Volume 49
Main Index

Issue 01

An Undecanuclear FeIII Single-Molecule Magnet Ayuk M. Ako, Valeriu Mereacre, Yanhua Lan, Wolfgang Wernsdorfer, Rodolphe Clrac, Christopher E. Anson and Annie K. Powell pp 1–3 DOI: 10.1021/ic901747w Supporting Info

Cobalt-Mediated B−H Activation and Cyclopentadienyl-Participated Diels−Alder Addition in the Reaction of a 16e CpCo Complex Containing an o-Carborane-1,2-dithiolato Ligand with HC≡C−C(O)Ph Yuguang Li, Qibai Jiang, Yizhi Li, Hong Yan and Vladimir I. Bregadze pp 4–6 DOI: 10.1021/ic901970b Supporting Info

Peroxo-Zr/Hf-Containing Undecatungstosilicates and -Germanates Sib Sankar Mal, Nadeen H. Nsouli, Mauro Carraro, Andrea Sartorel, Gianfranco Scorrano, Holger Oelrich, Lorenz Walder, Marcella Bonchio and Ulrich Kortz pp 7–9 DOI: 10.1021/ic902203p Supporting Info

Solid-State Photochemical Behavior of a Triple-Stranded Ladder Coordination Polymer Abdul Malik Puthan Peedikakkal and Jagadese J. Vittal pp 10–12 DOI: 10.1021/ic902158w Supporting Info

Exploratory Synthesis: The Fascinating and Diverse Chemistry of Polar Intermetallic Phases† This article is based on J. D. Corbett’s address upon receipt of the 2008 American Chemical Society’s F. Albert Cotton Award in Synthetic Inorganic Chemistry sponsored by the F. Albert Cotton Endowment Fund. John D. Corbett pp 13–28 DOI: 10.1021/ic901305g

Dynamics and Equilibrium of Heme Axial Ligation in Mesoporous Nanocrystalline TiO2 Thin Films Amanda J. Morris, Jonathan R. Stromberg and Gerald J. Meyer pp 29–37 DOI: 10.1021/ic9008015 Supporting Info

Theoretical Insights into the Mechanism of Selective Peptide Bond Hydrolysis Catalyzed by [Pd(H2O)4]2+ Amit Kumar, Xiaoxia Zhu, Kathryn Walsh and Rajeev Prabhakar pp 38–46 DOI: 10.1021/ic901071v Supporting Info

Synthesis of Novel Structured TiO2 with Mesopores by Anodic Oxidation Atsushi Nakahira, Koichi Konishi, Koji Yokota, Takashi Kubo, Yukichi Sasaki and Yuichiro Ikuhara pp 47–51 DOI: 10.1021/ic9010136

Unexpected Synthesis of an Unsymmetrical μ-Oxido Divanadium(V) Compound through a Reductive Cleavage of a N−O Bond and Cleavage-Hydrolysis of a C−N Bond of an N,N-Disubstituted Bis-(hydroxylamino) Ligand Vladimiros A. Nikolakis, Panagiotis Stathopoulos, Vassiliki Exarchou, John K. Gallos, Maciej Kubicki and Themistoklis A. Kabanos pp 52–61 DOI: 10.1021/ic901809f

Factors Dictating the Nuclearity/Aggregation and Acetate Coordination Modes of Lutidine-Coordinated Zinc(II) Acetate Complexes Umesh Kumar, Jency Thomas and Natesan Thirupathi pp 62–72 DOI: 10.1021/ic901100z Supporting Info

Reaction of a (Salen)ruthenium(VI) Nitrido Complex with Thiols. C−H Bond Activation by (Salen)ruthenium(IV) Sulfilamido Species Wai-Lun Man, William W. Y. Lam, Hoi-Ki Kwong, Shie-Ming Peng, Wing-Tak Wong and Tai-Chu Lau pp 73–81 DOI: 10.1021/ic901374f Supporting Info

Synthesis, Characterization, and Ligand Exchange Reactivity of a Series of First Row Divalent Metal 3-Hydroxyflavonolate Complexes Katarzyna Grubel, Katarzyna Rudzka, Atta M. Arif, Katie L. Klotz, Jason A. Halfen and Lisa M. Berreau pp 82–96 DOI: 10.1021/ic901405h Supporting Info

Dipyrazinyl Sulfoxide Complexes of Silver(I), Zinc(II), and Cadmium(II): Ligation Modes and Anion Tuning Chong-Qing Wan, Liang Zhao and Thomas C. W. Mak pp 97–107 DOI: 10.1021/ic901521j Supporting Info

Synthesis and Characterization of a Series of Structurally and Electronically Diverse Fe(II) Complexes Featuring a Family of Triphenylamido-Amine Ligands Patrina Paraskevopoulou, Lin Ai, Qiuwen Wang, Devender Pinnapareddy, Rama Acharyya, Rupam Dinda, Purak Das, Remle elenligil-etin, Georgios Floros, Yiannis Sanakis, Amitava Choudhury, Nigam P. Rath and Pericles Stavropoulos pp 108–122 DOI: 10.1021/ic9015838 Supporting Info

Cooperation between Cis and Trans Influences in cis-PtII(PPh3)2 Complexes: Structural, Spectroscopic, and Computational Studies Luca Rigamonti, Alessandra Forni, Mario Manassero, Carlo Manassero and Alessandro Pasini pp 123–135 DOI: 10.1021/ic901510m Supporting Info

A New Type of Asymmetric Tridentate Pyrrolyl-Linked Pincer Ligand and Its Aluminum Dihydride Complexes Yu-Ling Lien, Ya-Chi Chang, Nien-Tsu Chuang, Amitabha Datta, Shau-Jiun Chen, Ching-Han Hu, Wen-Yen Huang, Chia-Her Lin and Jui-Hsien Huang pp 136–143 DOI: 10.1021/ic9016189 Supporting Info

Presence or Absence of a Central Se Atom in Silver Selenide/Selenolate Clusters with Halite Topology: Syntheses and Properties of [(Ph3PAg)8Ag6(μ6-Se)1−x/2(SePh)12]x+ (x = 0, 1) Hari Pada Nayek, Werner Massa and Stefanie Dehnen pp 144–149 DOI: 10.1021/ic901629k Supporting Info

Fast Ligand Substitution at a Chromium(III) Hydroperoxo Complex Wenjing Song and Andreja Bakac pp 150–156 DOI: 10.1021/ic9016799 Supporting Info

Evaluation of Electronics, Electrostatics and Hydrogen Bond Cooperativity in the Binding of Cyanide and Fluoride by Lewis Acidic Ferrocenylboranes Alexander E. J. Broomsgrove, David A. Addy, Angela Di Paolo, Ian R. Morgan, Christopher Bresner, Victoria Chislett, Ian A. Fallis, Amber L. Thompson, Dragoslav Vidovic and Simon Aldridge pp 157–173 DOI: 10.1021/ic901673u Supporting Info

New Developments in the Comprehension of the Biotransformation and Transport of Insulin-Enhancing Vanadium Compounds in the Blood Serum Daniele Sanna, Giovanni Micera and Eugenio Garribba pp 174–187 DOI: 10.1021/ic9017213 Supporting Info

Density Functional Theory Applied to a Difference in Pathways Taken by the Enzymes Cytochrome P450 and Superoxide Reductase: Spin States of Ferric Hydroperoxo Intermediates and Hydrogen Bonds from Water Panida Surawatanawong, Jesse W. Tye and Michael B. Hall pp 188–198 DOI: 10.1021/ic9017272 Supporting Info

Mn7 and Mn12 Clusters From Use of 2-(Pyridine-2-yl)propan-2-ol: A New Half-Integer Single-Molecule Magnet Taketo Taguchi, Wolfgang Wernsdorfer, Khalil A. Abboud and George Christou pp 199–208 DOI: 10.1021/ic901741n Supporting Info

Visible Light-Driven Water Oxidation by a Molecular Ruthenium Catalyst in Homogeneous System Lele Duan, Yunhua Xu, Pan Zhang, Mei Wang and Licheng Sun pp 209–215 DOI: 10.1021/ic9017486 Supporting Info

An S-Shaped [Fe4Dy2] Complex Exhibiting Slow Relaxation of Magnetization: Synthesis, Magnetism, and Crystal Structures of a Family of [Fe4Ln2][Ln] Coordination Compounds (Ln = Nd, Gd, Tb, Dy, and Ho) Sanjit Nayak, Olivier Roubeau, Simon J. Teat, Christine M. Beavers, Patrick Gamez and Jan Reedijk pp 216–221 DOI: 10.1021/ic901781a Supporting Info

Uranium Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)− William J. Evans, Elizabeth Montalvo, Joseph W. Ziller, Antonio G. DiPasquale and Arnold L. Rheingold pp 222–228 DOI: 10.1021/ic901790t Supporting Info

A Vanadium Tellurate, (NH4)2[VO2]2[TeO4(OH)2], Containing Two Edge-Shared Square-Pyramidal VO5 Groups Gyiae Yun, Yunmi Hwang, Hoseop Yun, Junghwan Do and Allan J. Jacobson pp 229–233 DOI: 10.1021/ic9018025 Supporting Info

Structural Impact of Multitopic Third-Generation Bis(1-pyrazolyl)methane Ligands: Double, Mononuclear Metallacyclic Silver(I) Complexes Daniel L. Reger, Elizabeth A. Foley and Mark D. Smith pp 234–242 DOI: 10.1021/ic901899r Supporting Info

Electronic Structure of an Iron-Porphyrin−Nitrene Complex Jeanet Conradie and Abhik Ghosh pp 243–248 DOI: 10.1021/ic901897w Supporting Info

Playing the Quantum Chemical Slot Machine: An Exploration of ABX2 Compounds Xiao-Dong Wen, Thomas J. Cahill, Nicholas M. Gerovac, Michael J. Bucknum and Roald Hoffmann pp 249–260 DOI: 10.1021/ic901936s Supporting Info

Heats of Formation of XeF3+, XeF3−, XeF5+, XeF7+, XeF7−, and XeF8 from High Level Electronic Structure Calculations Daniel J. Grant, Tsang-Hsiu Wang and David A. Dixon, Karl O. Christe pp 261–270 DOI: 10.1021/ic901956g Supporting Info

Fluoride Ion Donor Properties of cis-OsO2F4: Synthesis, Raman Spectroscopic Study, and X-ray Crystal Structure of [OsO2F3][Sb2F11] Michael J. Hughes, Hlne P. A. Mercier and Gary J. Schrobilgen pp 271–284 DOI: 10.1021/ic901999e Supporting Info

Toward the Design of Ferromagnetic Molecular Complexes: Magnetostructural Correlations in Ferromagnetic Triply Bridged Dinuclear Cu(II) Compounds Containing Carboxylato and Hydroxo Bridges Ramon Costa, Ibrio de P.R. Moreira, Sujittra Youngme, Khatcharin Siriwong, Nanthawat Wannarit and Francesc Illas pp 285–294 DOI: 10.1021/ic902023u

Computationally Designed Metal-Free Hydrogen Activation Site: Reaching the Reactivity of Metal−Ligand Bifunctional Hydrogenation Catalysts Gang Lu, Haixia Li, Lili Zhao, Fang Huang and Zhi-Xiang Wang pp 295–301 DOI: 10.1021/ic902039g Supporting Info

Highly Cytotoxic Copper(II) Complexes with Modified Paullone Ligands Michael F. Primik, Gerhard Mhlgassner, Michael A. Jakupec, Olivier Zava, Paul J. Dyson, Vladimir B. Arion and Bernhard K. Keppler pp 302–311 DOI: 10.1021/ic902042a Supporting Info

Structural Phase Transitions in EuC2 Derk Wandner, Pascal Link, Oliver Heyer, John Mydosh, Mahmoud A. Ahmida, Mohsen M. Abd-Elmeguid, Manfred Speldrich, Heiko Lueken and Uwe Ruschewitz pp 312–318 DOI: 10.1021/ic901979v

Proof by EPR Spectroscopy that the Unpaired Electron in an Os27+ Species Is in a δ* Metal-based Molecular Orbital F. Albert Cotton, Gina M. Chiarella, Naresh S. Dalal, Carlos A. Murillo, Zhenxing Wang and Mark D. Young pp 319–324 DOI: 10.1021/ic902087e Supporting Info

Investigation of Surface Structures by Powder Diffraction: A Differential Pair Distribution Function Study on Arsenate Sorption on Ferrihydrite Richard Harrington, Douglas B. Hausner, Narayan Bhandari, Daniel R. Strongin, Karena W. Chapman, Peter J. Chupas, Derek S. Middlemiss, Clare P. Grey and John B. Parise pp 325–330 DOI: 10.1021/ic9022695

Assembly of Heteroleptic Copper Complexes with Silver Salts: From Discrete Trinuclear Complexes to Infinite Networks Dmitry Pogozhev, Stphane A. Baudron and Mir Wais Hosseini pp 331–338 DOI: 10.1021/ic902057d Supporting Info

Structures and Unusual Rearrangements of Coordination Adducts of MX5 (M = Nb, Ta; X = F, Cl) with Simple Diethers. A Crystallographic, Spectroscopic, and Computational Study Riccardo Bini, Cinzia Chiappe, Fabio Marchetti, Guido Pampaloni and Stefano Zacchini pp 339–351 DOI: 10.1021/ic9020806 Supporting Info

Issue 02

Indium Chalcogenido Clusters Coordinated by 1,10-Phenanthroline, [InQ(phen)Cl]4 (Q = Se, S), a Simplified Model of Inorganic−Organic Hybrid Material with Cluster-to-Ligand Charge Transfer Zhi-Xin Lei, Qin-Yu Zhu, Ming-Hui Zhang, Jian-Bing Jiang, Ya-Ping Zhang and Jie Dai pp 353–355 DOI: 10.1021/ic901143h Supporting Info

Vibrational Circular Dichroism of Δ-SAPR-8-tetrakis[(+)-heptafluorobutyrylcamphorato]lanthanide(III) Complexes with an Encapsulated Alkali Metal Ion Hisako Sato, Dai Shirotani, Kazuaki Yamanari and Sumio Kaizaki pp 356–358 DOI: 10.1021/ic9016646 Supporting Info

“Depolymerization” Approach in Mn Cluster Chemistry: Controlled Cleavage of a 1D Coordination Polymer Consisting of Mn8 Units in Its Constituent, Discrete Mn8 Complex Constantinos C. Stoumpos, Olivier Roubeau, Guillem Arom, Anastasios J. Tasiopoulos, Vassilios Nastopoulos, Albert Escuer and Spyros P. Perlepes pp 359–361 DOI: 10.1021/ic901974d Supporting Info

Novel Tripeptide Model of Nickel Superoxide Dismutase Mary E. Krause, Amanda M. Glass, Timothy A. Jackson and Jennifer S. Laurence pp 362–364 DOI: 10.1021/ic901828m Supporting Info

Unprecedented 4- and 6-Connected 2D Coordination Networks Based on 44-Subnet Tectons, Showing Unusual Supramolecular Motifs of Rotaxane and Helix Lu-Fang Ma, Li-Ya Wang, Miao Du and Stuart R. Batten pp 365–367 DOI: 10.1021/ic9019298 Supporting Info

Contrasting Magnetism of [MnIII4] and [MnII2MnIII2] Squares Takuto Matsumoto, Takuya Shiga, Mao Noguchi, Tatsuya Onuki, Graham N. Newton, Norihisa Hoshino, Motohiro Nakano and Hiroki Oshio pp 368–370 DOI: 10.1021/ic902052f Supporting Info

Reactivity of a Disilylene [{PhC(NBut)2}Si]2 toward Bromine: Synthesis and Characterization of a Stable Monomeric Bromosilylene Hui-Xian Yeong, Kai-Chung Lau, Hong-Wei Xi, Kok Hwa Lim and Cheuk-Wai So pp 371–373 DOI: 10.1021/ic9021382 Supporting Info

Cyclometalated RuII Complexes with Improved Octahedral Geometry: Synthesis and Photophysical Properties Michael Jger, Amanda Smeigh, Florian Lombeck, Helmar Grls, Jean-Paul Collin, Jean-Pierre Sauvage, Leif Hammarstrm and Olof Johansson pp 374–376 DOI: 10.1021/ic9020788 Supporting Info

Heterometallic 3d−4f Polyoxometalate Derived from the Weakley-Type Dimeric Structure Santiago Reinoso and Jos Ramn Galn-Mascars pp 377–379 DOI: 10.1021/ic902217g Supporting Info

Cluster-Bound Nitriles Do Not Click with Organic Azides: Unexpected Formation of Imino Complexes of the [Re6(μ3-Se)8]2+ Core-Containing Clusters Xiaoyan Tu, Ethan Boroson, Huong Truong, Alvaro Muoz-Castro, Ramiro Arratia-Prez, Gary, S. Nichol and Zhiping Zheng pp 380–382 DOI: 10.1021/ic902251z Supporting Info

Diorganotelluride-Catalyzed Oxidation of Silanes to Silanols under Atmospheric Oxygen Yasunori Okada, Makoto Oba, Atsushi Arai, Kazuhito Tanaka, Kozaburo Nishiyama and Wataru Ando pp 383–385 DOI: 10.1021/ic9022745 Supporting Info

Electronic and Magnetic Study of Polycationic Mn12 Single-Molecule Magnets with a Ground Spin State S = 11 Juan M. Clemente-Juan, Eugenio Coronado, Alicia Forment-Aliaga, Alejandro Gaita-Ario, Carlos Gimnez-Saiz, Francisco M. Romero, W. Wernsdorfer, R. Biagi and V. Corradini pp 386–396 DOI: 10.1021/ic901824d Supporting Info

Efficient and Long-Time Stable Red Iridium(III) Complexes for Organic Light-Emitting Diodes Based on Quinoxaline Ligands Daniel Schneidenbach, Sven Ammermann, Marc Debeaux, Andreas Freund, Mike Zllner, Constantin Daniliuc, Peter G. Jones, Wolfgang Kowalsky and Hans-Hermann Johannes pp 397–406 DOI: 10.1021/ic9009898 Supporting Info

Dynamic NMR Study of Ethene Exchange in Cationic CNN-Type Platinum(II) Complexes M. Rosaria Plutino, Lucia Fenech, Sergio Stoccoro, Silvia Rizzato, Carlo Castellano and Alberto Albinati pp 407–418 DOI: 10.1021/ic901078u Supporting Info

Chiral Indium Alkoxide Complexes as Initiators for the Stereoselective Ring-Opening Polymerization of rac-Lactide Jean-Charles Buffet, Jun Okuda and Polly L. Arnold pp 419–426 DOI: 10.1021/ic900740n Supporting Info

Crystal Structure and Magnetism of a Well Isolated 2D-Quantum Heisenberg Antiferromagnet, (Quinolinium)2CuBr4·2H2O, and Its Anhydrous Form Robert T. Butcher and Mark M. Turnbull , Christopher P. Landee, Alex Shapiro and Fan Xiao , David Garrett and Ward T. Robinson , Brendan Twamley pp 427–434 DOI: 10.1021/ic901216g Supporting Info

Protonation of Type-1 Cu Bound Histidines: A Quantum Chemical Study Peifeng Su and Hui Li pp 435–444 DOI: 10.1021/ic9012735

Crystal Growth, Transport, and the Structural and Magnetic Properties of Ln4FeGa12 with Ln = Y, Tb, Dy, Ho, and Er Brenton L. Drake, Fernande Grandjean, Michael J. Kangas, Edem K. Okudzeto, Amar B. Karki, Moulay T. Sougrati, David P. Young, Gary J. Long and Julia Y. Chan pp 445–456 DOI: 10.1021/ic9013202 Supporting Info

Steric Titration of Arylthiolate Coordination Modes at Pseudotetrahedral Nickel(II) Centers Swarup Chattopadhyay, Tapash Deb, Jeffrey L. Petersen, Victor G. Young, Jr. and Michael P. Jensen pp 457–467 DOI: 10.1021/ic901347p Supporting Info

Stable Silver(I) Hydride Complexes Supported by Diselenophosphate Ligands C. W. Liu, Hao-Wei Chang, Bijay Sarkar, Jean-Yves Saillard, Samia Kahlal and Ying-Yann Wu pp 468–475 DOI: 10.1021/ic901408n Supporting Info

Luminescent Platinum Complexes with Terdentate Ligands Forming 6-Membered Chelate Rings: Advantageous and Deleterious Effects in NNN and NCN-Coordinated Complexes Katherine L. Garner, Louise F. Parkes, Jason D. Piper and J. A. Gareth Williams pp 476–487 DOI: 10.1021/ic9016323 Supporting Info

Structural Motifs and Biological Studies of New Antimony(III) Iodide Complexes with Thiones I. Ozturk, S. Filimonova, S. K. Hadjikakou, N. Kourkoumelis, V. Dokorou, M. J. Manos, A. J. Tasiopoulos, M. M. Barsan, I. S. Butler, E. R. Milaeva, Jan Balzarini and N. Hadjiliadis pp 488–501 DOI: 10.1021/ic901442e

Synthetic, Cyclic Voltammetric, Structural, EPR, and UV−Vis Spectroscopic Studies of Thienyl-Containing meso-A2B-cor(CrV═O) Systems: Consideration of Three Interrelated Molecular Detection Modalities Olga A. Egorova, Olga G. Tsay, Snehadrinarayan Khatua, Bhupal Meka, Nilkamal Maiti, Min-Kyu Kim, Seong Jung Kwon, Jung Oh Huh, Daniela Bucella, Sa-Ouk Kang, Juhyoun Kwak and David G. Churchill pp 502–512 DOI: 10.1021/ic9021432 Supporting Info

Mono and Tetranuclear Gold(I) Complexes of Tris(1-benzylimidazole-2-yl)phosphine Alfredo Burini, Rossana Galassi, Simone Ricci, Fiorella Bachechi, Ahmed A. Mohamed and John P. Fackler, Jr. pp 513–518 DOI: 10.1021/ic901562d Supporting Info

Molecular Dynamics Studies of Concentrated Binary Aqueous Solutions of Lanthanide Salts: Structures and Exchange Dynamics Magali Duvail, Alexandre Ruas, Laurent Venault, Philippe Moisy and Philippe Guilbaud pp 519–530 DOI: 10.1021/ic9017085 Supporting Info

Excited-State Properties of Octahedral Hexarhenium(III) Complexes with Redox-active N-heteroaromatic Ligands Takashi Yoshimura, Chiaki Suo, Kiyoshi Tsuge, Shoji Ishizaka, Koichi Nozaki, Yoichi Sasaki, Noboru Kitamura and Atsushi Shinohara pp 531–540 DOI: 10.1021/ic9015788 Supporting Info

Copper(II) and Nickel(II) Complexes of β-Aminoketoxime Ligand: Syntheses, Crystal Structures, Magnetism, and Nickel(II) Templated Coupling of Oxime with Nitrile Oindrila Das, N. N. Adarsh, Ankan Paul and Tapan Kanti Paine pp 541–551 DOI: 10.1021/ic901614p Supporting Info

Covalent Bonding and the Trans Influence in Lanthanide Compounds Karsten Krogh-Jespersen, Michael D. Romanelli, Jonathan H. Melman, Thomas J. Emge and John G. Brennan pp 552–560 DOI: 10.1021/ic901571m Supporting Info

Novel Three-Dimensional Pillared-Layer Ln(III)−Cu(I) Coordination Polymers Featuring Spindle-Shaped Heterometallic Building Units Qi-Bing Bo, Guo-Xin Sun and Dong-Ling Geng pp 561–571 DOI: 10.1021/ic901730f Supporting Info

Cyclotetrasiloxanetetrols with Methyl Groups at Silicon: Isomers all-cis- and cis-trans-cis-[MeSi(O)OH]4 Yulia A. Pozdnyakova, Alexander A. Korlyukov, Elena G. Kononova, Konstantin A. Lyssenko, Alexander S. Peregudov and Olga I. Shchegolikhina pp 572–577 DOI: 10.1021/ic9017079 Supporting Info

σ-Donor and π-Acceptor Properties of Phosphorus Ligands: An Insight from the Natural Orbitals for Chemical Valence Mariusz P. Mitoraj and Artur Michalak pp 578–582 DOI: 10.1021/ic901736n

Cyanide Lability and Linkage Isomerism of Hexacyanochromate(III) Induced by the Co(II) Ion Carolina Avendano, Ferdi Karadas, Matthew Hilfiger, Michael Shatruk and Kim R. Dunbar pp 583–594 DOI: 10.1021/ic901681e Supporting Info

A Multifrequency High-Field Electron Paramagnetic Resonance Study of CoIIS4 Coordination Dimitrios Maganas, Sergey Milikisyants, Jorrit M. A. Rijnbeek, Silvia Sottini, Nikolaos Levesanos, Panayotis Kyritsis and Edgar J. J. Groenen pp 595–605 DOI: 10.1021/ic901911h Supporting Info

Unsymmetrical Tripodal Ligand for Lanthanide Complexation: Structural, Thermodynamic, and Photophysical Studies Badr El Aroussi, Nathalie Dupont, Grald Bernardinelli and Josef Hamacek pp 606–615 DOI: 10.1021/ic901757u Supporting Info

Dramatic Increase of Selectivity for Heavy Lanthanide(III) Cations by Tuning the Flexibility of Polydentate Chelators Lorenzo Tei, Zsolt Baranyai, Ern Brcher, Claudio Cassino, Fabio Demicheli, Norberto Masciocchi, Giovanni B. Giovenzana and Mauro Botta pp 616–625 DOI: 10.1021/ic901848p Supporting Info

Metal-Complexes As Ligands to Generate Asymmetric Homo- and Heterodinuclear MAIIIMBII Species: a Magneto-Structural and Spectroscopic Comparison of Imidazole-N versus Pyridine-N Biplab Biswas, Sunita Salunke-Gawali, Thomas Weyhermller, Vinzenz Bachler, Eckhard Bill and Phalguni Chaudhuri pp 626–641 DOI: 10.1021/ic9018426 Supporting Info

An Efficient, Selective, and Reducing Agent-Free Copper Catalyst for the Atom-Transfer Radical Addition of Halo Compounds to Activated Olefins Jos Mara Muoz-Molina, Toms R. Belderran and Pedro J. Prez pp 642–645 DOI: 10.1021/ic901942p Supporting Info

Spin Interaction in Octahedral Zinc Complexes of Mono- and Diradical Schiff and Mannich Bases M. Orio, C. Philouze, O. Jarjayes, F. Neese and F. Thomas pp 646–658 DOI: 10.1021/ic901846u Supporting Info

Experimental Determination of Enthalpies of Solution of Tetraphenyl Porphyrin (TPP) and Some Metal Derivatives, in Chloroform: Interpretation of the Solvation Processes at a Molecular Level Minerva Gamboa, Myriam Campos and Luis Alfonso Torres pp 659–664 DOI: 10.1021/ic901921q

Synthesis and Structural Studies of Heterobimetallic Alkoxide Complexes Supported by Bis(phenolate) Ligands: Efficient Catalysts for Ring-Opening Polymerization of l-Lactide Hsuan-Ying Chen, Mei-Yu Liu, Alekha Kumar Sutar and Chu-Chieh Lin pp 665–674 DOI: 10.1021/ic901938e Supporting Info

Tripodal 4-Pyridyl-Derived Host Ligands and Their Metallo-Supramolecular Chemistry: Stella Octangula and Bowl-Shaped Assemblies Tanya K. Ronson, Christopher Carruthers, Julie Fisher, Thierry Brotin, Lindsay P. Harding, Pierre J. Rizkallah and Michaele J. Hardie pp 675–685 DOI: 10.1021/ic901972h Supporting Info

Pseudotetragonal Structure of Li2+xCex3+Ce12−x4+F50: The First Mixed Valence Cerium Fluoride Guillaume Renaudin, Belto Dieudonn, Daniel Avignant, Elise Mapemba, Malika El-Ghozzi, Solne Fleutot, Herv Martinez, Radovan ern and Marc Dubois pp 686–694 DOI: 10.1021/ic901962k Supporting Info

Magnetism and Structure in Chains of Copper Dinuclear Paddlewheel Units Mireille Perec, Ricardo Baggio, Rosana P. Sartoris, Ricardo C. Santana, Octavio Pea and Rafael Calvo pp 695–703 DOI: 10.1021/ic902005m Supporting Info

Formation of {[HIPTN3N]Mo(III)H}− by Heterolytic Cleavage of H2 as Established by EPR and ENDOR Spectroscopy R. Adam Kinney, Dennis G. H. Hetterscheid, Brian S. Hanna, Richard R. Schrock and Brian M. Hoffman pp 704–713 DOI: 10.1021/ic902006v Supporting Info

Cyanide Anion Binding by a Triarylborane at the Outer Rim of a Cyclometalated Ruthenium(II) Cationic Complex Casey R. Wade and Franois P. Gabba pp 714–720 DOI: 10.1021/ic9020349 Supporting Info

Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation Miriam M. Gillett-Kunnath, Ivaylo Petrov and Slavi C. Sevov pp 721–729 DOI: 10.1021/ic9019487 Supporting Info

Homoleptic Heavy Alkaline Earth and Europium Triazenides Hyui Sul Lee and Mark Niemeyer pp 730–735 DOI: 10.1021/ic902055h Supporting Info

pH-Dependent Syntheses and Crystal Structures of a Series of Organic−Inorganic Hybrids Constructed from Keggin or Wells−Dawson Polyoxometalates and Silver Coordination Compounds Hongxun Yang, Shuiying Gao, Jian L, Bo Xu, Jingxiang Lin and Rong Cao pp 736–744 DOI: 10.1021/ic902091p Supporting Info

Pressure Effects on a Spin-Crossover Monomeric Compound [Fe(pmea)(SCN)2] (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine) Bao Li, Rong-Jia Wei, Jun Tao, Rong-Bin Huang and Lan-Sun Zheng pp 745–751 DOI: 10.1021/ic902161v Supporting Info

Diphosphine and Diarsine Complexes of Germanium(II) Halides—Preparation, Spectroscopic, and Structural Studies Fei Cheng, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster and Wenjian Zhang pp 752–760 DOI: 10.1021/ic902068z Supporting Info

Structural Mapping and Framework Interconversions in 1D, 2D, and 3D Divalent Metal R,S-Hydroxyphosphonoacetate Hybrids Rosario M. P. Colodrero, Pascual Olivera-Pastor, Aurelio Cabeza, Maria Papadaki, Konstantinos D. Demadis and Miguel A. G. Aranda pp 761–768 DOI: 10.1021/ic902048b Supporting Info

Issue 03

Unprecedented Marriage of a Cationic Pentanuclear Cluster and a 2D Polymeric Anionic Layer Based on a Flexible Tripodal Ligand and a CuII Ion Zheng-Bo Han, Guo-Xin Zhang, Ming-Hua Zeng, Da-Qiang Yuan, Qian-Rong Fang, Jian-Rong Li, Joan Ribas and Hong-Cai Zhou pp 769–771 DOI: 10.1021/ic902262u Supporting Info

Accurate Modeling of Spin-State Energetics in Spin-Crossover Systems with Modern Density Functional Theory Shengfa Ye and Frank Neese pp 772–774 DOI: 10.1021/ic902365a Supporting Info

Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand Jianfeng Li, Sebastian Merkel, Julian Henn, Kathrin Meindl, Alexander Dring, Herbert W. Roesky, Rajendra S. Ghadwal and Dietmar Stalke pp 775–777 DOI: 10.1021/ic9023162 Supporting Info

Thioester Hydrolysis Promoted by a Mononuclear Zinc Complex James J. Danford, Atta M. Arif and Lisa M. Berreau pp 778–780 DOI: 10.1021/ic902322h Supporting Info

Base-Catalyzed Insertion of Dioxygen into Rhodium−Hydrogen Bonds: Kinetics and Mechanism Ewa Szajna-Fuller and Andreja Bakac pp 781–785 DOI: 10.1021/ic901808t Supporting Info

Nature of Guanine Oxidation in RNA via the Flash-Quench Technique versus Direct Oxidation by a Metal Oxo Complex Dana R. Holcomb, Patricia A. Ropp, Elizabeth C. Theil and H. Holden Thorp pp 786–795 DOI: 10.1021/ic9008619

Anthracene-Bridged Binuclear Ruthenium Complexes: Electrochemical and Spectroscopic Evidence of Electronic Communication Through the π System Neus Vil, Yu-Wu Zhong, Jay C. Henderson and Hctor D. Abrua pp 796–804 DOI: 10.1021/ic900100w Supporting Info

Luminescent Mononuclear Ag(I)−Bis(diphosphine) Complexes: Correlation between the Photophysics and the Structures of Mononuclear Ag(I)−Bis(diphosphine) Complexes Kenji Matsumoto, Takao Shindo, Naoki Mukasa, Toshiaki Tsukuda and Taro Tsubomura pp 805–814 DOI: 10.1021/ic900203x Supporting Info

Synthesis and Characterization of K8−x(H2)ySi46 Doinita Neiner, Norihiko L. Okamoto, Ping Yu, Sharon Leonard, Cathie L. Condron, Michael F. Toney, Quentin M. Ramasse, Nigel D. Browning and Susan M. Kauzlarich pp 815–822 DOI: 10.1021/ic9004592 Supporting Info

New Series of Ruthenium(II) and Osmium(II) Complexes Showing Solid-State Phosphorescence in Far-Visible and Near-Infrared Jing-Lin Chen, Yun Chi and Kellen Chen, Yi-Ming Cheng, Min-Wen Chung, Ya-Chien Yu, Gene-Hsiang Lee and Pi-Tai Chou, Ching-Fong Shu pp 823–832 DOI: 10.1021/ic900586e Supporting Info

Measurement of Both the Equilibrium Constant and Rate Constant for Electronic Energy Transfer by Control of the Limiting Kinetic Regimes Michael T. Vagnini, W. Caleb Rutledge and Paul S. Wagenknecht pp 833–838 DOI: 10.1021/ic9013174 Supporting Info

Effect of Ancillary Ligands on the DNA Interaction of [Cr(diimine)3]3+ Complexes Containing the Intercalating Dipyridophenazine Ligand M. Scott Vandiver, E. Page Bridges, Ryan L. Koon, Alex N. Kinnaird, Jeff W. Glaeser, Jennifer F. Campbell, Chris J. Priedemann, William T. Rosenblatt, Brad J. Herbert, Sandra K. Wheeler, John F. Wheeler and Noel A. P. Kane-Maguire pp 839–848 DOI: 10.1021/ic9013619 Supporting Info

Photocytotoxic Oxovanadium(IV) Complexes Showing Light-Induced DNA and Protein Cleavage Activity Pijus K. Sasmal, Sounik Saha, Ritankar Majumdar, Rajan R. Dighe and Akhil R. Chakravarty pp 849–859 DOI: 10.1021/ic900701s Supporting Info

Oxidation State Characterization of Ruthenium 2−Iminoquinone Complexes through Experimental and Theoretical Studies Jonathan Rochford, Ming-Kang Tsai, David J. Szalda, Julie L. Boyer, James T. Muckerman and Etsuko Fujita pp 860–869 DOI: 10.1021/ic901194k Supporting Info

Computational Studies of Structural, Electronic, Spectroscopic, and Thermodynamic Properties of Methylmercury-Amino Acid Complexes and Their Se Analogues Abu Md. Asaduzzaman, Mohammad A. K. Khan, Georg Schreckenbach and Feiyue Wang pp 870–878 DOI: 10.1021/ic900827m Supporting Info

Synthesis and Characterization of Iron(II) Quinaldate Complexes Dylan T. Houghton, Nicholas W. Gydesen, Navamoney Arulsamy and Mark P. Mehn pp 879–887 DOI: 10.1021/ic901464b Supporting Info

Design and Synthesis of a Fluorescent Probe for Zn2+, 5,7-Bis(N,N-dimethylaminosulfonyl)-8-hydroxyquinoline-Pendant 1,4,7,10-Tetraazacyclododecane and Zn2+-Dependent Hydrolytic and Zn2+-Independent Photochemical Reactivation of Its Benzenesulfonyl-Caged Derivative Ryosuke Ohshima, Masanori Kitamura, Akinori Morita, Motoo Shiro, Yasuyuki Yamada, Masahiko Ikekita, Eiichi Kimura and Shin Aoki pp 888–899 DOI: 10.1021/ic901279t Supporting Info

Vertex-Fused Metallaborane Clusters: Synthesis, Characterization and Electronic Structure of [(η5-C5Me5Mo)3MoB9H18] Rajendra S. Dhayal, Satyanarayan Sahoo, K. Hari Krishna Reddy, Shaikh M. Mobin, Eluvathingal D. Jemmis and Sundargopal Ghosh pp 900–904 DOI: 10.1021/ic901481q Supporting Info

Synthesis, Crystal Structures, and Luminescent Properties of Two Series' of New Lanthanide (III) Amino-Carboxylate-Phosphonates Tian-Hua Zhou, Fei-Yan Yi, Pei-Xin Li and Jiang-Gao Mao pp 905–915 DOI: 10.1021/ic901621x Supporting Info

FerriCast: A Macrocyclic Photocage for Fe3+ Daniel P. Kennedy, Christopher D. Incarvito and Shawn C. Burdette pp 916–923 DOI: 10.1021/ic901182c Supporting Info

Actinide Redox-Active Ligand Complexes: Reversible Intramolecular Electron-Transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF) Eric J. Schelter, Ruilian Wu, Brian L. Scott, Joe D. Thompson, Thibault Cantat, Kevin D. John, Enrique R. Batista, David E. Morris and Jaqueline L. Kiplinger pp 924–933 DOI: 10.1021/ic901636f Supporting Info

Jahn−Teller Distorted Frameworks and Magnetic Order in the Rb−Mn−P−O System Fiona C. Coomer, Neal J. Checker and Adrian J. Wright pp 934–942 DOI: 10.1021/ic901668u

A Versatile Tripodal Amide Receptor for the Encapsulation of Anions or Hydrated Anions via Formation of Dimeric Capsules M. Arunachalam and Pradyut Ghosh pp 943–951 DOI: 10.1021/ic901644h Supporting Info

Synthesis, Substitution Kinetics, and Electrochemistry of the First Tetrathiafulvalene-Containing β-Diketonato Complexes of Rhodium(I) Eleanor Fourie, Jannie C. Swarts, Dominique Lorcy and Nathalie Bellec pp 952–959 DOI: 10.1021/ic901676e Supporting Info

Intramolecular Chalcogen−Tin Interactions in [(o-MeEC6H4)CH2]2SnPh2−nCln (E = S, O, CH2; n = 0, 1, 2) and Intermolecular Chlorine−Tin Interactions in the meta- and para-Methoxy Isomers Diana Gabriela Vargas-Pineda, Tanya Guardado, Francisco Cervantes-Lee, Alejandro J. Metta-Magana and Keith H. Pannell pp 960–968 DOI: 10.1021/ic901800c Supporting Info

Slow Relaxation Processes and Single-Ion Magnetic Behaviors in Dysprosium-Containing Complexes Ying Wang, Xi-Li Li, Tian-Wei Wang, You Song and Xiao-Zeng You pp 969–976 DOI: 10.1021/ic901720a Supporting Info

Family of V(III)-Tristhiolato Complexes Relevant to Functional Models of Vanadium Nitrogenase: Synthesis and Electronic Structure Investigations by Means of High-Frequency and -Field Electron Paramagnetic Resonance Coupled to Quantum Chemical Computations. Shengfa Ye, Frank Neese, Andrew Ozarowski, Dmitry Smirnov, J. Krzystek, Joshua Telser, Ju-Hsiou Liao, Chen-Hsiung Hung, Wei-Chen Chu, Yi-Feng Tsai, Rong-Chin Wang, Kun-Yuan Chen and Hua-Fen Hsu pp 977–988 DOI: 10.1021/ic9017745 Supporting Info

Asymmetric Synthesis of Functionalized 1,3-Diphosphines via Chiral Palladium Complex Promoted Hydrophosphination of Activated Olefins Mingjun Yuan, Na Zhang, Sumod A. Pullarkat, Yongxin Li, Fengli Liu, Phuong-Tu Pham and Pak-Hing Leung pp 989–996 DOI: 10.1021/ic9018053 Supporting Info

Octahedral Copper(II) and Tetrahedral Copper(I) Double-Strand Helicates: Chiral Self-Recognition and Redox Behavior Valeria Amendola, Massimo Boiocchi, Valentina Brega, Luigi Fabbrizzi and Lorenzo Mosca pp 997–1007 DOI: 10.1021/ic9019684 Supporting Info

Mechanism of Ionic Recognition by Polymer-Supported Reagents: Immobilized Tetramethylmalonamide and the Complexation of Lanthanide Ions Yijia Yang and Spiro D. Alexandratos pp 1008–1016 DOI: 10.1021/ic901813t

Hydrosulfide (HS−) Coordination in Iron Porphyrinates Jeffrey W. Pavlik, Bruce C. Noll, Allen G. Oliver, Charles E. Schulz and W. Robert Scheidt pp 1017–1026 DOI: 10.1021/ic901853p Supporting Info

Electrochemistry and Spectroelectrochemistry of β,β′-Fused Quinoxalinoporphyrins and Related Extended Bis-porphyrins with Co(III), Co(II), and Co(I) Central Metal Ions Weihua Zhu, Maxine Sintic, Zhongping Ou, Paul J. Sintic, James A. McDonald, Peter R. Brotherhood, Maxwell J. Crossley and Karl M. Kadish pp 1027–1038 DOI: 10.1021/ic901851u Supporting Info

Gas-Phase Structures of Iron Trihalides: A Computational Study of all Iron Trihalides and an Electron Diffraction Study of Iron Trichloride Zoltn Varga, Mria Kolonits and Magdolna Hargittai pp 1039–1045 DOI: 10.1021/ic901916q Supporting Info

Prospects for Making Organometallic Compounds with BF Ligands: Fluoroborylene Iron Carbonyls Liancai Xu, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 1046–1055 DOI: 10.1021/ic901964f Supporting Info

Third Row Transition Metal Hexafluorides, Extraordinary Oxidizers, and Lewis Acids: Electron Affinities, Fluoride Affinities, and Heats of Formation of WF6, ReF6, OsF6, IrF6, PtF6, and AuF6 Raluca Craciun, Dsire Picone, Rebecca T. Long, Shenggang Li and David A. Dixon, Kirk A. Peterson, Karl O. Christe pp 1056–1070 DOI: 10.1021/ic901967h Supporting Info

O2-Dependent Aliphatic Carbon−Carbon Bond Cleavage Reactivity in a Ni(II) Enolate Complex Having a Hydrogen Bond Donor Microenvironment; Comparison with a Hydrophobic Analogue Katarzyna Grubel, Amy L. Fuller, Bonnie M. Chambers, Atta M. Arif and Lisa M. Berreau pp 1071–1081 DOI: 10.1021/ic901981y Supporting Info

Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase Stanislav Groysman, Amit Majumdar, Shao-Liang Zheng and R. H. Holm pp 1082–1089 DOI: 10.1021/ic902066m Supporting Info

Reversible Reconstructive Phase Transition of Ba2SnSe5: A New High Temperature Modification with Completely Different Structural Motifs Mariya Zelinska, Abdeljalil Assoud, Christian Graf and Holger Kleinke pp 1090–1093 DOI: 10.1021/ic901989j Supporting Info

Template Synthesis of Iron(II) Complexes Containing Tridentate P−N−S, P−N−P, P−N−N, and Tetradentate P−N−N−P Ligands Paraskevi O. Lagaditis, Alexandre A. Mikhailine, Alan J. Lough and Robert H. Morris pp 1094–1102 DOI: 10.1021/ic901945c Supporting Info

Synthesis and Characterization of a Uranium(III) Complex Containing a Redox-Active 2,2′-Bipyridine Ligand Steven J. Kraft, Phillip E. Fanwick and Suzanne C. Bart pp 1103–1110 DOI: 10.1021/ic902008w Supporting Info

Amine− and Dimeric Amino−Borane Complexes of the {Rh(PiPr3)2}+ Fragment and Their Relevance to the Transition-Metal-Mediated Dehydrocoupling of Amine−Boranes Adrian B. Chaplin and Andrew S. Weller pp 1111–1121 DOI: 10.1021/ic9020542 Supporting Info

Oxovanadium(IV) Cyclam and Bicyclam Complexes: Potential CXCR4 Receptor Antagonists Allison Ross, Dinesh C. Soares, Danielle Covelli, Christophe Pannecouque, Laura Budd, Anna Collins, Neil Robertson, Simon Parsons, Erik De Clercq, Pierre Kennepohl and Peter J. Sadler pp 1122–1132 DOI: 10.1021/ic9020614 Supporting Info

Magnetic Ordering in Nitrides with the η-Carbide Structure, (Ni,Co,Fe)2(Ga,Ge)Mo3N Lev A. Sviridov, Peter D. Battle, Fernande Grandjean, Gary J. Long and Timothy J. Prior pp 1133–1143 DOI: 10.1021/ic902069w

Structural Diversity by Mixing Chalcogen Atoms in the Chalcophosphate System K/In/P/Q (Q = S, Se) Alexander Rothenberger, Hsien-Hau Wang, DuckYoung Chung and Mercouri G. Kanatzidis pp 1144–1151 DOI: 10.1021/ic902105j Supporting Info

Interconversion of Perovskite and Fluorite Structures in Ce−Sc−O System Rakesh Shukla, Ashok Arya and Avesh K. Tyagi pp 1152–1157 DOI: 10.1021/ic9020096

Porous Coordination Polymer with Flexibility Imparted by Coordinatively Changeable Lithium Ions on the Pore Surface Lin-Hua Xie, Jian-Bin Lin, Xiao-Min Liu, Yu Wang, Wei-Xiong Zhang, Jie-Peng Zhang and Xiao-Ming Chen pp 1158–1165 DOI: 10.1021/ic902077j Supporting Info

Anionic Amino Acid [closo-1-CB9H8-1-COO-10-NH3]− and Dinitrogen Acid [closo-1-CB9H8-1-COOH-10-N2] as Key Precursors to Advanced Materials: Synthesis and Reactivity Bryan Ringstrand, Piotr Kaszynski, Victor G. Young, Jr. and Zbynek Janouek pp 1166–1179 DOI: 10.1021/ic9021323 Supporting Info

A Photochemical Precursor for Carbon Monoxide Release in Aerated Aqueous Media R. Dale Rimmer, Heinrich Richter and Peter C. Ford pp 1180–1185 DOI: 10.1021/ic902147n Supporting Info

Syntheses and Characterization of a Series of Silver−Thioantimonates(III) and Thioarsenates(III) Containing Two Types of Silver−Sulfur Chains Hua-Gang Yao, Peng Zhou, Shou-Hua Ji, Ren-Chun Zhang, Min Ji, Yong-Lin An and Gui-Ling Ning pp 1186–1190 DOI: 10.1021/ic902084u Supporting Info

Fabrication of Crystalline Mesoporous Metal Oxides and Sulfides Keyan Xue, Dairong Chen and Xiuling Jiao pp 1191–1197 DOI: 10.1021/ic902160m Supporting Info

Synthesis, Structures, and Multinuclear NMR Spectra of Tin(II) and Lead(II) Complexes of Tellurium-Containing Imidodiphosphinate Ligands: Preparation of Two Morphologies of Phase-Pure PbTe from a Single-Source Precursor Jamie S. Ritch, Tristram Chivers, Kibriya Ahmad, Mohammad Afzaal and Paul O’Brien pp 1198–1205 DOI: 10.1021/ic9021728 Supporting Info

Imaging Different Interactions of Mercury and Silver with Live Cells by a Designed Fluorescence Probe Rhodamine B Selenolactone Wen Shi, Shuna Sun, Xiaohua Li and Huimin Ma pp 1206–1210 DOI: 10.1021/ic902192a Supporting Info

Cysteine Oxidation Enhanced by Iron in Tristetraprolin, A Zinc Finger Peptide Seung Jae Lee and Sarah L. J. Michel pp 1211–1219 DOI: 10.1021/ic9024298 Supporting Info

Lithium Furyl and Pyridyl Amidinates as Building Blocks in Coordination Polymers, Ladder and Cage Structures Sinai Aharonovich, Mark Botoshanski, Ziv Rabinovich, Robert M. Waymouth and Moris S. Eisen pp 1220–1229 DOI: 10.1021/ic902183c Supporting Info

Toward Verdazyl Radical-Based Materials: Ab Initio Inspection of Potential Organic Candidates for Spin-Crossover Phenomenon Jean-Baptiste Rota, Boris Le Guennic and Vincent Robert pp 1230–1237 DOI: 10.1021/ic902197f

Discrete Mercury(II) Complexes, One-Dimensional and Palladium(II)-Mediated Two-Dimensional Silver(I) Coordination Polymers of NS2-Macrocycle: Synthesis and Structural Characterization Sunhong Park, So Young Lee and Shim Sung Lee pp 1238–1244 DOI: 10.1021/ic9021678 Supporting Info

Synthesis and Properties of N7O+ Karl O. Christe, Ralf Haiges, William W. Wilson and Jerry A. Boatz pp 1245–1251 DOI: 10.1021/ic9022213

Planned Failures from the Principle of Maximum Site Occupancy in Lanthanide Helicates Jean-Franois Lemonnier, Laure Gune, Grald Bernardinelli, Jean-Franois Vigier, Bernard Bocquet and Claude Piguet pp 1252–1265 DOI: 10.1021/ic902314f Supporting Info

A Two-Dimensional Metal-Organic Framework Based on a Ferromagnetic Pentanuclear Copper(II) Xia Zhu, Jun-Wei Zhao, Bao-Long Li, You Song, Yu-Mei Zhang and Yong Zhang pp 1266–1270 DOI: 10.1021/ic902404b Supporting Info

Issue 04

A Cyano-Bridged CrIIICoII Ferromagnet with a Chiral Nanotubular Structure Constituted of Interlocked Single and Double Helices Yuan-Zhu Zhang and Osamu Sato pp 1271–1273 DOI: 10.1021/ic900224b Supporting Info

An Iron-Based Cytosolic Catalase and Superoxide Dismutase Mimic Complex Adolfo Horn, Jr., Gabrieli L. Parrilha, Karen V. Melo, Christiane Fernandes, Manfredo Horner, Lorenzo do C. Visentin, Jullyane A. S. Santos, Monique S. Santos, Elis C.A. Eleutherio and Marcos D. Pereira pp 1274–1276 DOI: 10.1021/ic901904b Supporting Info

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts Javier J. Concepcion, Jonah W. Jurss, Michael R. Norris, Zuofeng Chen, Joseph L. Templeton and Thomas J. Meyer pp 1277–1279 DOI: 10.1021/ic901437e Supporting Info

Structural and Catalytic Performance of a Polyoxometalate-Based Metal−Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block Dongbin Dang, Yan Bai, Cheng He, Jian Wang, Chunying Duan and Jingyang Niu pp 1280–1282 DOI: 10.1021/ic901504q Supporting Info

Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R3tach)ReO3]+ (R = −CH3, −CH2C6H5) and Its Substitution Reactions Henrik Braband, Sebastian Imstepf, Michael Felber, Bernhard Spingler and Roger Alberto pp 1283–1285 DOI: 10.1021/ic902114p Supporting Info

Ionic Ferroelectrics Based on Nickel Schiff Base Complexes Yan Sui, Dong-Ping Li, Cheng-Hui Li, Xin-Hui Zhou, Tao Wu and Xiao-Zeng You pp 1286–1288 DOI: 10.1021/ic902136f Supporting Info

In Situ C−C Coupling and Formation of a Heptanuclear Copper(II) Cluster Jia-Ping Tong, Xiao-Jun Sun, Jun Tao, Rong-Bin Huang and Lan-Sun Zheng pp 1289–1291 DOI: 10.1021/ic902205x Supporting Info

Titanocene Difluorides with Improved Cytotoxic Activity Silvia Eger, Timo A. Immel, James Claffey, Helge Mller-Bunz, Matthias Tacke, Ulrich Groth and Thomas Huhn pp 1292–1294 DOI: 10.1021/ic9022163 Supporting Info

Ordering of Pd2+ and Pd4+ in the Mixed-Valent Palladate KPd2O3 Rodion V. Panin, Nellie R. Khasanova, Catherine Bougerol, Walter Schnelle, Gustaaf Van Tendeloo and Evgeny V. Antipov pp 1295–1297 DOI: 10.1021/ic902187a Supporting Info

Vanadium(II) Heptacyanomolybdate(III)-Based Magnet Exhibiting a High Curie Temperature of 110 K Keisuke Tomono, Yoshihide Tsunobuchi, Koji Nakabayashi and Shin-ichi Ohkoshi pp 1298–1300 DOI: 10.1021/ic9022079 Supporting Info

Coumarin-Based, Electron-Trapping Iridium Complexes as Highly Efficient and Stable Phosphorescent Emitters for Organic Light-Emitting Diodes Xiaofan Ren, Marina E. Kondakova, David J. Giesen, Manju Rajeswaran, Marcel Madaras and William C. Lenhart pp 1301–1303 DOI: 10.1021/ic9022097 Supporting Info

Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged Mn3IIIMn2II Single-Molecule Magnets Patrick L. Feng, Casey J. Stephenson, Asma Amjad, Gavin Ogawa, Enrique del Barco and David N. Hendrickson pp 1304–1306 DOI: 10.1021/ic902298y Supporting Info

TTF-Annulated Phenanthroline and Unexpected Oxidative Cleavage of the C═C Bond in Its Ruthenium(II) Complex Lawrence K. Keniley, Jr., Lipika Ray, Kirill Kovnir, Logan A. Dellinger, Jordan M. Hoyt and Michael Shatruk pp 1307–1309 DOI: 10.1021/ic902230f Supporting Info

Interplay between Hydrido/Dihydrogen and Amine/Amido Ligands in Ruthenium-Catalyzed Transfer Hydrogenation of Ketones Alexandre Picot, Hellen Dyer, Antoine Buchard, Audrey Auffrant, Laure Vendier, Pascal Le Floch and Sylviane Sabo-Etienne pp 1310–1312 DOI: 10.1021/ic902339j Supporting Info

Confined Growth of Cyanide-Based Magnets in Two Dimensions Eugenio Coronado, Carlos Mart-Gastaldo, Efrn Navarro-Moratalla and Antonio Ribera pp 1313–1315 DOI: 10.1021/ic902552t Supporting Info

Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters Wendy L. Queen, Shiou-Jyh Hwu and Shane Reighard pp 1316–1318 DOI: 10.1021/ic902283g Supporting Info

Combination of a Fluorescent Dye and a Zn−S Cluster and Its Biological Application as a Stain for Bacteria Jingli Xie, Siyu Cao, David Good, Mingqian Wei and Xiaoming Ren pp 1319–1321 DOI: 10.1021/ic9023629 Supporting Info

Fc-Fc Electronic Interaction through Equatorial Pathways of a Diruthenium Core Darryl A. Boyd, Robert J. Crutchley, Phillip E. Fanwick and Tong Ren pp 1322–1324 DOI: 10.1021/ic902378h Supporting Info

Binding of Higher Alcohols onto Mn12 Single-Molecule Magnets (SMMs): Access to the Highest Barrier Mn12 SMM Christos Lampropoulos, Gage Redler, Saiti Data, Khalil A. Abboud, Stephen Hill and George Christou pp 1325–1336 DOI: 10.1021/ic901480y Supporting Info

Back-to-Back Dinuclear Platinum Terpyridyl Complexes: Synthesis and Photophysical Studies Zhiqiang Ji, Suyue Li, Yunjing Li and Wenfang Sun pp 1337–1346 DOI: 10.1021/ic9009674 Supporting Info

The Main Role of Inner Histidines in the Molecular Mechanism of Myoglobin Oxidation Catalyzed by Copper Compounds G. B. Postnikova, S. A. Moiseeva and E. A. Shekhovtsova pp 1347–1354 DOI: 10.1021/ic901049h

Electronic Structure and Circular Dichroism of Tris(bipyridyl) Metal Complexes within Density Functional Theory Jing Fan, Jochen Autschbach and Tom Ziegler pp 1355–1362 DOI: 10.1021/ic9011586 Supporting Info

Recognition of Some Lanthanides, Actinides, and Transition- and Heavy-Metal Cations by N-Donor Ligands: Thermodynamic and Kinetic Aspects Vronique Hubscher-Bruder, Jaouad Haddaoui, Saliha Bouhroum and Franoise Arnaud-Neu pp 1363–1371 DOI: 10.1021/ic9010899

Mono- versus Dinuclear Pt(II) 6-(5-Trifluoromethyl-Pyrazol-3-yl)-2,2′-Bipyridine Complexes: Synthesis, Characterization, and Remarkable Difference in Luminescent Properties Kang-Wei Wang, Jing-Lin Chen, Yi-Ming Cheng, Min-Wen Chung, Cheng-Chih Hsieh, Gene-Hsiang Lee, Pi-Tai Chou, Kellen Chen and Yun Chi pp 1372–1383 DOI: 10.1021/ic9011313 Supporting Info

Searching for the Interlayer Band and Unravelling the Bonding in β-ThSi2 and α-ThSi2 with NMTO Wannier-like Functions Eva Zurek, Ove Jepsen and Ole Krogh Andersen pp 1384–1396 DOI: 10.1021/ic9014515

Phase Evolution in Low-Dimensional Niobium Oxide Synthesized by a Topochemical Method Lihong Li, Jinxia Deng, Ranbo Yu, Jun Chen, Xiaowei Wang and Xianran Xing pp 1397–1403 DOI: 10.1021/ic902165r Supporting Info

Reductive Coupling of Nitrogen Monoxide (•NO) Facilitated by Heme/Copper Complexes Jun Wang, Mark P. Schopfer, Simona C. Puiu, Amy A. N. Sarjeant and Kenneth D. Karlin pp 1404–1419 DOI: 10.1021/ic901431r Supporting Info

Surface Science of Soft Scorpionates Dawn Wallace, Edward J. Quinn, David R. Armstrong, John Reglinski, Mark D. Spicer and W. Ewen Smith pp 1420–1427 DOI: 10.1021/ic9014898 Supporting Info

Stabilization of Long-Lived Metastable State in Long Alkylated Spin-Crossover Cobalt(II) Compound Shinya Hayami, Daisuke Urakami, Yoshihiro Kojima, Hokuto Yoshizaki, Yuuki Yamamoto, Kazuya Kato, Akira Fuyuhiro, Satoshi Kawata and Katsuya Inoue pp 1428–1432 DOI: 10.1021/ic9015417 Supporting Info

Structural Studies of Technetium−Zirconium Alloys by X-ray Diffraction, High-Resolution Electron Microscopy, and First-Principles Calculations Frederic Poineau, Thomas Hartmann, Philippe F. Weck, Eunja Kim, G. W. Chinthaka Silva, Gordon D. Jarvinen and Kenneth R. Czerwinski pp 1433–1438 DOI: 10.1021/ic9016257 Supporting Info

Electrochemiluminescent Functionalizable Cyclometalated Thiophene-Based Iridium(III) Complexes Marco Bandini, Michele Bianchi, Giovanni Valenti, Fabio Piccinelli, Francesco Paolucci, Magda Monari, Achille Umani-Ronchi and Massimo Marcaccio pp 1439–1448 DOI: 10.1021/ic901660m Supporting Info

Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and β-Ga2O3:Dy3+ Guogang Li, Chong Peng, Chunxia Li, Piaoping Yang, Zhiyao Hou, Yong Fan, Ziyong Cheng and Jun Lin pp 1449–1457 DOI: 10.1021/ic901682x Supporting Info

Synthesis and Characterization of 6,6′-(2,4,6-Triisopropylphenyl)-2,2′-bipyridine (tripbipy) and Its Complexes of the Late First Row Transition Metals Eric E. Benson, Arnold L. Rheingold and Clifford P. Kubiak pp 1458–1464 DOI: 10.1021/ic9016382 Supporting Info

Density Functional Analysis of the Trigonal Uranyl Equatorial Coordination in Hexahomotrioxacalix[3]arene-based Macrocyclic Complexes Philippe F. Weck, Eunja Kim, Bernardo Masci, Pierre Thury and Kenneth R. Czerwinski pp 1465–1470 DOI: 10.1021/ic901694g

