Volume 372
Main Index

Issue 1, Pages 1-182 (8 August 1989)

The Metal Carbonyl Centennial Page vii

The homogeneously catalysed addition reaction of polyhalogenoalkanes to olefins by divalent arylnickel complexes: comparative reactivity and some important mechanistic leads Pages C1-C6 David M. Grove, Augustinus H. M. Verschuuren, Gerard van Koten, Johannes A. M. van Beek

Author index Page C7

Ludwig Mond: Vorsprung durch Technik Pages 1-14 H. L. Roberts

Carbon monoxide: feestock for chemicals, present and future Pages 15-23 W. Keim

Tin–iron carbonyl clusters from the reaction of stannane, SnH4, with Fe2(CO)9; the crystal structure of SnFe5(CO)19 Pages 25-32 Skelten G. Anema, Kenneth M. Mackay, Brian K. Nicholson

Organo-transition-metal chemistry of highly fluorinated ligand systems : IX. Chemical and biological aspects of novel organo-transition-metal hexafluoro-arsenates and -antimonates Pages 33-40 Petra Gowik, Thomas Klapötke

Some group 4 metallocene derived carbene complex chemistry Pages 41-52 Gerhard Erker, Friedrich Sosna, Ursula Hoffmann

Synthetic and mechanistic studies on tripledecker complexes with bridging 1H-borole ligands Pages 53-60 G. E. Herberich, U. Büschges, B. A. Dunne, B. Heßner, N. Klaff, D. P. J. Köffer, K. Peters

EXAFS infrared and kinetic studies on a ruthenium carbonyl hydroformylation system Pages 61-66 John Evans, Gao Jingxing, Harriet Leach, Andrew C. Street

Cluster synthesis by photolysis of R3PAuN3. Crystal structure of [(Ph3PAu)7Mo(CO)3]OH and [(Ph3PAu)6AuCo2(CO)6]NO3 Pages 67-78 George Beuter, Joachim Strähle

New bimetallic hydrocarbon-bridged complexes by nucleophilic attack of carbonylmetallates to coordinated unsaturated hydrocarbons Pages 79-83 Wolfgang Beck, Burkhard Niemer, Josef Bremair, Jürgen Heidrich

Vibrational characteristics of μ-bridging hydride ligands in triangulo rhenium metal cluster compounds Pages 85-97 Christopher E. Anson, Upali A. Jayasooriya, Giuseppe D'Alfonso, Pier Luigi L. Stanghelli

Single electron and H+ coupled double electron transfer reductions of nitrosyl complexes: model reactions for key steps of the NO3− NH3 conversion in the nitrogen cycle Pages 99-107 D. Sellman

Clusters containing fluorocarbons Pages 109-115 Dieter Lentz, Heike Michael

Commercial conversion of carbon monoxide to fuels and chemicals Pages 117-127 Mark E. Dry

Mixed metal clusters: structural and reactivity trends Pages 129-139 Tapani A. Pakkanen, Jouni Pursiainen, Tapani Venäläinen, Tuula T. Pakkanen

Reductive carbonylation of cobalt(II) in the presence of diphenylphosphine: synthesis and structure of (PPN)[Co(CO)3(PPh2OMe)] and MeCOCo(CO)2(PPh2H)(PPh2OMe) Pages 141-150 Sándor Vastag, László Markó, Arnold L. Rheingold

Roles of metal carbonyl complexes in the homogeneous hydrogenation of carbon monoxide Pages 151-161 B. D. Dombek

The electronic structure of large organometallic clusters Pages 163-169 Robert E. Benfield

Electron-rich metal centres (Au, Pt) as sources of organometallic complexes with unusual features Pages 171-182 Rafael Usón

Issue 2, Pages 183-325 (15 August 1989)

Topics in Current Chemistry, Relationships and Mechanisms in the Periodic Table : Volume 150, contributions from D.J. Clouthier, P.L. Corio, N.D. Epiotis, C.K. Jørgensen and D.C. Moule, Springer-Verlag, 1989, 292 pages, ISBN 3-540-50045-6. DM168.00. Pages C19-C20 Penny A. Chaloner

Conversion of arenes to cyclohexa-1,3-dienes via (exo-5-dialkylphosphonoexo-6-R-η4-cyclohexadiene) manganese dicarbonylnitrosyl compounds Pages C12-C14 Taeg-Hwan Hyeon, Yong Keun Chung

Ru3(CO)9(PPh3)3: a convenient starting material for the synthesis of binuclear ruthenium(I) complexes. Crystal structure of Ru2(μ-L2)(CO)4(PPh3)2 (H2L2 = 1,8-diaminonaphthalene) Pages C15-C18 Pedro L. Andreu, Javier A. Cabeza, Victor Riera, Francis Robert and, Yves Jeannin

Fluoride ion-induced hydrosilylation of aldehydes and ketones under phase-transfer conditions Pages C9-C11 Yu. Goldberg, E. Abbele, M. Shymanska, e. Lukevics

