Volume 582
Main Index

Issue 1, Pages 1-142 (10 June 1999)

Preface Pages 1-2

Reactivity studies of η2-acyl complexes of molybdenum: reactions with strong bases and with bidentate phosphines Pages 3-8 Leopoldo Contreras, Antonio Pizzano, Luis Sánchez, Ernesto Carmona

Butenedithiolate triosmium cluster complexes from the reaction of Os3(CO)10(NCMe)2 with 3,6-dihydro-1,2-dithiin Pages 9-15 Richard D. Adams, Joseph L. Perrin

Synthesis and structural features of new sterically hindered azaphosphatrane systems: ZP(RNCH2CH2)3N Pages 16-24 X. Liu, Y. Bai, J. G. Verkade

Coordination chemistry of aminoborylphosphanes. Crystal structure determinations of (iPr2N)2BP(H)SiPh3·Cr(CO)5 and [(iPr2N)2BP(H)]2SiMe2·W(CO)4 Pages 25-31 Tuqiang Chen, Jeffery Jackson, Stephen A. Jasper, E. N. Duesler, H. Nöth, Robert T. Paine

Synthesis of an organogallium(I) compound [Ga(CH2CMe2Ph)]n with EPR spectral evidence for gallium clusters Pages 32-39 O. T. BeachleyJr., Matthew J. Noble, Robert D. Allendoerfer

Preparation of mercury–anthracene derivatives: π–π-stacking, HgCl and Hgπ interactions in the X-ray crystal structure of polymeric 9-chloromercurioanthracene Pages 40-44 Martin Tschinkl, Robert E. Bachman, François P. Gabbaï

Preparation of single-source precursors to nanocrystalline gallium arsenide and gallium antimonide. X-ray crystal structures of [Et2GaAs(SiMe3)2]2, [Et2GaSb(SiMe3)2]2 and Et2b(SiMe3)2 Pages 45-52 Edward E. Foos, Richard J. Jouet, Richard L. Wells, Arnold L. Rheingold, Louise M. Liable-Sands

From a terminal (cis-2-butene-1,4-diyl-1,4-diphosphinidene) complex to some new diphosphorus bicycles Pages 53-57 Ngoc Hoa Tran Huy, Louis Ricard, François Mathey

Cyclopentadienyl, indenyl, fluorenyl, and pentamethylcyclopentadienyl complexes of potassium with 18-crown-6 Pages 58-65 Swen Neander, Fifi E. Tio, Ralph Buschmann, Ulrich Behrens, Falk Olbrich

The first beryllium diorganoarsenide: synthesis and structure of (η5-C5Me5)BeAs(t-Bu)2 Pages 66-69 Scott L. Battle, Alan H. Cowley, Andreas Decken, Richard A. Jones, Stefan U. Koschmieder

Organometallic compounds of the lanthanides: Part CIXXX. Synthesis, structure and hydrolysis of ‘moderately stable’ hydrosilylation catalysts [(η5-C5H4SiMe3)2Ln(μ-Me)]2 and [(η5-C5H4SiMe2 tBu)2Ln(μ-Me)]2 Pages 70-82 Herbert Schumann, Markus R. Keitsch, Jörg Demtschuk, Gary A. Molander

Preparation and organometallic complexes of the new unsymmetrical ligand: Ph2PNHC6H4PPh2 Pages 83-89 Stephen M. Aucott, Alexandra M. Z. Slawin, J. Derek Woollins

Some di- and tri-metal complexes derived from the synthon [Ru(CO)2(THF)(η5-7,8-C2B9H11)] Pages 90-99 John C. Jeffery, Paul A. Jelliss, Gillian E. A. Rudd, Sumika Sakanishi, F. Gordon A. Stone, Jennifer Whitehead

Synthesis and structural characterization of (THF)3Na{(SnC6H3–2,6-Trip2)2} (Trip=C6H2-2,4,6-i-Pr3): effects of cation–anion association on Sn–Sn multiple bonding Pages 100-102 Lihung Pu, Scott T. Haubrich, Philip P. Power

Examination of dibenzyl aluminum and gallium azides as potential precursors to AlN and GaN Pages 103-107 Miguel-Ángel Muñoz-Hernández, Drew Rutherford, Heli Tiainen, David A. Atwood

