Volume 593-594
Main Index

Pages 1-506 (15 January 2000)

Editorial Page XIX

Novel η3-allyl complexes of titanium Pages 1-6 F. Albert Cotton, Carlos A. Murillo, Marina A. Petrukhina

Redox behavior of the molybdenum and tungsten metallafullerenes Mo(CO)3(dppe)(η2-C60) (dppe=bis-(1,2-diphenylphosphino)ethane) and W(CO)3(dppb)(η2-C60) (dppb=bis-(1,2-diphenylphosphino)benzene) Pages 7-11 Piero Zanello, Franco Laschi, Marco Fontani, Li-Cheng Song, Ying-Huai Zhu

New dinuclear diphenylphosphido-bridged palladium(I) derivatives and the X-ray crystal and molecular structures of the mononuclear homoleptic diphenylphosphine complexes Pd(PPh2H)4 and [Pd(PPh2H)4](BF4)2 Pages 12-18 Piero Leoni, Fabio Marchetti, Stefano Papucci, Marco Pasquali

Carbon monoxide and tertiary phosphines as ligands in cyclopentadienyl derivatives of Group 4 elements in high oxidation state Pages 19-26 Guido Pampaloni, Giovanna Tripepi

Preparation of trichloro- and tribromocyclopentadienyltungsten(IV) Pages 27-35 Haley Blackburn, James C. Fettinger, Heinz-Bernhard Kraatz, Rinaldo Poli, Raymund C. Torralba

The charge distribution on metal-bonded cyclopentadienyl rings from infrared intensities Pages 36-43 Pier Luigi Stanghellini, Eliano Diana, Enrico Boccaleri, Rosanna Rossetti

Cyanide bridged trinuclear complexes with Fe---CN---MCl2---NC---Fe backbones (M=Ni, Cu, Zn) Pages 44-48 Guy N. Richardson, Heinrich Vahrenkamp

Glycosylmanganese pentacarbonyl complexes: an organomanganese-based approach to the synthesis of C-glycosyl derivatives Pages 49-62 Philip DeShong, Eric D. Soli, Greg A. Slough, D. Richard Sidler, Varadaraj Elango, Philip J. Rybczynski, Laura J. S. Vosejpka, Thomas A. Lessen, Thuy X. Le, Gary B. Anderson, Wolfgang von Philipsborn, Markus Vöhler, Daniel Rentsch, Oliver Zerbe

Iridium clusters containing η1 organic ligands: the synthesis and the solid state structure of [Ir4(CO)11(CPh=CHPh)]− and [Ir6(CO)14(COOMe)2]2− Pages 63-68 Roberto Della Pergola, Luigi Garlaschelli, Secondo Martinengo, Mario Manassero, Mirella Sansoni

1-Aza-1,3-butadiene complexes of tantalum: preparation and alkylation of TaCl2(η5-C5Me5)(η4-1-aza-1,3-butadiene) Pages 69-76 Kazushi Mashima, Yutaka Matsuo, Shinya Nakahara, Kazuhide Tani

Alkyne diruthenium chemistry Pages 77-85 Joshi Kuncheria, Hameed A. Mirza, Jagadese J. Vittal, Richard J. Puddephatt

The use of macrocyclic and polydentate ligands in ruthenium organometallic chemistry Pages 86-95 Christine Stern, Federico Franceschi, Euro Solari, Carlo Floriani, Nazzareno Re, Rosario Scopelliti

Versatility of silica used as a ligand: effect of thermal treatments of silica on the nature of silica-supported alkyl tantalum species Pages 96-100 Laurent Lefort, Mathieu Chabanas, Olivier Maury, Damien Meunier, Christophe Copéret, Jean Thivolle-Cazat, Jean-Marie Basset

Organometallic crystals engineering: Part 7. Construction of mixed-metal crystalline systems via electrostatic interactions and cooperative strong and weak hydrogen bonds Pages 101-108 Dario Braga, Lucia Maini, Fabrizia Grepioni

Promotion of the [PPN][Rh(CO)4]-catalysed carbonylation of nitrobenzene by 2-hydroxypyridine and related molecules: an apparent bifunctional activation Pages 109-118 Fabio Ragaini, Emma Gallo, Sergio Cenini

