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25th Anniversary Volume Page ix |
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Über Metallalkyl- und -aryl-Verbindungen: XXXVII. Strukturverfeinerung von Methylkalium. Darstellung von KCD3 und Neutronenbeugungsuntersuchung bei 1.35 und 290 K Pages 1-14 Erwin Weiss, Thomas Lambertsen, Bernd Schubert, Jeremy Karl Cockcroft |
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Organoboranes: LI. Convenient procedures for the recovery of pinanediol in asymmetric synthesis via one-carbon homologation of boronic esters Pages 15-30 Herbert C. Brown, Milind V. Rangaishenvi |
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Electrosynthèse en chimie organosilicique: silylation sélective de polychlorométhanes Pages 31-37 P. Pons, C. Biran, M. Bordeau, J. Dunoguès |
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1-Halosilatranes Pages 39-55 M.G. Voronkov, V.P. Baryshok, L.P. Petukhov, V.I. Rakhlin, R.G. Mirskov, V.A. Pestunovich |
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On the nucleophilic activation of silyl enol ethers and esters; a survey and mechanistic interpretation Pages 57-66 Claude Chuit, Robert J.P. Corriu, Catherine Reyé |
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29Si---15N Spin-spin coupling constants; a novel probe for structural studies of nitrogen-containing organosilicon compounds Pages 67-75 E. Kupče, E. Lukevics |
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Réaction de dérivés à liaison germanium-azote (germylamines, cyclogermazanes et germa-imines transitoires) avec la di-t-butyl-3,5-orthoquinone Pages 77-93 M. Rivière-Baudet, P. Rivière, A. Khallaayoun, J. Satgé, K. Rauzy |
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Einkern- und Heterometall-Zweikernkomplexe mit Thio-, Seleno- und Telluroaldehyden als Liganden: Synthese, Struktur, Protonierungs- und Methylierungsreaktionen Pages 95-121 H. Werner, W. Paul, W. Knaup, J. Wolf, G. Müller, J. Riede |
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Polymethylcyclopentadienyltitanocene tetrahydridoaluminates and their reaction with butadiene; a spectroscopic study Pages 123-133 Karel Mach, Helena Antropiusová, Vojtech Varga, Vladimír Hanuš |
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Properties of electron deficient 1,3-diene complexes of the group 4A metals Pages 135-145 B. Hessen, J.H. Teuben |
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Structural and chemical aspects of electron deficient pentamethylcyclopentadienyltitanium halides, alkyls, and oxides Pages 147-159 M.Pilar Gómez-Sal, Miguel Mena, Pascual Royo, Ricardo Serrano |
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The formation of ring-substituted titanocene derivatives containing chloro and carbomethoxy substituents Pages 161-168 Marvin D. Rausch, John F. Lewison, William P. Hart |
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Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X = Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl Pages 169-183 Frederick H. Elsner, T.Don Tilley, Arnold L. Rheingold, Steven J. Geib |
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The coordination chemistry of electron-rich alkenes (enetetramines) Pages 185-213 Michael F. Lappert |
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The influence of silyl groups on the reactivity and formation of metal-carbon double bonds Pages 215-228 Ulrich Schubert |
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Übergangsmetalkoordinierte Heteroolefine als Synthesebausteine: Einfluss des Alkins auf die Geschwindigkeit und die Stereoselektivität der Reaktion mit Heteroaldehyd- bzw. -keton-Komplexen Pages 229-244 Helmut Fischer, Josef Hofmann, Ulrike Gerbing, Athanassios Tiriliomis |
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Unexpected ring opening of cycloaminocarbene complexes of chromium upon alkyne insertion reactions Pages 245-272 H. Rudler, A. Parlier, R. Yefsah, B. Denise, J.C. Daran, J. Vaissermann, C. Knobler |
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Reactions of alkynes at mononuclear electron-rich transition metal centres Pages 273-282 Armando J.L. Pombeiro |
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Trimethyl phosphine complexes of molybdenum and tungsten containing dinitrogen, ethylene, carbon dioxide and related ligands Pages 283-293 Ernesto Carmona |
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Synthesis, structure, and solution behavior of [Na · 15-crown-5][Mn(CO)5] Pages 295-300 Abbas Alvanipour, Hongming Zhang, Jerry L. Atwood |
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Schwefelabbau mit Halbsandwich-Komplexen des Mangans und Rheniums Pages 301-320 Max Herberhold, Bertram Schmidkonz |
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Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen: LVII. Alkyl- und Aryl-Komplexe der Organorhenium-Reihe Pages 321-338 Wolfgang A. Herrmann, Martina Flöel, Eberhardt Herdtweck |
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Synthesis and reactivity of rhenium carbonyl thiolate complexes, Et4N[Re2(μ-SR)3(CO)6] Pages 339-345 P.M. Treichel, M.H. Tegen |