Two Temperature-Independent Spinomers of the Dinuclear Mn(III) Compound [{Mn(H2O)(phen)}2(μ-2-ClC6H4COO)2(μ-O)](ClO4)2 Vernica Gmez, Montserrat Corbella and Gabriel Aulln pp 1471–1480 DOI: 10.1021/ic901719t Supporting Info

Synthesis and Characterization of an Asymmetric, Linear, Trinuclear Manganese(II) Complex Cristina M. Coates, Stephanie R. Fiedler, T. Laura McCullough, Thomas E. Albrecht-Schmitt, Matthew P. Shores and Christian R. Goldsmith pp 1481–1486 DOI: 10.1021/ic901758s Supporting Info

Ruthenium Nitrosyls Derived from Tetradentate Ligands Containing Carboxamido-N and Phenolato-O Donors: Syntheses, Structures, Photolability, and Time Dependent Density Functional Theory Studies Nicole L. Fry, Michael J. Rose, David L. Rogow, Crystal Nyitray, Manpreet Kaur and Pradip K. Mascharak pp 1487–1495 DOI: 10.1021/ic9017129 Supporting Info

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution? Antonio R. Tapia-Benavides, Luis H. Mendoza-Huizar, Francisco Prez-Garca, Hugo Tlahuext, Alejandro Alvarez and Margarita Tlahuextl pp 1496–1502 DOI: 10.1021/ic901740d Supporting Info

K23Au12Sn9—An Intermetallic Compound Containing a Large Gold−Tin Cluster: Synthesis, Structure, and Bonding Bin Li, Sung-Jin Kim, Gordon J. Miller and John D. Corbett pp 1503–1509 DOI: 10.1021/ic901771x Supporting Info

Characterization of the Order−Disorder Dielectric Transition in the Hybrid Organic−Inorganic Perovskite-Like Formate Mn(HCOO)3[(CH3)2NH2] M. Snchez-Andjar, S. Presedo, S. Yez-Vilar, S. Castro-Garca, J. Shamir and M. A. Sears-Rodrguez pp 1510–1516 DOI: 10.1021/ic901872g Supporting Info

One-Dimensional Spin-Crossover Iron(II) Complexes Bridged by Intermolecular Imidazole−Pyridine NH···N Hydrogen Bonds, [Fe(HLMe)3]X2 (HLMe = (2-Methylimidazol-4-yl-methylideneamino-2-ethylpyridine; X = PF6, ClO4, BF4) Koshiro Nishi, Shinobu Arata, Naohide Matsumoto, Seiichiro Iijima, Yukinari Sunatsuki, Hiroyuki Ishida and Masaaki Kojima pp 1517–1523 DOI: 10.1021/ic9017344 Supporting Info

Anomalous Non-Prussian Blue Structures and Magnetic Ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6] Jae-Hyuk Her, Peter W. Stephens, Christopher M. Kareis, Joshua G. Moore, Kil Sik Min, Jong-Won Park, Garima Bali, Bretni S. Kennon and Joel S. Miller pp 1524–1534 DOI: 10.1021/ic901903f Supporting Info

Series of 2D and 3D Coordination Polymers Based on 1,2,3,4-Benzenetetracarboxylate and N-Donor Ligands: Synthesis, Topological Structures, and Photoluminescent Properties Lai-Ping Zhang, Jian-Fang Ma, Jin Yang, Yuan-Yuan Pang and Ji-Cheng Ma pp 1535–1550 DOI: 10.1021/ic9019553 Supporting Info

Diverse Manganese(II) Coordination Polymers with Mixed Azide and Zwitterionic Dicarboxylate Ligands: Structure and Magnetic Properties Yan-Qin Wang, Qin-Xiang Jia, Kun Wang, Ai-Ling Cheng and En-Qing Gao pp 1551–1560 DOI: 10.1021/ic901798y Supporting Info

Cation Coordination Control of Anionic Group Alignment to Maximize SHG Effects in the BaMBO3F (M = Zn, Mg) Series R. K. Li and Peng Chen pp 1561–1565 DOI: 10.1021/ic901698b Supporting Info

Density Functional Theory Study of the Electron Paramagnetic Resonance Parameters and the Magnetic Circular Dichroism Spectrum for Model Compounds of Dimethyl Sulfoxide Reductase Elizabeth Hernandez-Marin, Michael Seth and Tom Ziegler pp 1566–1576 DOI: 10.1021/ic901888q Supporting Info

Selective Formation of Heteroligated Pt(II) Complexes with Bidentate Phosphine-Thioether (P,S) and Phosphine-Selenoether (P,Se) Ligands via the Halide-Induced Ligand Rearrangement Reaction Alexander M. Spokoyny, Mari S. Rosen, Pirmin A. Ulmann, Charlotte Stern and Chad A. Mirkin pp 1577–1586 DOI: 10.1021/ic901991w Supporting Info

Crystal Structure and Optical and Magnetic Properties of Pr2(MoO4)3 D. Logvinovich, A. Arakcheeva, P. Pattison, S. Eliseeva, P. Tome, I. Marozau and G. Chapuis pp 1587–1594 DOI: 10.1021/ic9019876 Supporting Info

Experimental Evidence for Magnetic Exchange in Di- and Trinuclear Uranium(IV) Ethynylbenzene Complexes Brian S. Newell, Anthony K. Rapp and Matthew P. Shores pp 1595–1606 DOI: 10.1021/ic901986w Supporting Info

trans-[OsIII(salen)(CN)2]−: A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials Jun-Fang Guo, Wai-Fun Yeung, Pui-Ha Lau, Xiu-Teng Wang, Song Gao, Wing-Tak Wong, Stephen Sin-Yin Chui, Chi-Ming Che, Wai-Yeung Wong and Tai-Chu Lau pp 1607–1614 DOI: 10.1021/ic9020178 Supporting Info

Cationic, Neutral, and Anionic PNP PdII and PtII Complexes: Dearomatization by Deprotonation and Double-Deprotonation of Pincer Systems Moran Feller, Eyal Ben-Ari, Mark A. Iron, Yael Diskin-Posner, Gregory Leitus, Linda J. W. Shimon, Leonid Konstantinovski and David Milstein pp 1615–1625 DOI: 10.1021/ic902012z Supporting Info

Reversible Cu4 ↔ Cu6 Core Interconversion and Temperature Induced Single-Crystal-to-Single-Crystal Phase Transition for Copper(I) Carboxylate Alexander S. Filatov, Oleksandr Hietsoi, Yulia Sevryugina, Nikolay N. Gerasimchuk and Marina A. Petrukhina pp 1626–1633 DOI: 10.1021/ic9020367 Supporting Info

Solvatochromic and Ionochromic Effects of Iron(II)bis(1,10-phenanthroline)dicyano: a Theoretical Study Ivelina Georgieva, Adlia J. A. Aquino, Natasha Trendafilova, Paulo S. Santos and Hans Lischka pp 1634–1646 DOI: 10.1021/ic9020299 Supporting Info

The Modular Nature of All-Ferrous Edge-Bridged Double Cubanes Mrinmoy Chakrabarti, Liang Deng, R. H. Holm, Eckard Mnck and Emile L. Bominaar pp 1647–1650 DOI: 10.1021/ic902050k Supporting Info

Unprecedented Layered Inorganic−Organic Hybrid Compound Mn3Sb2S6(C6H18N4) Composed of Mn4Sb2S6 Double-Cubane Units Showing Magnetic Long-Range Order and Frustration Zomaje Rejai, Henning Lhmann, Christian Nther, Reinhard K. Kremer and Wolfgang Bensch pp 1651–1657 DOI: 10.1021/ic902053b

Exploring Intertrimer Cu···Cu Interactions and Further Phosphorescent Properties of Aryl Trimer Copper(I) Pyrazolates via Substituent Changing and External Pressure Fangbin Gong, Qian Wang, Jun Chen, Zhipei Yang, Min Liu, Shayu Li and Guoqiang Yang, Ligang Bai, Jing Liu and Yuhui Dong pp 1658–1666 DOI: 10.1021/ic9020417 Supporting Info

Stacked Nickelocenes: Synthesis, Structural Characterization, and Magnetic Properties Sabrina Trtica, Marc Heinrich Prosenc, Michael Schmidt and Jrgen Heck, Ole Albrecht and Detlef Grlitz, Frank Reuter and Eva Rentschler pp 1667–1673 DOI: 10.1021/ic902058n

Facile Synthesis and Luminescence of Sr5(PO4)3Cl:Eu2+ Nanorod Bundles via a Hydrothermal Route Yanhua Song, Hongpeng You, Mei Yang, Yuhua Zheng, Kai Liu, Guang Jia, Yeju Huang, Lihui Zhang and Hongjie Zhang pp 1674–1678 DOI: 10.1021/ic902081r

Facile Fabrication of Hierarchical SnO2 Microspheres Film on Transparent FTO Glass Yu-Fen Wang, Bing-Xin Lei, Yuan-Fang Hou, Wen-Xia Zhao, Chao-Lun Liang, Cheng-Yong Su and Dai-Bin Kuang pp 1679–1686 DOI: 10.1021/ic902092e

Synthesis, Structures, Bonding, and Redox Chemistry of Ditungsten Butadiyne Complexes with W≡C—C≡W Backbones Jibin Sun, Sarah E. Shaner, Marya K. Jones, Daniel C. O’Hanlon, Jeffrey S. Mugridge and Michael D. Hopkins pp 1687–1698 DOI: 10.1021/ic902088x Supporting Info

In-Situ Powder X-ray Diffraction Investigation of Reaction Pathways for the BaCO3−CeO2−In2O3 and CeO2−In2O3 Systems Surinderjit Singh Bhella, Shahid P. Shafi, Francesca Trobec, Mario Bieringer and Venkataraman Thangadurai pp 1699–1704 DOI: 10.1021/ic902104r

A Bioinspired Approach to the Synthesis of Bimetallic CoNi Nanoparticles Natividad Glvez, Elsa Valero, Marcelo Ceolin, Susana Trasobares, Miguel Lpez-Haro, Jos J. Calvino and Jos M. Domnguez-Vera pp 1705–1711 DOI: 10.1021/ic902128g Supporting Info

Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds Rachel S. Crees, Marcus L. Cole, Lyall R. Hanton and Christopher J. Sumby pp 1712–1719 DOI: 10.1021/ic9021118 Supporting Info

Organometallic Trinuclear Niobium Cluster Complex in Aqueous Solution: Synthesis and Characterization of Niobium Complexes Containing Nb3(μ-η2:η2()-NCCH3)(μ2-O)36+ Cluster Core Hans Arni Nybo Joensen, Gro Kallehave Hansson, Svetlana G. Kozlova, Artem L. Gushchin, Inger Stofte and Bee-Lean Ooi pp 1720–1727 DOI: 10.1021/ic9019316 Supporting Info

Heterometallic Ln/Hg Tellurido Clusters Santanu Banerjee, John Sheckelton, Thomas J. Emge and John G. Brennan pp 1728–1732 DOI: 10.1021/ic9021189 Supporting Info

Dihydrogen/Dihydride or Tetrahydride? An Experimental and Computational Investigation of Pincer Iridium Polyhydrides Travis J. Hebden, Karen I. Goldberg, D. Michael Heinekey, Xiawei Zhang, Thomas J. Emge, Alan S. Goldman and Karsten Krogh-Jespersen pp 1733–1742 DOI: 10.1021/ic902163w Supporting Info

Reaction Chemistry of the U3+ Metallocene Amidinate (C5Me5)2[iPrNC(Me)NiPr]U Including the Isolation of a Uranium Complex of a Monodentate Acetate William J. Evans, Justin R. Walensky and Joseph W. Ziller pp 1743–1749 DOI: 10.1021/ic902141f Supporting Info

First-Principles Bottom-Up Study of 1D to 3D Magnetic Transformation in the Copper Pyrazine Dinitrate S = 1/2 Antiferromagnetic Crystal J. Jornet-Somoza, M. Deumal, M. A. Robb, C. P. Landee, M. M. Turnbull, R. Feyerherm and J. J. Novoa pp 1750–1760 DOI: 10.1021/ic902139h Supporting Info

Thermodynamics of Self-Assembly of Copper(II) 15-Metallacrown-5 of Eu(III) or Gd(III) with (S)-α-Alaninehydroxamic Acid in Aqueous Solution Francesco Dallavalle, Maurizio Remelli, Francesco Sansone, Dimitri Bacco and Matteo Tegoni pp 1761–1772 DOI: 10.1021/ic902146d Supporting Info

Mixed Cations and Structural Complexity in (Eu1−xCax)4In3Ge4 and (Eu1−xCax)3In2Ge3—The First Two Members of the Homologous Series A2[n+m]In2n+mGe2[n+m] (n, m = 1, 2, ...∞; A = Ca, Sr, Ba, Eu, or Yb) Tae-Soo You, Paul H. Tobash and Svilen Bobev pp 1773–1783 DOI: 10.1021/ic902144h Supporting Info

The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Complexes and Gold Nanoparticles† Dedicated to Prof. Dr. Hubert Schmidbaur on the occasion of his 75th birthday. Saira Naeem, Lionel Delaude, Andrew J. P. White and James D. E. T. Wilton-Ely pp 1784–1793 DOI: 10.1021/ic9021504 Supporting Info

Luminescence Change by the Solvent of Crystallization, Solvent Reorganization, and Vapochromism of Neutral Dicyanoruthenium(II) Complex in the Solid State Taichi Abe, Takayoshi Suzuki and Kazuteru Shinozaki pp 1794–1800 DOI: 10.1021/ic9021596 Supporting Info

Electronic Structures of PdII Dimers John E. Bercaw, Alec C. Durrell, Harry B. Gray, Jennifer C. Green, Nilay Hazari, Jay A. Labinger and Jay R. Winkler pp 1801–1810 DOI: 10.1021/ic902189g Supporting Info

Nanocluster Model of Intermetallic Compounds with Giant Unit Cells: β, β′-Mg2Al3 Polymorphs Vladislav A. Blatov, Gregory D. Ilyushin and Davide M. Proserpio pp 1811–1818 DOI: 10.1021/ic9021933 Supporting Info

Cation Controlled Assembly and Transformation of Mono- and Bi-Sulfite Templated Dawson-Type Polyoxotungstates Jun Yan, De-Liang Long, Haralampos N. Miras and Leroy Cronin pp 1819–1825 DOI: 10.1021/ic9021646 Supporting Info

3d−3d−4f Chain Complexes Constructed Using the Dinuclear Metallacyclic Complex [Ni2(mbpb)3]2− [H2mbpb = 1,3-Bis(pyridine-2-carboxamide)benzene] as a Ligand: Synthesis, Structures, and Magnetic Properties Enrique Colacio, Mara A. Palacios, Antonio Rodrguez-Diguez, Antonio J. Mota, Juan Manuel Herrera, Duane Choquesillo-Lazarte and Rodolphe Clrac pp 1826–1833 DOI: 10.1021/ic9021867 Supporting Info

Heterobimetallic Metal-Complex Assemblies Constructed from the Flexible Arm-Like Ligand 1,1′-Bis[(3-pyridylamino)carbonyl]ferrocene: Structural Versatility in the Solid State Kai-Ju Wei, Jia Ni and Yangzhong Liu pp 1834–1848 DOI: 10.1021/ic9021855 Supporting Info

Calibration of Scalar Relativistic Density Functional Theory for the Calculation of Sulfur K-Edge X-ray Absorption Spectra Serena DeBeer George and Frank Neese pp 1849–1853 DOI: 10.1021/ic902202s Supporting Info

Binding of Nitric Oxide to a Synthetic Model of Iron-Containing Nitrile Hydratase (Fe-NHase) and Its Photorelease: Relevance to Photoregulation of Fe-NHase by NO Michael J. Rose, Nolan M. Betterley, Allen G. Oliver and Pradip K. Mascharak pp 1854–1864 DOI: 10.1021/ic902220a Supporting Info

Unique (3,12)-Connected Porous Lanthanide−Organic Frameworks Based on Ln4O4 Clusters: Synthesis, Crystal Structures, Luminescence, and Magnetism Xia Li, Hao-Ling Sun, Xiao-Shuo Wu, Xiao Qiu and Miao Du pp 1865–1871 DOI: 10.1021/ic902241n Supporting Info

Design and Synthesis of Sn-Porphyrin Based Molecular Gates Aurlie Guenet, Ernest Graf, Nathalie Kyritsakas and Mir Wais Hosseini pp 1872–1883 DOI: 10.1021/ic902265e Supporting Info

Versatile New Bis(thiosemicarbazone) Bifunctional Chelators: Synthesis, Conjugation to Bombesin(7−14)-NH2, and Copper-64 Radiolabeling Brett M. Paterson, John A. Karas, Denis B. Scanlon, Jonathan M. White and Paul S. Donnelly pp 1884–1893 DOI: 10.1021/ic902204e Supporting Info

Hybrid Organic/Inorganic Complexes Based on Electroactive Tetrathiafulvalene-Functionalized Diphosphanes Tethered to C3-Symmetrized Mo3Q4 (Q = S, Se) Clusters Narcis Avarvari, Kaplan Kiracki, Rosa Llusar, Victor Polo, Ivan Sorribes and Cristian Vicent pp 1894–1904 DOI: 10.1021/ic902244m Supporting Info

Syntheses, Structures, and Magnetic Properties of Heterobimetallic Clusters with Tricyanometalate and π-Conjugated Ligands Containing 1,3-Dithiol-2-ylidene Yan-Hong Peng, Yi-Fei Meng, Liang Hu, Quan-Xiu Li, Yi-Zhi Li, Jing-Lin Zuo and Xiao-Zeng You pp 1905–1912 DOI: 10.1021/ic9023713 Supporting Info

New, Simple Synthetic Route to Functional Mono- and Biferrocenes Abdou Khadri Diallo, Jaime Ruiz and Didier Astruc pp 1913–1920 DOI: 10.1021/ic902332q Supporting Info

X-Ray Diffraction and μ-Raman Investigation of the Monoclinic-Orthorhombic Phase Transition in Th1−xUx(C2O4)2·2H2O Solid Solutions Nicolas Clavier, Nina Hingant, Murielle Rivenet, Sad Obbade, Nicolas Dacheux, Nicole Barr and Francis Abraham pp 1921–1931 DOI: 10.1021/ic902343r Supporting Info

High-Frequency Electron Paramagnetic Resonance Analysis of the Oxidation State and Local Structure of Ni and Mn Ions in Ni,Mn-Codoped LiCoO2 R. Stoyanova, A.-L. Barra, M. Yoncheva, E. Zhecheva, E. Shinova, P. Tzvetkova and S. Simova pp 1932–1941 DOI: 10.1021/ic902351u

Hydrothermal Synthesis of Ytterbium Silicate Nanoparticles Hongfei Chen, Yanfeng Gao, Yun Liu and Hongjie Luo pp 1942–1946 DOI: 10.1021/ic9023585 Supporting Info

Experimental and Theoretical Studies on Photophysical Properties: Tuning Redox-Active Amido-Tetrathiafulvalene Derivatives in Paramagnetic Coordination Complexes Fabrice Pointillart, Thomas Cauchy, Yann Le Gal, Stphane Golhen, Olivier Cador and Lahcne Ouahab pp 1947–1960 DOI: 10.1021/ic9023426 Supporting Info

Possibilities for Titanium−Titanium Multiple Bonding in Binuclear Cyclopentadienyltitanium Carbonyls: 16-Electron Metal Configurations and Four-Electron Donor Bridging Carbonyl Groups as Alternatives Xiuhui Zhang, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 1961–1975 DOI: 10.1021/ic902395v Supporting Info

A Family of Heteroleptic Titanium Guanidinates: Synthesis, Thermolysis, and Surface Reactivity Yamile A. Wasslen, Eva Tois, Suvi Haukka, Kevin A. Kreisel, Glenn P. A. Yap, Mathew D. Halls and Sen T. Barry pp 1976–1982 DOI: 10.1021/ic902411h Supporting Info

Efficient Syntheses of 5-X-B10H13 Halodecaboranes via the Photochemical (X = I) and/or Base-Catalyzed (X = Cl, Br, I) Isomerization Reactions of 6-X-B10H13 William C. Ewing, Patrick J. Carroll and Larry G. Sneddon pp 1983–1994 DOI: 10.1021/ic9024487 Supporting Info

Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide and Lanthanoid-Actinide Complexes Possessing Redox-Active Bridging Ligands Eric J. Schelter, Ruilian Wu, Jacqueline M. Veauthier, Eric D. Bauer, Corwin H. Booth, Robert K. Thomson, Christopher R. Graves, Kevin D. John, Brian L. Scott, Joe D. Thompson, David E. Morris and Jaqueline L. Kiplinger pp 1995–2007 DOI: 10.1021/ic9024475 Supporting Info

Synthetic and Computational Studies on Factors Controlling Structures of Molecular Triangles and Squares and Their Equilibrium in Solutions Kazuhiro Uehara, Ko Kasai and Noritaka Mizuno pp 2008–2015 DOI: 10.1021/ic100011a Supporting Info

Issue 05

Niobium-Complex-Based Syntheses of Sodium Niobate Nanowires Possessing Superior Photocatalytic Properties Kenji Saito and Akihiko Kudo pp 2017–2019 DOI: 10.1021/ic902107u Supporting Info

Silver-Guided Excimer Emission in an Adenine−Pyrene Conjugate: Fluorescence Lifetime and Crystal Studies Mrituanjay D. Pandey, Ashutosh Kumar Mishra, Vadapalli Chandrasekhar and Sandeep Verma pp 2020–2022 DOI: 10.1021/ic9022008 Supporting Info

Dinuclear [{Fe(NO)2}10−{Fe(NO)2}10] Dinitrosyl Iron Complex with Thiolate−CO-Bridged Ligands Chien-Hong Chen, Show-Jen Chiou and Hsuan-Yin Chen pp 2023–2025 DOI: 10.1021/ic902324d Supporting Info

Platinum Complexes of η2-Thiophenes Runyu Tan and Datong Song pp 2026–2028 DOI: 10.1021/ic902289h Supporting Info

Synthesis and Reactivity of Catecholate Complexes Containing Quadruply Bonded Metal Ions Jason Christ, Corinne Epps, Victoria Pritchard, Derek Schmeh, Cortlandt Pierpont and Ebbe Nordlander pp 2029–2031 DOI: 10.1021/ic902328m Supporting Info

Stable Eight-Coordinate Iron(III/II) Complexes Ashis K. Patra, Koustubh S. Dube, Georgia C. Papaefthymiou, Jeanet Conradie, Abhik Ghosh and Todd C. Harrop pp 2032–2034 DOI: 10.1021/ic1001336 Supporting Info

Europium Complexes of a Novel Ethylenedioxythiophene-Derivatized Bis(pyrazolyl)pyridine Ligand Exhibiting Efficient Lanthanide Sensitization Julie M. Stanley, Xunjin Zhu, Xiaoping Yang and Bradley J. Holliday pp 2035–2037 DOI: 10.1021/ic902481y Supporting Info

Computational Study of Methane C−H Activation by First-Row Late Transition Metal LnM═E (M: Fe, Co, Ni) Complexes Aaron W. Pierpont and Thomas R. Cundari pp 2038–2046 DOI: 10.1021/ic901250z Supporting Info

Bimetallic Materials Derived from Manganese(III) Schiff Base Complexes and Pentacyanidonitrosylferrate(II) Precursor: Structures and Magnetic Properties Chun Yang, Qing-Lun Wang, Yue Ma, Guo-Tao Tang, Dai-Zheng Liao, Shi-Ping Yan, Guang-Ming Yang and Peng Cheng pp 2047–2056 DOI: 10.1021/ic901600v Supporting Info

Axial Ligand Orientations in a Distorted Porphyrin Macrocycle: Synthesis, Structure, and Properties of Low-Spin Bis(imidazole)iron(III) and Iron(II) Porphyrinates† Dedicated to Prof. Animesh Chakravorty on the occasion of his 75th birthday. Ranjan Patra, Arvind Chaudhary, Sudip Kumar Ghosh and Sankar Prasad Rath pp 2057–2067 DOI: 10.1021/ic9016504 Supporting Info

Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2− Cluster Anion Patrina Paraskevopoulou, Christodoulos Makedonas, Nikolaos Psaroudakis, Christiana A. Mitsopoulou, Georgios Floros, Andriana Seressioti, Marinos Ioannou, Yiannis Sanakis, Nigam Rath, Carlos J. Gmez Garca, Pericles Stavropoulos and Konstantinos Mertis pp 2068–2076 DOI: 10.1021/ic901432j Supporting Info

Crystal and Electronic Structure of a Mixed-Valent Np(IV)−Np(V) Compound: [BuMeIm]5[Np(NpO2)3(H2O)6Cl12] Iraida Charushnikova, Emilie Boss, Dominique Guillaumont and Philippe Moisy pp 2077–2082 DOI: 10.1021/ic901526e Supporting Info

Formation of a Cobalt(III)−Phenoxyl Radical Complex by Acetic Acid Promoted Aerobic Oxidation of a Co(II)salen Complex Evi Vinck, Damien M. Murphy, Ian A. Fallis, Robert R. Strevens and Sabine Van Doorslaer pp 2083–2092 DOI: 10.1021/ic901849e Supporting Info

A Star-Shaped Heteronuclear CrIIIMnII3 Species and Its Precise Electronic and Magnetic Structure: Spin Frustration Studied by X-Ray Spectroscopic, Magnetic, and Theoretical Methods Manuel Prinz, Karsten Kuepper, Christian Taubitz, Michael Raekers, Sumit Khanra, Biplab Biswas, Thomas Weyhermller, Marc Uhlarz, Joachim Wosnitza, Jrgen Schnack, Andrei V. Postnikov, Christian Schrder, Simon J. George, Manfred Neumann and Phalguni Chaudhuri pp 2093–2102 DOI: 10.1021/ic9012119

Irreversible Insertion of Benzonitrile into Platinum(II)−Nitrogen Bonds of Nucleobase Complexes. Synthesis and Structural Characterization of Stable Azametallacycle Compounds Diego Montagner, Alfonso Venzo, Ennio Zangrando and Bruno Longato pp 2103–2110 DOI: 10.1021/ic901508w Supporting Info

Reactions of a Phosphinoaldehyde with PdII, RhI, and IrI Precursors, Including the Formation of Complexes Containing a P,OH-Chelated Phosphinohemiacetal Ligand: a New Bonding Mode Fabio Lorenzini, Dmitry Moiseev, Brian O. Patrick and Brian R. James pp 2111–2122 DOI: 10.1021/ic9015993 Supporting Info

Several Novel N-Donor Tridentate Ligands Formed in Chemical Studies of New fac-Re(CO)3 Complexes Relevant to fac-99mTc(CO)3 Radiopharmaceuticals: Attack of a Terminal Amine on Coordinated Acetonitrile Theshini Perera, Patricia A. Marzilli, Frank R. Fronczek and Luigi G. Marzilli pp 2123–2131 DOI: 10.1021/ic901705x Supporting Info

Structural and Dynamical Aspects of the Unsymmetric Hydration of Sb(III): An ab initio Quantum Mechanical Charge Field Molecular Dynamics Simulation Len Herald V. Lim, Anirban Bhattacharjee, S. Sikander Asam, Thomas S. Hofer, Bernhard R. Randolf and Bernd M. Rode pp 2132–2140 DOI: 10.1021/ic901737y

Modulation of Multimetal Complexation Behavior of Tetraoxime Ligand by Covalent Transformation of Olefinic Functionalities Shigehisa Akine, Satoko Kagiyama and Tatsuya Nabeshima pp 2141–2152 DOI: 10.1021/ic9019926 Supporting Info

Assembling Discrete D4R Zeolite SBUs through Noncovalent Interactions. 3. Mediation by Butanols and 1,2-Bis(dimethylamino)ethane Ramaswamy Murugavel, Subramaniam Kuppuswamy, Nayanmoni Gogoi and Alexander Steiner pp 2153–2162 DOI: 10.1021/ic901932r Supporting Info

Syntheses and Structures of Cationic and Neutral, Homo- and Heteroleptic tert-Butoxides of the Group 4 Metals Edmond Y. Njua, Alexander Steiner and Lothar Stahl pp 2163–2172 DOI: 10.1021/ic9019537 Supporting Info

Interactions of Diorganolead(IV) with 3-(2-Thienyl)-2-sulfanylpropenoic Acid and/or Thiamine: Chemical and in Vitro and in Vivo Toxicological Results Jos S. Casas, M. Victoria Castao, Agustn Snchez, Jos Sordo, M. Dolores Torres, Mara D. Couce, Angeles Gato, Carmen lvarez-Lorenzo, M. Flix Camia and Eduardo E. Castellano pp 2173–2181 DOI: 10.1021/ic901961g Supporting Info

Coordination Abilities of a Fragment Containing D1 and H12 Residues of Neuropeptide γ and Products of Metal-Catalyzed Oxidation Teresa Kowalik-Jankowska, Elbieta Jankowska and Franciszek Kasprzykowski pp 2182–2192 DOI: 10.1021/ic902021j Supporting Info

Two-Step Assembly of Multinuclear Metallacycles with Half-Sandwich Ir, Rh, and Ru Fragments for Counteranion Encapsulation Guo-Liang Wang, Yue-Jian Lin, Heinz Berke and Guo-Xin Jin pp 2193–2201 DOI: 10.1021/ic902011v Supporting Info

Insight into Water Oxidation by Mononuclear Polypyridyl Ru Catalysts Derek J. Wasylenko, Chelladurai Ganesamoorthy, Bryan D. Koivisto, Matthew A. Henderson and Curtis P. Berlinguette pp 2202–2209 DOI: 10.1021/ic902024s Supporting Info

Spectroscopic and Luminescence Studies on Square-Planar Platinum(II) Complexes with Anionic Tridentate 3-Bis(2-pyridylimino)isoindoline Derivatives Hui-Min Wen, Yu-Hui Wu, Yang Fan, Li-Yi Zhang, Chang-Neng Chen and Zhong-Ning Chen pp 2210–2221 DOI: 10.1021/ic902019s Supporting Info

Steric Control of Coordination Geometry in Titanium-Imido Complexes of N,N′-bis(arylimino)acenaphthylene Ligands Kensha Marie Clark, Joseph W. Ziller and Alan F. Heyduk pp 2222–2231 DOI: 10.1021/ic902101z Supporting Info

Hydrolysis of Bis(p-nitrophenyl)phosphate by Tetravalent Metal Complexes with Klui’s Oxygen Tripodal Ligand Xiao-Yi Yi, Tony C. H. Lam, Ian D. Williams and Wa-Hung Leung pp 2232–2238 DOI: 10.1021/ic902018u Supporting Info

Use of Perfluorinated Phosphines to Provide Thermomorphic Anticancer Complexes for Heat-Based Tumor Targeting Anna K. Renfrew, Rosario Scopelliti and Paul J. Dyson pp 2239–2246 DOI: 10.1021/ic9020433 Supporting Info

Spectroscopic Characterization of Alumina-Supported Bis(allyl)iridium Complexes: Site-Isolation, Reactivity, and Decomposition Studies Ryan J. Trovitch, Neng Guo, Michael T. Janicke, Hongbo Li, Christopher L. Marshall, Jeffrey T. Miller, Alfred P. Sattelberger, Kevin D. John and R. Thomas Baker pp 2247–2258 DOI: 10.1021/ic9021036 Supporting Info

First Structural and Magnetic Studies of Ni Clusters Containing 2,6-Diacetylpyridine-dioxime as a Ligand Albert Escuer, Jordi Esteban, Nria Aliaga-Alcalde, Merc Font-Bardia, Teresa Calvet, Olivier Roubeau and Simon J. Teat pp 2259–2266 DOI: 10.1021/ic9020965 Supporting Info

Temperature-Dependent Synthetic Routes to and Thermochemical Ranking of α- and β-SrNCN Michael Krings, Michael Wessel, Wolfgang Wilsmann, Paul Mller and Richard Dronskowski pp 2267–2272 DOI: 10.1021/ic902065q

Design, Synthesis, Photophysics, and Ion-binding Studies of a Ditopic Receptor Based on Gold(I) Phosphine Thiolate Complex Functionalized with Crown Ether and Urea Binding Units Xiaoming He and Vivian Wing-Wah Yam pp 2273–2279 DOI: 10.1021/ic9021068

Metal−Metal Bonding in Binuclear Metal Carbonyls with Three Bridging Methylaminobis(difluorophosphine) Ligands: Iron, Cobalt, and Nickel Derivatives Rong Zou, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 2280–2289 DOI: 10.1021/ic902133g Supporting Info

Structures and Phase Transitions in (MoO2)2P2O7 Sarah E. Lister, Anne Soleilhavoup, Ray L. Withers, Paul Hodgkinson and John S. O. Evans pp 2290–2301 DOI: 10.1021/ic902166j Supporting Info

Ultrathin SnO2 Nanorods: Template- and Surfactant-Free Solution Phase Synthesis, Growth Mechanism, Optical, Gas-Sensing, and Surface Adsorption Properties Guangcheng Xi and Jinhua Ye pp 2302–2309 DOI: 10.1021/ic902131a

Temperature Switch of LMCT Role: From Quenching to Sensitization of Europium Emission in a ZnII−EuIII Binuclear Complex Traian D. Pasatoiu, Augustin M. Madalan, Michael U. Kumke, Carmen Tiseanu and Marius Andruh pp 2310–2315 DOI: 10.1021/ic902169s Supporting Info

Synthesis and Characterization of Three Ytterbium Coordination Polymers Featuring Various Cationic Species and a Luminescence Study of a Terbium Analogue With Open Channels You-Wen Lin, Bo-Ren Jian, Sin-Chiang Huang, Chin-Her Huang and Kuei-Fang Hsu pp 2316–2324 DOI: 10.1021/ic9021992 Supporting Info

Ternary Rare-Earth Iron Arsenides RE12Fe57.5As41 (RE = La, Ce) Stanislav S. Stoyko, Peter E. R. Blanchard and Arthur Mar pp 2325–2333 DOI: 10.1021/ic902231b Supporting Info

Monometallic and Bimetallic Ruthenium(II) Complexes Derived from 4,5-Bis(benzimidazol-2-yl)imidazole (H3Imbzim) and 2,2′-Bipyridine as Colorimetric Sensors for Anions: Synthesis, Characterization, and Binding Studies Debasish Saha, Shyamal Das, Chanchal Bhaumik, Supriya Dutta and Sujoy Baitalik pp 2334–2348 DOI: 10.1021/ic9022272 Supporting Info

Molecular Structure and Electrochemical Behavior of Uranyl(VI) Complex with Pentadentate Schiff Base Ligand: Prevention of Uranyl(V) Cation−Cation Interaction by Fully Chelating Equatorial Coordination Sites Koichiro Takao, Masaru Kato, Shinobu Takao, Akira Nagasawa, Gert Bernhard, Christoph Hennig and Yasuhisa Ikeda pp 2349–2359 DOI: 10.1021/ic902225f Supporting Info

Ring-Opening Polymerization of Lactides Catalyzed by Natural Amino-Acid Based Zinc Catalysts Donald J. Darensbourg and Osit Karroonnirun pp 2360–2371 DOI: 10.1021/ic902271x Supporting Info

Heterometallic Chains and Clusters with Gold-Transition Metal Bonds: Synthesis and Interconversion Sabrina Sculfort, Richard Welter and Pierre Braunstein pp 2372–2382 DOI: 10.1021/ic902245v Supporting Info

Synthesis and Reactivity of Oxo-Peroxo-Vanadium(V) Bipyridine Compounds Christopher R. Waidmann, Antonio G. DiPasquale and James M. Mayer pp 2383–2391 DOI: 10.1021/ic9022618 Supporting Info

Novel Layered Hybrid Fluoroaluminate in the Composition Space Diagram of the Al(OH)3-HguaCl-HFaq-EtOH System Karim Adil, Armel Le Bail, Marc Leblanc and Vincent Maisonneuve pp 2392–2397 DOI: 10.1021/ic9022882 Supporting Info

Oxygenation of Cobalt Porphyrinates: Coordination or Oxidation? Jianfeng Li, Bruce C. Noll, Allen G. Oliver, Guillermo Ferraudi, A. Graham Lappin and W. Robert Scheidt pp 2398–2406 DOI: 10.1021/ic902309f Supporting Info

Synthesis, Crystal Structure, and Photoluminescence of Homodinuclear Lanthanide 4-(Dibenzylamino)benzoate Complexes A. R. Ramya, M. L. P. Reddy, Alan H. Cowley and Kalyan V. Vasudevan pp 2407–2415 DOI: 10.1021/ic902257u Supporting Info

Synthesis and Characterization of New Coordination Polymers with Tunable Luminescent Properties Generated from Bent 1,2,4-Triazole-Bridged N,N′-Dioxides and Ln(III) Salts Hai-Ying Wang, Jun-Yan Cheng, Jian-Ping Ma, Yu-Bin Dong and Ru-Qi Huang pp 2416–2426 DOI: 10.1021/ic902311g Supporting Info

Discrete Tetrairon(III) Cluster Exhibiting a Square-Planar Fe4(μ4-O) Core: Structural and Magnetic Properties Mariappan Murali, Sanjit Nayak, Jos Snchez Costa, Joan Ribas, Ilpo Mutikainen, Urho Turpeinen, Martin Clmancey, Ricardo Garcia-Serres, Jean-Marc Latour, Patrick Gamez, Genevive Blondin and Jan Reedijk pp 2427–2434 DOI: 10.1021/ic902360x Supporting Info

Rare-Earth Metal Alkyl, Amido, and Cyclopentadienyl Complexes Supported by Imidazolin-2-iminato Ligands: Synthesis, Structural Characterization, and Catalytic Application Alexandra G. Trambitas, Tarun K. Panda, Jelena Jenter, Peter W. Roesky, Constantin Daniliuc, Cristian G. Hrib, Peter G. Jones and Matthias Tamm pp 2435–2446 DOI: 10.1021/ic9024052 Supporting Info

Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 8. Central (ZnII, CuII, MgII(H2O), CdII) and Exocyclic (PdII) Metal Ion Binding in Heteropentametallic Complexes from Tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazine Maria Pia Donzello, Elisa Viola, Xiaohui Cai, Luisa Mannina, Claudio Ercolani and Karl M. Kadish pp 2447–2456 DOI: 10.1021/ic902317h Supporting Info

Lanthanide Complexes of Boraamidinate Ligands: Synthesis and X-ray Structures of {[Li(THF)4][bamLnCl2(THF)]}2 (bam = [PhB(NDipp)2]2−; Ln = Y, Pr, Nd, Sm, Ho, Er, Yb) and {bamLnCl(THF)2}2 (Ln = Y, Sm) Andrea M. Corrente and Tristram Chivers pp 2457–2463 DOI: 10.1021/ic9023184 Supporting Info

Theoretical Study on Activation and Protonation of Dinitrogen on Cubane-Type MIr3S4 Clusters (M = V, Cr, Mn, Fe, Co, Ni, Cu, Mo, Ru, and W) Hiromasa Tanaka, Fumihiro Ohsako, Hidetake Seino, Yasushi Mizobe and Kazunari Yoshizawa pp 2464–2470 DOI: 10.1021/ic902414n Supporting Info

Epoxidation of Alkenes with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate and Kinetic, Spectroscopic, and Theoretical Investigation of the Mechanism Keigo Kamata, Ryo Ishimoto, Tomohisa Hirano, Shinjiro Kuzuya, Kazuhiro Uehara and Noritaka Mizuno pp 2471–2478 DOI: 10.1021/ic902381b Supporting Info

Oxovanadium(IV) Silsesquioxane Complexes Christian Ohde, Christian Limberg, Reinhard Stsser and Serhiy Demeshko pp 2479–2485 DOI: 10.1021/ic902392y Supporting Info

Synthesis, Crystal Structures, and Physical Properties of the Novel CaxR17−xMo19O46 (4 ≤ x ≤ 7; R = Ce, Pr, Sm, and Gd) Compounds Containing Centered Mo19 ν2-Octahedral Clusters N. Barrier, P. Gall, T. Guizouarn and P. Gougeon pp 2486–2491 DOI: 10.1021/ic902394m Supporting Info

Antiferromagnetic Interaction between A′-Site Mn Spins in A-Site-Ordered Perovskite YMn3Al4O12 Takenori Tohyama, Takashi Saito, Masaichiro Mizumaki, Akane Agui and Yuichi Shimakawa pp 2492–2495 DOI: 10.1021/ic9024876

Effect of Electron-Withdrawing Dithiolate Bridge on the Electron-Transfer Steps in Diiron Molecules Related to [2Fe]H Subsite of the [FeFe]-Hydrogenases Kvin Charreteur, Mohamed Kdider, Jean-Franois Capon, Frdric Gloaguen, Franois Y. Ptillon, Philippe Schollhammer and Jean Talarmin pp 2496–2501 DOI: 10.1021/ic902401k Supporting Info

Electrooxidation of [(η5-C5H5)Fe(CO)2]2 As a Probe of the Nucleophilic Properties of Ionic Liquid Anions Angel A. J. Torriero, Muhammad J. A. Shiddiky, John P. Bullock, John F. Boas, Douglas R. MacFarlane and Alan M. Bond pp 2502–2511 DOI: 10.1021/ic9025238 Supporting Info

Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion Graham T. Sazama and Theodore A. Betley pp 2512–2524 DOI: 10.1021/ic100028y Supporting Info

Spin Canting and Slow Relaxation in a 3D Pillared Nickel−Organic Framework Fu-Ping Huang, Jin-Lei Tian, Dong-Dong Li, Gong-Jun Chen, Wen Gu, Shi-Ping Yan, Xin Liu, Dai-Zheng Liao and Peng Cheng pp 2525–2529 DOI: 10.1021/ic9024348 Supporting Info

Structure, Photophysical and Electrochemical Properties, Biomolecular Interactions, and Intracellular Uptake of Luminescent Cyclometalated Iridium(III) Dipyridoquinoxaline Complexes Kenneth Yin Zhang, Steve Po-Yam Li, Nianyong Zhu, Iyana Wai-Shan Or, Maggie Shau-Ha Cheung, Yun-Wah Lam and Kenneth Kam-Wing Lo pp 2530–2540 DOI: 10.1021/ic902465b Supporting Info

Promotive Effect of the Platinum Moiety on the DNA Cleavage Activity of Copper-Based Artificial Nucleases Xindian Dong, Xiaoyong Wang, Miaoxin Lin, Hui Sun, Xiaoliang Yang and Zijian Guo pp 2541–2549 DOI: 10.1021/ic100001x Supporting Info

Syntheses and Characterizations of Cs2Cr3(BP4O14)(P4O13) and CsFe(BP3O11) Compounds with Novel Borophosphate Anionic Partial Structures Weilong Zhang, Wendan Cheng, Hao Zhang, Lei Geng, Yeyu Li, Chensheng Lin and Zhangzhen He pp 2550–2556 DOI: 10.1021/ic902463t Supporting Info

Does the MgO(100)-Support Facilitate the Reaction of Nitrogen and Hydrogen Molecules Catalyzed by Zr2Pd2 Clusters? A Computational Study Aleksey E. Kuznetsov and Djamaladdin G. Musaev pp 2557–2567 DOI: 10.1021/ic902531p Supporting Info

La2U2Se9: An Ordered Lanthanide/Actinide Chalcogenide with a Novel Structure Type Daniel E. Bugaris, Roy Copping, Tolek Tyliszczak, David K. Shuh and James A. Ibers pp 2568–2575 DOI: 10.1021/ic902503n Supporting Info

Corrections to Toward Unidirectional Rotary Motion in Nickelacarboranes: Characterization of Diastereomeric Nickel Bis(Dicarbollide) Complexes Derived from the [Nido-7-CH3-7,8-C2B9H11]− Anion Robert D. Kennedy, Carolyn B. Knobler and M. Frederick Hawthorne p 2576 DOI: 10.1021/ic100051j

Issue 06

Single Crystals of Rb4C60: Synthesis and Structure Determination Stefan Hoffmann, Deepa Kasinathan and Thomas F. Fssler pp 2577–2579 DOI: 10.1021/ic902168u Supporting Info

Heterodinuclear FeIIIZnII-Bioinspired Complex Supported on 3-Aminopropyl Silica. Efficient Hydrolysis of Phosphate Diester Bonds Clovis Piovezan, Rafael Jovito, Adailton J. Bortoluzzi, Hernn Terenzi, Franciele L. Fischer, Patricia C. Severino, Claus T. Pich, Gisele G. Azzolini, Rosely A. Peralta, Liane M. Rossi and Ademir Neves pp 2580–2582 DOI: 10.1021/ic902489j Supporting Info

Metal-Controlled Assembly of Near-Infrared-Emitting Pentanuclear Lanthanide β-Diketone Clusters Xiao-Yan Chen, Xiaoping Yang and Bradley J. Holliday pp 2583–2585 DOI: 10.1021/ic902513z Supporting Info

Four-Coordinate AsIII-N,S Complexes: Synthesis, Structure, Properties, and Biological Relevance Vivian C. Ezeh, Ashis K. Patra and Todd C. Harrop pp 2586–2588 DOI: 10.1021/ic9025969 Supporting Info

MRI Sensing Based on the Displacement of Paramagnetic Ions from Chelated Complexes Tatjana Atanasijevic, Xiao-an Zhang, Stephen J. Lippard and Alan Jasanoff pp 2589–2591 DOI: 10.1021/ic100150e Supporting Info

Soluble Heterometallic Coordination Polymers Based on a Bis-terpyridine-Functionalized Dioxocyclam Ligand Aurlien Gasnier, Jean-Michel Barbe, Christophe Bucher, Carole Duboc, Jean-Claude Moutet, Eric Saint-Aman, Pierre Terech and Guy Royal pp 2592–2599 DOI: 10.1021/ic901832q

Hierarchical Assembly of Extended Coordination Networks Constructed by Novel Metallacalix[4]arenes Building Blocks Xia Li, Benlai Wu, Ruiying Wang, Hongyun Zhang, Caoyuan Niu, Yunyin Niu and Hongwei Hou pp 2600–2613 DOI: 10.1021/ic901113p Supporting Info

Syntheses, Characterization, and Photophysical Properties of Conjugated Organometallic Pt-Acetylide/Zn(II) Porphyrin-Containing Oligomers Feng-Lei Jiang, Daniel Fortin and Pierre D. Harvey pp 2614–2623 DOI: 10.1021/ic901421m Supporting Info

Functionalized O-Alkyldithiocarbonates: A New Class of Ligands Designed for Luminescent Heterometallic Materials Radu F. Semeniuc, Thomas J. Reamer, Jonathan P. Blitz, Kraig A. Wheeler and Mark D. Smith pp 2624–2629 DOI: 10.1021/ic901551t Supporting Info

Revisiting the Thermal Decomposition of Layered γ-Titanium Phosphate and Structural Elucidation of Its Intermediate Phases Santiago Garca-Granda, Sergei A. Khainakov, Aranzazu Espina and Jos R. Garca, Germn R. Castro, Joo Rocha and Lus Mafra pp 2630–2638 DOI: 10.1021/ic901254j Supporting Info

Evaluating Binuclear Copper(II) Complexes for Glycoside Hydrolysis Susanne Striegler, Natasha A. Dunaway, Moses G. Gichinga, James D. Barnett and Anna-Gay D. Nelson pp 2639–2648 DOI: 10.1021/ic9014064 Supporting Info

Redox Induced Electron Transfer in Doublet Azo-Anion Diradical Rhenium(II) Complexes. Characterization of Complete Electron Transfer Series Nandadulal Paul, Subhas Samanta and Sreebrata Goswami pp 2649–2655 DOI: 10.1021/ic9016195 Supporting Info

Structural Variety within Gallium Diphosphonates Affected by the Organic Linker Length Martin P. Attfield, Zhanhui Yuan, Howard G. Harvey and William Clegg pp 2656–2666 DOI: 10.1021/ic901651d Supporting Info

Reactions of Hydridochlorosilanes with 2,2′-Bipyridine and 1,10-Phenanthroline: Complexation versus Dismutation and Metal-Catalyst-Free 1,4-Hydrosilylation Gerrit W. Fester, Jana Eckstein, Daniela Gerlach, Jrg Wagler, Erica Brendler and Edwin Kroke pp 2667–2673 DOI: 10.1021/ic901620e Supporting Info

First Actinide Complexes of the Nitrogen-Containing Ligands Dinitramide (N(NO2)2−), 4,5-Dicyano-1,2,3-triazolate (C4N5−), and Dicyanamide (N(CN)2−) Margaret-Jane Crawford, Arkady Ellern, Konstantin Karaghiosoff, Franz Martin and Peter Mayer pp 2674–2683 DOI: 10.1021/ic901820b Supporting Info

Simple and Efficient Synthesis of a Nd:LaAlO3 NIR Nanophosphor from Rare Earth Alkoxo-Monoaluminates Ln2Al2(OiPr)12(iPrOH)2 Single Source Precursors by Bradley Reaction Robert Pazik, Gulaim A. Seisenbaeva, Suresh Gohil, Rafal Wiglusz, Leszek Kpiski, Wieslaw Strek and Vadim G. Kessler pp 2684–2691 DOI: 10.1021/ic902403f

Sn(IV) Porphyrin Based Axial-Bonding Type Porphyrin Triads Containing Heteroporphyrins as Axial Ligands Vijayendra S. Shetti and Mangalampalli Ravikanth pp 2692–2700 DOI: 10.1021/ic901920y Supporting Info

Electronic Structure of a Paramagnetic {MNO}6 Complex: MnNO 5,5-Tropocoronand Espen Tangen, Jeanet Conradie, Katherine Franz, Simone Friedle, Joshua Telser, Stephen J. Lippard and Abhik Ghosh pp 2701–2705 DOI: 10.1021/ic901860x Supporting Info

Screening of Bimetallic Heterogeneous Nanoparticle Catalysts for Arene Hydrogenation Activity under Ambient Conditions Nicole A. Dehm, Xiaojiang Zhang and Jillian M. Buriak pp 2706–2714 DOI: 10.1021/ic901928j Supporting Info

Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3 L. Wu, J. C. Sun, Y. Zhang, S. F. Jin, Y. F. Kong and J. J. Xu pp 2715–2720 DOI: 10.1021/ic901963t Supporting Info

Cyclometalated Cluster Complex with a Butterfly-Shaped Pt2Ag2 Core Sirous Jamali, Zahra Mazloomi, S. Masoud Nabavizadeh, Dalibor Mili, Reza Kia and Mehdi Rashidi pp 2721–2726 DOI: 10.1021/ic902044g Supporting Info

Electronic Structure Analysis of the Dinuclear Metal Center in the Bioremediator Glycerophosphodiesterase (GpdQ) from Enterobacter aerogenes Kieran S. Hadler, Nataa Miti, Sylvia Hsu-Chen Yip, Lawrence R Gahan, David L. Ollis, Gerhard Schenk and James A. Larrabee pp 2727–2734 DOI: 10.1021/ic901950c Supporting Info

The Theoretical Quest for Sulfate of Ag2+: Genuine Ag(II)SO4, Diamagnetic Ag(I)2S2O8, or Rather Mixed-Valence Ag(I)[Ag(III)(SO4)2]? Mariana Derzsi, Krzysztof Dymkowski and Wojciech Grochala pp 2735–2742 DOI: 10.1021/ic9019734 Supporting Info

New Chelating Ligands Based on S-Organosulfurdiimides: Synthesis and Single Crystal X-ray Structures of their Lithium Complexes Julius Till Enno Meyer, Thomas Schulz, Sushil Kumar Pandey and Dietmar Stalke pp 2743–2749 DOI: 10.1021/ic902071m

Synthesis, Spectral, Structural, Second-Order Nonlinear Optical Properties and Theoretical Studies On New Organometallic Donor−Acceptor Substituted Nickel(II) and Copper(II) Unsymmetrical Schiff-Base Complexes Alexander Trujillo, Mauricio Fuentealba, David Carrillo, Carolina Manzur, Isabelle Ledoux-Rak, Jean-Ren Hamon and Jean-Yves Saillard pp 2750–2764 DOI: 10.1021/ic902126a Supporting Info

Series of MI[Co(bpy)3][Mo(CN)8]·nH2O (MI = Li (1), K (2), Rb (3), Cs (4); n = 7−8) Exhibiting Reversible Diamagnetic to Paramagnetic Transition Coupled with Dehydration−Rehydration Process Marcin Kozieł, Robert Podgajny, Rafał Kania, Rmy Lebris, Corine Mathonire, Krzysztof Lewiski, Krzysztof Kruczała, Michał Rams, Christine Labrugre, Azzedine Bousseksou and Barbara Sieklucka pp 2765–2772 DOI: 10.1021/ic901985z Supporting Info

Ruthenium Intermetallics Grown from La−Ni Flux: Synthesis, Structure, and Physical Properties Julia V. Zaikina, Young-Jung Jo and Susan E. Latturner pp 2773–2781 DOI: 10.1021/ic902151d Supporting Info

Synthesis of Aryl-Substituted Bis(imino)pyridine Iron Dinitrogen Complexes Sarah K. Russell, Jonathan M. Darmon, Emil Lobkovsky and Paul J. Chirik pp 2782–2792 DOI: 10.1021/ic902162z Supporting Info

γ-Deprotonation of Anionic Bis(trimethylsilyl)amidolanthanide Complexes with a Countered [(TpMe2)2Ln]+ Cation Fuyan Han, Jie Zhang, Weiyin Yi, Zhengxing Zhang, Jingyi Yu, Linhong Weng and Xigeng Zhou pp 2793–2798 DOI: 10.1021/ic902296d Supporting Info

Excited State Localization and Internuclear Interactions in Asymmetric Ruthenium(II) and Osmium(II) bpy/tpy Based Dinuclear Compounds Yvonne Halpin, Danilo Dini, Hamid M. Younis Ahmed, Lynda Cassidy, Wesley R. Browne and Johannes G. Vos pp 2799–2807 DOI: 10.1021/ic902140t Supporting Info

Interaction of SbCl52− and Thioether Groups at the Open Coordination Sites of Platinum(II) Diimine Complexes Sayandev Chatterjee, Jeanette A. Krause, William B. Connick, Caroline Genre, Alexandre Rodrigue-Witchel and Christian Reber pp 2808–2815 DOI: 10.1021/ic9021917 Supporting Info

Molecular Geometry of Vanadium Dichloride and Vanadium Trichloride: A Gas-Phase Electron Diffraction and Computational Study Zoltn Varga, Brian Vest, Peter Schwerdtfeger and Magdolna Hargittai pp 2816–2821 DOI: 10.1021/ic902196t Supporting Info

MLi2Ti6O14 (M = Sr, Ba, 2Na) Lithium Insertion Titanate Materials: A Comparative Study Damien Dambournet, Ilias Belharouak and Khalil Amine pp 2822–2826 DOI: 10.1021/ic902222g

Spinel to CaFe2O4 Transformation: Mechanism and Properties of β-CdCr2O4 ngel M. Arvalo-Lpez, Antonio J. Dos santos-Garca, Elizabeth Castillo-Martnez, Alejandro Durn and Miguel . Alario-Franco pp 2827–2833 DOI: 10.1021/ic902228h Supporting Info

Tetranuclear Copper(I) Iodide Complexes of Chelating Bis(1-benzyl-1H-1,2,3-triazole) Ligands: Structural Characterization and Solid State Photoluminescence Gerald F. Manbeck, William W. Brennessel, Christopher M. Evans and Richard Eisenberg pp 2834–2843 DOI: 10.1021/ic902236n Supporting Info

Gas-Phase Thermolysis of a Guanidinate Precursor of Copper Studied by Matrix Isolation, Time-of-Flight Mass Spectrometry, and Computational Chemistry Jason P. Coyle, Paul A. Johnson, Gino A. DiLabio, Sen T. Barry and Jens Mller pp 2844–2850 DOI: 10.1021/ic902247w Supporting Info

Structural, Magnetic, EPR, and Electrochemical Characterizations of a Spin-Frustrated Trinuclear CrIII Polyoxometalate and Study of Its Reactivity with Lanthanum Cations Jean-Daniel Compain, Pierre Mialane, Anne Dolbecq, Isral Martyr Mbomekall, Jrme Marrot, Francis Scheresse, Carole Duboc and Eric Rivire pp 2851–2858 DOI: 10.1021/ic902341w Supporting Info

Hybrid Scorpionate/Cyclopentadienyl Magnesium and Zinc Complexes: Synthesis, Coordination Chemistry, and Ring-Opening Polymerization Studies on Cyclic Esters Andrs Garcs, Luis F. Snchez-Barba, Carlos Alonso-Moreno, Mariano Fajardo, Juan Fernndez-Baeza, Antonio Otero, Agustn Lara-Snchez, Isabel Lpez-Solera and Ana Mara Rodrguez pp 2859–2871 DOI: 10.1021/ic902399r Supporting Info

Synthesis of a Novel Sn(IV) Porphycene−Ferrocene Triad Linked by Axial Coordination and Solvent Polarity Effect in Photoinduced Charge Separation Process Daisuke Maeda, Hisashi Shimakoshi, Masaaki Abe, Mamoru Fujitsuka, Testuro Majima and Yoshio Hisaeda pp 2872–2880 DOI: 10.1021/ic902444x Supporting Info

Chemistry of Vanadaboranes: Synthesis, Structures, and Characterization of Organovanadium Sulfide Clusters with Disulfido Linkage Shubhankar Kumar Bose, K. Geetharani, V. Ramkumar, Babu Varghese and Sundargopal Ghosh pp 2881–2888 DOI: 10.1021/ic9023597 Supporting Info

Photobiological Activity of Ru(II) Dyads Based on (Pyren-1-yl)ethynyl Derivatives of 1,10-Phenanthroline Susan Monro, John Scott, Abdellatif Chouai, Richard Lincoln, Ruifa Zong, Randolph P. Thummel and Sherri A. McFarland pp 2889–2900 DOI: 10.1021/ic902427r

One- and Two-Electron-Transfer Reactions of (dpp-Bian)Sm(dme)3 Igor L. Fedushkin, Olga V. Maslova, Markus Hummert and Herbert Schumann pp 2901–2910 DOI: 10.1021/ic902439x Supporting Info

The Crucial Role of Dispersion in the Cohesion of Nonbridged Binuclear Os → Cr and Os → W Adducts Stefan Grimme and Jean-Pierre Djukic pp 2911–2919 DOI: 10.1021/ic9024662 Supporting Info

Hybrid Polyoxotungstate/MIL-101 Materials: Synthesis, Characterization, and Catalysis of H2O2-Based Alkene Epoxidation Nataliya V. Maksimchuk, Konstantin A. Kovalenko, Sergey S. Arzumanov, Yurii A. Chesalov, Maxim S. Melgunov, Alexander G. Stepanov, Vladimir P. Fedin and Oxana A. Kholdeeva pp 2920–2930 DOI: 10.1021/ic902459f

Two- and Three-Dimensional Open-Framework Uranium Arsenates: Synthesis, Structure, and Characterization V. Koteswara Rao, K. Bharathi, Ramanath Prabhu, Manabendra Chandra and Srinivasan Natarajan pp 2931–2947 DOI: 10.1021/ic902472h Supporting Info

How are Centrosymmetric and Noncentrosymmetric Structures Achieved in Uranyl Borates? Shuao Wang, Evgeny V. Alekseev, Jared T. Stritzinger, Wulf Depmeier and Thomas E. Albrecht-Schmitt pp 2948–2953 DOI: 10.1021/ic902480n Supporting Info

Synthesis and Properties of Tetracyanamidosilicates ARE[Si(CN2)4] Jochen Glaser, Helga Bettentrup, Thomas Jstel and H.-Jrgen Meyer pp 2954–2959 DOI: 10.1021/ic902498p

