Inorganica Chimica Acta
Volume 229
Main Index
Issues 1-2, Pages 1-492 (February 1995)
Editorial Board
Page iii
Preface
Pages 1-3
J. P. Fackler Jr.
Calixarene complexes of the molybdenum-molybdenum quadruple bond
Pages 5-8
Jacqueline A. Acho, Stephen J. Lippard
A model for the ‘shuttling ligand’ of cytochrome
c
oxidase. The synthesis and spectroscopic characterization of allyl-Fe(TPP) and Cp---Fe(TPP)
Pages 9-11
Chris A. James, William Woodruff
Organometallic phosphazenes: synthesis and characterization of Pt(II) and Pt(0) cinnammonitrile cyclophosphazene derivatives
Pages 13-15
Umberto Belluco, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Franco Zingales, Mario Gleria
Conformational diversity in the solid state structures of [Rh
2
(μ-CH
3
N(P(OCH
3
)
2
)
2
)
2
(CH
3
N(P(OCH
3
)
2
)
2
)
2
]X
2
(X = O
3
SCF
3
, B(C
6
H
5
)
4
)
Pages 17-25
Joel T. Mague
Preparation of anhydrous vanadium(II) sulfate compounds from aqueous solutions: the synthesis and characterization of [V(en)
3
]SO
4
, V(bpy)
2
SO
4
and V(py)
4
SO
4
Pages 27-32
Lee M. Daniels, Carlos A. Murillo, Kattia G. Rodríguez
An asymmetric homodinuclear complex containing the μ-oxo-bis(μ-carboxylato)diruthenium(III) core: X-ray structure of [Ru
2
O(O
2
CC
6
H
4
-
p
-OMe)
3
(en)(PPh
3
)
2
](ClO
4
)·3CHCl
3
Pages 33-38
Ariyanchira Syamala, Munirathinam Nethaji, Akhil R. Chakravarty
The resolution of CpMo(NO)(methylallyl)(X) complexes. X-ray crystal structures of (−)-CpMo(NO)(
syn
-crotyl)(1
S
)-10- camphorsulfonate) and (μ-OH)
2
[CpMo(NO)I]
2
Pages 39-45
J. W. Faller, Kevin J. Chase, Maria R. Mazzieri
Coordination and fragmentation of 1,4-dithiacyclohexane by a triosmium cluster
Pages 47-54
Richard D. Adams, Linfeng Chen, John H. Yamamoto
Preparation of
cis
-[MoI
4
(Ph
2
PCH
2
CH
2
PPh
2
)]
−
and structure of (THF)
3
Na(μ-I)
3
MoI(Ph
2
PCH
2
CH
2
PPh
2
) with a new coordination environment around sodium
Pages 55-60
Sundeep P. Mattamana, Rinaldo Poli
Activation of dinuclear gold(I) ylide complexes by Lewis acids. Isomerization of
trans
-[Au(CH
2
)
2
PPhMe]
2
, and the crystal structures of [Au(CH
2
)
2
PPhMe]
2
, [Au(CH
2
)
2
PPhMe]
2
[SO
2
]
2
, [Au(CH
2
)
2
PPh
2
]
2
[SO
2
]
2
and [Au(CH
2
)
2
PPhMe]
2
[S
2
CNEt
2
]
2
Pages 61-75
Dwight D. Heinrich, Richard J. Staples, John P. Fackler Jr.
