Volume 493
Main Index

Issues 1-2, Pages 1-277 (17 May 1995)

Editorial Board Page iii

In4{C(SiMe3)3}4 mit In4-tetraeder und In4Se4{C(SiMe3)3}4 mit In4Se4-heterocubanstruktur Pages C1-C5 Werner Uhl, Rene Graupner, Marcus Layh, Uwe Schütz

Author index of volume 493 Pages C32-C33

Organometallic reagents in synthesis : Paul R. Jenkins, Oxford Chemistry Primers, No. 3, Oxford University Press, Oxford, 1992, pp 92, £4.99 ISBN 0-19-855666-7 Page C29 J. R. Hanson

Dealkylation of thiols by alkyne-bridged dimolybdenum complexes Pages C25-C28 Harry Adams, Neil A. Bailey, Sally R. Gay, Trevor Hamilton, Michael J. Morris

Oxidative addition of cationic (η6-chloroarene)tricarbonylmanganese compounds to palladium(0) complexes. Synthesis, characterisation and reactivity Pages C22-C24 Jean-François Carpentier, Yves Castanet, Jacques Brocard, André Mortreux, Françoise Rose-Munch, Claudine Susanne, Eric Rose

Corrigendum Page C31

Synthesis and structure of cationic η3-allenyl/propargylpalladium complexes Pages C19-C21 Sensuke Ogoshi, Ken Tsutsumi, Hideo Kurosawa

Subject index of volume 493 Pages C34-C42

Sulfur reagents in organic synthesis : Harcourt Brace, London, 1994. 200 pages £50 ISBN 0-12-690770-6 Pages C29-C30 S. D. Craddick

Formation of Mo, W, Fe and Ru di(metal σ-acetylide) derivatives of 2.5-diethynylthiophene via palladium-catalyzed metal-carbon coupling Pages C9-C13 Egidio Viola, Claudio Lo Sterzo, Raffaella Crescenzi, Giuseppe Frachey

Metallorganische verbindungen der lanthanoide XCVI. Ylidartige olefinkoordination in komplexen dreiwertiger 4f-elemente Pages C14-C18 Herbert Schumann, Mario Glanz, Jörn Winterfeld, Holger Hemling, Norbert Kuhn, Hans Bohnen, Dieter Bläser, Roland Boese

Deltacyclene formation catalysed by cationic Co(II) complexes Pages C6-C8 P. Binger, S. Albus

Cationic platinum(II) - or palladium(II)-carbyl complexes and unsaturated substrates: a facile way to C-C bond formation Pages 1-11 Vicenzo De Felice, Maria E. Cucciolito, Augusto De Renzi, Francesco Ruffo, Diego Tesauro

The crystal structure of butylchlorobis(8-quinolinate)tin(IV) Pages 13-16 Eleonóra Kellö, Viktor Vrábel, Jaroslav Holeek, Július Sivý

Fulvalene titanium and zirconium complexes: synthesis and NMR study of phosphanido-, alkyl-, and alkynyl-derivatives. X-ray crystal structures of [{Ti(η5−C5H5)(μ−PPH2)}2{μ−(η5−C5H4−η5−C5H4)}] and [{Zr(η5−C5H5)(μ−C≡CSiMe3)}2{μ−(η5−C5H4−η5−C5H4)}] Pages 17-25 Ana Cano, Tomás Cuenca, Mikhail Galakhov, Gema M. Rodríguez, Pascual Royo, Christine J. Cardin, Maire A. Convery

Stereoselective electrochemical synthesis of silyl enol ethers using a sacrificial magnesium anode Pages 27-32 Dominique Bonafoux, Michel Bordeau, Claude Biran, Jacques Dunoguès

Zur darstellung von permethylierten cyclosilanylalkalimetall-derivaten Pages 33-40 Frank Uhlig, Peter Gspaltl, Manuela Trabi, Edwin Hengge

Electronic structure of [CpCoMe2SiC4H4], photoelectron and MSXα studies Pages 41-46 Marie-Gabrielle Faba, Danielle Gonbeau, Geneviève Pfister-Guillouzo

Chelating triarylgermyl anions as ligands in lanthanide chemistry: synthesis of Ln[GeAr3]2 [Ar = C6H4(2-CH2NMe2); Ln = Sm, Yb] and the crystal structure of an unusual μ-(o-tolylene) digermane byproduct Pages 47-54 David J. Berg, Chris K. Lee, Lisa Walker, Gordon W. Bushnell

Formation of metal σ-acetylides of Mo, W, and Ru via palladium-catalyzed metal-carbon coupling Pages 55-59 Egidio Viola, Claudio Lo Sterzo, Raffaella Crescenzi, Giuseppe Frachey

