Volume 254
Main Index

Issue 1, Pages 1-130 (20 September 1983)

Zur halbempirischen interpretation der 29Si-NMR-chemischen verschiebungen von disilanderivaten Pages C1-C5 R. Radeglia, G. Engelhardt

Author index Page C24

Synthesis and structural characterisation of [Au6(pph3)6]- (NO3)2·3CH2cl2; an edge-shared bitetrahedral gold cluster Pages C18-C20 Clive E. Briant, Kevin P. Hall, D. Michael P. Mingos

[(C6H5)3P]2 N+ [(ophen)(CO)(CN)2W()]− (ophen = 1,10-Phenanthrolin), der erste anionische keten-komplex eines übergangsmetalls Pages C21-C23 E. O. Fischer, Alexander C. Filippou, Helmut G. Alt, Klaus Ackermann

Reactions of organo-thallium(III) and -mercury(II) compounds with nitronate ion and N-benzyl-1,4-dihydronicotinamide: reductive electron-transfer activation of the metal-carbon bond toward homolysis Page C24 H. Kurosawa, H. Okada, M. Sato, T. Hattori

Isomerism and fluxional behaviour in η2 -vinyl complexes resulting in inversion of configuration at an asymmetric carbon atom. The crystal and molecular structures of two isomeric forms of [MoCl{η2 -C(CF3)C(CF3)(PEt3)} (CF3C---CCF3)(η5 -C5H5)] Pages C6-C10 Jack L. Davidson, William F. Wilson, Ljubica Manojlovi-Muir and, Kenneth W. Muir

(η2 -1,3-alkadien) (η5 -cyclopentadienyl)methylnickel-komplexe Pages C11-C14 Herbert Lehmkuhl, Friedhelm Danowski, Reinhard Benn, Anna Rufiska, Gerhard Schroth, Richard Mynott

Synthese und reaktivität von dienylmetallverbindungen : XVIII. Zur koordinierung von tetraphenyldiphosphan in cyclopentadienylnickel-komplexen Pages C15-C17 N. Kuhn, M. Winter

Zur bildungsweise von 1-phenylpropyllithium aus benzyllithium und ethylen in tetrahydrofuran Pages 1-12 Adalbert Maercker, Reinhard Stötzel

Silafunctional compounds in organic synthesis : XVIII. Oxidative cleavage of the silicon-carbon bond in alkenylfluorosilanes to carbonyl compounds: Synthetic and mechanistic aspects Pages 13-22 Kohei Tamao, Munetaka Akita, Makoto Kumada

Kristallstrukturen von isopropyl- und trimethylsilylmethylen-substituierten chloro-hydroxo-tetraorganyl-distannoxanen Pages 23-32 Heinrich Puff, Iris Bung, Edmund Friedrichs, Andrea Jansen

Darstellung und struktur von di-t-butylgermaniumdi-hydroxid und di-t-butylgermaniumoxid Pages 33-41 Heinrich Puff, Sybille Franken, Willi Schuh, Werner Schwab

Alcoholysis of (2-methoxycarbonyl)ethyltin compounds Pages 43-52 Hong-Shing Cheng, Tsai-Lih Hwang, Chao-Shiuan Liu

A new synthesis for methyl/trifluoromethyl organometallic compounds by low temperature cocondensation of trifluoromethyl radicals and main group methyl alkyls Pages 53-58 M. A. Guerra, R. L. Armstrong, W. I. Bailey Jr., R. J. Lagow

Bis(diphenylphosphino)amid-komplexe des platins, palladiums und nickels. Kristallstruktur des N-methylierungsprodukts {CH3N[(C6H5)2P]2}2Pd2+ 2SO3F− Pages 59-68 Hubert Schmidbaur, Sybille Lauteschläger, Beatrix Milewski-Mahrla

ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling Pages 69-73 Heinz Schwemlein, Hans H. Brintzinger

Preparation and properties of molybdenum and tungsten dinitrogen complexes : XX. Reactions of a tungsten-dinitrogen complex with water or alcohols in the presence of ketones. Conversion of ligating dinitrogen into ketazines and isolation of a novel chelate diazo complex as an intermediate Pages 75-82 Atsushi Watakabe, Tamotsu Takahashi, Dou-Man Jin, Ichiro Yokotake, Yasuzo Uchida, Masanobu Hidai

Preparation and properties of ethylene- and 1,3-butadiene-coordinated complexes of iron(0) having dimethylphenylphosphine ligands Pages 83-88 Sanshiro Komiya, Hironori Minato, Takao Ikariya, Takakazu Yamamoto, Akio Yamamoto

Photoinduced formation of phosphido-bridged clusters derived from Ru3(CO)9(PPh2H)3. Crystal and molecular structure of Ru3(μ-H)(μ-PPh2)3(CO)7 Pages 89-103 Richard P. Rosen, Gregory L. Geoffroy, Clifford Bueno, Melvyn Rowen Churchill and, Richard B. Ortega

The alkylation of some ruthenium(II) complexes of ambident heterocyclic ligands Pages 105-110 Edwin C. Constable, Jack Lewis

