Editorial Pages 1-2 |
Reversible coordination of the high oxidation state dioxo-acetylide fragment (C5Me5)W(O)2(CCPh) to a hexaruthenium cluster frame Pages 3-10 Wen-Ji Chao, Yun Chi, Cathy Chung, Arthur J. Carty, Esther Delgado, Shie-Ming Peng, Gene-Hsiang Lee |
The unusual attachment of an alkyne across the open edge of a Rh2Pd complex Pages 11-18 Geoffrey R. County, Ron S. Dickson, Gary D. Fallon |
Preparation and redox properties of phosphite derivatives of R2C2Co2(CO)6−n[P(OMe)3]n (R=CF3, MeO2C) Pages 19-28 Noel W. Duffy, C. John McAdam, Brian H. Robinson, Jim Simpson |
Water soluble, hydrolytically stable derivatives of the antitumor drug titanocene dichloride and binding studies with nucleotides Pages 29-35 George Mokdsi, Margaret M. Harding |
Some acetylene and hydride chemistry of group 8 metal complexes with cyclopentadienyls and their analogous ligands Pages 37-48 Guochen Jia, Chak Po Lau |
Reaction of ethynediyl, butadiynediyl and ethynyl iron complexes, (η5-C5R5)(CO)2Fe–(C![]() Pages 49-62 Munetaka Akita, Min-Chul Chung, Masako Terada, Masanori Miyauti, Masako Tanaka, Yoshihiko Moro-oka |
Buta-1,2,3-trienylidene, acylvinylidene and acylalkynyl ruthenium complexes via activation of alkynes with RuCl2(dppe)2. X-ray structure of trans-[Ru(=C=CHCOCH2Ph)(Cl)(dppe)2]O3SCF3 Pages 63-73 Pierre Haquette, Daniel Touchard, Loïc Toupet, Pierre Dixneuf |
Investigation of the iron–carbon bonding for alkyl, alkynyl, carbene, vinylidene, and allenylidene complexes using 57Fe Mössbauer spectroscopy Pages 75-80 Valérie Guillaume, Patrice Thominot, Françoise Coat, Alain Mari, Claude Lapinte |
Mixed-metal cluster chemistry IX: alkylarylphosphine derivatives of [CpWIr3(CO)11] and X-ray crystal structure of [CpWIr3(μ-CO)3(CO)7(PMe2Ph)] Pages 81-95 Susan M. Waterman, Mark G. Humphrey, David C. R. Hockless |
Parallel coordination of hydrazine to diruthenium units: synthesis and molecular structure of the cationic complexes [(η6-C6Me6)2Ru2(μ2-H)2(μ2-η1,η1-H2NNH2)]2+ and [(η6-C6Me6)2Ru2(μ2-H)(μ2-η1,η1-H2NNH2)(μ2-NH2)]2+ Pages 97-103 Manfred Jahncke, Antonia Neels, Helen Stoeckli-Evans, Georg Süss-Fink |
Towards linked clusters: reactions of [Ru6(CO)17B]− with dppm and [ClAu(L–L)AuCl] (L–L=bis(diphenylphosphino)-alkanes, -ethene and -ethyne, and the crystal structure of [HRu6(CO)15(P,P′-dppm)B] (dppm=bis(diphenylphosphino)methane) Pages 105-114 Catherine E. Housecroft, Arnold L. Rheingold, Anne Waller, Glenn P. A. Yap |
Mono and difunctionalisation of chiral ferrocenyl bis-acetals. X-Ray crystal structure of bis-1,1′-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene Pages 115-124 Gabriel Iftime, Jean-Claude Daran, Eric Manoury, Gilbert G. A. Balavoine |
Orthomanganation of arylhydrazones and related N-donor substrates Pages 125-134 Maarten B. Dinger, Lyndsay Main, Brian K. Nicholson |
Linking of benzyne and carbon monoxide at a triruthenium centre by migratory insertion Pages 141-151 Jonathan P. H. Charmant, Helen A. A. Dickson, Nigel J. Grist, Selby A. R. Knox, A. Guy Orpen, Kathryn Saynor, Josep M. Viñas |
Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(=C=C10H8)(CO)2(PPh3)2 Pages 153-158 Lisa-J. Baker, Clifton E. F. Rickard, Warren R. Roper, Scott D. Woodgate, L. James Wright |