Synthesis of a Solid Solution Series of Layered EuxGd1−x(OH)2.5Cl0.5·0.9H2O and Its Transformation into (EuxGd1−x)2O3 with Enhanced Photoluminescence Properties Linfeng Hu, Renzhi Ma, Tadashi C. Ozawa and Takayoshi Sasaki pp 2960–2968 DOI: 10.1021/ic902484v Supporting Info

Evaluation of [Ln(H2cmp)(H2O)] Metal Organic Framework Materials for Potential Application as Magnetic Resonance Imaging Contrast Agents Giovannia A. Pereira, Joop A. Peters, Filipe A. Almeida Paz, Joo Rocha and Carlos F. G. C. Geraldes pp 2969–2974 DOI: 10.1021/ic9025014 Supporting Info

Systematic Study of Modifications to Ruthenium(II) Polypyridine Dyads for Electron Injection Enhancement Elena Jakubikova, Richard L. Martin and Enrique R. Batista pp 2975–2982 DOI: 10.1021/ic902504y Supporting Info

Reactions of Organyl and Silyl Alanes with 1,3,4,5,6-Pentamethyl-2-aminoborazine Maomin Fan, Eileen N. Duesler, Heinrich Nth and Robert T. Paine pp 2983–2989 DOI: 10.1021/ic902490z Supporting Info

Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14 Vinna Jo, Min Kyung Kim, Dong Woo Lee, Il-Wun Shim and Kang Min Ok pp 2990–2995 DOI: 10.1021/ic902493r Supporting Info

Major Difference between the Isoelectronic Fluoroborylene and Carbonyl Ligands: Triply Bridging Fluoroborylene Ligands in Fe3(BF)3(CO)9 Isoelectronic with Fe3(CO)12 Liancai Xu, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 2996–3001 DOI: 10.1021/ic902511m Supporting Info

Spectroscopic and Structural Studies of Difluorophosphoryl Azide F2P(O)N3, Difluorophosphoryl Isocyanate F2P(O)NCO, and Difluorophosphoric Acid Anhydride, F2(O)POP(O)F2 Xiaoqing Zeng, Michael Gerken, Helmut Beckers and Helge Willner pp 3002–3010 DOI: 10.1021/ic902524u Supporting Info

Biscarbene Palladium(II) Complexes. Reactivity of Saturated Versus Unsaturated N-Heterocyclic Carbenes Ching-Feng Fu, Chun-Chin Lee, Yi-Hung Liu, Shie-Ming Peng, Stefan Warsink, Cornelis J. Elsevier, Jwu-Ting Chen and Shiuh-Tzung Liu pp 3011–3018 DOI: 10.1021/ic9025188 Supporting Info

Synthesis, Magnetic Structure, and Properties of a Layered Cobalt−Hydroxide Ferromagnet, Co5(OH)6(SeO4)2(H2O)4 Wassim Maalej, Serge Vilminot, Gilles Andr and Mohamedally Kurmoo pp 3019–3024 DOI: 10.1021/ic9025552 Supporting Info

On the Importance of the Interplaquette Spin Exchanges in Na3RuO4: Density Functional Theory Analysis of the Spin Exchange and Magnetic Properties Fang Wu, Erjun Kan and Myung-Hwan Whangbo pp 3025–3028 DOI: 10.1021/ic902568v

Rhodium−Germanium Carbonyl Complexes Richard D. Adams and Eszter Trufan pp 3029–3034 DOI: 10.1021/ic9025848 Supporting Info

Halogen Photoreductive Elimination from Metal−Metal Bonded Iridium(II)−Gold(II) Heterobimetallic Complexes Thomas S. Teets, Daniel A. Lutterman and Daniel G. Nocera pp 3035–3043 DOI: 10.1021/ic902590u Supporting Info

An Alkali-Metal Ion Extracted Layered Compound as a Template for a Metastable Phase Synthesis in a Low-Temperature Solid-State Reaction: Preparation of Brookite from K0.8Ti1.73Li0.27O4 Tadashi C. Ozawa and Takayoshi Sasaki pp 3044–3050 DOI: 10.1021/ic1000182

Large Changes in Electronic Structures of Ru26+ Species Caused by the Variations of the Bite Angle of Guanidinate Ligands: Tuning Magnetic Behavior Gina M. Chiarella, F. Albert Cotton, Carlos A. Murillo, Mark D. Young and Qinliang Zhao pp 3051–3056 DOI: 10.1021/ic100100a Supporting Info

Synthesis, Structure, and Phosphatase-Like Activity of a New Trinuclear Gd Complex with the Unsymmetrical Ligand H3L As a Model for Nucleases Maryene A. Camargo, Ademir Neves, Bruno Szpoganicz, Adailton J. Bortoluzzi, Franciele L. Fischer, Hernn Terenzi and Eduardo E. Castellano pp 3057–3063 DOI: 10.1021/ic100276z Supporting Info

Five-Membered Arsenic−Sulfur−Nitrogen Heterocycles, RAs(S2N2) (R = Me, Et, iPr, tBu, Ph, Mes) Vit Matuska, Alexandra M. Z. Slawin and J. Derek Woollins pp 3064–3069 DOI: 10.1021/ic1000107 Supporting Info

Issue 07

A Water-Soluble Bis(thiosemicarbazone) Ligand. A Sensitive Probe and Metal Buffer for Zinc Gojko Buncic, Paul S. Donnelly, Brett M. Paterson, Jonathan M. White, Matthias Zimmermann, Zhiguang Xiao and Anthony G. Wedd pp 3071–3073 DOI: 10.1021/ic902370a Supporting Info

Synthesis of p-Type Transparent LaOCuS Nanoparticles via Soft Chemistry Charlotte Doussier-Brochard, Benoit Chavillon, Laurent Cario and Stphane Jobic pp 3074–3076 DOI: 10.1021/ic902521r Supporting Info

α-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New MnIII9 Complex Evangelia S. Koumousi, Manolis J. Manos, Christos Lampropoulos, Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, George Christou and Theocharis C. Stamatatos pp 3077–3079 DOI: 10.1021/ic100178y Supporting Info

A Phosphine Gold(I) π-Alkyne Complex: Tuning the Metal−Alkyne Bond Character and Counterion Position by the Choice of the Ancillary Ligand Daniele Zuccaccia, Leonardo Belpassi, Luca Rocchigiani, Francesco Tarantelli and Alceo Macchioni pp 3080–3082 DOI: 10.1021/ic100093n Supporting Info

Epoxidations Catalyzed by Manganese(V) Oxo and Imido Complexes: Role of the Oxidant−Mn−Oxo (Imido) Intermediate Pannee Leeladee and David P. Goldberg pp 3083–3085 DOI: 10.1021/ic902517j Supporting Info

π-Back-Donation Effect of the Cyanide Ligands on the Electron Correlation and Charge Transfer in Prussian Blue RbMn[Fe(CN)6] Chuan Tian, Erjun Kan, Changhoon Lee and Myung-Hwan Whangbo pp 3086–3088 DOI: 10.1021/ic902577r Supporting Info

C76Cl34: High Chlorination of the Inherent Chiral Fullerene with a Helical Configuration Hua Liang, Yuan-Zhi Tan, Ting Zhou, Zhen-Liang Chen, Su-Yuan Xie, Rong-Bin Huang and Lan-Sun Zheng pp 3089–3091 DOI: 10.1021/ic902442p Supporting Info

[P3Se7]3−: A Phosphorus-Rich Square-Ring Selenophosphate In Chung, Daniel Holmes, David P. Weliky and Mercouri G. Kanatzidis pp 3092–3094 DOI: 10.1021/ic902561h Supporting Info

Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes Shahana Chatterjee, Patrick J. Carroll and Larry G. Sneddon pp 3095–3097 DOI: 10.1021/ic100323e Supporting Info

Coordination Studies of Bis-Strapped-Hanging-Carboxylate Porphyrins. X-ray Characterization of a Five-Coordinate Iron(II) Complex with a Built-in Axial Base Ismail Hijazi, Thierry Roisnel, Marc Fourmigu, Jean Weiss and Bernard Boitrel pp 3098–3100 DOI: 10.1021/ic1001072 Supporting Info

Eicosanuclear Cluster [Cu13W7] of Copper-Octacyanotungstate Bimetallic Assembly: Synthesis, Structure, and Magnetic Properties Jun Wang, Zai-Chao Zhang, Hui-Sheng Wang, Ling-Chen Kang, Hong-Bo Zhou, You Song and Xiao-Zeng You pp 3101–3103 DOI: 10.1021/ic100282w Supporting Info

Spectroscopic and Computational Studies of a trans-μ-1,2-Disulfido-Bridged Dinickel Species, [{(tmc)Ni}2(S2)](OTf)2: Comparison of End-on Disulfido and Peroxo Bonding in (NiII)2 and (CuII)2 Species Katherine M. Van Heuvelen, Matthew T. Kieber-Emmons, Charles G. Riordan and Thomas C. Brunold pp 3104–3112 DOI: 10.1021/ic901733h Supporting Info

Spectroscopic and Computational Studies of a μ-η2:η2-Disulfido-Bridged Dinickel(II) Species, [{(PhTttBu)Ni}2(μ-η2:η2-S2)]: Comparison of Side-On Disulfido and Peroxo Bonding in (NiII)2 and (CuII)2 Species Katherine M. Van Heuvelen, Jaeheung Cho, Charles G. Riordan and Thomas C. Brunold pp 3113–3120 DOI: 10.1021/ic901731b Supporting Info

A Unique Nickel System having Versatile Catalytic Activity of Biological Significance Tanmay Chattopadhyay, Madhuparna Mukherjee, Arindam Mondal, Pali Maiti, Arpita Banerjee, Kazi Sabnam Banu, Santanu Bhattacharya, Bappaditya Roy, D. J. Chattopadhyay, Tapan Kumar Mondal, Munirathinam Nethaji, Ennio Zangrando and Debasis Das pp 3121–3129 DOI: 10.1021/ic901546t Supporting Info

Synthesis, Structure, Bonding, and Properties of Sc3Al3O5C2 and ScAl2ONC—Unique Compounds with Ordered Distribution of Anions and Cations Melanie Schroeder, Tobias Schlder, Anna J. Lehner and Harald Hillebrecht pp 3130–3140 DOI: 10.1021/ic901784k

Coordination Modes of Multidentate Ligands in fac-[Re(CO)3(polyaminocarboxylate)] Analogues of 99mTc Radiopharmaceuticals. Dependence on Aqueous Solution Reaction Conditions Malgorzata Lipowska, Haiyang He, Xiaolong Xu, Andrew T. Taylor, Patricia A. Marzilli and Luigi G. Marzilli pp 3141–3151 DOI: 10.1021/ic9017568 Supporting Info

Structural and Electrochemical Studies of Co(III) Cage Amine Complexes with Pendent Thienylmethylamino Groups Jack M. Harrowfield, George A. Koutsantonis, Nigel A. Lengkeek, Brian W. Skelton and Allan H. White pp 3152–3161 DOI: 10.1021/ic9019603 Supporting Info

Magnetic Bistability in a Cobalt Bis(dioxolene) Complex: Long-Lived Photoinduced Valence Tautomerism Robert D. Schmidt, David A. Shultz and James D. Martin pp 3162–3168 DOI: 10.1021/ic901998p Supporting Info

Nucleation of Antiferromagnetically Coupled Chromium Dihalides: from Small Clusters to the Solid State Brian Vest, Andreas Hermann, Peter D. W. Boyd and Peter Schwerdtfeger pp 3169–3182 DOI: 10.1021/ic901949a Supporting Info

Conformationally Modulated Intramolecular Electron Transfer Process in a Diaza[2,2]ferrocenophane Francisco Otn, Imma Ratera, Arturo Espinosa, Alberto Trraga, Jaume Veciana and Pedro Molina pp 3183–3191 DOI: 10.1021/ic902059y Supporting Info

Density Functional Theory Investigations of the Homoleptic Tris(dithiolene) Complexes [M(dddt)3]−q (q = 3, 2 ; M = Nd3+ and U3+/4+) Related to Lanthanide(III)/Actinide(III) Differentiation Samir Meskaldji, Lotfi Belkhiri, Thrse Arliguie, Marc Fourmigu, Michel Ephritikhine and Abdou Boucekkine pp 3192–3200 DOI: 10.1021/ic902135t Supporting Info

Vibrational Analysis of the Model Complex (μ-edt)[Fe(CO)3]2 and Comparison to Iron-Only Hydrogenase: The Activation Scale of Hydrogenase Model Systems Mary Grace I. Galinato, C. Matthew Whaley and Nicolai Lehnert pp 3201–3215 DOI: 10.1021/ic9022135 Supporting Info

Correlation between the Structural Distortions and Thermoelectric Characteristics in La1−xAxCoO3 (A = Ca and Sr) Yang Wang, Yu Sui, Peng Ren, Lan Wang, Xianjie Wang, Wenhui Su and Hong Jin Fan pp 3216–3223 DOI: 10.1021/ic902072v

Mn2+ Complexes with Pyridine-Containing 15-Membered Macrocycles: Thermodynamic, Kinetic, Crystallographic, and 1H/17O Relaxation Studies Bohuslav Draho, Jan Kotek, Petr Hermann, Ivan Luke and va Tth pp 3224–3238 DOI: 10.1021/ic9020756 Supporting Info

Structural and Luminescence Studies on π···π and Pt···Pt Interactions in Mixed Chloro-Isocyanide Cyclometalated Platinum(II) Complexes lvaro Dez, Juan Fornis, Carmen Larraz, Elena Lalinde, Jos A. Lpez, Antonio Martn, M. Teresa Moreno and Violeta Sicilia pp 3239–3251 DOI: 10.1021/ic902094c Supporting Info

Zwitterionic Iridium Complexes: Synthesis, Luminescent Properties, and Their Application in Cell Imaging Weili Jiang, Yuan Gao, Yun Sun, Fei Ding, Yan Xu, Zuqiang Bian, Fuyou Li, Jiang Bian and Chunhui Huang pp 3252–3260 DOI: 10.1021/ic9021239 Supporting Info

Impact of the Carbon Chain Length of Novel Palladium(II) Complexes on Interaction with DNA and Cytotoxic Activity Enjun Gao, Mingchang Zhu, Lei Liu, Yun Huang, Lei Wang, Chuyue Shi, Wanzhong Zhang and Yaguang Sun pp 3261–3270 DOI: 10.1021/ic902176e

Metal Dilution Effects on Entropy and Light-Induced Valence Tautomeric Interconversion in a 1:1 Cobalt−Dioxolene Complex A. Dei, G. Poneti and L. Sorace pp 3271–3277 DOI: 10.1021/ic902255j Supporting Info

Theoretical Revisit of a Fe(CO)5-Catalyzed Water−Gas Shift Reaction Fuli Zhang, Liang Zhao, Chunming Xu and Yu Chen pp 3278–3281 DOI: 10.1021/ic902148y Supporting Info

Inorganic or Organic Azide-Containing Hypergolic Ionic Liquids As poster published in 1st Korean International Symposium on High Energy Materials, Incheon, Korea, October 6−9, 2009. Young-Hyuk Joo, Haixiang Gao, Yanqiang Zhang and Jean’ne M. Shreeve pp 3282–3288 DOI: 10.1021/ic902224t Supporting Info

Hydrogen Scrambling in [(C5R5)(L)M(H)(C2H4)]+ (M = Co, Rh). Relation of Experimental Kinetic Data to the Barriers of the Elementary Reaction Steps Rong Xu, Gnter Klatt, Hubert Wadepohl and Horst Kppel pp 3289–3296 DOI: 10.1021/ic902276a Supporting Info

Interplay between the Crystalline and Magnetic Structures in Lightly Cr-Doped Bi0.37Ca0.63Mn0.96Cr0.04O2.99 Chun-Chuen Yang, Wen-Hsien Li, Chun-Ming Wu, Carissa H. C. Li, Jirong Sun and Jeffrey W. Lynn pp 3297–3304 DOI: 10.1021/ic9022823

Sacrificial Template Method for Fabrication of Submicrometer-Sized YPO4:Eu3+ Hierarchical Hollow Spheres Lihui Zhang, Guang Jia, Hongpeng You, Kai Liu, Mei Yang, Yanhua Song, Yuhua Zheng, Yeju Huang, Ning Guo and Hongjie Zhang pp 3305–3309 DOI: 10.1021/ic9022739 Supporting Info

Controlling the Reactivity of Ruthenium(II) Arene Complexes by Tether Ring-Opening Ana M. Pizarro, Michael Melchart, Abraha Habtemariam, Luca Salassa, Francesca P. A. Fabbiani, Simon Parsons and Peter J. Sadler pp 3310–3319 DOI: 10.1021/ic902243q Supporting Info

Photoelectrochemical Behavior of Sensitized TiO2 Photoanodes in an Aqueous Environment: Application to Hydrogen Production Stefano Caramori, Vito Cristino, Roberto Argazzi, Laura Meda and Carlo A. Bignozzi pp 3320–3328 DOI: 10.1021/ic9023037 Supporting Info

Organically Modified Zirconium Phosphate by Reaction with 1,2-Epoxydodecane as Host Material for Polymer Intercalation: Synthesis and Physicochemical Characterization Mario Casciola, Donatella Capitani, Anna Donnadio, Giorgio Munari and Monica Pica pp 3329–3336 DOI: 10.1021/ic902330n

Comparisons of Pu(IV) and Ce(IV) Diphosphonates Juan Diwu, Anna-Gay D. Nelson, Shuao Wang, Charles F. Campana and Thomas E. Albrecht-Schmitt pp 3337–3342 DOI: 10.1021/ic100184q Supporting Info

Phthalocyanine as a Chemically Inert, Redox-Active Ligand: Structural and Electronic Properties of a Nb(IV)-Oxo Complex Incorporating a Highly Reduced Phthalocyanine(4−) Anion Edwin W. Y. Wong, Charles J. Walsby, Tim Storr and Daniel B. Leznoff pp 3343–3350 DOI: 10.1021/ic902409n Supporting Info

Uranyl Complexes of Carboxyl-Functionalized Ionic Liquids Peter Nockemann, Rik Van Deun, Ben Thijs, Diederik Huys, Evert Vanecht, Kristof Van Hecke, Luc Van Meervelt and Koen Binnemans pp 3351–3360 DOI: 10.1021/ic902406h Supporting Info

Mechanistic Insight on the Hydrogenation of Conjugated Alkenes with H2 Catalyzed by Early Main-Group Metal Catalysts Guixiang Zeng and Shuhua Li pp 3361–3369 DOI: 10.1021/ic902418v Supporting Info

Computational Exploration of the Mechanism of Alcohol Oxidation by Dioxygen Activated with Biquinolyl-Containing Cu Complexes Pavel M. Polestshuk and Tatiana V. Magdesieva pp 3370–3386 DOI: 10.1021/ic9024537 Supporting Info

Mssbauer, Electron Paramagnetic Resonance, and Magnetic Susceptibility Studies on Members of a New Family of Cyano-Bridged 3d-4f Complexes. Demonstration of Anisotropic Exchange in a Fe−Gd Complex Sebastian A. Stoian, Carmen Paraschiv, Nathalie Kiritsakas, Francesc Lloret, Eckard Mnck, Emile L. Bominaar and Marius Andruh pp 3387–3401 DOI: 10.1021/ic902516r Supporting Info

Structural Study of Mixed Crystals of [Zn1−xRux(bpy)3][NaCr(ox)3] Probed by High-Resolution Absorption Spectroscopy and High-Pressure Experiments Mia Milos, Tiphaine Penhouet, Prodipta Pal and Andreas Hauser pp 3402–3408 DOI: 10.1021/ic902514w Supporting Info

Ligand Metalation in the Reactivity of a Tetravalent Uranium Amides Ilia Korobkov and Sandro Gambarotta pp 3409–3418 DOI: 10.1021/ic902567m Supporting Info

Theoretical Study on the Possibility of Using Frustrated Lewis Pairs as Bifunctional Metal-Free Dehydrogenation Catalysts of Ammonia−Borane Yong Guo, Xiang He, Zhaosheng Li and Zhigang Zou pp 3419–3423 DOI: 10.1021/ic9024553 Supporting Info

Volume-Based Thermoelasticity: Compressibility of Inorganic Solids Leslie Glasser pp 3424–3427 DOI: 10.1021/ic902475n Supporting Info

Photoluminescent Lanthanide-Organic Bilayer Networks with 2,3-Pyrazinedicarboxylate and Oxalate Paula C. R. Soares-Santos, Lus Cunha-Silva, Filipe A. Almeida Paz, Rute A. S. Ferreira, Joo Rocha, Lus D. Carlos and Helena I. S. Nogueira pp 3428–3440 DOI: 10.1021/ic902522j Supporting Info

Mixed Alkali Metal/Transition Metal Coordination Polymers with the Mellitic Acid Hexaanion: 2-Dimensional Hexagonal Magnetic Nets Simon M. Humphrey, Richard A. Mole, Richard I. Thompson and Paul T. Wood pp 3441–3448 DOI: 10.1021/ic902527e Supporting Info

Synthesis and Characterization of anti-bisFe(III) Porphyrins, syn-bisFe(III)-μ-oxo Porphyrin, and syn-bisFe(III)-μ-oxo Porphyrin Cation Radical Sudip Kumar Ghosh, Ranjan Patra and Sankar Prasad Rath pp 3449–3460 DOI: 10.1021/ic100002c Supporting Info

An Efficient Route for the Synthesis of a Tin(II) Substituted Carbodiimide from a Diazo Compound Anukul Jana, Herbert W. Roesky, Carola Schulzke and Prinson P. Samuel pp 3461–3464 DOI: 10.1021/ic100031d Supporting Info

Synthesis and Structural Characterization of Bimetallic Iron−Nickel Carbido Cluster Complexes Sumit Saha, Lei Zhu and Burjor Captain pp 3465–3472 DOI: 10.1021/ic100057x Supporting Info

Photoluminescent Properties of Chalcobromide−capped Octahedral Hexarhenium(III) Complexes [{Re6Q8−nBrn}Br6]n−4 (Q = Se, n = 1−3; Q = S, n = 1, 2) Takashi Yoshimura, Ayumi Matsuda, Yuki Ito, Shoji Ishizaka, Satoshi Shinoda, Hiroshi Tsukube, Noboru Kitamura and Atsushi Shinohara pp 3473–3481 DOI: 10.1021/ic902582r Supporting Info

Metal-Radical Chains Based on Polychlorotriphenylmethyl Radicals: Synthesis, Structure, and Magnetic Properties Nans Roques, Neus Domingo, Daniel Maspoch, Klaus Wurst, Concepci Rovira, Javier Tejada, Daniel Ruiz-Molina and Jaume Veciana pp 3482–3488 DOI: 10.1021/ic100037z Supporting Info

A Series of New Manganese(II) Sulfonate-Arsonates with 2D Layer, 1D Chain, and 0D Clusters Structures Fei-Yan Yi, Qi-Pu Lin, Tian-Hua Zhou and Jiang-Gao Mao pp 3489–3500 DOI: 10.1021/ic100103k Supporting Info

Syntheses, Raman Spectra, and X-ray Crystal Structures of [XeF5][μ-F(OsO3F2)2] and [M][OsO3F3] (M = XeF5+, Xe2F11+) Michael J. Hughes, Hlne P. A. Mercier and Gary J. Schrobilgen pp 3501–3515 DOI: 10.1021/ic100062x Supporting Info

Spin−Spin Interactions in Porphyrin-Based Monoverdazyl Radical Hybrid Spin Systems Prashanth K. Poddutoori, Melanie Pilkington, Antonio Alberola, Victor Polo, John E. Warren and Art van der Est pp 3516–3524 DOI: 10.1021/ic1000649 Supporting Info

Synthesis, Characterization, and Structures of R3EOTcO3 Complexes (E = C, Si, Ge, Sn, Pb) and Related Compounds Elisabeth Oehlke, Roger Alberto and Ulrich Abram pp 3525–3530 DOI: 10.1021/ic1001094 Supporting Info

Copper/α-Ketocarboxylate Chemistry With Supporting Peralkylated Diamines: Reactivity of Copper(I) Complexes and Dicopper−Oxygen Intermediates Aalo K. Gupta and William B. Tolman pp 3531–3539 DOI: 10.1021/ic100032n Supporting Info

Fourth Generation Scorpionates: Coordination Behavior of a New Class of Conformationally Flexible Mixed-Donor (Pyrazol-1-yl)borates Elena V. Mutseneck, Susanne Bieller, Michael Bolte, Hans-Wolfram Lerner and Matthias Wagner pp 3540–3552 DOI: 10.1021/ic100104t Supporting Info

Correction to Ultrathin SnO2 Nanorods: Template- and Surfactant-Free Solution Phase Synthesis, Growth Mechanism, Optical, Gas-Sensing, and Surface Adsorption Properties Guangcheng Xi and Jinhua Ye p 3553 DOI: 10.1021/ic100324x

Issue 08

Preface: Forum on Dioxygen Activation and Reduction William B. Tolman and Edward I. Solomon pp 3555–3556 DOI: 10.1021/ic100161a

Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges Andrew A. Gewirth and Matthew S. Thorum pp 3557–3566 DOI: 10.1021/ic9022486

Enzymatic versus Inorganic Oxygen Reduction Catalysts: Comparison of the Energy Levels in a Free-Energy Scheme Christian H. Kjaergaard, Jan Rossmeisl and Jens K. Nørskov pp 3567–3572 DOI: 10.1021/ic900798q

Transition-Metal Ions in Zeolites: Coordination and Activation of Oxygen Pieter J. Smeets, Julia S. Woertink, Bert F. Sels, Edward I. Solomon and Robert A. Schoonheydt pp 3573–3583 DOI: 10.1021/ic901814f

Oxygen Activation with Transition-Metal Complexes in Aqueous Solution Andreja Bakac pp 3584–3593 DOI: 10.1021/ic9015405

Activation of Molecular Oxygen, Polyoxometalates, and Liquid-Phase Catalytic Oxidation Ronny Neumann pp 3594–3601 DOI: 10.1021/ic9015383

Dioxygen Activation for the Self-Degradation of Heme: Reaction Mechanism and Regulation of Heme Oxygenase Toshitaka Matsui, Mari Iwasaki, Ryota Sugiyama, Masaki Unno and Masao Ikeda-Saito pp 3602–3609 DOI: 10.1021/ic901869t

Cytochrome P450: The Active Oxidant and Its Spectrum Jonathan Rittle, Jarod M. Younker and Michael T. Green pp 3610–3617 DOI: 10.1021/ic902062d Supporting Info

Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective Anusree Mukherjee, Matthew A. Cranswick, Mrinmoy Chakrabarti, Tapan K. Paine, Kiyoshi Fujisawa, Eckard Mnck and Lawrence Que, Jr. pp 3618–3628 DOI: 10.1021/ic901891n Supporting Info

Heme−Copper−Dioxygen Complexes: Toward Understanding Ligand-Environmental Effects on the Coordination Geometry, Electronic Structure, and Reactivity Zakaria Halime, Matthew T. Kieber-Emmons, Munzarin F. Qayyum, Biplab Mondal, Thirumanavelan Gandhi, Simona C. Puiu, Eduardo E. Chufn, Amy A. N. Sarjeant, Keith O. Hodgson, Britt Hedman, Edward I. Solomon and Kenneth D. Karlin pp 3629–3645 DOI: 10.1021/ic9020993 Supporting Info

Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation Ryan L. Shook and A. S. Borovik pp 3646–3660 DOI: 10.1021/ic901550k Supporting Info

Oxygen Isotope Effects as Structural and Mechanistic Probes in Inorganic Oxidation Chemistry Daniel C. Ashley, David W. Brinkley and Justine P. Roth pp 3661–3675 DOI: 10.1021/ic901778g

New Polyoxometalate Species Stabilized in Coordination Networks Constructed with the Multinuclear Silver(I) Ethynediide Aggregate C2@Agn (n = 6 and 7) Xiao-Li Zhao and Thomas C. W. Mak pp 3676–3678 DOI: 10.1021/ic901697f Supporting Info

Construction of a Ag12 High-Nuclearity Metallamacrocyclic 3D Framework Jiyong Hu, Jin’an Zhao, Qianqian Guo, Hongwei Hou and Yaoting Fan pp 3679–3681 DOI: 10.1021/ic902450c Supporting Info

Deoxygenation of Nitroxyl Radicals by Oxorhenium(V) Complexes with Redox-Active Ligands Cameron A. Lippert and Jake D. Soper pp 3682–3684 DOI: 10.1021/ic9024684 Supporting Info

The Importance of Precursor and Successor Complex Formation in a Bimolecular Proton−Electron Transfer Reaction Elizabeth A. Mader and James M. Mayer pp 3685–3687 DOI: 10.1021/ic100143s Supporting Info

A Linear Tetranuclear Single-Molelcule Magnet of MnII2MnIII2 with the Anion of 2-(Hydroxymethyl)pyridine Dacheng Li, Huisheng Wang, Suna Wang, Yupeng Pan, Chengjuan Li, Jianmin Dou and You Song pp 3688–3690 DOI: 10.1021/ic100224j Supporting Info

Decanuclear Copper Framework Supported by a Tripodal Adenine Ligand Ashutosh Kumar Mishra and Sandeep Verma pp 3691–3693 DOI: 10.1021/ic100254t Supporting Info

Structural Study of Electronic States in Quasi-One-Dimensional Halogen-Bridged Mixed-Metal Complexes [Ni1−xPdx(chxn)2Br]Br2 Shinya Takaishi, Hashen Wu, Jimin Xie, Takashi Kajiwara, Brian K. Breedlove, Hitoshi Miyasaka and Masahiro Yamashita pp 3694–3696 DOI: 10.1021/ic1001368 Supporting Info

Cofacial Dicobalt Complex of a Binucleating Hexacarboxamide Cryptand Ligand Glen E. Alliger, Peter Mller, Christopher C. Cummins and Daniel G. Nocera pp 3697–3699 DOI: 10.1021/ic100395a Supporting Info

Magnetic and Conducting Properties of New Halide-Bridged Mixed-Valence CuI−CuII 1D Coordination Polymers Including a Hexamethylene Dithiocarbamate Ligand Takashi Okubo, Naoya Tanaka, Kyung Ho Kim, Hironobu Yone, Masahiko Maekawa and Takayoshi Kuroda-Sowa pp 3700–3702 DOI: 10.1021/ic1003098 Supporting Info

Unusual Metal-Coordinated Zwitterionic P−C−N−C−N−C Phosphido Adducts Allen T. Ekubo, Mark R. J. Elsegood, Andrew J. Lake and Martin B. Smith pp 3703–3705 DOI: 10.1021/ic1002308 Supporting Info

Electroabsorption of Dimers Containing MM (M = Mo, W) Quadruply Bonded Units: Insights into the Electronic Structure of Neutral Coupled Redox Centers and Their Relationship with Mixed Valence Ions Malcolm H. Chisholm, Benjamin J. Lear, Alberto Moscatelli and Linda A. Peteanu pp 3706–3713 DOI: 10.1021/ic901387q Supporting Info

Synthesis, Structure, and Electrochemistry of the Dicluster Molecular Pincer [Pt3(μ-PBut2)3(CO)2]2(μ-1′,1′′′-diethynylbiferrocene) Alberto Albinati, Federica Balzano, Fabrizia Fabrizi de Biani, Piero Leoni, Gabriele Manca, Lorella Marchetti, Silvia Rizzato, Gloria Uccello Barretta and Piero Zanello pp 3714–3720 DOI: 10.1021/ic9014459 Supporting Info

Catalytic Properties of [Pd(COOMe)nX2−n(PPh3)2] (n = 0, 1, 2; X = Cl, NO2, ONO2, OAc and OTs) in the Oxidative Carbonylation of MeOH Emanuele Amadio, Gianni Cavinato, Alessandro Dolmella and Luigi Toniolo pp 3721–3729 DOI: 10.1021/ic901569w Supporting Info

Boron Dipyrromethene (Bodipy) Phosphorescence Revealed in [Ir(ppy)2(bpy-C≡C-Bodipy)]+ Aaron A. Rachford, Raymond Ziessel, Thomas Bura, Pascal Retailleau and Felix N. Castellano pp 3730–3736 DOI: 10.1021/ic901996u Supporting Info

Synthesis and Characterization of Ruthenium(II)−Pyridylamine Complexes with Catechol Pendants as Metal Binding Sites Takahiko Kojima, Norihisa Hirasa, Daisuke Noguchi, Tomoya Ishizuka, Soushi Miyazaki, Yoshihito Shiota, Kazunari Yoshizawa and Shunichi Fukuzumi pp 3737–3745 DOI: 10.1021/ic902070q Supporting Info

New Manganese(II) Azido Coordination Polymers with Nicotinic/Isonicotinic Acids as Coligands: Synthesis, Structure, and Magnetic Properties Qian Yang, Jiong-Peng Zhao, Bo-Wen Hu, Xiao-Feng Zhang and Xian-He Bu pp 3746–3751 DOI: 10.1021/ic9021257 Supporting Info

A Triphenylamine-Grafted Imidazo[4,5-f][1,10]phenanthroline Ruthenium(II) Complex: Acid−Base and Photoelectric Properties Su-Hua Fan, An-Guo Zhang, Chuan-Chuan Ju, Li-Hua Gao and Ke-Zhi Wang pp 3752–3763 DOI: 10.1021/ic902100v Supporting Info

The Lowest Excited State of Brightly Emitting Gold(I) Triphosphine Complexes Rafał Czerwieniec, Thomas Hofbeck, Olga Crespo, Antonio Laguna, M. Concepcin Gimeno and Hartmut Yersin pp 3764–3767 DOI: 10.1021/ic902325n

Bifunctional Multidentate Ligand Modified Highly Stable Water-Soluble Quantum Dots Lu Liu, Xuhong Guo, Yan Li and Xinhua Zhong pp 3768–3775 DOI: 10.1021/ic902469d Supporting Info

Four Novel Frameworks Built by Imidazole-Based Dicarboxylate Ligands: Hydro(Solvo)thermal Synthesis, Crystal Structures, and Properties Fuwei Zhang, Zifeng Li, Tiezhu Ge, Hongchang Yao, Gang Li, Huijie Lu and Yanyan Zhu pp 3776–3788 DOI: 10.1021/ic902483m Supporting Info

Cyclam-Based “Clickates”: Homogeneous and Heterogeneous Fluorescent Sensors for Zn(II) Emiliano Tamanini, Kevin Flavin, Majid Motevalli, Silvia Piperno, Levi A. Gheber, Matthew H. Todd and Michael Watkinson pp 3789–3800 DOI: 10.1021/ic901939x Supporting Info

Thermal Polymorphism and Decomposition of Y(BH4)3 Dorthe B. Ravnsbæk, Yaroslav Filinchuk, Radovan ern, Morten B. Ley, Drthe Haase, Hans J. Jakobsen, Jrgen Skibsted and Torben R. Jensen pp 3801–3809 DOI: 10.1021/ic902279k Supporting Info

Synthesis, Properties, and Bishomoaromaticity of the First Tetrahalogenated Derivative of a 1, 5-Diphosphadithiatetrazocine: A Combined Experimental and Computational Investigation Tristram Chivers, Robert W. Hilts, Peng Jin, Zhongfang Chen and Xin Lu pp 3810–3815 DOI: 10.1021/ic902428j Supporting Info

Heavier Alkaline Earth Metal Borohydride Complexes Stabilized by β−Diketiminate Ligand Sankaranarayana Pillai Sarish, Anukul Jana, Herbert W. Roesky, Thomas Schulz, Michael John and Dietmar Stalke pp 3816–3820 DOI: 10.1021/ic902338r Supporting Info

Oxygen Exchange in Uranyl Hydroxide via Two “Nonclassical” Ions Michael Bhl and Georg Schreckenbach pp 3821–3827 DOI: 10.1021/ic902508z Supporting Info

First Examples of a Modulated Bridging μ2-1:2κN-Triazine in Double Helical Silver Compounds. Experimental and Theoretical Evidence M. Pilar Carranza, Blanca R. Manzano, Flix A. Jaln, Ana M. Rodrguez, Luca Santos and Miquel Moreno pp 3828–3835 DOI: 10.1021/ic902563d Supporting Info

Gas-Phase Reactions of Uranate Ions, UO2−, UO3−, UO4−, and UO4H−, with Methanol: a Convergence of Experiment and Theory Maria del Carmen Michelini, Joaquim Maralo, Nino Russo and John K. Gibson pp 3836–3850 DOI: 10.1021/ic902550g Supporting Info

Small Magnesium Clusters: Between van der Waals and Valence Bonds Alexander Kaufmann and Andreas Kornath, Anja Zoermer, Ralf Ludwig pp 3851–3856 DOI: 10.1021/ic902485z

Luminescent Low-Valent Rhenium Complexes with 1,2-Bis(dialkylphosphino)ethane Ligands. Synthesis and X-ray Crystallographic, Electrochemical, and Spectroscopic Characterization Stephania J. Messersmith, Kristin Kirschbaum and Jon R. Kirchhoff pp 3857–3865 DOI: 10.1021/ic902549b Supporting Info

Is [FeO]2+ the Active Center Also in Iron Containing Zeolites? A Density Functional Theory Study of Methane Hydroxylation Catalysis by Fe-ZSM-5 Zeolite Angela Rosa, Giampaolo Ricciardi and Evert Jan Baerends pp 3866–3880 DOI: 10.1021/ic1000073 Supporting Info

Magnetic and Structural Transitions at Dimerization of C60•− in Ionic Fullerene Complexes with Metalloporphyrins: {(TMP+)2·MIITPP}·(C60−)2·(C6H4Cl2)2·(C6H5CN)2 (M = Zn and Mn) Dmitri V. Konarev, Salavat S. Khasanov, Guzeliya R. Mukhamadieva, Leokadia V. Zorina, Akihiro Otsuka, Hideki Yamochi, Gunzi Saito and Rimma N. Lyubovskaya pp 3881–3887 DOI: 10.1021/ic100061e Supporting Info

Intercalation of Ethylene Glycol into Yttrium Hydroxide Layered Materials Yuanzhou Xi and Robert J. Davis pp 3888–3895 DOI: 10.1021/ic1000478

Aqueous Chemistry of Chlorocyclophosphazenes: Phosphates {PO2}, Phosphamides {P(O)NHR}, and the first Phosphites {PHO} and Pyrophosphates {(PO)2O} of These Heterocycles Joanne Ledger, Ramamoorthy Boomishankar and Alexander Steiner pp 3896–3904 DOI: 10.1021/ic100076t Supporting Info

Hydrogen Release Studies of Alkali Metal Amidoboranes Avery T. Luedtke and Tom Autrey pp 3905–3910 DOI: 10.1021/ic100119m

Stepwise and Selective Carborane Substitution in the B(3,6) Positions of a 16e CpCo Half-Sandwich Complex Containing a Chelating ortho-Carborane-1,2-dithiolate Ligand Yuguang Li, Qibai Jiang, Xiaolei Zhang, Yizhi Li, Hong Yan and Vladimir I. Bregadze pp 3911–3917 DOI: 10.1021/ic1001804 Supporting Info

Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile Aaron D. Wilson, Alexander J. M. Miller, Daniel L. DuBois, Jay A. Labinger and John E. Bercaw pp 3918–3926 DOI: 10.1021/ic100117y Supporting Info

N-Aryl Chromophore Ligands for Bright Europium Luminescence Nail M. Shavaleev, Svetlana V. Eliseeva, Rosario Scopelliti and Jean-Claude G. Bnzli pp 3927–3936 DOI: 10.1021/ic100129r Supporting Info

New Salts of the Waterstable P2Se64− Anion Christiane Rotter, Michael Schuster, Sebastian Gebler, Thomas M. Klaptke and Konstantin Karaghiosoff pp 3937–3941 DOI: 10.1021/ic100200b

Synthesis and Characterization of Pentaphosphino Zero-Valent Iron Complexes and Their Corresponding Iron(II)-Chloride and -Hydride Complexes Kristen A. Thoreson, Angela D. Follett and Kristopher McNeill pp 3942–3949 DOI: 10.1021/ic1003325 Supporting Info

Synthesis of Gold Phosphido Complexes Derived from Bis(secondary) Phosphines. Structure of Tetrameric [Au(MesP(CH2)3PMes)Au]4 Elizabeth M. Lane, Timothy W. Chapp, Russell P. Hughes, David S. Glueck, Brett C. Feland, Guy M. Bernard, Roderick E. Wasylishen and Arnold L. Rheingold pp 3950–3957 DOI: 10.1021/ic100219j Supporting Info

Correction to Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3 L. Wu, J. C. Sun, Y. Zhang, S. F. Jin, Y. F. Kong and J. J. Xu p 3958 DOI: 10.1021/ic100448v

Issue 09

Stepwise Introduction of Thiolates in Copper−Indium Binuclear Complexes Kelsey R. Margulieux, Chivin Sun, Lev N. Zakharov, Andrew W. Holland and Joshua J. Pak pp 3959–3961 DOI: 10.1021/ic9025602 Supporting Info

The Highest-Nuclearity Manganese/Oximate Complex: An Unusual MnII/III15 Cluster with an S = 6 Ground State Dimitris I. Alexandropoulos, Constantina Papatriantafyllopoulou, Guillem Arom, Olivier Roubeau, Simon J. Teat, Spyros P. Perlepes, George Christou and Theocharis C. Stamatatos pp 3962–3964 DOI: 10.1021/ic100267y Supporting Info

Metal Nanoparticles via the Atom-Economy Green Approach Suresh Babu Kalidindi, Udishnu Sanyal and Balaji R. Jagirdar pp 3965–3967 DOI: 10.1021/ic100431k Supporting Info

Central Role of Phenanthroline Mono-N-oxide in the Decomposition Reactions of Tris(1,10-phenanthroline)iron(II) and -iron(III) Complexes Gbor Bellr, Gbor Lente and Istvn Fbin pp 3968–3970 DOI: 10.1021/ic902554b Supporting Info

Magnetostructural D Correlation in Nickel(II) Complexes: Reinvestigation of the Zero-Field Splitting Jn Titi and Roman Boa pp 3971–3973 DOI: 10.1021/ic902569z Supporting Info

Gold(I) Triphenylphosphine Complexes Incorporating Pentaarylfulleride Ligands Merissa Halim, Robert D. Kennedy, Saeed I. Khan and Yves Rubin pp 3974–3976 DOI: 10.1021/ic100428f Supporting Info

Dithiodiolate Ligands: Group 4 Complexes and Application in Lactide Polymerization Ekaterina Sergeeva, Jacob Kopilov, Israel Goldberg and Moshe Kol pp 3977–3979 DOI: 10.1021/ic100390x Supporting Info

Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer Jonah W. Jurss, Javier C. Concepcion, Michael R. Norris, Joseph L. Templeton and Thomas J. Meyer pp 3980–3982 DOI: 10.1021/ic100469x Supporting Info

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination M. Sircoglou, S. Bontemps, M. Mercy, K. Miqueu, S. Ladeira, N. Saffon, L. Maron, G. Bouhadir and D. Bourissou pp 3983–3990 DOI: 10.1021/ic901896z Supporting Info

Rodlike Fluorescent π-Conjugated 3,3′-Bipyridazine Ligand: Optical, Electronic, and Complexation Properties Frdric Lincker, David Kreher, Andr-Jean Attias, Jaekwon Do, Eunkyoung Kim, Philippe Hapiot, Nolla Lematre, Bernard Geffroy, Gilles Ulrich and Raymond Ziessel pp 3991–4001 DOI: 10.1021/ic901925w

Both Visual and Fluorescent Sensor for Zn2+ Based on Quinoline Platform Xiaoyan Zhou, Bingran Yu, Yanling Guo, Xiaoliang Tang, Huihui Zhang and Weisheng Liu pp 4002–4007 DOI: 10.1021/ic901354x Supporting Info

Synthesis, Structure, and Two-Photon Absorption Studies of a Phosphorus-Based Tris Hydrazone Ligand (S)P[N(Me)N═CH-C6H3-2-OH-4-N(CH2CH3)2]3 and Its Metal Complexes Vadapalli Chandrasekhar, Ramachandran Azhakar, Balasubramanian Murugesapandian, Tapas Senapati, Prasenjit Bag, Mrituanjay D. Pandey, Sandeep Kumar Maurya and Debabrata Goswami pp 4008–4016 DOI: 10.1021/ic901531e Supporting Info

Formation of Aminoxy and Oxo Complexes from the Reaction of Nb(NMe2)5 with O2 and the Crystal Structure of Nb(NEt2)5 Shu-Jian Chen, Jian Zhang, Xianghua Yu, Xianhui Bu, Xue-Tai Chen and Zi-Ling Xue pp 4017–4022 DOI: 10.1021/ic901889m Supporting Info

Unfolding of the [Cu2(1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane)2]2+ Helicate. Coupling of the Chlorocarbon Dehalogenation to the Unfolding Process L. Lemus, J. Guerrero, J. Costamagna, G. Estiu, G. Ferraudi, A. Graham Lappin, A. Oliver and B. C. Noll pp 4023–4035 DOI: 10.1021/ic9018986 Supporting Info

Photocytotoxic Lanthanum(III) and Gadolinium(III) Complexes of Phenanthroline Bases Showing Light-Induced DNA Cleavage Activity Akhtar Hussain, Debojyoti Lahiri, Mohammed S. Ameerunisha Begum, Sounik Saha, Ritankar Majumdar, Rajan R. Dighe and Akhil R. Chakravarty pp 4036–4045 DOI: 10.1021/ic901791f Supporting Info

Experimental Charge Density Analysis of Symmetrically Substituted Ferrocene Derivatives Anna M. Makal, Damian Plauk, Janusz Zakrzewski, Bogusław Misterkiewicz and Krzysztof Woniak pp 4046–4059 DOI: 10.1021/ic9019958 Supporting Info

Diversity of Metal−Ligand Interactions in Halide (X = I, Br, Cl, F) and Halide-Free Ambiphilic Ligand Rhodium Complexes Bradley E. Cowie, David J. H. Emslie, Hilary A. Jenkins and James F. Britten pp 4060–4072 DOI: 10.1021/ic902109p Supporting Info

Excited States of Ru(II) and Re(I) Bipyridyl Complexes Attached to Cyclotriphosphazenes: A Synthetic, Spectroscopic, and Computational Study Raphael Horvath, Carl A. Otter, Keith C. Gordon, Andrew M. Brodie and Eric W. Ainscough pp 4073–4083 DOI: 10.1021/ic902171j Supporting Info

Electron-, Proton-, and Photon-Induced Spectroscopic Changes in Chromophore-Quencher Tricarbonyl(2,2′-Bipyridine)rhenium(I) Complexes with 4,4′-Azobis(pyridine) Gaston Pourrieux, Florencia Fagalde, Isabel Romero, Xavier Fontrodona, Teodor Parella and Nstor E. Katz pp 4084–4091 DOI: 10.1021/ic901893q Supporting Info

An Experimental Solution to the “Missing Hydrogens” Question Surrounding the Macropolyhedral 19-Vertex Boron Hydride Monoanion [B19H22]−, a Simplification of Its Synthesis, and Its Use As an Intermediate in the First Example of syn-B18H22 to anti-B18H22 Isomer Conversion Michael G. S. Londesborough, Jonathan Bould, Tom Bae, Drahomr Hnyk, Mario Bakardjiev, Josef Holub, Ivana Csaov and John D. Kennedy pp 4092–4098 DOI: 10.1021/ic901976y Supporting Info

Molecular, Electronic, and Crystal Structures of Self-Assembled Hydrothermally Synthesized Zn(II)−Mercaptonicotinate: A Combined Spectroscopic and Theoretical Approach Maurizio Casarin, Thomas Devic, Alessia Famengo, Daniel Forrer, Silvia Gross, Eugenio Tondello and Andrea Vittadini pp 4099–4108 DOI: 10.1021/ic902076r Supporting Info

Lanthanide(III) Complexes with 4,5-Bis(diphenylphosphinoyl)-1,2,3-triazolate and the Use of 1,10-Phenanthroline As Auxiliary Ligand Marisol Correa-Ascencio, Elizabeth K. Galvn-Miranda, Fernando Rascn-Cruz, Omar Jimnez-Sandoval, Sergio J. Jimnez-Sandoval, Raymundo Cea-Olivares, Vojtech Jancik, R. Alfredo Toscano and Vernica Garca-Montalvo pp 4109–4116 DOI: 10.1021/ic902120e Supporting Info

Self-Assembly of Metal−Organic Supramolecules: From a Metallamacrocycle and a Metal−Organic Coordination Cage to 1D or 2D Coordination Polymers Based on Flexible Dicarboxylate Ligands Fangna Dai, Jianmin Dou, Haiyan He, Xiaoliang Zhao and Daofeng Sun pp 4117–4124 DOI: 10.1021/ic902178c Supporting Info

A New Family of Sandwich-Type Polytungstophosphates Containing Two Types of Metals in the Central Belt: M′2M2(PW9O34)212− (M′ = Na or Li, M = Mn2+, Co2+, Ni2+, and Zn2+) Yu Hou, Lin Xu, Morgan J. Cichon, Sheri Lense, Kenneth I. Hardcastle and Craig L. Hill pp 4125–4132 DOI: 10.1021/ic9024712 Supporting Info

Nuclear Resonance Vibrational Spectroscopy Applied to [Fe(OEP)(NO)]: The Vibrational Assignments of Five-Coordinate Ferrous Heme−Nitrosyls and Implications for Electronic Structure Nicolai Lehnert, Mary Grace I. Galinato, Florian Paulat, George B. Richter-Addo, Wolfgang Sturhahn, Nan Xu and Jiyong Zhao pp 4133–4148 DOI: 10.1021/ic902181e Supporting Info

Vertex and Edge Truncated Octahedron Gold Crystals. N-alkylimidazole and Silver(I) Ion Controlled Morphology Transformation S. J. Hsu, Padi Y. S. Su, L. Y. Jian, A. H. H. Chang and Ivan J. B. Lin pp 4149–4155 DOI: 10.1021/ic902201u Supporting Info

1-Methyl-3-hydroxy-pyridin-2-one Complexes of Near Infra-Red Emitting Lanthanides: Efficient Sensitization of Yb(III) and Nd(III) in Aqueous Solution Evan G. Moore, Jide Xu, Sheel C. Dodani, Christoph J. Jocher, Anthony D’Alo, Michael Seitz and Kenneth N. Raymond pp 4156–4166 DOI: 10.1021/ic902219t Supporting Info

Sensitization of Nanocrystalline TiO2 Anchored with Pendant Catechol Functionality Using a New Tetracyanato Ruthenium(II) Polypyridyl Complex Prasenjit Kar, Sandeep Verma, Anik Sen, Amitava Das, Bishwajit Ganguly and Hirendra Nath Ghosh pp 4167–4174 DOI: 10.1021/ic902533x Supporting Info

Toward the Synthetic Control of the HOMO−LUMO Gap in Binuclear Systems: Insights from Density Functional Calculations Alvaro Muoz-Castro, Desmond Mac-Leod Carey, Cesar Morales-Verdejo, Ivonne Chvez, Juan Manuel Manrquez and Ramiro Arratia-Prez pp 4175–4178 DOI: 10.1021/ic902326y Supporting Info

Tellurium(0) as a Ligand: Synthesis and Characterization of 2-Pyridyltellurolates of Platinum(II) and Structures of [Pt{2-Te-3-(R)C5H3N}2Te(PR′3)] (R = H or Me) Rohit Singh Chauhan, G. Kedarnath, Amey Wadawale, Alvaro Muoz-Castro, Ramiro Arratia-Perez, Vimal K. Jain and Wolfgang Kaim pp 4179–4185 DOI: 10.1021/ic902347s Supporting Info

Photophysical Properties of Ruthenium(II) Polypyridyl-Gold(I) Ethynyl Dyads and Triads Containing Mono- or Diethynylphenanthroline Incorporated into Gold(I) Triphenylphosphine Organometallics Michito Shiotsuka, Yasushi Tsuji, Kazutoshi Keyaki and Koichi Nozaki pp 4186–4193 DOI: 10.1021/ic902417m Supporting Info

Isomerization Mechanisms of Stereolabile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigations Fabrice Riblet, Ghenadie Novitchi, Rosario Scopelliti, Lothar Helm, Aurelian Gulea and Andr E. Merbach pp 4194–4211 DOI: 10.1021/ic902494j Supporting Info

Molecular Recognition of Sialic Acid by Lanthanide(III) Complexes through Cooperative Two-Site Binding Martn Regueiro-Figueroa, Kristina Djanashvili, David Esteban-Gmez, Thomas Chauvin, va Tth, Andrs de Blas, Teresa Rodrguez-Blas and Carlos Platas-Iglesias pp 4212–4223 DOI: 10.1021/ic902461g Supporting Info

Hydration Properties of the Bromide Aqua Ion: the Interplay of First Principle and Classical Molecular Dynamics, and X-ray Absorption Spectroscopy Paola D’Angelo, Valentina Migliorati and Leonardo Guidoni pp 4224–4231 DOI: 10.1021/ic9025574

Rhomboidal Heterometallic Alkynyl Based Pt2Cd2 Clusters: Structural, Photophysical, and Theoretical Studies Jess R. Berenguer, Julio Fernndez, Beln Gil, Elena Lalinde and Sergio Snchez pp 4232–4244 DOI: 10.1021/ic100072a Supporting Info

Is Vanadate Reduced by Thiols under Biological Conditions? Changing the Redox Potential of V(V)/V(IV) by Complexation in Aqueous Solution Debbie C. Crans, Boyan Zhang, Ernestas Gaidamauskas, Anastasios D. Keramidas, Gail R. Willsky and Chris R. Roberts pp 4245–4256 DOI: 10.1021/ic100080k Supporting Info

Unusual Photophysical Properties of a Ruthenium(II) Complex Related to [Ru(bpy)2(dppz)]2+ Yujie Sun, Sibrina N. Collins, Lauren E. Joyce and Claudia Turro pp 4257–4262 DOI: 10.1021/ic9025365 Supporting Info

Molybdenum Difluoride Dioxide, MoO2F2 Hashem Shorafa, Halil Ficicioglu, Farhad Tamadon, Frank Girgsdies and Konrad Seppelt pp 4263–4267 DOI: 10.1021/ic1000864 Supporting Info

Magnetic Properties versus Network Dimensionality of Cerium(III) Octacyanotungstate(V) Compounds Marcin Kozieł, Robert Pełka, Michał Rams, Wojciech Nitek and Barbara Sieklucka pp 4268–4277 DOI: 10.1021/ic100158g Supporting Info

2-Anthryltriazolyl-Containing Multidentate Ligands: Zinc-Coordination Mediated Photophysical Processes and Potential in Live-Cell Imaging Applications Heather A. Michaels, Christopher S. Murphy, Ronald J. Clark, Michael W. Davidson and Lei Zhu pp 4278–4287 DOI: 10.1021/ic100145e Supporting Info

Coordinatively Diverse ortho-Phosphinoaniline Complexes of Ruthenium and Isolation of a Putative Intermediate in Ketone Transfer Hydrogenation Catalysis Lindsay J. Hounjet, Matthias Bierenstiel, Michael J. Ferguson, Robert McDonald and Martin Cowie pp 4288–4300 DOI: 10.1021/ic100165t Supporting Info

Three-Dimensional Porous Metal−Organic Frameworks Exhibiting Metamagnetic Behaviors: Synthesis, Structure, Adsorption, and Magnetic Properties Qun Yu, Yong-Fei Zeng, Jiong-Peng Zhao, Qian Yang, Bo-Wen Hu, Ze Chang and Xian-He Bu pp 4301–4306 DOI: 10.1021/ic100188w Supporting Info

Effect of Pnictogen Ligand Substitution on a Tripalladium Ditropylium Core Dominic C. Babbini, Frank L. Mulligan, Hannah R. Schulhauser, Tara C. Sweigart, Gary S. Nichol and Stephanie K. Hurst pp 4307–4312 DOI: 10.1021/ic100151x Supporting Info

Bismuth Allyloxides Christina Knispel, Christian Limberg and Burkhard Ziemer pp 4313–4318 DOI: 10.1021/ic100171f Supporting Info

Stepwise Phase Transition in the Formation of Lithium Amidoborane Chengzhang Wu, Guotao Wu, Zhitao Xiong, William I. F. David, Kate R. Ryan, Martin O. Jones, Peter P. Edwards, Hailiang Chu and Ping Chen pp 4319–4323 DOI: 10.1021/ic100308j

Reactions of α-Diimine Ligands with the in Situ Generated “S(OTf)2” Synthon Caleb D. Martin and Paul J. Ragogna pp 4324–4330 DOI: 10.1021/ic100320u Supporting Info

Synthesis, Characterization, and Catalytic Properties of New Electrophilic Iridium(III) Complexes Containing the (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl Ligand Abdurrahman C. Atesin, Jing Zhang, Tulaza Vaidya, William W. Brennessel, Alison J. Frontier and Richard Eisenberg pp 4331–4342 DOI: 10.1021/ic100300y Supporting Info

Mechanistic Studies on the Interaction of [(κ3-P,P,P-NP3)IrH3] [NP3 = N(CH2CH2PPh2)3] with HBF4 and Fluorinated Alcohols by Combined NMR, IR, and DFT Techniques Andrea Rossin, Evgenii I. Gutsul, Natalia V. Belkova, Lina M. Epstein, Luca Gonsalvi, Agust Lleds, Konstantin A. Lyssenko, Maurizio Peruzzini, Elena S. Shubina and Fabrizio Zanobini pp 4343–4354 DOI: 10.1021/ic100313j Supporting Info

Field Induced 4f5d [Re(salen)]2O3[Dy(hfac)3(H2O)]2 Single Molecule Magnet Fabrice Pointillart, K. Bernot, R. Sessoli and D. Gatteschi pp 4355–4361 DOI: 10.1021/ic1003287 Supporting Info

Controlled Protein Dimerization through Hybrid Coordination Motifs Robert J. Radford, Phuong C. Nguyen, Treffly B. Ditri, Joshua S. Figueroa and F. Akif Tezcan pp 4362–4369 DOI: 10.1021/ic100534y Supporting Info

An NMR and DFT Investigation on the Conformational Properties of Lanthanide(III) 1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetraacetate Analogues Containing Methylenephosphonate Pendant Arms Mihly Purgel, Zsolt Baranyai, Andrs de Blas, Teresa Rodrguez-Blas, Istvn Bnyai, Carlos Platas-Iglesias and Imre Tth pp 4370–4382 DOI: 10.1021/ic100177n Supporting Info

Conformation Changes and Luminescent Properties of Au−Ln (Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2′-Bipyridine Hai-Bing Xu, Li-Yi Zhang, Jun Ni, Hsiu-Yi Chao and Zhong-Ning Chen p 4383 DOI: 10.1021/ic802264d

Correction to Spectroscopic and Luminescence Studies on Square-Planar Platinum(II) Complexes with Anionic Tridentate 3-Bis(2-pyridineimino)isoindoline Derivatives Hui-Min Wen, Yu-Hui Wu, Yang Fan, Li-Yi Zhang, Chang-Neng Chen and Zhong-Ning Chen p 4384 DOI: 10.1021/ic1005133

Issue 10

Indium−Sulfur Supertetrahedral Clusters Integrated with a Metal Complex of 1,10-Phenanthroline Zhi-Xin Lei, Qin-Yu Zhu, Xu Zhang, Wen Luo, Wen-Qin Mu and Jie Dai pp 4385–4387 DOI: 10.1021/ic902572m Supporting Info

Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands Constantinos C. Stoumpos, Ross Inglis, Olivier Roubeau, Harikleia Sartzi, Alexandros A. Kitos, Constantinos J. Milios, Guillem Arom, Anastasios J. Tasiopoulos, Vasilios Nastopoulos, Euan K. Brechin and Spyros P. Perlepes pp 4388–4390 DOI: 10.1021/ic100089y Supporting Info

Synthesis of Nanosheet Crystallites of Ruthenate with an α-NaFeO2-Related Structure and Its Electrochemical Supercapacitor Property Katsutoshi Fukuda, Takahiro Saida, Jun Sato, Mihoko Yonezawa, Yoshio Takasu and Wataru Sugimoto pp 4391–4393 DOI: 10.1021/ic100176d Supporting Info

