Volume 279
Main Index

Issues 1-2, Pages 1-326 (8 January 1985)

Preface Pages VII-VIII Brian R. James

Rhodium(I) catalyzed cooligomerization of carbon monoxide with ethylene. direct evidence for a single mode of stepwise chain growth Pages C5-C10 Ayusman Sen, Jeffrey S. Brumbaugh

Polymerization of primary silanes to linear polysilanes catalyzed by titanocene derivatives Pages C11-C13 Claire Aitken, John F. Harrod, Edmond Samuel

Bidentate P,N ligand-modified rhodium(I) complexes: the impact of nitrogen ligands on isomerization capability Pages C1-C4 M. C. Bonnet, B. Stitou, I. Tkatchenko

Author index Page C14

At the academic/industry interface Pages 1-3 James F. Roth

Rhodium(I) complexes of ferrocenylphosphines as efficient asymmetric catalysts. The structure of Fe(η5-C5H3(P(CMe3)2-1,3)(η5-C5H3(CHMeNMe2)P(CMe3)2-1,2) Pages 5-21 Trevor D. Appleton, William R. Cullen, Stephen V. Evans, Tae-Jeong Kim, James Trotter

A facile method for the preparation of 2,4-bis(diphenylphosphino)pentane (BDPP) enantiomers and their application in asymmetric hydrogenation Pages 23-29 József Bakos, Imre Tóth, Bálint Heil, Lászlo Markó

Kinetic and mechanistic aspects of the binding of dihydrogen by bis(ditertiaryphosphine)rhodium(I) tetrafluoroborate complexes, and activity of the dihydrides for catalytic asymmetric hydrogenation of prochiral olefinic acids Pages 31-48 Brian R. James, Devinder Mahajan

Selective catalytic hydrogenation of 1,4-dienes to cis-monoenes using (naphthalene)(tricarbonyl)chromium Pages 49-62 James R. Tucker, Dennis P. Riley

Transition metal allyls : VI. The stoichiometric reaction of 1,3-dienes with ligand modified zerovalent-nickel systems Pages 63-86 R. Benn, B. Büssemeier, S. Holle, P. W. Jolly, R. Mynott, I. Tkatchenko, G. Wilke

Mechanistic aspects of catalytic hydrogenation of ketones by rhodium(I)-peralkyldiphosphine complexes Pages 87-101 Kazuhide Tani, Eiji Tanigawa, Yoshitaka Tatsuno, Sei Otsuka

Reactions at the rhodium vertex of isomeric closo-bis(triphenylphosphine)hydridorhodacarboranes, alkenyl acetate cleavage and subsequent reactions Pages 103-114 R. E. KingIII, D. C. Busby, M. F. Hawthorne

A new aromatic metallation reaction involving rhodium and iridium; the unusual reactivity of iodobenzene Pages 115-130 Manuel Gómez, Paul I. W. Yarrow, David J. Robinson, Peter M. Maitlis

Formation and reactivity of some aqueous ion-radicals containing metal-to-carbon bonds Pages 131-145 D. Katakis, J. Konstantatos, E. Vrachnou-Astra

The water gas shift reaction catalyzed by Rh6(CO)16 adsorbed on alumina or [Rh(CO)2Cl]2 adsorbed on alumina, Na-Y zeolite and H-Y zeolite Pages 147-158 J. M. Basset, A. Theolier, D. Commereuc and, Y. Chauvin

Is the hydroformylation reaction reversible? Pages 159-164 Changsoo Kim, Yasushi Matsui, Milton Orchin

CIDNP evidence for radical intermediates in the hydroformylation and reduction of styrene by HCo(CO)4/CO Pages 165-169 T. Michael Bockman, John F. Garst, R. Bruce King, László Markó and, Ferenc Ungváry

Aspects of anionic rhodium complexes. Ligand effects Pages 171-179 Albert S. C. Chan, Huey-Sheng Shieh, Jeffrey R. Hill

Preparation and characterization of mercapto-bridged dinuclear platinum(II) complexes. Catalytic activity of [(PEt3)PtCl(μ-SEt)]2/SnCl2 · 2H2O system in hydrogenation and hydroformylation of styrene Pages 181-191 H. C. Clark, V. K. Jain, G. S. Rao

