregory L. Hamilton, Toshio Kanai and F. Dean Toste pp 14984–14986 DOI: 10.1021/ja806431d Supporting Info

Single Chain Magnets Based on the Oxalate Ligand Eugenio Coronado, Jos R. Galn-Mascars and Carlos Martí-Gastaldo pp 14987–14989 DOI: 10.1021/ja806298t Supporting Info

Structural Insights into the Polymorphism of Amyloid-Like Fibrils Formed by Region 20−29 of Amylin Revealed by Solid-State NMR and X-ray Fiber Diffraction Jillian Madine, Edward Jack, Peter G. Stockley, Sheena E. Radford, Louise C. Serpell and David A. Middleton pp 14990–15001 DOI: 10.1021/ja802483d Supporting Info

Toward a Chemical Mechanism of Proton Pumping by the B-Type Cytochrome c Oxidases: Application of Density Functional Theory to Cytochrome ba3 of Thermus thermophilus James A. Fee, David A. Case and Louis Noodleman pp 15002–15021 DOI: 10.1021/ja803112w Supporting Info

Structural Analysis of the Mn(IV)/Fe(III) Cofactor of Chlamydia trachomatis Ribonucleotide Reductase by Extended X-ray Absorption Fine Structure Spectroscopy and Density Functional Theory Calculations Jarod M. Younker, Courtney M. Krest, Wei Jiang, Carsten Krebs, J. Martin Bollinger, and Michael T. Green pp 15022–15027 DOI: 10.1021/ja804365e Supporting Info

Transmission Electron Microscopy Studies of NaLaMgWO6: Spontaneous Formation of Compositionally Modulated Stripes Susana Garca-Martn, Esteban Urones-Garrote, Meghan C. Knapp, Graham King and Patrick M. Woodward pp 15028–15037 DOI: 10.1021/ja802511d Supporting Info

Hydrogen Bonding Lowers Intrinsic Nucleophilicity of Solvated Nucleophiles Xin Chen and John I. Brauman pp 15038–15046 DOI: 10.1021/ja802814a Supporting Info

New Hyperpolarized Contrast Agents for 13C-MRI from Para-Hydrogenation of Oligooxyethylenic Alkynes Francesca Reineri, Alessandra Viale, Giovanbattista Giovenzana, Daniela Santelia, Walter Dastr, Roberto Gobetto and Silvio Aime pp 15047–15053 DOI: 10.1021/ja8059733

Design of Quantum Dot-Conjugated Lipids for Long-Term, High-Speed Tracking Experiments on Cell Surfaces Michael J. Murcia, Daniel. E. Minner, Gina-Mirela Mustata, Kenneth Ritchie and Christoph A. Naumann pp 15054–15062 DOI: 10.1021/ja803325b Supporting Info

Redefinition of Rubisco Carboxylase Reaction Reveals Origin of Water for Hydration and New Roles for Active-Site Residues Babu Kannappan and Jill E. Gready pp 15063–15080 DOI: 10.1021/ja803464a Supporting Info

Surface Chemistry of Colloidal PbSe Nanocrystals Iwan Moreels, Bernd Fritzinger, Jos C. Martins and Zeger Hens pp 15081–15086 DOI: 10.1021/ja803994m

Synthesis and Characterization of {Ni(NO)}10 and {Co(NO)2}10 Complexes Supported by Thiolate Ligands Andrew G. Tennyson, Shanta Dhar and Stephen J. Lippard pp 15087–15098 DOI: 10.1021/ja803992y Supporting Info

Catalytic Reduction of Dioxygen and Nitrite Ion at a Met80Ala Cytochrome c-Functionalized Electrode Stefano Casalini, Gianantonio Battistuzzi, Marco Borsari, Antonio Ranieri and Marco Sola pp 15099–15104 DOI: 10.1021/ja8040724

The Structure of a TNA−TNA Complex in Solution: NMR Study of the Octamer Duplex Derived from α-(l)-Threofuranosyl-(3′-2′)-CGAATTCG Marc-Olivier Ebert, Christian Mang, Ramanarayanan Krishnamurthy, Albert Eschenmoser and Bernhard Jaun pp 15105–15115 DOI: 10.1021/ja8041959 Supporting Info

Catalase−Peroxidase Activity of Iron(III)−TAML Activators of Hydrogen Peroxide Anindya Ghosh, Douglas A. Mitchell, Arani Chanda, Alexander D. Ryabov, Delia Laura Popescu, Erin C. Upham, Gregory J. Collins and Terrence J. Collins pp 15116–15126 DOI: 10.1021/ja8043689 Supporting Info

A 3-fold “Butterfly Valve” in Command of the Encapsulation’s Kinetic Stability. Molecular Baskets at Work Bao-Yu Wang, Xiaoguang Bao, Zhiqing Yan, Veselin Maslak, Christopher M. Hadad and Jovica D. Badji pp 15127–15133 DOI: 10.1021/ja8041977 Supporting Info

Sequential Electron-Transfer and Proton-Transfer Pathways in Hydride-Transfer Reactions from Dihydronicotinamide Adenine Dinucleotide Analogues to Non-heme Oxoiron(IV) Complexes and p-Chloranil. Detection of Radical Cations of NADH Analogues in Acid-Promoted Hydride-Transfer Reactions Shunichi Fukuzumi, Hiroaki Kotani, Yong-Min Lee and Wonwoo Nam pp 15134–15142 DOI: 10.1021/ja804969k

Identification of Conical Structures in Small Aluminum Oxide Clusters: Infrared Spectroscopy of (Al2O3)1−4(AlO)+ Gabriele Santambrogio, Ewald Janssens, Shaohui Li, Torsten Siebert, Gerard Meijer, Knut R. Asmis, Jens Dbler, Marek Sierka and Joachim Sauer pp 15143–15149 DOI: 10.1021/ja805216e Supporting Info

Back-Electron Transfer Suppresses the Periodic Length Dependence of DNA-Mediated Charge Transport across Adenine Tracts Joseph C. Genereux, Katherine E. Augustyn, Molly L. Davis, Fangwei Shao and Jacqueline K. Barton pp 15150–15156 DOI: 10.1021/ja8052738 Supporting Info

Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study Manon Chaumontet, Riccardo Piccardi, Nicolas Audic, Julien Hitce, Jean-Louis Peglion, Eric Clot and Olivier Baudoin pp 15157–15166 DOI: 10.1021/ja805598s Supporting Info

Octanuclear Cubic Coordination Cages Ian S. Tidmarsh, Thomas B. Faust, Harry Adams, Lindsay P. Harding, Luca Russo, William Clegg and Michael D. Ward pp 15167–15175 DOI: 10.1021/ja805605y Supporting Info

Role of the Hydrophobic Effect in the Transfer of Chirality from Molecules to Complex Systems: From Chiral Surfactants to Porphyrin/Surfactant Aggregates Zoubir El-Hachemi, Giovanna Mancini, Josep M. Rib and Alessandro Sorrenti pp 15176–15184 DOI: 10.1021/ja805669v Supporting Info

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds Hien-Quang Do, Rana M. Kashif Khan and Olafs Daugulis pp 15185–15192 DOI: 10.1021/ja805688p Supporting Info

Helix Persistence and Breakdown in Oligoureas of Metaphenylenediamine: Apparent Diastereotopicity as a Spectroscopic Marker of Helix Length in Solution Jonathan Clayden, Loc Lemigre, Gareth A. Morris, Mark Pickworth, Timothy J. Snape and Lyn H. Jones pp 15193–15202 DOI: 10.1021/ja805758v Supporting Info

Simple Cubic Super Crystals Containing PbTe Nanocubes and Their Core−Shell Building Blocks Jun Zhang, Amar Kumbhar, Jibao He, Narayan Chandra Das, Kaikun Yang, Jian-Qing Wang, Howard Wang, Kevin L. Stokes and Jiye Fang pp 15203–15209 DOI: 10.1021/ja806120w Supporting Info

Ordered Mesoporous Alumina-Supported Metal Oxides Stacy M. Morris, Pasquale F. Fulvio and Mietek Jaroniec pp 15210–15216 DOI: 10.1021/ja806429q Supporting Info

Book Review of The Chemistry of Organomagnesium Compounds, Parts 1−2: R−Mg Robert E Mulvey p 15217 DOI: 10.1021/ja807539s

Book Review of Multidimensional Liquid Chromatography: Theory and Applications in Industrial Chemistry and the Life Sciences Abdul Malik pp 15217–15218 DOI: 10.1021/ja808005t

Book Review of Expert Systems in Chemistry Research p 15218 DOI: 10.1021/ja8078847

Book Review of Organic Synthesis with Enzymes in Non-Aqueous Media Reza A. Ghiladi pp 15218–15219 DOI: 10.1021/ja807826g

Book Review of Organocatalysis: Symposium Proceedings 07.2 p 15219 DOI: 10.1021/ja8078797

Book Review of Dynamic Stereochemistry of Chiral Compounds: Principles and Applications James W. Canary pp 15219–15220 DOI: 10.1021/ja8074055

Issue 46

Cation Exchange Induced Tunable Properties of a Nanoporous Octanuclear Cu(II) Wheel with Double-Helical Structure Jin’an Zhao, Liwei Mi, Jiyong Hu, Hongwei Hou and Yaoting Fan pp 15222–15223 DOI: 10.1021/ja8007227 Supporting Info

Epitaxial Ternary Nitride Thin Films Prepared by a Chemical Solution Method Hongmei Luo, Haiyan Wang, Zhenxing Bi, David M. Feldmann, Yongqiang Wang, Anthony K. Burrell, T. Mark McCleskey, Eve Bauer, Marilyn E. Hawley and Quanxi Jia pp 15224–15225 DOI: 10.1021/ja803544c Supporting Info

Selective Hetero-Trisfunctionalization of the Large Rim of a Biomimetic Calix[6]arene Using Host−Guest Chemistry as a Synthetic Tool Benoit Colasson and Olivia Reinaud pp 15226–15227 DOI: 10.1021/ja803878g Supporting Info

Ring-Opening of Aziridine-2-Carboxamides with Carbohydrate C1-O-Nucleophiles. Stereoselective Preparation of α- and β-O-Glycosyl Serine Conjugates Daniel A. Ryan and David Y. Gin pp 15228–15229 DOI: 10.1021/ja804589j Supporting Info

Stabilizing the Elusive ortho-Quinone/Copper(I) Oxidation State Combination through π/π Interaction in an Isolated Complex Sayak Roy, Biprajit Sarkar, Denis Bubrin, Mark Niemeyer, Stanislav Zli, Goutam Kumar Lahiri and Wolfgang Kaim pp 15230–15231 DOI: 10.1021/ja804429v Supporting Info

Molecular Dynamics Prediction of the Mechanism of Ester Hydrolysis in Water Hakan Gunaydin and K. N. Houk pp 15232–15233 DOI: 10.1021/ja8050525 Supporting Info

Detection of Transglucosidase-Catalyzed Polysaccharide Synthesis on a Surface in Real Time Using Surface Plasmon Resonance Spectroscopy Carla Cl, A. Patrick Gunning, Karl Syson, Laura Bowater, Robert A. Field and Stephen Bornemann pp 15234–15235 DOI: 10.1021/ja805264w Supporting Info

Once Cleaved C−C Bond Was Reformed: Reversible C−C Bond Cleavage of Dihydroindenyltitanium Complexes Tamotsu Takahashi, Zhiyi Song, Yi-Fang Hsieh, Kiyohiko Nakajima and Ken-ichiro Kanno pp 15236–15237 DOI: 10.1021/ja805352z Supporting Info

Three-Dimensional Open Framework Built from Cu−S Icosahedral Clusters and Its Photocatalytic Property Zhenyu Zhang, Jian Zhang, Tao Wu, Xianhui Bu and Pingyun Feng pp 15238–15239 DOI: 10.1021/ja805449p Supporting Info

An Entrant of Smaller Fullerene: C56 Captured by Chlorines and Aligned in Linear Chains Yuan-Zhi Tan, Xiao Han, Xin Wu, Ye-Yong Meng, Feng Zhu, Zhuo-Zhen Qian, Zhao-Jiang Liao, Ming-Hui Chen, Xin Lu, Su-Yuan Xie, Rong-Bin Huang and Lan-Sun Zheng pp 15240–15241 DOI: 10.1021/ja806352v Supporting Info

Peptide Imprinted Polymer Nanoparticles: A Plastic Antibody Yu Hoshino, Takashi Kodama, Yoshio Okahata and Kenneth J. Shea pp 15242–15243 DOI: 10.1021/ja8062875 Supporting Info

Surface Diffusive Motion in a Periodic and Asymmetric Potential Greg Pawin, Kin L. Wong, Ki-Young Kwon, Robert J. Frisbee, Talat S. Rahman and Ludwig Bartels pp 15244–15245 DOI: 10.1021/ja8064039 Supporting Info

Polypseudorotaxanes via Ring-Opening Metathesis Polymerizations of [2]Catenanes Songsu Kang, Brandon M. Berkshire, Zheng Xue, Manav Gupta, Christianah Layode, Preston A. May and Michael F. Mayer pp 15246–15247 DOI: 10.1021/ja806122r Supporting Info

Decarboxylative Biaryl Synthesis from Aromatic Carboxylates and Aryl Triflates Lukas J. Goossen, Nuria Rodrguez and Christophe Linder pp 15248–15249 DOI: 10.1021/ja8050926 Supporting Info

Nitrogenase Model Complexes [Cp*Fe(μ-SR1)2(μ-η2-R2NNH)FeCp*] (R1 = Me, Et; R2 = Me, Ph; Cp* = η5-C5Me5): Synthesis, Structure, and Catalytic N−N Bond Cleavage of Hydrazines on Diiron Centers Yanhui Chen, Yuhan Zhou, Pingping Chen, Yinsong Tao, Yang Li and Jingping Qu pp 15250–15251 DOI: 10.1021/ja805025w Supporting Info

All-Clay Photonic Crystals Bettina V. Lotsch and Geoffrey A. Ozin pp 15252–15253 DOI: 10.1021/ja806508h Supporting Info

Hydrocarboxylation of Allenes with CO2 Catalyzed by Silyl Pincer-Type Palladium Complex Jun Takaya and Nobuharu Iwasawa pp 15254–15255 DOI: 10.1021/ja806677w Supporting Info

“Umpolung” Photoinduced Charge Separation in an Anion-bound Supramolecular Complex Jonathan L. Sessler, Elizabeth Karnas, Sung Kuk Kim, Zhongping Ou, Min Zhang, Karl M. Kadish, Kei Ohkubo and Shunichi Fukuzumi pp 15256–15257 DOI: 10.1021/ja806813x Supporting Info

Ligand Exchange as the First Irreversible Step in the Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents Naohiko Yoshikai, Hirokazu Matsuda and Eiichi Nakamura pp 15258–15259 DOI: 10.1021/ja807000a Supporting Info

Investigating the Initial Steps in the Biosynthesis of Cyanobacterial Sunscreen Scytonemin Emily P. Balskus and Christopher T. Walsh pp 15260–15261 DOI: 10.1021/ja807192u Supporting Info

Structure and Absolute Stereochemistry of the Anticancer Agent EBC-23 from the Australian Rainforest Lin Dong, Victoria A. Gordon, Rebecca L. Grange, Jenny Johns, Peter G. Parsons, Achim Porzelle, Paul Reddell, Heiko Schill and Craig M. Williams pp 15262–15263 DOI: 10.1021/ja807133p Supporting Info

High-Order Multiphoton Fluorescence of Organic Molecules in Solution by Intense Femtosecond Laser Pulses Tomoyuki Yatsuhashi, Soh Ichikawa, Yukari Shigematsu and Nobuaki Nakashima pp 15264–15265 DOI: 10.1021/ja806488n Supporting Info

Evidence for the Cation−π Interaction between Cu2+ and Tryptophan Hanami Yorita, Kohei Otomo, Hirotsugu Hiramatsu, Akira Toyama, Takashi Miura and Hideo Takeuchi pp 15266–15267 DOI: 10.1021/ja807010f Supporting Info

Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions Wei Zhou, Hui Wu and Taner Yildirim pp 15268–15269 DOI: 10.1021/ja807023q Supporting Info

Supramolecular Control in Carbohydrate Epimerization: Discovery of a New Anion Host−Guest System Hai Dong, Martin Rahm, Tore Brinck and Olof Ramstrm pp 15270–15271 DOI: 10.1021/ja807044p Supporting Info

Nitroaromatic Actuation of Mitochondrial Bioelectrocatalysis for Self-Powered Explosive Sensors Marguerite N. Germain, Robert L. Arechederra and Shelley D. Minteer pp 15272–15273 DOI: 10.1021/ja807250b Supporting Info

Evolution of Solid Phase Homochirality for a Proteinogenic Amino Acid Cristobal Viedma, Jos E. Ortiz, Trinidad de Torres, Toshiko Izumi and Donna G. Blackmond pp 15274–15275 DOI: 10.1021/ja8074506 Supporting Info

Highly Luminescent BODIPY-Based Organoboron Polymer Exhibiting Supramolecular Self-Assemble Structure Atsushi Nagai, Junpei Miyake, Kenta Kokado, Yuuya Nagata and Yoshiki Chujo pp 15276–15278 DOI: 10.1021/ja806939w Supporting Info

Photoswitchable Nanoparticles Enable High-Resolution Cell Imaging: PULSAR Microscopy Dehong Hu, Zhiyuan Tian, Wuwei Wu, Wei Wan and Alexander D. Q. Li pp 15279–15281 DOI: 10.1021/ja805948u Supporting Info

Carbon Supported CdSe Nanocrystals Beatriz H. Jurez, Michaela Meyns, Alina Chanaewa, Yuxue Cai, Christian Klinke and Horst Weller pp 15282–15284 DOI: 10.1021/ja805662h Supporting Info

Dialkynylpyrenes: Strongly Fluorescent, Environment-Sensitive DNA Building Blocks Holger Bittermann, Doreen Siegemund, Vladimir L. Malinovskii and Robert Hner pp 15285–15287 DOI: 10.1021/ja806747h Supporting Info

Electronic Structure of Six-Coordinate Iron(III)−Porphyrin NO Adducts: The Elusive Iron(III)−NO(radical) State and Its Influence on the Properties of These Complexes V. K. K. Praneeth, Florian Paulat, Timothy C. Berto, Serena DeBeer George, Christian Nther, Corinne D. Sulok and Nicolai Lehnert pp 15288–15303 DOI: 10.1021/ja801860u Supporting Info

1,3-Dipolar Cycloaddition of Organic Azides to Alkynes by a Dicopper-Substituted Silicotungstate Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi and Noritaka Mizuno pp 15304–15310 DOI: 10.1021/ja806249n Supporting Info

Artificial Chemokines: Combining Chemistry and Molecular Biology for the Elucidation of Interleukin-8 Functionality Ralf David, Robert Gnther, Lars Baumann, Tessa Lhmann, Dieter Seebach, Hans-Jrg Hofmann and Annette G. Beck-Sickinger pp 15311–15317 DOI: 10.1021/ja802453x Supporting Info

Probing the Effect of Temperature on the Backbone Dynamics of the Human α-Lactalbumin Molten Globule Stphanie Ramboarina and Christina Redfield pp 15318–15326 DOI: 10.1021/ja802967k Supporting Info

Crystal Structure of a Ten-Amino Acid Protein Shinya Honda, Toshihiko Akiba, Yusuke S. Kato, Yoshito Sawada, Masakazu Sekijima, Miyuki Ishimura, Ayako Ooishi, Hideki Watanabe, Takayuki Odahara and Kazuaki Harata pp 15327–15331 DOI: 10.1021/ja8030533 Supporting Info

Unique Activity of Platinum Adislands in the CO Electrooxidation Reaction Dusan S. Strmcnik, Dusan V. Tripkovic, Dennis van der Vliet, Kee-Chul Chang, Vladimir Komanicky, Hoydoo You, Goran Karapetrov, Jeffrey P. Greeley, Vojislav R. Stamenkovic and Nenad M. Markovi pp 15332–15339 DOI: 10.1021/ja8032185 Supporting Info

