Volume 271
Main Index

Issues 1-3, Pages 1-407 (21 August 1984)

Introduction Pages ix-xiii Hideki Sakurai

Note by Regional Editors Page xv C. Eaborn, E. O. Fischer, R. B. King, J. F. Normant, O. A. Reutov

Author index Page C10

The synthesis of functionalised silyltriflates Pages C1-C3 Alan R. Bassindale*, Tim Stout

The chemistry of siloles. Synthesis and reactions of η6-[1-methyl-1-(trimethylsilyl)dibenzosilacyclopentadiene]chromium tricarbonyl Pages C4-C6 Mitsuo Ishikawa, Tatsuru Tabohashi

Le bis(trimethylsilylallyl)-1,3 propene comme precurseur du bis[η3-(trimethylsilyl-1-allyl)chloropalladium], synthese de vinylsilanes fonctionnalises (E) Pages C7-C9 R. J. P. Corriu, N. Escudié, C. Guerin

Subject index Pages C11-C13

Addition of dimethylsilylene to substituted 1,3-butadienes; evidence for concerted 1,2-addition followed by nonconcerted rearrangements via diradical intermediates Pages 1-8 Deqing Lei, Rong-Juh Hwang, Peter P. Caspar

Attempted preparation of silaethylenes from silanecarboxylate esters Pages 9-14 A. G. Brook, Laval Yau

Bicyclo[n.1.0]alkylsilanes: Nouvelle synthese et reactivite Pages 15-22 M. Ahra, M. Grignon-Dubois, J. Dunoguès

Chemistry of organosilicon compounds : CXC. An ESR study of conformational transmission in bis(trimethylsilylmethyl)methyl and related radicals Pages 23-31 Mitsuo Kira, Mieko Akiyama, Hideki Sakurai

Comparisons of the reactivities of the tri-t-butyl- and tris(trimethylsilyl)methyl-silicon compounds Pages 33-46 Colin Eaborn, Anil K. Saxena

Co-pyrolysis of dimethoxymethylsilylbis(trimethylsilyl)amine and hexamethylcyclotrisiloxane. 1,3-Sigmatropic rearrangements of silaimine intermediates Pages 47-53 Samih Amine Kazoura, William P. Weber

Direct spectroscopic study of silaolefins. Vibrational frequencies of R2Si=CD2 (R = CH3, CD3) in an argon matrix Pages 55-67 A. K. Maltsev, V. N. Khabashesku, O. M. Nefedov

Effect of trimethylsilyl groups on Beckmann rearrangements and fragmentations Pages 69-76 Paul F. Hudrlik, Morris A. Waugh, Anne M. Hudrlik

Equilibria between MexSiCl4-x, x = 3, 2, 1, 0 and alkyl carboxylate esters Pages 77-82 Godfrey C. Mbah, John L. Speier

Chemistry of alkali metal-unsaturated hydrocarbon adducts : XI. ESR monitoring of transient radical-anions from unsaturated organosilanes Pages 83-100 John J. Eisch, Leslie E. Smith

Experimental and theoretical study of electrochemical reduction of halosilanes Pages 101-106 Petr Duchek, Robert Ponec, Václav Chvalovský

Formation of organosilicon compounds , : CIV. Investigation into the formation and decomposition of the 1,1,3,3-tetramethyl-2,4-bis(trimethylsilyl)-1,3-disilabicyclo[1.1.0]butane Pages 107-127 G. Fritz, J. Thomas

Gas phase reactions of dichlorosilylene Pages 129-143 E. A. Chernyshev, N. G. Komalenkova, S. A. Bashkirova

Gas phase reactions : XXXXVI. Silabenzene: Photoelectron spectrum from 1-sila-2,5-hexadienepyrolysis and assignment of valence ionisation energies Pages 145-152 Hans Bock, Pavel Rosmus, Bahman Solouki, Günther Maier

Homogeneous catalysis : IX. Hydrosilylation using tris(Pentanedionato)rhodium(III)-trialkylaluminium as catalyst Pages 153-168 Andrew J. Cornish, Michael F. Läppert

Intramolecular coordination in molecules of C6H5COOCH2CH2SiX3 (X = F, Cl) Pages 169-172 M. G. Voronkov, L. I. Gubanova, Yu. L. Frolov, N. F. Chernov, G. A. Gavrilova, N. N. Chipanina

