Volume 601
Main Index

Issue 1, Pages 1-198 (20 April 2000)

Synthesis, characterization and X-ray structural determination of palladium(0)–olefin complexes containing pyridin-thioethers as ancillary ligands. Equilibria and rates of olefin and ligand exchange Pages 1-15 Luciano Canovese, Fabiano Visentin, Gavino Chessa, Paolo Uguagliati, Alessandro Dolmella

Studies on the nature of active species in W(CO)6/CCl4/hν system as applied to metathesis polymerisation reactions Pages 16-21 Gita Bhukta, Ramanujachary Manivannan, Govindarajan Sundararajan

Cyclometallated platinum complexes with thienyl imines. X-ray crystal structure of [PtMe{3-(PhCH2NCH)C4H2S}PPh3] Pages 22-33 Craig Anderson, Margarita Crespo, Mercè Font-Bardía, Axel Klein, Xavier Solans

From molecules to aggregates: crystal structures of molybdenum binuclear complexes Pages 34-42 Patrícia Pinto, Eva Barranco, Maria José Calhorda, Vitor Félix, Michael G. B. Drew

Cationic palladium complexes with ketophosphine and phosphino enolate ligands and their reactivity towards C---C coupling reactions. Crystal structures of [)Ph}(PCy3)](PF6) and [)Ph}(SMe2)2](PF6) Pages 43-50 Jacques Andrieu, Pierre Braunstein, Frédéric Naud, Richard D. Adams

Complexes cis-[PdCl2(OSMeR)2] (R=Me, Ph, and C6H4Me-4) in attempted asymmetric cyclometalation of dimethylaminomethylferrocene Pages 51-56 Alexander D. Ryabov, Irina M. Panyashkina, Gregory M. Kazankov, Vladimir A. Polyakov, Lyudmila G. Kuz’mina

Syntheses of monomeric iron and manganese complexes using bulky tripodal ligands: catalytic alkene epoxidations Pages 57-68 Jinyuan Chen, L. Keith Woo

Synthesis and molecular structure of [RuCl{C(=CHPh)OC(=O)CH2CH3}(CO)(PPh3)2]: a real intermediate in ruthenium complex-catalyzed selective synthesis of a (Z)-enol ester Pages 69-77 Hiroyuki Kawano, Yoshiko Masaki, Takahiro Matsunaga, Katsuma Hiraki, Masayoshi Onishi, Taro Tsubomura

Functionalised alkenylcarbene metal complexes (M=Ru, W, Cr) by activation of propargyl alcohol derivatives Pages 78-86 Karine Ulrich, Emmanuel Porhiel, Vincent Péron, Vincent Ferrand, Hubert Le Bozec

Reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) with azides. Synthesis of (μ-RE)(μ-p-R1C6H4N3H)Fe2(CO)6 and crystal structure of (μ-ButS)(μ-PhN3H)Fe2(CO)6 Pages 87-92 Zhong-Xia Wang, Shao-Bin Miao, Zhong-Yuan Zhou, Xiang-Ge Zhou

Synthesis, electrochemistry and electronic spectra of tetranuclear bis(η2-alkynyl) transition-metal complexes. The molecular structure of [(η5-C5H4SiMe3)2Ti(CCFc)2]CuBr Pages 93-99 Stephan Back, Gerd Rheinwald, Heinrich Lang

On the mechanism of hydroesterification of styrene using an in situ-formed cationic palladium complex Pages 100-107 A. Seayad, S. Jayasree, K. Damodaran, L. Toniolo, R. V. Chaudhari

Reactions of [(μ-RS)(μ-S){Fe2(CO)6}2(μ4-S)]− with acid chlorides and diacid chlorides. Crystal structure of (μ-PhCH2S)[μ-CH2=C(Me)COS][Fe2(CO)6]2(μ4-S) Pages 108-113 Zhong-Xia Wang, Cheng-Sheng Jia, Zhong-Yuan Zhou, Xiang-Ge Zhou

para-Substituted diphenylborylated organocobaloximes: effects of substituents on conformation and redox properties Pages 114-125 Fioretta Asaro, Renata Dreos*, Giorgio Nardin, Giorgio Pellizer, Silvia Peressini, Lucio Randaccio*, Patrizia Siega, Giovanni Tauzher, Claudio Tavagnacco

Selective oxidants for organometallic compounds containing a stabilising anion of highly reactive cations: (3,5(CF3)2C6H3)4B−)Cp2Fe+ and (3,5(CF3)2C6H3)4B−)Cp*2Fe+ Pages 126-132 Ivonne Chávez, Angel Alvarez-Carena, Elies Molins*, Anna Roig, Waldemar Maniukiewicz, Alenjandra Arancibia, Verónica Arancibia, Holger Brand, Juan Manuel Manríquez*