Synthesis and structural characterization of phenoxarsin-10-yl dithiocarbamates. O(C6H4) 2AsS2CN(CH2CH2)2, a compound containing an asymmetric mononuclear biconnective 1,1-dithiolato ligand Pages 61-67 Raymundo Cea-Olivares, Rubén-Alfredo Toscano, Cristian Silvestru, Patricia Garcia-García, Marcel López-Cardoso, Georgina Blass-Amador, Heinrich Nöth

Reaktionen von (Cp′AlCl2)2 und (CpAlCl2)2 mit alkyl- bzw. Arylalkaliverbindungen sowie lithiierten aminen: Struktur von (Cp′(Ph)AlCl)2 und [Cp′(Cl)AlN(H)tBu]2 Pages 69-75 Stephan Schulz, Herbert W. Roesky, Mathias Noltemeyer, Hans-Georg Schmidt

Pentahalophenyl palladium and platinum trinuclear complexes with tetrathiomolybdate and tetrathiotungstate Pages 77-82 José Ruiz, Venancio Rodríguez, Gregorio López, Penny A. Chaloner, Peter B. Hitchcock

Synthetic, structural and reactivity studies with new group 4 transition-metal silyl complexes Pages 83-89 Toru Imori, Richard H. Heyn, T. Don Tilley, Arnold L. Rheingold

Synthesis and structural investigation of two potential boronate affinity chromatography ligands catechol [2-(diisopropylamino)carbonyl]phenylboronate and catechol [2-(diethylamino)carbonyl, 4-methyl]phenylboronate Pages 91-94 Xiao-Chuan Liu, John L. Hubbard, William H. Scouten

Structural investigation into the suprising stability of free and complexed bis(amino) phosphine azides Pages 95-99 Alan H. Cowley, François P. Gabbaï, Guy Bertrand, Carl J. Carrano, Marcus R. Bond

Synthesis and X-ray crystal structure of (p-CH3C6H4)3As=N---S3N3 Pages 101-105 C. J. Thomas, R. Cea-Olivares, G. Espinosa-Pérez, R. W. Turner

Cationic complexes of diorganotin(IV) derivatives. The crystal structure of tetrakis[1-methyl-2(3H)-imidazolinethione]diethyltin(IV) nitrate Pages 107-111 J. S. Casas, E. García Martínez, A. Sánchez González, J. Sordo, U. Casellato, R. Graziani, U. Russo

Chemie metallacyclischer alkenylcarbenkomplexe II. Einfluß des zentralmetalls auf struktur, reaktivität und elektronentransfereigenschaften Pages 113-118 Rainer Schobert, Frank Hampel, Klaus-Dieter Roth, Michael Stöss

Metal carbonyl syntheses XXII. Low pressure carbonylation of [MOCl4]− and [MO4]−: the technetium(I) and rhenium(I) complexes [NEt4]2[MCl3(CO)3] Pages 119-127 Roger Alberto, Roger Schibli, Andre Egli, P. August Schubiger, Wolfgang A. Herrmann, Georg Artus, Ulrich Abram, Thomas A. Kaden

Synthesis and reactivity of hydrotris(pyrazolyl)borate σ-hydrocarbyl uranium(IV) complexes Pages 129-132 Manuela Silva, Noémia Marques, A. Pires de Matos

From phosphaimines to phosphanes via transient iminozirconiophosphoranes Pages 133-137 Christophe Larré, Armelle Mahieu, Alain Igau, Jean-Pierre Majoral

The first volatile Di(organogallio) transition metal carbonylates: cis-(CO)4Fe{Ga[(CH2)3NMe2](R)}2 (RtBu or C6H5), Precursors for Gallium rich thin Fe---Ga alloy films Pages 139-142 Roland A. Fischer, Markus M. Schulte, Thomas Priermeier

Aerobic epoxidation with a ruthenium-porphyrin catalyst: formation of an inactive carbonyl complex Pages 143-147 Bernd Scharbert, Eduard Zeisberger, Erich Paulus

Dicyclopentadienyl complexes of ytterbium(III). The crystal structure of [Yb(η5-C5H4SiMe3)2(μ-Cl)]2 Pages 149-151 Marie-Rose Spirlet, Jean Goffart

Synthesis and spectroscopic properties of Re(R)(CO)3(α-diimine) (R = alkyl; α-diimine = R′-pyCa, R′-DAB) complexes. Crystal structure of Re(Me) (CO)3 (iPr-DAB) Pages 153-162 Brenda D. Rossenaar, Cornelis J. Kleverlaan, Maartje C. E. van de Ven, Derk J. Stufkens, Ad Oskam, Jan Fraanje, Kees Goubitz

Chemical evidence for the existence of peralkylated niobocene in a fulvenoid form by its reaction with sulfur Pages 163-166 Henri Brunner, Günther Gehart, Walter Meier, Joachim Wachter, Thomas Burgemeister

The effect of trifluoromethyl substitution on the B=N bond in trifluoromethyl-dimethylaminoboranes, CF3(R) BNMe2: crystal and molecular structure of CF3(Et) (NCCH2) B · NHMe2 Pages 167-173 David J. Brauer, Hans Bürger, Thomas Dittmar, Gottfried Pawelke

