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Introduction Pages ix-xiii Hideki Sakurai |
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Note by Regional Editors Page xv C. Eaborn, E. O. Fischer, R. B. King, J. F. Normant, O. A. Reutov |
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Author index Page C10 |
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The synthesis of functionalised silyltriflates Pages C1-C3 Alan R. Bassindale*, Tim Stout |
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The chemistry of siloles. Synthesis and reactions of η6-[1-methyl-1-(trimethylsilyl)dibenzosilacyclopentadiene]chromium tricarbonyl Pages C4-C6 Mitsuo Ishikawa, Tatsuru Tabohashi |
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Le bis(trimethylsilylallyl)-1,3 propene comme precurseur du bis[η3-(trimethylsilyl-1-allyl)chloropalladium], synthese de vinylsilanes fonctionnalises (E) Pages C7-C9 R. J. P. Corriu, N. Escudié, C. Guerin |
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Subject index Pages C11-C13 |
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Addition of dimethylsilylene to substituted 1,3-butadienes; evidence for concerted 1,2-addition followed by nonconcerted rearrangements via diradical intermediates Pages 1-8 Deqing Lei, Rong-Juh Hwang, Peter P. Caspar |
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Attempted preparation of silaethylenes from silanecarboxylate esters Pages 9-14 A. G. Brook, Laval Yau |
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Bicyclo[n.1.0]alkylsilanes: Nouvelle synthese et reactivite Pages 15-22 M. Ahra, M. Grignon-Dubois, J. Dunoguès |
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Chemistry of organosilicon compounds : CXC. An ESR study of conformational transmission in bis(trimethylsilylmethyl)methyl and related radicals Pages 23-31 Mitsuo Kira, Mieko Akiyama, Hideki Sakurai |
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Comparisons of the reactivities of the tri-t-butyl- and tris(trimethylsilyl)methyl-silicon compounds Pages 33-46 Colin Eaborn, Anil K. Saxena |
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Co-pyrolysis of dimethoxymethylsilylbis(trimethylsilyl)amine and hexamethylcyclotrisiloxane. 1,3-Sigmatropic rearrangements of silaimine intermediates Pages 47-53 Samih Amine Kazoura, William P. Weber |
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Direct spectroscopic study of silaolefins. Vibrational frequencies of R2Si=CD2 (R = CH3, CD3) in an argon matrix Pages 55-67 A. K. Maltsev, V. N. Khabashesku, O. M. Nefedov |
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Effect of trimethylsilyl groups on Beckmann rearrangements and fragmentations Pages 69-76 Paul F. Hudrlik, Morris A. Waugh, Anne M. Hudrlik |
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Equilibria between MexSiCl4-x, x = 3, 2, 1, 0 and alkyl carboxylate esters Pages 77-82 Godfrey C. Mbah, John L. Speier |
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Chemistry of alkali metal-unsaturated hydrocarbon adducts : XI. ESR monitoring of transient radical-anions from unsaturated organosilanes Pages 83-100 John J. Eisch, Leslie E. Smith |
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Experimental and theoretical study of electrochemical reduction of halosilanes Pages 101-106 Petr Duchek, Robert Ponec, Václav Chvalovský |
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Gas phase reactions of dichlorosilylene Pages 129-143 E. A. Chernyshev, N. G. Komalenkova, S. A. Bashkirova |
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Gas phase reactions : XXXXVI. Silabenzene: Photoelectron spectrum from 1-sila-2,5-hexadienepyrolysis and assignment of valence ionisation energies Pages 145-152 Hans Bock, Pavel Rosmus, Bahman Solouki, Günther Maier |
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Homogeneous catalysis : IX. Hydrosilylation using tris(Pentanedionato)rhodium(III)-trialkylaluminium as catalyst Pages 153-168 Andrew J. Cornish, Michael F. Läppert |
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Intramolecular coordination in molecules of C6H5COOCH2CH2SiX3 (X = F, Cl) Pages 169-172 M. G. Voronkov, L. I. Gubanova, Yu. L. Frolov, N. F. Chernov, G. A. Gavrilova, N. N. Chipanina |
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Isomerism and conformation of (N-silyl)bis(diphenylphosphino)amines and bis(N-silyl)diphenylphosphinoamines Pages 173-180 Hubert Schmidbaur, Sybille Lauteschläger, Frank H. Köhler |
