Volume 488
Main Index

Issues 1-2, Pages 1-255 (22 February 1995)

Editorial Board Page iii

Preface Pages vii-ix G. P. Chiusoli

Author index of volume 488 Pages C23-C24

The role of SO2 as a ligand to mediate associative substitution reactions of some 18-electron molybdenum complexes Pages C1-C3 Jian Kun Shen, Fred Basolo, Gregory J. Kubas

Cis-(hydrido)hydrocarbylplatinum(IV) complexes as intermediates in the PtII---C bond breaking Pages C13-C14 Vincenzo De Felice, Augusto De Renzi, Achille Panunzi, Diego Tesauro

Vinyl-plus-vinyl coupling in rhodium complexes: formation of [(C5Me5)RhBr(η3-syn-1-methylallyl)] be reaction of [(C5Me5)RhBr2(Me2SO)] with vinylmagnesium bromide in homogeneous solution Pages C11-C12 Zhi-Qiang Wang, Michael L. Turner, A. Ryszard Kunicki, Peter M. Maitlis

Hydroformylation of some functionalized olefins catalyzed by rhodium(I) complexes with pydiphos and its P-oxide Pages C20-C22 C. Basoli, C. Botteghi, M. A. Cabras, G. Chelucci, M. Marchetti

Synthesis of methacrylate monomers from alkynes and arenealkenylruthenium(II) catalyst Pages C9-C10 Olivier Lavastre, Pierre H. Dixneuf

Oxidative carbonylation of methanol to dimethyl carbonate (DMC): a new catalytic system Pages C15-C19 Daniele Delledonne, Franco Rivetti, Ugo Romano

Structural and spectral characterization of novel charge-transfer salts of polyoxometalates and the cationic ferrocenyl donor Pages C4-C8 Patrick L. Veya, Jay K. Kochi

Subject index of volume 488 Pages C25-C32

Electronic interactions in organometallic dimers. An electrochemical approach Pages 1-7 Domenico Osella, Luciano Milone, Carlo Nervi, Mauro Ravera

Structures of polymetallaorganosiloxanolates—a novel class of organosilicon metal complexes Pages 9-14 Yu. T. Struchkov, S. V. Lindeman

Synthesis of cluster compounds by photolysis of azido complexes Pages 15-24 Joachim Strähle

Catalytic carbonylation of benzylic and allylic bromides by a rhodium zwitterionic complex under phase transfer catalysis conditions Pages 25-28 Shiyamalie Amaratunga, Howard Alper

Instability of 15-electron CpMoCl2L (L = 2-electron donor) derivatives. X-ray structure of CpMoCl2(PMe2Ph)2 and [CpMoCl2(PMe2Ph)2]AlCl4 Pages 29-38 Fatima Abugideiri, D. Webster Keogh, Heinz-Bernhard Kraatz, Wayne Pearson, Rinaldo Poli

New mono- and di-phosphido-bridged PdI dimers. Formation of tertiary dialkyl(allyl) phosphines from an allyl complex with a secondary phosphine Pages 39-45 Piero Leoni, Marco Pasquali, Tiziana Beringhelli, Giuseppe D'Alfonso, Anna P. Minoja

A new cyclopentadiene and its use as a ligand for catalytically active rhodium complexes Pages 47-53 Mirco Costa, Francisco Santos Dias, Gian Paolo Chiusoli, Gian Luca Gazzola

The different behaviour of the di-2-pyridylketone 2-thenoylhydrazone in two organotin compounds. Synthesis, X-ray structure and biological activity Pages 55-61 Mauro Carcelli, Corrado Pelizzi, Giancarlo Pelizzi, Piergiorgio Mazza, Franca Zani

Dialkylaminophosphorus metal carbonyls. 12. Insertion of phosphorus, sulfur, and selenium into the (iPr2NP)2Fe2(CO)6 unit and a novel product from the reaction of (iPr2NP)2COFe2(CO)6 with PhBCl2 Pages 63-71 Y. W. Li, M. G. Newton, R. B. King

Reductive carbonylations reactions of primary phosphine mono-η-cyclopentadienyltungsten (V) compounds Pages 73-78 Malcolm L. H. Green, Xavier M. Morise, Andy H. Hamilton, Alexander N. Chernega

Synthesis, X-ray structure and reactivity of cyclopalladated complexes of hydrazones of 1H-indole-3-carboxaldehyde Pages 79-83 Stefano Tollari, Giovanni Palmisano, Francesco Demartin, Maria Grassi, Stefano Magnaghi, Sergio Cenini

Ruthenium carbonyl complexes with polyfunctional phosphine ligands Pages 85-90 Ulf Bodensieck, Heinrich Vahrenkamp, Gerd Rheinwald, Helen Stoeckli-Evans

Chemoselective reduction of α,β-unsaturated ketones catalyzed by transition metal complexes with polydentate ligands Pages 91-97 C. Bianchini, M. Peruzzini, E. Farnetti, J. Kapar, M. Graziani

Water-soluble organometallic compounds. 5. The regio-selective catalytic hydrogenation of unsaturated aldehydes to saturated aldehydes in an aqueous two-phase solvent system using 1,3,5-triaza-7-phosphaadamantane complexes of rhodium Pages 99-108 Donald J. Darensbourg, Nicole White Stafford, Ferenc Joó, Joseph H. Reibenspies

