Volume 423
Main Index

Issue 1, Pages 1-161 (14 January 1992)

μ-[3-4-η-(1-Alken-3-yne)hexacarbonyldicobalt complexes: Radical cyclocondensation mediated by manganese(III) acetate Pages C24-C27 Gagik G. Melikyan, Otto Vostrowsky, Walter Bauerand, Hans Jürgen Bestmann

Synthesis, reactivity and crystal structure of trimesitylgermylamine, Mes3GeNH2 Pages C5-C8 Monique Rivière-Baudet, Alain Morère, James F. Britten and, Mario Onyszchuk

Die molekül- und kristallstruktur von (CH3)2 InNC4H4 Pages C1-C4 H. -D. Hausen, K. Locke, J. Weidlein*

Übergangsmetall-Heteroallen-Komplexe : XXIV. Synthese und Struktur von Dicarbonyl(cyclopentadienyl)(η2(C,C)-Ketenimin)mangan Pages C16-C19 Wolfram Ziegler, Ulrich Behrens

Scalar 13C---19 F spin-spin couplings between carbonyl carbons and aromatic fluorines in tricarbonylchromium complexes of biphenyl derivatives Pages C13-C15 Przemysaw Szczeciski, Krzysztof Winiewski

Author index Page C28

Styryl coupling vs. styryl acetate formation in reactions of styryl tellurides with palladium(II) salts Pages C9-C12 Sakae Uemura, Hidetaka Takahashi, Kouichi Ohe

Reaktionen von [CpRuOMe]2 : XI. Austausch mit Thiolen und Molekülstruktur von [C5Me4EtRuSEt]2 Pages C20-C23 U. Koelle, Chr. Rietmann, U. Englert

The reaction of trimethylaluminium with 1,2-dihydroxymethylbenzene Pages 1-4 S. Pasynkiewicz, W. Ziemkowska

The crystal structure of (Me3Si)3CSi(OH)2(OCOCF3). Novel hydrogen bonding Pages 5-12 Salih S. Al-Juaid, Colin Eaborn, Peter B. Hitchcock

Zur chemie der silylene: Cycloadditionen von methoxymethylsilylen mit heterodienen Pages 13-21 Joachim Heinicke, Barbara Gehrhus

Application of scalar 13C---19F spin—spin couplings between carbonyl carbons and aromatic fluorine to investigation of conformation of tricarbonylchromium complexes of fluorobenzenes Pages 23-29 Przemysaw Szczeciski

Half-sandwich complex with intramolecular amino group coordination: Synthesis of molybdenum iodide complexes Pages 31-38 Tein-Fu Wang, Tsung-Yi Lee, Jim-Wen Chou and, Chi-Wi Ong

Preparation and properties of molybdenum and tungsten dinitrogen complexes : XXXIV. Nucleophilic addition reactions of hydrazido(2 −) complexes with diphenylketene: Characterization of new acylhydrazido(2 −) complexes of molybdenum and tungsten Pages 39-50 Takayuki Aoshima, Yasushi Mizobe, Masanobu Hidai, Junichi Tsuchiya

Site selectivity studies on homonuclear metal dimer complexes: Substitution reactions of Re2(CO)9L Pages 51-64 Wayne L. Ingham, Neil J. Coville

Substitution reactions of dinuclear alkenyl-bridged iron-cobalt complexes with phosphines. Crystal structures of [(CO)3 Fe----Co(CO)2(PMe2Ph)] (μ-C(CO2Me)=C(CO2Me)H) and [(CO)2(PMe2Ph)Fe---Co(CO)2(PMe2Ph)]-(μ-C(CO)2Me)=C(CO2Me)H) Pages 65-82 Isabel Moldes, Josep Ros, René Mathieu, Xavier Solans and, Mercè Font-Bardía

Cluster chemistry : LXXV. Tetra-, penta- and hepta-nuclear clusters derived from {Ru4(μ-H)4(CO)11}2(μ-dppa) [dppa = C2(PPh2)2]: X-ray structures of Ru4(μ-H)[μ3-HC2PPh2{Ru4(μ-H)4 (CO)11}](μ-PPh2)(μ-CO)(CO)9 and Ru7(μ-H)3(μ5-HC2PPh2)(μ-PPh2)(CO)16 Pages 83-96 Chris J. Adams, Michael I. Bruce, Brian W. Skelton and, Allan H. White

Cluster chemistry : LXXVI. A new C2 complex from reactions of Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 with pyridine. X-Ray structure of Ru5(μ5-C2)(μ-PPh2)2(CO)11(py)2 Pages 97-104 Chris J. Adams, Michael I. Bruce, Brian W. Skelton and, Allan H. White