Reactions of trialkylgalliums with substituted hydrazines leading to the formation of rings and cages: X-ray structures of (iPr2GaNHNMe2)2 and (MeGaNHNtBu)4 Pages 108-115 David W. Peters, Edith D. Bourret, Maurice P. Power, John Arnold

Synthesis and X-ray structure of a [4]ferrocenophane containing a boron–boron bond Pages 116-118 M. J. Gerry Lesley, Ulricke Mock, Nicholas C. Norman, A. Guy Orpen, Craig R. Rice, Jonathan Starbuck

Compounds containing gallium–silicon bonding: syntheses and X-ray crystal structures of bis-[2(dimethylaminomethyl)phenyl]-[tris(trimethylsilyl)silyl]gallium, Aryl2GaSi(SiMe3)3 and diphenyl-[tris(trimethylsilyl)silyl]gallium, Ph2GaSi(SiMe3)3 · THF Pages 119-125 Nigel L. Pickett, Oliver Just, Xiaohua Li, Donald G. Vanderveer, William S. ReesJr.

Titanium σ-acetylides as building blocks for heterobimetallic transition metal complexes: synthesis and redox behaviour of π-conjugated organometallic systems Pages 126-138 Stephan Back, Robert A. Gossage, Gerd Rheinwald, Ignacio del Río, Heinrich Lang, Gerard van Koten

Hydrosilylation of an hexa-olefin star with organometallic hydrogenosilanes: ferrocenylsilylation and desilylenation Pages 139-141 Jaime Ruiz, Ester Alonso, Jean-Claude Blais, Didier Astruc

Index Page 142

Issue 2, Pages 143-391 (20 June 1999)

Organolanthanide chemistry with bis(trimethylsilyl)methyl- and tert-butyldimethylsilyl-substituted cyclopentadienyl ligands.: Synthesis and characterisation of tris(cyclopentadienyl)lanthanide(III) complexes, including crystal structures of [Ln{η5-C5H4CH(SiMe3)2}3] (Ln=Nd or Tm) and [Ce{η5-C5H3(SiMe2But)2-1,3}3] Pages 143-152 Salih Al-Juaid, Yurii K. Gun’ko, Peter B. Hitchcock, Michael F. Lappert, Shun Tian

Electronic coupling of two [Cp*ClM]+/[Cp*M] reaction centers via π conjugated bridging ligands: similarities and differences between rhodium and iridium analogues Pages 153-159 Wolfgang Kaim, Sascha Berger, Stefan Greulich, Ralf Reinhardt, Jan Fiedler

A facile and selective synthesis of hydridotrirhenium cluster under solvothermal conditions Pages 160-162 Ranganathan Sevvel, Tien-Wen Tseng, Kuang-Lieh Lu

Intermediates and anion effects in the activation of carbon–fluorine bonds by η5-pentamethylcyclopentadienylrhodium halide complexes; crystal structure of [{η5-C5Me3[CH2C6F4P(C6F5)CH2]2-1,3}RhBr]+·Br− Pages 163-172 Malcolm J. Atherton, John Fawcett, John H. Holloway, Eric G. Hope, David R. Russell, Graham C. Saunders

Ferrocenylpyrazolyl bridging rhodium dimers. Crystal structure of [Rh(μ-pzFc)(COD)]2 Pages 173-182 José A. Campo, Mercedes Cano, José V. Heras, Elena Pinilla, Marta Ruiz-Bermejo, Rosario Torres

Monitoring ECE transformations of metal carbonyls by in situ spectroelectrochemistry; SNIFTIRS of [Co3(CO)9C]2 Pages 183-187 Paula A. Brooksby, Noel W. Duffy, A. James McQuillan, Brian H. Robinson, Jim Simpson

Synthese, Struktur und Reaktivität zweikerniger Pentamethyl-Cyclopentadien-Nickelkomplexe mit verbrückenden Butadienliganden Pages 188-194 Jörg J. Schneider, Uwe Denninger, Richard Goddard, Carl Krüger, Christian W. Lehmann

Synthesis and characterization of triphenyl-, tri-n-butyl and di-n-butyltin derivatives of 4-carboxybenzo-18-crown-6 and -15-crown-5 Pages 195-203 Martine Kemmer, Laurent Ghys, Marcel Gielen, Monique Biesemans, Edward R. T. Tiekink, Rudolph Willem