Effect of anions on the isocyanide insertion reaction in cationic alkyl complexes of iron(II): kinetic, thermodynamic and solution interionic structural studies Pages 119-126 Gianfranco Bellachioma, Giuseppe Cardaci, Alceo Macchioni, Cristiano Zuccaccia

Adducts of cyclotriphosphorus complexes: synthesis, solid state structure and solution behaviour of the bis-adducts [{(triphos)Co}(P3){M(CO)5}2] [triphos=MeC(CH2PPh2)3; M=Cr, Mo, W] Pages 127-134 Massimo Di Vaira, Markus P. Ehses, Maurizio Peruzzini, Piero Stoppioni

Facile oxidative addition/reductive elimination of HX (X=Cl, Br, I) on (μ-H)2Os3(CO)10 Pages 135-141 Silvio Aime, Walter Dastrù, Roberto Gobetto, Alessandra Viale

Synthesis, reactions and structure of bromo(η5-diphenylphosphinylcyclopentadienyl)nickel(II) dimer Pages 142-146 Matthew S. Blais, Robin D. Rogers, Marvin D. Rausch

Reactivity of vinyl and alkynyl zirconium complexes with the di-ansa-[1,1′,2,2′-bis(dimethylsilanediyl) dicyclopentadienyl] ligand Pages 147-153 Francisco J. Fernández, Mikhail V. Galakhov, Pascual Royo

Catalytic and stoichiometric reactions of tertiary silanes with [Ir(Me)2Cp*L] (Cp*=η5-C5Me5; L=PMe3, PMe2Ph, PMePh2, PPh3) in the presence of one-electron oxidants. A unique case of Si---H, Si---C, Ir---C and P---F bonds one-step activation: crystal structure of [Ir(Ph)(SiPh2F)Cp*(PMe3)] Pages 154-160 Pietro Diversi, Fabio Marchetti, Valentina Ermini, Simona Matteoni

Crystal and molecular structures of 4,4′-bis(dimethylhydroxysilyl)-biphenyl and m-bis(dimethylhydroxysilyl)benzene Pages 161-166 David M. L. Goodgame, Paul D. Lickiss, Stephan Menzer, Stephanie J. Rooke, David J. Williams

Cyclopentadienyl transfer reaction: thermal reaction between Re2(CO)10 and a series of cyclopentadienyl transition metal complexes Pages 167-174 Siden Top, Christophe Lescop, Jean-Sébastien Lehn, Gérard Jaouen

Syntheses and structures of di- and trinuclear heterometallic complexes with nitrido bridges between rhenium and titanium Pages 175-179 Edwin Gauch, Holger Hoppe, Joachim Strähle

Stable alkynyl palladium(II) and nickel(II) complexes with terdentate PNO and PNN hydrazone ligands Pages 180-191 Alessia Bacchi, Mauro Carcelli, Mirco Costa, Andrea Fochi, Claudio Monici, Paolo Pelagatti, Corrado Pelizzi, Giancarlo Pelizzi, Luisa Maria Sanjuan Roca

A series of mono- and dihydrido- as well as mono- and dimethylosmium(II) complexes containing [(mes)Os(CNR)] as a building block Pages 192-201 H. Werner, U. Wecker

Synthesis and characterization of titanium(IV) complexes containing the diphenylphosphino- and diphenylthiophosphoryl-functionalized cyclopentadienyl ligand. Crystal and molecular structure of Ti(η5-C5H4PPh2)Cl3 Pages 202-210 Juan C. Flores, Rocío Hernández, Pascual Royo, Angelika Butt, Thomas P. Spaniol, Jun Okuda

The oxo-synthesis catalyzed by cationic palladium complexes, selectivity control by neutral ligand and anion Pages 211-225 E. Drent, P. H. M. Budzelaar

Conformational constraints and σ–π-vinyl interchange in μ3-η3-5,6-dihydroquinoline triosmium complexes Pages 226-231 Susan T. Beatty, Brian Bergman, Edward Rosenberg, Walter Dastru’, Roberto Gobetto, Luciano Milone, Alessandra Viale