Synthesis and structure of {Cu
2
(EBPYT)
3
(PF
6
)
2
}
n
(where EBPYT =
N
,
N
′-ethylenebis(pyridin-2-thione)); a novel polymeric complex containing 4-, 18- and 36-membered rings
Pages 77-80
David M. L. Goodgame, Dean A. Katahira, Stephan Menzer, David J. Williams
Evidence of zeolite-solution equilibrium for isomorphous substitution using aqueous metal fluoride complexes
Pages 81-85
Scott Han, Kirk D. Schmitt, Suzanne E. Schramm, David S. Shihabi, Clarence D. Chang
Neutral and anionic halide complexes of ruthenium(IV)
Pages 87-93
Jonathan W. Steed, Derek A. Tocher
Synthesis and crystal structure of the unique chiral anion [Re
2
Cl
7
PBzMePh]
−
and the direct determination of its δ-bond energy by molecular modelling
Pages 95-100
Patrick McArdle, Mary Rabbitte, Desmond Cunningham
Circular dichroism of configurationally chiral dimolybdenum complexes with chiral diamine ligands
Pages 101-103
Michael Gerards
Reactions of monodentate tertiary phosphines with the dirhenium(II) alkyne complexes [Re
2
Cl
3
(μ-dppm)
2
(CO)-(η
2
-RCCH)]X (X = PF
6
or O
3
SCF
3
) to form ylides
Pages 105-112
Keng-Yu Shih, Robert M. Tylicki, Wengan Wu, Phillip E. Fanwick, R. A. Walton
Synthesis and structure of W
2
Cl
4
(μ-dppm)
2
(η
2
-μ-CH
3
CN)
Pages 113-119
Judith L. Eglin, E. Marie Hines, Edward J. Valente, Jeffrey D. Zubkowski
Reaction of tetraethylorthosilicate and hexafluoroacetone trihydrate
Pages 121-125
Joseph P. Carpenter, C. M. Lukehart, Brennan T. Price, James E. Wittig
Tetrakis (μ-difluoroacetato) dimolybdenum(II): solution chemistry and mass spectrum
Pages 127-133
Thomas R. Webb, James D. Pollard, George W. Goodloe, Michael L. McKee
Characterization of the isocyanurate complexes [M(cyan-
N
)- (H
2
O)
5
](cyan-
N
)·2H
2
O (M = Ni, Co, Mn) compounds that form molecular ribbons in the solid state
Pages 135-142
Larry R. Falvello, Isabel Pascual, Milagros Tomás
Metal—metal interaction in ligand-bridged dimolybdenum(0,0) and -(I,0) complexes with very small frontier orbital gaps: electrochemistry and spectroscopic properties of three neighboring oxidation states
Pages 143-151
Wolfgang Kaim, Wolfgang Bruns, Stephan Kohlmann, Michael Krej
ik
Synthesis and structural characterization of some molybdenum carbonyl nitrosyl complexes of diethyldithiocarbamate
Pages 153-163
Kom-Bei Shiu, Sheng-Ting Lin, Shie-Ming Peng, Ming-Chu Cheng
Preparation and spectroscopic studies of the complexes of diacetamide with meta(II) perchlorates
Pages 165-169
Margaret Goodgame, Izhar Hussain
Atomic orbital energies in calcium to copper
Pages 171-178
James L. Bills, Richard L. Snow
Synthesis, spectroscopic studies and reactivity of η
6
-arene derivatives of titanium(IV)
Pages 179-186
Fausto Calderazzo, Guido Pampaloni, Andrea Vallieri
Hindered rotation about single bonds in RuHX(CO)(P
t
Bu
2
Me)
2
and IrHCl
2
(P
t
Bu
2
Me)
2
Pages 187-193
J. Ulrich Notheis, Richard H. Heyn, Kenneth G. Caulton
Transition metal complexes of a tridentate biquinone ligand: electronic structures, charge distributions and magnetic properties
Pages 195-202
Tong Ren
Photochemical ligand rearrangement in dirhodium(II) compounds. Structure of Rh
2
(O
2
CCH
3
)
2
(η
2
-O
2
CCH
3
)[(C
6
H
4
)PPh
2
] (η
2
-PCCl)(PCCl=P-ClC
6
H
4
)Ph
2
Pages 203-209
Abel Garcia-Bernabé, Pascual Lahuerta, M. Angeles Ubeda, Santiago García-Granda, Pilar Pertierra
Oxamide oxime-based copper(II) coordination polymers. Two- and three-dimensional structures controlled by dicarboxylates
Pages 211-219
Satoshi Kawata, Susumu Kitagawa, Hiroyuki Machida, Tadahiro Nakamoto, Mitsuru Kondo, Motomi Katada, Koichi Kikuchi, Isao Ikemoto
The ligand polyhedral model and its application to the fluxional behaviour of M
4
(CO)
12−
n
(M = Co, Rh, Ir;
n
= 1, 2, 4 clusters
Pages 221-227
Yvonne V. Roberts, Brian F. G. Johnson, R. E. Benfield
Protein-bound iron-sulfur clusters: application of a structural database
Pages 229-239
Jeffrey R. Long, R. H. Holm
Preparation and characterization of dirhenium complex anions of the type [Re
2
Cl
7
(dithioether)]
−
with Re---Re quadruple bonds
Pages 241-246