Extending π-Conjugation of Triarylborons with a 2,2-Bpy Core: Impact of Donor−Acceptor Geometry on Luminescence, Anion Sensing, and Metal Ion Binding Yi Sun and Suning Wang pp 4394–4404 DOI: 10.1021/ic1004159 Supporting Info

Five- and Six-Coordinate Adducts of Nitrosamines with Ferric Porphyrins: Structural Models for the Type II Interactions of Nitrosamines with Ferric Cytochrome P450 Nan Xu, Lauren E. Goodrich, Nicolai Lehnert, Douglas R. Powell and George B. Richter-Addo pp 4405–4419 DOI: 10.1021/ic901751z Supporting Info

Structural Study of the N,N′-Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ions Daniel Lundberg, Ingmar Persson, Lars Eriksson, Paola D’Angelo and Simone De Panfilis pp 4420–4432 DOI: 10.1021/ic100034q Supporting Info

Mixed-Donor, α-Hydroxy Acid-Containing Chelates for Binding and Light-Triggered Release of Iron Hannah Sayre, Kyle Milos, Michael J. Goldcamp, Cynthia A. Schroll, Jeanette A. Krause and Michael J. Baldwin pp 4433–4439 DOI: 10.1021/ic9018629 Supporting Info

New Chiral and Flexible Metal−Organic Framework with a Bifunctional Spiro Linker and Zn4O-Nodes Kristina Gedrich, Irena Senkovska, Igor A. Baburin, Uwe Mueller, Oliver Trapp and Stefan Kaskel pp 4440–4446 DOI: 10.1021/ic9022085 Supporting Info

Thiomethoxychalcone-Functionalized Ferrocene Ligands as Selective Chemodosimeters for Mercury(II): Single-Crystal X-ray Structural Signature of the [Hg8(μ8-S)(SCH3)12]2+ Cluster B. Nisar Ahamed, M. Arunachalam and Pradyut Ghosh pp 4447–4457 DOI: 10.1021/ic902300c Supporting Info

Quantifying Exchange Coupling in f-Ion Pairs Using the Diamagnetic Substitution Method Wayne W. Lukens and Marc D. Walter pp 4458–4465 DOI: 10.1021/ic100120d Supporting Info

Solvent Effects on Isomerization in a Ruthenium Sulfoxide Complex Tod A. Grusenmeyer, Beth Anne McClure, Christopher J. Ziegler and Jeffrey J. Rack pp 4466–4470 DOI: 10.1021/ic902047f Supporting Info

Elucidation of the Mechanism in Fluorine-Free Prepared YBa2Cu3O7−δ Coatings Pieter Vermeir, Iwein Cardinael, Joseph Schaubroeck, Kim Verbeken, Michael Bcker, Petra Lommens, Werner Knaepen, Jan D’haen, Klaartje De Buysser and Isabel Van Driessche pp 4471–4477 DOI: 10.1021/ic9021799

Dense Yttria Phase Eclipsing the A-Type Sesquioxide Structure: High-Pressure Experiments and ab initio Calculations Hitoshi Yusa, Taku Tsuchiya, Nagayoshi Sata and Yasuo Ohishi pp 4478–4485 DOI: 10.1021/ic100042z

Molten Salt Synthesis and Structural Characterization of Novel Salt-Inclusion Vanadium Bronze Cs5FeV5O13Cl6 Parisa Mahjoor and Susan E. Latturner pp 4486–4490 DOI: 10.1021/ic902211c Supporting Info

Face-to-Face Dinuclear Scaffolds Composed of Tetraazamacrocyclic Charged and Neutral Complexes Katarzyna Szczepaniak, Urszula E. Wawrzyniak, Jarosław Kowalski, Iwona Mames, Renata Bilewicz, Przemysław Kalicki and Bohdan Korybut-Daszkiewicz pp 4491–4498 DOI: 10.1021/ic902424z Supporting Info

Synthesis and Structural Characterization of 9-Azido-9-Borafluorene: Monomer and Cyclotrimer of a Borole Azide Sunanda Biswas, Iris M. Oppel and Holger F. Bettinger pp 4499–4506 DOI: 10.1021/ic902436s Supporting Info

Cyclometalated Platinum(II) 6-Phenyl-4-(9,9-dihexylfluoren-2-yl)-2,2′-bipyridine Complexes: Synthesis, Photophysics, and Nonlinear Absorption Pin Shao, Yunjing Li, Jing Yi, Timothy M. Pritchett and Wenfang Sun pp 4507–4517 DOI: 10.1021/ic902281a Supporting Info

A Functional Model of Extradiol-Cleaving Catechol Dioxygenases: Mimicking the 2-His-1-Carboxylate Facial Triad Sayantan Paria, Partha Halder and Tapan Kanti Paine pp 4518–4523 DOI: 10.1021/ic902462k Supporting Info

Synthesis, Characterization, Photoinduced Isomerization, and Spectroscopic Properties of Vinyl-1,8-naphthyridine Derivatives and Their Copper(I) Complexes Wen-Fu Fu, Lin-Fang Jia, Wei-Hua Mu, Xin Gan, Jia-Bing Zhang, Ping-Hua Liu, Qian-Yong Cao, Gui-Ju Zhang, Li Quan, Xiao-Jun Lv and Quan-Qing Xu pp 4524–4533 DOI: 10.1021/ic100094y Supporting Info

High Spin and Spin-Crossover Two-Dimensional Coordination Polymers Containing FeII(tetrazol-2-yl)4(solv)2 (solv = Ethanol, Acetonitrile) Cores Linked by Flexible/Elastic Spacers Agata Białoska and Robert Bronisz pp 4534–4542 DOI: 10.1021/ic9024603 Supporting Info

Acid−Base Mechanism for Ruthenium Water Oxidation Catalysts Lee-Ping Wang, Qin Wu and Troy Van Voorhis pp 4543–4553 DOI: 10.1021/ic100075k Supporting Info

Enhanced Photocatalysis of Rhenium(I) Complex by Light-Harvesting Periodic Mesoporous Organosilica Hiroyuki Takeda, Masataka Ohashi, Takao Tani, Osamu Ishitani and Shinji Inagaki pp 4554–4559 DOI: 10.1021/ic1000914 Supporting Info

Doubly Pyrazolate-Bridged Dinuclear Complexes of a Highly Constrained Bis-terdentate Ligand: Observation of a [High Spin-Low Spin] State for [FeII2(PMAP)2][SbF6]2·2.25(C3H8O) (PMAP = 3,5-bis{[N-(2-pyridylmethyl)amino]-methyl}-1H-pyrazolate) Andy Noble, Juan Olgun, Rodolphe Clrac and Sally Brooker pp 4560–4569 DOI: 10.1021/ic1001013 Supporting Info

M3(Au,Ge)19 and M3.25(Au,Ge)18 (M = Ca, Yb): Distinctive Phase Separations Driven by Configurational Disorder in Cubic YCd6-Type Derivatives Qisheng Lin and John D. Corbett pp 4570–4577 DOI: 10.1021/ic100118q Supporting Info

Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N,N-Dimethylaminodiboranates Scott R. Daly and Gregory S. Girolami pp 4578–4585 DOI: 10.1021/ic100292u Supporting Info

Structural and Magnetic Characteristics of Gd5GaxSi4−x Hui Wang, Sumohan Misra, Fei Wang and Gordon J. Miller pp 4586–4593 DOI: 10.1021/ic100142u Supporting Info

Structure and Magnetic Field-Induced Transition in a One-Dimensional Hybrid Inorganic−Organic Chain System, Co2(4,4′-bpy)(tfhba)2·4,4′-bpy (4,4′-bpy = 4,4′-Bipyridine; tfhba = 2,3,5,6-Tetrafluoro-4-hydroxybenzoate) Zeric Hulvey, Brent C. Melot and Anthony K. Cheetham pp 4594–4598 DOI: 10.1021/ic100164k Supporting Info

Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems Pei-Xin Li, Chun-Li Hu, Xiang Xu, Rui-Yao Wang, Chuan-Fu Sun and Jiang-Gao Mao pp 4599–4605 DOI: 10.1021/ic100234e Supporting Info

Thermal Decomposition of Pyridine-Substituted Cobaltic Acetate in Acetic Acid Charles E. Sumner, Jr., James Little, Adam S. Howard and Weimin C. Liang pp 4606–4610 DOI: 10.1021/ic100182n

Two-Electron Redox Energetics in Ligand-Bridged Dinuclear Molybdenum and Tungsten Complexes Richard L. Lord, Franklin A. Schultz and Mu-Hyun Baik pp 4611–4619 DOI: 10.1021/ic100186v Supporting Info

Synthesis and Spectroscopic and Computational Characterization of Zn4O(Alicyclic or Aromatic Carboxylate)6 Complexes as Potential MOF Precursors Sndor B. tvs, Ott Berkesi, Tams Krtvlyesi and Istvn Plink pp 4620–4625 DOI: 10.1021/ic100205n Supporting Info

Facile Synthesis of Bis(dichalcogenophosphinate)s and a Remarkable [Li8(OH)6]2+ Polyhedron Robert P. Davies, M. Giovanna Martinelli, Laura Patel and Andrew J. P. White pp 4626–4631 DOI: 10.1021/ic100272y Supporting Info

Cyanide-Bridged Fe(III)−Mn(III) Bimetallic Systems Assembled from the fac-Fe Tricyanide and Mn Schiff bases: Structures, Magnetic Properties, and Density Functional Theory Calculations Hyun Young Kwak, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Hyoung Chan Kim, Eui Kwan Koh, Jamin Krinsky and Chang Seop Hong pp 4632–4642 DOI: 10.1021/ic100301q Supporting Info

Terbium-Macrocycle Complexes as Chemical Sensors: Detection of an Aspirin Metabolite in Urine Using a Salicylurate-Specific Receptor Site Taran L. Esplin, Morgan L. Cable, Harry B. Gray and Adrian Ponce pp 4643–4647 DOI: 10.1021/ic1003066 Supporting Info

(dme)MCl3(NNPh2) (dme = dimethoxyethane; M = Nb, Ta): A Versatile Synthon for [Ta═NNPh2] Hydrazido(2-) Complexes Ian A. Tonks and John E. Bercaw pp 4648–4656 DOI: 10.1021/ic1004193 Supporting Info

Eu(III) Complexes of Tetradentate Ligands Related to 2,9-Di(pyrid-2′-yl)-1,10-phenanthroline and 2,2′-Bi-1,10-phenanthroline Ruifa Zong, Gang Zhang, Svetlana V. Eliseeva, Jean-Claude G. Bnzli and Randolph P. Thummel pp 4657–4664 DOI: 10.1021/ic100338t Supporting Info

Use of Molecular Electrostatic Potential at the Carbene Carbon as a Simple and Efficient Electronic Parameter of N-heterocyclic Carbenes Jomon Mathew and Cherumuttathu H. Suresh pp 4665–4669 DOI: 10.1021/ic1004243 Supporting Info

La4LiAuO8 and La2BaPdO5: Comparing Two Highly Stable d8 Square-Planar Oxides Joshua A. Kurzman, Xiaoying Ouyang, Won Bin Im, Jun Li, Jerry Hu, Susannah L. Scott and Ram Seshadri pp 4670–4680 DOI: 10.1021/ic100486g

Synthesis, Multinuclear NMR Spectra, and X-ray Structures of tBu2PNP(I)tBu2 and EPR2NP(I)R2 (E = Se, Te; R = iPr, tBu) Jamie S. Ritch, Stuart D. Robertson, Maarit Risto and Tristram Chivers pp 4681–4686 DOI: 10.1021/ic1005055 Supporting Info

Redox-Active Tripodal Aminetris(aryloxide) Complexes of Titanium(IV) Davide Lionetti, Andrew J. Medvecz, Vesela Ugrinova, Mauricio Quiroz-Guzman, Bruce C. Noll and Seth N. Brown pp 4687–4697 DOI: 10.1021/ic100347h Supporting Info

Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand Keith Izod, John Stewart, Ewan R. Clark, William Clegg and Ross W. Harrington pp 4698–4707 DOI: 10.1021/ic1003534 Supporting Info

Cleavage of Sn−C and S−Calkyl Bonds on an Organotin Scaffold: Synthesis and Characterization of a Novel Organotin-Sulfite Cluster Bearing Methyltin- and Dimethyltin Fragments Ravi Shankar, Archana Jain, Gabriele Kociok-Khn, Mary F. Mahon and Kieran C. Molloy pp 4708–4715 DOI: 10.1021/ic100465u Supporting Info

Issue 11

A Chiral 2,6-Bis(Oxazolinyl)Pyridine Ligand with Amide Groups to Form Isomorphous Complexes through All the Lanthanoid Series Kenji Matsumoto, Keita Suzuki, Toshiaki Tsukuda and Taro Tsubomura pp 4717–4719 DOI: 10.1021/ic901743q Supporting Info

fac-{Ru(CO)3}2+ Selectively Targets the Histidine Residues of the β-Amyloid Peptide 1-28. Implications for New Alzheimer's Disease Treatments Based on Ruthenium Complexes Daniela Valensin, Paolo Anzini, Elena Gaggelli, Nicola Gaggelli, Gabriella Tamasi, Renzo Cini, Chiara Gabbiani, Elena Michelucci, Luigi Messori, Henryk Kozlowski and Gianni Valensin pp 4720–4722 DOI: 10.1021/ic902593e Supporting Info

Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties Woo Ram Lee, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Eui Kwan Koh and Chang Seop Hong pp 4723–4725 DOI: 10.1021/ic902182x Supporting Info

High Yield C-Derivatization of Weakly Coordinating Carborane Anions Matthew J. Nava and Christopher A. Reed pp 4726–4728 DOI: 10.1021/ic100053u Supporting Info

[Ru(bpy)3−n(dpb)n]2+: Unusual Photophysical Property and Efficient DNA Photocleavage Activity Qian-Xiong Zhou, Wan-Hua Lei, Yi Sun, Jing-Rong Chen, Chao Li, Yuan-Jun Hou, Xue-Song Wang and Bao-Wen Zhang pp 4729–4731 DOI: 10.1021/ic100193w Supporting Info

Synthesis of 1,4,7-Triphenyl-1,4,7-triphosphacyclononane: The First Metal-Free Synthesis of a [9]-aneP3R3 Ring Daniel J. Lowry and Monte L. Helm pp 4732–4734 DOI: 10.1021/ic100274m Supporting Info

Slow Magnetic Relaxation in Lanthanide Complexes with Chelating Nitronyl Nitroxide Radical Xiao-Ling Wang, Li-Cun Li and Dai-Zheng Liao pp 4735–4737 DOI: 10.1021/ic100008g Supporting Info

Enhancing the Magnetic Anisotropy of Cyano-Ligated Chromium(II) and Chromium(III) Complexes via Heavy Halide Ligand Effects Hemamala I. Karunadasa, Kristine D. Arquero, Louise A. Berben and Jeffrey R. Long pp 4738–4740 DOI: 10.1021/ic1002995 Supporting Info

A Solvent-Free Method for Making Dioxolane and Dioxane from the Biorenewables Glycerol and Furfural Catalyzed by Oxorhenium(V) Oxazoline Benjamin L. Wegenhart and Mahdi M. Abu-Omar pp 4741–4743 DOI: 10.1021/ic1004352 Supporting Info

Rhenium-Catalyzed Deoxydehydration of Glycols by Sulfite Saidi Vkuturi, Garry Chapman, Irshad Ahmad and Kenneth M. Nicholas pp 4744–4746 DOI: 10.1021/ic100467p Supporting Info

Coordination-Driven Self-Assembly of Three-Dimensional Supramolecular Dendrimers Yao-Rong Zheng, Koushik Ghosh, Hai-Bo Yang and Peter J. Stang pp 4747–4749 DOI: 10.1021/ic100330c Supporting Info

One-Pot Synthesis of a New Magnetically Coupled Heterometallic Cu2Mn2 [2 × 2] Molecular Grid Yurii S. Moroz, Łukasz Szyrwiel, Serhiy Demeshko, Henryk Kozłowski, Franc Meyer and Igor O. Fritsky pp 4750–4752 DOI: 10.1021/ic100555s Supporting Info

First Structurally Characterized Tricyanomanganate(III) and its Magnetic {MnIII2MII2} Complexes (MII = Mn, Ni) Minao Tang, Dongfeng Li, Uma Prasad Mallik, Jeffrey R. Withers, Shari Brauer, Michael R. Rhodes, Rodolphe Clrac, Gordon T. Yee, Myung-Hwan Whangbo and Stephen M. Holmes pp 4753–4755 DOI: 10.1021/ic1006605 Supporting Info

Divergent Syntheses of Copper−Indium Bimetallic Single-Source Precursors via Thiolate Ligand Exchange Chivin Sun, Richard D. Westover, Kelsey R. Margulieux, Lev N. Zakharov, Andrew W. Holland and Joshua J. Pak pp 4756–4758 DOI: 10.1021/ic1006692 Supporting Info

Oxidation of Glutathione by [FeIV(O)(N4Py)]2+: Characterization of an [FeIII(SG)(N4Py)]2+ Intermediate Ashley A. Campanali, Timothy D. Kwiecien, Lew Hryhorczuk and Jeremy J. Kodanko pp 4759–4761 DOI: 10.1021/ic100439n Supporting Info

Cesium Hydroperoxostannate: First Complete Structural Characterization of a Homoleptic Hydroperoxocomplex Andrei V. Churakov, Sergey Sladkevich, Ovadia Lev, Tatiana A. Tripol’skaya and Petr V. Prikhodchenko pp 4762–4764 DOI: 10.1021/ic100554u Supporting Info

Structure of Silver(I) Complex Prepared from Azobenzenonaphthalenophane, Photochemical Coordination Change of Silver(I) and Silver(I)-Induced Acceleration of Z−E Thermal Isomerization of Azobenzene Unit Yoshimi Oka and Nobuyuki Tamaoki pp 4765–4767 DOI: 10.1021/ic100317p Supporting Info

Syntheses and Multi-NMR Study of fac- and mer-OsO3F2(NCCH3) and the X-ray Crystal Structure (n = 2) and Raman Spectrum (n = 0) of fac-OsO3F2(NCCH3)·nCH3CN Michael J. Hughes, Michael Gerken, Hlne P. A. Mercier and Gary J. Schrobilgen pp 4768–4780 DOI: 10.1021/ic100383p Supporting Info

Investigation of the Structural Properties of an Extended Series of Lanthanide Bis-hydroxychlorides Ln(OH)2Cl (Ln = Nd−Lu, except Pm and Sm) Ralph A. Zehnder, David L. Clark, Brian L. Scott, Robert J. Donohoe, Phillip D. Palmer, Wolfgang H. Runde and David E. Hobart pp 4781–4790 DOI: 10.1021/ic901617c Supporting Info

Solution Speciation, Kinetics, and Observing Reaction Intermediates in the Alkylation of Oxidovanadium Compounds Jessica M. Fautch and Jonathan J. Wilker pp 4791–4801 DOI: 10.1021/ic901922m Supporting Info

Effects of Solvation on the Spin State of Iron(III) in 2,8,12,18-Tetrabutyl-3,7,13,17-tetramethyl-5,10-diazaporphyrinatoiron(III) Chloride Pavel A. Stuzhin, Sergei E. Nefedov, Roman S. Kumeev, Anwar Ul-Haq, Vadim V. Minin and Svetlana S. Ivanova pp 4802–4813 DOI: 10.1021/ic9012075 Supporting Info

A New Hexanuclear Iron−Selenium Nitrosyl Cluster: Primary Exploration of the Preparation Methods, Structure, and Spectroscopic and Electrochemical Properties Rongming Wang, Wei Xu, Jian Zhang and Lijuan Li pp 4814–4819 DOI: 10.1021/ic9014509 Supporting Info

Click-Triazole N2 Coordination to Transition-Metal Ions Is Assisted by a Pendant Pyridine Substituent Damijana Urankar, Balazs Pinter, Andrej Pevec, Frank De Proft, Iztok Turel and Janez Komrlj pp 4820–4829 DOI: 10.1021/ic902354e Supporting Info

Synthesis, Characterization, and Crystal Structure of a New Trisodium Triborate, Na3[B3O4(OH)4] Jrme Andrieux, Christelle Goutaudier, Laetitia Laversenne, Erwann Jeanneau and Philippe Miele pp 4830–4835 DOI: 10.1021/ic902525s Supporting Info

Hydrogenation Inducing Ferromagnetism in the Ternary Antiferromagnet NdCoSi Sophie Tenc, Samir F. Matar, Gilles Andr, Etienne Gaudin and Bernard Chevalier pp 4836–4842 DOI: 10.1021/ic902079u

Self-Association of Ruthenium(II) Polypyridyl Complexes and Their Interactions with Calf Thymus DNA Satish S. Bhat, Avinash S. Kumbhar, Peter Lnnecke and Evamarie Hey-Hawkins pp 4843–4853 DOI: 10.1021/ic902374t Supporting Info

Differences Between Amine- and Phosphine-Boranes: Synthesis, Photoelectron Spectroscopy, and Quantum Chemical Study of the Cyclopropylic Derivatives Balzs Nmeth, Brahim Khater, Jean-Claude Guillemin and Tams Veszprmi pp 4854–4864 DOI: 10.1021/ic902180p Supporting Info

Sila-Substitution of Alkyl Nitrates: Synthesis, Structural Characterization, and Sensitivity Studies of Highly Explosive (Nitratomethyl)-, Bis(nitratomethyl)-, and Tris(nitratomethyl)silanes and Their Corresponding Carbon Analogues Camilla Evangelisti, Thomas M. Klaptke, Burkhard Krumm, Anian Nieder, Raphael J. F. Berger, Stuart A. Hayes, Norbert W. Mitzel, Dennis Troegel and Reinhold Tacke pp 4865–4880 DOI: 10.1021/ic902387y Supporting Info

Crystallographic, Photophysical, NMR Spectroscopic and Reactivity Manifestations of the “8-Heteroaryl Effect” in 4,4-Difluoro-8-(C4H3X)-4-bora-3a,4a-diaza-s-indacene (X = O, S, Se) (BODIPY) Systems Kibong Kim, Changbum Jo, Shanmugam Easwaramoorthi, Jooyoung Sung, Dong Ho Kim and David G. Churchill pp 4881–4894 DOI: 10.1021/ic902467h Supporting Info

Influence of the Oxygen Atom Acceptor on the Reaction Coordinate and Mechanism of Oxygen Atom Transfer From the Dioxo-Mo(VI) Complex, TpiPrMoO2(OPh), to Tertiary Phosphines Partha Basu, Brian W. Kail and Charles G. Young pp 4895–4900 DOI: 10.1021/ic902500h Supporting Info

Interaction of Thioether Groups at the Open Coordination Sites of Palladium(II) and Platinum(II) Complexes Probed by Luminescence Spectroscopy at Variable Pressure Esther Pierce, Etienne Lanthier, Caroline Genre, Yurii Chumakov, Dominique Luneau and Christian Reber pp 4901–4908 DOI: 10.1021/ic9024958 Supporting Info

Prussian Blue Analogues for CO2 and SO2 Capture and Separation Applications Praveen K. Thallapally, Radha Kishan Motkuri, Carlos A. Fernandez, B. Peter McGrail and Ghorishi S. Behrooz pp 4909–4915 DOI: 10.1021/ic902397w Supporting Info

Luminescence Dynamics in Tb3+-Doped CaWO4 and CaMoO4 Crystals Enrico Cavalli, Philippe Boutinaud, Rachid Mahiou, Marco Bettinelli and Pieter Dorenbos pp 4916–4921 DOI: 10.1021/ic902445c

Color Tuning of Direct White Light of Lanthanum Aluminate with Mixed-Valence Europium Zhi-yong Mao and Da-jian Wang pp 4922–4927 DOI: 10.1021/ic902538a Supporting Info

On the Mechanism of Oxygen Exchange Between Uranyl(VI) Oxygen and Water in Strongly Alkaline Solution as Studied by 17O NMR Magnetization Transfer Zoltn Szab and Ingmar Grenthe pp 4928–4933 DOI: 10.1021/ic9025624 Supporting Info

Structure, Photophysical Properties, and DFT Calculations of Selenide-Centered Pentacapped Trigonal Prismatic Silver(I) Clusters C. W. Liu, Ching-Shiang Feng, Rei-Jen Fu, Hao-Wei Chang, Jean-Yves Saillard, Samia Kahlal, Ju-Chun Wang and I-Jy Chang pp 4934–4941 DOI: 10.1021/ic902571q Supporting Info

Highly Volatile Magnesium Complexes with the Aminodiboranate Anion, a New Chelating Borohydride. Synthesis and Characterization of Mg(H3BNMe2BH3)2 and Related Compounds Do Young Kim and Gregory S. Girolami pp 4942–4948 DOI: 10.1021/ic1000667 Supporting Info

Cobalt, Manganese, Nickel, and Vanadium Derivatives of the Cyclic 48-Tungsto-8-Phosphate [H7P8W48O184]33− Bassem S. Bassil, Masooma Ibrahim, Sib Sankar Mal, Andreas Suchopar, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Saritha Nellutla, Johan van Tol, Naresh S. Dalal and Ulrich Kortz pp 4949–4959 DOI: 10.1021/ic100050r Supporting Info

Cyclometalated Ru Complexes of Type [RuII(NN)2(CN)]z: Physicochemical Response to Substituents Installed on the Anionic Ligand Paolo G. Bomben, Bryan D. Koivisto and Curtis P. Berlinguette pp 4960–4971 DOI: 10.1021/ic100063c Supporting Info

Highly Convenient Regioselective Intermolecular Hydroamination of Alkynes Yielding Ketimines Catalyzed by Gold(I) Complexes of 1,2,4-triazole Based N-heterocyclic Carbenes Chandrakanta Dash, Mobin M. Shaikh, Ray J. Butcher and Prasenjit Ghosh pp 4972–4983 DOI: 10.1021/ic100087d Supporting Info

Design of Luminescent Biotinylation Reagents Derived from Cyclometalated Iridium(III) and Rhodium(III) Bis(pyridylbenzaldehyde) Complexes Siu-Kit Leung, Karen Ying Kwok, Kenneth Yin Zhang and Kenneth Kam-Wing Lo pp 4984–4995 DOI: 10.1021/ic100092d Supporting Info

Low-Temperature Coprecipitation Synthesis and Luminescent Properties of LaPO4:Ln3+ (Ln3+ = Ce3+, Tb3+) Nanowires and LaPO4:Ce3+,Tb3+/LaPO4 Core/Shell Nanowires Mei Yang, Hongpeng You, Kai Liu, Yuhua Zheng, Ning Guo and Hongjie Zhang pp 4996–5002 DOI: 10.1021/ic100099w Supporting Info

Investigation on the Protonation of a Trisubstituted [Fe2(CO)3(PPh3)(κ2-phen)(μ-pdt)] Complex: Rotated versus Unrotated Intermediate Pathways Pierre-Yves Orain, Jean-Franois Capon, Frdric Gloaguen, Franois Y. Ptillon, Philippe Schollhammer and Jean Talarmin, Giuseppe Zampella and Luca De Gioia, Thierry Roisnel pp 5003–5008 DOI: 10.1021/ic100108h Supporting Info

Building Metallacrown Topology around a Discrete [M3(μ3-O)] (M = Ni(II) and Pd(II)) Core Using Oximato Oxygen Linkers: Synthesis, Structures, and Spectroscopic Characterization of a New Family of Compounds with an Inverse-9-MC-3 Motif Anandalok Audhya, Kisholoy Bhattacharya, Manoranjan Maity and Muktimoy Chaudhury pp 5009–5015 DOI: 10.1021/ic100179q Supporting Info

Synthesis and Structural Characterization of Cationic 5-Hydroxy-1,3-diketonate Stabilized Dinuclear Complexes and Tetranuclear Lanthanoid Clusters Philip C. Andrews, William J. Gee, Peter C. Junk and Jonathan G. MacLellan pp 5016–5024 DOI: 10.1021/ic1001732 Supporting Info

Highly Solvent Dependent Luminescence from [Ru(bpy)n(dppp2)3−n]2+ (n = 0−2) Yujie Sun and Claudia Turro pp 5025–5032 DOI: 10.1021/ic100106b Supporting Info

Control of Metal Ion Size-Based Selectivity through Chelate Ring Geometry. Metal Ion Complexing Properties of 2,2′-Biimidazole David Buist, Neil J. Williams, Joseph H. Reibenspies and Robert D. Hancock pp 5033–5039 DOI: 10.1021/ic100131z Supporting Info

Thiocyanation of closo-Dodecaborate B12H122−. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism Martin Lepk, Martin Srnec, Jaromr Pleek, Milo Budnsk, Blanka Klepetov, Drahomr Hnyk, Bohumr Grner and Lubomr Rulek pp 5040–5048 DOI: 10.1021/ic100206y Supporting Info

Synthesis, Characterization, Photophysical, and Anion-Binding Studies of Luminescent Heteroleptic Bis-Tridentate Ruthenium(II) Complexes Based on 2,6-Bis(Benzimidazole-2-yl)Pyridine and 4′-Substituted 2,2′:6′,2′′ Terpyridine Derivatives Chanchal Bhaumik, Shyamal Das, Debasish Saha, Supriya Dutta and Sujoy Baitalik pp 5049–5062 DOI: 10.1021/ic100138s Supporting Info

Thermodynamic and Kinetic Control on the Formation of Two Novel Metal-Organic Frameworks Based on the Er(III) Ion and the Asymmetric Dimethylsuccinate Ligand Mara C. Bernini, Victor A. de la Pea-O’Shea, Marta Iglesias, Natalia Snejko, Enrique Gutierrez-Puebla, Elena V. Brusau, Griselda E. Narda, Francesc Illas and M. ngeles Monge pp 5063–5071 DOI: 10.1021/ic100181d Supporting Info

Dendritically Encapsulated, Water-Soluble Fe4S4: Synthesis and Electrochemical Properties Anil K. Sharma, Namjin Kim, Christopher S. Cameron, Matthew Lyndon and Christopher B. Gorman pp 5072–5078 DOI: 10.1021/ic1002447 Supporting Info

Tetrahedral and Square Planar Ni[(SPR2)2N]2 complexes, R = Ph & iPr Revisited: Experimental and Theoretical Analysis of Interconversion Pathways, Structural Preferences, and Spin Delocalization Dimitrios Maganas, Alexios Grigoropoulos, Sarah S. Staniland, Spyros D. Chatziefthimiou, Andrew Harrison, Neil Robertson, Panayotis Kyritsis and Frank Neese pp 5079–5093 DOI: 10.1021/ic100163g Supporting Info

Synthesis, Structures, and Electroluminescent Properties of Scandium N,O-Chelated Complexes toward Near-White Organic Light-Emitting Diodes Marina A. Katkova, Tatyana V. Balashova, Vasilii A. Ilichev, Alexey N. Konev, Nikolai A. Isachenkov, Georgy K. Fukin, Sergey Yu. Ketkov and Mikhail N. Bochkarev pp 5094–5100 DOI: 10.1021/ic1002429 Supporting Info

A Quantum Mechanical Charge Field Molecular Dynamics Study of Fe2+ and Fe3+ Ions in Aqueous Solutions Syed Tarique Moin, Thomas S. Hofer, Andreas B. Pribil, Bernhard R. Randolf and Bernd M. Rode pp 5101–5106 DOI: 10.1021/ic1002572

Highly Luminescent Tetradentate Bis-Cyclometalated Platinum Complexes: Design, Synthesis, Structure, Photophysics, and Electroluminescence Application Dileep A. K. Vezzu, Joseph C. Deaton, James S. Jones, Libero Bartolotti, Caleb F. Harris, Alfred P. Marchetti, Marina Kondakova, Robert D. Pike and Shouquan Huo pp 5107–5119 DOI: 10.1021/ic1002226 Supporting Info

New Tetraazaannulene Hosts for Fullerenes Jimmy U. Franco, Justin C. Hammons, Daniel Rios and Marilyn M. Olmstead pp 5120–5125 DOI: 10.1021/ic1002513 Supporting Info

CuII Cross-Linked Antiparallel Dipeptide Duplexes Using Heterofunctional Ligand-Substituted Aminoethylglycine Matthew B. Coppock, Matthew T. Kapelewski, Hye Won Youm, Lauren A. Levine, James R. Miller, Carl P. Myers and Mary Elizabeth Williams pp 5126–5133 DOI: 10.1021/ic100252g Supporting Info

Supramolecular Aggregation/Deaggregation in Amphiphilic Dipolar Schiff-Base Zinc(II) Complexes Giuseppe Consiglio, Salvatore Failla, Paolo Finocchiaro, Ivan Pietro Oliveri, Roberto Purrello and Santo Di Bella pp 5134–5142 DOI: 10.1021/ic100284r Supporting Info

NCN Trianionic Pincer Ligand Precursors: Synthesis of Bimetallic, Chelating Diamide, and Pincer Group IV Complexes Soumya Sarkar, Kevin P. McGowan, Jeffrey A. Culver, Adam R. Carlson, Jrgen Koller, Andrew J. Peloquin, Melanie K. Veige, Khalil A. Abboud and Adam S. Veige pp 5143–5156 DOI: 10.1021/ic100232s Supporting Info

Synthesis, Characterization, and Structures of Uranium(III) N,N-Dimethylaminodiboranates Scott R. Daly and Gregory S. Girolami pp 5157–5166 DOI: 10.1021/ic100290j Supporting Info

The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching Kelvin B. Chang, Desmond J. Hubbard, Matthias Zeller, Joshua Schrier and Alexander J. Norquist pp 5167–5172 DOI: 10.1021/ic100297c Supporting Info

Isolated ∞1[ZnPn2]4− Chains in the Zintl Phases Ba2ZnPn2 (Pn = As, Sb, Bi)—Synthesis, Structure, and Bonding Bayrammurad Saparov and Svilen Bobev pp 5173–5179 DOI: 10.1021/ic100296x Supporting Info

Effect of Sulfur-Based Substituents on the Electronic Properties of Re(I) dppz Complexes Michael G. Fraser, Allan G. Blackman, Garth I. S. Irwin, Campbell P. Easton and Keith C. Gordon pp 5180–5189 DOI: 10.1021/ic1003116 Supporting Info

Thermodynamics of Core Metal Replacement and Self-Assembly of Ca2+ 15-Metallacrown-5 Matteo Tegoni, Michele Furlotti, Manuel Tropiano, Choong Sun Lim and Vincent L. Pecoraro pp 5190–5201 DOI: 10.1021/ic100315u Supporting Info

Synthesis, Characterization, and Theoretical Studies of Metal Complexes Derived from the Chiral Tripyridyldiamine Ligand Bn-CDPy3 Ahmed I. Abouelatta, Jason A. Sonk, Mirvat M. Hammoud, Danielle M. Zurcher, Joshua J. McKamie, H. Bernhard Schlegel and Jeremy J. Kodanko pp 5202–5211 DOI: 10.1021/ic100322p Supporting Info

Effect of the Central Oxoanion Size on the Voltammetric Properties of Keggin-Type [XW12O40]n− (n = 2−6) Complexes Kiyomi Nakajima, Kazuo Eda and Sadayuki Himeno pp 5212–5215 DOI: 10.1021/ic1003353 Supporting Info

On the Analysis of the Cr−Cr Multiple Bond in Several Classes of Dichromium Compounds G. La Macchia, G. Li Manni, T. K. Todorova, M. Brynda, F. Aquilante, B. O. Roos and L. Gagliardi pp 5216–5222 DOI: 10.1021/ic100345b Supporting Info

Synthesis, Characterization, and Crystal Structures of Silylium Compounds of the Weakly Coordinating Dianion [B12Cl12]2− Mathias Kessler, Carsten Knapp, Vanessa Sagawe, Harald Scherer and Rabiya Uzun pp 5223–5230 DOI: 10.1021/ic100337k Supporting Info

Disubstituted 1,8-Diamidonaphthalene Ligands as a Flexible, Responsive, and Reactive Framework for Tantalum Complexes Nathalie Lavoie, Serge I. Gorelsky, Zhixian Liu, Tara J. Burchell, Glenn P. A. Yap and Darrin S. Richeson pp 5231–5240 DOI: 10.1021/ic1003963 Supporting Info

Six-Membered Electron Transfer Series [V(dithiolene)3]z (z = 1+, 0, 1−, 2−, 3−, 4−). An X-ray Absorption Spectroscopic and Density Functional Theoretical Study Stephen Sproules, Thomas Weyhermller, Serena DeBeer and Karl Wieghardt pp 5241–5261 DOI: 10.1021/ic100344f Supporting Info

Synthesis, Structure, and Characterization of the Series BaBi1−xTaxO3 (0 ≤ x ≤ 0.5) Hui Wang, Chun-Hai Wang, Guobao Li, Tounan Jin, Fuhui Liao and Jianhua Lin pp 5262–5270 DOI: 10.1021/ic100361y Supporting Info

Metal-Dependent Phase Selection in Coordination Polymers Derived from a C2v-Symmetric Tricarboxylate Choong-Sun Lim, Jennifer K. Schnobrich, Antek G. Wong-Foy and Adam J. Matzger pp 5271–5275 DOI: 10.1021/ic100378p Supporting Info

Understanding the Borane Analogy in AlnHn+4 (n = 5−19): Unprecedented Stability of a Non-Wade−Mingos Cluster Al8H12 Fused by Two Td-like Al4H6 Li-juan Fu, Lin Jin, Chang-bin Shao and Yi-hong Ding pp 5276–5284 DOI: 10.1021/ic100429b Supporting Info

Cation Size and Anion Anisotropy in Structural Chemistry of Metal Borohydrides. The Peculiar Pressure Evolution of RbBH4 Yaroslav Filinchuk, Alexandr V. Talyzin, Hans Hagemann, Vladimir Dmitriev, Dmitry Chernyshov and Bertil Sundqvist pp 5285–5292 DOI: 10.1021/ic100359v Supporting Info

Family of MnIII2Ln2(μ4-O) Compounds: Syntheses, Structures, and Magnetic Properties Valeriu Mereacre, Yanhua Lan, Rodolphe Clrac, Ayuk M. Ako, Ian J. Hewitt, Wolfgang Wernsdorfer, Gernot Buth, Christopher E. Anson and Annie K. Powell pp 5293–5302 DOI: 10.1021/ic100373r Supporting Info

Synthesis, Characterization, and Photophysical Properties of Three Platinum(II) Complexes Bearing Fluorescent Analogues of the Di-2-pyridylmethane Ligand Justin J. Wilson, Juliana Fedoce Lopes and Stephen J. Lippard pp 5303–5315 DOI: 10.1021/ic100411p Supporting Info

Molecular Recognition of Inositol 1,4,5-Trisphosphate and Model Compounds in Aqueous Solution by Ditopic Zn2+ Complexes Containing Chiral Linkers Masanori Kitamura, Hiroyuki Nishimoto, Keita Aoki, Masato Tsukamoto and Shin Aoki pp 5316–5327 DOI: 10.1021/ic1004038 Supporting Info

High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand Deborha Bacciu, Chun-Hsing Chen, Panida Surawatanawong, Bruce M. Foxman and Oleg V. Ozerov pp 5328–5334 DOI: 10.1021/ic1004424 Supporting Info

Issue 12

Triphenylamine-Modified Ruthenium(II) Terpyridine Complexes: Enhancement of Light Absorption by Conjugated Bridging Motifs Kiyoshi C. D. Robson, Bryan D. Koivisto, Terry J. Gordon, Thomas Baumgartner and Curtis P. Berlinguette pp 5335–5337 DOI: 10.1021/ic9025427 Supporting Info

Framework Contraction in Na-Stuffed Si(cF136) Matt Beekman, Emmanuel N. Nenghabi, Koushik Biswas, Charles W. Myles, Michael Baitinger, Yuri Grin and George S. Nolas pp 5338–5340 DOI: 10.1021/ic1005049 Supporting Info

Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis Polly L. Arnold, Natalie A. Potter (ne Jones), Nicola Magnani, Christos Apostolidis, Jean-Christophe Griveau, Eric Colineau, Alfred Morgenstern, Roberto Caciuffo and Jason B. Love pp 5341–5343 DOI: 10.1021/ic100374j Supporting Info

Asymmetric Oxygenation of a Ruthenium Dithiolate Mimics the Mixed Sulfenato/Sulfinato Donor Sets of Nitrile Hydratase and Thiocyanate Hydrolase Csar A. Masitas, Mark S. Mashuta and Craig A. Grapperhaus pp 5344–5346 DOI: 10.1021/ic100414c Supporting Info

Chains of Face-Sharing {ZPr6} Octahedra with Alternating Endohedral Iridium Atoms and Chloride Ions in {(Ir,Cl)Pr6}Cl10 Nina Herzmann, Matthias Brhmann, Anja-Verena Mudring and Gerd Meyer pp 5347–5349 DOI: 10.1021/ic100487k Supporting Info

Multidentate Ligands for the Synthesis of Multimetallic Complexes. 2. Formation of a Planar Cu4OH Motif Abdullahi Mustapha, John Reglinski, Alan R. Kennedy, David R. Armstrong, Jrg Sassmannshausen and Mark Murrie pp 5350–5352 DOI: 10.1021/ic100594n Supporting Info

Trinuclear Nickel(II) Complex through a 2,3,5,6-Tetrakis(2-pyridyl)pyrazine Ligand with a Linear Exchange Pathway Lorena M. Callejo, Gotzon Madariaga, Luis Lezama, Luz Fidalgo, Noelia De la Pinta and Roberto Corts pp 5353–5355 DOI: 10.1021/ic100562e Supporting Info

Temperature-Dependent Supramolecular Motif in Coordination Compounds Hamid Reza Khavasi and Bahareh Mir Mohammad Sadegh pp 5356–5358 DOI: 10.1021/ic100604k Supporting Info

Novel Polynuclear Nickel(II) Complex: Hydrazine, Sulfato, and Hydroxo Bridging in an Unusual Metal Hexamer. Crystal Structure and Magnetic Properties of [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 Magnus Gustafsson, Andreas Fischer, Andrey Ilyukhin, Mikhail Maliarik and Per Nordblad pp 5359–5361 DOI: 10.1021/ic100648c Supporting Info

Bulky Bisphenol Ligand-Supported Aluminum−Sodium Inverse Crown Ether Complex Jincai Wu, Xiaobo Pan, Ning Tang and Chu-Chieh Lin pp 5362–5364 DOI: 10.1021/ic1006555 Supporting Info

Is Halogen Bonding the Basis for Iodothyronine Deiodinase Activity? Craig A. Bayse and Erin R. Rafferty pp 5365–5367 DOI: 10.1021/ic100711n Supporting Info

Monooxomolybdenum(VI) Complexes Possessing Olefinic Dithiolene Ligands: Probing Mo−S Covalency Contributions to Electron Transfer in Dimethyl Sulfoxide Reductase Family Molybdoenzymes Hideki Sugimoto, Susumu Tatemoto, Koichiro Suyama, Hiroyuki Miyake, Regina P. Mtei, Shinobu Itoh and Martin L. Kirk pp 5368–5370 DOI: 10.1021/ic100825x Supporting Info

Photophysical Properties, DNA Photocleavage, and Photocytotoxicity of a Series of Dppn Dirhodium(II,II) Complexes Lauren E. Joyce, J. Dafhne Aguirre, Alfredo M. Angeles-Boza, Abdellatif Chouai, Patty K.-L. Fu, Kim R. Dunbar and Claudia Turro pp 5371–5376 DOI: 10.1021/ic100588d Supporting Info

Characterization of A New Copper(I)−Nitrito Complex That Evolves Nitric Oxide Wan-Jung Chuang, I-Jung Lin, Hsing-Yin Chen, Yu-Lun Chang and Sodio C. N. Hsu pp 5377–5384 DOI: 10.1021/ic100083b Supporting Info

To Bend or Not to Bend: Electronic Structural Analysis of Linear versus Bent M−H−M Interactions in Dinickel Bis(dialkylphosphino)methane Complexes Zakiya S. Wilson and George G. Stanley, David A. Vicic pp 5385–5392 DOI: 10.1021/ic902198b Supporting Info

Bisamidate and Mixed Amine/Amidate NiN2S2 Complexes as Models for Nickel-Containing Acetyl Coenzyme A Synthase and Superoxide Dismutase: An Experimental and Computational Study Vaidyanathan Mathrubootham, Jason Thomas, Richard Staples, John McCraken, Jason Shearer and Eric L. Hegg pp 5393–5406 DOI: 10.1021/ic9023053 Supporting Info

First Representative of Optically Active P-l-Menthyl-Substituted (Aminomethyl)phosphine and Its Borane and Metal Complexes Svetlana N. Ignatieva, Anna S. Balueva, Andrey A. Karasik, Shamil K. Latypov, Anna G. Nikonova, Olga E. Naumova, Peter Lnnecke, Evamarie Hey-Hawkins and Oleg G. Sinyashin pp 5407–5412 DOI: 10.1021/ic902564n Supporting Info

Anhydrides of Real and Hypothetical [Hydroxy(R−O)iodo]benzenes Helen W. Richter, Noel M. Paul, Dale G. Ray, Charlotte A. Ray, Louise M. Liable-Sands, Tom Concolino, Matthew Lam, Arnold L. Rheingold, Gerald F. Koser and James A. Golen pp 5413–5423 DOI: 10.1021/ic1007318 Supporting Info

Solution Synthesis and Characterization of Indium−Zinc Formate Precursors for Transparent Conducting Oxides Robert M. Pasquarelli, Calvin J. Curtis, Alexander Miedaner, Maikel F.A.M. van Hest, Ryan P. O’Hayre and David S. Ginley pp 5424–5431 DOI: 10.1021/ic902430w Supporting Info

Luminescent Dendritic Cyclometalated Iridium(III) Polypyridine Complexes: Synthesis, Emission Behavior, and Biological Properties Kenneth Yin Zhang, Hua-Wei Liu, Tommy Tsz-Him Fong, Xian-Guang Chen and Kenneth Kam-Wing Lo pp 5432–5443 DOI: 10.1021/ic902443e Supporting Info

Synthesis and Structural Studies of Chiral Indium(III) Complexes Supported by Tridentate Diaminophenol Ligands Alberto Acosta-Ramrez, Amy F. Douglas, Insun Yu, Brian O. Patrick, Paula L. Diaconescu and Parisa Mehrkhodavandi pp 5444–5452 DOI: 10.1021/ic100185m Supporting Info

Interfacial Confined Formation of Mesoporous Spherical TiO2 Nanostructures with Improved Photoelectric Conversion Efficiency Wei Shao, Feng Gu, Chunzhong Li and Mengkai Lu pp 5453–5459 DOI: 10.1021/ic902553f Supporting Info

CrIII−CrIII Interactions in Two Alkoxo-Bridged Heterometallic Zn2Cr2 Complexes Self-Assembled from Zinc Oxide, Reinecke’s Salt, and Diethanolamine Valentyna V. Semenaka, Oksana V. Nesterova, Volodymyr N. Kokozay, Viktoriya V. Dyakonenko, Roman I. Zubatyuk, Oleg V. Shishkin, Roman Boa, Julia Jezierska and Andrew Ozarowski pp 5460–5471 DOI: 10.1021/ic1000123 Supporting Info

On the Origin of the Inverted Stability Order of the Reverse-Keggin [(MnO4)(CH3)12Sb12O24]6−: A DFT Study of α, β, γ, δ, and ε Isomers Fu-Qiang Zhang, Wei Guan, Yin-Tang Zhang, Mao-Tian Xu, Jian Li and Zhong-Min Su pp 5472–5481 DOI: 10.1021/ic100343t Supporting Info

Ruthenium Complexes with Cooperative PNP-Pincer Amine, Amido, Imine, and Enamido Ligands: Facile Ligand Backbone Functionalization Processes Anja Friedrich, Markus Drees, Martina Kss, Eberhardt Herdtweck and Sven Schneider pp 5482–5494 DOI: 10.1021/ic100358m Supporting Info

DMF/H2O Volume Ratio Controls the Syntheses and Transformations of a Series of Cobalt Complexes Constructed Using a Rigid Angular Multitopic Ligand Ai-Yun Fu, Yu-Lin Jiang, Yao-Yu Wang, Xiao-Nan Gao, Guo-Ping Yang, Lei Hou and Qi-Zhen Shi pp 5495–5502 DOI: 10.1021/ic902548f Supporting Info

Orientation and Stereodynamic Paths of Planar Monodentate Ligands in Square Planar Nickel N2S Complexes Roxanne M. Jenkins, Michael L. Singleton, Lauren A. Leamer, Joseph H. Reibenspies and Marcetta Y. Darensbourg pp 5503–5514 DOI: 10.1021/ic1002012 Supporting Info

Tunable Aqueous Phase Synthesis and Shape-Dependent Electrochemical Properties of Rhodium Nanostructures Qiang Yuan, Zhiyou Zhou, Jing Zhuang and Xun Wang pp 5515–5521 DOI: 10.1021/ic100249t Supporting Info

Incorporation of Phosphorus Guest Ions in the Calcium Silicate Phases of Portland Cement from 31P MAS NMR Spectroscopy Søren L. Poulsen, Hans J. Jakobsen and Jørgen Skibsted pp 5522–5529 DOI: 10.1021/ic100140j

Study of the Coordination Abilities of Stibine Ligands to Gold(I) Vilma R. Bojan, Eduardo J. Fernndez, Antonio Laguna, Jos M. Lpez-de-Luzuriaga, Miguel Monge, M. Elena Olmos, Raquel C. Puelles and Cristian Silvestru pp 5530–5541 DOI: 10.1021/ic1003484 Supporting Info

Observation of Magnetic Ordering for Layered (2-D) Potassium Diruthenium Tetracarbonate, K3[RuII/III2(O2CO)4]: A Rare Second Row Transition Metal-based Magnet Bretni S. Kennon and Joel S. Miller pp 5542–5545 DOI: 10.1021/ic100357q

Prediction of Reliable Metal−PH3 Bond Energies for Ni, Pd, and Pt in the 0 and +2 Oxidation States Raluca Craciun, Andrew J. Vincent, Kevin H. Shaughnessy and David A. Dixon pp 5546–5553 DOI: 10.1021/ic1004853 Supporting Info

Synthesis and Reaction of Monomeric Germanium(II) and Lead(II) Dimethylamide and the Synthesis of Germanium(II) Hydrazide by Clevage of one N−H bond of Hydrazine Anukul Jana, Herbert W. Roesky, Carola Schulzke, Prinson P. Samuel and Alexander Dring pp 5554–5559 DOI: 10.1021/ic1003808 Supporting Info

NH NMR Shifts of New Structurally Characterized fac-[Re(CO)3(polyamine)]n+ Complexes Probed via Outer-Sphere Hydrogen-Bonding Interactions to Anions, Including the Paramagnetic [ReIVBr6]2− Anion Theshini Perera, Patricia A. Marzilli, Frank R. Fronczek and Luigi G. Marzilli pp 5560–5572 DOI: 10.1021/ic100386c Supporting Info

Basic Coordination Chemistry Relevant to DNA Adducts Formed by the Cisplatin Anticancer Drug. NMR Studies on Compounds with Sterically Crowded Chiral Ligands Jamil S. Saad, Michele Benedetti, Giovanni Natile and Luigi G. Marzilli pp 5573–5583 DOI: 10.1021/ic100494f Supporting Info

Ligand-to-Metal Ratio Controlled Assembly of Cobalt Complexes Containing ortho-Carborane Thiolato and Butyl Thiolato Ligands Yuguang Li, Qibai Jiang, Yizhi Li, Xujie Shen, Hong Yan and Vladimir I. Bregadze pp 5584–5590 DOI: 10.1021/ic100497h Supporting Info

Efficient Spin Filtering through Cobalt-Based Extended Metal Atom Chains Vihar P. Georgiev and John E. McGrady pp 5591–5597 DOI: 10.1021/ic100493t Supporting Info

Synthesis of Alkali Metal Indium Thiophosphates Containing the Discrete Anions [In(PS4)(PS5)2]6− and [In(PS4)2(PS5)]6− Alexander Rothenberger, Collin Morris and Mercouri G. Kanatzidis pp 5598–5602 DOI: 10.1021/ic100495b Supporting Info

Synthesis, Characterization, and Crystallographic Study of the PbO−Bi2O3−V2O5 System: Pb3−xBi2x/3V2O8 (0.20 ≤ x ≤ 0.50) Prangya Parimita Sahoo, Etienne Gaudin, Jacques Darriet and T. N. Guru Row pp 5603–5610 DOI: 10.1021/ic100488t Supporting Info

Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst Susan K. Hanson, R. Tom Baker, John C. Gordon, Brian L. Scott and David L. Thorn pp 5611–5618 DOI: 10.1021/ic100528n Supporting Info

Hydrothermal Synthesis of Two Cationic Bismuthate Clusters: An Alkylenedisulfonate Bridged Hexamer, [Bi6O4(OH)4(H2O)2][(CH2)2(SO3)2]3 and a Rare Nonamer Templated by Triflate, [Bi9O8(OH)6][CF3SO3]5 David L. Rogow, Honghan Fei, Daniel P. Brennan, Mariko Ikehata, Peter Y. Zavalij, Allen G. Oliver and Scott R. J. Oliver pp 5619–5624 DOI: 10.1021/ic1004402 Supporting Info

Role of Substitution on the Photophysical Properties of 5,5′-Diaryl-2,2′-bipyridine (bpy*) in [Ir(ppy)2(bpy*)]PF6 Complexes: A Combined Experimental and Theoretical Study Sbastien Ladouceur, Daniel Fortin and Eli Zysman-Colman pp 5625–5641 DOI: 10.1021/ic100521t Supporting Info

Kinetic Studies of the Initiation Step in Copper Catalyzed Atom Transfer Radical Addition (ATRA) in the Presence of Free Radical Diazo Initiators as Reducing Agents Marielle Nicole C. Balili and Tomislav Pintauer pp 5642–5649 DOI: 10.1021/ic100540q

Pyrophosphate-Bridged CuII Chain Magnet: {[Na3Cu(P2O7)(NO3)]·3H2O}n Rosana P. Sartoris, Ricardo C. Santana, Ricardo F. Baggio, Octavio Pea, Mireille Perec and Rafael Calvo pp 5650–5657 DOI: 10.1021/ic100398k Supporting Info

The Possible Role of 94−125 Peptide Fragment of Histone H2B in Nickel-Induced Carcinogenesis Ana Mnica Nunes, Kimon Zavitsanos, Rebecca Del Conte, Gerasimos Malandrinos and Nick Hadjiliadis pp 5658–5668 DOI: 10.1021/ic1005665 Supporting Info

Novel Cis- and Trans-Configured Bis(oxime)platinum(II) Complexes: Synthesis, Characterization, and Cytotoxic Activity Yulia Yu. Scaffidi-Domianello, Kristof Meelich, Michael A. Jakupec, Vladimir B. Arion, Vadim Yu. Kukushkin, Markus Galanski and Bernhard K. Keppler pp 5669–5678 DOI: 10.1021/ic100584b Supporting Info

Enhancement of the Curie Temperature along the Perovskite Series RCu3Mn4O12 Driven by Chemical Pressure of R3+ Cations (R = Rare Earths) Javier Snchez-Bentez, Jos Antonio Alonso, Mara Jess Martnez-Lope, Alicia de Andrs and Mara Teresa Fernndez-Daz pp 5679–5685 DOI: 10.1021/ic100699u Supporting Info

Influence of the Redox Active Ligand on the Reactivity and Electronic Structure of a Series of Fe(TIM) Complexes Corinna R. Hess, Thomas Weyhermller, Eckhard Bill and Karl Wieghardt pp 5686–5700 DOI: 10.1021/ic100586h Supporting Info

Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates Pius O. Adelani and Thomas E. Albrecht-Schmitt pp 5701–5705 DOI: 10.1021/ic1006132 Supporting Info

Tuning Size and Thermal Hysteresis in Bistable Spin Crossover Nanoparticles Jos Ramn Galn-Mascars, Eugenio Coronado, Alicia Forment-Aliaga, Mara Monrabal-Capilla, Elena Pinilla-Cienfuegos and Marcelo Ceolin pp 5706–5714 DOI: 10.1021/ic100751a Supporting Info

Activation of Bis(guanidinate)lanthanide Alkyl and Aryl Complexes on Elemental Sulfur: Synthesis and Characterization of Bis(guanidinate)lanthanide Thiolates and Disulfides Zhengxing Zhang, Lixin Zhang, Yanrong Li, Longcheng Hong, Zhenxia Chen and Xigeng Zhou pp 5715–5722 DOI: 10.1021/ic100617n Supporting Info

Insights into the Origin of Cooperative Effects in the Spin Transition of [Fe(NH2trz)3](NO3)2: the Role of Supramolecular Interactions Evidenced in the Crystal Structure of [Cu(NH2trz)3](NO3)2·H2O Marinela M. Drtu, Christine Neuhausen, Anil D. Naik, Aurelian Rotaru, Leonard Spinu and Yann Garcia pp 5723–5736 DOI: 10.1021/ic100667f Supporting Info

Density Functional Study of the Thermodynamics of Hydrogen Production by Tetrairon Hexathiolate, Fe4[MeC(CH2S)3]2(CO)8, a Hydrogenase Model Panida Surawatanawong and Michael B. Hall pp 5737–5747 DOI: 10.1021/ic100687v Supporting Info

Organotin Chalcogenide Salts: Synthesis, Characterization, and Extended Crystal Structures Zohreh Hassanzadeh Fard, Małgorzata Hołyska and Stefanie Dehnen pp 5748–5752 DOI: 10.1021/ic100700f Supporting Info

Synthesis and Reactions of Ethynylferrocene-Derived Fluoro- and Chlorocyclotriphosphazenes Karunesh Keshav, Nem Singh and Anil J. Elias pp 5753–5765 DOI: 10.1021/ic100703h Supporting Info

Synthesis and Characterization of Free-Base, Copper, and Nickel Isocorroles Giuseppe Pomarico, Xiao Xiao, Sara Nardis, Roberto Paolesse, Frank R. Fronczek, Kevin M. Smith, Yuanyuan Fang, Zhongping Ou and Karl M. Kadish pp 5766–5774 DOI: 10.1021/ic100730j Supporting Info

Direct Evidence on the Existence of [Mo132] Keplerate-Type Species in Aqueous Solution Soumyajit Roy, Karel L. Planken, Robbert Kim, Dexx v. d. Mandele and Willem K. Kegel p 5775 DOI: 10.1021/ic100859m

Issue 13

1000-Fold Enhancement of Luminescence Lifetimes via Energy-Transfer Equilibration with the T1 State of Zn(TPP) Brian W. Cohen, Benjamin M. Lovaasen, Cheslan K. Simpson, Scott D. Cummings, Richard F. Dallinger and Michael D. Hopkins pp 5777–5779 DOI: 10.1021/ic100316s Supporting Info

Ferromagnetic Ordering and Simultaneous Fast Magnetization Tunneling in a Ni4 Single-Molecule Magnet Christopher C. Beedle, John J. Henderson, Pei-Chun Ho, Todd Sayles, Motohiro Nakano, James R. O’Brien, Katie J. Heroux, Enrique del Barco, M. Brian Maple and David N. Hendrickson pp 5780–5782 DOI: 10.1021/ic1003947 Supporting Info

Zinc Germanates Incorporating Organic Amine Ligands: Solvothermal Synthesis and Structural Characterization of Zn2Ge4O10(NH2CH2CH2CH2NH2) and ZnGe2O5(NH2CH2CH2NH2) Chih-Min Wang, Chia-Hui Lin, Ciao-Wei Yang and Kwang-Hwa Lii pp 5783–5785 DOI: 10.1021/ic1004825 Supporting Info

Reactivity Studies of a GeI−GeI Compound with and without Cleavage of the Ge−Ge Bond Sakya S. Sen, Daniel Kratzert, Daniel Stern, Herbert W. Roesky and Dietmar Stalke pp 5786–5788 DOI: 10.1021/ic100501e Supporting Info