The Co3(CO)9C moiety acts as an electroreducible marker for estradiol detection enhancement in the HPLC-ED technique Pages 232-239 Domenico Osella, Carlo Nervi, Luciano Milone, Francesco Galeotti, Anne Vessières, Gerard Jaouen

Aromatic arylation via palladacycles: interception of reaction intermediates Pages 240-244 Marta Catellani, Elena Motti, Luca Paterlini

Reaction of nickelocene with methyllithium in the presence of 2-butyne Pages 245-250 S. Pasynkiewicz, A. Pietrzykowski, B. Kryza-Niemiec, L. Jerzykiewicz

Synthesis of 9-anthrylmethyl-functionalised cyclopentadienyl derivatives of rhodium(I) and iridium(I) and study of their luminescence properties Pages 251-266 Francesca Cicogna, Massimo Colonna, Julien L. Houben, Giovanni Ingrosso, Fabio Marchetti

Absorption and luminescence as a function of pH for carboxylic acid-functionalized ReI tricarbonyls Pages 267-273 Ilaria Costa, Marco Montalti, Piersandro Pallavicini, Angelo Perotti, Luca Prodi, Nelsi Zaccheroni

Vinylic, allylic and homoallylic oxidations of alkenes via π- and σ-organopalladium complexes Pages 274-291 N. Yu. Kozitsyna, M. N. Vargaftik, I. I. Moiseev

Dimerization of terminal alkynes catalyzed by indenyl ruthenium(II) complexes Pages 292-298 Mauro Bassetti, Silvia Marini, Francesco Tortorella, Victorio Cadierno, Josefina Díez, M. Pilar Gamasa, José Gimeno

Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η6-p-cymene)Ru(amino acidato)Cl] and [(η6-p-cymene)Ru(amino acidato)]3(BF4)3 complexes Pages 299-306 Ágnes Kathó, Daniel Carmona, Fernando Viguri, Carlos D. Remacha, József Kovács, Ferenc Joó, Luis A. Oro

An experimental and theoretical study of the electronic and molecular structure of [Zn4(?4-S){μ-S2P(OC2H5)2}6]: the first molecular model of ZnS Pages 307-314 Alberto Albinati, Maurizio Casarin, Frank Eisentraeger, Chiara Maccato, Luciano Pandolfo, Andrea Vittadini

Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands Pages 315-324 Annalisa Bisello, Alberto Ceccon, Alessandro Gambaro, Paolo Ganis, Francesco Manoli, Saverio Santi, Alfonso Venzo

Synthesis and characterization of new paramagnetic nickel carbonyl clusters containing antimony atoms: X-ray structure of [NEt3CH2Ph]2[Ni15(μ12-Sb)(CO)24] and [NEt4]3[Ni10Sb2(μ12-Ni)(CO)18] Pages 325-334 Vincenzo G. Albano, Francesco Demartin, Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Magda Monari, Piero Zanello

New metallapyrrole complexes from [M2(μ-CNMe2)(μ-CO)(CO)2(Cp)2]SO3CF3 (M=Fe, Ru) and acetonitrile anions; structure of [(Cp)(CO)(CN)] Pages 335-341 Luigi Busetto, Chiara Camiletti, Valerio Zanotti, Vincenzo G. Albano, Piera Sabatino

Solution and solid–gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda=Me2NC2H4NMe2) Pages 342-353 Christian Gemel, John C. Huffman, Kenneth G. Caulton, Klaus Mauthner, Karl Kirchner

Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2−) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2− Pages 354-360 Giovanna Tripepi, Victor G. YoungJr., John E. Ellis

Synthesis and characterization of a first generation organorhenium dendrimer Pages 361-368 Ipe J. Mavunkal, John R. Moss, John Bacsa

Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene Pages 369-379 Nicolette Rot, Frans J. J. de Kanter, Friedrich Bickelhaupt, Wilberth J. J. Smeets, Anthony L. Spek

Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes Pages 380-387 Stefano Maiorana, Clara Baldoli, Paola Del Buttero, Emanuela Licandro, Antonio Papagni, Maurizio Lanfranchi, Antonio Tiripicchio

Reaction of phenylacetylene with (butadiene)tantalocene cation Pages 388-391 Hans Christian Strauch, Gerhard Erker, Roland Fröhlich