Cluster chemistry : LXXVII. Carbide clusters from Ru5(μ5-C2PPh2)-(μ-PPh2)(CO)13 and Fe2(CO)9: X-ray structures of MRu4(μ5-C)(μ-dppm)(CO)13 · 0.5CH2Cl2 (M = Fe and Ru) and FeRu5(μ-6-C)(μ-PPh2)2(CO)13(PMe2Ph) Pages 105-118 Chris J. Adams, Michael I. Bruce, Brian W. Skelton and, Allan H. White

Cluster chemistry : LXXVIII. Coupling of allene dimer and acetylide on an Ru5 cluster. X-Ray structure of Ru5(μ5-PPh2C2C6H8)(μ-PPh2)(CO)10{P(OMe)3} Pages 119-127 Chris J. Adams, Michael I. Bruce, Brian W. Skelton and, Allan H. White

Formation of metallacycles from terminal diynes with geminal methyl groups α to the triple bonds. Synthesis and crystal structure of Co2(CO)5[(HCCCMe2)2NMe], an intermediate in cobalt-catalyzed organic syntheses Pages 129-139 Giovanni Predieri, Antonio Tiripicchio, Marisa Tiripicchio Camellini, Mirco Costa, Enrico Sappa

Reactions of dithiolenes with diazo compounds: cycloaddition and dissociation of alkylidene groups Pages 141-161 Masami Sakurada, Masatsugu Kajitani, Kakushi Dohki, Takeo Akiyama, Akira Sugimori

Issue 2, Pages 163-305 (21 January 1992)

Author index Page C33

Advances in silicon chemistry : Vol. 1, G.L. Larson (Ed.), JAI Press, Greenwich (CT), 1991, xii + 387 pages, £54.00. ISBN 1-55938-176-0. Pages C30-C31 Colin Eaborn

Inorganic syntheses : Vol. 27, editor-in chief Alvin P. Ginsberg, John Wiley and Sons, New York, $47.50. ISBN 0-471-50976-0. Pages C29-C30 Alice C. Sullivan

Heteroatom chemistry : E. Block (Ed.), VCH, Weinheim, 1990, xi + 376 pages. DM178.00. ISBN 0-89573-743-4. Pages C31-C32 Colin Eaborn

Synthesis of bis(pentachlorophenyl) silanediol and related compounds. Crystal structure of diethoxybis(pentachlorophenyl) silane Pages 163-171 José Carilla, Lluís Fajarí, Luis Juliá, Juan Riera, Joaquin Lloveras, Nuria Verdaguer and, Ignacio Fita

Pyrrolyl compounds of main group elements. Synthesis of group 14 5-metallated pyrrole-2-carbaldehydes Pages 173-182 Franck Denat, Hafida Gaspard-Iloughmane, Jacques Dubac

Preparation and 119mSn Mössbauer spectral studies of diorganotin(IV) derivatives of isonicotinic acid and isonicotinic acid N-oxide Pages 183-193 G. K. Sandhu, N. S. Boparoy

TiIV and Mov complexes with diesters. The crystal structure of [o-C6H4(CO2CH2CH2Ph)2Cl4Ti], [C2O4(CH2CH2Ph)2Cl4Ti] and [o-C6H4(CO2Et)2Cl3MoO] · C6H6 Pages 195-210 Piotr Sobota, Sawomir Szafert, Józef Utko, Tadeusz Lis

Molekulares Design von übergangsmetallkomplexverbindungen zur aktivierung kleiner moleküle : II. Zur Carbonylierung von Bis(π-pentamethylcyclopentadienyl)metall-1,3-Dien-Komplexen Cp2M(1,3-Dien) (M = Zr, Hf)---Bildung einkerniger Metall-Endiolate Pages 211-222 Rüdiger Beckhaus, Dagmar Wilbrandt, Sabine Flatau, Wolf-Henning Böhmer

Electrochemical generation of 17-electron cation radicals from arene---M(CO)3 (M = Cr, Mo, W) and thiophene---Cr(CO)3 complexes in MeCN: Conventional cyclic voltammetric studies with digital simulation and microelectrode voltammetry in the absence of supporting electrolyte Pages 223-239 Frank Rourke, Rosslyn Gash, Joe A. Crayston

Ru3(CO)9BH5 and [Ru3(CO)9BH4]− as precursors to higher nuclearity homo- and heterometallic clusters: molecular structure of a second isomer of HRu6(CO)17B Pages 241-254 Sylvia M. Draper, Catherine E. Housecroft, Ann K. Keep, Dorn M. Matthews, Xuejing Song, Arnold L. Rheingold*

Electrochemical behaviour of the electronically and coordinatively unsaturated cluster [Os3(γ-H)(CO)8{Ph2PCH2P(Ph)C6H4})] Pages 255-261 Domenico Osella, Mauro Ravera, Anthony K. Smith and, A. Jane Mathews, Piero Zanello