Electrochemical studies on organometallic compounds , : V. Electrochemical oxidation of the anions [Co(CO)4]− and [Co(CO)3 PPhme2]− Pages 111-117 Y. Mugnier, P. Reeb, C. Moise, E. Laviron

The preparation of cis- and trans-[RhI(CO)(PAr3)2] (Ar= Aryl) and their ready dissociation in solution Pages 119-126 F. R. Hartley, S. G. Murray, D. M. Potter

Intramolecular metallation of o-carboranylphosphine-palladium(II) and -platinum(II) complexes Pages 127-130 V. N. Kalinin, A. V. Usatov, L. I. Zakharkin

Issue 2, Pages C25-C32, 131-271 (27 September 1983)

Interaction of organometallic moleties with carbanions and other electron-rich centers Pages 131-141 Robert C. Kerber

Derivate des borabenzols XVII. Tricarbonyl(1-methylborinato)chrom-derivate Pages 143-147 G.E. Herberich, D. Söhnen

Reactions of coordinated molecules XXXIV. The crystal and molecular structure of [fac-(OC)3Re(CH3CO)3]BBr and further refinement of the molecular structure of [fac-(OC)3Re(CH3CO)3]BCl Pages 149-157 A.J. Baskar, C.M. Lukehart

Synthesis and structure of alkylaluminoxanes Pages 159-166 M. Boleslawski, J. Serwatowski

Crystal and molecular structure of an yttrium dicyclopentadienyl chloride complex with triethylaminalane [ν-(C5H5)2YCl · AlH3 · NEt3]2 Pages 167-172 Emil B. Lobkovsky, Grigoriy L. Solveychik, Boris M. Bulychev, Anatoly B. Erofeev, Aleksey I. Gusev, Natalia I. Kirillova

Infrared spectroscopic study of very low pressure pyrolysis products of cyclosilthianes and 3,3-dimethyl-3-silathietane isolated in argon matrices. A new source of 1,1-dimethyl-1-silaethylene (Me2si=CH2), thioformaldehyde (H2C=S) and dimethylsilanthione (Me2Si=S) Pages 173-187 L.E. Gusel'nikov, V.V. Volkova, V.G. Avakyan, N.S. Nametkin, M.G. Voronkov, S.V. Kirpichenko, E.N. Suslova

Alkaline hydrolysis of methyl[tris(trimethylsilyl)methyl]dichlorostannanE Pages 189-192 V.K. Belsky, N.N. Zemlyansky, I.V. Borisova, N.D. Kolosova, I.P. Beletskaya

The effect on the base strengths of tropone and 2-alkoxytropones of π-complexation with a Cr(CO)3 group Pages 193-198 Kasturi Lal, Nigel T. Leckey, William E. Watts

Metal-stabilized carbanions V. A 1H NMR study of the structures of DI- and tri-phenylmethyl anions in benzylidene-ν5-tricarbonyl- (cyclohexadienyl)chromium(0) Pages 199-205 Alberto Ceccon, Alessandro Gambaro, Anna Maria Romanin, Alfonso Venzo

Electrochemical reduction of π-tricarbonylchromium-phenyldimethylsulfonium tetrafluoroborate in dimethyl sulfoxide Pages 207-217 Alberto Ceccon, Alessandro Gambaro, Anna Maria Romanin, Alfonso Venzo

Cyclisierung und fragmentierung aliphatischer azide an metall-metall-dreifachbindungen: Neuartige reaktionswege gegenüber ihrer thermischen zersetzung ln der gasphase [1,2] Pages 219-241 Wolfgang A. Herrmann, Gangolg W. Kriechbaum, Ralph Dammel, Hans Bock, Manfred L. Ziegler, Heike Pfisterer

Iron carbonyl complexes containing azomethylene fragments II. The trinuclear ortho-metallated Fe3[μ2-η6-o-C6H4CH2N(N=CHC6H5)](CO)8 from benzalazine and Fe3(CO))12 Pages 243-247 N.S. Nametkin, V.D. Tyurin, V.V. Trusov, A.M. Krapivin

Arene-iridium(i) complexes. Crystal structures of [Ir(TFB)(arene)]BF4 (TFB = tetrafluorobenzobarrelene; arene = 1,4-Me2C6H4 or C6Me6) Pages 249-260 R. Usón, L.A. Oro, D. Carmona, M.A. Esteruelas, C. Foces-Foces, F.H. Cano, S. Garcia-Blanco

Preparation and reactions of trans-[(PPh3)2Pt(CH2SR)Cl] (R = Me, Ph or C6H4Me-p) Pages 261-266 Helen D. McPherson, James L. Wardell

Oxalsäurederivate durch oxidative kupplung von kohlenmonoxid an nickel Pages 267-271 Heinz Hoberg, F. Javier Fañanás, Hans Josef RiegeI

Matrix isolation evidence for a primary co dissociation pathway in the photochemistry of the metal-metal bonded dimers (η5-C5H5)2M2(CO)6 (M = Mo, W) Pages C25-C28 Richard H. Hooker, Khalil A. Mahmoud, Antony J. Rest