Water-soluble metal complexes and catalysts: X. BIPHLOPHOS, a novel axially chiral diphosphine ligand: preparation and application in the asymmetric rhodium-catalyzed hydroformylation of styrene Pages 204-210 Florian A. Rampf, Michael Spiegler, Wolfgang A. Herrmann

Synthesis of asymmetric β-hydroxy-cyclopentadienyl ligands and of their bidentate lanthanide complexes Pages 211-217 Alexander Trifonov, Fabiola Ferri, Jacqueline Collin

The role of functionalized phosphines in the hydrogenation of carboxylic acids in the presence of phosphine substituted hydrido ruthenium complexes Pages 218-228 Antonella Salvini, Piero Frediani, Mario Bianchi, Franco Piacenti, Leonardo Pistolesi, Luca Rosi

Reactions of haloarenes, haloheteroarenes and dihalobenzenes with triphenylstannyl anions in DMSO and acetonitrile Pages 229-234 María T. Lockhart, Alicia B. Chopa, Roberto A. Rossi

Comparative chemistry of η3-oxaallyl and η3-allyl rhodium(I) complexes in the hydrosilylation of cyclopropyl ketones: observation of an unprecedented rearrangement Pages 235-245 Carrie Sun, Ambrose Tu, Greg A. Slough

Cyclopalladation of phenols in the form of mixed phosphite esters Pages 246-251 Viatcheslav I. Sokolov, Ludmila A. Bulygina, Oleg Ya. Borbulevych, Oleg. V Shishkin

Synthesis and characterization of novel organometallic compounds containing linked clusters. The molecular structure of (CO)8LCo2M(μ3-C)C(O)OCH2(μ-CCH)Co2(CO)6 [M=Co, W; L=CO, η5-C5H5] Pages 252-258 Jie Zhang, Xue-Nian Chen, Yuan-Qi Yin, Wen-Ling Wang, Xiao-Ying Huang

Synthesis and characterisation of linear triphos {PhP(CH2CH2PPh2)2} bridged tri-, tetra- and pentametallic molybdenum(II) (π-allyl)/tungsten(II) (alkyne) complexes Pages 259-266 Paul K. Baker, Margaret M. Meehan

Geometry and electronic structure of bis(tetrahydridoborato)bis(cyclopentadienyl)zirconium(IV) Pages 267-272 Bálint Sztáray, Edina Rosta, Zsolt Böcskey, László Szepes

Immobilization of zirconium amide on a Cp-modified silica surface and its use as a catalyst for ethylene polymerization Pages 273-278 Sari Timonen, Tuula T. Pakkanen, Eero I. Iiskola

Homolytic displacements at two reactive centers: organodicobaloximes and organodisulfonyl chloride Pages 279-281 B. D. Gupta, Veena Singh, K. Qanungo, V. Vijai Kanth, Raghvendra S. Sengar

A simple route to essential tricarbollides. A high-yield synthesis of 7-amine-nido-7,8,9-tricarbaundecaboranes(10), 7-L-nido-7,8,9-C3B8H10 (where L=H3N, Me2NH, Me3N, and ButH2N) Pages 282-285 Bohumil tíbr, Josef Holub, Jaromír Pleek, Tomá Jelínek, Bohumír Grüner, Francesc Teixidor, Clara Viñas

Organometallic Rh(III) complexes with the bifunctional ligand [2-(dimethylamino)ethyl]cyclopentadiene. Crystal structure of the [{η5:η1-C5H4(CH2)2NMe2}RhIIICl2] complex Pages 286-291 Athanassios I. Philippopoulos, Bruno Donnadieu, René Poilblanc, Nick Hadjiliadis

Synthesis and X-ray structures of trivalent lanthanide (+)-neomenthylcyclopentadienyl complexes Pages 292-300 Wing-Por Leung, Fu-Quan Song, Feng Xue, Ze-Ying Zhang, Thomas C. W. Mak

The first early transition metal perfluorovinyl complexes: the synthesis of Cp2M(CF=CF2)nX2−n (Cp: η5-C5H5−; M=Ti, Zr; X=Cl or F) and structures of Cp2Ti(CF=CF2)nX2−n (X=Cl, F) via Ti K-edge EXAFS studies Pages 301-309 Kulbinder K. Banger, Alan K. Brisdon