Gmelin handbook of inorganic chemistry : 8th edition, F — perflurohalogenoorgano Compounds of Main Group Elements, Supplement Volume 4: Heterocyclic Compounds of Nitrogen, Springer-Verlag, Berlin, etc., 1988, xiii + 348 pages, DM1540. ISBN 3-540-93569-X. Page C21 Kenneth R. Seddon

Gmelin handbook of inorganic chemistry : 8th edition, Sc, Y, La---Lu — Rare Earth Elements, Springer-Verlag, Berlin, etc., Volume A6a, Y, La, and the Lanthanoids. Geochemistry: Sedimentary Cycle. Metamorphic Cycle, xi + 424 pages, DM1903, 1988. ISBN 3-540-93571-1. Volume A6b, Y, La, and the Lanthanoids. Geochemistry: Hydrosphere. Atmosphere. Cosmo- and Geochemical Cycles. Balance, xi + 207 pages, DM 989, 1988. ISBN 3-540-93548-7. Page C20 Kenneth R. Seddon

Author index Page C22

Halogenation of alkynes and alkynylsilanes Pages 183-186 Mohammed I. Al-Hassan

73Ge NMR spectra of 1,3-dioxa-6-aza-2-germacyclooctanes Pages 187-188 E. Kupe, E. Lukevics, O. D. Flid, N. A. Viktorov and, T. K. Gar

73Ge NMR of hexacoordinate organogermanium compounds Pages 189-191 E. Kupe, L. M. Ignatovich, E. Lukevics

Structural chemistry of organotin carboxylates : II. The crystal structure of the dicarboxylato tetraorganodistannoxane:{sunBu2Sn(O2CC5H4N)]2O}2 Pages 193-199 C. S. Parulekar, V. K. Jain, T. K. Das, A. R. Gupta, B. F. Hoskins, E. R. T. Tiekink

First structural characterization of an α-diazophosphane: crystal structure of bis[bis(diisopropylamino)phosphanyl]diazomethane [(i-Pr2N)2P]2CN2 Pages 201-206 M. J. Menu, M. Dartiguenave, Y. Dartiguenave, J. J. Bonnet, G. Bertrand and, A. Baceiredo

Synthesis and characterization of transition metal complexes of (2-(2-methoxyethoxy)ethyl)diphenylphosphine and (2-(2-methoxyethoxy)ethyl)dimethylarsine Pages 207-216 V. Vijay Sen Reddy, J. E. Whitten, K. A. Redmill, A. Varshney, G. M. Gray

Synthesis and reactivity of naphthalene complexes of ytterbium Pages 217-224 M. N. Bochkarev, A. A. Trifonov, E. A. Fedorova, N. S. Emelyanova, T. A. Basalgina, G. S. Kalinina, G. A. Razuvaev

Barriers to rotation about the C(O)---N bond in tricarbonylchromium complexes of aromatic N,N-dialkylamides Pages 225-230 Adam Gryff-Keller, Przemyslaw Szczeciski, Hanna Koziel

Mass spectrometric studies of some bis(η5-pentamethylcyclopentadienyl)metal derivatives, and related complexes Pages 231-249 F. Geoffrey N. Cloke, Jeremy P. Day, Anthony M. Greenway, Kenneth R. Seddon, Amer A. Shimran, Anthony C. Swain

Organotransition-metal complexes of multidentate ligands : IX. Synthesis and structure of hydridotris(benzotriazol-l-yl) borate derivatives of the group VI metal carbonyls Pages 251-261 Kom-Bei Shiu, Fuw-Ming Shen, Sue-Lein Wang and, Shi-Chen Wei

Cationic but-2-yne complexes of tungsten(II). Preparation and spectral properties of [WI(CO)L(dppm)(η2-MeC2Me)][BF4] (L = neutral monodentate oxygen and sulphur donor ligands). Crystal structure of [WI(CO){SC(NH2)2}(dppm)-(η2-MeC2Me)][ClO4] Pages 263-272 Paul K. Baker, Kevin R. Flower, Paul A. Bates and, Michael B. Hursthouse

Competitive addition and substitution reactions in the interaction of CpWOs3(CO)9(μ-O)(μ3-CCH2Tol) with phosphorus donors. The crystal structure of CpWOs3(CO)8(PPh2Me)(μ-O)(μ3-CCH2Tol) Pages 273-285 Yun Chi, John R. Shapley, Melvyn Rowen Churchill and, James C. Fettinger

Preparation of transition metal isoxazole derivatives Pages 287-293 V. N. Kalinin, T. V. Rozantseva, P. V. Petrovskii, A. S. Batsanov, Yu. T. Struchkov

Reaktionen von Propiolaldehyd-derivaten mit dicarbonylbis(trimethylphosphit)eisen-fragmenten Pages 295-309 Christiane Löwe, Hans-Ulrich Hund, Heinz Berke

