Volume 621
Main Index

Issues 1-2, Pages 1-371 (1 March 2001)

Preface Pages 1-2 W. A. Herrmann

Mono(cyclopentadienyl)titanium complexes containing a sulfide-bridged bis(phenolato) ligand. Molecular structure of Ti{2,2′-S(OC6H2-4-Me-6-tBu)2}(η5-C5H5)Cl Pages 3-9 Francisco Amor, Stefan Fokken, Thomas Kleinhenn, Thomas P. Spaniol, Jun Okuda

Silaheterocyclen XXXVII.: Die Kombination Alkeninylhalogensilan/Lithium-tert-Butyl als Synthesebaustein zum Aufbau von Silaheterocyclen mit kumulierten CC-Doppelbindungen Pages 10-25 Norbert Auner, Martin Grasmann

Transition metal complexes with the C1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in different phase systems Pages 26-33 Claudio Bianchini, Pierluigi Barbaro, Giancarlo Scapacci

Tunable ferrocenyl diphosphine ligands for the Ir-catalyzed enantioselective hydrogenation of N-aryl imines Pages 34-38 Hans-Ulrich Blaser*, Hans-Peter Buser, Robert Häusel, Hans-Peter Jalett, Felix Spindler*

Stereoselective synthesis of chiral terminal (E)-1,3-enynes derived from the aldehydes (1R)-(−)-myrtenal and (S)-(−)-perillaldehyde using the alkynyl–phosphonio complex [Ru{CCCH2(PPh3)}(η5-C9H7)(PPh3)2][PF6] as synthon Pages 39-45 Victorio Cadierno, M. Pilar Gamasa, José Gimeno

Synthesis of poly(ferrocenyldialkoxysilane) polymers and their introduction into oxide matrices Pages 46-54 Gérard Calléja, Geneviève Cerveau, Robert J. P. Corriu

Reactions of Cp*Ir(2,5-dimethylthiophene) with electrophiles, acids, and maleic anhydride Pages 55-65 Jiabi Chen, Robert J. Angelici

The electronic structure and bonding in W2(μ-H)2(OiPr)4(DMPE)2 and a comparison with Mo2(OiPr)4(DMPE)2 Pages 66-69 Malcolm H. Chisholm, Matthew A. Lynn

Dihydroxylation of olefins using air as the terminal oxidant Pages 70-76 Christian Döbler, Gerald M. Mehltretter, Uta Sundermeier, Matthias Beller

Organotransition-metal-modified sugars: Part 17. Glucal-derived carbene complexes: synthesis and diastereoselective benzannulation Pages 77-88 Karl Heinz Dötz, Frank Otto, Martin Nieger

Part III. COD versus NBD precatalysts. Dramatic difference in the asymmetric hydrogenation of prochiral olefins with five-membered diphosphine Rh-hydrogenation catalysts Pages 89-102 Hans-Joachim Drexler, Wolfgang Baumann, Anke Spannenberg, Christine Fischer, Detlef Heller

Catalytic hydrogenation of aromatics under biphasic conditions: isolation and structural characterisation of the cluster intermediate [(η6-C6Me6)2(η6-C6H6)Ru3(μ2-H)2(μ2-OH)(μ3-O)]+ Pages 103-108 Matthieu Faure, Ana Tesouro Vallina, Helen Stoeckli-Evans, Georg Süss-Fink

Metallkomplexe mit biologisch wichtigen Liganden, CXXVII: Halbsandwich-Komplexe von Ruthenium, Rhodium und Iridium sowie phosphanhaltige Palladium- und Platin(II)-Komplexe mit Schiff-Basen aus α-Aminosäureanionen und Aldehyden Pages 109-119 Armin Fehn, Theodor Ederer, Shahram Mihan, Wolfgang Beck

Synthesis of achiral, but unsymmetric, seven-membered rhodium(I)-chelates for hydrogenation in the chiral environment of alkyl polyglucoside micelles Pages 120-129 V. Fehring, R. Kadyrov, M. Ludwig, J. Holz, K. Haage, R. Selke