Mixed-metal cluster chemistry: Part 14: reaction of [Cp2W2Ir2(CO)10] with trimethylphosphite; X-ray crystal structures of [Cp2W2Ir2(μ-CO)3(CO)5{P(OMe)3}2] and two modifications of [CpWIr3(μ-CO)3(CO)7{P(OMe)3}] Pages 310-318 Susan M. Waterman, Mark G. Humphrey, David C. R. Hockless

Synthesis, characterization and X-ray structural, electrochemical and Mössbauer study of mercury(II) complexes with 1′-(diphenylphosphino)ferrocenecarboxylic acid Pages 319-327 Petr tpnika, Ivana Císaová, Jaroslav Podlaha, Jií Ludvík, Martin Nejezchleba

Synthese und Polymerisationseigenschaften substituierter ansa-Bis(fluorenyliden)komplexe des Zirconiums Pages 328-337 Peter Schertl, Helmut G. Alt

Tribenzylidenemethane complexes of ruthenium. Synthesis and effects of the diastereoisomerism on the crystal packing Pages 338-344 Gerhard E. Herberich, Thomas P. Spaniola

Meta and para metallation of EPh4+ (E=P, As) and N(PPh3)2+ by the dinuclear acylanion [Re2(μ-H)(μ-PCy2)(CO)7ax-(C(Ph)O)]−. Formation of zwitterionic cluster complexes Re2(μ-H)(μ-PCy2)(CO)7(x-C6H4EPh3) (E=P, As; x=m, p) and Re2(μ-H)(μ-PCy2)(CO)7(x-C6H4PPh2NPPh3) Pages 345-351 Hans Egold, Markus Schraa, Ulrich Flörke

1-Dialkylamino-1-phospha-[1]ferrocenophanes—synthesis and characterisation Pages 352-357 Max Herberhold, Frank Hertel, Wolfgang Milius, Bernd Wrackmeyer

Synthesis of 1,3-dioxolanes by the addition of ketones to epoxides by using [Cp*Ir(NCMe)3]2+ as catalyst Pages 358-361 Richard D. Adams, Thomas S. Barnard, Kellie Brosius

N-heterocyclic carbenes: novel ruthenium–alkylidene complexes Pages 362-365 Thomas Weskamp, Florian J. Kohl, Wolfgang A. Herrmann

Erratum to “Reaction of aminocarbene complexes of chromium and tungsten 6. Rearrangements of and insertions of alkynes into aziridinylcarbene complexes”: [Journal of Organometallic Chemistry 494 (1995) 43–51] Page 366 Bernard Denise, Andrée Parlier, Henri Rudler, Jacqueline Vaissermann

Erratum to “Reaction of aminocarbene complexes of chromium with alkynes. IV. New transformations of the nitrogen ylide complexes derived therefrom”: [Journal of Organometallic Chemistry 496 (1995) 127–135] Page 367 Cecile Bouancheau, Michele Rudler, Evelyne Chelain, Henri Rudler, Jacqueline Vaissermann, Jean-Claude Daran

Erratum to “Reactions of TiCl4 with phosphines and alkylating reagents: an organometallic route to a titanium(II) cluster compound”, : [Journal of Organometallic Chemistry 573 (1999) 78–86] Page 368 F. Albert Cotton, Carlos A. Murillo, Marina A. Petrukhina

Erratum to “On the formation of (CH3)4Re2O4 from methyl trioxorhenium complex CH3ReO3 under non-alkylating conditions”: [Journal of Organometallic Chemistry 548 (1997) 295–299] Page 369 Henri Rudler, Jose Ribeiro Gregorio, Bernard Denise, Jacqueline Vaissermann

Erratum to “Synthesis of nickel phenyl complexes with new chelating κ2-P,N ligands derived from α-iminoazatriphenylphosphoranes”: [Journal of Organometallic Chemistry 529 (1997) 387–393] Page 370 Pierre Braunstein, Jörg Pietsch, Yves Chauvin, André DeCian, Jean Fischer

Synthesis of nickel phenyl complexes with new chelating κ2-P,N ligands derived from α-iminoazatriphenylphosphoranes Pages 371-377 Pierre Braunstein, Jörg Pietsch, Yves Chauvin, André DeCian, Jean Fischer

Index Pages 383-384

Index Pages 385-391