Reaction of platinum(II) derivatives with bis(pyrazolyl)propane. cleavage of a C(sp3)-N bond in a bis(pyrazolyl)alkane promoted by platinum(II) derivatives. crystal structure of cis-PT(pzH)2Cl2 (pzH = pyrazole) Pages 311-325 Maria Agostina Cinellu, Sergio Stoccoro, Giovanni Minghetti, Anna Laura Bandini and, Guido Banditelli, Bruna Bovio

Issue 3, Pages 327-471 (22 August 1989)

Synthese von Cp(CO)2 MnTCNE aus [Cp(CO)2MnXPh]n (X = S, Se, Te; n = 1,2); Festkörperstruktur und Magnetismus Pages C23-C28 Horst Braunwarth, Gottfried Huttner, Laszlo Zsolnai

Structure and Reactivity : edited by J.F. Liebman and A. Greenberg. VCH Verlagsgesellschaft Weinheim, Basel, Cambridge, New York 1988, 385 pages DM 195.-.£66.-. ISBN 0-89573-712-4 (New York), ISBN 3-527-26958-4 (Europe) Page C33 J. N. Murrell

Subject index Pages C36-C42

Photoredox reaction of cobalticinium pentacarbonylmanganate(−I) induced by outer-sphere metal to metal charge transfer excitation Pages C29-C32 Horst Kunkely, Arnd Vogler

Author index Pages C34-C35

119Sn, 15N, 13C and 1H NMR study of some tri- and di-organotin(IV) 8-quinolinethiolates Pages 327-338 Antonín Lyka, Josef Jirman, Jaroslav Holeek, Ivan Tká

Reaction of mesitylenetetracobaltnonacarbonyl with [Mo(CO)3C5H5]2. Syntheses and structures of the clusters C5H5(CO)2MoCo3(CO)6(μ-CO)3 and (C5H5)2(CO)3Mo2Co2(CO)4(μ-CO)3 Pages 339-349 V. S. Kaganovich, Yu. L. Slovokhotov, A. V. Mironov, Yu. T. Struchkov, M. I. Rybinskaya

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmettalen : LXIV. Methyl(trioxo)rhenium: Basenaddukte und Basenreaktionen. Kristallstruktur von [Natrium(benzo-15-krone-5)]-perrhenat Pages 351-370 Wolfgang A. Herrmann, Josef G. Kuchler, Georg Weischselbaumer, Eberhardt Herdtweck, Paul Kiprof

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : LXVII. Zur kenntnis der “metallsäure” methyl(trioxo)rhenium(VII): adduktbildung mit amin-basen und aromaten. die struktur des anilin-komplexes CH3ReO3·H2NC6H5 Pages 371-389 Wolfgang A. Herrmann, Georg Weichselbaumer, Eberhardt Herdtweck

CpFe(CO)2(η1-CH2SCH3): comportement photochimique et utilisation pour l'accès a des structures bimetalliques CpFe(CO)2[η1-CH2S(CH3)MLn] avec M = Cr, Mo, W, Mn Pages 391-396 A. Leboeuf, J. C. Leblanc, C. Moïse

η2-Coordination in pentacoordinate iron complexes Pages 397-410 Reiner Birk, Heinz Berke, Hans-Ulrich Hund, Gottfried Huttner and, Laszlo Zsolnai, Lutz Dahlenburg, Ulrich Behrens and, Thomas Sielisch

Synthesis, crystal and molecular structure of η3-allylundecacarbonylosmium tetrafluoroborate Pages 411-416 T. Asunta, K. Rissanen, V. V. Krivykh and, M. I. Rybinskaya

Reaction of Ph2PH with the tetracobalt cluster Co4(CO)10(μ4-PPh)2. Kinetic studies of sequential CO replacement and X-ray crystal structure of Co4(CO)8(μ4-PPh)2(Ph2PH)2 Pages 417-435 Ming-Jaw Don, Michael G. Richmond, William H. Watson and, Ante Nagl

The reaction of elemental sulfur with Rh(η5-C5H4Z)(PPh3)(2 (Z = H, CO2Me). Formation of RhS4, RhS5, RhS6, and (RhS2)2 catenated metallacycle complexes Pages 437-445 Yasuo Wakatsuki, Hiroshi Yamazaki, Cuobao Cheng

A new reaction of transition metal complexes with methyl formate Pages 447-451 Wilhelm Keim, Johannes Becker, Anna M. Trzexiak

Factors influencing linkage isomer preference in palladium(II)-chlorinilate complexes Pages 453-463 Woo-Yeong Jeong, Robert A. Holwerda

Synthesis and crystal structure of bis(triphenylphosphine)gold tricyanomethanide, [(PPh3)2Au]+ [C(CN)3]− Pages 465-471 T. V. Baukova, D. N. Kravtsov, L. G. Kuz'mina, N. V. Dvortsova and, M. A. Poray-Koshits, E. G. Perevalova