Rhodium- and platinum-catalyzed asymmetric hydroformylation with (2S,3S )-2,3-bis(diphenylphosphino)butane as the chiral ligand Pages 193-202 Giambattista Consiglio, Franco Morandini, Michelangelo Scalone, Piero Pino

New synthetic route to N-acyl-α-amino acids via amidocarbonylation by means of homogeneous binary catalyst systems Pages 203-214 Iwao Ojima, Kenji Hirai, Makoto Fujita, Takamasa Fuchikami

Catalysis by palladium salts : X. An investigation on the factors acting on the palladium-catalysed oxidative carbonylation of arylmercury compounds Pages 215-224 A. Chiesa, R. Ugo

Palladium-catalyzed C---C bond formation involving aromatic C---H activation : III. Aspects of aromatic substitution and structure of 1-bromo-3-[3-(2-methylenecyclohex-5-en-1-yl)bicyclo[2.2.1]hept-2-yl]-4-bicyclo[2.2.1]hept-2-ylbenzene Pages 225-232 G. Bocelli, M. Catellani, G. P. Chiusoli

Trans-cis isomerization of dimethylbis(diethylphenylphosphine)palladium(II) catalyzed by methylmagnesium compounds Pages 233-243 Fumiyuki Ozawa, Kunihiko Kurihara, Takakazu Yamamoto, Akio Yamamoto

Observations on olefin oxidation by neutral and cationic phosphineiridium complexes Pages 245-257 John M. Brown, Robert A. John, Andrew R. Lucy

A new organocobaloxime with an acetoxy substituted tertiary carbon to cobalt bond, derived from enolpyruvic acid Pages 259-261 Zoltán Szeverényi, László I. Simándi

Current state of organocobalt(IV) and organorhodium(IV) chemistry Pages 263-280 M. E. Vol'pin, I. Ya. Levitin, A. L. Sigan, A. T. Nikitaev

Synthesis and reactivity of alkenyl and alkynyl derivatives of permethylzirconocene and permethylhafnocene. Rearrangement of alkenyl derivatives involving β-H elimination from an sp2-hybridized carbon Pages 281-315 Christine McDade, John E. Bercaw

Electrode-catalyzed substitution of M(CO)4bipy (M = Cr, Mo, W) initiated by reduction Pages 317-326 D. Miholová, A. A. Vlek

Issue 3, Pages 327-460 (15 January 1985)

Isolation of the mixed-metal carbonyl cluster anion [RuIr3(CO)9(μ-CO)3]−. Crystal structure of its bis(triphenylphosphine)iminium salt Pages c33-c36 Alessandro Fumagalli, Francesco Demartin, Angelo Sironi

Unusual tetra- and penta-ruthenium complexes from linking of ethylidyne and vinylidene ligands Pages c38-c41 David L. Davies, Judith A. K. Howard, Selby A. R. Knox, Karen Marsden, Kevin A. Mead, Michael J. Morris, Melvyn C. Rendle

Chemistry of organolanthanoids: Lanthanoid-catalyzed tishchenko condensation of aldehydes to esters Pages c19-c21 Kazuhiro Yokoo, Norioko Mine, Hiroshi Taniguchi, Yuzo Fujiwara

Subject index Pages c49-c59

Second announcement Page c46

Electron Spin Resonance, Vol. 8. Specialist Periodical Report : Royal Society of Chemistry, 1984, 509 pages, £59.00, $106.00. ISBN 0-85186-821-5. Page c45 Richard A. Jackson

Synthesis and X-ray structure of [CuPPh3CCPh]4, an electron deficient molecule with μ-bridging phenylacetylide ligands Pages c42-c44 Luciana Naldini, Francesco Demartin, Mario Manassero, Mirella Sansoni, Gloria Rassu and, M. Antonietta Zoroddu

Preparation of new hydridoplatinum(II) carbene derivatives from hydridotrifluoromethyl complexes Pages c25-c28 Rino A. Michelin, Giacomo Facchin, Renzo Ros

Pentamethylcyclopentadienyl-übergangsmetall-π- komplexe : VIII. Darstellung und molekülstruktur von η5 -C5Me5CoCl(pyridin), eines stabilen halbsandwichkomplexes des cobalts(II) Pages c29-c32 E. Raabe, U. Koelle