Syntheses and structural studies of two adducts of cadmocene, [CdCp2. TMEDA] and [CdCp2. PMDETA] (TMEDA = Me2NCH2CH2NMe2, PMDETA = (Me2NCH2CH2)2NMe) Pages 175-179 Donald Barr, Andrew J. Edwards, Paul R. Raithby, Moira-Ann Rennie, Kerry L. Verhorevoort, Domonic S. Wright

Redox-induced activation of C---H bonds in 1,2,3,4,5-pentamethylcyclopentadiene platinum complexes Pages 181-187 Oleg V. Gusev, Larisa N. Morozova, Tatyana A. Peganova, Mikhail G. Peterleitner, Svetlana M. Peregudova, Larisa I. Denisovich, Pavel V. Petroskii, Yuri F. Oprunenko, Nikolai A. Ustynyuk

The assessment of some Sb---Te single-source compounds for MOCVD applications Pages 189-197 Ron S. Dickson, Kerryn D. Heazle

Synthesis and molecular structure of methyl 4,6-benzylidene-3-deoxy-3-diphenylarsino-α-D-altropyranoside Pages 199-203 Martyn A. Brown, R. Alan Howie, James L. Wardell, Philip J. Cox, Olga A. Melvin

Platinum(IV) organometallics I. Syntheses of trans-di(carboxylato)ethane-1,2-diamine-cis-bis(pentafluoro-phenyl)platinum(IV) complexes and the X-ray crystal structure of the n-butanoato derivative Pages 205-213 G. B. Deacon, E. T. Lawrenz, T. W. Hambley, S. Rainone, L. K. Webster

Regioselectivity in metallation reactions of 2-(2′-naphthyl)pyridine: 1′-versus 3′-reactivity in mercuration and palladation reactions. Crystal structure of chloro(pyridine) [2-(2−pyridiny)naphthyl-C3,N]palladium Pages 215-220 Alan Ford, Ekkehard Sinn, Simon Woodward

First optically active organometallic free radical in the cymantrene series Pages 221-222 V. A. Milukov, O. G. Sinyashin, A. G. Ginzburg, M. A. Kondratenko, N. M. Loim, V. P. Gubskaya, R. Z. Musin, V. I. Morozov, E. S. Batyeva, V. I. Sokolov

Synthese und kristallstruktur des ersten dimeren silaamidids Pages 223-227 Ina Hemme, Martina Schäfer, Regine Herbst-Irmer, Uwe Klingebiel

Reactions of the alkylidyne cluster [Os3(μ-H)2(CO)9(μ3-CNC5H4---CH=CH2)]. Crystal structures of [Os3(μ-H)2(CO)9(μ3-CNC5H4---CH=CH2)], [Os3(μ-H)2(CO)9(μ3-CNC5H4-μ-η2-CH=CH)Os3(μ-H)(CO)10] and [Os3(μ-H)2(CO)9(μ-3-CNC5H4-C(O)CH3)] Pages 229-237 Wai-Yeung Wong, Suzanna Chan, Wing-Tak Wong

Syntheses of ruthenium-containing heterometallic complexes by use of tridentate phosphine ligands Pages 239-242 Nagwa Nawar, Anthony K. Smith

Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3 Pages 243-249 Ronald J. Cross, Alan R. Kennedy, Ljubica Manojlovi-Muir, Kenneth W. Muir

Insertion of methylene group into Fe---Te bond: synthesis and characterization of {(CO)3Fe(μ-CH2)Te}2 Pages 251-255 Pradeep Mathur, Bala Manimaran, Md. Munkir Hossain, C. V. V. Satyanarayana, Vedavati G. Puranik, Sudam S. Tavale

Acetylenic derivatives of Fe2(CO)6(μ-Se2): synthesis and spectroscopic characterization of [(CO)6Fe2{μ-SeC(H)=C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)---C(H)}] Pages 257-260 Pradeep Mathur, Aswini K. Dash, Md. Munkir Hossain, C. V. V. Satyanarayana

Synthesis, characterization and some reactions of [(diene)Rh(μ-OSiMe3)]2 Pages 261-266 Bogdan Marciniec, Piotr Krzyanowski

Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids Pages 267-270 R. Szalay, D. Knausz, L. Szakács, K. Újszászy, B. Csákvári, P. Sohár

Dimetallation of N-ethynylpyrrole and subsequent regiospecific derivatization Pages 271-273 A. G. Mal'kina, R. den Besten, A. C. H. T. M. van der Kerk, L. Brandsma, B. A. Trofimov

The role of hydrogen bonds involving the metal atom in protonation of polyhydrides of molybdenum and tungsten of MH4(dppe)2 Pages 275-277 E. S. Shubina, A. N. Krylov, N. V. Belkova, L. M. Epstein, A. P. Borisov, V. D. Mahaev