Antenna Chemistry with Metallic Single-Walled Carbon Nanotubes Juan G. Duque, Matteo Pasquali and Howard K. Schmidt pp 15340–15347 DOI: 10.1021/ja803300u Supporting Info

Modulation of the Ligand-Field Anisotropy in a Series of Ferric Low-Spin Cytochrome c Mutants derived from Pseudomonas aeruginosa Cytochrome c-551 and Nitrosomonas europaea Cytochrome c-552: A Nuclear Magnetic Resonance and Electron Paramagnetic Resonance Study Giorgio Zoppellaro, Espen Harbitz, Ravinder Kaur, Amy A. Ensign, Kara L. Bren and K. Kristoffer Andersson pp 15348–15360 DOI: 10.1021/ja8033312 Supporting Info

Structural Reorganization and Preorganization in Enzyme Active Sites: Comparisons of Experimental and Theoretically Ideal Active Site Geometries in the Multistep Serine Esterase Reaction Cycle Adam J. T. Smith, Roger Mller, Miguel D. Toscano, Peter Kast, Homme W. Hellinga, Donald Hilvert and K. N. Houk pp 15361–15373 DOI: 10.1021/ja803213p Supporting Info

Wavelength Redistribution and Color Purification Action of a Photonic Crystal Enrico Bovero and Frank C. J. M. Van Veggel pp 15374–15380 DOI: 10.1021/ja803477h Supporting Info

Hydrated Alkali-Metal Cations: Infrared Spectroscopy and ab Initio Calculations of M+(H2O)x=2−5Ar cluster ions for M = Li, Na, K, and Cs Dorothy J. Miller and James M. Lisy pp 15381–15392 DOI: 10.1021/ja803665q Supporting Info

Entropic Effects on Hydrated Alkali-Metal Cations: Infrared Spectroscopy and ab Initio Calculations of M+(H2O)x=2−5 Cluster Ions for M = Li, Na, K, and Cs Dorothy J. Miller and James M. Lisy pp 15393–15404 DOI: 10.1021/ja803666m Supporting Info

Structural Transitions in Ion Coordination Driven by Changes in Competition for Ligand Binding Sameer Varma and Susan B. Rempe pp 15405–15419 DOI: 10.1021/ja803575y Supporting Info

π-Interaction Tuning of the Active Site Properties of Metalloproteins Sachiko Yanagisawa, Peter B. Crowley, Susan J. Firbank, Anne T. Lawler, David M. Hunter, William McFarlane, Chan Li, Takamitsu Kohzuma, Mark J. Banfield and Christopher Dennison pp 15420–15428 DOI: 10.1021/ja8038135 Supporting Info

Regioselective Synthesis of 1,4-Di(organo)[60]fullerenes through DMF-assisted Monoaddition of Silylmethyl Grignard Reagents and Subsequent Alkylation Reaction Yutaka Matsuo, Akihiko Iwashita, Yoko Abe, Chang-Zhi Li, Keiko Matsuo, Masahiko Hashiguchi and Eiichi Nakamura pp 15429–15436 DOI: 10.1021/ja8041299 Supporting Info

Inhibition of Amyloid β Protein Fibrillation by Polymeric Nanoparticles Celia Cabaleiro-Lago, Fiona Quinlan-Pluck, Iseult Lynch, Stina Lindman, Aedin M. Minogue, Eva Thulin, Dominic M. Walsh, Kenneth A. Dawson and Sara Linse pp 15437–15443 DOI: 10.1021/ja8041806 Supporting Info

Jammed Acid−Base Reactions at Interfaces Julianne M. Gibbs-Davis, Jennifer J. Kruk, Christopher T. Konek, Karl A. Scheidt and Franz M. Geiger pp 15444–15447 DOI: 10.1021/ja804302s Supporting Info

Defining the Electronic and Geometric Structure of One-Electron Oxidized Copper−Bis-phenoxide Complexes Tim Storr, Pratik Verma, Russell C. Pratt, Erik C. Wasinger, Yuichi Shimazaki and T. Daniel P. Stack pp 15448–15459 DOI: 10.1021/ja804339m Supporting Info

Electrospinning as a New Technique To Control the Crystal Morphology and Molecular Orientation of Polyoxymethylene Nanofibers Thontree Kongkhlang, Kohji Tashiro, Masaya Kotaki and Suwabun Chirachanchai pp 15460–15466 DOI: 10.1021/ja804185s Supporting Info

Probing General Base Catalysis in the Hammerhead Ribozyme Jason M. Thomas and David M. Perrin pp 15467–15475 DOI: 10.1021/ja804496z Supporting Info

Preparation of Fluorescent Magnetic Nanodiamonds and Cellular Imaging In Pin Chang, Kuo Chu Hwang and Chi-Shiun Chiang pp 15476–15481 DOI: 10.1021/ja804253y Supporting Info

Infrared Action Spectra of Ca2+(H2O)11−69 Exhibit Spectral Signatures for Condensed-Phase Structures with Increasing Cluster Size Matthew F. Bush, Richard J. Saykally and Evan R. Williams pp 15482–15489 DOI: 10.1021/ja804621r Supporting Info

Computational Study of the Reaction of C6F6 with [IrMe(PEt3)3]: Identification of a Phosphine-Assisted C−F Activation Pathway via a Metallophosphorane Intermediate Stefan Erhardt and Stuart A. Macgregor pp 15490–15498 DOI: 10.1021/ja804622j Supporting Info

Competing C−F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition Ainara Nova, Stefan Erhardt, Naseralla A. Jasim, Robin N. Perutz, Stuart A. Macgregor, John E. McGrady and Adrian C. Whitwood pp 15499–15511 DOI: 10.1021/ja8046238 Supporting Info

Synthesis and Degradation of Nucleic Acid Components by Formamide and Iron Sulfur Minerals Raffaele Saladino, Veronica Neri, Claudia Crestini, Giovanna Costanzo, Michele Graciotti and Ernesto Di Mauro pp 15512–15518 DOI: 10.1021/ja804782e

Pressure-Induced Magnetic Switching and Linkage Isomerism in K0.4Fe4[Cr(CN)6]2.8·16H2O: X-ray Absorption and Magnetic Circular Dichroism Studies Eugenio Coronado, M. Carmen Gimnez-Lpez, Tomasz Korzeniak, Georgiy Levchenko, Francisco M. Romero, Alfredo Segura, Valentn Garca-Baonza, Julio C. Cezar, Frank M. F. de Groot, Alla Milner and Moshe Paz-Pasternak pp 15519–15532 DOI: 10.1021/ja8047046 Supporting Info

Bistridentate Ruthenium(II)polypyridyl-Type Complexes with Microsecond 3MLCT State Lifetimes: Sensitizers for Rod-Like Molecular Arrays Maria Abrahamsson, Michael Jger, Rohan J. Kumar, Tomas sterman, Petter Persson, Hans-Christian Becker, Olof Johansson and Leif Hammarstrm pp 15533–15542 DOI: 10.1021/ja804890k Supporting Info

Screening Blockers Against a Potassium Channel with a Droplet Interface Bilayer Array Ruhma Syeda, Matthew A. Holden, William L. Hwang and Hagan Bayley pp 15543–15548 DOI: 10.1021/ja804968g Supporting Info

Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction Alexey G. Sergeev, Anke Spannenberg and Matthias Beller pp 15549–15563 DOI: 10.1021/ja804997z Supporting Info

Metastable Cd4Sb3: A Complex Structured Intermetallic Compound with Semiconductor Properties Andreas Tengå, Sven Lidin, Jean-Philippe Belieres, N. Newman, Yang Wu and Ulrich Häussermann pp 15564–15572 DOI: 10.1021/ja805454p Supporting Info

Simple and Generalized Synthesis of Oxide−Metal Heterostructured Nanoparticles and their Applications in Multimodal Biomedical Probes Sang-Hyun Choi, Hyon Bin Na, Yong Il Park, Kwangjin An, Soon Gu Kwon, Youngjin Jang, Mi-hyun Park, Jaewon Moon, Jae Sung Son, In Chan Song, Woo Kyung Moon and Taeghwan Hyeon pp 15573–15580 DOI: 10.1021/ja805311x Supporting Info

Synergy between Crystal Strain and Surface Energy in Morphological Evolution of Five-Fold-Twinned Silver Crystals Weijia Zhang, Yan Liu, Ronggen Cao, Zhenhua Li, Yahong Zhang, Yi Tang and Kangnian Fan pp 15581–15588 DOI: 10.1021/ja805606q Supporting Info

SERS-Melting: A New Method for Discriminating Mutations in DNA Sequences Sumeet Mahajan, James Richardson, Tom Brown and Philip N. Bartlett pp 15589–15601 DOI: 10.1021/ja805517q Supporting Info

Reactions of Synthetic [2Fe-2S] and [4Fe-4S] Clusters with Nitric Oxide and Nitrosothiols Todd C. Harrop, Zachary J. Tonzetich, Erwin Reisner and Stephen J. Lippard pp 15602–15610 DOI: 10.1021/ja8054996 Supporting Info

Translation of DNA into a Library of 13000 Synthetic Small-Molecule Macrocycles Suitable for in Vitro Selection Brian N. Tse, Thomas M. Snyder, Yinghua Shen and David R. Liu pp 15611–15626 DOI: 10.1021/ja805649f Supporting Info

Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes Erik J. Alexanian and John F. Hartwig pp 15627–15635 DOI: 10.1021/ja8056908 Supporting Info

Determination of Ground-State Hole-Transfer Rates Between Equivalent Sites in Oxidized Multiporphyrin Arrays Using Time-Resolved Optical Spectroscopy Hee-eun Song, Christine Kirmaier, Masahiko Taniguchi, James R. Diers, David F. Bocian, Jonathan S. Lindsey and Dewey Holten pp 15636–15648 DOI: 10.1021/ja805673m Supporting Info

On Doping CdS/ZnS Core/Shell Nanocrystals with Mn Yongan Yang, Ou Chen, Alexander Angerhofer and Y. Charles Cao pp 15649–15661 DOI: 10.1021/ja805736k

Homoleptic Permethylpentalene Complexes: “Double Metallocenes” of the First-Row Transition Metals Andrew E. Ashley, Robert T. Cooper, Gregory G. Wildgoose, Jennifer C. Green and Dermot O’Hare pp 15662–15677 DOI: 10.1021/ja8057138 Supporting Info

Water-Soluble Gold Nanoparticles Protected by Fluorinated Amphiphilic Thiolates Cristina Gentilini, Fabrizio Evangelista, Petra Rudolf, Paola Franchi, Marco Lucarini and Lucia Pasquato pp 15678–15682 DOI: 10.1021/ja8058364 Supporting Info

Valence Anion of Thymine in the DNA π-Stack Monika Kobyłecka, Jerzy Leszczynski and Janusz Rak pp 15683–15687 DOI: 10.1021/ja806251h Supporting Info

Diastereoselective Addition of Zincated Hydrazones to Alkenylboronates and Stereospecific Trapping of Boron/Zinc Bimetallic Intermediates by Carbon Electrophiles Takuji Hatakeyama, Masaharu Nakamura and Eiichi Nakamura pp 15688–15701 DOI: 10.1021/ja806258v Supporting Info

Sterol-Modified Phospholipids: Cholesterol and Phospholipid Chimeras with Improved Biomembrane Properties Zhaohua Huang and Francis C. Szoka, pp 15702–15712 DOI: 10.1021/ja8065557 Supporting Info

Second-Harmonic Generation in GFP-like Proteins Inge Asselberghs, Cristina Flors, Lara Ferrighi, Edith Botek, Benot Champagne, Hideaki Mizuno, Ryoko Ando, Atsushi Miyawaki, Johan Hofkens, Mark Van der Auweraer and Koen Clays pp 15713–15719 DOI: 10.1021/ja805171q Supporting Info

Iodine-Mediated Electrophilic Cyclization of 2-Alkynyl-1-methylene Azide Aromatics Leading to Highly Substituted Isoquinolines and Its Application to the Synthesis of Norchelerythrine Dirk Fischer, Hisamitsu Tomeba, Nirmal K. Pahadi, Nitin T. Patil, Zhibao Huo and Yoshinori Yamamoto pp 15720–15725 DOI: 10.1021/ja805326f Supporting Info

17O and 15N Solid State NMR Studies on Ligand-Assisted Templating and Oxygen Coordination in the Walls of Mesoporous Nb, Ta and Ti Oxides Yuxiang Rao, Tom F. Kemp, Michel Trudeau, Mark E. Smith and Dave M. Antonelli pp 15726–15731 DOI: 10.1021/ja8056387 Supporting Info

2,3-Diphosphino-1,4-diphosphonium Ions Yuen-ying Carpenter, C. Adam Dyker, Neil Burford, Michael D. Lumsden and Andreas Decken pp 15732–15741 DOI: 10.1021/ja805911a Supporting Info

Pyramidal Lead Sulfide Crystallites With High Energy {113} Facets Dongbo Fan, P. John Thomas and Paul O’Brien p 15742 DOI: 10.1021/ja8076318

Issue 47

Phosphate Diester and DNA Hydrolysis by a Multivalent, Nanoparticle-Based Catalyst Renato Bonomi, Francesco Selvestrel, Valentina Lombardo, Claudia Sissi, Stefano Polizzi, Fabrizio Mancin, Umberto Tonellato and Paolo Scrimin pp 15744–15745 DOI: 10.1021/ja801794t Supporting Info

Allosteric Effects on Substrate Dissociation from Cytochrome P450 3A4 in Nanodiscs Observed by Ensemble and Single-Molecule Fluorescence Spectroscopy Abhinav Nath, Peter K. Koo, Elizabeth Rhoades and William M. Atkins pp 15746–15747 DOI: 10.1021/ja805772r Supporting Info

Binding of YC-1 or BAY 41-2272 to Soluble Guanylyl Cyclase Induces a Geminate Phase in CO Photolysis Xiaohui Hu, Changjian Feng, James T. Hazzard, Gordon Tollin and William R. Montfort pp 15748–15749 DOI: 10.1021/ja804103y Supporting Info

Amphiphilic Diarylethene as a Photoswitchable Probe for Imaging Living Cells Ying Zou, Tao Yi, Shuzhang Xiao, Fuyou Li, Chunyan Li, Xia Gao, Junchen Wu, Mengxiao Yu and Chunhui Huang pp 15750–15751 DOI: 10.1021/ja8043163 Supporting Info

Nanometric Layers for Direct, Signal-On, Selective, and Sensitive Electrochemical Detection of Oligonucleotides Hybridization Grgory March, Vincent Nol, Benot Piro, Steeve Reisberg and Minh-Chau Pham pp 15752–15753 DOI: 10.1021/ja8047255 Supporting Info

DNA Attraction in Monovalent and Divalent Electrolytes Binquan Luan and Aleksei Aksimentiev pp 15754–15755 DOI: 10.1021/ja804802u Supporting Info

A Unifying Nitrososynthase Involved in Nitrosugar Biosynthesis Yunfeng Hu, Ahmad Al-Mestarihi, Catherine L. Grimes, Daniel Kahne and Brian O. Bachmann pp 15756–15757 DOI: 10.1021/ja8051415 Supporting Info

A Novel Small Molecule That Alters Shelterin Integrity and Triggers a DNA-Damage Response at Telomeres Raphal Rodriguez, Sebastian Mller, Justin A. Yeoman, Chantal Trentesaux, Jean-Franois Riou and Shankar Balasubramanian pp 15758–15759 DOI: 10.1021/ja805615w Supporting Info

Smart Hydrogels Containing Adenylate Kinase: Translating Substrate Recognition into Macroscopic Motion Weiwei Yuan, Jiyuan Yang, Pavla Kopekov and Jindich Kopeek pp 15760–15761 DOI: 10.1021/ja805634x Supporting Info

Introduction of Clutch Function into a Molecular Gear System by Silane−Silicate Interconversion Wataru Setaka, Takayoshi Nirengi, Chizuko Kabuto and Mitsuo Kira pp 15762–15763 DOI: 10.1021/ja805777p Supporting Info

Targeting Large Kinase Active Site with Rigid, Bulky Octahedral Ruthenium Complexes Jasna Maksimoska, Li Feng, Klaus Harms, Chunling Yi, Joseph Kissil, Ronen Marmorstein and Eric Meggers pp 15764–15765 DOI: 10.1021/ja805555a Supporting Info

An Activity-Based Protein Profiling Probe for the Nicotinic Acetylcholine Receptor Mathew Tantama, Wan-Chen Lin and Stuart Licht pp 15766–15767 DOI: 10.1021/ja805868x Supporting Info

Identification of the Nitrogen Donor Hydrogen Bonded with the Semiquinone at the QH Site of the Cytochrome bo3 from Escherichia coli Myat T. Lin, Rimma I. Samoilova, Robert B. Gennis and Sergei A. Dikanov pp 15768–15769 DOI: 10.1021/ja805906a Supporting Info

Asymmetric Carbonyl-Ene Reaction Catalyzed by Chiral N,N′-Dioxide-Nickel(II) Complex: Remarkably Broad Substrate Scope Ke Zheng, Jian Shi, Xiaohua Liu and Xiaoming Feng pp 15770–15771 DOI: 10.1021/ja808023y Supporting Info

Quantitative Prediction of Amyloid Fibril Growth of Short Peptides from Simulations: Calculating Association Constants To Dissect Side Chain Importance Maarten G. Wolf, Jaap A. Jongejan, Jon D. Laman and Simon W. de Leeuw pp 15772–15773 DOI: 10.1021/ja806606y Supporting Info

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates Hajime Ito, Yusuke Sasaki and Masaya Sawamura pp 15774–15775 DOI: 10.1021/ja806602h Supporting Info

Organelle-Specific Zinc Detection Using Zinpyr-Labeled Fusion Proteins in Live Cells Elisa Tomat, Elizabeth M. Nolan, Jacek Jaworski and Stephen J. Lippard pp 15776–15777 DOI: 10.1021/ja806634e Supporting Info

Construction of Highly Oriented Crystalline Surface Coordination Polymers Composed of Copper Dithiooxamide Complexes Katsuhiko Kanaizuka, Rie Haruki, Osami Sakata, Mamoru Yoshimoto, Yasuyuki Akita and Hiroshi Kitagawa pp 15778–15779 DOI: 10.1021/ja806799t Supporting Info

Silica Sodalite without Occluded Organic Matters by Topotactic Conversion of Lamellar Precursor Takahiko Moteki, Watcharop Chaikittisilp, Atsushi Shimojima and Tatsuya Okubo pp 15780–15781 DOI: 10.1021/ja806930h Supporting Info

Synthesis and Photophysics of Benzotexaphyrin: A Near-Infrared Emitter and Photosensitizer Tian Lu, Pin Shao, Iswarya Mathew, Andrew Sand and Wenfang Sun pp 15782–15783 DOI: 10.1021/ja807021n Supporting Info

Highly Conducting Transmembrane Pores Formed by Aromatic Oligoamide Macrocycles Amber Jade Helsel, Amy L. Brown, Kazuhiro Yamato, Wen Feng, Lihua Yuan, Aimee J. Clements, Stephanie V. Harding, Gabor Szabo, Zhifeng Shao and Bing Gong pp 15784–15785 DOI: 10.1021/ja807078y Supporting Info

Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes Xu Cheng, Sreekumar Vellalath, Richard Goddard and Benjamin List pp 15786–15787 DOI: 10.1021/ja8071034 Supporting Info

New Strategy for Quantifying Biological Zinc by a Modified Zinpyr Fluorescence Sensor Xiao-an Zhang, Dugan Hayes, Sarah J. Smith, Simone Friedle and Stephen J. Lippard pp 15788–15789 DOI: 10.1021/ja807156b Supporting Info

Electrochemical and Electrochromic Properties of Octathio[8]circulene Thin Films in Ionic Liquids Takuya Fujimoto, Michio M. Matsushita, Hirofumi Yoshikawa and Kunio Awaga pp 15790–15791 DOI: 10.1021/ja8072066 Supporting Info