Author index Pages c47-c48

Pentacarbonylfulminatowolframat, NEt4[W(CNO)(CO)5], und isomerisierung fulminat→isocyanat am metall Pages c22-c24 Ferdinand Beck, Wolf Peter Fehlhammer, Wolfgang Beck

Etude electrochimique de composes organometalliques : X. Oxydation electrochimique de (η5-Cp)2NbCl2. Evolution “singuliere” de l'espece cationique (η5-Cp)2NbCl2+ Pages c15-c18 A. Fakhr, Y. Mugnier, R. Broussier, B. Gautheron

Vibrational spectra of alkali metal cyclopentadienides Pages 327-335 I. A. Garbuzova, O. G. Garkusha, B. V. Lokshin, G. K. Borisov and, T. S. Morozova

Formation of thallium complexes with carbon dioxide during mass spectrometry of thallium(I) carboxylates Pages 337-342 Yu. S. Nekrasov, T. V. Lysyak, Yu. Ya. Kharitonov, I. S. Kolomnikov

Correlation of one-bond 15N---13C, 15N---M, 29Si---X (M = 11B, 29Si, 119Sn, X = 1H, 13C) nuclear spin-spin coupling constants with the structure of metallatranes in solution Pages 343-358 E. Kupe, E. Liepi, A. Lapsia, I. Urtne, G. Zelns, E. Lukevics

New air-stable trimethylsilyl-substituted trivinylboranes and carboranes Pages 359-371 Narayan S. Hosmane, Narayan N. Sirmokadam, Mark N. Mollenhauer

Diorganotin(IV) derivatives of N-phthaloyl amino acids Pages 373-384 G. K. Sandhu, R. Gupta, S. S. Sandhu, R. V. Parish and, K. Brown

Tin-119, phosphorus-31, carbon-13 and proton nuclear magnetic resonance and Mössbauer studies of mono-, di- and tri-organotin(IV) dialkyldithiophosphates Pages 385-394 H. C. Clark, V. K. Jain, R. C. Mehrotra, B. P. Singh and, G. Srivastava, T. Birchall

Syntheses and spectroscopic studies of mono- and di- cyclopentadienylzirconium(IV) derivatives with heterocyclic thiones Pages 395-402 Vinita Srivastava, Om P. Pandey, Soumitra K. Sengupta, Satish C. Tripathi

Crystal structure of (η5-C5H5)W[C(Ph)C(CMe3)C(Ph)]Cl2, a molecule possessing a localized, non-planar tungstenacyclobutadiene ring Pages 403-412 Melvyn Rowen Churchill, Joseph W. Ziller

Insertion d'une phosphine acétylénique dans un complexe μ-alkylidénique du tungstène suivie de la rupture d'une liaison C---P Pages 413-417 J. Levisalles, F. Rose-Munch, H. Rudler, J. C. Daran and, Y. Jeannin

Preparation of heterometallic complexes with chelating μ2-carbomethoxyvinylidene ligands. X-ray crystal structures of Cp(OC)2 MnOMe) and [Cp(OC)2Mn(μ2-C=CHCo(CO)2 (Cp = η5-C5H5) Pages 419-432 N. E. Kolobova, L. L. Ivanov, O. S. Zhvanko, A. S. Batsanov, Yu. T. Struchkov

Cationic ruthenium and osmium systems : V. Cationic osmium(II) hydrazine and hydrazone complexes derived from the polymer [OsCl2(COD)]x (COD = cyclo-octa-1,5-diene; x > 2). The crystal structure of [Os(COD(CNBut)2(NH2H:CMe2)2][BPh4]2·(acetone)2 Pages 433-446 Hester E. Oosthuizen, Eric Singleton, John S. Field and, Gillian C. Van Niekerk

Umsetzungen von schwefeldiimiden mit dreikernigen osmiumclustern: Synthese, kristallstruktur und stereochemie von (μ-H)Os3(CO)8(μ3-AstBu)[μ(N,As)-NSNAstBu2] Pages 447-457 G. Süss-Fink, K. Guldner, M. Herberhold, A. Gieren and, T. Hübner

Fundamental metal carbonyl equilibria : III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction Pages 459-460 Felix Oldani, György Bor