Highly efficient enantioselective catalysis in supercritical carbon dioxide using the perfluoroalkyl-substituted ligand (R,S)-3-H2F6-BINAPHOS Pages 130-142 Giancarlo Franciò, Klaus Wittmann, Walter Leitner

Alkinstabilisierte monomere Organo-Kupfer(I)-Verbindungen als Organyl-Transfer Reagenzien Pages 143-152 W. Frosch, S. Back, H. Lang

Ligands with cycloalkane backbones VIII. Steric effects in the ligand accelerated enantioselective alkylation of benzaldehyde Pages 153-157 Holger Glas, Michael Barz, Werner R. Thiel

Aqueous micellar and non-micellar effects during the asymmetric hydrogenation of dehydroamino acid derivatives: influence of amphiphiles on enantioselectivity and α-CH/CD exchange Pages 158-165 Ingrid Grassert, Günther Oehme

Cationic derivatives of RhCl[P(η2-C7H7)3]. An intramolecular Diels–Alder rearrangement in the tripodal ligand tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3 Pages 166-172 Max Herberhold, Stefan Eibl, Wolfgang Milius

Improved synthesis of the radical source bis[2,2,6,6-tetramethylpiperidyl-(1)]-disulfide and photoinduced reactions with M2(CO)10 (M=Mn, Re) Pages 173-176 Peter Jaitner, Karl Jäger, Astrid Dorfer, K. -E. Schwarzhans

Syntheses and properties of the novel co-catalysts N,N-dimethylanilinium- and trityl{tetrakis[4-(trifluoromethyl)-2,3,5,6-tetrafluorophenyl]borate} Pages 177-183 Franz A. R. Kaul, Gerd T. Puchta, Horst Schneider, Manja Grosche, Dimitrios Mihalios, Wolfgang A. Herrmann

Trimethylammonium[tetrakis(pentafluorophenoxy)borate], a safe way to synthesize novel co-catalysts for olefin polymerization Pages 184-189 Franz A. R. Kaul, Gerd T. Puchta, Horst Schneider, Manja Grosche, Dimitrios Mihalios, Wolfgang A. Herrmann

Synthesis and characterization of platinum(II)-terminated dendritic carbosilanes: X-ray crystal structure of the model species [PtCl(C6H3{CH2NMe2}-2-SiMe3-5)(PPh3)] Pages 190-196 Arjan W. Kleij, Robertus J. M. Klein Gebbink, Martin Lutz, Anthony L. Spek*, Gerard van Koten*

Preparation and structural features of 1-(2-pyridyl)- and 1-(2-furyl)indenyl-zirconium complexes Pages 197-206 Thorsten Dreier, Roland Fröhlich, Gerhard Erker

Chiral bis(oxazoline) and pyridyl alcoholate dioxo-molybdenum(VI) complexes: synthesis, characterization and catalytic examinations Pages 207-217 Fritz E. Kühn*, Ana M. Santos, André D. Lopes, Isabel S. Gonçalves, José E. Rodríguez-Borges, Martyn Pillinger, Carlos C. Romão*

Chelating behaviour of a phosphinoalcohol leading to a stable alcohol palladium complex Pages 218-223 Chris Mattheis, Pierre Braunstein

‘Supine’ or ‘prone’ ligands: geometric preference of conjugated diene, 1-azadiene, and 1,4-diazadiene ligands on half-metallocene complexes of early transition metals Pages 224-230 Akira Nakamura, Kazushi Mashima

A study of Noyori's reagent Pages 231-241 Heinrich Nöth, Andreas Schlegel, Max Suter

High performance liquid chromatography for facile analytical separation of the enantiomers of chiral organometallic complexes Pages 242-245 Sara N. Paisner, Robert G. Bergman

Stoichiometric cyclotrimerisation of chiral alkynes at a ruthenium centre: preparation of optically active (η6-arene)(η4-cycloocta-1,5-diene)ruthenium(0) complexes Pages 246-253 Paolo Pertici, Alessandra Verrazzani, Emanuela Pitzalis, Anna Maria Caporusso, Giovanni Vitulli