Transportation in MOCVD of traces of oxygenated aluminum and gallium organometallics Pages 133-137 Kazimierz B. Starowieyski, Marek Kaczorek, Krzysztof Pakua

Asymmetric catalytic hydroformylation of styrene: stereoselective ferrocenylethyldiphosphine rhodium catalysts Pages 138-141 Florian A. Rampf, Wolfgang A. Herrmann

Synthesis and structural characterisation of bis(trimethylsilyl)amidotin(II) triflate [{Sn(NR2)(μ-η2-∞ (R=SiMe3, −OTf=−OSO2CF3) Pages 142-146 Peter B. Hitchcock, Michael F. Lappert, Gerard A. Lawless, Geraldo M. de Lima, Luc J. -M. Pierssens

The ring expansion of a dimethyl-substituted vinylcyclobutene derivative by metal complexes that can undergo an inner-sphere electron transfer Pages 147-152 Herman L. HoltJr., Tom Russo, Allan R. Pinhas

Synthesis of γ-lactones and unsaturated bis γ-lactones via Cu–Fe-mediated reductive cyclization of di- and tri-α-halogenated carboxylic esters Pages 153-159 Iris Somech, Youval Shvo

Anionic dichlorolanthanocene compounds. X-ray crystal structures of [{(Me3Si)2C5H3}2LnCl2][Li(THF)4] (Ln=Er, Yb) and {(Me3Si)2C5H3}2Yb(μ-Cl)2Li(THF)2 Pages 160-163 Hoi-Shan Chan, Qingchuan Yang, Thomas C. W. Mak, Zuowei Xie

Synthesis and characterisation of cyclometallated orthoazobenzene complexes of Ru(II): crystal and molecular structure of [RuCl(CO)(η2-C,N-C6H4N=NPh)(PPh3)2]·0.5CHCl3·0.5Et2O. Is there a similarity to the hydroxyazo/ketohydrazone tautomerisation in ortho-hydroxyazobenzenes? Pages 164-171 Wendy I. Cross, Kevin R. Flower, R. G. Pritchard

Functionalisation of tetraalkylsilanes derived from C---H activation; towards annulations of diterpenoids Pages 172-190 Paul W. R. Harris, Clifton E. F. Rickard, Paul D. Woodgate

Synthesis and characterization of single-source precursors to nanocrystalline GaP, GaPxAs1−x, and GaPxSb1−x. X-ray crystal structures of [Et2GaP(SiMe3)2]2, (Me3Si)2P[μ-GaEt2]2As(SiMe3)2, and (Me3Si)2P[μ-GaEt2]2Sb(SiMe3)2 Pages 191-198 Richard J. Jouet, Richard L. Wells, Arnold L. Rheingold, Christopher D. Incarvito

Issue 2, Pages 201-355 (28 April 2000)

Reactivity of [Pd3(μ-OAc)3(μ,η2-MeSCHCO2Et-C,S)3] in the presence of triphenylphosphine: a model of the early steps of the Pd/PR3-catalysed Heck reaction Pages 201-210 Marino Basato*, Barbara Sesto, Marco Zecca*, Giovanni Valle, Sabrina Antonello, Flavio Maran*

Optically active transition-metal complexes: Part 124. Chiral 1-phospha[1]ferrocenophanes and 1,12-diphospha[1.1]ferrocenophanes — synthesis, characterization and ring-opening polymerization Pages 211-219 Henri Brunner, Jürgen Klankermayer, Manfred Zabel

Synthesis, structure, and reactivity of ruthenium(II) complexes with a hemilabile tetradentate etherdiphosphine ligand Pages 220-225 Ekkehard Lindner, Joachim Wald, Klaus Eichele, Riad Fawzi

Zur Umsetzung von Bis(alkinyl)-Titanocenen mit Übergangsmetall-Verbindungen von Cu(II), Pd(II), Pt(II), Fe(III) und Au(III) Pages 226-232 W. Frosch, S. Back, K. Köhler, H. Lang

Tetrahalogenomethanes: simple reagents for the synthesis of monohalogenated and mixed dihalogenated aromatic heterocycles via metal–halogen exchange from lithium compounds Pages 233-236 Carla Boga, Erminia Del Vecchio, Luciano Forlani, Paolo Edgardo Todesco

Synthesis, structures and luminescent properties of metal complexes containing 4-[2-(9-anthryl)vinyl]pyridine Pages 237-245 Wai-Yeung Wong, Kai-Yin Tsang, Ka-Hang Tam, Guo-Liang Lu, Chaode Sun

Oxidation potential of benzylferrocenes and related compounds: effects of the ortho-methoxy substituent in the phenyl group Pages 246-252 Masahiro Asahara, Satoko Natsume, Hideaki Kurihara, Takuya Yamaguchi, Tatsuo Erabi, Masanori Wada