Orthogonal Reactivity in Boryl-Substituted Organotrifluoroborates Gary A. Molander and Deidre L. Sandrock pp 15792–15793 DOI: 10.1021/ja807076d Supporting Info

Three Component Coupling of α-Iminoesters via Umpolung Addition of Organometals: Synthesis of α,α-Disubstituted α-Amino Acids Joshua S. Dickstein, Michael W. Fennie, Amber L. Norman, Betty J. Paulose and Marisa C. Kozlowski pp 15794–15795 DOI: 10.1021/ja8073006 Supporting Info

Kinetics and Mechanism of Catalytic Partial Oxidation Reactions of Alkanes on Rhodium Surfaces Jarod N. Wilson, Ryan A. Pedigo and Francisco Zaera pp 15796–15797 DOI: 10.1021/ja807475g Supporting Info

C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki−Miyaura Cross-Coupling Antonio Bermejo, Abel Ros, Rosario Fernndez and Jos M. Lassaletta pp 15798–15799 DOI: 10.1021/ja8074693 Supporting Info

Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2 Michihisa Murata, Shuhei Maeda, Yuta Morinaka, Yasujiro Murata and Koichi Komatsu pp 15800–15801 DOI: 10.1021/ja8076846 Supporting Info

Solutions of Negatively Charged Graphene Sheets and Ribbons Cristina Valls, Carlos Drummond, Hassan Saadaoui, Clascidia A. Furtado, Maoshuai He, Olivier Roubeau, Luca Ortolani, Marc Monthioux and Alain Pnicaud pp 15802–15804 DOI: 10.1021/ja808001a Supporting Info

Multiple-Timescale Dynamics of Side-Chain Carboxyl and Carbonyl Groups in Proteins by 13C Nuclear Spin Relaxation Raphal Paquin, Fabien Ferrage, Frans A. A. Mulder, Mikael Akke and Geoffrey Bodenhausen pp 15805–15807 DOI: 10.1021/ja803794g Supporting Info

Preparation of Hierarchical Hollow CaCO3 Particles and the Application as Anticancer Drug Carrier Wei Wei, Guang-Hui Ma, Gang Hu, Di Yu, Tom Mcleish, Zhi-Guo Su and Zhe-Yu Shen pp 15808–15810 DOI: 10.1021/ja8039585 Supporting Info

Caged Quantum Dots Gang Han, Taleb Mokari, Caroline Ajo-Franklin and Bruce E. Cohen pp 15811–15813 DOI: 10.1021/ja804948s Supporting Info

Oxo-ester Mediated Native Chemical Ligation: Concept and Applications Qian Wan, Jin Chen, Yu Yuan and Samuel J. Danishefsky pp 15814–15816 DOI: 10.1021/ja804993y Supporting Info

Evidence for Concerted Proton−Electron Transfer in the Electrochemical Oxidation of Phenols with Water As Proton Acceptor. Tri-tert-butylphenol. Cyrille Costentin, Cyril Louault, Marc Robert and Jean-Michel Savant pp 15817–15819 DOI: 10.1021/ja8064914 Supporting Info

Metallothionein-Cross-Linked Hydrogels for the Selective Removal of Heavy Metals from Water Aaron P. Esser-Kahn, Anthony T. Iavarone and Matthew B. Francis pp 15820–15822 DOI: 10.1021/ja807095r Supporting Info

Indium-Catalyzed Annulation of 2-Aryl- and 2-Heteroarylindoles with Propargyl Ethers: Concise Synthesis and Photophysical Properties of Diverse Aryl- and Heteroaryl-Annulated[a]carbazoles Teruhisa Tsuchimoto, Hiromichi Matsubayashi, Masayoshi Kaneko, Yuta Nagase, Takuhiro Miyamura and Eiji Shirakawa pp 15823–15835 DOI: 10.1021/ja803954e Supporting Info

Preparation and Characterization of Simple Dihalomethylidene Platinum Dihalide Complexes in Reactions of Laser-Ablated Pt Atoms with Tetrahalomethanes Han-Gook Cho and Lester Andrews pp 15836–15841 DOI: 10.1021/ja805862j Supporting Info

Metal Content and Localization during Turnover in B. cereus Metallo-β-lactamase Leticia I. Llarrull, Mariana F. Tioni and Alejandro J. Vila pp 15842–15851 DOI: 10.1021/ja801168r Supporting Info

Trapping and Characterization of a Reaction Intermediate in Carbapenem Hydrolysis by B. cereus Metallo-β-lactamase Mariana F. Tioni, Leticia I. Llarrull, Andrs A. Poeylaut-Palena, Marcelo A. Mart, Miguel Saggu, Gopal R. Periyannan, Ernesto G. Mata, Brian Bennett, Daniel H. Murgida and Alejandro J. Vila pp 15852–15863 DOI: 10.1021/ja801169j Supporting Info

Expansion by Contraction: Diversifying the Photochemical Reactivity Scope of Diazo-oxochlorins toward Development of in Situ Alkylating Agents Tillmann Kpke, Maren Pink and Jeffrey M. Zaleski pp 15864–15871 DOI: 10.1021/ja800094e Supporting Info

Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives Yuji Kikukawa, Syuhei Yamaguchi, Yoshinao Nakagawa, Kazuhiro Uehara, Sayaka Uchida, Kazuya Yamaguchi and Noritaka Mizuno pp 15872–15878 DOI: 10.1021/ja8014154 Supporting Info

Experimental and Theoretical Study of the Reactions between Small Neutral Iron Oxide Clusters and Carbon Monoxide Wei Xue, Zhe-Chen Wang, Sheng-Gui He, Yan Xie and Elliot R. Bernstein pp 15879–15888 DOI: 10.1021/ja8023093 Supporting Info

Self-Assembled DNA Photonic Wire for Long-Range Energy Transfer Jonas K. Hannestad, Peter Sandin and Bo Albinsson pp 15889–15895 DOI: 10.1021/ja803407t Supporting Info

Further Investigation of the Effect of Framework Catenation on Hydrogen Uptake in Metal−Organic Frameworks Shengqian Ma, Juergen Eckert, Paul M. Forster, Ji Woong Yoon, Young Kyu Hwang, Jong-San Chang, Christopher D. Collier, John B. Parise and Hong-Cai Zhou pp 15896–15902 DOI: 10.1021/ja803492q Supporting Info

Photoelectron Spectroscopy of Gramicidin Polyanions: Competition between Delayed and Direct Emission Katerina Matheis, Laure Joly, Rodolphe Antoine, Franck Lpine, Christian Bordas, Oli T. Ehrler, Abdul-Rahman Allouche, Manfred M. Kappes and Philippe Dugourd pp 15903–15906 DOI: 10.1021/ja803758w

Catalytic Mechanism and Performance of Computationally Designed Enzymes for Kemp Elimination Anastassia N. Alexandrova, Daniela Rthlisberger, David Baker and William L. Jorgensen pp 15907–15915 DOI: 10.1021/ja804040s

Controlling Film Morphology in Conjugated Polymer:Fullerene Blends with Surface Patterning Lee Y. Park, Andrea M. Munro and David S. Ginger pp 15916–15926 DOI: 10.1021/ja804088j Supporting Info

16-Fold Degeneracy of Peptide Plane Orientations from Residual Dipolar Couplings: Analytical Treatment and Implications for Protein Structure Determination Jean-Christophe Hus, Loc Salmon, Guillaume Bouvignies, Johannes Lotze, Martin Blackledge and Rafael Brschweiler pp 15927–15937 DOI: 10.1021/ja804274s Supporting Info

Room-Temperature Synthesis of Manganese Oxide Monosheets Kazuya Kai, Yukihiro Yoshida, Hiroshi Kageyama, Gunzi Saito, Tetsuo Ishigaki, Yu Furukawa and Jun Kawamata pp 15938–15943 DOI: 10.1021/ja804503f Supporting Info

Electrostatically Controlled Nanostructure of Cationic Porphyrin Diacid on Sulfate/Bisulfate Adlayer at Electrochemical Interface Soichiro Yoshimoto and Takahiro Sawaguchi pp 15944–15949 DOI: 10.1021/ja804564f Supporting Info

Diarylethynyl Amides That Recognize the Parallel Conformation of Genomic Promoter DNA G-Quadruplexes Jyotirmayee Dash, Pravin S. Shirude, Shang-Te Danny Hsu and Shankar Balasubramanian pp 15950–15956 DOI: 10.1021/ja8046552 Supporting Info

Structural Features and Reactivity of (Sparteine)PdCl2: A Model for Selectivity in the Oxidative Kinetic Resolution of Secondary Alcohols Raissa M. Trend and Brian M. Stoltz pp 15957–15966 DOI: 10.1021/ja804955e Supporting Info

Structural Transformations and Adsorption of Fuel-Related Gases of a Structurally Responsive Nickel Phosphonate Metal−Organic Framework, Ni-STA-12 Stuart R. Miller, Gordon M. Pearce, Paul A. Wright, Francesca Bonino, Sachin Chavan, Silvia Bordiga, Irene Margiolaki, Nathalie Guillou, Grard Frey, Sandrine Bourrelly and Philip L. Llewellyn pp 15967–15981 DOI: 10.1021/ja804936z Supporting Info

Rhodium-Catalyzed Silylation and Intramolecular Arylation of Nitriles via the Silicon-Assisted Cleavage of Carbon−Cyano Bonds Mamoru Tobisu, Yusuke Kita, Yusuke Ano and Naoto Chatani pp 15982–15989 DOI: 10.1021/ja804992n Supporting Info

Structure Determination of Protein−Protein Complexes Using NMR Chemical Shifts: Case of an Endonuclease Colicin−Immunity Protein Complex Rinaldo W. Montalvao, Andrea Cavalli, Xavier Salvatella, Tom L. Blundell and Michele Vendruscolo pp 15990–15996 DOI: 10.1021/ja805258z

Low-Valent Titanium-Mediated Stereoselective Alkylation of Allylic Alcohols Ivan L. Lysenko, Keunho Kim, Hyung Goo Lee and Jin Kun Cha pp 15997–16002 DOI: 10.1021/ja806440m Supporting Info

Remarkable Oxidation Stability of Glycals: Excellent Substrates for Cerium(IV)-Mediated Radical Reactions Torsten Linker, Dirk Schanzenbach, Elangovan Elamparuthi, Thomas Sommermann, Werner Fudickar, Viktor Gyllai, Lszl Somsk, Wolfgang Demuth and Michael Schmittel pp 16003–16010 DOI: 10.1021/ja8052706 Supporting Info

Aging of Cholinesterases Phosphylated by Tabun Proceeds through O-Dealkylation Eugnie Carletti, He Li, Bin Li, Fredrik Ekstrm, Yvain Nicolet, Mlanie Loiodice, Emilie Gillon, Marie T. Froment, Oksana Lockridge, Lawrence M. Schopfer, Patrick Masson and Florian Nachon pp 16011–16020 DOI: 10.1021/ja804941z

Characterization of Reactive Intermediates Generated During Photolysis of 4-Acetoxy-4-aryl-2,5-cyclohexadienones: Oxenium Ions and Aryloxy Radicals Yue-Ting Wang, Kyoung Joo Jin, Samuel H. Leopold, Jin Wang, Huo-Lei Peng, Matthew S. Platz, Jiadan Xue, David Lee Phillips, Stephen A. Glover and Michael Novak pp 16021–16030 DOI: 10.1021/ja805336d Supporting Info

Solid-Phase Synthesis of Stereoregular Oligodeoxyribonucleoside Phosphorothioates Using Bicyclic Oxazaphospholidine Derivatives as Monomer Units Natsuhisa Oka, Mika Yamamoto, Terutoshi Sato and Takeshi Wada pp 16031–16037 DOI: 10.1021/ja805780u Supporting Info

Analysis of Chemical Shift Changes Reveals the Binding Modes of Isoindolinone Inhibitors of the MDM2-p53 Interaction Christiane Riedinger, Jane A. Endicott, Stuart J. Kemp, Lynette A. Smyth, Anna Watson, Eric Valeur, Bernard T. Golding, Roger J. Griffin, Ian R. Hardcastle, Martin E. Noble and James M. McDonnell pp 16038–16044 DOI: 10.1021/ja8062088 Supporting Info

Electrolyte Gating in Redox-Active Tunneling JunctionsAn Electrochemical STM Approach Ilya V. Pobelov, Zhihai Li and Thomas Wandlowski pp 16045–16054 DOI: 10.1021/ja8054194

Double-Helical → Ladder Structural Transition in the B-DNA is Induced by a Loss of Dispersion Energy Ji ern, Martin Kabel and Pavel Hobza pp 16055–16059 DOI: 10.1021/ja805428q Supporting Info

Generating Arrays with High Content and Minimal Consumption of Functional Membrane Proteins Sheereen Majd and Michael Mayer pp 16060–16064 DOI: 10.1021/ja8055485 Supporting Info

Cuaq+/Cuaq2+ Redox Reaction Exhibits Strong Nonlinear Solvent Response Due to Change in Coordination Number Jochen Blumberger pp 16065–16068 DOI: 10.1021/ja805471a Supporting Info

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity Yasutomo Segawa, Yuta Suzuki, Makoto Yamashita and Kyoko Nozaki pp 16069–16079 DOI: 10.1021/ja8057919 Supporting Info

Lattice Dynamics To Trigger Low Temperature Oxygen Mobility in Solid Oxide Ion Conductors Werner Paulus, Helmut Schober, Stefan Eibl, Mark Johnson, Tanguy Berthier, Olivier Hernandez, Monica Ceretti, Marie Plazanet, Kazimierz Conder and Carlo Lamberti pp 16080–16085 DOI: 10.1021/ja806144a Supporting Info

Higher Manganese Silicide Nanowires of Nowotny Chimney Ladder Phase Jeremy M. Higgins, Andrew L. Schmitt, Ilia A. Guzei and Song Jin pp 16086–16094 DOI: 10.1021/ja8065122 Supporting Info

Molecular-Based Synthetic Approach to New Group IV Materials for High-Efficiency, Low-Cost Solar Cells and Si-Based Optoelectronics Yan-Yan Fang, Junqi Xie, John Tolle, Radek Roucka, Vijay R. D’Costa, Andrew V. G. Chizmeshya, Jose Menendez and John Kouvetakis pp 16095–16102 DOI: 10.1021/ja806636c

Hydrogen-Mediated Metal−Carbon to Metal−Boron Bond Conversion in Metal−Carboranyl Complexes Dongmei Liu, Li Dang, Yi Sun, Hoi-Shan Chan, Zhenyang Lin and Zuowei Xie pp 16103–16110 DOI: 10.1021/ja8067098 Supporting Info

Cationic Terminal Gallylene Complexes by Halide Abstraction: Coordination Chemistry of a Valence Isoelectronic Analogue of CO and N2 Natalie D. Coombs, Dragoslav Vidovic, Joanna K. Day, Amber L. Thompson, Delphine D. Le Pevelen, Andreas Stasch, William Clegg, Luca Russo, Louise Male, Michael B. Hursthouse, David J. Willock and Simon Aldridge pp 16111–16124 DOI: 10.1021/ja806655f Supporting Info

Issue 48

Prompt Determination of Absolute Configuration for Epoxy Alcohols via Exciton Chirality Protocol Xiaoyong Li and Babak Borhan pp 16126–16127 DOI: 10.1021/ja805058t Supporting Info

Addition of Mild Electrophiles to a Mo≡N Triple Bond and Nitrile Synthesis via Metal-Mediated N-Atom Transfer to Acid Chlorides Soumya Sarkar, Khalil A. Abboud and Adam S. Veige pp 16128–16129 DOI: 10.1021/ja805629x Supporting Info

Carbonic Anhydrase Inhibitor Coated Gold Nanoparticles Selectively Inhibit the Tumor-Associated Isoform IX over the Cytosolic Isozymes I and II Maamar Stiti, Alessandro Cecchi, Marouan Rami, Mohamed Abdaoui, Vronique Barragan-Montero, Andrea Scozzafava, Yannick Guari, Jean-Yves Winum and Claudiu T. Supuran pp 16130–16131 DOI: 10.1021/ja805558k Supporting Info

Enantioselective Synthesis of Silanol Kazunobu Igawa, Junko Takada, Tomohiro Shimono and Katsuhiko Tomooka pp 16132–16133 DOI: 10.1021/ja805848z Supporting Info

Direct Observation of Carbene and Diazo Formation from Aryldiazirines by Ultrafast Infrared Spectroscopy Yunlong Zhang, Gotard Burdzinski, Jacek Kubicki and Matthew S. Platz pp 16134–16135 DOI: 10.1021/ja805922b Supporting Info

Selective Synthesis of Co3O4 Nanocrystal with Different Shape and Crystal Plane Effect on Catalytic Property for Methane Combustion Linhua Hu, Qing Peng and Yadong Li pp 16136–16137 DOI: 10.1021/ja806400e Supporting Info

Hydrogen Switches and Sensors Fabricated by Combining Electropolymerization and Pd Electrodeposition at Microgap Electrodes Radhika Dasari and Francis P. Zamborini pp 16138–16139 DOI: 10.1021/ja806428y Supporting Info

Diastereoselective Construction of Functionalized Homoallylic Alcohols by Ni-Catalyzed Diboron-Promoted Coupling of Dienes and Aldehydes Hee Yeon Cho and James P. Morken pp 16140–16141 DOI: 10.1021/ja806113v Supporting Info

Striking Confinement Effect: AuCl4− Binding to Amines in a Nanocage Cavity Juan D. Henao, Young-Woong Suh, Jeong-Kyu Lee, Mayfair C. Kung and Harold H. Kung pp 16142–16143 DOI: 10.1021/ja806179j Supporting Info

Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole Jianhui Hou, Hsiang-Yu Chen, Shaoqing Zhang, Gang Li and Yang Yang pp 16144–16145 DOI: 10.1021/ja806687u Supporting Info

Asymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) Complex Yao Du, Li-Wen Xu, Yohei Shimizu, Kounosuke Oisaki, Motomu Kanai and Masakatsu Shibasaki pp 16146–16147 DOI: 10.1021/ja8069727 Supporting Info

Weak Alignment of Biomacromolecules in Collagen Gels: An Alternative Way to Yield Residual Dipolar Couplings for NMR Measurements Junhe Ma, Gregory I. Goldberg and Nico Tjandra pp 16148–16149 DOI: 10.1021/ja807064k Supporting Info

Direct Mannich Reaction of Glycinate Schiff Bases with N-(8-Quinolyl)sulfonyl Imines: A Catalytic Asymmetric Approach to anti-α,β-Diamino Esters Jorge Hernndez-Toribio, Ramn Gmez Arrays and Juan C. Carretero pp 16150–16151 DOI: 10.1021/ja807583n Supporting Info

Highly Enantioselective Radical Addition to N-Benzoyl Hydrazones Using Chiral Ammonium Salts Doo Ok Jang and Sang Yoon Kim pp 16152–16153 DOI: 10.1021/ja807685r Supporting Info

TiO2−WO3 Composite Nanotubes by Alloy Anodization: Growth and Enhanced Electrochromic Properties Yoon-Chae Nah, Andrei Ghicov, Doohun Kim, Steffen Berger and Patrik Schmuki pp 16154–16155 DOI: 10.1021/ja807106y Supporting Info

Single Peptide Assembly onto a 1.5 nm Au Surface via a Histidine Tag Joshua M. Kogot, Hannah J. England, Geoffrey F. Strouse and Timothy M. Logan pp 16156–16157 DOI: 10.1021/ja8064717 Supporting Info

Synthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C−H Bond Functionalization of Pyrroles Seung Jun Hwang, Seung Hwan Cho and Sukbok Chang pp 16158–16159 DOI: 10.1021/ja806897h Supporting Info