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Methyl- und halogen-substituierte 1-silacyclohexene-2 Pages 181-190 Rainer Münstedt, Dieter Wrobel, Ulrich Wannagat |
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Novel 2,4-disilathietane ring system from [2 + 2]cycloaddition of 1,1-dimethyl-1-silaethylene,Me2Si=CH2, to dimethylsilanthione, Me2Si=S. Perturbation molecular orbital (PMO) study on reactivity of intermediates with a double-bonded silicon atom Pages 191-206 L. E. Gusel'nikov, V. V. Volkova, V. G. Avakyan, E. A. Volnina, V. G. Zaikin, N. S. Nametkin, A. A. Polyakova and, M. I. Tokarev |
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Organosilicon synthesis of isocyanates Pages 207-224 V. F. Mironov |
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Peralkylcyclotrisilane: Crystal and molecular structure of [(t-BuCH2)2Si]3 Pages 225-233 Hamao Watanabe, Motohiko Kato, Tadashi Okawa, Yoichiro Nagai, Midori Goto |
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Preparation and properties of silyl- and germyl-trifluoromethylacetylenes (1,1,1-trifluoro-4-silabut-2-yne and 1,1,1-trifluoro-4-germabut-2-yne), and molecular structure of silyltrifluoromethylacetylene determined by electron diffraction Pages 235-247 Duncan W. W. Anderson, Stephen Cradock, E. A. V. Ebsworth, Anthony R. Green, David W. H. Rankin, Alan G. Robiette |
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Quantitative aspects of some unimolecular isomerization reactions of organosilicon intermediates Pages 249-260 Iain M. T. Davidson, Robert J. Scampton |
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Reactions of organopolysilanes with organic peroxides Pages 261-280 G. A. Razuvaev, T. N. Brevnova, V. V. Semenov |
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The relative stereochemistry of some α-methyl-β-silylcarbonyl compounds produced by the diastereoselective alkylation of β-silylenolates Pages 281-288 Werner Bernhard, Ian Fleming |
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1-Silaphenalenes, potential precursors to aromatic silylenium ions and aromatic silyl anions. Spectroscopic and chemical studies Pages 289-297 Ratnasabapathy Sooriyakumaran, Philip Boudjouk |
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Silene stereochemistry : IV. The configurational stability of 1-phenyl-1-methyl-2-neopentylsilene under flash vacuum thermolysis conditions Pages 299-306 Paul Ronald Jones, Myong E. Lee |
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Silylation of hydroxyl-containing compounds with aryl- and heteroaryl-hydrosilanes in the presence of amines Pages 307-317 E. Lukevics, M. Dzintara |
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Simplified approach to silaanthrones and disilaanthracenes Pages 319-326 J. Y. Corey, W. Z. McCarthy |
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Tertiary alcoholysis of chlorosilanes via tetracoordinate silylated quaternary ammonium intermediates Pages 327-336 H. K. Chu, M. D. Johnson, C. L. Frye |
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The chemistry of octamethyl-1,2-disilacyclobutane. Some Si---Si cleavage and insertion reactions Pages 337-352 Dietmar Seyferth, Emma W. Goldman, Jean Escudié |
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The ethylmethylcyclosilanes Pages 353-367 Anita Katti, Corey W. Carlson, Robert West |
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Theoretical studies of disilabenzenes Pages 369-379 Kim K. Baldridge, Mark S. Gordon |
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Unsaturated silicon compounds : VII. Preparation and structure of a silaethene tetrahydrofuranate Pages 381-391 Nils Wiberg, Gerhard Wagner, Gerhard Müller and, Jürgen Riede |
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Penta(methoxycarbonyl)cyclopentadienyl-substituted germanium(II) and tin(II) compounds. X-ray crystal structure of bis[penta(methoxycarbonyl)cyclopentadienyl]tin(II) Pages 393-402 Peter Jutzi, Franz-Xaver Kohl, Ewald Schlüter, Michael B. Hursthouse and, Nigel P. C. Walker |
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Metal-ylide complexes: Mercury(II), cadmium(II), cobalt(II), and nickel(II) complexes of ambidentate sulfonium ylides Pages 403-407 Ram S. Tewari, Alok K. Awasthi |