Lithium Complexes of N-Confused Porphyrin Saovalak Sripothongnak and Christopher J. Ziegler pp 5789–5791 DOI: 10.1021/ic1005659 Supporting Info

Unusual Dimeric Chemical Structure for a Carboplatin Analogue as a Potential Anticancer Complex Mingjin Xie, Weiping Liu, Liguang Lou, Xizhu Chen, Qingsong Ye, Yao Yu, Qiaowen Chang and Shuqian Hou pp 5792–5794 DOI: 10.1021/ic100638u Supporting Info

Complexes of the [K(18-Crown-6)]+ Fragment with Bis(tetrazolyl)borate Ligands: Unexpected Boron−Nitrogen Bond Isomerism and Associated Enforcement of κ3-N,N′,H-Ligand Chelation Dongmei Lu and Charles H. Winter pp 5795–5797 DOI: 10.1021/ic100959j Supporting Info

Recent Applications of a Synthetic Model of Cytochrome c Oxidase: Beyond Functional Modeling† This award article is an extended version of the Ronald Breslow Award for Achievement in Biomimetic Chemistry, 2009, presented at the 237th American Chemical Society National Meeting at Salt Lake City, UT. James P. Collman and Somdatta Ghosh pp 5798–5810 DOI: 10.1021/ic100472p

Syntheses, Crystal and Electronic Structures, and Physical Properties of Quaternary Semiconductors: Ln2Mn3Sb4S12 (Ln = Pr, Nd, Sm, Gd) Hua-Jun Zhao, Long-Hua Li, Li-Ming Wu and Ling Chen pp 5811–5817 DOI: 10.1021/ic9025206 Supporting Info

A Unifying Structural and Electronic Concept for Hmd and [FeFe] Hydrogenase Active Sites Martin T. Stiebritz and Markus Reiher pp 5818–5823 DOI: 10.1021/ic902529c

Photochromism, Electrical Properties, and Structural Investigations of a Series of Hydrated Methylviologen Halobismuthate Hybrids: Influence of the Anionic Oligomer Size and Iodide Doping on the Photoinduced Properties and on the Dehydration Process Nicolas Leblanc, Wenhua Bi, Nicolas Mercier, Pascale Auban-Senzier and Claude Pasquier pp 5824–5833 DOI: 10.1021/ic901525p Supporting Info

Reactivity of CuI and CuBr toward Et2S: a Reinvestigation on the Self-Assembly of Luminescent Copper(I) Coordination Polymers Michael Knorr, Abdoulaye Pam, Abderrahim Khatyr, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Shawkat M. Aly, Daniel Fortin and Pierre D. Harvey pp 5834–5844 DOI: 10.1021/ic901906h Supporting Info

Formation Mechanism of TiO2-Derived Titanate Nanotubes Prepared by the Hydrothermal Process Atsushi Nakahira, Takashi Kubo and Chiya Numako pp 5845–5852 DOI: 10.1021/ic9025816

A Five-Coordinate [2Fe−2S] Cluster Michael G. G. Fuchs, Sebastian Dechert, Serhiy Demeshko, Ulf Ryde and Franc Meyer pp 5853–5858 DOI: 10.1021/ic902559n Supporting Info

Preparation and Tunable Photoluminescence of Carbogenic Nanoparticles Confined in a Microporous Magnesium-Aluminophosphate Yang Xiu, Qian Gao, Guo-Dong Li, Kai-Xue Wang and Jie-Sheng Chen pp 5859–5867 DOI: 10.1021/ic1000039 Supporting Info

Synthesis, Structures, and Magnetism of Three 1D MnIII Chains with Oxazoline-Based Ligands Yan Zhang, Xiu-Teng Wang, Xiao-Man Zhang, Tian-Fu Liu, Wen-Guo Xu and Song Gao pp 5868–5875 DOI: 10.1021/ic100006a Supporting Info

Synthesis, Spectroscopic and Electrochemical Properties, and Electronic Structures of Octahedral Hexatechnetium(III) Clusters [Tc6Q8(CN)6]4− (Q = S, Se) Takashi Yoshimura, Takuya Ikai, Tsutomu Takayama, Tsutomu Sekine, Yasushi Kino and Atsushi Shinohara pp 5876–5882 DOI: 10.1021/ic1000717 Supporting Info

Two-Dimensional Coordination Polymer with a Non-interpenetrated (4,4) Net Showing Anion Exchange and Structural Transformation in Single-Crystal-to-Single-Crystal Fashion Arshad Aijaz, Prem Lama and Parimal K. Bharadwaj pp 5883–5889 DOI: 10.1021/ic100183y Supporting Info

Rb16Cd25.39(3)Sb36: An Electron-Deficient Zintl Phase Containing Infinite Dodecahedron Chains Wu-Zui Zheng, Peng Wang, Li-Ming Wu, Yi Liu and Ling Chen pp 5890–5896 DOI: 10.1021/ic100360n Supporting Info

Dinuclear Cadmium(II), Zinc(II), and Manganese(II), Trinuclear Nickel(II), and Pentanuclear Copper(II) Complexes with Novel Macrocyclic and Acyclic Schiff-Base Ligands Having Enantiopure or Racemic Camphoric Diamine Components Jue-Chao Jiang, Zhao-Lian Chu, Wei Huang, Gang Wang and Xiao-Zeng You pp 5897–5911 DOI: 10.1021/ic100349d Supporting Info

Structural Chemistry and Magnetic Properties of Ln18Li8Rh5−xFexO39 (Ln = La, Nd) Peter D. Battle, Sin E. Dutton and Nirawat Thammajak, Fernande Grandjean and Moulay T. Sougrati, Gary J. Long, Katsuyoshi Oh-ishi and Shinji Nakanishi pp 5912–5922 DOI: 10.1021/ic100377s Supporting Info

Control of Self-Assembly through the Influence of Terminal Hydroxymethyl Groups on the Metal Coordination of Pyrimidine−Hydrazone Cu(II) Complexes Daniel J. Hutchinson, Lyall R. Hanton and Stephen C. Moratti pp 5923–5934 DOI: 10.1021/ic100384e Supporting Info

Chiral [Mo3S4H3(diphosphine)3]+ Hydrido Clusters and Study of the Effect of the Metal Atom on the Kinetics of the Acid-Assisted Substitution of the Coordinated Hydride: Mo vs W Andrs G. Algarra, Manuel G. Basallote, M. Jess Fernndez-Trujillo, Marta Feliz, Eva Guillamn, Rosa Llusar, Ivan Sorribes and Cristian Vicent pp 5935–5942 DOI: 10.1021/ic100381u Supporting Info

A Series of New Phases Containing Three Different Asymmetric Building Units Pei-Xin Li, Fang Kong, Chun-Li Hu, Na Zhao and Jiang-Gao Mao pp 5943–5952 DOI: 10.1021/ic100462r Supporting Info

A Doughnut-Like (MnIII)12 Metallocycle Formed by a Rigid Angular Bis-Catecholate with a Nanometer-Sized Central Hole Brendan F. Abrahams, Nicholas J. FitzGerald and Richard Robson pp 5953–5956 DOI: 10.1021/ic1004006 Supporting Info

Synthesis and Thermal Stability of the Solid Solution AFeO2 (A = Ba, Sr, Ca) Takafumi Yamamoto, Zhaofei Li, Cdric Tassel, Naoaki Hayashi, Mikio Takano, Masahiko Isobe, Yutaka Ueda, Kenji Ohoyama, Kazuyoshi Yoshimura, Yoji Kobayashi and Hiroshi Kageyama pp 5957–5962 DOI: 10.1021/ic100452m Supporting Info

Activation of a PARACEST Agent for MRI through Selective Outersphere Interactions with Phosphate Diesters Ching-Hui Huang, Jacob Hammell, S. James Ratnakar, A. Dean Sherry and Janet R. Morrow pp 5963–5970 DOI: 10.1021/ic1004616 Supporting Info

Efficient Synthetic Strategy to Construct Three-Dimensional 4f−5d Networks Using Neutral Two-Dimensional Layers As Building Blocks Hu Zhou, Ai-Hua Yuan, Su-Yan Qian, You Song and Guo-Wang Diao pp 5971–5976 DOI: 10.1021/ic100518b Supporting Info

Mechanistic Study of Amine to Imine Oxidation in a Dinuclear Cu(II) Complex Containing an Octaaza Dinucleating Ligand Gemma J. Christian, Antoni Llobet and Feliu Maseras pp 5977–5985 DOI: 10.1021/ic100502x Supporting Info

The Trigonal Prismatic Cluster Compound W6CCl15 and a Carambolage of Tungsten Clusters in the Structure of the Heteroleptic Cluster Compound W30C2(Cl,Br)68 Markus Strbele and H.-Jrgen Meyer pp 5986–5991 DOI: 10.1021/ic100516t Supporting Info

Self-Assembly of [Pt3n(CO)6n]2− (n = 4−8) Carbonyl Clusters: from Molecules to Conducting Molecular Metal Wires Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Tatiana Lovato, Stefano Stagni and Stefano Zacchini pp 5992–6004 DOI: 10.1021/ic100547j Supporting Info

Four New Dysprosium and Neodymium Octamolybdate Hydrates: Assembly of RE2(Mo8O27) Sheets and Topotactic Transformations Xiaojun Kuang and Ivana R. Evans pp 6005–6012 DOI: 10.1021/ic100646e Supporting Info

Efficient Phosphodiester Hydrolysis by Luminescent Terbium(III) and Europium(III) Complexes Maryene A. Camargo, Ademir Neves, Adailton J. Bortoluzzi, Bruno Szpoganicz, Franciele L. Fischer, Hernn Terenzi, Osvaldo A. Serra, Vanessa G. Santos, Boniek G. Vaz and Marcos N. Eberlin pp 6013–6025 DOI: 10.1021/ic100549u Supporting Info

Oxygen−Sulfur Species Distribution and Kinetic Analysis in the Hydrogen Peroxide−Thiosulfate System Yongchao Lu, Qingyu Gao, Li Xu, Yuemin Zhao and Irving R. Epstein pp 6026–6034 DOI: 10.1021/ic100573a Supporting Info

Proton-Transfer Reactions to Half-Sandwich Ruthenium Trihydride Complexes Bearing Hemilabile P,N Ligands: Experimental and Density Functional Theory Studies† Dedicated to Prof. Serafin Bernal in recognition of his contribution to inorganic chemistry, on the occasion of his retirement. Manuel Jimnez-Tenorio, M. Carmen Puerta and Pedro Valerga, Salvador Moncho, Gregori Ujaque and Agust Lleds pp 6035–6057 DOI: 10.1021/ic100710d Supporting Info

Crystal Structure and Phase Transitions in Sr3WO6 Graham King, Artem M. Abakumov, J. Hadermann, Anastasiya M. Alekseeva, Marina G. Rozova, Tyche Perkisas, Patrick M. Woodward, Gustaaf Van Tendeloo and Evgeny V. Antipov pp 6058–6065 DOI: 10.1021/ic100598v Supporting Info

Density Functional Theory Study of the Magnetic Circular Dichroism Spectra of Molybdenyl Complexes Elizabeth Hernandez-Marin, Michael Seth and Tom Ziegler pp 6066–6076 DOI: 10.1021/ic100624q

Efficient Dipyrrin-Centered Phosphorescence at Room Temperature from Bis-Cyclometalated Iridium(III) Dipyrrinato Complexes Kenneth Hanson, Arnold Tamayo, Vyacheslav V. Diev, Matthew T. Whited, Peter I. Djurovich and Mark E. Thompson pp 6077–6084 DOI: 10.1021/ic100633w Supporting Info

Branching the Electron-Reservoir Complex [Fe(η5-C5H5)(η6-C6Me6)][PF6] onto Large Dendrimers: “Click”, Amide, and Ionic Bonds Rodrigue Djeda, Ctia Ornelas, Jaime Ruiz and Didier Astruc pp 6085–6101 DOI: 10.1021/ic100797x Supporting Info

Synthesis of Coordinatively Unsaturated Mesityliron Thiolate Complexes and Their Reactions with Elemental Sulfur Takayoshi Hashimoto, Yasuhiro Ohki and Kazuyuki Tatsumi pp 6102–6109 DOI: 10.1021/ic100692v Supporting Info

Reduced N-Alkyl Substituted Bis(imino)pyridine Cobalt Complexes: Molecular and Electronic Structures for Compounds Varying by Three Oxidation States Amanda C. Bowman, Carsten Milsmann, Eckhard Bill, Emil Lobkovsky, Thomas Weyhermller, Karl Wieghardt and Paul J. Chirik pp 6110–6123 DOI: 10.1021/ic100717w Supporting Info

Macrocyclic Gd3+ Chelates Attached to a Silsesquioxane Core as Potential Magnetic Resonance Imaging Contrast Agents: Synthesis, Physicochemical Characterization, and Stability Studies Jrg Henig, va Tth, Jrn Engelmann, Sven Gottschalk and Hermann A. Mayer pp 6124–6138 DOI: 10.1021/ic1007395 Supporting Info

Ruthenium-Catalyzed Metathesis Reactions of ortho- and meta-Dialkenyl-Carboranes: Efficient Ring-Closing and Acyclic Diene Polymerization Reactions Marta Guron, Xiaolan Wei, Patrick J. Carroll and Larry G. Sneddon pp 6139–6147 DOI: 10.1021/ic100801y Supporting Info

Bimetallic Ni−Pt Nanocatalysts for Selective Decomposition of Hydrazine in Aqueous Solution to Hydrogen at Room Temperature for Chemical Hydrogen Storage Sanjay K. Singh and Qiang Xu pp 6148–6152 DOI: 10.1021/ic1007654 Supporting Info

Synthesis, Characterization, and Computational Study of MoSF4 Jared Nieboer, Johnathan P. Mack, Hlne P. A. Mercier and Michael Gerken pp 6153–6159 DOI: 10.1021/ic100766d Supporting Info

Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2′-bipyridine)(mes)2 and [FeII(2,2′-bipyridine)(mes)2]−, a Complex Containing a 2,2′-Bipyridyl Radical Anion Mark Irwin, Rhiannon K. Jenkins, Mark S. Denning, Tobias Krmer, Fernande Grandjean, Gary J. Long, Radovan Herchel, John E. McGrady and Jose M. Goicoechea pp 6160–6171 DOI: 10.1021/ic100817s Supporting Info

Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation Ryan E. Cowley, Nathan J. DeYonker, Nathan A. Eckert, Thomas R. Cundari, Serena DeBeer, Eckhard Bill, Xavier Ottenwaelder, Christine Flaschenriem and Patrick L. Holland pp 6172–6187 DOI: 10.1021/ic100846b Supporting Info

Reactions of the Platinum (Tri-tert-butylphosphine) Group with Bridging SbPh2 Ligands in Rhenium−Antimony Carbonyl Complexes Richard D. Adams and William C. Pearl, Jr. pp 6188–6195 DOI: 10.1021/ic1008335 Supporting Info

Untypical [VOPO4]− Layer in Vanadyl Phosphates with Variant Interlayer Gap of Double-Tiered Template Ya-Ching Yang, Yi-Chun Lai, Joel R. Salazar, Vtzslav Zima, Kwang-Hua Lii and Sue-Lein Wang pp 6196–6202 DOI: 10.1021/ic100898g Supporting Info

Monomeric and Dimeric Nickel Complexes Derived from a Pincer Ligand Featuring a Secondary Amine Donor Moiety Denis M. Spasyuk and Davit Zargarian pp 6203–6213 DOI: 10.1021/ic100914x Supporting Info

Side-on Bound Diazene and Hydrazine Complexes of Ruthenium Leslie D. Field, Hsiu L. Li and Scott J. Dalgarno pp 6214–6221 DOI: 10.1021/ic100821u Supporting Info

Issue 14

Preface for the Inorganic Chemistry Forum: The Coordination Chemistry of Nitric Oxide and Its Significance for Metabolism, Signaling, and Toxicity in Biology Nicolai Lehnert and W. Robert Scheidt pp 6223–6225 DOI: 10.1021/ic101080g

Reactions of NO and Nitrite with Heme Models and Proteins Peter C. Ford pp 6226–6239 DOI: 10.1021/ic902073z

Electronic Structure and Dynamics of Nitrosyl Porphyrins W. Robert Scheidt, Alexander Barabanschikov, Jeffrey W. Pavlik, Nathan J. Silvernail and J. Timothy Sage pp 6240–6252 DOI: 10.1021/ic100261b

Linkage Isomerization in Heme−NOx Compounds: Understanding NO, Nitrite, and Hyponitrite Interactions with Iron Porphyrins Nan Xu, Jun Yi and George B. Richter-Addo pp 6253–6266 DOI: 10.1021/ic902423v

Bioinspired Heme, Heme/Nonheme Diiron, Heme/Copper, and Inorganic NOx Chemistry: •NO(g) Oxidation, Peroxynitrite−Metal Chemistry, and •NO(g) Reductive Coupling Mark P. Schopfer, Jun Wang and Kenneth D. Karlin pp 6267–6282 DOI: 10.1021/ic100033y

Reactions of HNO with Heme Proteins: New Routes to HNO−Heme Complexes and Insight into Physiological Effects Murugaeson R. Kumar, Jon M. Fukuto, Katrina M. Miranda and Patrick J. Farmer pp 6283–6292 DOI: 10.1021/ic902319d Supporting Info

Electronic Structure of Heme-Nitrosyls and Its Significance for Nitric Oxide Reactivity, Sensing, Transport, and Toxicity in Biological Systems Lauren E. Goodrich, Florian Paulat, V. K. K. Praneeth and Nicolai Lehnert pp 6293–6316 DOI: 10.1021/ic902304a Supporting Info

Mechanisms of Peroxynitrite Interactions with Heme Proteins Jia Su and John T. Groves pp 6317–6329 DOI: 10.1021/ic902157z

EPR Spectroscopy of Nitrite Complexes of Methemoglobin David E. Schwab, Jonathan S. Stamler, David J. Singel pp 6330–6337 DOI: 10.1021/ic902085s Supporting Info

Detecting and Understanding the Roles of Nitric Oxide in Biology Zachary J. Tonzetich, Lindsey E. McQuade and Stephen J. Lippard pp 6338–6348 DOI: 10.1021/ic9022757

Heme-Based Sensing by the Mammalian Circadian Protein CLOCK Gudrun S. Lukat-Rodgers, Cristina Correia, Maria Victoria Botuyan, Georges Mer and Kenton R. Rodgers pp 6349–6365 DOI: 10.1021/ic902388q Supporting Info

Ruthenium Polypyridyl Complexes That Induce Mitochondria-Mediated Apoptosis in Cancer Cells Tianfeng Chen, Yanan Liu, Wen-Jie Zheng, Jie Liu and Yum-Shing Wong pp 6366–6368 DOI: 10.1021/ic100277w Supporting Info

Spontaneous Symmetry Breaking during Self-Assembly of a Double Stranded Biphenolate-Based Ti(IV)-Helicate Carine Diebold, Pierre Mobian, Clarisse Huguenard, Lionel Allouche and Marc Henry pp 6369–6371 DOI: 10.1021/ic100475c Supporting Info

Copper-Rich Framework Sulfides: A4Cu8Ge3S12 (A = K, Rb) with Cubic Perovskite Structure Ren-Chun Zhang, Hua-Gang Yao, Shou-Hua Ji, Mei-Chen Liu, Min Ji and Yong-Lin An pp 6372–6374 DOI: 10.1021/ic100690q Supporting Info

Unusual Organic Chemistry of a Metallaborane Substrate: Formation of a Tantalaborane Complex with a Bridging Acyl Group (μ-η2) Shubhankar Kumar Bose, K. Geetharani, Babu Varghese and Sundargopal Ghosh pp 6375–6377 DOI: 10.1021/ic1004962 Supporting Info

Potential Hydrogen Bottleneck in Nickel−Iron Hydrogenase Jason M. Keith and Michael B. Hall pp 6378–6380 DOI: 10.1021/ic100522f Supporting Info

First Synthesis of Uranyl Aluminate Nanoparticles Tony Chave, Sergey I. Nikitenko, Andreas C. Scheinost, Claude Berthon, Bndicte Arab-Chapelet and Philippe Moisy pp 6381–6383 DOI: 10.1021/ic100597m Supporting Info

Understanding Eu3+ Emission by Using 15N Vibronic Shifts Wenyu Li and Peter A. Tanner pp 6384–6386 DOI: 10.1021/ic1007928 Supporting Info

Ring-Opening Reactions within Porous Metal−Organic Frameworks David Britt, Chain Lee, Fernando J. Uribe-Romo, Hiroyasu Furukawa and Omar M. Yaghi pp 6387–6389 DOI: 10.1021/ic100652x Supporting Info

Bringing an “Old” Biological Buffer to Coordination Chemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for Mild Hydrocarboxylation of Alkanes Alexander M. Kirillov, Jaime A. S. Coelho, Marina V. Kirillova, M. Ftima C. Guedes da Silva, Dmytro S. Nesterov, Katrin R. Gruenwald, Matti Haukka and Armando J. L. Pombeiro pp 6390–6392 DOI: 10.1021/ic1007999 Supporting Info

Isostructural Single-Chain and Single-Molecule Magnets Patrick L. Feng and David N. Hendrickson pp 6393–6395 DOI: 10.1021/ic101016t Supporting Info

The Elusive closo-Ge102− Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge10Mn(CO)4]3− Daniel Rios and Slavi C. Sevov pp 6396–6398 DOI: 10.1021/ic100877u Supporting Info

Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase Marcello Gennari, Maylis Orio, Jacques Pcaut, Frank Neese, Marie-Nolle Collomb and Carole Duboc pp 6399–6401 DOI: 10.1021/ic100945n Supporting Info

Phosphorescence Imaging of Homocysteine and Cysteine in Living Cells Based on a Cationic Iridium(III) Complex Liqin Xiong, Qiang Zhao, Huili Chen, Yanbo Wu, Zesheng Dong, Zhiguo Zhou and Fuyou Li pp 6402–6408 DOI: 10.1021/ic902266x Supporting Info

Secondary Coordination Sphere Interactions within the Biomimetic Iron Azadithiolate Complexes Related to Fe-Only Hydrogenase: Dynamic Measure of Electron Density about the Fe Sites Yu-Chiao Liu, Ling-Kuang Tu, Tao-Hung Yen, Gene-Hsiang Lee, Shu-Ting Yang and Ming-Hsi Chiang pp 6409–6420 DOI: 10.1021/ic100484a Supporting Info

Preparation and Properties of Dimethyltetrafluorophosphate Christian Hohenstein and Andreas Kornath, Frank Neumann, Ralf Ludwig pp 6421–6427 DOI: 10.1021/ic902438e Supporting Info

Combined Computational and Experimental Study of Uranyl(VI) 1:2 Complexation by Aromatic Acids Jonas Wiebke, Anna Weigand, Daniel Weissmann, Maja Glorius, Henry Moll, Gert Bernhard and Michael Dolg pp 6428–6435 DOI: 10.1021/ic902496u Supporting Info

A Unique Cobalt(II)-Based Molecular Magnet Constructed of Hydroxyl/Carboxylate Bridges with a 3D Pillared-Layer Motif Ming-Hua Zeng, Yan-Ling Zhou, Mei-Chun Wu, Hao-Ling Sun and Miao Du pp 6436–6442 DOI: 10.1021/ic100021f Supporting Info

Experimental Electron Density Study of Tetrakis-μ-(acetylsalicylate)dicopper(II): a Polymeric Structure with Cu···Cu Short Contacts Nouzha Bouhmaida, Miguel A. Mndez-Rojas, Aarn Prez-Bentez, Gabriel Merino, Bernard Fraisse and Nour Eddine Ghermani pp 6443–6452 DOI: 10.1021/ic100090h Supporting Info

A Highly Stable Rhenium−Cobalt System for Photocatalytic H2 Production: Unraveling the Performance-Limiting Steps Benjamin Probst, Alexander Rodenberg, Miguel Guttentag, Peter Hamm and Roger Alberto pp 6453–6460 DOI: 10.1021/ic100036v Supporting Info

Ag6Mo2O7F3Cl: A New Silver Cathode Material for Enhanced ICD Primary Lithium Batteries F. Sauvage, V. Bodenez, J.-M. Tarascon and K. R. Poeppelmeier pp 6461–6467 DOI: 10.1021/ic100125v Supporting Info

Sulfur-Metal Orbital Hybridization in Sulfur-Bearing Compounds Studied by X-ray Emission Spectroscopy R. Alonso Mori, E. Paris, G. Giuli, S. G. Eeckhout, M. Kavi, M. itnik, K. Buar, L. G. M. Pettersson and P. Glatzel pp 6468–6473 DOI: 10.1021/ic100304z

Reaction Controlled Assemblies of Polyoxotungstates (-molybdates) and Coordination Polymers Guangfeng Hou, Lihua Bi, Bao Li and Lixin Wu pp 6474–6483 DOI: 10.1021/ic1001495 Supporting Info

Competitive Complexation of Nitrates and Chlorides to Uranyl in a Room Temperature Ionic Liquid C. Gaillard, A. Chaumont, I. Billard, C. Hennig, A. Ouadi, S. Georg and G. Wipff pp 6484–6494 DOI: 10.1021/ic100170t

Versatile New C3-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize CuI and RhI Species and Tune Their Reactivity Jeroen Wassenaar, Maxime A. Siegler, Anthony L. Spek, Bas de Bruin, Joost N. H. Reek and Jarl Ivar van der Vlugt pp 6495–6508 DOI: 10.1021/ic100221w Supporting Info

Binuclear Hexa- and Pentavalent Uranium Complexes with a Polypyrrolic Ligand: A Density Functional Study of Water- and Hydronium-Induced Reactions Qing-Jiang Pan and Georg Schreckenbach pp 6509–6517 DOI: 10.1021/ic100245a Supporting Info

Structure Change via Partial Se/Te Substitution: Crystal Structure and Physical Properties of the Telluride Ba2Cu4−xTe5 in Contrast to the Selenide-Telluride Ba2Cu4−xSeyTe5−y Oottil Mayasree, Yanjie Cui, Abdeljalil Assoud and Holger Kleinke pp 6518–6524 DOI: 10.1021/ic100268q Supporting Info

Mechanism of Cadmium Ion Substitution in Mammalian Zinc Metallothionein and Metallothionein α Domain: Kinetic and Structural Studies John Ejnik, C. Frank Shaw, III and David H. Petering pp 6525–6534 DOI: 10.1021/ic1003148 Supporting Info

Spectroscopic and Computational Studies of a Series of High-Spin Ni(II) Thiolate Complexes Katherine M. Van Heuvelen, Jaeheung Cho, Timothy Dingee, Charles G. Riordan and Thomas C. Brunold pp 6535–6544 DOI: 10.1021/ic100362q Supporting Info

Theoretical Studies of AnII2(C8H8)2 (An = Th, Pa, U, and Np) Complexes: The Search for Double-Stuffed Actinide Metallocenes Jia Zhou, Jason L. Sonnenberg and H. Bernhard Schlegel pp 6545–6551 DOI: 10.1021/ic100427t Supporting Info

Dynamics of NO Motion in Solid-State [Co(tetraphenylporphinato)(NO)] Laura M. Grande, Bruce C. Noll, Allen G. Oliver and W. Robert Scheidt pp 6552–6557 DOI: 10.1021/ic1003462 Supporting Info

Synthesis and Structural Characterization of Molecular Dy(III) and Er(III) Tetra-Carbonates George S. Goff, Michael R. Cisneros, Chandra Kluk, Kevin Williamson, Brian Scott, Sean Reilly and Wolfgang Runde pp 6558–6564 DOI: 10.1021/ic1004598 Supporting Info

Carboxylate Tolerance of the Redox-Active Platform [Ru(μ-tppz)Ru]n, where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, in the Electron-Transfer Series [(L)ClRu(μ-tppz)RuCl(L)]n, n = 2+, +, 0, −, 2−, with 2-Picolinato, Quinaldato, and 8-Quinolinecarboxylato Ligands (L−) Tanaya Kundu, Biprajit Sarkar, Tapan Kumar Mondal, Jan Fiedler, Shaikh M. Mobin, Wolfgang Kaim and Goutam Kumar Lahiri pp 6565–6574 DOI: 10.1021/ic100500p Supporting Info

New μ4-Oxido-Bridged Copper Benzoate Quasi-Tetrahedron and Bis-μ3-Hydroxido-Bridged Copper Azide and Copper Thiocyanate Stepped Cubanes: Core Conversion, Structural Diversity, and Magnetic Properties Mrinal Sarkar, Rodolphe Clrac, Corine Mathonire, Nigel G. R. Hearns, Valerio Bertolasi and Debashis Ray pp 6575–6585 DOI: 10.1021/ic100356y Supporting Info

Polymer-Bound Oxidovanadium(IV) and Dioxidovanadium(V) Complexes As Catalysts for the Oxidative Desulfurization of Model Fuel Diesel Mannar R. Maurya, Aarti Arya, Amit Kumar, Maxim L. Kuznetsov, Fernando Avecilla and Joo Costa Pessoa pp 6586–6600 DOI: 10.1021/ic1004209 Supporting Info

One-Pot Synthesis and Optical Property of Copper(I) Sulfide Nanodisks Yan Wang, Yongxing Hu, Qiao Zhang, Jianping Ge, Zhenda Lu, Yanbing Hou and Yadong Yin pp 6601–6608 DOI: 10.1021/ic100473e

BaM(BS3)S (M = Sb, Bi): Two New Thioborate Compounds with One-Dimensional Polymeric Chain Structure Lei Geng, Wen-Dan Cheng, Wei-Long Zhang, Chen-Sheng Lin, Hao Zhang, Ye-Yu Li and Zhang-Zhen He pp 6609–6615 DOI: 10.1021/ic100535q Supporting Info

A Unique Example of Structural and Magnetic Diversity in Four Interconvertible Copper(II)−Azide Complexes with the Same Schiff Base Ligand: A Monomer, a Dimer, a Chain, and a Layer Subrata Naiya, Chaitali Biswas, Michael G. B. Drew, Carlos J. Gmez-Garca, Juan M. Clemente-Juan and Ashutosh Ghosh pp 6616–6627 DOI: 10.1021/ic1005456 Supporting Info

Optically Active Homoleptic Bis(phthalocyaninato) Rare Earth Double-Decker Complexes Bearing Peripheral Chiral Menthol Moieties: Effect of π−π Interaction on the Chiral Information Transfer at the Molecular Level Wei Lv, Peihua Zhu, Yongzhong Bian, Changqin Ma, Xiaomei Zhang and Jianzhuang Jiang pp 6628–6635 DOI: 10.1021/ic100552j Supporting Info

Sequence-Specific Ni(II)-Dependent Peptide Bond Hydrolysis for Protein Engineering: Reaction Conditions and Molecular Mechanism Edyta Kopera, Artur Krel, Anna Maria Protas, Agnieszka Belczyk, Arkadiusz Bonna, Aleksandra Wysłouch-Cieszyska, Jarosław Poznaski and Wojciech Bal pp 6636–6645 DOI: 10.1021/ic1005709 Supporting Info

Structural, Spectroscopic, and Multiconfigurational Quantum Chemical Investigations of the Electron-Rich Metal−Metal Triple-Bonded Tc2X4(PMe3)4 (X = Cl, Br) Complexes Frederic Poineau, Paul M. Forster, Tanya K. Todorova, Laura Gagliardi, Alfred P. Sattelberger and Kenneth R. Czerwinski pp 6646–6654 DOI: 10.1021/ic100641j Supporting Info

Synthesis and Reactivity of Bis(tetramethylcyclopentadienyl) Yttrium Metallocenes Including the Reduction of Me3SiN3 to [(Me3Si)2N]− with [(C5Me4H)2Y(THF)]2(μ-η2:η2-N2) Sara E. Lorenz, Benjamin M. Schmiege, David S. Lee, Joseph W. Ziller and William J. Evans pp 6655–6663 DOI: 10.1021/ic100682d Supporting Info

Unique Properties and Reactivity of High-Valent Manganese−Oxo versus Manganese−Hydroxo in the Salen Platform Takuya Kurahashi, Akihiro Kikuchi, Yoshitsugu Shiro, Masahiko Hada and Hiroshi Fujii pp 6664–6672 DOI: 10.1021/ic100673b Supporting Info

XeF2 Coordination to a Halogen Center; Raman Spectra (n = 1, 2) and X-ray Crystal Structures (n = 2) of [BrOF2][AsF6]·nXeF2 and [XOF2][AsF6] (X = Cl, Br) David S. Brock, Jonathan J. Casalis de Pury, Hlne P. A. Mercier, Gary J. Schrobilgen and Bernard Silvi pp 6673–6689 DOI: 10.1021/ic100712y Supporting Info

Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes Shuao Wang, Evgeny V. Alekseev, Jared T. Stritzinger, Wulf Depmeier and Thomas E. Albrecht-Schmitt pp 6690–6696 DOI: 10.1021/ic100728s Supporting Info

[Fe4S4]q Cubane Clusters (q = 4+, 3+, 2+) with Terminal Amide Ligands Christopher R. Sharp, Jeremiah S. Duncan and Sonny C. Lee pp 6697–6705 DOI: 10.1021/ic100742c Supporting Info

Ln3+ (Ln = Eu, Dy, Sm, and Er) Ion-Doped YVO4 Nano/Microcrystals with Multiform Morphologies: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties Zhenhe Xu, Xiaojiao Kang, Chunxia Li, Zhiyao Hou, Cuimiao Zhang, Dongmei Yang, Guogang Li and Jun Lin pp 6706–6715 DOI: 10.1021/ic100953m

Hydrothermal Synthesis of Uranyl Squarates and Squarate-Oxalates: Hydrolysis Trends and in Situ Oxalate Formation Clare E. Rowland and Christopher L. Cahill pp 6716–6724 DOI: 10.1021/ic100887c Supporting Info

GaIII Complexes as Models for the MIII Site of Purple Acid Phosphatase: Ligand Effects on the Hydrolytic Reactivity Toward Bis(2,4-dinitrophenyl) phosphate Fergal Coleman, Michael J. Hynes and Andrea Erxleben pp 6725–6733 DOI: 10.1021/ic100722w Supporting Info

Comparative Studies of Preferential Binding of Group Nine Metalloporphyrins (M = Co, Rh, Ir) with Methoxide/Methanol in Competition with Hydroxide/Water in Aqueous Solution Salome Bhagan, Sounak Sarkar and Bradford B. Wayland pp 6734–6739 DOI: 10.1021/ic100773y Supporting Info

Single-Component Molecular Conductor [Cu(tmdt)2] Containing an Antiferromagnetic Heisenberg Chain Biao Zhou, Hiroyuki Yajima, Akiko Kobayashi, Yoshinori Okano, Hisashi Tanaka, Tetsuya Kumashiro, Eiji Nishibori, Hiroshi Sawa and Hayao Kobayashi pp 6740–6747 DOI: 10.1021/ic100845f Supporting Info

Na2SO4 Monocrystal Nanowires—Aspect Ratio Control and Electron Beam Radiolysis Ruiting Zheng, Jinwei Gao, Tengfei Yang, Yucheng Lan, Guoan Cheng, Dezhi Wang, Zhifeng Ren and Gang Chen pp 6748–6754 DOI: 10.1021/ic100874r Supporting Info

Influence of Linker Geometry on Uranyl Complexation by Rigidly Linked Bis(3-hydroxy-N-methyl-pyridin-2-one) Gza Szigethy and Kenneth N. Raymond pp 6755–6765 DOI: 10.1021/ic1007878 Supporting Info

Modular, Active, and Robust Lewis Acid Catalysts Supported on a Metal−Organic Framework Kristine K. Tanabe and Seth M. Cohen pp 6766–6774 DOI: 10.1021/ic101125m Supporting Info

Issue 15

Metal−Organic Frameworks Containing a Tetrapyridylcyclobutane Ligand Derived from Isomerization Reaction Abdul Malik Puthan Peedikakkal, Charlene Shi Yun Peh, Lip Lin Koh and Jagadese J. Vittal pp 6775–6777 DOI: 10.1021/ic100853h Supporting Info

CaCu3Pt4O12: The First Perovskite with the B Site Fully Occupied by Pt4+ Ikuya Yamada, Yuka Takahashi, Kenya Ohgushi, Norimasa Nishiyama, Ryoji Takahashi, Kohei Wada, Takehiro Kunimoto, Hiroaki Ohfuji, Yohei Kojima, Toru Inoue and Tetsuo Irifune pp 6778–6780 DOI: 10.1021/ic100474x Supporting Info

IR Spectra of Boron-Stabilized Anions in the Gas Phase Jos Oomens, Jeffrey D. Steill and Thomas Hellman Morton pp 6781–6783 DOI: 10.1021/ic1005874 Supporting Info

Synthesis and Properties of a Family of Unsymmetric Dinuclear Complexes of LnIII (Ln = Eu, Gd, Tb) David Aguil, Leon A. Barrios, Fernando Luis, Ana Repolls, Olivier Roubeau, Simon J. Teat and Guillem Arom pp 6784–6786 DOI: 10.1021/ic1008285 Supporting Info

Metal-Interrupted Perylene Diimide: Toward a New Class of Tunable n-Type Inorganic−Organic Hybrid Semiconductors Kate R. Edelman and Bradley J. Holliday pp 6787–6789 DOI: 10.1021/ic100785r Supporting Info

Expanding Monomeric Pyrophosphate Complexes beyond Platinum Nadia Marino, Anthony R. Vortherms, Amanda E. Hoffman and Robert P. Doyle pp 6790–6792 DOI: 10.1021/ic1006007 Supporting Info

Uranium(VI) Tetraoxido Core Coordinated by Bidentate Nitrate Daniel K. Unruh, Michelle Baranay, Melissa Baranay and Peter C. Burns pp 6793–6795 DOI: 10.1021/ic100871z Supporting Info

A RuII-TAP Complex, Photoreagent for Tryptophan-Containing Peptides: Structure of the Covalent Photoadduct Nicolas Gauthier, Julien De Winter, Pascal Gerbaux, Ccile Moucheron, Michel Luhmer and Andre Kirsch-De Mesmaeker pp 6796–6798 DOI: 10.1021/ic101151e Supporting Info

Theoretical Calculation of the Magnetic Resonance Parameters of Trigonal-Prismatic Tris(o-aminobenzenethiol)technetium and -rhenium Complexes Simon C. Drew, John Baldas and John F. Boas pp 6799–6801 DOI: 10.1021/ic1009175 Supporting Info

Naphthalimide Phosphorescence Finally Exposed in a Platinum(II) Diimine Complex Huimin Guo, Maria L. Muro-Small, Shaomin Ji, Jianzhang Zhao and Felix N. Castellano pp 6802–6804 DOI: 10.1021/ic101107b Supporting Info

Highly Emissive Cyclometalated Rhenium Metallacycles: Structure−Luminescence Relationship Yi-Hsiu Tseng, Dibyendu Bhattacharya, Shih-Ming Lin, P. Thanasekaran, Jing-Yun Wu, Li-Wei Lee, M. Sathiyendiran, Mei-Lin Ho, Min-Wen Chung, Kung-Chung Hsu, Pi-Tai Chou and Kuang-Lieh Lu pp 6805–6807 DOI: 10.1021/ic100882u Supporting Info

Toward the Detection of Cellular Copper(II) by a Light-Activated Fluorescence Increase Katie L. Ciesienski, Lynne M. Hyman, Samir Derisavifard and Katherine J. Franz pp 6808–6810 DOI: 10.1021/ic1004165 Supporting Info

Intramolecular σ-Bond Metathesis/Protonolysis on Zirconium(IV) and Hafnium(IV) Pyridylamido Olefin Polymerization Catalyst Precursors: Exploring Unexpected Reactivity Paths Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, Claudio Bianchini and Agust Lleds pp 6811–6813 DOI: 10.1021/ic100947q Supporting Info

A Red-Emitting Light Switch Based on a Heteroleptic Ruthenium(II) Complex Containing a Tridentate dppz Analogue David J. Stewart, Phillip E. Fanwick and David R. McMillin pp 6814–6816 DOI: 10.1021/ic1010117 Supporting Info

Monomeric and Dimeric Disulfide Complexes of Nickel(II) Vlad M. Iluc, Carl A. Laskowski, Carl K. Brozek, Nicole D. Harrold and Gregory L. Hillhouse pp 6817–6819 DOI: 10.1021/ic101242c Supporting Info

Oxygenation Chemistry at a Mononuclear Copper(II) Hydroquinone System with O2 Kae Tabuchi, Hideki Sugimoto, Atsushi Kunishita, Nobutaka Fujieda and Shinobu Itoh pp 6820–6822 DOI: 10.1021/ic101037v Supporting Info

Dinitrogen Difluoride Chemistry. Improved Syntheses of cis- and trans-N2F2, Synthesis and Characterization of N2F+Sn2F9−, Ordered Crystal Structure of N2F+Sb2F11−, High-Level Electronic Structure Calculations of cis-N2F2, trans-N2F2, F2N═N, and N2F+, and Mechanism of the trans−cis Isomerization of N2F2 Karl O. Christe, David A. Dixon, Daniel J. Grant, Ralf Haiges, Fook S. Tham, Ashwani Vij, Vandana Vij, Tsang-Hsiu Wang and William W. Wilson pp 6823–6833 DOI: 10.1021/ic100471s Supporting Info

Hydrothermal Synthesis and Characterization of LiREF4 (RE = Y, Tb−Lu) Nanocrystals and Their Core−Shell Nanostructures Qiang Zhang and Bing Yan pp 6834–6839 DOI: 10.1021/ic100445y Supporting Info

Effects of Electronic Mixing in Ruthenium(II) Complexes with Two Equivalent Acceptor Ligands. Spectroscopic, Electrochemical, and Computational Studies Marco M. Allard, Onduru. S. Odongo, Mandy M. Lee, Yuan-Jang Chen, John F. Endicott and H. Bernhard Schlegel pp 6840–6852 DOI: 10.1021/ic100202h Supporting Info

Investigation of Ga Substitution in ZnO Powder and Opto-Electronic Properties Hlne Serier, Alain Demourgues and Manuel Gaudon pp 6853–6858 DOI: 10.1021/ic1000733

First-Principles Prediction on the High-Pressure Structures of Transition Metal Diborides (TMB2, TM = Sc, Ti, Y, Zr) Meiguang Zhang, Hui Wang, Hongbo Wang, Xinxin Zhang, Toshiaki Iitaka and Yanming Ma pp 6859–6864 DOI: 10.1021/ic100214v

Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n Marta Abrantes, Tatiana R. Amarante, Margarida M. Antunes, Sandra Gago, Filipe A. Almeida Paz, Irene Margiolaki, Alrio E. Rodrigues, Martyn Pillinger, Anabela A. Valente and Isabel S. Gonalves pp 6865–6873 DOI: 10.1021/ic100479a Supporting Info

Cation−π Interaction in Complex Formation Between Tl+ Ion and Calix[4]crown-6 and Some Calix[4]biscrown-6 Derivatives: Thallium-203 NMR, Proton NMR, and X-ray Evidence Hedayat Haddadi and Naader Alizadeh, Mojtaba Shamsipur, Zouhair Asfari, Vito Lippolis, Carla Bazzicalupi pp 6874–6882 DOI: 10.1021/ic100097v Supporting Info

Phosphate Mono- and Diesterase Activities of the Trinuclear Zinc Enzyme Nuclease P1—Insights from Quantum Chemical Calculations Rong-Zhen Liao, Jian-Guo Yu and Fahmi Himo pp 6883–6888 DOI: 10.1021/ic100266n Supporting Info

Core Conversion Reactions of the Cubane-Type Metal-Sulfido Clusters: Shape Shift, Contraction, and Expansion of the MM′Re2S4 Cubanes (M = Ir, Rh, Ru; M′ = Pt, Pd) Rie Shibata, Hidetake Seino, Shunpei Fujii and Yasushi Mizobe pp 6889–6896 DOI: 10.1021/ic100339f Supporting Info

Synthesis and Properties of Dinuclear Ru(II)/Os(II) Complexes Based on a Heteroditopic Phenanthroline−Terpyridine Bridging Ligand Eugenio Coronado, Pablo Gavia, Sergio Tatay, Robert Groarke and Johannes G. Vos pp 6897–6903 DOI: 10.1021/ic1004177

SrNp(PO4)2: an Original Ordered Modification of Cheralite Karin Popa, Gilles Wallez, Philippe E. Raison, Damien Bregiroux, Christos Apostolidis, Patric Lindqvist-Reis and Rudy J. M. Konings pp 6904–6908 DOI: 10.1021/ic100376u

Unusual Specificity of a Receptor for Nd3+ Among Other Lanthanide Ions for Selective Colorimetric Recognition Priyadip Das, Amrita Ghosh and Amitava Das pp 6909–6916 DOI: 10.1021/ic100236c Supporting Info

First-Principles Study of the Electronic, Optical Properties and Lattice Dynamics of Tantalum Oxynitride Pan Li, Weiliu Fan, Yanlu Li, Honggang Sun, Xiufeng Cheng, Xian Zhao and Minhua Jiang pp 6917–6924 DOI: 10.1021/ic1004819 Supporting Info

Widely Differing Photochemical Behavior in Related Octahedral {Ru-NO}6 Compounds: Intramolecular Redox Isomerism of the Excited State Controlling the Photodelivery of NO Ariel G. De Candia, Juan P. Marcolongo, Roberto Etchenique and Leonardo D. Slep pp 6925–6930 DOI: 10.1021/ic100491g Supporting Info

A Density Functional Theory- and Atoms in Molecules-based Study of NiNTA and NiNTPA Complexes toward Physical Properties Controlling their Stability. A New Method of Computing a Formation Constant Ignacy Cukrowski and Krishna K. Govender pp 6931–6941 DOI: 10.1021/ic100453v Supporting Info

Exchange-Coupled Cobalt(II) Dimer with Unusual Magnetic Circular Dichroism Saturation Behavior S. Ostrovsky, Z. Tomkowicz and W. Haase pp 6942–6947 DOI: 10.1021/ic100556p

Infrared Spectroelectrochemical Reduction of Iron Porphyrin Complexes Zhongcheng Wei and Michael D. Ryan pp 6948–6954 DOI: 10.1021/ic100614h

A Surface Effect Allows HNO/NO Discrimination by a Cobalt Porphyrin Bound to Gold Sebastin A. Surez, Mariano H. Fonticelli, Aldo A. Rubert, Ezequiel de la Llave, Damin Scherlis, Roberto C. Salvarezza, Marcelo A. Mart and Fabio Doctorovich pp 6955–6966 DOI: 10.1021/ic1007022 Supporting Info

Mechanism of Accumulation and Incorporation of Organometallic Pd Complexes into the Protein Nanocage of apo-Ferritin Satoshi Abe, Tatsuo Hikage, Yoshihito Watanabe, Susumu Kitagawa and Takafumi Ueno pp 6967–6973 DOI: 10.1021/ic1003758

1,3,5-Tris(thiocyanatomethyl)mesitylene as a Ligand. Pseudooctahedral Molybdenum, Manganese, and Rhenium Carbonyl Complexes and Copper and Silver Dimers. Copper-Catalyzed Carbene- and Nitrene-Transfer Reactions Hctor Martnez-Garca, Dolores Morales, Julio Prez, Marcos Puerto and Daniel Miguel pp 6974–6985 DOI: 10.1021/ic1006082 Supporting Info

A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties Jeongho Yeon, Sang-Hwan Kim and P. Shiv Halasyamani pp 6986–6993 DOI: 10.1021/ic1008297 Supporting Info

Structure and Bonding Energy Analysis of M−Ga Bonds in Dihalogallyl Complexes trans-[X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I) Krishna K. Pandey, Pankaj Patidar and Holger Braunschweig pp 6994–7000 DOI: 10.1021/ic1005506 Supporting Info

Influence of the Heteroatom Size on the Redox Potentials of Selected Polyoxoanions Isral-Martyr Mbomekall, Xavier Lpez, Josep M. Poblet, Francis Scheresse, Bineta Keita and Louis Nadjo pp 7001–7006 DOI: 10.1021/ic100675h Supporting Info

Li+, Cu+, and Ag+ Oligonuclear Structures with the Sterically Demanding Bis(3,5-tertbutylpyrazol-1-yl)dithioacetate Heteroscorpionate Ligand Irene Bassanetti, Marcello Gennari, Luciano Marchi, Mattia Terenghi and Lisa Elviri pp 7007–7015 DOI: 10.1021/ic100886x Supporting Info

Hydrogen and Copper Ion Induced Molecular Reorganizations in Two New Scorpiand-Like Ligands Appended with Pyridine Rings Salvador Blasco, Begoa Verdejo, M. Paz Clares, Carmen E. Castillo, Andrs G. Algarra, Julio Latorre, M. Angeles Mez, Manuel G. Basallote, Conxa Soriano and Enrique Garca-Espaa pp 7016–7027 DOI: 10.1021/ic100609h Supporting Info

New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2 Min Kyung Kim, Sang-Hwan Kim, Hong-Young Chang, P. Shiv Halasyamani and Kang Min Ok pp 7028–7034 DOI: 10.1021/ic100706n Supporting Info

Superbasic Amidine Monodentate Ligands in fac-[Re(CO)3(5,5′-Me2bipy)(Amidine)]BF4 Complexes: Dependence of Amidine Configuration on the Remote Nitrogen Substituents Theshini Perera, Frank R. Fronczek, Patricia A. Marzilli and Luigi G. Marzilli pp 7035–7045 DOI: 10.1021/ic100714m Supporting Info

Thermally Triggered Reversible Transformation between Parallel Staggered Stacking and Plywood-Like Stacking of 1D Coordination Polymer Chains Jian-Ke Sun, Xu-Hui Jin, Chao Chen and Jie Zhang pp 7046–7051 DOI: 10.1021/ic1008494 Supporting Info

A Heteroleptic Bis(tridentate)ruthenium(II) Polypyridine Complex with Improved Photophysical Properties and Integrated Functionalizability Aaron Breivogel, Christoph Frster and Katja Heinze pp 7052–7056 DOI: 10.1021/ic1007236 Supporting Info

Phosphorus−Nitrogen Compounds. 21. Syntheses, Structural Investigations, Biological Activities, and DNA Interactions of New N/O Spirocyclic Phosphazene Derivatives. The NMR Behaviors of Chiral Phosphazenes with Stereogenic Centers upon the Addition of Chiral Solvating Agents Muhammet Iıklan, Nuran Asmafiliz, Ezgi Elif zalp, Elif Ece lter, Zeynel Kılı, Bnyemin out, Serkan Yeilot, Adem Kılı, Aslı ztrk, Tuncer Hkelek, L. Yasemin Ko Bilir, Leyla Aık and Emel Akyz pp 7057–7071 DOI: 10.1021/ic100781v Supporting Info

New Ru(II) Complexes with Anionic and Neutral N-Donor Ligands as Epoxidation Catalysts: An Evaluation of Geometrical and Electronic Effects Mohamed Dakkach, M. Isabel Lpez, Isabel Romero, Montserrat Rodrguez, Ahmed Atlamsani, Teodor Parella, Xavier Fontrodona and Antoni Llobet pp 7072–7079 DOI: 10.1021/ic100862y Supporting Info

Exploring the Effects of H-Bonding in Synthetic Analogues of Nickel Superoxide Dismutase (Ni-SOD): Experimental and Theoretical Implications for Protection of the Ni−SCys Bond Eric M. Gale, Beulah S. Narendrapurapu, Andrew C. Simmonett, Henry F. Schaefer, III and Todd C. Harrop pp 7080–7096 DOI: 10.1021/ic1009187 Supporting Info

Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2 [M = Ge, Sn, Pb; Ar# = C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2 (M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal−Ligand Interactions William A. Merrill, Robert J. Wright, Corneliu S. Stanciu, Marilyn M. Olmstead, James C. Fettinger and Philip P. Power pp 7097–7105 DOI: 10.1021/ic100831c Supporting Info

Modular and Versatile Hybrid Coordination Motifs on α-Helical Protein Surfaces Robert J. Radford, Phuong C. Nguyen and F. Akif Tezcan pp 7106–7115 DOI: 10.1021/ic100926g Supporting Info

Oxalate Bridged Triangles Incorporating Mo24+ Units. Electronic Structure and Bonding Malcolm H. Chisholm, Nathan J. Patmore, Carly R. Reed and Namrata Singh pp 7116–7122 DOI: 10.1021/ic1009237 Supporting Info

Syntheses, Structures, and Characterization of Open-Framework Uranyl Germanates Jie Ling, Jessica M. Morrison, Matthew Ward, Kelsey Poinsatte-Jones and Peter C. Burns pp 7123–7128 DOI: 10.1021/ic1010242 Supporting Info

Effects of Counter Anions on Intense Photoluminescence of 1-D Chain Gold(I) Complexes Masashi Saitoh, Alan L. Balch, Junpei Yuasa and Tsuyoshi Kawai pp 7129–7134 DOI: 10.1021/ic100948m Supporting Info

3-D Coordination Polymers Based on the Tetrathiafulvalenetetracarboxylate (TTF-TC) Derivative: Synthesis, Characterization, and Oxidation Issues Thi Le Anh Nguyen, Rezan Demir-Cakan, Thomas Devic, Mathieu Morcrette, Tim Ahnfeldt, Pascale Auban-Senzier, Norbert Stock, Anne-Marie Goncalves, Yaroslav Filinchuk, Jean-Marie Tarascon and Grard Frey pp 7135–7143 DOI: 10.1021/ic100950n Supporting Info

Highly Volatile Alkaline Earth Metal Fluoroalkoxides William D. Buchanan, Marites A. Guino-o and Karin Ruhlandt-Senge pp 7144–7155 DOI: 10.1021/ic100960z

Polyfluoride Anions, a Matrix-Isolation and Quantum-Chemical Investigation Sebastian Riedel, Tobias Kchner, Xuefeng Wang and Lester Andrews pp 7156–7164 DOI: 10.1021/ic100981c Supporting Info

Reactions of Aromatic Heterocycles with Uranium Alkyl Complexes Selma Duhovi, Marisa J. Monreal and Paula L. Diaconescu pp 7165–7169 DOI: 10.1021/ic1009835 Supporting Info

Osmium−Bismuth Complexes from the Reaction of Os3(CO)11(NCMe) with BiPh3 Richard D. Adams and William C. Pearl, Jr. pp 7170–7175 DOI: 10.1021/ic100994t Supporting Info

Group 4 Salalen Complexes and Their Application for the Ring-Opening Polymerization of rac-Lactide Emma L. Whitelaw, Matthew D. Jones and Mary F. Mahon pp 7176–7181 DOI: 10.1021/ic1010488 Supporting Info

Preparation, Crystal Structure, and Unusually Facile Redox Chemistry of a Macrocyclic Nitrosylrhodium Complex Kathleen E. Kristian, Wenjing Song, Arkady Ellern, Ilia A. Guzei and Andreja Bakac pp 7182–7187 DOI: 10.1021/ic101236x Supporting Info

Solvent and Temperature Induced Switching Between Structural Isomers of RhI Phosphinoalkyl Thioether (PS) Complexes Michael J. Wiester, Adam B. Braunschweig, Hyojong Yoo and Chad A. Mirkin pp 7188–7196 DOI: 10.1021/ic101021t Supporting Info

Oriented Single-Crystal Nuclear Resonance Vibrational Spectroscopy of [Fe(TPP)(MI)(NO)]: Quantitative Assessment of the trans Effect of NO Nicolai Lehnert, J. Timothy Sage, Nathan Silvernail, W. Robert Scheidt, E. Ercan Alp, Wolfgang Sturhahn and Jiyong Zhao pp 7197–7215 DOI: 10.1021/ic1010677 Supporting Info

Issue 16

Controllable Synthesis of CuO Nanowires and Cu2O Crystals with Shape Evolution via γ-Irradiation Zibin Hai, Chunhua Zhu, Jianliu Huang, Huarong Liu and Jiafu Chen pp 7217–7219 DOI: 10.1021/ic101143u Supporting Info

A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity Yoshimasa Makita, Kazuya Sugimoto, Kenta Furuyoshi, Keisuke Ikeda, Shin-ichi Fujiwara, Tsutomu Shin-ike and Akiya Ogawa pp 7220–7222 DOI: 10.1021/ic100725j Supporting Info

Anion Recognition and Sensing by a New Macrocyclic Dinuclear Copper(II) Complex: A Selective Receptor for Iodide John S. Mendy, Musabbir A. Saeed, Frank R. Fronczek, Douglas R. Powell and Md. Alamgir Hossain pp 7223–7225 DOI: 10.1021/ic100686m Supporting Info

A Modular Approach to Redox-Active Multimetallic Hydrophobes of Discoid Topology Frank D. Lesh, Rama Shanmugam, Marco M. Allard, Maurcio Lanznaster, Mary Jane Heeg, M. T. Rodgers, Jason M. Shearer and Cludio N. Verani pp 7226–7228 DOI: 10.1021/ic1009626 Supporting Info

Conformationally Constrained (Coumarin−Triazolyl−Bipyridyl) Click Fluoroionophore as a Selective Al3+ Sensor Debabrata Maity and T. Govindaraju pp 7229–7231 DOI: 10.1021/ic1009994 Supporting Info

Self-Assembly and Chiral Recognition of a Two-Dimensional Coordination Polymer from a Chiral Nickel(II) Macrocyclic Complex and Trimesic Acid Jae Jeong Ryoo, Jong Won Shin, Hwan-Seok Dho and Kil Sik Min pp 7232–7234 DOI: 10.1021/ic101127z Supporting Info

Oxidative Cyclization of a Phenolic Schiff Base and Synthesis of a Cyclometalated Ruthenium Nitrosyl Complex: Photoinduced NO Release by Visible Light Kaushik Ghosh, Sushil Kumar, Rajan Kumar, Udai P. Singh and Nidhi Goel pp 7235–7237 DOI: 10.1021/ic1009847 Supporting Info

Reversible Hydrogen Activation by the Pt Complex Pt(SntBu3)2(CNtBu)2 Veeranna Yempally, Lei Zhu and Burjor Captain pp 7238–7240 DOI: 10.1021/ic101025h Supporting Info

Construction of a Novel Zn−Ni Trinuclear Schiff Base and a Ni2+ Chemosensor Guo-Bi Li, Hua-Cai Fang, Yue-Peng Cai, Zheng-Yuan Zhou, Praveen K. Thallapally and Jian Tian pp 7241–7243 DOI: 10.1021/ic101036m Supporting Info

Pincer Phosphine Complexes of Ruthenium: Formation of Ru(P−O−P)(PPh3)HCl (P−O−P = xantphos, DPEphos, (Ph2PCH2CH2)2O) and Ru(dppf)(PPh3)HCl and Characterization of Cationic Dioxygen, Dihydrogen, Dinitrogen, and Arene Coordinated Phosphine Products Araminta E. W. Ledger, Aitor Moreno, Charles E. Ellul, Mary F. Mahon, Paul S. Pregosin, Michael K. Whittlesey and Jonathan M. J. Williams pp 7244–7256 DOI: 10.1021/ic100438d Supporting Info

Polymorphic Crystal Approach to Changing the Emission of [AuCl(PPh3)2], Analyzed by Direct Observation of the Photoexcited Structures by X-ray Photocrystallography Manabu Hoshino, Hidehiro Uekusa, Satoshi Ishii, Takuhiro Otsuka, Youkoh Kaizu, Yoshiki, Ozawa and Koshiro Toriumi pp 7257–7265 DOI: 10.1021/ic901261u Supporting Info

Density Functional Theory Analysis of Structure, Energetics, and Spectroscopy for the Mn−Fe Active Site of Chlamydia trachomatis Ribonucleotide Reductase in Four Oxidation States Wen-Ge Han, Debra Ann Giammona, Donald Bashford and Louis Noodleman pp 7266–7281 DOI: 10.1021/ic902051t Supporting Info