A simple synthesis and crystal structure of the dinuclear diphosphido-bridged palladium(I) complex [Pd(PtBu2H)(μ-PtBu2)]2 Pages 263-270 Piero Leoni, Milena Sommovigo, Marco Pasquali, Piera Sabatino and, Dario Braga

Influence of β-arranged substituents in chiral seven-membered rhodium diphosphine rings on asymmetric hydrogenation of amino acid precursors Pages 271-279 Hanswalter Krause, Cornelia Sailer

Conjugate addition of organocuprates to γ-methyl-δ-oxy-α,β-enones. Influence of the alkoxy substituent on the diastereoselection Pages 281-305 Gilles Courtemanche, Alexandre Alexakis, Jacqueline Vaissermann, Jean-F. Normant

Issue 3, Pages 307-430 (28 January 1992)

Photochemistry of (Me3P)4Mo(η-CO2)2: Deoxygenation of coordinated carbon dioxide and phosphine oxidation Pages C35-C37 Wolfram Ziegler, Kenneth M. Nicholas

Author index Pages C49-C50

Octahedral bis(acetylide) and bis(diacetylide) complexes of ruthenium(II) with linear C2MC2 and C4MC4 chains: The first X-ray structures of the all trans bis(acetylides) Ru(CO)2(CCPh)2(PEt3)2 and Ru(CO)2(CCH)2(PEt3)2 Pages C43-C47 Yan Sun, Nicholas J. Taylor, Arthur J. Carty

Molecular electrochemistry of inorganic, bioinorganic, and organometallic compounds Page C48

Complexes with functional phosphines : XVII. Synthesis and characterization of ruthenium clusters with ketophosphine ligands. Crystal structure of the cluster [Ru3(μ-H){μ-η1(O):η (P,O)-O( CPh) CHPPh2} (CO)9] containing a bridging phosphinoenolate ligand Pages C38-C42 Pierre Braunstein, Silverio Coco Cea, Michael I. Bruce, Brian W. Skelton and, Allan H. White

Subject index Pages C51-C55

Organometallics of groups 4 and 5: Oxidation states II and lower Pages 307-328 Fausto Calderazzo, Guido Pampaloni

Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen : XLV. Reaktionen von Tetra-t-butyldisilen mit CN-Mehrfachbindungen: Cycloadditionen und Umlagerungen Pages 329-337 Manfred Weidenbruch, Axel Lesch, Karl Peters and, Hans Georg von Schnering

Darstellung und struktur von (EtO)2P(O)CH2Si(Me)2CH2SnMe2Cl—ein sechsringchelat mit sesselkonformation und P=O Sn(Cl)Me2CH2-trigonaler bipyramide am Lewis-aciden Zinn Pages 339-350 Ute Kolb, Martin Dräger, Elke Fischer and, Klaus Jurkschat

Novel class of transition metal coordination compounds with macrocyclic organosiloxanolate ligands; their synthesis and crystal structure Pages 351-360 V. A. Igonin, O. I. Shchegolikhina, S. V. Lindeman, M. M. Levitsky, Yu. T. Struchkov, A. A. Zhdanov

Organostannyl mediated synthesis of 1-alkyl and 1-sulfonyl-2-trifluoromethylbenzimidazole derivatives Pages 361-366 N. Narayanan, T. R. Balasubramanian

Synthesis and reactivity of molybdenocene isocyanide complexes; crystal structure of (η5-C5H5)2MoCNtBu Pages 367-390 Ana M. Martins, Maria J. Calhorda, Carlos C. Romão, Christian Völkl, Paul Kiprof and, Alexander Constantin Filippou

Rapid [SR]+ exchange between metal-thiolate and metal-organic disulphide complexes Pages 391-398 P. M. Treichel, E. K. Rublein

Dodecacarbonyl triiron, an efficient catalyst for photochemical isomerization of unsaturated alcohols, ethers and ester to their corresponding carbonyl compounds, enol ethers and esters Pages 399-404 Nasser Iranpoor, Enayatolah Mottaghinejad

Ruthenium complex-catalyzed coupling of vinyl halides with olefins Pages 405-414 Take-aki Mitsudo, Masakazu Takagi, Shi-Wei Zhang, Yoshihisa Watanabe

Chemistry of PdII complexes containing both BINAP (2′2′-bis(diphenylphosphino)binaphthyl) and a η3-pinene or -allyl ligand. NMR studies on [Pd(η3-C10H15){S(−)BINAP}] (CF3SO3). The crystal structure of [Pd(η3-C10H15)(4,4′-dimethylbipyridine)](CF3SO3) Pages 415-430 Christian J. Ammann, Paul S. Pregosin, Heinz Rüegger, Alberto Albinati and, Francesca Lianza, Roland W. Kunz