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Diiron μ-vinylcarbyne complexes have unusually low barriers to vinyl rotation because conjugation is maintained throughout rotation Pages 347-361 Charles P. Casey, Mark S. Konings, Seth R. Marder, Yoshiaki Takezawa |
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On the problem of stabilization of α-carbocationic centers in metallocene series. Related interconversions of permethylated α-metallocenylcarbocations and metallocenium cation-radicals of the iron sub-group Pages 363-374 M.I. Rybinskaya, A.Z. Kreindlin, S.S. Fadeeva |
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Organometallic solid state chemistry Pages 375-388 Malcolm L.H. Green, Jingui Qin, Dermot O'Hare |
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Réactions des dérivés de l'iode(III) avec les ferroporphyrines et le cytochrome P-450: Formation de complexes σ-aryles du fer(III) et de N-aryl-porphyrines du fer(II) à partir de sels de diaryliodonium Pages 389-400 Jean-Paul Battioni, Daniel Dupré, Marcel Delaforge, Maryse Jaouen, Daniel Mansuy |
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The cyclodextrin inclusion complexes of acylferrocenes: their preparation, and the induced Cotton effects in their circular dichroism spectra Pages 401-403 V.I. Sokolov, V.L. Bondareva, I.F. Golovaneva |
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Radical formation during an attempted photochemical substitution reaction of η5-C5Me5Os(CO)2CH2Ph Pages 405-409 Laura J. Johnston, Michael C. Baird |
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Stable terminal methylene complexes of osmium(II) and ruthenium(II). The unexpected preferential migration of aσ-aryl ligand to carbon monoxide rather than to methylene Pages 411-447 D. Scott Bohle, George R. Clark, Clifton E.F. Rickard, Warren R. Roper, L.James Wright |
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Metallacarborane diene π-complexes. I. Synthesis of rhodacarboranes with a η2,η3-2-methylenenorbornadienyl ligand at the rhodium vertex Pages 449-461 L.I. Zakharkin, I.T. Chizhevsky, G.G. Zhigareva, P.V. Petrovskii, A.V. Polyakov, A.I. Yanovsky, Yu.T. Struchkov |
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Redox-rotational phenomena in organometallic chemistry. Unique features of the crystal structure and stereodynamic behaviour of acetylacetonato- and cyclopentadienylrhodium complexes with potentially dipolar two-ring semiquinoid ligands in solution Pages 463-494 V.A. Nikanorov, V.I. Bakhmutov, M.V. Galakhov, S.V. Sergeev, E.V. Stepanova, A.I. Yanovsky, Yu.T. Struchkov, V.I. Rozenberg, O.A. Reutov |
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Rhodium-catalyzed C---C coupling reactions involving ring opening of strained molecules: II. Addition to olefins and aromatic substitution Pages 495-505 Gian Paolo Chiusoli, Mirco Costa, Luca Melli |
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Nickela-Heterocyclen als Intermediate der präparativen Isocyanatchemie Pages 507-517 Heinz Hoberg |
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Zur Lewis-Acidität von Nickel(0): VIII. Komplexe von (Cyclododecatrien)nickel(0) mit LiH2AliBu2 und LiAlH4 Pages 519-524 Klaus R. Pörschke, Günther Wilke |
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Anionic perhaloaryl-palladium and -platinum complexes as sources of unusual homo- and hetero-nuclear compounds Pages 525-543 Rafael Usón, Juan Forniés, Milagros Tomás |
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Organopalladium complexes with bidentate phosphorus and nitrogen containing ligands Pages 545-562 Wim de Graaf, Sjoerd Harder, Jaap Boersma, Gerard van Koten, Jan A. Kanters |
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Palladium-catalyzed carbonylation of aryl iodides in aqueous media Pages 563-565 N.A. Bumagin, K.V. Nikitin, I.P. Beletskaya |
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Reactions of electrophilic transition metal cations with olefins and small ring compounds. Rearrangements and polymerizations Pages 567-588 Ayusman Sen, Ta-Wang Lai, Richard R. Thomas |
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Pentacoordinate silicon intermediates in relay substitution reactions of organosilanes: successive nucleophilic attack at silicon and its adjacent carbon Pages C1-C5 John J. Eisch, Chingchen S. Chiu |
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Docosahedral carbaboranetungsten-alkylidyne complexes: synthesis of compounds with heteronuclear metal-metal bonds Pages C6-C10 David D. Devore, Sandra J.B. Henderson, Judith A.K. Howard, F. Gordon, A. Stone |
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Synthesis, structure, and stability of cyclopentadienyl-(triphenylphosphine)(α-benzenesulfonylalkyl)nickel complexes Pages C11-C16 M. Julia, H. Lauron, J.N. Verpeaux, Y. Jeannin, C. Bois |
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Low temperature activation of molecular hydrogen in Co/H2 mixtures in the presence of CoRh(CO)7 Pages C17-C22 István T. Horváth, Marc Garland, György Bor, Piero Pino |
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A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3− Pages C23-C25 Secondo Martinengo, Gianfranco Ciani, Angelo Sironi |
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Author index Pages C26-C27 |
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Subject index Pages C28-C33 |