A Highly Sensitive and Selective OFF-ON Fluorescent Sensor for Cadmium in Aqueous Solution and Living Cell Tanyu Cheng, Yufang Xu, Shenyi Zhang, Weiping Zhu, Xuhong Qian and Liping Duan pp 16160–16161 DOI: 10.1021/ja806928n Supporting Info

Catalytic Enantioselective Meerwein−Eschenmoser Claisen Rearrangement: Asymmetric Synthesis of Allyl Oxindoles Elizabeth C. Linton and Marisa C. Kozlowski pp 16162–16163 DOI: 10.1021/ja807026z Supporting Info

Boron Dipyrromethene Chromophores: Next Generation Triplet Acceptors/Annihilators for Low Power Upconversion Schemes Tanya N. Singh-Rachford, Alexandre Haefele, Raymond Ziessel and Felix N. Castellano pp 16164–16165 DOI: 10.1021/ja807056a Supporting Info

Redox-Responsive Gel−Sol/Sol−Gel Transition in Poly(acrylic acid) Aqueous Solution Containing Fe(III) Ions Switched by Light Fei Peng, Guangzhao Li, Xinxing Liu, Shuizhu Wu and Zhen Tong pp 16166–16167 DOI: 10.1021/ja807087z Supporting Info

Ligand-Induced Conformational Heterogeneity of Cytochrome P450 CYP119 Identified by 2D NMR Spectroscopy with the Unnatural Amino Acid 13C-p-Methoxyphenylalanine Jed N. Lampe, Stephen N. Floor, John D. Gross, Clinton R. Nishida, Yongying Jiang, Michael J. Trnka and Paul R. Ortiz de Montellano pp 16168–16169 DOI: 10.1021/ja8071463 Supporting Info

Nickel-Catalyzed Alkenylation and Alkylation of Fluoroarenes via Activation of C−H Bond over C−F Bond Yoshiaki Nakao, Natsuko Kashihara, Kyalo Stephen Kanyiva and Tamejiro Hiyama pp 16170–16171 DOI: 10.1021/ja807258m Supporting Info

Synthesis of Directly and Doubly Linked Dioxoisobacteriochlorin Dimers Satoru Hiroto, Ichiro Hisaki, Hiroshi Shinokubo and Atsuhiro Osuka pp 16172–16173 DOI: 10.1021/ja807659h Supporting Info

Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of γ-Methylidene-δ-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams Ryo Shintani, Soyoung Park, Fumitaka Shirozu, Masataka Murakami and Tamio Hayashi pp 16174–16175 DOI: 10.1021/ja807662b Supporting Info

Ruthenium- and Palladium-Catalyzed Enyne Cycloisomerizations: Differentially Stereoselective Syntheses of Bicyclic Structures Barry M. Trost, Eric M. Ferreira and Alicia C. Gutierrez pp 16176–16177 DOI: 10.1021/ja8078835 Supporting Info

Time-Resolved RNA SHAPE Chemistry Stefanie A. Mortimer and Kevin M. Weeks pp 16178–16180 DOI: 10.1021/ja8061216 Supporting Info

Ab Initio Modeling of Protein/Biomaterial Interactions: Glycine Adsorption at Hydroxyapatite Surfaces Albert Rimola, Marta Corno, Claudio Marcelo Zicovich-Wilson and Piero Ugliengo pp 16181–16183 DOI: 10.1021/ja806520d Supporting Info

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature James A. Jordan-Hore, Carin C. C. Johansson, Moises Gulias, Elizabeth M. Beck and Matthew J. Gaunt pp 16184–16186 DOI: 10.1021/ja806543s Supporting Info

Reactivity of Mo(PMe3)6 towards Benzothiophene and Selenophenes: New Pathways Relevant to Hydrodesulfurization Daniela Buccella, Kevin E. Janak and Gerard Parkin pp 16187–16189 DOI: 10.1021/ja8070545 Supporting Info

Exploiting Orthogonally Reactive Functionality: Synthesis and Stereochemical Assignment of (−)-Ushikulide A Barry M. Trost and Brendan M. O’Boyle pp 16190–16192 DOI: 10.1021/ja807127s Supporting Info

Mixed Alkylamido Aluminate as a Kinetically Controlled Base Hiroshi Naka, James V. Morey, Joanna Haywood, Dana J. Eisler, Mary McPartlin, Felipe Garca, Hironaga Kudo, Yoshinori Kondo, Masanobu Uchiyama and Andrew E. H. Wheatley pp 16193–16200 DOI: 10.1021/ja804749y Supporting Info

Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets Jay R. Lomeda, Condell D. Doyle, Dmitry V. Kosynkin, Wen-Fang Hwang and James M. Tour pp 16201–16206 DOI: 10.1021/ja806499w Supporting Info

Uniquely Shaped Double-Decker BuckyferrocenesDistinct Electron Donor−Acceptor Interactions Renata Marczak, Mateusz Wielopolski, S. Shankara Gayathri, Dirk M. Guldi, Yutaka Matsuo, Keiko Matsuo, Kazukuni Tahara and Eiichi Nakamura pp 16207–16215 DOI: 10.1021/ja8013902 Supporting Info

Dehydrative Cyclocondensation Reactions on Hydrogen-Terminated Si(100) and Si(111): An ex Situ Tool for the Modification of Semiconductor Surfaces Timothy R. Leftwich, Mark R. Madachik and Andrew V. Teplyakov pp 16216–16223 DOI: 10.1021/ja802645t Supporting Info

Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C82 Yuta Takano, Akinori Yomogida, Hidefumi Nikawa, Michio Yamada, Takatsugu Wakahara, Takahiro Tsuchiya, Midori O. Ishitsuka, Yutaka Maeda, Takeshi Akasaka, Tatsuhisa Kato, Zdenek Slanina, Naomi Mizorogi and Shigeru Nagase pp 16224–16230 DOI: 10.1021/ja802748q Supporting Info

The Mechanism of Water Oxidation Catalysis Promoted by [tpyRu(IV)O]2L3+: A Computational Study Xiaofan Yang and Mu-Hyun Baik pp 16231–16240 DOI: 10.1021/ja8034043 Supporting Info

“Associative” Electron Attachment to Azabenzene−(CO2)n van der Waals Complexes: Stepwise Formation of Covalent Bonds with Additive Electron Affinities Sang Hak Lee, Namdoo Kim, Dong Gyun Ha and Seong Keun Kim pp 16241–16244 DOI: 10.1021/ja8039103 Supporting Info

Oxidative Reactivity Difference among the Metal Oxo and Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction by a Manganese(IV) Complex Having Two Hydroxide Ligands Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper and Daryle H. Busch pp 16245–16253 DOI: 10.1021/ja804305x Supporting Info

Dynamic Combinatorial Selection of Molecules Capable of Inhibiting the (CUG) Repeat RNA−MBNL1 Interaction In Vitro: Discovery of Lead Compounds Targeting Myotonic Dystrophy (DM1) Peter C. Gareiss, Krzysztof Sobczak, Brian R. McNaughton, Prakash B. Palde, Charles A. Thornton and Benjamin L. Miller pp 16254–16261 DOI: 10.1021/ja804398y Supporting Info

Spectroscopic and Electronic Structure Studies of Phenolate Cu(II) Complexes: Phenolate Ring Orientation and Activation Related to Cofactor Biogenesis Somdatta Ghosh, Jordi Cirera, Michael A. Vance, Tetsuya Ono, Kiyoshi Fujisawa and Edward I. Solomon pp 16262–16273 DOI: 10.1021/ja8044986 Supporting Info

Substituent Effects in Pentacenes: Gaining Control over HOMO−LUMO Gaps and Photooxidative Resistances Irvinder Kaur, Wenling Jia, Ryan P. Kopreski, Selvapraba Selvarasah, Mehmet R. Dokmeci, Chandrani Pramanik, Nicol E. McGruer and Glen P. Miller pp 16274–16286 DOI: 10.1021/ja804515y Supporting Info

Polyplexes from Poly(aspartamide) Bearing 1,2-Diaminoethane Side Chains Induce pH-Selective, Endosomal Membrane Destabilization with Amplified Transfection and Negligible Cytotoxicity Kanjiro Miyata, Makoto Oba, Masataka Nakanishi, Shigeto Fukushima, Yuichi Yamasaki, Hiroyuki Koyama, Nobuhiro Nishiyama and Kazunori Kataoka pp 16287–16294 DOI: 10.1021/ja804561g Supporting Info

Total Synthesis of (+)-Azaspiracid-1. An Exhibition of the Intricacies of Complex Molecule Synthesis David A. Evans, Lisbet Kværnø, Travis B. Dunn, Andr Beauchemin, Brian Raymer, Jason A. Mulder, Edward J. Olhava, Martin Juhl, Katsuji Kagechika and David A. Favor pp 16295–16309 DOI: 10.1021/ja804659n Supporting Info

Engineering Complex Riboswitch Regulation by Dual Genetic Selection Vandana Sharma, Yoko Nomura and Yohei Yokobayashi pp 16310–16315 DOI: 10.1021/ja805203w Supporting Info

Enzyme-like Specificity in Zeolites: A Unique Site Position in Mordenite for Selective Carbonylation of Methanol and Dimethyl Ether with CO Mercedes Boronat, Cristina Martnez-Snchez, David Law and Avelino Corma pp 16316–16323 DOI: 10.1021/ja805607m Supporting Info

The Influence of Poly(3-hexylthiophene) Regioregularity on Fullerene-Composite Solar Cell Performance Claire H. Woo, Barry C. Thompson, Bumjoon J. Kim, Michael F. Toney and Jean M. J. Frchet pp 16324–16329 DOI: 10.1021/ja806493n Supporting Info

Swelling the Micelle Core Surrounding Single-Walled Carbon Nanotubes with Water-Immiscible Organic Solvents Randy K. Wang, Wei-Chiang Chen, Daisy K. Campos and Kirk J. Ziegler pp 16330–16337 DOI: 10.1021/ja806586v

Lipid Modification of Proteins through Sortase-Catalyzed Transpeptidation John M. Antos, Gwenn M. Miller, Gijsbert M. Grotenbreg and Hidde L. Ploegh pp 16338–16343 DOI: 10.1021/ja806779e Supporting Info

General Synthesis and Structural Evolution of a Layered Family of Ln8(OH)20Cl4·nH2O (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Y) Fengxia Geng, Yoshitaka Matsushita, Renzhi Ma, Hao Xin, Masahiko Tanaka, Fujio Izumi, Nobuo Iyi and Takayoshi Sasaki pp 16344–16350 DOI: 10.1021/ja807050e Supporting Info

Biosensing and Supramolecular Bioconjugation in Single Conical Polymer Nanochannels. Facile Incorporation of Biorecognition Elements into Nanoconfined Geometries Mubarak Ali, Basit Yameen, Reinhard Neumann, Wolfgang Ensinger, Wolfgang Knoll and Omar Azzaroni pp 16351–16357 DOI: 10.1021/ja8071258

A Case of Remote Asymmetric Induction in the Peptide-Catalyzed Desymmetrization of a Bis(phenol) Chad A. Lewis, Jeffrey L. Gustafson, Anna Chiu, Jaume Balsells, David Pollard, Jerry Murry, Robert A. Reamer, Karl B. Hansen and Scott J. Miller pp 16358–16365 DOI: 10.1021/ja807120z Supporting Info

Enhanced Ferromagnetism and Tunable Saturation Magnetization of Mn/C-Codoped GaN Nanostructures Synthesized by Carbothermal Nitridation Zeyan Wang, Baibiao Huang, Lin Yu, Ying Dai, Peng Wang, Xiaoyan Qin, Xiaoyang Zhang, Jiyong Wei, Jie Zhan, Xiangyang Jing, Haixia Liu and Myung-Hwan Whangbo pp 16366–16373 DOI: 10.1021/ja807030v

Spectroscopic Study of the Cobalamin-Dependent Methionine Synthase in the Activation Conformation: Effects of the Y1139 Residue and S-Adenosylmethionine on the B12 Cofactor Matthew D. Liptak, Supratim Datta, Rowena G. Matthews and Thomas C. Brunold pp 16374–16381 DOI: 10.1021/ja8038129 Supporting Info

Cross-Coupling of Aromatic Bromides with Allylic Silanolate Salts Scott E. Denmark and Nathan S. Werner pp 16382–16393 DOI: 10.1021/ja805951j Supporting Info

New Cationic and Zwitterionic Cp*M(κ2-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation Kevin D. Hesp, Robert McDonald, Michael J. Ferguson and Mark Stradiotto pp 16394–16406 DOI: 10.1021/ja8062277 Supporting Info

Total Syntheses of (+)-Tedanolide and (+)-13-Deoxytedanolide Joshua R. Dunetz, Lisa D. Julian, Jason S. Newcom and William R. Roush pp 16407–16416 DOI: 10.1021/ja8063205 Supporting Info

Gold-Catalyzed Deoxygenative Nazarov Cyclization of 2,4-Dien-1-als for Stereoselective Synthesis of Highly Substituted Cyclopentenes Chung-Chang Lin, Tse-Min Teng, Chung-Chih Tsai, Hsin-Yi Liao and Rai-Shung Liu pp 16417–16423 DOI: 10.1021/ja806415t Supporting Info

Total Synthesis of (−)-Pseudolaric Acid B Barry M. Trost, Jerome Waser and Arndt Meyer pp 16424–16434 DOI: 10.1021/ja806724x Supporting Info

Configurationally Stable Longitudinally Twisted Polycyclic Aromatic Compounds Robert S. Walters, Christina M. Kraml, Neal Byrne, Douglas M. Ho, Qian Qin, Frederick J. Coughlin, Stefan Bernhard and Robert A. Pascal, pp 16435–16441 DOI: 10.1021/ja806958x Supporting Info

How the π Conjugation Length Affects the Fluorescence Emission Efficiency Yoshihiro Yamaguchi, Yoshio Matsubara, Takanori Ochi, Tateaki Wakamiya and Zen-ichi Yoshida p 16442 DOI: 10.1021/ja808258q

Issue 49

Formation of a Bridged Butterfly-Type μ-η2:η2-Peroxo Dicopper Core Structure with a Carboxylate Group Yasuhiro Funahashi, Tomohide Nishikawa, Yuko Wasada-Tsutsui, Yuji Kajita, Syuhei Yamaguchi, Hidekazu Arii, Tomohiro Ozawa, Koichiro Jitsukawa, Takehiko Tosha, Shun Hirota, Teizo Kitagawa and Hideki Masuda pp 16444–16445 DOI: 10.1021/ja804201z Supporting Info

Redox-Coupled Complexation of 23-Phospha-21-thiaporphyrin with Group 10 Metals: A Convenient Access to Stable Core-Modified Isophlorin−Metal Complexes Yoshihiro Matano, Takashi Nakabuchi, Shinya Fujishige, Haruyuki Nakano and Hiroshi Imahori pp 16446–16447 DOI: 10.1021/ja807742g Supporting Info

Selective Ion Passage through Functionalized Graphene Nanopores Kyaw Sint, Boyang Wang and Petr Krl pp 16448–16449 DOI: 10.1021/ja804409f Supporting Info

Enantioselective Preparation of a Stable Boronate Complex Stereogenic Only at Boron Peter F. Kaiser, Jonathan M. White and Craig A. Hutton pp 16450–16451 DOI: 10.1021/ja8044629 Supporting Info

A New Mechanism for the Conversion of Transition Metal Azides to Imido Complexes Hong Wu and Michael B. Hall pp 16452–16453 DOI: 10.1021/ja805105q Supporting Info

Bamboo-Type TiO2 Nanotubes: Improved Conversion Efficiency in Dye-Sensitized Solar Cells Doohun Kim, Andrei Ghicov, Sergiu P. Albu and Patrik Schmuki pp 16454–16455 DOI: 10.1021/ja805201v Supporting Info

Sensitivity and Multiplexing Capabilities of MRI Based on Polarized 129Xe Biosensors Patrick Berthault, Aurore Bogaert-Buchmann, Herv Desvaux, Gaspard Huber and Yves Boulard pp 16456–16457 DOI: 10.1021/ja805274u Supporting Info

Selective Oxidation of Ethanol to Acetaldehyde on Gold Jinlong Gong and C. Buddie Mullins pp 16458–16459 DOI: 10.1021/ja805303s Supporting Info

Oxidation-Resistant Fluorogenic Probe for Mercury Based on Alkyne Oxymercuration Fengling Song, Shuji Watanabe, Paul E. Floreancig and Kazunori Koide pp 16460–16461 DOI: 10.1021/ja805678r Supporting Info

One Site is Enough. Catalytic Water Oxidation by [Ru(tpy)(bpm)(OH2)]2+ and [Ru(tpy)(bpz)(OH2)]2+ Javier J. Concepcion, Jonah W. Jurss, Joseph L. Templeton and Thomas J. Meyer pp 16462–16463 DOI: 10.1021/ja8059649 Supporting Info

Catalytic Enantioselective Additions of Indoles to Nitroalkenes Madhu Ganesh and Daniel Seidel pp 16464–16465 DOI: 10.1021/ja8063292 Supporting Info

In Situ Monitoring of Bindings between Dasatinib and Its Target Protein Kinases Using Magnetic Nanoparticles in Live Cells Dae-Joong Kim, Yong-Weon Yi and Jin Hwan Kim pp 16466–16467 DOI: 10.1021/ja8063843 Supporting Info

6′-Derivatised α-GalCer Analogues Capable of Inducing Strong CD1d-Mediated Th1-Biased NKT Cell Responses in Mice Matthias Trappeniers, Katrien Van Beneden, Tine Decruy, Ulrik Hillaert, Bruno Linclau, Dirk Elewaut and Serge Van Calenbergh pp 16468–16469 DOI: 10.1021/ja8064182 Supporting Info

Stable Lariat Formation Based on a G-Quadruplex Scaffold Yan Xu, Hiroyuki Sato, Yuta Sannohe, Ken-ichi Shinohara and Hiroshi Sugiyama pp 16470–16471 DOI: 10.1021/ja806535j Supporting Info

Oxidation State-Specific Fluorescent Method for Palladium(II) and Platinum(IV) Based on the Catalyzed Aromatic Claisen Rearrangement Amanda L. Garner and Kazunori Koide pp 16472–16473 DOI: 10.1021/ja8065539 Supporting Info

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes David R. Stuart, Mgan Bertrand-Laperle, Kevin M. N. Burgess and Keith Fagnou pp 16474–16475 DOI: 10.1021/ja806955s Supporting Info

A Catalytic Cycle for Oxidation of tert-Butyl Methyl Ether by a Double C−H Activation-Group Transfer Process Matthew T. Whited and Robert H. Grubbs pp 16476–16477 DOI: 10.1021/ja8071385 Supporting Info

A Facile One-Pot Synthesis of meso-Aryl-Substituted [14]Triphyrin(2.1.1) Zhao-Li Xue, Zhen Shen, John Mack, Daiki Kuzuhara, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Xiao-Zeng You and Nagao Kobayashi pp 16478–16479 DOI: 10.1021/ja8068769 Supporting Info

Direct Imaging of the Ligand Monolayer on an Anion-Protected Metal Nanoparticle through Cryogenic Trapping of its Solution-State Structure Alevtina Neyman, Louisa Meshi, Leila Zeiri and Ira A. Weinstock pp 16480–16481 DOI: 10.1021/ja807160f Supporting Info

A Zeolitic Structure (ITQ-34) with Connected 9- and 10-Ring Channels Obtained with Phosphonium Cations as Structure Directing Agents Avelino Corma, Maria J. Diaz-Cabanas, Jose L. Jorda, Fernando Rey, German Sastre and Karl G. Strohmaier pp 16482–16483 DOI: 10.1021/ja806903c Supporting Info

Self-Assembled Dinuclear Cobalt(II)-Salen Catalyst Through Hydrogen-Bonding and Its Application to Enantioselective Nitro-Aldol (Henry) Reaction Jongwoo Park, Kai Lang, Khalil A. Abboud and Sukwon Hong pp 16484–16485 DOI: 10.1021/ja807221s Supporting Info