Solid state and solution structural studies of silver(I) cyclic complexes bearing the (Bzim)Ph2P ligand Pages 392-402 Fiorella Bachechi, Alfredo Burini, Rossana Galassi, Alceo Macchioni, Bianca Rosa Pietroni, Fabio Ziarelli, Cristiano Zuccaccia

Structural properties of the metallointercalator cationic complex (2,2′:6′,2″-terpyridine)methylplatinum(II) ion Pages 403-408 Raffaello Romeo, Luigi Monsù Scolaro, Maria Rosaria Plutino, Alberto Albinati

Palladium-catalyzed synthesis of 2E-[(methoxycarbonyl)methylene]tetrahydrofurans: oxidative cyclization–methoxycarbonylation of 4-yn-1-ols versus cycloisomerization–hydromethoxylation Pages 409-415 Bartolo Gabriele, Giuseppe Salerno, Francesca De Pascali, Mirco Costa, Gian Paolo Chiusoli

Ruthenium sulfophthalocyanine catalyst for the oxidation of chlorinated olefins with hydrogen peroxide Pages 416-420 Mario Bressan, Nicola Celli, Nicola d’Alessandro, Lolita Liberatore, Antonino Morvillo, Lucia Tonucci

Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt–Hg bonds unsupported by covalent bridging ligands Pages 421-426 José María Casas, Larry R. Falvello, Juan Forniés, Julio Gomez, Angel Rueda

New routes to the synthesis of chloro-carbonyls of palladium(II) and platinum(II) Pages 427-430 Daniela Belli Dell’Amico, Luca Labella

Pd(II) and Rh(I) chelate complexes of the bidentate phosphino–thiourea ligand PhNHC(S)NHCH2CH2PPh2: structural properties and activity in homogeneous and hybrid catalysis Pages 431-444 Daniele Cauzzi, Mirco Costa, Nicola Cucci, Claudia Graiff, Federica Grandi, Giovanni Predieri, Antonio Tiripicchio, Roberto Zanoni

Pt(IV) derivatives formed by oxidative addition of organic halides to [Pt(CH3)2(N,N-chelate)] substrates: geometric isomers at equilibrium Pages 445-453 Vincenzo De Felice, Bruno Giovannitti, Augusto De Renzi, Diego Tesauro, Achille Panunzi

Ruthenium clay catalyzed reduction of α-iminoesters and α-iminoketones, and the reductive amination of α-ketoesters Pages 454-457 Raluca Aldea, Howard Alper

The synthesis, structure, and reactivity of the osmium(IV) trihydrido silyl complex, OsH3(SiMe3)(CO)(PPh3)2 Pages 458-464 Michael Möhlen, Clifton E. F. Rickard, Warren R. Roper, David M. Salter, L. James Wright

Reactions of binuclear ruthenium–platinum μ-allenyl complexes with nucleophilic and electrophilic reagents. The characterization of two 1:1 adducts of L(PPh3)Pt(μ-η1:η2α,β-C(Ph)=C=CH2)Ru(CO)Cp (L=PPh3, t-BuNC) and p-toluenesulfonyl isocyanate Pages 465-478 Richard R. Willis, Mario Calligaris, Paolo Faleschini, Judith C. Gallucci, Andrew Wojcicki

Hydride elimination from an iridium(III) alkoxide complex: a case in which a vacant cis coordination site is not required Pages 479-484 Ofer Blum, David Milstein

Ruthenium-assisted synthesis of gem-deuterated alkenes from monosubstituted propargyl alcohols and D2O Pages 485-488 Claudio Bianchini, Isaac de los Rios, Carlos Lopez, Maurizio Peruzzini, Antonio Romerosa

Convenient syntheses of novel ruthenium catalysts bearing N-heterocyclic carbenes Pages 489-493 Walter Baratta, Wolfgang A. Herrmann, Pierluigi Rigo, Jürgen Schwarz

Synthesis and X-ray crystal structure of decamethylrhodocenium hexafluorophosphate Pages 494-496 Dirk Buchholz, Laszló Zsolnai, Gottfried Huttner, Didier Astruc

Index Pages 497-498

Index Pages 499-506