Sugars to Control Ligand Shape in Metal Complexes: Conformationally Constrained Glycoligands with a Predetermination of Stereochemistry and a Structural Control Ludivine Garcia, Stphane Maisonneuve, Juan Xie, Rgis Guillot, Pierre Dorlet, Eric Rivire, Michel Desmadril, Franois Lambert and Clotilde Policar pp 7282–7288 DOI: 10.1021/ic1002379 Supporting Info

Trimethylsilylchalcogenolates of Co(II) and Mn(II): From Mononuclear Coordination Complexes to Clusters Containing −ESiMe3 Moieties (E = S, Se) Chhatra B. Khadka, Daniel G. Macdonald, Yanhua Lan, Annie K. Powell, Dieter Fenske and John F. Corrigan pp 7289–7297 DOI: 10.1021/ic902346u Supporting Info

Photophysical Characterization of the Interactions among Tris(2,2′-bipyridyl)ruthenium(II) Complexes Ion-Exchanged within Zirconium Phosphate Angel A. Mart and Jorge L. Coln pp 7298–7303 DOI: 10.1021/ic902419z Supporting Info

Zinc, Cadmium, and Mercury Complexes with Fluorinated Selenolate Ligands Thomas J. Emge, Michael D. Romanelli, Brian F. Moore and John G. Brennan pp 7304–7312 DOI: 10.1021/ic1002989 Supporting Info

CO Releasing Properties and Cytoprotective Effect of cis-trans- [ReII(CO)2Br2L2]n Complexes Fabio Zobi, Alois Degonda, Marcus C. Schaub and Anna Yu. Bogdanova pp 7313–7322 DOI: 10.1021/ic100458j

Synthesis, Crystal Structure, and Characterization of a Heterometallic One-Dimensional Complex with Metal−Metal Bonds Kazuhiro Uemura, Kichi Fukui, Kana Yamasaki, Kazuko Matsumoto and Masahiro Ebihara pp 7323–7330 DOI: 10.1021/ic1004775 Supporting Info

Bistrimethylsilylamide Transition-Metal Complexes as Starting Reagents in the Synthesis of Ternary Cd−Mn−Se Cluster Complexes Andreas Eichhfer, Oliver Hampe, Sergei Lebedkin and Florian Weigend pp 7331–7339 DOI: 10.1021/ic100310w Supporting Info

Unsymmetric Ru(II) Complexes with N-Heterocyclic Carbene and/or Terpyridine Ligands: Synthesis, Characterization, Ground- and Excited-State Electronic Structures and Their Application for DSSC Sensitizers Hee-Jun Park, Kyeong Ha Kim, Soo Young Choi, Hyeong-Mook Kim, Wan In Lee, Youn K. Kang and Young Keun Chung pp 7340–7352 DOI: 10.1021/ic100325c Supporting Info

New Iridathiaboranes with Reversible Isonido ↔ Nido Cluster Flexibility Jonathan Bould, Carmen Cunchillos, Fernando J. Lahoz, Luis A. Oro, John D. Kennedy and Ramn Macas pp 7353–7361 DOI: 10.1021/ic1004769 Supporting Info

Structural and Electronic Effects in the Metalation of Porphyrinoids. Theory and Experiment Łukasz Orzeł, Agnieszka Kania, Dorota Rutkowska-bik, Anna Susz, Grayna Stochel and Leszek Fiedor pp 7362–7371 DOI: 10.1021/ic100466s Supporting Info

Tetrathiafulvalene−Tetracarboxylate: An Intriguing Building Block with Versatility in Coordination Structures and Redox Properties Yu-Rong Qin, Qin-Yu Zhu, Li-Bin Huo, Zheng Shi, Guo-Qing Bian and Jie Dai pp 7372–7381 DOI: 10.1021/ic100546r Supporting Info

Structure, Stereochemistry, and Physico-Chemical Properties of Trinuclear and Dinuclear Metal(II) Complexes of a Phenol-Based Tetrapodal Schiff Base Ligand Supriya Dutta, Papu Biswas, Ulrich Flrke and Kamalaksha Nag pp 7382–7400 DOI: 10.1021/ic100666t Supporting Info

Structural, Transport, and Electrochemical Investigation of Novel AMSO4F (A = Na, Li; M = Fe, Co, Ni, Mn) Metal Fluorosulphates Prepared Using Low Temperature Synthesis Routes Prabeer Barpanda, Jean-Nol Chotard, Nadir Recham, Charles Delacourt, Mohamed Ati, Loic Dupont, Michel Armand and Jean-Marie Tarascon pp 7401–7413 DOI: 10.1021/ic100583f Supporting Info

Synthesis, Characterization, and Quantum-Chemical Studies of Ni(CN)2MX (M = Rb, Cs; X = Cl, Br) Xiaohui Liu, Manfred Speldrich, Paul Kgerler, Richard Dronskowski and Andrei L. Tchougreff pp 7414–7423 DOI: 10.1021/ic100599z

Syntheses and Magnetostructural Investigations on Kuratowski-Type Homo- and Heteropentanuclear Coordination Compounds [MZn4Cl4(L)6] (MII = Zn, Fe, Co, Ni, or Cu; L = 5,6-Dimethyl-1,2,3-benzotriazolate) Represented by the Nonplanar K3,3 Graph Shyam Biswas, Markus Tonigold, Manfred Speldrich, Paul Kgerler, Matthias Weil and Dirk Volkmer pp 7424–7434 DOI: 10.1021/ic100749k Supporting Info

Para-Quinone-Containing Bis(pyrazol-1-yl)methane Ligands: Coordination Behavior Toward CoII and a C−H Activation Reaction with CeIV Florian Blasberg, Jan W. Bats, Michael Bolte, Hans-Wolfram Lerner and Matthias Wagner pp 7435–7445 DOI: 10.1021/ic100754k Supporting Info

Crystal Structure of a New Polymorph of Li2FeSiO4 Chutchamon Sirisopanaporn, Adrien Boulineau, Darko Hanzel, Robert Dominko, Bojan Budic, A. Robert Armstrong, Peter G. Bruce and Christian Masquelier pp 7446–7451 DOI: 10.1021/ic100741x

Vanadium Diaminebis(phenolate) Complexes: Syntheses, Structures, and Reactivity in Sulfoxidation Catalysis Snia Barroso, Pedro Ado, Filipe Madeira, M. Teresa Duarte, Joo Costa Pessoa and Ana M. Martins pp 7452–7463 DOI: 10.1021/ic1007704 Supporting Info

Fluorescence-Based Nitric Oxide Sensing by Cu(II) Complexes That Can Be Trapped in Living Cells Lindsey E. McQuade and Stephen J. Lippard pp 7464–7471 DOI: 10.1021/ic100802q Supporting Info

A Novel 1D-AF Hybrid Organic−Inorganic Chromium(II) Methyl Phosphonate Dihydrate: Synthesis, X-Ray Crystal and Molecular Structure, and Magnetic Properties Elvira M. Bauer, Carlo Bellitto, Patrizia Imperatori, Guido Righini, Marcello Colapietro, Gustavo Portalone and Carlos J. Gmez-Garca pp 7472–7477 DOI: 10.1021/ic1009362 Supporting Info

Magnetic Ordering in Two Molecule-Based (10,3)-a Nets Prepared from a Copper(II) Trinuclear Secondary Building Unit Beatriz Gil-Hernndez, Pedro Gili, Jana K. Vieth, Christoph Janiak and Joaqun Sanchiz pp 7478–7490 DOI: 10.1021/ic100796e Supporting Info

Synthesis, Crystal and Electronic Structures, and Physical Properties of Caged Ternary Cu-Rich Antimonide: BaCu7.31(3)Sb5 Wu-Zui Zheng, Peng Wang, Li-Ming Wu and Ling Chen pp 7491–7496 DOI: 10.1021/ic100790r Supporting Info

Long-Range Electronic Communication in Free-Base meso-Poly(Ferrocenyl)-Containing Porphyrins Victor N. Nemykin, Gregory T. Rohde, Christopher D. Barrett, Ryan G. Hadt, Jared R. Sabin, Giacomo Reina, Pierluca Galloni and Barbara Floris pp 7497–7509 DOI: 10.1021/ic101012a Supporting Info

Sulfur-Containing Mixed-Donor Tribenzo-Macrocycles and Their Endo- and Exocyclic Supramolecular Silver(I) and Copper(I) Complexes Eun-Ju Kang, So Young Lee, Hayan Lee and Shim Sung Lee pp 7510–7520 DOI: 10.1021/ic1007473 Supporting Info

Transition Metal Complexes Supported by a Neutral Tetraamine Ligand Containing N,N-dimethylaniline Units Lei Chu, Kenneth I. Hardcastle and Cora E. MacBeth pp 7521–7529 DOI: 10.1021/ic1008347 Supporting Info

Oxo- and Hydroxomanganese(IV) Adducts: A Comparative Spectroscopic and Computational Study Swarup Chattopadhyay, Robert A. Geiger, Guochuan Yin, Daryle H. Busch and Timothy A. Jackson pp 7530–7535 DOI: 10.1021/ic101014g Supporting Info

Structural Characterization of Zinc and Iron (II/III) Complexes of a Porphyrin Bearing Two Built-in Nitrogen Bases. An Example of High-Spin Diaqua-Iron(III) Bromo Complex Ismail Hijazi, Thierry Roisnel, Pascale Even-Hernandez, Florence Geneste, Olivier Cador, Thierry Guizouarn and Bernard Boitrel pp 7536–7544 DOI: 10.1021/ic1009384 Supporting Info

Theoretical Analysis of the Spin Exchange and Magnetic Dipole−Dipole Interactions Leading to the Magnetic Structure of Ni3TeO6 Fang Wu, Erjun Kan, Chuan Tian and Myung-Hwan Whangbo pp 7545–7548 DOI: 10.1021/ic101022f

Magnetic Properties of Dysprosium Cubanes Dictated by the M−O−M Angles of the [Dy4(μ3-OH)4] Core Hongshan Ke, Patrick Gamez, Lang Zhao, Gong-Feng Xu, Shufang Xue and Jinkui Tang pp 7549–7557 DOI: 10.1021/ic101057e Supporting Info

Heterospin π-Heterocyclic Radical-Anion Salt: Synthesis, Structure, and Magnetic Properties of Decamethylchromocenium [1,2,5]Thiadiazolo[3,4-c][1,2,5]thiadiazolidyl Nikolay A. Semenov, Nikolay A. Pushkarevsky, Anton V. Lonchakov, Artem S. Bogomyakov, Elena A. Pritchina, Elizaveta A. Suturina, Nina P. Gritsan, Sergey N. Konchenko, Ruediger Mews, Victor I. Ovcharenko and Andrey V. Zibarev pp 7558–7564 DOI: 10.1021/ic101064c Supporting Info

Nature of Magnetic Interactions in 3D {[MII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (M = Mn, Fe, Co, Ni) Molecular Magnets Dawid Pinkowicz, Robert Pełka, Olga Drath, Wojciech Nitek, Maria Bałanda, Anna Małgorzata Majcher, Giordano Poneti and Barbara Sieklucka pp 7565–7576 DOI: 10.1021/ic100937h Supporting Info

Hypervalent Adducts of Chalcogen-Containing peri-Substituted Naphthalenes; Reactions of Sulfur, Selenium, and Tellurium with Dihalogens Fergus R. Knight, Amy L. Fuller, Michael Bhl, Alexandra M. Z. Slawin and J. Derek Woollins pp 7577–7596 DOI: 10.1021/ic101086h Supporting Info

Ligand Substitution from the (η5-DMP)Mn(CO)2(Solv) [DMP = 2,5-dimethylpyrrole, Solv = solvent] Complexes: To Ring Slip or Not to Ring Slip? Bert H. G. Swennenhuis, Ross Poland, Wai Yip Fan, Donald J. Darensbourg and Ashfaq A. Bengali pp 7597–7604 DOI: 10.1021/ic101123y Supporting Info

Issue 17

Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties Haiyan He, Daqiang Yuan, Huiqing Ma, Daofeng Sun, Guoqing Zhang and Hong-Cai Zhou pp 7605–7607 DOI: 10.1021/ic100822s Supporting Info

Nonplanar, Noninnocent, and Chiral: A Strongly Saddled Metallocorrole Abraham B. Alemayehu, Lars Kristian Hansen and Abhik Ghosh pp 7608–7610 DOI: 10.1021/ic1008736 Supporting Info

Structure Determination of Neptunium(VI) μ3-Hydroxobenzoate, [(NpO2)2(μ3-OH)2(H5C6COO)2]·2H2O Iraida A. Charushnikova, Nikolai N. Krot and Vadim I. Makarenkov pp 7611–7613 DOI: 10.1021/ic100951y Supporting Info

Novel Diphenoxo-Bridged Dinuclear Zinc Complexes: Generation of Phenoxyl-Radical Species and Nuclease Activity Kaushik Ghosh, Pramod Kumar, Nidhi Tyagi and Udai P. Singh pp 7614–7616 DOI: 10.1021/ic1004837 Supporting Info

Slow Magnetic Relaxation in an Octanuclear Manganese Chain Chen-I Yang, Shao-Po Hung, Gene-Hsiang Lee, Motohiro Nakano and Hui-Lien Tsai pp 7617–7619 DOI: 10.1021/ic100580g Supporting Info

Crystallographic Evidence of a Base-Free Uranium(IV) Terminal Oxo Species Steven J. Kraft, Justin Walensky, Phillip E. Fanwick, Michael B. Hall and Suzanne C. Bart pp 7620–7622 DOI: 10.1021/ic101136j Supporting Info

Hexanickel Enediolate Cluster Generated in an Acireductone Dioxygenase Model Reaction Katarzyna Rudzka, Katarzyna Grubel, Atta M. Arif and Lisa M. Berreau pp 7623–7625 DOI: 10.1021/ic100775m Supporting Info

Ligand Influence on Metal Aggregation: a Unique Bonding Mode for Pyridylpyrrolides Jos G. Andino, Jaime A. Flores, Jonathan A. Karty, Joseph P. Massa, Hyunsoo Park, Nikolay P. Tsvetkov, Robert J. Wolfe and Kenneth G. Caulton pp 7626–7628 DOI: 10.1021/ic100878s Supporting Info

Reactions of H2S with AgCl within a Porous Coordination Network Xiao-Ping Zhou, Zhengtao Xu, Matthias Zeller, Allen D. Hunter, Stephen Sin-Yin Chui, Chi-Ming Che and Jianhua Lin pp 7629–7631 DOI: 10.1021/ic101051r Supporting Info

A New Strategy for Ring Modification of Metallocenes: Carbodiimide Insertion into the η5-Y−C5H5 Bond and Subsequent Isomerization Chengfu Pi, Xiaoqing Li, Lili Zhang, Ruiting Liu, Linhong Weng and Xigeng Zhou pp 7632–7634 DOI: 10.1021/ic101346b Supporting Info

Isomerism with Metallacalix[4]arenes of the Nonsymmetrical Pyrimidine Nucleobase Cytosine: How Connectivity and Rotamer State Determine the Topology of Multinuclear Derivatives Anupam Khutia, Pablo J. Sanz Miguel and Bernhard Lippert pp 7635–7637 DOI: 10.1021/ic100794s Supporting Info

Complexation of Cyclohexanocucurbit[6]uril with Cadmium Ions: X-ray Crystallographic and Electrochemical Study Xing Feng, Zhong-Fei Li, Sai-Feng Xue, Zhu Tao, Qian-Jiang Zhu, Yun-Qian Zhang and Jing-Xin Liu pp 7638–7640 DOI: 10.1021/ic1013494 Supporting Info

Dinuclear Gold Diselenophosphate Complexes: Structures and Photoluminescence Hong-Jhin You, Ching-Shiang Fang, Ju-Ling Lin, Shih-Sheng Sun and C. W. Liu pp 7641–7643 DOI: 10.1021/ic101390e Supporting Info

New Members of the {Fe(NO)2}10 Dinitrosyliron Complexes Bound with [Thiolate, Thiolate] and [Amide, Amide] Ligations Jheng-Hong Wang and Chien-Hong Chen pp 7644–7646 DOI: 10.1021/ic101126v Supporting Info

A Pd6 Molecular Cage via Multicomponent Self-Assembly Incorporating Both Neutral and Anionic Linkers Arun Kumar Bar, Golam Mostafa and Partha Sarathi Mukherjee pp 7647–7649 DOI: 10.1021/ic101139s Supporting Info

Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine Matthew F. Cain, Russell P. Hughes, David S. Glueck, James A. Golen, Curtis E. Moore and Arnold L. Rheingold pp 7650–7662 DOI: 10.1021/ic100816u Supporting Info

Seleno-Auranofin (Et3PAuSe-tagl): Synthesis, Spectroscopic (EXAFS, 197Au Mssbauer, 31P, 1H, 13C, and 77Se NMR, ESI-MS) Characterization, Biological Activity, and Rapid Serum Albumin-Induced Triethylphosphine Oxide Generation David T. Hill, Anvarhusein A. Isab, Don E. Griswold, Michael J. DiMartino, Elizabeth D. Matz, Angel L. Figueroa, Joyce E. Wawro, Charles DeBrosse, William M. Reiff, Richard C. Elder, Benjamin Jones, James W. Webb and C. Frank Shaw, III pp 7663–7675 DOI: 10.1021/ic902335z Supporting Info

Torsionally Controlled Electronic Coupling in Mixed-Valence Oxodimolybdenum Nitrosyl Scorpionates - a DFT Study Piotr P. Romaczyk, Klemens Noga, Andrzej J. Włodarczyk, Wojciech Nitek and Ewa Broclawik pp 7676–7684 DOI: 10.1021/ic100024h Supporting Info

Porous Coordination Polymers of Transition Metal Sulfides with PtS Topology Built on a Semirigid Tetrahedral Linker Jun Zhang, Yun-Shan Xue, Li-Li Liang, Shi-Bin Ren, Yi-Zhi Li, Hong-Bin Du and Xiao-Zeng You pp 7685–7691 DOI: 10.1021/ic100212q Supporting Info

Chiral Salicyloxazolines as Auxiliaries for the Asymmetric Synthesis of Ruthenium Polypyridyl Complexes Lei Gong, Seann P. Mulcahy, Deepa Devarajan, Klaus Harms, Gernot Frenking and Eric Meggers pp 7692–7699 DOI: 10.1021/ic100229e Supporting Info

Probing the Structure, Conformation, and Stereochemical Exchange in a Family of Lanthanide Complexes Derived from Tetrapyridyl-Appended Cyclen Louise S. Natrajan, Ntai M. Khoabane, Benjamin L. Dadds, Christopher A. Muryn, Robin G. Pritchard, Sarah L. Heath, Alan M. Kenwright, Ilya Kuprov and Stephen Faulkner pp 7700–7709 DOI: 10.1021/ic100447m Supporting Info

Theoretical Investigations on the Formation and Dehydrogenation Reaction Pathways of H(NH2BH2)nH (n = 1−4) Oligomers: Importance of Dihydrogen Interactions Jun Li, Shawn M. Kathmann, Han-Shi Hu, Gregory K. Schenter, Tom Autrey and Maciej Gutowski pp 7710–7720 DOI: 10.1021/ic100418a Supporting Info

Facile Synthesis and Luminescence of Uniform Y2O3 Hollow Spheres by a Sacrificial Template Route Guang Jia, Hongpeng You, Yanhua Song, Yeju Huang, Mei Yang and Hongjie Zhang pp 7721–7725 DOI: 10.1021/ic100430g Supporting Info

Reaction of RuII Diazafluorenone Compound with Nanocrystalline TiO2 Thin Film William B. Heuer, Hai-Long Xia, Maria Abrahamsson, Zhen Zhou, Shane Ardo, Amy A. Narducci Sarjeant and Gerald J. Meyer pp 7726–7734 DOI: 10.1021/ic100527d Supporting Info

Three p-tert-Butylthiacalix[4]arene-Supported Cobalt Compounds Obtained in One Pot Involving In Situ Formation of N6H2 Ligand Yanfeng Bi, Wuping Liao, Guancheng Xu, Ruiping Deng, Meiyan Wang, Zhijian Wu, Song Gao and Hongjie Zhang pp 7735–7740 DOI: 10.1021/ic1005105 Supporting Info

Chemistry of Molybdaboranes: Synthesis, Structures, and Characterization of a New Class of Open-Cage Dimolybdaheteroborane Clusters Rajendra Singh Dhayal, Kiran Kumar Varma Chakrahari, Babu Varghese, Shaikh M. Mobin and Sundargopal Ghosh pp 7741–7747 DOI: 10.1021/ic100520k Supporting Info

Self-Assembly of Alkali-Uranyl-Peroxide Clusters May Nyman and Mark A. Rodriguez, Charles F. Campana pp 7748–7755 DOI: 10.1021/ic1005192 Supporting Info

Manganese(II)-Octacyanometallate(V) Bimetallic Ferrimagnets with Tc from 41 to 53 K Obtained in Acidic Media Tian-Wei Wang, Jun Wang, Shin-ichi Ohkoshi, You Song and Xiao-Zeng You pp 7756–7763 DOI: 10.1021/ic100591h Supporting Info

One-Dimensional Coordination Polymers from Hexanuclear Manganese Carboxylate Clusters Featuring a {MnII4MnIII2(μ4-O)2} Core and Spacer Linkers Iurii L. Malaestean, Victor Ch. Kravtsov, Manfred Speldrich, Galina Dulcevscaia, Yurii A. Simonov, Janusz Lipkowski, Arkady Ellern, Svetlana G. Baca and Paul Kgerler pp 7764–7772 DOI: 10.1021/ic100541m Supporting Info

Density Functional Theory Study on the Mechanism of the Reductive Cleavage of CO2 by a Bis-β-Diketoiminatediiron Dinitrogen Complex Alireza Ariafard, Nigel J. Brookes, Robert Stranger, Peter D.W. Boyd and Brian F. Yates pp 7773–7782 DOI: 10.1021/ic1005715 Supporting Info

Self-Assembly and Host−Guest Interaction of Metallomacrocycles Using Fluorescent Dipyrazole Linker with Dimetallic Clips Guo-Hong Ning, Liao-Yuan Yao, Li-Xia Liu, Ting-Zheng Xie, Yi-Zhi Li, Yu Qin, Yuan-Jiang Pan and Shu-Yan Yu pp 7783–7792 DOI: 10.1021/ic100724r Supporting Info

Six-Coordinate Nitrosyl and Nitro Complexes of meso-Tetratolylporphyrinatocobalt with Trans Sulfur-Donor Ligands Tigran S. Kurtikyan, Gurgen M. Gulyan, Arina M. Dalaloyan, Bryce E. Kidd and John A. Goodwin pp 7793–7798 DOI: 10.1021/ic1007846

Precisely Controlled Growth of Heterostructured Nanocrystals via a Dissolution−Attachment Process Shuling Shen, Zhihong Tang, Qing Liu and Xun Wang pp 7799–7807 DOI: 10.1021/ic100601a Supporting Info

Trends in Aqueous Hydration Across the 4f Period Assessed by Reliable Computational Methods Jadwiga Kuta and Aurora E. Clark pp 7808–7817 DOI: 10.1021/ic100623y Supporting Info

Bright Sky-Blue Phosphorescence of [n-Bu4N][Pt(4,6-dFppy)(CN)2]: Synthesis, Crystal Structure, and Detailed Photophysical Studies Andreas F. Rausch, Uwe V. Monkowius, Manfred Zabel and Hartmut Yersin pp 7818–7825 DOI: 10.1021/ic100851b Supporting Info

Density Functional Theory Interpretation of the 1H Photo-Chemically Induced Dynamic Nuclear Polarization Enhancements Characterizing Photoreduced Polyazaaromatic Ru(II) Coordination Complexes Emilie Caut, Stuart Bogatko, Epiphanie Mugeniwabagara, Luca Fusaro, Andre Kirsch-De Mesmaeker, Michel Luhmer and Nathalie Vaeck pp 7826–7831 DOI: 10.1021/ic100636j Supporting Info

Separation of Geometric Isomers of a Dicopper Complex by Using a 19F-Labeled Ligand: Dynamics, Structures, and DFT Calculations Stphanie Durot, Laila H. Hossain, Sylvain Hamman, Hlne Jamet, Maylis Orio, Isabelle Gautier-Luneau, Dominique Luneau, Christian Philouze, Jean-Louis Pierre and Catherine Belle pp 7832–7840 DOI: 10.1021/ic1006567 Supporting Info

Coordination of Cu2+ Ions to C2 Symmetric Pseudopeptides Derived from Valine Salvador Blasco, M. Isabel Burguete, M. Paz Clares, Enrique Garca-Espaa, Jorge Escorihuela and Santiago V. Luis pp 7841–7852 DOI: 10.1021/ic100748g Supporting Info

X-Ray Structural Characterization of the Bis-Guanine Derivative of a Cisplatin Analogue Having Just One Proton on Each Coordinated Nitrogen and a Head-to-Head Conformation: [Pt{(±)-N,N′-Dimethyl-2,3-diaminobutane}(9-ethyl-guanine)2]dinitrate Francesco P. Intini, Renzo Cini, Gabriella Tamasi, Michael B. Hursthouse, Luigi G. Marzilli and Giovanni Natile pp 7853–7860 DOI: 10.1021/ic100972s Supporting Info

Preparation and Characterization of (CNSSS)2(A)2 (A = AsF6−, SbF6−, Sb2F11−) Containing the O2-like 5,5′-Bis(1,2,3,4-trithiazolium) Dication: The Second Example of a Simple Nonsterically Hindered Main-Group Diradical That Retains Its Paramagnetism in the Solid State T. Stanley Cameron, Andreas Decken, Friedrich Grein, Carsten Knapp, Jack Passmore, J. Mikko Rautiainen, Konstantin V. Shuvaev, Robert C. Thompson and Dale J. Wood pp 7861–7879 DOI: 10.1021/ic100760t Supporting Info

[Cu3(Hmesox)3]3−: a Precursor for the Rational Design of Chiral Molecule-Based Magnets (H4mesox = 2-dihydroxymalonic acid) Joaqun Sanchiz, Jorge Pasn, Oscar Fabelo, Francesc Lloret, Miguel Julve and Catalina Ruiz-Prez pp 7880–7889 DOI: 10.1021/ic100786j Supporting Info

Variation and Analysis of Second-Sphere Interactions and Axial Histidinate Character in c-type Cytochromes Sarah E. J. Bowman and Kara L. Bren pp 7890–7897 DOI: 10.1021/ic100899k Supporting Info

Turn-on Luminescent Probe for Cysteine/Homocysteine Based on a Ruthenium(II) Complex Run Zhang, Xiaojing Yu, Zhiqiang Ye, Guilan Wang, Wenzhu Zhang and Jingli Yuan pp 7898–7903 DOI: 10.1021/ic100810z

Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to Ammonia J. M. Chin, R. R. Schrock and P. Mller pp 7904–7916 DOI: 10.1021/ic100856n Supporting Info

Metal Organic Frameworks Assembled from Y(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates Zakariae Amghouz, Laura Roces, Santiago Garca-Granda and Jos R. Garca, Badredine Souhail, Lus Mafra, Fa-nian Shi and Joo Rocha pp 7917–7926 DOI: 10.1021/ic100867w Supporting Info

Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium Padmini Ramaswamy, Ramanath Prabhu and Srinivasan Natarajan pp 7927–7934 DOI: 10.1021/ic101043z Supporting Info

BaGa2Pn2 (Pn = P, As): New Semiconducting Phosphides and Arsenides with Layered Structures Hua He, Ryan Stearrett, Edmund R. Nowak and Svilen Bobev pp 7935–7940 DOI: 10.1021/ic100940b Supporting Info

Synthesis and Coordination Chemistry of a New N4-Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of FeII, ZnII, NiII, VIV, PdII and Use for Heterobimetallic Systems Riccardo Wanke, M. Ftima C. Guedes da Silva, Stefano Lancianesi, Telma F. S. Silva, Lusa M. D. R. S. Martins, Claudio Pettinari and Armando J. L. Pombeiro pp 7941–7952 DOI: 10.1021/ic100966u Supporting Info

Is the Reactivity of M(II)−Arene Complexes of 3-Hydroxy-2(1H)-pyridones to Biomolecules the Anticancer Activity Determining Parameter? Muhammad Hanif, Helena Henke, Samuel M. Meier, Sanela Martic, Mahmoud Labib, Wolfgang Kandioller, Michael A. Jakupec, Vladimir B. Arion, Heinz-Bernhard Kraatz, Bernhard K. Keppler and Christian G. Hartinger pp 7953–7963 DOI: 10.1021/ic1009785 Supporting Info

Structure and Dynamics of the Chromate Ion in Aqueous Solution. An ab Initio QMCF-MD Simulation Ernst Hinteregger, Andreas B. Pribil, Thomas S. Hofer, Bernhard R. Randolf, Alexander K. H. Weiss and Bernd M. Rode pp 7964–7968 DOI: 10.1021/ic101001e Supporting Info

Two 3D Triazolate−Tricarboxylate-Bridged CuII/I Frameworks by One-Pot Hydrothermal Synthesis Exhibiting Spin-Canted Antiferromagnetism and Strong Antiferromagnetic Couplings En-Cui Yang, Zhong-Yi Liu, Xiang-Jun Shi, Qing-Qing Liang and Xiao-Jun Zhao pp 7969–7975 DOI: 10.1021/ic100880j Supporting Info

P−P Bond Activation of P4 Tetrahedron by Group 13 Carbenoid and its Bis Molybdenum Pentacarbonyl Adduct Ganesan Prabusankar, Adinarayana Doddi, Christian Gemel, Manuela Winter and Roland A. Fischer pp 7976–7980 DOI: 10.1021/ic1010743 Supporting Info

Synthesis and Solution Phase Characterization of Strongly Photooxidizing Heteroleptic Cr(III) Tris-Dipyridyl Complexes Ashley M. McDaniel, Huan-Wei Tseng, Niels H. Damrauer and Matthew P. Shores pp 7981–7991 DOI: 10.1021/ic1009972 Supporting Info

Breaking the Cycle: Impact of Sterically-Tailored Tetra(pyrazolyl)lutidines on the Self-Assembly of Silver(I) Complexes Tyler J. Morin, Andrew Merkel, Sergey V. Lindeman and James R. Gardinier pp 7992–8002 DOI: 10.1021/ic1010538 Supporting Info

Amino-Alcohol Ligands: Synthesis and Structure of N,N′-bis(2-hydroxycyclopentyl)ethane-1,2-diamine and Its Salts, and an Assessment of Its Fitness and That of Related Ligands for Complexing Metal Ions Alvaro S. de Sousa, Manuel A. Fernandes, Kamentheren Padayachy and Helder M. Marques pp 8003–8011 DOI: 10.1021/ic101018b Supporting Info

Interconnected Trimeric, Pentameric, and Hexameric Metallacycles in a Singular Silver−Adenine Framework Ashutosh Kumar Mishra and Sandeep Verma pp 8012–8016 DOI: 10.1021/ic1010902 Supporting Info

The Magnetism of (5MAP)2CuBr4 [5MAP = 5-Methyl-2-aminopyridinium]: A Quasi-2D or a 3D Magnetic System? Joaquim Jornet-Somoza, Merc Deumal, Christopher P. Landee, Mark M. Turnbull and Juan J. Novoa pp 8017–8024 DOI: 10.1021/ic101023b Supporting Info

Mechanism of Nitric Oxide Reactivity and Fluorescence Enhancement of the NO-Specific Probe CuFL1 Lindsey E. McQuade, Michael D. Pluth and Stephen J. Lippard pp 8025–8033 DOI: 10.1021/ic101054u Supporting Info

Differences of pH-Dependent Mechanisms on Generation of Hydride Donors using Ru(II) Complexes Containing Geometric Isomers of NAD+ Model Ligands: NMR and Radiolysis Studies in Aqueous Solution Brian W. Cohen, Dmitry E. Polyansky, Ruifa Zong, Hui Zhou, Theany Ouk, Diane E. Cabelli, Randolph P. Thummel and Etsuko Fujita pp 8034–8044 DOI: 10.1021/ic101098v Supporting Info

Sulfur-Based Redox Reactions in Mo3S74+ and Mo3S44+ Clusters Bearing Halide and 1,2-Dithiolene Ligands: a Mass Spectrometric and Density Functional Theory Study Rosa Llusar, Victor Polo, Ederley Velez and Cristian Vicent pp 8045–8055 DOI: 10.1021/ic1010693 Supporting Info

Chromium−Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C═O Activation of Acetone Minghuey Shieh, Chien-Nan Lin, Chia-Yeh Miu, Miao-Hsing Hsu, Yi-Wen Pan and Li-Fang Ho pp 8056–8066 DOI: 10.1021/ic101118y Supporting Info

Series of Isostructural Planar Lanthanide Complexes [LnIII4(μ3-OH)2(mdeaH)2(piv)8] with Single Molecule Magnet Behavior for the Dy4 Analogue Ghulam Abbas, Yanhua Lan, George E. Kostakis, Wolfgang Wernsdorfer, Christopher E. Anson and Annie K. Powell pp 8067–8072 DOI: 10.1021/ic1011605 Supporting Info

Role of Orbital Degeneracy in the Single Molecule Magnet Behavior of a Mononuclear High-Spin Fe(II) Complex A. V. Palii, J. M. Clemente-Juan, E. Coronado, S. I. Klokishner, S. M. Ostrovsky and O.S. Reu pp 8073–8077 DOI: 10.1021/ic1011296

Structural and Magnetic Effects of meso-Substitution in Alkyl-Substituted Metalloporphyrinate π-Cation Radicals: Characterization of [Fe(TalkylP•)(Cl)]SbCl6 (alkyl = ethyl and n-propyl) Ming Li, Teresa J. Neal, Graeme R. A. Wyllie, Charles E. Schulz and W. Robert Scheidt pp 8078–8085 DOI: 10.1021/ic101099z Supporting Info

Evaluation of Heterogeneous Metal−Organic Framework Organocatalysts Prepared by Postsynthetic Modification Sergio J. Garibay, Zhenqiang Wang and Seth M. Cohen pp 8086–8091 DOI: 10.1021/ic1011549 Supporting Info

Novel Three-Dimensional Metal-Azide Network Induced by a Bipyridine-Based Zwitterionic Monocarboxylate Ligand: Structures and Magnetism Yu Ma, Xiu-Bing Li, Xiu-Chun Yi, Qin-Xiang Jia, En-Qing Gao and Cai-Ming Liu pp 8092–8098 DOI: 10.1021/ic1011633 Supporting Info

2-(Aminomethyl)phenyl Complexes of Au(III), Mixed Au(III)/Ag(I), and Pd(II) with the 2,2-Diacetyl-1,1-Ethylenedithiolato Ligand: Dancing of Palladacycles around a Juggler Ligand Jos Vicente, Mara-Teresa Chicote, Elosa Martnez-Viviente, Antonio-Jess Martnez-Martnez and Nicols Snchez-Moya, Peter G. Jones pp 8099–8111 DOI: 10.1021/ic101188z Supporting Info

Syntheses of Selenolato-Bridged Dinuclear Hydridoplatinum Complexes [Pt2H2(μ-SetBu)2(PPh3)2] and [Pt2H(SetBu)(μ-SetBu)2(PPh3)2]: Unusual Thermal Reaction of Hydrido(1,1-Dimethylethaneselenolato) Platinum Complex cis-[PtH(SetBu)(PPh3)2] Norio Nakata, Takashige Ikeda and Akihiko Ishii pp 8112–8116 DOI: 10.1021/ic1011742 Supporting Info

The Bis Metallacyclic Anion [U(N{SiMe3}2)(CH2SiMe2N{SiMe3})2]− Olivier Bnaud, Jean-Claude Berthet, Pierre Thury and Michel Ephritikhine pp 8117–8130 DOI: 10.1021/ic1012044 Supporting Info

Iridium Ziegler-Type Hydrogenation Catalysts Made from [(1,5-COD)Ir(μ-O2C8H15)]2 and AlEt3: Spectroscopic and Kinetic Evidence for the Irn Species Present and for Nanoparticles as the Fastest Catalyst William M. Alley, Isil K. Hamdemir, Qi Wang, Anatoly I. Frenkel, Long Li, Judith C. Yang, Laurent D. Menard, Ralph G. Nuzzo, Saim zkar, Kimberly A. Johnson and Richard G. Finke pp 8131–8147 DOI: 10.1021/ic101237c Supporting Info

His-Oriented Peptide Hydrolysis Promoted by cis-[Pt(en)(H2O)2]2+: a New Specific Peptide Cleavage Site Jin Hong, Yang Jiao, Weijiang He, Zijian Guo, Zhen Yu, Junfeng Zhang and Longgen Zhu pp 8148–8154 DOI: 10.1021/ic101191m Supporting Info

Use of a Reduced Schiff-Base Ligand to Prepare Novel Chloro-Bridged Chains of Rare Cu(II) Trinuclear Complexes with Mixed Azido/Oxo and Chloro/Oxo Bridges Apurba Biswas, Michael G. B. Drew, Carlos J. Gmez-Garca and Ashutosh Ghosh pp 8155–8163 DOI: 10.1021/ic101183n Supporting Info

Synthesis and Reactivity of Sulfur(II) Dications Stabilized Using Monodentate Ligands Caleb D. Martin and Paul J. Ragogna pp 8164–8172 DOI: 10.1021/ic1012582 Supporting Info

Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds Jean-Claude Berthet, Pierre Thury and Michel Ephritikhine pp 8173–8177 DOI: 10.1021/ic101310z Supporting Info

Issue 18

Application of High Surface Area Tin-Doped Indium Oxide Nanoparticle Films as Transparent Conducting Electrodes Paul G. Hoertz, Zuofeng Chen, Caleb A. Kent, and Thomas J. Meyer pp 8179–8181 DOI: 10.1021/ic100719r Supporting Info

N-Heterocyclic Carbene Embedded in an N-Confused Porphyrin Framework Motoki Toganoh, Takayoshi Hihara, and Hiroyuki Furuta pp 8182–8184 DOI: 10.1021/ic1016356 Supporting Info

A Simple and Efficient Way to Synthesize Unsolvated Sodium Octahydrotriborate Zhenguo Huang, Graham King, Xuenian Chen, Jason Hoy, Teshome Yisgedu, Hima K. Lingam, Sheldon G. Shore, Patrick M. Woodward, and Ji-Cheng Zhao pp 8185–8187 DOI: 10.1021/ic101543v Supporting Info

Catalytically Stable and Active CeO2 Mesoporous Spheres Xin Liang, Junjia Xiao, Biaohua Chen, and Yadong Li pp 8188–8190 DOI: 10.1021/ic100795p Supporting Info

Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation Properties Qing-Yan Liu, Yu-Ling Wang, Zeng-Mei Shan, Rong Cao, Yun-Liang Jiang, Zu-Jian Wang, and Er-Lei Yang pp 8191–8193 DOI: 10.1021/ic1009303 Supporting Info

Sandwich-Type Zinc-Containing Polyoxometalates with a Hexaprismane Core [{Zn2W(O)O3}2]4+ Synthesized by Thermally Induced Isomerization of a Metastable Polyoxometalate Yuji Kikukawa, Kazuya Yamaguchi, and Noritaka Mizuno pp 8194–8196 DOI: 10.1021/ic101419a Supporting Info

Improved Synthesis of Bis(borano)hypophosphite Salts Mitchell R. Anstey, Michael T. Corbett, Eric H. Majzoub, and Joseph G. Cordaro pp 8197–8199 DOI: 10.1021/ic101326c Supporting Info

Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0) Brian V. Popp, Christine M. Morales, Clark R. Landis, and Shannon S. Stahl pp 8200–8207 DOI: 10.1021/ic100806w Supporting Info

Synthesis and Iron Sequestration Equilibria of Novel Exocyclic 3-Hydroxy-2-pyridinone Donor Group Siderophore Mimics James M. Harrington, Sumathi Chittamuru, Suraj Dhungana, Hollie K. Jacobs, Aravamudan S. Gopalan, and Alvin L. Crumbliss pp 8208–8221 DOI: 10.1021/ic902595c Supporting Info

Nickel(II)-Dipeptidoamine-Based Tetrameric Complex: Structural Study in Solution and in Solid State Katalin Selmeczi, Patrick Gizzi, Delphine Champmartin, Patrice Rubini, Emmanuel Aubert, Slimane Dahaoui, and Bernard Henry pp 8222–8229 DOI: 10.1021/ic101167f Supporting Info

Correlation between Structural and Semiconductor−Metal Changes and Extreme Conditions Materials Chemistry in Ge−Sn Christophe L. Guillaume, George Serghiou, Andrew Thomson, Jean-Paul Morniroli, Dan J. Frost, Nicholas Odling, and Chris E. Jeffree pp 8230–8236 DOI: 10.1021/ic100273q Supporting Info

Bis(maltolato)vanadium(III)-Polypyridyl Complexes: Synthesis, Characterization, DNA Cleavage, and Insulin Mimetic Activity Md. Nazrul Islam, Anupa A. Kumbhar, Avinash S. Kumbhar, Matthias Zeller, Raymond J. Butcher, Menakshi Bhat Dusane, and Bimba N. Joshi pp 8237–8246 DOI: 10.1021/ic9025359 Supporting Info

Intercluster Compound between a Tetrakis{triphenylphosphinegold(I)}oxonium Cation and a Keggin Polyoxometalate (POM): Formation during the Course of Carboxylate Elimination of a Monomeric Triphenylphosphinegold(I) Carboxylate in the Presence of POMs Kenji Nomiya, Takuya Yoshida, Yoshitaka Sakai, Arisa Nanba, and Shinichiro Tsuruta pp 8247–8254 DOI: 10.1021/ic100530h Supporting Info

Heteropolynuclear Gold Complexes with Metallophilic Interactions: Modulation of the Luminescent Properties Maria Jos Calhorda, Carmen Ceamanos, Olga Crespo, M. Concepcin Gimeno, Antonio Laguna, Carmen Larraz, Pedro D. Vaz, and M. Dolores Villacampa pp 8255–8269 DOI: 10.1021/ic100413x Supporting Info

Ionothermal Synthesis of Layered Zirconium Phosphates and Their Tribological Properties in Mineral Oil Lei Liu, Zhao-Feng Chen, Hai-Bo Wei, Yang Li, Yu-Chuan Fu, Hong Xu, Jin-Ping Li, Alexandra M. Z. Slawin, and Jin-Xiang Dong pp 8270–8275 DOI: 10.1021/ic100657a Supporting Info

Hg2+ Detection by New Anthracene Pendant-Arm Derivatives of Mixed N/S- and N/S/O-Donor Macrocycles: Fluorescence, Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry and Density Functional Theory Studies Marta Mameli, Vito Lippolis, Claudia Caltagirone, Jos Luis Capelo, Olalla Nieto Faza, and Carlos Lodeiro pp 8276–8286 DOI: 10.1021/ic1007439 Supporting Info

Effect of Five Membered Versus Six Membered Meso-Substituents on Structure and Electronic Properties of Mg(II) Porphyrins: A Combined Experimental and Theoretical Study Avijit Ghosh, Shaikh M. Mobin, Roland Frhlich, Ray J. Butcher, Dilip K. Maity, and Mangalampalli Ravikanth pp 8287–8297 DOI: 10.1021/ic1008522

Oxygen Close-Packed Structure in Amorphous Indium Zinc Oxide Thin Films Tatsuya Eguchi, Hiroyuki Inoue, Atsunobu Masuno, Koji Kita, and Futoshi Utsuno pp 8298–8304 DOI: 10.1021/ic1006617

New Three-Dimensional Thiostannates Composed of Linked Cu8S12 Clusters and the First Example of a Mixed-Metal Cu7SnS12 Cluster Malte Behrens, Marie-Eve Ordolff, Christian Nther, Wolfgang Bensch, Klaus-Dieter Becker, Catherine Guillot-Deudon, Alain Lafond, and Jason A. Cody pp 8305–8309 DOI: 10.1021/ic100688z Supporting Info

Mssbauer, Electron Paramagnetic Resonance, and Density Functional Theory Studies of Synthetic S = 1/2 FeIII−O−FeIV═O Complexes. Superexchange-Mediated Spin Transition at the FeIV═O Site Raymond F. De Hont, Genqiang Xue, Michael P. Hendrich, Lawrence Que, Jr., Emile L. Bominaar, and Eckard Mnck pp 8310–8322 DOI: 10.1021/ic100870v Supporting Info

Ligand Identification in Titanium Complexes Using X-ray Valence-to-Core Emission Spectroscopy Janine C. Swarbrick, Yaroslav Kvashnin, Karina Schulte, Kalaivani Seenivasan, Carlo Lamberti, and Pieter Glatzel pp 8323–8332 DOI: 10.1021/ic100755t Supporting Info

Energy Transfer Dynamics in Multichromophoric Arrays Engineered from Phosphorescent PtII/RuII/OsII Centers Linked to a Central Truxene Platform Barbara Ventura, Andrea Barbieri, Francesco Barigelletti, Stphane Diring, and Raymond Ziessel pp 8333–8346 DOI: 10.1021/ic1008413 Supporting Info

Electronic Coupling between Two Cyclometalated Ruthenium Centers Bridged by 1,3,6,8-Tetra(2-pyridyl)pyrene (tppyr) Chang-Jiang Yao, Long-Zhen Sui, Hai-Yan Xie, Wen-Jing Xiao, Yu-Wu Zhong, and Jiannian Yao pp 8347–8350 DOI: 10.1021/ic100857y Supporting Info

New Efficient Ruthenium Sensitizers with Unsymmetrical Indeno[1,2-b]thiophene or a Fused Dithiophene Ligand for Dye-Sensitized Solar Cells Jeum-Jong Kim, Kimin Lim, Hyunbong Choi, Shengqiang Fan, Moon-Sung Kang, Guohua Gao, Hong Seok Kang, and Jaejung Ko pp 8351–8357 DOI: 10.1021/ic1009658 Supporting Info

Single-Chain Magnets Constructed by Using the Strict Orthogonality of Easy-Planes: Use of Structural Flexibility to Control the Magnetic Properties Takashi Kajiwara, Hiroki Tanaka, Motohiro Nakano, Shinya Takaishi, Yasuhiro Nakazawa, and Masahiro Yamashita pp 8358–8370 DOI: 10.1021/ic100843k Supporting Info

Two Metals Are Better than One: Investigations on the Interactions between Dinuclear Metal Complexes and Quadruplex DNA Kogularamanan Suntharalingam, Andrew J. P. White, and Ramon Vilar pp 8371–8380 DOI: 10.1021/ic100884p Supporting Info

Dichalcogenide Bonding in Seven Alkali-Metal Actinide Chalcogenides of the KTh2Se6 Structure Type Daniel E. Bugaris, Daniel M. Wells, Jiyong Yao, S. Skanthakumar, Richard G. Haire, L. Soderholm, and James A. Ibers pp 8381–8388 DOI: 10.1021/ic1008895 Supporting Info

Porphyrin−Fullerene, C60, Cocrystallates: Influence of C60 on the Porphyrin Ring Conformation P. Bhyrappa and K. Karunanithi pp 8389–8400 DOI: 10.1021/ic101030h Supporting Info

Incorporation of Boron, Aluminum, and Gallium Derivatives into [{Ti(η5-C5Me5)(μ-O)}3(μ3-CR)] (R = H, Me) Alberto Hernn-Gmez, Avelino Martn, Miguel Mena, and Cristina Santamara pp 8401–8410 DOI: 10.1021/ic100912p Supporting Info

Continuous Shape- and Spectroscopy-Tuning of Hematite Nanocrystals Liqiao Chen, Xianfeng Yang, Jian Chen, Jia Liu, Hao Wu, Hongquan Zhan, Chaolun Liang, and Mingmei Wu pp 8411–8420 DOI: 10.1021/ic100919a Supporting Info

Ligand Effects on the [Cu(PhO)(PhOH)]+ Redox Active Complex Elixabete Rezabal, Lucie Duchkov, Petr Milko, Max C. Holthausen, and Jana Roithov pp 8421–8429 DOI: 10.1021/ic100952q Supporting Info

Monomeric Square-Planar Cobalt(II) Acetylacetonate: Mystery or Mistake? Volodimir D. Vreshch, Jen-Hsien Yang, Haitao Zhang, Alexander S. Filatov, and Evgeny V. Dikarev pp 8430–8434 DOI: 10.1021/ic100963r Supporting Info

Associative and Dissociative Mechanisms in the Formation of Phthalazine Bridged Organodiplatinum(II) Complexes Mehdi Rashidi, S. Masoud Nabavizadeh, Ahad Zare, Sirous Jamali, and Richard J. Puddephatt pp 8435–8443 DOI: 10.1021/ic1010067 Supporting Info

A Robust Highly Interpenetrated Metal−Organic Framework Constructed from Pentanuclear Clusters for Selective Sorption of Gas Molecules Zhangjing Zhang, Shengchang Xiang, Yu-Sheng Chen, Shengqian Ma, Yongwoo Lee, Thomas Phely-Bobin, and Banglin Chen pp 8444–8448 DOI: 10.1021/ic1010083 Supporting Info

Mixed d−f3 Coordination Complexes Possessing Improved Near-Infrared (NIR) Lanthanide Luminescent Properties in Aqueous Solution Aline M. Nonat, Clmence Allain, Stephen Faulkner, and Thorfinnur Gunnlaugsson pp 8449–8456 DOI: 10.1021/ic1010852 Supporting Info

TiO2(B) Nanoribbons As Negative Electrode Material for Lithium Ion Batteries with High Rate Performance Thomas Beuvier, Mireille Richard-Plouet, Maryline Mancini-Le Granvalet, Thierry Brousse, Olivier Crosnier, and Luc Brohan pp 8457–8464 DOI: 10.1021/ic1010192 Supporting Info

Preparation, Size Control, Surface Deposition, and Catalytic Reactivity of Hydrophobic Corrolazine Nanoparticles in an Aqueous Environment Kevin Cho, William D. Kerber, Se Ryeon Lee, Albert Wan, James D. Batteas, and David P. Goldberg pp 8465–8473 DOI: 10.1021/ic101035q Supporting Info

Metal Monophosphonates M{(2-C5H4NO)CH2PO3}(H2O)2 (M = Co, Ni, Mn, Cd): Synthesis, Structure, and Magnetism Ting-Hai Yang, Elisabeth S. Knowles, Daniel M. Pajerowski, Jian-Sheng Xia, Liang Yin, Song Gao, Mark W. Meisel, and Li-Min Zheng pp 8474–8480 DOI: 10.1021/ic101033n Supporting Info

Synthesis and Characterization of the M(II) (M = Ge, Sn, or Pb) Phosphinidene Dimers {M(μ-PAr′)}2 (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2) W. Alexander Merrill, Eric Rivard, Jeffrey S. DeRopp, Xinping Wang, Bobby D. Ellis, James C. Fettinger, Bernd Wrackmeyer, and Philip P. Power pp 8481–8486 DOI: 10.1021/ic101068a Supporting Info

All-Nitrogen Coordinated Amidinato/Imido Complexes of Molybdenum and Tungsten: Syntheses and Characterization Vanessa Gwildies, Tobias B. Thiede, Saeed Amirjalayer, Louay Alsamman, Anjana Devi, and Roland A. Fischer pp 8487–8494 DOI: 10.1021/ic101060s Supporting Info

Iron Thiobiurets: Single-Source Precursors for Iron Sulfide Thin Films Karthik Ramasamy, Mohammad A. Malik, Madeline Helliwell, Floriana Tuna, and Paul O’Brien pp 8495–8503 DOI: 10.1021/ic1011204 Supporting Info

X-ray Crystal Structures of [XeF][MF6] (M = As, Sb, Bi), [XeF][M2F11] (M = Sb, Bi) and Estimated Thermochemical Data and Predicted Stabilities for Noble-Gas Fluorocation Salts using Volume-Based Thermodynamics Hugh St. A. Elliott, John F. Lehmann, Hlne P.A. Mercier, H. Donald Brooke Jenkins, and Gary J. Schrobilgen pp 8504–8523 DOI: 10.1021/ic101152x Supporting Info

Pnictogen-Hydride Activation by (silox)3Ta (silox = tBu3SiO); Attempts to Circumvent the Constraints of Orbital Symmetry in N2 Activation Elliott B. Hulley, Jeffrey B. Bonanno, Peter T. Wolczanski, Thomas R. Cundari, and Emil B. Lobkovsky pp 8524–8544 DOI: 10.1021/ic101147x Supporting Info

Synthesis and Structure of Pillared Molybdates and Tungstates with Framework Layers Jennifer L. Nicholls, Sarah E. Hulse, Samantha K. Callear, Graham J. Tizzard, Richard A. Stephenson, Michael B. Hursthouse, William Clegg, Ross W. Harrington, and Andrew M. Fogg pp 8545–8551 DOI: 10.1021/ic101145p Supporting Info

Rationally Designed Fluorescence Turn-On Sensors: A New Design Strategy Based on Orbital Control Hyo Sung Jung, Kyoung Chul Ko, Jae Hong Lee, Sang Hoon Kim, Sankarprasad Bhuniya, Jin Yong Lee, Youngmee Kim, Sung Jin Kim, and Jong Seung Kim pp 8552–8557 DOI: 10.1021/ic101165k Supporting Info

Interaction of Cationic Nickel and Manganese Porphyrins with the Minor Groove of DNA Carmen Romera, Laurent Sabater, Antonio Garofalo, Isabelle M. Dixon, and Genevive Pratviel pp 8558–8567 DOI: 10.1021/ic101178n Supporting Info

Characterization of Uranyl(VI) Nitrate Complexes in a Room Temperature Ionic Liquid Using Attenuated Total Reflection-Fourier Transform Infrared Spectrometry Donna L. Quach, Chien M. Wai, and Sofie P. Pasilis pp 8568–8572 DOI: 10.1021/ic101197j Supporting Info

Geometric Control of Ground State Multiplicity in a Copper(I) Bis(verdazyl) Complex David J. R. Brook, Gordon T. Yee, Mike Hundley, David Rogow, Janice Wong, and Khanh Van-Tu pp 8573–8577 DOI: 10.1021/ic1011764 Supporting Info

Synthesis and Characterization of the Crystal Structure and Magnetic Properties of the Ternary Manganese Vanadate NaMnVO4 Hamdi Ben Yahia, Etienne Gaudin, Khalid Boulahya, Jacques Darriet, Won-Joon Son, and Myung-Hwan Whangbo pp 8578–8582 DOI: 10.1021/ic101180h Supporting Info

Mixed Azide and 5-(Pyrimidyl)tetrazole Bridged Co(II)/Mn(II) Polymers: Synthesis, Crystal Structures, Ferroelectric and Magnetic Behavior Oindrila Sengupta and Partha Sarathi Mukherjee pp 8583–8590 DOI: 10.1021/ic101213q Supporting Info

Asymmetrical [Ni(dmit)2]− Arrangements Induced by (1R,2R)-Cyclohexanediammonium - Crown Ether Supramolecules Qiong Ye, Tomoyuki Akutagawa, Toru Endo, Shin-ichiro Noro, Takayoshi Nakamura, and Ren-Gen Xiong pp 8591–8600 DOI: 10.1021/ic101253g Supporting Info

Dimerization of Dendrimeric Lanthanide Complexes: Thermodynamic, Thermal, and Liquid-Crystalline Properties Thomas Binderup Jensen, Emmanuel Terazzi, Kerry-Lee Buchwalder, Laure Gune, Homayoun Nozary, Kurt Schenk, Benot Heinrich, Bertrand Donnio, Daniel Guillon, and Claude Piguet pp 8601–8619 DOI: 10.1021/ic101220v Supporting Info

Nonheme Manganese-Catalyzed Asymmetric Oxidation. A Lewis Acid Activation versus Oxygen Rebound Mechanism: Evidence for the “Third Oxidant” Roman V. Ottenbacher, Konstantin P. Bryliakov, and Evgenii P. Talsi pp 8620–8628 DOI: 10.1021/ic101297x Supporting Info

Tricyclic Host for Linear Anions Sung Ok Kang, Victor W. Day, and Kristin Bowman-James pp 8629–8636 DOI: 10.1021/ic1013297 Supporting Info

Reductive Metalation of Cyclic and Acyclic Pseudopeptidic Bis-Disulfides and Back Conversion of the Resulting Diamidato/Dithiolato Complexes to Bis-Disulfides Nicolas Desbenot, Erwan Galardon, Yves Frapart, Alain Tomas, and Isabelle Artaud pp 8637–8644 DOI: 10.1021/ic101148c Supporting Info

Corrections to Theoretical Study of Dioxygen Induced Inhibition of [FeFe]-Hydrogenase Martin T. Stiebritz and Markus Reiher p 8645 DOI: 10.1021/ic1015737

Issue 19

Novel Functionalized Metal−Organic Framework Based on Unique Hexagonal Prismatic Clusters Qi Yue, Li Yan, Jian-Yong Zhang, and En-Qing Gao pp 8647–8649 DOI: 10.1021/ic100558x Supporting Info

Supramolecular Isomerism in Honeycomb Metal−Organic Frameworks Driven by CH···π Interactions: Homochiral Crystallization from an Achiral Ligand through Chiral Inducement Xiaoliang Zhao, Haiyan He, Fangna Dai, Daofeng Sun, and Yanxiong Ke pp 8650–8652 DOI: 10.1021/ic100603g Supporting Info

Construction of Hexagonal Prisms of Variable Size via Coordination-Driven Multicomponent Self-Assembly Zhigang Zhao, Yao-Rong Zheng, Ming Wang, J. Bryant Pollock, and Peter J. Stang pp 8653–8655 DOI: 10.1021/ic1014219 Supporting Info

Synthesis and Stabilization of a Monomeric Iron(II) Hydroxo Complex via Intramolecular Hydrogen Bonding in the Secondary Coordination Sphere Alexander J. Kendall, Lev N. Zakharov, and John D. Gilbertson pp 8656–8658 DOI: 10.1021/ic101408e Supporting Info

Carboxylic Acid Appended Dipyrrin for the Formation of a Hexanuclear Iridium/Copper Paddlewheel Complex Catherine Bronner, Stphane A. Baudron, and Mir Wais Hosseini pp 8659–8661 DOI: 10.1021/ic101458r Supporting Info

The Population of SAP and TSAP Isomers in Cyclen-Based Lanthanide(III) Chelates Is Substantially Affected by Solvent Kyle J. Miller, Ali A. Saherwala, Benjamin C. Webber, Yunkou Wu, A. Dean Sherry, and Mark Woods pp 8662–8664 DOI: 10.1021/ic101489t Supporting Info

Osmium(III) Complexes with POP Pincer Ligands: Preparation from Commercially Available OsCl3·3H2O and Their X-ray Structures Gregorio Asensio, Ana B. Cuenca, Miguel A. Esteruelas, Mercedes Medio-Simn, Montserrat Olivn, and Marta Valencia pp 8665–8667 DOI: 10.1021/ic101498h Supporting Info

Capturing Hydrolysis Products in the Solid State: Effects of pH on Uranyl Squarates under Ambient Conditions Clare E. Rowland and Christopher L. Cahill pp 8668–8673 DOI: 10.1021/ic1000792 Supporting Info

Simple Shape-Controlled Synthesis of Carbon Hollow Structures Mingtao Zheng, Yingliang Liu, Shuai Zhao, Wenqi He, Yong Xiao, and Dingsheng Yuan pp 8674–8683 DOI: 10.1021/ic9024316 Supporting Info

Raman Spectroscopic Investigation of Tetraethylammonium Polybromides Xiaoyun Chen, Mark A. Rickard, John W. Hull, Jr., Chao Zheng, Anne Leugers, and Petra Simoncic pp 8684–8689 DOI: 10.1021/ic100869r Supporting Info

Structural Characterization and Antimicrobial Activity of the Zn(II) Complex with P113 (Demegen), a Derivative of Histatin 5 Elena Porciatti, Marina Milenkovi, Elena Gaggelli, Gianni Valensin, Henryk Kozlowski, Wojciech Kamysz, and Daniela Valensin pp 8690–8698 DOI: 10.1021/ic902547t Supporting Info