Synthesis and Reactivity of Functionalized Arylcopper Compounds by Transmetalation of Organosilanes Jessica R. Herron and Zachary T. Ball pp 16486–16487 DOI: 10.1021/ja8070804 Supporting Info

Gold-Catalyzed 1,3-Addition of a sp3-Hybridized C−H Bond to Alkenylcarbenoid Intermediate Sabyasachi Bhunia and Rai-Shung Liu pp 16488–16489 DOI: 10.1021/ja807384a Supporting Info

Total Syntheses of (±)-Massadine and Massadine Chloride Shun Su, Ian B. Seiple, Ian S. Young and Phil S. Baran pp 16490–16491 DOI: 10.1021/ja8074852 Supporting Info

Highly Enantioselective Carbonyl-ene Reactions Catalyzed by In(III)−PyBox Complex Jun-Feng Zhao, Hoi-Yan Tsui, Pei-Jia Wu, Jun Lu and Teck-Peng Loh pp 16492–16493 DOI: 10.1021/ja807501a Supporting Info

Enantioselective Organo-Singly Occupied Molecular Orbital Catalysis: The Carbo-oxidation of Styrenes Thomas H. Graham, Casey M. Jones, Nathan T. Jui and David W. C. MacMillan pp 16494–16495 DOI: 10.1021/ja8075633 Supporting Info

Analyte-Triggered Gelation: Initiating Self-Assembly via Oxidation-Induced Planarization Jing Chen and Anne J. McNeil pp 16496–16497 DOI: 10.1021/ja807651a Supporting Info

Intermediates Involved in the Two Electron Reduction of NO to N2O by a Functional Synthetic Model of Heme Containing Bacterial NO Reductase James P. Collman, Abhishek Dey, Ying Yang, Richard A. Decrau, Takehiro Ohta and Edward I. Solomon pp 16498–16499 DOI: 10.1021/ja807700n Supporting Info

Convergent and Stereoselective Synthesis of Trisubstituted E-Alkenyl Bromides and Iodides via β-Oxido Phosphonium Ylides David M. Hodgson and Tanzeel Arif pp 16500–16501 DOI: 10.1021/ja8076999 Supporting Info

A Ruthenium-Catalyzed, Atom-Economical Synthesis of Nitrogen Heterocycles Barry M. Trost, Nuno Maulide and Robert C. Livingston pp 16502–16503 DOI: 10.1021/ja807696e Supporting Info

Quasi 2D Colloidal CdSe Platelets with Thicknesses Controlled at the Atomic Level Sandrine Ithurria and Benoit Dubertret pp 16504–16505 DOI: 10.1021/ja807724e Supporting Info

Initial Catalyst−Substrate Association Step in Enyne Metathesis Catalyzed by Grubbs Ruthenium Complex Probed by Time-Dependent Fluorescence Quenching Jeong-Hun Sohn, Kyung Hwan Kim, Hee-Yoon Lee, Zae Sung No and Hyotcherl Ihee pp 16506–16507 DOI: 10.1021/ja807717s Supporting Info

An “Inside-Out” Microfluidic Approach to Monodisperse Emulsions Stabilized by Solid Particles Zhihong Nie, Jai Il Park, Wei Li, Stefan A. F. Bon and Eugenia Kumacheva pp 16508–16509 DOI: 10.1021/ja807764m Supporting Info

Defects in a Polyelectrolyte Multilayer: The Inside Story Yao Wang, Erwin Stedronsky and Steven L. Regen pp 16510–16511 DOI: 10.1021/ja808135e Supporting Info

Temperature-Dependent Transmembrane Insertion of the Amphiphilic Peptide PGLa in Lipid Bilayers Observed by Solid State 19F NMR Spectroscopy Sergii Afonin, Stephan L. Grage, Marco Ieronimo, Parvesh Wadhwani and Anne S. Ulrich pp 16512–16514 DOI: 10.1021/ja803156d Supporting Info

Using a Sterically Restrictive Amino Acid as a 19F NMR label To Monitor and To Control Peptide Aggregation in Membranes Parvesh Wadhwani, Jochen Brck, Erik Strandberg, Christian Mink, Sergii Afonin and Anne S. Ulrich pp 16515–16517 DOI: 10.1021/ja804928q Supporting Info

NMR Determination of Amide N−H Equilibrium Bond Length from Concerted Dipolar Coupling Measurements Lishan Yao, Beat Vgeli, Jinfa Ying and Ad Bax pp 16518–16520 DOI: 10.1021/ja805654f Supporting Info

An Additional Spirocyclization for Duocarmycin SA Karen S. MacMillan and Dale L. Boger pp 16521–16523 DOI: 10.1021/ja806593w Supporting Info

Visible−Near Infrared Absorbing Dithienylcyclopentadienone−Thiophene Copolymers for Organic Thin-Film Transistors Changduk Yang, Shinuk Cho, Ryan C. Chiechi, Wesley Walker, Nelson E. Coates, Daniel Moses, Alan J. Heeger and Fred Wudl pp 16524–16526 DOI: 10.1021/ja806784e Supporting Info

Controlled Assembly of Bifunctional Chimeric Protein Cages and Composition Analysis Using Noncovalent Mass Spectrometry Sebyung Kang, Luke M. Oltrogge, Chris C. Broomell, Lars O. Liepold, Peter E. Prevelige, Mark Young and Trevor Douglas pp 16527–16529 DOI: 10.1021/ja807655t Supporting Info

The Tail of the Telomere Luigi Petraccone, John O. Trent and Jonathan B. Chaires pp 16530–16532 DOI: 10.1021/ja8075567 Supporting Info

Links Between Single-Site Heterogeneous and Homogeneous Catalysis. DFT Analysis of Pathways for Organozirconium Catalyst Chemisorptive Activation and Olefin Polymerization on γ-Alumina Alessandro Motta, Ignazio L. Fragal and Tobin J. Marks pp 16533–16546 DOI: 10.1021/ja802439u Supporting Info

Efficient Catalytic Promiscuity in an Enzyme Superfamily: An Arylsulfatase Shows a Rate Acceleration of 1013 for Phosphate Monoester Hydrolysis Luis F. Olguin, Sarah E. Askew, AnnMarie C. O’Donoghue and Florian Hollfelder pp 16547–16555 DOI: 10.1021/ja8047943 Supporting Info

Electronic Effects on the Surface Potential at the Vapor−Liquid Interface of Water Shawn M. Kathmann, I-Feng William Kuo and Christopher J. Mundy pp 16556–16561 DOI: 10.1021/ja802851w

Mechanistic Studies of the Hydroamination of Norbornene with Electrophilic Platinum Complexes: The Role of Proton Transfer Jennifer L. McBee, Alexis T. Bell and T. Don Tilley pp 16562–16571 DOI: 10.1021/ja8030104 Supporting Info

Photochemical Strategies for the Synthesis of Gold Nanoparticles from Au(III) and Au(I) Using Photoinduced Free Radical Generation M. Luisa Marin, Katherine L. McGilvray and Juan C. Scaiano pp 16572–16584 DOI: 10.1021/ja803490n Supporting Info

Nanoscale Growth Factor Patterns by Immobilization on a Heparin-Mimicking Polymer Karen L. Christman, Vimary Vzquez-Dorbatt, Eric Schopf, Christopher M. Kolodziej, Ronald C. Li, Rebecca M. Broyer, Yong Chen and Heather D. Maynard pp 16585–16591 DOI: 10.1021/ja803676r Supporting Info

Observing Metal-Catalyzed Chemical Reactions in Situ Using Surface-Enhanced Raman Spectroscopy on Pd−Au Nanoshells Kimberly N. Heck, Benjamin G. Janesko, Gustavo E. Scuseria, Naomi J. Halas and Michael S. Wong pp 16592–16600 DOI: 10.1021/ja803556k Supporting Info

Nucleation and Growth of ZnO in Organic Solvents - an in Situ Study C. Lizandara-Pueyo, M. W. E. van den Berg, A. De Toni, T. Goes and S. Polarz pp 16601–16610 DOI: 10.1021/ja804071h Supporting Info

Protein Side-Chain Dynamics As Observed by Solution- and Solid-State NMR Spectroscopy: A Similarity Revealed Vipin Agarwal, Yi Xue, Bernd Reif and Nikolai R. Skrynnikov pp 16611–16621 DOI: 10.1021/ja804275p Supporting Info

Oligo(N-aryl glycines): A New Twist on Structured Peptoids Neel H. Shah, Glenn L. Butterfoss, Khanh Nguyen, Barney Yoo, Richard Bonneau, Dallas L. Rabenstein and Kent Kirshenbaum pp 16622–16632 DOI: 10.1021/ja804580n Supporting Info

Polynuclear Cation−Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure Grgory Nocton, Pawel Horeglad, Jacques Pcaut and Marinella Mazzanti pp 16633–16645 DOI: 10.1021/ja804766r Supporting Info

Carbon Complexes as Electronically and Sterically Tunable Analogues of Carbon Monoxide in Coordination Chemistry Andreas Krapp and Gernot Frenking pp 16646–16658 DOI: 10.1021/ja8047915 Supporting Info

Kinetics and Mechanism for the Reaction of Hexafluoroacetylacetone with CuO in Supercritical Carbon Dioxide Michael Durando, Rachel Morrish and Anthony J. Muscat pp 16659–16668 DOI: 10.1021/ja8050662 Supporting Info

Current Transients in Single Nanoparticle Collision Events Xiaoyin Xiao, Fu-Ren F. Fan, Jiping Zhou and Allen J. Bard pp 16669–16677 DOI: 10.1021/ja8051393

van der Waals versus Hydrogen-Bonding Forces in a Crystalline Analog of Cellotetraose: Cyclohexyl 4′-O-Cyclohexyl β-d-Cellobioside Cyclohexane Solvate Yuko Yoneda, Kurt Mereiter, Christian Jaeger, Lothar Brecker, Paul Kosma, Thomas Rosenau and Alfred French pp 16678–16690 DOI: 10.1021/ja805147t Supporting Info

Modeling Differential Binding of α4β2 Nicotinic Acetylcholine Receptor with Agonists and Antagonists Xiaoqin Huang, Fang Zheng and Chang-Guo Zhan pp 16691–16696 DOI: 10.1021/ja8055326 Supporting Info

Stiffness- and Conformation-Dependent Polymer Wrapping onto Single-Walled Carbon Nanotubes Masanobu Naito, Kazuyuki Nobusawa, Hisanari Onouchi, Masashi Nakamura, Ken-ichiro Yasui, Atsushi Ikeda and Michiya Fujiki pp 16697–16703 DOI: 10.1021/ja806109z Supporting Info

Application of Affinity Selection/Mass Spectrometry to Determine the Structural Isomer of Parnafungins Responsible for Binding Polyadenosine Polymerase Gregory C. Adam, Craig A. Parish, Douglas Wisniewski, Juncai Meng, Min Liu, Kathleen Calati, Benjamin D. Stein, John Athanasopoulos, Paul Liberator, Terry Roemer, Guy Harris and Kevin T. Chapman pp 16704–16710 DOI: 10.1021/ja805531w Supporting Info

Biomimetic Cleavage of RNA Models Promoted by a Dinuclear Zn(II) Complex in Ethanol. Greater than 30 kcal/mol Stabilization of the Transition State for Cleavage of a Phosphate Diester C. Tony Liu, Alexei A. Neverov and R. Stan Brown pp 16711–16720 DOI: 10.1021/ja806462x Supporting Info

Highly Dissociative and Concerted Mechanism for the Nicotinamide Cleavage Reaction in Sir2Tm Enzyme Suggested by Ab Initio QM/MM Molecular Dynamics Simulations Po Hu, Shenglong Wang and Yingkai Zhang pp 16721–16728 DOI: 10.1021/ja807269j Supporting Info

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine−Borane Marie Sircoglou, Sbastien Bontemps, Ghenwa Bouhadir, Nathalie Saffon, Karinne Miqueu, Weixing Gu, Maxime Mercy, Chun-Hsing Chen, Bruce M. Foxman, Laurent Maron, Oleg V. Ozerov and Didier Bourissou pp 16729–16738 DOI: 10.1021/ja8070072 Supporting Info

MoS2 Nanoribbons: High Stability and Unusual Electronic and Magnetic Properties Yafei Li, Zhen Zhou, Shengbai Zhang and Zhongfang Chen pp 16739–16744 DOI: 10.1021/ja805545x Supporting Info

Interactions between Redox Complexes and Semiconductor Quantum Dots Coupled via a Peptide Bridge Igor L. Medintz, Thomas Pons, Scott A. Trammell, Amy F. Grimes, Doug S. English, Juan B. Blanco-Canosa, Philip E. Dawson and Hedi Mattoussi pp 16745–16756 DOI: 10.1021/ja805456x Supporting Info

Extensive Backbone Dynamics in the GCAA RNA Tetraloop Analyzed Using 13C NMR Spin Relaxation and Specific Isotope Labeling James E. Johnson, and Charles G. Hoogstraten pp 16757–16769 DOI: 10.1021/ja805759z Supporting Info

Synthesis of CuInS2, CuInSe2, and Cu(InxGa1-x)Se2 (CIGS) Nanocrystal “Inks” for Printable Photovoltaics Matthew G. Panthani, Vahid Akhavan, Brian Goodfellow, Johanna P. Schmidtke, Lawrence Dunn, Ananth Dodabalapur, Paul F. Barbara and Brian A. Korgel pp 16770–16777 DOI: 10.1021/ja805845q Supporting Info

Functionalized Single-Walled Carbon Nanotubes as Rationally Designed Vehicles for Tumor-Targeted Drug Delivery Jingyi Chen, Shuyi Chen, Xianrui Zhao, Larisa V. Kuznetsova, Stanislaus S. Wong and Iwao Ojima pp 16778–16785 DOI: 10.1021/ja805570f Supporting Info

Synthesis of Pluraflavin A “Aglycone” Benjamin J. D. Wright, John Hartung, Feng Peng, Ryan Van de Water, Haibo Liu, Quen-Hui Tan, Ting-Chao Chou and Samuel J. Danishefsky pp 16786–16790 DOI: 10.1021/ja805936v Supporting Info

Chemical Synthesis of All Phosphatidylinositol Mannoside (PIM) Glycans from Mycobacterium tuberculosis Siwarutt Boonyarattanakalin, Xinyu Liu, Mario Michieletti, Bernd Lepenies and Peter H. Seeberger pp 16791–16799 DOI: 10.1021/ja806283e Supporting Info

Direct Observation of Stacking Faults and Pore Connections in Ordered Cage-Type Mesoporous Silica FDU-12 by Electron Tomography Ovidiu Ersen, Julien Parmentier, Leonid A. Solovyov, Marc Drillon, Cuong Pham-Huu, Jacques Werckmann and Patrick Schultz pp 16800–16806 DOI: 10.1021/ja806267r

Biomimetic Asymmetric Total Synthesis of (−)-Laurefucin via an Organoselenium-Mediated Intramolecular Hydroxyetherification Byungsook Kim, Miseon Lee, Mi Jung Kim, Hyunjoo Lee, Sanghee Kim, Deukjoon Kim, Minseob Koh, Seung Bum Park and Kye Jung Shin pp 16807–16811 DOI: 10.1021/ja806304s Supporting Info

Dendritic Molecular Switch: Chiral Folding and Helicity Inversion Xuan Jiang, Young-Kwan Lim, Bong June Zhang, Elizabeth A. Opsitnick, Mu-Hyun Baik and Dongwhan Lee pp 16812–16822 DOI: 10.1021/ja806723e Supporting Info

Issue 50

Molecular Modeling of Complex Chemical Systems Donald G. Truhlar pp 16824–16827 DOI: 10.1021/ja808927h

Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation Suk Joong Lee, So-Hye Cho, Karen L. Mulfort, David M. Tiede, Joseph T. Hupp and SonBinh T. Nguyen pp 16828–16829 DOI: 10.1021/ja804014y Supporting Info

Spatial Anticorrelation between Nonlinear White-Light Generation and Single Molecule Surface-Enhanced Raman Scattering Manfred J. Walter, Nicholas J. Borys, Gerald Gaefke, Sigurd Hger and John M. Lupton pp 16830–16831 DOI: 10.1021/ja8054518 Supporting Info

A Complete Reactant−Product Analysis of the Oxygen Transfer Reaction in [V4O11·C3H6]−: A Cluster Complex for Modeling Surface Activation and Reactivity Shaohui Li, Aldo Mirabal, Juri Demuth, Ludger Wste and Torsten Siebert pp 16832–16833 DOI: 10.1021/ja804995m

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases Bryan E. Barton, Matthew T. Olsen and Thomas B. Rauchfuss pp 16834–16835 DOI: 10.1021/ja8057666 Supporting Info

Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence Guillaume Bordeau, Rémy Lartia, Germain Metge, Céline Fiorini-Debuisschert, Fabrice Charra and Marie-Paule Teulade-Fichou pp 16836–16837 DOI: 10.1021/ja8055112 Supporting Info

Metal-Mediated Cyclization of Aryl and Benzyl Glycidyl Ethers: A Complete Scenario Roco Marcos, Carles Rodrguez-Escrich, Clara I. Herreras and Miquel A. Perics pp 16838–16839 DOI: 10.1021/ja8062887 Supporting Info

Superresolution Microscopy on the Basis of Engineered Dark States Christian Steinhauer, Carsten Forthmann, Jan Vogelsang and Philip Tinnefeld pp 16840–16841 DOI: 10.1021/ja806590m Supporting Info

Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO2 Separation Applications Praveen K. Thallapally, Jian Tian, Motkuri Radha Kishan, Carlos A. Fernandez, Scott J. Dalgarno, Peter B. McGrail, John E. Warren and Jerry L. Atwood pp 16842–16843 DOI: 10.1021/ja806391k Supporting Info

Efficient Synthesis of an η2-Pyridine Complex and a Preliminary Investigation of the Bound Heterocycle’s Reactivity Daniel P. Harrison, Kevin D. Welch, Adam C. Nichols-Nielander, Michal Sabat, William H. Myers and W. Dean Harman pp 16844–16845 DOI: 10.1021/ja807521d Supporting Info

The H-Bonding Network of Acylguanidine Complexes: Combined Intermolecular 2hJH,P and 3hJN,P Scalar Couplings Provide an Insight into the Geometric Arrangement Guido Federwisch, Roland Kleinmaier, Diana Drettwan and Ruth M. Gschwind pp 16846–16847 DOI: 10.1021/ja807042u Supporting Info

Reactivity of the Disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward Silylcyanide: Two Pathways To Form the Bis-Adduct [RSiSiR(CNSiMe3)2] with Some Silaketenimine Character and a 1,4-Diaza-2,3-disilabenzene Analogue Katsuhiko Takeuchi, Masaaki Ichinohe and Akira Sekiguchi pp 16848–16849 DOI: 10.1021/ja807974a Supporting Info

Multilayered Nanocomposite Polymer Colloids Using Emulsion Polymerization Stabilized by Solid Particles Patrick J. Colver, Catheline A. L. Colard and Stefan A. F. Bon pp 16850–16851 DOI: 10.1021/ja807242k Supporting Info

Cytoplasmic Water and Hydration Layer Dynamics in Human Red Blood Cells Andreas M. Stadler, Jan P. Embs, Ilya Digel, Gerhard M. Artmann, Tobias Unruh, Georg Bldt and Giuseppe Zaccai pp 16852–16853 DOI: 10.1021/ja807691j Supporting Info

Total Synthesis of (−)-Serotobenine Yasuaki Koizumi, Hideki Kobayashi, Toshiyuki Wakimoto, Takumi Furuta, Tohru Fukuyama and Toshiyuki Kan pp 16854–16855 DOI: 10.1021/ja807676v Supporting Info

Formation of Vinylidenes from Internal Alkynes at a Cyclotriphosphato Ruthenium Complex Yousuke Ikeda, Takafumi Yamaguchi, Keiichiro Kanao, Kazuhiro Kimura, Sou Kamimura, Yuichiro Mutoh, Yoshiaki Tanabe and Youichi Ishii pp 16856–16857 DOI: 10.1021/ja8080567 Supporting Info