Restudies of the spin state in (isothiocyanato)(pyridine)(porphinato)iron(III) hemipyridine complex. A spin-crossover complex with two magnetically distinct sites Pages 253-258 Teng-Yuan Dong, Pei-Har Ho, Ching-Hung Cheng, Yu Wang

Mixed reagent (aminosilyl)lithium/i-PrMgBr for the synthesis of functionalized oligosilanes Pages 259-266 Atsushi Kawachi, Kohei Tamao

The crystal structure of 5-hydro- and 7-hydro-s-indacenide-Rh(COD). A comparison with similar complexes Pages 267-270 Alberto Ceccon, Paolo Ganis, Francesco Manoli, Alfonso Venzo

Regiospecificity in reactions of alkynes and phosphines with the phosphido-bridged iron–cobalt complex [(OC)4Fe(μ-PPh2)Co(CO)3] Pages 271-283 Jason D. King, Martin J. Mays*, Chi-Yu Mo, Paul R. Raithby, Moira A. Rennie, Gregory A. Solan*, Trushar Adatia, Gráinne Conole

Rh and Ir complexes containing multidentate, C2-symmetry ligands. Structural and catalytic properties in asymmetric hydrogenation Pages 284-292 M. J. Alcón, M. Iglesias*, F. Sánchez*, I. Viani

Synthesis and solvatochromism of some dipolar aryl-phosphonium and -phosphine oxide systems Pages 293-298 David W. Allen, Josephine P. Mifflin, Peter J. Skabara

Cyclometallated complexes of ruthenium and osmium containing the o-C6H4PPh2 ligand Pages 299-304 Martin A. Bennett, Alex M. Clark, María Contel, Clifton E. F. Rickard, Warren R. Roper, L. James Wright

Chiral cyclopalladated liquid crystals from amino acids Pages 305-310 Daniel J. Saccomando, Catherine Black, Gareth W. V. Cave, Donocadh P. Lydon, Jonathan P. Rourke

Pentacoordinated diolefinic rhodium(I) organocomplexes with α-diimine ligands. Crystal structures of [Rh(Nbd)(LL)(PPh3)]ClO4 (Nbd=norbornadiene; LL=Bdh, biacetylidihydrazone; Pvdh, pyruvaldihydrazone; Bda, biacetyldianil) Pages 311-319 Mohammed Bikrani, Rachad El Mail, María A. Garralda*, Lourdes Ibarlucea, Elena Pinilla*, M. Rosario Torres

Rhodium-catalyzed hydroformylation of 1-allylpyrrole as an unexpected way to 5,6-dihydroindolizine synthesis Pages 320-323 Raffaello Lazzaroni, Roberta Settambolo, Aldo Caiazzo, Lorenzo Pontorno

Photolysis of 7,8-digermabicyclo[2.2.2]octadiene. The investigation of the elementary stages by means of 1H CIDNP and laser pulse photolysis Pages 324-329 M. B. Taraban, O. S. Volkova, V. F. Plyusnin, Yu. V. Ivanov, T. V. Leshina, M. P. Egorov, O. M. Nefedov, T. Kayamori, K. Mochida

Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH2PPh2) Pages 330-334 Hon Man Lee, Chuluo Yang, Guochen Jia

Ligating similarities between the novel five-electron-donor η4-P3C2But2(R)H ring system, (R=CH(SiMe3)2) and the η5-cyclopentadienyl ring. Syntheses, crystal and molecular structures of [Co2(CO)5(μ-P3C2But2CH(SiMe3)2)] and [Co(CO)2(η4-P3C2But2H(CH(SiMe3)2] Pages 335-340 Peter B. Hitchcock, John F. Nixon, Nurgün Sakarya

On the in situ trimethylsilylation of zinc acetylides Pages 341-342 Uno Mäeorg, Säde Viirlaid, Hannes Hagu, Hermann D. Verkruijsse, Lambert Brandsma

Erratum to “An experiment and theoretical study of the electronic and molecular structure of [Zn4(μ4-S){μ-S2P(OC2H5)2}6]: the first molecular model of ZnS”: [Journal of Organometallic Chemistry 593–594 (2000) 307–314] Page 343 Alberto Albinati, Maurizio Casarin, Frank Eisentraeger, Chiara Maccato, Luciano Pandolfo, Andrea Vittadini

Erratum to “Conformational constraints and σ–π-vinyl interchange in μ3-η3-5,6-dihydroquinoline triosmium complexes”: [Journal of Organometallic Chemistry 593–594 (2000) 226–231] Page 344 Susan T. Beatty, Brian Bergman, Edward Rosenberg, Walter Dastru’, Roberto Gobetto, Luciano Milone, Alessandra Viale

Index Pages 347-348

Index Pages 349-355