Comparison of the Structure and Stability of New α-Diimine Complexes of Copper(I) and Silver(I): Density Functional Theory versus Experimental Vitor Rosa, Carla I. M. Santos, Richard Welter, Gabriel Aulln, Carlos Lodeiro, and Teresa Avils pp 8699–8708 DOI: 10.1021/ic100450y Supporting Info

Square Coordinated MnO2-Units in BiMn7O12 Hiroshi Okamoto, Naoki Imamura, Maarit Karppinen, Hisao Yamauchi, and Helmer Fjellvg pp 8709–8712 DOI: 10.1021/ic100499d

Diphenyl(1-naphthyl)phosphine Ancillary for Assembling of Red and Orange-Emitting Ir(III) Based Phosphors; Strategic Synthesis, Photophysics, and Organic Light-Emitting Diode Fabrication Bo-Sian Du, Chen-Huey Lin, Yun Chi, Jui-Yi Hung, Min-Wen Chung, Tsung-Yi Lin, Gene-Hsiang Lee, Ken-Tsung Wong, Pi-Tai Chou, Wen-Yi Hung, and Hao-Chih Chiu pp 8713–8723 DOI: 10.1021/ic100935b Supporting Info

Simultaneous Two-Hydrogen Transfer as a Mechanism for Efficient CO2 Reduction Paul M. Zimmerman, Zhiyong Zhang, and Charles B. Musgrave pp 8724–8728 DOI: 10.1021/ic100454z Supporting Info

High-Frequency Electron-Spin-Resonance Study of the Octanuclear Ferric Wheel CsFe8 Jan Dreiser, Oliver Waldmann, Graham Carver, Christopher Dobe, Hans-Ulrich Gdel, Høgni Weihe, and Anne-Laure Barra pp 8729–8735 DOI: 10.1021/ic100664g

Discrepancies in Thorium Oxide Solubility Values: Study of Attachment/Detachment Processes at the Solid/Solution Interface Johan Vandenborre, Bernd Grambow, and Abdessalam Abdelouas pp 8736–8748 DOI: 10.1021/ic100756f Supporting Info

Reactivity of Anhydrous Keggin-Type Heteropolyacids with Alkylsilanes: Synthesis and Characterization Eva Grinenval, Jean-Marie Basset, and Frdric Lefebvre pp 8749–8755 DOI: 10.1021/ic100777z Supporting Info

Room-Temperature Synthesis of Nickel Borides via Decomposition of NaBH4 Promoted by Nickel Bromide Riccarda Caputo, Fabrizio Guzzetta, and Alexander Angerhofer pp 8756–8762 DOI: 10.1021/ic100896a Supporting Info

Phase Transformation and Crystal Structure of La2Ni7Hx Studied by in situ X-ray Diffraction Kenji Iwase, Kouji Sakaki, Yumiko Nakamura, and Etsuo Akiba pp 8763–8768 DOI: 10.1021/ic100964j

Electron Paramagnetic Resonance Studies of Nitrosyl and Thionitrosyl and Density Functional Theory Studies of Nitrido, Nitrosyl, Thionitrosyl, and Selenonitrosyl Complexes of Chromium Johannes R. Dethlefsen, Anders Døssing, and Erik D. Hedegrd pp 8769–8778 DOI: 10.1021/ic1009797 Supporting Info

Synthesis, X-ray Structure, Magnetic Resonance, and DFT Analysis of a Soluble Copper(II) Phthalocyanine Lacking C−H Bonds Hans Moons, Łukasz Łapok, Andrei Loas, Sabine Van Doorslaer, and Sergiu M. Gorun pp 8779–8789 DOI: 10.1021/ic100814j Supporting Info

Dinuclear Copper(I) Complexes Containing Cyclodiphosphazane Derivatives and Pyridyl Ligands: Synthesis, Structural Studies, and Antiproliferative Activity toward Human Cervical and Breast Cancer Cells Maravanji S. Balakrishna, D. Suresh, Ankit Rai, Joel T. Mague, and Dulal Panda pp 8790–8801 DOI: 10.1021/ic100944d Supporting Info

Photophysical Properties and Electropolymerization of Gold Complexes of 3,3′′-Diethynyl-2,2′:5′,2′′-terthiophene Angela M. Kuchison, Michael O. Wolf, and Brian O. Patrick pp 8802–8812 DOI: 10.1021/ic100961w Supporting Info

An Aminolytic Approach toward Hierarchical β-Ni(OH)2 Nanoporous Architectures: A Bimodal Forum for Photocatalytic and Surface-Enhanced Raman Scattering Activity Sougata Sarkar, Mukul Pradhan, Arun Kumar Sinha, Mrinmoyee Basu, Yuichi Negishi, and Tarasankar Pal pp 8813–8827 DOI: 10.1021/ic1015065 Supporting Info

New [2 × 2] Copper(I) Grids as Anion Receptors. Effect of Ligand Functionalization on the Ability to Host Counteranions by Hydrogen Bonds M. Isabel Ortiz, M. Laura Soriano, M. Pilar Carranza, Flix A. Jaln, Jonathan W. Steed, Kurt Mereiter, Ana M. Rodrguez, David Quionero, Pere M. Dey, and Blanca R. Manzano pp 8828–8847 DOI: 10.1021/ic1009913 Supporting Info

Para-Derivatized Pybox Ligands As Sensitizers in Highly Luminescent Ln(III) Complexes Ana de Bettencourt-Dias, Patrick S. Barber, Subha Viswanathan, Daniel T. de Lill, Alexandra Rollett, George Ling, and Sultan Altun pp 8848–8861 DOI: 10.1021/ic101034y Supporting Info

Theoretical Investigation on the Photophysical Properties of Model Ruthenium Complexes with Diazabutadiene Ligands [Ru(bpy)3−x(dab)x]2+ (x = 1−3) Thomas Guillon, Martial Boggio-Pasqua, Fabienne Alary, Jean-Louis Heully, Emilie Lebon, Pierre Sutra, and Alain Igau pp 8862–8872 DOI: 10.1021/ic1009863 Supporting Info

Sulfur Donor Atom Effects on Copper(I)/O2 Chemistry with Thioanisole Containing Tetradentate N3S Ligand Leading to μ-1,2-Peroxo-Dicopper(II) Species Yunho Lee, Dong-Heon Lee, Ga Young Park, Heather R. Lucas, Amy A. Narducci Sarjeant, Matthew T. Kieber-Emmons, Michael A. Vance, Ashley E. Milligan, Edward I. Solomon, and Kenneth D. Karlin pp 8873–8885 DOI: 10.1021/ic101041m Supporting Info

Slow Magnetic Relaxation and Charge-Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN)7]3−/4− Joseph M. Zadrozny, Danna E. Freedman, David M. Jenkins, T. David Harris, Anthony T. Iavarone, Corine Mathonire, Rodolphe Clrac, and Jeffrey R. Long pp 8886–8896 DOI: 10.1021/ic101132z Supporting Info

Comparison of 2,2′-Bipyridine and 2,2′-Bipyridyl-N,N′-dioxide as Ligands in Zinc Complexes Lucie Duchkov, Vincent Steinmetz, Jol Lemaire, and Jana Roithov pp 8897–8903 DOI: 10.1021/ic101061p Supporting Info

Photoisomerizable Metallomesogens and Soft Crystals Based on Orthopalladated Complexes M. J. Baena, P. Espinet, C. L. Folcia, J. Ortega, and J. Etxebarra pp 8904–8913 DOI: 10.1021/ic1010665 Supporting Info

Replacement of an Oxo by an Imido Group in Oxotransferase Model Compounds: Influence on the Oxygen Atom Transfer Nadia C. Msch-Zanetti, Dietmar Wurm, Manuel Volpe, Ganna Lyashenko, Bastian Harum, Ferdinand Belaj, and Judith Baumgartner pp 8914–8921 DOI: 10.1021/ic101159g Supporting Info

Improvement in Phosphorescence Efficiency through Tuning of Coordination Geometry of Tridentate Cyclometalated Platinum(II) Complexes Deepak Ravindranathan, Dileep A. K. Vezzu, Libero Bartolotti, Paul D. Boyle, and Shouquan Huo pp 8922–8928 DOI: 10.1021/ic101109h Supporting Info

Three-Metal Coordination by Novel Bisporphyrin Architectures Jean-Michel Barbe, Benoit Habermeyer, Tony Khoury, Claude P. Gros, Philippe Richard, Ping Chen, and Karl M. Kadish pp 8929–8940 DOI: 10.1021/ic101170k Supporting Info

Group 6 Carbon Monoxide-Releasing Metal Complexes with Biologically-Compatible Leaving Groups Wei-Qiang Zhang, Adrian C. Whitwood, Ian J. S. Fairlamb, and Jason M. Lynam pp 8941–8952 DOI: 10.1021/ic101230j Supporting Info

cis-2,2′-Bipyrimidine-Bridged Polynuclear Complex: A Stairway-like Mixed-Valent {Fe4} Cluster Pablo Albors and Eva Rentschler pp 8953–8961 DOI: 10.1021/ic1013472 Supporting Info

Chemistry of the Oxophosphinidene Ligand. 1. Electronic Structure of the Anionic Complexes [MCp{P(O)R*}(CO)2]− (M = Mo, W; R* = 2,4,6-C6H2tBu3) and Their Reactions with H+ and C-Based Electrophiles. Mara Alonso, M. Angeles Alvarez, M. Esther Garca, Daniel Garca-Viv, and Miguel A. Ruiz pp 8962–8976 DOI: 10.1021/ic101261f Supporting Info

Theoretical Study of Excited States of Pyrazolate- and Pyridinethiolate-Bridged Dinuclear Platinum(II) Complexes: Relationship between Geometries of Excited States and Phosphorescence Spectra Ken Saito, Yoshihide Nakao, Keisuke Umakoshi, and Shigeyoshi Sakaki pp 8977–8985 DOI: 10.1021/ic101257b Supporting Info

Theoretical and Experimental Study of the Effectiveness of the 5-Pyrimidyl-tetrazolate Bridging Ligand in Mediating Magnetic Exchange Interactions Antonio J. Mota, A. Rodrguez-Diguez, M. A. Palacios, J. M. Herrera, Dominique Luneau, and Enrique Colacio pp 8986–8996 DOI: 10.1021/ic101322s Supporting Info

NMR Spectroscopic Evidence for the Intermediacy of XeF3− in XeF2/F− Exchange, Attempted Syntheses and Thermochemistry of XeF3− Salts, and Theoretical Studies of the XeF3− Anion Neil Vasdev, Matthew D. Moran, Heikki M. Tuononen, Raman Chirakal, Reijo J. Suontamo, Alex D. Bain, and Gary J. Schrobilgen pp 8997–9004 DOI: 10.1021/ic101275m Supporting Info

Novel Pathway to Synthesize Unsymmetrical 2,3,9,10,16,17,23-heptakis(alkoxyl)-24-mono(dimethylaminoalkoxyl)phthalocyanines Zhaopin Bai, Yingning Gao, Peihua Zhu, Yongzhong Bian, and Jianzhuang Jiang pp 9005–9011 DOI: 10.1021/ic101362y Supporting Info

Syntheses, Structures, and Magnetic Properties of Diphenoxo-Bridged CuIILnIII and NiII(Low-Spin)LnIII Compounds Derived from a Compartmental Ligand (Ln = Ce−Yb) Arpita Jana, Samit Majumder, Luca Carrella, Malabika Nayak, Thomas Weyhermueller, Supriya Dutta, Dieter Schollmeyer, Eva Rentschler, Rajesh Koner, and Sasankasekhar Mohanta pp 9012–9025 DOI: 10.1021/ic101445n Supporting Info

Tri- and Tetranuclear Nickel(II) Inverse Metallacrown Complexes Involving Oximato Oxygen Linkers: Role of the Guest Anion (Oxo versus Alkoxo) in Controlling the Size of the Ring Topology Anandalok Audhya, Manoranjan Maity, Kisholoy Bhattacharya, Rodolphe Clrac, and Muktimoy Chaudhury pp 9026–9035 DOI: 10.1021/ic101273y Supporting Info

Structural Diversity in Supramolecular Complexes of MCl3 (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands William Levason, Seema Maheshwari, Raju Ratnani, Gillian Reid, Michael Webster, and Wenjian Zhang pp 9036–9048 DOI: 10.1021/ic101296e Supporting Info

Arsenic-Containing Chalcophosphate Molecular Anions Collin D. Morris and Mercouri G. Kanatzidis pp 9049–9054 DOI: 10.1021/ic101461w Supporting Info

Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium Complex Supported by a Carbazole-Based Fluorinated β-Diketonate Ligand and a 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Oxide Co-Ligand D. B. Ambili Raj, Biju Francis, M. L. P. Reddy, Rachel R. Butorac, Vincent M. Lynch, and Alan H. Cowley pp 9055–9063 DOI: 10.1021/ic1015324 Supporting Info

Use of Metallopeptide Based Mimics Demonstrates That the Metalloprotein Nitrile Hydratase Requires Two Oxidized Cysteinates for Catalytic Activity Jason Shearer, Paige E. Callan, and Justina Amie pp 9064–9077 DOI: 10.1021/ic101765h Supporting Info

Second-Sphere Tethering of Rare-Earth Ions to Cucurbit[6]uril by Iminodiacetic Acid Involving Carboxylic Group Encapsulation Pierre Thury pp 9078–9085 DOI: 10.1021/ic101396a Supporting Info

Mixed-Valence Dinitrogen-Bridged Fe(0)/Fe(II) Complex Leslie D. Field, Ruth W. Guest, and Peter Turner pp 9086–9093 DOI: 10.1021/ic101646p Supporting Info

Issue 20

Observations on the Low-Energy Limits for Metal-to-Ligand Charge-Transfer Excited-State Energies of Ruthenium(II) Polypyridyl Complexes Onduru S. Odongo, Marco M. Allard, H. Bernhard Schlegel, and John F. Endicott pp 9095–9097 DOI: 10.1021/ic1008329 Supporting Info

(Ag2TeS3)2·A2S6 (A = Rb, Cs): Layers of Silver Thiotellurite Intergrown with Alkali-Metal Polysulfides Sandy L. Nguyen, Joon I. Jang, John B. Ketterson, and Mercouri G. Kanatzidis pp 9098–9100 DOI: 10.1021/ic1011346 Supporting Info

Self-Assembled Molecular Wires from Organoiron Metalloligands and Ruthenium Tetramesitylporphyrin Floriane Malvolti, Paul Le Maux, Loic Toupet, Mark E. Smith, Wing Y. Man, Paul J. Low, Erwan Galardon, Grard Simonneaux, and Frdric Paul pp 9101–9103 DOI: 10.1021/ic1012445 Supporting Info

A Mixed 3d−4f 14-Metallacrown-5 Complex That Displays Slow Magnetic Relaxation through Geometric Control of Magnetoanisotropy Thaddeus T. Boron, III, Jeff W. Kampf, and Vincent L. Pecoraro pp 9104–9106 DOI: 10.1021/ic101121d Supporting Info

Three-Dimensional Metal−Organic Frameworks Based on Tetrahedral and Square-Planar Building Blocks: Hydrogen Sorption and Dye Uptake Studies Demin Liu, Zhigang Xie, Liqing Ma, and Wenbin Lin pp 9107–9109 DOI: 10.1021/ic1009169 Supporting Info

Antimony Tin Oxide (ATO) Nanoparticle Formation from H2O2 Solutions: a New Generic Film Coating from Basic Solutions Sergey Sladkevich, Alexey A. Mikhaylov, Petr V. Prikhodchenko, Tatiana A. Tripol’skaya, and Ovadia Lev pp 9110–9112 DOI: 10.1021/ic1015862 Supporting Info

Ratiometric and Intensity-Based Zinc Sensors Built on Rhodol and Rhodamine Platforms Elisa Tomat and Stephen J. Lippard pp 9113–9115 DOI: 10.1021/ic101513a Supporting Info

Magnetic/Conducting Bifunctionality due to π/σ-Conjugated Functional Moieties in a Stacked Ferrimagnetic Chain Hitoshi Miyasaka, Yuichiro Asai, Natsuko Motokawa, Kazuya Kubo, and Masahiro Yamashita pp 9116–9118 DOI: 10.1021/ic101564x Supporting Info

An Alternate Route to Disulfanido Complexes by Nucleophilic Attack of Thiolates on Ruthenium-Bound Thiosulfonato Ligands Erwan Galardon, Patrick Deschamps, Alain Tomas, Pascal Roussel, and Isabelle Artaud pp 9119–9121 DOI: 10.1021/ic101795s Supporting Info

Complete Enantioseparation through Supramolecular Complex Formation between Tris(1,3-diaminopropane)cobalt(III) Phosphate and β-Cyclodextrin, [Co(tn)3]PO4·β-CDX Natsuki Ohta, Akira Fuyuhiro, and Kazuaki Yamanari pp 9122–9124 DOI: 10.1021/ic101858y Supporting Info

Face-Sharing Heterotrinuclear MII−LnIII−MII (M = Mn, Fe, Co, Zn; Ln = La, Gd, Tb, Dy) Complexes: Synthesis, Structures, and Magnetic Properties Tomoka Yamaguchi, Jean-Pierre Costes, Yukana Kishima, Masaaki Kojima, Yukinari Sunatsuki, Nicolas Brfuel, Jean-Pierre Tuchagues, Laure Vendier, and Wolfgang Wernsdorfer pp 9125–9135 DOI: 10.1021/ic100460w Supporting Info

Nickel(II) and Palladium(II) Complexes of Azobenzene-Containing Ligands as Dichroic Dyes Octavia A. Blackburn, Benjamin J. Coe, John Fielden, Madeleine Helliwell, Joseph J. W. McDouall, and Michael G. Hutchings pp 9136–9150 DOI: 10.1021/ic1000842 Supporting Info

Photophysical Properties of the Series fac- and mer-(1-Phenylisoquinolinato-NC2′)x(2-phenylpyridinato-NC2′)3−xIridium(III) (x = 1−3) Joseph C. Deaton, Ralph H. Young, Jerome R. Lenhard, Manju Rajeswaran, and Shouquan Huo pp 9151–9161 DOI: 10.1021/ic1002594 Supporting Info

Calculation of Dramatic Differences in the Activation Energy of Phenyl Migratory Insertion in the Isomers of [Rh(PMe3)2Cl(CO)(Ph)H]: Important Effects from Both the Ligand trans to Ph and the Ligand trans to CO Faraj Hasanayn and Dina Abu-El-Ez pp 9162–9168 DOI: 10.1021/ic100198u Supporting Info

Highly Fluorescent Platinum(II) Organometallic Complexes of Perylene and Perylene Monoimide, with Pt σ-Bonded Directly to the Perylene Core Sergio Lentijo, Jess A. Miguel, and Pablo Espinet pp 9169–9177 DOI: 10.1021/ic1003319 Supporting Info

X-ray Absorption Spectroscopy and Reactivity of Thiolate-Ligated FeIII−OOR Complexes Jay Stasser, Frances Namuswe, Gary D. Kasper, Yunbo Jiang, Courtney M. Krest, Michael T. Green, James Penner-Hahn, and David P. Goldberg pp 9178–9190 DOI: 10.1021/ic100670k Supporting Info

Synthesis, Crystal Structure, and Photoluminescent Properties of Ternary Cd(II)/Triazolate/Chloride System Gang Wei, Yu-Feng Shen, Yong-Ru Li, and Xiao-Chun Huang pp 9191–9199 DOI: 10.1021/ic100610t Supporting Info

Probing the Antioxidant Action of Selenium and Sulfur Using Cu(I)-Chalcogenone Tris(pyrazolyl)methane and -borate Complexes Martin M. Kimani, Julia L. Brumaghim, and Don VanDerveer pp 9200–9211 DOI: 10.1021/ic100668b Supporting Info

BaGa4Se7: A New Congruent-Melting IR Nonlinear Optical Material Jiyong Yao, Dajiang Mei, Lei Bai, Zheshuai Lin, Wenlong Yin, Peizhen Fu, and Yicheng Wu pp 9212–9216 DOI: 10.1021/ic1006742 Supporting Info

Chemoselectivity Diversity in the Reaction of LiNC6F5SiMe3 with Nitriles and the Synthesis, Structure, and Reactivity of Zirconium Mono- and Tris[2-(2-pyridyl)tetrafluorobenzimidazolate] Complexes Sinai Aharonovich, Mark Botoshansky, Robert M. Waymouth, and Moris S. Eisen pp 9217–9229 DOI: 10.1021/ic100696r Supporting Info

U and P4 Reaction Products: A Quantum Chemical and Matrix Isolation Spectroscopic Investigation Bess Vlaisavljevich and Laura Gagliardi, Xuefeng Wang, Binyong Liang, and Lester Andrews, Ivan Infante pp 9230–9235 DOI: 10.1021/ic100407e Supporting Info

The Absolute Configuration of Palladium(II) and Ruthenium(II) Pseudochiral Centers in either Chiral or Achiral Environments Santo Lanza, Francesco Nicol, Grazia Cafeo, Hadi Amiri Rudbari, and Giuseppe Bruno pp 9236–9246 DOI: 10.1021/ic100715v Supporting Info

Dynamic Changes in Dimensional Structures of Co-Complex Crystals Atsushi Kondo, Tomohiro Nakagawa, Hiroshi Kajiro, Ayako Chinen, Yoshiyuki Hattori, Fujio Okino, Tomonori Ohba, Katsumi Kaneko, and Hirofumi Kanoh pp 9247–9252 DOI: 10.1021/ic100753g Supporting Info

Finite Magnetization Plateau from a Two-Dimensional Antiferromagnet: Density Functional Analysis of the Magnetic Structure of Cu3(P2O6OH)2 Hyun-Joo Koo and Myung-Hwan Whangbo pp 9253–9256 DOI: 10.1021/ic100906s Supporting Info

Multifunctional Homochiral Lanthanide Camphorates with Mixed Achiral Terephthalate Ligands Ming-Ling Sun, Jian Zhang, Qi-Pu Lin, Pei-Xiu Yin, and Yuan-Gen Yao pp 9257–9264 DOI: 10.1021/ic1007445 Supporting Info

Electronic Influences on Metallophilic Interactions in [Pt(tpy)X][Au(C6F5)2] Double Salts Val Phillips, Kathryn J. Willard, James A. Golen, Curtis J. Moore, Arnold L. Rheingold, and Linda H. Doerrer pp 9265–9274 DOI: 10.1021/ic1008208 Supporting Info

Syntheses, Structures, and Magnetic Properties of Two Kinds of Unique Heterometallic Chains with Mixed-Bridging Ligands of Tricyanometalate and Alkoxide Ling-Chen Kang, Xin Chen, Hui-Sheng Wang, Yi-Zhi Li, You Song, Jing-Lin Zuo, and Xiao-Zeng You pp 9275–9282 DOI: 10.1021/ic100861n Supporting Info

Re(bipy-tBu)(CO)3Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies Jonathan M. Smieja and Clifford P. Kubiak pp 9283–9289 DOI: 10.1021/ic1008363 Supporting Info

The Triplet State of fac-Ir(ppy)3 Thomas Hofbeck and Hartmut Yersin pp 9290–9299 DOI: 10.1021/ic100872w

Highly Luminescent and Triboluminescent Coordination Polymers Assembled from Lanthanide β-Diketonates and Aromatic Bidentate O-Donor Ligands Svetlana V. Eliseeva, Dmitry N. Pleshkov, Konstantin A. Lyssenko, Leonid S. Lepnev, Jean-Claude G. Bnzli, and Natalia P. Kuzmina pp 9300–9311 DOI: 10.1021/ic100974e Supporting Info

Structure Change Associated with the [MII/III 1,4,7-Triazacyclononane-N,N′,N′′-triacetate (TCTA)]−/0 Electron Transfers (M = Mn, Fe, and Ni): Crystal Structure for [FeII(H2O)6][FeII(TCTA)]2 Thomas L. Hatfield, Richard J. Staples, and David T. Pierce pp 9312–9320 DOI: 10.1021/ic100933t Supporting Info

Binding and Removal of Sulfate, Phosphate, Arsenate, Tetrachloromercurate, and Chromate in Aqueous Solution by Means of an Activated Carbon Functionalized with a Pyrimidine-Based Anion Receptor (HL). Crystal Structures of [H3L(HgCl4)]·H2O and [H3L(HgBr4)]·H2O Showing Anion−π Interactions Paloma Arranz, Antonio Bianchi, Rafael Cuesta, Claudia Giorgi, M. Luz Godino, M. D. Gutirrez, Rafael Lpez, and Antonio Santiago pp 9321–9332 DOI: 10.1021/ic100929f Supporting Info

Tunable Phosphorescent NIR Oxygen Indicators Based on Mixed Benzo- and Naphthoporphyrin Complexes Fabian Niedermair, Sergey M. Borisov, Gunter Zenkl, Oliver T. Hofmann, Hansjrg Weber, Robert Saf, and Ingo Klimant pp 9333–9342 DOI: 10.1021/ic100955z Supporting Info

Synthesis, Crystal Structure, Atomic Hirshfeld Surfaces, and Physical Properties of Hexagonal CeMnNi4 Iben Skovsen, Mogens Christensen, Henrik Fanø Clausen, Jacob Overgaard, Christian Stiewe, Titas Desgupta, Eckhard Mueller, Mark A. Spackman, and Bo B. Iversen pp 9343–9349 DOI: 10.1021/ic100990a Supporting Info

Optimized Synthesis of Tetrafluoroterephthalic Acid: A Versatile Linking Ligand for the Construction of New Coordination Polymers and Metal-Organic Frameworks Andreas Orthaber, Christiane Seidel, Ferdinand Belaj, Jrg H. Albering, Rudolf Pietschnig, and Uwe Ruschewitz pp 9350–9357 DOI: 10.1021/ic1009829 Supporting Info

Cyanocarbanion-Based Spin-Crossover Materials: Photocrystallographic and Photomagnetic Studies of a New Iron(II) Neutral Chain Gaelle Dupouy, Smail Triki, Mathieu Marchivie, Nathalie Cosquer, Carlos J. Gmez-Garca, Sbastien Pillet, El-Eulmi Bendeif, Claude Lecomte, Saket Asthana, and Jean-Franois Ltard pp 9358–9368 DOI: 10.1021/ic101038z Supporting Info

Synthesis and Reactivity of (Benzoxazol-2-ylmethyl)phosphonic Acid Sylvie Pailloux, Cornel Edicome Shirima, Karen Ann Smith, Eileen N. Duesler, Robert T. Paine, Neil J. Williams, and Robert D. Hancock pp 9369–9379 DOI: 10.1021/ic101079b Supporting Info

Iron(II) and Ruthenium(II) Complexes Containing P, N, and H Ligands: Structure, Spectroscopy, Electrochemistry, and Reactivity Jinzhu Chen, David J. Szalda, Etsuko Fujita, and Carol Creutz pp 9380–9391 DOI: 10.1021/ic101077t Supporting Info

Mechanistic Insight into the Alcohol Oxidation Mediated by an Efficient Green [CuBr2(2,2′-bipy)]-TEMPO Catalyst by Density Functional Method Lin Cheng, Jinping Wang, Meiyan Wang, and Zhijian Wu pp 9392–9399 DOI: 10.1021/ic100996b Supporting Info

“Hexagonal Molybdenum Trioxide”—Known for 100 Years and Still a Fount of New Discoveries Hans-Joachim Lunk, Hans Hartl, Monika A. Hartl, Martin J. G. Fait, Ilya G. Shenderovich, Michael Feist, Timothy A. Frisk, Luke L. Daemen, Daniel Mauder, Reinhard Eckelt, and Andrey A. Gurinov pp 9400–9408 DOI: 10.1021/ic101103g Supporting Info

High Yield Precipitation of Crystalline α-Zirconium Phosphate from Oxalic Acid Solutions Donatella Capitani, Mario Casciola, Anna Donnadio, and Riccardo Vivani pp 9409–9415 DOI: 10.1021/ic101200f

Synthesis and Structural Studies of Lithium and Sodium Complexes with OOO-Tridentate Bis(phenolate) Ligands: Effective Catalysts for the Ring-Opening Polymerization of l-Lactide Yong Huang, Yueh-Hsuan Tsai, Wen-Chou Hung, Chieh-Shen Lin, Wei Wang, Jui-Hsien Huang, Saikat Dutta, and Chu-Chieh Lin pp 9416–9425 DOI: 10.1021/ic1011154 Supporting Info

{Mo96La8} Eggshell Ring and Self-Assembly to {Mo132} Keplerate through Mo-blue Intermediate, Involved in UV-Photolysis of [Mo7O24]6−/Carboxylic Acid System at pH 4 Toshihiro Yamase, Shun Kumagai, Petra V. Prokop, Eri Ishikawa, and Adrian-Raul Tomsa pp 9426–9437 DOI: 10.1021/ic101027d Supporting Info

New Insights into the Factors That Govern the Square/Triangle Equilibria of Pd(II) and Pt(II) Supramolecules. Unexpected Participation of a Mononuclear Species in the Equilibrium Montserrat Ferrer, Albert Pedrosa, Laura Rodrguez, Oriol Rossell, and Marta Vilaseca pp 9438–9449 DOI: 10.1021/ic101150p Supporting Info

Spectroscopic and Computational Studies of an End-on Bound Superoxo-Cu(II) Complex: Geometric and Electronic Factors That Determine the Ground State Julia S. Woertink, Li Tian, Debabrata Maiti, Heather R. Lucas, Richard A. Himes, Kenneth D. Karlin, Frank Neese, Christian Wrtele, Max C. Holthausen, Eckhard Bill, Jrg Sundermeyer, Siegfried Schindler, and Edward I. Solomon pp 9450–9459 DOI: 10.1021/ic101138u Supporting Info

cis-Dioxo- and cis-(Hydroxo)oxo-Mo(V) Complexes Stabilized by Intramolecular Hydrogen-Bonding Victor W. L. Ng, Michelle K. Taylor, Jonathan M. White, and Charles G. Young pp 9460–9469 DOI: 10.1021/ic1011428 Supporting Info

Brillouin Spectroscopy, Calculated Elastic and Bond Properties of GaAsO4 Gopalkrishna M. Bhalerao, Olivier Cambon, and Julien Haines, Claire Levelut, Alain Mermet and Sergey Sirotkin, Bertrand Mnaert and Jrme Debray, Isabelle Baraille, Clovis Darrigan, and Michel Rrat pp 9470–9478 DOI: 10.1021/ic1011499

Iron Catalyzed Competitive Olefin Oxidation and ipso-Hydroxylation of Benzoic Acids: Further Evidence for an FeV═O Oxidant Parthapratim Das and Lawrence Que, Jr. pp 9479–9485 DOI: 10.1021/ic101144s

Ag(I) Organometallic Coordination Polymers and Capsule with Tris-Allyl Cyclotriveratrylene Derivatives Marc A. Little, Malcolm A. Halcrow, Lindsay P. Harding, and Michaele J. Hardie pp 9486–9496 DOI: 10.1021/ic101211n Supporting Info

Unusual Electronic Effects Imparted by Bridging Dinitrogen: an Experimental and Theoretical Investigation Wesley A. Hoffert, Anthony K. Rapp, and Matthew P. Shores pp 9497–9507 DOI: 10.1021/ic101528d Supporting Info

Slicing the Perovskite Structure with Crystallographic Shear Planes: The AnBnO3n−2 Homologous Series Artem M. Abakumov, Joke Hadermann, Maria Batuk, Hans D’Hondt, Oleg A. Tyablikov, Marina G. Rozova, Konstantin V. Pokholok, Dmitry S. Filimonov, Denis V. Sheptyakov, Alexander A. Tsirlin, Daniel Niermann, Joachim Hemberger, Gustaaf Van Tendeloo, and Evgeny V. Antipov pp 9508–9516 DOI: 10.1021/ic101233s Supporting Info

Magneto-Structural Correlation Studies and Theoretical Calculations of a Unique Family of Single End-to-End Azide-Bridged NiII4 Cyclic Clusters Sujit Sasmal, Susanta Hazra, Parimal Kundu, Samit Majumder, Nria Aliaga-Alcalde, Eliseo Ruiz, and Sasankasekhar Mohanta pp 9517–9526 DOI: 10.1021/ic101209m Supporting Info

Organometallic Complexes with Terminal Imidazolato Ligands and Their Use as Metalloligands Eva Gmez, Miguel A. Huertos, Julio Prez, Luca Riera, and Amador Menndez-Velzquez pp 9527–9534 DOI: 10.1021/ic1012395 Supporting Info

Cell-Trappable Quinoline-Derivatized Fluoresceins for Selective and Reversible Biological Zn(II) Detection Lindsey E. McQuade and Stephen J. Lippard pp 9535–9545 DOI: 10.1021/ic1012507 Supporting Info

Turn-Off-and-On: Chemosensing Ensembles for Sensing Chloride in Water by Fluorescence Spectroscopy Thomas Riis-Johannessen, Kurt Schenk, and Kay Severin pp 9546–9553 DOI: 10.1021/ic1012878 Supporting Info

The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine Claude Berthon, Nathalie Boubals, Iraida A. Charushnikova, David Collison, Stphanie M. Cornet, Christophe Den Auwer, Andrew J. Gaunt, Nikolas Kaltsoyannis, Iain May, Sebastien Petit, Michael P. Redmond, Sean D. Reilly, and Brian L. Scott pp 9554–9562 DOI: 10.1021/ic101251a Supporting Info

Determination of the Photolysis Products of [FeFe]Hydrogenase Enzyme Model Systems using Ultrafast Multidimensional Infrared Spectroscopy Andrew I. Stewart, Joseph A. Wright, Gregory M. Greetham, Spiridon Kaziannis, Stefano Santabarbara, Michael Towrie, Anthony W. Parker, Christopher J. Pickett, and Neil T. Hunt pp 9563–9573 DOI: 10.1021/ic101289s

Indium Flux-Growth of Eu2AuGe3: A New Germanide with an AlB2 Superstructure C. Peter Sebastian, Christos D. Malliakas, Maria Chondroudi, Inga Schellenberg, Sudhindra Rayaprol, Rolf-Dieter Hoffmann, Rainer Pttgen, and Mercouri G. Kanatzidis pp 9574–9580 DOI: 10.1021/ic101340a Supporting Info

Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates Chuan-Fu Sun, Chun-Li Hu, Xiang Xu, and Jiang-Gao Mao pp 9581–9589 DOI: 10.1021/ic101370v Supporting Info

Facile Determination of the Spectra of Unstable Electrode Products Using Simultaneous Fiber-Optic Chronoabsorptometry and Chronoamperometry Michael J. Shaw, Daniel L. Cranford, Kenneth W. Rodgers, James E. Eilers, Bradley Noble, Adam J. Warhausen, and George B. Richter-Addo pp 9590–9598 DOI: 10.1021/ic1012654 Supporting Info

Mechanism for the Formation of Substituted Manganese(V) Cyanidonitrido Complexes: Crystallographic and Kinetic Study of the Substitution Reactions of trans-[MnN(H2O)(CN)4]2− with Monodentate Pyridine and Bidentate Pyridine−Carboxylate Ligands Hendrik J. van der Westhuizen, Reinout Meijboom, Marietjie Schutte, and Andreas Roodt pp 9599–9608 DOI: 10.1021/ic101274q Supporting Info

The Use of Polarizable [AuX2(CN)2]− (X = Br, I) Building Blocks Toward the Formation of Birefringent Coordination Polymers Jeffrey S. Ovens, Andrew R. Geisheimer, Alexei A. Bokov, Zuo-Guang Ye, and Daniel B. Leznoff pp 9609–9616 DOI: 10.1021/ic101357y Supporting Info

From Infinite One-Dimensional Helix to Discrete CuII15 Cluster along with in Situ SN2 Ring-Cleavage of cis-Epoxysuccinic Acid: pH-Controlled Assemblies, Crystal Structures, and Properties Shao-Ming Fang, Qiang Zhang, Min Hu, E. Carolina Saudo, Miao Du, and Chun-Sen Liu pp 9617–9626 DOI: 10.1021/ic101278w Supporting Info

6-(3,5-Dimethyl-1H-pyrazol-1-yl)-2,2′-bipyridine as Ligand for Actinide(III)/Lanthanide(III) Separation Denise Girnt, Peter W. Roesky, Andreas Geist, Christian M. Ruff, Petra J. Panak, and Melissa A. Denecke pp 9627–9635 DOI: 10.1021/ic101309j Supporting Info

Mechanistic Studies of the Reaction of Ir(III) Porphyrin Hydride with 2,2,6,6-Tetramethylpiperidine-1-oxyl to an Unsupported Ir−Ir Porphyrin Dimer Siu Yin Lee, Chi Wai Cheung, I-Jui Hsu, and Kin Shing Chan pp 9636–9640 DOI: 10.1021/ic1013544

Magnetic Properties of Largest-Spin Single Molecule Magnets: Mn17 Complexes—A Density Functional Theory Approach Eduard Cremades and Eliseo Ruiz pp 9641–9648 DOI: 10.1021/ic1014253

The Topotactic Reduction of Sr3Fe2O5Cl2—Square Planar Fe(II) in an Extended Oxyhalide Edward Dixon and Michael A. Hayward pp 9649–9654 DOI: 10.1021/ic101371z Supporting Info

Copper Curcuminoids Containing Anthracene Groups: Fluorescent Molecules with Cytotoxic Activity Nria Aliaga-Alcalde, Patricia Marqus-Gallego, Mirte Kraaijkamp, Coral Herranz-Lancho, Hans den Dulk, Helmut Grner, Olivier Roubeau, Simon J. Teat, Thomas Weyhermller, and Jan Reedijk pp 9655–9663 DOI: 10.1021/ic101331c Supporting Info

Synthesis and Crystal Structure from X-ray Powder Diffraction Data of Two Zirconium Diphosphonates Containing Piperazine Groups Marco Taddei, Ferdinando Costantino, and Riccardo Vivani pp 9664–9670 DOI: 10.1021/ic1014048 Supporting Info

Two Novel Thioindate-Thioantimonate Compounds [Ni(dien)2]2In2Sb4S11 and [Ni(dien)2]3(In3Sb2S9)2·2H2O with Transition Metal Complexes Jian Zhou, Xian-Hong Yin, and Feng Zhang pp 9671–9676 DOI: 10.1021/ic101382u Supporting Info

Chemistry of the Phosphorus−Nitrogen Ligands. Multiple Isomeric Transformations of the Diphosphinohydrazine Bearing 8-Quinolyl Substituent: P→C, P→N, and P→P Migrations Caused by Different Factors Alexander N. Kornev, Natalia V. Belina, Vyacheslav V. Sushev, Julia S. Panova, Olga V. Lukoyanova, Sergey Y. Ketkov, Georgy K. Fukin, Mikhail A. Lopatin, and Gleb A. Abakumov pp 9677–9682 DOI: 10.1021/ic101410u Supporting Info

Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2 Dong Zhang, Helmuth Berger, Reinhard K. Kremer, Dirk Wulferding, Peter Lemmens, and Mats Johnsson pp 9683–9688 DOI: 10.1021/ic101431g Supporting Info

One Pot Synthesis of Disilatricycloheptene Analogue and Jutzi’s Disilene Shabana Khan, Sakya S. Sen, Herbert W. Roesky, Daniel Kratzert, Reent Michel, and Dietmar Stalke pp 9689–9693 DOI: 10.1021/ic101552r Supporting Info

Synthesis and Characterization of Carbonyl Diazide, OC(N3)2 Xiaoqing Zeng, Michael Gerken, Helmut Beckers, and Helge Willner pp 9694–9699 DOI: 10.1021/ic1015143 Supporting Info

Magnetic Properties of Segregated Layers Containing MII3(μ3−OH)2 (M = Co or Ni) Diamond Chains Bridged by cis,cis,cis-1,2,4,5-Cyclohexanetetracarboxylate Mohamedally Kurmoo, Kazuya Otsubo and Hiroshi Kitagawa, Marc Henry, Masaaki Ohba, Seishi Takagi pp 9700–9708 DOI: 10.1021/ic101521k Supporting Info

Low-Coordinate Germylene and Stannylene Heterocycles featuring Sterically Tunable Bis(amido)silyl Ligands S. M. Ibrahim Al-Rafia, Paul A. Lummis, Michael J. Ferguson, Robert McDonald, and Eric Rivard pp 9709–9717 DOI: 10.1021/ic101485a Supporting Info

Electrochemistry of 1,1′-Bis(2,4-dialkylphosphetanyl)ferrocene and 1,1′-Bis(2,5-dialkylphospholanyl)ferrocene Ligands: Free Phosphines, Metal Complexes, and Chalcogenides Chelsea L. Mandell, Shannon S. Kleinbach, William G. Dougherty, W. Scott Kassel, and Chip Nataro pp 9718–9727 DOI: 10.1021/ic1016164 Supporting Info

Correction to Synthesis and Characterization of Luminescent Rhenium(I) Tricarbonyl Diimine Complexes with a Triarylboron Moiety and the Study of Their Fluoride Ion-Binding Properties Siu-Tung Lam, Nianyong Zhu, and Vivian Wing-Wah Yam p 9728 DOI: 10.1021/ic101850t

Correction to Investigation of the Effect of Oxy Bridging Groups in Dinuclear Zn(II) Complexes that Catalyze the Cleavage of a Simple Phosphate Diester RNA Analogue Mark F. Mohamed, Alexei A. Neverov, and R. Stan Brown p 9729 DOI: 10.1021/ic101857n

Issue 21

Transition Metal Complexes as Linkages for Assembly of Supertetrahedral T4 Clusters Yu-Hong Wang, Ming-Hui Zhang, Yun-Meng Yan, Guo-Qing Bian, Qin-Yu Zhu, and Jie Dai pp 9731–9733 DOI: 10.1021/ic100088n Supporting Info

Single-Molecule-Magnet Behavior in a Fe12Sm4 Cluster Yong-Fei Zeng, Guan-Cheng Xu, Xin Hu, Zhuo Chen, Xian-He Bu, Song Gao, and E. C. Saudo pp 9734–9736 DOI: 10.1021/ic1009708 Supporting Info

Nickel/Lanthanide Single-Molecule Magnets: {Ni3Ln} “Stars” with a Ligand Derived from the Metal-Promoted Reduction of Di-2-pyridyl Ketone under Solvothermal Conditions Constantinos G. Efthymiou, Theocharis C. Stamatatos, Constantina Papatriantafyllopoulou, Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Spyros P. Perlepes, and George Christou pp 9737–9739 DOI: 10.1021/ic101504c Supporting Info

A New Oxomolybdate Component Extracted from the “Virtual Dynamic Library” Yielding the Macrocyclic Anion [(MoVI8O28)4(MoV2O2S2)4]24− Vladimir S. Korenev, Antoine G. Boulay, Anne Dolbecq, Maxim N. Sokolov, Akram Hijazi, Sbastien Floquet, Vladimir P. Fedin, and Emmanuel Cadot pp 9740–9742 DOI: 10.1021/ic101545w Supporting Info

A High-Nuclearity 3d/4f Metal Oxime Cluster: An Unusual Ni8Dy8 “Core−Shell” Complex from the Use of 2-Pyridinealdoxime Constantina Papatriantafyllopoulou, Theocharis C. Stamatatos, Constantinos G. Efthymiou, Luis Cunha-Silva, Filipe A. Almeida Paz, Spyros P. Perlepes, and George Christou pp 9743–9745 DOI: 10.1021/ic101581g Supporting Info

A Carbonyl-Rich Bridging Hydride Complex Relevant to the Fe−Fe Hydrogenase Active Site Steven L. Matthews and D. Michael Heinekey pp 9746–9748 DOI: 10.1021/ic1017328 Supporting Info

Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb3(AlQ2)3(GeQ2)7 (Q = S, Se) Alexander Rothenberger, Maryam Shafaei-Fallah, and Mercouri G. Kanatzidis pp 9749–9751 DOI: 10.1021/ic101627v Supporting Info

Anionic Tuning of the Dimensionality in Copper Oximato Chemistry Albert Escuer, Beatriz Cordero, Merc Font-Bardia, and Teresa Calvet pp 9752–9754 DOI: 10.1021/ic101636r Supporting Info

Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate Shuao Wang, Evgeny V. Alekseev, Hannah M. Miller, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 9755–9757 DOI: 10.1021/ic101678d Supporting Info

Synthesis and Catalytic Activity of Gold Chiral Nitrogen Acyclic Carbenes and Gold Hydrogen Bonded Heterocyclic Carbenes in Cyclopropanation of Vinyl Arenes and in Intramolecular Hydroalkoxylation of Allenes Camino Bartolom, Domingo Garca-Cuadrado, Zoraida Ramiro, and Pablo Espinet pp 9758–9764 DOI: 10.1021/ic101059c Supporting Info

PKU-10: A New 3D Open-Framework Germanate with 13-Ring Channels Jie Su, Yingxia Wang, Zheming Wang, Fuhui Liao, and Jianhua Lin pp 9765–9769 DOI: 10.1021/ic100195r Supporting Info

9Mg(OH)2·MgCl2·4H2O, a High Temperature Phase of the Magnesia Binder System Robert E. Dinnebier, Daniela Freyer, Sebastian Bette, and Melanie Oestreich pp 9770–9776 DOI: 10.1021/ic1004566 Supporting Info

Structural Distortions upon Oxidation in Heteroleptic [Cp2W(dmit)] Tungsten Dithiolene Complex: Combined Structural, Spectroscopic, and Magnetic Studies Eric W. Reinheimer, Iwona Olejniczak, Andrzej Łapiski, Roman wietlik, Olivier Jeannin, and Marc Fourmigu pp 9777–9787 DOI: 10.1021/ic1006296 Supporting Info

Synthesis, Crystal Structure, Quantum Chemical Calculations, DNA Interactions, and Antimicrobial Activity of [Ag(2-amino-3-methylpyridine)2]NO3 and [Ag(pyridine-2-carboxaldoxime)NO3] Morsy A. M. Abu-Youssef, Saied M. Soliman, Vratislav Langer, Yousry M. Gohar, Ahmed A. Hasanen, Mohamed A. Makhyoun, Amira H. Zaky, and Lars R. hrstrm pp 9788–9797 DOI: 10.1021/ic100581k Supporting Info

Intramolecular NH···Pt Interactions of Platinum(II) Diimine Complexes with Phenyl Ligands Sayandev Chatterjee, Jeanette A. Krause, Allen G. Oliver, and William B. Connick pp 9798–9808 DOI: 10.1021/ic1007582 Supporting Info

Hydride Ion Transfer from Ruthenium(II) Complexes in Water: Kinetics and Mechanism Carol Creutz, Mei H. Chou, Hua Hou, and James T. Muckerman pp 9809–9822 DOI: 10.1021/ic101124q Supporting Info

Photoinduced Electron Transfer in Zn(II)porphyrin−Bridge−Pt(II)acetylide Complexes: Variation in Rate with Anchoring Group and Position of the Bridge Erik Gransson, Julien Boixel, Cyrille Monnereau, Errol Blart, Yann Pellegrin, Hans-Christian Becker, Leif Hammarstrm, and Fabrice Odobel pp 9823–9832 DOI: 10.1021/ic100605t Supporting Info

New Lanthanide Silicates Based on Anionic Silicate Chain, Layer, and Framework Prepared under High-Temperature and High-Pressure Conditions Xinguang Zhao, Jiyang Li, Peng Chen, Yi Li, Qingxin Chu, Xiaoyang Liu, Jihong Yu, and Ruren Xu pp 9833–9838 DOI: 10.1021/ic1006154 Supporting Info

Case Study on a Rare Effect: The Experimental and Theoretical Analysis of a Manganese(III) Spin-Crossover System Shi Wang, Marilena Ferbinteanu, Crina Marinescu, Alexandra Dobrinescu, Qi-Dan Ling, and Wei Huang pp 9839–9851 DOI: 10.1021/ic100364v Supporting Info

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization Christophe Volkringer, Thierry Loiseau, Nathalie Guillou, Grard Frey, Mohamed Haouas, Francis Taulelle, Erik Elkaim, and Norbert Stock pp 9852–9862 DOI: 10.1021/ic101128w Supporting Info

Light Insensitive Silver(I) Cyanoximates As Antimicrobial Agents for Indwelling Medical Devices Nikolay Gerasimchuk, Andrzej Gamian, Garrett Glover, and Bogumila Szponar pp 9863–9874 DOI: 10.1021/ic100830x Supporting Info

Computational Study of Alkynes Insertion into Metal-Hydride Bonds Catalyzed by Bimetallic Complexes Stefania Di Tommaso, Vincent Tognetti, Emilia Sicilia, Carlo Adamo, and Nino Russo pp 9875–9883 DOI: 10.1021/ic100850f Supporting Info

Nature of Transannular Intramolecular Interactions in Group 4 and 6 Metallatranes: A Combined Density Functional Theory and Atoms in Molecules Theory Study Ashwini K. Phukan and Ankur Kanti Guha pp 9884–9890 DOI: 10.1021/ic101542m Supporting Info

Iridium Metal Complexes Containing N-Heterocyclic Carbene Ligands for Blue-Light-Emitting Electrochemical Cells Cheng-Han Yang, Juan Beltran, Vincent Lemaur, Jrme Cornil, David Hartmann, Wiebke Sarfert, Roland Frhlich, Claudia Bizzarri, and Luisa De Cola pp 9891–9901 DOI: 10.1021/ic1009253 Supporting Info

One-Pot Conditional Self-Assembly of Multicopper Metallacycles Kom-Bei Shiu, Shih-An Liu, and Gene-Hsiang Lee pp 9902–9908 DOI: 10.1021/ic1008957 Supporting Info

Highly Non-Planar Dendritic Porphyrin for pH Sensing: Observation of Porphyrin Monocation Sujatha Thyagarajan, Thom Leiding, Sindra Peterson Årskld, Andrei V. Cheprakov, and Sergei A. Vinogradov pp 9909–9920 DOI: 10.1021/ic100968p Supporting Info

The X-Ray Crystal Structure of Glutathionylcobalamin Revealed Luciana Hannibal, Clyde A. Smith, and Donald W. Jacobsen pp 9921–9927 DOI: 10.1021/ic101173b Supporting Info

Eu(III) Complexes of Functionalized Octadentate 1-Hydroxypyridin-2-ones: Stability, Bioconjugation, and Luminescence Resonance Energy Transfer Studies Evan G. Moore, Jide Xu, Christoph J. Jocher, Todd M. Corneillie, and Kenneth N. Raymond pp 9928–9939 DOI: 10.1021/ic101133w Supporting Info

Efficient Fluorescent Sensors Based on 2,5-Diphenyl[1,3,4]oxadiazole: A Case of Specific Response to Zn(II) at Physiological pH Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi pp 9940–9948 DOI: 10.1021/ic101210d Supporting Info

Contrasts in Structural and Bonding Representations among Polar Intermetallic Compounds. Strongly Differentiated Hamilton Populations for Three Related Condensed Cluster Halides of the Rare-Earth Elements Shalabh Gupta, Gerd Meyer, and John D. Corbett pp 9949–9957 DOI: 10.1021/ic101216z Supporting Info

X-Ray-Induced Lysis of the Fe−CO Bond in Carbonmonoxy-Myoglobin Stefano Della Longa and Alessandro Arcovito pp 9958–9961 DOI: 10.1021/ic101186m

Thermodynamical and Structural Study of Protactinium(V) Oxalate Complexes in Solution Mickal Mendes, Sna Hamadi, Claire Le Naour, Jrme Roques, Aurlie Jeanson, Christophe Den Auwer, Philippe Moisy, Sylvain Topin, Jean Aupiais, Christoph Hennig, and Maria-Vita Di Giandomenico pp 9962–9971 DOI: 10.1021/ic101189w Supporting Info

Trifluoroselenoacetic acid, CF3C(O)SeH: Preparation and Properties Jovanny A. Gmez Castao, Rosana M. Romano, Helmut Beckers, Helge Willner, and Carlos O. Della Vdova pp 9972–9977 DOI: 10.1021/ic101254k Supporting Info

Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume H. Donald Brooke Jenkins, Leslie Glasser, and Joe Lee pp 9978–9984 DOI: 10.1021/ic101398g

Self-Assembled E2L3 Cryptands (E = P, As, Sb, Bi): Transmetalation, Homo- and Heterometallic Assemblies, and Conformational Isomerism Virginia M. Cangelosi, Timothy G. Carter, Justin L. Crossland, Lev N. Zakharov, and Darren W. Johnson pp 9985–9992 DOI: 10.1021/ic1012186 Supporting Info

Decorating Poly(alkyl aryl-ether) Dendrimers with Metallacarboranes Rosario Nez, Emilio Jos Jurez-Prez, Francesc Teixidor, Rosa Santillan, Norberto Farfn, Arturo Abreu, Rebeca Ypez, and Clara Vias pp 9993–10000 DOI: 10.1021/ic101306w Supporting Info

A Series of (6,6)-Connected Porous Lanthanide−Organic Framework Enantiomers with High Thermostability and Exposed Metal Sites: Scalable Syntheses, Structures, and Sorption Properties Hai-Long Jiang, Nobuko Tsumori, and Qiang Xu pp 10001–10006 DOI: 10.1021/ic101294s Supporting Info

Importance of Energy Level Matching for Bonding in Th3+-Am3+ Actinide Metallocene Amidinates, (C5Me5)2[iPrNC(Me)NiPr]An Justin R. Walensky, Richard L. Martin, Joseph W. Ziller, and William J. Evans pp 10007–10012 DOI: 10.1021/ic1013285 Supporting Info

Crystal Chemistry of the Noncentrosymmetric Eulytites: A3Bi(XO4)3 (X = V, A = Pb; X = P, A = Ca, Cd, Sr, Pb) Prangya Parimita Sahoo and T. N. Guru Row pp 10013–10021 DOI: 10.1021/ic101316u Supporting Info

Spin-Crossover and Liquid Crystal Properties in 2D Cyanide-Bridged FeII−MI/II Metalorganic Frameworks M. Seredyuk, A. B. Gaspar, V. Ksenofontov, Y. Galyametdinov, M. Verdaguer, F. Villain, and P. Gtlich pp 10022–10031 DOI: 10.1021/ic101304v Supporting Info

Preparation, Properties, and Crystal Structures of Organometallic Ionic Liquids Comprising 1-Ferrocenyl-3-alkylimidazolium-Based Salts of Bis(trifluoromethanesulfonyl)amide and Hexafluorophosphate Yuji Miura, Fumiko Shimizu, and Tomoyuki Mochida pp 10032–10040 DOI: 10.1021/ic1013363 Supporting Info

Structure and Ultrafast Dynamics of the Charge-Transfer Excited State and Redox Activity of the Ground State of Mono- and Binuclear Platinum(II) Diimine Catecholate and Bis-catecholate Complexes: A Transient Absorption, TRIR, DFT, and Electrochemical Study Jonathan Best, Igor V. Sazanovich, Harry Adams, Robert D. Bennett, E. Stephen Davies, Anthony J. H. M. Meijer, Michael Towrie, Sergei A. Tikhomirov, Oleg V. Bouganov, Michael D. Ward, and Julia A. Weinstein pp 10041–10056 DOI: 10.1021/ic101344t Supporting Info

Iron Complexes for the Catalytic Transfer Hydrogenation of Acetophenone: Steric and Electronic Effects Imposed by Alkyl Substituents at Phosphorus Paraskevi O. Lagaditis, Alan J. Lough, and Robert H. Morris pp 10057–10066 DOI: 10.1021/ic101366z Supporting Info

Autogenic Synthesis of Green- and Red-Emitting Single-Phase Pr2O2CO3 and PrO1.833 Luminescent Nanopowders Jose M. Calderon Moreno, Vilas G. Pol, Soong-Hyuck Suh, and Monica Popa pp 10067–10073 DOI: 10.1021/ic101414x

Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates Juan Diwu, Shuao Wang, Zuolei Liao, Peter C. Burns, and Thomas E. Albrecht-Schmitt pp 10074–10080 DOI: 10.1021/ic1015912 Supporting Info

Coordination Properties of Ionic Liquid-Mediated Chromium(II) and Copper(II) Chlorides and Their Complexes with Glucose Evgeny A. Pidko, Volkan Degirmenci, Rutger A. van Santen, and Emiel J. M. Hensen pp 10081–10091 DOI: 10.1021/ic101402r Supporting Info

Facially Coordinating Triamine Ligands with a Cyclic Backbone: Some Structure−Stability Correlations Christian Neis, David Petry, Alexandre Demangeon, Bernd Morgenstern, Dirk Kuppert, Jochen Huppert, Stefan Stucky, and Kaspar Hegetschweiler pp 10092–10107 DOI: 10.1021/ic101360d Supporting Info

Dinuclear Cu(II) Hypocrellin B Complexes with Enhanced Photonuclease Activity Yi Sun, Yuan-Jun Hou, Qian-Xiong Zhou, Wan-Hua Lei, Jing-Rong Chen, Xue-Song Wang, and Bao-Wen Zhang pp 10108–10116 DOI: 10.1021/ic101391x Supporting Info

Models for the Active Site in [FeFe] Hydrogenase with Iron-Bound Ligands Derived from Bis-, Tris-, and Tetrakis(mercaptomethyl)silanes Ulf-Peter Apfel, Dennis Troegel, Yvonne Halpin, Stefanie Tschierlei, Ute Uhlemann, Helmar Grls, Michael Schmitt, Jrgen Popp, Peter Dunne, Munuswamy Venkatesan, Michael Coey, Manfred Rudolph, Johannes G. Vos, Reinhold Tacke, and Wolfgang Weigand pp 10117–10132 DOI: 10.1021/ic101399k Supporting Info

Two-Step Adsorption on Jungle-Gym-Type Porous Coordination Polymers: Dependence on Hydrogen-Bonding Capability of Adsorbates, Ligand-Substituent Effect, and Temperature Kazuhiro Uemura, Yukari Yamasaki, Fumiaki Onishi, Hidetoshi Kita, and Masahiro Ebihara pp 10133–10143 DOI: 10.1021/ic101517t Supporting Info

Spin-Transition-Like Behavior on One Side in a Nitroxide-Copper(II)-Nitroxide Triad System Atsushi Okazawa and Takayuki Ishida pp 10144–10147 DOI: 10.1021/ic101536q Supporting Info

Ternary Nitride GaFe3N: An Experimental and Quantum-Theoretical Study Jens Burghaus, Michael Wessel, Andreas Houben, and Richard Dronskowski pp 10148–10155 DOI: 10.1021/ic1016033

Antiferromagnetic versus Ferromagnetic Exchange Interactions in Bis(μ-Ooximate)dinickel(II) Units for a Series of Closely Related Cube Shaped Carboxamideoximate-Bridged Ni4 Complexes. A Combined Experimental and Theoretical Magneto-Structural Study M. A. Palacios, Antonio J. Mota, Jess E. Perea-Buceta, Fraser J. White, Euan K. Brechin, and Enrique Colacio pp 10156–10165 DOI: 10.1021/ic101435b Supporting Info

Assembly of Robust and Porous Hydrogen-Bonded Coordination Frameworks: Isomorphism, Polymorphism, and Selective Adsorption Ji-Jun Jiang, Mei Pan, Jun-Min Liu, Wei Wang, and Cheng-Yong Su pp 10166–10173 DOI: 10.1021/ic1014384 Supporting Info

Synthetic and Structural Investigations of Linear and Macrocyclic Nickel/Iron/Sulfur Cluster Complexes Li-Cheng Song, Yu-Long Li, Ling Li, Zhen-Chao Gu, and Qing-Mei Hu pp 10174–10182 DOI: 10.1021/ic101451y Supporting Info

Persistent Metal Bis(Hexafluoroacetylacetonato) Complexes Featuring a 2,2′-Bipyridine Substituted Triarylamminium Radical Cation Sharew Adugna, Kseniya Revunova, Brandon Djukic, Serge I. Gorelsky, Hilary A. Jenkins, and Martin T. Lemaire pp 10183–10190 DOI: 10.1021/ic101471u Supporting Info