Bruce J. Heyen, J. Gregory Jennings, Gregory L. Powell
Sorption and coprecipitation of trace concentrations of thorium with various minerals under conditions simulating an acid uranium mill effluent environment
Pages 247-252
Edward R. Landa, Anh H. Le, Rudy L. Luck, Philip J. Yeich
Bisperoxovanadium compounds: synthesis and reactivity of some insulin mimetic complexes
Pages 253-260
Alan Shaver, David A. Hall, Jesse B. Ng, Anne-Marie Lebuis, Rosemary C. Hynes, Barry I. Posner
A novel triply bridged dinuclear manganese (III) complex containing the [Mn
2
O(OAc)
2
]
2+
core: synthesis, crystal structure and properties of [Mn
2
(μ-O)(μ-OAc)
2
(bpea)
2
](ClO
4
)
2
Pages 261-270
Sanjay K. Mandal, William H. Armstrong
Gold binding sites in red blood cells
Pages 271-280
Yafei Zhang, Evelyn V. Hess, Keith G. Pryhuber, John G. Dorsey, Katherine Tepperman, R. C. Elder
Magnetic properties of binuclear manganese(II), cobalt(II), nickel(II) and copper(II) complexes of a macrocyclic ligand derived from pyridine-
N
-oxide, and crystal structure of the nickel complex
Pages 281-290
Antony B. Blake, Ekk Sinn, Ahmad Yavari, Boujemaa Moubaraki, Keith S. Murray
Synthesis, structure and reactivity of stable dianionic organometallic complexes of Pt(IV). Crystal structure of [PEtPh
3
]
2
[
cis
-Pt(C
6
F
5
)
2
Cl
4
] and [NBu
4
mer
-Pt(C
6
F
5
)
2
Cl
3
- (NH
2
-
p
-C
6
H
4
CH
3
)]
Pages 291-298
JoséM. Casas, Antonio Martín, Joaquín Oliva, Milagros Tomás
Dinuclear gold(I) and silver(I) derivatives with bridging phosphines containing an imidazole ring; X-ray crystal structure of (1-benzyl-2-imidazolyl)diphenylphosphinegold(I)chloride
Pages 299-305
Alfredo Burini, Bianca Rosa Pietroni, Rossana Galassi, Giovanni Valle, Sandro Calogero
Cycloheptatrienyl bridged heterobimetallic complexes: fluxional behavior and X-ray crystal structure of
syn
-(μ
3
: η
2
-C
7
H
7
)Fe(CO)
3
Pd(η
3
-C
3
H
5
)
Pages 307-313
Wenyi Fu, Robert McDonald, Josef Takats, Andrew H. Bond, Robin D. Rogers
Synthesis and structure of tris[dihydrobis(pyrazolyl)borate](tetrahydrofuran)uranium(III), U[H(μ-H)Bpz
2
]
3
(THF): three-center B---H§d U(III) interactions in the presence of coordinated THF ligand
Pages 315-322
Yimin Sun, Josef Takats, Todd Eberspacher, Victor Day
Synthesis, structure and solid-state polymerization of dimethyl(propynoato)thallium
Pages 323-328
Michael J. Moloney, Bruce M. Foxman
The effect of salt on selectivity in water soluble hydroformylation catalysts
Pages 329-333
Hao Ding, Brian E. Hanson, Thomas E. Glass
Synthesis and structure of titanium tetrathiolate and tantalum pentathiolate complexes. Metal-sulfur bonding in early transition metal compounds
Pages 335-342
Douglas T. Corwin Jr., James F. Corning, Stephen A. Koch, Michelle Millar
Metal-silicon bonding energetics in organo-Group 4 and organo—f-element complexes. Implications for bonding and reactivity
Pages 343-354
Wayne A. King, Tobin J. Marks
The higher hydridospherosiloxanes: synthesis and structures of H
n
Si
n
O
1.5
n
(
n
= 12, 14, 16, 18)
Pages 355-364
Pradyot A. Agaskar, Walter G. Klemperer
Reaction of Rh
2
(μ
2
-O
2
CCH
3
)
3
[μ
2
-(C
6
H
4
)PMePh](HO
2
CCH
3
)
2
with triphenylphosphine: rearrangement of the metalated PMePh
2
ligand and formation of a compound with a diphenylphosphinomethanide group in (P,C) coordination; crystal structure of [Rh
2
(μ
2
-O
2
CCH
3
)
2
{μ
2
-(CH
2
)PPh
2
}- {μ
2
-(C
6
H
4
)PPh
2
}(PPh
3
)]·2CH
2
Cl
2
Pages 365-371
Francisco Estevan, Santiago García-Granda, Pascual Lahuerta, Julio Latorre, Eduardo Peris, Mercedes Sanaú
Acetonitrile complexes of diiridium Part 1. Isolation and characterization of the partially solvated cations [Ir
2
(COD)(μ-form)
2
(MeCN)
3
]
2+
and [Ir
2
(μ-form)
2
(MeCN)
6
]
2+
(COD = 1,5-cyclooctadiene, FORM =
N
,
N
′ -di-
p
-tolylformamidinate)
Pages 373-382
Kim R. Dunbar, Shannon O. Majors, Jui-Sui Sun
On correlating the frequency of the
7
F
0
→
5
D
0
transition in Eu
3+
complexes with the sum of ‘nephelauxetic parameters’ for all of the coordinating atoms
Pages 383-390
Steven T. Frey, William DeW. Horrocks Jr.