Silsesquioxanes: Part I: A key intermediate in the building of molecular composite materials Pages 159-164 Arthur Provatas, Martin Luft, Jun C. Mu, Alan H. White, Jani G. Matisons, Brian W. Skelton |
Synthesis and reaction chemistry of mixed ligand methylpalladium–carbene complexes Pages 165-178 David S. McGuinness, Melinda J. Green, Kingsley J. Cavell, Brian W. Skelton, Allan H. White |
Use of metal carbonyls in the formation of [H5O2+·15-crown-5][MOCl4(H2O)-], (M=Mo, W), and a second sphere coordination complex in [mer-CrCl3(H2O)3·15-crown-5] Pages 179-186 Peter C. Junk, Jerry L. Atwood |
Attachment of cyanometal units to the Fe4S4 cluster Pages 187-192 Nianyong Zhu, Ralf Appelt, Heinrich Vahrenkamp |
High nuclearity ruthenium carbonyl cluster chemistry VII. Synthesis, NMR studies, electrochemistry and X-ray crystal structure of [PPN] [Ru8(μ8-P)(CO)22] Pages 193-200 Marie P. Cifuentes, Susan M. Waterman, Mark G. Humphrey, Graham A. Heath, Brian W. Skelton, Allan H. White, M. P. Seneka Perera, Michael L. Williams |
Organolanthanoids XXIII complexes of tris(cyclopentadienyl)lanthanoids with tertiary phosphine oxides and the X-ray crystal structures of [YbCp3(OPPh3)] and [NdCp3(OPBun3)] Pages 201-210 Glen B. Deacon, Gary D. Fallon, Craig M. Forsyth, Bryan M. Gatehouse, Peter C. Junk, Anna Philosof, Paul A. White |
Perspectives in syntheses, structures and bonding of acetylide-containing clusters of group 11 metals Pages 211-216 Omar M. Abu-Salah |
Five-coordinate hydrogen in hydrido rhodium cluster compounds: A theoretical analysis Pages 217-224 Régis Gautier, Jean-François Halet |
A series of triisopropylstibine ruthenium and osmium complexes including the X-ray crystal structure of [RuCl2(CO)(SbiPr3)3] and [RuCl2(=C=C=CPh2)(CO)(SbiPr3)2] Pages 231-241 H. Werner, C. Grünwald, P. Steinert, O. Gevert, J. Wolf |
Diferrocenyltriphosphines 1: five-coordinate ruthenium complexes Pages 243-258 Ian R. Butler, Ulrich Griesbach, Piero Zanello, Marco Fontani, David Hibbs, Michael B. Hursthouse, K. L. M. Abdul Malik |
Reactions of metalloalkynes 3. Facile synthesis of pentanuclear ruthenium clusters. X-ray structures of [Ru5(μ5-C![]() Pages 259-265 Lindsay T. Byrne, Christopher S. Griffith, James P. Hos, George A. Koutsantonis, Brian W. Skelton, Allan H. White |
Synthesis and X-ray structure of Ru3(CO)6(μ2-CO)(μ2-AsPh2)(μ-O=C---C12H17), a first example of a CO insertion reaction to a cluster-bound hydrocarbon Pages 267-270 Omar bin Shawkataly, K. Puvanesvary, H. K. Fun, K. Sivakumar |
Organometallic clusters: What is an appropriate DFT treatment? Pages 271-277 Michael J. Liddell |
1,6-Bis(trimethylsilyl)hexa-1,3,5-triyne as a precursor to ruthenium clusters containing highly ethynylated ligands Pages 279-282 Paul J. Low, Gary D. Enright, Arthur J. Carty |
The preparation of mixed ligand ruthenocenes containing bulky cyclopentadienyl ligands. Crystal structures of pentaphenylruthenocene, [Ru(η5-C5Ph5)(η5-C5H5)], pentaparatolylruthenocene, [Ru{η5-C5(p-MeC6H4)5}(η5-C5H5)] and pentaphenylpentamethylruthenocene, [Ru(η5-C5Ph5)(η5-C5Me5)] Pages 283-296 C. U. Beck, L. D. Field, T. W. Hambley, P. A. Humphrey, A. F. Masters, P. Turner |
Index Page 297 |
Index Pages 299-303 |