Surface organometallic chemistry: the easy conversion of [Ir6(CO)16] supported on silica into [Ir4(CO)12] Pages 109-114 Dominique Roberto, Elena Cariati, Rinaldo Psaro, Renato Ugo

Anchoring rhodium(I) on benzoylthiourea-functionalized silica xerogels. Production of recyclable hydroformylation catalysts and the crystal structure of the model compound [Rh(cod)(Hbztu)Cl] Pages 115-125 Daniele Cauzzi, Maurizio Lanfranchi, Giovanna Marzolini, Giovanni Predieri, Antonio Tiripicchio, Mirco Costa, Roberto Zanoni

Preparation of α-vinylidene-γ-lactones by palladium-catalyzed carbonylation of 5-hydroxy-2-alkynyl methyl carbonates under mild conditions Pages 127-131 Tadakatsu Mandai, Yoshikazu Tsujiguchi, Shin Matsuoka, Seiki Saito, Jiro Tsuji

Synthesis of dinuclear iron and ruthenium aminoalkylidene complexes and the molecular structure of the novel cis-[Ru2(CO)2(Cp)2{μ-C(CN)N(Me)Bz}2](Cp = η-C5H5; Bz= CH2Ph) Pages 133-139 Vincenzo G. Albano, Luigi Busetto, Lucia Carlucci, Maria Cristina Cassani, Magda Monari, Valerio Zanotti

A novel class of hexanuclear titanoxanes: synthesis, structure and electronic configuration Pages 141-154 Tommaso Carofiglio, Carlo Floriani, Alan Roth, Antonio Sgamellotti, Marzio Rosi, Angiola Chiesi-Villa, Corrado Rizzoli

The geometry of SiOCN and SiNCO linkages. The crystal structures of (Me3Si)2(Ph2MeSi)CSiMe2OCN and (PhMe2Si)3CSiMe2NCO Pages 155-160 Salih S. Al-Juaid, Ahmed A. K. Al-Nasr, G. Adefikayo Ayoko, Colin Eaborn, Peter Hitchcock

Kinetics and mechanism of H2-hydrogenation of styrene catalyzed by [RuCl(dppb) (μ-Cl)]2 (dppb = 1,4-bis(dipphenylphosphino)butane). Evidence for hydrogen transfer from a dinuclear molecular hydrogen species Pages 161-167 Ajey M. Joshi, Kenneth S. MacFarlane, Brian R. James

Vinylidene transition metal complexes XXXIV the preparation and structure of neutral vinylidene and allenylidene ruthenium(II) compounds of the half-sandwich type containing iPr2PCH2CO2Me as supporting ligand Pages 169-176 T. Braun, P. Steinert, H. Werner

Oxidative η2-iminoacyl formation by reaction of amidozirconocene complexes with tris(pentafluorophenyl)borane Pages 177-182 Bodo Temme, Gerhard Erker

Pd4 clusters: the sensitivity of the cluster metal core geometry to the surrounding ligands Pages 183-190 Ilya I. Moiseev

A novel enantiopure proline-based organonickel(III) halide monocation with a pentadentate C, N2, O2-bonded bis(ortho-chelating) aryldiamine ligand Pages 191-197 Lucia A. van de Kuil, Yvonne S. J. Veldhuizen, David M. Grove, Jan W. Zwikker, Leonardus W. Jenneskens, Wiendelt Drenth, Wilberth J. J. Smeets, Anthony L. Spek, Gerard van Koten

Octahedral iridium carbonyl clusters. Synthesis, characterization and solid state structure of the nitrosyl cluster [Ir6(CO)11(μ-CO)3NO]− Pages 199-204 Roberto Della Pergola, Luigi Garlaschelli, Mario Manassero, Norberto Masciocchi

Donor-acceptor-based vinylidene and σ-acetylide complexes of ruthenium and osmium Pages 205-210 Andrew J. Hodge, Scott L. Ingham, Ashok K. Kakkar, Muhammad S. Khan, Jack Lewis, Nicholas J. Long, David G. Parker, Paul R. Raithby

Novel, CO2-promoted synthesis of anhydrous alkylammonium tetraphenylborates: a study on their reactivity as intra- and inter-molecular proton-transfer agents Pages 211-222 Michele Aresta, Eugenio Quaranta

The reactions of tridentate cationic palladium(II) complexes with olefins and nucleophiles Pages 223-232 Heinz-Bernhard Kraatz, David Milstein

Determination of the absolute configurations of the epimers of the P-chiral phosphine Ph2PCH2CH2PPh(L-(−)-methyl) by use of two-dimensional NMR spectroscopy in combination with a palladium(II) “reporter complex” Pages 233-240 Qiongzhong Jiang, Heinz Rüegger, Luigi M. Venanzi

Transformation of the bis(trimethylsilyl)methyl into a 1,3-diaza-allyl ligand. Synthesis and crystal structures of [] and [{UCl(μ-Cl)(L)(NR)}2][UCl2(L)(L′)]2[R = SiMe3; Ar = C6Me2-2,5; L = ; L′ = ] Pages 241-248 Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu

Rhodium(III) complexes of (EEE)-1,5,9-cyclododecatriene. Syntheses, structures and absolute configurations of derivatives of catena-poly-[μ-dichloro-(1,2,12-η)-1,5,8 cyclododecatrienylrhodium] Pages 249-255 Gastone Paiaro, Luciano Pandolfo, Paolo Ganis, Giovanni Valle, Silvio Darin Fioretto