Pyridinium 1,1′-Binaphthyl-2,2′-disulfonates as Highly Effective Chiral Brønsted Acid−Base Combined Salt Catalysts for Enantioselective Mannich-Type Reaction Manabu Hatano, Toshikatsu Maki, Katsuhiko Moriyama, Manabu Arinobe and Kazuaki Ishihara pp 16858–16860 DOI: 10.1021/ja806875c Supporting Info

Ribosomal Synthesis of Polypeptoids and Peptoid−Peptide Hybrids Takashi Kawakami, Hiroshi Murakami and Hiroaki Suga pp 16861–16863 DOI: 10.1021/ja806998v Supporting Info

Enantioselective Synthesis of (+)-Cortistatin A, a Potent and Selective Inhibitor of Endothelial Cell Proliferation Hong Myung Lee, Cristina Nieto-Oberhuber and Matthew D. Shair pp 16864–16866 DOI: 10.1021/ja8071918 Supporting Info

Nucleobase-Directed Amyloid Nanotube Assembly Peng Liu, Rong Ni, Anil K. Mehta, W. Seth Childers, Ami Lakdawala, Sai Venkatesh Pingali, Pappannan Thiyagarajan and David G. Lynn pp 16867–16869 DOI: 10.1021/ja807425h Supporting Info

Conversion of Allylic Alcohols to Stereodefined Trisubstituted Alkenes: A Complementary Process to the Claisen Rearrangement Justin K. Belardi and Glenn C. Micalizio pp 16870–16872 DOI: 10.1021/ja8074242 Supporting Info

Structural and Dynamic Characterization of Intrinsically Disordered Human Securin by NMR Spectroscopy Veronika Csizmok, Isabella C. Felli, Peter Tompa, Lucia Banci and Ivano Bertini pp 16873–16879 DOI: 10.1021/ja805510b Supporting Info

Electronic Evolution of Poly(3,4-ethylenedioxythiophene) (PEDOT): From the Isolated Chain to the Pristine and Heavily Doped Crystals Eung-Gun Kim and Jean-Luc Brdas pp 16880–16889 DOI: 10.1021/ja806389b Supporting Info

Quantum Chemical Approach to the Mechanism for the Biological Conversion of Tyrosine to Dopaquinone Toshinori Inoue, Yoshihito Shiota and Kazunari Yoshizawa pp 16890–16897 DOI: 10.1021/ja802618s Supporting Info

Theoretical and Experimental Studies on the Mechanism of Norbornadiene Pauson−Khand Cycloadducts Photorearrangement. Is There a Pathway on the Excited Singlet Potential Energy Surface? Santiago Olivella, Albert Sol, Agust Lled, Yining Ji, Xavier Verdaguer, Rafael Suau and Antoni Riera pp 16898–16907 DOI: 10.1021/ja802666v Supporting Info

Generation of Oxide Nanopatterns by Combining Self-Assembly of S-Layer Proteins and Area-Selective Atomic Layer Deposition Jiurong Liu, Yuanbing Mao, Esther Lan, Diosdado Rey Banatao, G. Jason Forse, Jun Lu, Hans-Olof Blom, Todd O. Yeates, Bruce Dunn and Jane P. Chang pp 16908–16913 DOI: 10.1021/ja803186e Supporting Info

Extensive Formation of Off-Pathway Species during Folding of an α−β Parallel Protein Is Due to Docking of (Non)native Structure Elements in Unfolded Molecules Sanne M. Nabuurs, Adrie H. Westphal and Carlo P. M. van Mierlo pp 16914–16920 DOI: 10.1021/ja803841n Supporting Info

Generation and O2 Adsorption Studies of the Microporous Magnets CsNi[Cr(CN)6] (TC = 75 K) and Cr3[Cr(CN)6]2·6H2O (TN = 219 K) Steven S. Kaye, Hye Jin Choi and Jeffrey R. Long pp 16921–16925 DOI: 10.1021/ja803926y Supporting Info

Hydrocarbon Adsorption in the Flexible Metal Organic Frameworks MIL-53(Al, Cr) Thuy Khuong Trung, Philippe Trens, Nathalie Tanchoux, Sandrine Bourrelly, Philip L. Llewellyn, Sandra Loera-Serna, Christian Serre, Thierry Loiseau, Franois Fajula and Grard Frey pp 16926–16932 DOI: 10.1021/ja8039579 Supporting Info

Involvement of Water in Carbohydrate−Protein Binding: Concanavalin A Revisited Renuka Kadirvelraj, B. Lachele Foley, Jane D. Dyekjær and Robert J. Woods pp 16933–16942 DOI: 10.1021/ja8039663 Supporting Info

Growth-Controlled Formation of Porous Coordination Polymer Particles Won Cho, Hee Jung Lee and Moonhyun Oh pp 16943–16946 DOI: 10.1021/ja8039794 Supporting Info

Base-by-Base Dynamics in DNA Hybridization Probed by Fluorescence Correlation Spectroscopy Xudong Chen, Yan Zhou, Peng Qu and Xin Sheng Zhao pp 16947–16952 DOI: 10.1021/ja804628x

Preparation and Properties of Metallic, Superhard Rhenium Diboride Crystals Jonathan B. Levine, Sandy L. Nguyen, Haider I. Rasool, Jeffrey A. Wright, Stuart E. Brown and Richard B. Kaner pp 16953–16958 DOI: 10.1021/ja804989q

Metal Quinolinolate−Fullerene(s) Donor−Acceptor Complexes: Evidence for Organic LED Molecules Acting as Electron Donors in Photoinduced Electron-Transfer Reactions Francis D’Souza, Eranda Maligaspe, Melvin E. Zandler, Navaneetha K. Subbaiyan, Kei Ohkubo and Shunichi Fukuzumi pp 16959–16967 DOI: 10.1021/ja805027r Supporting Info

Large-Scale Synthesis of Single-Crystalline Iron Oxide Magnetic Nanorings Chun-Jiang Jia, Ling-Dong Sun, Feng Luo, Xiao-Dong Han, Laura J. Heyderman, Zheng-Guang Yan, Chun-Hua Yan, Kun Zheng, Ze Zhang, Mikio Takano, Naoaki Hayashi, Matthias Eltschka, Mathias Klui, Ulrich Rdiger, Takeshi Kasama, Lionel Cervera-Gontard, Rafal E. Dunin-Borkowski, George Tzvetkov and Jrg Raabe pp 16968–16977 DOI: 10.1021/ja805152t Supporting Info

Combined NMR and DFT Studies for the Absolute Configuration Elucidation of the Spore Photoproduct, a UV-Induced DNA Lesion Claire Mantel, Alexia Chandor, Didier Gasparutto, Thierry Douki, Mohamed Atta, Marc Fontecave, Pierre-Alain Bayle, Jean-Marie Mouesca and Michel Bardet pp 16978–16984 DOI: 10.1021/ja805032r Supporting Info

Interrogation of Surfaces for the Quantification of Adsorbed Species on Electrodes: Oxygen on Gold and Platinum in Neutral Media Joaqun Rodrguez-Lpez, Mario A. Alpuche-Avils and Allen J. Bard pp 16985–16995 DOI: 10.1021/ja8050553 Supporting Info

A Tunable Photosensor Yan-Li Zhao, Liangbing Hu, George Grner and J. Fraser Stoddart pp 16996–17003 DOI: 10.1021/ja805393b Supporting Info

Composition Control and Localization of S2− in CdSSe Quantum Dots Grown from Li4[Cd10Se4(SPh)16] Derek D. Lovingood, Ryan E. Oyler and Geoffrey F. Strouse pp 17004–17011 DOI: 10.1021/ja805453s Supporting Info

Electron Emission Originated from Free-Electron-like States of Alkali-Doped Boron−Nitride Nanotubes Binghai Yan, Changwon Park, Jisoon Ihm, Gang Zhou, Wenhui Duan and Noejung Park pp 17012–17015 DOI: 10.1021/ja805557g Supporting Info

Kinetic Analysis of Arsenic−Metalation of Human Metallothionein: Significance of the Two-Domain Structure Thanh T. Ngu, Alexandria Easton and Martin J. Stillman pp 17016–17028 DOI: 10.1021/ja8060326 Supporting Info

Synthesis and Characterization of Fluorescent Displacers for Online Monitoring of Displacement Chromatography Christopher J. Morrison, Sun Kyu Park, Chester Simocko, Scott A. McCallum, Steven M. Cramer and J. A. Moore pp 17029–17037 DOI: 10.1021/ja806279x

Role of Solvent, pH, and Molecular Size in Excited-State Deactivation of Key Eumelanin Building Blocks: Implications for Melanin Pigment Photostability M. Gauden, A. Pezzella, L. Panzella, M. T. Neves-Petersen, E. Skovsen, S. B. Petersen, K. M. Mullen, A. Napolitano, M. d’Ischia and V. Sundstrm pp 17038–17043 DOI: 10.1021/ja806345q

Morphology-Controlled Self-Assembled Nanostructures of 5,15-Di[4-(5-acetylsulfanylpentyloxy)phenyl]porphyrin Derivatives. Effect of Metal−Ligand Coordination Bonding on Tuning the Intermolecular Interaction Yingning Gao, Xiaomei Zhang, Changqin Ma, Xiyou Li and Jianzhuang Jiang pp 17044–17052 DOI: 10.1021/ja8067337 Supporting Info

PhzA/B Catalyzes the Formation of the Tricycle in Phenazine Biosynthesis Ekta G. Ahuja, Petra Janning, Matthias Mentel, Almut Graebsch, Rolf Breinbauer, Wolf Hiller, Burkhard Costisella, Linda S. Thomashow, Dmitri V. Mavrodi and Wulf Blankenfeldt pp 17053–17061 DOI: 10.1021/ja806325k Supporting Info

Molecular Puzzle Ring: pseudo[1]Rotaxane from a Flexible Cyclodextrin Derivative Atsuhisa Miyawaki, Paul Kuad, Yoshinori Takashima, Hiroyasu Yamaguchi and Akira Harada pp 17062–17069 DOI: 10.1021/ja806620z Supporting Info

Silk Fiber Assembly Studied by Synchrotron Radiation SAXS/WAXS and Raman Spectroscopy Anne Martel, Manfred Burghammer, Richard J. Davies, Emanuela Di Cola, Charlotte Vendrely and Christian Riekel pp 17070–17074 DOI: 10.1021/ja806654t Supporting Info

Targeting Inactive Enzyme Conformation: Aryl Diketoacid Derivatives as a New Class of PTP1B Inhibitors Sijiu Liu, Li-Fan Zeng, Li Wu, Xiao Yu, Ting Xue, Andrea M. Gunawan, Ya-Qiu Long and Zhong-Yin Zhang pp 17075–17084 DOI: 10.1021/ja8068177 Supporting Info

A Surprising Mechanistic “Switch” in Lewis Acid Activation: A Bifunctional, Asymmetric Approach to α-Hydroxy Acid Derivatives Ciby J. Abraham, Daniel H. Paull, Tefsit Bekele, Michael T. Scerba, Travis Dudding and Thomas Lectka pp 17085–17094 DOI: 10.1021/ja806818a Supporting Info

Photostable Single-Molecule Nanoparticle Optical Biosensors for Real-Time Sensing of Single Cytokine Molecules and Their Binding Reactions Tao Huang, Prakash D. Nallathamby and Xiao-Hong Nancy Xu pp 17095–17105 DOI: 10.1021/ja8068853 Supporting Info

Molecular Tectonics: Control of Reversible Water Release in Porous Charge-Assisted H-Bonded Networks Pierre Dechambenoit, Sylvie Ferlay, Nathalie Kyritsakas and Mir Wais Hosseini pp 17106–17113 DOI: 10.1021/ja806916t Supporting Info

Control of H- and J-Aggregate Formation via Host−Guest Complexation using Cucurbituril Hosts Suresh Gadde, Elizabeth K. Batchelor, Joshua P. Weiss, Yonghua Ling and Angel E. Kaifer pp 17114–17119 DOI: 10.1021/ja807197c Supporting Info

Conformation and Dynamics of a Rhodamine Probe Attached at Two Sites on a Protein: Implications for Molecular Structure Determination in situ Alfonso De Simone, John E. T. Corrie, Robert E. Dale, Malcolm Irving and Franca Fraternali pp 17120–17128 DOI: 10.1021/ja807264v Supporting Info

Protein Polarization Is Critical to Stabilizing AF-2 and Helix-2′ Domains in Ligand Binding to PPAR-γ C. G. Ji and J. Z. H. Zhang pp 17129–17133 DOI: 10.1021/ja807374x

Self-Assembling Peptide Coatings Designed for Highly Luminescent Suspension of Single-Walled Carbon Nanotubes Dmitri A. Tsyboulski, Erica L. Bakota, Leah S. Witus, John-David R. Rocha, Jeffrey D. Hartgerink and R. Bruce Weisman pp 17134–17140 DOI: 10.1021/ja807224x Supporting Info

Isolation and Crystal Structures of Both Enol and Keto Tautomer Intermediates in a Hydration of an Alkyne−Carboxylic Acid Ester Catalyzed by Iridium Complexes in Water Hironobu Kanemitsu, Keiji Uehara, Shunichi Fukuzumi and Seiji Ogo pp 17141–17147 DOI: 10.1021/ja807254d Supporting Info

Competition Saturation Transfer Difference Experiments Improved with Isotope Editing and Filtering Schemes in NMR-Based Screening Krisztina Fehr, Patrick Groves, Gyula Batta, Jess Jimnez-Barbero, Claudia Muhle-Goll and Katalin E. Kvr pp 17148–17153 DOI: 10.1021/ja804468k Supporting Info

Transformation of Dinitrosyl Iron Complexes [(NO)2Fe(SR)2]− (R = Et, Ph) into [4Fe-4S] Clusters [Fe4S4(SPh)4]2−: Relevance to the Repair of the Nitric Oxide-Modified Ferredoxin [4Fe-4S] Clusters Chih-Chin Tsou, Zong-Sian Lin, Tsai-Te Lu and Wen-Feng Liaw pp 17154–17160 DOI: 10.1021/ja806050x Supporting Info

Efficient Formation of Ring Structures Utilizing Multisite Activation by Indium Catalysis Yoshimitsu Itoh, Hayato Tsuji, Ken-ichi Yamagata, Kohei Endo, Iku Tanaka, Masaharu Nakamura and Eiichi Nakamura pp 17161–17167 DOI: 10.1021/ja805657h Supporting Info

Spontaneous Compositional Nanopatterning in Li-Containing Perovskite Oxides Beth S. Guiton and Peter K. Davies pp 17168–17173 DOI: 10.1021/ja806130u Supporting Info

C−H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene Yasuhiro Ohki, Tsubasa Hatanaka and Kazuyuki Tatsumi pp 17174–17186 DOI: 10.1021/ja8063028 Supporting Info

The Taxol Pathway 10-O-Acetyltransferase Shows Regioselective Promiscuity with the Oxetane Hydroxyl of 4-Deacetyltaxanes Mark E. Ondari and Kevin D. Walker pp 17187–17194 DOI: 10.1021/ja8067534

Production of H2 from Combined Endothermic and Exothermic Hydrogen Carriers Dominik Wechsler, Yi Cui, Darrell Dean, Boyd Davis and Philip G. Jessop pp 17195–17203 DOI: 10.1021/ja806721s Supporting Info

Book Review of Science and Technology of Polymer Nanofibers p 17204 DOI: 10.1021/ja808193u

Book Review of Chemical Glycobiology. ACS Symposium Series 990 p 17204 DOI: 10.1021/ja808194s

Book Review of What is What in the Nanoworld: A Handbook on Nanoscience and Nanotechnology, Completely Revised and Enlarged 2nd ed. p 17204 DOI: 10.1021/ja808460u

Issue 51

Structure of (E)-4-Hydroxy-3-methyl-but-2-enyl Diphosphate Reductase, the Terminal Enzyme of the Non-Mevalonate Pathway Ingo Rekittke, Jochen Wiesner, Rene Rhrich, Ulrike Demmer, Eberhard Warkentin, Weiya Xu, Kathrin Troschke, Martin Hintz, Joo Hwan No, Evert C. Duin, Eric Oldfield, Hassan Jomaa and Ulrich Ermler pp 17206–17207 DOI: 10.1021/ja806668q Supporting Info

Electron-Transfer-Catalyzed Dimerization of trans-Anethole: Detection of the Distonic Tetramethylene Radical Cation Intermediate by Extractive Electrospray Ionization Mass Spectrometry Cesar A. Marquez, Haoyang Wang, Francesco Fabbretti and Jrgen O. Metzger pp 17208–17209 DOI: 10.1021/ja806791c Supporting Info

Alternate 13C−12C Labeling for Complete Mainchain Resonance Assignments using Cα Direct-Detection with Applicability Toward Fast Relaxing Protein Systems Koh Takeuchi, Zhen-Yu J. Sun and Gerhard Wagner pp 17210–17211 DOI: 10.1021/ja806956p Supporting Info

Synthesis and Two-Photon Absorption Enhancement of Porphyrin Macrocycles Jeffery E. Raymond, Ajit Bhaskar, Theodore Goodson, , Naoyuki Makiuchi, Kazuya Ogawa and Yoshiaki Kobuke pp 17212–17213 DOI: 10.1021/ja804415b Supporting Info

Surface-Enhanced Raman Scattering Tags for Rapid and Homogeneous Detection of Circulating Tumor Cells in the Presence of Human Whole Blood Michael Y. Sha, Hongxia Xu, Michael J. Natan and Remy Cromer pp 17214–17215 DOI: 10.1021/ja804494m Supporting Info

Band-Selective 1H−13C Cross-Polarization in Fast Magic Angle Spinning Solid-State NMR Spectroscopy Sgolne Laage, Alessandro Marchetti, Julien Sein, Roberta Pierattelli, Hans Juergen Sass, Stephan Grzesiek, Anne Lesage, Guido Pintacuda and Lyndon Emsley pp 17216–17217 DOI: 10.1021/ja805926d Supporting Info

Diamond-Based Molecular Platform for Photoelectrochemistry Yu Lin Zhong, Anupam Midya, Zhaoyue Ng, Zhi-Kuan Chen, Michael Daenen, Milos Nesladek and Kian Ping Loh pp 17218–17219 DOI: 10.1021/ja805977f Supporting Info

Glutamic Acid 181 Is Uncharged in Dark-Adapted Visual Rhodopsin Sivakumar Sekharan and Volker Buss pp 17220–17221 DOI: 10.1021/ja805992d

Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks Chun-Long Chen and Alicia M. Beatty pp 17222–17223 DOI: 10.1021/ja806180z Supporting Info

A Fok I/DNA Machine that Duplicates its Analyte Gene Sequence Yossi Weizmann, Zoya Cheglakov and Itamar Willner pp 17224–17225 DOI: 10.1021/ja806222e Supporting Info

Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes Yuichi Kajita, Takuya Kurahashi and Seijiro Matsubara pp 17226–17227 DOI: 10.1021/ja806569h Supporting Info

Lowest Transition State for the Chirality-Determining Step in Ru((R)-BINAP)-Catalyzed Asymmetric Hydrogenation of Methyl-3-Oxobutanoate Satoshi Maeda and Koichi Ohno pp 17228–17229 DOI: 10.1021/ja8065732 Supporting Info

19F NMR Spectroscopy for the Analysis of RNA Secondary Structure Populations Dagmar Graber, Holger Moroder and Ronald Micura pp 17230–17231 DOI: 10.1021/ja806716s Supporting Info

Catalytic Enantioselective Intermolecular Hydroacylation: Rhodium-Catalyzed Combination of β-S-Aldehydes and 1,3-Disubstituted Allenes James D. Osborne, Helen E. Randell-Sly, Gordon S. Currie, Andrew R. Cowley and Michael C. Willis pp 17232–17233 DOI: 10.1021/ja8069133 Supporting Info