Isomerism and conformation of (N-silyl)bis(diphenylphosphino)amines and bis(N-silyl)diphenylphosphinoamines Pages 173-180 Hubert Schmidbaur, Sybille Lauteschläger, Frank H. Köhler

Methyl- und halogen-substituierte 1-silacyclohexene-2 Pages 181-190 Rainer Münstedt, Dieter Wrobel, Ulrich Wannagat

Novel 2,4-disilathietane ring system from [2 + 2]cycloaddition of 1,1-dimethyl-1-silaethylene,Me2Si=CH2, to dimethylsilanthione, Me2Si=S. Perturbation molecular orbital (PMO) study on reactivity of intermediates with a double-bonded silicon atom Pages 191-206 L. E. Gusel'nikov, V. V. Volkova, V. G. Avakyan, E. A. Volnina, V. G. Zaikin, N. S. Nametkin, A. A. Polyakova and, M. I. Tokarev

Organosilicon synthesis of isocyanates Pages 207-224 V. F. Mironov

Peralkylcyclotrisilane: Crystal and molecular structure of [(t-BuCH2)2Si]3 Pages 225-233 Hamao Watanabe, Motohiko Kato, Tadashi Okawa, Yoichiro Nagai, Midori Goto

Preparation and properties of silyl- and germyl-trifluoromethylacetylenes (1,1,1-trifluoro-4-silabut-2-yne and 1,1,1-trifluoro-4-germabut-2-yne), and molecular structure of silyltrifluoromethylacetylene determined by electron diffraction Pages 235-247 Duncan W. W. Anderson, Stephen Cradock, E. A. V. Ebsworth, Anthony R. Green, David W. H. Rankin, Alan G. Robiette

Quantitative aspects of some unimolecular isomerization reactions of organosilicon intermediates Pages 249-260 Iain M. T. Davidson, Robert J. Scampton

Reactions of organopolysilanes with organic peroxides Pages 261-280 G. A. Razuvaev, T. N. Brevnova, V. V. Semenov

The relative stereochemistry of some α-methyl-β-silylcarbonyl compounds produced by the diastereoselective alkylation of β-silylenolates Pages 281-288 Werner Bernhard, Ian Fleming

1-Silaphenalenes, potential precursors to aromatic silylenium ions and aromatic silyl anions. Spectroscopic and chemical studies Pages 289-297 Ratnasabapathy Sooriyakumaran, Philip Boudjouk

Silene stereochemistry : IV. The configurational stability of 1-phenyl-1-methyl-2-neopentylsilene under flash vacuum thermolysis conditions Pages 299-306 Paul Ronald Jones, Myong E. Lee

Silylation of hydroxyl-containing compounds with aryl- and heteroaryl-hydrosilanes in the presence of amines Pages 307-317 E. Lukevics, M. Dzintara

Simplified approach to silaanthrones and disilaanthracenes Pages 319-326 J. Y. Corey, W. Z. McCarthy

Tertiary alcoholysis of chlorosilanes via tetracoordinate silylated quaternary ammonium intermediates Pages 327-336 H. K. Chu, M. D. Johnson, C. L. Frye

The chemistry of octamethyl-1,2-disilacyclobutane. Some Si---Si cleavage and insertion reactions Pages 337-352 Dietmar Seyferth, Emma W. Goldman, Jean Escudié

The ethylmethylcyclosilanes Pages 353-367 Anita Katti, Corey W. Carlson, Robert West

Theoretical studies of disilabenzenes Pages 369-379 Kim K. Baldridge, Mark S. Gordon

Unsaturated silicon compounds : VII. Preparation and structure of a silaethene tetrahydrofuranate Pages 381-391 Nils Wiberg, Gerhard Wagner, Gerhard Müller and, Jürgen Riede

Penta(methoxycarbonyl)cyclopentadienyl-substituted germanium(II) and tin(II) compounds. X-ray crystal structure of bis[penta(methoxycarbonyl)cyclopentadienyl]tin(II) Pages 393-402 Peter Jutzi, Franz-Xaver Kohl, Ewald Schlüter, Michael B. Hursthouse and, Nigel P. C. Walker

Metal-ylide complexes: Mercury(II), cadmium(II), cobalt(II), and nickel(II) complexes of ambidentate sulfonium ylides Pages 403-407 Ram S. Tewari, Alok K. Awasthi