Low-nuclearity titanium oxoalkoxides: the trititanates [Ti
3
O](OPr
i
)
10
and [Ti
3
O](OPr
i
)
9
(OMe)
Pages 391-405
Victor W. Day, Todd A. Eberspacher, Yuewu Chen, Jinling Hao, Walter G. Klemperer
An X-ray determination of the electron distribution in crystals of hexapyridine-
N
-oxide cobalt(II) perchlorate and the electronic structure of the Co
2+
ion
Pages 407-415
John S. Wood
Structure and reactivity of an intermediate in the two-electron reduction of dimolybdenum(III) by a hydride ligand in the Mo---H---Mo system
Pages 417-420
Michael Ardon, Avi Bino
Synthesis and identification of pentachloropyridinemolybdate(III) and pentabromopyridinemolybdate(III): crystal structures of [NH
2
(CH
3
)
2
]
2
[MopyCl
5
] and [N(CH
3
)
4
]
2
[MopyCl
5
] (py = pyridine)
Pages 421-424
Jurij V. Bren
i
, Ivan Leban, Barbara Modec, Oliviero Carugo
The binding of dinucleoside phosphonates in the active site of the metallo-enzyme, Staphylococcal nuclease: synthetic, solution and preliminary crystallographic studies
Pages 425-436
P. W. Tucker, M. D. Edge, G. H. Jones, J. G. Moffatt
An analysis of the bonding in some ‘nonclassical’ d
0
and d
10
metal carbonyl complexes
Pages 437-443
Matthew A. Lynn, Bruce E. Bursten
Metal-metal bonding in pentamethylcyclopentadienylmolybdenum(IV) dinuclear compounds: chloride abstraction from non-bonded Cp
*
2
Mo
2
Cl
6
to afford bonded [Cp
*
2
Mo
2
Cl
5
]
+
Pages 445-454
Fatima Abugideiri, James C. Fettinger, Rinaldo Poli
Chemical bonding and electronic structure in the ionic species CrNO
2
and [Cr(H
2
O)
5
NO]
2+
by all electron ab initio multi configurations self consistent field calculations
Pages 455-460
Irene Shim, Karl A. Gingerich, Kim Mandix, Xuejun Feng
Cycloheptatrinyl bridged heterobimetallic complexes: synthesis, fluxional behaviour and X-ray crystal structure of
syn
-[(μ-η
3
;η
2
-C
7
H
7
)Fe(CO)
3
Pt(η
2
, σ
1
-C
8
H
12
---C
5
H
5
)]
Pages 461-468
Marta Airoldi, Tiziana Beringhelli, Giulio Deganello, Giuseppe Gennaro, Massimo Moret, Filippo Saiano, Angelo Sironi
Ultrafast studies of metal-metal bond cleavage in Fe
3
(CO)
12
in solution
Pages 469-471
N. J. Tro, J. C. King, C. B. Harris
Preparation and structure of the face-sharing bioctachedral ion [Mo
2
Cl
8
(PEt
3
)]
2−
Pages 473-476
K. Vidyasagar
Hexacoordinated complexes of bivalent zinc incorporating thioether binding
Pages 477-481
Partha Chakraborty, Swapan Kumar Chandra, Animesh Chakravorty
Preparation and crystal structure of the cluster complex Os
7
H
2
(CO)
21
P(OMe)
3
Pages 483-486
Gregory L. Powell, Thomas F. Tekut
Conference calendar
Pages 487-489
Author index of volume 229
Pages 491-492