Discrete Magnetic Patterns of Nonionic and Ionic Clathrate Hydrates Kyuchul Shin, Minjun Cha, Sukjeong Choi, Joonghoe Dho and Huen Lee pp 17234–17235 DOI: 10.1021/ja806927d Supporting Info

Enantioselective Total Syntheses of Trichodermamides A and B Xiaobo Wan and Madeleine M. Joulli pp 17236–17237 DOI: 10.1021/ja807011b Supporting Info

Pick-and-Place Using Chemically Actuated Microgrippers Jatinder S. Randhawa, Timothy G. Leong, Noy Bassik, Bryan R. Benson, Matthew T. Jochmans and David H. Gracias pp 17238–17239 DOI: 10.1021/ja806961p Supporting Info

Control of Surface Plasmon Localization via Self-Assembly of Silver Nanoparticles along Silver Nanowires M. Linh Tran, Silvia P. Centeno, James A. Hutchison, Hans Engelkamp, Duoduo Liang, Gustaaf Van Tendeloo, Bert F. Sels, Johan Hofkens and Hiroshi Uji-i pp 17240–17241 DOI: 10.1021/ja807218e Supporting Info

A Simple and Versatile Route to Stable Quantum Dot−Dye Hybrids in Nonaqueous and Aqueous Solutions Ting Ren, Prasun K. Mandal, Wolfgang Erker, Zhihong Liu, Yuri Avlasevich, Larissa Puhl, Klaus Mllen and Thomas Basch pp 17242–17243 DOI: 10.1021/ja8073962 Supporting Info

An Efficient Convergent Synthesis of GP1c Ganglioside Epitope Hiroshi Tanaka, Yuji Nishiura and Takashi Takahashi pp 17244–17245 DOI: 10.1021/ja807482t Supporting Info

Integrated Molecular Chirality, Absolute Helicity, and Intrinsic Chiral Topology in Three-Dimensional Open-Framework Materials Jian Zhang, Shumei Chen, Areg Zingiryan and Xianhui Bu pp 17246–17247 DOI: 10.1021/ja8075692 Supporting Info

α-Helix Stabilization within a Peptide Dendrimer Sacha Javor, Antonino Natalello, Silvia Maria Doglia and Jean-Louis Reymond pp 17248–17249 DOI: 10.1021/ja8076236 Supporting Info

Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by Copper(I)/TF-BiphamPhos Complexes Chun-Jiang Wang, Gang Liang, Zhi-Yong Xue and Feng Gao pp 17250–17251 DOI: 10.1021/ja807669q Supporting Info

Evidence for Iodine Atoms as Intermediates in the Dye Sensitized Formation of I−I Bonds James M. Gardner, Jovan M. Giaimuccio and Gerald J. Meyer pp 17252–17253 DOI: 10.1021/ja807703m

(S)-2-Amino-6-nitrohexanoic Acid Binds to Human Arginase I through Multiple Nitro−Metal Coordination Interactions in the Binuclear Manganese Cluster Tatiana Y. Zakharian, Luigi Di Costanzo and David W. Christianson pp 17254–17255 DOI: 10.1021/ja807702q Supporting Info

Phase Control in the Synthesis of Magnetic Iron Sulfide Nanocrystals From a Cubane-Type Fe−S Cluster P. V. Vanitha and Paul O’Brien pp 17256–17257 DOI: 10.1021/ja8078187 Supporting Info

Stereoselective, Dual-Mode Ruthenium-Catalyzed Ring Expansion of Alkynylcyclopropanols Barry M. Trost, Jia Xie and Nuno Maulide pp 17258–17259 DOI: 10.1021/ja807894t Supporting Info

Catalytic, Asymmetric α-Fluorination of Acid Chlorides: Dual Metal−Ketene Enolate Activation Daniel H. Paull, Michael T. Scerba, Ethan Alden-Danforth, Leland R. Widger and Thomas Lectka pp 17260–17261 DOI: 10.1021/ja807792c Supporting Info

Ion Transport to the Interior of Metal−Organic Pyrogallol[4]arene Nanocapsules Ping Jin, Scott J. Dalgarno, Charles Barnes, Simon J. Teat and Jerry L. Atwood pp 17262–17263 DOI: 10.1021/ja807983t Supporting Info

Unidirectional Growth of Single-Walled Carbon Nanotubes Naoki Ishigami, Hiroki Ago, Tetsushi Nishi, Ken-ichi Ikeda, Masaharu Tsuji, Tatsuya Ikuta and Koji Takahashi pp 17264–17265 DOI: 10.1021/ja8080549 Supporting Info

Cyclic Ketimines as Superior Electrophiles for NHC-Catalyzed Homoenolate Additions with Broad Scope and Low Catalyst Loadings Michael Rommel, Takeo Fukuzumi and Jeffrey W. Bode pp 17266–17267 DOI: 10.1021/ja807937m Supporting Info

Copper-Catalyzed Reaction of α-Aryldiazoesters with Terminal Alkynes: A Formal [3 + 2] Cycloaddition Route Leading to Indene Derivatives Eun Ju Park, Seok Hwan Kim and Sukbok Chang pp 17268–17269 DOI: 10.1021/ja808080h Supporting Info

A Concise Total Synthesis of (−)-Quinocarcin via Aryne Annulation Kevin M. Allan and Brian M. Stoltz pp 17270–17271 DOI: 10.1021/ja808112y Supporting Info

Adsorbate-Driven Morphological Changes of a Gold Surface at Low Temperatures Jan Hrbek, Friedrich M. Hoffmann, Joon B. Park, Ping Liu, Dario Stacchiola, Yong Soo Hoo, Shuguo Ma, Akira Nambu, Jose A. Rodriguez and Michael G. White pp 17272–17273 DOI: 10.1021/ja8081268

Membrane Transporters for Anions That Use a Relay Mechanism Beth A. McNally, Edward J. O’Neil, Anh Nguyen and Bradley D. Smith pp 17274–17275 DOI: 10.1021/ja8082363 Supporting Info

Palladium-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between Allylic Acetates and Arylboronic Acids Hirohisa Ohmiya, Yusuke Makida, Tatsunori Tanaka and Masaya Sawamura pp 17276–17277 DOI: 10.1021/ja808673n Supporting Info

Unexpected Intermediates and Products in the C−F Bond Activation of Tetrafluorobenzenes with a Bis(triethylphosphine)Nickel Synthon: Direct Evidence of a Rapid and Reversible C−H Bond Activation by Ni(0) Samuel A. Johnson, Carla W. Huff, Ferheen Mustafa and Mark Saliba pp 17278–17280 DOI: 10.1021/ja8081395 Supporting Info

Self-Consistent Synthesis of the Squalene Synthase Inhibitor Zaragozic Acid C via Controlled Oligomerization David A. Nicewicz, Andrew D. Satterfield, Daniel C. Schmitt and Jeffrey S. Johnson pp 17281–17283 DOI: 10.1021/ja808347q Supporting Info

A Structural Resolution Cryo-TEM Study of the Early Stages of MFI Growth Sandeep Kumar, Zhuopeng Wang, R. Lee Penn and Michael Tsapatsis pp 17284–17286 DOI: 10.1021/ja8063167 Supporting Info

Control of Aldol Reaction Pathways of Enolizable Aldehydes in an Aqueous Environment with a Hyperbranched Polymeric Catalyst Yonggui Chi, Steven T. Scroggins, Emine Boz and Jean M. J. Frchet pp 17287–17289 DOI: 10.1021/ja806584q Supporting Info

Self-Assembling Fullerenes for Improved Bulk-Heterojunction Photovoltaic Devices Robert D. Kennedy, Alexander L. Ayzner, Darcy D. Wanger, Christopher T Day, Merissa Halim, Saeed I. Khan, Sarah H. Tolbert, Benjamin J. Schwartz and Yves Rubin pp 17290–17292 DOI: 10.1021/ja807627u Supporting Info

Dipole-Promoted and Size-Dependent Cooperativity between Pyridyl-Containing Triazolophanes and Halides Leads to Persistent Sandwich Complexes with Iodide Yongjun Li, Maren Pink, Jonathan A. Karty and Amar H. Flood pp 17293–17295 DOI: 10.1021/ja8077329 Supporting Info

Detection of a Family of Gadolinium-Containing Endohedral Fullerenes and the Isolation and Crystallographic Characterization of One Member as a Metal−Carbide Encapsulated inside a Large Fullerene Cage Hua Yang, Chunxin Lu, Ziyang Liu, Hongxiao Jin, Yuliang Che, Marilyn M. Olmstead and Alan L. Balch pp 17296–17300 DOI: 10.1021/ja8078303 Supporting Info

Quantum Interference in Acyclic Systems: Conductance of Cross-Conjugated Molecules Gemma C. Solomon, David Q. Andrews, Randall H. Goldsmith, Thorsten Hansen, Michael R. Wasielewski, Richard P. Van Duyne and Mark A. Ratner pp 17301–17308 DOI: 10.1021/ja8044053 Supporting Info

Single Molecule Electronics: Increasing Dynamic Range and Switching Speed Using Cross-Conjugated Species David Q. Andrews, Gemma C. Solomon, Richard P. Van Duyne and Mark A. Ratner pp 17309–17319 DOI: 10.1021/ja804399q Supporting Info

De Novo Design for Functional Amorphous Materials: Synthesis and Thermal and Light-Emitting Properties of Twisted Anthracene-Functionalized Bimesitylenes Jarugu Narasimha Moorthy, Parthasarathy Venkatakrishnan, Palani Natarajan, Duo-Fong Huang and Tahsin J. Chow pp 17320–17333 DOI: 10.1021/ja8042905 Supporting Info

Structures of β-Amino Ester Enolates: New Strategies Using the Method of Continuous Variation Lara R. Liou, Anne J. McNeil, Gilman E. S. Toombes and David B. Collum pp 17334–17341 DOI: 10.1021/ja8016957 Supporting Info

Path Sampling Calculation of Methane Diffusivity in Natural Gas Hydrates from a Water-Vacancy Assisted Mechanism Baron Peters, Nils E. R. Zimmermann, Gregg T. Beckham, Jefferson W. Tester and Bernhardt L. Trout pp 17342–17350 DOI: 10.1021/ja802014m

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Supported by a Sterically Encumbering β-Diketiminate Ligand Hongjun Fan, Debashis Adhikari, Anas A. Saleh, Rodney L. Clark, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, John C. Huffman, Maren Pink, Daniel J. Mindiola and Mu-Hyun Baik pp 17351–17361 DOI: 10.1021/ja803798b Supporting Info

Vertical Columnar Block-Copolymer-Templated Mesoporous Silica via Confined Phase Transformation Barbara Platschek, Nikolay Petkov, Dieter Himsl, Silvia Zimdars, Zhuo Li, Ralf Khn and Thomas Bein pp 17362–17371 DOI: 10.1021/ja803102y Supporting Info

Redox-Active Organometallics: Magnetic and Electronic Couplings through Carbon−Silicon Hybrid Molecular Connectors Paul Hamon, Frederic Justaud, Olivier Cador, Philippe Hapiot, Stphane Rigaut, Loc Toupet, Lahcne Ouahab, Harald Stueger, Jean-Ren Hamon and Claude Lapinte pp 17372–17383 DOI: 10.1021/ja804608z Supporting Info

Pathway for Unfolding of Ubiquitin in Sodium Dodecyl Sulfate, Studied by Capillary Electrophoresis Grgory F. Schneider, Bryan F. Shaw, Andrew Lee, Emanuel Carillho and George M. Whitesides pp 17384–17393 DOI: 10.1021/ja804736t Supporting Info

Solid-State NMR on a Type III Antifreeze Protein in the Presence of Ice Ansgar B. Siemer and Ann E. McDermott pp 17394–17399 DOI: 10.1021/ja8047893 Supporting Info

Hydrolytic Cleavage of an RNA-Model Phosphodiester Catalyzed by a Highly Negatively Charged Polyoxomolybdate [Mo7O24]6− Cluster Gregory Absillis, Els Cartuyvels, Rik Van Deun and Tatjana N. Parac-Vogt pp 17400–17408 DOI: 10.1021/ja804823g Supporting Info

New Highly Polar Semiconductor Ferroelectrics through d8 Cation-O Vacancy Substitution into PbTiO3: A Theoretical Study Joseph W. Bennett, Ilya Grinberg and Andrew M. Rappe pp 17409–17412 DOI: 10.1021/ja8052249

Effects of the Arctic (E22→G) Mutation on Amyloid β-Protein Folding: Discrete Molecular Dynamics Study A. R. Lam, D. B. Teplow, H. E. Stanley and B. Urbanc pp 17413–17422 DOI: 10.1021/ja804984h

Alkylaluminum-Complexed Zirconocene Hydrides: Identification of Hydride-Bridged Species by NMR Spectroscopy Steven M. Baldwin, John E. Bercaw and Hans H. Brintzinger pp 17423–17433 DOI: 10.1021/ja8054723 Supporting Info

Adsorption of CTAB on Hydrophilic Silica Studied by Linear and Nonlinear Optical Spectroscopy Eric Tyrode, Mark W. Rutland and Colin D. Bain pp 17434–17445 DOI: 10.1021/ja805169z Supporting Info

High-Throughput Selection for Cellulase Catalysts Using Chemical Complementation Pamela Peralta-Yahya, Brian T. Carter, Hening Lin, Haiyan Tao and Virginia W. Cornish pp 17446–17452 DOI: 10.1021/ja8055744 Supporting Info

Electron Transfer Dissociation Facilitates the Measurement of Deuterium Incorporation into Selectively Labeled Peptides with Single Residue Resolution Martin Zehl, Kasper D. Rand, Ole N. Jensen and Thomas J. D. Jørgensen pp 17453–17459 DOI: 10.1021/ja805573h Supporting Info

Formation of Formal Disilene Fluoride Adducts Michaela Zirngast, Michaela Flock, Judith Baumgartner and Christoph Marschner pp 17460–17470 DOI: 10.1021/ja805753d Supporting Info

Short Intramolecular Hydrogen Bonds: Derivatives of Malonaldehyde with Symmetrical Substituents Jacqueline C. Hargis, Francesco A. Evangelista, Justin B. Ingels and Henry F. Schaefer, pp 17471–17478 DOI: 10.1021/ja8060672 Supporting Info

Rh−Pt Bimetallic Catalysts: Synthesis, Characterization, and Catalysis of Core−Shell, Alloy, and Monometallic Nanoparticles Selim Alayoglu and Bryan Eichhorn pp 17479–17486 DOI: 10.1021/ja8061425 Supporting Info

Spectral Diffusion Induced by Proton Dynamics in Pigment−Protein Complexes Marc Brecht, Hauke Studier, Volker Radics, Jana B. Nieder and Robert Bittl pp 17487–17493 DOI: 10.1021/ja806216p

Hydration IndexA Better Parameter for Explaining Small Molecule Hydration in Inhibition of Ice Recrystallization Roger Y. Tam, Sandra S. Ferreira, Pawel Czechura, Jennifer L. Chaytor and Robert N. Ben pp 17494–17501 DOI: 10.1021/ja806284x Supporting Info

2H Solid-State NMR of Ruthenium Complexes Bernadeta Walaszek, Anna Adamczyk, Tal Pery, Xu Yeping, Torsten Gutmann, Nader de Sousa Amadeu, Stefan Ulrich, Hergen Breitzke, Hans Martin Vieth, Sylviane Sabo-Etienne, Bruno Chaudret, Hans-Heinrich Limbach and Gerd Buntkowsky pp 17502–17508 DOI: 10.1021/ja806344y

Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Triethylsilane Jian Yang, Peter S. White and Maurice Brookhart pp 17509–17518 DOI: 10.1021/ja806419h Supporting Info

Gradual Ordering in Red Abalone Nacre P. U. P. A. Gilbert, Rebecca A. Metzler, Dong Zhou, Andreas Scholl, Andrew Doran, Anthony Young, Martin Kunz, Nobumichi Tamura and Susan N. Coppersmith pp 17519–17527 DOI: 10.1021/ja8065495 Supporting Info

Zeolite-Inspired Low-k Dielectrics Overcoming Limitations of Zeolite Films Salvador Eslava, Jone Urrutia, Abheesh N. Busawon, Mikhail R. Baklanov, Francesca Iacopi, Steliana Aldea, Karen Maex, Johan A. Martens and Christine E. A. Kirschhock pp 17528–17536 DOI: 10.1021/ja8066572

Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes Thibault Cantat, Christopher R. Graves, Kimberly C. Jantunen, Carol J. Burns, Brian L. Scott, Eric J. Schelter, David E. Morris, P. Jeffrey Hay and Jaqueline L. Kiplinger pp 17537–17551 DOI: 10.1021/ja8067287 Supporting Info

Elucidating the Mechanism of a Two-Step Spin Transition in a Nanoporous Metal−Organic Framework Gregory J. Halder, Karena W. Chapman, Suzanne M. Neville, Boujemaa Moubaraki, Keith S. Murray, Jean-Franois Ltard and Cameron J. Kepert pp 17552–17562 DOI: 10.1021/ja8068038 Supporting Info

Nonaqueous Production of Nanostructured Anatase with High-Energy Facets Binghui Wu, Changyou Guo, Nanfeng Zheng, Zhaoxiong Xie and Galen D. Stucky pp 17563–17567 DOI: 10.1021/ja8069715 Supporting Info

Tuning a Three-Component Reaction For Trapping Kinase Substrate Complexes Alexander V. Statsuk, Dustin J. Maly, Markus A. Seeliger, Miles A. Fabian, William H. Biggs, , David J. Lockhart, Patrick P. Zarrinkar, John Kuriyan and Kevan M. Shokat pp 17568–17574 DOI: 10.1021/ja807066f Supporting Info

Intramolecular Valence and Spin Interaction in meso and rac Diastereomers of a p-Quinonoid-Bridged Diruthenium Complex Doyel Kumbhakar, Biprajit Sarkar, Somnath Maji, Shaikh M. Mobin, Jan Fiedler, Francisco A. Urbanos, Reyes Jimnez-Aparicio, Wolfgang Kaim and Goutam Kumar Lahiri pp 17575–17583 DOI: 10.1021/ja807043s Supporting Info

The Role of Electrostatics in Siderophore Recognition by the Immunoprotein Siderocalin1 Trisha M. Hoette, Rebecca J. Abergel, Jide Xu, Roland K. Strong and Kenneth N. Raymond pp 17584–17592 DOI: 10.1021/ja8074665 Supporting Info

Mechanism and Active Site Residues of GDP-Fucose Synthase Stephen T. B. Lau and Martin E. Tanner pp 17593–17602 DOI: 10.1021/ja807799k Supporting Info

Aqueous Inorganic Inks for Low-Temperature Fabrication of ZnO TFTs Stephen T. Meyers, Jeremy T. Anderson, Celia M. Hung, John Thompson, John F. Wager and Douglas A. Keszler pp 17603–17609 DOI: 10.1021/ja808243k

Endohedral Hydrogen Exchange Reactions in C60 (nH2@C60, n = 1−5): Comparison of Recent Methods in a High-Pressure Cooker Tae Bum Lee and Michael L. McKee pp 17610–17619 DOI: 10.1021/ja8071868 Supporting Info

Elucidating the Nature of the Streptomyces plicatus β-Hexosaminidase-Bound Intermediate Using ab initio Molecular Dynamics Simulations Ian R. Greig, Federico Zahariev and Stephen G. Withers pp 17620–17628 DOI: 10.1021/ja805640c Supporting Info

Accurately Probing Slow Motions on Millisecond Timescales with a Robust NMR Relaxation Experiment Dong Long, Maili Liu and Daiwen Yang p 17629 DOI: 10.1021/ja8083253

Design of an Organic Chromophore for P-Type Dye-Sensitized Solar Cells Peng Qin, Hongjun Zhu, Tomas Edvinsson, Gerrit Boschloo, Anders Hagfeldt and Licheng Sun p 17629 DOI: 10.1021/ja8087289