Self-assembly of [Cu(CN)4]3− ions with cationic {Me3Sn}+ or {Me2Sn(CH2)3SnMe2}2+ fragments in the presence of a nBu4N+ template Pages 254-260 Eyck-Michael Poll, Jens-Udo Schütze, R. Dieter Fischer, Nicola A. Davies, David C. Apperley, Robin K. Harris

Intramolecularly donor-stabilized silenes: Part 3. Synthesis and structure of 1-[2,6-bis(dimethylaminomethyl)phenyl]-1,2,2-tris(trimethylsilyl)silene Pages 261-266 Matthias Pötter, Ute Bäumer, Martin Mickoleit, Rhett Kempe, Hartmut Oehme

Preparation and crystal structures of the complexes (η5-C5H3TMS–CMe2–η5-C13H8)MCl2 and [3,6-ditButC13H6–SiMe2–NtBu]MCl2 (M=Hf, Zr or Ti): mechanistic aspects of the catalytic formation of a isotactic–syndiotactic stereoblock-type polypropylene Pages 267-276 Abbas Razavi, Ulf Thewalt

Cyclooctatetraene complexes of yttrium and the lanthanides with chiral and achiral aminotroponiminates Pages 277-283 Peter W. Roesky

Meta, para and meta, ortho double exo nucleophilic additions of trimethylsilylester enolates derived from saturated and unsaturated carboxylic acids to tricarbonylchromium complexes of aryl ethers: dearomatizing cyclization to lactones Pages 284-298 Henri Rudler, Virginie Comte, Eva Garrier, Moncef Bellassoued, Evelyne Chelain, Jacqueline Vaissermann

Insertion of carbon dioxide and isocyanide into tantalum–amide and tantalum–methyl bonds Pages 299-303 Javier Sánchez-Nieves, Pascual Royo

Unbridged metallocene dichloride complexes with mono-substituted indenyl ligands and their application for the polymerization of propene Pages 304-309 Roland Schmidt, Helmut G. Alt

Preparation of bistrimethylsilylmethylniobiumtetrafluoride and the application of KHF2 and n-Bu4NHF2 as fluorinating reagents Pages 310-316 Mark Schormann, Saji P. Varkey, Herbert W. Roesky, Mathias Noltemeyer

Synthese und Charakterisierung chiraler Organogallium- und -aluminiumalkoholate mit intramolekularer Stickstoffstabilisierung. Röntgenstrukturanalyse von Dimethylgallium-(S)-2-dimethylamino-3-methyl-1-butanolat, Dimethylgallium-(S)-2-dimethylamino-3-phenyl-1-propanolat und Dimethylgallium-(R)-2-dimethylamino-1-butanolat Pages 317-326 Herbert Schumann, Sonja Wernik, Birgit C. Wassermann, Frank Girgsdies

Komplexkatalyse: LVII. Vereinfachte Synthese des Nd(π-C3H5)3·C4H8O2 nach der Grignard-Methode und Darstellung der neuen Allylneodym(III)-Komplexe [Nd(π-C5Me5)(π-C3H5)2·C4H8O2] und [Nd(π-C3H5)Cl(THF)5]B(C6H5)4·THF als Präkatalysatoren für die stereospezifische Butadienpolymerisation Pages 327-336 Rudolf Taube, Steffen Maiwald, Joachim Sieler

Catalytic conversions in water: Part 19. Smooth hydroformylation of N-allylacetamide in mono- and biphasic aqueous media Pages 337-343 Göran Verspui, Guido Elbertse, Georgios Papadogianakis, Roger A. Sheldon

Synthesis of chiral β-aminoalcohol-substituted carbene complexes of manganese and influence of the chiral carbene ligand on the diastereoselectivity of the CO/PR3 exchange Pages 344-351 Kerstin Weißenbach, Helmut Fischer

Diastereoselective oxidative addition of cyclic thiosulfinates to platinum(0) compounds: chiral platinum(II) complexes with sulfenato ligands Crystal structures of and dppePt[S(O)–(CH2)4–S]: Part 16. Metal complexes of functionalized sulfur-containing ligands Pages 352-358 Ralf Wünsch, Gabriele Bosl, Christian Robl, Wolfgang Weigand

Author Index Page 359

Subject Index Pages 361-367

Contents of Volume 621 Pages 369-371