Preparation and hydride reduction of the electron-rich cations [(Me5C5)Fe(CO)2L]+ (L = CO, PPh3, PMe3) and [(Me5C5)Fe(CO)(Ph2PCH2CH2PPh2)]+ Pages C29-C32 Stephen G. Davies, Stephen J. Simpson, Susan E. Thomas

Issue 3, Pages 273-397 (4 October 1983)

Complex formation between nickel(0) and a phosphaalkene: Influence of the second ligand on the η1- and η2-coordination mode Pages C33-C36 Theodorus A. van der Knaap, Leo W. Jenneskens, Hendrik J. Meeuwissen, Friedrich Bickelhaupt, Dirk Walther, Eckard Dinjus and, Egon Uhlig, Anthony L. Spek

Subject index Pages C42-C47

Author index Pages C41-C42

A reactive and versatile trirhenium carbonyl cluster obtained by oxidation of [re3 (μ-H)4 (CO)10]−. Synthesis, x-ray characterization and reactivity of re3 (μ-H)3 (CO)10(NCMe)2 Pages C37-C41 Gianfranco Ciani, Angelo Sironi, Giuseppe D'Alfonso, Pierfrancesco Romiti and, Maria Freni

Reactions of some sterically-hindered organosilicon hydrides and iodides with halogens Pages 273-282 Colin Eaborn, Abdulrahman I. Mansour

The crystal and molecular structure of tris[(triphenylstannyl)methyl]methane Pages 283-291 André L. Beauchamp, Stephan Latour, Marc J. Olivier, James D. Wuest

Allylstannation III. Synthesis of homoallylic alcohols and 4-chloro-2,6-dialkyl-3-methyltetrahydropyrans by reactions between (E/Z)-2-butenyldichloro-n-butyltin and aldehydes Pages 293-304 Alessandro Gambaro, Andrea Boaretto, Daniele Marton, Giuseppe Tagliavini

Crystal and molecular structure of tricyclopentadienyltetrahydrofuranuranium(III), (η5-C5H5)3U·OC4H8 Pages 305-311 H. J. Wasserman, A. J. Zozulin, D. C. Moody, R. R. Ryan, K. V. Salazar

Electrochemical substitution of a carbonyl group by a phosphorus ligand in arenechromium tricarbonyl complexes Pages 313-315 M. G. Peterleitner, M. V. Tolstaya, V. V. Krivykh, L. I. Denisovitch, M. I. Rybinskaya

Die stereochemie des insertionsprodukts aus bis(η5-cyclopentadienyl)molybdändihydrid und acetylendicarbonsäuredimethylester. Die kristall- und molekülstruktur von bis(η5-cyclopentadienyl)hydrido-[{η1-1,2-bis(methoxycarbonyl)-(Z)-vinyl}molybdän Pages 317-324 G. E. Herberich, B. Hessner, J. Okuda

Reactions of the carbonyl complexes M(CO)3(L)3 (L = py, M = Mo, W; L = NH3, M = Mo) and M(CO)4(2-Mepy)2 (M = Mo,W) with HgX2 (X = Cl, CN, SCN) Pages 325-332 M. A. Lobo, M. F. Perpiñan, M. P. Pardo, M. Cano

The preparation of α-methoxyalkyliron complexes: precursors of secondary carbeneiron complexes Pages 333-337 Charles P. Casey, William H. Miles

Iron carbonyl complexes containing an azomethylene moiety III. Mass-spectrometric study of diiron hexacarbonyl complexes from azomethynes and azines Pages 339-344 A. I. Mikaya, V. G. Zaikin, V. V. Trusov, A. I. Nekhaev, V. D. Tyurin

57Fe NMR Chemical shifts and 57fe, 13C coupling constants in α-ferrocenyl carbocations. Direct metal participation in the stabilization of metallocenyl carbocations Pages 345-360 A. A. Koridze, N. M. Astakhova, P. V. Petrovskii

Cluster chemistry XXIV. X-ray structure of H4 Ru4(CO)9(PMe2 Ph)[P(OC6H4 Me-p)3]-[P(OCH2)3CEt], a chiral cluster complex containing four different ligands Pages 361-369 Michael I. Bruce, Brian K. Nicholson, Jennifer M. Patrick and, Allan H. White

Reactions of [Pd(C6F5)2(CNR)2] with [PdCl2(NCPh)2]. Insertion of p-MeC6H4NC into Pd-C6F5 bonds Pages 371-379 R. Uson, J. Fornies, P. Espinet, E. Lalinde

Reactions of a 2-picolyl-bridged palladium(ii) complex with some pyrazole derivatives Pages 381-387 Masayoshi Onishi, Katsuma Hiraki, Toshihiro Itoh, Yushichiro Ohama

Trigonal bipyramidal platinum complexes as models for ziegler-nasa catalytic sites Pages 389-397 P. Ammendola, M. R. Ciajolo, A. Panunzi, A. Tuzi