Systematic Synthesis, Isolation, and Photophysical Properties of Linear-Shaped Re(I) Oligomers and Polymers with 2−20 Units Youhei Yamamoto, Shuhei Sawa, Yusuke Funada, Tatsuki Morimoto, Magnus Falkenstrm, Hiroshi Miyasaka, Sayaka Shishido, Tomoji Ozeki, Kazuhide Koike and Osamu Ishitani p 17630 DOI: 10.1021/ja8082945

Issue 52

Experimental Evidence for Hydrogen Tunneling when the Isotopic Arrhenius Prefactor (AH/AD) is Unity Sudhir C. Sharma and Judith P. Klinman pp 17632–17633 DOI: 10.1021/ja806354w Supporting Info

A New 1′-Methylenedisulfide Deoxyribose that Forms an Efficient Cross-Link to DNA Cytosine-5 Methyltransferase (DNMT) Uddhav Kumar Shigdel and Chuan He pp 17634–17635 DOI: 10.1021/ja8064304 Supporting Info

Ethylene/Polar Monomer Copolymerization Behavior of Bis(phenoxy–imine)Ti Complexes: Formation of Polar Monomer Copolymers Hiroshi Terao, Seiichi Ishii, Makoto Mitani, Hidetsugu Tanaka and Terunori Fujita pp 17636–17637 DOI: 10.1021/ja8060479 Supporting Info

Copper Catalyzed Enantioselective Intramolecular Aminooxygenation of Alkenes Peter H. Fuller, Jin-Woo Kim and Sherry R. Chemler pp 17638–17639 DOI: 10.1021/ja806585m Supporting Info

Efficient Squaraine-Based Solution Processable Bulk-Heterojunction Solar Cells Fabio Silvestri, Michael D. Irwin, Luca Beverina, Antonio Facchetti, Giorgio A. Pagani and Tobin J. Marks pp 17640–17641 DOI: 10.1021/ja8067879 Supporting Info

Synthesis and Structural Characterization of Stable Organogold(I) Compounds. Evidence for the Mechanism of Gold-Catalyzed Cyclizations Le-Ping Liu, Bo Xu, Mark S. Mashuta and Gerald B. Hammond pp 17642–17643 DOI: 10.1021/ja806685j Supporting Info

IRMPD Spectroscopy Shows That AGG Forms an Oxazolone b2+ Ion Sung Hwan Yoon, Julia Chamot-Rooke, Brittany R. Perkins, Amy E. Hilderbrand, John C. Poutsma and Vicki H. Wysocki pp 17644–17645 DOI: 10.1021/ja8067929 Supporting Info

Synthesis, Characterization, and Theory of [9]-, [12]-, and [18]Cycloparaphenylene: Carbon Nanohoop Structures Ramesh Jasti, Joydeep Bhattacharjee, Jeffrey B. Neaton and Carolyn R. Bertozzi pp 17646–17647 DOI: 10.1021/ja807126u Supporting Info

Detection of Breast Cancer Microcalcifications Using a Dual-modality SPECT/NIR Fluorescent Probe Kumar R. Bhushan, Preeti Misra, Fangbing Liu, Sanjeev Mathur, Robert E. Lenkinski and John V. Frangioni pp 17648–17649 DOI: 10.1021/ja807099s Supporting Info

Visible Light Responsive Pristine Metal Oxide Photocatalyst: Enhancement of Activity by Crystallization under Hydrothermal Treatment Fumiaki Amano, Akira Yamakata, Kohei Nogami, Masatoshi Osawa and Bunsho Ohtani pp 17650–17651 DOI: 10.1021/ja807438z Supporting Info

7-Azabicyclo[2.2.1]heptane as a Unique and Effective Dialkylamino Auxochrome Moiety: Demonstration in a Fluorescent Rhodamine Dye Xiangzhi Song, Alexis Johnson and James Foley pp 17652–17653 DOI: 10.1021/ja8075617 Supporting Info

Hydrogen Tunneling in Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: Mechanistic Implications John E. Bercaw, George S. Chen, Jay A. Labinger and Bo-Lin Lin pp 17654–17655 DOI: 10.1021/ja807427d Supporting Info

Catalytic Stamp Lithography for Sub-100 nm Patterning of Organic Monolayers Hidenori Mizuno and Jillian M. Buriak pp 17656–17657 DOI: 10.1021/ja807708r Supporting Info

Enantioselective Polymerization of Epoxides: A Highly Active and Selective Catalyst for the Preparation of Stereoregular Polyethers and Enantiopure Epoxides Wataru Hirahata, Renee M. Thomas, Emil B. Lobkovsky and Geoffrey W. Coates pp 17658–17659 DOI: 10.1021/ja807709j Supporting Info

Growth Inhibition to Enhance Conformal Coverage in Thin Film Chemical Vapor Deposition Navneet Kumar, Angel Yanguas-Gil, Scott R. Daly, Gregory S. Girolami and John R. Abelson pp 17660–17661 DOI: 10.1021/ja807802r Supporting Info

Characterization of CalE10, the N-Oxidase Involved in Calicheamicin Hydroxyaminosugar Formation Heather D. Johnson and Jon S. Thorson pp 17662–17663 DOI: 10.1021/ja807557a Supporting Info

A General and Efficient Method for the Site-Specific Dual-Labeling of Proteins for Single Molecule Fluorescence Resonance Energy Transfer Eric M. Brustad, Edward A. Lemke, Peter G. Schultz and Ashok A. Deniz pp 17664–17665 DOI: 10.1021/ja807430h Supporting Info

Complete Switch of Product Selectivity in Asymmetric Direct Aldol Reaction with Two Different Chiral Organocatalysts from a Common Chiral Source Keiji Nakayama and Keiji Maruoka pp 17666–17667 DOI: 10.1021/ja807807p Supporting Info

Mixed Charge-Ordering State of MMX-Type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes with Binary Countercations Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki and Hiroshi Okamoto pp 17668–17669 DOI: 10.1021/ja807901p Supporting Info

Stable Scaffolds for Reacting Si Nanowires with Further Organic Functionalities while Preserving Si−C Passivation of Surface Sites Ossama Assad, Sreenivasa Reddy Puniredd, Thomas Stelzner, Silke Christiansen and Hossam Haick pp 17670–17671 DOI: 10.1021/ja807888k Supporting Info

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen Lars Ulrik Nordstrøm, Henning Vogt and Robert Madsen pp 17672–17673 DOI: 10.1021/ja808129p Supporting Info

Recombination of an Fe−Si−P Linkage to an Fe−P−Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane Masaaki Okazaki, Takahiko Yoshitomi, Junpei Naito, Akira Sato, Takashi Komuro and Hiromi Tobita pp 17674–17675 DOI: 10.1021/ja808443v Supporting Info

Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids Dong-Hui Wang, Tian-Sheng Mei and Jin-Quan Yu pp 17676–17677 DOI: 10.1021/ja806681z Supporting Info

Using Magnetic Levitation To Distinguish Atomic-Level Differences in Chemical Composition of Polymers, and To Monitor Chemical Reactions on Solid Supports Katherine A. Mirica, Scott T. Phillips, Sergey S. Shevkoplyas and George M. Whitesides pp 17678–17680 DOI: 10.1021/ja8074727 Supporting Info

A “Kite” Shaped Styryl End-Capped Benzo[2,1-b:3,4-b′]dithiophene with High Electrical Performances in Organic Thin Film Transistors Yahia Didane, Georg H. Mehl, Atsufumi Kumagai, Noriyuki Yoshimoto, Christine Videlot-Ackermann and Hugues Brisset pp 17681–17683 DOI: 10.1021/ja807504k Supporting Info

Reversible Switching of pRNA Activity on the DNA Packaging Motor of Bacteriophage phi29 Seung Hyeon Ko, Yi Chen, Dan Shu, Peixuan Guo and Chengde Mao pp 17684–17687 DOI: 10.1021/ja806075d

Structural and Dynamics Study of DNA Dodecamer Duplexes That Contain Un-, Hemi-, or Fully Methylated GATC Sites Jongchul Bang, Sung-Hun Bae, Chin-Ju Park, Joon-Hwa Lee and Byong-Seok Choi pp 17688–17696 DOI: 10.1021/ja8038272

Correlation of Hydrogen-Atom Abstraction Reaction Efficiencies for Aryl Radicals with their Vertical Electron Affinities and the Vertical Ionization Energies of the Hydrogen-Atom Donors Linhong Jing, John J. Nash and Hilkka I. Kenttmaa pp 17697–17709 DOI: 10.1021/ja801707p Supporting Info

Complete Mechanism of σ* Intramolecular Aromatic Hydroxylation through O2 Activation by a Macrocyclic Dicopper(I) Complex Albert Poater, Xavi Ribas, Antoni Llobet, Luigi Cavallo and Miquel Sol pp 17710–17717 DOI: 10.1021/ja801913b Supporting Info

Evidence for Partially Bound States in Cooperative Molecular Recognition Interfaces Elena Chekmeneva, Christopher A. Hunter, Martin J. Packer and Simon M. Turega pp 17718–17725 DOI: 10.1021/ja803434z Supporting Info

Hindered Cluster Rotation and 45Sc Hyperfine Splitting Constant in Distonoid Anion Radical Sc3N@C80−, and Spatial Spin−Charge Separation as a General Principle for Anions of Endohedral Fullerenes with Metal-Localized Lowest Unoccupied Molecular Orbitals Alexey A. Popov and Lothar Dunsch pp 17726–17742 DOI: 10.1021/ja804226a Supporting Info

Sequence-Specific Unusual (1→2)-Type Helical Turns in α/β-Hybrid Peptides Panchami Prabhakaran, Sangram S. Kale, Vedavati G. Puranik, P. R. Rajamohanan, Olga Chetina, Judith A. K. Howard, Hans-Jrg Hofmann and Gangadhar J. Sanjayan pp 17743–17754 DOI: 10.1021/ja804297f Supporting Info

Highly Regioselective Derivatization of Trimetallic Nitride Templated Endohedral Metallofullerenes via a Facile Photochemical Reaction Chunying Shu, Carla Slebodnick, Liaosa Xu, Hunter Champion, Tim Fuhrer, Ting Cai, Jonathan E. Reid, Wujun Fu, Kim Harich, Harry C. Dorn and Harry W. Gibson pp 17755–17760 DOI: 10.1021/ja804909t Supporting Info

Helical Lanthanide(III) Complexes with Chiral Nonaaza Macrocycle Janusz Gregoliski, Przemysław Starynowicz, KimNgan T. Hua, Jamie L. Lunkley, Gilles Muller and Jerzy Lisowski pp 17761–17773 DOI: 10.1021/ja805033j Supporting Info

Sequence-Scrambling Fragmentation Pathways of Protonated Peptides Christian Bleiholder, Sandra Osburn, Todd D. Williams, Sndor Suhai, Michael Van Stipdonk, Alex G. Harrison and Bla Paizs pp 17774–17789 DOI: 10.1021/ja805074d Supporting Info

Regeneration of Lithium Aluminum Hydride Jason Graetz, James Wegrzyn and James J. Reilly pp 17790–17794 DOI: 10.1021/ja805353w

In Situ Characterization of Elusive Salt HydratesThe Crystal Structures of the Heptahydrate and Octahydrate of Sodium Sulfate Iain D. H. Oswald, Andrea Hamilton, Christopher Hall, William G. Marshall, Timothy J. Prior and Colin R. Pulham pp 17795–17800 DOI: 10.1021/ja805429m Supporting Info

Facilitated Diffusion of Iron(II) and Dioxygen Substrates into Human H-Chain Ferritin. A Fluorescence and Absorbance Study Employing the Ferroxidase Center Substitution Y34W Fadi Bou-Abdallah, Guanghua Zhao, Giorgio Biasiotto, Maura Poli, Paolo Arosio and N. Dennis Chasteen pp 17801–17811 DOI: 10.1021/ja8054035 Supporting Info

Axially Chiral β,β′-Bisporphyrins: Synthesis and Configurational Stability Tuned by the Central Metals Gerhard Bringmann, Daniel C. G. Gtz, Tobias A. M. Gulder, Tim H. Gehrke, Torsten Bruhn, Thomas Kupfer, Krzysztof Radacki, Holger Braunschweig, Alexander Heckmann and Christoph Lambert pp 17812–17825 DOI: 10.1021/ja8055886 Supporting Info

The Amyloid-β Peptide of Alzheimer’s Disease Binds CuI in a Linear Bis-His Coordination Environment: Insight into a Possible Neuroprotective Mechanism for the Amyloid-β Peptide Jason Shearer and Veronika A. Szalai pp 17826–17835 DOI: 10.1021/ja805940m Supporting Info

Photochromism of an Organorhodium Dithionite Complex in the Crystalline-State: Molecular Motion of Pentamethylcyclopentadienyl Ligands Coupled to Atom Rearrangement in a Dithionite Ligand Hidetaka Nakai, Takashi Nonaka, Yousuke Miyano, Motohiro Mizuno, Yoshiki Ozawa, Koshiro Toriumi, Nobuaki Koga, Takanori Nishioka, Masahiro Irie and Kiyoshi Isobe pp 17836–17845 DOI: 10.1021/ja807150a Supporting Info

Terahertz Spectra and Normal Mode Analysis of the Crystalline VA Class Dipeptide Nanotubes Hailiang Zhang, Karen Siegrist, David F. Plusquellic and Susan K. Gregurick pp 17846–17857 DOI: 10.1021/ja805581n Supporting Info

Altered Transition State for the Reaction of an RNA Model Catalyzed by a Dinuclear Zinc(II) Catalyst Tim Humphry, Subashree Iyer, Olga Iranzo, Janet R. Morrow, John P. Richard, Piotr Paneth and Alvan C. Hengge pp 17858–17866 DOI: 10.1021/ja8059864 Supporting Info

Allosteric Actuation of Inverse Phase Transition of a Stimulus-Responsive Fusion Polypeptide by Ligand Binding Bumjoon Kim and Ashutosh Chilkoti pp 17867–17873 DOI: 10.1021/ja8059057 Supporting Info

Interfacial Electron-Transfer Kinetics in Metal-Free Organic Dye-Sensitized Solar Cells: Combined Effects of Molecular Structure of Dyes and Electrolytes Masanori Miyashita, Kenji Sunahara, Tomohiro Nishikawa, Yu Uemura, Nagatoshi Koumura, Kohjiro Hara, Atsunori Mori, Takao Abe, Eiji Suzuki and Shogo Mori pp 17874–17881 DOI: 10.1021/ja803534u Supporting Info

Structural and Magnetic Study of O2 Molecules Arranged along a Channel in a Flexible Single-Crystal Host Family Satoshi Takamizawa, Ei-ichi Nakata, Takamasa Akatsuka, Chihiro Kachi-Terajima and Ryosuke Miyake pp 17882–17892 DOI: 10.1021/ja806257m Supporting Info

Intermolecular Cope-Type Hydroamination of Alkenes and Alkynes using Hydroxylamines Joseph Moran, Serge I. Gorelsky, Elena Dimitrijevic, Marie-Eve Lebrun, Anne-Catherine Bdard, Catherine Sguin and Andr M. Beauchemin pp 17893–17906 DOI: 10.1021/ja806300r Supporting Info

Rate-Dependent Energy Release Mechanism of Gold Nanowires under Elongation Qing Pu, Yongsheng Leng and Peter T. Cummings pp 17907–17912 DOI: 10.1021/ja806319g Supporting Info

A Robust Platform for the Synthesis of New Tetracycline Antibiotics Cuixiang Sun, Qiu Wang, Jason D. Brubaker, Peter M. Wright, Christian D. Lerner, Kevin Noson, Mark Charest, Dionicio R. Siegel, Yi-Ming Wang and Andrew G. Myers pp 17913–17927 DOI: 10.1021/ja806629e Supporting Info

Persistence of Camptothecin Analog−Topoisomerase I−DNA Ternary Complexes: A Molecular Dynamics Study Fung-Ming Siu and Chi-Ming Che pp 17928–17937 DOI: 10.1021/ja806934y Supporting Info

Enantiospecific Total Synthesis of the Hapalindoles, Fischerindoles, and Welwitindolinones via a Redox Economic Approach Jeremy M. Richter, Yoshihiro Ishihara, Takeshi Masuda, Brandon W. Whitefield, Toms Llamas, Antti Pohjakallio and Phil S. Baran pp 17938–17954 DOI: 10.1021/ja806981k Supporting Info

The Changing Hydrogen-Bond Network of Water from the Bulk to the Surface of a Cluster: A Born−Oppenheimer Molecular Dynamics Study N. Galamba and B. J. Costa Cabral pp 17955–17960 DOI: 10.1021/ja807111y Supporting Info

Three-Component Ag-Catalyzed Enantioselective Vinylogous Mannich and Aza-Diels−Alder Reactions with Alkyl-Substituted Aldehydes Hiroki Mandai, Kyoko Mandai, Marc L. Snapper and Amir H. Hoveyda pp 17961–17969 DOI: 10.1021/ja807243t Supporting Info

Fully Conjugated Tri(perylene bisimides): An Approach to the Construction of n-Type Graphene Nanoribbons Hualei Qian, Fabrizia Negri, Chunru Wang and Zhaohui Wang pp 17970–17976 DOI: 10.1021/ja807803j Supporting Info

Micelle Fission through Surface Instability and Formation of an Interdigitating Stalk Maria Sammalkorpi, Mikko Karttunen and Mikko Haataja pp 17977–17980 DOI: 10.1021/ja8077413 Supporting Info

Multinuclear NMR and Kinetic Analysis of DNA Interstrand Cross-Link Formation Hui Ding, Ananya Majumdar, Joel R. Tolman and Marc M. Greenberg pp 17981–17987 DOI: 10.1021/ja807845n Supporting Info

Late Stage Oxidations during the Biosynthesis of the 2-Pyridone Tenellin in the Entomopathogenic Fungus Beauveria bassiana Laura M. Halo, Mary N. Heneghan, Ahmed A. Yakasai, Zhongshu Song, Katherine Williams, Andrew M. Bailey, Russell J. Cox, Colin M. Lazarus and Thomas J. Simpson pp 17988–17996 DOI: 10.1021/ja807052c Supporting Info

Stabilities and Partitioning of Arenonium Ions in Aqueous Media D. A. Lawlor, R. A. More O’Ferrall and S. N. Rao pp 17997–18007 DOI: 10.1021/ja806899d Supporting Info

Autocatalysis in Lithium Diisopropylamide-Mediated Ortholithiations Kanwal J. Singh, Alexander C. Hoepker and David B. Collum pp 18008–18017 DOI: 10.1021/ja807331k Supporting Info

Key Role of Ti(IV) in the Selective Radical−Radical Cross-Coupling Mediated by the Ingold-Fischer Effect Raffaele Spaccini, Nadia Pastori, Angelo Clerici, Carlo Punta and Ombretta Porta pp 18018–18024 DOI: 10.1021/ja807613q Supporting Info

Book Review of Supramolecular Catalysis Jonathan R. Parquette p 18025 DOI: 10.1021/ja808283s

Book Review of International Tables for Crystallography, Volume B: Reciprocal Space, 3rd ed. p 18025 DOI: 10.1021/ja809071k

Book Review of Stereoselective Polymerization with Single-Site Catalysts Eugene Y.-X. Chen pp 18025–18026 DOI: 10.1021/ja808368p

Book Review of Drug−DNA Interactions: Structures and Spectra Jonathan B. Chaires p 18026 DOI: 10.1021/ja808922k

Book Review of Bioorganic and Medicinal Chemistry of Fluorine Gerald B. Hammond pp 18026–18027 DOI: 10.1021/ja808757n

Book Review of Protein Folding, Misfolding and Aggregation: Classical Themes and Novel Approaches Regina Murphy pp 18027–18028 DOI: 10.1021/ja809101f

Book Review of Semiconductor Nanocrystal Quantum Dots: Synthesis, Assembly, Spectroscopy and Applications Gregory D. Scholes p 18028 DOI: 10.1021/ja809158b