Coordination Networks from Cu Cations and Tetrakis(methylthio)benzenedicarboxylic Acid: Tunable Bonding Patterns and Selective Sensing for NH3 Gas Xiao-Ping Zhou, Zhengtao Xu, Jun He, Matthias Zeller, Allen D. Hunter, Rodolphe Clrac, Corine Mathonire, Stephen Sin-Yin Chui, and Chi-Ming Che pp 10191–10198 DOI: 10.1021/ic101501p Supporting Info

Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes Gaper Tavar, Sakya S. Sen, Ramachandran Azhakar, Andrea Thorn, and Herbert W. Roesky pp 10199–10202 DOI: 10.1021/ic101556s Supporting Info

Reactions of CO2 and CS2 with 1,2-Bis(di-tert-butylphosphino)ethane Complexes of Nickel(0) and Nickel(I) John S. Anderson, Vlad M. Iluc, and Gregory L. Hillhouse pp 10203–10207 DOI: 10.1021/ic101652e Supporting Info

Correction to Synthesis and Reaction of Monomeric Germanium(II) and Lead(II) Dimethylamide and the Synthesis of Germanium(II) Hydrazide by Cleavage of One N−H Bond of Hydrazine Anukul Jana, Herbert W. Roesky, Carola Schulzke, Prinson P. Samuel, and Alexander Dring pp 10208–10209 DOI: 10.1021/ic101845t Supporting Info

Correction to Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation Properties Qing-Yan Liu, Yu-Ling Wang, Zeng-Mei Shan, Rong Cao, Yun-Liang Jiang, Zu-Jian Wang, and Er-Lei Yang p 10210 DOI: 10.1021/ic101921c

Issue 22

Metal−Organogermanate Frameworks Built by Two Kinds of Infinite Ge−O Chains with High Thermostability and Luminescent Properties Gao-Juan Cao, Shou-Tian Zheng, Na Zhao, Jian-Ke Sun, and Guo-Yu Yang pp 10211–10213 DOI: 10.1021/ic1012796 Supporting Info

Evidence for Cobalt−Cobalt Bond Homolysis and Wavelength-Dependent CO Loss in (μ2-Alkyne)Co2(CO)6 Complexes Nicola M. Boyle, Anthony C. Coleman, Conor Long, Kate L. Ronayne, Wesley R. Browne, Ben L. Feringa, and Mary T. Pryce pp 10214–10216 DOI: 10.1021/ic101321u Supporting Info

A Bioinspired Synthetic Approach for Building Metal−Organic Frameworks with Accessible Metal Centers Paul M. Barron, Curtis A. Wray, Chunhua Hu, Zhiyong Guo, and Wonyoung Choe pp 10217–10219 DOI: 10.1021/ic101459j Supporting Info

“Naked-Eye” Screening of Metal-Based Chemosensors for Biologically Important Anions Christine Mnnel-Crois, Christian Meister, and Felix Zelder pp 10220–10222 DOI: 10.1021/ic1015115 Supporting Info

Flash-Quench Technique Employed To Study the One-Electron Reduction of Triiodide in Acetonitrile: Evidence for a Diiodide Reaction Product Byron H. Farnum, James M. Gardner, and Gerald J. Meyer pp 10223–10225 DOI: 10.1021/ic1015466

Illuminating Metal-Ion Sensors: Benzimidazolesulfonamide Metal Complexes David Martin, Matthieu Rouffet, and Seth M. Cohen pp 10226–10228 DOI: 10.1021/ic101700t Supporting Info

Solvothermal Synthesis of Two Polymorphs of an Indium Germanate Incorporating an Organic Amine Ligand: β- and γ-In2Ge6O15(NH2CH2CH2NH2)2 Chih-Min Wang, Ciao-Wei Yang, Chia-Hui Lin, and Kwang-Hwa Lii pp 10229–10231 DOI: 10.1021/ic1017856 Supporting Info

Zinc(II) Silsesquioxane Complexes and Their Application for the Ring-Opening Polymerization of rac-Lactide Carlo Di Iulio, Matthew D. Jones, Mary F. Mahon, and David C. Apperley pp 10232–10234 DOI: 10.1021/ic101809r Supporting Info

Ruthenium−Oxygen Coordination-Driven Self-Assembly of a RuII8 Incomplete Prism: Synthesis, Structure, and Shape-Selective Molecular Recognition Study Sankarasekaran Shanmugaraju, Arun Kumar Bar, and Partha Sarathi Mukherjee pp 10235–10237 DOI: 10.1021/ic101823s Supporting Info

Coordination-Driven Self-Assembly of Truncated Tetrahedra Capable of Encapsulating 1,3,5-Triphenylbenzene Yao-Rong Zheng, Zhigang Zhao, Hyunuk Kim, Ming Wang, Koushik Ghosh, J. Bryant Pollock, Ki-Whan Chi, and Peter J. Stang pp 10238–10240 DOI: 10.1021/ic1018373 Supporting Info

Hard/Soft Heterometallic Network Complex of a Macrocycle with Endo/Exocyclic Coordination Yongnu Jin, Hyun Jee Kim, Jai Young Lee, So Young Lee, Won Joon Shim, Sang Hee Hong, and Shim Sung Lee pp 10241–10243 DOI: 10.1021/ic101880r Supporting Info

Fabrication of Apatite-Type La9.33(SiO4)6O2 Hollow Nanoshells as Energy-Saving Oxidative Catalysts Xian-Hua Zhang, Xiaodong Yi, Jiawei Zhang, Zhaoxiong Xie, Junyong Kang, and Lansun Zheng pp 10244–10246 DOI: 10.1021/ic1018949 Supporting Info

Microwave-Assisted Alkylation of [CB11H12]− and Related Anions Michal Valek, Jan tursa, Radek Pohl, and Josef Michl pp 10247–10254 DOI: 10.1021/ic101234p

Lithium Salts of [1,12-Dialkyl-CB11Me10]− Anions Michal Valek, Jan tursa, Radek Pohl, and Josef Michl pp 10255–10263 DOI: 10.1021/ic101235e

Quinonoid-Bridged Chair-Shaped Dirhenium(I) Metallacycles: Synthesis, Characterization, and Spectroelectrochemical Studies Dibyendu Bhattacharya, Malaichamy Sathiyendiran, Jing-Yun Wu, Che-Hao Chang, Sung-Chou Huang, Yu-Ling Zeng, Ching-Yao Lin, P. Thanasekaran, Bo-Chao Lin, Chao-Ping Hsu, Gene-Hsiang Lee, Shie-Ming Peng, and Kuang-Lieh Lu pp 10264–10272 DOI: 10.1021/ic9018794 Supporting Info

A Kinetic Study of Rearrangement and Degradation Reactions of Tetrathionate and Trithionate in Near-Neutral Solutions Hongguang Zhang and Matthew I. Jeffrey pp 10273–10282 DOI: 10.1021/ic9023025

Theoretical Investigations on the Chemical Bonding, Electronic Structure, And Optical Properties of the Metal−Organic Framework MOF-5 Li-Ming Yang, Ponniah Vajeeston, Ponniah Ravindran, Helmer Fjellvg, and Mats Tilset pp 10283–10290 DOI: 10.1021/ic100694w

Thermodynamic Properties of Co3O4 and Sr6Co5O15 from First-Principles James E. Saal, Yi Wang, ShunLi Shang, and Zi-Kui Liu pp 10291–10298 DOI: 10.1021/ic100835a

Application of Tetrazole-Functionalized Thioethers with Different Spacer Lengths in the Self-Assembly of Polyoxometalate-Based Hybrid Compounds Xiuli Wang, Hailiang Hu, Aixiang Tian, Hongyan Lin, and Jin Li pp 10299–10306 DOI: 10.1021/ic100840a Supporting Info

First-Principles Study of the Separation of AmIII/CmIII from EuIII with Cyanex301 Xiaoyan Cao, Daniel Heidelberg, Jan Ciupka, and Michael Dolg pp 10307–10315 DOI: 10.1021/ic100844t Supporting Info

Copper Corroles: the Question of Noninnocence Kristine Pierloot, Hailiang Zhao, and Steven Vancoillie pp 10316–10329 DOI: 10.1021/ic100866z Supporting Info

Pathway from Chain to Dimer in Cu(I) Camphor Hydrazone Complexes M. Fernanda N. N. Carvalho, M. Teresa Duarte, Tiago A. Fernandes, Adelino M. Galvo, and Ana M. Botelho do Rego pp 10330–10337 DOI: 10.1021/ic101075g

H2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation Vincent Fourmond, Pierre-Andr Jacques, Marc Fontecave, and Vincent Artero pp 10338–10347 DOI: 10.1021/ic101187v Supporting Info

The Role of Oxygen Stoichiometry on Phase Stability, Structure, and Magnetic Properties of Sr2CoIrO6−δ D. Mikhailova, N. Narayanan, W. Gruner, A. Voss, A. Senyshyn, D. M. Trots, H. Fuess, and H. Ehrenberg pp 10348–10356 DOI: 10.1021/ic100973p

Donor−Acceptor Complexes of Borazines Anna S. Lisovenko and Alexey Y. Timoshkin pp 10357–10369 DOI: 10.1021/ic101081k Supporting Info

Ligand Electronic Parameters as a Measure of the Polarization of the C≡O Bond in [M(CO)xLy]n Complexes and of the Relative Stabilization of [M(CO)xLy]n/n+1 Species Fabio Zobi pp 10370–10377 DOI: 10.1021/ic101246a Supporting Info

Structural Study of the Li0.5Na0.5MnFe2(PO4)3 and Li0.75Na0.25MnFe2(PO4)3 Alluaudite Phases and Their Electrochemical Properties As Positive Electrodes in Lithium Batteries Khiem Trad, Dany Carlier, Laurence Croguennec, Alain Wattiaux, Mongi Ben Amara, and Claude Delmas pp 10378–10389 DOI: 10.1021/ic101130m

Magnetic Behavior Control in Niccolite Structural Metal Formate Frameworks [NH2(CH3)2][FeIIIMII(HCOO)6] (M = Fe, Mn, and Co) by Varying the Divalent Metal Ions Jiong-Peng Zhao, Bo-Wen Hu, Francesc Lloret, Jun Tao, Qian Yang, Xiao-Feng Zhang, and Xian-He Bu pp 10390–10399 DOI: 10.1021/ic1014863 Supporting Info

Electronic Structure of Highly Ruffled Low-Spin Iron(III) Porphyrinates with Electron Withdrawing Heptafluoropropyl Groups at the meso Positions Akira Tozuka, Yoshiki Ohgo, Akira Ikezaki, Miyoko Taniguchi, and Mikio Nakamura pp 10400–10408 DOI: 10.1021/ic101184y Supporting Info

A Chemical Bond Theory of Quantum Size Effects of Semiconductor Clusters Faming Gao pp 10409–10414 DOI: 10.1021/ic1011378

Crucial Role of the Reaction Conditions in Isolating Several Metastable Phases in a Gd−Ce−Zr−O System B. P. Mandal, R. Shukla, S. N. Achary, and A. K. Tyagi pp 10415–10421 DOI: 10.1021/ic1018482

An Unusual 3D Entangled Co(II) Coordination Polymer Directed by Ferromagnetic Molecular Building Block Jian-Qiang Liu, Bin Liu, Yao-Yu Wang, Ping Liu, Guo-Ping Yang, Rui-Ting Liu, Qi-Zhen Shi, and Stuart R. Batten pp 10422–10426 DOI: 10.1021/ic101286j Supporting Info

Synthesis, Structure, and Solution Properties of [(mim-TASN)FeCl2]+ and Its μ-Oxo Derivative Jinlan Cui, Mark S. Mashuta, Robert M. Buchanan, and Craig A. Grapperhaus pp 10427–10435 DOI: 10.1021/ic1012999 Supporting Info

Development of an Icosahedral Quasicrystal and Two Approximants in the Ca−Au−Sn System: Syntheses and Structural Analyses Qisheng Lin and John D. Corbett pp 10436–10444 DOI: 10.1021/ic101356n Supporting Info

Structural Analysis, Spectroscopic, and Magnetic Properties of the 1D Triple-Bridged Compounds [M(dca)2(bpa)] (M = Mn, Fe, Co, Zn; dca = dicyanamide; bpa = 1,2-bis(4-pyridyl)ethane) and the 3D [Ni(dca)(bpa)2]dca·6H2O Noelia de la Pinta, Susana Martn, M. Karmele Urtiaga, M. Gotzone Barandika, M. Isabel Arriortua, Luis Lezama, Gotzon Madariaga, and Roberto Corts pp 10445–10454 DOI: 10.1021/ic1014626 Supporting Info

Structural, Electronic, and Magnetic Properties of UFeS3 and UFeSe3 Geng Bang Jin, Emilie Ringe, Gary J. Long, Fernande Grandjean, Moulay T. Sougrati, Eun Sang Choi, Daniel M. Wells, Mahalingam Balasubramanian, and James A. Ibers pp 10455–10467 DOI: 10.1021/ic101474e Supporting Info

New Intermetallics YbAu2In4 and Yb2Au3In5 C. Peter Sebastian, James Salvador, Joshua B. Martin, and Mercouri G. Kanatzidis pp 10468–10474 DOI: 10.1021/ic101502e Supporting Info

Coordination Chemistry in the Solid State: Reactivity of Manganese and Cadmium Chlorides with Imidazole and Pyrazole and Their Hydrochlorides Christopher J. Adams, Mukhtar A. Kurawa, and A. Guy Orpen pp 10475–10485 DOI: 10.1021/ic101403j Supporting Info

Combining Azide, Carboxylate, and 2-Pyridyloximate Ligands in Transition-Metal Chemistry: Ferromagnetic NiII5 Clusters with a Bowtie Skeleton Constantina Papatriantafyllopoulou, Theocharis C. Stamatatos, Wolfgang Wernsdorfer, Simon J. Teat, Anastasios J. Tasiopoulos, Albert Escuer, and Spyros P. Perlepes pp 10486–10496 DOI: 10.1021/ic1014829 Supporting Info

The Reactivity of Phosphagermaallene Tip(t-Bu)Ge═C═PMes* with Doubly and Triply Bonded Nitrogen Compounds Dumitru Ghereg, Heinz Gornitzka, Jean Escudi, and Sonia Ladeira pp 10497–10505 DOI: 10.1021/ic1014913 Supporting Info

Reduction of Dinitrogen with an Yttrium Metallocene Hydride Precursor, [(C5Me5)2YH]2 Benjamin M. Schmiege, Joseph W. Ziller, and William J. Evans pp 10506–10511 DOI: 10.1021/ic101558e Supporting Info

Thermochemistry of Lewis Adducts of BH3 and Nucleophilic Substitution of Triethylamine on NH3BH3 in Tetrahydrofuran Robert G. Potter and Donald M. Camaioni, Monica Vasiliu and David A. Dixon pp 10512–10521 DOI: 10.1021/ic101481c Supporting Info

Eu3+/Tb3+-Doped La2O2CO3/La2O3 Nano/Microcrystals with Multiform Morphologies: Facile Synthesis, Growth Mechanism, and Luminescence Properties Guogang Li, Chong Peng, Cuimiao Zhang, Zhenhe Xu, Mengmeng Shang, Dongmei Yang, Xiaojiao Kang, Wenxin Wang, Chunxia Li, Ziyong Cheng, and Jun Lin pp 10522–10535 DOI: 10.1021/ic101541q Supporting Info

Ru9Zn7Sb8: A Structure with a 2 × 2 × 2 Supercell of the Half-Heusler Phase Ding-Bang Xiong, Yufeng Zhao, Norihiko L. Okamoto, Clemens Pietzonka, Takeshi Waki, and Haruyuki Inui pp 10536–10542 DOI: 10.1021/ic1015669 Supporting Info

Synthesis and Coordination Chemistry of Two N2-Donor Chelating Di(indazolyl)methane Ligands: Structural Characterization and Comparison of Their Metal Chelation Aptitudes Claudio Pettinari, Alessandro Marinelli, Fabio Marchetti, Jean Ngoune, Agustn Galindo, Eleuterio lvarez, and Margarita Gmez pp 10543–10556 DOI: 10.1021/ic101577k Supporting Info

Spectroscopic and Magnetic Properties of a Series of μ-Cyano Bridged Bimetallic Compounds of the Type MII−NC−FeIII (M = Mn, Co, and Zn) Using the Building Block [FeIII(CN)5imidazole]2− Helose Tchouka, Auke Meetsma, and Wesley R. Browne pp 10557–10570 DOI: 10.1021/ic101447q Supporting Info

Site-Differentiated Solid Solution in (Na1−xCux)2Ta4O11 and Its Electronic Structure and Optical Properties Olena Palasyuk, Andriy Palasyuk, and Paul A. Maggard pp 10571–10578 DOI: 10.1021/ic101529n Supporting Info

Mn8 and Mn16 Clusters from the Use of 2-(Hydroxymethyl)pyridine, and Comparison with the Products from Bulkier Chelates: A New High Nuclearity Single-Molecule Magnet Taketo Taguchi, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 10579–10589 DOI: 10.1021/ic101594d Supporting Info

Preparation and Bifunctional Gas Sensing Properties of Porous In2O3−CeO2 Binary Oxide Nanotubes Lin Xu, Hongwei Song, Biao Dong, Yu Wang, Jiansheng Chen, and Xue Bai pp 10590–10597 DOI: 10.1021/ic101602a

Complexation of Lactate with Neodymium(III) and Europium(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption, and Luminescence Spectroscopy Guoxin Tian, Leigh R. Martin, and Linfeng Rao pp 10598–10605 DOI: 10.1021/ic101592h

Hexa Boron-Dipyrromethene Cyclotriphosphazenes: Synthesis, Crystal Structure, and Photophysical Properties M. Rajeswara Rao, R. Bolligarla, Ray J. Butcher, and M. Ravikanth pp 10606–10616 DOI: 10.1021/ic1016092 Supporting Info

Structural Comparison of Copper(I) and Copper(II) Complexes with Tris(2-pyridylmethyl)amine Ligand William T. Eckenhoff and Tomislav Pintauer pp 10617–10626 DOI: 10.1021/ic1016142 Supporting Info

Novel Approach to Aminocarboranes by Mild Amidation of Selected Iodo-carboranes Yulia Sevryugina, Richard L. Julius, and M. Frederick Hawthorne pp 10627–10634 DOI: 10.1021/ic101620h Supporting Info

Harnessing Low-Valent Metal Centers through Non-Bonding Orbital Interactions Titel Jurca, Ilia Korobkov, Glenn P. A. Yap, Serge I. Gorelsky, and Darrin S. Richeson pp 10635–10641 DOI: 10.1021/ic1016438 Supporting Info

Trapping Unstable Terminal M−O Multiple Bonds of Monocyclopentadienyl Niobium and Tantalum Complexes with Lewis Acids Javier Snchez-Nieves, Luis M. Frutos, Pascual Royo, Obis Castao, Eberhardt Herdtweck, and Marta E. G. Mosquera pp 10642–10648 DOI: 10.1021/ic1016609 Supporting Info

Addition of Water Across Si−Ir Bonds in Iridium Complexes with κ-P,P,Si (biPSi) Pincer Ligands Alba Garca-Camprub, Marta Martn, and Eduardo Sola pp 10649–10657 DOI: 10.1021/ic1016774 Supporting Info

A Series of CuII-Azide Polymers of Cu6 Building Units and the Role of Chelating Diamine in Controlling their Dimensionality: Synthesis, Structures, and Magnetic Behavior Sandip Mukherjee and Partha Sarathi Mukherjee pp 10658–10667 DOI: 10.1021/ic1016966 Supporting Info

Bioinorganic Chemistry of Parkinson’s Disease: Structural Determinants for the Copper-Mediated Amyloid Formation of Alpha-Synuclein Andrs Binolfi, Esa E. Rodriguez, Daniela Valensin, Nicola D’Amelio, Emiliano Ippoliti, Gonzalo Obal, Rosario Duran, Alessandra Magistrato, Otto Pritsch, Markus Zweckstetter, Gianni Valensin, Paolo Carloni, Liliana Quintanar, Christian Griesinger, and Claudio O. Fernndez pp 10668–10679 DOI: 10.1021/ic1016752 Supporting Info

Formation of Diaryl Telluroxides and Tellurones by Photosensitized Oxygenation of Diaryl Tellurides Makoto Oba, Yasunori Okada, Masaki Endo, Kazuhito Tanaka, Kozaburo Nishiyama, Shigeru Shimada, and Wataru Ando pp 10680–10686 DOI: 10.1021/ic101708y Supporting Info

Isomorphous Substitutions of Rare Earth Elements for Calcium in Synthetic Hydroxyapatites Lyudmyla I. Ardanova, Evgeni I. Get’man, Stanislav N. Loboda, Vadim V. Prisedsky, Tatiana V. Tkachenko, Valeriy I. Marchenko, Valeriy P. Antonovich, Nataliya A. Chivireva, Konstantin A. Chebishev, and Alexandra S. Lyashenko pp 10687–10693 DOI: 10.1021/ic1015127 Supporting Info

Rhenium Complexes with 2-(Diphenylphosphinomethyl)aniline: Formation of a Cyclic, Trinuclear Oxorhenium(V) Core Jennifer Schroer, Stefan Wagner, and Ulrich Abram pp 10694–10701 DOI: 10.1021/ic101792j Supporting Info

“Click” Synthesis and Properties of Carborane-Appended Large Dendrimers Rodrigue Djeda, Jaime Ruiz, Didier Astruc, Rashmirekha Satapathy, Barada Prasanna Dash, and Narayan S. Hosmane pp 10702–10709 DOI: 10.1021/ic101729s Supporting Info

Reinvestigation of the MII (M = Ni, Co)/TetraThiafulvaleneTetraCarboxylate System Using High-Throughput Methods: Isolation of a Molecular Complex and Its Single-Crystal-to-Single-Crystal Transformation to a Two-Dimensional Coordination Polymer Thi Le Anh Nguyen, Thomas Devic, Pierre Mialane, Eric Rivire, Andreas Sonnauer, Norbert Stock, Rezan Demir-Cakan, Mathieu Morcrette, Carine Livage, Jrome Marrot, Jean-Marie Tarascon, and Grard Frey pp 10710–10717 DOI: 10.1021/ic101906u Supporting Info

Two-Dimensional, Pyrazine-Based Nonlinear Optical Chromophores with Ruthenium(II) Ammine Electron Donors Benjamin J. Coe, John Fielden, Simon P. Foxon, Inge Asselberghs, Koen Clays, and Bruce S. Brunschwig pp 10718–10726 DOI: 10.1021/ic1019197

Supramolecular Effects on Anion-Dependent Spin-State Switching Properties in Heteroleptic Iron(II) Complexes Zhaoping Ni and Matthew P. Shores pp 10727–10735 DOI: 10.1021/ic102004c Supporting Info

Synthesis and Structures of Pb3O2(CH3COO)2·0.5H2O and Pb2O(HCOO)2: Two Corrosion Products Revisited Catherine M. Mauck, Titus W. P. van den Heuvel, Michaela M. Hull, Matthias Zeller, and Catherine M. Oertel pp 10736–10743 DOI: 10.1021/ic101904j Supporting Info

Correction to Thioester Hydrolysis Reactivity of an Fe(III)Zn(II) Complex James J. Danford, Piotr Dobrowolski, and Lisa M. Berreau p 10744 DOI: 10.1021/ic1020109

Correction to Synthesis, Characterization, and Ligand Exchange Reactivity of a Series of First Row Divalent Metal 3-Hydroxyflavonolate Complexes Katarzyna Grubel, Katarzyna Rudzka, Atta M. Arif, Katie L. Klotz, Jason A. Halfen, and Lisa M. Berreau p 10745 DOI: 10.1021/ic1020115

Issue 23

Mechanochromic Luminescence Quenching: Force-Enhanced Singlet-to-Triplet Intersystem Crossing for Iodide-Substituted Difluoroboron−Dibenzoylmethane−Dodecane in the Solid State Guoqing Zhang, Jiwei Lu, and Cassandra L. Fraser pp 10747–10749 DOI: 10.1021/ic902591s Supporting Info

First Ruthenium Organometallic Complex of Antibacterial Agent Ofloxacin. Crystal Structure and Interactions with DNA Iztok Turel, Jakob Kljun, Franc Perdih, Elena Morozova, Vladimir Bakulev, Nina Kasyanenko, Jo Ann W. Byl, and Neil Osheroff pp 10750–10752 DOI: 10.1021/ic101355d Supporting Info

A Highly Selective Turn-On Colorimetric, Red Fluorescent Sensor for Detecting Mobile Zinc in Living Cells Pingwu Du and Stephen J. Lippard pp 10753–10755 DOI: 10.1021/ic101569a Supporting Info

A Hybrid Lithium Oxalate−Phosphinate Salt Andrew R. Shaffer, Nihal Deligonul, Daniel A. Scherson, and John D. Protasiewicz pp 10756–10758 DOI: 10.1021/ic1018532 Supporting Info

Pseudotetrahedral d0, d1, and d2 Metal−Oxo Cores within a Tris(alkoxide) Platform Stanislav Groysman, Dino Villagrn, and Daniel G. Nocera pp 10759–10761 DOI: 10.1021/ic101968s Supporting Info

Organometallic Quinonoid Linkers: A Versatile Tether for the Design of Panchromatic Ruthenium(II) Heteroleptic Complexes Aurlie Damas, Barbara Ventura, M. Rosa Axet, Alessandra Degli Esposti, Lise-Marie Chamoreau, Andrea Barbieri, and Hani Amouri pp 10762–10764 DOI: 10.1021/ic102019b Supporting Info

Chemistry of Carbon Dioxide Relevant to Its Utilization: A Personal Perspective Donald J. Darensbourg pp 10765–10780 DOI: 10.1021/ic101800d

Structures and Properties of Porous Coordination Polymers Based on Lanthanide Carboxylate Building Units Yinfeng Han, Xiaoyan Li, Liqing Li, Chunlin Ma, Zhen Shen, You Song, and Xiaozeng You pp 10781–10787 DOI: 10.1021/ic902194g Supporting Info

Complex Alloys Containing Double-Mackay Clusters and (Sb1−δZnδ)24 Snub Cubes Filled with Highly Disordered Zinc Aggregates: Synthesis, Structures, and Physical Properties of Ruthenium Zinc Antimonides Ding-Bang Xiong, Yufeng Zhao, Walter Schnelle, Norihiko L. Okamoto, and Haruyuki Inui pp 10788–10797 DOI: 10.1021/ic101804m Supporting Info

Series of Comparable Dinuclear Group 4 Neo-pentoxide Precursors for Production of pH Dependent Group 4 Nanoceramic Morphologies Timothy J. Boyle, Leigh Anna M. Ottley, and Sarah M. Hoppe, Charles F. Campana pp 10798–10808 DOI: 10.1021/ic101205d Supporting Info

Crystal Structures and Magnetic Properties of New Europium Melilites Eu2MSi2O7 (M = Mg, Mn) and Their Strontium Analogues Takashi Endo, Yoshihiro Doi, Makoto Wakeshima, and Yukio Hinatsu pp 10809–10814 DOI: 10.1021/ic1011007 Supporting Info

Determination of the Kinetic Profile of a Dinuclear Platinum Anticancer Complex in the Presence of Sulfate: Introducing a New Tool for the Expedited Analysis of 2D [1H, 15N] HSQC NMR Spectra Rasha A. Ruhayel, Ben Corry, Carlos Braun, Donald S. Thomas, Susan J. Berners-Price, and Nicholas P. Farrell pp 10815–10819 DOI: 10.1021/ic100576k Supporting Info

Boronyl Ligand as a Member of the Isoelectronic Series BO− → CO → NO+: Viable Cobalt Carbonyl Boronyl Derivatives? Xiaoli Gong, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer, III pp 10820–10832 DOI: 10.1021/ic101215v Supporting Info

Topologies of Metal−Organic Frameworks Based on Pyrimidine-5-carboxylate and Unexpected Gas-Sorption Selectivity for CO2 Jinwoo Seo, Narae Jin, and Hyungphil Chun pp 10833–10839 DOI: 10.1021/ic1012523 Supporting Info

Control of the Stability of Hydrogenobacter Thermophilus Cytochrome c552 through Alteration of the Basicity of the N-Terminal Amino Group of the Polypeptide Chain Hulin Tai, Toratane Munegumi, and Yasuhiko Yamamoto pp 10840–10846 DOI: 10.1021/ic1005924 Supporting Info

Exploring the Emissive Properties of New Azacrown Compounds Bearing Aryl, Furyl, or Thienyl Moieties: A Special Case of Chelation Enhancement of Fluorescence upon Interaction with Ca2+, Cu2+, or Ni2+ Elisabete Oliveira, Rosa M. F. Baptista, Susana P. G. Costa, M. Manuela M. Raposo, and Carlos Lodeiro pp 10847–10857 DOI: 10.1021/ic101095y Supporting Info

Tiopronin Gold Nanoparticle Precursor Forms Aurophilic Ring Tetramer Carrie A. Simpson, Christopher L. Farrow, Peng Tian, Simon J. L. Billinge, Brian J. Huffman, Kellen M. Harkness, and David E. Cliffel pp 10858–10866 DOI: 10.1021/ic101146e Supporting Info

Photoinduced Electron Transfer from Tryptophan to RuIITAP Complexes: The Primary Process for Photo-Cross-Linking with Oligopeptides Mateusz Rebarz, Jonathan Ghesquire, Arnaud Boisdenghien, Eric Defrancq, Ccile Moucheron, and Andre Kirsch-De Mesmaeker pp 10867–10874 DOI: 10.1021/ic101214m Supporting Info

Controlled Sulfur Oxygenation of the Ruthenium Dithiolate (4,7-Bis-(2′-methyl-2′-mercaptopropyl)-1-thia-4,7-diazacyclononane)RuPPh3 under Limiting O2 Conditions Yields Thiolato/Sulfinato, Sulfenato/Sulfinato, and Bis-Sulfinato Derivatives Csar A. Masitas, Manoj Kumar, Mark S. Mashuta, Pawel M. Kozlowski, and Craig A. Grapperhaus pp 10875–10881 DOI: 10.1021/ic101221z Supporting Info

Binary Boron-Rich Borides of Magnesium: Single-Crystal Investigations and Properties of MgB7 and the New Boride Mg5B44 Alexis Pediaditakis, Melanie Schroeder, Vanessa Sagawe, Thilo Ludwig, and Harald Hillebrecht pp 10882–10893 DOI: 10.1021/ic1012389 Supporting Info

Slow Relaxation of the Magnetization in Non-Linear Optical Active Layered Mixed Metal Oxalate Chains Elena Cariati, Renato Ugo, Giuseppe Santoro, Elisa Tordin, Lorenzo Sorace, Andrea Caneschi, Angelo Sironi, Piero Macchi, and Nicola Casati pp 10894–10901 DOI: 10.1021/ic1013076 Supporting Info

Effect of Ligand Substitution on the Exchange Interactions in {Mn12}-Type Single-Molecule Magnets Danil W. Boukhvalov, Viatcheslav V. Dobrovitski, Paul Kgerler, Mohammad Al-Saqer, Mikhail I. Katsnelson, Alexander I. Lichtenstein, and Bruce N. Harmon pp 10902–10906 DOI: 10.1021/ic101229p

Ca9Lu(PO4)7:Eu2+,Mn2+: A Potential Single-Phased White-Light-Emitting Phosphor Suitable for White-Light-Emitting Diodes Ning Guo, Yeju Huang, Hongpeng You, Mei Yang, Yanhua Song, Kai Liu, and Yuhua Zheng pp 10907–10913 DOI: 10.1021/ic101749g Supporting Info

Solution and Structural Characterization of Iron(II) Complexes with Ortho-Halogenated Phenolates: Insights Into Potential Substrate Binding Modes in Hydroquinone Dioxygenases Sara S. Rocks, William W. Brennessel, Timothy E. Machonkin, and Patrick L. Holland pp 10914–10929 DOI: 10.1021/ic101377u Supporting Info

Computational Studies on the Photophysical Properties and NMR Fluxionality of Dinuclear Platinum(II) A-Frame Alkynyl Diphosphine Complexes Wai Han Lam and Vivian Wing-Wah Yam pp 10930–10939 DOI: 10.1021/ic101271d Supporting Info

Water-Based Route to Colloidal Mn-Doped ZnSe and Core/Shell ZnSe/ZnS Quantum Dots Abdelhay Aboulaich, Malgorzata Geszke, Lavinia Balan, Jaafar Ghanbaja, Ghouti Medjahdi, and Raphal Schneider pp 10940–10948 DOI: 10.1021/ic101302q

Formation of Nanometric HT-LiCoO2 by a Precipitation and Aging Process in an Alcoholic Solution Dominique Larcher, Bruno Delobel, Lydia Dantras-Laffont, Evelyne Simon, Jean-Franois Blach, and Emmanuel Baudrin pp 10949–10955 DOI: 10.1021/ic101324e

Analysis of the Magnetic Structure and Ferroelectric Polarization of Monoclinic MnSb2S4 by Density Functional Theory Calculations Chuan Tian, Changhoon Lee, Erjun Kan, Fang Wu, and Myung-Hwan Whangbo pp 10956–10959 DOI: 10.1021/ic101351b

Gallium(III) Complexes of DOTA and DOTA−Monoamide: Kinetic and Thermodynamic Studies Vojtch Kubek, Jana Havlkov, Jan Kotek, Gyula Tircs, Petr Hermann, va Tth, and Ivan Luke pp 10960–10969 DOI: 10.1021/ic101378s Supporting Info

Site-Selective Lanthanide Doping in a Nonanuclear Yttrium(III) Cluster Revealed by Crystal Structures and Luminescence Spectra Franois Baril-Robert, Sarah Petit, Guillaume Pilet, Guillaume Chastanet, Christian Reber, and Dominique Luneau pp 10970–10976 DOI: 10.1021/ic1011082 Supporting Info

High Conductivity in Hydrothermally Grown AgCuO2 Single Crystals Verified Using Focused-Ion-Beam-Deposited Nanocontacts David Muoz-Rojas, Rosa Crdoba, Amalio Fernndez-Pacheco, Jos Mara De Teresa, Guillaume Sauthier, Jordi Fraxedas, Richard I. Walton, and Nieves Casa-Pastor pp 10977–10983 DOI: 10.1021/ic101420c

Electronic Configuration of Five-Coordinate High-Spin Pyrazole-Ligated Iron(II) Porphyrinates Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 10984–10991 DOI: 10.1021/ic101469e Supporting Info

Nature of Bonding in Group 13 Dimetallenes: a Delicate Balance between Singlet Diradical Character and Closed Shell Interactions Jani Moilanen, Philip P. Power, and Heikki M. Tuononen pp 10992–11000 DOI: 10.1021/ic101487g Supporting Info

Novel Bismuth and Lead Coordination Polymers Synthesized with Pyridine-2,5-Dicarboxylates: Two Single Component “White” Light Emitting Phosphors Arief C. Wibowo, Shae A. Vaughn, Mark D. Smith, and Hans-Conrad zur Loye pp 11001–11008 DOI: 10.1021/ic1014708 Supporting Info

Photoenhanced Oxidative DNA Cleavage with Non-Heme Iron(II) Complexes Qian Li, Wesley R. Browne, and Gerard Roelfes pp 11009–11017 DOI: 10.1021/ic1014785 Supporting Info

Dependence of the Chemical Properties of Macrocyclic [NiII2L(μ-O2CR)]+ Complexes on the Basicity of the Carboxylato Coligands (L2− = macrocyclic N6S2 ligand) Ulrike Lehmann, Julia Klingele, Vasile Lozan, Gunther Steinfeld, Marco H. Klingele, Steffen Kss, Axel Rodenstein, and Berthold Kersting pp 11018–11029 DOI: 10.1021/ic101574a Supporting Info

Bis(μ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates Peng Kang, Elena Bobyr, John Dustman, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and T. Daniel P. Stack pp 11030–11038 DOI: 10.1021/ic101515g Supporting Info

Effect of the Structure of the Diamine Backbone of P−N−N−P ligands in Iron(II) Complexes on Catalytic Activity in the Transfer Hydrogenation of Acetophenone Alexandre A. Mikhailine and Robert H. Morris pp 11039–11044 DOI: 10.1021/ic101548j Supporting Info

Dimensionality Switching Through a Thermally Induced Reversible Single-Crystal-to-Single-Crystal Phase Transition in a Cyanide Complex Ruxandra Gheorghe, Marguerite Kalisz, Rodolphe Clrac, Corine Mathonire, Patrick Herson, Yanling Li, Mannan Seuleiman, Rodrigue Lescouzec, Francesc Lloret, and Miguel Julve pp 11045–11056 DOI: 10.1021/ic1015725 Supporting Info

Reliability and Storage Capacity: a Compromise Illustrated in the Two-Step Spin-Crossover System [Fe(bapbpy)(NCS)2] Mikael Kepenekian, Jos Snchez Costa, Boris Le Guennic, Pascale Maldivi, Sylvestre Bonnet, Jan Reedijk, Patrick Gamez, and Vincent Robert pp 11057–11061 DOI: 10.1021/ic101669b

Sr3Co2O4.33H0.84: An Extended Transition Metal Oxide-Hydride Rebecca M. Helps, Nicholas H. Rees, and Michael A. Hayward pp 11062–11068 DOI: 10.1021/ic101613b Supporting Info

First Halogen Anion-Bridged (MMX)n-Type One-Dimensional Coordination Polymer Built upon d10−d10 Dimers Tianle Zhang, Changpeng Ji, Kaili Wang, Daniel Fortin, and Pierre D. Harvey pp 11069–11076 DOI: 10.1021/ic101619y Supporting Info

Selective Oxygen-Plasma-Etching Technique for the Formation of ZnO−FTO Heterostructure Nanotubes and Their Rectified Photocatalytic Properties N. Chantarat, Yu-Wei Chen, Chin-Ching Lin, Mei-Ching Chiang, and San-Yuan Chen pp 11077–11083 DOI: 10.1021/ic1016214

Structure−Activity Relationships of Highly Cytotoxic Copper(II) Complexes with Modified Indolo[3,2-c]quinoline Ligands Michael F. Primik, Simone Gschl, Michael A. Jakupec, Alexander Roller, Bernhard K. Keppler, and Vladimir B. Arion pp 11084–11095 DOI: 10.1021/ic101633z Supporting Info

Self-Assembled 3D Heterometallic CuII/FeII Coordination Polymers with Octahedral Net Skeletons: Structural Features, Molecular Magnetism, Thermal and Oxidation Catalytic Properties Yauhen Y. Karabach, M. Ftima C. Guedes da Silva, Maximilian N. Kopylovich, Beatriz Gil-Hernndez, Joaquin Sanchiz, Alexander M. Kirillov, and Armando J. L. Pombeiro pp 11096–11105 DOI: 10.1021/ic101668f Supporting Info

Iron(II) Complexes with Tetradentate Bis(aminophenolate) Ligands: Synthesis and Characterization, Solution Behavior, and Reactivity with O2 Christopher J. Whiteoak, Rafael Torres Martin de Rosales, Andrew J. P. White, and George J. P. Britovsek pp 11106–11117 DOI: 10.1021/ic1016998 Supporting Info

Stabilization of 3:1 Site-Differentiated Cubane-Type Clusters in the [Fe4S4]1+ Core Oxidation State by Tertiary Phosphine Ligation: Synthesis, Core Structural Diversity, and S = 1/2 Ground States Liang Deng, Amit Majumdar, Wayne Lo, and R. H. Holm pp 11118–11126 DOI: 10.1021/ic101702b Supporting Info

Two Heptacopper(II) Disk Complexes with a [Cu7(μ3-OH)4(μ-OR)2]8+ Core James J. Henkelis, Leigh F. Jones, Marcelo P. de Miranda, Colin A. Kilner, and Malcolm A. Halcrow pp 11127–11132 DOI: 10.1021/ic1020093 Supporting Info

Reactivity of Bis(2,2,5,5-tetramethyl-2,5-disila-1-azacyclopent-1-yl)tin with CO2, OCS, and CS2 and Comparison to That of Bis[bis(trimethylsilyl)amido]tin Constantine A. Stewart, Diane A. Dickie, Marie V. Parkes, Josephat A. Saria, and Richard A. Kemp pp 11133–11141 DOI: 10.1021/ic101709q

Vibrational Spectra, Crystal Structures, Constitutional and Rotational Isomerism of FC(O)SCN and FC(O)NCS Luis A. Ramos, Sonia E. Ulic, Rosana M. Romano, Mauricio F. Erben, Christian W. Lehmann, Eduard Bernhardt, Helmut Beckers, Helge Willner, and Carlos O. Della Vdova pp 11142–11157 DOI: 10.1021/ic101741e Supporting Info

Systematic and In Situ Energy Dispersive X-ray Diffraction Investigations on the Formation of Lanthanide Phosphonatobutanesulfonates: Ln(O3P-C4H8-SO3)(H2O) (Ln = La−Gd) Mark Feyand, Christian Nther, Andr Rothkirch, and Norbert Stock pp 11158–11163 DOI: 10.1021/ic101786r Supporting Info

Adsorption and Separation of Organic Six-Membered Ring Analogues on Neutral Cd(II)-MOF Generated from Asymmetric Schiff-Base Ligand Li Duan, Zhen-Hua Wu, Jian-Ping Ma, Xiang-Wen Wu, and Yu-Bin Dong pp 11164–11173 DOI: 10.1021/ic101756t Supporting Info

Conformational Control of Benzyl-o-carboranylbenzene Derivatives and Molecular Encapsulation of Acetone in the Dynamically Formed Space of 1,3,5-Tris(2-benzyl-o-carboran-1-yl)benzene Chalermkiat Songkram, Kiminori Ohta, Kentaro Yamaguchi, Fabio Pichierri, and Yasuyuki Endo pp 11174–11183 DOI: 10.1021/ic101862n Supporting Info

Novel Heteroleptic Heterobimetallic Alkoxide Complexes as Facile Single-Source Precursors for Ta5+ Doped TiO2−SnO2 Nanoparticles Shashank Mishra, Erwann Jeanneau, Marie-Hlne Berger, Jean-Franois Hochepied, and Stphane Daniele pp 11184–11189 DOI: 10.1021/ic102134w Supporting Info

Crystal Structures and Solution Properties of Discrete Complexes Composed of Saddle-Distorted Molybdenum(V)-Dodecaphenylporphyrins and Keggin-Type Heteropolyoxometalates Linked by Direct Coordination Atsutoshi Yokoyama, Takahiko Kojima, Kei Ohkubo, and Shunichi Fukuzumi pp 11190–11198 DOI: 10.1021/ic1019586 Supporting Info

Controlled Assembly of Ruthenium Complexes through ortho-Carborane Dithiolate and Polysulfide Ligands Jiurong Hu, Guifeng Liu, Qibai Jiang, Rui Zhang, Wei Huang, and Hong Yan pp 11199–11204 DOI: 10.1021/ic101817u Supporting Info

Solid-State 15N CPMAS NMR and Computational Analysis of Ligand Hapticity in Rhodium(η-diene) Poly(pyrazolyl)borate Complexes Riccardo Pettinari, Claudio Pettinari, Fabio Marchetti, Roberto Gobetto, Carlo Nervi, Michele R. Chierotti, Eric J. Chan, Brian W. Skelton, and Allan H. White pp 11205–11215 DOI: 10.1021/ic101830e Supporting Info

Aqueous Telluridoindate Chemistry: Water-Soluble Salts of Monomeric, Dimeric, and Trimeric In/Te Anions [InTe4]5−, [In2Te6]6−, and [In3Te10]11− Johanna Heine and Stefanie Dehnen pp 11216–11222 DOI: 10.1021/ic101881j Supporting Info

First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im Jeremy M. Smith and Jeffrey R. Long pp 11223–11230 DOI: 10.1021/ic1018407 Supporting Info

Heterometallic Architectures Based on the Combination of Heteroleptic Copper and Cobalt Complexes with Silver Salts Brandon Kilduff, Dmitry Pogozhev, Stphane A. Baudron, and Mir Wais Hosseini pp 11231–11239 DOI: 10.1021/ic1019235 Supporting Info

Photo-Induced Pyridine Substitution in cis-[Ru(bpy)2(py)2]Cl2: A Snapshot by Time-Resolved X-ray Solution Scattering Luca Salassa, Elisa Borfecchia, Tiziana Ruiu, Claudio Garino, Diego Gianolio, Roberto Gobetto, Peter J. Sadler, Marco Cammarata, Michael Wulff, and Carlo Lamberti pp 11240–11248 DOI: 10.1021/ic102021k Supporting Info

Ligand Effects in Bimetallic High Oxidation State Palladium Systems Alireza Ariafard, Christopher J. T. Hyland, Allan J. Canty, Manab Sharma, Nigel J. Brookes, and Brian F. Yates pp 11249–11253 DOI: 10.1021/ic1020912 Supporting Info

Volume Profile Analysis for the Reversible Binding of Superoxide to Form Iron(II)-Superoxo/Iron(III)-Peroxo Porphyrin Complexes Katharina Drr, Norbert Jux, Achim Zahl, Rudi van Eldik, and Ivana Ivanovi-Burmazovi pp 11254–11260 DOI: 10.1021/ic102092h Supporting Info

Issue 24

Trigonal Bi- and Monopyramidal Cobalt(II) Complexes of a Novel Guanidine-Based Tripodal Ligand Cassandra E. Searls, Scott T. Kleespies, Matthew L. Eppright, Sarina C. Schwartz, Glenn P. A. Yap, and Robert C. Scarrow pp 11261–11263 DOI: 10.1021/ic101612f Supporting Info

Tuning the Spin Ground State in Heterononanuclear Nickel(II)−Copper(II) Cylinders with a Triangular Metallacyclophane Core Marie-Claire Dul, Jess Ferrando-Soria, Emilio Pardo, Rodrigue Lescouzec, Yves Journaux, Rafael Ruiz-Garca, Joan Cano, Miguel Julve, Francesc Lloret, Oscar Fabelo, Jorge Pasn, and Catalina Ruiz-Prez pp 11264–11266 DOI: 10.1021/ic102037m Supporting Info

Nitrile-Rich Coordination Polymer 1∞{[Fe(CH3CN)4(pyrazine)](ClO4)2} Exhibiting a HS LS Transition Agata Białoska, Robert Bronisz, Kamilla Darowska, Krzysztof Drabent, Joachim Kusz, Miłosz Siczek, Marek Weselski, Maciej Zubko, and Andrew Ozarowski pp 11267–11269 DOI: 10.1021/ic102040y Supporting Info

Structure and Bonding of γ-B28: Is the High Pressure Form of Elemental Boron Ionic? Ulrich Hussermann and Arkady S. Mikhaylushkin pp 11270–11275 DOI: 10.1021/ic101266d

Facile Synthesis and Characterization of Phosphorescent Pt(NCN)X Complexes Zixing Wang, Eric Turner, Vanessa Mahoney, Sijesh Madakuni, Thomas Groy, and Jian Li pp 11276–11286 DOI: 10.1021/ic100740e Supporting Info

Kinetics and Mechanism of Peroxymonocarbonate Formation Ekaterina V. Bakhmutova-Albert, Huirong Yao, Daniel E. Denevan, and David E. Richardson pp 11287–11296 DOI: 10.1021/ic1007389

Synthesis and Characterization of Luminescent Bis-Cyclometalated PlatinumIV Complexes Dustin M. Jenkins and Stefan Bernhard pp 11297–11308 DOI: 10.1021/ic100761f Supporting Info

How Does the Synthesis Temperature Impact Hybrid Organic−Inorganic Molybdate Material Design? Rmi Dessapt, Daniel Kervern, Martine Bujoli-Doeuff, Philippe Deniard, Michel Evain, and Stphane Jobic pp 11309–11316 DOI: 10.1021/ic1007796 Supporting Info

The Quantum Cutting of Tb3+ in Ca6Ln2Na2(PO4)6F2 (Ln = Gd, La) under VUV−UV Excitation: with and without Gd3+ Mubiao Xie, Ye Tao, Yan Huang, Hongbin Liang, and Qiang Su pp 11317–11324 DOI: 10.1021/ic101028n

One Pot Synthesis of Heterometallic 3d−3d Azide Coordination Architectures: Effect of the Single-Ion Anisotropy Jiong-Peng Zhao, Bo-Wen Hu, Xiao-Feng Zhang, Qian Yang, M. S. El Fallah, J. Ribas, and Xian-He Bu pp 11325–11332 DOI: 10.1021/ic101089n Supporting Info

Modulating the Light Switch by 3MLCT-3ππ* State Interconversion Brigitte R. Spencer, Brian J. Kraft, Chris G. Hughes, Maren Pink, and Jeffrey M. Zaleski pp 11333–11345 DOI: 10.1021/ic1011617 Supporting Info

Influence of the Synthetic Conditions on the Structural Diversity of Extended Manganese−Oxalato−1,2-bis(4-pyridyl)ethylene Systems Urko Garca-Couceiro, Oscar Castillo, Javier Cepeda, Mnica Lanchas, Antonio Luque, Sonia Prez-Yez, Pascual Romn, and Daniel Vallejo-Snchez pp 11346–11361 DOI: 10.1021/ic100928t Supporting Info

Relationship between Cation Arrangement and Photocatalytic Activity for Sr−Al−Nb−O Double Perovskite Hironori Iwakura, Hisahiro Einaga, and Yasutake Teraoka pp 11362–11369 DOI: 10.1021/ic101208q

Polytypism, Disorder, and Anion Exchange Properties of Divalent Ion (Zn, Co) Containing Bayerite-Derived Layered Double Hydroxides Sylvia Britto and P. Vishnu Kamath pp 11370–11377 DOI: 10.1021/ic101177d Supporting Info

Establishment of Structure-Conductivity Relationship for Tris(2,2′-bipyridine) Ruthenium Ionic C60 Salts Jie Hong, Matthew P. Shores, and C. Michael Elliott pp 11378–11385 DOI: 10.1021/ic1013126 Supporting Info

Substitution of the Terminal Chloride Ligands of [Re6S8Cl6]4− with Triethylphosphine: Photophysical and Electrochemical Properties of a New Series of [Re6S8]2+ Based Clusters Lisa F. Szczepura, David L. Cedeo, Dean B. Johnson, Robert McDonald, Stanley A. Knott, Kristen M. Jeans, and Jessica L. Durham pp 11386–11394 DOI: 10.1021/ic101348h Supporting Info

Insights into Metal Borohydride and Aluminohydride Bonding: X-Ray and Neutron Diffraction Structures and a DFT and Charge Density Study of [Na(15-crown-5)][EH4] (E = B, Al) Peter Sirsch, Natascha L. N. Clark, Lenua Onu, Richard P. L. Burchell, Andreas Decken, G. Sean McGrady, Aziz Daoud-Aladine, and Matthias J. Gutmann pp 11395–11402 DOI: 10.1021/ic1014187 Supporting Info

Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes Haiyan An, Zhengbo Han, and Tieqi Xu pp 11403–11414 DOI: 10.1021/ic1013335 Supporting Info

Anion-Directed Self-Assembly in Coordination Networks: Architectural Control via Cooperative Noncovalent Interactions Behrouz Notash, Nasser Safari, and Hamid Reza Khavasi pp 11415–11420 DOI: 10.1021/ic101387c Supporting Info

Electronic Structure and Spectro-Structural Correlations of FeIIIZnII Biomimetics for Purple Acid Phosphatases: Relevance to DNA Cleavage and Cytotoxic Activity Rosely A. Peralta, Adailton J. Bortoluzzi, Bernardo de Souza, Rafael Jovito, Fernando R. Xavier, Ricardo A. A. Couto, Annelise Casellato, Faruk Nome, Andrew Dick, Lawrence. R. Gahan, Gerhard Schenk, Graeme R. Hanson, Flvia C. S. de Paula, Elene C. Pereira-Maia, Sergio de P. Machado, Patricia C. Severino, Claus Pich, Tiago Bortolotto, Hernn Terenzi, Eduardo E. Castellano, Ademir Neves, and Mark J. Riley pp 11421–11438 DOI: 10.1021/ic101433t Supporting Info

Thermodynamic, Electrochemical, High-Pressure Kinetic, and Mechanistic Studies of the Formation of Oxo FeIV−TAML Species in Water Delia-Laura Popescu, Melanie Vrabel, Ariane Brausam, Peter Madsen, Gabor Lente, Istvan Fabian, Alexander D. Ryabov, Rudi van Eldik, and Terrence J. Collins pp 11439–11448 DOI: 10.1021/ic1015109 Supporting Info

Hydrothermal Synthesis and Characterization of 2D M(II)-Quinate (M = Co,Zn) Metal−Organic Lattice Assemblies: Solid-State Solution Structure Correlation in M(II)-Hydroxycarboxylate Systems M. Menelaou, A. Konstantopai, N. Lalioti, C. P. Raptopoulou, V. Psycharis, A. Terzis, C. Mateescu, K. Tsarhopoulos, P. Rigas, and A. Salifoglou pp 11449–11462 DOI: 10.1021/ic1013945 Supporting Info

Stable and Tunable Phosphorescent Neutral Cyclometalated Au(III) Diaryl Complexes Jai Anand Garg, Olivier Blacque, Thomas Fox, and Koushik Venkatesan pp 11463–11472 DOI: 10.1021/ic101437h Supporting Info

Non-Centrosymmetric Tetrameric Assemblies of Tetramethylammonium Halides with Uranyl Salophen Complexes in the Solid State Massimo Cametti, Laura Ilander, Arto Valkonen, Martin Nieger, Maija Nissinen, Elisa Nauha, and Kari Rissanen pp 11473–11484 DOI: 10.1021/ic101547r Supporting Info

Recognition of Hg2+ Using Diametrically Disubstituted Cyclam Unit Prasenjit Mahato, Amrita Ghosh, Sukdeb Saha, Sandhya Mishra, Sanjiv K. Mishra, and Amitava Das pp 11485–11492 DOI: 10.1021/ic1014797 Supporting Info

Group 3 Metal Complexes of Radical-Anionic 2,2′-Bipyridyl Ligands Bryan N. Williams, Wenliang Huang, Kevin L. Miller, and Paula L. Diaconescu pp 11493–11498 DOI: 10.1021/ic101493k Supporting Info

Highly Uniform and Monodisperse Gd2O2S:Ln3+ (Ln = Eu, Tb) Submicrospheres: Solvothermal Synthesis and Luminescence Properties Yanhua Song, Hongpeng You, Yeju Huang, Mei Yang, Yuhua Zheng, Lihui Zhang, and Ning Guo pp 11499–11504 DOI: 10.1021/ic101608b Supporting Info

Rhombohedrally Distorted γ-Brasses Cr1−xFexGa Hyunjin Ko, Olivier Gourdon, Delphine Gout, Eun-Deok Mun, Srinivasa Thimmaiah, and Gordon J. Miller pp 11505–11515 DOI: 10.1021/ic101671k Supporting Info

A “Push−Pull” Mechanism for Heterolytic O−O Bond Cleavage in Hydroperoxo Manganese Porphyrins Ning Jin, Dorothe E. Lahaye, and John T. Groves pp 11516–11524 DOI: 10.1021/ic1015274 Supporting Info

Diruthenium Compounds Bearing Equatorial Fc-containing Ligands: Synthesis and Electronic Structure Darryl A. Boyd, Zhi Cao, You Song, Tian-Wei Wang, Phillip E. Fanwick, Robert J. Crutchley, and Tong Ren pp 11525–11531 DOI: 10.1021/ic101628z Supporting Info

Single-Source Materials for Metal-Doped Titanium Oxide: Syntheses, Structures, and Properties of a Series of Heterometallic Transition-Metal Titanium Oxo Cages Salvador Eslava, Mary McPartlin, Richard I. Thomson, Jeremy M. Rawson, and Dominic S. Wright pp 11532–11540 DOI: 10.1021/ic101687m Supporting Info

Defective Dicubane-like Tetranuclear Nickel(II) Cyanate and Azide Nanoscale Magnets Zurine Serna, Noelia De la Pinta, M. Karmele Urtiaga, Luis Lezama, Gotzon Madariaga, J. Modesto Clemente-Juan, Eugenio Coronado, and Roberto Corts pp 11541–11549 DOI: 10.1021/ic101970j Supporting Info

Synthesis of Triple-Stranded Complexes Using Bis(dipyrromethene) Ligands Zhan Zhang and David Dolphin pp 11550–11555 DOI: 10.1021/ic101694z Supporting Info

Multiple Silicon−Hydrogen Bond Activations at Adjacent Rhodium and Iridium Centers Md Hosnay Mobarok, Okemona Oke, Michael J. Ferguson, Robert McDonald, and Martin Cowie pp 11556–11572 DOI: 10.1021/ic1017196 Supporting Info

A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System Fang Kong, Xiang Xu, and Jiang-Gao Mao pp 11573–11580 DOI: 10.1021/ic101843g Supporting Info

New Three-Dimensional Porous Metal Organic Framework with Tetrazole Functionalized Aromatic Carboxylic Acid: Synthesis, Structure, and Gas Adsorption Properties Shu-Ming Zhang, Ze Chang, Tong-Liang Hu, and Xian-He Bu pp 11581–11586 DOI: 10.1021/ic1017467 Supporting Info

A Family of 3d-4f Octa-Nuclear [MnIII4LnIII4] Wheels (Ln = Sm, Gd, Tb, Dy, Ho, Er, and Y): Synthesis, Structure, and Magnetism Mengyuan Li, Yanhua Lan, Ayuk M. Ako, Wolfgang Wernsdorfer, Christopher E. Anson, Gernot Buth, Annie K. Powell, Zheming Wang, and Song Gao pp 11587–11594 DOI: 10.1021/ic101754g Supporting Info

Chemistry of the Oxophosphinidene Ligand. 2. Reactivity of the Anionic Complexes [MCp{P(O)R*}(CO)2]− (M = Mo, W; R* = 2,4,6-C6H2tBu3) Toward Electrophiles Based on Elements Different from Carbon. Mara Alonso, M. Angeles Alvarez, M. Esther Garca, Miguel A. Ruiz, Hayrullo Hamidov, and John C. Jeffery pp 11595–11605 DOI: 10.1021/ic101839k Supporting Info

High-Nuclearity Pt−Tl−Fe Complexes: Structural, Electrochemistry, and Spectroelectrochemistry Studies lvaro Dez, Julio Fernndez, Elena Lalinde, M. Teresa Moreno, and Sergio Snchez pp 11606–11618 DOI: 10.1021/ic102000s Supporting Info

Ordered Mesoporous MFe2O4 (M = Co, Cu, Mg, Ni, Zn) Thin Films with Nanocrystalline Walls, Uniform 16 nm Diameter Pores and High Thermal Stability: Template-Directed Synthesis and Characterization of Redox Active Trevorite Jan Haetge, Christian Suchomski, and Torsten Brezesinski pp 11619–11626 DOI: 10.1021/ic102052r Supporting Info

Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites Su-Yun Zhang, Chun-Li Hu, Chuan-Fu Sun, and Jiang-Gao Mao pp 11627–11636 DOI: 10.1021/ic1020737 Supporting Info

Functional Mesoporous Metal−Organic Frameworks for the Capture of Heavy Metal Ions and Size-Selective Catalysis Qian-Rong Fang, Da-Qian Yuan, Julian Sculley, Jian-Rong Li, Zheng-Bo Han, and Hong-Cai Zhou pp 11637–11642 DOI: 10.1021/ic101935f Supporting Info

Correction to Catenation of Loop-Containing 2D Layers with a 3D pcu Skeleton into a New Type of Entangled Framework Having Polyrotaxane and Polycatenane Character Chao Qin, Xin-Long Wang, En-Bo Wang, and Zhong-Min Su p 11643 DOI: 10.1021/ic101319e Supporting Info

Correction to Extended Organics−Inorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates Zhiming Zhang, Yangguang Li, Yonghui Wang, Yanfei Qi, and Enbo Wang p 11644 DOI: 10.1021/ic102289u Supporting Info